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HomeMy WebLinkAboutNC0000396_J15030308 Report_20150823DUE Analytical Laboratory Page 1 of 109 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report J15030308 AB GW ASSESSMENT SOIL Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker 200 CP and L Drive Arden,NC 28704 Margaret Galvin -Karr Phone: 980-875-5219 marge.galvin-karr@du ke- U�w°A energy.com 2015.04.1010:34:39-04'00' Date: Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 4/9/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time 2015006954 2015006955 2015006956 2015006957 2015006958 2015006959 2015006960 2015006961 2015006962 9 Total Samples Collected By Sample Description Page 2 of 109 ASHEVILLE 10 -Mar -15 9:55 AM Illegible Equipment Blank ASHEVILLE 10 -Mar -15 10:00 AM Illegible ABMW-02 5B (2-3) ASHEVILLE 10 -Mar -15 11:45 AM Illegible ABMW-02 513 (16.5-17) ASHEVILLE 10 -Mar -15 10:50 AM Illegible ABMW-02 5B (28-29) ASHEVILLE 10 -Mar -15 12:00 PM Illegible ABMW-02 5B (33-34) ASHEVILLE 10 -Mar -15 11:50 AM Illegible ABMW-02 5B (40-41) ASHEVILLE 10 -Mar -15 4:45 PM Illegible ABMW-08 5B (4-5) ASHEVILLE 10 -Mar -15 5:00 PM Illegible ABMW-08 5B (25-27) ASHEVILLE 10 -Mar -15 5:15 PM Illegible ABMW-08 5B (30-31) Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: LU Job Summary Report ❑ Sample Identification P/1 Technical Validation of Data Package J❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Page 3 of 109 LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries d❑ Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 4/9/2015 Certificate of Laboratory Analysis Page 4 of 109 This report shall not be reproduced, except in full. Order # J15030308 Site: Equipment Blank Collection Date: 10 -Mar -15 9:55 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015006954 Matrix: OTHER Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030308 Site: ABMW-02 5B (2-3) Collection Date: 10 -Mar -15 10:00 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 5 of 109 Sample #: 2015006955 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030308 Site: ABMW-02 5B (16.5-17) Collection Date: 10 -Mar -15 11:45 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 6 of 109 Sample #: 2015006956 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030308 Site: ABMW-02 5B (28-29) Collection Date: 10 -Mar -15 10:50 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 7 of 109 Sample #: 2015006957 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030308 Site: ABMW-02 5B (33-34) Collection Date: 10 -Mar -15 12:00 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 8 of 109 Sample #: 2015006958 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030308 Site: ABMW-02 5B (40-41) Collection Date: 10 -Mar -15 11:50 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 9 of 109 Sample #: 2015006959 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030308 Site: ABMW-08 5B (4-5) Collection Date: 10 -Mar -15 4:45 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 10 of 109 Sample #: 2015006960 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030308 Site: ABMW-08 5B (25-27) Collection Date: 10 -Mar -15 5:00 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 11 of 109 Sample #: 2015006961 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030308 Site: ABMW-08 5B (30-31) Collection Date: 10 -Mar -15 5:15 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 12 of 109 Sample #: 2015006962 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE aceAnaiXical www.pacelabs.com March 31, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15030308 Pace Project No.: 92241060 Pace Analytical Services, Inc. P3Syyg01lsweyNe. Suite 100 Huntersville, INC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on March 12, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy HiQ p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� ��� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 96 lacmnalyfica( www.pacelabs.com Project: J15030308 Pace Project No.: 92241060 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21 -A Certification #: 2926.01 Alaska Certification #: UST -078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ -0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH -0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. 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Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN -002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 96 aceAnaiXical www.pacelabs.com Project: J15030308 Pace Project No.: 92241060 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. P3Syyg011 weyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 96 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15030308 Pace Project No.: 92241060 Lab ID Sample ID Matrix Date Collected Date Received 92241060001 2015006954 Solid 03/10/15 09:55 03/12/15 16:20 92241060002 2015006955 Solid 03/10/1510:00 03/12/1516:20 92241060003 2015006956 Solid 03/10/1511:45 03/12/1516:20 92241060004 2015006959 Solid 03/10/1511:50 03/12/1516:20 92241060005 2015006960 Solid 03/10/1516:45 03/12/1516:20 92241060006 2015006957 Solid 03/10/1510:50 03/12/1516:20 92241060007 2015006958 Solid 03/10/1512:00 03/12/1516:20 92241060008 2015006961 Solid 03/10/1517:00 03/12/1516:20 92241060009 2015006962 Solid 03/10/1517:15 03/12/1516:20 92241060010 2015006957 SPLP Water 03/10/15 10:50 03/12/15 16:20 92241060011 2015006958 SPLP Water 03/10/15 12:00 03/12/15 16:20 92241060012 2015006961 SPLP Water 03/10/15 17:00 03/12/15 16:20 92241060013 2015006962 SPLP Water 03/10/15 17:15 03/12/15 16:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. p3ago t weyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 96 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. Pggoi wleyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15030308 92241060 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92241060001 2015006954 EPA 6020A RJS 24 PASI-M EPA 7470 JDD 1 PASI-M 92241060002 2015006955 EPA 6010 CKJ, TAP 15 PASI-0 EPA 6020 DRS 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9045 KAM 1 PASI-O EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241060003 2015006956 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 HEA 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241060004 2015006959 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241060005 2015006960 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241060006 2015006957 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 96 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Project: J15030308 Pace Project No.: 92241060 Pace Analytical Services, Inc. Pggoi wleyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 7471 TAP 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E DMN 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241060007 2015006958 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E DMN 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241060008 2015006961 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 HEA 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E DMN 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241060009 2015006962 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 HEA 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 96 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Project: J15030308 Pace Project No.: 92241060 Pace Analytical Services, Inc. P36g01qrwyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E DMN 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241060010 2015006957 SPLP EPA 6020A TT3 24 PASI-M EPA 7470 DM 1 PASI-M 92241060011 2015006958 SPLP EPA 6020A TT3 24 PASI-M EPA 7470 DM 1 PASI-M 92241060012 2015006961 SPLP EPA 6020A TT3 24 PASI-M EPA 7470 DM 1 PASI-M 92241060013 2015006962 SPLP EPA 6020A TT3 24 PASI-M EPA 7470 DM 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 96 aceAnaiXical www.pacelabs.com Project: J15030308 Pace Project No.: 92241060 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. P3608rWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92241060001 2015006954 EPA 6020A Aluminum 326 ug/L 10.0 03/18/15 11:44 EPA 6020A Barium 2.6 ug/L 0.30 03/18/15 11:44 EPA 6020A Calcium 71.4 ug/L 40.0 03/18/15 11:44 EPA 6020A Chromium 0.61 ug/L 0.50 03/18/15 11:44 EPA 6020A Cobalt 1.2 ug/L 0.50 03/18/15 11:44 EPA 6020A Iron 361 ug/L 50.0 03/18/15 11:44 EPA 6020A Lead 0.34 ug/L 0.10 03/18/15 11:44 EPA 6020A Magnesium 76.9 ug/L 10.0 03/18/15 11:44 EPA 6020A Manganese 9.2 ug/L 0.50 03/18/15 11:44 EPA 6020A Potassium 67.2 ug/L 50.0 03/18/15 11:44 92241060002 2015006955 EPA 6010 Aluminum 13900 mg/kg 6.8 03/24/15 12:47 EPA 6010 Barium 274 mg/kg 0.68 03/24/15 12:47 EPA 6010 Boron 28.9 mg/kg 16.9 03/24/15 15:53 EPA 6010 Calcium 1700 mg/kg 33.8 03/24/15 12:47 EPA 6010 Chromium 36.6 mg/kg 1.7 03/24/15 15:53 EPA 6010 Copper 47.4 mg/kg 1.7 03/24/15 15:53 EPA 6010 Iron 6070 mg/kg 2.7 03/24/15 12:47 EPA 6010 Magnesium 987 mg/kg 33.8 03/24/15 12:47 EPA 6010 Manganese 61.0 mg/kg 1.7 03/24/15 15:53 EPA 6010 Molybdenum 1.4 mg/kg 0.68 03/24/15 12:47 EPA 6010 Nickel 18.2 mg/kg 0.34 03/24/15 12:47 EPA 6010 Potassium 2680 mg/kg 67.7 03/24/15 12:47 EPA 6010 Sodium 270 mg/kg 67.7 03/24/15 12:47 EPA 6010 Strontium 158 mg/kg 0.68 03/24/15 12:47 EPA 6010 Zinc 39.4 mg/kg 1.4 03/24/15 12:47 EPA 6020 Arsenic 233 mg/kg 3.4 03/24/15 10:09 EPA 6020 Beryllium 3.4 mg/kg 0.41 03/24/15 10:09 EPA 6020 Cadmium 0.38J mg/kg 0.41 03/24/15 10:09 EPA 6020 Cobalt 13.5 mg/kg 3.4 03/24/15 10:09 EPA 6020 Lead 25.9 mg/kg 3.4 03/24/15 10:09 EPA 6020 Selenium 16.6 mg/kg 3.4 03/24/15 10:09 EPA 6020 Vanadium 63.8 mg/kg 3.4 03/24/15 10:09 EPA 7471 Mercury 0.26 mg/kg 0.010 03/24/15 17:59 ASTM D2974-87 Percent Moisture 23.8 % 0.10 03/24/15 14:03 EPA 9045 pH at 25 Degrees C 8.8 Std. Units 0.10 03/17/15 15:25 EPA 9045 pH at 25 Degrees C 7.1 Std. Units 0.10 03/23/15 13:27 EPA 9060 Total Organic Carbon 28800 mg/kg 6080 03/20/15 08:37 EPA 9060 Total Organic Carbon 20000 mg/kg 6120 03/20/15 08:42 EPA 9060 Total Organic Carbon 23600 mg/kg 6370 03/20/15 08:48 EPA 9060 Total Organic Carbon 38800 mg/kg 6210 03/20/15 08:53 EPA 9060 Mean Total Organic Carbon 27800 mg/kg 6190 03/20/15 08:37 EPA 9060 RSD% 29.5 % 03/20/15 08:37 92241060003 2015006956 D3 D3 D3 D3 D4 D3 D3 D3 D3 D3 D4 0. Qualifiers EPA 6010 Aluminum 10800 mg/kg 35.6 03/24/1509:55 D3,M1 EPA 6010 Barium 281 mg/kg 3.6 03/24/1509:55 D3,M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 96 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Pace Analytical Services, Inc. PggcO SirpyN.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15030308 92241060 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92241060003 2015006956 EPA 6010 Beryllium 1.8 mg/kg 0.071 03/24/15 09:50 EPA 6010 Boron 26.9 mg/kg 3.6 03/24/15 09:50 EPA 6010 Calcium 2840 mg/kg 35.6 03/24/15 09:50 EPA 6010 Chromium 15.3 mg/kg 1.8 03/24/1509:55 D3,M1 EPA 6010 Copper 30.5 mg/kg 1.8 03/24/1509:55 D3,M1 EPA 6010 Iron 6090 mg/kg 14.2 03/24/1509:55 D3,M1 EPA 6010 Magnesium 919 mg/kg 178 03/24/15 09:55 D3 EPA 6010 Manganese 38.7 mg/kg 1.8 03/24/1509:55 D3,M1 EPA 6010 Molybdenum 1.1 mg/kg 0.71 03/24/15 09:50 M1 EPA 6010 Nickel 17.0 mg/kg 1.8 03/24/1509:55 D3,M1 EPA 6010 Potassium 1480 mg/kg 71.2 03/24/15 09:50 M1 EPA 6010 Sodium 186 mg/kg 71.2 03/24/15 09:50 EPA 6010 Strontium 232 mg/kg 3.6 03/24/1509:55 D3,M1 EPA 6010 Zinc 26.0 mg/kg 7.1 03/24/15 09:55 D3 EPA 6020 Arsenic 64.2 mg/kg 3.6 03/23/1513:34 D3,M6 EPA 6020 Cadmium 0.44 mg/kg 0.43 03/23/15 13:34 D3 EPA 6020 Cobalt 7.2 mg/kg 3.6 03/23/1513:34 D3,M6 EPA 6020 Lead 11.7 mg/kg 3.6 03/23/1513:34 D3,M6 EPA 6020 Selenium 8.4 mg/kg 3.6 03/23/15 13:34 D3 EPA 6020 Vanadium 44.9 mg/kg 3.6 03/23/1513:34 D3,M6 EPA 7471 Mercury 0.29 mg/kg 0.011 03/23/15 13:28 ASTM D2974-87 Percent Moisture 28.2 % 0.10 03/23/15 15:58 EPA 9045 pH at 25 Degrees C 8.4 Std. Units 0.10 03/17/15 15:25 EPA 9060 Total Organic Carbon 74700 mg/kg 4510 03/20/15 09:45 EPA 9060 Total Organic Carbon 94200 mg/kg 4530 03/20/15 09:51 EPA 9060 Total Organic Carbon 78600 mg/kg 4440 03/20/15 09:58 EPA 9060 Total Organic Carbon 88500 mg/kg 4560 03/20/15 10:05 EPA 9060 Mean Total Organic Carbon 84000 mg/kg 4510 03/20/15 09:45 EPA 9060 RSD% 10.6 % 03/20/15 09:45 92241060004 2015006959 EPA 6010 Aluminum 15500 mg/kg 6.5 03/20/15 13:45 EPA 6010 Barium 140 mg/kg 0.65 03/20/15 13:45 EPA 6010 Beryllium 0.70 mg/kg 0.065 03/20/15 13:45 EPA 6010 Boron 13.3 mg/kg 3.3 03/20/15 13:45 EPA 6010 Calcium 61.4 mg/kg 32.7 03/20/15 13:45 EPA 6010 Chromium 10.7 mg/kg 0.33 03/20/15 13:45 EPA 6010 Copper 9.4 mg/kg 0.33 03/20/15 13:45 EPA 6010 Iron 17000 mg/kg 2.6 03/20/15 13:45 EPA 6010 Magnesium 3580 mg/kg 32.7 03/20/15 13:45 EPA 6010 Manganese 1140 mg/kg 1.6 03/20/15 19:46 D4 EPA 6010 Nickel 6.9 mg/kg 0.33 03/20/15 13:45 EPA 6010 Potassium 5150 mg/kg 65.4 03/20/15 13:45 EPA 6010 Strontium 4.8 mg/kg 0.65 03/20/15 13:45 EPA 6010 Zinc 60.4 mg/kg 1.3 03/20/15 13:45 EPA 6020 Arsenic 2.9J mg/kg 3.3 03/20/15 17:47 D3 EPA 6020 Cobalt 59.2 mg/kg 3.3 03/20/15 17:47 D3 EPA 6020 Lead 3.6 mg/kg 3.3 03/20/15 17:47 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 96 aceAnaiXical www.pacelabs.com Project: J15030308 Pace Project No.: 92241060 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. P360916fyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92241060004 2015006959 EPA 6020 Selenium 4.4 mg/kg 3.3 03/20/15 17:47 D3 EPA 6020 Vanadium 36.9 mg/kg 3.3 03/20/15 17:47 D3 ASTM D2974-87 Percent Moisture 20.2 % 0.10 03/23/15 15:59 EPA 9045 pH at 25 Degrees C 5.4 Std. Units 0.10 03/17/15 15:25 EPA 9056 Sulfate 246J mg/kg 310 03/17/15 21:37 D3 EPA 9060 RSD% 1.0 % 03/20/15 10:11 92241060005 2015006960 EPA 6010 Aluminum 10100 mg/kg 6.9 03/20/15 13:49 EPA 6010 Barium 272 mg/kg 0.69 03/20/15 13:49 EPA 6010 Beryllium 1.4 mg/kg 0.069 03/20/15 13:49 EPA 6010 Boron 18.0 mg/kg 3.5 03/20/15 13:49 EPA 6010 Calcium 1520 mg/kg 34.7 03/20/15 13:49 EPA 6010 Chromium 13.7 mg/kg 0.35 03/20/15 13:49 EPA 6010 Copper 23.5 mg/kg 0.35 03/20/15 13:49 EPA 6010 Iron 11800 mg/kg 2.8 03/20/15 13:49 EPA 6010 Magnesium 1090 mg/kg 34.7 03/20/15 13:49 EPA 6010 Manganese 103 mg/kg 0.35 03/20/15 13:49 EPA 6010 Molybdenum 0.98 mg/kg 0.69 03/20/15 13:49 EPA 6010 Nickel 12.3 mg/kg 0.35 03/20/15 13:49 EPA 6010 Potassium 1780 mg/kg 69.4 03/20/15 13:49 EPA 6010 Sodium 145 mg/kg 69.4 03/20/15 13:49 EPA 6010 Strontium 119 mg/kg 0.69 03/20/15 13:49 EPA 6010 Zinc 27.7 mg/kg 1.4 03/20/15 13:49 EPA 6020 Arsenic 55.1 mg/kg 3.5 03/20/15 17:49 D3 EPA 6020 Cobalt 9.5 mg/kg 3.5 03/20/15 17:49 D3 EPA 6020 Lead 12.0 mg/kg 3.5 03/20/15 17:49 D3 EPA 6020 Selenium 7.8 mg/kg 3.5 03/20/15 17:49 D3 EPA 6020 Vanadium 41.5 mg/kg 3.5 03/20/15 17:49 D3 EPA 7471 Mercury 0.18 mg/kg 0.011 03/20/15 17:45 ASTM D2974-87 Percent Moisture 24.4 % 0.10 03/23/15 15:59 EPA 9045 pH at 25 Degrees C 7.3 Std. Units 0.10 03/17/15 15:25 EPA 9060 Total Organic Carbon 51000 mg/kg 4870 03/20/15 10:34 EPA 9060 Total Organic Carbon 53400 mg/kg 4730 03/20/15 10:39 EPA 9060 Total Organic Carbon 48600 mg/kg 4830 03/20/15 10:45 EPA 9060 Total Organic Carbon 47200 mg/kg 4870 03/20/15 10:51 EPA 9060 Mean Total Organic Carbon 50000 mg/kg 4820 03/20/15 10:34 EPA 9060 RSD% 5.5 % 03/20/15 10:34 92241060006 2015006957 EPA 6010 Aluminum 14400 mg/kg 6.5 03/20/15 13:54 EPA 6010 Barium 158 mg/kg 0.65 03/20/15 13:54 EPA 6010 Beryllium 0.68 mg/kg 0.065 03/20/15 13:54 EPA 6010 Boron 20.2 mg/kg 3.3 03/20/15 13:54 EPA 6010 Calcium 2020 mg/kg 32.6 03/20/15 13:54 EPA 6010 Chromium 11.3 mg/kg 0.33 03/20/15 13:54 EPA 6010 Copper 11.8 mg/kg 0.33 03/20/15 13:54 EPA 6010 Iron 12000 mg/kg 2.6 03/20/15 13:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 96 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Pace Analytical Services, Inc. P3S�OzslWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15030308 92241060 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92241060006 2015006957 EPA 6010 Magnesium 919 mg/kg 32.6 03/20/15 13:54 EPA 6010 Manganese 70.0 mg/kg 0.33 03/20/15 13:54 EPA 6010 Molybdenum 113 mg/kg 0.65 03/20/15 13:54 EPA 6010 Nickel 12.7 mg/kg 0.33 03/20/15 13:54 EPA 6010 Potassium 1140 mg/kg 65.1 03/20/15 13:54 EPA 6010 Sodium 54.OJ mg/kg 65.1 03/20/15 13:54 EPA 6010 Strontium 93.8 mg/kg 0.65 03/20/15 13:54 EPA 6010 Zinc 33.0 mg/kg 1.3 03/20/15 13:54 EPA 6020 Antimony 1.8J mg/kg 3.3 03/20/1517:52 D3,N2 EPA 6020 Arsenic 247 mg/kg 3.3 03/20/15 17:52 D3 EPA 6020 Cadmium 0.68 mg/kg 0.39 03/20/15 17:52 D3 EPA 6020 Cobalt 9.7 mg/kg 3.3 03/20/15 17:52 D3 EPA 6020 Lead 16.4 mg/kg 3.3 03/20/15 17:52 D3 EPA 6020 Selenium 39.9 mg/kg 3.3 03/20/15 17:52 D3 EPA 6020 Vanadium 56.6 mg/kg 3.3 03/20/15 17:52 D3 EPA 7471 Mercury 0.040 mg/kg 0.0096 03/20/15 17:47 ASTM D2974-87 Percent Moisture 20.6 % 0.10 03/23/15 16:00 EPA 9045 pH at 25 Degrees C 7.4 Std. Units 0.10 03/17/15 15:25 EPA 300.0 Sulfate 7.0 mg/L 2.5 03/20/15 00:15 SM 4500 -CI -E Chloride 21.5 mg/L 6.3 03/19/15 21:16 EPA 9060 Total Organic Carbon 13600 mg/kg 981 03/20/15 10:57 EPA 9060 Total Organic Carbon 13000 mg/kg 983 03/20/15 11:03 EPA 9060 Total Organic Carbon 9370 mg/kg 986 03/20/15 11:09 EPA 9060 Total Organic Carbon 10100 mg/kg 984 03/20/15 11:15 EPA 9060 Mean Total Organic Carbon 11500 mg/kg 984 03/20/15 10:57 EPA 9060 RSD% 18.1 % 03/20/15 10:57 92241060007 2015006958 EPA 6010 Aluminum 6880 mg/kg 5.8 03/20/15 13:58 EPA 6010 Barium 47.7 mg/kg 0.58 03/20/15 13:58 EPA 6010 Beryllium 0.31 mg/kg 0.058 03/20/15 13:58 EPA 6010 Boron 8.6 mg/kg 2.9 03/20/15 13:58 EPA 6010 Calcium 192 mg/kg 29.1 03/20/15 13:58 EPA 6010 Chromium 5.1 mg/kg 0.29 03/20/15 13:58 EPA 6010 Copper 2.6 mg/kg 0.29 03/20/15 13:58 EPA 6010 Iron 9480 mg/kg 2.3 03/20/15 13:58 EPA 6010 Magnesium 1060 mg/kg 29.1 03/20/15 13:58 EPA 6010 Manganese 93.2 mg/kg 0.29 03/20/15 13:58 EPA 6010 Molybdenum 1.1 mg/kg 0.58 03/20/15 13:58 EPA 6010 Nickel 3.0 mg/kg 0.29 03/20/15 13:58 EPA 6010 Potassium 1590 mg/kg 58.2 03/20/15 13:58 EPA 6010 Strontium 10.4 mg/kg 0.58 03/20/15 13:58 EPA 6010 Zinc 32.3 mg/kg 1.2 03/20/15 13:58 EPA 6020 Arsenic 28.9 mg/kg 2.9 03/20/15 17:54 D3 EPA 6020 Cobalt 10.3 mg/kg 2.9 03/20/15 17:54 D3 EPA 6020 Lead 9.9 mg/kg 2.9 03/20/15 17:54 D3 EPA 6020 Selenium 10.3 mg/kg 2.9 03/20/15 17:54 D3 EPA 6020 Vanadium 17.6 mg/kg 2.9 03/20/15 17:54 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 96 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Pace Analytical Services, Inc. PARGA WyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92241060007 2015006958 ASTM D2974-87 Percent Moisture 15.8 % 0.10 03/23/15 16:00 EPA 9045 pH at 25 Degrees C 5.9 Std. Units 0.10 03/17/15 15:25 EPA 300.0 Sulfate 8.2 mg/L 2.4 03/20/15 00:29 EPA 353.2 Nitrogen, Nitrate 0.34 mg/L 0.24 03/18/1516:57 B,H1 EPA 9060 RSD% 3.9 % 03/20/15 11:20 92241060008 2015006961 EPA 6010 Aluminum 16100 mg/kg 6.2 03/20/15 20:12 EPA 6010 Barium 66.0 mg/kg 0.62 03/20/15 20:12 EPA 6010 Beryllium 0.86 mg/kg 0.31 03/20/15 20:16 D3 EPA 6010 Boron 23.1 mg/kg 15.4 03/20/15 20:16 D3 EPA 6010 Calcium 247 mg/kg 30.9 03/20/15 20:12 EPA 6010 Chromium 21.5 mg/kg 1.5 03/20/15 20:16 D3 EPA 6010 Copper 19.4 mg/kg 1.5 03/20/15 20:16 D3 EPA 6010 Iron 33000 mg/kg 12.4 03/20/15 20:16 D3 EPA 6010 Magnesium 1240 mg/kg 30.9 03/20/15 20:12 EPA 6010 Manganese 120 mg/kg 1.5 03/20/15 20:16 D3 EPA 6010 Molybdenum 0.46J mg/kg 0.62 03/20/15 20:12 EPA 6010 Nickel 5.0 mg/kg 0.31 03/20/15 20:12 EPA 6010 Potassium 870 mg/kg 61.8 03/20/15 20:12 EPA 6010 Sodium 33AJ mg/kg 61.8 03/20/15 20:12 EPA 6010 Strontium 9.9 mg/kg 0.62 03/20/15 20:12 EPA 6010 Zinc 24.9 mg/kg 1.2 03/20/15 20:12 EPA 6020 Arsenic 8.3 mg/kg 3.1 03/20/15 17:57 D3 EPA 6020 Cobalt 7.7 mg/kg 3.1 03/20/15 17:57 D3 EPA 6020 Lead 13.4 mg/kg 3.1 03/20/15 17:57 D3 EPA 6020 Selenium 2.9J mg/kg 3.1 03/20/15 17:57 D3 EPA 6020 Vanadium 33.7 mg/kg 3.1 03/20/15 17:57 D3 EPA 7471 Mercury 0.028 mg/kg 0.0098 03/23/15 13:39 ASTM D2974-87 Percent Moisture 20.7 % 0.10 03/23/15 16:01 EPA 9045 pH at 25 Degrees C 6.1 Std. Units 0.10 03/18/15 18:50 EPA 300.0 Sulfate 3.5 mg/L 2.5 03/20/15 00:42 SM 4500 -CI -E Chloride 16.2 mg/L 6.3 03/19/15 21:17 EPA 9060 Total Organic Carbon 8880 mg/kg 757 03/20/15 12:25 EPA 9060 Total Organic Carbon 10000 mg/kg 753 03/20/15 12:31 EPA 9060 Total Organic Carbon 12100 mg/kg 760 03/20/15 12:37 EPA 9060 Total Organic Carbon 7530 mg/kg 762 03/20/15 12:45 EPA 9060 Mean Total Organic Carbon 9630 mg/kg 758 03/20/15 12:25 EPA 9060 RSD% 20.0 % 03/20/15 12:25 92241060009 2015006962 EPA 6010 Aluminum 14900 mg/kg 5.9 03/20/15 20:20 EPA 6010 Barium 65.8 mg/kg 0.59 03/20/15 20:20 EPA 6010 Beryllium 0.75 mg/kg 0.30 03/20/15 20:25 D3 EPA 6010 Boron 17.9 mg/kg 14.8 03/20/15 20:25 D3 EPA 6010 Calcium 421 mg/kg 29.5 03/20/15 20:20 EPA 6010 Chromium 21.0 mg/kg 1.5 03/20/15 20:25 D3 EPA 6010 Copper 19.0 mg/kg 1.5 03/20/15 20:25 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 96 aceAnaiXical www.pacelabs.com Project: J15030308 Pace Project No.: 92241060 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. PARGArWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92241060009 2015006962 EPA 6010 Iron 19200 mg/kg 2.4 03/20/15 20:20 EPA 6010 Magnesium 2220 mg/kg 29.5 03/20/15 20:20 EPA 6010 Manganese 163 mg/kg 1.5 03/20/15 20:25 EPA 6010 Molybdenum 0.38J mg/kg 0.59 03/20/15 20:20 EPA 6010 Nickel 6.7 mg/kg 0.30 03/20/15 20:20 EPA 6010 Potassium 1660 mg/kg 59.1 03/20/15 20:20 EPA 6010 Sodium 40.OJ mg/kg 59.1 03/20/15 20:20 EPA 6010 Strontium 9.8 mg/kg 0.59 03/20/15 20:20 EPA 6010 Zinc 33.0 mg/kg 1.2 03/20/15 20:20 EPA 6020 Arsenic 6.3 mg/kg 3.0 03/20/15 17:59 EPA 6020 Cobalt 7.6 mg/kg 3.0 03/20/15 17:59 EPA 6020 Lead 12.9 mg/kg 3.0 03/20/15 17:59 EPA 6020 Selenium 2.8J mg/kg 3.0 03/20/15 17:59 EPA 6020 Vanadium 28.7 mg/kg 3.0 03/20/15 17:59 EPA 7471 Mercury 0.031 mg/kg 0.0089 03/23/15 13:41 ASTM D2974-87 Percent Moisture 12.6 % 0.10 03/23/15 16:01 EPA 9045 pH at 25 Degrees C 6.5 Std. Units 0.10 03/18/15 18:50 EPA 300.0 Sulfate 3.4 mg/L 2.3 03/20/15 00:56 SM 4500 -CI -E Chloride 16.0 mg/L 5.7 03/19/15 21:18 EPA 9060 Total Organic Carbon 12700 mg/kg 683 03/20/15 12:51 EPA 9060 Total Organic Carbon 13600 mg/kg 687 03/20/15 12:56 EPA 9060 Total Organic Carbon 13500 mg/kg 692 03/20/15 13:03 EPA 9060 Total Organic Carbon 14000 mg/kg 681 03/20/15 13:08 EPA 9060 Mean Total Organic Carbon 13500 mg/kg 686 03/20/15 12:51 EPA 9060 RSD% 4.0 % 03/20/15 12:51 92241060010 2015006957 SPLP EPA 6020A Aluminum 30300 ug/L 50.0 03/27/15 14:49 EPA 6020A Antimony 4.1 ug/L 0.50 03/27/15 14:40 EPA 6020A Arsenic 380 ug/L 0.50 03/27/15 14:40 EPA 6020A Barium 185 ug/L 0.30 03/27/15 14:40 EPA 6020A Beryllium 1.7 ug/L 0.20 03/27/15 14:40 EPA 6020A Boron 179 ug/L 5.0 03/27/15 14:40 EPA 6020A Cadmium 0.43 ug/L 0.080 03/27/15 14:40 EPA 6020A Calcium 11900 ug/L 40.0 03/27/15 14:40 EPA 6020A Chromium 20.3 ug/L 0.50 03/27/15 14:40 EPA 6020A Cobalt 6.8 ug/L 0.50 03/27/15 14:40 EPA 6020A Copper 10.3 ug/L 1.0 03/27/15 14:40 EPA 6020A Iron 20000 ug/L 50.0 03/27/15 14:40 EPA 6020A Lead 36.2 ug/L 0.10 03/27/15 14:40 EPA 6020A Magnesium 1570 ug/L 10.0 03/27/15 14:40 EPA 6020A Manganese 153 ug/L 0.50 03/27/15 14:40 EPA 6020A Molybdenum 470 ug/L 2.5 03/27/15 14:49 EPA 6020A Nickel 10.8 ug/L 0.50 03/27/15 14:40 EPA 6020A Potassium 5000 ug/L 50.0 03/27/15 14:40 EPA 6020A Selenium 5.0 ug/L 0.50 03/27/15 14:40 EPA 6020A Sodium 1050 ug/L 50.0 03/27/15 14:40 EPA 6020A Strontium 391 ug/L 0.50 03/27/15 14:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. D3 D3 D3 D3 D3 D3 Qualifiers Page 13 of 96 aceAnaiXical www.pacelabs.com Project: J15030308 Pace Project No.: 92241060 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. PAROzl IWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92241060010 2015006957 SPLP EPA 6020A Thallium 0.49 ug/L 0.10 03/27/15 14:40 EPA 6020A Vanadium 141 ug/L 1.0 03/27/15 14:40 EPA 6020A Zinc 24.4 ug/L 5.0 03/27/15 14:40 92241060011 2015006958 SPLP EPA 6020A Aluminum 940 ug/L 10.0 03/27/15 14:43 EPA 6020A Arsenic 5.0 ug/L 0.50 03/27/15 14:43 EPA 6020A Barium 13.1 ug/L 0.30 03/27/15 14:43 EPA 6020A Boron 32.8 ug/L 5.0 03/27/15 14:43 EPA 6020A Calcium 1700 ug/L 40.0 03/27/15 14:43 EPA 6020A Chromium 1.1 ug/L 0.50 03/27/15 14:43 EPA 6020A Cobalt 1.3 ug/L 0.50 03/27/15 14:43 EPA 6020A Iron 541 ug/L 50.0 03/27/15 14:43 EPA 6020A Lead 0.96 ug/L 0.10 03/27/15 14:43 EPA 6020A Magnesium 443 ug/L 10.0 03/27/15 14:43 EPA 6020A Manganese 192 ug/L 0.50 03/27/15 14:43 EPA 6020A Molybdenum 10.5 ug/L 0.50 03/27/15 14:43 EPA 6020A Nickel 0.89 ug/L 0.50 03/27/15 14:43 EPA 6020A Potassium 2460 ug/L 50.0 03/27/15 14:43 EPA 6020A Sodium 1250 ug/L 50.0 03/27/15 14:43 EPA 6020A Strontium 64.8 ug/L 0.50 03/27/15 14:43 92241060012 2015006961 SPLP EPA 6020A Aluminum 20900 ug/L 10.0 03/27/15 15:06 EPA 6020A Arsenic 13.4 ug/L 0.50 03/27/15 15:06 EPA 6020A Barium 161 ug/L 0.30 03/27/15 15:06 EPA 6020A Beryllium 2.0 ug/L 0.20 03/27/15 15:06 EPA 6020A Boron 53.5 ug/L 5.0 03/27/15 15:06 EPA 6020A Cadmium 0.13 ug/L 0.080 03/27/15 15:06 EPA 6020A Calcium 1300 ug/L 40.0 03/27/15 15:06 EPA 6020A Chromium 22.4 ug/L 0.50 03/27/15 15:06 EPA 6020A Cobalt 14.3 ug/L 0.50 03/27/15 15:06 EPA 6020A Copper 42.2 ug/L 1.0 03/27/15 15:06 EPA 6020A Iron 16800 ug/L 50.0 03/27/15 15:06 EPA 6020A Lead 34.7 ug/L 0.10 03/27/15 15:06 EPA 6020A Magnesium 1070 ug/L 10.0 03/27/15 15:06 EPA 6020A Manganese 38.4 ug/L 0.50 03/27/15 15:06 EPA 6020A Nickel 7.1 ug/L 0.50 03/27/15 15:06 EPA 6020A Potassium 2680 ug/L 50.0 03/27/15 15:06 EPA 6020A Selenium 0.92 ug/L 0.50 03/27/15 15:06 EPA 6020A Sodium 2920 ug/L 50.0 03/27/15 15:06 EPA 6020A Strontium 57.9 ug/L 0.50 03/27/15 15:06 EPA 6020A Thallium 0.35 ug/L 0.10 03/27/15 15:06 EPA 6020A Vanadium 63.8 ug/L 1.0 03/27/15 15:06 EPA 6020A Zinc 19.0 ug/L 5.0 03/27/15 15:06 92241060013 2015006962 SPLP EPA 6020A Aluminum 35800 ug/L 50.0 03/27/15 16:41 EPA 6020A Arsenic 13.8 ug/L 0.50 03/27/15 15:09 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 96 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Project: J15030308 Pace Project No.: 92241060 Lab Sample ID Client Sample ID 03/27/1515:09 Method Parameters Result 92241060013 2015006962 SPLP 03/27/1515:09 EPA 6020A Barium 204 EPA 6020A Beryllium 2.2 EPA 6020A Boron 128 EPA 6020A Cadmium 0.16 EPA 6020A Calcium 2040 EPA 6020A Chromium 31.5 EPA 6020A Cobalt 17.7 EPA 6020A Copper 46.7 EPA 6020A Iron 25400 EPA 6020A Lead 61.5 EPA 6020A Magnesium 1420 EPA 6020A Manganese 136 EPA 6020A Molybdenum 0.84 EPA 6020A Nickel 12.0 EPA 6020A Potassium 3480 EPA 6020A Selenium 1.3 EPA 6020A Sodium 7770 EPA 6020A Strontium 47.1 EPA 6020A Thallium 0.28 EPA 6020A Vanadium 80.4 EPA 6020A Zinc 40.7 Pace Analytical Services, Inc. PW1*r6fy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Units Report Limit Analyzed Qualifiers ug/L 0.30 03/27/1515:09 ug/L 0.20 03/27/1515:09 ug/L 5.0 03/27/1515:09 ug/L 0.080 03/27/1515:09 ug/L 40.0 03/27/1515:09 ug/L 0.50 03/27/1515:09 ug/L 0.50 03/27/1515:09 ug/L 1.0 03/27/1515:09 ug/L 250 03/27/1516:41 ug/L 0.10 03/27/1515:09 ug/L 10.0 03/27/1515:09 ug/L 0.50 03/27/1515:09 ug/L 0.50 03/27/1515:09 ug/L 0.50 03/27/1515:09 ug/L 50.0 03/27/1515:09 ug/L 0.50 03/27/1515:09 ug/L 50.0 03/27/1515:09 ug/L 0.50 03/27/1515:09 ug/L 0.10 03/27/1515:09 ug/L 1.0 03/27/1515:09 ug/L 5.0 03/27/1515:09 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARGArWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 31, 2015 General Information: 8 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23172 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92240782001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1161438) • Aluminum • Barium • Beryllium • Chromium • Copper • Iron • Magnesium • Manganese • Molybdenum • Nickel • Potassium • MSD (Lab ID: 1161439) • Aluminum • Barium • Beryllium • Chromium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARGArWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 31, 2015 QC Batch: MPRP/23172 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92240782001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Copper • Iron • Magnesium • Manganese • Molybdenum • Nickel • Potassium R1: RPD value was outside control limits. • MSD (Lab ID: 1161439) • Manganese • Molybdenum QC Batch: MPRP/23184 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241060003 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1162081) • Aluminum • Barium • Chromium • Iron • Manganese • Molybdenum • Potassium • Strontium • MSD (Lab ID: 1162082) • Aluminum • Barium • Chromium • Copper • Iron • Manganese • Molybdenum • Nickel • Potassium • Strontium QC Batch: MPRP/23201 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241387002 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1162649) • Aluminum • Barium • Calcium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PWIbrwy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 31, 2015 QC Batch: MPRP/23201 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241387002 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Iron • Potassium • Strontium • MSD (Lab ID: 1162650) • Aluminum • Barium • Boron • Calcium • Iron • Potassium • Strontium Additional Comments: Analyte Comments: QC Batch: MPRP/23172 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006961 (Lab ID: 92241060008) • Boron • Beryllium • Chromium • Copper • Iron • Manganese •2015006962 (Lab ID: 92241060009) • Boron • Beryllium • Chromium • Copper • Manganese • MS (Lab ID: 1161438) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 96 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 31, 2015 Analyte Comments: QC Batch: MPRP/23172 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • MS (Lab ID: 1161438) • Molybdenum • Sodium • Nickel • Strontium • Zinc • MSD (Lab ID: 1161439) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc Pace Analytical Services, Inc. P36gmirpYN.. Suite 100 y Huntersville, NC 28078 (704)875-9092 D4: Sample was diluted due to the presence of high levels of target analytes. •2015006959 (Lab ID: 92241060004) • Manganese P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1161436) • Aluminum • Manganese QC Batch: MPRP/23184 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006956 (Lab ID: 92241060003) • Aluminum • Barium • Chromium • Copper • Iron • Magnesium • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PW1*r6fy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 31, 2015 Analyte Comments: QC Batch: MPRP/23184 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006956 (Lab ID: 92241060003) • Nickel • Strontium • Zinc QC Batch: MPRP/23201 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006955 (Lab ID: 92241060002) • Boron • Chromium • Copper • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36911rWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 31, 2015 General Information: 8 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23173 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92240782002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1161442) • Antimony • Arsenic • Cobalt • Lead • Selenium • Vanadium • MSD (Lab ID: 1161443) • Antimony • Arsenic • Cobalt • Lead • Selenium • Vanadium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PAROAirWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 31, 2015 QC Batch: MPRP/23173 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92240782002 R1: RPD value was outside control limits. • MSD (Lab ID: 1161443) • Cobalt QC Batch: MPRP/23185 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241060003 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1162088) • Antimony • Arsenic • Thallium • MSD (Lab ID: 1162089) • Antimony • Arsenic • Cobalt • Lead • Thallium • Vanadium QC Batch: MPRP/23202 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241387002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1162653) • Antimony • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Selenium • Thallium • Vanadium • MSD (Lab ID: 1162654) • Antimony • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Selenium • Thallium • Vanadium R1: RPD value was outside control limits. • MSD (Lab ID: 1162654) REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARIArWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 31, 2015 QC Batch: MPRP/23202 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241387002 R1: RPD value was outside control limits. • Antimony • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Selenium • Thallium • Vanadium Additional Comments: Analyte Comments: QC Batch: MPRP/23173 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006957 (Lab ID: 92241060006) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015006958 (Lab ID:92241060007) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015006959 (Lab ID:92241060004) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARGArWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 31, 2015 Analyte Comments: QC Batch: MPRP/23173 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006960 (Lab ID: 92241060005) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015006961 (Lab ID:92241060008) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015006962 (Lab ID:92241060009) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • MS (Lab ID: 1161442) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • MSD (Lab ID: 1161443) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. POQ WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 31, 2015 Analyte Comments: QC Batch: MPRP/23173 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • MSD (Lab ID: 1161443) • Thallium • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •2015006957 (Lab ID:92241060006) • Antimony •2015006958 (Lab ID:92241060007) • Antimony •2015006959 (Lab ID:92241060004) • Antimony •2015006960 (Lab ID:92241060005) • Antimony •2015006961 (Lab ID:92241060008) • Antimony •2015006962 (Lab ID:92241060009) • Antimony • BLANK (Lab ID: 1161440) • Antimony • LCS (Lab ID: 1161441) • Antimony • MS (Lab ID: 1161442) • Antimony • MSD (Lab ID: 1161443) • Antimony QC Batch: MPRP/23185 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006956 (Lab ID: 92241060003) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •2015006956 (Lab ID: 92241060003) • Antimony • BLANK (Lab ID: 1162086) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARGArWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 31, 2015 Analyte Comments: QC Batch: MPRP/23185 N2: The lab does not hold TNI accreditation for this parameter. • LCS (Lab ID: 1162087) • Antimony • MS (Lab ID: 1162088) • Antimony • MSD (Lab ID: 1162089) • Antimony QC Batch: MPRP/23202 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006955 (Lab ID:92241060002) • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium D4: Sample was diluted due to the presence of high levels of target analytes. •2015006955 (Lab ID: 92241060002) • Arsenic • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •2015006955 (Lab ID: 92241060002) • Antimony • BLANK (Lab ID: 1162651) • Antimony • LCS (Lab ID: 1162652) • Antimony • MS (Lab ID: 1162653) • Antimony • MSD (Lab ID: 1162654) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARIArWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: March 31, 2015 General Information: 5 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/52981 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241061001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1918972) • Aluminum • MSD (Lab ID: 1918973) • Aluminum QC Batch: MPRP/53205 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242374012 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1926431) • Aluminum • MSD (Lab ID: 1926432) • Aluminum • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P369041bir6fY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: March 31, 2015 QC Batch: MPRP/53205 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242374012 R1: RPD value was outside control limits. • MSD (Lab ID: 1926432) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904fflirWYN" Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: March 31, 2015 General Information: 5 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/13071 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242374012 R1: RPD value was outside control limits. • MSD (Lab ID: 1926033) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904K W%e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: March 31, 2015 General Information: 8 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5493 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35179481001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1161942) • Mercury • MSD (Lab ID: 1161943) • Mercury QC Batch: MERP/5502 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35179122001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1164139) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904K WeY(%e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: March 31, 2015 General Information: 8 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-16: Analysis initiated outside of the 15 minute EPA recommended holding time. •2015006955 (Lab ID: 92241060002) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/36284 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1413496) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P369041�ir6fY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: March 31, 2015 General Information: 4 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P3690AW%e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: March 31, 2015 General Information: 4 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015006957 (Lab ID: 92241060006) •2015006958 (Lab ID: 92241060007) •2015006961 (Lab ID: 92241060008) •2015006962 (Lab ID: 92241060009) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22256 B: Analyte was detected in the associated method blank. • BLANK for HBN 256042 [WETA/222 (Lab ID: 1413768) • Nitrogen, Nitrate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 33 of 96 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: SM 4500 -CI -E Description: 4500 Chloride, SPLP Client: Duke Energy Date: March 31, 2015 Pace Analytical Services, Inc. P369041 WeY(%e. Suite 100 y Huntersville, NC 28078 (704)875-9092 General Information: 4 samples were analyzed for SM 4500 -CI -E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 34 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904f WeYNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: March 31, 2015 General Information: 8 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015006956 (Lab ID: 92241060003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44604 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006956 (Lab ID:92241060003) • Chloride • Sulfate •2015006957 (Lab ID:92241060006) • Chloride • Sulfate •2015006958 (Lab ID:92241060007) • Chloride • Sulfate •2015006959 (Lab ID:92241060004) • Chloride • Sulfate •2015006960 (Lab ID:92241060005) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 35 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904 W%e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: March 31, 2015 Analyte Comments: QC Batch: WETA/44604 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006961 (Lab ID: 92241060008) • Chloride • Sulfate •2015006962 (Lab ID: 92241060009) • Chloride • Sulfate QC Batch: WETA/44698 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006955 (Lab ID: 92241060002) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 36 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904f WeY(%e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: March 31, 2015 General Information: 8 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015006955 (Lab ID:92241060002) •2015006956 (Lab ID:92241060003) •2015006957 (Lab ID:92241060006) •2015006958 (Lab ID:92241060007) •2015006959 (Lab ID:92241060004) •2015006960 (Lab ID:92241060005) •2015006961 (Lab ID:92241060008) •2015006962 (Lab ID:92241060009) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44700 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006955 (Lab ID: 92241060002) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 37 of 96 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PO05k WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030308 Pace Project No.: 92241060 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: March 31, 2015 General Information: 8 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 38 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. PggcO )irpyN.. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 Sample: 2015006954 Lab ID: 92241060001 Collected: 03/10/15 09:55 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020A MET ICPMS Analytical Method: EPA 6020A Preparation Method: EPA 3020 Aluminum 326 ug/L 10.0 1.2 1 03/16/1514:45 03/18/1511:44 7429-90-5 Antimony ND ug/L 0.50 0.25 1 03/16/1514:45 03/18/1511:44 7440-36-0 Arsenic ND ug/L 0.50 0.25 1 03/16/1514:45 03/18/1511:44 7440-38-2 Barium 2.6 ug/L 0.30 0.14 1 03/16/1514:45 03/18/1511:44 7440-39-3 Beryllium ND ug/L 0.20 0.066 1 03/16/1514:45 03/18/1511:44 7440-41-7 Boron ND ug/L 5.0 1.0 1 03/16/1514:45 03/18/1511:44 7440-42-8 Cadmium ND ug/L 0.080 0.033 1 03/16/1514:45 03/18/1511:44 7440-43-9 Calcium 71.4 ug/L 40.0 8.4 1 03/16/1514:45 03/18/1511:44 7440-70-2 Chromium 0.61 ug/L 0.50 0.22 1 03/16/1514:45 03/18/1511:44 7440-47-3 Cobalt 1.2 ug/L 0.50 0.25 1 03/16/1514:45 03/18/1511:44 7440-48-4 Copper ND ug/L 1.0 0.22 1 03/16/1514:45 03/18/1511:44 7440-50-8 Iron 361 ug/L 50.0 8.0 1 03/16/1514:45 03/18/1511:44 7439-89-6 Lead 0.34 ug/L 0.10 0.046 1 03/16/1514:45 03/18/1511:44 7439-92-1 Magnesium 76.9 ug/L 10.0 2.8 1 03/16/1514:45 03/18/1511:44 7439-95-4 Manganese 9.2 ug/L 0.50 0.14 1 03/16/1514:45 03/18/1511:44 7439-96-5 Molybdenum ND ug/L 0.50 0.24 1 03/16/1514:45 03/18/1511:44 7439-98-7 Nickel ND ug/L 0.50 0.23 1 03/16/1514:45 03/18/1511:44 7440-02-0 Potassium 67.2 ug/L 50.0 8.3 1 03/16/1514:45 03/18/1511:44 7440-09-7 Selenium ND ug/L 0.50 0.25 1 03/16/1514:45 03/18/1511:44 7782-49-2 Sodium ND ug/L 50.0 18.2 1 03/16/1514:45 03/18/1511:44 7440-23-5 Strontium ND ug/L 0.50 0.057 1 03/16/1514:45 03/18/1511:44 7440-24-6 Thallium ND ug/L 0.10 0.025 1 03/16/1514:45 03/18/1511:44 7440-28-0 Vanadium ND ug/L 1.0 0.21 1 03/16/1514:45 03/18/1511:44 7440-62-2 Zinc ND ug/L 5.0 2.5 1 03/16/1514:45 03/18/1511:44 7440-66-6 7470 Mercury Analytical Method: EPA 7470 Preparation Method: EPA 7470 Mercury ND ug/L 0.20 0.026 1 03/18/1513:00 03/19/1511:39 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 39 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030308 Pace Project No.: 92241060 Pace Analytical Services, Inc. PO05kf WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015006955 Lab ID: 92241060002 Collected: 03/10/15 10:00 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 13900 mg/kg 6.8 3.4 1 03/21/1518:50 03/24/1512:47 7429-90-5 Barium 274 mg/kg 0.68 0.34 1 03/21/1518:50 03/24/1512:47 7440-39-3 Boron 28.9 mg/kg 16.9 8.5 5 03/21/1518:50 03/24/1515:53 7440-42-8 Calcium 1700 mg/kg 33.8 16.9 1 03/21/1518:50 03/24/1512:47 7440-70-2 Chromium 36.6 mg/kg 1.7 0.85 5 03/21/1518:50 03/24/1515:53 7440-47-3 Copper 47.4 mg/kg 1.7 0.85 5 03/21/1518:50 03/24/1515:53 7440-50-8 Iron 6070 mg/kg 2.7 1.4 1 03/21/1518:50 03/24/1512:47 7439-89-6 Magnesium 987 mg/kg 33.8 16.9 1 03/21/1518:50 03/24/1512:47 7439-95-4 Manganese 61.0 mg/kg 1.7 0.85 5 03/21/1518:50 03/24/1515:53 7439-96-5 Molybdenum 1.4 mg/kg 0.68 0.34 1 03/21/1518:50 03/24/1512:47 7439-98-7 Nickel 18.2 mg/kg 0.34 0.17 1 03/21/1518:50 03/24/1512:47 7440-02-0 Potassium 2680 mg/kg 67.7 33.8 1 03/21/1518:50 03/24/1512:47 7440-09-7 Sodium 270 mg/kg 67.7 33.8 1 03/21/1518:50 03/24/1512:47 7440-23-5 Strontium 158 mg/kg 0.68 0.34 1 03/21/1518:50 03/24/1512:47 7440-24-6 Zinc 39.4 mg/kg 1.4 0.68 1 03/21/1518:50 03/24/1512:47 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.4 1.7 50 03/21/1518:50 03/24/1510:09 7440-36-0 Arsenic 233 mg/kg 3.4 1.7 50 03/21/1518:50 03/24/1510:09 7440-38-2 Beryllium 3.4 mg/kg 0.41 0.20 50 03/21/1518:50 03/24/1510:09 7440-41-7 Cadmium 0.38J mg/kg 0.41 0.20 50 03/21/1518:50 03/24/1510:09 7440-43-9 Cobalt 13.5 mg/kg 3.4 1.7 50 03/21/1518:50 03/24/1510:09 7440-48-4 Lead 25.9 mg/kg 3.4 1.7 50 03/21/1518:50 03/24/1510:09 7439-92-1 Selenium 16.6 mg/kg 3.4 1.7 50 03/21/1518:50 03/24/1510:09 7782-49-2 Thallium ND mg/kg 3.4 1.7 50 03/21/1518:50 03/24/1510:09 7440-28-0 Vanadium 63.8 mg/kg 3.4 1.7 50 03/21/1518:50 03/24/1510:09 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.26 mg/kg 0.010 0.0052 1 03/24/1513:02 03/24/1517:59 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 23.8 % 0.10 0.10 1 03/24/15 14:03 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 8.8 Std. Units 0.10 0.10 1 pH at 25 Degrees C 7.1 Std. Units 0.10 0.10 1 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 326 163 5 Sulfate ND mg/kg 326 163 5 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 32.6 16.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. 03/17/15 15:25 03/23/15 13:27 D3 D3 D3 D3 D3,N2 D4 D3 D3 D3 D3 D3 D3 D4 H6 03/20/15 06:32 16887-00-6 D3 03/20/15 06:32 14808-79-8 D3 03/20/15 06:32 14797-55-8 D3,H3 Page 40 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030308 Pace Project No.: 92241060 Pace Analytical Services, Inc. P�S�05kf WYNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015006955 Lab ID: 92241060002 Collected: 03/10/15 10:00 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 28800 mg/kg 6080 3040 1 03/20/15 08:37 7440-44-0 Total Organic Carbon 20000 mg/kg 6120 3060 1 03/20/15 08:42 7440-44-0 Total Organic Carbon 23600 mg/kg 6370 3180 1 03/20/15 08:48 7440-44-0 Total Organic Carbon 38800 mg/kg 6210 3100 1 03/20/15 08:53 7440-44-0 Mean Total Organic Carbon 27800 mg/kg 6190 3100 1 03/20/15 08:37 7440-44-0 Surrogates RSD% 29.5 % 1 03/20/15 08:37 Date: 03/31/2015 05:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 41 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030308 Pace Project No.: 92241060 Pace Analytical Services, Inc. PAMIirWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015006956 Lab ID: 92241060003 Collected: 03/10/15 11:45 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 03/31/2015 05:20 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 10800 mg/kg 35.6 17.8 5 03/20/15 12:45 03/24/15 09:55 7429-90-5 281 mg/kg 3.6 1.8 5 03/20/15 12:45 03/24/15 09:55 7440-39-3 1.8 mg/kg 0.071 0.036 1 03/20/15 12:45 03/24/15 09:50 7440-41-7 26.9 mg/kg 3.6 1.8 1 03/20/15 12:45 03/24/15 09:50 7440-42-8 2840 mg/kg 35.6 17.8 1 03/20/15 12:45 03/24/15 09:50 7440-70-2 15.3 mg/kg 1.8 0.89 5 03/20/15 12:45 03/24/15 09:55 7440-47-3 30.5 mg/kg 1.8 0.89 5 03/20/15 12:45 03/24/15 09:55 7440-50-8 6090 mg/kg 14.2 7.1 5 03/20/15 12:45 03/24/15 09:55 7439-89-6 919 mg/kg 178 89.0 5 03/20/15 12:45 03/24/15 09:55 7439-95-4 38.7 mg/kg 1.8 0.89 5 03/20/15 12:45 03/24/15 09:55 7439-96-5 1.1 mg/kg 0.71 0.36 1 03/20/15 12:45 03/24/15 09:50 7439-98-7 17.0 mg/kg 1.8 0.89 5 03/20/15 12:45 03/24/15 09:55 7440-02-0 1480 mg/kg 71.2 35.6 1 03/20/15 12:45 03/24/15 09:50 7440-09-7 186 mg/kg 71.2 35.6 1 03/20/15 12:45 03/24/15 09:50 7440-23-5 232 mg/kg 3.6 1.8 5 03/20/15 12:45 03/24/15 09:55 7440-24-6 26.0 mg/kg 7.1 3.6 5 03/20/15 12:45 03/24/15 09:55 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.6 1.8 50 03/20/1512:45 03/23/1513:34 7440-36-0 64.2 mg/kg 3.6 1.8 50 03/20/1512:45 03/23/1513:34 7440-38-2 0.44 mg/kg 0.43 0.21 50 03/20/1512:45 03/23/1513:34 7440-43-9 7.2 mg/kg 3.6 1.8 50 03/20/1512:45 03/23/1513:34 7440-48-4 11.7 mg/kg 3.6 1.8 50 03/20/1512:45 03/23/1513:34 7439-92-1 8.4 mg/kg 3.6 1.8 50 03/20/1512:45 03/23/1513:34 7782-49-2 ND mg/kg 3.6 1.8 50 03/20/1512:45 03/23/1513:34 7440-28-0 44.9 mg/kg 3.6 1.8 50 03/20/1512:45 03/23/1513:34 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.29 mg/kg 0.011 0.0057 1 03/20/1513:25 03/23/1513:28 7439-97-6 Analytical Method: ASTM D2974-87 28.2 % 0.10 0.10 1 03/23/1515:58 Analytical Method: EPA 9045 8.4 Std. Units 0.10 0.10 1 03/17/15 15:25 Analytical Method: EPA 9056 D3,M1 D3,M1 D3,M1 D3,M1 D3,M1 D3 D3,M1 M1 D3,M1 M1 D3,M1 D3 D3,M6, N2 D3,M6 D3 D3,M6 D3,M6 D3 D3,M6 D3,M6 ND mg/kg 345 173 5 03/17/15 20:33 16887-00-6 D3,H3 ND mg/kg 345 173 5 03/17/15 20:33 14808-79-8 D3,H3 Analytical Method: EPA 9056 ND mg/kg 34.5 17.3 5 03/17/15 20:33 14797-55-8 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 42 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030308 Pace Project No.: 92241060 Pace Analytical Services, Inc. PAROAirWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015006956 Lab ID: 92241060003 Collected: 03/10/15 11:45 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 74700 mg/kg 4510 2250 1 03/20/15 09:45 7440-44-0 Total Organic Carbon 94200 mg/kg 4530 2270 1 03/20/15 09:51 7440-44-0 Total Organic Carbon 78600 mg/kg 4440 2220 1 03/20/15 09:58 7440-44-0 Total Organic Carbon 88500 mg/kg 4560 2280 1 03/20/15 10:05 7440-44-0 Mean Total Organic Carbon 84000 mg/kg 4510 2250 1 03/20/15 09:45 7440-44-0 Surrogates RSD% 10.6 % 1 03/20/15 09:45 Date: 03/31/2015 05:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 43 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. POO WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 Sample: 2015006959 Lab ID: 92241060004 Collected: 03/10/15 11:50 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 15500 mg/kg 6.5 3.3 1 03/20/15 06:37 03/20/15 13:45 7429-90-5 Barium 140 mg/kg 0.65 0.33 1 03/20/15 06:37 03/20/15 13:45 7440-39-3 Beryllium 0.70 mg/kg 0.065 0.033 1 03/20/15 06:37 03/20/15 13:45 7440-41-7 Boron 13.3 mg/kg 3.3 1.6 1 03/20/15 06:37 03/20/15 13:45 7440-42-8 Calcium 61.4 mg/kg 32.7 16.3 1 03/20/15 06:37 03/20/15 13:45 7440-70-2 Chromium 10.7 mg/kg 0.33 0.16 1 03/20/15 06:37 03/20/15 13:45 7440-47-3 Copper 9.4 mg/kg 0.33 0.16 1 03/20/15 06:37 03/20/15 13:45 7440-50-8 Iron 17000 mg/kg 2.6 1.3 1 03/20/15 06:37 03/20/15 13:45 7439-89-6 Magnesium 3580 mg/kg 32.7 16.3 1 03/20/15 06:37 03/20/15 13:45 7439-95-4 Manganese 1140 mg/kg 1.6 0.82 5 03/20/15 06:37 03/20/15 19:46 7439-96-5 D4 Molybdenum ND mg/kg 0.65 0.33 1 03/20/15 06:37 03/20/15 13:45 7439-98-7 Nickel 6.9 mg/kg 0.33 0.16 1 03/20/15 06:37 03/20/15 13:45 7440-02-0 Potassium 5150 mg/kg 65.4 32.7 1 03/20/15 06:37 03/20/15 13:45 7440-09-7 Sodium ND mg/kg 65.4 32.7 1 03/20/15 06:37 03/20/15 13:45 7440-23-5 Strontium 4.8 mg/kg 0.65 0.33 1 03/20/15 06:37 03/20/15 13:45 7440-24-6 Zinc 60.4 mg/kg 1.3 0.65 1 03/20/15 06:37 03/20/15 13:45 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.3 1.6 50 03/20/15 06:37 03/20/15 17:47 7440-36-0 D3,N2 Arsenic 2.9J mg/kg 3.3 1.6 50 03/20/15 06:37 03/20/15 17:47 7440-38-2 D3 Cadmium ND mg/kg 0.39 0.20 50 03/20/15 06:37 03/20/15 17:47 7440-43-9 D3 Cobalt 59.2 mg/kg 3.3 1.6 50 03/20/15 06:37 03/20/15 17:47 7440-48-4 D3 Lead 3.6 mg/kg 3.3 1.6 50 03/20/15 06:37 03/20/15 17:47 7439-92-1 D3 Selenium 4.4 mg/kg 3.3 1.6 50 03/20/15 06:37 03/20/15 17:47 7782-49-2 D3 Thallium ND mg/kg 3.3 1.6 50 03/20/15 06:37 03/20/15 17:47 7440-28-0 D3 Vanadium 36.9 mg/kg 3.3 1.6 50 03/20/15 06:37 03/20/15 17:47 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.010 0.0052 1 03/20/1513:25 03/20/1517:43 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 20.2 % 0.10 0.10 1 03/23/15 15:59 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.4 Std. Units 0.10 0.10 1 03/17/15 15:25 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 310 155 5 03/17/15 21:37 16887-00-6 D3 Sulfate 246J mg/kg 310 155 5 03/17/15 21:37 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.0 15.5 5 03/17/15 21:37 14797-55-8 H3 Date: 03/31/2015 05:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 44 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030308 Pace Project No.: 92241060 Pace Analytical Services, Inc. P3690*rWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015006959 Lab ID: 92241060004 Collected: 03/10/15 11:50 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 756 378 1 03/20/15 10:11 7440-44-0 Total Organic Carbon ND mg/kg 754 377 1 03/20/15 10:18 7440-44-0 Total Organic Carbon ND mg/kg 754 377 1 03/20/15 10:23 7440-44-0 Total Organic Carbon ND mg/kg 757 379 1 03/20/15 10:28 7440-44-0 Mean Total Organic Carbon ND mg/kg 755 378 1 03/20/15 10:11 7440-44-0 Surrogates RSD% 1.0 % 1 03/20/1510:11 Date: 03/31/2015 05:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 45 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. PAROAirWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 Sample: 2015006960 Lab ID: 92241060005 Collected: 03/10/15 16:45 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 10100 mg/kg 6.9 3.5 1 03/20/15 06:37 03/20/15 13:49 7429-90-5 Barium 272 mg/kg 0.69 0.35 1 03/20/15 06:37 03/20/15 13:49 7440-39-3 Beryllium 1.4 mg/kg 0.069 0.035 1 03/20/15 06:37 03/20/15 13:49 7440-41-7 Boron 18.0 mg/kg 3.5 1.7 1 03/20/15 06:37 03/20/15 13:49 7440-42-8 Calcium 1520 mg/kg 34.7 17.3 1 03/20/15 06:37 03/20/15 13:49 7440-70-2 Chromium 13.7 mg/kg 0.35 0.17 1 03/20/15 06:37 03/20/15 13:49 7440-47-3 Copper 23.5 mg/kg 0.35 0.17 1 03/20/15 06:37 03/20/15 13:49 7440-50-8 Iron 11800 mg/kg 2.8 1.4 1 03/20/15 06:37 03/20/15 13:49 7439-89-6 Magnesium 1090 mg/kg 34.7 17.3 1 03/20/15 06:37 03/20/15 13:49 7439-95-4 Manganese 103 mg/kg 0.35 0.17 1 03/20/15 06:37 03/20/15 13:49 7439-96-5 Molybdenum 0.98 mg/kg 0.69 0.35 1 03/20/15 06:37 03/20/15 13:49 7439-98-7 Nickel 12.3 mg/kg 0.35 0.17 1 03/20/15 06:37 03/20/15 13:49 7440-02-0 Potassium 1780 mg/kg 69.4 34.7 1 03/20/15 06:37 03/20/15 13:49 7440-09-7 Sodium 145 mg/kg 69.4 34.7 1 03/20/15 06:37 03/20/15 13:49 7440-23-5 Strontium 119 mg/kg 0.69 0.35 1 03/20/15 06:37 03/20/15 13:49 7440-24-6 Zinc 27.7 mg/kg 1.4 0.69 1 03/20/15 06:37 03/20/15 13:49 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.5 1.7 50 03/20/15 06:37 03/20/15 17:49 7440-36-0 D3,N2 Arsenic 55.1 mg/kg 3.5 1.7 50 03/20/15 06:37 03/20/15 17:49 7440-38-2 D3 Cadmium ND mg/kg 0.42 0.21 50 03/20/15 06:37 03/20/15 17:49 7440-43-9 D3 Cobalt 9.5 mg/kg 3.5 1.7 50 03/20/15 06:37 03/20/15 17:49 7440-48-4 D3 Lead 12.0 mg/kg 3.5 1.7 50 03/20/15 06:37 03/20/15 17:49 7439-92-1 D3 Selenium 7.8 mg/kg 3.5 1.7 50 03/20/15 06:37 03/20/15 17:49 7782-49-2 D3 Thallium ND mg/kg 3.5 1.7 50 03/20/15 06:37 03/20/15 17:49 7440-28-0 D3 Vanadium 41.5 mg/kg 3.5 1.7 50 03/20/15 06:37 03/20/15 17:49 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.18 mg/kg 0.011 0.0054 1 03/20/1513:25 03/20/1517:45 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 24.4 % 0.10 0.10 1 03/23/15 15:59 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 7.3 Std. Units 0.10 0.10 1 03/17/15 15:25 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 330 165 5 03/17/15 21:58 16887-00-6 D3 Sulfate ND mg/kg 330 165 5 03/17/15 21:58 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 33.0 16.5 5 03/17/15 21:58 14797-55-8 H3 Date: 03/31/2015 05:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 46 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030308 Pace Project No.: 92241060 Pace Analytical Services, Inc. POO WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015006960 Lab ID: 92241060005 Collected: 03/10/15 16:45 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 51000 mg/kg 4870 2440 1 03/20/15 10:34 7440-44-0 Total Organic Carbon 53400 mg/kg 4730 2370 1 03/20/15 10:39 7440-44-0 Total Organic Carbon 48600 mg/kg 4830 2410 1 03/20/15 10:45 7440-44-0 Total Organic Carbon 47200 mg/kg 4870 2430 1 03/20/15 10:51 7440-44-0 Mean Total Organic Carbon 50000 mg/kg 4820 2410 1 03/20/15 10:34 7440-44-0 Surrogates RSD% 5.5 % 1 03/20/1510:34 Date: 03/31/2015 05:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 47 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. P369%1bir6fy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 Sample: 2015006957 Lab ID: 92241060006 Collected: 03/10/15 10:50 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 14400 mg/kg 6.5 3.3 1 03/20/15 06:37 03/20/15 13:54 7429-90-5 Barium 158 mg/kg 0.65 0.33 1 03/20/15 06:37 03/20/15 13:54 7440-39-3 Beryllium 0.68 mg/kg 0.065 0.033 1 03/20/15 06:37 03/20/15 13:54 7440-41-7 Boron 20.2 mg/kg 3.3 1.6 1 03/20/15 06:37 03/20/15 13:54 7440-42-8 Calcium 2020 mg/kg 32.6 16.3 1 03/20/15 06:37 03/20/15 13:54 7440-70-2 Chromium 11.3 mg/kg 0.33 0.16 1 03/20/15 06:37 03/20/15 13:54 7440-47-3 Copper 11.8 mg/kg 0.33 0.16 1 03/20/15 06:37 03/20/15 13:54 7440-50-8 Iron 12000 mg/kg 2.6 1.3 1 03/20/15 06:37 03/20/15 13:54 7439-89-6 Magnesium 919 mg/kg 32.6 16.3 1 03/20/15 06:37 03/20/15 13:54 7439-95-4 Manganese 70.0 mg/kg 0.33 0.16 1 03/20/15 06:37 03/20/15 13:54 7439-96-5 Molybdenum 113 mg/kg 0.65 0.33 1 03/20/15 06:37 03/20/15 13:54 7439-98-7 Nickel 12.7 mg/kg 0.33 0.16 1 03/20/15 06:37 03/20/15 13:54 7440-02-0 Potassium 1140 mg/kg 65.1 32.6 1 03/20/15 06:37 03/20/15 13:54 7440-09-7 Sodium 54.OJ mg/kg 65.1 32.6 1 03/20/15 06:37 03/20/15 13:54 7440-23-5 Strontium 93.8 mg/kg 0.65 0.33 1 03/20/15 06:37 03/20/15 13:54 7440-24-6 Zinc 33.0 mg/kg 1.3 0.65 1 03/20/15 06:37 03/20/15 13:54 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony 1.81 mg/kg 3.3 1.6 50 03/20/15 06:37 03/20/15 17:52 7440-36-0 D3,N2 Arsenic 247 mg/kg 3.3 1.6 50 03/20/15 06:37 03/20/15 17:52 7440-38-2 D3 Cadmium 0.68 mg/kg 0.39 0.20 50 03/20/15 06:37 03/20/15 17:52 7440-43-9 D3 Cobalt 9.7 mg/kg 3.3 1.6 50 03/20/15 06:37 03/20/15 17:52 7440-48-4 D3 Lead 16.4 mg/kg 3.3 1.6 50 03/20/15 06:37 03/20/15 17:52 7439-92-1 D3 Selenium 39.9 mg/kg 3.3 1.6 50 03/20/15 06:37 03/20/15 17:52 7782-49-2 D3 Thallium ND mg/kg 3.3 1.6 50 03/20/15 06:37 03/20/15 17:52 7440-28-0 D3 Vanadium 56.6 mg/kg 3.3 1.6 50 03/20/15 06:37 03/20/15 17:52 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.040 mg/kg 0.0096 0.0048 1 03/20/1513:25 03/20/1517:47 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 20.6 % 0.10 0.10 1 03/23/15 16:00 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 7.4 Std. Units 0.10 0.10 1 03/17/15 15:25 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Sulfate 7.0 mg/L 2.5 1.3 1 03/20/15 00:15 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Nitrogen, Nitrate ND mg/L 0.25 0.25 1 03/18/15 16:56 H1 4500 Chloride, SPLP Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 03/16/15 14:15 Chloride 21.5 mg/L 6.3 3.2 1 03/19/15 21:16 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 48 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. PggmirpYN.. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 Sample: 2015006957 Lab ID: 92241060006 Collected: 03/10/15 10:50 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 312 156 5 03/17/15 22:20 16887-00-6 D3 Sulfate ND mg/kg 312 156 5 03/17/15 22:20 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.2 15.6 5 03/17/15 22:20 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 13600 mg/kg 981 491 1 03/20/15 10:57 7440-44-0 Total Organic Carbon 13000 mg/kg 983 492 1 03/20/15 11:03 7440-44-0 Total Organic Carbon 9370 mg/kg 986 493 1 03/20/15 11:09 7440-44-0 Total Organic Carbon 10100 mg/kg 984 492 1 03/20/15 11:15 7440-44-0 Mean Total Organic Carbon 11500 mg/kg 984 492 1 03/20/15 10:57 7440-44-0 Surrogates RSD% 18.1 % 1 03/20/1510:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 49 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. P�S�06Jf WyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 Sample: 2015006958 Lab ID: 92241060007 Collected: 03/10/15 12:00 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 6880 mg/kg 5.8 2.9 1 03/20/15 06:37 03/20/15 13:58 7429-90-5 Barium 47.7 mg/kg 0.58 0.29 1 03/20/15 06:37 03/20/15 13:58 7440-39-3 Beryllium 0.31 mg/kg 0.058 0.029 1 03/20/15 06:37 03/20/15 13:58 7440-41-7 Boron 8.6 mg/kg 2.9 1.5 1 03/20/15 06:37 03/20/15 13:58 7440-42-8 Calcium 192 mg/kg 29.1 14.6 1 03/20/15 06:37 03/20/15 13:58 7440-70-2 Chromium 5.1 mg/kg 0.29 0.15 1 03/20/15 06:37 03/20/15 13:58 7440-47-3 Copper 2.6 mg/kg 0.29 0.15 1 03/20/15 06:37 03/20/15 13:58 7440-50-8 Iron 9480 mg/kg 2.3 1.2 1 03/20/15 06:37 03/20/15 13:58 7439-89-6 Magnesium 1060 mg/kg 29.1 14.6 1 03/20/15 06:37 03/20/15 13:58 7439-95-4 Manganese 93.2 mg/kg 0.29 0.15 1 03/20/15 06:37 03/20/15 13:58 7439-96-5 Molybdenum 1.1 mg/kg 0.58 0.29 1 03/20/15 06:37 03/20/15 13:58 7439-98-7 Nickel 3.0 mg/kg 0.29 0.15 1 03/20/15 06:37 03/20/15 13:58 7440-02-0 Potassium 1590 mg/kg 58.2 29.1 1 03/20/15 06:37 03/20/15 13:58 7440-09-7 Sodium ND mg/kg 58.2 29.1 1 03/20/15 06:37 03/20/15 13:58 7440-23-5 Strontium 10.4 mg/kg 0.58 0.29 1 03/20/15 06:37 03/20/15 13:58 7440-24-6 Zinc 32.3 mg/kg 1.2 0.58 1 03/20/15 06:37 03/20/15 13:58 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 2.9 1.5 50 03/20/15 06:37 03/20/15 17:54 7440-36-0 D3,N2 Arsenic 28.9 mg/kg 2.9 1.5 50 03/20/15 06:37 03/20/15 17:54 7440-38-2 D3 Cadmium ND mg/kg 0.35 0.17 50 03/20/15 06:37 03/20/15 17:54 7440-43-9 D3 Cobalt 10.3 mg/kg 2.9 1.5 50 03/20/15 06:37 03/20/15 17:54 7440-48-4 D3 Lead 9.9 mg/kg 2.9 1.5 50 03/20/15 06:37 03/20/15 17:54 7439-92-1 D3 Selenium 10.3 mg/kg 2.9 1.5 50 03/20/15 06:37 03/20/15 17:54 7782-49-2 D3 Thallium ND mg/kg 2.9 1.5 50 03/20/15 06:37 03/20/15 17:54 7440-28-0 D3 Vanadium 17.6 mg/kg 2.9 1.5 50 03/20/15 06:37 03/20/15 17:54 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0095 0.0048 1 03/20/1513:25 03/20/1516:55 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 15.8 % 0.10 0.10 1 03/23/15 16:00 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.9 Std. Units 0.10 0.10 1 03/17/15 15:25 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Sulfate 8.2 mg/L 2.4 1.2 1 03/20/15 00:29 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Nitrogen, Nitrate 0.34 mg/L 0.24 0.24 1 03/18/15 16:57 B,H1 4500 Chloride, SPLP Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 03/16/15 14:15 Chloride ND mg/L 5.9 3.0 1 03/19/15 21:17 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 50 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. PW%1Sr6fy(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 Sample: 2015006958 Lab ID: 92241060007 Collected: 03/10/15 12:00 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 295 148 5 03/17/15 22:41 16887-00-6 D3 Sulfate ND mg/kg 295 148 5 03/17/15 22:41 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 29.5 14.8 5 03/17/15 22:41 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 713 357 1 03/20/15 11:20 7440-44-0 Total Organic Carbon ND mg/kg 708 354 1 03/20/15 11:27 7440-44-0 Total Organic Carbon ND mg/kg 718 359 1 03/20/15 11:32 7440-44-0 Total Organic Carbon ND mg/kg 716 358 1 03/20/15 11:37 7440-44-0 Mean Total Organic Carbon ND mg/kg 714 357 1 03/20/15 11:20 7440-44-0 Surrogates RSD% 3.9 % 1 03/20/1511:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 51 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. P369%1�irWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 Sample: 2015006961 Lab ID: 92241060008 Collected: 03/10/15 17:00 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 16100 mg/kg 6.2 3.1 1 03/20/15 06:37 03/20/15 20:12 7429-90-5 Barium 66.0 mg/kg 0.62 0.31 1 03/20/15 06:37 03/20/15 20:12 7440-39-3 Beryllium 0.86 mg/kg 0.31 0.15 5 03/20/15 06:37 03/20/15 20:16 7440-41-7 D3 Boron 23.1 mg/kg 15.4 7.7 5 03/20/15 06:37 03/20/15 20:16 7440-42-8 D3 Calcium 247 mg/kg 30.9 15.4 1 03/20/15 06:37 03/20/15 20:12 7440-70-2 Chromium 21.5 mg/kg 1.5 0.77 5 03/20/15 06:37 03/20/15 20:16 7440-47-3 D3 Copper 19.4 mg/kg 1.5 0.77 5 03/20/15 06:37 03/20/15 20:16 7440-50-8 D3 Iron 33000 mg/kg 12.4 6.2 5 03/20/15 06:37 03/20/15 20:16 7439-89-6 D3 Magnesium 1240 mg/kg 30.9 15.4 1 03/20/15 06:37 03/20/15 20:12 7439-95-4 Manganese 120 mg/kg 1.5 0.77 5 03/20/15 06:37 03/20/15 20:16 7439-96-5 D3 Molybdenum 0.46J mg/kg 0.62 0.31 1 03/20/15 06:37 03/20/15 20:12 7439-98-7 Nickel 5.0 mg/kg 0.31 0.15 1 03/20/15 06:37 03/20/15 20:12 7440-02-0 Potassium 870 mg/kg 61.8 30.9 1 03/20/15 06:37 03/20/15 20:12 7440-09-7 Sodium 33AJ mg/kg 61.8 30.9 1 03/20/15 06:37 03/20/15 20:12 7440-23-5 Strontium 9.9 mg/kg 0.62 0.31 1 03/20/15 06:37 03/20/15 20:12 7440-24-6 Zinc 24.9 mg/kg 1.2 0.62 1 03/20/15 06:37 03/20/15 20:12 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.1 1.5 50 03/20/15 06:37 03/20/15 17:57 7440-36-0 D3,N2 Arsenic 8.3 mg/kg 3.1 1.5 50 03/20/15 06:37 03/20/15 17:57 7440-38-2 D3 Cadmium ND mg/kg 0.37 0.19 50 03/20/15 06:37 03/20/15 17:57 7440-43-9 D3 Cobalt 7.7 mg/kg 3.1 1.5 50 03/20/15 06:37 03/20/15 17:57 7440-48-4 D3 Lead 13.4 mg/kg 3.1 1.5 50 03/20/15 06:37 03/20/15 17:57 7439-92-1 D3 Selenium 2.9J mg/kg 3.1 1.5 50 03/20/15 06:37 03/20/15 17:57 7782-49-2 D3 Thallium ND mg/kg 3.1 1.5 50 03/20/15 06:37 03/20/15 17:57 7440-28-0 D3 Vanadium 33.7 mg/kg 3.1 1.5 50 03/20/15 06:37 03/20/15 17:57 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.028 mg/kg 0.0098 0.0049 1 03/20/1513:25 03/23/1513:39 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 20.7 % 0.10 0.10 1 03/23/15 16:01 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.1 Std. Units 0.10 0.10 1 03/18/15 18:50 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Sulfate 3.5 mg/L 2.5 1.3 1 03/20/15 00:42 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Nitrogen, Nitrate ND mg/L 0.25 0.25 1 03/18/15 16:58 H1 4500 Chloride, SPLP Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 03/16/15 14:15 Chloride 16.2 mg/L 6.3 3.2 1 03/19/15 21:17 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 52 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. PAR18rWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 Sample: 2015006961 Lab ID: 92241060008 Collected: 03/10/15 17:00 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 313 157 5 03/17/15 23:02 16887-00-6 D3 Sulfate ND mg/kg 313 157 5 03/17/15 23:02 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.3 15.7 5 03/17/15 23:02 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 8880 mg/kg 757 378 1 03/20/15 12:25 7440-44-0 Total Organic Carbon 10000 mg/kg 753 377 1 03/20/15 12:31 7440-44-0 Total Organic Carbon 12100 mg/kg 760 380 1 03/20/15 12:37 7440-44-0 Total Organic Carbon 7530 mg/kg 762 381 1 03/20/15 12:45 7440-44-0 Mean Total Organic Carbon 9630 mg/kg 758 379 1 03/20/15 12:25 7440-44-0 Surrogates RSD% 20.0 % 1 03/20/1512:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 53 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. PARWrWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 Sample: 2015006962 Lab ID: 92241060009 Collected: 03/10/15 17:15 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 14900 mg/kg 5.9 3.0 1 03/20/15 06:37 03/20/15 20:20 7429-90-5 Barium 65.8 mg/kg 0.59 0.30 1 03/20/15 06:37 03/20/15 20:20 7440-39-3 Beryllium 0.75 mg/kg 0.30 0.15 5 03/20/15 06:37 03/20/15 20:25 7440-41-7 D3 Boron 17.9 mg/kg 14.8 7.4 5 03/20/15 06:37 03/20/15 20:25 7440-42-8 D3 Calcium 421 mg/kg 29.5 14.8 1 03/20/15 06:37 03/20/15 20:20 7440-70-2 Chromium 21.0 mg/kg 1.5 0.74 5 03/20/15 06:37 03/20/15 20:25 7440-47-3 D3 Copper 19.0 mg/kg 1.5 0.74 5 03/20/15 06:37 03/20/15 20:25 7440-50-8 D3 Iron 19200 mg/kg 2.4 1.2 1 03/20/15 06:37 03/20/15 20:20 7439-89-6 Magnesium 2220 mg/kg 29.5 14.8 1 03/20/15 06:37 03/20/15 20:20 7439-95-4 Manganese 163 mg/kg 1.5 0.74 5 03/20/15 06:37 03/20/15 20:25 7439-96-5 D3 Molybdenum 0.38J mg/kg 0.59 0.30 1 03/20/15 06:37 03/20/15 20:20 7439-98-7 Nickel 6.7 mg/kg 0.30 0.15 1 03/20/15 06:37 03/20/15 20:20 7440-02-0 Potassium 1660 mg/kg 59.1 29.5 1 03/20/15 06:37 03/20/15 20:20 7440-09-7 Sodium 40.OJ mg/kg 59.1 29.5 1 03/20/15 06:37 03/20/15 20:20 7440-23-5 Strontium 9.8 mg/kg 0.59 0.30 1 03/20/15 06:37 03/20/15 20:20 7440-24-6 Zinc 33.0 mg/kg 1.2 0.59 1 03/20/15 06:37 03/20/15 20:20 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.0 1.5 50 03/20/15 06:37 03/20/15 17:59 7440-36-0 D3,N2 Arsenic 6.3 mg/kg 3.0 1.5 50 03/20/15 06:37 03/20/15 17:59 7440-38-2 D3 Cadmium ND mg/kg 0.35 0.18 50 03/20/15 06:37 03/20/15 17:59 7440-43-9 D3 Cobalt 7.6 mg/kg 3.0 1.5 50 03/20/15 06:37 03/20/15 17:59 7440-48-4 D3 Lead 12.9 mg/kg 3.0 1.5 50 03/20/15 06:37 03/20/15 17:59 7439-92-1 D3 Selenium 2.8J mg/kg 3.0 1.5 50 03/20/15 06:37 03/20/15 17:59 7782-49-2 D3 Thallium ND mg/kg 3.0 1.5 50 03/20/15 06:37 03/20/15 17:59 7440-28-0 D3 Vanadium 28.7 mg/kg 3.0 1.5 50 03/20/15 06:37 03/20/15 17:59 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.031 mg/kg 0.0089 0.0045 1 03/20/1513:25 03/23/1513:41 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 12.6 % 0.10 0.10 1 03/23/15 16:01 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.5 Std. Units 0.10 0.10 1 03/18/15 18:50 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Sulfate 3.4 mg/L 2.3 1.1 1 03/20/15 00:56 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Nitrogen, Nitrate ND mg/L 0.23 0.23 1 03/18/15 17:03 H1 4500 Chloride, SPLP Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 03/16/15 14:15 Chloride 16.0 mg/L 5.7 2.9 1 03/19/15 21:18 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 54 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. PARVr6fY(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 Sample: 2015006962 Lab ID: 92241060009 Collected: 03/10/15 17:15 Received: 03/12/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 284 142 5 03/18/15 00:07 16887-00-6 D3 Sulfate ND mg/kg 284 142 5 03/18/15 00:07 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 28.4 14.2 5 03/18/15 00:07 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 12700 mg/kg 683 342 1 03/20/15 12:51 7440-44-0 Total Organic Carbon 13600 mg/kg 687 344 1 03/20/15 12:56 7440-44-0 Total Organic Carbon 13500 mg/kg 692 346 1 03/20/15 13:03 7440-44-0 Total Organic Carbon 14000 mg/kg 681 340 1 03/20/15 13:08 7440-44-0 Mean Total Organic Carbon 13500 mg/kg 686 343 1 03/20/15 12:51 7440-44-0 Surrogates RSD% 4.0 % 1 03/20/1512:51 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 55 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030308 Pace Project No.: 92241060 Pace Analytical Services, Inc. PAR816fyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015006957 SPLP Lab ID: 92241060010 Collected: 03/10/15 10:50 Received: 03/12/15 16:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\��il=11 a r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 03/31/2015 05:20 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 30300 ug/L 50.0 5.8 5 03/26/1519:01 03/27/1514:49 7429-90-5 4.1 ug/L 0.50 0.25 1 03/26/1519:01 03/27/1514:40 7440-36-0 380 ug/L 0.50 0.25 1 03/26/1519:01 03/27/1514:40 7440-38-2 185 ug/L 0.30 0.14 1 03/26/1519:01 03/27/1514:40 7440-39-3 1.7 ug/L 0.20 0.066 1 03/26/1519:01 03/27/1514:40 7440-41-7 179 ug/L 5.0 1.0 1 03/26/1519:01 03/27/1514:40 7440-42-8 0.43 ug/L 0.080 0.033 1 03/26/1519:01 03/27/1514:40 7440-43-9 11900 ug/L 40.0 8.4 1 03/26/1519:01 03/27/1514:40 7440-70-2 20.3 ug/L 0.50 0.22 1 03/26/1519:01 03/27/1514:40 7440-47-3 6.8 ug/L 0.50 0.25 1 03/26/1519:01 03/27/1514:40 7440-48-4 10.3 ug/L 1.0 0.22 1 03/26/1519:01 03/27/1514:40 7440-50-8 20000 ug/L 50.0 8.0 1 03/26/1519:01 03/27/1514:40 7439-89-6 36.2 ug/L 0.10 0.046 1 03/26/1519:01 03/27/1514:40 7439-92-1 1570 ug/L 10.0 2.8 1 03/26/1519:01 03/27/1514:40 7439-95-4 153 ug/L 0.50 0.14 1 03/26/1519:01 03/27/1514:40 7439-96-5 470 ug/L 2.5 1.2 5 03/26/1519:01 03/27/1514:49 7439-98-7 10.8 ug/L 0.50 0.23 1 03/26/1519:01 03/27/1514:40 7440-02-0 5000 ug/L 50.0 8.3 1 03/26/1519:01 03/27/1514:40 7440-09-7 5.0 ug/L 0.50 0.25 1 03/26/1519:01 03/27/1514:40 7782-49-2 1050 ug/L 50.0 18.2 1 03/26/1519:01 03/27/1514:40 7440-23-5 391 ug/L 0.50 0.057 1 03/26/1519:01 03/27/1514:40 7440-24-6 0.49 ug/L 0.10 0.025 1 03/26/1519:01 03/27/1514:40 7440-28-0 141 ug/L 1.0 0.21 1 03/26/1519:01 03/27/1514:40 7440-62-2 24.4 ug/L 5.0 2.5 1 03/26/1519:01 03/27/1514:40 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.60 0.078 1 03/26/1519:10 03/27/1513:09 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 56 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030308 Pace Project No.: 92241060 Pace Analytical Services, Inc. PA9%16r6fy�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015006958 SPLP Lab ID: 92241060011 Collected: 03/10/15 12:00 Received: 03/12/15 16:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\riil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 03/31/2015 05:20 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 940 ug/L 10.0 1.2 1 03/26/1519:01 03/27/1514:43 7429-90-5 ND ug/L 0.50 0.25 1 03/26/1519:01 03/27/1514:43 7440-36-0 5.0 ug/L 0.50 0.25 1 03/26/1519:01 03/27/1514:43 7440-38-2 13.1 ug/L 0.30 0.14 1 03/26/1519:01 03/27/1514:43 7440-39-3 ND ug/L 0.20 0.066 1 03/26/1519:01 03/27/1514:43 7440-41-7 32.8 ug/L 5.0 1.0 1 03/26/1519:01 03/27/1514:43 7440-42-8 ND ug/L 0.080 0.033 1 03/26/1519:01 03/27/1514:43 7440-43-9 1700 ug/L 40.0 8.4 1 03/26/1519:01 03/27/1514:43 7440-70-2 1.1 ug/L 0.50 0.22 1 03/26/1519:01 03/27/1514:43 7440-47-3 1.3 ug/L 0.50 0.25 1 03/26/1519:01 03/27/1514:43 7440-48-4 ND ug/L 1.0 0.22 1 03/26/1519:01 03/27/1514:43 7440-50-8 541 ug/L 50.0 8.0 1 03/26/1519:01 03/27/1514:43 7439-89-6 0.96 ug/L 0.10 0.046 1 03/26/1519:01 03/27/1514:43 7439-92-1 443 ug/L 10.0 2.8 1 03/26/1519:01 03/27/1514:43 7439-95-4 192 ug/L 0.50 0.14 1 03/26/1519:01 03/27/1514:43 7439-96-5 10.5 ug/L 0.50 0.24 1 03/26/1519:01 03/27/1514:43 7439-98-7 0.89 ug/L 0.50 0.23 1 03/26/1519:01 03/27/1514:43 7440-02-0 2460 ug/L 50.0 8.3 1 03/26/1519:01 03/27/1514:43 7440-09-7 ND ug/L 0.50 0.25 1 03/26/1519:01 03/27/1514:43 7782-49-2 1250 ug/L 50.0 18.2 1 03/26/1519:01 03/27/1514:43 7440-23-5 64.8 ug/L 0.50 0.057 1 03/26/1519:01 03/27/1514:43 7440-24-6 ND ug/L 0.10 0.025 1 03/26/1519:01 03/27/1514:43 7440-28-0 ND ug/L 1.0 0.21 1 03/26/1519:01 03/27/1514:43 7440-62-2 ND ug/L 5.0 2.5 1 03/26/1519:01 03/27/1514:43 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.026 1 03/26/1519:10 03/27/1513:12 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 57 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030308 Pace Project No.: 92241060 Pace Analytical Services, Inc. P36907blWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015006961 SPLP Lab ID: 92241060012 Collected: 03/10/15 17:00 Received: 03/12/15 16:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 03/31/2015 05:20 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 20900 ug/L 10.0 1.2 1 03/26/1519:01 03/27/1515:06 7429-90-5 ND ug/L 0.50 0.25 1 03/26/1519:01 03/27/1515:06 7440-36-0 13.4 ug/L 0.50 0.25 1 03/26/1519:01 03/27/1515:06 7440-38-2 161 ug/L 0.30 0.14 1 03/26/1519:01 03/27/1515:06 7440-39-3 2.0 ug/L 0.20 0.066 1 03/26/1519:01 03/27/1515:06 7440-41-7 53.5 ug/L 5.0 1.0 1 03/26/1519:01 03/27/1515:06 7440-42-8 0.13 ug/L 0.080 0.033 1 03/26/1519:01 03/27/1515:06 7440-43-9 1300 ug/L 40.0 8.4 1 03/26/1519:01 03/27/1515:06 7440-70-2 22.4 ug/L 0.50 0.22 1 03/26/1519:01 03/27/1515:06 7440-47-3 14.3 ug/L 0.50 0.25 1 03/26/1519:01 03/27/1515:06 7440-48-4 42.2 ug/L 1.0 0.22 1 03/26/1519:01 03/27/1515:06 7440-50-8 16800 ug/L 50.0 8.0 1 03/26/1519:01 03/27/1515:06 7439-89-6 34.7 ug/L 0.10 0.046 1 03/26/1519:01 03/27/1515:06 7439-92-1 1070 ug/L 10.0 2.8 1 03/26/1519:01 03/27/1515:06 7439-95-4 38.4 ug/L 0.50 0.14 1 03/26/1519:01 03/27/1515:06 7439-96-5 ND ug/L 0.50 0.24 1 03/26/1519:01 03/27/1515:06 7439-98-7 7.1 ug/L 0.50 0.23 1 03/26/1519:01 03/27/1515:06 7440-02-0 2680 ug/L 50.0 8.3 1 03/26/1519:01 03/27/1515:06 7440-09-7 0.92 ug/L 0.50 0.25 1 03/26/1519:01 03/27/1515:06 7782-49-2 2920 ug/L 50.0 18.2 1 03/26/1519:01 03/27/1515:06 7440-23-5 57.9 ug/L 0.50 0.057 1 03/26/1519:01 03/27/1515:06 7440-24-6 0.35 ug/L 0.10 0.025 1 03/26/1519:01 03/27/1515:06 7440-28-0 63.8 ug/L 1.0 0.21 1 03/26/1519:01 03/27/1515:06 7440-62-2 19.0 ug/L 5.0 2.5 1 03/26/1519:01 03/27/1515:06 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.60 0.078 1 03/26/1519:10 03/27/1513:14 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 58 of 96 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030308 Pace Project No.: 92241060 Pace Analytical Services, Inc. PgRoAirpyN.. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015006962 SPLP Lab ID: 92241060013 Collected: 03/10/15 17:15 Received: 03/12/15 16:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\r�il=11 a r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 03/31/2015 05:20 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 35800 ug/L 50.0 5.8 5 03/26/1519:01 03/27/1516:41 7429-90-5 ND ug/L 0.50 0.25 1 03/26/1519:01 03/27/1515:09 7440-36-0 13.8 ug/L 0.50 0.25 1 03/26/1519:01 03/27/1515:09 7440-38-2 204 ug/L 0.30 0.14 1 03/26/1519:01 03/27/1515:09 7440-39-3 2.2 ug/L 0.20 0.066 1 03/26/1519:01 03/27/1515:09 7440-41-7 128 ug/L 5.0 1.0 1 03/26/1519:01 03/27/1515:09 7440-42-8 0.16 ug/L 0.080 0.033 1 03/26/1519:01 03/27/1515:09 7440-43-9 2040 ug/L 40.0 8.4 1 03/26/1519:01 03/27/1515:09 7440-70-2 31.5 ug/L 0.50 0.22 1 03/26/1519:01 03/27/1515:09 7440-47-3 17.7 ug/L 0.50 0.25 1 03/26/1519:01 03/27/1515:09 7440-48-4 46.7 ug/L 1.0 0.22 1 03/26/1519:01 03/27/1515:09 7440-50-8 25400 ug/L 250 40.1 5 03/26/1519:01 03/27/1516:41 7439-89-6 61.5 ug/L 0.10 0.046 1 03/26/1519:01 03/27/1515:09 7439-92-1 1420 ug/L 10.0 2.8 1 03/26/1519:01 03/27/1515:09 7439-95-4 136 ug/L 0.50 0.14 1 03/26/1519:01 03/27/1515:09 7439-96-5 0.84 ug/L 0.50 0.24 1 03/26/1519:01 03/27/1515:09 7439-98-7 12.0 ug/L 0.50 0.23 1 03/26/1519:01 03/27/1515:09 7440-02-0 3480 ug/L 50.0 8.3 1 03/26/1519:01 03/27/1515:09 7440-09-7 1.3 ug/L 0.50 0.25 1 03/26/1519:01 03/27/1515:09 7782-49-2 7770 ug/L 50.0 18.2 1 03/26/1519:01 03/27/1515:09 7440-23-5 47.1 ug/L 0.50 0.057 1 03/26/1519:01 03/27/1515:09 7440-24-6 0.28 ug/L 0.10 0.025 1 03/26/1519:01 03/27/1515:09 7440-28-0 80.4 ug/L 1.0 0.21 1 03/26/1519:01 03/27/1515:09 7440-62-2 40.7 ug/L 5.0 2.5 1 03/26/1519:01 03/27/1515:09 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.60 0.078 1 03/26/1519:10 03/27/1513:16 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 59 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P369ohlWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 QC Batch: MERP/12999 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92241060001 METHOD BLANK: 1920255 Matrix: Water Associated Lab Samples: 92241060001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/19/1511:34 LABORATORY CONTROL SAMPLE: 1920256 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.9 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1920257 1920258 MS MSD 92241061002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.0 5.0 99 100 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 60 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P3690 3irWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 QC Batch: MERP/13071 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92241060010, 92241060011, 92241060012, 92241060013 METHOD BLANK: 1926030 Matrix: Water Associated Lab Samples: 92241060010, 92241060011, 92241060012, 92241060013 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/27/1512:24 LABORATORY CONTROL SAMPLE: 1926031 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.9 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1926032 1926033 MS MSD 92242374012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.2 5.1 83 102 75-125 21 20 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 61 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P36907ir6fY(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 QC Batch: MERP/5492 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92241060004, 92241060005, 92241060006, 92241060007 METHOD BLANK: 1161936 Matrix: Solid Associated Lab Samples: 92241060004, 92241060005, 92241060006, 92241060007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0083 03/20/1516:51 LABORATORY CONTROL SAMPLE: 1161937 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .08 0.074 93 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1161938 1161939 MS MSD 92241060007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND .0915 .095 0.083 0.088 89 91 80-120 7 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 62 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P36908r6fyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 QC Batch: MERP/5493 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92241060003, 92241060008, 92241060009 METHOD BLANK: 1161940 Matrix: Solid Associated Lab Samples: 92241060003, 92241060008, 92241060009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0082 03/23/1513:24 LABORATORY CONTROL SAMPLE: 1161941 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .082 0.077 94 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1161942 1161943 MS MSD 35179481001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.38 .787 .787 0.94 0.82 72 56 80-120 14 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 63 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P3690 �irWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 QC Batch: MERP/5502 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92241060002 METHOD BLANK: 1164137 Matrix: Solid Associated Lab Samples: 92241060002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0079 03/24/1517:27 LABORATORY CONTROL SAMPLE: 1164138 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .081 0.086 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1164139 1164140 MS MSD 35179122001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.084 .333 .309 0.30 0.36 64 89 80-120 18 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 64 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030308 Pace Project No.: 92241060 QC Batch: MPRP/23172 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92241060004, 92241060005, 92241060006, 92241060007, 92241060008, 92241060009 METHOD BLANK: 1161436 Matrix: Solid Associated Lab Samples: 92241060004, 92241060005, 92241060006, 92241060007, 92241060008, 92241060009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Aluminum mg/kg 3AJ 4.9 03/20/1519:15 P8 Barium mg/kg ND 0.49 03/20/1519:15 Beryllium mg/kg ND 0.049 03/20/1519:15 Boron mg/kg ND 2.4 03/20/1519:15 Calcium mg/kg ND 24.3 03/20/1519:15 Chromium mg/kg ND 0.24 03/20/1519:15 Copper mg/kg ND 0.24 03/20/1519:15 Iron mg/kg ND 1.9 03/20/1519:15 Magnesium mg/kg ND 24.3 03/20/1519:15 Manganese mg/kg 0.18J 0.24 03/20/1519:15 P8 Molybdenum mg/kg ND 0.49 03/20/1519:15 Nickel mg/kg ND 0.24 03/20/1519:15 Potassium mg/kg ND 48.6 03/20/1519:15 Sodium mg/kg ND 48.6 03/20/1519:15 Strontium mg/kg ND 0.49 03/20/1519:15 Zinc mg/kg ND 0.97 03/20/1519:15 Pace Analytical Services, Inc. PAROnrWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1161437 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum mg/kg 126 129 103 80-120 Barium mg/kg 12.6 12.9 102 80-120 Beryllium mg/kg 1.3 1.3 101 80-120 Boron mg/kg 126 127 100 80-120 Calcium mg/kg 631 647 102 80-120 Chromium mg/kg 12.6 12.7 101 80-120 Copper mg/kg 12.6 12.5 99 80-120 Iron mg/kg 126 127 101 80-120 Magnesium mg/kg 631 647 102 80-120 Manganese mg/kg 12.6 12.7 101 80-120 Molybdenum mg/kg 12.6 12.6 100 80-120 Nickel mg/kg 12.6 13.0 103 80-120 Potassium mg/kg 631 628 100 80-120 Sodium mg/kg 631 648 103 80-120 Strontium mg/kg 12.6 12.4 99 80-120 Zinc mg/kg 63.1 64.4 102 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 65 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P3690 �irWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1161438 1161439 MS MSD 92240782001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 16000 183 171 24200 22600 4440 3870 75-125 7 20 D3,M1 Barium mg/kg 488 18.3 17.1 658 620 928 771 75-125 6 20 D3,M1 Beryllium mg/kg 2.7 1.89 1.74 5.1 5.0 131 132 75-125 3 20 D3,M1 Boron mg/kg 17.OJ 183 171 173 157 85 82 75-125 10 20 D3 Calcium mg/kg 381 917 855 1340 1270 105 105 75-125 5 20 D3 Chromium mg/kg 36.8 18.3 17.1 76.5 78.2 216 242 75-125 2 20 D3,M1 Copper mg/kg 44.6 18.3 17.1 54.0 48.0 51 19 75-125 12 20 D3,M1 Iron mg/kg 26100 183 171 37000 34800 5940 5050 75-125 6 20 D3,M1 Magnesium mg/kg 9390 917 855 15400 14700 653 617 75-125 5 20 D3,M1 Manganese mg/kg 226 18.3 17.1 451 315 1230 523 75-125 35 20 D3,M1, R1 Molybdenum mg/kg ND 18.3 17.1 8.1 6.3 44 37 75-125 24 20 D3,M1, R1 Nickel mg/kg 19.5 18.3 17.1 52.6 50.7 180 182 75-125 4 20 D3,M1 Potassium mg/kg 8060 917 855 12700 11800 504 442 75-125 7 20 D3,M1 Sodium mg/kg ND 917 855 962 872 97 93 75-125 10 20 D3 Strontium mg/kg 9.6 18.3 17.1 28.5 26.7 103 100 75-125 7 20 D3 Zinc mg/kg 56.9 91.7 85.5 168 158 121 118 75-125 6 20 D3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 66 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030308 Pace Project No.: 92241060 QC Batch: MPRP/23184 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92241060003 METHOD BLANK: 1162079 Associated Lab Samples: 92241060003 Parameter Units Aluminum mg/kg Barium mg/kg Beryllium mg/kg Boron mg/kg Calcium mg/kg Chromium mg/kg Copper mg/kg Iron mg/kg Magnesium mg/kg Manganese mg/kg Molybdenum mg/kg Nickel mg/kg Potassium mg/kg Sodium mg/kg Strontium mg/kg Zinc mg/kg Matrix: Solid Blank Result Reporting Limit Analyzed ND 5.1 03/24/15 09:42 ND 0.51 03/24/15 09:42 ND 0.051 03/24/15 09:42 ND 2.5 03/24/15 09:42 ND 25.3 03/24/15 09:42 ND 0.25 03/24/15 09:42 ND 0.25 03/24/15 09:42 ND 2.0 03/24/15 09:42 ND 25.3 03/24/15 09:42 ND 0.25 03/24/15 09:42 ND 0.51 03/24/15 09:42 ND 0.25 03/24/15 09:42 ND 50.7 03/24/15 09:42 ND 50.7 03/24/15 09:42 ND 0.51 03/24/15 09:42 ND 1.0 03/24/15 09:42 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1162080 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 127 128 101 80-120 Barium mg/kg 12.7 13.0 103 80-120 Beryllium mg/kg 1.3 1.2 98 80-120 Boron mg/kg 127 123 97 80-120 Calcium mg/kg 635 634 100 80-120 Chromium mg/kg 12.7 12.9 102 80-120 Copper mg/kg 12.7 12.6 99 80-120 Iron mg/kg 127 122 96 80-120 Magnesium mg/kg 635 631 99 80-120 Manganese mg/kg 12.7 12.3 97 80-120 Molybdenum mg/kg 12.7 12.3 97 80-120 Nickel mg/kg 12.7 12.7 100 80-120 Potassium mg/kg 635 632 100 80-120 Sodium mg/kg 635 649 102 80-120 Strontium mg/kg 12.7 12.3 97 80-120 Zinc mg/kg 63.5 63.3 100 80-120 Pace Analytical Services, Inc. P3690 �irWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 67 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. POO WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1162081 1162082 MS MSD 92241060003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 10800 174 177 12300 11100 864 190 75-125 10 20 M1 Barium mg/kg 281 17.4 17.7 289 282 44 4 75-125 2 20 M1 Beryllium mg/kg 1.8 1.81 1.81 3.6 3.3 103 88 75-125 7 20 Boron mg/kg 26.9 174 177 164 160 78 75 75-125 2 20 Calcium mg/kg 2840 873 887 3890 3730 120 100 75-125 4 20 Chromium mg/kg 15.3 17.4 17.7 27.6 26.9 70 65 75-125 3 20 M1 Copper mg/kg 30.5 17.4 17.7 43.9 40.8 76 58 75-125 7 20 M1 Iron mg/kg 6090 174 177 5910 5640 -102 -253 75-125 5 20 M1 Magnesium mg/kg 919 873 887 1700 1630 89 80 75-125 4 20 Manganese mg/kg 38.7 17.4 17.7 49.0 46.7 59 45 75-125 5 20 M1 Molybdenum mg/kg 1.1 17.4 17.7 14.1 14.2 74 74 75-125 1 20 M1 Nickel mg/kg 17.0 17.4 17.7 31.0 29.9 80 72 75-125 4 20 M1 Potassium mg/kg 1480 873 887 2920 2730 165 142 75-125 7 20 M1 Sodium mg/kg 186 873 887 1020 998 95 92 75-125 2 20 Strontium mg/kg 232 17.4 17.7 239 223 42 -49 75-125 7 20 M1 Zinc mg/kg 26.0 87.3 88.7 99.3 96.5 84 80 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 68 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030308 Pace Project No.: 92241060 QC Batch: MPRP/23201 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92241060002 METHOD BLANK: 1162647 Associated Lab Samples: 92241060002 Parameter Units Matrix: Blank Result Solid Reporting Limit Analyzed Aluminum mg/kg ND 5.1 03/24/1510:30 Barium mg/kg ND 0.51 03/24/1510:30 Boron mg/kg ND 2.6 03/24/1510:30 Calcium mg/kg ND 25.6 03/24/1510:30 Chromium mg/kg ND 0.26 03/24/1510:30 Copper mg/kg ND 0.26 03/24/1510:30 Iron mg/kg 1.2J 2.0 03/24/1510:30 Magnesium mg/kg ND 25.6 03/24/1510:30 Manganese mg/kg ND 0.26 03/24/1510:30 Molybdenum mg/kg ND 0.51 03/24/1510:30 Nickel mg/kg ND 0.26 03/24/1510:30 Potassium mg/kg ND 51.1 03/24/1510:30 Sodium mg/kg ND 51.1 03/24/1510:30 Strontium mg/kg ND 0.51 03/24/1510:30 Zinc mg/kg ND 1.0 03/24/1510:30 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1162648 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 127 130 102 80-120 Barium mg/kg 12.7 13.2 103 80-120 Boron mg/kg 127 125 98 80-120 Calcium mg/kg 637 649 102 80-120 Chromium mg/kg 12.7 12.9 101 80-120 Copper mg/kg 12.7 13.0 102 80-120 Iron mg/kg 127 123 97 80-120 Magnesium mg/kg 637 637 100 80-120 Manganese mg/kg 12.7 12.5 98 80-120 Molybdenum mg/kg 12.7 12.3 96 80-120 Nickel mg/kg 12.7 12.7 100 80-120 Potassium mg/kg 637 644 101 80-120 Sodium mg/kg 637 667 105 80-120 Strontium mg/kg 12.7 12.7 100 80-120 Zinc mg/kg 63.7 63.8 100 80-120 Pace Analytical Services, Inc. P36R08 6fyN.. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 69 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. PARYWYNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1162649 1162650 MS MSD 92241387002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 6360 150 149 7810 8060 963 1130 75-125 3 20 M1 Barium mg/kg 368 15 14.9 397 433 189 432 75-125 9 20 M1 Boron mg/kg 13.1 150 149 129 125 77 74 75-125 4 20 M1 Calcium mg/kg 2870 750 748 3830 3310 128 59 75-125 15 20 M1 Chromium mg/kg 12.0 15 14.9 24.6 25.0 84 87 75-125 2 20 Copper mg/kg 23.6 15 14.9 37.1 37.5 90 93 75-125 1 20 Iron mg/kg 5150 150 149 5960 6580 541 959 75-125 10 20 M1 Magnesium mg/kg 659 750 748 1470 1360 108 94 75-125 8 20 Manganese mg/kg 46.6 15 14.9 61.1 60.0 97 90 75-125 2 20 Molybdenum mg/kg 1.1 15 14.9 12.7 12.8 77 78 75-125 1 20 Nickel mg/kg 9.6 15 14.9 23.7 24.7 94 101 75-125 4 20 Potassium mg/kg 1010 750 748 2000 2080 132 143 75-125 4 20 M1 Sodium mg/kg 147 750 748 875 842 97 93 75-125 4 20 Strontium mg/kg 115 15 14.9 136 140 140 167 75-125 3 20 M1 Zinc mg/kg 14.9 75 74.8 79.7 79.2 86 86 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 70 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030308 Pace Project No.: 92241060 QC Batch: MPRP/23173 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92241060004, 92241060005, 92241060006, 92241060007, 92241060008, 92241060009 METHOD BLANK: 1161440 Matrix: Solid LCS Result Associated Lab Samples: 92241060004, 92241060005, 92241060006, 92241060007, 92241060008, 92241060009 2.5 2.4 Blank Reporting Arsenic Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.049 03/20/1517:06 N2 Arsenic mg/kg ND 0.049 03/20/1517:06 Cadmium mg/kg ND 0.0058 03/20/1517:06 Cobalt mg/kg ND 0.049 03/20/1517:06 Lead mg/kg ND 0.049 03/20/1517:06 Selenium mg/kg ND 0.049 03/20/1517:06 Thallium mg/kg ND 0.049 03/20/1517:06 Vanadium mg/kg ND 0.049 03/20/1517:06 Pace Analytical Services, Inc. PARYWYNe. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1161441 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.4 98 80-120 N2 Arsenic mg/kg 2.5 2.5 99 80-120 Cadmium mg/kg .25 0.24 98 80-120 Cobalt mg/kg 2.5 2.5 102 80-120 Lead mg/kg 2.5 2.4 98 80-120 Selenium mg/kg 2.5 2.4 97 80-120 Thallium mg/kg 2.5 2.5 101 80-120 Vanadium mg/kg 2.5 2.5 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1161442 MS 92240782002 Spike Parameter Units Result Conc. MSD Spike Conc. 1161443 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Antimony mg/kg ND 3.39 3.39 2.1J 2.2J 60 61 75-125 20 D3,M6, N2 Arsenic mg/kg 3.3J 3.39 3.39 4.9 5.1 47 53 75-125 4 20 D3,M6 Cadmium mg/kg ND .339 .339 0.43 0.44 112 117 75-125 3 20 D3 Cobalt mg/kg 6.9 3.39 3.39 9.3 11.7 70 142 75-125 23 20 D3,M6, R1 Lead mg/kg 17.5 3.39 3.39 19.8 22.0 67 135 75-125 11 20 D3,M6 Selenium mg/kg 4.0 3.39 3.39 5.1 5.3 31 37 75-125 4 20 D3,M6 Thallium mg/kg ND 3.39 3.39 3.5 3.5 88 89 75-125 0 20 D3 Vanadium mg/kg 20.7 3.39 3.39 21.6 25.5 27 144 75-125 17 20 D3,M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 71 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030308 Pace Project No.: 92241060 QC Batch: MPRP/23185 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92241060003 METHOD BLANK: 1162086 Matrix: Solid Associated Lab Samples: 92241060003 Blank Reporting LCS Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg 0.034J 0.051 03/23/1513:29 N2 Arsenic mg/kg ND 0.051 03/23/1513:29 Cadmium mg/kg ND 0.0061 03/23/1513:29 Cobalt mg/kg ND 0.051 03/23/1513:29 Lead mg/kg ND 0.051 03/23/1513:29 Selenium mg/kg ND 0.051 03/23/1513:29 Thallium mg/kg ND 0.051 03/23/1513:29 Vanadium mg/kg ND 0.051 03/23/1513:29 Pace Analytical Services, Inc. PAMIirWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1162087 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony mg/kg 2.6 2.6 99 80-120 N2 Arsenic mg/kg 2.6 2.6 103 80-120 Cadmium mg/kg .26 0.26 103 80-120 Cobalt mg/kg 2.6 2.6 102 80-120 Lead mg/kg 2.6 2.6 103 80-120 Selenium mg/kg 2.6 2.7 106 80-120 Thallium mg/kg 2.6 2.6 103 80-120 Vanadium mg/kg 2.6 2.6 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1162088 1162089 MS MSD 92241060003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.34 3.62 2.6J 2.5J 48 42 75-125 20 M6, N2 Arsenic mg/kg 64.2 3.34 3.62 66.0 70.4 52 170 75-125 6 20 M6 Cadmium mg/kg 0.44 .334 .362 0.70 0.71 77 76 75-125 2 20 Cobalt mg/kg 7.2 3.34 3.62 10.4 11.8 95 129 75-125 13 20 M6 Lead mg/kg 11.7 3.34 3.62 15.5 17.5 113 160 75-125 12 20 M6 Selenium mg/kg 8.4 3.34 3.62 11.1 11.3 80 80 75-125 1 20 Thallium mg/kg ND 3.34 3.62 2.9J 3.OJ 51 50 75-125 20 M6 Vanadium mg/kg 44.9 3.34 3.62 49.1 54.6 125 270 75-125 11 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 72 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030308 Pace Project No.: 92241060 QC Batch: MPRP/23202 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92241060002 METHOD BLANK: 1162651 1162652 Units Matrix: Solid LCS % Rec Associated Lab Samples: 92241060002 Antimony mg/kg 5.1 5.0 99 80-120 N2 Blank Reporting 5.1 Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 03/24/15 08:24 N2 Arsenic mg/kg ND 0.051 03/24/15 08:24 Beryllium mg/kg ND 0.0061 03/24/15 08:24 Cadmium mg/kg ND 0.0061 03/24/15 08:24 Cobalt mg/kg ND 0.051 03/24/15 08:24 Lead mg/kg ND 0.051 03/24/15 08:24 Selenium mg/kg ND 0.051 03/24/15 08:24 Thallium mg/kg ND 0.051 03/24/15 08:24 Vanadium mg/kg ND 0.051 03/24/15 08:24 Pace Analytical Services, Inc. POO WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1162652 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 5.1 5.0 99 80-120 N2 Arsenic mg/kg 5.1 4.9 96 80-120 Beryllium mg/kg .51 0.53 104 80-120 Cadmium mg/kg .51 0.51 101 80-120 Cobalt mg/kg 5.1 4.9 97 80-120 Lead mg/kg 5.1 5.0 98 80-120 Selenium mg/kg 5.1 5.0 99 80-120 Thallium mg/kg 5.1 5.1 100 80-120 Vanadium mg/kg 5.1 4.9 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1162653 MS 92241387002 Spike Parameter Units Result Conc. MSD Spike Conc. 1162654 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Antimony mg/kg ND 6.09 2.87 10.2 18.9 151 612 75-125 59 20 M6, N2, R1 Arsenic mg/kg 59.9 6.09 2.87 77.2 142 283 2800 75-125 59 20 M6, R1 Beryllium mg/kg 2.0 .609 .287 3.5 7.3 252 1810 75-125 69 20 M6, R1 Cadmium mg/kg 0.20J .609 .287 1.7 3.2 237 1030 75-125 64 20 M6, R1 Cobalt mg/kg 6.6 6.09 2.87 23.3 45.2 273 1320 75-125 64 20 M6, R1 Lead mg/kg 8.8 6.09 2.87 23.9 48.3 247 1350 75-125 68 20 M6,R1 Selenium mg/kg 14.6 6.09 2.87 25.0 47.5 170 1130 75-125 62 20 M6,R1 Thallium mg/kg ND 6.09 2.87 13.4 26.2 199 852 75-125 64 20 M6,R1 Vanadium mg/kg 39.9 6.09 2.87 58.4 109 302 2370 75-125 61 20 M6,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 73 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030308 Pace Project No.: 92241060 QC Batch: MPRP/52981 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92241060001 METHOD BLANK: 1918970 Associated Lab Samples: 92241060001 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 03/18/1511:34 ND 0.50 03/18/1511:34 ND 0.50 03/18/1511:34 ND 0.30 03/18/1511:34 ND 0.20 03/18/1511:34 ND 5.0 03/18/1511:34 ND 0.080 03/18/1511:34 ND 40.0 03/18/1511:34 ND 0.50 03/18/1511:34 ND 0.50 03/18/1511:34 ND 1.0 03/18/1511:34 ND 50.0 03/18/1511:34 ND 0.10 03/18/1511:34 ND 10.0 03/18/1511:34 ND 0.50 03/18/1511:34 ND 0.50 03/18/1511:34 ND 0.50 03/18/1511:34 ND 50.0 03/18/1511:34 ND 0.50 03/18/1511:34 ND 50.0 03/18/1511:34 ND 0.50 03/18/1511:34 ND 0.10 03/18/1511:34 ND 1.0 03/18/1511:34 ND 5.0 03/18/1511:34 Qualifiers Pace Analytical Services, Inc. PARVrwY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1918971 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 81.1 101 80-120 Antimony ug/L 80 81.8 102 80-120 Arsenic ug/L 80 83.5 104 80-120 Barium ug/L 80 81.6 102 80-120 Beryllium ug/L 80 86.7 108 80-120 Boron ug/L 80 87.6 110 80-120 Cadmium ug/L 80 81.0 101 80-120 Calcium ug/L 1000 1000 100 80-120 Chromium ug/L 80 83.5 104 80-120 Cobalt ug/L 80 82.7 103 80-120 Copper ug/L 80 83.1 104 80-120 Iron ug/L 1000 1030 103 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 74 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. PARVIWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 LABORATORY CONTROL SAMPLE: 1918971 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 82.8 104 80-120 Magnesium ug/L 1000 1030 103 80-120 Manganese ug/L 80 82.6 103 80-120 Molybdenum ug/L 80 81.7 102 80-120 Nickel ug/L 80 83.2 104 80-120 Potassium ug/L 1000 1050 105 80-120 Selenium ug/L 80 81.7 102 80-120 Sodium ug/L 1000 1020 102 80-120 Strontium ug/L 80 82.9 104 80-120 Thallium ug/L 80 82.6 103 80-120 Vanadium ug/L 80 83.0 104 80-120 Zinc ug/L 80 82.0 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1918972 1918973 MS MSD 92241061001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 388 80 80 963 971 718 728 75-125 1 20 M1 Antimony ug/L ND 80 80 82.7 80.7 103 101 75-125 2 20 Arsenic ug/L ND 80 80 83.2 81.4 104 102 75-125 2 20 Barium ug/L 4.7 80 80 88.9 87.1 105 103 75-125 2 20 Beryllium ug/L ND 80 80 84.9 88.1 106 110 75-125 4 20 Boron ug/L ND 80 80 86.8 91.4 108 113 75-125 5 20 Cadmium ug/L ND 80 80 82.2 80.4 103 100 75-125 2 20 Calcium ug/L 127 1000 1000 1250 1170 112 104 75-125 6 20 Chromium ug/L 6.1 80 80 89.9 87.9 105 102 75-125 2 20 Cobalt ug/L ND 80 80 82.9 81.6 103 101 75-125 2 20 Copper ug/L 2.7 80 80 85.9 84.8 104 103 75-125 1 20 Iron ug/L 1170 1000 1000 2340 2290 117 112 75-125 2 20 Lead ug/L 0.13 80 80 84.4 82.7 105 103 75-125 2 20 Magnesium ug/L 221 1000 1000 1270 1260 105 104 75-125 1 20 Manganese ug/L 23.8 80 80 110 105 107 102 75-125 4 20 Molybdenum ug/L 1.0 80 80 83.6 81.4 103 100 75-125 3 20 Nickel ug/L 1.7 80 80 85.2 83.5 104 102 75-125 2 20 Potassium ug/L 86.6 1000 1000 1150 1140 107 105 75-125 1 20 Selenium ug/L ND 80 80 83.3 82.2 104 103 75-125 1 20 Sodium ug/L ND 1000 1000 1070 1080 104 104 75-125 0 20 Strontium ug/L 1.6 80 80 85.9 84.8 105 104 75-125 1 20 Thallium ug/L ND 80 80 86.5 84.8 108 106 75-125 2 20 Vanadium ug/L 1.4 80 80 85.5 83.9 105 103 75-125 2 20 Zinc ug/L ND 80 80 85.3 84.8 103 102 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 75 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030308 Pace Project No.: 92241060 QC Batch: MPRP/53205 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92241060010, 92241060011, 92241060012, 92241060013 METHOD BLANK: 1926005 Matrix: Water Associated Lab Samples: 92241060010, 92241060011, 92241060012, 92241060013 Blank Reporting Parameter Units Result Limit Analyzed Aluminum ug/L ND 10.0 03/27/1513:48 Antimony ug/L ND 0.50 03/27/1513:48 Arsenic ug/L ND 0.50 03/27/1513:48 Barium ug/L ND 0.30 03/27/1513:48 Beryllium ug/L ND 0.20 03/27/1513:48 Boron ug/L ND 5.0 03/27/1513:48 Cadmium ug/L ND 0.080 03/27/1513:48 Calcium ug/L ND 40.0 03/27/1513:48 Chromium ug/L ND 0.50 03/27/1513:48 Cobalt ug/L ND 0.50 03/27/1513:48 Copper ug/L ND 1.0 03/27/1513:48 Iron ug/L ND 50.0 03/27/1513:48 Lead ug/L ND 0.10 03/27/1513:48 Magnesium ug/L ND 10.0 03/27/1513:48 Manganese ug/L ND 0.50 03/27/1513:48 Molybdenum ug/L ND 0.50 03/27/1513:48 Nickel ug/L ND 0.50 03/27/1513:48 Potassium ug/L ND 50.0 03/27/1513:48 Selenium ug/L ND 0.50 03/27/1513:48 Sodium ug/L ND 50.0 03/27/1513:48 Strontium ug/L ND 0.50 03/27/1513:48 Thallium ug/L ND 0.10 03/27/1513:48 Vanadium ug/L ND 1.0 03/27/1513:48 Zinc ug/L ND 5.0 03/27/1513:48 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1926006 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum ug/L 80 90.1 113 80-120 Antimony ug/L 80 81.4 102 80-120 Arsenic ug/L 80 81.9 102 80-120 Barium ug/L 80 86.1 108 80-120 Beryllium ug/L 80 81.9 102 80-120 Boron ug/L 80 84.7 106 80-120 Cadmium ug/L 80 86.8 108 80-120 Calcium ug/L 1000 1100 110 80-120 Chromium ug/L 80 87.4 109 80-120 Cobalt ug/L 80 85.9 107 80-120 Copper ug/L 80 85.1 106 80-120 Iron ug/L 1000 1120 112 80-120 Pace Analytical Services, Inc. PARI&WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 76 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. POO WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 LABORATORY CONTROL SAMPLE: 1926006 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 85.0 106 80-120 Magnesium ug/L 1000 1050 105 80-120 Manganese ug/L 80 89.4 112 80-120 Molybdenum ug/L 80 84.4 105 80-120 Nickel ug/L 80 87.2 109 80-120 Potassium ug/L 1000 1080 108 80-120 Selenium ug/L 80 82.6 103 80-120 Sodium ug/L 1000 1080 108 80-120 Strontium ug/L 80 84.2 105 80-120 Thallium ug/L 80 88.7 111 80-120 Vanadium ug/L 80 86.8 108 80-120 Zinc ug/L 80 87.7 110 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1926431 1926432 MS MSD 92242374012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 57.4 80 80 190 332 166 344 75-125 55 20 M1,R1 Antimony ug/L ND 80 80 79.8 80.0 100 100 75-125 0 20 Arsenic ug/L ND 80 80 80.6 80.6 101 101 75-125 0 20 Barium ug/L 2.2 80 80 87.7 86.6 107 105 75-125 1 20 Beryllium ug/L ND 80 80 82.7 81.4 103 102 75-125 2 20 Boron ug/L ND 80 80 88.3 87.1 108 107 75-125 1 20 Cadmium ug/L ND 80 80 87.1 87.1 109 109 75-125 0 20 Calcium ug/L 102 1000 1000 1170 1200 106 110 75-125 3 20 Chromium ug/L 1.5 80 80 88.9 87.7 109 108 75-125 1 20 Cobalt ug/L ND 80 80 87.1 86.2 109 108 75-125 1 20 Copper ug/L 1.3 80 80 86.6 85.2 107 105 75-125 2 20 Iron ug/L 553 1000 1000 1680 1870 113 131 75-125 10 20 M1 Lead ug/L 0.12 80 80 83.8 82.4 105 103 75-125 2 20 Magnesium ug/L 29.0 1000 1000 1100 1090 107 106 75-125 0 20 Manganese ug/L 13.6 80 80 102 101 111 110 75-125 1 20 Molybdenum ug/L ND 80 80 83.0 83.2 104 104 75-125 0 20 Nickel ug/L 1.3 80 80 88.8 87.6 109 108 75-125 1 20 Potassium ug/L ND 1000 1000 1100 1100 106 106 75-125 0 20 Selenium ug/L ND 80 80 82.9 82.9 104 104 75-125 0 20 Sodium ug/L 108 1000 1000 1190 1170 108 106 75-125 2 20 Strontium ug/L 0.95 80 80 84.1 83.3 104 103 75-125 1 20 Thallium ug/L ND 80 80 87.8 86.6 110 108 75-125 1 20 Vanadium ug/L ND 80 80 85.8 84.6 107 105 75-125 1 20 Zinc ug/L 26.6 80 80 111 111 106 105 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 77 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030308 Pace Project No.: 92241060 Pace Analytical Services, Inc. PARVrwY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QC Batch: PMST/3367 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92241060003,92241060004,92241060005,92241060006,92241060007,92241060008,92241060009 SAMPLE DUPLICATE: 1163572 92241060003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 28.2 28.6 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 78 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P36gmirpYN.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 QC Batch: PMST/3372 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92241060002 SAMPLE DUPLICATE: 1164355 35179495002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 36.5 61.7 51 10 D6 SAMPLE DUPLICATE: 1164356 92241387008 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 25.0 27.7 10 10 SAMPLE DUPLICATE: 1164357 92241477008 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 6.9 6.7 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 79 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030308 Pace Project No.: 92241060 QC Batch: WET/29878 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92241060002 Pace Analytical Services, Inc. P36906rWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1163201 92241060002 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.1 7.1 0 20 H6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 80 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030308 Pace Project No.: 92241060 QC Batch: WET/36257 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92241060002, 92241060003, 92241060004, 92241060005, 92241060006, 92241060007 Pace Analytical Services, Inc. P36906rWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1412422 92240258001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.7 6.7 0 10 SAMPLE DUPLICATE: 1412423 Parameter pH at 25 Degrees C 92240781003 Dup Units Result Result Std. Units 6.2 6.1 Max RPD RPD Qualifiers 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 81 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030308 Pace Project No.: 92241060 QC Batch: WET/36284 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92241060008, 92241060009 Pace Analytical Services, Inc. PAROAirWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1413495 92240107001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.1 6.2 1 10 SAMPLE DUPLICATE: 1413496 92241387003 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.5 6.4 1 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 82 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. PAROAirWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 QC Batch: WETA/22270 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92241060006, 92241060007, 92241060008, 92241060009 METHOD BLANK: 1415171 Matrix: Water Associated Lab Samples: 92241060006, 92241060007, 92241060008, 92241060009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L ND 2.0 03/19/1518:22 LABORATORY CONTROL SAMPLE: 1415172 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 18.7 94 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415173 1415174 MS MSD 92239540001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 3.5 24 24 25.8 25.8 93 93 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415175 1415176 MS MSD 92240158010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 3.0 25.5 25.5 26.8 26.8 93 93 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 83 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. PAROAlWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 QC Batch: WETA/22256 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92241060006, 92241060007, 92241060008, 92241060009 METHOD BLANK: 1413768 Matrix: Water Associated Lab Samples: 92241060006, 92241060007, 92241060008, 92241060009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.22 0.020 03/18/15 16:20 B LABORATORY CONTROL SAMPLE: 1413769 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1413770 1413771 MS MSD 92239540001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.41 3 3 3.3 3.3 95 95 90-110 0 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1413772 1413773 MS MSD 92239540002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.33 2.9 2.9 3.2 3.2 98 98 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 84 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. P3690orwyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 QC Batch: WETA/22273 Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 92241060006, 92241060007, 92241060008, 92241060009 METHOD BLANK: 1415463 Matrix: Water Associated Lab Samples: 92241060006, 92241060007, 92241060008, 92241060009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 03/19/15 20:57 LABORATORY CONTROL SAMPLE: 1415464 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.4 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415465 1415466 MS MSD 92239540003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 23.9 23.9 24.7 24.6 101 101 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415467 1415468 MS MSD 92239543006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 5.7J 24.7 24.7 31.0 30.7 102 101 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 85 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030308 Pace Project No.: 92241060 Pace Analytical Services, Inc. PARVr6fY�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QC Batch: WETA/44604 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92241060003, 92241060004, 92241060005, 92241060006, 92241060007, 92241060008, 92241060009 METHOD BLANK: 1158273 1158274 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1158276 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.5 03/17/1519:50 Sulfate mg/kg ND 49.5 03/17/1519:50 LABORATORY CONTROL SAMPLE: 1158274 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1158276 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1158275 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 499 489 98 80-120 499 490 98 80-120 92241060003 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 697 689 99 80-120 H3 ND 697 745 93 80-120 H3 92241060003 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 D3,H3 20 D3,H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 86 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030308 Pace Project No.: 92241060 QC Batch: WETA/44698 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92241060002 METHOD BLANK: 1160802 1160803 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1160805 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.6 03/20/15 05:49 Sulfate mg/kg ND 49.6 03/20/15 05:49 LABORATORY CONTROL SAMPLE: 1160803 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1160805 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1160804 Parameter Chloride Sulfate Pace Analytical Services, Inc. P36906rWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 496 468 94 80-120 496 471 95 80-120 92241477010 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers 412 3770 986 15 80-120 M1 1460 3770 2320 23 80-120 M1 92241477010 Dup Units Result Result mg/kg 412 440 mg/kg 1460 1750 Max RPD RPD Qualifiers 7 20 18 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 87 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. Pa89QMr6fy(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 QC Batch: WETA/44603 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92241060003,92241060004,92241060005,92241060006,92241060007,92241060008,92241060009 METHOD BLANK: 1158269 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 03/17/15 19:50 LABORATORY CONTROL SAMPLE: 1158270 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.9 50.9 102 80-120 MATRIX SPIKE SAMPLE: 1158272 92241060003 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 69.7 70.3 101 80-120 H3 SAMPLE DUPLICATE: 1158271 92241060003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 88 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. Padg"lirpyN.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 QC Batch: WETA/44700 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92241060002 METHOD BLANK: 1160812 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 03/20/15 05:49 LABORATORY CONTROL SAMPLE: 1160813 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.6 49.1 99 80-120 MATRIX SPIKE SAMPLE: 1160815 92241477010 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 377 68.7 18 80-120 H3,M1 SAMPLE DUPLICATE: 1160814 92241477010 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 89 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. Padg"rWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030308 Pace Project No.: 92241060 QC Batch: WETA/27642 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92241060002, 92241060003, 92241060004, 92241060005, 92241060006, 92241060007, 92241060008, 92241060009 METHOD BLANK: 1129344 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 03/20/15 07:53 LABORATORY CONTROL SAMPLE: 1129345 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 112000 93 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1129346 1129347 MS MSD 92241060002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 27800 61700 62400 93200 86300 106 94 50-150 8 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 90 of 96 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15030308 Pace Project No.: 92241060 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, Inc. Padg iWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. H6 Analysis initiated outside of the 15 minute EPA recommended holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 91 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. PaWffl�116fyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15030308 92241060 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92241060002 2015006955 EPA 3050 MPRP/23201 EPA 6010 ICP/14202 92241060003 2015006956 EPA 3050 MPRP/23184 EPA 6010 ICP/14189 92241060004 2015006959 EPA 3050 MPRP/23172 EPA 6010 ICP/14182 92241060005 2015006960 EPA 3050 MPRP/23172 EPA 6010 ICP/14182 92241060006 2015006957 EPA 3050 MPRP/23172 EPA6010 ICP/14182 92241060007 2015006958 EPA 3050 MPRP/23172 EPA 6010 ICP/14182 92241060008 2015006961 EPA 3050 MPRP/23172 EPA 6010 ICP/14182 92241060009 2015006962 EPA 3050 MPRP/23172 EPA 6010 ICP/14182 92241060002 2015006955 EPA 3050 MPRP/23202 EPA 6020 ICPM/9455 92241060003 2015006956 EPA 3050 MPRP/23185 EPA 6020 ICPM/9454 92241060004 2015006959 EPA 3050 MPRP/23173 EPA 6020 ICPM/9448 92241060005 2015006960 EPA 3050 MPRP/23173 EPA 6020 ICPM/9448 92241060006 2015006957 EPA 3050 MPRP/23173 EPA 6020 ICPM/9448 92241060007 2015006958 EPA 3050 MPRP/23173 EPA 6020 ICPM/9448 92241060008 2015006961 EPA 3050 MPRP/23173 EPA 6020 ICPM/9448 92241060009 2015006962 EPA 3050 MPRP/23173 EPA 6020 ICPM/9448 92241060001 2015006954 EPA 3020 MPRP/52981 EPA 6020A ICPM/23473 92241060010 2015006957 SPLP EPA 3020 MPRP/53205 EPA 6020A ICPM/23572 92241060011 2015006958 SPLP EPA 3020 MPRP/53205 EPA 6020A ICPM/23572 92241060012 2015006961 SPLP EPA 3020 MPRP/53205 EPA 6020A ICPM/23572 92241060013 2015006962 SPLP EPA 3020 MPRP/53205 EPA 6020A ICPM/23572 92241060001 2015006954 EPA 7470 MERP/12999 EPA 7470 MERC/15078 92241060010 2015006957 SPLP EPA 7470 MERP/13071 EPA 7470 MERC/15183 92241060011 2015006958 SPLP EPA 7470 MERP/13071 EPA 7470 MERC/15183 92241060012 2015006961 SPLP EPA 7470 MERP/13071 EPA 7470 MERC/15183 92241060013 2015006962 SPLP EPA 7470 MERP/13071 EPA 7470 MERC/15183 92241060002 2015006955 EPA 7471 MERP/5502 EPA 7471 MERC/5492 92241060003 2015006956 EPA 7471 MERP/5493 EPA 7471 MERC/5482 92241060004 2015006959 EPA 7471 MERP/5492 EPA 7471 MERC/5481 92241060005 2015006960 EPA 7471 MERP/5492 EPA 7471 MERC/5481 92241060006 2015006957 EPA 7471 MERP/5492 EPA 7471 MERC/5481 92241060007 2015006958 EPA 7471 MERP/5492 EPA 7471 MERC/5481 92241060008 2015006961 EPA 7471 MERP/5493 EPA 7471 MERC/5482 92241060009 2015006962 EPA 7471 MERP/5493 EPA 7471 MERC/5482 92241060002 2015006955 ASTM D2974-87 PMST/3372 92241060003 2015006956 ASTM D2974-87 PMST/3367 92241060004 2015006959 ASTM D2974-87 PMST/3367 92241060005 2015006960 ASTM D2974-87 PMST/3367 92241060006 2015006957 ASTM D2974-87 PMST/3367 92241060007 2015006958 ASTM D2974-87 PMST/3367 92241060008 2015006961 ASTM D2974-87 PMST/3367 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Page 92 of 96 acmnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030308 Pace Project No.: 92241060 Lab ID Sample ID QC Batch Method QC Batch 92241060009 2015006962 ASTM D2974-87 PMST/3367 92241060002 2015006955 EPA 9045 WET/29878 92241060002 2015006955 EPA 9045 WET/36257 92241060003 2015006956 EPA 9045 WET/36257 92241060004 2015006959 EPA 9045 WET/36257 92241060005 2015006960 EPA 9045 WET/36257 92241060006 2015006957 EPA 9045 WET/36257 92241060007 2015006958 EPA 9045 WET/36257 92241060008 2015006961 EPA 9045 WET/36284 92241060009 2015006962 EPA 9045 WET/36284 92241060006 2015006957 EPA 300.0 WETA/22270 92241060007 2015006958 EPA 300.0 WETA/22270 92241060008 2015006961 EPA 300.0 WETA/22270 92241060009 2015006962 EPA 300.0 WETA/22270 92241060006 2015006957 EPA 353.2 WETA/22256 92241060007 2015006958 EPA 353.2 WETA/22256 92241060008 2015006961 EPA 353.2 WETA/22256 92241060009 2015006962 EPA 353.2 WETA/22256 92241060006 2015006957 SM 4500 -CI -E WETA/22273 92241060007 2015006958 SM 4500 -CI -E WETA/22273 92241060008 2015006961 SM 4500 -CI -E WETA/22273 92241060009 2015006962 SM 4500 -CI -E WETA/22273 92241060002 2015006955 EPA 9056 WETA/44698 92241060003 2015006956 EPA 9056 WETA/44604 92241060004 2015006959 EPA 9056 WETA/44604 92241060005 2015006960 EPA 9056 WETA/44604 92241060006 2015006957 EPA 9056 WETA/44604 92241060007 2015006958 EPA 9056 WETA/44604 92241060008 2015006961 EPA 9056 WETA/44604 92241060009 2015006962 EPA 9056 WETA/44604 92241060002 2015006955 EPA 9056 WETA/44700 92241060003 2015006956 EPA 9056 WETA/44603 92241060004 2015006959 EPA 9056 WETA/44603 92241060005 2015006960 EPA 9056 WETA/44603 92241060006 2015006957 EPA 9056 WETA/44603 92241060007 2015006958 EPA 9056 WETA/44603 92241060008 2015006961 EPA 9056 WETA/44603 92241060009 2015006962 EPA 9056 WETA/44603 92241060002 2015006955 EPA 9060 WETA/27642 92241060002 2015006955 EPA 9060 WETA/27643 92241060003 2015006956 EPA 9060 WETA/27642 92241060003 2015006956 EPA 9060 WETA/27643 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/31/2015 05:20 PM without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. Padg"reyol.r. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical Analytical Method Batch Page 93 of 96 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030308 Pace Project No.: 92241060 Lab ID Sample ID QC Batch Method QC Batch 92241060004 2015006959 EPA 9060 WETA/27642 92241060004 2015006959 EPA 9060 WETA/27643 92241060005 2015006960 EPA 9060 WETA/27642 92241060005 2015006960 EPA 9060 WETA/27643 92241060006 2015006957 EPA 9060 WETA/27642 92241060006 2015006957 EPA 9060 WETA/27643 92241060007 2015006958 EPA 9060 WETA/27642 92241060007 2015006958 EPA 9060 WETA/27643 92241060008 2015006961 EPA 9060 WETA/27642 92241060008 2015006961 EPA 9060 WETA/27643 92241060009 2015006962 EPA 9060 WETA/27642 92241060009 2015006962 EPA 9060 WETA/27643 Date: 03/31/2015 05:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. Pa89Qft16fy(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical Method Analytical Batch Page 94 of 96 _ , 2ceArkilytical I5 Document Name: Condition Upon Receil Document Number: F-CHR-CS-003-rev.15 Client Name: ��� f CfV Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑��no mmercial❑ a� Other_ Custody Seal on Cooler/Box Present: El yes Seals intact: ❑ yes Packing Material: ❑ Bubble 1/Dp Bubble Bags ❑ None Other Thermometer Used: IR Gun T 4 Type of Ice-6W ce: W � Blue None Tmmn r`nrraMinn VnMew Anl Nn (:nrrarfinn Document Kevlsea: oepitmwui Page 1 of 2 Issuing AuP190 t 7 of 109 Pace Huntersville Quality Office ❑ no Samples on ice, cooling process has begun �- °C Biological Tissue is Frozen: Yes No Date and Initials,ppf p rson examin{ng r� Corrected Cooler Temp.: contents: Temp should be above freezing to 6°C Comments: Chain of Custody Present: ❑ s ❑ ON /A 1. Chain of Custody Filled Out: es o ❑N/A 2. Chain of Custody Relinquished: es ONN/A 3. Sampler Name & Signature on COC: es ❑ ❑N/A 4. Samples Arrived within Hold Time: s ❑No N/A 5. Short Hold Time Analysis (<72hr): ❑Yes ItKo /A 6. Rush Turn Around Time Requested: ❑Yes oo ❑N/A 7. Sufficient Volume:es No ❑N/A 8. Correct Containers Used: 9le, Uifo /A 9. Ues ❑N/A -Pace Containers Used: Containers Intact: ❑Yes ❑No ❑N/A 10. Filtered volume received for Dissolved tests ❑Yes ❑ o /A 11. Sample Labels match COC: ❑ 4610No ❑N/A 12. -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. Yes ❑ o ❑N/A 13. All containers needing preservation are found to be in YeLJ s E ❑N/A compliance with EPA recommendation. exceptions: VOA, coliform, TOC, 0&G, WI -DRO (water) ❑Yes n 1-11 Samples checked for dechlorination: ❑Yes ❑No 0 /A -1-4. Headspace in VOA Vials (>6mm): ❑Yes ❑No 13< 15. Trip Blank Present: ❑Yes ❑No Z/A 16. Trip Blank Custody Seals Present ❑Yes ❑No Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Field Data Required? Y / N Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: %-lt� Date: 3112-115- SRF Review: I LA I Date: t Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le out of hold, incorrect preservative, out of temp, incorrect containers) 1060W0# w 922 - I U4111101111 92241060 (if no label available) Page 95 of 96 .._ ._. _.. .._ ._. _.. .. .._ ._. _.. Customer must _ .. .._ ._. _.. .._. .._..m..� y 1 8 N 0 ED y 7 ]G as c N 4`z t O z <i11 Customer to complete appropriate columns to right 'O R n a CA �m rn} 3 ' 0 M o _a O D ' ' N 2 s rn p (T - R o v p W a° 3 r �► ty i �, 3 a m z t} 3 = s A -I ro�mr�N�N�a� «nn Vi H N O ^ 01 rW n M c a D U) » w Z 0 OCL A IT C Sg om v o g CN " tr1 v m t a ,aa o (D •• R R a m 41 ED VA1 3 ! i I � y0 ID c 3 w m i a j� �d 0 3 tJ r A S \M CD ''Comp. "A aly3 S o x 18Grab Req ire Total Metals , Anions, pH 1 - 8 oz jar (PACE) 5 TOC 1 - 4 oz jar 4 (PACE) SPLP - Total Metals and Anions 2 - 8 oz jars (PACE) 5 Sediment specific tests 2 - 8 oz jar (ACCESS ANALYTICAL) 5 5 9 08 of 1, z a M Z� M 7C �rn C 7 C. D H Ip I I � Di i to I s N I m d I 3! x 0i n p I + In $WOtj H!;gs.xG1 di 0 'o�e4op0 �!C) aeNz3 ^' 00IZ K z I(j.1�A�O W OID Z iR 4C Q _ l o I° Sam �jz X10 S AT I to 0 'C L '— _._ — V ---I ' q O ' m�1 ,0 D C- .0 C) n m N M r-"��W o !X a I m N w !n O �� i0 00 t !D N iz �v —s - n z iZ :. °o D i D N o d;r U)5! 3 O o!t%i r Df I Cl) oil W j ojp N ZiC 3 c i j1j I�H m w A ? 0 i "t 0 � <; i0 i T I;0 4 � 3 iN�ht I` '°Total # of Containers o Ili d I v a Z x1010 K Page 96 of 96 e 3 wN 0a Z(A c c �J ? C y Q� y a y v o 0 0 to O n V� w T ID Q 3Ll a to D n D n D n rn 0 0- = \! rL f7 pp i Mtn pZ fn n CAI- m < O N V ID o= M (D CL o a W N � ICJ W m v C N � N F' v °a c x � m C C CL .._ ._. _.. .._ ._. _.. .. .._ ._. _.. Customer must _ .. .._ ._. _.. .._. .._..m..� y 1 8 N 0 ED y 7 ]G as c N 4`z t O z <i11 Customer to complete appropriate columns to right 'O R n a CA �m rn} 3 ' 0 M o _a O D ' ' N 2 s rn p (T - R o v p W a° 3 r �► ty i �, 3 a m z t} 3 = s A -I ro�mr�N�N�a� «nn Vi H N O ^ 01 rW n M c a D U) » w Z 0 OCL A IT C Sg om v o g CN " tr1 v m t a ,aa o (D •• R R a m 41 ED VA1 3 ! i I � y0 ID c 3 w m i a j� �d 0 3 tJ r A S \M CD ''Comp. "A aly3 S o x 18Grab Req ire Total Metals , Anions, pH 1 - 8 oz jar (PACE) 5 TOC 1 - 4 oz jar 4 (PACE) SPLP - Total Metals and Anions 2 - 8 oz jars (PACE) 5 Sediment specific tests 2 - 8 oz jar (ACCESS ANALYTICAL) 5 5 9 08 of 1, z a M Z� M 7C �rn C 7 C. D H Ip I I � Di i to I s N I m d I 3! x 0i n p I + In $WOtj H!;gs.xG1 di 0 'o�e4op0 �!C) aeNz3 ^' 00IZ K z I(j.1�A�O W OID Z iR 4C Q _ l o I° Sam �jz X10 S AT I to 0 'C L '— _._ — V ---I ' q O ' m�1 ,0 D C- .0 C) n m N M r-"��W o !X a I m N w !n O �� i0 00 t !D N iz �v —s - n z iZ :. °o D i D N o d;r U)5! 3 O o!t%i r Df I Cl) oil W j ojp N ZiC 3 c i j1j I�H m w A ? 0 i "t 0 � <; i0 i T I;0 4 � 3 iN�ht I` '°Total # of Containers o Ili d I v a Z x1010 K Page 96 of 96 - CHAIN OF GUSTOO Y RECORD AND ANALYSIS REQUEST FORM --- Ana"cal Sarvires i i Analgt-!l Laboratory Use Only ------------ DUKEM41P Cad* MCAMM I lluildbng -1,195p WartyC~ NC -?L I of I I &US Hmg�FOFTV Rd �jI5'0303 wift: SOIL sc-- I DISTRIBUtION Hun0viville, N_C_M7m ! - amrR94"Orl"snoF [L�goWft COO IL Two ORIGINAL CO LAB, ENERGY, IN jmoj a7s-&"s COPY m CLIENT ........ .. z'/j - LUL ; CJ EAhIKF PROfIRAM GrmM Wmm NpnF,, Othikr Floril PACE Z. I 'Collection Informalion N C4 in 0 a- x LU -j I co 4E e -J -u 0 41— REV ELATE 2r9OM96 "u.bc JSML ANN] T3. -'am Ie Descriodon or ID PO 1142-081 2=11 i4e% -3W TS -q L - da -�'Q blqs��- :'2=-- 1 LU v df Proieryatives when v"d mum he CIL N Z L 0 LIN aa(hud with In IS m Invies of sample collectl4m LAMUSE CWLY I mamm 'Collection Informalion N C4 in 0 a- x LU -j I co 4E e -J -u 0 41— %� "u.bc JSML ANN] T3. -'am Ie Descriodon or ID UP P 0 < "k i4e% -3W TS -q L - da -�'Q blqs��- :'2=-- 1 7 2b Lp Meftills: A], Sb, AnlOfil: Cl, Nil 1-09 -5) 311 Aj/d z -'s fps x X EOUIPMENT BLANK (1 PER DAY Z; A -M U s 12 It r Bi*, B, C4 Cs, Cr. CO, Cu. Fe, Pb, Ift Mil, Mo, N1, K, S4, NN. Sr. T1, V. Zn, Mercury, PH 1,804 Sedimimt SpeckHcPma malm, %Sofidis, CIE CPartimells Site Dilatributlan. Redox Polenitial "Roquimled Turnaround 14 m" VA -5T - 48 fV -Add CoM Vff ApW Meftills: A], Sb, AnlOfil: Cl, Nil 1-09 -5) 311 Aj/d z -'s fps x X EOUIPMENT BLANK (1 PER DAY Z; A -M U s 12 It r Bi*, B, C4 Cs, Cr. CO, Cu. Fe, Pb, Ift Mil, Mo, N1, K, S4, NN. Sr. T1, V. Zn, Mercury, PH 1,804 Sedimimt SpeckHcPma malm, %Sofidis, CIE CPartimells Site Dilatributlan. Redox Polenitial "Roquimled Turnaround 14 m" VA -5T - 48 fV -Add CoM Vff ApW