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HomeMy WebLinkAboutNC0000396_J15030402 Report_20150823DUE Analytical Laboratory Page 1 of 100 ' ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report J15030402 AB GW ASSESSMENT SOIL Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker 200 CP and L Drive Arden,NC 28704 Margaret Galvin -Karr Phone: 980-875-5219 �,� ma gygomn-karr@duke- u aI�RGY Date: 2015.04.21 13:45:31 -04'00' Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 4/21/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015007392 ASHEVILLE 12 -Mar -15 12:55 PM illegible AB -01 (4-5') 2015007393 ASHEVILLE 12 -Mar -15 1:25 PM illegible AB -01 (19-20') 2015007394 ASHEVILLE 12 -Mar -15 1:45 PM illegible AB -01 (24-25') 2015007395 ASHEVILLE 12 -Mar -15 2:00 PM illegible AB -01 (30-31') 2015007396 ASHEVILLE 12 -Mar -15 5:15 PM illegible MW -04 SB (2-3') 2015007397 ASHEVILLE 12 -Mar -15 5:25 PM illegible MW -04 SB (8-10') 2015007398 ASHEVILLE 12 -Mar -15 5:35 PM illegible MW -04 SB (24-25') 2015007399 ASHEVILLE 12 -Mar -15 5:45 PM illegible MW -04 SB (37-39') 2015007400 ASHEVILLE 12 -Mar -15 12:45 PM illegible Equipment Blank 9 Total Samples Page 2 of 100 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: LU Job Summary Report ❑ Sample Identification P/1 Technical Validation of Data Package J❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Page 3 of 100 LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries d❑ Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 4/21/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030402 Site: AB -01 (4-5') Collection Date: 12 -Mar -15 12:55 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 4 of 100 Sample #: 2015007392 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030402 Site: AB -01 (19-20') Collection Date: 12 -Mar -15 1:25 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 5 of 100 Sample #: 2015007393 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030402 Site: AB -01 (24-25') Collection Date: 12 -Mar -15 1:45 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 6 of 100 Sample #: 2015007394 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030402 Site: AB -01 (30-31') Collection Date: 12 -Mar -15 2:00 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 7 of 100 Sample #: 2015007395 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030402 Site: MW -04 SB (2-3') Collection Date: 12 -Mar -15 5:15 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 8 of 100 Sample #: 2015007396 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030402 Site: MW -04 SB (8-10') Collection Date: 12 -Mar -15 5:25 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 9 of 100 Sample #: 2015007397 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030402 Site: MW -04 SB (24-25') Collection Date: 12 -Mar -15 5:35 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 10 of 100 Sample #: 2015007398 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030402 Site: MW -04 SB (37-39') Collection Date: 12 -Mar -15 5:45 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 11 of 100 Sample #: 2015007399 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030402 Site: Equipment Blank Collection Date: 12 -Mar -15 12:45 PM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 12 of 100 Sample #: 2015007400 Matrix: OTHER Method Analysis Date/Time Analyst Vendor Method V_PACE aceAnaiXical www.pacelabs.com April 13, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. P3Syyg01lswey&e. Suite 100 Huntersville, INC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on March 16, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. This report was revised 4/13/15 to remove duplicate reporting of pH. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Rodney Wilke, Duke Energy Program Manager, Duke Energy �pQ N—C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, y without the written consent of Pace Analytical Services, Inc.. Page 1 of 87 9eO -ATO lacmnalyfica( www.pacelabs.com Project: J15030402 Pace Project No.: 92241387 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21 -A Certification #: 2926.01 Alaska Certification #: UST -078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ -0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH -0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. 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Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN -002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 87 aceAnaiXical www.pacelabs.com Project: J15030402 Pace Project No.: 92241387 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. P3Syyg011 weylte. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 87 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15030402 Pace Project No.: 92241387 Lab ID Sample ID Matrix Date Collected Date Received 92241387001 2015007400 Water 03/12/1512:45 03/16/1515:08 92241387002 2015007392 Solid 03/12/1512:55 03/16/1515:08 92241387003 2015007395 Solid 03/12/1514:00 03/16/1515:08 92241387004 2015007396 Solid 03/12/1517:15 03/16/1515:08 92241387005 2015007393 Solid 03/12/1513:25 03/16/1515:08 92241387006 2015007394 Solid 03/12/1513:45 03/16/1515:08 92241387007 2015007397 Solid 03/12/1517:25 03/16/1515:08 92241387008 2015007398 Solid 03/12/1517:35 03/16/1515:08 92241387009 2015007399 Solid 03/12/1517:45 03/16/1515:08 92241387010 2015007393 SPLP Water 03/12/15 13:25 03/16/15 15:08 92241387011 2015007394 SPLP Water 03/12/15 13:45 03/16/15 15:08 92241387012 2015007397 SPLP Water 03/12/15 17:25 03/16/15 15:08 92241387013 2015007398 SPLP Water 03/12/15 17:35 03/16/15 15:08 92241387014 2015007399 SPLP Water 03/12/15 17:45 03/16/15 15:08 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. p3ago t wey&e. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 87 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. Pggoi wleylte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15030402 92241387 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92241387001 2015007400 EPA 6020A TT3 24 PASI-M EPA 7470 LMW 1 PASI-M 92241387002 2015007392 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241387003 2015007395 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241387004 2015007396 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241387005 2015007393 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 87 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. Pggoi wleylte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92241387006 2015007394 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241387007 2015007397 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241387008 2015007398 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241387009 2015007399 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 RPM 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 87 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. P36g01qrwylte. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 9045 KAM 1 PASI-O EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241387010 2015007393 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 LMW 1 PASI-M 92241387011 2015007394 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 LMW 1 PASI-M 92241387012 2015007397 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 LMW 1 PASI-M 92241387013 2015007398 SPLP EPA 6020A TT3 24 PASI-M EPA 7470 LMW 1 PASI-M 92241387014 2015007399 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 LMW 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 87 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Pace Analytical Services, Inc. P360816fY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92241387001 2015007400 EPA 6020A Aluminum 106 ug/L 10.0 03/23/15 09:49 M1 EPA 6020A Barium 2.8 ug/L 0.30 03/23/15 09:49 EPA 6020A Calcium 245 ug/L 40.0 03/23/15 09:49 EPA 6020A Chromium 0.90 ug/L 0.50 03/23/15 09:49 EPA 6020A Cobalt 1.1 ug/L 0.50 03/23/15 09:49 EPA 6020A Iron 489 ug/L 50.0 03/23/15 09:49 EPA 6020A Lead 0.11 ug/L 0.10 03/23/15 09:49 EPA 6020A Magnesium 36.5 ug/L 10.0 03/23/15 09:49 EPA 6020A Manganese 10.3 ug/L 0.50 03/23/15 09:49 EPA 6020A Potassium 73.0 ug/L 50.0 03/23/15 09:49 EPA 6020A Strontium 0.70 ug/L 0.50 03/23/15 09:49 92241387002 2015007392 EPA 6010 Aluminum 6360 mg/kg 6.0 03/24/1510:39 M1 EPA 6010 Barium 368 mg/kg 0.60 03/24/15 10:39 M1 EPA 6010 Beryllium 1.5 mg/kg 0.060 03/24/15 10:39 EPA 6010 Boron 13.1 mg/kg 3.0 03/24/1510:39 M1 EPA 6010 Calcium 2870 mg/kg 30.1 03/24/15 10:39 M1 EPA 6010 Chromium 12.0 mg/kg 0.30 03/24/15 10:39 EPA 6010 Copper 23.6 mg/kg 0.30 03/24/15 10:39 EPA 6010 Iron 5150 mg/kg 2.4 03/24/15 10:39 M1 EPA 6010 Magnesium 659 mg/kg 30.1 03/24/15 10:39 EPA 6010 Manganese 46.6 mg/kg 0.30 03/24/15 10:39 EPA 6010 Molybdenum 1.1 mg/kg 0.60 03/24/15 10:39 EPA 6010 Nickel 9.6 mg/kg 0.30 03/24/15 10:39 EPA 6010 Potassium 1010 mg/kg 60.1 03/24/1510:39 M1 EPA 6010 Sodium 147 mg/kg 60.1 03/24/15 10:39 EPA 6010 Strontium 115 mg/kg 0.60 03/24/1510:39 M1 EPA 6010 Zinc 14.9 mg/kg 1.2 03/24/15 10:39 EPA 6020 Arsenic 59.9 mg/kg 3.0 03/24/15 08:40 M6, R1 EPA 6020 Cadmium 0.20J mg/kg 0.36 03/24/15 08:40 M6, R1 EPA 6020 Cobalt 6.6 mg/kg 3.0 03/24/15 08:40 M6, R1 EPA 6020 Lead 8.8 mg/kg 3.0 03/24/15 08:40 M6, R1 EPA 6020 Selenium 14.6 mg/kg 3.0 03/24/15 08:40 M6, R1 EPA 6020 Vanadium 39.9 mg/kg 3.0 03/24/15 08:40 M6, R1 EPA 7471 Mercury 0.17 mg/kg 0.0097 03/24/1516:33 M1 ASTM D2974-87 Percent Moisture 16.3 % 0.10 03/24/15 13:53 EPA 9045 pH at 25 Degrees C 8.1 Std. Units 0.10 03/19/15 13:45 H6 EPA 9060 Total Organic Carbon 64900 mg/kg 5940 03/23/15 12:28 EPA 9060 Total Organic Carbon 80100 mg/kg 5830 03/23/15 12:34 EPA 9060 Total Organic Carbon 80500 mg/kg 5940 03/23/15 12:46 EPA 9060 Total Organic Carbon 86000 mg/kg 5960 03/23/15 13:01 EPA 9060 Mean Total Organic Carbon 77900 mg/kg 5920 03/23/15 12:28 EPA 9060 RSD% 11.6 % 03/23/15 12:28 92241387003 2015007395 EPA 6010 Aluminum 53700 mg/kg 153 03/24/15 15:10 D3 EPA 6010 Barium 678 mg/kg 15.3 03/24/15 15:10 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 87 aceAnaiXical www.pacelabs.com Project: J15030402 Pace Project No.: 92241387 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. Pggc0 Sirpy&e. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92241387003 2015007395 EPA 6010 Beryllium 2.2 mg/kg 0.31 03/24/15 15:06 D3 EPA 6010 Boron 38.7 mg/kg 15.3 03/24/15 15:06 D3 EPA 6010 Calcium 459 mg/kg 153 03/24/15 15:06 D3 EPA 6010 Chromium 112 mg/kg 7.7 03/24/15 15:10 D3 EPA 6010 Copper 27.3 mg/kg 7.7 03/24/15 15:10 D3 EPA 6010 Iron 53100 mg/kg 61.3 03/24/15 15:10 D3 EPA 6010 Magnesium 14900 mg/kg 766 03/24/15 15:10 D3 EPA 6010 Manganese 2190 mg/kg 7.7 03/24/15 15:10 D3 EPA 6010 Nickel 48.5 mg/kg 7.7 03/24/15 15:10 D3 EPA 6010 Potassium 11300 mg/kg 1530 03/24/15 15:10 D3 EPA 6010 Strontium 7.2 mg/kg 3.1 03/24/15 15:06 D3 EPA 6010 Zinc 138 mg/kg 30.7 03/24/15 15:10 D3 EPA 6020 Arsenic 1.6J mg/kg 3.1 03/24/15 08:49 D3 EPA 6020 Cobalt 49.3 mg/kg 3.1 03/24/15 08:49 D4 EPA 6020 Lead 25.8 mg/kg 3.1 03/24/15 08:49 D3 EPA 6020 Selenium 3.2 mg/kg 3.1 03/24/15 08:49 D3 EPA 6020 Vanadium 71.4 mg/kg 3.1 03/24/15 08:49 D4 ASTM D2974-87 Percent Moisture 16.9 % 0.10 03/24/15 13:53 EPA 9045 pH at 25 Degrees C 6.3 Std. Units 0.10 03/19/15 13:45 H6 EPA 9060 Total Organic Carbon 777 mg/kg 725 03/24/15 19:13 EPA 9060 Total Organic Carbon 485J mg/kg 724 03/24/15 19:19 EPA 9060 Total Organic Carbon 431J mg/kg 728 03/24/15 19:24 EPA 9060 Total Organic Carbon 440J mg/kg 720 03/24/15 19:31 EPA 9060 Mean Total Organic Carbon 533J mg/kg 724 03/24/15 19:13 EPA 9060 RSD% 30.8 % 03/24/15 19:13 92241387004 2015007396 EPA 6010 Aluminum 8700 mg/kg 7.0 03/24/15 11:23 EPA 6010 Barium 444 mg/kg 0.70 03/24/15 11:23 EPA 6010 Beryllium 2.8 mg/kg 0.35 03/24/15 15:15 D3 EPA 6010 Boron 19.3 mg/kg 17.4 03/24/15 15:15 D3 EPA 6010 Calcium 1770 mg/kg 34.9 03/24/15 11:23 EPA 6010 Chromium 20.4 mg/kg 1.7 03/24/15 15:15 D3 EPA 6010 Copper 39.5 mg/kg 1.7 03/24/15 15:15 D3 EPA 6010 Iron 6220 mg/kg 2.8 03/24/15 11:23 EPA 6010 Magnesium 803 mg/kg 34.9 03/24/15 11:23 EPA 6010 Manganese 60.1 mg/kg 1.7 03/24/15 15:15 D3 EPA 6010 Molybdenum 1.2 mg/kg 0.70 03/24/15 11:23 EPA 6010 Nickel 13.8 mg/kg 0.35 03/24/15 11:23 EPA 6010 Potassium 1640 mg/kg 69.7 03/24/15 11:23 EPA 6010 Sodium 233 mg/kg 69.7 03/24/15 11:23 EPA 6010 Strontium 141 mg/kg 0.70 03/24/15 11:23 EPA 6010 Zinc 22.7 mg/kg 1.4 03/24/15 11:23 EPA 6020 Arsenic 91.5 mg/kg 3.5 03/24/15 09:01 D4 EPA 6020 Cadmium 0.30J mg/kg 0.42 03/24/15 09:01 D3 EPA 6020 Cobalt 9.1 mg/kg 3.5 03/24/15 09:01 D3 EPA 6020 Lead 15.5 mg/kg 3.5 03/24/15 09:01 D3 EPA 6020 Selenium 16.9 mg/kg 3.5 03/24/15 09:01 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 9 of 87 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Pace Analytical Services, Inc. P360916fY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15030402 92241387 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92241387004 2015007396 EPA 6020 Vanadium 58.2 mg/kg 3.5 03/24/15 09:01 D4 EPA 7471 Mercury 0.35 mg/kg 0.011 03/24/15 16:43 ASTM D2974-87 Percent Moisture 28.3 % 0.10 03/24/15 13:54 EPA 9045 pH at 25 Degrees C 8.3 Std. Units 0.10 03/19/15 13:45 H6 EPA 9060 Total Organic Carbon 110000 mg/kg 5410 03/24/15 15:43 EPA 9060 Total Organic Carbon 102000 mg/kg 5280 03/24/15 15:50 EPA 9060 Total Organic Carbon 121000 mg/kg 5360 03/24/15 15:55 EPA 9060 Total Organic Carbon 146000 mg/kg 5290 03/24/15 16:00 EPA 9060 Mean Total Organic Carbon 120000 mg/kg 5330 03/24/15 15:43 EPA 9060 RSD% 15.8 % 03/24/15 15:43 92241387005 2015007393 EPA 6010 Aluminum 16500 mg/kg 6.3 03/24/15 11:28 EPA 6010 Barium 197 mg/kg 0.63 03/24/15 11:28 EPA 6010 Beryllium 1.9 mg/kg 0.32 03/24/15 15:19 D3 EPA 6010 Boron 38.9 mg/kg 15.8 03/24/15 15:19 D3 EPA 6010 Calcium 1470 mg/kg 31.7 03/24/15 11:28 EPA 6010 Chromium 25.4 mg/kg 1.6 03/24/15 15:19 D3 EPA 6010 Copper 36.2 mg/kg 1.6 03/24/15 15:19 D3 EPA 6010 Iron 17000 mg/kg 2.5 03/24/15 11:28 EPA 6010 Magnesium 1350 mg/kg 31.7 03/24/15 11:28 EPA 6010 Manganese 199 mg/kg 1.6 03/24/15 15:19 D3 EPA 6010 Molybdenum 1.5 mg/kg 0.63 03/24/15 11:28 EPA 6010 Nickel 13.1 mg/kg 0.32 03/24/15 11:28 EPA 6010 Potassium 2250 mg/kg 63.3 03/24/15 11:28 EPA 6010 Sodium 172 mg/kg 63.3 03/24/15 11:28 EPA 6010 Strontium 124 mg/kg 0.63 03/24/15 11:28 EPA 6010 Zinc 29.3 mg/kg 1.3 03/24/15 11:28 EPA 6020 Arsenic 58.8 mg/kg 3.2 03/24/15 09:04 D4 EPA 6020 Cadmium 0.33J mg/kg 0.38 03/24/15 09:04 D3 EPA 6020 Cobalt 14.1 mg/kg 3.2 03/24/15 09:04 D3 EPA 6020 Lead 17.9 mg/kg 3.2 03/24/15 09:04 D3 EPA 6020 Selenium 6.9 mg/kg 3.2 03/24/15 09:04 D3 EPA 6020 Vanadium 59.0 mg/kg 3.2 03/24/15 09:04 D4 EPA 7471 Mercury 0.18 mg/kg 0.0098 03/24/15 16:46 ASTM D2974-87 Percent Moisture 21.4 % 0.10 03/24/15 13:54 EPA 9045 pH at 25 Degrees C 7.8 Std. Units 0.10 03/19/15 13:45 H6 EPA 300.0 Sulfate 4.5 mg/L 2.5 04/01/1510:46 B EPA 353.2 Nitrogen, Nitrate 22.9 mg/L 0.25 03/31/1516:31 B,H1 EPA 9060 Total Organic Carbon 21400 mg/kg 760 03/24/15 16:54 EPA 9060 Total Organic Carbon 18100 mg/kg 766 03/24/15 17:01 EPA 9060 Total Organic Carbon 15900 mg/kg 757 03/24/15 17:07 EPA 9060 Total Organic Carbon 18600 mg/kg 769 03/24/15 17:14 EPA 9060 Mean Total Organic Carbon 18500 mg/kg 763 03/24/15 16:54 EPA 9060 RSD% 12.2 % 03/24/15 16:54 92241387006 2015007394 EPA 6010 Aluminum 15900 mg/kg 5.5 03/24/15 11:33 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 87 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Pace Analytical Services, Inc. PA O S16fY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15030402 92241387 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92241387006 2015007394 EPA 6010 Barium 88.5 mg/kg 0.55 03/24/15 11:33 EPA 6010 Beryllium 0.48 mg/kg 0.28 03/24/15 15:23 D3 EPA 6010 Boron 22.7 mg/kg 13.9 03/24/15 15:23 D3 EPA 6010 Calcium 165 mg/kg 27.7 03/24/15 11:33 EPA 6010 Chromium 17.6 mg/kg 1.4 03/24/15 15:23 D3 EPA 6010 Copper 25.1 mg/kg 1.4 03/24/15 15:23 D3 EPA 6010 Iron 27500 mg/kg 11.1 03/24/15 15:23 D3 EPA 6010 Magnesium 4960 mg/kg 27.7 03/24/15 11:33 EPA 6010 Manganese 191 mg/kg 1.4 03/24/15 15:23 D3 EPA 6010 Nickel 5.4 mg/kg 0.28 03/24/15 11:33 EPA 6010 Potassium 4350 mg/kg 55.4 03/24/15 11:33 EPA 6010 Sodium 59.4 mg/kg 55.4 03/24/15 11:33 EPA 6010 Strontium 2.4 mg/kg 0.55 03/24/15 11:33 EPA 6010 Zinc 69.0 mg/kg 1.1 03/24/15 11:33 EPA 6020 Arsenic 1.91 mg/kg 2.8 03/24/15 09:17 D3 EPA 6020 Cobalt 10.2 mg/kg 2.8 03/24/15 09:17 D3 EPA 6020 Lead 4.1 mg/kg 2.8 03/24/15 09:17 D3 EPA 6020 Selenium 2.6J mg/kg 2.8 03/24/15 09:17 D3 EPA 6020 Vanadium 25.2 mg/kg 2.8 03/24/15 09:17 D4 EPA 7471 Mercury 0.010 mg/kg 0.0087 03/24/15 16:48 ASTM D2974-87 Percent Moisture 10.1 % 0.10 03/24/15 13:54 EPA 9045 pH at 25 Degrees C 7.2 Std. Units 0.10 03/19/15 13:45 H6 EPA 300.0 Sulfate 14.6 mg/L 4.5 04/02/1512:08 B,D3 EPA 353.2 Nitrogen, Nitrate 467 mg/L 22.3 03/31/1518:48 B,H1,M6 EPA 9060 Total Organic Carbon 9530 mg/kg 665 03/24/15 17:20 EPA 9060 Total Organic Carbon 11700 mg/kg 674 03/24/15 17:27 EPA 9060 Total Organic Carbon 9900 mg/kg 667 03/24/15 17:34 EPA 9060 Total Organic Carbon 12500 mg/kg 664 03/24/15 17:41 EPA 9060 Mean Total Organic Carbon 10900 mg/kg 668 03/24/15 17:20 EPA 9060 RSD% 13.0 % 03/24/15 17:20 92241387007 2015007397 EPA 6010 Aluminum 10900 mg/kg 6.5 03/24/15 11:37 EPA 6010 Barium 166 mg/kg 0.65 03/24/15 11:37 EPA 6010 Beryllium 1.3 mg/kg 0.32 03/24/15 15:28 D3 EPA 6010 Boron 25.1 mg/kg 16.2 03/24/15 15:28 D3 EPA 6010 Calcium 1130 mg/kg 32.4 03/24/15 11:37 EPA 6010 Chromium 52.7 mg/kg 1.6 03/24/15 15:28 D3 EPA 6010 Copper 33.1 mg/kg 1.6 03/24/15 15:28 D3 EPA 6010 Iron 20500 mg/kg 2.6 03/24/15 11:37 EPA 6010 Magnesium 1250 mg/kg 32.4 03/24/15 11:37 EPA 6010 Manganese 334 mg/kg 1.6 03/24/15 15:28 D3 EPA 6010 Molybdenum 1.1 mg/kg 0.65 03/24/15 11:37 EPA 6010 Nickel 8.1 mg/kg 0.32 03/24/15 11:37 EPA 6010 Potassium 1720 mg/kg 64.9 03/24/15 11:37 EPA 6010 Sodium 85.1 mg/kg 64.9 03/24/15 11:37 EPA 6010 Strontium 46.0 mg/kg 0.65 03/24/15 11:37 EPA 6010 Zinc 28.1 mg/kg 1.3 03/24/15 11:37 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 87 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Pace Analytical Services, Inc. PARGArWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15030402 92241387 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92241387007 2015007397 EPA 6020 Arsenic 16.1 mg/kg 3.2 03/24/15 09:20 D3 EPA 6020 Cobalt 10.8 mg/kg 3.2 03/24/15 09:20 D3 EPA 6020 Lead 12.8 mg/kg 3.2 03/24/15 09:20 D3 EPA 6020 Selenium 3.6 mg/kg 3.2 03/24/15 09:20 D3 EPA 6020 Vanadium 39.1 mg/kg 3.2 03/24/15 09:20 D4 EPA 7471 Mercury 0.12 mg/kg 0.011 03/24/15 16:54 ASTM D2974-87 Percent Moisture 24.2 % 0.10 03/24/15 13:55 EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 03/19/15 13:45 H6 EPA 300.0 Sulfate 13.6 mg/L 13.2 04/01/1511:13 B,D3 EPA 353.2 Nitrogen, Nitrate 317 mg/L 13.2 03/31/1518:56 B,H1,M6 EPA 9060 Total Organic Carbon 32800 mg/kg 3240 03/24/15 19:38 EPA 9060 Total Organic Carbon 34400 mg/kg 3270 03/24/15 19:44 EPA 9060 Total Organic Carbon 40200 mg/kg 3260 03/24/15 19:50 EPA 9060 Total Organic Carbon 34000 mg/kg 3280 03/24/15 19:55 EPA 9060 Mean Total Organic Carbon 35400 mg/kg 3260 03/24/15 19:38 EPA 9060 RSD% 9.4 % 03/24/15 19:38 92241387008 2015007398 EPA 6010 Aluminum 20700 mg/kg 34.5 03/24/15 15:32 D3 EPA 6010 Barium 220 mg/kg 3.4 03/24/15 15:32 D3 EPA 6010 Beryllium 1.0 mg/kg 0.34 03/24/15 15:32 D3 EPA 6010 Boron 10.8J mg/kg 17.2 03/24/15 15:32 D3 EPA 6010 Calcium 246 mg/kg 172 03/24/15 15:32 D3 EPA 6010 Chromium 21.4 mg/kg 1.7 03/24/15 15:32 D3 EPA 6010 Copper 24.6 mg/kg 1.7 03/24/15 15:32 D3 EPA 6010 Iron 12900 mg/kg 13.8 03/24/15 15:32 D3 EPA 6010 Magnesium 4250 mg/kg 172 03/24/15 15:32 D3 EPA 6010 Manganese 71.8 mg/kg 1.7 03/24/15 15:32 D3 EPA 6010 Nickel 11.5 mg/kg 1.7 03/24/15 15:32 D3 EPA 6010 Potassium 3150 mg/kg 345 03/24/15 15:32 D3 EPA 6010 Strontium 3.7 mg/kg 3.4 03/24/15 15:32 D3 EPA 6010 Zinc 72.1 mg/kg 6.9 03/24/15 15:32 D3 EPA 6020 Arsenic 1.8J mg/kg 3.4 03/24/15 09:23 D3 EPA 6020 Cobalt 6.6 mg/kg 3.4 03/24/15 09:23 D3 EPA 6020 Lead 4.4 mg/kg 3.4 03/24/15 09:23 D3 EPA 6020 Selenium 2AJ mg/kg 3.4 03/24/15 09:23 D3 EPA 6020 Vanadium 26.4 mg/kg 3.4 03/24/15 09:23 D3 EPA 7471 Mercury 0.0082J mg/kg 0.010 03/24/15 16:56 ASTM D2974-87 Percent Moisture 25.0 % 0.10 03/24/15 13:55 EPA 9045 pH at 25 Degrees C 6.2 Std. Units 0.10 03/19/15 13:45 H6 EPA 300.0 Sulfate 3.8 mg/L 2.7 04/01/1511:26 B EPA 353.2 Nitrogen, Nitrate 17.6 mg/L 1.3 03/31/1518:01 B,H1 EPA 9060 Total Organic Carbon 3710 mg/kg 806 03/24/15 18:11 EPA 9060 Total Organic Carbon 3350 mg/kg 794 03/24/15 18:18 EPA 9060 Total Organic Carbon 3470 mg/kg 797 03/24/15 18:24 EPA 9060 Total Organic Carbon 2940 mg/kg 805 03/24/15 18:30 EPA 9060 Mean Total Organic Carbon 3370 mg/kg 801 03/24/15 18:11 EPA 9060 RSD% 9.6 % 03/24/15 18:11 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 87 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Pace Analytical Services, Inc. PARGArWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15030402 92241387 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92241387009 2015007399 EPA 6010 Aluminum 6580 mg/kg 59.7 03/24/15 15:36 D3 EPA 6010 Barium 31.5 mg/kg 6.0 03/24/15 15:36 D3 EPA 6010 Beryllium 0.52J mg/kg 0.60 03/24/15 15:36 D3 EPA 6010 Boron 15.91 mg/kg 29.8 03/24/15 15:36 D3 EPA 6010 Calcium 239J mg/kg 298 03/24/15 15:36 D3 EPA 6010 Chromium 4.6 mg/kg 3.0 03/24/15 15:36 D3 EPA 6010 Copper 68.9 mg/kg 3.0 03/24/15 15:36 D3 EPA 6010 Iron 19300 mg/kg 23.9 03/24/15 15:36 D3 EPA 6010 Magnesium 2130 mg/kg 298 03/24/15 15:36 D3 EPA 6010 Manganese 85.7 mg/kg 3.0 03/24/15 15:36 D3 EPA 6010 Nickel 8.1 mg/kg 3.0 03/24/15 15:36 D3 EPA 6010 Potassium 343J mg/kg 597 03/24/15 15:36 D3 EPA 6010 Zinc 30.9 mg/kg 11.9 03/24/15 15:36 D3 EPA 6020 Arsenic 5.6 mg/kg 3.0 03/24/15 09:26 D3 EPA 6020 Cobalt 5.5 mg/kg 3.0 03/24/15 09:26 D3 EPA 6020 Lead 2.5J mg/kg 3.0 03/24/15 09:26 D3 EPA 6020 Selenium 10.4 mg/kg 3.0 03/24/15 09:26 D3 EPA 6020 Vanadium 4.7 mg/kg 3.0 03/24/15 09:26 D3 ASTM D2974-87 Percent Moisture 17.2 % 0.10 03/24/15 13:56 EPA 9045 pH at 25 Degrees C 6.3 Std. Units 0.10 03/19/15 13:45 H6 EPA 300.0 Sulfate 13.8 mg/L 2.4 04/01/1511:40 B EPA 353.2 Nitrogen, Nitrate 207 mg/L 12.1 03/31/15 18:59 B,H1 EPA 9060 Total Organic Carbon 8140 mg/kg 726 03/24/15 18:48 EPA 9060 Total Organic Carbon 7400 mg/kg 732 03/24/15 18:54 EPA 9060 Total Organic Carbon 8110 mg/kg 722 03/24/15 19:00 EPA 9060 Total Organic Carbon 8230 mg/kg 729 03/24/15 19:07 EPA 9060 Mean Total Organic Carbon 7970 mg/kg 727 03/24/15 18:48 EPA 9060 RSD% 4.8 % 03/24/15 18:48 92241387010 2015007393 SPLP EPA 6020A Aluminum 6110 ug/L 10.0 04/02/15 10:29 EPA 6020A Antimony 1.0 ug/L 0.50 04/02/15 10:29 EPA 6020A Arsenic 25.5 ug/L 0.50 04/02/15 10:29 EPA 6020A Barium 72.4 ug/L 0.30 04/02/15 10:29 EPA 6020A Beryllium 0.23 ug/L 0.20 04/02/15 10:29 EPA 6020A Boron 676 ug/L 25.0 04/02/15 13:26 EPA 6020A Calcium 7340 ug/L 40.0 04/02/15 10:29 EPA 6020A Chromium 6.9 ug/L 0.50 04/02/15 10:29 EPA 6020A Cobalt 3.3 ug/L 0.50 04/02/15 10:29 EPA 6020A Copper 7.8 ug/L 1.0 04/02/15 10:29 EPA 6020A Iron 4360 ug/L 50.0 04/02/15 10:29 EPA 6020A Lead 3.0 ug/L 0.10 04/02/15 10:29 EPA 6020A Magnesium 2160 ug/L 10.0 04/02/15 10:29 EPA 6020A Manganese 161 ug/L 0.50 04/02/15 10:29 EPA 6020A Molybdenum 7.4 ug/L 0.50 04/02/15 10:29 EPA 6020A Nickel 2.9 ug/L 0.50 04/02/15 10:29 EPA 6020A Potassium 2140 ug/L 50.0 04/02/15 10:29 EPA 6020A Selenium 1.6 ug/L 0.50 04/02/15 10:29 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 87 aceAnaiXical www.pacelabs.com Project: J15030402 Pace Project No.: 92241387 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. PAROzl IWY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92241387010 2015007393 SPLP EPA 6020A Sodium 15200 ug/L 50.0 04/02/15 10:29 EPA 6020A Strontium 191 ug/L 0.50 04/02/15 10:29 EPA 6020A Thallium 0.20 ug/L 0.10 04/02/15 10:29 EPA 6020A Vanadium 18.0 ug/L 1.0 04/02/15 10:29 EPA 6020A Zinc 33.1 ug/L 5.0 04/02/15 10:29 92241387011 2015007394 SPLP EPA 6020A Aluminum 136 ug/L 10.0 04/02/15 10:33 EPA 6020A Antimony 0.65 ug/L 0.50 04/02/15 10:33 EPA 6020A Barium 418 ug/L 0.30 04/02/15 10:33 EPA 6020A Boron 155 ug/L 5.0 04/02/15 10:33 EPA 6020A Calcium 699 ug/L 40.0 04/02/15 10:33 EPA 6020A Chromium 18.5 ug/L 0.50 04/02/15 10:33 EPA 6020A Cobalt 0.88 ug/L 0.50 04/02/15 10:33 EPA 6020A Copper 12.4 ug/L 1.0 04/02/15 10:33 EPA 6020A Iron 210 ug/L 50.0 04/02/15 10:33 EPA 6020A Lead 2.2 ug/L 0.10 04/02/15 10:33 EPA 6020A Magnesium 196 ug/L 10.0 04/02/15 10:33 EPA 6020A Manganese 174 ug/L 0.50 04/02/15 10:33 EPA 6020A Molybdenum 1.7 ug/L 0.50 04/02/15 10:33 EPA 6020A Nickel 6.3 ug/L 0.50 04/02/15 10:33 EPA 6020A Potassium 1040 ug/L 50.0 04/02/15 10:33 EPA 6020A Selenium 1.1 ug/L 0.50 04/02/15 10:33 EPA 6020A Sodium 2320 ug/L 50.0 04/02/15 10:33 EPA 6020A Strontium 10.2 ug/L 0.50 04/02/15 10:33 EPA 6020A Thallium 0.13 ug/L 0.10 04/02/15 10:33 EPA 6020A Zinc 227 ug/L 5.0 04/02/15 10:33 92241387012 2015007397 SPLP EPA 6020A Aluminum 564 ug/L 10.0 04/02/15 10:38 EPA 6020A Antimony 0.56 ug/L 0.50 04/02/15 10:38 EPA 6020A Arsenic 4.2 ug/L 0.50 04/02/15 10:38 EPA 6020A Barium 938 ug/L 1.5 04/02/15 13:16 EPA 6020A Beryllium 0.36 ug/L 0.20 04/02/15 10:38 EPA 6020A Boron 183 ug/L 5.0 04/02/15 10:38 EPA 6020A Cadmium 0.24 ug/L 0.080 04/02/15 10:38 EPA 6020A Calcium 4330 ug/L 40.0 04/02/15 10:38 EPA 6020A Chromium 3.7 ug/L 0.50 04/02/15 10:38 EPA 6020A Cobalt 3.2 ug/L 0.50 04/02/15 10:38 EPA 6020A Copper 16.7 ug/L 1.0 04/02/15 10:38 EPA 6020A Iron 184 ug/L 50.0 04/02/15 10:38 EPA 6020A Lead 4.6 ug/L 0.10 04/02/15 10:38 EPA 6020A Magnesium 1020 ug/L 10.0 04/02/15 10:38 EPA 6020A Manganese 102 ug/L 0.50 04/02/15 10:38 EPA 6020A Molybdenum 1.0 ug/L 0.50 04/02/15 10:38 EPA 6020A Nickel 4.3 ug/L 0.50 04/02/15 10:38 EPA 6020A Potassium 2610 ug/L 50.0 04/02/15 10:38 EPA 6020A Sodium 2260 ug/L 50.0 04/02/15 10:38 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 87 aceAnaiXical www.pacelabs.com Project: J15030402 Pace Project No.: 92241387 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. PW1*r6fy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92241387012 2015007397 SPLP EPA 6020A Strontium 517 ug/L 2.5 04/02/15 13:16 EPA 6020A Thallium 0.74 ug/L 0.10 04/02/15 10:38 EPA 6020A Vanadium 1.9 ug/L 1.0 04/02/15 10:38 EPA 6020A Zinc 247 ug/L 5.0 04/02/15 10:38 92241387013 2015007398 SPLP EPA 6020A Aluminum 37400 ug/L 50.0 04/01/1510:34 EPA 6020A Arsenic 1.9 ug/L 0.50 03/31/1518:25 EPA 6020A Barium 240 ug/L 0.30 03/31/1518:25 EPA 6020A Beryllium 0.72 ug/L 0.20 03/31/1518:25 EPA 6020A Boron 114 ug/L 25.0 04/01/1510:34 EPA 6020A Calcium 1050 ug/L 40.0 03/31/1518:25 EPA 6020A Chromium 18.7 ug/L 0.50 03/31/1518:25 EPA 6020A Cobalt 1.6 ug/L 0.50 03/31/1518:25 EPA 6020A Copper 63.3 ug/L 1.0 03/31/1518:25 EPA 6020A Iron 3720 ug/L 50.0 03/31/1518:25 EPA 6020A Lead 6.1 ug/L 0.10 03/31/1518:25 EPA 6020A Magnesium 626 ug/L 10.0 03/31/1518:25 EPA 6020A Manganese 27.9 ug/L 0.50 03/31/1518:25 EPA 6020A Nickel 14.4 ug/L 0.50 03/31/1518:25 EPA 6020A Potassium 1730 ug/L 50.0 03/31/1518:25 EPA 6020A Sodium 3110 ug/L 50.0 03/31/1518:25 EPA 6020A Strontium 7.5 ug/L 0.50 03/31/1518:25 EPA 6020A Thallium 0.20 ug/L 0.10 03/31/1518:25 EPA 6020A Vanadium 28.2 ug/L 1.0 03/31/1518:25 EPA 6020A Zinc 24.8 ug/L 5.0 03/31/1518:25 92241387014 2015007399 SPLP EPA 6020A Aluminum 183 ug/L 10.0 04/02/15 10:53 EPA 6020A Arsenic 0.61 ug/L 0.50 04/02/15 10:53 EPA 6020A Barium 409 ug/L 0.30 04/02/15 10:53 EPA 6020A Boron 138 ug/L 5.0 04/02/15 10:53 EPA 6020A Calcium 791 ug/L 40.0 04/02/15 10:53 EPA 6020A Chromium 6.0 ug/L 0.50 04/02/15 10:53 EPA 6020A Cobalt 2.5 ug/L 0.50 04/02/15 10:53 EPA 6020A Copper 9.9 ug/L 1.0 04/02/15 10:53 EPA 6020A Iron 134 ug/L 50.0 04/02/15 10:53 EPA 6020A Lead 3.0 ug/L 0.10 04/02/15 10:53 EPA 6020A Magnesium 350 ug/L 10.0 04/02/15 10:53 EPA 6020A Manganese 54.7 ug/L 0.50 04/02/15 10:53 EPA 6020A Molybdenum 1.9 ug/L 0.50 04/02/15 10:53 EPA 6020A Nickel 3.5 ug/L 0.50 04/02/15 10:53 EPA 6020A Potassium 2090 ug/L 50.0 04/02/15 10:53 EPA 6020A Sodium 2280 ug/L 50.0 04/02/15 10:53 EPA 6020A Strontium 11.6 ug/L 0.50 04/02/15 10:53 EPA 6020A Zinc 212 ug/L 5.0 04/02/15 10:53 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 15 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARGArWY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 13, 2015 General Information: 8 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23201 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241387002 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1162649) • Aluminum • Barium • Calcium • Iron • Potassium • Strontium • MSD (Lab ID: 1162650) • Aluminum • Barium • Boron • Calcium • Iron • Potassium • Strontium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARGArWY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 13, 2015 Analyte Comments: QC Batch: MPRP/23201 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007393 (Lab ID: 92241387005) • Boron • Beryllium • Chromium • Copper • Manganese •2015007394 (Lab ID: 92241387006) • Boron • Beryllium • Chromium • Copper • Iron • Manganese •2015007395 (Lab ID: 92241387003) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015007396 (Lab ID: 92241387004) • Boron • Beryllium • Chromium • Copper • Manganese •2015007397 (Lab ID: 92241387007) • Boron • Beryllium • Chromium • Copper • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PWIbrwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 13, 2015 Analyte Comments: QC Batch: MPRP/23201 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007398 (Lab ID: 92241387008) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015007399 (Lab ID: 92241387009) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36gmirpY&.. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 13, 2015 General Information: 8 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23202 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241387002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1162653) • Antimony • Arsenic • Cadmium • Cobalt • Lead • Selenium • Thallium • Vanadium • MSD (Lab ID: 1162654) • Antimony • Arsenic • Cadmium • Cobalt REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PW1*r6fy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 13, 2015 QC Batch: MPRP/23202 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241387002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • Lead • Selenium • Thallium • Vanadium R1: RPD value was outside control limits. • MSD (Lab ID: 1162654) • Antimony • Arsenic • Cadmium • Cobalt • Lead • Selenium • Thallium • Vanadium Additional Comments: Analyte Comments: QC Batch: MPRP/23202 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007393 (Lab ID:92241387005) • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015007394 (Lab ID:92241387006) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015007395 (Lab ID:92241387003) • Arsenic • Cadmium • Lead • Antimony • Selenium • Thallium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36911rWY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 13, 2015 Analyte Comments: QC Batch: MPRP/23202 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007396 (Lab ID:92241387004) • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015007397 (Lab ID:92241387007) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015007398 (Lab ID:92241387008) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015007399 (Lab ID:92241387009) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium D4: Sample was diluted due to the presence of high levels of target analytes. •2015007393 (Lab ID: 92241387005) • Arsenic • Vanadium •2015007394 (Lab ID: 92241387006) • Vanadium •2015007395 (Lab ID: 92241387003) • Cobalt • Vanadium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PAROAir6fY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 13, 2015 Analyte Comments: QC Batch: MPRP/23202 D4: Sample was diluted due to the presence of high levels of target analytes. •2015007396 (Lab ID: 92241387004) • Arsenic • Vanadium •2015007397 (Lab ID: 92241387007) • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •2015007392 (Lab ID:92241387002) • Antimony •2015007393 (Lab ID:92241387005) • Antimony •2015007394 (Lab ID:92241387006) • Antimony •2015007395 (Lab ID:92241387003) • Antimony •2015007396 (Lab ID:92241387004) • Antimony •2015007397 (Lab ID:92241387007) • Antimony •2015007398 (Lab ID:92241387008) • Antimony •2015007399 (Lab ID:92241387009) • Antimony • BLANK (Lab ID: 1162651) • Antimony • LCS (Lab ID: 1162652) • Antimony • MS (Lab ID: 1162653) • Antimony • MSD (Lab ID: 1162654) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARIArWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: April 13, 2015 General Information: 6 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/53084 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241387001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1922978) • Aluminum QC Batch: MPRP/53234 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10301215001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1928546) • Aluminum • Calcium • Sodium • MSD (Lab ID: 1928547) • Aluminum REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 87 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: April 13, 2015 QC Batch: MPRP/53309 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241387014 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1929569) • Aluminum Additional Comments: Analyte Comments: Pace Analytical Services, Inc. PARGArWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QC Batch: MPRP/53234 P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1927025) • Copper REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. POQ WY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: April 13, 2015 General Information: 6 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/13085 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241387013 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1929417) • Mercury R1: RPD value was outside control limits. • MSD (Lab ID: 1929418) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARGArWY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: April 13, 2015 General Information: 8 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5501 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241387002 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1164066) • Mercury • MSD (Lab ID: 1164067) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARIArWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: April 13, 2015 General Information: 8 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-16: Analysis initiated outside of the 15 minute EPA recommended holding time. •2015007392 (Lab ID:92241387002) •2015007393 (Lab ID:92241387005) •2015007394 (Lab ID:92241387006) •2015007395 (Lab ID:92241387003) •2015007396 (Lab ID:92241387004) •2015007397 (Lab ID:92241387007) •2015007398 (Lab ID:92241387008) •2015007399 (Lab ID:92241387009) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WET/29835 •2015007392 (Lab ID: 92241387002) • pH at 25 Degrees C •2015007393 (Lab ID: 92241387005) • pH at 25 Degrees C •2015007394 (Lab ID: 92241387006) • pH at 25 Degrees C •2015007395 (Lab ID: 92241387003) • pH at 25 Degrees C •2015007396 (Lab ID: 92241387004) • pH at 25 Degrees C •2015007397 (Lab ID: 92241387007) • pH at 25 Degrees C •2015007398 (Lab ID: 92241387008) • pH at 25 Degrees C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 87 aceAnaiXical www.pacelabs.com Project: J15030402 Pace Project No.: 92241387 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: April 13, 2015 Analyte Comments: QC Batch: WET/29835 •2015007399 (Lab ID: 92241387009) • pH at 25 Degrees C Pace Analytical Services, Inc. P369041bir6fY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904fflirWY(t" Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: April 13, 2015 General Information: 5 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22391 B: Analyte was detected in the associated method blank. • BLANK for HBN 257604 [WETA/223 (Lab ID: 1422986) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/22391 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007394 (Lab ID: 92241387006) • Sulfate •2015007397 (Lab ID: 92241387007) • Sulfate • BLANK (Lab ID: 1422986) • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 87 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: April 13, 2015 General Information: 5 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015007393 (Lab ID: 92241387005) •2015007394 (Lab ID: 92241387006) •2015007397 (Lab ID: 92241387007) •2015007398 (Lab ID: 92241387008) •2015007399 (Lab ID: 92241387009) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22397 B: Analyte was detected in the associated method blank. • BLANK for HBN 257672 [WETA/223 (Lab ID: 1423312) • Nitrogen, Nitrate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/22397 Pace Analytical Services, Inc. P36904K WeY&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241387006,92241387007 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1423314) • Nitrogen, Nitrate • MS (Lab ID: 1423316) • Nitrogen, Nitrate • MSD (Lab ID: 1423315) • Nitrogen, Nitrate • MSD (Lab ID: 1423317) • Nitrogen, Nitrate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 87 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: April 13, 2015 Additional Comments: Analyte Comments: QC Batch: WETA/22397 Pace Analytical Services, Inc. P36904K WeY&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1423312) • Nitrogen, Nitrate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 87 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: SM 4500 -CI -E Description: 4500 Chloride, SPLP Client: Duke Energy Date: April 13, 2015 Pace Analytical Services, Inc. P369041�ir6fY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 General Information: 5 samples were analyzed for SM 4500 -CI -E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/22349 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007394 (Lab ID: 92241387006) • Chloride REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P369041 WeY&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: April 13, 2015 General Information: 8 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44698 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007392 (Lab ID:92241387002) • Chloride • Sulfate •2015007393 (Lab ID:92241387005) • Chloride • Sulfate •2015007394 (Lab ID:92241387006) • Chloride • Sulfate •2015007395 (Lab ID:92241387003) • Chloride • Sulfate •2015007396 (Lab ID:92241387004) • Chloride • Sulfate •2015007397 (Lab ID:92241387007) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 33 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P369041 WeY046e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: April 13, 2015 Analyte Comments: QC Batch: WETA/44698 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007398 (Lab ID: 92241387008) • Chloride • Sulfate •2015007399 (Lab ID: 92241387009) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 34 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904f WeY046e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: April 13, 2015 General Information: 8 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015007392 (Lab ID:92241387002) •2015007393 (Lab ID:92241387005) •2015007394 (Lab ID:92241387006) •2015007395 (Lab ID:92241387003) •2015007396 (Lab ID:92241387004) •2015007397 (Lab ID:92241387007) •2015007398 (Lab ID:92241387008) •2015007399 (Lab ID:92241387009) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44700 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007392 (Lab ID: 92241387002) • Nitrate as N •2015007393 (Lab ID: 92241387005) • Nitrate as N •2015007394 (Lab ID: 92241387006) • Nitrate as N •2015007395 (Lab ID: 92241387003) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 35 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P369041 WeY&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: April 13, 2015 Analyte Comments: QC Batch: WETA/44700 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007396 (Lab ID: 92241387004) • Nitrate as N •2015007397 (Lab ID: 92241387007) • Nitrate as N •2015007398 (Lab ID: 92241387008) • Nitrate as N •2015007399 (Lab ID: 92241387009) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 36 of 87 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904f WeY&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030402 Pace Project No.: 92241387 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: April 13, 2015 General Information: 8 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 37 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. PO05k WY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015007400 Lab ID: 92241387001 Collected: 03/12/15 12:45 Received: 03/16/15 15:08 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/13/2015 04:11 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 106 ug/L 10.0 1.2 1 03/22/15 16:10 03/23/15 09:49 7429-90-5 M1 ND ug/L 0.50 0.25 1 03/22/15 16:10 03/23/15 09:49 7440-36-0 ND ug/L 0.50 0.25 1 03/22/15 16:10 03/23/15 09:49 7440-38-2 2.8 ug/L 0.30 0.14 1 03/22/15 16:10 03/23/15 09:49 7440-39-3 ND ug/L 0.20 0.066 1 03/22/15 16:10 03/23/15 09:49 7440-41-7 ND ug/L 5.0 1.0 1 03/22/15 16:10 03/23/15 09:49 7440-42-8 ND ug/L 0.080 0.033 1 03/22/15 16:10 03/23/15 09:49 7440-43-9 245 ug/L 40.0 8.4 1 03/22/15 16:10 03/23/15 09:49 7440-70-2 0.90 ug/L 0.50 0.22 1 03/22/15 16:10 03/23/15 09:49 7440-47-3 1.1 ug/L 0.50 0.25 1 03/22/15 16:10 03/23/15 09:49 7440-48-4 ND ug/L 1.0 0.22 1 03/22/15 16:10 03/23/15 09:49 7440-50-8 489 ug/L 50.0 8.0 1 03/22/15 16:10 03/23/15 09:49 7439-89-6 0.11 ug/L 0.10 0.046 1 03/22/15 16:10 03/23/15 09:49 7439-92-1 36.5 ug/L 10.0 2.8 1 03/22/15 16:10 03/23/15 09:49 7439-95-4 10.3 ug/L 0.50 0.14 1 03/22/15 16:10 03/23/15 09:49 7439-96-5 ND ug/L 0.50 0.24 1 03/22/15 16:10 03/23/15 09:49 7439-98-7 ND ug/L 0.50 0.23 1 03/22/15 16:10 03/23/15 09:49 7440-02-0 73.0 ug/L 50.0 8.3 1 03/22/15 16:10 03/23/15 09:49 7440-09-7 ND ug/L 0.50 0.25 1 03/22/15 16:10 03/23/15 09:49 7782-49-2 ND ug/L 50.0 18.2 1 03/22/15 16:10 03/23/15 09:49 7440-23-5 0.70 ug/L 0.50 0.057 1 03/22/15 16:10 03/23/15 09:49 7440-24-6 ND ug/L 0.10 0.025 1 03/22/15 16:10 03/23/15 09:49 7440-28-0 ND ug/L 1.0 0.21 1 03/22/15 16:10 03/23/15 09:49 7440-62-2 ND ug/L 5.0 2.5 1 03/22/15 16:10 03/23/15 09:49 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.026 1 03/23/1516:50 03/24/1517:36 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 38 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. PggcO )irpy&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 Sample: 2015007392 Lab ID: 92241387002 Collected: 03/12/15 12:55 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 6360 mg/kg 6.0 3.0 1 03/21/1518:50 03/24/1510:39 7429-90-5 M1 Barium 368 mg/kg 0.60 0.30 1 03/21/1518:50 03/24/1510:39 7440-39-3 M1 Beryllium 1.5 mg/kg 0.060 0.030 1 03/21/1518:50 03/24/1510:39 7440-41-7 Boron 13.1 mg/kg 3.0 1.5 1 03/21/1518:50 03/24/1510:39 7440-42-8 M1 Calcium 2870 mg/kg 30.1 15.0 1 03/21/1518:50 03/24/1510:39 7440-70-2 M1 Chromium 12.0 mg/kg 0.30 0.15 1 03/21/1518:50 03/24/1510:39 7440-47-3 Copper 23.6 mg/kg 0.30 0.15 1 03/21/1518:50 03/24/1510:39 7440-50-8 Iron 5150 mg/kg 2.4 1.2 1 03/21/1518:50 03/24/1510:39 7439-89-6 M1 Magnesium 659 mg/kg 30.1 15.0 1 03/21/1518:50 03/24/1510:39 7439-95-4 Manganese 46.6 mg/kg 0.30 0.15 1 03/21/1518:50 03/24/1510:39 7439-96-5 Molybdenum 1.1 mg/kg 0.60 0.30 1 03/21/1518:50 03/24/1510:39 7439-98-7 Nickel 9.6 mg/kg 0.30 0.15 1 03/21/1518:50 03/24/1510:39 7440-02-0 Potassium 1010 mg/kg 60.1 30.1 1 03/21/1518:50 03/24/1510:39 7440-09-7 M1 Sodium 147 mg/kg 60.1 30.1 1 03/21/1518:50 03/24/1510:39 7440-23-5 Strontium 115 mg/kg 0.60 0.30 1 03/21/1518:50 03/24/1510:39 7440-24-6 M1 Zinc 14.9 mg/kg 1.2 0.60 1 03/21/1518:50 03/24/1510:39 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.0 1.5 50 03/21/1518:50 03/24/1508:40 7440-36-0 M6, N2, R1 Arsenic 59.9 mg/kg 3.0 1.5 50 03/21/1518:50 03/24/1508:40 7440-38-2 M6,R1 Cadmium 0.20J mg/kg 0.36 0.18 50 03/21/1518:50 03/24/1508:40 7440-43-9 M6,R1 Cobalt 6.6 mg/kg 3.0 1.5 50 03/21/1518:50 03/24/1508:40 7440-48-4 M6,R1 Lead 8.8 mg/kg 3.0 1.5 50 03/21/1518:50 03/24/1508:40 7439-92-1 M6,R1 Selenium 14.6 mg/kg 3.0 1.5 50 03/21/1518:50 03/24/1508:40 7782-49-2 M6,R1 Thallium ND mg/kg 3.0 1.5 50 03/21/1518:50 03/24/1508:40 7440-28-0 M6,R1 Vanadium 39.9 mg/kg 3.0 1.5 50 03/21/1518:50 03/24/1508:40 7440-62-2 M6,R1 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.17 mg/kg 0.0097 0.0048 1 03/24/1513:02 03/24/1516:33 7439-97-6 M1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 16.3 % 0.10 0.10 1 03/24/15 13:53 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 8.1 Std. Units 0.10 0.10 1 03/19/15 13:45 H6 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 293 147 5 03/20/15 06:54 16887-00-6 D3 Sulfate ND mg/kg 293 147 5 03/20/15 06:54 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 29.3 14.7 5 03/20/15 06:54 14797-55-8 D3,H3 Date: 04/13/2015 04:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 39 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. PO05kf WY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015007392 Lab ID: 92241387002 Collected: 03/12/15 12:55 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 64900 mg/kg 5940 2970 1 03/23/15 12:28 7440-44-0 Total Organic Carbon 80100 mg/kg 5830 2920 1 03/23/15 12:34 7440-44-0 Total Organic Carbon 80500 mg/kg 5940 2970 1 03/23/15 12:46 7440-44-0 Total Organic Carbon 86000 mg/kg 5960 2980 1 03/23/15 13:01 7440-44-0 Mean Total Organic Carbon 77900 mg/kg 5920 2960 1 03/23/15 12:28 7440-44-0 Surrogates RSD% 11.6 % 1 03/23/1512:28 Date: 04/13/2015 04:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 40 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. PO05kf WY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015007395 Lab ID: 92241387003 Collected: 03/12/15 14:00 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 04/13/2015 04:11 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 53700 mg/kg 153 76.6 25 03/21/15 18:50 03/24/15 15:10 7429-90-5 678 mg/kg 15.3 7.7 25 03/21/1518:50 03/24/1515:10 7440-39-3 2.2 mg/kg 0.31 0.15 5 03/21/1518:50 03/24/1515:06 7440-41-7 38.7 mg/kg 15.3 7.7 5 03/21/15 18:50 03/24/15 15:06 7440-42-8 459 mg/kg 153 76.6 5 03/21/1518:50 03/24/1515:06 7440-70-2 112 mg/kg 7.7 3.8 25 03/21/1518:50 03/24/1515:10 7440-47-3 27.3 mg/kg 7.7 3.8 25 03/21/15 18:50 03/24/15 15:10 7440-50-8 53100 mg/kg 61.3 30.7 25 03/21/1518:50 03/24/1515:10 7439-89-6 14900 mg/kg 766 383 25 03/21/15 18:50 03/24/15 15:10 7439-95-4 2190 mg/kg 7.7 3.8 25 03/21/1518:50 03/24/1515:10 7439-96-5 ND mg/kg 3.1 1.5 5 03/21/1518:50 03/24/1515:06 7439-98-7 48.5 mg/kg 7.7 3.8 25 03/21/15 18:50 03/24/15 15:10 7440-02-0 11300 mg/kg 1530 766 25 03/21/1518:50 03/24/1515:10 7440-09-7 ND mg/kg 307 153 5 03/21/1518:50 03/24/1515:06 7440-23-5 7.2 mg/kg 3.1 1.5 5 03/21/15 18:50 03/24/15 15:06 7440-24-6 138 mg/kg 30.7 15.3 25 03/21/15 18:50 03/24/15 15:10 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.1 1.5 50 03/21/1518:50 03/24/1508:49 7440-36-0 1.6J mg/kg 3.1 1.5 50 03/21/15 18:50 03/24/15 08:49 7440-38-2 ND mg/kg 0.37 0.18 50 03/21/15 18:50 03/24/15 08:49 7440-43-9 49.3 mg/kg 3.1 1.5 50 03/21/15 18:50 03/24/15 08:49 7440-48-4 25.8 mg/kg 3.1 1.5 50 03/21/1518:50 03/24/1508:49 7439-92-1 3.2 mg/kg 3.1 1.5 50 03/21/15 18:50 03/24/15 08:49 7782-49-2 ND mg/kg 3.1 1.5 50 03/21/15 18:50 03/24/15 08:49 7440-28-0 71.4 mg/kg 3.1 1.5 50 03/21/15 18:50 03/24/15 08:49 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.010 0.0050 1 03/24/1513:02 03/24/1516:39 7439-97-6 Analytical Method: ASTM D2974-87 16.9 % 0.10 0.10 1 03/24/1513:53 Analytical Method: EPA 9045 6.3 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 299 150 5 ND mg/kg 299 150 5 Analytical Method: EPA 9056 ND mg/kg 29.9 15.0 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3,N2 D3 D3 D4 D3 D3 D3 D4 03/20/15 07:15 16887-00-6 D3 03/20/15 07:15 14808-79-8 D3 03/20/15 07:15 14797-55-8 D3,H3 Page 41 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. PAMIirWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015007395 Lab ID: 92241387003 Collected: 03/12/15 14:00 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 777 mg/kg 725 363 1 03/24/15 19:13 7440-44-0 Total Organic Carbon 485J mg/kg 724 362 1 03/24/15 19:19 7440-44-0 Total Organic Carbon 431J mg/kg 728 364 1 03/24/15 19:24 7440-44-0 Total Organic Carbon 440J mg/kg 720 360 1 03/24/15 19:31 7440-44-0 Mean Total Organic Carbon 533J mg/kg 724 362 1 03/24/15 19:13 7440-44-0 Surrogates RSD% 30.8 % 1 03/24/1519:13 Date: 04/13/2015 04:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 42 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. PAROAirWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015007396 Lab ID: 92241387004 Collected: 03/12/15 17:15 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 04/13/2015 04:11 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 8700 mg/kg 7.0 3.5 1 03/21/15 18:50 03/24/15 11:23 7429-90-5 444 mg/kg 0.70 0.35 1 03/21/1518:50 03/24/1511:23 7440-39-3 2.8 mg/kg 0.35 0.17 5 03/21/1518:50 03/24/1515:15 7440-41-7 19.3 mg/kg 17.4 8.7 5 03/21/15 18:50 03/24/15 15:15 7440-42-8 1770 mg/kg 34.9 17.4 1 03/21/1518:50 03/24/1511:23 7440-70-2 20.4 mg/kg 1.7 0.87 5 03/21/1518:50 03/24/1515:15 7440-47-3 39.5 mg/kg 1.7 0.87 5 03/21/15 18:50 03/24/15 15:15 7440-50-8 6220 mg/kg 2.8 1.4 1 03/21/15 18:50 03/24/15 11:23 7439-89-6 803 mg/kg 34.9 17.4 1 03/21/15 18:50 03/24/15 11:23 7439-95-4 60.1 mg/kg 1.7 0.87 5 03/21/1518:50 03/24/1515:15 7439-96-5 1.2 mg/kg 0.70 0.35 1 03/21/1518:50 03/24/1511:23 7439-98-7 13.8 mg/kg 0.35 0.17 1 03/21/15 18:50 03/24/15 11:23 7440-02-0 1640 mg/kg 69.7 34.9 1 03/21/1518:50 03/24/1511:23 7440-09-7 233 mg/kg 69.7 34.9 1 03/21/1518:50 03/24/1511:23 7440-23-5 141 mg/kg 0.70 0.35 1 03/21/15 18:50 03/24/15 11:23 7440-24-6 22.7 mg/kg 1.4 0.70 1 03/21/15 18:50 03/24/15 11:23 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.5 1.7 50 03/21/1518:50 03/24/1509:01 7440-36-0 91.5 mg/kg 3.5 1.7 50 03/21/15 18:50 03/24/15 09:01 7440-38-2 0.30J mg/kg 0.42 0.21 50 03/21/15 18:50 03/24/15 09:01 7440-43-9 9.1 mg/kg 3.5 1.7 50 03/21/15 18:50 03/24/15 09:01 7440-48-4 15.5 mg/kg 3.5 1.7 50 03/21/15 18:50 03/24/15 09:01 7439-92-1 16.9 mg/kg 3.5 1.7 50 03/21/15 18:50 03/24/15 09:01 7782-49-2 ND mg/kg 3.5 1.7 50 03/21/15 18:50 03/24/15 09:01 7440-28-0 58.2 mg/kg 3.5 1.7 50 03/21/15 18:50 03/24/15 09:01 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.35 mg/kg 0.011 0.0054 1 03/24/1513:02 03/24/1516:43 7439-97-6 Analytical Method: ASTM D2974-87 28.3 % 0.10 0.10 1 03/24/1513:54 Analytical Method: EPA 9045 8.3 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 343 171 5 ND mg/kg 343 171 5 Analytical Method: EPA 9056 ND mg/kg 34.3 17.1 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 18xT`P7`N0Kx D3 D3 D3 D3 D3 D3,N2 D4 D3 D3 D3 D3 D3 D4 03/20/15 07:36 16887-00-6 D3 03/20/15 07:36 14808-79-8 D3 03/20/15 07:36 14797-55-8 D3,H3 Page 43 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. POO WY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015007396 Lab ID: 92241387004 Collected: 03/12/15 17:15 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 110000 mg/kg 5410 2700 1 03/24/15 15:43 7440-44-0 Total Organic Carbon 102000 mg/kg 5280 2640 1 03/24/15 15:50 7440-44-0 Total Organic Carbon 121000 mg/kg 5360 2680 1 03/24/15 15:55 7440-44-0 Total Organic Carbon 146000 mg/kg 5290 2640 1 03/24/15 16:00 7440-44-0 Mean Total Organic Carbon 120000 mg/kg 5330 2670 1 03/24/15 15:43 7440-44-0 Surrogates RSD% 15.8 % 1 03/24/1515:43 Date: 04/13/2015 04:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 44 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. P3690*rWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015007393 Lab ID: 92241387005 Collected: 03/12/15 13:25 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 04/13/2015 04:11 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 16500 mg/kg 6.3 3.2 1 03/21/15 18:50 03/24/15 11:28 7429-90-5 197 mg/kg 0.63 0.32 1 03/21/1518:50 03/24/1511:28 7440-39-3 1.9 mg/kg 0.32 0.16 5 03/21/1518:50 03/24/1515:19 7440-41-7 D3 38.9 mg/kg 15.8 7.9 5 03/21/15 18:50 03/24/15 15:19 7440-42-8 D3 1470 mg/kg 31.7 15.8 1 03/21/1518:50 03/24/1511:28 7440-70-2 25.4 mg/kg 1.6 0.79 5 03/21/1518:50 03/24/1515:19 7440-47-3 D3 36.2 mg/kg 1.6 0.79 5 03/21/15 18:50 03/24/15 15:19 7440-50-8 D3 17000 mg/kg 2.5 1.3 1 03/21/15 18:50 03/24/15 11:28 7439-89-6 1350 mg/kg 31.7 15.8 1 03/21/15 18:50 03/24/15 11:28 7439-95-4 199 mg/kg 1.6 0.79 5 03/21/1518:50 03/24/1515:19 7439-96-5 D3 1.5 mg/kg 0.63 0.32 1 03/21/1518:50 03/24/1511:28 7439-98-7 13.1 mg/kg 0.32 0.16 1 03/21/15 18:50 03/24/15 11:28 7440-02-0 2250 mg/kg 63.3 31.7 1 03/21/1518:50 03/24/1511:28 7440-09-7 172 mg/kg 63.3 31.7 1 03/21/1518:50 03/24/1511:28 7440-23-5 124 mg/kg 0.63 0.32 1 03/21/15 18:50 03/24/15 11:28 7440-24-6 29.3 mg/kg 1.3 0.63 1 03/21/15 18:50 03/24/15 11:28 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.2 1.6 50 03/21/1518:50 03/24/1509:04 7440-36-0 D3,N2 58.8 mg/kg 3.2 1.6 50 03/21/15 18:50 03/24/15 09:04 7440-38-2 D4 0.33J mg/kg 0.38 0.19 50 03/21/15 18:50 03/24/15 09:04 7440-43-9 D3 14.1 mg/kg 3.2 1.6 50 03/21/15 18:50 03/24/15 09:04 7440-48-4 D3 17.9 mg/kg 3.2 1.6 50 03/21/15 18:50 03/24/15 09:04 7439-92-1 D3 6.9 mg/kg 3.2 1.6 50 03/21/15 18:50 03/24/15 09:04 7782-49-2 D3 ND mg/kg 3.2 1.6 50 03/21/15 18:50 03/24/15 09:04 7440-28-0 D3 59.0 mg/kg 3.2 1.6 50 03/21/15 18:50 03/24/15 09:04 7440-62-2 D4 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.18 mg/kg 0.0098 0.0049 1 03/24/1513:02 03/24/1516:46 7439-97-6 Analytical Method: ASTM D2974-87 21.4 % 0.10 0.10 1 03/24/1513:54 Analytical Method: EPA 9045 7.8 Std. Units 0.10 0.10 1 03/19/15 13:45 H6 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/24/15 16:15 4.5 mg/L 2.5 1.3 1 04/01/15 10:46 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/24/15 16:15 22.9 mg/L 0.25 0.25 1 03/31/1516:31 B,H1 Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 03/24/15 16:15 ND mg/L 6.4 3.2 1 03/27/15 04:31 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 45 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. PAROAirWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 Sample: 2015007393 Lab ID: 92241387005 Collected: 03/12/15 13:25 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 314 157 5 03/20/15 07:58 16887-00-6 D3 Sulfate ND mg/kg 314 157 5 03/20/15 07:58 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.4 15.7 5 03/20/15 07:58 14797-55-8 D3,1-13 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 21400 mg/kg 760 380 1 03/24/15 16:54 7440-44-0 Total Organic Carbon 18100 mg/kg 766 383 1 03/24/15 17:01 7440-44-0 Total Organic Carbon 15900 mg/kg 757 379 1 03/24/15 17:07 7440-44-0 Total Organic Carbon 18600 mg/kg 769 385 1 03/24/15 17:14 7440-44-0 Mean Total Organic Carbon 18500 mg/kg 763 382 1 03/24/15 16:54 7440-44-0 Surrogates RSD% 12.2 % 1 03/24/1516:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 46 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. POO WY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 Sample: 2015007394 Lab ID: 92241387006 Collected: 03/12/15 13:45 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 15900 mg/kg 5.5 2.8 1 03/21/1518:50 03/24/1511:33 7429-90-5 Barium 88.5 mg/kg 0.55 0.28 1 03/21/1518:50 03/24/1511:33 7440-39-3 Beryllium 0.48 mg/kg 0.28 0.14 5 03/21/1518:50 03/24/1515:23 7440-41-7 D3 Boron 22.7 mg/kg 13.9 6.9 5 03/21/1518:50 03/24/1515:23 7440-42-8 D3 Calcium 165 mg/kg 27.7 13.9 1 03/21/1518:50 03/24/1511:33 7440-70-2 Chromium 17.6 mg/kg 1.4 0.69 5 03/21/1518:50 03/24/1515:23 7440-47-3 D3 Copper 25.1 mg/kg 1.4 0.69 5 03/21/1518:50 03/24/1515:23 7440-50-8 D3 Iron 27500 mg/kg 11.1 5.5 5 03/21/1518:50 03/24/1515:23 7439-89-6 D3 Magnesium 4960 mg/kg 27.7 13.9 1 03/21/1518:50 03/24/1511:33 7439-95-4 Manganese 191 mg/kg 1.4 0.69 5 03/21/1518:50 03/24/1515:23 7439-96-5 D3 Molybdenum ND mg/kg 0.55 0.28 1 03/21/1518:50 03/24/1511:33 7439-98-7 Nickel 5.4 mg/kg 0.28 0.14 1 03/21/1518:50 03/24/1511:33 7440-02-0 Potassium 4350 mg/kg 55.4 27.7 1 03/21/1518:50 03/24/1511:33 7440-09-7 Sodium 59.4 mg/kg 55.4 27.7 1 03/21/1518:50 03/24/1511:33 7440-23-5 Strontium 2.4 mg/kg 0.55 0.28 1 03/21/1518:50 03/24/1511:33 7440-24-6 Zinc 69.0 mg/kg 1.1 0.55 1 03/21/1518:50 03/24/1511:33 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 2.8 1.4 50 03/21/1518:50 03/24/1509:17 7440-36-0 D3,N2 Arsenic 1.91 mg/kg 2.8 1.4 50 03/21/15 18:50 03/24/15 09:17 7440-38-2 D3 Cadmium ND mg/kg 0.33 0.17 50 03/21/15 18:50 03/24/15 09:17 7440-43-9 D3 Cobalt 10.2 mg/kg 2.8 1.4 50 03/21/15 18:50 03/24/15 09:17 7440-48-4 D3 Lead 4.1 mg/kg 2.8 1.4 50 03/21/15 18:50 03/24/15 09:17 7439-92-1 D3 Selenium 2.61 mg/kg 2.8 1.4 50 03/21/15 18:50 03/24/15 09:17 7782-49-2 D3 Thallium ND mg/kg 2.8 1.4 50 03/21/15 18:50 03/24/15 09:17 7440-28-0 D3 Vanadium 25.2 mg/kg 2.8 1.4 50 03/21/15 18:50 03/24/15 09:17 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.010 mg/kg 0.0087 0.0044 1 03/24/1513:02 03/24/1516:48 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 10.1 % 0.10 0.10 1 03/24/15 13:54 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 7.2 Std. Units 0.10 0.10 1 03/19/15 13:45 H6 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/24/15 16:15 Sulfate 14.6 mg/L 4.5 2.2 2 04/02/1512:08 14808-79-8 B,D3 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/24/15 16:15 Nitrogen, Nitrate 467 mg/L 22.3 22.3 100 03/31/15 18:48 B,H1, M6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. P�SR18rWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015007394 Lab ID: 92241387006 Collected: 03/12/15 13:45 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500 Chloride, SPLP Chloride 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Total Organic Carbon Quad Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Mean Total Organic Carbon Surrogates RSD% Date: 04/13/2015 04:11 PM Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 03/24/15 16:15 ND mg/L 27.8 13.9 5 03/27/15 04:46 16887-00-6 D3 Analytical Method: EPA 9056 ND mg/kg 277 139 5 03/20/15 08:19 16887-00-6 D3 ND mg/kg 277 139 5 03/20/15 08:19 14808-79-8 D3 Analytical Method: EPA 9056 ND mg/kg 27.7 13.9 5 03/20/15 08:19 14797-55-8 D3,H3 Analytical Method: EPA 9060 9530 mg/kg 665 333 1 03/24/1517:20 7440-44-0 11700 mg/kg 674 337 1 03/24/1517:27 7440-44-0 9900 mg/kg 667 334 1 03/24/1517:34 7440-44-0 12500 mg/kg 664 332 1 03/24/1517:41 7440-44-0 10900 mg/kg 668 334 1 03/24/1517:20 7440-44-0 13.0 % 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 03/24/15 17:20 Page 48 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. PggmirpY&.. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 Sample: 2015007397 Lab ID: 92241387007 Collected: 03/12/15 17:25 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 10900 mg/kg 6.5 3.2 1 03/21/1518:50 03/24/1511:37 7429-90-5 Barium 166 mg/kg 0.65 0.32 1 03/21/1518:50 03/24/1511:37 7440-39-3 Beryllium 1.3 mg/kg 0.32 0.16 5 03/21/1518:50 03/24/1515:28 7440-41-7 D3 Boron 25.1 mg/kg 16.2 8.1 5 03/21/1518:50 03/24/1515:28 7440-42-8 D3 Calcium 1130 mg/kg 32.4 16.2 1 03/21/1518:50 03/24/1511:37 7440-70-2 Chromium 52.7 mg/kg 1.6 0.81 5 03/21/1518:50 03/24/1515:28 7440-47-3 D3 Copper 33.1 mg/kg 1.6 0.81 5 03/21/1518:50 03/24/1515:28 7440-50-8 D3 Iron 20500 mg/kg 2.6 1.3 1 03/21/1518:50 03/24/1511:37 7439-89-6 Magnesium 1250 mg/kg 32.4 16.2 1 03/21/1518:50 03/24/1511:37 7439-95-4 Manganese 334 mg/kg 1.6 0.81 5 03/21/1518:50 03/24/1515:28 7439-96-5 D3 Molybdenum 1.1 mg/kg 0.65 0.32 1 03/21/1518:50 03/24/1511:37 7439-98-7 Nickel 8.1 mg/kg 0.32 0.16 1 03/21/1518:50 03/24/1511:37 7440-02-0 Potassium 1720 mg/kg 64.9 32.4 1 03/21/1518:50 03/24/1511:37 7440-09-7 Sodium 85.1 mg/kg 64.9 32.4 1 03/21/1518:50 03/24/1511:37 7440-23-5 Strontium 46.0 mg/kg 0.65 0.32 1 03/21/1518:50 03/24/1511:37 7440-24-6 Zinc 28.1 mg/kg 1.3 0.65 1 03/21/1518:50 03/24/1511:37 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.2 1.6 50 03/21/1518:50 03/24/1509:20 7440-36-0 D3,N2 Arsenic 16.1 mg/kg 3.2 1.6 50 03/21/15 18:50 03/24/15 09:20 7440-38-2 D3 Cadmium ND mg/kg 0.39 0.19 50 03/21/15 18:50 03/24/15 09:20 7440-43-9 D3 Cobalt 10.8 mg/kg 3.2 1.6 50 03/21/15 18:50 03/24/15 09:20 7440-48-4 D3 Lead 12.8 mg/kg 3.2 1.6 50 03/21/15 18:50 03/24/15 09:20 7439-92-1 D3 Selenium 3.6 mg/kg 3.2 1.6 50 03/21/15 18:50 03/24/15 09:20 7782-49-2 D3 Thallium ND mg/kg 3.2 1.6 50 03/21/15 18:50 03/24/15 09:20 7440-28-0 D3 Vanadium 39.1 mg/kg 3.2 1.6 50 03/21/15 18:50 03/24/15 09:20 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.12 mg/kg 0.011 0.0053 1 03/24/1513:02 03/24/1516:54 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 24.2 % 0.10 0.10 1 03/24/15 13:55 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 0.10 1 03/19/15 13:45 H6 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/24/15 16:15 Sulfate 13.6 mg/L 13.2 6.6 5 04/01/1511:13 14808-79-8 B,D3 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/24/15 16:15 Nitrogen, Nitrate 317 mg/L 13.2 13.2 50 03/31/15 18:56 B,H1, M6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 49 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. P�S�06Jf WY046e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015007397 Lab ID: 92241387007 Collected: 03/12/15 17:25 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500 Chloride, SPLP Chloride 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Total Organic Carbon Quad Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Mean Total Organic Carbon Surrogates RSD% Date: 04/13/2015 04:11 PM Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 03/24/15 16:15 ND mg/L 6.6 3.3 1 03/27/15 04:33 16887-00-6 Analytical Method: EPA 9056 ND mg/kg 330 165 5 03/20/15 08:41 16887-00-6 D3 ND mg/kg 330 165 5 03/20/15 08:41 14808-79-8 D3 Analytical Method: EPA 9056 ND mg/kg 33.0 16.5 5 03/20/15 08:41 14797-55-8 D3,H3 Analytical Method: EPA 9060 32800 mg/kg 3240 1620 1 03/24/1519:38 7440-44-0 34400 mg/kg 3270 1630 1 03/24/1519:44 7440-44-0 40200 mg/kg 3260 1630 1 03/24/1519:50 7440-44-0 34000 mg/kg 3280 1640 1 03/24/1519:55 7440-44-0 35400 mg/kg 3260 1630 1 03/24/1519:38 7440-44-0 9.4 % 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 03/24/15 19:38 Page 50 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. P�S�06Jf3irWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015007398 Lab ID: 92241387008 Collected: 03/12/15 17:35 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 04/13/2015 04:11 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 20700 mg/kg 34.5 17.2 5 03/21/15 18:50 03/24/15 15:32 7429-90-5 220 mg/kg 3.4 1.7 5 03/21/1518:50 03/24/1515:32 7440-39-3 1.0 mg/kg 0.34 0.17 5 03/21/1518:50 03/24/1515:32 7440-41-7 10.8J mg/kg 17.2 8.6 5 03/21/15 18:50 03/24/15 15:32 7440-42-8 246 mg/kg 172 86.1 5 03/21/1518:50 03/24/1515:32 7440-70-2 21.4 mg/kg 1.7 0.86 5 03/21/1518:50 03/24/1515:32 7440-47-3 24.6 mg/kg 1.7 0.86 5 03/21/15 18:50 03/24/15 15:32 7440-50-8 12900 mg/kg 13.8 6.9 5 03/21/1518:50 03/24/1515:32 7439-89-6 4250 mg/kg 172 86.1 5 03/21/15 18:50 03/24/15 15:32 7439-95-4 71.8 mg/kg 1.7 0.86 5 03/21/1518:50 03/24/1515:32 7439-96-5 ND mg/kg 3.4 1.7 5 03/21/1518:50 03/24/1515:32 7439-98-7 11.5 mg/kg 1.7 0.86 5 03/21/15 18:50 03/24/15 15:32 7440-02-0 3150 mg/kg 345 172 5 03/21/1518:50 03/24/1515:32 7440-09-7 ND mg/kg 345 172 5 03/21/1518:50 03/24/1515:32 7440-23-5 3.7 mg/kg 3.4 1.7 5 03/21/15 18:50 03/24/15 15:32 7440-24-6 72.1 mg/kg 6.9 3.4 5 03/21/15 18:50 03/24/15 15:32 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.4 1.7 50 03/21/1518:50 03/24/1509:23 7440-36-0 1.8J mg/kg 3.4 1.7 50 03/21/15 18:50 03/24/15 09:23 7440-38-2 ND mg/kg 0.41 0.21 50 03/21/15 18:50 03/24/15 09:23 7440-43-9 6.6 mg/kg 3.4 1.7 50 03/21/15 18:50 03/24/15 09:23 7440-48-4 4.4 mg/kg 3.4 1.7 50 03/21/15 18:50 03/24/15 09:23 7439-92-1 2AJ mg/kg 3.4 1.7 50 03/21/15 18:50 03/24/15 09:23 7782-49-2 ND mg/kg 3.4 1.7 50 03/21/15 18:50 03/24/15 09:23 7440-28-0 26.4 mg/kg 3.4 1.7 50 03/21/15 18:50 03/24/15 09:23 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.0082J mg/kg 0.010 0.0051 1 03/24/1513:02 03/24/1516:56 7439-97-6 Analytical Method: ASTM D2974-87 25.0 % 0.10 0.10 1 03/24/1513:55 Analytical Method: EPA 9045 6.2 Std. Units 0.10 0.10 1 03/19/15 13:45 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3,N2 D3 D3 D3 D3 D3 D3 D3 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/24/15 16:15 3.8 mg/L 2.7 1.3 1 04/01/15 11:26 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/24/15 16:15 17.6 mg/L 1.3 1.3 5 03/31/1518:01 B,H1 Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 03/24/15 16:15 ND mg/L 6.7 3.3 1 03/27/15 04:33 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 51 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. P� %'0 Iirwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 Sample: 2015007398 Lab ID: 92241387008 Collected: 03/12/15 17:35 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 337 169 5 03/20/15 09:02 16887-00-6 D3 Sulfate ND mg/kg 337 169 5 03/20/15 09:02 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 33.7 16.9 5 03/20/15 09:02 14797-55-8 D3,1-13 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 3710 mg/kg 806 403 1 03/24/15 18:11 7440-44-0 Total Organic Carbon 3350 mg/kg 794 397 1 03/24/15 18:18 7440-44-0 Total Organic Carbon 3470 mg/kg 797 399 1 03/24/15 18:24 7440-44-0 Total Organic Carbon 2940 mg/kg 805 403 1 03/24/15 18:30 7440-44-0 Mean Total Organic Carbon 3370 mg/kg 801 400 1 03/24/15 18:11 7440-44-0 Surrogates RSD% 9.6 % 1 03/24/1518:11 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 52 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. PAR18rWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015007399 Lab ID: 92241387009 Collected: 03/12/15 17:45 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 04/13/2015 04:11 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 6580 mg/kg 59.7 29.8 10 03/21/15 18:50 03/24/15 15:36 7429-90-5 D3 31.5 mg/kg 6.0 3.0 10 03/21/1518:50 03/24/1515:36 7440-39-3 D3 0.52J mg/kg 0.60 0.30 10 03/21/1518:50 03/24/1515:36 7440-41-7 D3 15.9J mg/kg 29.8 14.9 10 03/21/15 18:50 03/24/15 15:36 7440-42-8 D3 239J mg/kg 298 149 10 03/21/1518:50 03/24/1515:36 7440-70-2 D3 4.6 mg/kg 3.0 1.5 10 03/21/1518:50 03/24/1515:36 7440-47-3 D3 68.9 mg/kg 3.0 1.5 10 03/21/15 18:50 03/24/15 15:36 7440-50-8 D3 19300 mg/kg 23.9 11.9 10 03/21/1518:50 03/24/1515:36 7439-89-6 D3 2130 mg/kg 298 149 10 03/21/15 18:50 03/24/15 15:36 7439-95-4 D3 85.7 mg/kg 3.0 1.5 10 03/21/1518:50 03/24/1515:36 7439-96-5 D3 ND mg/kg 6.0 3.0 10 03/21/1518:50 03/24/1515:36 7439-98-7 D3 8.1 mg/kg 3.0 1.5 10 03/21/15 18:50 03/24/15 15:36 7440-02-0 D3 343J mg/kg 597 298 10 03/21/1518:50 03/24/1515:36 7440-09-7 D3 ND mg/kg 597 298 10 03/21/1518:50 03/24/1515:36 7440-23-5 D3 ND mg/kg 6.0 3.0 10 03/21/1518:50 03/24/1515:36 7440-24-6 D3 30.9 mg/kg 11.9 6.0 10 03/21/15 18:50 03/24/15 15:36 7440-66-6 D3 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.0 1.5 50 03/21/1518:50 03/24/1509:26 7440-36-0 D3,N2 5.6 mg/kg 3.0 1.5 50 03/21/15 18:50 03/24/15 09:26 7440-38-2 D3 ND mg/kg 0.36 0.18 50 03/21/15 18:50 03/24/15 09:26 7440-43-9 D3 5.5 mg/kg 3.0 1.5 50 03/21/15 18:50 03/24/15 09:26 7440-48-4 D3 2.5J mg/kg 3.0 1.5 50 03/21/15 18:50 03/24/15 09:26 7439-92-1 D3 10.4 mg/kg 3.0 1.5 50 03/21/15 18:50 03/24/15 09:26 7782-49-2 D3 ND mg/kg 3.0 1.5 50 03/21/15 18:50 03/24/15 09:26 7440-28-0 D3 4.7 mg/kg 3.0 1.5 50 03/21/15 18:50 03/24/15 09:26 7440-62-2 D3 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0095 0.0048 1 03/24/1513:02 03/24/1516:58 7439-97-6 Analytical Method: ASTM D2974-87 17.2 % 0.10 0.10 1 03/24/1513:56 Analytical Method: EPA 9045 6.3 Std. Units 0.10 0.10 1 03/19/15 13:45 H6 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/24/15 16:15 13.8 mg/L 2.4 1.2 1 04/01/15 11:40 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/24/15 16:15 207 mg/L 12.1 12.1 50 03/31/1518:59 B,H1 Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 03/24/15 16:15 ND mg/L 6.0 3.0 1 03/27/15 04:34 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 53 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. P�S�06} WY046e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 Sample: 2015007399 Lab ID: 92241387009 Collected: 03/12/15 17:45 Received: 03/16/15 15:08 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 306 153 5 03/20/15 09:23 16887-00-6 D3 Sulfate ND mg/kg 306 153 5 03/20/15 09:23 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.6 15.3 5 03/20/15 09:23 14797-55-8 D3,1-13 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 8140 mg/kg 726 363 1 03/24/15 18:48 7440-44-0 Total Organic Carbon 7400 mg/kg 732 366 1 03/24/15 18:54 7440-44-0 Total Organic Carbon 8110 mg/kg 722 361 1 03/24/15 19:00 7440-44-0 Total Organic Carbon 8230 mg/kg 729 365 1 03/24/15 19:07 7440-44-0 Mean Total Organic Carbon 7970 mg/kg 727 364 1 03/24/15 18:48 7440-44-0 Surrogates RSD% 4.8 % 1 03/24/1518:48 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 54 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. PARVrWY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015007393 SPLP Lab ID: 92241387010 Collected: 03/12/15 13:25 Received: 03/16/15 15:08 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\riil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/13/2015 04:11 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 6110 ug/L 10.0 3.0 1 04/01/1514:38 04/02/1510:29 7429-90-5 1.0 ug/L 0.50 0.15 1 04/01/15 14:38 04/02/15 10:29 7440-36-0 25.5 ug/L 0.50 0.11 1 04/01/15 14:38 04/02/15 10:29 7440-38-2 72.4 ug/L 0.30 0.081 1 04/01/1514:38 04/02/1510:29 7440-39-3 0.23 ug/L 0.20 0.067 1 04/01/1514:38 04/02/1510:29 7440-41-7 676 ug/L 25.0 5.6 5 04/01/1514:38 04/02/1513:26 7440-42-8 ND ug/L 0.080 0.024 1 04/01/1514:38 04/02/1510:29 7440-43-9 7340 ug/L 40.0 16.0 1 04/01/1514:38 04/02/1510:29 7440-70-2 6.9 ug/L 0.50 0.17 1 04/01/1514:38 04/02/1510:29 7440-47-3 3.3 ug/L 0.50 0.13 1 04/01/15 14:38 04/02/15 10:29 7440-48-4 7.8 ug/L 1.0 0.21 1 04/01/15 14:38 04/02/15 10:29 7440-50-8 4360 ug/L 50.0 13.7 1 04/01/1514:38 04/02/1510:29 7439-89-6 3.0 ug/L 0.10 0.046 1 04/01/1514:38 04/02/1510:29 7439-92-1 2160 ug/L 10.0 3.2 1 04/01/1514:38 04/02/1510:29 7439-95-4 161 ug/L 0.50 0.24 1 04/01/15 14:38 04/02/15 10:29 7439-96-5 7.4 ug/L 0.50 0.094 1 04/01/1514:38 04/02/1510:29 7439-98-7 2.9 ug/L 0.50 0.16 1 04/01/15 14:38 04/02/15 10:29 7440-02-0 2140 ug/L 50.0 11.7 1 04/01/15 14:38 04/02/15 10:29 7440-09-7 1.6 ug/L 0.50 0.20 1 04/01/15 14:38 04/02/15 10:29 7782-49-2 15200 ug/L 50.0 16.3 1 04/01/1514:38 04/02/1510:29 7440-23-5 191 ug/L 0.50 0.13 1 04/01/1514:38 04/02/1510:29 7440-24-6 0.20 ug/L 0.10 0.015 1 04/01/1514:38 04/02/1510:29 7440-28-0 18.0 ug/L 1.0 0.28 1 04/01/15 14:38 04/02/15 10:29 7440-62-2 33.1 ug/L 5.0 2.4 1 04/01/1514:38 04/02/1510:29 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/01/15 09:02 04/01/15 11:39 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 55 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. PAR816fY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015007394 SPLP Lab ID: 92241387011 Collected: 03/12/15 13:45 Received: 03/16/15 15:08 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/13/2015 04:11 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 136 ug/L 10.0 3.0 1 04/01/1514:38 04/02/1510:33 7429-90-5 0.65 ug/L 0.50 0.15 1 04/01/15 14:38 04/02/15 10:33 7440-36-0 ND ug/L 0.50 0.11 1 04/01/1514:38 04/02/1510:33 7440-38-2 418 ug/L 0.30 0.081 1 04/01/1514:38 04/02/1510:33 7440-39-3 ND ug/L 0.20 0.067 1 04/01/1514:38 04/02/1510:33 7440-41-7 155 ug/L 5.0 1.1 1 04/01/1514:38 04/02/1510:33 7440-42-8 ND ug/L 0.080 0.024 1 04/01/1514:38 04/02/1510:33 7440-43-9 699 ug/L 40.0 16.0 1 04/01/1514:38 04/02/1510:33 7440-70-2 18.5 ug/L 0.50 0.17 1 04/01/1514:38 04/02/1510:33 7440-47-3 0.88 ug/L 0.50 0.13 1 04/01/15 14:38 04/02/15 10:33 7440-48-4 12.4 ug/L 1.0 0.21 1 04/01/15 14:38 04/02/15 10:33 7440-50-8 210 ug/L 50.0 13.7 1 04/01/1514:38 04/02/1510:33 7439-89-6 2.2 ug/L 0.10 0.046 1 04/01/1514:38 04/02/1510:33 7439-92-1 196 ug/L 10.0 3.2 1 04/01/1514:38 04/02/1510:33 7439-95-4 174 ug/L 0.50 0.24 1 04/01/15 14:38 04/02/15 10:33 7439-96-5 1.7 ug/L 0.50 0.094 1 04/01/1514:38 04/02/1510:33 7439-98-7 6.3 ug/L 0.50 0.16 1 04/01/15 14:38 04/02/15 10:33 7440-02-0 1040 ug/L 50.0 11.7 1 04/01/15 14:38 04/02/15 10:33 7440-09-7 1.1 ug/L 0.50 0.20 1 04/01/15 14:38 04/02/15 10:33 7782-49-2 2320 ug/L 50.0 16.3 1 04/01/1514:38 04/02/1510:33 7440-23-5 10.2 ug/L 0.50 0.13 1 04/01/1514:38 04/02/1510:33 7440-24-6 0.13 ug/L 0.10 0.015 1 04/01/1514:38 04/02/1510:33 7440-28-0 ND ug/L 1.0 0.28 1 04/01/1514:38 04/02/1510:33 7440-62-2 227 ug/L 5.0 2.4 1 04/01/1514:38 04/02/1510:33 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/01/15 09:02 04/01/15 11:42 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 56 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. PAR16rWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015007397 SPLP Lab ID: 92241387012 Collected: 03/12/15 17:25 Received: 03/16/15 15:08 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\riil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/13/2015 04:11 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 564 ug/L 10.0 3.0 1 04/01/1514:38 04/02/1510:38 7429-90-5 0.56 ug/L 0.50 0.15 1 04/01/15 14:38 04/02/15 10:38 7440-36-0 4.2 ug/L 0.50 0.11 1 04/01/15 14:38 04/02/15 10:38 7440-38-2 938 ug/L 1.5 0.40 5 04/01/1514:38 04/02/1513:16 7440-39-3 0.36 ug/L 0.20 0.067 1 04/01/1514:38 04/02/1510:38 7440-41-7 183 ug/L 5.0 1.1 1 04/01/1514:38 04/02/1510:38 7440-42-8 0.24 ug/L 0.080 0.024 1 04/01/15 14:38 04/02/15 10:38 7440-43-9 4330 ug/L 40.0 16.0 1 04/01/1514:38 04/02/1510:38 7440-70-2 3.7 ug/L 0.50 0.17 1 04/01/1514:38 04/02/1510:38 7440-47-3 3.2 ug/L 0.50 0.13 1 04/01/15 14:38 04/02/15 10:38 7440-48-4 16.7 ug/L 1.0 0.21 1 04/01/15 14:38 04/02/15 10:38 7440-50-8 184 ug/L 50.0 13.7 1 04/01/1514:38 04/02/1510:38 7439-89-6 4.6 ug/L 0.10 0.046 1 04/01/1514:38 04/02/1510:38 7439-92-1 1020 ug/L 10.0 3.2 1 04/01/1514:38 04/02/1510:38 7439-95-4 102 ug/L 0.50 0.24 1 04/01/15 14:38 04/02/15 10:38 7439-96-5 1.0 ug/L 0.50 0.094 1 04/01/1514:38 04/02/1510:38 7439-98-7 4.3 ug/L 0.50 0.16 1 04/01/15 14:38 04/02/15 10:38 7440-02-0 2610 ug/L 50.0 11.7 1 04/01/15 14:38 04/02/15 10:38 7440-09-7 ND ug/L 0.50 0.20 1 04/01/1514:38 04/02/1510:38 7782-49-2 2260 ug/L 50.0 16.3 1 04/01/1514:38 04/02/1510:38 7440-23-5 517 ug/L 2.5 0.66 5 04/01/1514:38 04/02/1513:16 7440-24-6 0.74 ug/L 0.10 0.015 1 04/01/1514:38 04/02/1510:38 7440-28-0 1.9 ug/L 1.0 0.28 1 04/01/15 14:38 04/02/15 10:38 7440-62-2 247 ug/L 5.0 2.4 1 04/01/1514:38 04/02/1510:38 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/01/15 09:02 04/01/15 11:49 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 57 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. P36907`bir6fY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015007398 SPLP Lab ID: 92241387013 Collected: 03/12/15 17:35 Received: 03/16/15 15:08 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\��il=11 a r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/13/2015 04:11 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 37400 ug/L 50.0 14.9 5 03/31/15 09:50 04/01/15 10:34 7429-90-5 ND ug/L 0.50 0.25 1 03/31/15 09:50 03/31/15 18:25 7440-36-0 1.9 ug/L 0.50 0.25 1 03/31/15 09:50 03/31/15 18:25 7440-38-2 240 ug/L 0.30 0.14 1 03/31/15 09:50 03/31/15 18:25 7440-39-3 0.72 ug/L 0.20 0.066 1 03/31/15 09:50 03/31/15 18:25 7440-41-7 114 ug/L 25.0 5.6 5 03/31/15 09:50 04/01/15 10:34 7440-42-8 ND ug/L 0.080 0.033 1 03/31/15 09:50 03/31/15 18:25 7440-43-9 1050 ug/L 40.0 8.4 1 03/31/15 09:50 03/31/15 18:25 7440-70-2 18.7 ug/L 0.50 0.22 1 03/31/15 09:50 03/31/15 18:25 7440-47-3 1.6 ug/L 0.50 0.25 1 03/31/15 09:50 03/31/15 18:25 7440-48-4 63.3 ug/L 1.0 0.22 1 03/31/15 09:50 03/31/15 18:25 7440-50-8 3720 ug/L 50.0 8.0 1 03/31/15 09:50 03/31/15 18:25 7439-89-6 6.1 ug/L 0.10 0.046 1 03/31/15 09:50 03/31/15 18:25 7439-92-1 626 ug/L 10.0 2.8 1 03/31/15 09:50 03/31/15 18:25 7439-95-4 27.9 ug/L 0.50 0.14 1 03/31/15 09:50 03/31/15 18:25 7439-96-5 ND ug/L 0.50 0.24 1 03/31/15 09:50 03/31/15 18:25 7439-98-7 14.4 ug/L 0.50 0.23 1 03/31/15 09:50 03/31/15 18:25 7440-02-0 1730 ug/L 50.0 8.3 1 03/31/15 09:50 03/31/15 18:25 7440-09-7 ND ug/L 0.50 0.25 1 03/31/15 09:50 03/31/15 18:25 7782-49-2 3110 ug/L 50.0 18.2 1 03/31/15 09:50 03/31/15 18:25 7440-23-5 7.5 ug/L 0.50 0.057 1 03/31/15 09:50 03/31/15 18:25 7440-24-6 0.20 ug/L 0.10 0.025 1 03/31/15 09:50 03/31/15 18:25 7440-28-0 28.2 ug/L 1.0 0.21 1 03/31/15 09:50 03/31/15 18:25 7440-62-2 24.8 ug/L 5.0 2.5 1 03/31/15 09:50 03/31/15 18:25 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/01/15 09:02 04/01/15 11:52 7439-97-6 M 1, R 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 58 of 87 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. P36ROAirpy&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015007399 SPLP Lab ID: 92241387014 Collected: 03/12/15 17:45 Received: 03/16/15 15:08 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\riil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/13/2015 04:11 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 183 ug/L 10.0 3.0 1 04/01/1514:38 04/02/1510:53 7429-90-5 ND ug/L 0.50 0.15 1 04/01/1514:38 04/02/1510:53 7440-36-0 0.61 ug/L 0.50 0.11 1 04/01/15 14:38 04/02/15 10:53 7440-38-2 409 ug/L 0.30 0.081 1 04/01/1514:38 04/02/1510:53 7440-39-3 ND ug/L 0.20 0.067 1 04/01/1514:38 04/02/1510:53 7440-41-7 138 ug/L 5.0 1.1 1 04/01/1514:38 04/02/1510:53 7440-42-8 ND ug/L 0.080 0.024 1 04/01/1514:38 04/02/1510:53 7440-43-9 791 ug/L 40.0 16.0 1 04/01/1514:38 04/02/1510:53 7440-70-2 6.0 ug/L 0.50 0.17 1 04/01/1514:38 04/02/1510:53 7440-47-3 2.5 ug/L 0.50 0.13 1 04/01/15 14:38 04/02/15 10:53 7440-48-4 9.9 ug/L 1.0 0.21 1 04/01/15 14:38 04/02/15 10:53 7440-50-8 134 ug/L 50.0 13.7 1 04/01/1514:38 04/02/1510:53 7439-89-6 3.0 ug/L 0.10 0.046 1 04/01/1514:38 04/02/1510:53 7439-92-1 350 ug/L 10.0 3.2 1 04/01/1514:38 04/02/1510:53 7439-95-4 54.7 ug/L 0.50 0.24 1 04/01/15 14:38 04/02/15 10:53 7439-96-5 1.9 ug/L 0.50 0.094 1 04/01/1514:38 04/02/1510:53 7439-98-7 3.5 ug/L 0.50 0.16 1 04/01/15 14:38 04/02/15 10:53 7440-02-0 2090 ug/L 50.0 11.7 1 04/01/15 14:38 04/02/15 10:53 7440-09-7 ND ug/L 0.50 0.20 1 04/01/1514:38 04/02/1510:53 7782-49-2 2280 ug/L 50.0 16.3 1 04/01/1514:38 04/02/1510:53 7440-23-5 11.6 ug/L 0.50 0.13 1 04/01/1514:38 04/02/1510:53 7440-24-6 ND ug/L 0.10 0.015 1 04/01/1514:38 04/02/1510:53 7440-28-0 ND ug/L 1.0 0.28 1 04/01/1514:38 04/02/1510:53 7440-62-2 212 ug/L 5.0 2.4 1 04/01/1514:38 04/02/1510:53 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/01/15 09:02 04/01/15 11:59 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 59 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. PARO&WY046e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 QC Batch: MERP/13035 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92241387001 METHOD BLANK: 1923207 Matrix: Water Associated Lab Samples: 92241387001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/24/1517:29 LABORATORY CONTROL SAMPLE: 1923208 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.1 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1923844 1923845 MS MSD 92241387001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.2 5.4 104 107 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 60 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P3690 �irwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 QC Batch: MERP/13085 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92241387010, 92241387011, 92241387012, 92241387013, 92241387014 METHOD BLANK: 1927072 Matrix: Water Associated Lab Samples: 92241387010, 92241387011, 92241387012, 92241387013, 92241387014 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/01/1511:25 LABORATORY CONTROL SAMPLE: 1927073 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.1 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1929417 1929418 MS MSD 92241387013 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 3.6 5.4 72 108 75-125 39 20 M1,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 61 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P36907ir6fY0%e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 QC Batch: MERP/5501 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92241387002, 92241387003, 92241387004, 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 METHOD BLANK: 1164064 Matrix: Solid Associated Lab Samples: 92241387002, 92241387003, 92241387004, 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0083 03/24/1516:28 LABORATORY CONTROL SAMPLE: 1164065 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .078 0.080 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1164066 1164067 MS MSD 92241387002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Mercury mg/kg 0.17 .1 .0967 0.23 0.24 62 67 80-120 1 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 62 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. P36908rwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QC Batch: MPRP/23201 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92241387002, 92241387003, 92241387004, 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 METHOD BLANK: 1162647 Matrix: Solid Associated Lab Samples: 92241387002, 92241387003, 92241387004, 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 Parameter Units Blank Result Reporting Limit Aluminum mg/kg ND 5.1 Barium mg/kg ND 0.51 Beryllium mg/kg ND 0.051 Boron mg/kg ND 2.6 Calcium mg/kg ND 25.6 Chromium mg/kg ND 0.26 Copper mg/kg ND 0.26 Iron mg/kg 1.2J 2.0 Magnesium mg/kg ND 25.6 Manganese mg/kg ND 0.26 Molybdenum mg/kg ND 0.51 Nickel mg/kg ND 0.26 Potassium mg/kg ND 51.1 Sodium mg/kg ND 51.1 Strontium mg/kg ND 0.51 Zinc mg/kg ND 1.0 Analyzed Qualifiers 03/24/15 10:30 03/24/15 10:30 03/24/15 10:30 03/24/15 10:30 03/24/15 10:30 03/24/15 10:30 03/24/15 10:30 03/24/15 10:30 03/24/15 10:30 03/24/15 10:30 03/24/15 10:30 03/24/15 10:30 03/24/15 10:30 03/24/15 10:30 03/24/15 10:30 03/24/15 10:30 LABORATORY CONTROL SAMPLE: Parameter 1162648 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 127 130 102 80-120 Barium mg/kg 12.7 13.2 103 80-120 Beryllium mg/kg 1.3 1.3 100 80-120 Boron mg/kg 127 125 98 80-120 Calcium mg/kg 637 649 102 80-120 Chromium mg/kg 12.7 12.9 101 80-120 Copper mg/kg 12.7 13.0 102 80-120 Iron mg/kg 127 123 97 80-120 Magnesium mg/kg 637 637 100 80-120 Manganese mg/kg 12.7 12.5 98 80-120 Molybdenum mg/kg 12.7 12.3 96 80-120 Nickel mg/kg 12.7 12.7 100 80-120 Potassium mg/kg 637 644 101 80-120 Sodium mg/kg 637 667 105 80-120 Strontium mg/kg 12.7 12.7 100 80-120 Zinc mg/kg 63.7 63.8 100 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 63 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P3690 �irWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1162649 1162650 MS MSD 92241387002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 6360 150 149 7810 8060 963 1130 75-125 3 20 M1 Barium mg/kg 368 15 14.9 397 433 189 432 75-125 9 20 M1 Beryllium mg/kg 1.5 1.55 1.55 2.8 2.9 89 93 75-125 2 20 Boron mg/kg 13.1 150 149 129 125 77 74 75-125 4 20 M1 Calcium mg/kg 2870 750 748 3830 3310 128 59 75-125 15 20 M1 Chromium mg/kg 12.0 15 14.9 24.6 25.0 84 87 75-125 2 20 Copper mg/kg 23.6 15 14.9 37.1 37.5 90 93 75-125 1 20 Iron mg/kg 5150 150 149 5960 6580 541 959 75-125 10 20 M1 Magnesium mg/kg 659 750 748 1470 1360 108 94 75-125 8 20 Manganese mg/kg 46.6 15 14.9 61.1 60.0 97 90 75-125 2 20 Molybdenum mg/kg 1.1 15 14.9 12.7 12.8 77 78 75-125 1 20 Nickel mg/kg 9.6 15 14.9 23.7 24.7 94 101 75-125 4 20 Potassium mg/kg 1010 750 748 2000 2080 132 143 75-125 4 20 M1 Sodium mg/kg 147 750 748 875 842 97 93 75-125 4 20 Strontium mg/kg 115 15 14.9 136 140 140 167 75-125 3 20 M1 Zinc mg/kg 14.9 75 74.8 79.7 79.2 86 86 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 64 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. PAROnrWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QC Batch: MPRP/23202 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92241387002, 92241387003, 92241387004, 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 METHOD BLANK: 1162651 Matrix: Solid 1162654 Associated Lab Samples: 92241387002, 92241387003, 92241387004, 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 MS MSD Blank Reporting 92241387002 Parameter Units Result MS Limit Analyzed Qualifiers Antimony mg/kg Max ND 0.051 03/24/15 08:24 N2 Arsenic mg/kg Result ND 0.051 03/24/15 08:24 RPD Cadmium mg/kg mg/kg ND 0.0061 03/24/15 08:24 10.2 Cobalt mg/kg 612 ND 0.051 03/24/15 08:24 Lead mg/kg ND 0.051 03/24/15 08:24 Selenium mg/kg ND 0.051 03/24/15 08:24 59.9 Thallium mg/kg 77.2 ND 0.051 03/24/15 08:24 75-125 Vanadium mg/kg Cadmium ND 0.051 03/24/15 08:24 .287 LABORATORY CONTROL SAMPLE: 1162652 237 1030 75-125 64 20 M6, R1 Cobalt mg/kg Spike 6.09 LCS LCS % Rec Parameter Units Conc. 64 Result % Rec Limits Qualifiers Antimony mg/kg 5.1 2.87 5.0 99 80-120 N2 Arsenic mg/kg 5.1 20 M6, R1 4.9 96 80-120 Cadmium mg/kg .51 47.5 0.51 101 80-120 Cobalt mg/kg 5.1 mg/kg 4.9 97 80-120 Lead mg/kg 5.1 852 5.0 98 80-120 Selenium mg/kg 5.1 6.09 5.0 99 80-120 Thallium mg/kg 5.1 61 5.1 100 80-120 Vanadium mg/kg 5.1 4.9 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1162653 1162654 MS MSD 92241387002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 6.09 2.87 10.2 18.9 151 612 75-125 59 20 M6, N2, R1 Arsenic mg/kg 59.9 6.09 2.87 77.2 142 283 2800 75-125 59 20 M6, R1 Cadmium mg/kg 0.20J .609 .287 1.7 3.2 237 1030 75-125 64 20 M6, R1 Cobalt mg/kg 6.6 6.09 2.87 23.3 45.2 273 1320 75-125 64 20 M6, R1 Lead mg/kg 8.8 6.09 2.87 23.9 48.3 247 1350 75-125 68 20 M6, R1 Selenium mg/kg 14.6 6.09 2.87 25.0 47.5 170 1130 75-125 62 20 M6, R1 Thallium mg/kg ND 6.09 2.87 13.4 26.2 199 852 75-125 64 20 M6, R1 Vanadium mg/kg 39.9 6.09 2.87 58.4 109 302 2370 75-125 61 20 M6, R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 65 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030402 Pace Project No.: 92241387 QC Batch: MPRP/53084 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92241387001 METHOD BLANK: 1922975 Associated Lab Samples: 92241387001 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 03/23/15 09:41 ND 0.50 03/23/15 09:41 ND 0.50 03/23/15 09:41 ND 0.30 03/23/15 09:41 ND 0.20 03/23/15 09:41 ND 5.0 03/23/15 09:41 ND 0.080 03/23/15 09:41 ND 40.0 03/23/15 09:41 ND 0.50 03/23/15 09:41 ND 0.50 03/23/15 09:41 ND 1.0 03/23/15 09:41 ND 50.0 03/23/15 09:41 ND 0.10 03/23/15 09:41 ND 10.0 03/23/15 09:41 ND 0.50 03/23/15 09:41 ND 0.50 03/23/15 09:41 ND 0.50 03/23/15 09:41 ND 50.0 03/23/15 09:41 ND 0.50 03/23/15 09:41 ND 50.0 03/23/15 09:41 ND 0.50 03/23/15 09:41 ND 0.10 03/23/15 09:41 ND 1.0 03/23/15 09:41 ND 5.0 03/23/15 09:41 Qualifiers Pace Analytical Services, Inc. P3690 �irwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1922976 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 85.9 107 80-120 Antimony ug/L 80 79.8 100 80-120 Arsenic ug/L 80 82.2 103 80-120 Barium ug/L 80 80.1 100 80-120 Beryllium ug/L 80 82.4 103 80-120 Boron ug/L 80 81.9 102 80-120 Cadmium ug/L 80 86.3 108 80-120 Calcium ug/L 1000 1090 109 80-120 Chromium ug/L 80 87.2 109 80-120 Cobalt ug/L 80 86.4 108 80-120 Copper ug/L 80 90.3 113 80-120 Iron ug/L 1000 1090 109 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 66 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P3690 �irwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 LABORATORY CONTROL SAMPLE: 1922976 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 80.7 101 80-120 Magnesium ug/L 1000 1070 107 80-120 Manganese ug/L 80 87.1 109 80-120 Molybdenum ug/L 80 84.1 105 80-120 Nickel ug/L 80 87.3 109 80-120 Potassium ug/L 1000 1050 105 80-120 Selenium ug/L 80 82.4 103 80-120 Sodium ug/L 1000 1080 108 80-120 Strontium ug/L 80 82.4 103 80-120 Thallium ug/L 80 86.8 109 80-120 Vanadium ug/L 80 85.2 107 80-120 Zinc ug/L 80 86.2 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1922977 1922978 MS MSD 92241387001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 106 80 80 196 235 112 161 75-125 18 20 M1 Antimony ug/L ND 80 80 78.9 79.5 98 99 75-125 1 20 Arsenic ug/L ND 80 80 81.6 82.2 102 103 75-125 1 20 Barium ug/L 2.8 80 80 83.3 84.4 101 102 75-125 1 20 Beryllium ug/L ND 80 80 83.3 83.8 104 105 75-125 1 20 Boron ug/L ND 80 80 88.5 89.4 110 111 75-125 1 20 Cadmium ug/L ND 80 80 86.4 87.5 108 109 75-125 1 20 Calcium ug/L 245 1000 1000 1280 1300 104 106 75-125 2 20 Chromium ug/L 0.90 80 80 87.2 89.0 108 110 75-125 2 20 Cobalt ug/L 1.1 80 80 88.4 89.6 109 111 75-125 1 20 Copper ug/L ND 80 80 91.8 92.2 114 114 75-125 0 20 Iron ug/L 489 1000 1000 1580 1670 110 118 75-125 5 20 Lead ug/L 0.11 80 80 79.6 81.0 99 101 75-125 2 20 Magnesium ug/L 36.5 1000 1000 1120 1140 108 110 75-125 2 20 Manganese ug/L 10.3 80 80 96.5 98.7 108 110 75-125 2 20 Molybdenum ug/L ND 80 80 84.5 84.0 105 105 75-125 1 20 Nickel ug/L ND 80 80 89.0 89.2 111 111 75-125 0 20 Potassium ug/L 73.0 1000 1000 1120 1140 105 107 75-125 2 20 Selenium ug/L ND 80 80 84.1 83.7 105 105 75-125 0 20 Sodium ug/L ND 1000 1000 1090 1110 104 107 75-125 2 20 Strontium ug/L 0.70 80 80 83.0 83.2 103 103 75-125 0 20 Thallium ug/L ND 80 80 85.8 86.7 107 108 75-125 1 20 Vanadium ug/L ND 80 80 84.5 86.1 105 107 75-125 2 20 Zinc ug/L ND 80 80 90.0 90.1 106 107 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 67 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030402 Pace Project No.: 92241387 QC Batch: MPRP/53234 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92241387013 METHOD BLANK: 1927025 Associated Lab Samples: 92241387013 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 04/01/15 09:57 ND 0.50 04/01/15 09:57 ND 0.50 04/01/15 09:57 ND 0.30 04/01/15 09:57 ND 0.20 04/01/15 09:57 ND 5.0 04/01/15 09:57 ND 0.080 04/01/15 09:57 ND 40.0 04/01/15 09:57 ND 0.50 04/01/15 09:57 ND 0.50 04/01/15 09:57 2.8 1.0 04/01/15 09:57 ND 50.0 04/01/15 09:57 ND 0.10 04/01/15 09:57 ND 10.0 04/01/15 09:57 ND 0.50 04/01/15 09:57 ND 0.50 04/01/15 09:57 ND 0.50 04/01/15 09:57 ND 50.0 04/01/15 09:57 ND 0.50 04/01/15 09:57 ND 50.0 04/01/15 09:57 ND 0.50 04/01/15 09:57 ND 0.10 04/01/15 09:57 ND 1.0 04/01/15 09:57 ND 5.0 04/01/15 09:57 P8 Qualifiers Pace Analytical Services, Inc. POO WY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1927026 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 87.0 109 80-120 Antimony ug/L 80 78.3 98 80-120 Arsenic ug/L 80 79.7 100 80-120 Barium ug/L 80 79.2 99 80-120 Beryllium ug/L 80 84.0 105 80-120 Boron ug/L 80 83.7 105 80-120 Cadmium ug/L 80 84.2 105 80-120 Calcium ug/L 1000 1060 106 80-120 Chromium ug/L 80 84.8 106 80-120 Cobalt ug/L 80 84.6 106 80-120 Copper ug/L 80 84.4 105 80-120 Iron ug/L 1000 1040 104 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 68 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P36R08 6fy&.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 LABORATORY CONTROL SAMPLE: 1927026 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 85.7 107 80-120 Magnesium ug/L 1000 1060 106 80-120 Manganese ug/L 80 85.9 107 80-120 Molybdenum ug/L 80 81.9 102 80-120 Nickel ug/L 80 85.1 106 80-120 Potassium ug/L 1000 1030 103 80-120 Selenium ug/L 80 81.4 102 80-120 Sodium ug/L 1000 1090 109 80-120 Strontium ug/L 80 79.6 100 80-120 Thallium ug/L 80 85.9 107 80-120 Vanadium ug/L 80 83.0 104 80-120 Zinc ug/L 80 86.6 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1928546 1928547 MS MSD 10301215001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 462 80 80 736 659 342 246 75-125 11 20 M1 Antimony ug/L ND 80 80 79.5 76.8 99 96 75-125 3 20 Arsenic ug/L 0.72 80 80 80.5 78.1 100 97 75-125 3 20 Barium ug/L 9.5 80 80 91.3 87.6 102 98 75-125 4 20 Beryllium ug/L ND 80 80 84.2 82.1 105 102 75-125 3 20 Boron ug/L ND 80 80 94.7 88.2 113 104 75-125 7 20 Cadmium ug/L ND 80 80 84.6 81.9 106 102 75-125 3 20 Calcium ug/L 8420 1000 1000 9820 9580 140 117 75-125 2 20 M1 Chromium ug/L 14.6 80 80 101 98.4 108 105 75-125 3 20 Cobalt ug/L 0.69 80 80 86.0 83.0 107 103 75-125 3 20 Copper ug/L 7.6 80 80 88.2 84.6 101 96 75-125 4 20 Iron ug/L 4930 1000 1000 6160 5670 124 75 75-125 8 20 Lead ug/L 1.2 80 80 86.9 84.2 107 104 75-125 3 20 Magnesium ug/L 680 1000 1000 1790 1730 111 105 75-125 3 20 Manganese ug/L 261 80 80 357 349 119 110 75-125 2 20 Molybdenum ug/L 2.5 80 80 84.6 81.8 103 99 75-125 3 20 Nickel ug/L 3.6 80 80 88.9 85.9 107 103 75-125 3 20 Potassium ug/L 130 1000 1000 1190 1160 106 103 75-125 2 20 Selenium ug/L ND 80 80 82.0 79.9 102 100 75-125 3 20 Sodium ug/L 4590 1000 1000 5850 5690 126 111 75-125 3 20 M1 Strontium ug/L 19.6 80 80 101 97.5 101 97 75-125 3 20 Thallium ug/L ND 80 80 86.7 84.3 108 105 75-125 3 20 Vanadium ug/L 2.4 80 80 87.3 85.1 106 103 75-125 3 20 Zinc ug/L 75.4 80 80 161 156 108 100 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 69 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030402 Pace Project No.: 92241387 QC Batch: MPRP/53309 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92241387010, 92241387011, 92241387012, 92241387014 METHOD BLANK: 1929565 Matrix: Water Associated Lab Samples: 92241387010, 92241387011, 92241387012, 92241387014 Blank Reporting Parameter Units Result Limit Analyzed Aluminum ug/L ND 10.0 04/02/15 09:30 Antimony ug/L ND 0.50 04/02/15 09:30 Arsenic ug/L ND 0.50 04/02/15 09:30 Barium ug/L ND 0.30 04/02/15 09:30 Beryllium ug/L ND 0.20 04/02/15 09:30 Boron ug/L ND 5.0 04/02/15 09:30 Cadmium ug/L ND 0.080 04/02/15 09:30 Calcium ug/L ND 40.0 04/02/15 09:30 Chromium ug/L ND 0.50 04/02/15 09:30 Cobalt ug/L ND 0.50 04/02/15 09:30 Copper ug/L ND 1.0 04/02/15 09:30 Iron ug/L ND 50.0 04/02/15 09:30 Lead ug/L ND 0.10 04/02/15 09:30 Magnesium ug/L ND 10.0 04/02/15 09:30 Manganese ug/L ND 0.50 04/02/15 09:30 Molybdenum ug/L ND 0.50 04/02/15 09:30 Nickel ug/L ND 0.50 04/02/15 09:30 Potassium ug/L ND 50.0 04/02/15 09:30 Selenium ug/L ND 0.50 04/02/15 09:30 Sodium ug/L ND 50.0 04/02/15 09:30 Strontium ug/L ND 0.50 04/02/15 09:30 Thallium ug/L ND 0.10 04/02/15 09:30 Vanadium ug/L ND 1.0 04/02/15 09:30 Zinc ug/L ND 5.0 04/02/15 09:30 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1929566 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum ug/L 80 79.6 99 80-120 Antimony ug/L 80 77.6 97 80-120 Arsenic ug/L 80 77.6 97 80-120 Barium ug/L 80 77.0 96 80-120 Beryllium ug/L 80 77.9 97 80-120 Boron ug/L 80 85.6 107 80-120 Cadmium ug/L 80 79.2 99 80-120 Calcium ug/L 1000 933 93 80-120 Chromium ug/L 80 79.6 99 80-120 Cobalt ug/L 80 78.1 98 80-120 Copper ug/L 80 92.9 116 80-120 Iron ug/L 1000 993 99 80-120 Pace Analytical Services, Inc. PARYWY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 70 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. PARYWY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 LABORATORY CONTROL SAMPLE: 1929566 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 83.2 104 80-120 Magnesium ug/L 1000 995 99 80-120 Manganese ug/L 80 79.5 99 80-120 Molybdenum ug/L 80 77.6 97 80-120 Nickel ug/L 80 80.3 100 80-120 Potassium ug/L 1000 973 97 80-120 Selenium ug/L 80 76.6 96 80-120 Sodium ug/L 1000 982 98 80-120 Strontium ug/L 80 76.8 96 80-120 Thallium ug/L 80 79.5 99 80-120 Vanadium ug/L 80 79.2 99 80-120 Zinc ug/L 80 80.7 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1929567 1929569 MS MSD 92241387014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 183 80 80 279 292 120 136 75-125 4 20 M1 Antimony ug/L ND 80 80 76.4 76.1 95 95 75-125 0 20 Arsenic ug/L 0.61 80 80 75.6 76.7 94 95 75-125 1 20 Barium ug/L 409 80 80 498 502 110 116 75-125 1 20 Beryllium ug/L ND 80 80 77.9 77.3 97 97 75-125 1 20 Boron ug/L 138 80 80 235 236 121 122 75-125 0 20 Cadmium ug/L ND 80 80 76.4 76.6 95 96 75-125 0 20 Calcium ug/L 791 1000 1000 1720 1790 93 100 75-125 4 20 Chromium ug/L 6.0 80 80 83.8 83.7 97 97 75-125 0 20 Cobalt ug/L 2.5 80 80 78.2 79.1 95 96 75-125 1 20 Copper ug/L 9.9 80 80 86.9 88.1 96 98 75-125 1 20 Iron ug/L 134 1000 1000 1090 1100 95 96 75-125 1 20 Lead ug/L 3.0 80 80 83.8 84.1 101 101 75-125 0 20 Magnesium ug/L 350 1000 1000 1320 1320 97 97 75-125 0 20 Manganese ug/L 54.7 80 80 131 132 96 96 75-125 0 20 Molybdenum ug/L 1.9 80 80 77.2 78.6 94 96 75-125 2 20 Nickel ug/L 3.5 80 80 81.4 81.2 97 97 75-125 0 20 Potassium ug/L 2090 1000 1000 3080 3130 99 104 75-125 2 20 Selenium ug/L ND 80 80 74.2 75.9 92 94 75-125 2 20 Sodium ug/L 2280 1000 1000 3330 3360 104 108 75-125 1 20 Strontium ug/L 11.6 80 80 86.6 87.2 94 94 75-125 1 20 Thallium ug/L ND 80 80 78.9 79.6 99 99 75-125 1 20 Vanadium ug/L ND 80 80 78.2 77.9 97 96 75-125 0 20 Zinc ug/L 212 80 80 300 305 110 116 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 71 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. PAMIirWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 QC Batch: PMST/3372 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92241387002, 92241387003, 92241387004, 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 SAMPLE DUPLICATE: 1164355 35179495002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 36.5 61.7 51 10 D6 SAMPLE DUPLICATE: 1164356 92241387008 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 25.0 27.7 10 10 SAMPLE DUPLICATE: 1164357 92241477008 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 6.9 6.7 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 72 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. POO WY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: WET/29835 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92241387002, 92241387003, 92241387004, 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 SAMPLE DUPLICATE: 1161038 92241387002 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 8.1 8.1 0 20 H6 SAMPLE DUPLICATE: 1161039 92241477002 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.4 6.5 0 20 H6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 73 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. PARVrWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 QC Batch: WETA/22391 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 METHOD BLANK: 1422986 Matrix: Water Associated Lab Samples: 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 4.9 4.0 04/02/1511:41 D3 LABORATORY CONTROL SAMPLE: 1422987 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.3 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1422988 1422989 MS MSD 92241061007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 8.5 24.8 24.8 32.9 33.2 98 99 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1422990 1422991 MS MSD 92241965003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 45.8 29.5 29.5 42.6 47.5 -11 6 11 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 74 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. PARV16fY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 QC Batch: WETA/22397 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 METHOD BLANK: 1423312 Matrix: Water Associated Lab Samples: 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 148 1.0 03/31/15 18:55 P8 LABORATORY CONTROL SAMPLE: 1423313 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.3 94 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1423314 1423315 MS MSD 92241387006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 467 2.8 2.8 478 480 418 490 90-110 0 10 H1,M6 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1423316 1423317 MS MSD 92241387007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 317 3.3 3.3 316 317 -34 -16 90-110 0 10 H1,M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 75 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P36919rwyo%e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 QC Batch: WETA/22349 Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 METHOD BLANK: 1420866 Matrix: Water Associated Lab Samples: 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 03/27/15 04:28 LABORATORY CONTROL SAMPLE: 1420867 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.1 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1420868 1420869 MS MSD 92241061007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 24.8 24.8 25.6 25.5 101 100 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1420870 1420871 MS MSD 92241225003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 29.6 29.6 32.4 32.3 104 104 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 76 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030402 Pace Project No.: 92241387 Pace Analytical Services, Inc. POO WY046e. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: WETA/44698 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92241387002, 92241387003, 92241387004, 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 METHOD BLANK: 1160802 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.6 03/20/15 05:49 Sulfate mg/kg ND 49.6 03/20/15 05:49 LABORATORY CONTROL SAMPLE: 1160803 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1160805 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1160804 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 496 468 94 80-120 496 471 95 80-120 92241477010 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers 412 3770 986 15 80-120 M1 1460 3770 2320 23 80-120 M1 92241477010 Dup Units Result Result mg/kg 412 440 mg/kg 1460 1750 Max RPD RPD Qualifiers 7 20 18 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 77 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. PARVrWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 QC Batch: WETA/44700 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92241387002, 92241387003, 92241387004, 92241387005, 92241387006, 92241387007, 92241387008, 92241387009 METHOD BLANK: 1160812 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 03/20/15 05:49 LABORATORY CONTROL SAMPLE: 1160813 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.6 49.1 99 80-120 MATRIX SPIKE SAMPLE: 1160815 92241477010 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 377 68.7 18 80-120 H3,M1 SAMPLE DUPLICATE: 1160814 92241477010 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 78 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P36gmirpY&.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 QC Batch: WETA/27666 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92241387002 METHOD BLANK: 1129856 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 03/23/15 07:17 LABORATORY CONTROL SAMPLE: 1129857 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 110000 91 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1129858 1129859 MS MSD 92241061010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 35200 52700 52600 75300 65000 76 57 50-150 15 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 79 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P36906rwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030402 Pace Project No.: 92241387 QC Batch: WETA/27681 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92241387003,92241387004,92241387005,92241387006,92241387007,92241387008,92241387009 METHOD BLANK: 1130748 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 03/24/15 14:34 LABORATORY CONTROL SAMPLE: 1130749 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 105000 88 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1130750 1130751 MS MSD 92241387004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 120000 54000 54100 155000 152000 65 60 50-150 2 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 80 of 87 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15030402 Pace Project No.: 92241387 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, Inc. P36906rWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. H6 Analysis initiated outside of the 15 minute EPA recommended holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 81 of 87 aceAnaiXical www.pacelabs.com Project: J15030402 Pace Project No.: 92241387 ANALYTE QUALIFIERS QUALIFIERS REPORT OF LABORATORY ANALYSIS Pace Analytical Services, Inc. PAROAirWY�e. Suite 100 y Huntersville, INC 28078 (704)875-9092 This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 82 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. PAROAirWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15030402 92241387 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92241387002 2015007392 EPA 3050 MPRP/23201 EPA 6010 ICP/14202 92241387003 2015007395 EPA 3050 MPRP/23201 EPA 6010 ICP/14202 92241387004 2015007396 EPA 3050 MPRP/23201 EPA 6010 ICP/14202 92241387005 2015007393 EPA 3050 MPRP/23201 EPA 6010 ICP/14202 92241387006 2015007394 EPA 3050 MPRP/23201 EPA 6010 ICP/14202 92241387007 2015007397 EPA 3050 MPRP/23201 EPA6010 ICP/14202 92241387008 2015007398 EPA 3050 MPRP/23201 EPA 6010 ICP/14202 92241387009 2015007399 EPA 3050 MPRP/23201 EPA 6010 ICP/14202 92241387002 2015007392 EPA 3050 MPRP/23202 EPA 6020 ICPM/9455 92241387003 2015007395 EPA 3050 MPRP/23202 EPA 6020 ICPM/9455 92241387004 2015007396 EPA 3050 MPRP/23202 EPA 6020 ICPM/9455 92241387005 2015007393 EPA 3050 MPRP/23202 EPA 6020 ICPM/9455 92241387006 2015007394 EPA 3050 MPRP/23202 EPA 6020 ICPM/9455 92241387007 2015007397 EPA 3050 MPRP/23202 EPA 6020 ICPM/9455 92241387008 2015007398 EPA 3050 MPRP/23202 EPA 6020 ICPM/9455 92241387009 2015007399 EPA 3050 MPRP/23202 EPA 6020 ICPM/9455 92241387001 2015007400 EPA 3020 MPRP/53084 EPA 6020A ICPM/23509 92241387010 2015007393 SPLP EPA 3020 MPRP/53309 EPA 6020A ICPM/23628 92241387011 2015007394 SPLP EPA 3020 MPRP/53309 EPA 6020A ICPM/23628 92241387012 2015007397 SPLP EPA 3020 MPRP/53309 EPA 6020A ICPM/23628 92241387013 2015007398 SPLP EPA 3020 MPRP/53234 EPA 6020A ICPM/23613 92241387014 2015007399 SPLP EPA 3020 MPRP/53309 EPA 6020A ICPM/23628 92241387001 2015007400 EPA 7470 MERP/13035 EPA 7470 MERC/15132 92241387010 2015007393 SPLP EPA 7470 MERP/13085 EPA 7470 MERC/15217 92241387011 2015007394 SPLP EPA 7470 MERP/13085 EPA 7470 MERC/15217 92241387012 2015007397 SPLP EPA 7470 MERP/13085 EPA 7470 MERC/15217 92241387013 2015007398 SPLP EPA 7470 MERP/13085 EPA 7470 MERC/15217 92241387014 2015007399 SPLP EPA 7470 MERP/13085 EPA 7470 MERC/15217 92241387002 2015007392 EPA 7471 MERP/5501 EPA 7471 MERC/5491 92241387003 2015007395 EPA 7471 MERP/5501 EPA 7471 MERC/5491 92241387004 2015007396 EPA 7471 MERP/5501 EPA 7471 MERC/5491 92241387005 2015007393 EPA 7471 MERP/5501 EPA 7471 MERC/5491 92241387006 2015007394 EPA 7471 MERP/5501 EPA 7471 MERC/5491 92241387007 2015007397 EPA 7471 MERP/5501 EPA 7471 MERC/5491 92241387008 2015007398 EPA 7471 MERP/5501 EPA 7471 MERC/5491 92241387009 2015007399 EPA 7471 MERP/5501 EPA 7471 MERC/5491 92241387002 2015007392 ASTM D2974-87 PMST/3372 92241387003 2015007395 ASTM D2974-87 PMST/3372 92241387004 2015007396 ASTM D2974-87 PMST/3372 92241387005 2015007393 ASTM D2974-87 PMST/3372 92241387006 2015007394 ASTM D2974-87 PMST/3372 92241387007 2015007397 ASTM D2974-87 PMST/3372 92241387008 2015007398 ASTM D2974-87 PMST/3372 92241387009 2015007399 ASTM D2974-87 PMST/3372 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Page 83 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030402 Pace Project No.: 92241387 Lab ID Sample ID QC Batch Method QC Batch 92241387002 2015007392 EPA 9045 WET/29835 92241387003 2015007395 EPA 9045 WET/29835 92241387004 2015007396 EPA 9045 WET/29835 92241387005 2015007393 EPA 9045 WET/29835 92241387006 2015007394 EPA 9045 WET/29835 92241387007 2015007397 EPA 9045 WET/29835 92241387008 2015007398 EPA 9045 WET/29835 92241387009 2015007399 EPA 9045 WET/29835 92241387005 2015007393 EPA 300.0 WETA/22391 92241387006 2015007394 EPA 300.0 WETA/22391 92241387007 2015007397 EPA 300.0 WETA/22391 92241387008 2015007398 EPA 300.0 WETA/22391 92241387009 2015007399 EPA 300.0 WETA/22391 92241387005 2015007393 EPA 353.2 WETA/22397 92241387006 2015007394 EPA 353.2 WETA/22397 92241387007 2015007397 EPA 353.2 WETA/22397 92241387008 2015007398 EPA 353.2 WETA/22397 92241387009 2015007399 EPA 353.2 WETA/22397 92241387005 2015007393 SM 4500 -CI -E WETA/22349 92241387006 2015007394 SM 4500 -CI -E WETA/22349 92241387007 2015007397 SM 4500 -CI -E WETA/22349 92241387008 2015007398 SM 4500 -CI -E WETA/22349 92241387009 2015007399 SM 4500 -CI -E WETA/22349 92241387002 2015007392 EPA 9056 WETA/44698 92241387003 2015007395 EPA 9056 WETA/44698 92241387004 2015007396 EPA 9056 WETA/44698 92241387005 2015007393 EPA 9056 WETA/44698 92241387006 2015007394 EPA 9056 WETA/44698 92241387007 2015007397 EPA 9056 WETA/44698 92241387008 2015007398 EPA 9056 WETA/44698 92241387009 2015007399 EPA 9056 WETA/44698 92241387002 2015007392 EPA 9056 WETA/44700 92241387003 2015007395 EPA 9056 WETA/44700 92241387004 2015007396 EPA 9056 WETA/44700 92241387005 2015007393 EPA 9056 WETA/44700 92241387006 2015007394 EPA 9056 WETA/44700 92241387007 2015007397 EPA 9056 WETA/44700 92241387008 2015007398 EPA 9056 WETA/44700 92241387009 2015007399 EPA 9056 WETA/44700 92241387002 2015007392 EPA 9060 WETA/27666 92241387002 2015007392 EPA 9060 WETA/27667 92241387003 2015007395 EPA 9060 WETA/27681 92241387003 2015007395 EPA 9060 WETA/27682 92241387004 2015007396 EPA 9060 WETA/27681 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/13/2015 04:11 PM without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. PAROAirWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Analytical Analytical Method Batch Page 84 of 87 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030402 Pace Project No.: 92241387 Lab ID Sample ID QC Batch Method QC Batch 92241387004 2015007396 EPA 9060 WETA/27682 92241387005 2015007393 EPA 9060 WETA/27681 92241387005 2015007393 EPA 9060 WETA/27682 92241387006 2015007394 EPA 9060 WETA/27681 92241387006 2015007394 EPA 9060 WETA/27682 92241387007 2015007397 EPA 9060 WETA/27681 92241387007 2015007397 EPA 9060 WETA/27682 92241387008 2015007398 EPA 9060 WETA/27681 92241387008 2015007398 EPA 9060 WETA/27682 92241387009 2015007399 EPA 9060 WETA/27681 92241387009 2015007399 EPA 9060 WETA/27682 Date: 04/13/2015 04:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. PAROOrWY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Analytical Method Analytical Batch Page 85 of 87 s r�cc,4llt�tyfical� I Client Name: 1�'A () Document Name: Sample Condition Upon Receil Document Number: F-CMR-CS-003-rev.15 URI IDocument Revised: September 22, ZU14 _Page 1 of 2 issuing Auf F" ' VU Pace Huntersville Quality Office Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ Commercial❑ Pace Other Custody Seal on Cooler/Box Present: a yes ❑Y no Seals intact: ❑ yes ❑ no Packing Material: ❑ Bubble V❑p ❑Aubble Bags ❑ None ❑ Other Thermometer Used: IR Gun T1401 Type of Ice: (We Blue None ❑'Samples on ice, cooling process has begun Tmmn (`.nrrnrFinn Farinr T1dt14 Nn rnrrpctinn ;!� 'C Biological Tissue is Frozen: Yes No NIA Date Em ,lnitials)of person examining Corrected Cooler Temp.: .` conte�it ? C� Temp should be above freezing to 6°C Comments: Chain of Custody Present: pfes ONO ®NIA 1. Chain of Custody Filled Out: pies ❑No ONIA 2. Chain of Custody Relinquished: 1JYes ONO ❑NIA 3. Sampler Name & Signature on COC: dyes []No ❑NIA 4. Samples Arrived within Hold Time: KYes ONO ❑NIA 5, Short Hold Time Analysis (<72hr): Oyes 117No ❑NIA 6. Rush Turn Around Time Requested: Dyes INo ❑NIA 7. Sufficient Volume: -Elyes []No ❑NIA 8. Correct Containers Used: Ives ONO ❑NIA 9. -Pace Containers Used: []Yes ❑tufo El NIA Containers Intact: IYes ❑No ❑NIA 10. Filtered volume received for Dissolved tests Dyes L]No 171 NIA 11. Sample Labels match COC: ❑Yes ONO ❑NIA 12. -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. Yes ON EQ 13: All containers needing preservation are found to be in ,/ IQYes ❑No - N, . )� LP O IA compliance with EPA recommendation. exceptions: VOA, coliform, TOC, O&G, Wl DRO (water) ❑Yes ❑ No Samples checked for dechlorination: Dyes ONO ❑ 1A 14. Headspace in VOA Vials >6mm): ❑Yes ONO LIMA 15. Trip Blank Present: ❑Yes ❑No NIA 16. Trip Blank Custody Seals Present Dyes ONO ❑NIA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Field Data Required? Y 1 N Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: I Date: 3 / I SRF Revlew Date: f(7 Note: Whenever there a discrepancy affecting North Carolina compliance samples, a copv of this form will be sent to the North Carolina DEHNR WO#92241387 1111111111111111111111 Certification Office ( Le out of hold, incorrect preservative, out of temp, incorrect containers) Page 86 of 87 I a 9 Ax j ; o rnID �.� N Z Q 0 O ,a x7 o 3 :E Z -i y ! nQ :r ro m A I I i i e Lk R :EE N N' t i i Y �v�y�Iri`a4 W VV 3 —. Customer to complete appropriate o!unu s to Fight Z C (�y � � /t'► ! [� G 4 J � a _ - � N n S ��yW1� w�a �a �1 ± a �J m a 0 g n v o° 07 S Ax rnID �.� N 0 O ,a x7 o 3 :E Z -i y ! nQ :r ro m A I I i i e Lk R :EE N N' t i i K „ m 0 O i =fir Cutio—Fr -1 s16om01e1eage 99 of 100 AWNS rnID 0 M O c 3 :E Z -i y ! nQ :r ro m A I I i i e a R :EE N N' t i i K „ m 0 O i =fir g o JiX� � {.r R x I � I I a 9 00 i � ! 'ri i gj l i In r. •.r 3 L_ -,-,_,_,_,_•i U) 0 :E Z -i y ! N i K „ m 0 O 0 00 r. •.r 3 ( �. O C , I Z •� 17Cpmp.10A aly6 S k "Grab Req Ire a ' Total Metals , Anions, p1 O i� ; pH -" 1 - 8 oz jar (PACE) 5 o ■ 5+,t4S 0. Im o - c� TOC 1-4ozjar: 4 3 aim (PACE) I e i fA 0! SPLP -Total Metals 9J R� and Anions - i 2 - 8 oz jars (PACE) " Ai Sediment specific tests 2.8 oz Jar m (ACCESS i ANALYTICAL) 5 i z i o m ri -_- 7 A O O'y ! p p y =1 O t3�C —1 fS; rc' UI 0... z 450 z 20rotal a of Containers b Page 87 of 87 1 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM DIU ! Analytical Laboratory Services - -i i - - - - - Analytical Laboratory 1 faiiil,,, Use Only ------------- ._._.-.-•------------ I x- Pag�e•I df 100 Mail Code MG03A2 (Building 7466) Matrix. { ��7"+�entOider 7 ,OIL �`1 Vo 13338 Hagers Ferry Rd � i DISTRIBUTION I I [.. ENERGY Huntersville, N. C. 28676 I ILo88sd By oat. s Tama Samples Orl inatln From pH — I ORIGINAL to LAB, M Ileo) els-sz4s l l ! 1� I COPY to CLIENT t _ _ _ _ _ _Fax; 996 875-4348 5� • �}i� .�_..1.._._. _. _._-_._._. _._I _ _ SAMPLE PROGRAM Groundwater NPDESj I IProject Name AB Groundwater Assessment - Soil 2)Phons No: PACE Clc Q Other_ Plant _ 1 j REV DATE 21100015 Asheville Cooler Ternp JCJ 31Cllerd 4)Fsx No: PO 1142051 uPr Accept "- DMeftime �-� - a t Seatedlt_ocked By DatelTme SealedlLock opened ay DatetTime 48 Hr 24jcammeMe Metals: Al, Sb, As, Be, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg., Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Mercury, pH Anions. Cl,Nitrate-N, SO4 Sediment Specific Parameters: %Solids CEC Particle Size Distribution Redox Potential serv.:1=H AB GW 2=H,t7� 3=H -••-••_.._.._.._. ._.._,.� .�j 4=Ice 3= one u7 u3 $)Business Unit: ajProject ID: ?)Mall code; a. LOOK 1-4 u; ej Operative unit; xt: - fejprocess ID 14sv tE , y Q N ELjj ... _. o Q 0 N < _ Important: when specific accounting has been established and is not indicated above. Preservatives when used must be � � � ., N d Q O -j � t' we need the following: 1) Enter correct accounting in all 5 accounting fields above, Of added within 15 minutes of sampleL 2 Prowde ,d, I�S c � � � Q correct accountin tnr O eratin Unit and Process ID. collection N .i-\ � p A C ' (i9 ny F LAB USE ONLY I Matrix 74Cgllection Information E Uj U Q 00 V V ;j O .� {Soil, Sediment, As 13 (� Crj Z i "Lab ID ; Sam le Description or ID Dale Ttma Signature ~ Q Q 0 i� C d N i.i Z ti plv1S�__t4g)— IN ^'K,/ 3[lz, a 245 4 L .Sill* j C�j ia`F♦*iio�ll 1ji� / , 1 L?� 10i 24-Z5 { _ 3-3+ 3lr4s liralr ;IrO1�--f x,2- ?S 6' a Sell CZ -3 i a til1315_ 3&2411 i125' 0' - {`1 _ - 04 d L-+ 3kk otliw �0 I 1� 1 io I Y I I I I I 1 i W TER EQUIPMENT BLANK (1 PER DAY) 2ijRalinqulshed aY > 6asdTlma r + . . -,5'1 Accepted By: Datairn to 22 Requested Turnaround , ,Tf� Relinquished � Dasa& in7s r Accepted By: T 14 Days -Daterrlme 1 x_ Relinquished By- • _� t7 7 Days Accept "- DMeftime �-� - a t Seatedlt_ocked By DatelTme SealedlLock opened ay DatetTime 48 Hr 24jcammeMe Metals: Al, Sb, As, Be, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg., Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Mercury, pH Anions. Cl,Nitrate-N, SO4 Sediment Specific Parameters: %Solids CEC Particle Size Distribution Redox Potential