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Home My WebLink AboutNC0000396_J15020367 Report_20150823DUE Analytical Laboratory Page 1of73 ' ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report J15020367 AB GW ASSESSMENT SOIL Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker 200 CP and L Drive Arden,NC 28704 Margaret Galvin -Karr Phone: 980-875-5219 L marge.galvin-karr@duke- V �¢:;'GY 2015.0.18 Date: I�4CK 2015.03.18 12:55:43-04'00' Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 3/10/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description Page 2 of 73 2015004085 ASHEVILLE 06 -Feb -15 10:30 AM Synterra Equipment Blank 2015004090 ASHEVILLE 06 -Feb -15 11:00 AM Synterra MW -15 5B (1.5-2) 2015004091 ASHEVILLE 06 -Feb -15 11:00 AM Synterra MW -15 5B (1.5-2) Dup 2015004092 ASHEVILLE 06 -Feb -15 12:05 PM Synterra MW -15 5B (14-14.5) 2015004093 ASHEVILLE 06 -Feb -15 12:25 PM Synterra MW -15 513 (33.5-34) 2015004094 ASHEVILLE 12 -Feb -15 8:15 AM Synterra Equipment Blank 2015004095 ASHEVILLE 12 -Feb -15 8:45 AM Synterra MW -17 5B (1.5-2) 2015004096 ASHEVILLE 12 -Feb -15 8:50 AM Synterra MW -17 5B (6.5-7) 2015004097 ASHEVILLE 12 -Feb -15 10:30 AM Synterra MW -17 5B (8.5-9) 9 Total Samples Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: LU Job Summary Report ❑ Sample Identification P/1 Technical Validation of Data Package J❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Page 3 of 73 LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries d❑ Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 3/10/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020367 Site: Equipment Blank Collection Date: 06 -Feb -15 10:30 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015004085 Matrix: SOIL Page 4 of 73 Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020367 Site: MW -15 5B (1.5-2) Collection Date: 06 -Feb -15 11:00 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 5 of 73 Sample #: 2015004090 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020367 Site: MW -15 5B (1.5-2) Dup Collection Date: 06 -Feb -15 11:00 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 6 of 73 Sample #: 2015004091 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020367 Site: MW -15 5B (14-14.5) Collection Date: 06 -Feb -15 12:05 PM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 7 of 73 Sample #: 2015004092 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020367 Site: MW -15 5B (33.5-34) Collection Date: 06 -Feb -15 12:25 PM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 8 of 73 Sample #: 2015004093 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis Page 9 of 73 This report shall not be reproduced, except in full. Order # J15020367 Site: Equipment Blank Collection Date: 12 -Feb -15 8:15 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015004094 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020367 Site: MW -17 5B (1.5-2) Collection Date: 12 -Feb -15 8:45 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 10 of 73 Sample #: 2015004095 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020367 Site: MW -17 5B (6.5-7) Collection Date: 12 -Feb -15 8:50 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 11 of 73 Sample #: 2015004096 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020367 Site: MW -17 5B (8.5-9) Collection Date: 12 -Feb -15 10:30 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 12 of 73 Sample #: 2015004097 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE aceAnaiXical www.pacelabs.com March 04, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 09Qgff�i�c&fie. Suite 100 y Huntersville, INC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on February 16, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy HiQ p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 60 lacmnalyfica( www.pacelabs.com Project: J15020367 Pace Project No.: 92237903 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21 -A Certification #: 2926.01 Alaska Certification #: UST -078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ -0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH -0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. 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Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN -002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity New York Certification #: 11888 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 60 aceAnaiXical www.pacelabs.com Project: J15020367 Pace Project No.: 92237903 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 09Qgff�i�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Page 3 of 60 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15020367 Pace Project No.: 92237903 Lab ID Sample ID Matrix Date Collected Date Received 92237903001 2015004085 Water 02/06/1510:30 02/16/1514:30 92237903002 2015004094 Water 02/12/15 08:15 02/16/15 14:30 92237903003 2015004090 Solid 02/06/1511:00 02/16/1514:30 92237903004 2015004091 Solid 02/06/1511:00 02/16/1514:30 92237903005 2015004092 Solid 02/06/1512:05 02/16/1514:30 92237903006 2015004093 Solid 02/06/1512:25 02/16/1514:30 92237903007 2015004095 Solid 02/12/15 08:45 02/16/15 14:30 92237903008 2015004096 Solid 02/12/15 08:50 02/16/15 14:30 92237903009 2015004097 Solid 02/12/1510:30 02/16/1514:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 09Qgff�i�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Page 4 of 60 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 09Qgfflic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15020367 92237903 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92237903001 2015004085 EPA 6010 WBS 14 PASI-M EPA 6020 RJS 10 PASI-M EPA 7470 LMW 1 PASI-M 92237903002 2015004094 EPA 6010 WBS 14 PASI-M EPA 6020 RJS 10 PASI-M EPA 7470 LMW 1 PASI-M 92237903003 2015004090 EPA 6010 TAP 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237903004 2015004091 EPA 6010 TAP 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237903005 2015004092 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237903006 2015004093 EPA 6010 CKJ, TAP 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 60 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 09Qgffligc&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 9045 MLS 1 PASI-A EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237903007 2015004095 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237903008 2015004096 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237903009 2015004097 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 60 aceAnaiXical www.pacelabs.com Project: J15020367 Pace Project No.: 92237903 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 09Qgffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92237903001 2015004085 EPA 6010 Aluminum 1420 ug/L 200 02/23/15 10:38 EPA 6010 Barium 15.3 ug/L 10.0 02/23/15 10:38 EPA 6010 Calcium 27200 ug/L 500 02/23/15 10:38 EPA 6010 Iron 1510 ug/L 50.0 02/23/15 10:38 EPA 6010 Magnesium 523 ug/L 500 02/23/15 10:38 EPA 6010 Manganese 31.5 ug/L 5.0 02/23/15 10:38 EPA 6010 Zinc 42.6 ug/L 20.0 02/23/15 10:38 EPA 6020 Antimony 0.76 ug/L 0.50 02/23/15 17:35 EPA 6020 Arsenic 1.1 ug/L 0.50 02/23/15 17:35 EPA 6020 Beryllium 0.20 ug/L 0.20 02/23/15 17:35 EPA 6020 Cobalt 0.91 ug/L 0.50 02/23/15 17:35 EPA 6020 Lead 2.1 ug/L 0.10 02/23/15 17:35 EPA 6020 Strontium 50.8 ug/L 0.50 02/23/15 17:35 EPA 6020 Vanadium 5.1 ug/L 1.0 02/23/15 17:35 92237903002 2015004094 EPA 6010 Iron 678 ug/L 50.0 02/23/15 10:53 EPA 6010 Manganese 12.4 ug/L 5.0 02/23/15 10:53 EPA 6020 Arsenic 1.1 ug/L 0.50 02/23/15 17:40 EPA 6020 Lead 0.17 ug/L 0.10 02/23/15 17:40 EPA 6020 Strontium 1.4 ug/L 0.50 02/23/15 17:40 92237903003 2015004090 EPA 6010 Aluminum 10200 mg/kg 7.9 02/24/15 16:17 EPA 6010 Barium 59.9 mg/kg 0.79 02/24/15 16:17 EPA 6010 Calcium 218 mg/kg 39.6 02/24/15 16:17 EPA 6010 Chromium 7.9 mg/kg 0.40 02/24/15 16:17 EPA 6010 Copper 4.0 mg/kg 0.40 02/24/15 16:17 EPA 6010 Iron 8710 mg/kg 3.2 02/24/15 16:17 EPA 6010 Magnesium 1840 mg/kg 39.6 02/24/15 16:17 EPA 6010 Manganese 161 mg/kg 0.40 02/24/15 16:17 EPA 6010 Nickel 4.5 mg/kg 0.40 02/24/15 16:17 EPA 6010 Potassium 1050 mg/kg 79.2 02/24/15 16:17 EPA 6010 Strontium 2.3 mg/kg 0.79 02/24/15 16:17 EPA 6010 Zinc 30.0 mg/kg 1.6 02/24/15 16:17 EPA 6020 Beryllium 0.98 mg/kg 0.19 02/25/15 11:01 EPA 6020 Cobalt 5.3 mg/kg 1.6 02/25/15 11:01 EPA 6020 Lead 6.1 mg/kg 1.6 02/25/15 11:01 EPA 6020 Vanadium 16.4 mg/kg 1.6 02/25/15 11:01 ASTM D2974-87 Percent Moisture 35.5 % 0.10 02/25/15 14:09 EPA 9045 pH at 25 Degrees C 5.5 Std. Units 0.10 02/19/15 10:25 EPA 9045 pH at 25 Degrees C 5.6 Std. Units 0.10 02/20/15 13:40 EPA 9060 Total Organic Carbon 9430 mg/kg 1650 02/27/15 11:26 EPA 9060 Total Organic Carbon 10600 mg/kg 1650 02/27/15 11:31 EPA 9060 Total Organic Carbon 8830 mg/kg 1650 02/27/15 11:37 EPA 9060 Total Organic Carbon 6960 mg/kg 1640 02/27/15 11:43 EPA 9060 Mean Total Organic Carbon 8950 mg/kg 1650 02/27/15 11:26 EPA 9060 RSD% 16.8 % 02/27/15 11:26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. D3 D3 D3 D3 D6 H6 Qualifiers Page 7 of 60 aceAnaiXical www.pacelabs.com Project: J15020367 Pace Project No.: 92237903 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 0988 %-8fhre. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92237903004 2015004091 EPA 6010 Aluminum 8940 mg/kg 6.4 02/24/15 16:34 EPA 6010 Barium 51.0 mg/kg 0.64 02/24/15 16:34 EPA 6010 Calcium 210 mg/kg 32.1 02/24/15 16:34 EPA 6010 Chromium 6.8 mg/kg 0.32 02/24/15 16:34 EPA 6010 Copper 3.3 mg/kg 0.32 02/24/15 16:34 EPA 6010 Iron 7570 mg/kg 2.6 02/24/15 16:34 EPA 6010 Magnesium 1570 mg/kg 32.1 02/24/15 16:34 EPA 6010 Manganese 137 mg/kg 0.32 02/24/15 16:34 EPA 6010 Nickel 3.9 mg/kg 0.32 02/24/15 16:34 EPA 6010 Potassium 924 mg/kg 64.3 02/24/15 16:34 EPA 6010 Strontium 2.0 mg/kg 0.64 02/24/15 16:34 EPA 6010 Zinc 25.7 mg/kg 1.3 02/24/15 16:34 EPA 6020 Beryllium 1.0 mg/kg 0.15 02/25/15 11:04 D3 EPA 6020 Cobalt 5.0 mg/kg 1.3 02/25/15 11:04 D3 EPA 6020 Lead 5.9 mg/kg 1.3 02/25/15 11:04 D3 EPA 6020 Vanadium 15.5 mg/kg 1.3 02/25/15 11:04 D3 EPA 7471 Mercury 0.011 mg/kg 0.010 02/24/15 12:08 ASTM D2974-87 Percent Moisture 19.6 % 0.10 02/25/15 14:09 EPA 9045 pH at 25 Degrees C 5.1 Std. Units 0.10 02/19/15 10:25 EPA 9045 pH at 25 Degrees C 5.8 Std. Units 0.10 02/20/15 13:40 H6 EPA 9060 Total Organic Carbon 7180 mg/kg 2870 02/27/15 13:16 EPA 9060 Total Organic Carbon 7590 mg/kg 2820 02/27/15 13:21 EPA 9060 Total Organic Carbon 7860 mg/kg 2840 02/27/15 13:28 EPA 9060 Total Organic Carbon 10700 mg/kg 2820 02/27/15 13:34 EPA 9060 Mean Total Organic Carbon 8330 mg/kg 2840 02/27/15 13:16 EPA 9060 RSD% 19.2 % 02/27/15 13:16 92237903005 2015004092 EPA 6010 Aluminum 12700 mg/kg 5.7 02/24/15 16:55 EPA 6010 Barium 168 mg/kg 0.57 02/24/15 16:55 EPA 6010 Calcium 588 mg/kg 28.4 02/24/15 16:55 EPA 6010 Chromium 15.4 mg/kg 0.28 02/24/15 16:55 EPA 6010 Copper 10.9 mg/kg 0.28 02/24/15 16:55 EPA 6010 Iron 16200 mg/kg 2.3 02/24/15 16:55 EPA 6010 Magnesium 6070 mg/kg 28.4 02/24/15 16:55 EPA 6010 Manganese 231 mg/kg 0.28 02/24/15 16:55 EPA 6010 Nickel 13.3 mg/kg 0.28 02/24/15 16:55 EPA 6010 Potassium 7660 mg/kg 56.8 02/24/15 16:55 EPA 6010 Sodium 71.3 mg/kg 56.8 02/24/15 16:55 EPA 6010 Strontium 12.4 mg/kg 0.57 02/24/15 16:55 EPA 6010 Zinc 75.4 mg/kg 1.1 02/24/15 16:55 EPA 6020 Beryllium 1.3 mg/kg 0.14 02/25/15 11:07 D3 EPA 6020 Cobalt 10.7 mg/kg 1.1 02/25/15 11:07 D3 EPA 6020 Lead 4.7 mg/kg 1.1 02/25/15 11:07 D3 EPA 6020 Vanadium 27.4 mg/kg 1.1 02/25/15 11:07 D4 ASTM D2974-87 Percent Moisture 14.4 % 0.10 02/25/15 14:10 EPA 9045 pH at 25 Degrees C 5.5 Std. Units 0.10 02/19/15 10:25 EPA 9045 pH at 25 Degrees C 5.9 Std. Units 0.10 02/20/15 13:40 H6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 8 of 60 aceAnaiXical www.pacelabs.com Project: J15020367 Pace Project No.: 92237903 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 098gKinlvhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92237903005 2015004092 EPA 9060 RSD% 2.0 % 02/27/15 13:41 92237903006 2015004093 EPA 6010 Aluminum 12800 mg/kg 6.5 02/24/15 16:59 EPA 6010 Barium 181 mg/kg 0.65 02/24/15 16:59 EPA 6010 Calcium 2130 mg/kg 32.4 02/24/15 16:59 EPA 6010 Chromium 21.4 mg/kg 1.6 02/25/15 07:09 D3 EPA 6010 Copper 3.3 mg/kg 1.6 02/25/15 07:09 D3 EPA 6010 Iron 18500 mg/kg 2.6 02/24/15 16:59 EPA 6010 Magnesium 7580 mg/kg 32.4 02/24/15 16:59 EPA 6010 Manganese 473 mg/kg 1.6 02/25/15 07:09 D3 EPA 6010 Nickel 15.3 mg/kg 0.32 02/24/15 16:59 EPA 6010 Potassium 10200 mg/kg 64.7 02/24/15 16:59 EPA 6010 Sodium 101 mg/kg 64.7 02/24/15 16:59 EPA 6010 Strontium 12.6 mg/kg 0.65 02/24/15 16:59 EPA 6010 Zinc 83.3 mg/kg 1.3 02/24/15 16:59 EPA 6020 Arsenic 1.3 mg/kg 1.3 02/25/15 11:10 D3 EPA 6020 Beryllium 0.83 mg/kg 0.16 02/25/15 11:10 D3 EPA 6020 Cobalt 13.5 mg/kg 1.3 02/25/15 11:10 D3 EPA 6020 Lead 6.5 mg/kg 1.3 02/25/15 11:10 D3 EPA 6020 Selenium 2.0 mg/kg 1.3 02/25/15 11:10 D3 EPA 6020 Vanadium 27.7 mg/kg 1.3 02/25/15 11:10 D3 ASTM D2974-87 Percent Moisture 18.9 % 0.10 02/25/15 14:12 EPA 9045 pH at 25 Degrees C 7.1 Std. Units 0.10 02/19/15 10:25 EPA 9045 pH at 25 Degrees C 7.4 Std. Units 0.10 02/20/15 13:40 H6 EPA 9060 RSD% 0.43 % 02/27/15 14:05 92237903007 2015004095 EPA 6010 Aluminum 11500 mg/kg 6.8 02/24/15 17:04 EPA 6010 Barium 58.6 mg/kg 0.68 02/24/15 17:04 EPA 6010 Calcium 1070 mg/kg 33.9 02/24/15 17:04 EPA 6010 Chromium 9.5 mg/kg 0.34 02/24/15 17:04 EPA 6010 Copper 6.7 mg/kg 0.34 02/24/15 17:04 EPA 6010 Iron 11900 mg/kg 2.7 02/24/15 17:04 EPA 6010 Magnesium 2100 mg/kg 33.9 02/24/15 17:04 EPA 6010 Manganese 160 mg/kg 0.34 02/24/15 17:04 EPA 6010 Molybdenum 1.4 mg/kg 0.68 02/24/15 17:04 EPA 6010 Nickel 5.6 mg/kg 0.34 02/24/15 17:04 EPA 6010 Potassium 1470 mg/kg 67.9 02/24/15 17:04 EPA 6010 Strontium 7.1 mg/kg 0.68 02/24/15 17:04 EPA 6010 Zinc 34.1 mg/kg 1.4 02/24/15 17:04 EPA 6020 Arsenic 3.9 mg/kg 1.4 02/25/15 11:14 D3 EPA 6020 Beryllium 0.91 mg/kg 0.16 02/25/15 11:14 D3 EPA 6020 Cobalt 5.4 mg/kg 1.4 02/25/15 11:14 D3 EPA 6020 Lead 9.1 mg/kg 1.4 02/25/15 11:14 D3 EPA 6020 Selenium 1.7 mg/kg 1.4 02/25/15 11:14 D3 EPA 6020 Vanadium 23.6 mg/kg 1.4 02/25/15 11:14 D3 EPA 7471 Mercury 0.026 mg/kg 0.011 02/24/15 12:14 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 60 aceAnaiXical www.pacelabs.com Project: J15020367 Pace Project No.: 92237903 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 098gKi� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92237903007 2015004095 ASTM D2974-87 Percent Moisture 27.1 % 0.10 02/25/15 14:12 EPA 9045 pH at 25 Degrees C 6.1 Std. Units 0.10 02/19/15 10:25 EPA 9045 pH at 25 Degrees C 6.3 Std. Units 0.10 02/20/15 13:40 EPA 9060 Total Organic Carbon 5960 mg/kg 831 02/27/15 14:29 EPA 9060 Total Organic Carbon 4840 mg/kg 818 02/27/15 14:34 EPA 9060 Total Organic Carbon 5180 mg/kg 831 02/27/15 14:40 EPA 9060 Total Organic Carbon 4650 mg/kg 830 02/27/15 14:46 EPA 9060 Mean Total Organic Carbon 5160 mg/kg 827 02/27/15 14:29 EPA 9060 RSD% 11.1 % 02/27/15 14:29 92237903008 2015004096 EPA 6010 Aluminum 12300 mg/kg 7.3 02/24/15 17:08 EPA 6010 Barium 61.3 mg/kg 0.73 02/24/15 17:08 EPA 6010 Calcium 419 mg/kg 36.7 02/24/15 17:08 EPA 6010 Chromium 9.9 mg/kg 0.37 02/24/15 17:08 EPA 6010 Copper 2.5 mg/kg 0.37 02/24/15 17:08 EPA 6010 Iron 14800 mg/kg 2.9 02/24/15 17:08 EPA 6010 Magnesium 2770 mg/kg 36.7 02/24/15 17:08 EPA 6010 Manganese 112 mg/kg 0.37 02/24/15 17:08 EPA 6010 Nickel 5.3 mg/kg 0.37 02/24/15 17:08 EPA 6010 Potassium 1890 mg/kg 73.3 02/24/15 17:08 EPA 6010 Strontium 3.8 mg/kg 0.73 02/24/15 17:08 EPA 6010 Zinc 35.4 mg/kg 1.5 02/24/15 17:08 EPA 6020 Beryllium 0.96 mg/kg 0.18 02/25/15 11:30 EPA 6020 Cobalt 5.1 mg/kg 1.5 02/25/15 11:30 EPA 6020 Lead 6.5 mg/kg 1.5 02/25/15 11:30 EPA 6020 Vanadium 25.4 mg/kg 1.5 02/25/15 11:30 EPA 7471 Mercury 0.016 mg/kg 0.011 02/24/15 12:16 ASTM D2974-87 Percent Moisture 29.4 % 0.10 02/25/15 14:13 EPA 9045 pH at 25 Degrees C 4.9 Std. Units 0.10 02/19/15 10:25 EPA 9045 pH at 25 Degrees C 5.0 Std. Units 0.10 02/20/15 13:40 EPA 9060 Total Organic Carbon 1620 mg/kg 850 02/27/15 14:52 EPA 9060 Total Organic Carbon 1790 mg/kg 844 02/27/15 14:58 EPA 9060 Total Organic Carbon 1720 mg/kg 854 02/27/15 15:03 EPA 9060 Total Organic Carbon 1580 mg/kg 846 02/27/15 15:09 EPA 9060 Mean Total Organic Carbon 1680 mg/kg 849 02/27/15 14:52 EPA 9060 RSD% 5.6 % 02/27/15 14:52 92237903009 2015004097 EPA 6010 Aluminum 6570 mg/kg 5.8 02/24/15 17:12 EPA 6010 Barium 48.4 mg/kg 0.58 02/24/15 17:12 EPA 6010 Calcium 292 mg/kg 29.2 02/24/15 17:12 EPA 6010 Chromium 6.5 mg/kg 0.29 02/24/15 17:12 EPA 6010 Copper 6.0 mg/kg 0.29 02/24/15 17:12 EPA 6010 Iron 5920 mg/kg 2.3 02/24/15 17:12 EPA 6010 Magnesium 1810 mg/kg 29.2 02/24/15 17:12 EPA 6010 Manganese 38.3 mg/kg 0.29 02/24/15 17:12 EPA 6010 Nickel 4.4 mg/kg 0.29 02/24/15 17:12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 0. D3 D3 D3 D3 H6 Qualifiers Page 10 of 60 aceAnaiXical www.pacelabs.com Project: J15020367 Pace Project No.: 92237903 Lab Sample ID Method Client Sample ID Parameters 92237903009 2015004097 EPA 6010 Potassium EPA 6010 Sodium EPA 6010 Strontium EPA 6010 Zinc EPA 6020 Beryllium EPA 6020 Cobalt EPA 6020 Lead EPA 6020 Vanadium ASTM D2974-87 Percent Moisture EPA 9045 pH at 25 Degrees C EPA 9045 pH at 25 Degrees C EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Mean Total Organic Carbon EPA 9060 RSD% Pace Analytical Services, Inc. 098gKi� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 1830 mg/kg 111 mg/kg 2.5 mg/kg 15.5 mg/kg 0.21 mg/kg 3.8 mg/kg 2.5 mg/kg 11.4 mg/kg 11.5 % 5.9 Std. Units 5.4 Std. Units 1180 mg/kg 1110 mg/kg 1100 mg/kg 1170 mg/kg 1140 mg/kg 3.6 % REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 58.5 02/24/1517:12 58.5 02/24/1517:12 0.58 02/24/1517:12 1.2 02/24/1517:12 0.14 02/25/1511:34 D3,M6 1.2 02/25/1511:34 D3,M6 1.2 02/25/1511:34 D3,M6,R1 1.2 02/25/1511:34 D3,M6,R1 0.10 02/25/1514:13 0.10 02/19/1510:25 0.10 02/20/1513:40 H6 684 02/27/1515:14 673 02/27/1515:19 678 02/27/1515:25 675 02/27/1515:30 678 02/27/1515:14 02/27/15 15:14 Page 11 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Qgtr4-8yhe. Suite 100 yy Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020367 Pace Project No.: 92237903 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 04, 2015 General Information: 9 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3010 with any exceptions noted below. The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22793 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92237904001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1138267) • Aluminum • Barium • Iron • Manganese • Potassium • Strontium • MSD (Lab ID: 1138268) • Aluminum • Barium • Iron • Manganese • Potassium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Qgtr� .8fhre. Suite 100 yy Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020367 Pace Project No.: 92237903 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 04, 2015 Analyte Comments: QC Batch: MPRP/22793 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015004093 (Lab ID: 92237903006) • Boron • Chromium • Copper • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K�i�vhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020367 Pace Project No.: 92237903 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 04, 2015 General Information: 9 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22796 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92237903009 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1138466) • Antimony • Beryllium • Cobalt • Vanadium • MSD (Lab ID: 1138467) • Antimony • Beryllium • Cobalt • Lead • Vanadium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098v i�vhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020367 Pace Project No.: 92237903 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 04, 2015 QC Batch: MPRP/22796 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92237903009 R1: RPD value was outside control limits. • MSD (Lab ID: 1138467) • Lead • Vanadium Additional Comments: Analyte Comments: QC Batch: MPRP/22796 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015004090 (Lab ID: 92237903003) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015004091 (Lab ID:92237903004) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015004092 (Lab ID:92237903005) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015004093 (Lab ID: 92237903006) • Arsenic • Beryllium • Cadmium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 %.8fhre. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020367 Pace Project No.: 92237903 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 04, 2015 Analyte Comments: QC Batch: MPRP/22796 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015004093 (Lab ID: 92237903006) • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015004095 (Lab ID:92237903007) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015004096 (Lab ID:92237903008) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015004097 (Lab ID:92237903009) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • MS (Lab ID: 1138466) • Arsenic • Beryllium • Cadmium • Cobalt • Lead REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 .8fhre. Suite 100 �yJ Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020367 Pace Project No.: 92237903 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 04, 2015 Analyte Comments: QC Batch: MPRP/22796 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • MS (Lab ID: 1138466) • Antimony • Selenium • Thallium • Vanadium • MSD (Lab ID: 1138467) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium D4: Sample was diluted due to the presence of high levels of target analytes. •2015004092 (Lab ID: 92237903005) • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •2015004090 (Lab ID:92237903003) • Antimony •2015004091 (Lab ID:92237903004) • Antimony •2015004092 (Lab ID:92237903005) • Antimony •2015004093 (Lab ID:92237903006) • Antimony •2015004095 (Lab ID:92237903007) • Antimony •2015004096 (Lab ID:92237903008) • Antimony •2015004097 (Lab ID:92237903009) • Antimony • BLANK (Lab ID: 1138464) • Antimony • LCS (Lab ID: 1138465) • Antimony • MS (Lab ID: 1138466) • Antimony • MSD (Lab ID: 1138467) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020367 Pace Project No.: 92237903 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: March 04, 2015 General Information: 2 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninivhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020367 Pace Project No.: 92237903 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: March 04, 2015 General Information: 7 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020367 Pace Project No.: 92237903 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: March 04, 2015 General Information: 7 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-16: Analysis initiated outside of the 15 minute EPA recommended holding time. •2015004090 (Lab ID:92237903003) •2015004091 (Lab ID:92237903004) •2015004092 (Lab ID:92237903005) •2015004093 (Lab ID:92237903006) •2015004095 (Lab ID:92237903007) •2015004096 (Lab ID:92237903008) •2015004097 (Lab ID:92237903009) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020367 Pace Project No.: 92237903 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: March 04, 2015 General Information: 7 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/43844 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015004090 (Lab ID:92237903003) • Chloride • Sulfate •2015004091 (Lab ID:92237903004) • Chloride • Sulfate •2015004092 (Lab ID:92237903005) • Chloride • Sulfate •2015004093 (Lab ID:92237903006) • Chloride • Sulfate •2015004095 (Lab ID:92237903007) • Chloride • Sulfate •2015004096 (Lab ID:92237903008) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K�i�vhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020367 Pace Project No.: 92237903 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: March 04, 2015 Analyte Comments: QC Batch: WETA/43844 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015004097 (Lab ID: 92237903009) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020367 Pace Project No.: 92237903 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: March 04, 2015 General Information: 7 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015004090 (Lab ID:92237903003) •2015004091 (Lab ID:92237903004) •2015004092 (Lab ID:92237903005) •2015004093 (Lab ID:92237903006) •2015004095 (Lab ID:92237903007) •2015004096 (Lab ID:92237903008) •2015004097 (Lab ID:92237903009) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020367 Pace Project No.: 92237903 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: March 04, 2015 General Information: 7 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 098v i�vhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020367 Pace Project No.: 92237903 Sample: 2015004085 Lab ID: 92237903001 Collected: 02/06/15 10:30 Received: 02/16/15 14:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Aluminum 1420 ug/L 200 100 1 02/21/1515:03 02/23/1510:38 7429-90-5 Barium 15.3 ug/L 10.0 5.0 1 02/21/1515:03 02/23/1510:38 7440-39-3 Boron ND ug/L 150 75.0 1 02/21/1515:03 02/23/1510:38 7440-42-8 Calcium 27200 ug/L 500 250 1 02/21/1515:03 02/23/1510:38 7440-70-2 Chromium ND ug/L 10.0 5.0 1 02/21/1515:03 02/23/1510:38 7440-47-3 Copper ND ug/L 10.0 1.2 1 02/21/1515:03 02/23/1510:38 7440-50-8 Iron 1510 ug/L 50.0 4.8 1 02/21/1515:03 02/23/1510:38 7439-89-6 Magnesium 523 ug/L 500 250 1 02/21/1515:03 02/23/1510:38 7439-95-4 Manganese 31.5 ug/L 5.0 2.5 1 02/21/1515:03 02/23/1510:38 7439-96-5 Molybdenum ND ug/L 15.0 2.3 1 02/21/1515:03 02/23/1510:38 7439-98-7 Nickel ND ug/L 20.0 10.0 1 02/21/1515:03 02/23/1510:38 7440-02-0 Potassium ND ug/L 2500 1250 1 02/21/1515:03 02/23/1510:38 7440-09-7 Sodium ND ug/L 1000 500 1 02/21/1515:03 02/23/1517:50 7440-23-5 Zinc 42.6 ug/L 20.0 4.6 1 02/21/1515:03 02/23/1510:38 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3020 Antimony 0.76 ug/L 0.50 0.25 1 02/20/1512:22 02/23/1517:35 7440-36-0 Arsenic 1.1 ug/L 0.50 0.25 1 02/20/1512:22 02/23/1517:35 7440-38-2 Beryllium 0.20 ug/L 0.20 0.066 1 02/20/1512:22 02/23/1517:35 7440-41-7 Cadmium ND ug/L 0.080 0.033 1 02/20/1512:22 02/23/1517:35 7440-43-9 Cobalt 0.91 ug/L 0.50 0.25 1 02/20/1512:22 02/23/1517:35 7440-48-4 Lead 2.1 ug/L 0.10 0.046 1 02/20/1512:22 02/23/1517:35 7439-92-1 Selenium ND ug/L 0.50 0.25 1 02/20/1512:22 02/23/1517:35 7782-49-2 Strontium 50.8 ug/L 0.50 0.057 1 02/20/1512:22 02/23/1517:35 7440-24-6 Thallium ND ug/L 0.10 0.025 1 02/20/1512:22 02/23/1517:35 7440-28-0 Vanadium 5.1 ug/L 1.0 0.21 1 02/20/1512:22 02/23/1517:35 7440-62-2 7470 Mercury Analytical Method: EPA 7470 Preparation Method: EPA 7470 Mercury ND ug/L 0.20 0.026 1 02/20/1513:30 02/24/1518:23 7439-97-6 Date: 03/04/2015 05:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 098nig yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020367 Pace Project No.: 92237903 Sample: 2015004094 Lab ID: 92237903002 Collected: 02/12/15 08:15 Received: 02/16/15 14:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Aluminum ND ug/L 200 100 1 02/21/1515:03 02/23/1510:53 7429-90-5 Barium ND ug/L 10.0 5.0 1 02/21/1515:03 02/23/1510:53 7440-39-3 Boron ND ug/L 150 75.0 1 02/21/1515:03 02/23/1510:53 7440-42-8 Calcium ND ug/L 500 250 1 02/21/1515:03 02/23/1510:53 7440-70-2 Chromium ND ug/L 10.0 5.0 1 02/21/1515:03 02/23/1510:53 7440-47-3 Copper ND ug/L 10.0 1.2 1 02/21/1515:03 02/23/1510:53 7440-50-8 Iron 678 ug/L 50.0 4.8 1 02/21/1515:03 02/23/1510:53 7439-89-6 Magnesium ND ug/L 500 250 1 02/21/1515:03 02/23/1510:53 7439-95-4 Manganese 12.4 ug/L 5.0 2.5 1 02/21/1515:03 02/23/1510:53 7439-96-5 Molybdenum ND ug/L 15.0 2.3 1 02/21/1515:03 02/23/1510:53 7439-98-7 Nickel ND ug/L 20.0 10.0 1 02/21/1515:03 02/23/1510:53 7440-02-0 Potassium ND ug/L 2500 1250 1 02/21/1515:03 02/23/1510:53 7440-09-7 Sodium ND ug/L 1000 500 1 02/21/1515:03 02/23/1518:04 7440-23-5 Zinc ND ug/L 20.0 4.6 1 02/21/1515:03 02/23/1510:53 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3020 Antimony ND ug/L 0.50 0.25 1 02/20/1512:22 02/23/1517:40 7440-36-0 Arsenic 1.1 ug/L 0.50 0.25 1 02/20/1512:22 02/23/1517:40 7440-38-2 Beryllium ND ug/L 0.20 0.066 1 02/20/1512:22 02/23/1517:40 7440-41-7 Cadmium ND ug/L 0.080 0.033 1 02/20/1512:22 02/23/1517:40 7440-43-9 Cobalt ND ug/L 0.50 0.25 1 02/20/1512:22 02/23/1517:40 7440-48-4 Lead 0.17 ug/L 0.10 0.046 1 02/20/1512:22 02/23/1517:40 7439-92-1 Selenium ND ug/L 0.50 0.25 1 02/20/1512:22 02/23/1517:40 7782-49-2 Strontium 1.4 ug/L 0.50 0.057 1 02/20/1512:22 02/23/1517:40 7440-24-6 Thallium ND ug/L 0.10 0.025 1 02/20/1512:22 02/23/1517:40 7440-28-0 Vanadium ND ug/L 1.0 0.21 1 02/20/1512:22 02/23/1517:40 7440-62-2 7470 Mercury Analytical Method: EPA 7470 Preparation Method: EPA 7470 Mercury ND ug/L 0.20 0.026 1 02/20/1513:30 02/24/1518:26 7439-97-6 Date: 03/04/2015 05:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098ni� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015004090 Lab ID: 92237903003 Collected: 02/06/15 11:00 Received: 02/16/15 14:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 10200 mg/kg 7.9 4.0 1 02/24/15 09:00 02/24/15 16:17 7429-90-5 Barium 59.9 mg/kg 0.79 0.40 1 02/24/15 09:00 02/24/15 16:17 7440-39-3 Boron ND mg/kg 4.0 2.0 1 02/24/15 09:00 02/24/15 16:17 7440-42-8 Calcium 218 mg/kg 39.6 19.8 1 02/24/15 09:00 02/24/15 16:17 7440-70-2 Chromium 7.9 mg/kg 0.40 0.20 1 02/24/15 09:00 02/24/15 16:17 7440-47-3 Copper 4.0 mg/kg 0.40 0.20 1 02/24/15 09:00 02/24/15 16:17 7440-50-8 Iron 8710 mg/kg 3.2 1.6 1 02/24/15 09:00 02/24/15 16:17 7439-89-6 Magnesium 1840 mg/kg 39.6 19.8 1 02/24/15 09:00 02/24/15 16:17 7439-95-4 Manganese 161 mg/kg 0.40 0.20 1 02/24/15 09:00 02/24/15 16:17 7439-96-5 Molybdenum ND mg/kg 0.79 0.40 1 02/24/15 09:00 02/24/15 16:17 7439-98-7 Nickel 4.5 mg/kg 0.40 0.20 1 02/24/15 09:00 02/24/15 16:17 7440-02-0 Potassium 1050 mg/kg 79.2 39.6 1 02/24/15 09:00 02/24/15 16:17 7440-09-7 Sodium ND mg/kg 79.2 39.6 1 02/24/15 09:00 02/24/15 16:17 7440-23-5 Strontium 2.3 mg/kg 0.79 0.40 1 02/24/15 09:00 02/24/15 16:17 7440-24-6 Zinc 30.0 mg/kg 1.6 0.79 1 02/24/15 09:00 02/24/15 16:17 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.6 0.79 20 02/24/15 09:00 02/25/15 11:01 7440-36-0 Arsenic ND mg/kg 1.6 0.79 20 02/24/15 09:00 02/25/15 11:01 7440-38-2 Beryllium 0.98 mg/kg 0.19 0.095 20 02/24/15 09:00 02/25/15 11:01 7440-41-7 Cadmium ND mg/kg 0.19 0.095 20 02/24/15 09:00 02/25/15 11:01 7440-43-9 Cobalt 5.3 mg/kg 1.6 0.79 20 02/24/15 09:00 02/25/15 11:01 7440-48-4 Lead 6.1 mg/kg 1.6 0.79 20 02/24/15 09:00 02/25/15 11:01 7439-92-1 Selenium ND mg/kg 1.6 0.79 20 02/24/15 09:00 02/25/15 11:01 7782-49-2 Thallium ND mg/kg 1.6 0.79 20 02/24/15 09:00 02/25/15 11:01 7440-28-0 Vanadium 16.4 mg/kg 1.6 0.79 20 02/24/15 09:00 02/25/15 11:01 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.013 0.0063 1 02/24/15 09:05 02/24/15 12:05 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 35.5 % 0.10 0.10 1 02/25/15 14:09 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.5 Std. Units 0.10 0.10 1 pH at 25 Degrees C 5.6 Std. Units 0.10 0.10 1 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 387 193 5 Sulfate ND mg/kg 387 193 5 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 38.7 19.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. 02/19/15 10:25 02/20/15 13:40 D3,N2 D3 D3 D3 D3 D3 D3 D3 D3 D6 H6 02/21/15 01:31 16887-00-6 D3 02/21/15 01:31 14808-79-8 D3 02/21/1501:31 14797-55-8 H3 Page 27 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098gwi� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015004090 Lab ID: 92237903003 Collected: 02/06/15 11:00 Received: 02/16/15 14:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 9430 mg/kg 1650 823 1 02/27/15 11:26 7440-44-0 Total Organic Carbon 10600 mg/kg 1650 825 1 02/27/15 11:31 7440-44-0 Total Organic Carbon 8830 mg/kg 1650 825 1 02/27/15 11:37 7440-44-0 Total Organic Carbon 6960 mg/kg 1640 821 1 02/27/15 11:43 7440-44-0 Mean Total Organic Carbon 8950 mg/kg 1650 824 1 02/27/15 11:26 7440-44-0 Surrogates RSD% 16.8 % 1 02/27/1511:26 Date: 03/04/2015 05:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098gWinic&�rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015004091 Lab ID: 92237903004 Collected: 02/06/15 11:00 Received: 02/16/15 14:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 8940 mg/kg 6.4 3.2 1 02/24/15 09:00 02/24/15 16:34 7429-90-5 Barium 51.0 mg/kg 0.64 0.32 1 02/24/15 09:00 02/24/15 16:34 7440-39-3 Boron ND mg/kg 3.2 1.6 1 02/24/15 09:00 02/24/15 16:34 7440-42-8 Calcium 210 mg/kg 32.1 16.1 1 02/24/15 09:00 02/24/15 16:34 7440-70-2 Chromium 6.8 mg/kg 0.32 0.16 1 02/24/15 09:00 02/24/15 16:34 7440-47-3 Copper 3.3 mg/kg 0.32 0.16 1 02/24/15 09:00 02/24/15 16:34 7440-50-8 Iron 7570 mg/kg 2.6 1.3 1 02/24/15 09:00 02/24/15 16:34 7439-89-6 Magnesium 1570 mg/kg 32.1 16.1 1 02/24/15 09:00 02/24/15 16:34 7439-95-4 Manganese 137 mg/kg 0.32 0.16 1 02/24/15 09:00 02/24/15 16:34 7439-96-5 Molybdenum ND mg/kg 0.64 0.32 1 02/24/15 09:00 02/24/15 16:34 7439-98-7 Nickel 3.9 mg/kg 0.32 0.16 1 02/24/15 09:00 02/24/15 16:34 7440-02-0 Potassium 924 mg/kg 64.3 32.1 1 02/24/15 09:00 02/24/15 16:34 7440-09-7 Sodium ND mg/kg 64.3 32.1 1 02/24/15 09:00 02/24/15 16:34 7440-23-5 Strontium 2.0 mg/kg 0.64 0.32 1 02/24/15 09:00 02/24/15 16:34 7440-24-6 Zinc 25.7 mg/kg 1.3 0.64 1 02/24/15 09:00 02/24/15 16:34 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.3 0.64 20 02/24/15 09:00 02/25/15 11:04 7440-36-0 Arsenic ND mg/kg 1.3 0.64 20 02/24/15 09:00 02/25/15 11:04 7440-38-2 Beryllium 1.0 mg/kg 0.15 0.077 20 02/24/15 09:00 02/25/15 11:04 7440-41-7 Cadmium ND mg/kg 0.15 0.077 20 02/24/15 09:00 02/25/15 11:04 7440-43-9 Cobalt 5.0 mg/kg 1.3 0.64 20 02/24/15 09:00 02/25/15 11:04 7440-48-4 Lead 5.9 mg/kg 1.3 0.64 20 02/24/15 09:00 02/25/15 11:04 7439-92-1 Selenium ND mg/kg 1.3 0.64 20 02/24/15 09:00 02/25/15 11:04 7782-49-2 Thallium ND mg/kg 1.3 0.64 20 02/24/15 09:00 02/25/15 11:04 7440-28-0 Vanadium 15.5 mg/kg 1.3 0.64 20 02/24/15 09:00 02/25/15 11:04 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.011 mg/kg 0.010 0.0051 1 02/24/15 09:05 02/24/15 12:08 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 19.6 % 0.10 0.10 1 02/25/15 14:09 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.1 Std. Units 0.10 0.10 1 pH at 25 Degrees C 5.8 Std. Units 0.10 0.10 1 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 305 152 5 Sulfate ND mg/kg 305 152 5 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.5 15.2 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. 02/19/15 10:25 02/20/15 13:40 D3,N2 D3 D3 D3 D3 D3 D3 D3 D3 H6 02/21/15 01:54 16887-00-6 D3 02/21/15 01:54 14808-79-8 D3 02/21/1501:54 14797-55-8 H3 Page 29 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098gwi� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015004091 Lab ID: 92237903004 Collected: 02/06/15 11:00 Received: 02/16/15 14:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 7180 mg/kg 2870 1430 1 02/27/15 13:16 7440-44-0 Total Organic Carbon 7590 mg/kg 2820 1410 1 02/27/15 13:21 7440-44-0 Total Organic Carbon 7860 mg/kg 2840 1420 1 02/27/15 13:28 7440-44-0 Total Organic Carbon 10700 mg/kg 2820 1410 1 02/27/15 13:34 7440-44-0 Mean Total Organic Carbon 8330 mg/kg 2840 1420 1 02/27/15 13:16 7440-44-0 Surrogates RSD% 19.2 % 1 02/27/1513:16 Date: 03/04/2015 05:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098gwi� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015004092 Lab ID: 92237903005 Collected: 02/06/15 12:05 Received: 02/16/15 14:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 12700 mg/kg 5.7 2.8 1 02/24/15 09:00 02/24/15 16:55 7429-90-5 Barium 168 mg/kg 0.57 0.28 1 02/24/15 09:00 02/24/15 16:55 7440-39-3 Boron ND mg/kg 2.8 1.4 1 02/24/15 09:00 02/24/15 16:55 7440-42-8 Calcium 588 mg/kg 28.4 14.2 1 02/24/15 09:00 02/24/15 16:55 7440-70-2 Chromium 15.4 mg/kg 0.28 0.14 1 02/24/15 09:00 02/24/15 16:55 7440-47-3 Copper 10.9 mg/kg 0.28 0.14 1 02/24/15 09:00 02/24/15 16:55 7440-50-8 Iron 16200 mg/kg 2.3 1.1 1 02/24/15 09:00 02/24/15 16:55 7439-89-6 Magnesium 6070 mg/kg 28.4 14.2 1 02/24/15 09:00 02/24/15 16:55 7439-95-4 Manganese 231 mg/kg 0.28 0.14 1 02/24/15 09:00 02/24/15 16:55 7439-96-5 Molybdenum ND mg/kg 0.57 0.28 1 02/24/15 09:00 02/24/15 16:55 7439-98-7 Nickel 13.3 mg/kg 0.28 0.14 1 02/24/15 09:00 02/24/15 16:55 7440-02-0 Potassium 7660 mg/kg 56.8 28.4 1 02/24/15 09:00 02/24/15 16:55 7440-09-7 Sodium 71.3 mg/kg 56.8 28.4 1 02/24/15 09:00 02/24/15 16:55 7440-23-5 Strontium 12.4 mg/kg 0.57 0.28 1 02/24/15 09:00 02/24/15 16:55 7440-24-6 Zinc 75.4 mg/kg 1.1 0.57 1 02/24/15 09:00 02/24/15 16:55 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.1 0.57 20 02/24/15 09:00 02/25/15 11:07 7440-36-0 Arsenic ND mg/kg 1.1 0.57 20 02/24/15 09:00 02/25/15 11:07 7440-38-2 Beryllium 1.3 mg/kg 0.14 0.068 20 02/24/15 09:00 02/25/15 11:07 7440-41-7 Cadmium ND mg/kg 0.14 0.068 20 02/24/15 09:00 02/25/15 11:07 7440-43-9 Cobalt 10.7 mg/kg 1.1 0.57 20 02/24/15 09:00 02/25/15 11:07 7440-48-4 Lead 4.7 mg/kg 1.1 0.57 20 02/24/15 09:00 02/25/15 11:07 7439-92-1 Selenium ND mg/kg 1.1 0.57 20 02/24/15 09:00 02/25/15 11:07 7782-49-2 Thallium ND mg/kg 1.1 0.57 20 02/24/15 09:00 02/25/15 11:07 7440-28-0 Vanadium 27.4 mg/kg 1.1 0.57 20 02/24/15 09:00 02/25/15 11:07 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0093 0.0047 1 02/24/15 09:05 02/24/15 12:10 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 14.4 % 0.10 0.10 1 02/25/15 14:10 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.5 Std. Units 0.10 0.10 1 pH at 25 Degrees C 5.9 Std. Units 0.10 0.10 1 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 292 146 5 Sulfate ND mg/kg 292 146 5 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 29.2 14.6 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. 02/19/15 10:25 02/20/15 13:40 D3,N2 D3 D3 D3 D3 D3 D3 D3 D4 H6 02/21/15 02:16 16887-00-6 D3 02/21/15 02:16 14808-79-8 D3 02/21/1502:16 14797-55-8 H3 Page 31 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098�t�i .8fhre. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015004092 Lab ID: 92237903005 Collected: 02/06/15 12:05 Received: 02/16/15 14:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 700 350 1 02/27/15 13:41 7440-44-0 Total Organic Carbon ND mg/kg 708 354 1 02/27/15 13:46 7440-44-0 Total Organic Carbon ND mg/kg 701 350 1 02/27/15 13:53 7440-44-0 Total Organic Carbon ND mg/kg 695 348 1 02/27/15 13:59 7440-44-0 Mean Total Organic Carbon ND mg/kg 701 351 1 02/27/15 13:41 7440-44-0 Surrogates RSD% 2.0 % 1 02/27/1513:41 Date: 03/04/2015 05:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098gwi� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015004093 Lab ID: 92237903006 Collected: 02/06/15 12:25 Received: 02/16/15 14:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 12800 mg/kg 6.5 3.2 1 02/24/15 09:00 02/24/15 16:59 7429-90-5 Barium 181 mg/kg 0.65 0.32 1 02/24/15 09:00 02/24/15 16:59 7440-39-3 Boron ND mg/kg 16.2 8.1 5 02/24/15 09:00 02/25/15 07:09 7440-42-8 Calcium 2130 mg/kg 32.4 16.2 1 02/24/15 09:00 02/24/15 16:59 7440-70-2 Chromium 21.4 mg/kg 1.6 0.81 5 02/24/15 09:00 02/25/15 07:09 7440-47-3 Copper 3.3 mg/kg 1.6 0.81 5 02/24/15 09:00 02/25/15 07:09 7440-50-8 Iron 18500 mg/kg 2.6 1.3 1 02/24/15 09:00 02/24/15 16:59 7439-89-6 Magnesium 7580 mg/kg 32.4 16.2 1 02/24/15 09:00 02/24/15 16:59 7439-95-4 Manganese 473 mg/kg 1.6 0.81 5 02/24/15 09:00 02/25/15 07:09 7439-96-5 Molybdenum ND mg/kg 0.65 0.32 1 02/24/15 09:00 02/24/15 16:59 7439-98-7 Nickel 15.3 mg/kg 0.32 0.16 1 02/24/15 09:00 02/24/15 16:59 7440-02-0 Potassium 10200 mg/kg 64.7 32.4 1 02/24/15 09:00 02/24/15 16:59 7440-09-7 Sodium 101 mg/kg 64.7 32.4 1 02/24/15 09:00 02/24/15 16:59 7440-23-5 Strontium 12.6 mg/kg 0.65 0.32 1 02/24/15 09:00 02/24/15 16:59 7440-24-6 Zinc 83.3 mg/kg 1.3 0.65 1 02/24/15 09:00 02/24/15 16:59 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.3 0.65 20 02/24/15 09:00 02/25/15 11:10 7440-36-0 Arsenic 1.3 mg/kg 1.3 0.65 20 02/24/15 09:00 02/25/15 11:10 7440-38-2 Beryllium 0.83 mg/kg 0.16 0.078 20 02/24/15 09:00 02/25/15 11:10 7440-41-7 Cadmium ND mg/kg 0.16 0.078 20 02/24/15 09:00 02/25/15 11:10 7440-43-9 Cobalt 13.5 mg/kg 1.3 0.65 20 02/24/15 09:00 02/25/15 11:10 7440-48-4 Lead 6.5 mg/kg 1.3 0.65 20 02/24/15 09:00 02/25/15 11:10 7439-92-1 Selenium 2.0 mg/kg 1.3 0.65 20 02/24/15 09:00 02/25/15 11:10 7782-49-2 Thallium ND mg/kg 1.3 0.65 20 02/24/15 09:00 02/25/15 11:10 7440-28-0 Vanadium 27.7 mg/kg 1.3 0.65 20 02/24/15 09:00 02/25/15 11:10 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0097 0.0048 1 02/24/15 09:05 02/24/15 12:12 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 18.9 % 0.10 0.10 1 02/25/15 14:12 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 7.1 Std. Units 0.10 0.10 1 pH at 25 Degrees C 7.4 Std. Units 0.10 0.10 1 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 308 154 5 Sulfate ND mg/kg 308 154 5 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.8 15.4 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. 02/19/15 10:25 02/20/15 13:40 D3 D3 D3 D3 D3,N2 D3 D3 D3 D3 D3 D3 D3 D3 H6 02/21/15 02:38 16887-00-6 D3 02/21/15 02:38 14808-79-8 D3 02/21/1502:38 14797-55-8 H3 Page 33 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098gwi� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015004093 Lab ID: 92237903006 Collected: 02/06/15 12:25 Received: 02/16/15 14:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 741 371 1 02/27/15 14:05 7440-44-0 Total Organic Carbon ND mg/kg 734 367 1 02/27/15 14:10 7440-44-0 Total Organic Carbon ND mg/kg 738 369 1 02/27/15 14:15 7440-44-0 Total Organic Carbon ND mg/kg 738 369 1 02/27/15 14:22 7440-44-0 Mean Total Organic Carbon ND mg/kg 738 369 1 02/27/15 14:05 7440-44-0 Surrogates RSD% 0.43 % 1 02/27/1514:05 Date: 03/04/2015 05:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 34 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098gwi� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015004095 Lab ID: 92237903007 Collected: 02/12/15 08:45 Received: 02/16/15 14:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 11500 mg/kg 6.8 3.4 1 02/24/15 09:00 02/24/15 17:04 7429-90-5 Barium 58.6 mg/kg 0.68 0.34 1 02/24/15 09:00 02/24/15 17:04 7440-39-3 Boron ND mg/kg 3.4 1.7 1 02/24/15 09:00 02/24/15 17:04 7440-42-8 Calcium 1070 mg/kg 33.9 17.0 1 02/24/15 09:00 02/24/15 17:04 7440-70-2 Chromium 9.5 mg/kg 0.34 0.17 1 02/24/15 09:00 02/24/15 17:04 7440-47-3 Copper 6.7 mg/kg 0.34 0.17 1 02/24/15 09:00 02/24/15 17:04 7440-50-8 Iron 11900 mg/kg 2.7 1.4 1 02/24/15 09:00 02/24/15 17:04 7439-89-6 Magnesium 2100 mg/kg 33.9 17.0 1 02/24/15 09:00 02/24/15 17:04 7439-95-4 Manganese 160 mg/kg 0.34 0.17 1 02/24/15 09:00 02/24/15 17:04 7439-96-5 Molybdenum 1.4 mg/kg 0.68 0.34 1 02/24/15 09:00 02/24/15 17:04 7439-98-7 Nickel 5.6 mg/kg 0.34 0.17 1 02/24/15 09:00 02/24/15 17:04 7440-02-0 Potassium 1470 mg/kg 67.9 33.9 1 02/24/15 09:00 02/24/15 17:04 7440-09-7 Sodium ND mg/kg 67.9 33.9 1 02/24/15 09:00 02/24/15 17:04 7440-23-5 Strontium 7.1 mg/kg 0.68 0.34 1 02/24/15 09:00 02/24/15 17:04 7440-24-6 Zinc 34.1 mg/kg 1.4 0.68 1 02/24/15 09:00 02/24/15 17:04 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.4 0.68 20 02/24/15 09:00 02/25/15 11:14 7440-36-0 Arsenic 3.9 mg/kg 1.4 0.68 20 02/24/15 09:00 02/25/15 11:14 7440-38-2 Beryllium 0.91 mg/kg 0.16 0.081 20 02/24/15 09:00 02/25/15 11:14 7440-41-7 Cadmium ND mg/kg 0.16 0.081 20 02/24/15 09:00 02/25/15 11:14 7440-43-9 Cobalt 5.4 mg/kg 1.4 0.68 20 02/24/15 09:00 02/25/15 11:14 7440-48-4 Lead 9.1 mg/kg 1.4 0.68 20 02/24/15 09:00 02/25/15 11:14 7439-92-1 Selenium 1.7 mg/kg 1.4 0.68 20 02/24/15 09:00 02/25/15 11:14 7782-49-2 Thallium ND mg/kg 1.4 0.68 20 02/24/15 09:00 02/25/15 11:14 7440-28-0 Vanadium 23.6 mg/kg 1.4 0.68 20 02/24/15 09:00 02/25/15 11:14 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.026 mg/kg 0.011 0.0053 1 02/24/15 09:05 02/24/15 12:14 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 27.1 % 0.10 0.10 1 02/25/15 14:12 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.1 Std. Units 0.10 0.10 1 pH at 25 Degrees C 6.3 Std. Units 0.10 0.10 1 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 348 174 5 Sulfate ND mg/kg 348 174 5 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 34.8 17.4 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. 02/19/15 10:25 02/20/15 13:40 D3,N2 D3 D3 D3 D3 D3 D3 D3 D3 H6 02/21/15 03:00 16887-00-6 D3 02/21/15 03:00 14808-79-8 D3 02/21/1503:00 14797-55-8 H3 Page 35 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098gwig yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015004095 Lab ID: 92237903007 Collected: 02/12/15 08:45 Received: 02/16/15 14:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 5960 mg/kg 831 416 1 02/27/15 14:29 7440-44-0 Total Organic Carbon 4840 mg/kg 818 409 1 02/27/15 14:34 7440-44-0 Total Organic Carbon 5180 mg/kg 831 415 1 02/27/15 14:40 7440-44-0 Total Organic Carbon 4650 mg/kg 830 415 1 02/27/15 14:46 7440-44-0 Mean Total Organic Carbon 5160 mg/kg 827 414 1 02/27/15 14:29 7440-44-0 Surrogates RSD% 11.1 % 1 02/27/1514:29 Date: 03/04/2015 05:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 36 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098gwi� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015004096 Lab ID: 92237903008 Collected: 02/12/15 08:50 Received: 02/16/15 14:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 12300 mg/kg 7.3 3.7 1 02/24/15 09:00 02/24/15 17:08 7429-90-5 Barium 61.3 mg/kg 0.73 0.37 1 02/24/15 09:00 02/24/15 17:08 7440-39-3 Boron ND mg/kg 3.7 1.8 1 02/24/15 09:00 02/24/15 17:08 7440-42-8 Calcium 419 mg/kg 36.7 18.3 1 02/24/15 09:00 02/24/15 17:08 7440-70-2 Chromium 9.9 mg/kg 0.37 0.18 1 02/24/15 09:00 02/24/15 17:08 7440-47-3 Copper 2.5 mg/kg 0.37 0.18 1 02/24/15 09:00 02/24/15 17:08 7440-50-8 Iron 14800 mg/kg 2.9 1.5 1 02/24/15 09:00 02/24/15 17:08 7439-89-6 Magnesium 2770 mg/kg 36.7 18.3 1 02/24/15 09:00 02/24/15 17:08 7439-95-4 Manganese 112 mg/kg 0.37 0.18 1 02/24/15 09:00 02/24/15 17:08 7439-96-5 Molybdenum ND mg/kg 0.73 0.37 1 02/24/15 09:00 02/24/15 17:08 7439-98-7 Nickel 5.3 mg/kg 0.37 0.18 1 02/24/15 09:00 02/24/15 17:08 7440-02-0 Potassium 1890 mg/kg 73.3 36.7 1 02/24/15 09:00 02/24/15 17:08 7440-09-7 Sodium ND mg/kg 73.3 36.7 1 02/24/15 09:00 02/24/15 17:08 7440-23-5 Strontium 3.8 mg/kg 0.73 0.37 1 02/24/15 09:00 02/24/15 17:08 7440-24-6 Zinc 35.4 mg/kg 1.5 0.73 1 02/24/15 09:00 02/24/15 17:08 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.5 0.73 20 02/24/15 09:00 02/25/15 11:30 7440-36-0 Arsenic ND mg/kg 1.5 0.73 20 02/24/15 09:00 02/25/15 11:30 7440-38-2 Beryllium 0.96 mg/kg 0.18 0.088 20 02/24/15 09:00 02/25/15 11:30 7440-41-7 Cadmium ND mg/kg 0.18 0.088 20 02/24/15 09:00 02/25/15 11:30 7440-43-9 Cobalt 5.1 mg/kg 1.5 0.73 20 02/24/15 09:00 02/25/15 11:30 7440-48-4 Lead 6.5 mg/kg 1.5 0.73 20 02/24/15 09:00 02/25/15 11:30 7439-92-1 Selenium ND mg/kg 1.5 0.73 20 02/24/15 09:00 02/25/15 11:30 7782-49-2 Thallium ND mg/kg 1.5 0.73 20 02/24/15 09:00 02/25/15 11:30 7440-28-0 Vanadium 25.4 mg/kg 1.5 0.73 20 02/24/15 09:00 02/25/15 11:30 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.016 mg/kg 0.011 0.0057 1 02/24/15 09:05 02/24/15 12:16 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 29.4 % 0.10 0.10 1 02/25/15 14:13 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 4.9 Std. Units 0.10 0.10 1 pH at 25 Degrees C 5.0 Std. Units 0.10 0.10 1 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 353 177 5 Sulfate ND mg/kg 353 177 5 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 35.3 17.7 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. 02/19/15 10:25 02/20/15 13:40 D3,N2 D3 D3 D3 D3 D3 D3 D3 D3 H6 02/21/15 03:22 16887-00-6 D3 02/21/15 03:22 14808-79-8 D3 02/21/1503:22 14797-55-8 H3 Page 37 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098onyhe. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015004096 Lab ID: 92237903008 Collected: 02/12/15 08:50 Received: 02/16/15 14:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1620 mg/kg 850 425 1 02/27/15 14:52 7440-44-0 Total Organic Carbon 1790 mg/kg 844 422 1 02/27/15 14:58 7440-44-0 Total Organic Carbon 1720 mg/kg 854 427 1 02/27/15 15:03 7440-44-0 Total Organic Carbon 1580 mg/kg 846 423 1 02/27/15 15:09 7440-44-0 Mean Total Organic Carbon 1680 mg/kg 849 424 1 02/27/15 14:52 7440-44-0 Surrogates RSD% 5.6 % 1 02/27/1514:52 Date: 03/04/2015 05:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 38 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098onic8fhe. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015004097 Lab ID: 92237903009 Collected: 02/12/15 10:30 Received: 02/16/15 14:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Beryllium Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C pH at 25 Degrees C 9056 IC Anions Chloride Sulfate Date: 03/04/2015 05:40 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 6570 mg/kg 5.8 2.9 1 02/24/15 09:00 02/24/15 17:12 7429-90-5 48.4 mg/kg 0.58 0.29 1 02/24/15 09:00 02/24/15 17:12 7440-39-3 ND mg/kg 2.9 1.5 1 02/24/15 09:00 02/24/15 17:12 7440-42-8 292 mg/kg 29.2 14.6 1 02/24/15 09:00 02/24/15 17:12 7440-70-2 6.5 mg/kg 0.29 0.15 1 02/24/15 09:00 02/24/15 17:12 7440-47-3 6.0 mg/kg 0.29 0.15 1 02/24/15 09:00 02/24/15 17:12 7440-50-8 5920 mg/kg 2.3 1.2 1 02/24/15 09:00 02/24/15 17:12 7439-89-6 1810 mg/kg 29.2 14.6 1 02/24/15 09:00 02/24/15 17:12 7439-95-4 38.3 mg/kg 0.29 0.15 1 02/24/15 09:00 02/24/15 17:12 7439-96-5 ND mg/kg 0.58 0.29 1 02/24/15 09:00 02/24/15 17:12 7439-98-7 4.4 mg/kg 0.29 0.15 1 02/24/15 09:00 02/24/15 17:12 7440-02-0 1830 mg/kg 58.5 29.2 1 02/24/15 09:00 02/24/15 17:12 7440-09-7 111 mg/kg 58.5 29.2 1 02/24/15 09:00 02/24/15 17:12 7440-23-5 2.5 mg/kg 0.58 0.29 1 02/24/15 09:00 02/24/15 17:12 7440-24-6 15.5 mg/kg 1.2 0.58 1 02/24/15 09:00 02/24/15 17:12 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 1.2 0.58 20 02/24/15 09:00 02/25/15 11:34 7440-36-0 ND mg/kg 1.2 0.58 20 02/24/15 09:00 02/25/15 11:34 7440-38-2 0.21 mg/kg 0.14 0.070 20 02/24/15 09:00 02/25/15 11:34 7440-41-7 ND mg/kg 0.14 0.070 20 02/24/15 09:00 02/25/15 11:34 7440-43-9 3.8 mg/kg 1.2 0.58 20 02/24/15 09:00 02/25/15 11:34 7440-48-4 2.5 mg/kg 1.2 0.58 20 02/24/15 09:00 02/25/15 11:34 7439-92-1 ND mg/kg 1.2 0.58 20 02/24/15 09:00 02/25/15 11:34 7782-49-2 ND mg/kg 1.2 0.58 20 02/24/15 09:00 02/25/15 11:34 7440-28-0 11.4 mg/kg 1.2 0.58 20 02/24/15 09:00 02/25/15 11:34 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 D3,M6, N2 D3 D3,M6 D3 D3,M6 D3,M6, R1 D3 D3 D3,M6, R1 ND mg/kg 0.0088 0.0044 1 02/24/15 09:05 02/24/15 12:18 7439-97-6 Analytical Method: ASTM D2974-87 11.5 % 0.10 0.10 1 02/25/1514:13 Analytical Method: EPA 9045 5.9 Std. Units 0.10 0.10 1 02/19/15 10:25 5.4 Std. Units 0.10 0.10 1 02/20/15 13:40 H6 Analytical Method: EPA 9056 ND mg/kg 279 139 5 02/21/15 04:29 16887-00-6 D3 ND mg/kg 279 139 5 02/21/15 04:29 14808-79-8 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 39 of 60 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 098onyhe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020367 Pace Project No.: 92237903 Sample: 2015004097 Lab ID: 92237903009 Collected: 02/12/15 10:30 Received: 02/16/15 14:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 27.9 13.9 5 02/21/15 04:29 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1180 mg/kg 684 342 1 02/27/15 15:14 7440-44-0 Total Organic Carbon 1110 mg/kg 673 337 1 02/27/15 15:19 7440-44-0 Total Organic Carbon 1100 mg/kg 678 339 1 02/27/15 15:25 7440-44-0 Total Organic Carbon 1170 mg/kg 675 338 1 02/27/15 15:30 7440-44-0 Mean Total Organic Carbon 1140 mg/kg 678 339 1 02/27/15 15:14 7440-44-0 Surrogates RSD% 3.6 % 1 02/27/1515:14 Date: 03/04/2015 05:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 40 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098nnyhe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020367 Pace Project No.: 92237903 QC Batch: MERP/12789 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92237903001, 92237903002 METHOD BLANK: 1903078 Matrix: Water Associated Lab Samples: 92237903001, 92237903002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 02/24/1518:06 LABORATORY CONTROL SAMPLE: 1903079 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.9 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1903080 1903081 MS MSD 10297119001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.9 5.0 99 100 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 41 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098mvhe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020367 Pace Project No.: 92237903 QC Batch: MERP/5402 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92237903003, 92237903004, 92237903005, 92237903006, 92237903007, 92237903008, 92237903009 METHOD BLANK: 1138287 Matrix: Solid Associated Lab Samples: 92237903003, 92237903004, 92237903005, 92237903006, 92237903007, 92237903008, 92237903009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0080 02/24/1511:24 LABORATORY CONTROL SAMPLE: 1138288 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .081 0.081 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1138289 1138290 MS MSD 92237904001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.33 .105 .103 0.43 0.42 90 85 80-120 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 42 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098nnyhe. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: MPRP/22793 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92237903003, 92237903004, 92237903005, 92237903006, 92237903007, 92237903008, 92237903009 METHOD BLANK: 1138265 Matrix: Solid Associated Lab Samples: 92237903003, 92237903004, 92237903005, 92237903006, 92237903007, 92237903008, 92237903009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Aluminum mg/kg ND 5.1 02/24/1514:54 Barium mg/kg ND 0.51 02/24/1514:54 Boron mg/kg ND 2.5 02/24/1514:54 Calcium mg/kg ND 25.4 02/24/1514:54 Chromium mg/kg ND 0.25 02/24/1514:54 Copper mg/kg ND 0.25 02/24/1514:54 Iron mg/kg ND 2.0 02/24/1514:54 Magnesium mg/kg ND 25.4 02/24/1514:54 Manganese mg/kg ND 0.25 02/24/1514:54 Molybdenum mg/kg ND 0.51 02/24/1514:54 Nickel mg/kg ND 0.25 02/24/1514:54 Potassium mg/kg ND 50.7 02/24/1514:54 Sodium mg/kg ND 50.7 02/24/1514:54 Strontium mg/kg ND 0.51 02/24/1514:54 Zinc mg/kg ND 1.0 02/24/1514:54 LABORATORY CONTROL SAMPLE: Parameter 1138266 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum mg/kg 125 134 107 80-120 Barium mg/kg 12.5 13.3 107 80-120 Boron mg/kg 125 125 100 80-120 Calcium mg/kg 624 647 104 80-120 Chromium mg/kg 12.5 12.5 100 80-120 Copper mg/kg 12.5 12.3 99 80-120 Iron mg/kg 125 127 102 80-120 Magnesium mg/kg 624 611 98 80-120 Manganese mg/kg 12.5 12.7 101 80-120 Molybdenum mg/kg 12.5 12.8 103 80-120 Nickel mg/kg 12.5 13.2 106 80-120 Potassium mg/kg 624 657 105 80-120 Sodium mg/kg 624 654 105 80-120 Strontium mg/kg 12.5 12.8 103 80-120 Zinc mg/kg 62.4 65.2 104 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 43 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098onyhe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020367 Pace Project No.: 92237903 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1138267 1138268 MS MSD 92237904001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 6630 158 165 8450 8670 1150 1240 75-125 3 20 M1 Barium mg/kg 409 15.8 16.5 400 405 -55 -23 75-125 1 20 M1 Boron mg/kg 9.7 158 165 140 147 82 83 75-125 5 20 Calcium mg/kg 1100 791 826 1760 1860 84 91 75-125 5 20 Chromium mg/kg 8.4 15.8 16.5 21.6 22.1 84 83 75-125 3 20 Copper mg/kg 21.0 15.8 16.5 35.2 36.8 90 96 75-125 4 20 Iron mg/kg 4980 158 165 6190 6000 761 618 75-125 3 20 M1 Magnesium mg/kg 640 791 826 1430 1480 100 101 75-125 3 20 Manganese mg/kg 49.5 15.8 16.5 79.1 71.2 187 131 75-125 11 20 M1 Molybdenum mg/kg 1.6 15.8 16.5 14.6 15.1 82 82 75-125 3 20 Nickel mg/kg 9.6 15.8 16.5 24.1 25.8 92 98 75-125 7 20 Potassium mg/kg 1310 791 826 2360 2520 132 146 75-125 7 20 M1 Sodium mg/kg 147 791 826 887 916 94 93 75-125 3 20 Strontium mg/kg 92.7 15.8 16.5 104 112 72 115 75-125 7 20 M1 Zinc mg/kg 16.0 79.1 82.6 86.3 90.8 89 91 75-125 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 44 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020367 Pace Project No.: 92237903 QC Batch: MPRP/52512 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 92237903001, 92237903002 METHOD BLANK: 1903045 Associated Lab Samples: 92237903001, 92237903002 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Aluminum ug/L ND 200 02/23/1510:20 Barium ug/L ND 10.0 02/23/1510:20 Boron ug/L ND 150 02/23/1510:20 Calcium ug/L ND 500 02/23/1510:20 Chromium ug/L ND 10.0 02/23/1510:20 Copper ug/L ND 10.0 02/23/1510:20 Iron ug/L ND 50.0 02/23/1510:20 Magnesium ug/L ND 500 02/23/1510:20 Manganese ug/L ND 5.0 02/23/1510:20 Molybdenum ug/L ND 15.0 02/23/1510:20 Nickel ug/L ND 20.0 02/23/1510:20 Potassium ug/L ND 2500 02/23/1510:20 Sodium ug/L ND 1000 02/23/1510:20 Zinc ug/L ND 20.0 02/23/1510:20 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1903046 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum ug/L 10000 9810 98 80-120 Barium ug/L 1000 1080 108 80-120 Boron ug/L 1000 985 99 80-120 Calcium ug/L 10000 9930 99 80-120 Chromium ug/L 1000 969 97 80-120 Copper ug/L 1000 970 97 80-120 Iron ug/L 10000 9740 97 80-120 Magnesium ug/L 10000 9920 99 80-120 Manganese ug/L 1000 1010 101 80-120 Molybdenum ug/L 1000 987 99 80-120 Nickel ug/L 1000 987 99 80-120 Potassium ug/L 10000 9160 92 80-120 Sodium ug/L 10000 8930 89 80-120 Zinc ug/L 1000 995 100 80-120 Pace Analytical Services, Inc. 0988 i�vhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1904102 1904103 MS MSD 92237903001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 1420 10000 10000 11400 11300 99 99 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 45 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098og yhe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020367 Pace Project No.: 92237903 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1904102 1904103 MS MSD 92237903001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Barium ug/L 15.3 1000 1000 1100 1100 108 108 75-125 0 20 Boron ug/L ND 1000 1000 1000 1000 100 100 75-125 0 20 Calcium ug/L 27200 10000 10000 38800 38200 115 110 75-125 1 20 Chromium ug/L ND 1000 1000 978 979 97 97 75-125 0 20 Copper ug/L ND 1000 1000 996 987 99 98 75-125 1 20 Iron ug/L 1510 10000 10000 11300 11300 98 98 75-125 0 20 Magnesium ug/L 523 10000 10000 10500 10500 99 99 75-125 0 20 Manganese ug/L 31.5 1000 1000 1040 1040 101 101 75-125 0 20 Molybdenum ug/L ND 1000 1000 992 992 99 99 75-125 0 20 Nickel ug/L ND 1000 1000 990 985 99 98 75-125 1 20 Potassium ug/L ND 10000 10000 9590 9590 94 94 75-125 0 20 Sodium ug/L ND 10000 10000 9750 9850 97 98 75-125 1 20 Zinc ug/L 42.6 1000 1000 1030 1030 99 99 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 46 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098onyhe. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: MPRP/22796 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET Associated Lab Samples: 92237903003, 92237903004, 92237903005, 92237903006, 92237903007, 92237903008, 92237903009 METHOD BLANK: 1138464 Matrix: Solid LCS Result Associated Lab Samples: 92237903003, 92237903004, 92237903005, 92237903006, 92237903007, 92237903008, 92237903009 2.5 2.6 Blank Reporting Arsenic Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.050 02/25/1510:01 N2 Arsenic mg/kg ND 0.050 02/25/1510:01 Beryllium mg/kg ND 0.0060 02/25/1510:01 Cadmium mg/kg ND 0.0060 02/25/1510:01 Cobalt mg/kg ND 0.050 02/25/1510:01 Lead mg/kg ND 0.050 02/25/1510:01 Selenium mg/kg ND 0.050 02/25/1510:01 Thallium mg/kg ND 0.050 02/25/1510:01 Vanadium mg/kg ND 0.050 02/25/1510:01 LABORATORY CONTROL SAMPLE: Parameter 1138465 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.6 102 80-120 N2 Arsenic mg/kg 2.5 2.6 105 80-120 Beryllium mg/kg .25 0.28 109 80-120 Cadmium mg/kg .25 0.26 103 80-120 Cobalt mg/kg 2.5 2.6 103 80-120 Lead mg/kg 2.5 2.6 104 80-120 Selenium mg/kg 2.5 2.7 107 80-120 Thallium mg/kg 2.5 2.6 104 80-120 Vanadium mg/kg 2.5 2.6 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1138466 MS 92237903009 Spike Parameter Units Result Conc. MSD Spike Conc. 1138467 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Antimony mg/kg ND 2.83 2.83 1.8 1.7 64 62 75-125 2 20 D3,M6, N2 Arsenic mg/kg ND 2.83 2.83 2.8 2.9 91 93 75-125 3 20 D3 Beryllium mg/kg 0.21 .283 .283 0.63 0.70 151 176 75-125 12 20 D3,M6 Cadmium mg/kg ND .283 .283 0.32 0.31 112 107 75-125 3 20 D3 Cobalt mg/kg 3.8 2.83 2.83 5.7 5.8 67 71 75-125 2 20 D3,M6 Lead mg/kg 2.5 2.83 2.83 5.6 9.1 113 236 75-125 47 20 D3,M6, R1 Selenium mg/kg ND 2.83 2.83 3.2 3.1 101 97 75-125 3 20 D3 Thallium mg/kg ND 2.83 2.83 3.0 3.0 104 103 75-125 1 20 D3 Vanadium mg/kg 11.4 2.83 2.83 12.3 15.8 35 156 75-125 24 20 D3,M6, R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020367 Pace Project No.: 92237903 QC Batch: MPRP/52504 Analysis Method: EPA 6020 QC Batch Method: EPA 3020 Analysis Description: 6020 MET Associated Lab Samples: 92237903001, 92237903002 METHOD BLANK: 1902866 Associated Lab Samples: 92237903001, 92237903002 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Antimony ug/L ND 0.50 02/23/1516:57 Arsenic ug/L ND 0.50 02/23/1516:57 Beryllium ug/L ND 0.20 02/23/1516:57 Cadmium ug/L ND 0.080 02/23/1516:57 Cobalt ug/L ND 0.50 02/23/1516:57 Lead ug/L ND 0.10 02/23/1516:57 Selenium ug/L ND 0.50 02/23/1516:57 Strontium ug/L ND 0.50 02/23/1516:57 Thallium ug/L ND 0.10 02/23/1516:57 Vanadium ug/L ND 1.0 02/23/1516:57 LABORATORY CONTROL SAMPLE: 1902867 Parameter Units Antimony ug/L Arsenic ug/L Beryllium ug/L Cadmium ug/L Cobalt ug/L Lead ug/L Selenium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Pace Analytical Services, Inc. 098oi� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Qualifiers Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 80 80.4 100 80-120 80 80.5 101 80-120 80 82.2 103 80-120 80 82.1 103 80-120 80 81.6 102 80-120 80 84.3 105 80-120 80 83.5 104 80-120 80 80.9 101 80-120 80 82.5 103 80-120 80 81.3 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1902868 1902869 MS MSD 92237904012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 80 80 82.5 79.8 103 99 75-125 3 20 Arsenic ug/L ND 80 80 81.2 79.3 102 99 75-125 2 20 Beryllium ug/L ND 80 80 84.1 85.1 105 106 75-125 1 20 Cadmium ug/L ND 80 80 82.4 80.4 103 100 75-125 3 20 Cobalt ug/L ND 80 80 82.7 80.5 103 101 75-125 3 20 Lead ug/L ND 80 80 85.2 83.1 106 104 75-125 2 20 Selenium ug/L ND 80 80 83.7 81.1 105 101 75-125 3 20 Strontium ug/L ND 80 80 81.8 79.7 102 100 75-125 3 20 Thallium ug/L ND 80 80 86.3 84.1 108 105 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 48 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098oinlc&�rhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1902868 1902869 MS MSD 92237904012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Vanadium ug/L ND 80 80 82.6 79.6 103 100 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 49 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098oi� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020367 Pace Project No.: 92237903 QC Batch: PMST/3287 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92237903003, 92237903004, 92237903005, 92237903006, 92237903007, 92237903008, 92237903009 SAMPLE DUPLICATE: 1139680 35175568001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 74.2 74.5 0 10 SAMPLE DUPLICATE: 1139681 35176087004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 3.6 3.6 1 10 SAMPLE DUPLICATE: 1139682 92237904008 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 22.9 22.9 0 10 SAMPLE DUPLICATE: 1139683 35176315001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 20.8 19.4 7 10 SAMPLE DUPLICATE: 1139684 35176730003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 9.8 10.1 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 50 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098oi� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 QC Batch: WET/29355 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92237903003, 92237903004, 92237903005, 92237903006, 92237903007, 92237903008, 92237903009 SAMPLE DUPLICATE: 1136238 92237903003 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.6 5.6 0 20 H6 SAMPLE DUPLICATE: 1136794 92237904003 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.0 7.0 0 20 H6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 51 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098mvhe. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: WET/35767 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92237903003, 92237903004, 92237903005, 92237903006, 92237903007, 92237903008, 92237903009 SAMPLE DUPLICATE: 1393405 92237903003 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.5 5.5 1 10 SAMPLE DUPLICATE: 1393406 92237903009 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.9 6.0 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 52 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15020367 Pace Project No.: 92237903 Pace Analytical Services, Inc. 098oi� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 QC Batch: WETA/43844 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92237903003, 92237903004, 92237903005, 92237903006, 92237903007, 92237903008, 92237903009 METHOD BLANK: 1136814 1136815 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1136817 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.9 02/20/15 22:34 Sulfate mg/kg ND 49.9 02/20/15 22:34 LABORATORY CONTROL SAMPLE: 1136815 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1136817 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1136816 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 499 528 106 80-120 499 524 105 80-120 92237648001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 510 478 72 80-120 M1 247J 510 693 87 80-120 92237648001 Dup Units Result Result mg/kg ND ND mg/kg 247J 257 Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 53 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098oi� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020367 Pace Project No.: 92237903 QC Batch: WETA/43843 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92237903003, 92237903004, 92237903005, 92237903006, 92237903007, 92237903008, 92237903009 METHOD BLANK: 1136806 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 02/20/15 22:34 LABORATORY CONTROL SAMPLE: 1136807 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.9 53.9 108 80-120 MATRIX SPIKE SAMPLE: 1136809 92237648001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 51 47.0 92 80-120 H3 SAMPLE DUPLICATE: 1136808 92237648001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 54 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 0988 i�vhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020367 Pace Project No.: 92237903 QC Batch: WETA/27384 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92237903003, 92237903004, 92237903005, 92237903006, 92237903007, 92237903008, 92237903009 METHOD BLANK: 1121664 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 02/27/15 07:30 LABORATORY CONTROL SAMPLE: 1121665 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 114000 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1121136 1121137 MS MSD 92238285001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 46600 57300 58300 98700 94900 91 83 50-150 4 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1121666 1121667 MS MSD 92237903003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 8950 16400 16400 24400 25100 94 98 50-150 3 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 55 of 60 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15020367 Pace Project No.: 92237903 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, Inc. 098oig yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. H6 Analysis initiated outside of the 15 minute EPA recommended holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 56 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. 098oi� yhe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020367 Pace Project No.: 92237903 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92237903003 2015004090 EPA 3050 MPRP/22793 EPA 6010 ICP/13946 92237903004 2015004091 EPA 3050 MPRP/22793 EPA 6010 ICP/13946 92237903005 2015004092 EPA 3050 MPRP/22793 EPA 6010 ICP/13946 92237903006 2015004093 EPA 3050 MPRP/22793 EPA 6010 ICP/13946 92237903007 2015004095 EPA 3050 MPRP/22793 EPA 6010 ICP/13946 92237903008 2015004096 EPA 3050 MPRP/22793 EPA6010 ICP/13946 92237903009 2015004097 EPA 3050 MPRP/22793 EPA6010 ICP/13946 92237903001 2015004085 EPA 3010 MPRP/52512 EPA6010 ICP/22794 92237903002 2015004094 EPA 3010 MPRP/52512 EPA6010 ICP/22794 92237903003 2015004090 EPA 3050 MPRP/22796 EPA 6020 ICPM/9305 92237903004 2015004091 EPA 3050 MPRP/22796 EPA 6020 ICPM/9305 92237903005 2015004092 EPA 3050 MPRP/22796 EPA 6020 ICPM/9305 92237903006 2015004093 EPA 3050 MPRP/22796 EPA 6020 ICPM/9305 92237903007 2015004095 EPA 3050 MPRP/22796 EPA 6020 ICPM/9305 92237903008 2015004096 EPA 3050 MPRP/22796 EPA 6020 ICPM/9305 92237903009 2015004097 EPA 3050 MPRP/22796 EPA 6020 ICPM/9305 92237903001 2015004085 EPA 3020 MPRP/52504 EPA 6020 ICPM/23296 92237903002 2015004094 EPA 3020 MPRP/52504 EPA 6020 ICPM/23296 92237903001 2015004085 EPA 7470 MERP/12789 EPA 7470 MERC/14849 92237903002 2015004094 EPA 7470 MERP/12789 EPA 7470 MERC/14849 92237903003 2015004090 EPA 7471 MERP/5402 EPA 7471 MERC/5393 92237903004 2015004091 EPA 7471 MERP/5402 EPA 7471 MERC/5393 92237903005 2015004092 EPA 7471 MERP/5402 EPA 7471 MERC/5393 92237903006 2015004093 EPA 7471 MERP/5402 EPA 7471 MERC/5393 92237903007 2015004095 EPA 7471 MERP/5402 EPA 7471 MERC/5393 92237903008 2015004096 EPA 7471 MERP/5402 EPA 7471 MERC/5393 92237903009 2015004097 EPA 7471 MERP/5402 EPA 7471 MERC/5393 92237903003 2015004090 ASTM D2974-87 PMST/3287 92237903004 2015004091 ASTM D2974-87 PMST/3287 92237903005 2015004092 ASTM D2974-87 PMST/3287 92237903006 2015004093 ASTM D2974-87 PMST/3287 92237903007 2015004095 ASTM D2974-87 PMST/3287 92237903008 2015004096 ASTM D2974-87 PMST/3287 92237903009 2015004097 ASTM D2974-87 PMST/3287 92237903003 2015004090 EPA 9045 WET/29355 92237903003 2015004090 EPA 9045 WET/35767 92237903004 2015004091 EPA 9045 WET/29355 92237903004 2015004091 EPA 9045 WET/35767 92237903005 2015004092 EPA 9045 WET/29355 92237903005 2015004092 EPA 9045 WET/35767 92237903006 2015004093 EPA 9045 WET/29355 92237903006 2015004093 EPA 9045 WET/35767 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 57 of 60 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. 098onyhe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020367 Pace Project No.: 92237903 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92237903007 2015004095 EPA 9045 WET/29355 92237903007 2015004095 EPA 9045 WET/35767 92237903008 2015004096 EPA 9045 WET/29355 92237903008 2015004096 EPA 9045 WET/35767 92237903009 2015004097 EPA 9045 WET/29355 92237903009 2015004097 EPA 9045 WET/35767 92237903003 2015004090 EPA 9056 WETA/43844 92237903004 2015004091 EPA 9056 WETA/43844 92237903005 2015004092 EPA 9056 WETA/43844 92237903006 2015004093 EPA 9056 WETA/43844 92237903007 2015004095 EPA 9056 WETA/43844 92237903008 2015004096 EPA 9056 WETA/43844 92237903009 2015004097 EPA 9056 WETA/43844 92237903003 2015004090 EPA 9056 WETA/43843 92237903004 2015004091 EPA 9056 WETA/43843 92237903005 2015004092 EPA 9056 WETA/43843 92237903006 2015004093 EPA 9056 WETA/43843 92237903007 2015004095 EPA 9056 WETA/43843 92237903008 2015004096 EPA 9056 WETA/43843 92237903009 2015004097 EPA 9056 WETA/43843 92237903003 2015004090 EPA 9060 WETA/27384 92237903003 2015004090 EPA 9060 WETA/27385 92237903004 2015004091 EPA 9060 WETA/27384 92237903004 2015004091 EPA 9060 WETA/27385 92237903005 2015004092 EPA 9060 WETA/27384 92237903005 2015004092 EPA 9060 WETA/27385 92237903006 2015004093 EPA 9060 WETA/27384 92237903006 2015004093 EPA 9060 WETA/27385 92237903007 2015004095 EPA 9060 WETA/27384 92237903007 2015004095 EPA 9060 WETA/27385 92237903008 2015004096 EPA 9060 WETA/27384 92237903008 2015004096 EPA 9060 WETA/27385 92237903009 2015004097 EPA 9060 WETA/27384 92237903009 2015004097 EPA 9060 WETA/27385 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:40 PM without the written consent of Pace Analytical Services, Inc.. Page 58 of 60 lcohialylloal' Document Dame: le Condition Upon Receit Document Number: F-CHR-CS-003-rey.15 Document Revised: September 22. ;-U14 Pae 1 of 2 Issuing Authw#y71 of 73 Pace Huntersville Quality Office Client fume:�> s Courier: ❑ Fed Ex ❑ UPS[] USPS❑ Client❑ Commercia[❑ Pace Other Q ti r Custody Seal on Cooler/Box Present: ❑ yes n} Seals intact: [❑ yes ❑ no Packing Material: ❑ Bubble V❑p ❑ubble Ba�s [-1 None ❑ Other Thermometer Used: IR Gun T1401 Type of Ice: �t5 Blue None ❑ Samples on ice, cooling process has begun Temn Correction Facfor T1401 No Correction Corrected Cooler Temp.: 3 ' �' 'C Biological Tissue is Frozen: Yes No NfA Date and Initials p rso a�i lnr contents: Temp should be above freezing to VC Comments: Chain of Custody Present: ©es L]No ❑NIA 1. l Chain of Custody Filled Out: [mss ONo ❑NIA 2. Chain of Custody Relinquished: .Yes ONO ❑NIA 3. Sampler Name & Signature on COC: Dyes ®tt' ❑NIA 4. Samples Arrived within Hold Time: 9Y"es ONO ❑NIA 5. Short Hold Time Analysis (<72hr): ❑Yes MX/, ❑NIA 6. Rush Turn Around Time Requested: ❑Yes MN ❑NIA 7. Sufficient Volume: Gros 0 N 11 NIA g, Correct Containers Used: ®Yes ❑No ❑NIA 9. -Pace Containers Used: Dyes ©Atli ❑ NIA Containers Intact: LBYes ONO El NIA 10. Filtered volume received for Dissolved tests ❑Yes ❑No [Ul+flA 11. Sample Labels match COC: 1'J es ONO ❑NIA 12. -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. Yes ❑No 11 N/A 13. All containers needing preservation are found to be in L]rTes ONO ❑NIA compliance with EPA recommendation. _ / ❑Yes exceptions: VOA, coliform, TOC, O&G, WI -DRO (water) ViNo Samples checked for dechlorination: ❑Yes ONO [�KIA 14. Headspace in VOA Vials (>6mm): ❑Yes ONO fUf& 15. Trip Blank Present: ❑Yes ONO fI 71A 16. Trip Blank Custody Seals Present Oyes ONO IN Pace Trip Blank Lot # (ifpurchased): Client Notification/ Resolution: Field Data Required? Y / N Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: KUL Date:kLp', Wo#;92237903 SRF Review: L Date:r + Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( [.e out of hold, incorrect preservative, out of temp, incorrect containers) 1114 IINIIIIIIIIInI --1 59 of 60 Zmr �oszw p�oU PIx Q a PC7a orx0 5 s,auieIUOD jo k pejo•., sseaad) slsea oyloods;uewlpeS Dm�ti o"o e°o � Ej s (33tld) suolua pue g I SMOW 0101- dldS O (33Vd) Hd10 k x Luii ,� 5 (33Vd) suoiuy X1 Alx >� n i ° wd) sle7eW lenol x X X ,Xy ij iE x g aait civic)"m {sm oA $��4! dwaa O Q�a �j I d 1 C C A C \ I 0! c i r -I 3 T e o00 cl q O I LU ❑jj�j`A-f $ (.) ' nW `. . Q_ (� aa� ti0■s qqy0 ri N {' Ci N CL O i a a ib i s U $ o S A 8 n x Z �1 •� 7 VcC i? mv�i o wh 4�60Ci i �°a!`o! rr 73 N LL01owM 0 nC) A u� 72 6!l9 p0r S'w2i � � LU � y q � E ,@,. N Q Uic iN Nt; sa 3333, 333 ! !_ c 9 o Q ° �€ v © � LU li Q 6r c Lum ' Q �� c 14op of suwnloa olepdmdde toa dwoa oi,owolsnD o i..�.._.. .._ ._. _.. .._ ._. 6.1 W l _ Cu " ! g o aialtluio� Isnw �awoisn� 9C o / r(iG�' alo, Wo el Page 72 of 73 0 4 Page 60 of 60 E xl A F- ci � fl ` M ■1 ■ 2 N c tl N � ?z r� to z z •LQ C 2 CL LL v E O � � U U m N a ui 7. Alrc 0 4 Page 60 of 60 CHAIN OF CUSTODYR__ECO_R_D_ REQUEST FORM Page 73 of 73 __ DUKE Analytical Laboratory Services Mail Code MG03A2 (Building 7405) _A__N_D_ _A_N_ALYSIS j i Analytical Laboratory Use Work ober Only NC x i Page 1 Of 1 g Ferry rater Hll ereFer Rd Huntersville, N. C. 28078 ENERGYr Matrix: SOIL ISbab31� j Logged By Date a Time From lesOriginating — SC OH — — DISTRIBUTION ORIGINAL to LAB, K (980) 875.5245COPY 1 I ��'` �•�� I ��G '1 } - )•� I S 7Days SAMPLE 1 PROGRAM Ground Water I to CLIENT _ ....... FJ98 _ _ ax_J875-4Mi._.___._._._.i _ Other_ NPDES Plant RCRA j j i REV DATE 1f23/2015 t)Project Name AB Groundwater Assessment -Soil 2)Phone No: 1 J PACE —I Asheville 4,Fax No: Cooler Tem PO 1142081 tr Pr serv.:1=H C _x_ E 3)CIieM John Toepfer, Duke [24)Comments Metals: Al, Sb, As, Be, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Mercury ■■� H Anions: Cl, Nitrate -N, SO4 Heather Smith, Synterra 2=H SO. 3=H Mark McDade, S nterra E y 7)Mall Coder 4=Ice = one " N u') Lr) U-) U-) U-) t� 0 5)Business Unit: 6)Project ID: ACLAE1402��fi,. as ��■cam ■■■■©�■■■■■nMOM E 10)Process ID .,_,_ ___ - rn , ;d t .► 8) Operating Unit: 9)Activhy ID: G adNCCPSPM Q 3AE00 v '� IX U_ a C. y lme When specific accounting has been established and is not indicated above Preservatives when used must be U) we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or added within 15 minutes of sample Q W +� rn 4 4) 2 Provide correct accounting for Operating Unit and Process ID. collection 0) d U O v V �I I LAB USE ONLY14 Matrix Collection Information _ _ a a �� w C a `-' Q •— N f 4 E m J "Lab ID (Soil, Sediment, Ash) "Sample Description or ID Dat. I Tlttte slanamra U m a a tart r ® Y Accepted By: ULi©��.i��©�■■■©■■ �� / � 22 Requested Turnaround 14 Days x_ Relinquished By Date/Time Accepted By: Date/Time e // O ✓ - C �( .2,13 45rU '1 } - )•� I S 7Days ■■F� Accepts D)aternme r-4 )15— QJ�0 ■�ffili■��©©■■■�■■ Sealed/Locked By Date/Time Sesled/Lock Opened By t Datarrime 48 Hr [24)Comments Metals: Al, Sb, As, Be, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Mercury ■■� H Anions: Cl, Nitrate -N, SO4 as ��■cam ■■■■©�■■■■■nMOM 21)Relinquished By DatelTlme . S 3 � Accepted By: Date/Time �� / � 22 Requested Turnaround 14 Days x_ Relinquished By Date/Time Accepted By: Date/Time e // O ✓ - C �( .2,13 45rU '1 } - )•� I S 7Days Relinquished By Dat/q/�ilme Accepts D)aternme r-4 )15— QJ�0 Sealed/Locked By Date/Time Sesled/Lock Opened By t Datarrime 48 Hr [24)Comments Metals: Al, Sb, As, Be, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Mercury H Anions: Cl, Nitrate -N, SO4