The URL can be used to link to this page

Home My WebLink AboutNC0000396_J15030219 Report_20150823DUE Analytical Laboratory Page 1of62 ' ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report J15030219 AB GW ASSESSMENT SOIL Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker 200 CP and L Drive Arden,NC 28704 Margaret Galvin -Karr Phone: 980-875-5219 (� marge.galvin-karr@duke- U,�� energy.com Date: U 2015.04.21 13:34:38 -04'00' Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 4/21/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time 2015006612 2015006613 2015006614 2015006615 4 Total Samples Collected By Sample Description ASHEVILLE 05 -Mar -15 1:40 PM illegible Equipment Blank ASHEVILLE 05 -Mar -15 2:10 PM illegible MW-16SB (1.5-2) ASHEVILLE 05 -Mar -15 2:20 PM illegible MW 16SB (7-9) ASHEVILLE 05 -Mar -15 2:30 PM illegible MW-16SB (12-13) Page 2 of 62 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: LU Job Summary Report ❑ Sample Identification P/1 Technical Validation of Data Package J❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Page 3 of 62 LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries d❑ Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 4/21/2015 Certificate of Laboratory Analysis Page 4 of 62 This report shall not be reproduced, except in full. Order # J15030219 Site: Equipment Blank Collection Date: 05 -Mar -15 1:40 PM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015006612 Matrix: OTHER Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030219 Site: MW-16SB (1.5-2) Collection Date: 05 -Mar -15 2:10 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 5 of 62 Sample #: 2015006613 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030219 Site: MW 16SB (7-9) Collection Date: 05 -Mar -15 2:20 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 6 of 62 Sample #: 2015006614 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030219 Site: MW-16SB (12-13) Collection Date: 05 -Mar -15 2:30 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 7 of 62 Sample #: 2015006615 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE aceAnaiXical www.pacelabs.com April 08, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15030219 Pace Project No.: 92240314 Pace Analytical Services, Inc. 9P2Q.�C8,8y6e. Suite 100 �Huntersville, INC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on March 09, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy HiQ p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 54 lacmnalyfica( www.pacelabs.com Project: J15030219 Pace Project No.: 92240314 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21 -A Certification #: 2926.01 Alaska Certification #: UST -078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ -0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH -0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH -0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Pace Analytical Services, Inc. G09?I6i§cw6e. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN -002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 54 aceAnaiXical www.pacelabs.com Project: J15030219 Pace Project No.: 92240314 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 0g8pli6'8y6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Page 3 of 54 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15030219 Pace Project No.: 92240314 Lab ID Sample ID Matrix Date Collected Date Received 92240314001 2015006612 Water 03/05/1513:40 03/09/1516:29 92240314002 2015006613 Solid 03/05/1514:10 03/09/1516:29 92240314003 2015006615 Solid 03/05/1514:30 03/09/1516:29 92240314004 2015006614 Solid 03/05/1514:20 03/09/1516:29 92240314005 2015006614 SPLP Water 03/05/15 14:20 03/09/15 16:29 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. �Q�ff�in�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Page 4 of 54 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15030219 92240314 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92240314001 2015006612 EPA 6020A RJS 24 PASI-M EPA 7470 DM 1 PASI-M 92240314002 2015006613 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92240314003 2015006615 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92240314004 2015006614 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E DMN 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92240314005 2015006614 SPLP EPA 6020A TT3 24 PASI-M EPA 7470 DM 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 54 aceAnaiXical www.pacelabs.com Project: J15030219 Pace Project No.: 92240314 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92240314001 2015006612 EPA 6020A Aluminum 682 ug/L 10.0 03/16/15 13:53 EPA 6020A Arsenic 1.5 ug/L 0.50 03/16/15 13:53 EPA 6020A Barium 10.3 ug/L 0.30 03/16/15 13:53 EPA 6020A Calcium 2800 ug/L 40.0 03/16/15 13:53 EPA 6020A Chromium 8.7 ug/L 0.50 03/16/15 13:53 EPA 6020A Cobalt 3.8 ug/L 0.50 03/16/15 13:53 EPA 6020A Copper 8.9 ug/L 1.0 03/16/15 13:53 EPA 6020A Iron 3620 ug/L 50.0 03/16/15 13:53 EPA 6020A Lead 0.82 ug/L 0.10 03/16/15 13:53 EPA 6020A Magnesium 274 ug/L 10.0 03/16/15 13:53 EPA 6020A Manganese 51.6 ug/L 0.50 03/16/15 13:53 EPA 6020A Molybdenum 2.8 ug/L 0.50 03/16/15 13:53 EPA 6020A Nickel 3.6 ug/L 0.50 03/16/15 13:53 EPA 6020A Potassium 389 ug/L 50.0 03/16/15 13:53 EPA 6020A Sodium 177 ug/L 50.0 03/16/15 13:53 EPA 6020A Strontium 5.6 ug/L 0.50 03/16/15 13:53 EPA 6020A Vanadium 1.6 ug/L 1.0 03/16/15 13:53 EPA 6020A Zinc 21.3 ug/L 5.0 03/16/15 13:53 92240314002 2015006613 EPA 6010 Aluminum 6330 mg/kg 7.3 03/17/15 17:48 EPA 6010 Barium 26.4 mg/kg 0.73 03/17/15 17:48 EPA 6010 Beryllium 0.41 mg/kg 0.073 03/17/15 17:48 EPA 6010 Boron 3.9 mg/kg 3.6 03/17/15 17:48 EPA 6010 Calcium 94.0 mg/kg 36.4 03/17/15 17:48 EPA 6010 Chromium 5.3 mg/kg 0.36 03/17/15 17:48 EPA 6010 Copper 2.5 mg/kg 0.36 03/17/15 17:48 EPA 6010 Iron 6590 mg/kg 2.9 03/17/15 17:48 EPA 6010 Magnesium 1310 mg/kg 36.4 03/17/15 17:48 EPA 6010 Manganese 81.2 mg/kg 0.36 03/17/15 17:48 EPA 6010 Nickel 3.4 mg/kg 0.36 03/17/15 17:48 EPA 6010 Potassium 809 mg/kg 72.7 03/17/15 17:48 EPA 6010 Strontium 1.2 mg/kg 0.73 03/17/15 17:48 EPA 6010 Zinc 19.2 mg/kg 1.5 03/17/15 17:48 EPA 6020 Cobalt 2.7 mg/kg 1.5 03/17/15 15:14 D3 EPA 6020 Lead 3.4 mg/kg 1.5 03/17/15 15:14 D3 EPA 6020 Vanadium 11.3 mg/kg 1.5 03/17/15 15:14 D3 EPA 7471 Mercury 0.0089J mg/kg 0.012 03/17/15 11:31 ASTM D2974-87 Percent Moisture 31.2 % 0.10 03/18/15 10:22 EPA 9045 pH at 25 Degrees C 5.7 Std. Units 0.10 03/16/15 20:00 EPA 9060 Total Organic Carbon 4240 mg/kg 867 03/18/15 12:45 EPA 9060 Total Organic Carbon 4020 mg/kg 874 03/18/15 12:50 EPA 9060 Total Organic Carbon 4150 mg/kg 877 03/18/15 12:55 EPA 9060 Total Organic Carbon 4270 mg/kg 868 03/18/15 13:01 EPA 9060 Mean Total Organic Carbon 4170 mg/kg 871 03/18/15 12:45 EPA 9060 RSD% 2.7 % 03/18/15 12:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 6 of 54 aceAnaiXical www.pacelabs.com Project: J15030219 Pace Project No.: 92240314 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. �Q�fflic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92240314003 2015006615 EPA 6010 Aluminum 2130 mg/kg 5.9 03/17/15 17:53 EPA 6010 Barium 5.9 mg/kg 0.59 03/17/15 17:53 EPA 6010 Beryllium 0.25 mg/kg 0.059 03/17/15 17:53 EPA 6010 Boron 2AJ mg/kg 2.9 03/17/1517:53 EPA 6010 Calcium 36.1 mg/kg 29.4 03/17/15 17:53 EPA 6010 Chromium 1.5 mg/kg 0.29 03/17/15 17:53 EPA 6010 Copper 1.0 mg/kg 0.29 03/17/15 17:53 EPA 6010 Iron 3580 mg/kg 2.4 03/17/15 17:53 EPA 6010 Magnesium 191 mg/kg 29.4 03/17/15 17:53 EPA 6010 Manganese 13.4 mg/kg 0.29 03/17/15 17:53 EPA 6010 Nickel 0.65 mg/kg 0.29 03/17/15 17:53 EPA 6010 Potassium 183 mg/kg 58.8 03/17/15 17:53 EPA 6010 Strontium 0.36J mg/kg 0.59 03/17/15 17:53 EPA 6010 Zinc 3.2 mg/kg 1.2 03/17/15 17:53 EPA 6020 Lead 0.97J mg/kg 1.2 03/17/15 15:16 EPA 6020 Vanadium 4.1 mg/kg 1.2 03/17/15 15:16 ASTM D2974-87 Percent Moisture 18.5 % 0.10 03/18/15 10:23 EPA 9045 pH at 25 Degrees C 5.9 Std. Units 0.10 03/16/15 20:00 EPA 9060 Total Organic Carbon 759 mg/kg 734 03/18/15 13:06 EPA 9060 Total Organic Carbon 1010 mg/kg 743 03/18/15 13:11 EPA 9060 Total Organic Carbon 904 mg/kg 735 03/18/15 13:18 EPA 9060 Total Organic Carbon 787 mg/kg 735 03/18/15 13:24 EPA 9060 Mean Total Organic Carbon 865 mg/kg 737 03/18/15 13:06 EPA 9060 RSD% 13.3 % 03/18/15 13:06 92240314004 2015006614 EPA 6010 Aluminum 16000 mg/kg 7.1 03/17/15 17:57 EPA 6010 Barium 62.6 mg/kg 0.71 03/17/15 17:57 EPA 6010 Beryllium 1.2 mg/kg 0.35 03/18/15 09:00 EPA 6010 Calcium 241 mg/kg 35.3 03/17/15 17:57 EPA 6010 Chromium 15.5 mg/kg 1.8 03/18/15 09:00 EPA 6010 Copper 8.4 mg/kg 1.8 03/18/15 09:00 EPA 6010 Iron 14900 mg/kg 2.8 03/17/15 17:57 EPA 6010 Magnesium 2600 mg/kg 35.3 03/17/15 17:57 EPA 6010 Manganese 151 mg/kg 1.8 03/18/15 09:00 EPA 6010 Nickel 6.5 mg/kg 0.35 03/17/15 17:57 EPA 6010 Potassium 1500 mg/kg 70.6 03/17/15 17:57 EPA 6010 Strontium 3.0 mg/kg 0.71 03/17/15 17:57 EPA 6010 Zinc 36.2 mg/kg 1.4 03/17/15 17:57 EPA 6020 Arsenic 1.5 mg/kg 1.4 03/17/15 15:19 EPA 6020 Cobalt 5.4 mg/kg 1.4 03/17/15 15:19 EPA 6020 Lead 9.6 mg/kg 1.4 03/17/15 15:19 EPA 6020 Selenium 1.5 mg/kg 1.4 03/17/15 15:19 EPA 6020 Vanadium 31.1 mg/kg 1.4 03/17/15 15:19 EPA 7471 Mercury 0.031 mg/kg 0.012 03/17/15 11:35 ASTM D2974-87 Percent Moisture 30.4 % 0.10 03/18/15 10:23 EPA 9045 pH at 25 Degrees C 5.1 Std. Units 0.10 03/16/15 20:00 EPA 300.0 Sulfate 6.9 mg/L 2.9 03/19/15 23:48 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. D3 D3 D3 D3 D3 D3 Qualifiers Page 7 of 54 aceAnaiXical www.pacelabs.com Project: J15030219 Pace Project No.: 92240314 Lab Sample ID Method Client Sample ID Parameters 92240314004 2015006614 EPA 353.2 Nitrogen, Nitrate EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Mean Total Organic Carbon EPA 9060 RSD% 92240314005 2015006614 SPLP EPA 6020A Aluminum EPA 6020A Barium EPA 6020A Boron EPA 6020A Calcium EPA 6020A Chromium EPA 6020A Cobalt EPA 6020A Copper EPA 6020A Iron EPA 6020A Lead EPA 6020A Magnesium EPA 6020A Manganese EPA 6020A Nickel EPA 6020A Potassium EPA 6020A Sodium EPA 6020A Strontium EPA 6020A Vanadium Pace Analytical Services, Inc. �Q�ffii�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 0.42 mg/L 0.29 03/18/1516:54 H1 3810 mg/kg 862 03/18/1513:30 3810 mg/kg 866 03/18/1513:36 4010 mg/kg 860 03/18/1513:42 3840 mg/kg 867 03/18/1513:47 3870 mg/kg 864 03/18/1513:30 2.5 % 03/18/1513:30 4580 ug/L 10.0 03/27/1514:37 18.5 ug/L 0.30 03/27/1514:37 20.4 ug/L 5.0 03/27/1514:37 1910 ug/L 40.0 03/27/1514:37 2.5 ug/L 0.50 03/27/1514:37 0.74 ug/L 0.50 03/27/1514:37 9.1 ug/L 1.0 03/27/1514:37 1890 ug/L 50.0 03/27/1514:37 1.0 ug/L 0.10 03/27/1514:37 621 ug/L 10.0 03/27/1514:37 113 ug/L 0.50 03/27/1514:37 1.2 ug/L 0.50 03/27/1514:37 509 ug/L 50.0 03/27/1514:37 2950 ug/L 50.0 03/27/1514:37 10 ug/L 0.50 03/27/1514:37 3.9 ug/L 1.0 03/27/1514:37 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&)e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 08, 2015 General Information: 3 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23101 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92240320001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1157390) • Aluminum • Barium • Boron • Iron • Manganese • Molybdenum • MSD (Lab ID: 1157391) • Aluminum • Boron • Iron • Manganese • Molybdenum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�fflic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 08, 2015 Analyte Comments: QC Batch: MPRP/23101 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006614 (Lab ID: 92240314004) • Boron • Beryllium • Chromium • Copper • Manganese E: Analyte concentration exceeded the calibration range. The reported result is estimated. • MS (Lab ID: 1157390) • Manganese • MSD (Lab ID: 1157391) • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffligc&)e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 08, 2015 General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23102 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92240320001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1157396) • Antimony • Arsenic • Vanadium • MSD (Lab ID: 1157397) • Antimony • Arsenic • Selenium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 08, 2015 Analyte Comments: QC Batch: MPRP/23102 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006613 (Lab ID: 92240314002) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015006615 (Lab ID:92240314003) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • MS (Lab ID: 1157396) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • MSD (Lab ID: 1157397) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium D4: Sample was diluted due to the presence of high levels of target analytes. • MS (Lab ID: 1157396) • Vanadium • MSD (Lab ID: 1157397) • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •2015006613 (Lab ID: 92240314002) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 i�v6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 08, 2015 Analyte Comments: QC Batch: MPRP/23102 N2: The lab does not hold TNI accreditation for this parameter. •2015006614 (Lab ID: 92240314004) • Antimony •2015006615 (Lab ID: 92240314003) • Antimony • BLANK (Lab ID: 1157394) • Antimony • LCS (Lab ID: 1157395) • Antimony • MS (Lab ID: 1157396) • Antimony • MSD (Lab ID: 1157397) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKiniv6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: April 08, 2015 General Information: 2 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/52947 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92240314001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1918581) • Aluminum • MSD (Lab ID: 1918582) • Aluminum QC Batch: MPRP/53205 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242374012 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1926431) • Aluminum • MSD (Lab ID: 1926432) • Aluminum • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKiQv6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: April 08, 2015 QC Batch: MPRP/53205 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242374012 R1: RPD value was outside control limits. • MSD (Lab ID: 1926432) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKiny6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: April 08, 2015 General Information: 2 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/13071 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242374012 R1: RPD value was outside control limits. • MSD (Lab ID: 1926033) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: April 08, 2015 General Information: 3 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 i�v6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: April 08, 2015 General Information: 3 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K�i�v6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: April 08, 2015 General Information: 1 sample was analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098v i�v6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: April 08, 2015 General Information: 1 sample was analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015006614 (Lab ID: 92240314004) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 igv6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: SM 4500 -CI -E Description: 4500 Chloride, SPLP Client: Duke Energy Date: April 08, 2015 General Information: 1 sample was analyzed for SM 4500 -CI -E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 i�v6e. Suite 100 �J Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: April 08, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44517 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006613 (Lab ID:92240314002) • Chloride • Sulfate •2015006614 (Lab ID:92240314004) • Chloride • Sulfate •2015006615 (Lab ID:92240314003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098niny6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: April 08, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015006613 (Lab ID: 92240314002) •2015006614 (Lab ID: 92240314004) •2015006615 (Lab ID: 92240314003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44516 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006613 (Lab ID: 92240314002) • Nitrate as N •2015006614 (Lab ID: 92240314004) • Nitrate as N •2015006615 (Lab ID: 92240314003) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninlv6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030219 Pace Project No.: 92240314 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: April 08, 2015 General Information: 3 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 54 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030219 Pace Project No.: 92240314 Pace Analytical Services, Inc. 098niny6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015006612 Lab ID: 92240314001 Collected: 03/05/15 13:40 Received: 03/09/15 16:29 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/08/2015 11:52 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 682 ug/L 10.0 1.2 1 03/15/1512:45 03/16/1513:53 7429-90-5 ND ug/L 0.50 0.25 1 03/15/1512:45 03/16/1513:53 7440-36-0 1.5 ug/L 0.50 0.25 1 03/15/1512:45 03/16/1513:53 7440-38-2 10.3 ug/L 0.30 0.14 1 03/15/1512:45 03/16/1513:53 7440-39-3 ND ug/L 0.20 0.066 1 03/15/1512:45 03/16/1513:53 7440-41-7 ND ug/L 5.0 1.0 1 03/15/1512:45 03/16/1513:53 7440-42-8 ND ug/L 0.080 0.033 1 03/15/1512:45 03/16/1513:53 7440-43-9 2800 ug/L 40.0 8.4 1 03/15/1512:45 03/16/1513:53 7440-70-2 8.7 ug/L 0.50 0.22 1 03/15/1512:45 03/16/1513:53 7440-47-3 3.8 ug/L 0.50 0.25 1 03/15/1512:45 03/16/1513:53 7440-48-4 8.9 ug/L 1.0 0.22 1 03/15/1512:45 03/16/1513:53 7440-50-8 3620 ug/L 50.0 8.0 1 03/15/1512:45 03/16/1513:53 7439-89-6 0.82 ug/L 0.10 0.046 1 03/15/1512:45 03/16/1513:53 7439-92-1 274 ug/L 10.0 2.8 1 03/15/1512:45 03/16/1513:53 7439-95-4 51.6 ug/L 0.50 0.14 1 03/15/1512:45 03/16/1513:53 7439-96-5 2.8 ug/L 0.50 0.24 1 03/15/1512:45 03/16/1513:53 7439-98-7 3.6 ug/L 0.50 0.23 1 03/15/1512:45 03/16/1513:53 7440-02-0 389 ug/L 50.0 8.3 1 03/15/1512:45 03/16/1513:53 7440-09-7 ND ug/L 0.50 0.25 1 03/15/1512:45 03/16/1513:53 7782-49-2 177 ug/L 50.0 18.2 1 03/15/1512:45 03/16/1513:53 7440-23-5 5.6 ug/L 0.50 0.057 1 03/15/1512:45 03/16/1513:53 7440-24-6 ND ug/L 0.10 0.025 1 03/15/1512:45 03/16/1513:53 7440-28-0 1.6 ug/L 1.0 0.21 1 03/15/1512:45 03/16/1513:53 7440-62-2 21.3 ug/L 5.0 2.5 1 03/15/1512:45 03/16/1513:53 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.026 1 03/12/1511:18 03/12/1515:04 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 54 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 098niny6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 Sample: 2015006613 Lab ID: 92240314002 Collected: 03/05/15 14:10 Received: 03/09/15 16:29 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 6330 mg/kg 7.3 3.6 1 03/17/15 05:50 03/17/15 17:48 7429-90-5 Barium 26.4 mg/kg 0.73 0.36 1 03/17/15 05:50 03/17/15 17:48 7440-39-3 Beryllium 0.41 mg/kg 0.073 0.036 1 03/17/15 05:50 03/17/15 17:48 7440-41-7 Boron 3.9 mg/kg 3.6 1.8 1 03/17/15 05:50 03/17/15 17:48 7440-42-8 Calcium 94.0 mg/kg 36.4 18.2 1 03/17/15 05:50 03/17/15 17:48 7440-70-2 Chromium 5.3 mg/kg 0.36 0.18 1 03/17/15 05:50 03/17/15 17:48 7440-47-3 Copper 2.5 mg/kg 0.36 0.18 1 03/17/15 05:50 03/17/15 17:48 7440-50-8 Iron 6590 mg/kg 2.9 1.5 1 03/17/15 05:50 03/17/15 17:48 7439-89-6 Magnesium 1310 mg/kg 36.4 18.2 1 03/17/15 05:50 03/17/15 17:48 7439-95-4 Manganese 81.2 mg/kg 0.36 0.18 1 03/17/15 05:50 03/17/15 17:48 7439-96-5 Molybdenum ND mg/kg 0.73 0.36 1 03/17/15 05:50 03/17/15 17:48 7439-98-7 Nickel 3.4 mg/kg 0.36 0.18 1 03/17/15 05:50 03/17/15 17:48 7440-02-0 Potassium 809 mg/kg 72.7 36.4 1 03/17/15 05:50 03/17/15 17:48 7440-09-7 Sodium ND mg/kg 72.7 36.4 1 03/17/15 05:50 03/17/15 17:48 7440-23-5 Strontium 1.2 mg/kg 0.73 0.36 1 03/17/15 05:50 03/17/15 17:48 7440-24-6 Zinc 19.2 mg/kg 1.5 0.73 1 03/17/15 05:50 03/17/15 17:48 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.5 0.73 20 03/17/15 05:50 03/17/15 15:14 7440-36-0 D3,N2 Arsenic ND mg/kg 1.5 0.73 20 03/17/15 05:50 03/17/15 15:14 7440-38-2 D3 Cadmium ND mg/kg 0.17 0.087 20 03/17/15 05:50 03/17/15 15:14 7440-43-9 D3 Cobalt 2.7 mg/kg 1.5 0.73 20 03/17/15 05:50 03/17/15 15:14 7440-48-4 D3 Lead 3.4 mg/kg 1.5 0.73 20 03/17/15 05:50 03/17/15 15:14 7439-92-1 D3 Selenium ND mg/kg 1.5 0.73 20 03/17/15 05:50 03/17/15 15:14 7782-49-2 D3 Thallium ND mg/kg 1.5 0.73 20 03/17/15 05:50 03/17/15 15:14 7440-28-0 D3 Vanadium 11.3 mg/kg 1.5 0.73 20 03/17/15 05:50 03/17/15 15:14 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.0089J mg/kg 0.012 0.0060 1 03/17/15 06:13 03/17/15 11:31 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 31.2 % 0.10 0.10 1 03/18/15 10:22 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.7 Std. Units 0.10 0.10 1 03/16/15 20:00 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 358 179 5 03/14/15 09:51 16887-00-6 D3 Sulfate ND mg/kg 358 179 5 03/14/15 09:51 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 35.8 17.9 5 03/14/15 09:51 14797-55-8 D3,H3 Date: 04/08/2015 11:52 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 54 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030219 Pace Project No.: 92240314 Pace Analytical Services, Inc. 09Q�K�i�v6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015006613 Lab ID: 92240314002 Collected: 03/05/15 14:10 Received: 03/09/15 16:29 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 4240 mg/kg 867 433 1 03/18/15 12:45 7440-44-0 Total Organic Carbon 4020 mg/kg 874 437 1 03/18/15 12:50 7440-44-0 Total Organic Carbon 4150 mg/kg 877 438 1 03/18/15 12:55 7440-44-0 Total Organic Carbon 4270 mg/kg 868 434 1 03/18/15 13:01 7440-44-0 Mean Total Organic Carbon 4170 mg/kg 871 436 1 03/18/15 12:45 7440-44-0 Surrogates RSD% 2.7 % 1 03/18/1512:45 Date: 04/08/2015 11:52 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 54 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 098niny6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 Sample: 2015006615 Lab ID: 92240314003 Collected: 03/05/15 14:30 Received: 03/09/15 16:29 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 2130 mg/kg 5.9 2.9 1 03/17/15 05:50 03/17/15 17:53 7429-90-5 Barium 5.9 mg/kg 0.59 0.29 1 03/17/15 05:50 03/17/15 17:53 7440-39-3 Beryllium 0.25 mg/kg 0.059 0.029 1 03/17/15 05:50 03/17/15 17:53 7440-41-7 Boron 2.1J mg/kg 2.9 1.5 1 03/17/15 05:50 03/17/15 17:53 7440-42-8 Calcium 36.1 mg/kg 29.4 14.7 1 03/17/15 05:50 03/17/15 17:53 7440-70-2 Chromium 1.5 mg/kg 0.29 0.15 1 03/17/15 05:50 03/17/15 17:53 7440-47-3 Copper 1.0 mg/kg 0.29 0.15 1 03/17/15 05:50 03/17/15 17:53 7440-50-8 Iron 3580 mg/kg 2.4 1.2 1 03/17/15 05:50 03/17/15 17:53 7439-89-6 Magnesium 191 mg/kg 29.4 14.7 1 03/17/15 05:50 03/17/15 17:53 7439-95-4 Manganese 13.4 mg/kg 0.29 0.15 1 03/17/15 05:50 03/17/15 17:53 7439-96-5 Molybdenum ND mg/kg 0.59 0.29 1 03/17/15 05:50 03/17/15 17:53 7439-98-7 Nickel 0.65 mg/kg 0.29 0.15 1 03/17/15 05:50 03/17/15 17:53 7440-02-0 Potassium 183 mg/kg 58.8 29.4 1 03/17/15 05:50 03/17/15 17:53 7440-09-7 Sodium ND mg/kg 58.8 29.4 1 03/17/15 05:50 03/17/15 17:53 7440-23-5 Strontium 0.36J mg/kg 0.59 0.29 1 03/17/15 05:50 03/17/15 17:53 7440-24-6 Zinc 3.2 mg/kg 1.2 0.59 1 03/17/15 05:50 03/17/15 17:53 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.2 0.59 20 03/17/15 05:50 03/17/15 15:16 7440-36-0 D3,N2 Arsenic ND mg/kg 1.2 0.59 20 03/17/15 05:50 03/17/15 15:16 7440-38-2 D3 Cadmium ND mg/kg 0.14 0.071 20 03/17/15 05:50 03/17/15 15:16 7440-43-9 D3 Cobalt ND mg/kg 1.2 0.59 20 03/17/15 05:50 03/17/15 15:16 7440-48-4 D3 Lead 0.97J mg/kg 1.2 0.59 20 03/17/15 05:50 03/17/15 15:16 7439-92-1 D3 Selenium ND mg/kg 1.2 0.59 20 03/17/15 05:50 03/17/15 15:16 7782-49-2 D3 Thallium ND mg/kg 1.2 0.59 20 03/17/15 05:50 03/17/15 15:16 7440-28-0 D3 Vanadium 4.1 mg/kg 1.2 0.59 20 03/17/15 05:50 03/17/15 15:16 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0097 0.0049 1 03/17/15 06:13 03/17/15 11:33 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 18.5 % 0.10 0.10 1 03/18/15 10:23 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.9 Std. Units 0.10 0.10 1 03/16/15 20:00 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 311 155 5 03/14/1510:13 16887-00-6 D3 Sulfate ND mg/kg 311 155 5 03/14/1510:13 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.1 15.5 5 03/14/15 10:13 14797-55-8 D3,H3 Date: 04/08/2015 11:52 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 54 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030219 Pace Project No.: 92240314 Pace Analytical Services, Inc. 098niny6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015006615 Lab ID: 92240314003 Collected: 03/05/15 14:30 Received: 03/09/15 16:29 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 759 mg/kg 734 367 1 03/18/15 13:06 7440-44-0 Total Organic Carbon 1010 mg/kg 743 371 1 03/18/15 13:11 7440-44-0 Total Organic Carbon 904 mg/kg 735 368 1 03/18/15 13:18 7440-44-0 Total Organic Carbon 787 mg/kg 735 368 1 03/18/15 13:24 7440-44-0 Mean Total Organic Carbon 865 mg/kg 737 368 1 03/18/15 13:06 7440-44-0 Surrogates RSD% 13.3 % 1 03/18/1513:06 Date: 04/08/2015 11:52 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 54 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 098v i�v6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 Sample: 2015006614 Lab ID: 92240314004 Collected: 03/05/15 14:20 Received: 03/09/15 16:29 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 16000 mg/kg 7.1 3.5 1 03/17/15 05:50 03/17/15 17:57 7429-90-5 Barium 62.6 mg/kg 0.71 0.35 1 03/17/15 05:50 03/17/15 17:57 7440-39-3 Beryllium 1.2 mg/kg 0.35 0.18 5 03/17/15 05:50 03/18/15 09:00 7440-41-7 D3 Boron ND mg/kg 17.7 8.8 5 03/17/15 05:50 03/18/15 09:00 7440-42-8 D3 Calcium 241 mg/kg 35.3 17.7 1 03/17/15 05:50 03/17/15 17:57 7440-70-2 Chromium 15.5 mg/kg 1.8 0.88 5 03/17/15 05:50 03/18/15 09:00 7440-47-3 D3 Copper 8.4 mg/kg 1.8 0.88 5 03/17/15 05:50 03/18/15 09:00 7440-50-8 D3 Iron 14900 mg/kg 2.8 1.4 1 03/17/15 05:50 03/17/15 17:57 7439-89-6 Magnesium 2600 mg/kg 35.3 17.7 1 03/17/15 05:50 03/17/15 17:57 7439-95-4 Manganese 151 mg/kg 1.8 0.88 5 03/17/15 05:50 03/18/15 09:00 7439-96-5 D3 Molybdenum ND mg/kg 0.71 0.35 1 03/17/15 05:50 03/17/15 17:57 7439-98-7 Nickel 6.5 mg/kg 0.35 0.18 1 03/17/15 05:50 03/17/15 17:57 7440-02-0 Potassium 1500 mg/kg 70.6 35.3 1 03/17/15 05:50 03/17/15 17:57 7440-09-7 Sodium ND mg/kg 70.6 35.3 1 03/17/15 05:50 03/17/15 17:57 7440-23-5 Strontium 3.0 mg/kg 0.71 0.35 1 03/17/15 05:50 03/17/15 17:57 7440-24-6 Zinc 36.2 mg/kg 1.4 0.71 1 03/17/15 05:50 03/17/15 17:57 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.4 0.71 20 03/17/15 05:50 03/17/15 15:19 7440-36-0 N2 Arsenic 1.5 mg/kg 1.4 0.71 20 03/17/15 05:50 03/17/15 15:19 7440-38-2 Cadmium ND mg/kg 0.17 0.085 20 03/17/15 05:50 03/17/15 15:19 7440-43-9 Cobalt 5.4 mg/kg 1.4 0.71 20 03/17/15 05:50 03/17/15 15:19 7440-48-4 Lead 9.6 mg/kg 1.4 0.71 20 03/17/15 05:50 03/17/15 15:19 7439-92-1 Selenium 1.5 mg/kg 1.4 0.71 20 03/17/15 05:50 03/17/15 15:19 7782-49-2 Thallium ND mg/kg 1.4 0.71 20 03/17/15 05:50 03/17/15 15:19 7440-28-0 Vanadium 31.1 mg/kg 1.4 0.71 20 03/17/15 05:50 03/17/15 15:19 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.031 mg/kg 0.012 0.0058 1 03/17/15 06:13 03/17/15 11:35 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 30.4 % 0.10 0.10 1 03/18/15 10:23 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.1 Std. Units 0.10 0.10 1 03/16/15 20:00 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Sulfate 6.9 mg/L 2.9 1.4 1 03/19/15 23:48 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Nitrogen, Nitrate 0.42 mg/L 0.29 0.29 1 03/18/15 16:54 H1 4500 Chloride, SPLP Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 03/16/15 14:15 Chloride ND mg/L 7.2 3.6 1 03/19/15 21:14 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 30 of 54 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 098niny6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 Sample: 2015006614 Lab ID: 92240314004 Collected: 03/05/15 14:20 Received: 03/09/15 16:29 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 354 177 5 03/14/1510:34 16887-00-6 D3 Sulfate ND mg/kg 354 177 5 03/14/1510:34 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 35.4 17.7 5 03/14/15 10:34 14797-55-8 D3,1-13 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 3810 mg/kg 862 431 1 03/18/15 13:30 7440-44-0 Total Organic Carbon 3810 mg/kg 866 433 1 03/18/15 13:36 7440-44-0 Total Organic Carbon 4010 mg/kg 860 430 1 03/18/15 13:42 7440-44-0 Total Organic Carbon 3840 mg/kg 867 433 1 03/18/15 13:47 7440-44-0 Mean Total Organic Carbon 3870 mg/kg 864 432 1 03/18/15 13:30 7440-44-0 Surrogates RSD% 2.5 % 1 03/18/1513:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 54 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030219 Pace Project No.: 92240314 Pace Analytical Services, Inc. 098niny6e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015006614 SPLP Lab ID: 92240314005 Collected: 03/05/15 14:20 Received: 03/09/15 16:29 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/08/2015 11:52 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 4580 ug/L 10.0 1.2 1 03/26/1519:01 03/27/1514:37 7429-90-5 ND ug/L 0.50 0.25 1 03/26/1519:01 03/27/1514:37 7440-36-0 ND ug/L 0.50 0.25 1 03/26/1519:01 03/27/1514:37 7440-38-2 18.5 ug/L 0.30 0.14 1 03/26/1519:01 03/27/1514:37 7440-39-3 ND ug/L 0.20 0.066 1 03/26/1519:01 03/27/1514:37 7440-41-7 20.4 ug/L 5.0 1.0 1 03/26/1519:01 03/27/1514:37 7440-42-8 ND ug/L 0.080 0.033 1 03/26/1519:01 03/27/1514:37 7440-43-9 1910 ug/L 40.0 8.4 1 03/26/1519:01 03/27/1514:37 7440-70-2 2.5 ug/L 0.50 0.22 1 03/26/1519:01 03/27/1514:37 7440-47-3 0.74 ug/L 0.50 0.25 1 03/26/1519:01 03/27/1514:37 7440-48-4 9.1 ug/L 1.0 0.22 1 03/26/1519:01 03/27/1514:37 7440-50-8 1890 ug/L 50.0 8.0 1 03/26/1519:01 03/27/1514:37 7439-89-6 1.0 ug/L 0.10 0.046 1 03/26/1519:01 03/27/1514:37 7439-92-1 621 ug/L 10.0 2.8 1 03/26/1519:01 03/27/1514:37 7439-95-4 113 ug/L 0.50 0.14 1 03/26/1519:01 03/27/1514:37 7439-96-5 ND ug/L 0.50 0.24 1 03/26/1519:01 03/27/1514:37 7439-98-7 1.2 ug/L 0.50 0.23 1 03/26/1519:01 03/27/1514:37 7440-02-0 509 ug/L 50.0 8.3 1 03/26/1519:01 03/27/1514:37 7440-09-7 ND ug/L 0.50 0.25 1 03/26/1519:01 03/27/1514:37 7782-49-2 2950 ug/L 50.0 18.2 1 03/26/1519:01 03/27/1514:37 7440-23-5 10 ug/L 0.50 0.057 1 03/26/1519:01 03/27/1514:37 7440-24-6 ND ug/L 0.10 0.025 1 03/26/1519:01 03/27/1514:37 7440-28-0 3.9 ug/L 1.0 0.21 1 03/26/1519:01 03/27/1514:37 7440-62-2 ND ug/L 5.0 2.5 1 03/26/1519:01 03/27/1514:37 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.026 1 03/26/1519:10 03/27/1513:07 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098gwinyloe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 QC Batch: MERP/12953 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92240314001 METHOD BLANK: 1916588 Matrix: Water Associated Lab Samples: 92240314001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/12/1514:47 LABORATORY CONTROL SAMPLE: 1916589 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.9 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1916590 1916591 MS MSD 92239540010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.9 4.8 98 95 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 33 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098gwinvloe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 QC Batch: MERP/13071 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92240314005 METHOD BLANK: 1926030 Matrix: Water Associated Lab Samples: 92240314005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/27/1512:24 LABORATORY CONTROL SAMPLE: 1926031 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.9 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1926032 1926033 MS MSD 92242374012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.2 5.1 83 102 75-125 21 20 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098gwinyloe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 QC Batch: MERP/5472 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92240314002, 92240314003, 92240314004 METHOD BLANK: 1157570 Matrix: Solid Associated Lab Samples: 92240314002, 92240314003, 92240314004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0083 03/17/1511:03 LABORATORY CONTROL SAMPLE: 1157571 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .083 0.083 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1157572 1157573 MS MSD 92240314004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.031 .112 .112 0.15 0.14 106 99 80-120 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 35 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030219 Pace Project No.: 92240314 QC Batch: MPRP/23101 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92240314002, 92240314003, 92240314004 METHOD BLANK: 1157388 Matrix: Associated Lab Samples: 92240314002, 92240314003, 92240314004 Blank Parameter Units Result Solid Reporting Limit Analyzed Aluminum mg/kg ND 5.2 03/17/1516:41 Barium mg/kg ND 0.52 03/17/1516:41 Beryllium mg/kg ND 0.052 03/17/1516:41 Boron mg/kg ND 2.6 03/17/1516:41 Calcium mg/kg ND 26.0 03/17/1516:41 Chromium mg/kg ND 0.26 03/17/1516:41 Copper mg/kg ND 0.26 03/17/1516:41 Iron mg/kg ND 2.1 03/17/1516:41 Magnesium mg/kg ND 26.0 03/17/1516:41 Manganese mg/kg ND 0.26 03/17/1516:41 Molybdenum mg/kg ND 0.52 03/17/1516:41 Nickel mg/kg ND 0.26 03/17/1516:41 Potassium mg/kg ND 52.0 03/17/1516:41 Sodium mg/kg ND 52.0 03/17/1516:41 Strontium mg/kg ND 0.52 03/17/1516:41 Zinc mg/kg ND 1.0 03/17/1516:41 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1157389 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 129 130 101 80-120 Barium mg/kg 12.9 13.6 105 80-120 Beryllium mg/kg 1.3 1.3 102 80-120 Boron mg/kg 129 131 102 80-120 Calcium mg/kg 645 657 102 80-120 Chromium mg/kg 12.9 13.1 102 80-120 Copper mg/kg 12.9 13.1 101 80-120 Iron mg/kg 129 124 96 80-120 Magnesium mg/kg 645 641 99 80-120 Manganese mg/kg 12.9 13.1 102 80-120 Molybdenum mg/kg 12.9 12.9 100 80-120 Nickel mg/kg 12.9 13.2 102 80-120 Potassium mg/kg 645 636 99 80-120 Sodium mg/kg 645 670 104 80-120 Strontium mg/kg 12.9 13.1 102 80-120 Zinc mg/kg 64.5 66.5 103 80-120 Pace Analytical Services, Inc. 098gwinyloe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 36 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 0988 i vloe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1157390 1157391 MS MSD 92240320001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 8460 156 163 9710 9550 805 661 75-125 2 20 M1 Barium mg/kg 54.2 15.6 16.3 75.1 72.9 135 114 75-125 3 20 M1 Beryllium mg/kg 0.43 1.56 1.68 1.6 1.7 75 76 75-125 4 20 Boron mg/kg 9.0 156 163 113 120 67 68 75-125 6 20 M1 Calcium mg/kg 647 775 819 1310 1330 85 83 75-125 1 20 Chromium mg/kg 10.6 15.6 16.3 22.7 23.8 78 81 75-125 5 20 Copper mg/kg 9.9 15.6 16.3 21.8 22.6 77 77 75-125 3 20 Iron mg/kg 13200 156 163 12800 12300 -253 -504 75-125 3 20 M1 Magnesium mg/kg 1760 775 819 2390 2400 82 78 75-125 0 20 Manganese mg/kg 1320 15.6 16.3 832 812 -3180 -3130 75-125 2 20 E,M1 Molybdenum mg/kg ND 15.6 16.3 10.5 10.6 68 64 75-125 1 20 M1 Nickel mg/kg 5.1 15.6 16.3 18.5 19.2 86 86 75-125 4 20 Potassium mg/kg 124 775 819 794 831 87 86 75-125 5 20 Sodium mg/kg ND 775 819 739 771 91 90 75-125 4 20 Strontium mg/kg 8.3 15.6 16.3 23.2 23.5 96 93 75-125 1 20 Zinc mg/kg 21.8 77.5 81.9 88.5 92.7 86 86 75-125 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 37 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030219 Pace Project No.: 92240314 QC Batch: MPRP/23102 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92240314002, 92240314003, 92240314004 METHOD BLANK: 1157394 Matrix: Solid LCS Result Associated Lab Samples: 92240314002, 92240314003, 92240314004 mg/kg 2.6 2.6 99 Blank Reporting mg/kg Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.052 03/17/1516:09 N2 Arsenic mg/kg ND 0.052 03/17/1516:09 Cadmium mg/kg ND 0.0062 03/17/1516:09 Cobalt mg/kg ND 0.052 03/17/1516:09 Lead mg/kg ND 0.052 03/17/1516:09 Selenium mg/kg ND 0.052 03/17/1516:09 Thallium mg/kg ND 0.052 03/17/1516:09 Vanadium mg/kg ND 0.052 03/17/1516:09 Pace Analytical Services, Inc. 098gwinyloe. Suite 100 y Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1157395 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.6 2.6 99 80-120 N2 Arsenic mg/kg 2.6 2.7 105 80-120 Cadmium mg/kg .26 0.26 100 80-120 Cobalt mg/kg 2.6 2.7 105 80-120 Lead mg/kg 2.6 2.6 102 80-120 Selenium mg/kg 2.6 2.8 107 80-120 Thallium mg/kg 2.6 2.6 102 80-120 Vanadium mg/kg 2.6 2.7 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1157396 MS 92240320001 Spike Parameter Units Result Conc. MSD Spike Conc. 1157397 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Antimony mg/kg ND 3.11 3.37 1.8 1.8 56 54 75-125 4 20 D3,M6, N2 Arsenic mg/kg 1.5 3.11 3.37 3.7 3.9 74 74 75-125 5 20 D3,M6 Cadmium mg/kg ND .311 .337 0.30 0.36 88 97 75-125 16 20 D3 Cobalt mg/kg 9.2 3.11 3.37 11.9 11.8 85 76 75-125 1 20 D3 Lead mg/kg 7.9 3.11 3.37 10.6 10.8 89 88 75-125 2 20 D3 Selenium mg/kg 1.2J 3.11 3.37 3.6 3.6 79 72 75-125 1 20 D3,M6 Thallium mg/kg ND 3.11 3.37 3.2 3.4 98 96 75-125 6 20 D3 Vanadium mg/kg 39.6 3.11 3.37 38.7 40.6 -31 28 75-125 5 20 D4,M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 38 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030219 Pace Project No.: 92240314 QC Batch: MPRP/52947 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92240314001 METHOD BLANK: 1917891 Associated Lab Samples: 92240314001 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 03/16/1513:08 ND 0.50 03/16/1513:08 ND 0.50 03/16/1513:08 ND 0.30 03/16/1513:08 ND 0.20 03/16/1513:08 ND 5.0 03/16/1513:08 ND 0.080 03/16/1513:08 ND 40.0 03/16/1513:08 ND 0.50 03/16/1513:08 ND 0.50 03/16/1513:08 ND 1.0 03/16/1513:08 ND 50.0 03/16/1513:08 ND 0.10 03/16/1513:08 ND 10.0 03/16/1513:08 ND 0.50 03/16/1513:08 ND 0.50 03/16/1513:08 ND 0.50 03/16/1513:08 ND 50.0 03/16/1513:08 ND 0.50 03/16/1513:08 ND 50.0 03/16/1513:08 ND 0.50 03/16/1513:08 ND 0.10 03/16/1513:08 ND 1.0 03/16/1513:08 ND 5.0 03/16/1513:08 Qualifiers Pace Analytical Services, Inc. 098gwinyloe. Suite 100 y Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1917892 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 85.9 107 80-120 Antimony ug/L 80 82.8 104 80-120 Arsenic ug/L 80 82.0 103 80-120 Barium ug/L 80 82.2 103 80-120 Beryllium ug/L 80 80.2 100 80-120 Boron ug/L 80 81.6 102 80-120 Cadmium ug/L 80 83.6 105 80-120 Calcium ug/L 1000 987 99 80-120 Chromium ug/L 80 80.9 101 80-120 Cobalt ug/L 80 82.8 104 80-120 Copper ug/L 80 84.9 106 80-120 Iron ug/L 1000 1020 102 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 39 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098gwinyloe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 LABORATORY CONTROL SAMPLE: 1917892 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 81.8 102 80-120 Magnesium ug/L 1000 1030 103 80-120 Manganese ug/L 80 84.8 106 80-120 Molybdenum ug/L 80 82.6 103 80-120 Nickel ug/L 80 85.3 107 80-120 Potassium ug/L 1000 1030 103 80-120 Selenium ug/L 80 81.7 102 80-120 Sodium ug/L 1000 1000 100 80-120 Strontium ug/L 80 81.1 101 80-120 Thallium ug/L 80 82.0 102 80-120 Vanadium ug/L 80 81.4 102 80-120 Zinc ug/L 80 80.8 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1918581 1918582 MS MSD 92240314001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 682 80 80 1210 1140 664 567 75-125 7 20 M1 Antimony ug/L ND 80 80 85.3 82.1 106 103 75-125 4 20 Arsenic ug/L 1.5 80 80 85.3 82.4 105 101 75-125 4 20 Barium ug/L 10.3 80 80 95.8 92.3 107 103 75-125 4 20 Beryllium ug/L ND 80 80 81.9 80.2 102 100 75-125 2 20 Boron ug/L ND 80 80 83.8 81.5 104 101 75-125 3 20 Cadmium ug/L ND 80 80 86.7 82.6 108 103 75-125 5 20 Calcium ug/L 2800 1000 1000 3970 3750 117 96 75-125 6 20 Chromium ug/L 8.7 80 80 95.1 89.9 108 101 75-125 6 20 Cobalt ug/L 3.8 80 80 88.3 86.0 106 103 75-125 3 20 Copper ug/L 8.9 80 80 96.6 93.2 110 105 75-125 4 20 Iron ug/L 3620 1000 1000 4840 4640 121 102 75-125 4 20 Lead ug/L 0.82 80 80 84.7 81.8 105 101 75-125 4 20 Magnesium ug/L 274 1000 1000 1380 1310 110 104 75-125 5 20 Manganese ug/L 51.6 80 80 140 135 110 104 75-125 3 20 Molybdenum ug/L 2.8 80 80 88.5 85.7 107 104 75-125 3 20 Nickel ug/L 3.6 80 80 91.7 88.6 110 106 75-125 3 20 Potassium ug/L 389 1000 1000 1460 1430 107 104 75-125 3 20 Selenium ug/L ND 80 80 83.8 81.1 105 101 75-125 3 20 Sodium ug/L 177 1000 1000 1270 1240 109 106 75-125 2 20 Strontium ug/L 5.6 80 80 90.2 86.6 106 101 75-125 4 20 Thallium ug/L ND 80 80 86.3 83.5 108 104 75-125 3 20 Vanadium ug/L 1.6 80 80 86.3 83.6 106 103 75-125 3 20 Zinc ug/L 21.3 80 80 105 103 104 103 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 40 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030219 Pace Project No.: 92240314 QC Batch: MPRP/53205 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92240314005 METHOD BLANK: 1926005 Associated Lab Samples: 92240314005 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 03/27/1513:48 ND 0.50 03/27/1513:48 ND 0.50 03/27/1513:48 ND 0.30 03/27/1513:48 ND 0.20 03/27/1513:48 ND 5.0 03/27/1513:48 ND 0.080 03/27/1513:48 ND 40.0 03/27/1513:48 ND 0.50 03/27/1513:48 ND 0.50 03/27/1513:48 ND 1.0 03/27/1513:48 ND 50.0 03/27/1513:48 ND 0.10 03/27/1513:48 ND 10.0 03/27/1513:48 ND 0.50 03/27/1513:48 ND 0.50 03/27/1513:48 ND 0.50 03/27/1513:48 ND 50.0 03/27/1513:48 ND 0.50 03/27/1513:48 ND 50.0 03/27/1513:48 ND 0.50 03/27/1513:48 ND 0.10 03/27/1513:48 ND 1.0 03/27/1513:48 ND 5.0 03/27/1513:48 Qualifiers Pace Analytical Services, Inc. 098gwinyloe. Suite 100 y Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1926006 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 90.1 113 80-120 Antimony ug/L 80 81.4 102 80-120 Arsenic ug/L 80 81.9 102 80-120 Barium ug/L 80 86.1 108 80-120 Beryllium ug/L 80 81.9 102 80-120 Boron ug/L 80 84.7 106 80-120 Cadmium ug/L 80 86.8 108 80-120 Calcium ug/L 1000 1100 110 80-120 Chromium ug/L 80 87.4 109 80-120 Cobalt ug/L 80 85.9 107 80-120 Copper ug/L 80 85.1 106 80-120 Iron ug/L 1000 1120 112 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 41 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098m.8f6e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 LABORATORY CONTROL SAMPLE: 1926006 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 85.0 106 80-120 Magnesium ug/L 1000 1050 105 80-120 Manganese ug/L 80 89.4 112 80-120 Molybdenum ug/L 80 84.4 105 80-120 Nickel ug/L 80 87.2 109 80-120 Potassium ug/L 1000 1080 108 80-120 Selenium ug/L 80 82.6 103 80-120 Sodium ug/L 1000 1080 108 80-120 Strontium ug/L 80 84.2 105 80-120 Thallium ug/L 80 88.7 111 80-120 Vanadium ug/L 80 86.8 108 80-120 Zinc ug/L 80 87.7 110 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1926431 1926432 MS MSD 92242374012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 57.4 80 80 190 332 166 344 75-125 55 20 M1,R1 Antimony ug/L ND 80 80 79.8 80.0 100 100 75-125 0 20 Arsenic ug/L ND 80 80 80.6 80.6 101 101 75-125 0 20 Barium ug/L 2.2 80 80 87.7 86.6 107 105 75-125 1 20 Beryllium ug/L ND 80 80 82.7 81.4 103 102 75-125 2 20 Boron ug/L ND 80 80 88.3 87.1 108 107 75-125 1 20 Cadmium ug/L ND 80 80 87.1 87.1 109 109 75-125 0 20 Calcium ug/L 102 1000 1000 1170 1200 106 110 75-125 3 20 Chromium ug/L 1.5 80 80 88.9 87.7 109 108 75-125 1 20 Cobalt ug/L ND 80 80 87.1 86.2 109 108 75-125 1 20 Copper ug/L 1.3 80 80 86.6 85.2 107 105 75-125 2 20 Iron ug/L 553 1000 1000 1680 1870 113 131 75-125 10 20 M1 Lead ug/L 0.12 80 80 83.8 82.4 105 103 75-125 2 20 Magnesium ug/L 29.0 1000 1000 1100 1090 107 106 75-125 0 20 Manganese ug/L 13.6 80 80 102 101 111 110 75-125 1 20 Molybdenum ug/L ND 80 80 83.0 83.2 104 104 75-125 0 20 Nickel ug/L 1.3 80 80 88.8 87.6 109 108 75-125 1 20 Potassium ug/L ND 1000 1000 1100 1100 106 106 75-125 0 20 Selenium ug/L ND 80 80 82.9 82.9 104 104 75-125 0 20 Sodium ug/L 108 1000 1000 1190 1170 108 106 75-125 2 20 Strontium ug/L 0.95 80 80 84.1 83.3 104 103 75-125 1 20 Thallium ug/L ND 80 80 87.8 86.6 110 108 75-125 1 20 Vanadium ug/L ND 80 80 85.8 84.6 107 105 75-125 1 20 Zinc ug/L 26.6 80 80 111 111 106 105 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 42 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098onyloe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 QC Batch: PMST/3351 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92240314002, 92240314003, 92240314004 SAMPLE DUPLICATE: 1159425 35178495001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 14.2 13.8 3 10 SAMPLE DUPLICATE: 1159426 35179141001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 6.2 9.7 45 10 D6 SAMPLE DUPLICATE: 1159427 92241104003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 23.3 2 10 SAMPLE DUPLICATE: 1159428 35179439005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 22.2 21.1 5 10 SAMPLE DUPLICATE: 1159429 35179503008 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 5.4 5.2 4 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 43 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030219 Pace Project No.: 92240314 QC Batch: WET/36234 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92240314002, 92240314003, 92240314004 Pace Analytical Services, Inc. 098onvloe. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1411760 92239985005 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.6 6.6 0 10 SAMPLE DUPLICATE: 1411761 92240320001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 4.9 4.9 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 44 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098onyloe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 QC Batch: WETA/22270 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92240314004 METHOD BLANK: 1415171 Matrix: Water Associated Lab Samples: 92240314004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L ND 2.0 03/19/1518:22 LABORATORY CONTROL SAMPLE: 1415172 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 18.7 94 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415173 1415174 MS MSD 92239540001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 3.5 24 24 25.8 25.8 93 93 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415175 1415176 MS MSD 92240158010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 3.0 25.5 25.5 26.8 26.8 93 93 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 45 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098nnyloe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 QC Batch: WETA/22256 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92240314004 METHOD BLANK: 1413768 Matrix: Water Associated Lab Samples: 92240314004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.22 0.020 03/18/15 16:20 B LABORATORY CONTROL SAMPLE: 1413769 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1413770 1413771 MS MSD 92239540001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.41 3 3 3.3 3.3 95 95 90-110 0 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1413772 1413773 MS MSD 92239540002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.33 2.9 2.9 3.2 3.2 98 98 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 46 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098mvloe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 QC Batch: WETA/22273 Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 92240314004 METHOD BLANK: 1415463 Matrix: Water Associated Lab Samples: 92240314004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 03/19/15 20:57 LABORATORY CONTROL SAMPLE: 1415464 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.4 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415465 1415466 MS MSD 92239540003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 23.9 23.9 24.7 24.6 101 101 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415467 1415468 MS MSD 92239543006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 5.7J 24.7 24.7 31.0 30.7 102 101 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 47 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030219 Pace Project No.: 92240314 QC Batch: WETA/44517 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92240314002, 92240314003, 92240314004 METHOD BLANK: 1155879 1155880 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1155882 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.8 03/14/15 01:39 Sulfate mg/kg ND 49.8 03/14/15 01:39 LABORATORY CONTROL SAMPLE: 1155880 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1155882 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1155881 Parameter Chloride Sulfate Pace Analytical Services, Inc. 098nnyloe. Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 500 475 95 80-120 500 477 95 80-120 92240170016 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 579 506 69 80-120 M1 ND 579 513 89 80-120 92240170016 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 48 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098onyloe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 QC Batch: WETA/44516 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92240314002, 92240314003, 92240314004 METHOD BLANK: 1155872 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 03/14/15 01:39 LABORATORY CONTROL SAMPLE: 1155873 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50 49.9 100 80-120 MATRIX SPIKE SAMPLE: 1155875 92240170016 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 57.9 52.2 86 80-120 H3 SAMPLE DUPLICATE: 1155874 92240170016 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 49 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 0988 i vloe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030219 Pace Project No.: 92240314 QC Batch: WETA/27605 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92240314002, 92240314003, 92240314004 METHOD BLANK: 1128361 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 03/18/15 07:25 LABORATORY CONTROL SAMPLE: 1128362 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 119000 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1128363 1128364 MS MSD 92240170030 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 7740 7770 11100 10100 139 126 50-150 9 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 50 of 54 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15030219 Pace Project No.: 92240314 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, Inc. 098ony6e. Suite 100 Huntersville, NC 28078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. E Analyte concentration exceeded the calibration range. The reported result is estimated. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/08/2015 11:52 AM without the written consent of Pace Analytical Services, Inc.. Page 51 of 54 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030219 Pace Project No.: 92240314 Pace Analytical Services, Inc. 098ony6e. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92240314002 2015006613 EPA 3050 MPRP/23101 EPA 6010 92240314003 2015006615 EPA 3050 MPRP/23101 EPA 6010 92240314004 2015006614 EPA 3050 MPRP/23101 EPA 6010 92240314002 2015006613 EPA 3050 MPRP/23102 EPA 6020 92240314003 2015006615 EPA 3050 MPRP/23102 EPA 6020 92240314004 2015006614 EPA 3050 MPRP/23102 EPA 6020 92240314001 2015006612 EPA 3020 MPRP/52947 EPA 6020A 92240314005 2015006614 SPLP EPA 3020 MPRP/53205 EPA 6020A 92240314001 2015006612 EPA 7470 MERP/12953 EPA 7470 92240314005 2015006614 SPLP EPA 7470 MERP/13071 EPA 7470 92240314002 2015006613 EPA 7471 MERP/5472 EPA 7471 92240314003 2015006615 EPA 7471 MERP/5472 EPA 7471 92240314004 2015006614 EPA 7471 MERP/5472 EPA 7471 92240314002 2015006613 ASTM D2974-87 PMST/3351 92240314003 2015006615 ASTM D2974-87 PMST/3351 92240314004 2015006614 ASTM D2974-87 PMST/3351 92240314002 2015006613 EPA 9045 WET/36234 92240314003 2015006615 EPA 9045 WET/36234 92240314004 2015006614 EPA 9045 WET/36234 92240314004 2015006614 EPA 300.0 WETA/22270 92240314004 2015006614 EPA 353.2 WETA/22256 92240314004 2015006614 SM 4500 -CI -E WETA/22273 92240314002 2015006613 EPA 9056 WETA/44517 92240314003 2015006615 EPA 9056 WETA/44517 92240314004 2015006614 EPA 9056 WETA/44517 92240314002 2015006613 EPA 9056 WETA/44516 92240314003 2015006615 EPA 9056 WETA/44516 92240314004 2015006614 EPA 9056 WETA/44516 92240314002 2015006613 EPA 9060 WETA/27605 92240314002 2015006613 EPA 9060 WETA/27606 92240314003 2015006615 EPA 9060 WETA/27605 92240314003 2015006615 EPA 9060 WETA/27606 92240314004 2015006614 EPA 9060 WETA/27605 92240314004 2015006614 EPA 9060 WETA/27606 Date: 04/08/2015 11:52 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14137 ICP/14137 ICP/14137 ICPM/9424 ICPM/9424 ICPM/9424 ICPM/23467 ICPM/23572 MERC/15027 MERC/15183 MERC/5462 MERC/5462 MERC/5462 Page 52 of 54 umuuuuiiiiiiiii 4TEObZZ6:#OM (sJaulaluoa;oa)Jooul Page 60 of 62 'dwal to )no 'anl;eJUasaad loaJJoou! 'ploy to )no a-1 ) aa}lp uolleal)laJa0 l]NH30 eullORD VON eg; of;uos aq ll!M wJol sly; to Adoa e'seldwes anuildwoa eulloJeo g1JoN 6ul)aaya AouedaJoslp a sl aJaq; JanauegM :91ON q1 ly a)ea 'MOIAaa =INS Sli C :0)e° :MalAab:junoS mol)nlosa-�j /s)uawwo0 :awlJJa)e(] ;pa10elu00 uosJad N 1 A LpaJlnbad a;eq plaid :uoploseN luolleolll)oN }u8110 un6eq seg ss000Jd 6ull000 'eol uo saldauoN an1q )a ml }o adA.L pyy ung al :pas"Ja)awowJaglg J� fg dD 9lggn9 ® :lelJOIEW Bulsloed ou [] saA ❑ :)Dalin sleas ou ❑ saA ❑ :luasWd x0gl101000 uo IeaS Ap04sn0 Jagj0 ( 90d ❑Ie010uill5o0 Dwain ❑sdSn ❑sdn ❑ x:] pad ["] :JapnoO �r a vj ayU :GWEN IU9110 ao!�}0 )!land alUnsJa}unH ao>?d g�'AGJ-£00-SO-NH0-d :Ajpoq)ny 6ulnssl :JagwnN juawnooatj�uya3 Z;o t a ed unos !aaaa uo - - u0111pu00 alawes Page 53 of :(pasegoJnd;) # )o-) Jluelg dui aced V!N ONE]saA❑ luasaJd sleas Apo)sn0 jUei9 dlJl 'NrN ONE] saAp :luasaJd �uelg dlJl '84 Yr ❑ ONE]saA❑ :(wwg< s�e1A HOA ul aoedspeaH b VIN [I ONE] saA❑ :uolleulJolgoap Jo} paNDago soldweS ON saA❑ Galeas) 08Cl-LM '0'80 '00J. 'wJoypoa 'YQn :suolldaoxa 'uol;epuawwooaJ yd3 gl!m aouelldwoo ❑ ON❑ saA❑ ul aq of punol ala uollemesaid 6ulpaau sJaule)uoo Iib YjNM ONE] saA❑ paloago uaaq aneg uoilaAJasaJd 6ulpaau sJauleluoa lIY :xuleW sls leudldllawl)la)ep sapnloul- 'Z� VINE] ONE] sax❑ :000 galew slegel eldweS E lvI ❑saA❑ slsa) panloss10 J0; panlaaaJ awnlon paJallld a VIN© OND saA :)oelul SJBU10JU00 YIN❑ saA❑ TOM sJ2Ulelu00 aasd- -6 ON© sa :pasn sJaulewoo loamo S VIN ❑s :ewnlon)Uafo M I VIN❑ saA© :palsan e-8 etull punoJV uJnl gsnM 'g V/Nlff o saAlp :(J4Z1>) slsAleuy Owil. pl0H :PogS q ON s :awll ploH u!gl!M pan1JJV saldweg 17 VrN❑ ❑ :000 uo aJn)eu lS 19 aweN JaldweS 'E VIN❑ ❑ ea :pagslnbulla-d Apolsn0 jo upq0 'Z VINE] ONE11,59 :Ino pell!d Apo)sn0 jo U1ego L VIN© oN sa :)uasaJd Apolsn0lo uleg0 :s;uawwo0 0,9 01 6ulzaeJl anoge aq pinogs dwa_L .— j ,� s)ua;uoaJ� N saA :uazoJd sl anssll leolSolom 9 0• :'dwal JalooO pa;oaJJoO 6ululwexe uosrad54 el)lul pus a)ep ?I --. . -1- . .. fi.i AA.- An-, un6eq seg ss000Jd 6ull000 'eol uo saldauoN an1q )a ml }o adA.L pyy ung al :pas"Ja)awowJaglg J� fg dD 9lggn9 ® :lelJOIEW Bulsloed ou [] saA ❑ :)Dalin sleas ou ❑ saA ❑ :luasWd x0gl101000 uo IeaS Ap04sn0 Jagj0 ( 90d ❑Ie010uill5o0 Dwain ❑sdSn ❑sdn ❑ x:] pad ["] :JapnoO �r a vj ayU :GWEN IU9110 ao!�}0 )!land alUnsJa}unH ao>?d g�'AGJ-£00-SO-NH0-d :Ajpoq)ny 6ulnssl :JagwnN juawnooatj�uya3 Z;o t a ed unos !aaaa uo - - u0111pu00 alawes Page 53 of siauleluo3 Jo 4 lelolaz $ N'YO 1"40-t 9 hb'011AldNV SS333d) -ls[ zo g - Z s;ser al)loeds ruewipos s [33dd) sael za g - Z suoluv pue SIMIN lerol - dldS vJ {33ed) aefzoy 301 (33dd) ref zo g - � Hd )Iuv I sferew 1er41 bad Qe��sl ,p d91 j i i I Z I s I a -1 0o I- O i v 0 R � o d 6 o K ° c w uO roL) izi a ma o l a �C9a Dcc o O N v j-- --- _,_ J ._._, ul (p I v I t w CL Z i 0. I j i x' iI coo a d i l I i a 3 gf e® UO — 10 O a CD� rqq f Yl _ R I Ly N N l0 V llki0 (i@ a0 Q d u O C K i7 I %I S�Sv �I •q9 I j v > o C)j �i r(, o° OQ 0 r�j m 0 Q b R a o O i._ _.1� _ C1 C1 f siauleluo3 Jo 4 lelolaz $ N'YO 1"40-t 9 hb'011AldNV SS333d) -ls[ zo g - Z s;ser al)loeds ruewipos s [33dd) sael za g - Z suoluv pue SIMIN lerol - dldS vJ {33ed) aefzoy 301 (33dd) ref zo g - � Hd )Iuv I sferew 1er41 bad Qe��sl ,p d91 j i i I Z I s I a -1 c n a V � 0 R � o d 6 o K ° c w uO 'p izi u v7 N v t d ycr ? K 0. c a c n 7 so 0 � V C a0 Q u O C K •q9 I v > o r a .Y a m E. b �aon�wop r.��w ��umisn� a L 0 m f w 3gle 61 of 62 o izi a Q ycr ? K � I rrJ C'4N A v W ni CL z J M Z 8 a w xG P f I ui c \ w 41 I ;%jup o) suwnloo eaelidoidde elaidwoo op lawolsno a '} _..�.._t._.i_..i_.. .__ c� Z 0 2 c Page 54 of 54 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM ---------------------------------------------- — ... ------------------- -- ---------------------- Arialyticall-aborato Use0n� i ft" Nc—k- 1041 DUKE MO rkids 14GMA2 I Rul6ding 74M) SOIL SCL— DISTRIBUFION I MO Flogwe F*rFy Rd i Z Spmpk* *rICIii-*ft jj ORIGINAL to LAB. Hursomwilki, N- C. 28078 lt-gu-ay D40 A T11 COPY 1E., C. I PLX 1 ENERUT, 9 49MI)p VS -%24S i -3 ------------- Fm J4LSN. .--i , 75 — — SAMPLE moaiiAm Gra" Yvaw E 0 PACE 2, <� CuukHr Temn IC I PO 1142081 "Pr A=H > �i C"v %rd— REV DATE V10906 2zHi 50, '-H A .......... 4=1ce 15 ---Nandi L0 It L rj 41 W < Prpservalives when must be S 1cE —'n added within 15 m. iRutes of sa rnple I, V co (3 4�- colleclic" lk I o matfl,x "Collection lnforrrl tical g� .0 U 'r -j ISGIN, Sed"norc Aahj 0 106 CL r— z Sample Description OF ID Tin- J—L-- -, us W Z ikv-(6 S2 WATER ] EQUIPMENT BLANK {1 PER Mpjaln: Al, Sh. As, Na, Imo, Anions.: CI, Nitrale-N, $04 Emil NERE I milli NEI OMNI &Lll 15 ALL;IF ,&d Z: Djulume A&C M� Lock Ova cu. Fe. pb, 'ft. Win., Mo, N1, K. Se. Na, Sr, 71, V, Zin, Mercury, PH mcific Pararmters: %SoHds, CEC, Parocle Size 111strIbution, Redox Putenflal 14 72keiquesv2d Turnaround 14 ()Rys "' Days - -48 ft