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Home My WebLink AboutNC0000396_J15030047 Report_20150823DUE Analytical Laboratory Page 1of68 ' ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report J15030047 AB GW ASSESSMENT SOIL Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker 200 CP and L Drive Arden,NC 28704 Margaret Galvin -Karr Phone: 980-875-5219 1�,G 1�4 ka marge.galvin-karr@duke- °(3 energy.com Date: 2015.04.08 14:03:00 -04'00' Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 4/6/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015005864 ASHEVILLE 23 -Feb -15 3:00 PM illegible Equipment Blank 2015005865 ASHEVILLE 27 -Feb -15 10:20 AM illegible MW -08 SB (1.5-2) 2015005866 ASHEVILLE 27 -Feb -15 10:40 AM illegible MW -08 SB (36-37) 2015005867 ASHEVILLE 27 -Feb -15 11:00 AM illegible MW -08 SB (42-43) 4 Total Samples Page 2 of 68 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: LU Job Summary Report ❑ Sample Identification P/1 Technical Validation of Data Package J❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Page 3 of 68 LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries d❑ Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 4/6/2015 Certificate of Laboratory Analysis Page 4 of 68 This report shall not be reproduced, except in full. Order # J15030047 Site: Equipment Blank Collection Date: 23 -Feb -15 3:00 PM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015005864 Matrix: OTHER Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030047 Site: MW -08 SB (1.5-2) Collection Date: 27 -Feb -15 10:20 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 5 of 68 Sample #: 2015005865 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030047 Site: MW -08 SB (36-37) Collection Date: 27 -Feb -15 10:40 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 6 of 68 Sample #: 2015005866 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030047 Site: MW -08 SB (42-43) Collection Date: 27 -Feb -15 11:00 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 7 of 68 Sample #: 2015005867 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE aceAnaiXical www.pacelabs.com April 03, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15030047 Pace Project No.: 92239543 Pace Analytical Services, Inc. 9P2Q.�C8,8y&ie. Suite 100 �Huntersville, INC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on March 03, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy HiQ p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 60 lacmnalyfica( www.pacelabs.com Project: J15030047 Pace Project No.: 92239543 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21 -A Certification #: 2926.01 Alaska Certification #: UST -078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ -0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH -0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. 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Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN -002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 60 aceAnaiXical www.pacelabs.com Project: J15030047 Pace Project No.: 92239543 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 0g8pli6'8y&ie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Page 3 of 60 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15030047 Pace Project No.: 92239543 Lab ID Sample ID Matrix Date Collected Date Received 92239543001 2015005864 Water 02/23/1515:00 03/03/1517:00 92239543003 2015005866 SPLP Water 02/27/15 10:40 03/03/15 17:00 92239543004 2015005867 SPLP Water 02/27/15 11:00 03/03/15 17:00 92239543005 2015005865 Solid 02/27/1510:20 03/03/1517:00 92239543006 2015005866 Solid 02/27/1510:40 03/03/1517:00 92239543007 2015005867 Solid 02/27/1511:00 03/03/1517:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. �Q�ff�in�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Page 4 of 60 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15030047 92239543 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92239543001 2015005864 EPA 6020A TT3 24 PASI-M EPA 7470 LMW 1 PASI-M 92239543003 2015005866 SPLP EPA 6020A TT3 24 PASI-M EPA 7470 DM 1 PASI-M 92239543004 2015005867 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 DM 1 PASI-M 92239543005 2015005865 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92239543006 2015005866 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E DMN 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92239543007 2015005867 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E DMN 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 60 aceAnaiXical www.pacelabs.com Project: J15030047 Pace Project No.: 92239543 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92239543001 2015005864 EPA 6020A Aluminum 37.6 ug/L 10.0 03/10/15 08:01 EPA 6020A Barium 1.0 ug/L 0.30 03/10/15 08:01 EPA 6020A Calcium 529 ug/L 40.0 03/10/15 08:01 EPA 6020A Chromium 0.50 ug/L 0.50 03/10/15 08:01 EPA 6020A Iron 117 ug/L 50.0 03/10/15 08:01 EPA 6020A Lead 0.20 ug/L 0.10 03/10/15 08:01 EPA 6020A Magnesium 25.0 ug/L 10.0 03/10/15 08:01 EPA 6020A Manganese 3.0 ug/L 0.50 03/10/15 08:01 EPA 6020A Molybdenum 2.0 ug/L 0.50 03/10/15 08:01 EPA 6020A Nickel 0.61 ug/L 0.50 03/10/15 08:01 EPA 6020A Potassium 79.1 ug/L 50.0 03/10/15 08:01 EPA 6020A Strontium 0.90 ug/L 0.50 03/10/15 08:01 92239543003 2015005866 SPLP EPA 6020A Aluminum 120 ug/L 10.0 03/27/15 13:31 EPA 6020A Barium 10.5 ug/L 0.30 03/27/15 13:31 EPA 6020A Boron 129 ug/L 5.0 03/27/15 13:31 EPA 6020A Calcium 4150 ug/L 40.0 03/27/15 13:31 EPA 6020A Chromium 0.76 ug/L 0.50 03/27/15 13:31 EPA 6020A Cobalt 0.77 ug/L 0.50 03/27/15 13:31 EPA 6020A Iron 176 ug/L 50.0 03/27/15 13:31 EPA 6020A Lead 0.12 ug/L 0.10 03/27/15 13:31 EPA 6020A Magnesium 1100 ug/L 10.0 03/27/15 13:31 EPA 6020A Manganese 44.4 ug/L 0.50 03/27/15 13:31 EPA 6020A Potassium 418 ug/L 50.0 03/27/15 13:31 EPA 6020A Sodium 1210 ug/L 50.0 03/27/15 13:31 EPA 6020A Strontium 58.6 ug/L 0.50 03/27/15 13:31 92239543004 2015005867 SPLP EPA 6020A Aluminum 17.4 ug/L 10.0 04/02/15 09:45 EPA 6020A Barium 2.7 ug/L 0.30 04/02/15 09:45 EPA 6020A Boron 59.3 ug/L 5.0 04/02/15 09:45 EPA 6020A Calcium 926 ug/L 40.0 04/02/15 09:45 EPA 6020A Chromium 0.73 ug/L 0.50 04/02/15 09:45 EPA 6020A Magnesium 337 ug/L 10.0 04/02/15 09:45 EPA 6020A Manganese 21.7 ug/L 0.50 04/02/15 09:45 EPA 6020A Nickel 0.57 ug/L 0.50 04/02/15 09:45 EPA 6020A Potassium 2020 ug/L 50.0 04/02/15 09:45 EPA 6020A Sodium 2690 ug/L 50.0 04/02/15 09:45 EPA 6020A Strontium 5.0 ug/L 0.50 04/02/15 09:45 92239543005 2015005865 EPA 6010 Aluminum 27800 mg/kg 67.3 03/16/15 18:02 D3 EPA 6010 Barium 38.7 mg/kg 6.7 03/16/15 18:02 D3 EPA 6010 Beryllium 0.76 mg/kg 0.67 03/16/15 18:02 D3 EPA 6010 Calcium 186J mg/kg 336 03/16/15 18:02 D3 EPA 6010 Chromium 55.1 mg/kg 3.4 03/16/15 18:02 D3 EPA 6010 Copper 38.1 mg/kg 3.4 03/16/15 18:02 D3 EPA 6010 Iron 65200 mg/kg 26.9 03/16/15 18:02 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 60 aceAnaiXical www.pacelabs.com Project: J15030047 Pace Project No.: 92239543 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. �Q�fflic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92239543005 2015005865 EPA 6010 Magnesium 383 mg/kg 336 03/16/15 18:02 D3 EPA 6010 Manganese 931 mg/kg 3.4 03/16/15 18:02 D3 EPA 6010 Nickel 3.OJ mg/kg 3.4 03/16/15 18:02 D3 EPA 6010 Zinc 15.0 mg/kg 13.5 03/16/15 18:02 D3 EPA 6020 Cobalt 39.4 mg/kg 13.5 03/12/15 12:02 D3 EPA 6020 Lead 23.6 mg/kg 1.3 03/12/15 11:09 D3 EPA 6020 Vanadium 75.0 mg/kg 13.5 03/12/15 12:02 D4 EPA 7471 Mercury 0.057 mg/kg 0.010 03/12/15 13:50 ASTM D2974-87 Percent Moisture 25.6 % 0.10 03/12/15 10:49 EPA 9045 pH at 25 Degrees C 5.4 Std. Units 0.10 03/19/15 16:00 H3 EPA 9060 Total Organic Carbon 3170 mg/kg 806 03/12/15 11:59 EPA 9060 Total Organic Carbon 1750 mg/kg 806 03/12/15 12:05 EPA 9060 Total Organic Carbon 1860 mg/kg 807 03/12/15 12:11 EPA 9060 Total Organic Carbon 1810 mg/kg 805 03/12/15 12:17 EPA 9060 Mean Total Organic Carbon 2150 mg/kg 806 03/12/15 11:59 EPA 9060 RSD% 31.8 % 03/12/15 11:59 92239543006 2015005866 EPA 6010 Aluminum 19800 mg/kg 65.4 03/16/15 18:06 D3 EPA 6010 Barium 199 mg/kg 6.5 03/16/15 18:06 D3 EPA 6010 Calcium 450 mg/kg 327 03/16/15 18:06 D3 EPA 6010 Chromium 29.8 mg/kg 3.3 03/16/15 18:06 D3 EPA 6010 Copper 20.1 mg/kg 3.3 03/16/15 18:06 D3 EPA 6010 Iron 27100 mg/kg 26.1 03/16/15 18:06 D3 EPA 6010 Magnesium 9570 mg/kg 327 03/16/15 18:06 D3 EPA 6010 Manganese 806 mg/kg 3.3 03/16/15 18:06 D3 EPA 6010 Nickel 16.2 mg/kg 3.3 03/16/15 18:06 D3 EPA 6010 Potassium 8110 mg/kg 654 03/16/15 18:06 D3 EPA 6010 Strontium 19.4 mg/kg 6.5 03/16/15 18:06 D3 EPA 6010 Zinc 103 mg/kg 13.1 03/16/15 18:06 D3 EPA 6020 Arsenic 4.4 mg/kg 3.3 03/12/15 11:44 D3 EPA 6020 Beryllium 1.9 mg/kg 1.6 03/12/15 12:14 D3 EPA 6020 Cadmium 0.089J mg/kg 0.16 03/12/15 11:32 D3 EPA 6020 Cobalt 30.3 mg/kg 3.3 03/12/15 11:44 D4 EPA 6020 Lead 10.4 mg/kg 1.3 03/12/15 11:32 D3 EPA 6020 Selenium 7.4 mg/kg 3.3 03/12/15 11:44 D3 EPA 6020 Thallium 0.76J mg/kg 1.3 03/12/15 11:32 D3 EPA 6020 Vanadium 42.5 mg/kg 3.3 03/12/15 11:44 D4 ASTM D2974-87 Percent Moisture 19.1 % 0.10 03/12/15 10:49 EPA 9045 pH at 25 Degrees C 5.7 Std. Units 0.10 03/06/15 15:45 EPA 300.0 Sulfate 8.9 mg/L 2.5 03/19/15 19:57 EPA 353.2 Nitrogen, Nitrate 0.35 mg/L 0.25 03/18/1516:38 H1 SM 4500 -CI -E Chloride 5.7J mg/L 6.2 03/19/15 21:02 EPA 9056 Chloride 164J mg/kg 308 03/10/15 01:56 EPA 9056 Sulfate 154J mg/kg 308 03/10/15 01:56 EPA 9060 RSD% 2.8 % 03/12/15 12:26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 7 of 60 aceAnaiXical www.pacelabs.com Project: J15030047 Pace Project No.: 92239543 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92239543007 2015005867 EPA 6010 Aluminum 27600 mg/kg 55.5 03/16/15 18:10 D3 EPA 6010 Barium 310 mg/kg 5.6 03/16/15 18:10 D3 EPA 6010 Calcium 1450 mg/kg 278 03/16/15 18:10 D3 EPA 6010 Chromium 36.3 mg/kg 2.8 03/16/15 18:10 D3 EPA 6010 Copper 23.4 mg/kg 2.8 03/16/15 18:10 D3 EPA 6010 Iron 44200 mg/kg 22.2 03/16/15 18:10 D3 EPA 6010 Magnesium 16200 mg/kg 278 03/16/15 18:10 D3 EPA 6010 Manganese 459 mg/kg 2.8 03/16/15 18:10 D3 EPA 6010 Nickel 28.4 mg/kg 2.8 03/16/15 18:10 D3 EPA 6010 Potassium 14300 mg/kg 555 03/16/15 18:10 D3 EPA 6010 Strontium 9.7 mg/kg 5.6 03/16/15 18:10 D3 EPA 6010 Zinc 132 mg/kg 11.1 03/16/15 18:10 D3 EPA 6020 Arsenic 3.7 mg/kg 1.1 03/12/15 11:35 D3 EPA 6020 Cadmium 0.068J mg/kg 0.13 03/12/15 11:35 D3 EPA 6020 Cobalt 15.7 mg/kg 1.1 03/12/15 11:35 D3 EPA 6020 Lead 3.8 mg/kg 1.1 03/12/15 11:35 D3 EPA 6020 Selenium 5.0 mg/kg 1.1 03/12/15 11:35 D3 EPA 6020 Thallium 0.991 mg/kg 1.1 03/12/15 11:35 D3 EPA 6020 Vanadium 55.2 mg/kg 1.1 03/12/15 11:35 D4 ASTM D2974-87 Percent Moisture 7.1 % 0.10 03/12/15 10:50 EPA 9045 pH at 25 Degrees C 6.0 Std. Units 0.10 03/06/15 15:45 EPA 300.0 Sulfate 4.8 mg/L 2.2 03/19/15 20:11 EPA 353.2 Nitrogen, Nitrate 0.32 mg/L 0.22 03/18/1516:40 B,H1 EPA 9060 Total Organic Carbon 815 mg/kg 647 03/12/15 12:54 EPA 9060 Total Organic Carbon 507J mg/kg 649 03/12/15 13:03 EPA 9060 Total Organic Carbon 880 mg/kg 646 03/12/15 13:10 EPA 9060 Total Organic Carbon 782 mg/kg 643 03/12/15 13:18 EPA 9060 Mean Total Organic Carbon 746 mg/kg 646 03/12/15 12:54 EPA 9060 RSD% 22.0 % 03/12/15 12:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&)e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 03, 2015 General Information: 3 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23029 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35177233002 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1152989) • Manganese • MSD (Lab ID: 1152990) • Barium • Manganese M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1152989) • Aluminum • Calcium • Iron • Magnesium • Sodium • Strontium • MSD (Lab ID: 1152990) • Aluminum • Calcium • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�fflic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 03, 2015 QC Batch: MPRP/23029 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35177233002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • Magnesium • Sodium • Strontium R1: RPD value was outside control limits. • MSD (Lab ID: 1152990) • Barium Additional Comments: Analyte Comments: QC Batch: MPRP/23029 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015005865 (Lab ID: 92239543005) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015005866 (Lab ID: 92239543006) • Aluminum • Boron • Barium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 60 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 03, 2015 Analyte Comments: QC Batch: MPRP/23029 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015005866 (Lab ID: 92239543006) • Nickel • Strontium • Zinc •2015005867 (Lab ID: 92239543007) • Aluminum • Boron • Barium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc Pace Analytical Services, Inc. �Q�ffligc&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1152987) • Iron • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&)e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 03, 2015 General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23030 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92239594001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1152997) • Antimony • Arsenic • Lead • Selenium • MSD (Lab ID: 1152998) • Antimony • Lead • Selenium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 i�c& oe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 03, 2015 Analyte Comments: QC Batch: MPRP/23030 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015005865 (Lab ID: 92239543005) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015005866 (Lab ID:92239543006) • Arsenic • Beryllium • Cadmium • Lead • Antimony • Selenium • Thallium •2015005867 (Lab ID:92239543007) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • MS (Lab ID: 1152997) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • MSD (Lab ID: 1152998) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKin�c& oe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 03, 2015 Analyte Comments: QC Batch: MPRP/23030 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • MSD (Lab ID: 1152998) • Thallium • Vanadium D4: Sample was diluted due to the presence of high levels of target analytes. •2015005865 (Lab ID:92239543005) • Vanadium •2015005866 (Lab ID:92239543006) • Cobalt • Vanadium •2015005867 (Lab ID: 92239543007) • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •2015005865 (Lab ID:92239543005) • Antimony •2015005866 (Lab ID:92239543006) • Antimony •2015005867 (Lab ID:92239543007) • Antimony • BLANK (Lab ID: 1152995) • Antimony • LCS (Lab ID: 1152996) • Antimony • MS (Lab ID: 1152997) • Antimony • MSD (Lab ID: 1152998) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKi�c yoe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: April 03, 2015 General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/53204 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242504001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1926004) • Aluminum • Zinc R1: RPD value was outside control limits. • MSD (Lab ID: 1926004) • Aluminum • Zinc QC Batch: MPRP/53309 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241387014 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1929569) • Aluminum REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 60 aceAnaiXical www.pacelabs.com Project: J15030047 Pace Project No.: 92239543 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: April 03, 2015 Additional Comments: Pace Analytical Services, Inc. 098gKi�c yoe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gK4-8y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: April 03, 2015 General Information: 3 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 i�c& oe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: April 03, 2015 General Information: 3 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K�i�c& oe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: April 03, 2015 General Information: 3 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015005865 (Lab ID: 92239543005) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098v i�c& oe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: April 03, 2015 General Information: 2 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 igc& oe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: April 03, 2015 General Information: 2 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015005866 (Lab ID: 92239543006) •2015005867 (Lab ID: 92239543007) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22256 B: Analyte was detected in the associated method blank. • BLANK for HBN 256042 [WETA/222 (Lab ID: 1413768) • Nitrogen, Nitrate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 60 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: SM 4500 -CI -E Description: 4500 Chloride, SPLP Client: Duke Energy Date: April 03, 2015 Pace Analytical Services, Inc. 0988 i�c& oe. Suite 100 �J Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for SM 4500 -CI -E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni�c yoe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: April 03, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninic& oe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: April 03, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015005865 (Lab ID: 92239543005) •2015005866 (Lab ID: 92239543006) •2015005867 (Lab ID: 92239543007) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni�c yoe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030047 Pace Project No.: 92239543 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: April 03, 2015 General Information: 3 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030047 Pace Project No.: 92239543 Pace Analytical Services, Inc. 098ni�c yoe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015005864 Lab ID: 92239543001 Collected: 02/23/15 15:00 Received: 03/03/15 17:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/03/2015 06:51 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 37.6 ug/L 10.0 1.2 1 03/09/15 15:03 03/10/15 08:01 7429-90-5 ND ug/L 0.50 0.25 1 03/09/15 15:03 03/10/15 08:01 7440-36-0 ND ug/L 0.50 0.25 1 03/09/15 15:03 03/10/15 08:01 7440-38-2 1.0 ug/L 0.30 0.14 1 03/09/15 15:03 03/10/15 08:01 7440-39-3 ND ug/L 0.20 0.066 1 03/09/15 15:03 03/10/15 08:01 7440-41-7 ND ug/L 5.0 1.0 1 03/09/15 15:03 03/10/15 08:01 7440-42-8 ND ug/L 0.080 0.033 1 03/09/15 15:03 03/10/15 08:01 7440-43-9 529 ug/L 40.0 8.4 1 03/09/15 15:03 03/10/15 08:01 7440-70-2 0.50 ug/L 0.50 0.22 1 03/09/15 15:03 03/10/15 08:01 7440-47-3 ND ug/L 0.50 0.25 1 03/09/15 15:03 03/10/15 08:01 7440-48-4 ND ug/L 1.0 0.22 1 03/09/15 15:03 03/10/15 08:01 7440-50-8 117 ug/L 50.0 8.0 1 03/09/15 15:03 03/10/15 08:01 7439-89-6 0.20 ug/L 0.10 0.046 1 03/09/15 15:03 03/10/15 08:01 7439-92-1 25.0 ug/L 10.0 2.8 1 03/09/15 15:03 03/10/15 08:01 7439-95-4 3.0 ug/L 0.50 0.14 1 03/09/15 15:03 03/10/15 08:01 7439-96-5 2.0 ug/L 0.50 0.24 1 03/09/15 15:03 03/10/15 08:01 7439-98-7 0.61 ug/L 0.50 0.23 1 03/09/15 15:03 03/10/15 08:01 7440-02-0 79.1 ug/L 50.0 8.3 1 03/09/15 15:03 03/10/15 08:01 7440-09-7 ND ug/L 0.50 0.25 1 03/09/15 15:03 03/10/15 08:01 7782-49-2 ND ug/L 50.0 18.2 1 03/09/15 15:03 03/10/15 08:01 7440-23-5 0.90 ug/L 0.50 0.057 1 03/09/15 15:03 03/10/15 08:01 7440-24-6 ND ug/L 0.10 0.025 1 03/09/15 15:03 03/10/15 08:01 7440-28-0 ND ug/L 1.0 0.21 1 03/09/15 15:03 03/10/15 08:01 7440-62-2 ND ug/L 5.0 2.5 1 03/09/15 15:03 03/10/15 08:01 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.026 1 03/09/1517:05 03/10/1515:59 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030047 Pace Project No.: 92239543 Pace Analytical Services, Inc. 09Q�K3i�c& oe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015005866 SPLP Lab ID: 92239543003 Collected: 02/27/15 10:40 Received: 03/03/15 17:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/03/2015 06:51 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 120 ug/L 10.0 1.2 1 03/26/1518:39 03/27/1513:31 7429-90-5 ND ug/L 0.50 0.25 1 03/26/1518:39 03/27/1513:31 7440-36-0 ND ug/L 0.50 0.25 1 03/26/1518:39 03/27/1513:31 7440-38-2 10.5 ug/L 0.30 0.14 1 03/26/1518:39 03/27/1513:31 7440-39-3 ND ug/L 0.20 0.066 1 03/26/1518:39 03/27/1513:31 7440-41-7 129 ug/L 5.0 1.0 1 03/26/1518:39 03/27/1513:31 7440-42-8 ND ug/L 0.080 0.033 1 03/26/1518:39 03/27/1513:31 7440-43-9 4150 ug/L 40.0 8.4 1 03/26/1518:39 03/27/1513:31 7440-70-2 0.76 ug/L 0.50 0.22 1 03/26/1518:39 03/27/1513:31 7440-47-3 0.77 ug/L 0.50 0.25 1 03/26/1518:39 03/27/1513:31 7440-48-4 ND ug/L 1.0 0.22 1 03/26/1518:39 03/27/1513:31 7440-50-8 176 ug/L 50.0 8.0 1 03/26/1518:39 03/27/1513:31 7439-89-6 0.12 ug/L 0.10 0.046 1 03/26/1518:39 03/27/1513:31 7439-92-1 1100 ug/L 10.0 2.8 1 03/26/1518:39 03/27/1513:31 7439-95-4 44.4 ug/L 0.50 0.14 1 03/26/1518:39 03/27/1513:31 7439-96-5 ND ug/L 0.50 0.24 1 03/26/1518:39 03/27/1513:31 7439-98-7 ND ug/L 0.50 0.23 1 03/26/1518:39 03/27/1513:31 7440-02-0 418 ug/L 50.0 8.3 1 03/26/1518:39 03/27/1513:31 7440-09-7 ND ug/L 0.50 0.25 1 03/26/1518:39 03/27/1513:31 7782-49-2 1210 ug/L 50.0 18.2 1 03/26/1518:39 03/27/1513:31 7440-23-5 58.6 ug/L 0.50 0.057 1 03/26/1518:39 03/27/1513:31 7440-24-6 ND ug/L 0.10 0.025 1 03/26/1518:39 03/27/1513:31 7440-28-0 ND ug/L 1.0 0.21 1 03/26/1518:39 03/27/1513:31 7440-62-2 ND ug/L 5.0 2.5 1 03/26/1518:39 03/27/1513:31 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.026 1 03/26/1519:10 03/27/1511:35 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030047 Pace Project No.: 92239543 Pace Analytical Services, Inc. 098ni�c yoe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015005867 SPLP Lab ID: 92239543004 Collected: 02/27/15 11:00 Received: 03/03/15 17:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/03/2015 06:51 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 17.4 ug/L 10.0 3.0 1 04/01/15 14:38 04/02/15 09:45 7429-90-5 ND ug/L 0.50 0.15 1 04/01/1514:38 04/02/1509:45 7440-36-0 ND ug/L 0.50 0.11 1 04/01/1514:38 04/02/1509:45 7440-38-2 2.7 ug/L 0.30 0.081 1 04/01/15 14:38 04/02/15 09:45 7440-39-3 ND ug/L 0.20 0.067 1 04/01/15 14:38 04/02/15 09:45 7440-41-7 59.3 ug/L 5.0 1.1 1 04/01/15 14:38 04/02/15 09:45 7440-42-8 ND ug/L 0.080 0.024 1 04/01/15 14:38 04/02/15 09:45 7440-43-9 926 ug/L 40.0 16.0 1 04/01/15 14:38 04/02/15 09:45 7440-70-2 0.73 ug/L 0.50 0.17 1 04/01/15 14:38 04/02/15 09:45 7440-47-3 ND ug/L 0.50 0.13 1 04/01/1514:38 04/02/1509:45 7440-48-4 ND ug/L 1.0 0.21 1 04/01/1514:38 04/02/1509:45 7440-50-8 ND ug/L 50.0 13.7 1 04/01/15 14:38 04/02/15 09:45 7439-89-6 ND ug/L 0.10 0.046 1 04/01/15 14:38 04/02/15 09:45 7439-92-1 337 ug/L 10.0 3.2 1 04/01/15 14:38 04/02/15 09:45 7439-95-4 21.7 ug/L 0.50 0.24 1 04/01/15 14:38 04/02/15 09:45 7439-96-5 ND ug/L 0.50 0.094 1 04/01/15 14:38 04/02/15 09:45 7439-98-7 0.57 ug/L 0.50 0.16 1 04/01/15 14:38 04/02/15 09:45 7440-02-0 2020 ug/L 50.0 11.7 1 04/01/15 14:38 04/02/15 09:45 7440-09-7 ND ug/L 0.50 0.20 1 04/01/1514:38 04/02/1509:45 7782-49-2 2690 ug/L 50.0 16.3 1 04/01/15 14:38 04/02/15 09:45 7440-23-5 5.0 ug/L 0.50 0.13 1 04/01/15 14:38 04/02/15 09:45 7440-24-6 ND ug/L 0.10 0.015 1 04/01/15 14:38 04/02/15 09:45 7440-28-0 ND ug/L 1.0 0.28 1 04/01/15 14:38 04/02/15 09:45 7440-62-2 ND ug/L 5.0 2.4 1 04/01/15 14:38 04/02/15 09:45 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.026 1 03/26/1519:10 03/27/1511:37 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 098ni�c yoe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030047 Pace Project No.: 92239543 Sample: 2015005865 Lab ID: 92239543005 Collected: 02/27/15 10:20 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 27800 mg/kg 67.3 33.6 10 03/11/1517:15 03/16/1518:02 7429-90-5 D3 Barium 38.7 mg/kg 6.7 3.4 10 03/11/1517:15 03/16/1518:02 7440-39-3 D3 Beryllium 0.76 mg/kg 0.67 0.34 10 03/11/1517:15 03/16/1518:02 7440-41-7 D3 Boron ND mg/kg 33.6 16.8 10 03/11/1517:15 03/16/1518:02 7440-42-8 D3 Calcium 186J mg/kg 336 168 10 03/11/1517:15 03/16/1518:02 7440-70-2 D3 Chromium 55.1 mg/kg 3.4 1.7 10 03/11/1517:15 03/16/1518:02 7440-47-3 D3 Copper 38.1 mg/kg 3.4 1.7 10 03/11/1517:15 03/16/1518:02 7440-50-8 D3 Iron 65200 mg/kg 26.9 13.5 10 03/11/1517:15 03/16/1518:02 7439-89-6 D3 Magnesium 383 mg/kg 336 168 10 03/11/1517:15 03/16/1518:02 7439-95-4 D3 Manganese 931 mg/kg 3.4 1.7 10 03/11/1517:15 03/16/1518:02 7439-96-5 D3 Molybdenum ND mg/kg 6.7 3.4 10 03/11/1517:15 03/16/1518:02 7439-98-7 D3 Nickel 3.OJ mg/kg 3.4 1.7 10 03/11/1517:15 03/16/1518:02 7440-02-0 D3 Potassium ND mg/kg 673 336 10 03/11/1517:15 03/16/1518:02 7440-09-7 D3 Sodium ND mg/kg 673 336 10 03/11/1517:15 03/16/1518:02 7440-23-5 D3 Strontium ND mg/kg 6.7 3.4 10 03/11/1517:15 03/16/1518:02 7440-24-6 D3 Zinc 15.0 mg/kg 13.5 6.7 10 03/11/1517:15 03/16/1518:02 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.3 0.67 20 03/11/1517:15 03/12/1511:09 7440-36-0 D3,N2 Arsenic ND mg/kg 13.5 6.7 200 03/11/1517:15 03/12/1512:02 7440-38-2 D3 Cadmium ND mg/kg 0.16 0.081 20 03/11/1517:15 03/12/1511:09 7440-43-9 D3 Cobalt 39.4 mg/kg 13.5 6.7 200 03/11/1517:15 03/12/1512:02 7440-48-4 D3 Lead 23.6 mg/kg 1.3 0.67 20 03/11/1517:15 03/12/1511:09 7439-92-1 D3 Selenium ND mg/kg 13.5 6.7 200 03/11/1517:15 03/12/1512:02 7782-49-2 D3 Thallium ND mg/kg 1.3 0.67 20 03/11/1517:15 03/12/1511:09 7440-28-0 D3 Vanadium 75.0 mg/kg 13.5 6.7 200 03/11/1517:15 03/12/1512:02 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.057 mg/kg 0.010 0.0052 1 03/11/1514:40 03/12/1513:50 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 25.6 % 0.10 0.10 1 03/12/15 10:49 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.4 Std. Units 0.10 0.10 1 03/19/15 16:00 H3 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 331 166 5 03/10/15 00:49 16887-00-6 M1 Sulfate ND mg/kg 331 166 5 03/10/15 00:49 14808-79-8 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 33.1 16.6 5 03/10/15 00:49 14797-55-8 H3 Date: 04/03/2015 06:51 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030047 Pace Project No.: 92239543 Pace Analytical Services, Inc. 098v i�c& oe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015005865 Lab ID: 92239543005 Collected: 02/27/15 10:20 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 3170 mg/kg 806 403 1 03/12/15 11:59 7440-44-0 Total Organic Carbon 1750 mg/kg 806 403 1 03/12/15 12:05 7440-44-0 Total Organic Carbon 1860 mg/kg 807 403 1 03/12/15 12:11 7440-44-0 Total Organic Carbon 1810 mg/kg 805 403 1 03/12/15 12:17 7440-44-0 Mean Total Organic Carbon 2150 mg/kg 806 403 1 03/12/15 11:59 7440-44-0 Surrogates RSD% 31.8 % 1 03/12/1511:59 Date: 04/03/2015 06:51 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 098nigc yoe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030047 Pace Project No.: 92239543 Sample: 2015005866 Lab ID: 92239543006 Collected: 02/27/15 10:40 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 19800 mg/kg 65.4 32.7 10 03/11/1517:15 03/16/1518:06 7429-90-5 D3 Barium 199 mg/kg 6.5 3.3 10 03/11/1517:15 03/16/1518:06 7440-39-3 D3 Boron ND mg/kg 32.7 16.3 10 03/11/1517:15 03/16/1518:06 7440-42-8 D3 Calcium 450 mg/kg 327 163 10 03/11/1517:15 03/16/1518:06 7440-70-2 D3 Chromium 29.8 mg/kg 3.3 1.6 10 03/11/1517:15 03/16/1518:06 7440-47-3 D3 Copper 20.1 mg/kg 3.3 1.6 10 03/11/1517:15 03/16/1518:06 7440-50-8 D3 Iron 27100 mg/kg 26.1 13.1 10 03/11/1517:15 03/16/1518:06 7439-89-6 D3 Magnesium 9570 mg/kg 327 163 10 03/11/1517:15 03/16/1518:06 7439-95-4 D3 Manganese 806 mg/kg 3.3 1.6 10 03/11/1517:15 03/16/1518:06 7439-96-5 D3 Molybdenum ND mg/kg 6.5 3.3 10 03/11/1517:15 03/16/1518:06 7439-98-7 D3 Nickel 16.2 mg/kg 3.3 1.6 10 03/11/1517:15 03/16/1518:06 7440-02-0 D3 Potassium 8110 mg/kg 654 327 10 03/11/1517:15 03/16/1518:06 7440-09-7 D3 Sodium ND mg/kg 654 327 10 03/11/1517:15 03/16/1518:06 7440-23-5 D3 Strontium 19.4 mg/kg 6.5 3.3 10 03/11/1517:15 03/16/1518:06 7440-24-6 D3 Zinc 103 mg/kg 13.1 6.5 10 03/11/1517:15 03/16/1518:06 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.3 0.65 20 03/11/1517:15 03/12/1511:32 7440-36-0 D3,N2 Arsenic 4.4 mg/kg 3.3 1.6 50 03/11/1517:15 03/12/1511:44 7440-38-2 D3 Beryllium 1.9 mg/kg 1.6 0.78 200 03/11/1517:15 03/12/1512:14 7440-41-7 D3 Cadmium 0.089J mg/kg 0.16 0.078 20 03/11/1517:15 03/12/1511:32 7440-43-9 D3 Cobalt 30.3 mg/kg 3.3 1.6 50 03/11/1517:15 03/12/1511:44 7440-48-4 D4 Lead 10.4 mg/kg 1.3 0.65 20 03/11/1517:15 03/12/1511:32 7439-92-1 D3 Selenium 7.4 mg/kg 3.3 1.6 50 03/11/1517:15 03/12/1511:44 7782-49-2 D3 Thallium 0.76J mg/kg 1.3 0.65 20 03/11/1517:15 03/12/1511:32 7440-28-0 D3 Vanadium 42.5 mg/kg 3.3 1.6 50 03/11/1517:15 03/12/1511:44 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0098 0.0049 1 03/11/1514:40 03/12/1513:52 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 19.1 % 0.10 0.10 1 03/12/15 10:49 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.7 Std. Units 0.10 0.10 1 03/06/15 15:45 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Sulfate 8.9 mg/L 2.5 1.2 1 03/19/1519:57 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Nitrogen, Nitrate 0.35 mg/L 0.25 0.25 1 03/18/15 16:38 H1 4500 Chloride, SPLP Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 03/16/15 14:15 Chloride 5.7J mg/L 6.2 3.1 1 03/19/15 21:02 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030047 Pace Project No.: 92239543 Pace Analytical Services, Inc. 098ni�c yoe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015005866 Lab ID: 92239543006 Collected: 02/27/15 10:40 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride 164J mg/kg 308 154 5 03/10/15 01:56 16887-00-6 Sulfate 154J mg/kg 308 154 5 03/10/15 01:56 14808-79-8 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.8 15.4 5 03/10/15 01:56 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 737 368 1 03/12/15 12:26 7440-44-0 Total Organic Carbon ND mg/kg 738 369 1 03/12/15 12:33 7440-44-0 Total Organic Carbon ND mg/kg 739 370 1 03/12/15 12:38 7440-44-0 Total Organic Carbon ND mg/kg 738 369 1 03/12/15 12:44 7440-44-0 Mean Total Organic Carbon ND mg/kg 738 369 1 03/12/15 12:26 7440-44-0 Surrogates RSD% 2.8 % 1 03/12/1512:26 Date: 04/03/2015 06:51 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 098gwi�c yoe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030047 Pace Project No.: 92239543 Sample: 2015005867 Lab ID: 92239543007 Collected: 02/27/15 11:00 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 27600 mg/kg 55.5 27.8 10 03/11/1517:15 03/16/1518:10 7429-90-5 D3 Barium 310 mg/kg 5.6 2.8 10 03/11/1517:15 03/16/1518:10 7440-39-3 D3 Boron ND mg/kg 27.8 13.9 10 03/11/1517:15 03/16/1518:10 7440-42-8 D3 Calcium 1450 mg/kg 278 139 10 03/11/1517:15 03/16/1518:10 7440-70-2 D3 Chromium 36.3 mg/kg 2.8 1.4 10 03/11/1517:15 03/16/1518:10 7440-47-3 D3 Copper 23.4 mg/kg 2.8 1.4 10 03/11/1517:15 03/16/1518:10 7440-50-8 D3 Iron 44200 mg/kg 22.2 11.1 10 03/11/1517:15 03/16/1518:10 7439-89-6 D3 Magnesium 16200 mg/kg 278 139 10 03/11/1517:15 03/16/1518:10 7439-95-4 D3 Manganese 459 mg/kg 2.8 1.4 10 03/11/1517:15 03/16/1518:10 7439-96-5 D3 Molybdenum ND mg/kg 5.6 2.8 10 03/11/1517:15 03/16/1518:10 7439-98-7 D3 Nickel 28.4 mg/kg 2.8 1.4 10 03/11/1517:15 03/16/1518:10 7440-02-0 D3 Potassium 14300 mg/kg 555 278 10 03/11/1517:15 03/16/1518:10 7440-09-7 D3 Sodium ND mg/kg 555 278 10 03/11/1517:15 03/16/1518:10 7440-23-5 D3 Strontium 9.7 mg/kg 5.6 2.8 10 03/11/1517:15 03/16/1518:10 7440-24-6 D3 Zinc 132 mg/kg 11.1 5.6 10 03/11/1517:15 03/16/1518:10 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.1 0.56 20 03/11/1517:15 03/12/1511:35 7440-36-0 D3,N2 Arsenic 3.7 mg/kg 1.1 0.56 20 03/11/1517:15 03/12/1511:35 7440-38-2 D3 Beryllium ND mg/kg 1.3 0.67 200 03/11/1517:15 03/12/1512:17 7440-41-7 D3 Cadmium 0.068J mg/kg 0.13 0.067 20 03/11/1517:15 03/12/1511:35 7440-43-9 D3 Cobalt 15.7 mg/kg 1.1 0.56 20 03/11/1517:15 03/12/1511:35 7440-48-4 D3 Lead 3.8 mg/kg 1.1 0.56 20 03/11/1517:15 03/12/1511:35 7439-92-1 D3 Selenium 5.0 mg/kg 1.1 0.56 20 03/11/1517:15 03/12/1511:35 7782-49-2 D3 Thallium 0.991 mg/kg 1.1 0.56 20 03/11/1517:15 03/12/1511:35 7440-28-0 D3 Vanadium 55.2 mg/kg 1.1 0.56 20 03/11/1517:15 03/12/1511:35 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0089 0.0045 1 03/11/1514:40 03/12/1513:54 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 7.1 % 0.10 0.10 1 03/12/15 10:50 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.0 Std. Units 0.10 0.10 1 03/06/15 15:45 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Sulfate 4.8 mg/L 2.2 1.1 1 03/19/15 20:11 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Nitrogen, Nitrate 0.32 mg/L 0.22 0.22 1 03/18/15 16:40 B,H1 4500 Chloride, SPLP Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 03/16/15 14:15 Chloride ND mg/L 5.4 2.7 1 03/19/15 21:06 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 33 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15030047 Pace Project No.: 92239543 Pace Analytical Services, Inc. 098gwin�c& oe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015005867 Lab ID: 92239543007 Collected: 02/27/15 11:00 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 268 134 5 03/10/15 02:18 16887-00-6 Sulfate ND mg/kg 268 134 5 03/10/15 02:18 14808-79-8 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 26.8 13.4 5 03/10/15 02:18 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 815 mg/kg 647 324 1 03/12/15 12:54 7440-44-0 Total Organic Carbon 507J mg/kg 649 324 1 03/12/15 13:03 7440-44-0 Total Organic Carbon 880 mg/kg 646 323 1 03/12/15 13:10 7440-44-0 Total Organic Carbon 782 mg/kg 643 322 1 03/12/15 13:18 7440-44-0 Mean Total Organic Carbon 746 mg/kg 646 323 1 03/12/15 12:54 7440-44-0 Surrogates RSD% 22.0 % 1 03/12/1512:54 Date: 04/03/2015 06:51 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 34 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098oi�cfoe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030047 Pace Project No.: 92239543 QC Batch: MERP/12928 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92239543001 METHOD BLANK: 1914231 Matrix: Water Associated Lab Samples: 92239543001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/10/1515:55 LABORATORY CONTROL SAMPLE: 1914232 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.6 91 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1914233 1914234 MS MSD 92239543001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.7 4.7 94 94 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 35 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098m.8foie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030047 Pace Project No.: 92239543 QC Batch: MERP/13070 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92239543003, 92239543004 METHOD BLANK: 1926026 Matrix: Water Associated Lab Samples: 92239543003, 92239543004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/27/1511:30 LABORATORY CONTROL SAMPLE: 1926027 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.8 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1926429 1926430 MS MSD 92242504002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.6 5.0 92 101 75-125 9 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 36 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 0988 i�c& oe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030047 Pace Project No.: 92239543 QC Batch: MERP/5460 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92239543005, 92239543006, 92239543007 METHOD BLANK: 1152887 Matrix: Solid Associated Lab Samples: 92239543005, 92239543006, 92239543007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0080 03/12/1513:27 LABORATORY CONTROL SAMPLE: 1152888 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .08 0.075 94 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1152889 1152890 MS MSD 35177233002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.0048U .0994 .0982 0.097 0.085 94 84 80-120 13 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 37 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030047 Pace Project No.: 92239543 QC Batch: MPRP/23029 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92239543005, 92239543006, 92239543007 METHOD BLANK: 1152987 Matrix: Associated Lab Samples: 92239543005, 92239543006, 92239543007 Blank Parameter Units Result Solid Reporting Limit Analyzed Aluminum mg/kg ND 5.1 03/16/1516:57 Barium mg/kg ND 0.51 03/16/1516:57 Beryllium mg/kg ND 0.051 03/16/1516:57 Boron mg/kg ND 2.6 03/16/1516:57 Calcium mg/kg ND 25.6 03/16/1516:57 Chromium mg/kg ND 0.26 03/16/1516:57 Copper mg/kg ND 0.26 03/16/1516:57 Iron mg/kg 1.6J 2.0 03/16/1516:57 P8 Magnesium mg/kg ND 25.6 03/16/1516:57 Manganese mg/kg 0.55 0.26 03/16/1516:57 P8 Molybdenum mg/kg ND 0.51 03/16/1516:57 Nickel mg/kg ND 0.26 03/16/1516:57 Potassium mg/kg ND 51.1 03/16/1516:57 Sodium mg/kg ND 51.1 03/16/1516:57 Strontium mg/kg ND 0.51 03/16/1516:57 Zinc mg/kg ND 1.0 03/16/1516:57 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1152988 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 125 137 110 80-120 Barium mg/kg 12.5 13.3 107 80-120 Beryllium mg/kg 1.2 1.3 103 80-120 Boron mg/kg 125 127 101 80-120 Calcium mg/kg 624 652 105 80-120 Chromium mg/kg 12.5 12.6 101 80-120 Copper mg/kg 12.5 13.0 104 80-120 Iron mg/kg 125 129 103 80-120 Magnesium mg/kg 624 678 109 80-120 Manganese mg/kg 12.5 12.7 102 80-120 Molybdenum mg/kg 12.5 13.0 104 80-120 Nickel mg/kg 12.5 13.3 107 80-120 Potassium mg/kg 624 621 99 80-120 Sodium mg/kg 624 650 104 80-120 Strontium mg/kg 12.5 12.9 104 80-120 Zinc mg/kg 62.4 64.6 104 80-120 Pace Analytical Services, Inc. 098m.8foie. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 38 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030047 Pace Project No.: 92239543 Pace Analytical Services, Inc. 098m.8foie. Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1152989 MS 35177233002 Spike Parameter Units Result Conc. MSD Spike Conc. 1152990 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Aluminum mg/kg 1580 151 150 2350 2420 513 568 75-125 3 20 M6 Barium mg/kg 6.6 15.1 15 22.8 36.1 107 198 75-125 45 20 M1,R1 Beryllium mg/kg 0.029U 1.47 1.47 1.4 1.4 90 91 75-125 0 20 Boron mg/kg 24.9 151 150 166 164 94 93 75-125 1 20 Calcium mg/kg 216000 756 746 181000 165000 -4590 -6820 75-125 9 20 M6 Chromium mg/kg 5.1 15.1 15 17.4 19.5 81 97 75-125 12 20 Copper mg/kg 18.7 15.1 15 37.1 30.6 122 80 75-125 19 20 Iron mg/kg 6820 151 150 10800 10200 2650 2270 75-125 6 20 M6 Magnesium mg/kg 7720 756 746 7790 7840 9 15 75-125 1 20 M6 Manganese mg/kg 32.9 15.1 15 60.1 53.2 180 136 75-125 12 20 M1 Molybdenum mg/kg 0.74 15.1 15 14.9 15.9 94 101 75-125 6 20 Nickel mg/kg 1.1 15.1 15 15.7 15.0 96 93 75-125 5 20 Potassium mg/kg 295U 756 746 1080 1100 113 116 75-125 2 20 Sodium mg/kg 5230 756 746 5820 5280 78 7 75-125 10 20 M6 Strontium mg/kg 3080 15.1 15 2580 2310 -3310 -5130 75-125 11 20 M6 Zinc mg/kg 23.6 75.6 74.6 104 95.1 106 96 75-125 9 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 39 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030047 Pace Project No.: 92239543 QC Batch: MPRP/23030 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92239543005, 92239543006, 92239543007 METHOD BLANK: 1152995 Matrix: Solid LCS Result Associated Lab Samples: 92239543005, 92239543006, 92239543007 mg/kg 2.5 2.5 101 Blank Reporting mg/kg Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 03/12/1510:42 N2 Arsenic mg/kg ND 0.051 03/12/1510:42 Beryllium mg/kg ND 0.0061 03/12/1510:42 Cadmium mg/kg ND 0.0061 03/12/1510:42 Cobalt mg/kg ND 0.051 03/12/1510:42 Lead mg/kg ND 0.051 03/12/1510:42 Selenium mg/kg ND 0.051 03/12/1510:42 Thallium mg/kg ND 0.051 03/12/1510:42 Vanadium mg/kg ND 0.051 03/12/1510:42 Pace Analytical Services, Inc. 098mc& oe. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1152996 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.5 101 80-120 N2 Arsenic mg/kg 2.5 2.6 102 80-120 Beryllium mg/kg .25 0.27 106 80-120 Cadmium mg/kg .25 0.25 100 80-120 Cobalt mg/kg 2.5 2.6 102 80-120 Lead mg/kg 2.5 2.6 103 80-120 Selenium mg/kg 2.5 2.6 103 80-120 Thallium mg/kg 2.5 2.6 102 80-120 Vanadium mg/kg 2.5 2.5 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1152997 MS 92239594001 Spike Parameter Units Result Conc. MSD Spike Conc. 1152998 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Antimony mg/kg ND 3.02 2.79 1.9 1.7 59 58 75-125 11 20 D3,M6, N2 Arsenic mg/kg 2.8 3.02 2.79 4.9 5.3 69 89 75-125 6 20 D3,M6 Beryllium mg/kg ND .302 .279 0.41 0.37 104 104 75-125 8 20 D3 Cadmium mg/kg 0.33 .302 .279 0.67 0.58 113 92 75-125 15 20 D3 Cobalt mg/kg ND 3.02 2.79 3.9 3.7 110 114 75-125 5 20 D3 Lead mg/kg 13.9 3.02 2.79 17.9 14.9 132 35 75-125 19 20 D3,M6 Selenium mg/kg ND 3.02 2.79 2.8 2.5 69 66 75-125 10 20 D3,M6 Thallium mg/kg ND 3.02 2.79 3.0 2.8 93 98 75-125 4 20 D3 Vanadium mg/kg 18.5 3.02 2.79 22.2 24.8 122 232 75-125 11 20 D3,M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 40 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030047 Pace Project No.: 92239543 QC Batch: MPRP/52837 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92239543001 METHOD BLANK: 1914175 Associated Lab Samples: 92239543001 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 03/10/15 07:50 ND 0.50 03/10/15 07:50 ND 0.50 03/10/15 07:50 ND 0.30 03/10/15 07:50 ND 0.20 03/10/15 07:50 ND 5.0 03/10/15 07:50 ND 0.080 03/10/15 07:50 ND 40.0 03/10/15 07:50 ND 0.50 03/10/15 07:50 ND 0.50 03/10/15 07:50 ND 1.0 03/10/15 07:50 ND 50.0 03/10/15 07:50 ND 0.10 03/10/15 07:50 ND 10.0 03/10/15 07:50 ND 0.50 03/10/15 07:50 ND 0.50 03/10/15 07:50 ND 0.50 03/10/15 07:50 ND 50.0 03/10/15 07:50 ND 0.50 03/10/15 07:50 ND 50.0 03/10/15 07:50 ND 0.50 03/10/15 07:50 ND 0.10 03/10/15 07:50 ND 1.0 03/10/15 07:50 ND 5.0 03/10/15 07:50 Qualifiers Pace Analytical Services, Inc. 098m.8foie. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1914176 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 86.3 108 80-120 Antimony ug/L 80 85.1 106 80-120 Arsenic ug/L 80 84.9 106 80-120 Barium ug/L 80 83.6 104 80-120 Beryllium ug/L 80 85.6 107 80-120 Boron ug/L 80 86.0 107 80-120 Cadmium ug/L 80 87.1 109 80-120 Calcium ug/L 1000 1070 107 80-120 Chromium ug/L 80 87.8 110 80-120 Cobalt ug/L 80 87.9 110 80-120 Copper ug/L 80 90.4 113 80-120 Iron ug/L 1000 1100 110 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 41 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098m.8foie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030047 Pace Project No.: 92239543 LABORATORY CONTROL SAMPLE: 1914176 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 87.6 110 80-120 Magnesium ug/L 1000 1090 109 80-120 Manganese ug/L 80 87.1 109 80-120 Molybdenum ug/L 80 85.2 107 80-120 Nickel ug/L 80 88.7 111 80-120 Potassium ug/L 1000 1050 105 80-120 Selenium ug/L 80 84.3 105 80-120 Sodium ug/L 1000 1090 109 80-120 Strontium ug/L 80 84.1 105 80-120 Thallium ug/L 80 88.8 111 80-120 Vanadium ug/L 80 85.9 107 80-120 Zinc ug/L 80 87.3 109 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1914177 1914178 MS MSD 92239543001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 37.6 80 80 126 126 111 111 75-125 0 20 Antimony ug/L ND 80 80 84.5 80.8 105 101 75-125 4 20 Arsenic ug/L ND 80 80 85.0 82.7 106 103 75-125 3 20 Barium ug/L 1.0 80 80 83.2 81.7 103 101 75-125 2 20 Beryllium ug/L ND 80 80 84.4 84.1 106 105 75-125 0 20 Boron ug/L ND 80 80 87.1 88.9 108 110 75-125 2 20 Cadmium ug/L ND 80 80 87.3 85.3 109 107 75-125 2 20 Calcium ug/L 529 1000 1000 1580 1590 105 106 75-125 1 20 Chromium ug/L 0.50 80 80 87.8 86.0 109 107 75-125 2 20 Cobalt ug/L ND 80 80 84.8 82.9 106 104 75-125 2 20 Copper ug/L ND 80 80 90.9 89.3 112 110 75-125 2 20 Iron ug/L 117 1000 1000 1220 1190 110 108 75-125 2 20 Lead ug/L 0.20 80 80 86.9 84.0 108 105 75-125 3 20 Magnesium ug/L 25.0 1000 1000 1120 1100 110 107 75-125 2 20 Manganese ug/L 3.0 80 80 89.8 88.4 109 107 75-125 2 20 Molybdenum ug/L 2.0 80 80 85.7 83.9 105 102 75-125 2 20 Nickel ug/L 0.61 80 80 88.9 87.5 110 109 75-125 2 20 Potassium ug/L 79.1 1000 1000 1110 1090 103 101 75-125 2 20 Selenium ug/L ND 80 80 83.9 83.6 105 104 75-125 0 20 Sodium ug/L ND 1000 1000 1110 1080 107 104 75-125 3 20 Strontium ug/L 0.90 80 80 84.5 82.9 105 103 75-125 2 20 Thallium ug/L ND 80 80 86.5 83.3 108 104 75-125 4 20 Vanadium ug/L ND 80 80 84.5 83.1 105 104 75-125 2 20 Zinc ug/L ND 80 80 87.9 90.4 105 108 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 42 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030047 Pace Project No.: 92239543 QC Batch: MPRP/53204 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92239543003 METHOD BLANK: 1926001 Associated Lab Samples: 92239543003 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 03/27/1512:28 ND 0.50 03/27/1512:28 ND 0.50 03/27/1512:28 0.94 0.30 03/27/1512:28 ND 0.20 03/27/1512:28 ND 5.0 03/27/1512:28 ND 0.080 03/27/1512:28 ND 40.0 03/27/1512:28 ND 0.50 03/27/1512:28 ND 0.50 03/27/1512:28 ND 1.0 03/27/1512:28 ND 50.0 03/27/1512:28 ND 0.10 03/27/1512:28 ND 10.0 03/27/1512:28 0.54 0.50 03/27/1512:28 ND 0.50 03/27/1512:28 ND 0.50 03/27/1512:28 ND 50.0 03/27/1512:28 ND 0.50 03/27/1512:28 ND 50.0 03/27/1512:28 ND 0.50 03/27/1512:28 ND 0.10 03/27/1512:28 ND 1.0 03/27/1512:28 ND 5.0 03/27/1512:28 Qualifiers Pace Analytical Services, Inc. 098onyoe. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1926002 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 89.4 112 80-120 Antimony ug/L 80 82.2 103 80-120 Arsenic ug/L 80 81.9 102 80-120 Barium ug/L 80 84.5 106 80-120 Beryllium ug/L 80 86.3 108 80-120 Boron ug/L 80 90.3 113 80-120 Cadmium ug/L 80 87.9 110 80-120 Calcium ug/L 1000 1100 110 80-120 Chromium ug/L 80 88.3 110 80-120 Cobalt ug/L 80 86.5 108 80-120 Copper ug/L 80 85.2 107 80-120 Iron ug/L 1000 1120 112 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 43 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 09Q�Ijinic& oe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030047 Pace Project No.: 92239543 LABORATORY CONTROL SAMPLE: 1926002 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 85.3 107 80-120 Magnesium ug/L 1000 1070 107 80-120 Manganese ug/L 80 89.1 111 80-120 Molybdenum ug/L 80 84.9 106 80-120 Nickel ug/L 80 87.3 109 80-120 Potassium ug/L 1000 1090 109 80-120 Selenium ug/L 80 86.0 107 80-120 Sodium ug/L 1000 1100 110 80-120 Strontium ug/L 80 83.6 105 80-120 Thallium ug/L 80 89.4 112 80-120 Vanadium ug/L 80 86.6 108 80-120 Zinc ug/L 80 87.5 109 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1926003 1926004 MS MSD 92242504001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L ND 80 80 89.9 142 109 175 75-125 45 20 M1,R1 Antimony ug/L ND 80 80 81.2 81.4 102 102 75-125 0 20 Arsenic ug/L ND 80 80 81.7 81.2 102 102 75-125 1 20 Barium ug/L ND 80 80 85.9 85.0 107 106 75-125 1 20 Beryllium ug/L ND 80 80 83.8 84.4 105 105 75-125 1 20 Boron ug/L ND 80 80 90.3 92.7 113 116 75-125 3 20 Cadmium ug/L ND 80 80 89.1 87.7 111 110 75-125 2 20 Calcium ug/L ND 1000 1000 1080 1140 107 113 75-125 6 20 Chromium ug/L ND 80 80 88.2 88.0 110 110 75-125 0 20 Cobalt ug/L ND 80 80 88.4 87.7 110 110 75-125 1 20 Copper ug/L ND 80 80 86.3 85.6 108 107 75-125 1 20 Iron ug/L ND 1000 1000 1120 1120 112 111 75-125 0 20 Lead ug/L ND 80 80 85.2 84.3 107 105 75-125 1 20 Magnesium ug/L ND 1000 1000 1080 1080 107 107 75-125 0 20 Manganese ug/L ND 80 80 89.1 90.6 111 113 75-125 2 20 Molybdenum ug/L ND 80 80 85.0 83.5 106 104 75-125 2 20 Nickel ug/L ND 80 80 88.6 88.6 111 111 75-125 0 20 Potassium ug/L ND 1000 1000 1080 1080 108 108 75-125 1 20 Selenium ug/L ND 80 80 84.5 83.2 106 104 75-125 2 20 Sodium ug/L ND 1000 1000 1100 1110 110 111 75-125 1 20 Strontium ug/L ND 80 80 84.0 82.6 105 103 75-125 2 20 Thallium ug/L ND 80 80 89.2 88.8 111 111 75-125 0 20 Vanadium ug/L ND 80 80 86.5 86.2 108 108 75-125 0 20 Zinc ug/L ND 80 80 89.8 121 111 150 75-125 30 20 M1,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 44 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030047 Pace Project No.: 92239543 QC Batch: MPRP/53309 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92239543004 METHOD BLANK: 1929565 Associated Lab Samples: 92239543004 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 04/02/15 09:30 ND 0.50 04/02/15 09:30 ND 0.50 04/02/15 09:30 ND 0.30 04/02/15 09:30 ND 0.20 04/02/15 09:30 ND 5.0 04/02/15 09:30 ND 0.080 04/02/15 09:30 ND 40.0 04/02/15 09:30 ND 0.50 04/02/15 09:30 ND 0.50 04/02/15 09:30 ND 1.0 04/02/15 09:30 ND 50.0 04/02/15 09:30 ND 0.10 04/02/15 09:30 ND 10.0 04/02/15 09:30 ND 0.50 04/02/15 09:30 ND 0.50 04/02/15 09:30 ND 0.50 04/02/15 09:30 ND 50.0 04/02/15 09:30 ND 0.50 04/02/15 09:30 ND 50.0 04/02/15 09:30 ND 0.50 04/02/15 09:30 ND 0.10 04/02/15 09:30 ND 1.0 04/02/15 09:30 ND 5.0 04/02/15 09:30 Qualifiers Pace Analytical Services, Inc. 098onyoe. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1929566 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 79.6 99 80-120 Antimony ug/L 80 77.6 97 80-120 Arsenic ug/L 80 77.6 97 80-120 Barium ug/L 80 77.0 96 80-120 Beryllium ug/L 80 77.9 97 80-120 Boron ug/L 80 85.6 107 80-120 Cadmium ug/L 80 79.2 99 80-120 Calcium ug/L 1000 933 93 80-120 Chromium ug/L 80 79.6 99 80-120 Cobalt ug/L 80 78.1 98 80-120 Copper ug/L 80 92.9 116 80-120 Iron ug/L 1000 993 99 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 45 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098nnyoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030047 Pace Project No.: 92239543 LABORATORY CONTROL SAMPLE: 1929566 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 83.2 104 80-120 Magnesium ug/L 1000 995 99 80-120 Manganese ug/L 80 79.5 99 80-120 Molybdenum ug/L 80 77.6 97 80-120 Nickel ug/L 80 80.3 100 80-120 Potassium ug/L 1000 973 97 80-120 Selenium ug/L 80 76.6 96 80-120 Sodium ug/L 1000 982 98 80-120 Strontium ug/L 80 76.8 96 80-120 Thallium ug/L 80 79.5 99 80-120 Vanadium ug/L 80 79.2 99 80-120 Zinc ug/L 80 80.7 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1929567 1929569 MS MSD 92241387014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 183 80 80 279 292 120 136 75-125 4 20 M1 Antimony ug/L ND 80 80 76.4 76.1 95 95 75-125 0 20 Arsenic ug/L 0.61 80 80 75.6 76.7 94 95 75-125 1 20 Barium ug/L 409 80 80 498 502 110 116 75-125 1 20 Beryllium ug/L ND 80 80 77.9 77.3 97 97 75-125 1 20 Boron ug/L 138 80 80 235 236 121 122 75-125 0 20 Cadmium ug/L ND 80 80 76.4 76.6 95 96 75-125 0 20 Calcium ug/L 791 1000 1000 1720 1790 93 100 75-125 4 20 Chromium ug/L 6.0 80 80 83.8 83.7 97 97 75-125 0 20 Cobalt ug/L 2.5 80 80 78.2 79.1 95 96 75-125 1 20 Copper ug/L 9.9 80 80 86.9 88.1 96 98 75-125 1 20 Iron ug/L 134 1000 1000 1090 1100 95 96 75-125 1 20 Lead ug/L 3.0 80 80 83.8 84.1 101 101 75-125 0 20 Magnesium ug/L 350 1000 1000 1320 1320 97 97 75-125 0 20 Manganese ug/L 54.7 80 80 131 132 96 96 75-125 0 20 Molybdenum ug/L 1.9 80 80 77.2 78.6 94 96 75-125 2 20 Nickel ug/L 3.5 80 80 81.4 81.2 97 97 75-125 0 20 Potassium ug/L 2090 1000 1000 3080 3130 99 104 75-125 2 20 Selenium ug/L ND 80 80 74.2 75.9 92 94 75-125 2 20 Sodium ug/L 2280 1000 1000 3330 3360 104 108 75-125 1 20 Strontium ug/L 11.6 80 80 86.6 87.2 94 94 75-125 1 20 Thallium ug/L ND 80 80 78.9 79.6 99 99 75-125 1 20 Vanadium ug/L ND 80 80 78.2 77.9 97 96 75-125 0 20 Zinc ug/L 212 80 80 300 305 110 116 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 46 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098mc& oe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030047 Pace Project No.: 92239543 QC Batch: PMST/3333 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92239543005, 92239543006, 92239543007 SAMPLE DUPLICATE: 1154050 35177015001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 99.3 99.3 0 10 SAMPLE DUPLICATE: 1154051 35178192001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 1.9 28 10 D6 SAMPLE DUPLICATE: 1154052 92239543006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 19.1 18.1 5 10 SAMPLE DUPLICATE: 1154053 35178862005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 5.1 4.9 5 10 SAMPLE DUPLICATE: 1154054 35178887002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 19.0 17.1 11 10 D6 SAMPLE DUPLICATE: 1154055 35178914008 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 8.7 8.3 4 10 SAMPLE DUPLICATE: 1154056 35178914018 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 4.7 4.9 5 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 47 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030047 Pace Project No.: 92239543 QC Batch: WET/36041 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92239543006, 92239543007 Pace Analytical Services, Inc. 098nnyoe. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1403559 92239540001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.1 5.1 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 48 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030047 Pace Project No.: 92239543 QC Batch: WET/36319 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92239543005 SAMPLE DUPLICATE: 1414757 Parameter pH at 25 Degrees C 92239543005 Dup Units Result Result Std. Units 5.4 5.6 Pace Analytical Services, Inc. 098onyoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Max RPD RPD Qualifiers 4 10 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 49 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 0988 i .8foie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030047 Pace Project No.: 92239543 QC Batch: WETA/22270 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92239543006, 92239543007 METHOD BLANK: 1415171 Matrix: Water Associated Lab Samples: 92239543006, 92239543007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L ND 2.0 03/19/1518:22 LABORATORY CONTROL SAMPLE: 1415172 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 18.7 94 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415173 1415174 MS MSD 92239540001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 3.5 24 24 25.8 25.8 93 93 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415175 1415176 MS MSD 92240158010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 3.0 25.5 25.5 26.8 26.8 93 93 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 50 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098ogc yoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030047 Pace Project No.: 92239543 QC Batch: WETA/22256 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92239543006, 92239543007 METHOD BLANK: 1413768 Matrix: Water Associated Lab Samples: 92239543006, 92239543007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.22 0.020 03/18/15 16:20 B LABORATORY CONTROL SAMPLE: 1413769 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1413770 1413771 MS MSD 92239540001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.41 3 3 3.3 3.3 95 95 90-110 0 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1413772 1413773 MS MSD 92239540002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.33 2.9 2.9 3.2 3.2 98 98 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 51 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098onyoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030047 Pace Project No.: 92239543 QC Batch: WETA/22273 Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 92239543006, 92239543007 METHOD BLANK: 1415463 Matrix: Water Associated Lab Samples: 92239543006, 92239543007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 03/19/15 20:57 LABORATORY CONTROL SAMPLE: 1415464 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.4 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415465 1415466 MS MSD 92239540003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 23.9 23.9 24.7 24.6 101 101 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415467 1415468 MS MSD 92239543006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 5.7J 24.7 24.7 31.0 30.7 102 101 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 52 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15030047 Pace Project No.: 92239543 QC Batch: WETA/44361 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92239543005, 92239543006, 92239543007 METHOD BLANK: 1150712 1150713 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1150715 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.4 03/09/15 22:58 Sulfate mg/kg ND 49.4 03/09/15 22:58 LABORATORY CONTROL SAMPLE: 1150713 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1150715 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1150714 Parameter Chloride Sulfate Pace Analytical Services, Inc. 098oi�c yoe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 495 509 103 80-120 495 502 101 80-120 92239543005 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 662 563 68 80-120 M1 ND 662 741 96 80-120 92239543005 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 53 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098oinlc& oe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030047 Pace Project No.: 92239543 QC Batch: WETA/44360 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92239543005, 92239543006, 92239543007 METHOD BLANK: 1150708 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 4.9 03/09/15 22:58 LABORATORY CONTROL SAMPLE: 1150709 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.5 51.1 103 80-120 MATRIX SPIKE SAMPLE: 1150711 92239543005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 66.2 58.8 84 80-120 H3 SAMPLE DUPLICATE: 1150710 92239543005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 54 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098oi�c yoe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030047 Pace Project No.: 92239543 QC Batch: WETA/27532 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92239543005, 92239543006, 92239543007 METHOD BLANK: 1125810 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 03/12/15 07:13 LABORATORY CONTROL SAMPLE: 1125811 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 121000 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1125812 1125813 MS MSD 92239539001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 4370 7510 7510 10200 9980 77 75 50-150 2 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1125814 1125815 MS MSD 92239540001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 2000 6010 6010 7060 7300 84 88 50-150 3 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 55 of 60 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15030047 Pace Project No.: 92239543 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, Inc. 098oi�c yoe. Suite 100 y Huntersville, NC 28078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 56 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030047 Pace Project No.: 92239543 Pace Analytical Services, Inc. 098mc& oe. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92239543005 2015005865 EPA 3050 MPRP/23029 EPA 6010 92239543006 2015005866 EPA 3050 MPRP/23029 EPA 6010 92239543007 2015005867 EPA 3050 MPRP/23029 EPA 6010 92239543005 2015005865 EPA 3050 MPRP/23030 EPA 6020 92239543006 2015005866 EPA 3050 MPRP/23030 EPA 6020 92239543007 2015005867 EPA 3050 MPRP/23030 EPA 6020 92239543001 2015005864 EPA 3020 MPRP/52837 EPA 6020A 92239543003 2015005866 SPLP EPA 3020 MPRP/53204 EPA 6020A 92239543004 2015005867 SPLP EPA 3020 MPRP/53309 EPA 6020A 92239543001 2015005864 EPA 7470 MERP/12928 EPA 7470 92239543003 2015005866 SPLP EPA 7470 MERP/13070 EPA 7470 92239543004 2015005867 SPLP EPA 7470 MERP/13070 EPA 7470 92239543005 2015005865 EPA 7471 MERP/5460 EPA 7471 92239543006 2015005866 EPA 7471 MERP/5460 EPA 7471 92239543007 2015005867 EPA 7471 MERP/5460 EPA 7471 92239543005 2015005865 ASTM D2974-87 PMST/3333 92239543006 2015005866 ASTM D2974-87 PMST/3333 92239543007 2015005867 ASTM D2974-87 PMST/3333 92239543005 2015005865 EPA 9045 WET/36319 92239543006 2015005866 EPA 9045 WET/36041 92239543007 2015005867 EPA 9045 WET/36041 92239543006 2015005866 EPA 300.0 WETA/22270 92239543007 2015005867 EPA 300.0 WETA/22270 92239543006 2015005866 EPA 353.2 WETA/22256 92239543007 2015005867 EPA 353.2 WETA/22256 92239543006 2015005866 SM 4500 -CI -E WETA/22273 92239543007 2015005867 SM 4500 -CI -E WETA/22273 92239543005 2015005865 EPA 9056 WETA/44361 92239543006 2015005866 EPA 9056 WETA/44361 92239543007 2015005867 EPA 9056 WETA/44361 92239543005 2015005865 EPA 9056 WETA/44360 92239543006 2015005866 EPA 9056 WETA/44360 92239543007 2015005867 EPA 9056 WETA/44360 92239543005 2015005865 EPA 9060 WETA/27532 92239543005 2015005865 EPA 9060 WETA/27533 92239543006 2015005866 EPA 9060 WETA/27532 92239543006 2015005866 EPA 9060 WETA/27533 92239543007 2015005867 EPA 9060 WETA/27532 Date: 04/03/2015 06:51 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14090 ICP/14090 ICP/14090 ICPM/9396 ICPM/9396 ICPM/9396 ICPM/23421 ICPM/23569 ICPM/23628 MERC/15006 MERC/15182 MERC/15182 MERC/5450 MERC/5450 MERC/5450 Page 57 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030047 Pace Project No.: 92239543 Pace Analytical Services, Inc. 098oi�c yoe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92239543007 2015005867 EPA 9060 WETA/27533 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/03/2015 06:51 AM without the written consent of Pace Analytical Services, Inc.. Page 58 of 60 IU IIIII II IIIIN 111111 £b96EZZ6:#OM — (saauleluoo pen0oul Page 66 of 68 `ducal jo Ino 'anllenaaswd loemou! 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N n +� a m � �r • 0 � n CL - yn n y47 9 I F> o i tfr © SAyCJ j Jr j 4 �vAjlIIt 0= �?i3t g IU4JrC°mp nO A tllys eq Ire > % v9 .ryaRcaTotal Metals Anions, o I w v } pH n r-jf I- i- 8 oz jar (PACS) 5 v I oil a TOC 1- 4 oz jar 4 3 c (PACS) m ! 1 O!. c� SPLP - Total Metals p M 9� and Anions A 2.8 oz jars (PACS) a i Sediment spocific I tests 2 - 8 oz jar I (ACCESS I!I ANALYTICAL) 5 $ ti I '• —�—P m I N �F-_ 1�'- O a 0rC s p z 0 I I I t 'I eO .y u a `.-` X`rotal # of Containers C' Pag 67 If 6J -n w 1" i"I h � O 7 --el CL � all ' <n� y N I I i ni a 4 I c C) Id_° Ol I din L^X rl i� l b j? co w U2t Iw in -n I a p I ' v 5 i` •— H �!horyo `2 i- y� n 0 i CL - yn n y47 9 I F> o i tfr © SAyCJ j Jr j 4 �vAjlIIt 0= �?i3t g IU4JrC°mp nO A tllys eq Ire > % v9 .ryaRcaTotal Metals Anions, o I w v } pH n r-jf I- i- 8 oz jar (PACS) 5 v I oil a TOC 1- 4 oz jar 4 3 c (PACS) m ! 1 O!. c� SPLP - Total Metals p M 9� and Anions A 2.8 oz jars (PACS) a i Sediment spocific I tests 2 - 8 oz jar I (ACCESS I!I ANALYTICAL) 5 $ ti I '• —�—P m I N �F-_ 1�'- O a 0rC s p z 0 I I I t 'I eO .y u a `.-` X`rotal # of Containers C' CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM Page 68 of 68 mai}y.. DUKE Analytical Laboratory Services i i 1 I Analytical Laborato Use Only i 1 Page 1 of 1 NC_x_ WortOrder Accepted By: Data! ime 33 1 Mail Code MG03A2 (Building 7405) 13339 Hagers Ferry Rd ^n j 1SD3o0 Matrix: SOIL sC_ 1 DISTRIBUTION OH— ENERGY i i Huntersville, N. C. 28078 I iLoppw Samples Originating From I ORIGINAL to LAB, ! By DeMSTMIe t, (980)875.5245 i iI (J-- /1,5— COPY to CLIENT ............. Fax�980Z875_4349_ _ ... ,..... i '-3 6 SAMPLE PROGRAM Ground Water_ NPDESi Other Plant i REV DATE 2/1012015 1 Pro ct Name I 1e AB Groundwater Assessment Soil 2 Phone No: ) iVendor i Asheville ! PACE Cooler Tem C 5eery-:1= P011420810, 3)Cllem AB GW '""°` 3 i one u) y u1 'n 5)13usiness Unit: 6)Project ID: 7)Mall Code: o complete `!4:M3:1x41,�_ .,—�,m _--,..-_,-�. jt'p c 8) Operating Unit: 9)Ac2ivlty ID: 10)Proceas ID ::: Q U a T. N E a p J d U Important: When specific accounting has been established and is not indicated abo- Preservatives when used must be tp CL we need the following: 1) Enter correct accounting in all 5 accounting fields above, or added within 15 minutes of sample i C ` to oo U y at 2 Provide correct accountin for Operating Unit and Process ID. collection d N 14Collection Information ll.l � O � C N r in (13 .o Q _ •k O - _.._.._.._.._ 1 LAB USE ONLY •I Matrix 1 1 i "Lab ID i (So{I, Sediment, Ash) 13Sam le Description or ID .,. , Date Time Signature ~ t2 �" O d , t% c0 N N N V Q Q �y ✓ _ ��J !'C J�i� W�� JFK I•s ['EL /L�i �W�'Dd — -- Saki MW-O$S2- Z7 1100 J 1 a ii b'�% is 1 1� i is .e I is :d 1 IE 1 lu 1 1N i-1 t I 1 1 I 1 1 �i ! ! WATER EQUIPMENT BLANK 1 PER DAY 21)Relinqulehed DaterTime Accepted By: Date/Time 722 Requested Turnaround Relinquished By Date/Time dt' �r Accepted By: Data! ime 33 1 14 Days _ _ _ _ x_ Relinquished By Dat lm e Act; e B DatNT am '7 Days Sealecl/LoOa 13.1161TInji SealedA o pen y DateRlme 48 Hr 24)Commente Metals: Al, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Mercury, pH Anions: Cl, Nitrate -N, SO4 Sediment Specific Parameters: %Solids CEC, Particle Size Distribution, Redox Potential `other ___ 24 I* _ 'Add Cost Will �