HomeMy WebLinkAboutNC0000396_J15040042report_20150823DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: 980-875-5245 Fax: 980-875-4349
Order Summary Report
Order Number: J15040042
Project Name: AB GW ASSESSMENT WATER
Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker
Customer Address: 200 CP and L Drive
Arden,NC 28704
Lab Contact: Mary Ann Ogle Phone: 980-875-5274
)eJ1 (t Mary Ann Ogle
Report Authorized By: ! ', 2015.04.22 16:55:28 pate: 4/22/2015
(Signature) 1%_1GY -04'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Page 1 of 39
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2015009340
2015009341
2015009342
2015009343
2015009344
5 Total Samples
Collected By
Sample Description
ASHEVILLE
31 -Mar -15 10:30 AM
Synterra
ABMW-04D
ASHEVILLE
31 -Mar -15 12:53 PM
Synterra
ABMW-04
ASHEVILLE
31 -Mar -15 4:05 PM
Synterra
MW -12D
ASHEVILLE
31 -Mar -15 9:20 AM
Synterra
Equipment Blank
ASHEVILLE
31 -Mar -15 9:20 AM
Synterra
Filter Blank
Page 2 of 39
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes No
All laboratory QA/QC requirements are acceptable. (] Yes ❑ No
Report Sections Included:
LU Job Summary Report
❑ Sample Identification
P/1 Technical Validation of Data Package
J❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Page 3 of 39
LVI Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
d❑ Chain of Custody
LVI Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 4/22/2015
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040042
Site: ABMW-04D
Collection Date: 31 -Mar -15 10:30 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 353.2
04/07/2015 12:20
Vendor Parameter
Complete
EPA 300.0
04/06/2015 21:12
NITRITE + NITRATE (COLORIMETRIC)
20
EPA 300.0
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 245.1
Chloride
12
mg/L
2
Sulfate
100
mg/L
2
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
04/02/2015 11:11
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
04/02/2015 11:11
MHALL3
Aluminum (AI)
0.021
mg/L
0.005
Barium (Ba)
0.083
mg/L
0.005
Boron (B)
1.06
mg/L
0.05
Iron (Fe)
8.01
mg/L
0.01
Manganese (Mn)
5.84
mg/L
0.005
Strontium (Sr)
0.209
mg/L
0.005
Zinc (Zn)
0.022
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
04/07/2015 08:58
MHH7131
Calcium (Ca)
31.7
mg/L
0.01
Magnesium (Mg)
12.9
mg/L
0.005
Potassium (K)
2.10
mg/L
0.1
Sodium (Na)
5.59
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.385
mg/L
0.005
Barium (Ba)
0.085
mg/L
0.005
Boron (B)
1.05
mg/L
0.05
Iron (Fe)
8.37
mg/L
0.01
Manganese (Mn)
6.07
mg/L
0.005
Strontium (Sr)
0.214
mg/L
0.005
Zinc (Zn)
0.021
mg/L
0.005
Page 4 of 39
Sample #: 2015009340
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
04/07/2015 12:20
BGN9034
20
EPA 300.0
04/06/2015 21:12
JAHERMA
20
EPA 300.0
04/06/2015 21:12
JAHERMA
1
EPA 245.1
04/07/2015 12:08
ACPAYNE
1
EPA 245.1
04/08/2015 11:02
ACPAYNE
1
EPA 200.7
04/02/2015 11:11
MHALL3
1
EPA 200.7
04/02/2015 11:11
MHALL3
1
EPA 200.7
04/02/2015 11:11
MHALL3
1
EPA 200.7
04/02/2015 11:11
MHALL3
1
EPA 200.7
04/02/2015 11:11
MHALL3
1
EPA 200.7
04/02/2015 11:11
MHALL3
1
EPA 200.7
04/02/2015 11:11
MHALL3
1
EPA 200.7
04/02/2015 12:02
MHALL3
1
EPA 200.7
04/02/2015 12:02
MHALL3
1
EPA 200.7
04/02/2015 12:02
MHALL3
1
EPA 200.7
04/02/2015 12:02
MHALL3
1
EPA 200.7
04/07/2015 08:58
MHH7131
1
EPA 200.7
04/07/2015 08:58
MHH7131
1
EPA 200.7
04/07/2015 08:58
MHH7131
1
EPA 200.7
04/07/2015 08:58
MHH7131
1
EPA 200.7
04/07/2015 08:58
MHH7131
1
EPA 200.7
04/07/2015 08:58
MHH7131
1
EPA 200.7
04/07/2015 08:58
MHH7131
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040042
Site: ABMW-04D
Collection Date: 31 -Mar -15 10:30 AM
Analyte
Result
DISSOLVED METALS BY ICP -MS
Sample #:
Antimony (Sb)
< 1
Arsenic (As)
1.52
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
66.1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
1.15
Nickel (Ni)
2.41
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
Arsenic (As)
2.15
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
67.3
Copper (Cu)
<1
Lead (Pb)
< 1
Molybdenum (Mo)
1.22
Nickel (Ni)
2.50
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
0.789
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
ug/L
TDS
240
Total Carbon
04/17/2015 12:07
TOC
0.618
TOTAL SUSPENDED SOLIDS
1
TSS
5.0
Page 5 of 39
ug/L
1
1
Sample #:
2015009340
JAHERMA
ug/L
1
1
Matrix:
GW WW
JAHERMA
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
04/17/2015 12:07
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:07
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:07
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:07
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:07
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:07
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:07
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:07
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:07
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:07
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:07
DJSULL1
ug/L
0.2
1
EPA 200.8
04/17/2015 12:07
DJSULL1
ug/L
0.3
1
EPA 200.8
04/17/2015 12:07
DJSULL1
ug/L
1
1
EPA 200.8
04/16/2015 13:34
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:34
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:34
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:34
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:34
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:34
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:34
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:34
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:34
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:34
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:34
JAHERMA
ug/L
0.2
1
EPA 200.8
04/16/2015 13:34
JAHERMA
ug/L
0.3
1
EPA 200.8
04/16/2015 13:34
JAHERMA
Vendor Method
V_SHEALY
Vendor Method
V_ELE1
mg/L
25
1
SM2540C
04/06/201514:18
AGIBBS5
mg/L
0.1
1
SM5310C/EPA9060A
04/08/201512:53
TJA7067
mg/L
5
1
SM2540D
04/03/2015 08:15
AGIBBS5
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040042
Site: ABMW-04
Collection Date: 31 -Mar -15 12:53 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 353.2
04/07/2015 12:23
Vendor Parameter
Complete
EPA 300.0
04/06/2015 21:30
NITRITE + NITRATE (COLORIMETRIC)
50
EPA 300.0
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 245.1
Chloride
12
mg/L
2
Sulfate
260
mg/L
5
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
04/02/2015 11:00
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
04/02/2015 11:00
MHALL3
Aluminum (AI)
0.042
mg/L
0.005
Barium (Ba)
0.301
mg/L
0.005
Boron (B)
3.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.146
mg/L
0.005
Strontium (Sr)
4.10
mg/L
0.005
Zinc (Zn)
0.037
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
04/07/2015 09:02
MHH7131
Calcium (Ca)
150
mg/L
0.1
Magnesium (Mg)
45.8
mg/L
0.005
Potassium (K)
24.4
mg/L
0.1
Sodium (Na)
42.6
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.792
mg/L
0.005
Barium (Ba)
0.315
mg/L
0.005
Boron (B)
3.08
mg/L
0.05
Iron (Fe)
0.328
mg/L
0.01
Manganese (Mn)
0.147
mg/L
0.005
Strontium (Sr)
4.21
mg/L
0.005
Zinc (Zn)
0.039
mg/L
0.005
Page 6 of 39
Sample #: 2015009341
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
04/07/2015 12:23
BGN9034
20
EPA 300.0
04/06/2015 21:30
JAHERMA
50
EPA 300.0
04/06/2015 21:30
JAHERMA
1
EPA 245.1
04/07/2015 12:11
ACPAYNE
1
EPA 245.1
04/08/2015 11:05
ACPAYNE
1
EPA 200.7
04/02/2015 11:00
MHALL3
1
EPA 200.7
04/02/2015 11:00
MHALL3
1
EPA 200.7
04/02/2015 11:00
MHALL3
1
EPA 200.7
04/02/2015 11:00
MHALL3
1
EPA 200.7
04/02/2015 11:00
MHALL3
1
EPA 200.7
04/02/2015 11:00
MHALL3
1
EPA 200.7
04/02/2015 11:00
MHALL3
10
EPA 200.7
04/02/2015 11:55
MHALL3
1
EPA 200.7
04/02/2015 11:55
MHALL3
1
EPA 200.7
04/02/2015 11:55
MHALL3
1
EPA 200.7
04/02/2015 11:55
MHALL3
1
EPA 200.7
04/07/2015 09:02
MHH7131
1
EPA 200.7
04/07/2015 09:02
MHH7131
1
EPA 200.7
04/07/2015 09:02
MHH7131
1
EPA 200.7
04/07/2015 09:02
MHH7131
1
EPA 200.7
04/07/2015 09:02
MHH7131
1
EPA 200.7
04/07/2015 09:02
MHH7131
1
EPA 200.7
04/07/2015 09:02
MHH7131
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040042
Site: ABMW-04
Collection Date: 31 -Mar -15 12:53 PM
Analyte
Result
DISSOLVED METALS BY ICP -MS
Sample #:
Antimony (Sb)
6.49
Arsenic (As)
441
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper(Cu)
1.79
Lead (Pb)
< 1
Molybdenum (Mo)
673
Nickel (Ni)
1.58
Selenium (Se)
6.99
Thallium (TI) Low Level
2.54
Vanadium (V) Low Level
66.7
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
6.22
Arsenic (As)
447
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
32.6
Cobalt (Co)
1.57
Copper (Cu)
4.50
Lead (Pb)
< 1
Molybdenum (Mo)
675
Nickel (Ni)
6.93
Selenium (Se)
6.75
Thallium (TI) Low Level
2.81
Vanadium (V) Low Level
70.8
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
ug/L
TDS
800
Total Carbon
04/17/2015 12:11
TOC
0.780
TOTAL SUSPENDED SOLIDS
1
TSS
12
Page 7 of 39
ug/L
1
1
Sample #:
2015009341
JAHERMA
ug/L
1
1
Matrix:
GW WW
JAHERMA
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
04/17/2015 12:11
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:11
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:11
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:11
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:11
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:11
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:11
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:11
DJSULL1
ug/L
1
20
EPA 200.8
04/17/2015 12:11
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:11
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:11
DJSULL1
ug/L
0.2
1
EPA 200.8
04/17/2015 12:11
DJSULL1
ug/L
0.3
1
EPA 200.8
04/17/2015 12:11
DJSULL1
ug/L
1
1
EPA 200.8
04/16/2015 13:38
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:38
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:38
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:38
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:38
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:38
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:38
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:38
JAHERMA
ug/L
5
5
EPA 200.8
04/16/2015 13:38
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:38
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:38
JAHERMA
ug/L
0.2
1
EPA 200.8
04/16/2015 13:38
JAHERMA
ug/L
0.3
1
EPA 200.8
04/16/2015 13:38
JAHERMA
Vendor Method
V_SHEALY
Vendor Method
V_ELE1
mg/L
25
1
SM2540C
04/06/201514:18
AGIBBS5
mg/L
0.1
1
SM5310C/EPA9060A
04/08/201512:53
TJA7067
mg/L
5
1
SM2540D
04/03/2015 08:15
AGIBBS5
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040042
Site: MW -12D
Collection Date: 31 -Mar -15 4:05 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
BGN9034
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 300.0
04/07/2015 09:07
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 245.1
04/07/2015 12:13
Nitrite + Nitrate (Colorimetric)
1.4
mg-N/L
0.01
INORGANIC IONS BY IC
04/02/2015 11:15
MHALL3
1 EPA 200.7
Chloride
8.0
mg/L
0.1
Sulfate
7.2
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
04/02/2015 11:15
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
MHALL3
1 EPA 200.7
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1 EPA 200.7
04/02/2015 11:43
MHALL3
Aluminum (AI)
0.045
mg/L
0.005
Barium (Ba)
0.061
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.073
mg/L
0.01
Manganese (Mn)
0.463
mg/L
0.005
Strontium (Sr)
0.027
mg/L
0.005
Zinc (Zn)
0.043
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
3.64
mg/L
0.01
Magnesium (Mg)
2.45
mg/L
0.005
Potassium (K)
1.37
mg/L
0.1
Sodium (Na)
7.66
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.384
mg/L
0.005
Barium (Ba)
0.063
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.433
mg/L
0.01
Manganese (Mn)
0.480
mg/L
0.005
Strontium (Sr)
0.024
mg/L
0.005
Zinc (Zn)
0.037
mg/L
0.005
Page 8 of 39
Sample #: 2015009342
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
04/07/2015 12:34
BGN9034
1 EPA 300.0
04/07/2015 09:07
JAHERMA
1 EPA 300.0
04/07/2015 09:07
JAHERMA
1 EPA 245.1
04/07/2015 12:13
ACPAYNE
1 EPA 245.1
04/08/2015 11:07
ACPAYNE
1 EPA 200.7
04/02/2015 11:15
MHALL3
1 EPA 200.7
04/02/2015 11:15
MHALL3
1 EPA 200.7
04/02/2015 11:15
MHALL3
1 EPA 200.7
04/02/2015 11:15
MHALL3
1 EPA 200.7
04/02/2015 11:15
MHALL3
1 EPA 200.7
04/02/2015 11:15
MHALL3
1 EPA 200.7
04/02/2015 11:15
MHALL3
1 EPA 200.7
04/02/2015 11:43
MHALL3
1 EPA 200.7
04/02/2015 11:43
MHALL3
1 EPA 200.7
04/02/2015 11:43
MHALL3
1 EPA 200.7
04/02/2015 11:43
MHALL3
1 EPA 200.7
04/07/2015 09:06
MHH7131
1 EPA 200.7
04/07/2015 09:06
MHH7131
1 EPA 200.7
04/07/2015 09:06
MHH7131
1 EPA 200.7
04/07/2015 09:06
MHH7131
1 EPA 200.7
04/07/2015 09:06
MHH7131
1 EPA 200.7
04/07/2015 09:06
MHH7131
1 EPA 200.7
04/07/2015 09:06
MHH7131
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040042
Site: MW -12D
Collection Date: 31 -Mar -15 4:05 PM
Analyte
Result
DISSOLVED METALS BY ICP -MS
Sample #:
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
10.7
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
1.88
Nickel (Ni)
4.66
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
3.35
Cobalt (Co)
11.0
Copper (Cu)
<1
Lead (Pb)
< 1
Molybdenum (Mo)
2.09
Nickel (Ni)
5.90
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
0.388
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
ug/L
TDS
56
Total Carbon
04/17/2015 12:16
TOC
0.615
TOTAL SUSPENDED SOLIDS
1
TSS
5.0
Page 9 of 39
ug/L
1
1
Sample #:
2015009342
JAHERMA
ug/L
1
1
Matrix:
GW WW
JAHERMA
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
04/17/2015 12:16
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:16
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:16
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:16
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:16
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:16
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:16
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:16
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:16
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:16
DJSULL1
ug/L
1
1
EPA 200.8
04/17/2015 12:16
DJSULL1
ug/L
0.2
1
EPA 200.8
04/17/2015 12:16
DJSULL1
ug/L
0.3
1
EPA 200.8
04/17/2015 12:16
DJSULL1
ug/L
1
1
EPA 200.8
04/16/2015 13:43
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:43
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:43
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:43
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:43
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:43
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:43
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:43
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:43
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:43
JAHERMA
ug/L
1
1
EPA 200.8
04/16/2015 13:43
JAHERMA
ug/L
0.2
1
EPA 200.8
04/16/2015 13:43
JAHERMA
ug/L
0.3
1
EPA 200.8
04/16/2015 13:43
JAHERMA
Vendor Method
V_SHEALY
Vendor Method
V_ELE1
mg/L
25
1
SM2540C
04/06/201514:18
AGIBBS5
mg/L
0.1
1
SM5310C/EPA9060A
04/08/201512:53
TJA7067
mg/L
5
1
SM2540D
04/03/2015 08:15
AGIBBS5
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040042
Site: Equipment Blank
Collection Date: 31 -Mar -15 9:20 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 300.0
04/06/2015 22:24
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 245.1
04/07/2015 12:15
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
04/02/2015 12:11
MHALL3
1 EPA 200.7
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
04/07/2015 09:18
MHH7131
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
MHH7131
1 EPA 200.7
04/07/2015 09:18
Calcium (Ca)
< 0.01
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
04/16/2015 13:48
JAHERMA
Aluminum (AI)
0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Page 10 of 39
Sample #: 2015009343
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
04/07/2015 12:26
BGN9034
1 EPA 300.0
04/06/2015 22:24
JAHERMA
1 EPA 300.0
04/06/2015 22:24
JAHERMA
1 EPA 245.1
04/07/2015 12:15
ACPAYNE
1 EPA 200.7
04/02/2015 12:11
MHALL3
1 EPA 200.7
04/02/2015 12:11
MHALL3
1 EPA 200.7
04/02/2015 12:11
MHALL3
1 EPA 200.7
04/02/2015 12:11
MHALL3
1 EPA 200.7
04/07/2015 09:18
MHH7131
1 EPA 200.7
04/07/2015 09:18
MHH7131
1 EPA 200.7
04/07/2015 09:18
MHH7131
1 EPA 200.7
04/07/2015 09:18
MHH7131
1 EPA 200.7
04/07/2015 09:18
MHH7131
1 EPA 200.7
04/07/2015 09:18
MHH7131
1 EPA 200.7
04/07/2015 09:18
MHH7131
1 EPA 200.8
04/16/2015 13:48
JAHERMA
1 EPA 200.8
04/16/2015 13:48
JAHERMA
1 EPA 200.8
04/16/2015 13:48
JAHERMA
1 EPA 200.8
04/16/2015 13:48
JAHERMA
1 EPA 200.8
04/16/2015 13:48
JAHERMA
1 EPA 200.8
04/16/2015 13:48
JAHERMA
1 EPA 200.8
04/16/2015 13:48
JAHERMA
1 EPA 200.8
04/16/2015 13:48
JAHERMA
1 EPA 200.8
04/16/2015 13:48
JAHERMA
1 EPA 200.8
04/16/2015 13:48
JAHERMA
1 EPA 200.8
04/16/2015 13:48
JAHERMA
1 EPA 200.8
04/16/2015 13:48
JAHERMA
1 EPA 200.8
04/16/2015 13:48
JAHERMA
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040042
Page 11 of 39
Site: Equipment Blank
Sample #: 2015009343
Collection Date: 31 -Mar -15 9:20 AM
Matrix: GW WW
Analyte
Result
Units Qualifiers
RDL
DF
Method Analysis Date/Time
Analyst
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
< 25
mg/L
25
1
SM2540C 04/06/2015 14:18
AGIBBS5
Total Carbon
TOC
0.133
mg/L
0.1
1
SM5310C/EPA9060A 04/08/201512:53
TJA7067
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
1
SM2540D 04/03/2015 08:15
AGIBBS5
Certificate of Laboratory Analysis Page 12 of 39
This report shall not be reproduced, except in full.
Order # J15040042
Site: Filter Blank
Collection Date: 31 -Mar -15 9:20 AM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 245.1
04/08/2015 11:09
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1
EPA 200.7
04/02/2015 11:19
Aluminum (Al)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
DISSOLVED METALS BY ICP -MS
1
EPA 200.8
04/17/2015 11:49
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015009344
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
04/08/2015 11:09
ACPAYNE
1
EPA 200.7
04/02/2015 11:19
MHALL3
1
EPA 200.7
04/02/2015 11:19
MHALL3
1
EPA 200.7
04/02/2015 11:19
MHALL3
1
EPA 200.7
04/02/2015 11:19
MHALL3
1
EPA 200.7
04/02/2015 11:19
MHALL3
1
EPA 200.7
04/02/2015 11:19
MHALL3
1
EPA 200.7
04/02/2015 11:19
MHALL3
1
EPA 200.8
04/17/2015 11:49
DJSULL1
1
EPA 200.8
04/17/2015 11:49
DJSULL1
1
EPA 200.8
04/17/2015 11:49
DJSULL1
1
EPA 200.8
04/17/2015 11:49
DJSULL1
1
EPA 200.8
04/17/2015 11:49
DJSULL1
1
EPA 200.8
04/17/2015 11:49
DJSULL1
1
EPA 200.8
04/17/2015 11:49
DJSULL1
1
EPA 200.8
04/17/2015 11:49
DJSULL1
1
EPA 200.8
04/17/2015 11:49
DJSULL1
1
EPA 200.8
04/17/2015 11:49
DJSULL1
1
EPA 200.8
04/17/2015 11:49
DJSULL1
1
EPA 200.8
04/17/2015 11:49
DJSULL1
1
EPA 200.8
04/17/2015 11:49
DJSULL1
e
Page 13 of 39
Element One Ince
6319-D Carolina Beach Rd.
Wilmington, NC 28412
Phone: 910 793-0128
Fau: 910 792-6853
e1 lab@e1 labs --
One
REPORT OF ANALYSES
Duke Energy April 3, 2015
Laboratory Services Client Project Name AB GW Assessment Water — Asheville
13339 Hagers Ferry Road Bld. MG03A Client Project Number J15040042
Huntersville, NC 28078 PO Number
Sample Matrix
GW WW
Sample Type
Grab
Date Received
04/03/2015
Date Analyzed
04/03/2015
Method
SM 4500 S2- D
Time Received
1155
Delivered by
FedEx
Received by
JRC
eOne ID
Duke Energy ID
Parameter
Result
Unit
Dil
DL Date
Time
Sampled
Sampled
24432-1
ABMW-04D
Sulfide
< 0.1
mg/L
1
0.1 03/31/15
1030
24432-2
ABMW-04
Sulfide
< 0.1
mg/L
1
0.1 03/31/15
1253
24432-3
MW -12D
Sulfide
< 0.1
mg/L
1
0.1 03/31/15
1605
24432-4
Equipment Blank
Sulfide
< 0.1
mg/L
1
0.1 03/31/15
0920
Ken mith, Laboratory Director
24432 Duke Report Packet Compiled bye-
NC Certifications: DW 37788 and DWQ DENR 604
Page 14 of 39
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Page 14 of 39
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e ementOne SAMPLE SUBMISSION FORM
TAT 7 BD
Hold Time Expiration 04.07.15 @ 0920 AM
Client: Duke Energy
LIMS No J15040042
Project I D AB GW Assessment Water - Asheville
Lab Mage U42
Analysis Due Date 04.03.15
Report Due Date 04.15.15
Date Rec: 04.03.15
Time Rec: 1155_
Rec By JRC
H >9 Yes No
Tem <_ 6°C Yes No
Ref. Method:
SM4500 S2 D
If No, Record
If No, Record
Sample Identification & Collection Information
Lab ID
Client ID Collection Date
Collection Time
Analysis Requested
1
ABMW-04D 03.31.15
1030 AM
Sulfide
03.3 1 15
"I'�M 11 153
Sulfide
3
MW -12D 03.31.15
1605 XM
Sulfide
4
Equipment Blank 03.31.��
q p ment Bla15
0920 AM
Ifide
Sulfide
u
The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
NOTE for Sulfide at 100 pg/L spike the sample to render the final spike concentration at — 500 pg/L
All AB Groundwater Assessment jobs need a RL of 0.1
SS Page 1 1 Prep By / Date k�'5 �a
SS by Labeled By / Date jP- `f- 3 <( S-
4/3/2015
4/3/2015 2:04:13 PM ID Verification By /Date(. 3- 1
Page 16 of 39
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVELLuql
5
Lab ID#
24432
Na2S•9H2O Lot #
40721
MAX ALIQUOT
10.00'
Date: 4.3.15
STANDARD conc(ppm)
X
Time Analysis Begun 1430`
Cal Std Lot: WC2-68-3
10
Time Analysis Ended 1448'
QC Std Lot: WC2-68-4
Analyst: KLS
STD ABSORPTION0900
Y
ugX
STD
SOLUTION
rAB
0.800
07000.00
00
1.00
2;50
5.00
7:500.614
10.00
0.225
0.417
1 0.763
6800'
0 500Y
°°
0.400
030°
0.200
0100
0.000
....:200
W
600
600
000
1600 1100
-:
SAMPLE SAMP
I.D. ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Slope',
ALI in mL
TAKEN
0.076661538
RESULTS
ug/mL
Correlation
LESS THAN
% SPK REC
0.998114218';
SPIKE
LEVEL
0.00
0.00
-0.4453
10
10
10
<
0.00
1.00
0.089
0.7408
10
10
10
<
74%
1.00
5.00
0.216
2.4723
10
10
10
0.247
99%
2.50
5.00
0.412
5.1445
10
10
10
0.514
103%
5.00
7.50
0.594
7.6259
10
10
10
0.763
102%
7.50
10.00
0.748
9.7255
10
10
10
0.973
97%
10.00
24432-1
0.004
-0.4180
10
10
10
24432-1 spk
0.345
4.2311
10
10
10
0.423
85%
5.0
24432-2
0.008
-0.3635
10
10
10
24432-2 s k
0.374
4.6265
10
10
10
0.463
93%
5.0
24432-3
0.007
-0.3771
10
10
10%
24432-3 s k
0.368
4.5447
10
10
10
0.454
91%
5.0
24432-4
0.001
-0.4589
10
10
10
24432-4 spk
0.421
5.2672
10
10
10
0.527
105%
5.0
Purchased Std
0.667
8.6211
10
10
10
0.862
108%
8.0
Blank
0
0.0000
10
10
10
<
QC
0.412
5.1445
10
10
10
0.514
103%
5.0
Submitted for QA/QC-
Date:
4.3.15
By: (Print)
KLS
(sig
SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - Asheville
Project Number:J15040042
Lot Number:QD03018
Date Completed:04/16/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
* QD0301 8*
Shealy Environmental Services, Inc. Page: 1 of 12
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QD03018
Project Name: AB GW Assessment Water - Asheville
Project Number: J15040042
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QD03018
Project Name: AB GW Assessment Water - Asheville
Project Number: J15040042
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2015009340
Aqueous
03/31/20151030
04/03/2015
002
2015009341
Aqueous
03/31/20151253
04/03/2015
003
2015009342
Aqueous
03/31/20151605
04/03/2015
004
2015009343
Aqueous
03/31/2015 0920
04/03/2015
(4 samples)
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SHEALY ENVIRONMENTAL SERVICES, INC.
(8 detections)
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Executive Summary
Duke Energy
Lot Number: QD03018
Project Name: AB GW Assessment Water - Asheville
Project Number: J15040042
Sample Sample ID
Matrix Parameter Method Result Q
Units
Page
001
2015009340
Aqueous Alkalinity SM 2320B-
50
mg/L
5
001
2015009340
Aqueous Bicarbonate Alkalinity SM 2320B-
50
mg/L
5
001
2015009340
Aqueous Methane RSK - 175
44
ug/L
6
002
2015009341
Aqueous Alkalinity SM 2320B-
340
mg/L
7
002
2015009341
Aqueous Bicarbonate Alkalinity SM 2320B-
340
mg/L
7
002
2015009341
Aqueous Methane RSK - 175
33
ug/L
8
003
2015009342
Aqueous Alkalinity SM 2320B-
13
mg/L
9
003
2015009342
Aqueous Bicarbonate Alkalinity SM 2320B-
13
mg/L
9
(8 detections)
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QD03018-001
Description: 2015009340 Matrix: Aqueous
Date Sampled:03/31/2015 1030 Project Name: AB GW Assessment Water -
Date Received: 04/03/2015 Project Number: J15040042
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
2
(Alkalinity) SM 2320B-2011
1 04/09/2015 1152
HMA 72090
1
(Bicarbonate ) SM 2320B-2011
1 04/09/2015 1152
HMA
1
(Carbonate Al) SM 2320B-2011
1 04/09/2015 1152
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
50
10
mg/L
2
Bicarbonate Alkalinity
SM 2320B-20
50
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QD03018-001
Description: 2015009340 Matrix: Aqueous
Date Sampled:03/31/2015 1030 Project Name: AB GW Assessment Water -
Date Received: 04/03/2015 Project Number: J15040042
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 04/08/2015 1337 DCS 72089
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 44 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QD03018-002
Description: 2015009341 Matrix: Aqueous
Date Sampled:03/31/2015 1253 Project Name: AB GW Assessment Water -
Date Received: 04/03/2015 Project Number: J15040042
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
2
(Alkalinity) SM 2320B-2011
1 04/09/2015 1214
HMA 72090
1
(Bicarbonate ) SM 2320B-2011
1 04/09/2015 1214
HMA
1
(Carbonate Al) SM 2320B-2011
1 04/09/2015 1214
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
340
10
mg/L
2
Bicarbonate Alkalinity
SM 2320B-20
340
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QD03018-002
Description: 2015009341 Matrix: Aqueous
Date Sampled:03/31/2015 1253 Project Name: AB GW Assessment Water -
Date Received: 04/03/2015 Project Number: J15040042
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 04/08/2015 1347 DCS 72089
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 33 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QD03018-003
Description: 2015009342 Matrix: Aqueous
Date Sampled:03/31/2015 1605 Project Name: AB GW Assessment Water -
Date Received: 04/03/2015 Project Number: J15040042
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
2
(Alkalinity) SM 2320B-2011
1 04/09/2015 1218
HMA 72090
1
(Bicarbonate ) SM 2320B-2011
1 04/09/2015 1218
HMA
1
(Carbonate Al) SM 2320B-2011
1 04/09/2015 1218
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
13
10
mg/L
2
Bicarbonate Alkalinity
SM 2320B-20
13
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QD03018-003
Description: 2015009342 Matrix: Aqueous
Date Sampled:03/31/2015 1605 Project Name: AB GW Assessment Water -
Date Received: 04/03/2015 Project Number: J15040042
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 04/08/2015 1400 DCS 72089
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QD03018-004
Description: 2015009343 Matrix: Aqueous
Date Sampled:03/31/2015 0920 Project Name: AB GW Assessment Water -
Date Received: 04/03/2015 Project Number: J15040042
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
2
(Alkalinity) SM 2320B-2011
1 04/09/2015 1223
HMA 72090
1
(Bicarbonate ) SM 2320B-2011
1 04/09/2015 1223
HMA
1
(Carbonate Al) SM 2320B-2011
1 04/09/2015 1223
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
2
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QD03018-004
Description: 2015009343 Matrix: Aqueous
Date Sampled:03/31/2015 0920 Project Name: AB GW Assessment Water -
Date Received: 04/03/2015 Project Number: J15040042
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 04/08/2015 1410 DCS 72089
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018
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Inorganic non-metals - Ii
Sample ID: QQ72090-001 Matrix: Aqueous
Batch: 72090
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 04/09/20151141
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018
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Inorganic non-metals - LCS
Sample ID: QQ72090-002 Matrix: Aqueous
Batch: 72090
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 96 1 96 90-110 04/09/20151147
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018
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Inorganic non-metals - MS
Sample ID: QD03018-001 MS Matrix: Aqueous
Batch: 72090
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 50 100 130 1 84 70-130 04/09/20151200
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018
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Inorganic non-metals - MSD
Sample ID: QD03018-001MD Matrix: Aqueous
Batch: 72090
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity 50 100 140 1 86 1.5 70-130 20 04/09/20151206
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1
Methane - MB
Sample ID: QQ72089-001 Matrix: Aqueous
Batch: 72089
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 04/08/2015 0943
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1
Methane - LCS
Sample ID: QQ72089-002 Matrix: Aqueous
Batch: 72089
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 150 1 97 70-130 04/08/2015 0920
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1
Methane - LCSD
Sample ID: QQ72089-003 Matrix: Aqueous
Batch: 72089
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 150 1 98 0.84 70-130 30 04/08/2015 0932
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sfrcaly CmirowntmW Senria5, lef, lkagc I of
Dmum.nl Jd umbev l' -AD -Q 16 Itepl arts Derr 07+15114
Rke�Slun Alunhes 15 Eifcriivc Delo 1U07ii4
Sample Receipt Checklist (SRC)
Client. . i,._. �r oaler Inspected hy1date: Nvc-x,.rQ�-+ \71i. Lot tf:
Means ofreccipt: ❑ SLS] ❑ Client ❑ UPS FedEac ❑ Airborri . Exp ❑ Other
Yee LJ I Nil L4
1. Wcrc coLody sus present oft the coolej*
Yes Ll I No ❑ I NA_kL
12. If custody seals were present, wem theX intact and tmbrokcr►7
(con-ected) temperature on erature uprc.
CoDlcr D/OriSinai telrKrature upon ItlL7m6p,erired a
. +ccip#
i� Ll_L- Ile d f -PC f � plc I F €"C
Mdhod: ❑ Temperature lanikagainst Bottles Ili Gun ID: 44 IR Gun Correction Factor; P-
Method of cool"' Wet lee ❑ Blue Iee ❑ Dry [cc Xone
Yes ❑l�Fo ❑ NA �`
3. Iftelrlperalure of any cooler exceeded 6.0°C, was Project Manager notified?
PNI noWied by SRC, phone, note (circle one), other
(For wulers received via commercial courier, PMate m he notiftod
jmt7iuli3tely',)
Yes Na 0 NA ❑
4. Is the conmerclal courier's packing slip shed to this f4rrn?
Yes ZI Na ❑
5. W= MpeT cltst , procedures relin uishedlrcccivcd follow rztV
Yc* pip ❑ NA ❑
5 a Were samples relinquished by client to commercial courier?
YeaNo Ll6.
Wcrc sairiplc IDs I6MA ort the Cf?C
Yes 51 140 U
7. Wort sample IDs lista on all sample. -containers?
Yes No ❑
$. Was ctollaeti€ln date & time Iist,cd on the CXK7
Yes 9�No ❑
9. 10plas collection date & time listed on all sample eomiiners?
Yes Ata ❑
10. Did all container labc1 in.l rrnalicnl 117 [trate, time ree with the COC7
Yes 01140 ❑
11- Were tests to be pert&mcd listed an the COC?
Yep Na ❑
12. Did all samples arrive in the proper coataieer�; for each test?
YN Alo ❑
13. Did all containers arriva in gwd col clition (unbroken. lids on, a%.)7
Y" El No ❑
14. Was adequate sample volume avail calalc'?
Yes [71 No,15-
car
Werc all samples rmeived Within 1L the balding, time or 48 hours, whichever
zriea fir-KO
Y ❑ rlo
16- Were any sam les cont'aineTs missin
Yes ❑ Ala
1.7. Were there aTgr. tx4e�; same ler. nat listed on COC?
Yes 4a NA
18. Were bubbks re nt` cR-siz+c" W'or 6rrim in diameter) in any VOA vials'1
Yes ❑ No ❑ NA
19. Were all metal RIO&QVINUnutrient &U11 les rer,:ehrod ata H of ---2?
Yes [l No a NA Vr
20. Were all cyanide and,+or sulfide spm les received ata pH ? 12?
Yes ❑ No ❑ NAW
21. Were all applicable R EBP1 KN+cyanidelphenol (<02ing/L) samples free of
residual chlorine?
Yes ❑IVo ❑ NA
22. Were rollectim temperature. documented on the C)[ c for NC sarrl les?
Yes E] lila ❑ NA
3. Were. client remarlcslrequests (i.e. reque.%ted diltlt ons, hdS+MSD dcsignations,
etc_..) correctly transcribed from the (,(X' into the colmncnt sc+c=lion in LIMS?
Yss NO
24- Was the quatc nl3rrl} er used taken from the container label?
Sample Pnemrvation (Must be completed for any yarn ic(s) incorrectly pre rved or with heads ce,)
Samples) were reccivud incorrectly preserved and were adjilsted
acwrdin 1 In t;a rl le receiving With )1RSQ4,HN0_i,HCl Na0H) ut4 g SR #
-Sample(s)
were reo6vcd with lubbles>6 r1in in diameter.
Sam le(s)
vem received with.'FRC~ -0-2 m `l. If 421 is No
SC Drinking trier Protect Sarnplc�s) pH vuriflud to be > 2 by 17uste
Sara le(s) v%,erc nD m civlxl til a pH c1f'c2 and v.crc adGustcd a.c )dingly using SRA
I Stullple labels applied by: lverified b : Date:
(,Olilllnent5;
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1
! ---.- --- ----- - - - - -------Duica Ener-- Analyticallaboratory r I 'r••Ana{,-„al Laborat
Duke Energy
° Nail Cade MG03AZ lauilding 74051 ! iOrder A�! 1i atrix Gw WW
Analytical Laboratory 13359 Fingers Ferry NO { G y��
I Chafn Of Custody Hantelnvllle, N. c. 20079 i f �,
(7ga) 075.5245 ; iLo ® Dela s Timed •
Sample Log �Rit. �' �' 4_'"
° ._._ .......-_._._._._Palog4b]B755U30._._.__ I
Protact Name AB GW Assessment water Pheee Na: *
Element 1 �'
I Cooker TemR1CL.-_..
v Useoni~--}------------------------. ._.
ewes Crle r.a F— NC
5C
SAMPLE PRa(if3l1M
Ground Water NPDES_
�---
Drinking Water DST_
RCRA Waste _
DISTRIBUTION
ORIGINAL to LAB, COPY 1q CLIENT
!
o ° . COC REV DATE 112212U15
Cllertt Ad
Faa No:
PO 1142133
on 1045 urnj
b uftflltered
{1 uttered
Unit;
Activity ro:
° Preservative Ise Ice Ice hl s2 W Ice ,
SHEALY
airier Volume (mL) 2000 nom{ 300 125 500 500 5007HDPE
Container Type PET glass PET PET PET PET ` HDP
ry 114zubS )'
Sample Description or ID
iron—shaded areas.
Collection Information
GPS Location
Dale Time nature
C
N
0)
F
2n
NI
2 -
4
L)
�
4
C1
F- 2
P e c i
om ' y
u
4 rA U >
r
m
v N
"TUI
>
rA --
# 0 fA00
CD
ISA m
c
_
Y
E' a
e e
u r9
�}SI
%
1
2
1
1
1
1
1 1
B
i6vs ..—
2
a
—
o
0
0
0
0
-
0
X
a
I
r
Filter Blank
0
0
1
1
TOTAL
1 2 1 1 1 ti
No itcz int (oyer- (0()jer GLv)- icy reFn-ePu.b✓ RFI(.e - fL Y-245
4r;S 0 t,ny�d (ool<t' artd pla" Za--Vl*s rn rcFrryikrcJor — rSaaJl+PkS were 00 iu Go ]) '� iv>��tsparl. P►C�(L IS
Total 2
Page 39 of 39