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HomeMy WebLinkAboutNC0000396_J15040042report_20150823DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Order Number: J15040042 Project Name: AB GW ASSESSMENT WATER Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker Customer Address: 200 CP and L Drive Arden,NC 28704 Lab Contact: Mary Ann Ogle Phone: 980-875-5274 )eJ1 (t Mary Ann Ogle Report Authorized By: ! ', 2015.04.22 16:55:28 pate: 4/22/2015 (Signature) 1%_1GY -04'00' Mary Ann Ogle Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Page 1 of 39 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time 2015009340 2015009341 2015009342 2015009343 2015009344 5 Total Samples Collected By Sample Description ASHEVILLE 31 -Mar -15 10:30 AM Synterra ABMW-04D ASHEVILLE 31 -Mar -15 12:53 PM Synterra ABMW-04 ASHEVILLE 31 -Mar -15 4:05 PM Synterra MW -12D ASHEVILLE 31 -Mar -15 9:20 AM Synterra Equipment Blank ASHEVILLE 31 -Mar -15 9:20 AM Synterra Filter Blank Page 2 of 39 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: LU Job Summary Report ❑ Sample Identification P/1 Technical Validation of Data Package J❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Page 3 of 39 LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries d❑ Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 4/22/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040042 Site: ABMW-04D Collection Date: 31 -Mar -15 10:30 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) EPA 353.2 04/07/2015 12:20 Vendor Parameter Complete EPA 300.0 04/06/2015 21:12 NITRITE + NITRATE (COLORIMETRIC) 20 EPA 300.0 Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC ACPAYNE 1 EPA 245.1 Chloride 12 mg/L 2 Sulfate 100 mg/L 2 MERCURY (COLD VAPOR) IN WATER MHALL3 1 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) 04/02/2015 11:11 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP EPA 200.7 04/02/2015 11:11 MHALL3 Aluminum (AI) 0.021 mg/L 0.005 Barium (Ba) 0.083 mg/L 0.005 Boron (B) 1.06 mg/L 0.05 Iron (Fe) 8.01 mg/L 0.01 Manganese (Mn) 5.84 mg/L 0.005 Strontium (Sr) 0.209 mg/L 0.005 Zinc (Zn) 0.022 mg/L 0.005 UNDIGESTED METALS BY ICP EPA 200.7 04/07/2015 08:58 MHH7131 Calcium (Ca) 31.7 mg/L 0.01 Magnesium (Mg) 12.9 mg/L 0.005 Potassium (K) 2.10 mg/L 0.1 Sodium (Na) 5.59 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.385 mg/L 0.005 Barium (Ba) 0.085 mg/L 0.005 Boron (B) 1.05 mg/L 0.05 Iron (Fe) 8.37 mg/L 0.01 Manganese (Mn) 6.07 mg/L 0.005 Strontium (Sr) 0.214 mg/L 0.005 Zinc (Zn) 0.021 mg/L 0.005 Page 4 of 39 Sample #: 2015009340 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 04/07/2015 12:20 BGN9034 20 EPA 300.0 04/06/2015 21:12 JAHERMA 20 EPA 300.0 04/06/2015 21:12 JAHERMA 1 EPA 245.1 04/07/2015 12:08 ACPAYNE 1 EPA 245.1 04/08/2015 11:02 ACPAYNE 1 EPA 200.7 04/02/2015 11:11 MHALL3 1 EPA 200.7 04/02/2015 11:11 MHALL3 1 EPA 200.7 04/02/2015 11:11 MHALL3 1 EPA 200.7 04/02/2015 11:11 MHALL3 1 EPA 200.7 04/02/2015 11:11 MHALL3 1 EPA 200.7 04/02/2015 11:11 MHALL3 1 EPA 200.7 04/02/2015 11:11 MHALL3 1 EPA 200.7 04/02/2015 12:02 MHALL3 1 EPA 200.7 04/02/2015 12:02 MHALL3 1 EPA 200.7 04/02/2015 12:02 MHALL3 1 EPA 200.7 04/02/2015 12:02 MHALL3 1 EPA 200.7 04/07/2015 08:58 MHH7131 1 EPA 200.7 04/07/2015 08:58 MHH7131 1 EPA 200.7 04/07/2015 08:58 MHH7131 1 EPA 200.7 04/07/2015 08:58 MHH7131 1 EPA 200.7 04/07/2015 08:58 MHH7131 1 EPA 200.7 04/07/2015 08:58 MHH7131 1 EPA 200.7 04/07/2015 08:58 MHH7131 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040042 Site: ABMW-04D Collection Date: 31 -Mar -15 10:30 AM Analyte Result DISSOLVED METALS BY ICP -MS Sample #: Antimony (Sb) < 1 Arsenic (As) 1.52 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 66.1 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) 1.15 Nickel (Ni) 2.41 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 Arsenic (As) 2.15 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 67.3 Copper (Cu) <1 Lead (Pb) < 1 Molybdenum (Mo) 1.22 Nickel (Ni) 2.50 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level 0.789 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS ug/L TDS 240 Total Carbon 04/17/2015 12:07 TOC 0.618 TOTAL SUSPENDED SOLIDS 1 TSS 5.0 Page 5 of 39 ug/L 1 1 Sample #: 2015009340 JAHERMA ug/L 1 1 Matrix: GW WW JAHERMA Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 04/17/2015 12:07 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:07 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:07 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:07 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:07 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:07 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:07 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:07 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:07 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:07 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:07 DJSULL1 ug/L 0.2 1 EPA 200.8 04/17/2015 12:07 DJSULL1 ug/L 0.3 1 EPA 200.8 04/17/2015 12:07 DJSULL1 ug/L 1 1 EPA 200.8 04/16/2015 13:34 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:34 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:34 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:34 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:34 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:34 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:34 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:34 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:34 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:34 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:34 JAHERMA ug/L 0.2 1 EPA 200.8 04/16/2015 13:34 JAHERMA ug/L 0.3 1 EPA 200.8 04/16/2015 13:34 JAHERMA Vendor Method V_SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 04/06/201514:18 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 04/08/201512:53 TJA7067 mg/L 5 1 SM2540D 04/03/2015 08:15 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040042 Site: ABMW-04 Collection Date: 31 -Mar -15 12:53 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) EPA 353.2 04/07/2015 12:23 Vendor Parameter Complete EPA 300.0 04/06/2015 21:30 NITRITE + NITRATE (COLORIMETRIC) 50 EPA 300.0 Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC ACPAYNE 1 EPA 245.1 Chloride 12 mg/L 2 Sulfate 260 mg/L 5 MERCURY (COLD VAPOR) IN WATER MHALL3 1 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) 04/02/2015 11:00 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP EPA 200.7 04/02/2015 11:00 MHALL3 Aluminum (AI) 0.042 mg/L 0.005 Barium (Ba) 0.301 mg/L 0.005 Boron (B) 3.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.146 mg/L 0.005 Strontium (Sr) 4.10 mg/L 0.005 Zinc (Zn) 0.037 mg/L 0.005 UNDIGESTED METALS BY ICP EPA 200.7 04/07/2015 09:02 MHH7131 Calcium (Ca) 150 mg/L 0.1 Magnesium (Mg) 45.8 mg/L 0.005 Potassium (K) 24.4 mg/L 0.1 Sodium (Na) 42.6 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.792 mg/L 0.005 Barium (Ba) 0.315 mg/L 0.005 Boron (B) 3.08 mg/L 0.05 Iron (Fe) 0.328 mg/L 0.01 Manganese (Mn) 0.147 mg/L 0.005 Strontium (Sr) 4.21 mg/L 0.005 Zinc (Zn) 0.039 mg/L 0.005 Page 6 of 39 Sample #: 2015009341 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 04/07/2015 12:23 BGN9034 20 EPA 300.0 04/06/2015 21:30 JAHERMA 50 EPA 300.0 04/06/2015 21:30 JAHERMA 1 EPA 245.1 04/07/2015 12:11 ACPAYNE 1 EPA 245.1 04/08/2015 11:05 ACPAYNE 1 EPA 200.7 04/02/2015 11:00 MHALL3 1 EPA 200.7 04/02/2015 11:00 MHALL3 1 EPA 200.7 04/02/2015 11:00 MHALL3 1 EPA 200.7 04/02/2015 11:00 MHALL3 1 EPA 200.7 04/02/2015 11:00 MHALL3 1 EPA 200.7 04/02/2015 11:00 MHALL3 1 EPA 200.7 04/02/2015 11:00 MHALL3 10 EPA 200.7 04/02/2015 11:55 MHALL3 1 EPA 200.7 04/02/2015 11:55 MHALL3 1 EPA 200.7 04/02/2015 11:55 MHALL3 1 EPA 200.7 04/02/2015 11:55 MHALL3 1 EPA 200.7 04/07/2015 09:02 MHH7131 1 EPA 200.7 04/07/2015 09:02 MHH7131 1 EPA 200.7 04/07/2015 09:02 MHH7131 1 EPA 200.7 04/07/2015 09:02 MHH7131 1 EPA 200.7 04/07/2015 09:02 MHH7131 1 EPA 200.7 04/07/2015 09:02 MHH7131 1 EPA 200.7 04/07/2015 09:02 MHH7131 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040042 Site: ABMW-04 Collection Date: 31 -Mar -15 12:53 PM Analyte Result DISSOLVED METALS BY ICP -MS Sample #: Antimony (Sb) 6.49 Arsenic (As) 441 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) < 1 Copper(Cu) 1.79 Lead (Pb) < 1 Molybdenum (Mo) 673 Nickel (Ni) 1.58 Selenium (Se) 6.99 Thallium (TI) Low Level 2.54 Vanadium (V) Low Level 66.7 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) 6.22 Arsenic (As) 447 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) 32.6 Cobalt (Co) 1.57 Copper (Cu) 4.50 Lead (Pb) < 1 Molybdenum (Mo) 675 Nickel (Ni) 6.93 Selenium (Se) 6.75 Thallium (TI) Low Level 2.81 Vanadium (V) Low Level 70.8 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS ug/L TDS 800 Total Carbon 04/17/2015 12:11 TOC 0.780 TOTAL SUSPENDED SOLIDS 1 TSS 12 Page 7 of 39 ug/L 1 1 Sample #: 2015009341 JAHERMA ug/L 1 1 Matrix: GW WW JAHERMA Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 04/17/2015 12:11 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:11 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:11 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:11 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:11 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:11 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:11 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:11 DJSULL1 ug/L 1 20 EPA 200.8 04/17/2015 12:11 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:11 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:11 DJSULL1 ug/L 0.2 1 EPA 200.8 04/17/2015 12:11 DJSULL1 ug/L 0.3 1 EPA 200.8 04/17/2015 12:11 DJSULL1 ug/L 1 1 EPA 200.8 04/16/2015 13:38 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:38 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:38 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:38 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:38 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:38 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:38 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:38 JAHERMA ug/L 5 5 EPA 200.8 04/16/2015 13:38 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:38 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:38 JAHERMA ug/L 0.2 1 EPA 200.8 04/16/2015 13:38 JAHERMA ug/L 0.3 1 EPA 200.8 04/16/2015 13:38 JAHERMA Vendor Method V_SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 04/06/201514:18 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 04/08/201512:53 TJA7067 mg/L 5 1 SM2540D 04/03/2015 08:15 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040042 Site: MW -12D Collection Date: 31 -Mar -15 4:05 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) BGN9034 1 EPA 300.0 Vendor Parameter Complete 1 EPA 300.0 04/07/2015 09:07 NITRITE + NITRATE (COLORIMETRIC) 1 EPA 245.1 04/07/2015 12:13 Nitrite + Nitrate (Colorimetric) 1.4 mg-N/L 0.01 INORGANIC IONS BY IC 04/02/2015 11:15 MHALL3 1 EPA 200.7 Chloride 8.0 mg/L 0.1 Sulfate 7.2 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER 04/02/2015 11:15 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) MHALL3 1 EPA 200.7 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP 1 EPA 200.7 04/02/2015 11:43 MHALL3 Aluminum (AI) 0.045 mg/L 0.005 Barium (Ba) 0.061 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.073 mg/L 0.01 Manganese (Mn) 0.463 mg/L 0.005 Strontium (Sr) 0.027 mg/L 0.005 Zinc (Zn) 0.043 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 3.64 mg/L 0.01 Magnesium (Mg) 2.45 mg/L 0.005 Potassium (K) 1.37 mg/L 0.1 Sodium (Na) 7.66 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.384 mg/L 0.005 Barium (Ba) 0.063 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.433 mg/L 0.01 Manganese (Mn) 0.480 mg/L 0.005 Strontium (Sr) 0.024 mg/L 0.005 Zinc (Zn) 0.037 mg/L 0.005 Page 8 of 39 Sample #: 2015009342 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 04/07/2015 12:34 BGN9034 1 EPA 300.0 04/07/2015 09:07 JAHERMA 1 EPA 300.0 04/07/2015 09:07 JAHERMA 1 EPA 245.1 04/07/2015 12:13 ACPAYNE 1 EPA 245.1 04/08/2015 11:07 ACPAYNE 1 EPA 200.7 04/02/2015 11:15 MHALL3 1 EPA 200.7 04/02/2015 11:15 MHALL3 1 EPA 200.7 04/02/2015 11:15 MHALL3 1 EPA 200.7 04/02/2015 11:15 MHALL3 1 EPA 200.7 04/02/2015 11:15 MHALL3 1 EPA 200.7 04/02/2015 11:15 MHALL3 1 EPA 200.7 04/02/2015 11:15 MHALL3 1 EPA 200.7 04/02/2015 11:43 MHALL3 1 EPA 200.7 04/02/2015 11:43 MHALL3 1 EPA 200.7 04/02/2015 11:43 MHALL3 1 EPA 200.7 04/02/2015 11:43 MHALL3 1 EPA 200.7 04/07/2015 09:06 MHH7131 1 EPA 200.7 04/07/2015 09:06 MHH7131 1 EPA 200.7 04/07/2015 09:06 MHH7131 1 EPA 200.7 04/07/2015 09:06 MHH7131 1 EPA 200.7 04/07/2015 09:06 MHH7131 1 EPA 200.7 04/07/2015 09:06 MHH7131 1 EPA 200.7 04/07/2015 09:06 MHH7131 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040042 Site: MW -12D Collection Date: 31 -Mar -15 4:05 PM Analyte Result DISSOLVED METALS BY ICP -MS Sample #: Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 10.7 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) 1.88 Nickel (Ni) 4.66 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) 3.35 Cobalt (Co) 11.0 Copper (Cu) <1 Lead (Pb) < 1 Molybdenum (Mo) 2.09 Nickel (Ni) 5.90 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level 0.388 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS ug/L TDS 56 Total Carbon 04/17/2015 12:16 TOC 0.615 TOTAL SUSPENDED SOLIDS 1 TSS 5.0 Page 9 of 39 ug/L 1 1 Sample #: 2015009342 JAHERMA ug/L 1 1 Matrix: GW WW JAHERMA Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 04/17/2015 12:16 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:16 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:16 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:16 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:16 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:16 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:16 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:16 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:16 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:16 DJSULL1 ug/L 1 1 EPA 200.8 04/17/2015 12:16 DJSULL1 ug/L 0.2 1 EPA 200.8 04/17/2015 12:16 DJSULL1 ug/L 0.3 1 EPA 200.8 04/17/2015 12:16 DJSULL1 ug/L 1 1 EPA 200.8 04/16/2015 13:43 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:43 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:43 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:43 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:43 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:43 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:43 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:43 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:43 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:43 JAHERMA ug/L 1 1 EPA 200.8 04/16/2015 13:43 JAHERMA ug/L 0.2 1 EPA 200.8 04/16/2015 13:43 JAHERMA ug/L 0.3 1 EPA 200.8 04/16/2015 13:43 JAHERMA Vendor Method V_SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 04/06/201514:18 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 04/08/201512:53 TJA7067 mg/L 5 1 SM2540D 04/03/2015 08:15 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040042 Site: Equipment Blank Collection Date: 31 -Mar -15 9:20 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) 1 EPA 300.0 Vendor Parameter Complete 1 EPA 300.0 04/06/2015 22:24 NITRITE + NITRATE (COLORIMETRIC) 1 EPA 245.1 04/07/2015 12:15 Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC 04/02/2015 12:11 MHALL3 1 EPA 200.7 Chloride < 0.1 mg/L 0.1 Sulfate < 0.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER 04/07/2015 09:18 MHH7131 Mercury (Hg) < 0.05 ug/L 0.05 UNDIGESTED METALS BY ICP MHH7131 1 EPA 200.7 04/07/2015 09:18 Calcium (Ca) < 0.01 mg/L 0.01 Magnesium (Mg) < 0.005 mg/L 0.005 Potassium (K) < 0.1 mg/L 0.1 Sodium (Na) < 0.05 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP 04/16/2015 13:48 JAHERMA Aluminum (AI) 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Page 10 of 39 Sample #: 2015009343 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 04/07/2015 12:26 BGN9034 1 EPA 300.0 04/06/2015 22:24 JAHERMA 1 EPA 300.0 04/06/2015 22:24 JAHERMA 1 EPA 245.1 04/07/2015 12:15 ACPAYNE 1 EPA 200.7 04/02/2015 12:11 MHALL3 1 EPA 200.7 04/02/2015 12:11 MHALL3 1 EPA 200.7 04/02/2015 12:11 MHALL3 1 EPA 200.7 04/02/2015 12:11 MHALL3 1 EPA 200.7 04/07/2015 09:18 MHH7131 1 EPA 200.7 04/07/2015 09:18 MHH7131 1 EPA 200.7 04/07/2015 09:18 MHH7131 1 EPA 200.7 04/07/2015 09:18 MHH7131 1 EPA 200.7 04/07/2015 09:18 MHH7131 1 EPA 200.7 04/07/2015 09:18 MHH7131 1 EPA 200.7 04/07/2015 09:18 MHH7131 1 EPA 200.8 04/16/2015 13:48 JAHERMA 1 EPA 200.8 04/16/2015 13:48 JAHERMA 1 EPA 200.8 04/16/2015 13:48 JAHERMA 1 EPA 200.8 04/16/2015 13:48 JAHERMA 1 EPA 200.8 04/16/2015 13:48 JAHERMA 1 EPA 200.8 04/16/2015 13:48 JAHERMA 1 EPA 200.8 04/16/2015 13:48 JAHERMA 1 EPA 200.8 04/16/2015 13:48 JAHERMA 1 EPA 200.8 04/16/2015 13:48 JAHERMA 1 EPA 200.8 04/16/2015 13:48 JAHERMA 1 EPA 200.8 04/16/2015 13:48 JAHERMA 1 EPA 200.8 04/16/2015 13:48 JAHERMA 1 EPA 200.8 04/16/2015 13:48 JAHERMA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040042 Page 11 of 39 Site: Equipment Blank Sample #: 2015009343 Collection Date: 31 -Mar -15 9:20 AM Matrix: GW WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 SM2540C 04/06/2015 14:18 AGIBBS5 Total Carbon TOC 0.133 mg/L 0.1 1 SM5310C/EPA9060A 04/08/201512:53 TJA7067 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 04/03/2015 08:15 AGIBBS5 Certificate of Laboratory Analysis Page 12 of 39 This report shall not be reproduced, except in full. Order # J15040042 Site: Filter Blank Collection Date: 31 -Mar -15 9:20 AM Analyte Result Units Qualifiers RDL Mercury Dissolved (cold vapor) in Water (Filtered) EPA 245.1 04/08/2015 11:09 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP 1 EPA 200.7 04/02/2015 11:19 Aluminum (Al) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 DISSOLVED METALS BY ICP -MS 1 EPA 200.8 04/17/2015 11:49 Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2015009344 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 245.1 04/08/2015 11:09 ACPAYNE 1 EPA 200.7 04/02/2015 11:19 MHALL3 1 EPA 200.7 04/02/2015 11:19 MHALL3 1 EPA 200.7 04/02/2015 11:19 MHALL3 1 EPA 200.7 04/02/2015 11:19 MHALL3 1 EPA 200.7 04/02/2015 11:19 MHALL3 1 EPA 200.7 04/02/2015 11:19 MHALL3 1 EPA 200.7 04/02/2015 11:19 MHALL3 1 EPA 200.8 04/17/2015 11:49 DJSULL1 1 EPA 200.8 04/17/2015 11:49 DJSULL1 1 EPA 200.8 04/17/2015 11:49 DJSULL1 1 EPA 200.8 04/17/2015 11:49 DJSULL1 1 EPA 200.8 04/17/2015 11:49 DJSULL1 1 EPA 200.8 04/17/2015 11:49 DJSULL1 1 EPA 200.8 04/17/2015 11:49 DJSULL1 1 EPA 200.8 04/17/2015 11:49 DJSULL1 1 EPA 200.8 04/17/2015 11:49 DJSULL1 1 EPA 200.8 04/17/2015 11:49 DJSULL1 1 EPA 200.8 04/17/2015 11:49 DJSULL1 1 EPA 200.8 04/17/2015 11:49 DJSULL1 1 EPA 200.8 04/17/2015 11:49 DJSULL1 e Page 13 of 39 Element One Ince 6319-D Carolina Beach Rd. Wilmington, NC 28412 Phone: 910 793-0128 Fau: 910 792-6853 e1 lab@e1 labs -- One REPORT OF ANALYSES Duke Energy April 3, 2015 Laboratory Services Client Project Name AB GW Assessment Water — Asheville 13339 Hagers Ferry Road Bld. MG03A Client Project Number J15040042 Huntersville, NC 28078 PO Number Sample Matrix GW WW Sample Type Grab Date Received 04/03/2015 Date Analyzed 04/03/2015 Method SM 4500 S2- D Time Received 1155 Delivered by FedEx Received by JRC eOne ID Duke Energy ID Parameter Result Unit Dil DL Date Time Sampled Sampled 24432-1 ABMW-04D Sulfide < 0.1 mg/L 1 0.1 03/31/15 1030 24432-2 ABMW-04 Sulfide < 0.1 mg/L 1 0.1 03/31/15 1253 24432-3 MW -12D Sulfide < 0.1 mg/L 1 0.1 03/31/15 1605 24432-4 Equipment Blank Sulfide < 0.1 mg/L 1 0.1 03/31/15 0920 Ken mith, Laboratory Director 24432 Duke Report Packet Compiled bye- NC Certifications: DW 37788 and DWQ DENR 604 Page 14 of 39 D treulquo� A Rlol e, e o o e e e e e e e Lu v J )� spnew Z VY > C ' J � N pe rn m lIyyy b C 1 dCL 2 U M..— U .N V _ LL l _ $ m F m mlN o b L ar a m U E� E le .. CL1ZI V U � a OE 'VO) C 2W2Wo J J N Ex ........... W W a i 1 7S luew013 n1 opulnS SI ZC $ S 7S nl'euoq+Q� a i s •aleuopirrl9 i 'RiWIInI1V I3 as ! _ $ -KWMN'001 '►os'la pc� ' CCC ! i b $ E g a w Al -4S A (9LL 348H) Due4lery 7 .u�; ~! Eauo x X Do a F dwoo 0 > 3 cc S C V 2 p F g N 1 IQ - kr C ! 01 E O ; M� C-4 ! ! J ,� ........... c d Mcg z ! w o O. E- E o VZZ -{'- a�b a Toy '--------'-1 U mLill ! Page 14 of 39 D V 16' punoiewni peilsep eleolpul eseeld aueliodwl Veiuolsno v J Z VY > C ' J � J U rn m lIyyy b C 1 dCL 2 U U .N V _ LL l _ $ m F m \ ar a m U E� E le .. CL1ZI V U � a OE 'VO) C 2W2Wo J J N W W a e ementOne SAMPLE SUBMISSION FORM TAT 7 BD Hold Time Expiration 04.07.15 @ 0920 AM Client: Duke Energy LIMS No J15040042 Project I D AB GW Assessment Water - Asheville Lab Mage U42 Analysis Due Date 04.03.15 Report Due Date 04.15.15 Date Rec: 04.03.15 Time Rec: 1155_ Rec By JRC H >9 Yes No Tem <_ 6°C Yes No Ref. Method: SM4500 S2 D If No, Record If No, Record Sample Identification & Collection Information Lab ID Client ID Collection Date Collection Time Analysis Requested 1 ABMW-04D 03.31.15 1030 AM Sulfide 03.3 1 15 "I'�M 11 153 Sulfide 3 MW -12D 03.31.15 1605 XM Sulfide 4 Equipment Blank 03.31.�� q p ment Bla15 0920 AM Ifide Sulfide u The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected NOTE for Sulfide at 100 pg/L spike the sample to render the final spike concentration at — 500 pg/L All AB Groundwater Assessment jobs need a RL of 0.1 SS Page 1 1 Prep By / Date k�'5 �a SS by Labeled By / Date jP- `f- 3 <( S- 4/3/2015 4/3/2015 2:04:13 PM ID Verification By /Date(. 3- 1 Page 16 of 39 METHOD: SM 4500 S2- D ELEMENT ONE ELEMENT ASSAY: Sulfide Spectrophotometer Wave Length 664 UNITS OF ANSWER ug/mL DETECTION LIMIT u 1.000 CLIENT: Duke SPK LEVELLuql 5 Lab ID# 24432 Na2S•9H2O Lot # 40721 MAX ALIQUOT 10.00' Date: 4.3.15 STANDARD conc(ppm) X Time Analysis Begun 1430` Cal Std Lot: WC2-68-3 10 Time Analysis Ended 1448' QC Std Lot: WC2-68-4 Analyst: KLS STD ABSORPTION0900 Y ugX STD SOLUTION rAB 0.800 07000.00 00 1.00 2;50 5.00 7:500.614 10.00 0.225 0.417 1 0.763 6800' 0 500Y °° 0.400 030° 0.200 0100 0.000 ....:200 W 600 600 000 1600 1100 -: SAMPLE SAMP I.D. ABS ug PER ALIQUOT ALI in mL ANALYZED PREP VOL in mL Slope', ALI in mL TAKEN 0.076661538 RESULTS ug/mL Correlation LESS THAN % SPK REC 0.998114218'; SPIKE LEVEL 0.00 0.00 -0.4453 10 10 10 < 0.00 1.00 0.089 0.7408 10 10 10 < 74% 1.00 5.00 0.216 2.4723 10 10 10 0.247 99% 2.50 5.00 0.412 5.1445 10 10 10 0.514 103% 5.00 7.50 0.594 7.6259 10 10 10 0.763 102% 7.50 10.00 0.748 9.7255 10 10 10 0.973 97% 10.00 24432-1 0.004 -0.4180 10 10 10 24432-1 spk 0.345 4.2311 10 10 10 0.423 85% 5.0 24432-2 0.008 -0.3635 10 10 10 24432-2 s k 0.374 4.6265 10 10 10 0.463 93% 5.0 24432-3 0.007 -0.3771 10 10 10% 24432-3 s k 0.368 4.5447 10 10 10 0.454 91% 5.0 24432-4 0.001 -0.4589 10 10 10 24432-4 spk 0.421 5.2672 10 10 10 0.527 105% 5.0 Purchased Std 0.667 8.6211 10 10 10 0.862 108% 8.0 Blank 0 0.0000 10 10 10 < QC 0.412 5.1445 10 10 10 0.514 103% 5.0 Submitted for QA/QC- Date: 4.3.15 By: (Print) KLS (sig SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle Project Name: AB GW Assessment Water - Asheville Project Number:J15040042 Lot Number:QD03018 Date Completed:04/16/2015 Grant Wilton Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. * QD0301 8* Shealy Environmental Services, Inc. Page: 1 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Duke Energy Lot Number: QD03018 Project Name: AB GW Assessment Water - Asheville Project Number: J15040042 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page Shealy Environmental Services, Inc. Page: 2 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QD03018 Project Name: AB GW Assessment Water - Asheville Project Number: J15040042 Sample Number Sample ID Matrix Date Sampled Date Received 001 2015009340 Aqueous 03/31/20151030 04/03/2015 002 2015009341 Aqueous 03/31/20151253 04/03/2015 003 2015009342 Aqueous 03/31/20151605 04/03/2015 004 2015009343 Aqueous 03/31/2015 0920 04/03/2015 (4 samples) Shealy Environmental Services, Inc. Page: 3 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. (8 detections) Shealy Environmental Services, Inc. Page: 4 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Executive Summary Duke Energy Lot Number: QD03018 Project Name: AB GW Assessment Water - Asheville Project Number: J15040042 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015009340 Aqueous Alkalinity SM 2320B- 50 mg/L 5 001 2015009340 Aqueous Bicarbonate Alkalinity SM 2320B- 50 mg/L 5 001 2015009340 Aqueous Methane RSK - 175 44 ug/L 6 002 2015009341 Aqueous Alkalinity SM 2320B- 340 mg/L 7 002 2015009341 Aqueous Bicarbonate Alkalinity SM 2320B- 340 mg/L 7 002 2015009341 Aqueous Methane RSK - 175 33 ug/L 8 003 2015009342 Aqueous Alkalinity SM 2320B- 13 mg/L 9 003 2015009342 Aqueous Bicarbonate Alkalinity SM 2320B- 13 mg/L 9 (8 detections) Shealy Environmental Services, Inc. Page: 4 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QD03018-001 Description: 2015009340 Matrix: Aqueous Date Sampled:03/31/2015 1030 Project Name: AB GW Assessment Water - Date Received: 04/03/2015 Project Number: J15040042 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 (Alkalinity) SM 2320B-2011 1 04/09/2015 1152 HMA 72090 1 (Bicarbonate ) SM 2320B-2011 1 04/09/2015 1152 HMA 1 (Carbonate Al) SM 2320B-2011 1 04/09/2015 1152 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 5 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 50 10 mg/L 2 Bicarbonate Alkalinity SM 2320B-20 50 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 5 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QD03018-001 Description: 2015009340 Matrix: Aqueous Date Sampled:03/31/2015 1030 Project Name: AB GW Assessment Water - Date Received: 04/03/2015 Project Number: J15040042 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/08/2015 1337 DCS 72089 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 44 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 6 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QD03018-002 Description: 2015009341 Matrix: Aqueous Date Sampled:03/31/2015 1253 Project Name: AB GW Assessment Water - Date Received: 04/03/2015 Project Number: J15040042 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 (Alkalinity) SM 2320B-2011 1 04/09/2015 1214 HMA 72090 1 (Bicarbonate ) SM 2320B-2011 1 04/09/2015 1214 HMA 1 (Carbonate Al) SM 2320B-2011 1 04/09/2015 1214 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 7 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 340 10 mg/L 2 Bicarbonate Alkalinity SM 2320B-20 340 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 7 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QD03018-002 Description: 2015009341 Matrix: Aqueous Date Sampled:03/31/2015 1253 Project Name: AB GW Assessment Water - Date Received: 04/03/2015 Project Number: J15040042 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/08/2015 1347 DCS 72089 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 33 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 8 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QD03018-003 Description: 2015009342 Matrix: Aqueous Date Sampled:03/31/2015 1605 Project Name: AB GW Assessment Water - Date Received: 04/03/2015 Project Number: J15040042 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 (Alkalinity) SM 2320B-2011 1 04/09/2015 1218 HMA 72090 1 (Bicarbonate ) SM 2320B-2011 1 04/09/2015 1218 HMA 1 (Carbonate Al) SM 2320B-2011 1 04/09/2015 1218 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 9 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 13 10 mg/L 2 Bicarbonate Alkalinity SM 2320B-20 13 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 9 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QD03018-003 Description: 2015009342 Matrix: Aqueous Date Sampled:03/31/2015 1605 Project Name: AB GW Assessment Water - Date Received: 04/03/2015 Project Number: J15040042 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/08/2015 1400 DCS 72089 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 10 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QD03018-004 Description: 2015009343 Matrix: Aqueous Date Sampled:03/31/2015 0920 Project Name: AB GW Assessment Water - Date Received: 04/03/2015 Project Number: J15040042 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 (Alkalinity) SM 2320B-2011 1 04/09/2015 1223 HMA 72090 1 (Bicarbonate ) SM 2320B-2011 1 04/09/2015 1223 HMA 1 (Carbonate Al) SM 2320B-2011 1 04/09/2015 1223 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 11 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 2 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 11 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QD03018-004 Description: 2015009343 Matrix: Aqueous Date Sampled:03/31/2015 0920 Project Name: AB GW Assessment Water - Date Received: 04/03/2015 Project Number: J15040042 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/08/2015 1410 DCS 72089 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 12 of 12 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 QC Summary Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - Ii Sample ID: QQ72090-001 Matrix: Aqueous Batch: 72090 Analytical Method: SM 2320B-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 04/09/20151141 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - LCS Sample ID: QQ72090-002 Matrix: Aqueous Batch: 72090 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 96 1 96 90-110 04/09/20151147 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MS Sample ID: QD03018-001 MS Matrix: Aqueous Batch: 72090 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 50 100 130 1 84 70-130 04/09/20151200 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MSD Sample ID: QD03018-001MD Matrix: Aqueous Batch: 72090 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Alkalinity 50 100 140 1 86 1.5 70-130 20 04/09/20151206 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ72089-001 Matrix: Aqueous Batch: 72089 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 04/08/2015 0943 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ72089-002 Matrix: Aqueous Batch: 72089 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 150 150 1 97 70-130 04/08/2015 0920 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ72089-003 Matrix: Aqueous Batch: 72089 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 150 150 1 98 0.84 70-130 30 04/08/2015 0932 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD03018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 �nmpdm000movom000 ■u ■a�■■■v ie�oee��■ I�111111�1=111111111 f �OIIINIIIIIINIIi wbojeWn P"9o31 NIF:)I ' asreLd �urtyi�q "I oLar* 0 SHEALY ENVIRONMENTAL SERVICES, INC. Sfrcaly CmirowntmW Senria5, lef, lkagc I of Dmum.nl Jd umbev l' -AD -Q 16 Itepl arts Derr 07+15114 Rke�Slun Alunhes 15 Eifcriivc Delo 1U07ii4 Sample Receipt Checklist (SRC) Client. . i,._. �r oaler Inspected hy1date: Nvc-x,.rQ�-+ \71i. Lot tf: Means ofreccipt: ❑ SLS] ❑ Client ❑ UPS FedEac ❑ Airborri . Exp ❑ Other Yee LJ I Nil L4 1. Wcrc coLody sus present oft the coolej* Yes Ll I No ❑ I NA_kL 12. If custody seals were present, wem theX intact and tmbrokcr►7 (con-ected) temperature on erature uprc. CoDlcr D/OriSinai telrKrature upon ItlL7m6p,erired a . +ccip# i� Ll_L- Ile d f -PC f � plc I F €"C Mdhod: ❑ Temperature lanikagainst Bottles Ili Gun ID: 44 IR Gun Correction Factor; P- Method of cool"' Wet lee ❑ Blue Iee ❑ Dry [cc Xone Yes ❑l�Fo ❑ NA �` 3. Iftelrlperalure of any cooler exceeded 6.0°C, was Project Manager notified? PNI noWied by SRC, phone, note (circle one), other (For wulers received via commercial courier, PMate m he notiftod jmt7iuli3tely',) Yes Na 0 NA ❑ 4. Is the conmerclal courier's packing slip shed to this f4rrn? Yes ZI Na ❑ 5. W= MpeT cltst , procedures relin uishedlrcccivcd follow rztV Yc* pip ❑ NA ❑ 5 a Were samples relinquished by client to commercial courier? YeaNo Ll6. Wcrc sairiplc IDs I6MA ort the Cf?C Yes 51 140 U 7. Wort sample IDs lista on all sample. -containers? Yes No ❑ $. Was ctollaeti€ln date & time Iist,cd on the CXK7 Yes 9�No ❑ 9. 10plas collection date & time listed on all sample eomiiners? Yes Ata ❑ 10. Did all container labc1 in.l rrnalicnl 117 [trate, time ree with the COC7 Yes 01140 ❑ 11- Were tests to be pert&mcd listed an the COC? Yep Na ❑ 12. Did all samples arrive in the proper coataieer�; for each test? YN Alo ❑ 13. Did all containers arriva in gwd col clition (unbroken. lids on, a%.)7 Y" El No ❑ 14. Was adequate sample volume avail calalc'? Yes [71 No,15- car Werc all samples rmeived Within 1L the balding, time or 48 hours, whichever zriea fir-KO Y ❑ rlo 16- Were any sam les cont'aineTs missin Yes ❑ Ala 1.7. Were there aTgr. tx4e�; same ler. nat listed on COC? Yes 4a NA 18. Were bubbks re nt` cR-siz+c" W'or 6rrim in diameter) in any VOA vials'1 Yes ❑ No ❑ NA 19. Were all metal RIO&QVINUnutrient &U11 les rer,:ehrod ata H of ---2? Yes [l No a NA Vr 20. Were all cyanide and,+or sulfide spm les received ata pH ? 12? Yes ❑ No ❑ NAW 21. Were all applicable R EBP1 KN+cyanidelphenol (<02ing/L) samples free of residual chlorine? Yes ❑IVo ❑ NA 22. Were rollectim temperature. documented on the C)[ c for NC sarrl les? Yes E] lila ❑ NA 3. Were. client remarlcslrequests (i.e. reque.%ted diltlt ons, hdS+MSD dcsignations, etc_..) correctly transcribed from the (,(X' into the colmncnt sc+c=lion in LIMS? Yss NO 24- Was the quatc nl3rrl} er used taken from the container label? Sample Pnemrvation (Must be completed for any yarn ic(s) incorrectly pre rved or with heads ce,) Samples) were reccivud incorrectly preserved and were adjilsted acwrdin 1 In t;a rl le receiving With )1RSQ4,HN0_i,HCl Na0H) ut4 g SR # -Sample(s) were reo6vcd with lubbles>6 r1in in diameter. Sam le(s) vem received with.'FRC~ -0-2 m `l. If 421 is No SC Drinking trier Protect Sarnplc�s) pH vuriflud to be > 2 by 17uste Sara le(s) v%,erc nD m civlxl til a pH c1f'c2 and v.crc adGustcd a.c )dingly using SRA I Stullple labels applied by: lverified b : Date: (,Olilllnent5; Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 ! ---.- --- ----- - - - - -------Duica Ener-- Analyticallaboratory r I 'r••Ana{,-„al Laborat Duke Energy ° Nail Cade MG03AZ lauilding 74051 ! iOrder A�! 1i atrix Gw WW Analytical Laboratory 13359 Fingers Ferry NO { G y�� I Chafn Of Custody Hantelnvllle, N. c. 20079 i f �, (7ga) 075.5245 ; iLo ® Dela s Timed • Sample Log �Rit. �' �' 4_'" ° ._._ .......-_._._._._Palog4b]B755U30._._.__ I Protact Name AB GW Assessment water Pheee Na: * Element 1 �' I Cooker TemR1CL.-_.. v Useoni~--}------------------------. ._. ewes Crle r.a F— NC 5C SAMPLE PRa(if3l1M Ground Water NPDES_ �--- Drinking Water DST_ RCRA Waste _ DISTRIBUTION ORIGINAL to LAB, COPY 1q CLIENT ! o ° . COC REV DATE 112212U15 Cllertt Ad Faa No: PO 1142133 on 1045 urnj b uftflltered {1 uttered Unit; Activity ro: ° Preservative Ise Ice Ice hl s2 W Ice , SHEALY airier Volume (mL) 2000 nom{ 300 125 500 500 5007HDPE Container Type PET glass PET PET PET PET ` HDP ry 114zubS )' Sample Description or ID iron—shaded areas. Collection Information GPS Location Dale Time nature C N 0) F 2n NI 2 - 4 L) � 4 C1 F- 2 P e c i om ' y u 4 rA U > r m v N "TUI > rA -- # 0 fA00 CD ISA m c _ Y E' a e e u r9 �}SI % 1 2 1 1 1 1 1 1 B i6vs ..— 2 a — o 0 0 0 0 - 0 X a I r Filter Blank 0 0 1 1 TOTAL 1 2 1 1 1 ti No itcz int (oyer- (0()jer GLv)- icy reFn-ePu.b✓ RFI(.e - fL Y-245 4r;S 0 t,ny�d (ool<t' artd pla" Za--Vl*s rn rcFrryikrcJor — rSaaJl+PkS were 00 iu Go ]) '� iv>��tsparl. P►C�(L IS Total 2 Page 39 of 39