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WQ0001105_Monitoring Report_20170103
\\\ PotashCorp PotashCorp -Aurora Helping Nature Provide December 28, 2016 BETTY G. WILCOX NCDEQ DIVISION OF WATER RESOURCES GROUNDWATER SECTION — PERMITS AND COMPLIANCE UNIT 1636 MAIL SERVICE CENTER RALEIGH, N. C. 27699-1636 �Cply® JAN Re: Semiannual Groundwater Monitoring Data ?Ol% Coolie PondsWRSEcr Permit No. 05 1NFpR��, �PION R�ESS Cooling Facility ING UNIT Wastewater Recycle System PCS Phosphate Inc. - Beaufort County Per Condition No. 20 of the above referenced permit, please find attached the semiannual groundwater monitor well sampling report for samples taken in November 2016. Also attached are a GW -59A Compliance Report Form and a Spreadsheet addressing line item 5 in the GW -59A Form. Please do not hesitate to call me at 252-322-8283 should you have any questions concerning this. Sincerely, /D' I�CL�j KH D. Daniel Winstead III M7. Senior Environmental Engineer SAN 11 PCS Phosphate PC: David May — DWR, WaRO (w/attachments) 12-02-003-02 (w/attachments) 1530 NC Hwy 306 South, Aurora, NC USA 27806 T (252) 322-4111 PotashCorp. I www.potashcorp.com Name: Name (if di' Addresss Well 2626-.:151? #�hot�.. (91S1$0�-i;3ee #: __ VV00001105 EXPIRATION DATE: _ charge X _ UIC - TYPE OF PERMITTED OPERATION BEING MONITORED fort _ Lagoon Remediation: Infiltration Gallery (252)322-8283 Spray Field Remediation No. of Wells to be Sampled 12, Rotary Distributor Land, Application of Sludge ,....�........a..�...........�, %. .., . _ - For Groundwater Treatment II Depth: 21.35 ft. Well Diamter: 2 inch Systems Check One: eened Interval': 18:85ft.. to 20.85 ft. influent (98) pth to Water Level.' 5.37- ft. below measuring point.. HEffluent.(90) asuring Point is 2.85 ft above land surface. .ILITERS of water pumped/bailed before sampling: 2700 Id Analysis: pH 5.5' , Specific Conductance 2640 uMhos Temp: 21.2 oC„ Odor NONE, Appearance: CLEAR PARAMETERS: (Samples for metals were collected, unfiltered` [X YesF_-] No COD N/A mg/L Coliform: MF Fecal N/A /100mL Coliform: MF Total N/A _/100mL boratory Name: PCS PHOSPHATE (Note: Use MPN method for highly turbid samples) rtification No(s) 330 10 Dissolved Solids: Total 2110 mg/L pH (when analyzed,) 5.2 units TOC - -- _ 12.0 mg/L Chloride 43.0 mg/L Arsenic N/A ug/L Grease and Oils N/A mg/L Phenol N/A__ mg/L Sulfate 1206.0 mg/L Specific Conductance N/A uMhos Total Ammonia _ N/A mg/L TKN as N N/A mg/L NOTE: GW -59 Rev 4/98 Water Source Heat Pump te° values should reflect dissolved and If WELL WAS colloidal concentrations DRY at time to sample collected,: 11121/2016_ of sampling, to sample analyzed: 11/21/2016 to 12/15/2016' check boratory Name: PCS PHOSPHATE here: rtification No(s) 330 10 mg/L and field acidified, []Yes ENO) Nitrite (NO2 as N) N/A mg/L Nitrate (NO3 as N) N/A mg/L Phosphorus: Total as P 102.000 mg1L. Orthophosphate - N/A mg/L Al - Aluminum - N/A mg/L Ba - Barium N/A , ug/L Ca - Calcium __ _ __ _ _ _ N/A mg/L Cd- Cadmium <1.0 ug/L Chromium: Total <5.0 uglL Cu - Copper _ _ NLA mg/L Fe - Iron N/A _ ug/L Hg - Mercury N/A ug/L K- Potassium N/A _ mg/L. Mg - Magnesium N/A mg/L Mn - Manganese N/A ug/L Ni - Nickel _ - 14 ug/L Pb_ Lead X5.0,_ ug/L Zn -Zinc N/A_ _ ug /L Ammonia Nitrogen mg/L Other (Specify Compounds and Concentration Units) Fluoride 4:46 mg/L MIRK N/A - ug/L Ag - Silver - - _ _ -. - N/A ug/L Se- Selenium <-10.0 ug/L Sodium 352100 ug/L Organics: (GC, GC/MS, HPLC) (Specify test method #. Attach lab report.) Report, attached? Yes X (1) No (2); VOC BDL method# 6200C method# method#, -Mark D. Johnson, General Manager P ittee (of Authorized, Agent) Name and Title - Please type or print Facilty Name: PCS PHOSPHATE CO., INC. -Aurora Division Permit Name (if different) Facility_ Addresss 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Danny Winstead_ Telephone: (252)322-8283 Well Locations/Site Name: #1 Cooling Pond --- No. of Wells to be Sampled, u iurriuriaauuri INumuer k11V111 rG11111Lf. Hnrr I,-:uc For Groundwater Trea_t_ment h Depth: 33.00 - ft. Well Diamter: 2 inch systema Check ane: ,eened Interval: 30.10 ft. to 32.10 ft. Influent (98) pth to Water Level: 6.02 ft, below measuring point. Effluent (99) asuring Point is 24901 ft above, land surface. :ILITERS ofwater ,pumpe/bailed beore sampling: 2200 Id Analysis: pH 6.4 , Specific Conductance 3600 .uMhos Temp. 20.1 oC, Odor NONE Appearance:. CLEAR Values shouldreflect dissolved and If WELL WAS colloidal concentrations DRY at time sample collected': 1172112016 of sampling,, sample analyzed: 11/21/2016 to 12/15/2016 check ratory Name: PCS PHOSPHATE here: fication No(s) 330 10 Ni - Nickel _ PARAMETERS: (Samples for metals were collected unfiltered ❑X Yes No and field acidified DYes x COD N/A mg/L Nitrite (NO2 as N) N/A mg/L Ni - Nickel _ <10.0 _ ug/L. Coliform: MF Fecal N/A /100mL Nitrate (NO3 as N) N/A mg/L Pb - Leadg/L <5.0 _ u Coliform: MF Total N/A /100mL Phosphorus: 'Total as P' 4.400 mg/L Zn - Zinc N/A ug/L. (Note: use MPN method for highly turbid samples) Orthophosphate N/A. - mg/L Ammonia Nitrogen mg/L Dissolved Solids: Total 3060 mg1L Al - Aluminum N/A mg/L Other (specify compounds and concentration Units) pH (when, analyzed) 6.5 units Ba -'Barium _ _ N/A ug/L Fluoride _ _ <0.3 mg/L TOC 7.7 m JL g Ca -Calcium NIA m 7L 9 MIBK _ - N/A ug/L Chloride -44.0 mg/L Cd- Cadmium _ _ - X1:0 ug/L Ag - Silver N/A _ -_ ug/,L Arsenic _ N/A ug/L Chromium: Total <5'. ug/L Se- Selenium _ <10.0 u9 /L Grease and Oils N/A mg/L Cu - Copper N/A mg/L Sodium - 291750 ug/L Phenol _ _ N/A mg/L Fe - Iron N/A ug/L Organics: (GC; GC/MS, HPLC) Sulfate 17230 mg/L Hg - Mercury N/A ug/L (Specify test method #: Attach lab report.) Specific Conductance N/A uMhos K- Potassium N/A m /L Report attached es X (1) (2j Total Ammonia N/A mg/L Mg -Magnesium __. N/A mg/L G method# VOC _ BD th 62000 TKN as N N/A mg/L Mn - Manganese N/A ug/L method# method# NOTE: GW -59 Rev 4'/98 Mark D. Johnson, General Manager Permittee (of Authorized Agent) Name and Title - Please type or print' f Signature of Permittee (or Authorized Agent) (Date) acilty Name: PCS PHOSPHATE CO, INC. - Aurora Division Dermit Name (if different): acility Addresss 1530 NC Hwy 306 South Aurora, NG 27806 County: Beaufort contact Person: Danny Winstead Telephone, (252)322-8283 Well Locations/Site Name: #1 Cooling Pond No. of Wells to: be Sampled Depth: 22.00 ft. Well Diamter: ened :Interval:. -18.51 ft, to 20.51 ft. MW1=4A For Groundwater Treatment 2inch Systems Check One "Influent (98) Depth. to Water, Level, NIA ft. below measuring point Effluent (99) Measuring Point is 3.10 - ft above land surface. MILILITERS of water pumped/bailed before sampling: NIA Field Analysis: pH N/A , Specific Conductance NIA uMhos Temp. NIA oC„ Odor NONE Appearance: CLEAR PARAMETERS: (Samplesformetals were collected unfiltered 1 Yes n/a No COD N/A mg/L Coliform: MF Fecal N/A. /100mL Coliform: MF Total N/A /100mL (Note:' Use MPN method for highly turbid :samples) - Dissolved Solids: T I N! m /L pH (when analyzed N s TOC N I� Chloride _ WA mg/L Arsenic N/A ug/L Grease and Oils N/A mg/L Phenol N/A mg/ Sulfate NIA -L mg/L 'Specific Conductance N/A uMhos Total Ammonia NIA mg/L TKN as N N/A mg/L NOTE: GW -59 Rev 4/98'. Nitrite (NO2, as N) N/A Nitrate (NO3 as N) N/A Phosphorus: Total as P N/A RMIT #: W00001105 EXPIRATION DATE: t n -Discharge X UIC DES PE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray'Field Remediation : Rotary Distributor Land Application of Sludge Water Source Heat Pump Values should reflect dissolved and If WELL WAS colloidal concentrations DRY at time Date sample collected: 11121/2016 of sampling, Date sample analyzed: 11/2112016' to 11/2112016 check Laboratory Name: PCS PHOSPHATE here::' Certification No(s) 330 10 Chromium: Total N/A Cu - Copper' N/A Fe - Iron N/A Hg - Mercury N/A K- Potassium N/A Mg - Magnesium N/A Mn - Manganese N/A _. and field acidified Des R No ) mg/L Ni -Nickel _ ._ N/A ug/L mg/L Pb - Lead N/A ug/L. mg/L Zn - Zinc _ __ _ _ _ N/A ug/L m61L Ammonia Nitrogen mg/L mg/!_ Compounds and Concentration Units) ug/1" .0ther'S,ecify ft. N/A /L g_ I9 m 9 N/A u /L g ug/L Ag - Silver _ N/A ug/L ug/L Se- Selenium. _ N/A ug/L mg/L Sodium N/A ug/L ug/L Organics: (GG, GC/MS, HPLC) ug/L (Specify test method #. Attach lab report.) mg/L Report attached? Yes (1)� No X (2) mg/L VOC method# ug/L _ _ method# method# Mark D. Johnson General Manager P mittee (of Authorized Agent) Name and Title - Please type or print c•�.a p -y-. ilk_ 1�'eA� �: J c��n.t�r+✓ � JAZC bag i Signature of Permittee (or Authorized Agent) (Date) Depth to'Water Level: N/A ft. below measuring point. Effluent (99) Measuring Point is 3.15 ft above land surface. MILILITERS of water pumped/bailed before sampling: N/A Field Analysis: pH N/A , Specific. Conductance N1A _uMhos Temp. N/A oC, Odor NONE Appearance: CLEAR colloidal concentrations DRY at time sample collected: 11/21/2016 of sampling, sample analyzed: 11/21/2016 to 11/2112.01_6 check ratory Name: PCS PHOSPHATE here: Fication No(s) 330 10 PARAMETERS: (Samples for metals were collected unfiltered Yes n/a No and field acidified UYes n/a INo ) COD N/A mg/L Coliform: MF Fecal N/A /100ml- Coliform: MF Total N/A /1OOmL (Note: Use MPN method for highly turbid samples) Dissolved Solids: Total N/A mg/L pH (when analyzed) N/A units TOC NIA_ Chloride N/ Arsenic N/A ug/L Grease and Oils N/A mg/L Phenol N/A mg/L Sulfate N/A mg/L Specific Conductance N/A uMhos Total Ammonia N/A mg/L TKN as N N/A mg/L NOTE: GW -59 Rev 4/98 Nitrite (NO2 as N) N/A mg/L Ni - Nickel N/A ug/L Nitrate (NO3 as N) N/A mg/L Pb - Lead N/A ug/L Phosphorus: Total as P N/A mg/L Zn - Zinc N/A ug/L Orthophosphate N/A mg/L Ammonia Nitrogen mg/L Al - Aluminum N/A mg/L Other (Specify Compounds and Concentration Units) Ba - Bariun N ug/L Fluoride N/A mg/L _ g/L - N/A ug/L i g/L N/A ug/L C r ium:�o�ta N/A — ug/L e-"Seenium NIA ug/L Cu - Copper N/A mg/L Sodium N/A ug/L Fe - Iron N/A ug/L Organics: (GC, GC/MS, HPLC) Hg - Mercury N/A ug/L (Specify test method #. Attach lab report.) K- Potassium N/A , mg/L Report attached? Yes (1) No X (2) Mg - Magnesium N/A mg/L VOC method# Mn - Manganese N/A ug/L method# method# Mark D. Johnson General Manager Permittee (of Authorized Agent) Name and Title - Please type qr print Signature of Permittee (or Authorized Agent) (Date) Facilty Name: PCS PHOSPHATE, CO., INC. -Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South _ Aurora, NC -27806 County: Beaufort Contact Person: Danny Winstead Telephone: (252)322-8283 Well Locations/Site Name: #1 Cooling Pond No. of Wells to, be Sampled. IFor Groundwater Treatment Check One: ened Interval 30.0027.15 ft to Well 2i9: 5erft 2 inch systems Influent (98) 3th to. Water Level: NIA ft. below measuring point. I I (Effluent (99) asuring Point is 2.92 ft•above land surface. .ILITERS of water pumped/bailed before sampling,: NIA 10 Analysis pH N/A , Specific Conductance N/A_ uMhos Temp. NIA oC, Odor NONE Appearance: _ CLEAR'___ [jJi��,[Unj IYy KFV�LV /a?Il � {II[J1K \a [aJ VV -VVVV M WQ0001106 EXPIRATION DATE: _ r.harge _ X LlIC OF PERMITTED OPERATION BEING MONITORED, Lagoon Remediation: Infiltration Gallery Spray Field Remediation RotaryDistributor Land Application of Sludge Other Water Source Heat Pump Values should reflect dissolved and. If WELL WAS colloidal concentrations DRY at time sample collected: 11/21/201.6 of sampling, sample analyzed: 11/21/2016 to 11/2112016 check ratory Name: PCS PHOSPHATE' here; Fication No(s) 330 10 PARAMETERS: (_Samples for metals were collected unfiltered Yes n/a No and fieldacidified E]Yes Na No ) COD N/A mg/L Nitrite (NO2 as N) N/A mg/L Ni - Nickel _ N/A ug/L Coliform; MF Fecal N/A- /100mL Nitrate (NO3 as N) N/A mg/L Pb - _Lead N/A ug/L Coliform: MF Total N/A /100mL Phosphorus: Total as P N/A mg/L. Zn - Zinc N/A ug/L (Note: Use MPN method for highly turbids Pies) Orthophosphate N/A g/L mmonia Nitrogen mg/L Dissolved dTotal um - . � �9/ her . d ntration units) pH ' (_.when analyzed) ) r N/A ori N/A mg/L TOC _ J N/A g rt N/A ug/L. Chloride N/A, mg/L Cd- Cadmium N/A ug/L Ag Silver N/A ug/L Arsenic N/A ug/L Chromium: Total N/A ug/L Se= Selenium _ N/A ug/L Grease and Oils. NIA, mg/L Cu - Copper N/A mg/L Sodium _ N/A ug/L Phenol N/A. _ mg/L Fe - Iron N/A ug/L Organics- (GC, GC/MS HPLC) Sulfate N/A rng/L Hg - Mercury N/A ug/L (Specify test method #. Attach lab report.). Specific Conductance N/AuMhos K- Potassium NIA _ mg/L Report attached? •Yes (1) No X (2). Total Ammonia, N/A mg/L Mg -Magnesium __ - ___ N/A mg/L VOC - - method# TKN as'N N/A mg/L Mn- Manganese _ _ NSA ug/L method# method#' NOTE: GW -59 Rev 4/98 Mark D. Johnson, General Manager _ Pepr�mittee (of Authorized Agent) Name and Title - Please type qr print e ) Q Signature of Permittee (or Authorized Agent) (Date) Facilty Name: PCS PHOSPHATE CO., INC. -Aurora Division - Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South __- Aurora, NC 27806 County: Beaufort Contact Person: Danny. WinsteadTelephone: (262)322-8283 'Well Locations/Site Name: 41 Cooling Pond No. of Wells to be Sampled 12 !u IUCI un6auvII IYUMILMI 1uvu1 rC11111y: inrr Ivo For Groundwater Treatment 11 Depth: 38.50 ft. Well Diamter: 2 inch systems Check 0.ne: reened Interval: 35.60 ft. to 37.60 ft. Influent (98) pth to Water Level: NIA ft. below, measuring point. Effluent (99)_ asuring Point is 2.44 ft above land surface. _ILITERS of water pumped/bailed before, sampling: NIA Id Analysis: pH NIA , Specific Conductance NIA _uMhos Temp., NIA oC, Odor NONE Appearance CLEAR - .MIT #: WQ0001105 EXPIRATION DATE:' -Discharge X UIC OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation:' Infiltration Gallery Spray Field Remediation Rotary Distributor Land Application of"Sludge Water Source Heat Pump Values should reflect dissolvedand colloidal concentrations sample collected: sample analyzed: y Name: on No(s) 11121/2046 11121/2016 to 11/2112016 10 - PARAMETERS: (Samples for metals were collected unfiltered Yes .nia No and field acidified uYes n/a No ) COD N/A mg/L Nitrite (NO2 as N) N/A mg/L. Coliform; MF'Fecal N/A.__ /100mL Nitrate (NO3 as N) - N/A mg/L Coliform: MF Total N/A /100ml- Phosphorus: Total as P N/A mg/L (Note: Use MPN method for highly to �s les) Orthophosphate N/A /L Dissolved Solids: Total I! m I N/A ! pH' (when analyzed) TOC /A mga -lakl'!A!!�N/A mg/L Chloride _- - _ N/A mg/L Cd- Cadmium _ N/A ug/L. Arsenic N/A ug/L Chromium: Total -_ _ NIA ug/L Grease and Oils NIA mg/L Cu -Copper N/A mg/L Phenol. N/A _ mg/L Fe - Iron N/A ug/L Sulfate N/A mg/L Hg -Mercury N/A ug/L Specific Conductance N/A uMhos K- Potassium - N/A mg/L Total Ammonia - NIA mg/L Mg - Magnesium __ _- _ N/A mg/L TKN as 'N _ N/A mg/L Mn - Manganese _ -__ N/A ug/L NOTE: If WELL WAS DRY at time of sampling_ „ check Ni -Nickel Pb - Lead Zn - Zine -_ - N/A N/A N/A ug/L ug/L ug/L (Aorrionia Nitrogen mg/L mg/Lwr N/A ug/L. Ag - Silver _. _ - _ NIA uglL Se- Selenium N/A ug/L Sodium N/A ug/L Organics: (GC, GC/MS, HPLC) (Specify test method #'. Attach lab report.) Report attached? Yes (1) No X (2) VOC method# method# method# - Permittee (of Authorized Agent) Name and Title - Please type or print - ?�-�- F� ; _ r�►/�11- P, 170h"4014-2 GW -59 Rev 4/98 Signature=of Permittee (or Authorized Agent) r i PkRtAIIENi QF F.Narl120ht1UEENt § IV41URAL RESf1l1RCh 7 �U l�i�'' %��-� .n��o ttoilr - • • ©IVIS10Nd ©Fw .7 R£SflL1R�ES Ifi1FCdRiY#AtIQhE PRot ESSRVCS liNiT `s.OMP�NkiCi �G�R� _ :::. -.: • •• • i6�7IUikll..:.at`ERyaCECENTIrR;. N/A EAI- IS N, -NG 276261$17 i�hone- 1919100 63A6 FACILITY' INFORMATION PERMIT M W00001.105 _ EXPIRATION DATE: 06/30/19 Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Non -Discharge X UIC _ Permit Name (if different): NPDES Facility Addresss: 1530 NC Hwy 306 South TYPE OF PERMITTED OPERATION BEING MONITORED Aurora, NC 27806 County-. Beaufort. Lagoon Remediation: infiltration Gallery Contact Person:- Danny Winstead.. Telephone; (252)322-8283 Spray Field Remediation: Well Locations/Site Name: #1 Cooling Pond No. of Wells to be Sampled 12 Rotary Distributor Land Application of Sludge Well Identification Number (from Permit): MW1-6AR For Groundwater Treatment X __Other Water Source Heat Pump - Well Depth;' 33,00 ft. Well Diamter 2 inches systems check One: 7.500 Screened Interval30.00 ft.. to 32.00 ft. Uffluent.(99) fluent (98) Note: Values should reflect dissolved and If WELL WAS Depth to'Water Level: 6.16 ft. below measuring point. Orthophosphate _ colloidal concentrations DRY at time Measuring Point is 3.05- . ft above -land surface. Date sample collected: '11/2212016 of sampling; MILILITERS of water pumpedibailed before samplings 2.200 Date sample analyzed: 11122/2016 to 12/1512016_ check Field Analysis: pH 6.1 Specific Conductance 1570 uMhos Laboratory Name: PCS PHOSPHATE, here: Temp. 16.9 oC, Odor NONE Appearance: CLEAR _ _ _ Certification No(s) 330 10 6.0 units PARAMETERS: (Samples for metals were collected unfiltered 0 Yes F—] No and field acidified [jYes ]No) COD N/A mg/L Nitrite (NO2 as N) N/A mg/L Ni - Nickel <10.0 ug/L Coliform: MF Fecal N/A /100mL Nitrate (NO3 as N) N/A mg/L Pb- Lead <5.0 ug/L Coliform: MF Total. N/A /100mL Phosphorus: Total as P 7.500 mg/L Zn - Zinc NIA ug/L (Note: u'se,MPN method for highly turbid samples) Orthophosphate N/A mg/L Ammonia Nitrogen mg/L Dissolved Solids: Total 1170' mg/L Al - Aluminum N/A mg/L Other (Specify Compounds and Concentration Units) pH (when analyzed) 6.0 units Ba - Barium N/A ug/L Fluoride 0.63 mg/L TOC 12.3 - mg/L Ca - Calcium _ N/A mg/L MIRK _ N/A ug/L Chloride 39.0 nig/L Cd- Cadmium - <1:0 ug/L Ag - Silver N/A ug/_L Arsenic N/A ug/L Chromium: Total _ _ <5,O ug/L Se- Selenium <10.0 ug/L Grease and Oils N/A mg/L Cu - Copper N/A mg/L Sodium 69160 ug/L Phenol N/A _ mg/L. Fe - Iron NIA _ ug/L Organics: (GC, GC/MS, HPLC) Sulfate _ __ 460.0 mg/L. Hg- Mercury N/A ug/L (Specify'test method#.. Attach lab report.) Specific Conductance N/A uMhos K- Potassium N/A ' mg/L Reportattached? Yes X (1) No (2) Total Ammonia N/A mg/L Mg - Magnesium _ __. _N/A _ mg/L VOC BDL method# 2600C TKN as N' N/A mg/L Mn - Manganese _ _ N/A ug/L method# _ method# NOTE; GW -59 Rev -4/98 Mark D. Johnson: General Manager Permittee (of Authorized Agent) Name and Title - Please type of print j FoFoe_ ia'1Ae14 T —70ai".Q J S � p.9,✓i'z t Signature of Permittee (or Authorized Agent) (Date) LI,NCE RPtT It}RM Facilty Name: PCSPHOSPHATECO., INC. -,Aurora: Division_ Permit Name'(if different): FacilityAddresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Danny Winstead Telephone: (252)322-8283 Well LocationslSite Name: 41 Cooling Pond No. of Wells to be Sampled - 1211 1UW1la1waLwu wu111ucr tnvIu rC11111L). Jr1rr I -0L31\ - For Groundwater Treatment ell Depth: 46.50_ -_ - ft. Well Diamter: 2 inches systems check One: ;reeved Interval: 43.50 ft. to 45.50 ft.Influent (98) apth to. Water Level: 6.08 ft. below measuring point., HIEffluent (99) easuring Poinfis 2.95- ft above land surface. ILILITERS of water pumped/bailed before sampling: 2200 eld Analysis: pH 6.4 , Specific Conductance 3090 uMhos Temp. 16.7 OC, Odor NONE Appearance: CLEAR .MIT#: WQ0001105 EXPIRATION DATE: 06/30/19 -Discharge X UIC E OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field Remediation: Rotary Distributor Land Application of`Sludge Water Source Heat Pump Values should -reflect dissolved and WELL WAS colloidal concentrations DRY at time sample collected: 1112212016 of'sampling, sample analyzed 11/22/2016 to 12/15/201_6 check ratory Name: PCS PHOSPHATE here: fication No(s) 330 10 PARAMETERS: (Samples, for metals were collected unfiltered Yes No and field acidified uYes u'No ) COD N/A mg/L Nitrite (NO2 as N) N/A rng/L Ni - Nickel <100 ug/L Coliform: MF Fecal N/A /100mL Nitrate. (NO3 as N). N/A mg/L Pb - Lead <5.0 _ ug/L Coliform:; MF Total N/A /100mL Phosphorus: Total as P 0.450 mg/L Zn -Zinc N/A ug/L. (Note: Use MPN method for highly turbid samples) Orthophosphate _ N/A mgLL Ammonia Nitrogen mg/L Dissolved Solids;: Total 2640 mg/L Al - Aluminum N/A mg/L Other (Specify Compounds and Concentration Units) pH (when analyzed) 6.6 units Ba- Barium N1A ug/L Fluoride 0.59 mg/L TOC -_ , _ _ 6.6 mg/L Ca - Calcium N/A mg/L MIRK _ _ N/A ug/L Chloride,--_ 72.0 mg/L Cd- Cadmium <.1.0 ug/L Ag-- Silver N/A ug/L Arsenic N/A ug/L Chromium: Total <5.0 ug/L Se- Selenium <10.A ug/L Grease and Oils N/A mg/L Cu - Copper _ - _ N/A mg/L Sodium 220550 ug/L Phenol N/A, mg1L Fe - Iron N/A ug/L Organics: (GC, GC/MS; HPLC) Sulfate . _ ___ _ - _ __ 1461.0 mg/L Hg - Mercury N/A. ug/L (Specify test method #. Attach lab report,) Specific Conductance N/A uMhos K Potassium NLA mg/L Report attached? Yes X (1) No (2) Total Ammonia N/A mg/L Mg - Magnesium N/A mg/L VOC _ _ _ 'BDL method# 62000 TKN as N N/A mg/L Mn - _Manganese _ N/A ug/L method# method# NOTE: Permittee (of'Authorized Agent) Name and Title - Please type or print GW -59 Rev 4/98' Signature of Permittee (or Authorized Agent) (Date) U`tY MQ+11TaRtIUk fiitRM...::.;.....:.:. acilty Name: PCS. PHOSPHATE, CO., INC. - Aurora Division 2ermit Name (if different): -acility Addresss 1530 NC Hwy 306South Aurora, NC 27806 County:- Beaufort contact Person; DannyWinstead Telephoner (262)322-8283 Well Locations/Site, Name: #1 Cooling Pond No. of Wells to be Sampled - - ------ -- --------- fell Depth: 15.00- ft. Well Diamter: 2 inch Systems Check One: creened interval-: 11.80 ft. to 13.80 ft. Influent (98) epth to Water Level: - 6.77 ft. below measuring •point. Effluent (99) leasuring Point is 3.04 ft above land'surface: IILILITERS of water pumped/bailed before sampling: 2100 ield Analysis: pH 5.3- Specific Conductance 1081 uMh.os Temp.. 17.6 oC, Odor NONE - Appearance: CLEAR_ M W00001106 EXPIRATION DATE: harge X UIC OF PERMITTED_ OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field Remediation: Rotary Distributor Land Application of Sludge: Water Source Heat. Pump Values should reflect dissolved and If WELL WAS colloidal concentrations DRY at time sample collected:- 11/2112016 of sampling, sample analyzed-.- _11/21/2016 to 12/15/2016 check ratory Name: PCS PHOSPHATE here: fication No(s) 330 10 Ni - Nickel PARAMETERS: (Samples for metals were collected' unfiltered Yes No and field acidified Yes x COD NLA mg/L Nitrite (NO2 as N) N/A mg/L Ni - Nickel 14 ug/L Coliform: MF Fecal - N/A 1100mL. Nitrate (NO3 as N) N/A mg/L Pb - Lead' <5.0 __ ug/L Coliform:: MF Total NIA. /100mL. Phosphorus: Total as P 18.950 mg/L Zn - Zinc N/A ug/L (NoW use MPN method for highly turbid samples) Orthophosphate - N/A mg/L Ammonia Nitrogen mg/L Dissolved Solids: Total 861 mg/L All - Aluminum N/A mg/L Other (Specify Compounds and Concentration Units) pH (when analyzed) - 5,4 units Ba - Barium. NIA ug/L Fluoride 11.40' mg/L TOC 8.0 rng/L Ca - Calcium N/A mg/L MIBK N/A ug/L Chloride 11.0 mg/L Cd- Cadmium <1.0 ug/L Ag - Silver N/A ug/L A eniice s NLA ug/L Chromium: Total' X5.0 _ ug/L Se- Selenium <10:0 ug/L. Grease and Oils N/A mg/L Cu - Copper N/A mg/L Sodium _ 51,330 ug/L Phenol N/A mg/L Fe - Iron N/A_ ug/L 'Organics: (GC, GC/MS, HPLC) Sulfate - __- _. _ _ 435.0• mg/L Hg - Mercury N/A ug/L (Specify test method #; Attach lab report.) Specific Conductance NIA uMhos K -Potassium NIA mg/L Reportattached? Yes X (1) No (2) Total Ammonia N/A mg/L Mg - Magnesium -__ _ N/A _ . mg/L VOC BDL method# 6200C _ TKN as N NIA mg/L Mn - Manganese _ - N/A_ ug/L method# - method# NOTE: Pe rttee (of Authorized Agent Name and Title - Please type or print GW -59 Rev 4/98! M WQ0001105'EXPIRATION DATE: charge X UIC PERMITTED OPERATION BEING MONITORED Lagoon. Remediation: Infiltration Gallery Spray Field Remediation : Rotary Distributor Land Application of Sludge ill Identification. Number (from Permit): MW1.713 For Groundwater Treatment X Other Water Source Meat Pump 41 Depth: 37.50 _ _ ft. Well Diamter. 2 inch Systems Check One: reened interval: 34.40 ft. to 36.40 it. Influent (98) Note: Values should reflect dissolved and pth to Water Level:, 5.38 ft. below measuring point. Effluent (99)_ colloidal concentrations asuring Point is 3.08 ft above land surface. Date sample collected: 11/21/2016 _ILITERS of water pumped/bailed before sampling;' 2200. Date sample analyzed: 11/21/2016 to 12/15/2016, �Id Analysis: pH 6.6 , Specific Conductance 21.20 uMhos Laboratory Name: PCS PHOSPHATE Temp. 17.5 _ oC„ Odor NONE Appearance: CLEAR _ _ Certification No($) 330 10 NELL WAS IY at time sampling, PARAMETERS: (Samples for metals were collected unfiltered Yes F—] No and field acidified []Yes FX ]No) COD N/A mg/L Nitrite (NO2 as N) N/A mg/L Ni - Nickel <10.0 ug/L Coliform. MF Fecal _N/A /100mL Nitrate (NO3 as N) N/A mg/L Pb - Lead <5.0 ug/L, Coliform: MF Total' N/A /100mL Phosphorus: Total as P 0.460 mg/L Zn -Zinc. NIA ug/L (Note: Use MPN method for highly turbid samples) Orthophosphate . N/A mg/L Ammonia Nitrogen mg/L Dissolved Solids:' Total 1450 mg/L AI - Aluminum N/A mg/L Other (Specify Compounds and Concentration Units), pH (when analyzed) 6.7 units Ba - Barium N/A ug/L Fluoride <0:3 mg/L TOC _ 3,0 mg/L Ca - Calcium N/A mg/L MII3K N/A ug/L Chloride 150.0 mg/L Cd'- Cadmium <1:0 ug/L Ag - Silver . N/A ug/L. Arsenic. N/A ug/L Chromium: Total <5.0 _ ug/L Se -Selenium <10.0 ug/L Grease and Oils N/A mg/L Cu - Copper _ N/A mg/L Sodium 151450 ug/L Phenol' 'N/A mg/L Fe - Iron N/A _ _ ug/L Organics: (GC, GC/MS; HPLC) Sulfate _ _374,0 mg/L Hg - Mercury N/A ug/L (Specify test method #. Attach lab report.) Specific Conductance N/A uMhos K- Potassium NIA mg/L Report attached? Yes X (1) No (2) Total Ammonia _ NIA mg/L Mg - Magnesium _ 'N/A mg/L VOC _ _ BDL method# 6200C TKN as N N/A mg/L Mn - Manganese N_ /A. ug1L method# method# NOTE: P m ee (ofAuthorizedAgentL-N-ame and Title - Please tipe or print e A1,N_ dam' nfnn i R, Vo xi /—L 4 4 Ti"44K .t/< i��4k3�J✓ GW -59 .Rev 4/98 Signature of Permittee (or -acilty Name: PCS PHOSPHATECO., INC. - Au-rora Division, Dermit Name (if different): :acilityAddresssm 1530 NC Hwy 306 South Aurora, NC_27806 County- Beaufort 'ontact Person:Danny Winstead Telephone: (252)322-8283' Well Locations/Site Name: #1 Cooling Pond No. of Wells to be Sampled Identification Number (from Permit): MW1-8A IForGroundwaterTreatntent Depth: 16.50 ft. Well Diamter: 2 inch• systemsCheck One: Bned lnterval: 13.10 ft. to 15.10 ft'. Influent (98) pth to. Water Level: 5.19 ft. below measuring point. I I J Effluent (I asuring Point is 3.08 ft above land surface. -(LITERS of water pumped/bailed'before sampling; 2200 Id Analysis: pH 4.6 , Specific Conductance 2100 uMhos Temp. 18.3' oC,• Odor NONE Appearance; CLEAR PARAMETERS: (Samples for metals were collected unfiltered [X Yes F-1 No COD . N/A mg/L Coliform: MF Fecal N/A /100mL Coliform_ : MF Total N/A. /100mL (Note: Use MPN method for highly turbid samples) N/A Dissolved Solids; Total 1950 mg/L pH (when analyzed) 4.2 units TOC 6.7 mg/L Chloride 15.0 mg/L Arsenic N/A ug/L Grease and Oils N/A mg/L Phenol N/A mg/L Sulfate 1207.0 mg/L Specific Conductance N/A uMhos Total Ammonia _ N/A mg/L TKN as N N/A mg/L NOTE: GW -59 Rev 4/98 (....... ... #: WQ0001105 EXPIRATION DATE: charge X UIC OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray field Remediation Rotary Distributor Land Application of'Sludge Water Source Heat Pump Values:should reflect dissolved and WELL WAS colloidal Concentrations. DRY at t time sample collected:-' 11/21/2016 of sampling, sample analyzed: 11/21/2016 to 12115/2016' check ratory Name: PCS PHOSPHATE here: hcation No(s) 330 10 and field acidified Des X�No ). Nitrite (NO2 as N) N/A mg/L Nitrate,(NOs as N) N/A mg/L Phosphorus: Total as. P 76.500_ mg/L Orthophosphate _• N/A mg/l, Al - Aluminum N/A_ _ mg/l_ Ba - Barium N/A _ ug%L Ca - Calcium NLA mg/L Cd- Cadmium <1.0 ug/L Chromium: Total 6.0 ug/L Cu - Copper N/A mg/L - Fe - Iron N/A ug/L: Hg - Mercury N/A ug/L K- Potassium N/A... mg/L Mg - Magnesium N/A mg/L. Mn - Manganese N/A ug/L Ni - Nickel, 59 ug/L Pb - Lead <5:0 ug/L Zn - Zinc N/A ug/L Ammonia Nitrogen mg/L, Other (Specify Compounds and'Concentration Units) Fluoride 26.00 mg[L MIBK N/A ug/L Ag -'Silver N/A ug/L Se- Selenium <10.0 ug/L Sodium - -_ -- 107850 _ ug/L. Organics: (GC, GUMS, HPLC) . (Specify test method #. Attach lab report:) Report attached? Yes X (1) No (2) VOC _ _ _ BDL method# 6200C method# _ method# P. tee (ofAuthorized Agent) Name and Title - Please type or print 2 jp p -acilty Name: PCS PHOSPHATE CO., INC. - Aurora Division 3ermit Name (if different): =acility Addresss: 1530 NC Hwy 306"South Aurora, NC 27806 County Beaufort ontact Person: Danny Winstead Telephone: (252)322-8283' Well, Locations/Site Name: #1 Cooling Pond No. of Wells to be Sampled IT #: WQ00011. 05 EXPIRATION DATE: ischarge X UIC OF PERMITTED OPERATION'BEING MONITORED: Lagoon Remediation: Infiltration Gallery Spray Field Remediation Rotary Distributor LandApplication of Sludge II Identification Number (from Permit): MW1-813 For Groundwater Treatment II Depth: 36.50 ft. Well Diamter: 2 inch_ _ _ systems Check one: •eened Interval: 33.00 ft. to 35.00 ft. Influent (98) HEffluent -- --X- Other Water Source Heat Pump Note: Values should reflect dissolved and If WELL. WAS pth to Water Level: 3.54 ft. below measuring point (99) _ colloidal concentrations DRY at time asuring Point is 3.04 ft above land surface. Date sample collected: 11129/2016 of sampling, .ILITERS of water pumped/bailed. before sampling: 2600 Date sample analyzed: 11/21/2016 to 12/15/2016 check Id Analysis: pH 6.2 , Specific Conductance 6020 uMhos Laboratory Name: PCS PHOSPHATE here: Temp. 16.9 oC, Odor NONE Appearance: CLEAR Certification No(s) 330 10 N/A PARAMETERS: (Samples for metals were collected unfiltered ❑X Yes F-1 No and field acidified HYes IX I No ) COD N/A m /L g Nitrite NOz as N ( ) N/A m /L g Ni -Nickel <10 0 ug/L Coliform: MF Fecal N/A I100mL Nitrate (NO3 as N) N/A mg/L - _- Pb - Lead <5.0 ug/L Coliform: MF Total N/A /1 OOmL Phosphorus: Total as P 1.520 mg/L Zn - Zinc N/A ug/L (Note: Use MPN method for highly turbid samples) Orthophosphate N/A mg/L Ammonia Nitrogen mg/L Dissolved' Solids: Total _ 5390 mg/L Al -Aluminum -_ -_ N/A mg/L Other (Specify Compounds and Concentration Units) pH (when analyzed) 6.4 units Ba - Barium NIA ug/L Fluoride <0.3 mg/L. TOC 5' 9 mg/L Ca - Calcium N/A mg/L MLBK N/A ug/L Chloride 134.0 mg/L Cd- Cadmium <1.0 ug/L Ag - Silver N/A ug/L Arsenic - N/A ug/L Chromium: Total <5.0 ug/L Se- Selenium <100 _ ug/L Grease and Oils _._ N/A mg/L Cu - Copper _ N/A mg/L Sodium 42630.0_ ug/L Phenol N/A mg1L Fe - Iron N/A ug/L Organics: (GC, GC/MS; HPLC) Sulfate _. 2893.0 mg/L Hg - Mercury _ N/A ug/L (Specify test method #. Attach lab report.) Specific Conductance N/A uMhos K- Potassium N/A mg/L Report attached? Yes X (1) No (2). Total Ammonia N/A mg/L Mg - Magnesium N/A mg/L VOC BDL method# 62000 TKN as N __ N/A mg/L Mn -Manganese N/A vg/L method# _ - method# NOTE: Mark D. Johnson. General Manager • � Pee �f Authorized Agent) Name and Please type or print GW -59 Rev 4/98 Signature of Permittee (or Authorized Agent) (Date) -acilty Name: PCS PHOSPHATE, CO., INC. -Aurora Division_ 'ermit Name (if different) =acility Address; 1530 NC, Hwy 306 South Aurora, NC 27806 County: Beaufort ontact Person:. Danny Winstead Telephone: (252)32278283 Well Locations/Site Name: #2 Cooling Pond No. of Wells to be Sampled' I Identification Number (from Permit);, MW24AR. F I Depth:; 23.50 ft. WellDiamter: 2 inch_ s :ened Interval: 20.70 ft., to 23.20 ft. ith to Water Level: 15.64 ft: below measuring point. Isuring Point is 3.00 ft above land surface. ILITERS of water pumped/bailed before sarripling: 3200 (98). Id Analysis: pH 5.2 , Specific Conductance 938 uMhos Temp. 20.3 oC, Odor NONEAppearance: CLEAR _. PARAMETERS: (Samples for metals were collected unfiltered ❑X Yes F_1 No COD NLA mg/L Coliform: MF Fecal N/A /100mL Coliform: MF Total N/A _. /100mL (Note: Use MPN method for highly turbid samples) N_ /A Dissolved Solids: Total 683 mg /L pH (when analyzed) 5.2 units TOC 4.4. mg/L Chloride 47.0 mg/L. Arsenic N/A ug/L Grease and Oils N/A mgLL Phenol: N/A. mg/L Sulfate 296:0 mg/L Specific Conductance N/A uMhos Total Ammonia. N/A. mg/L TKN as N N/A mg/L NOTE: GW -59 Rev 4/98. M W0000.1.105 EXPIRATION DATE: X UIC �L3NITs':i 06/30/19 TYPE' OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field Remediation: Rotary Distributor Land Application of Sludge X Other Water Source Heat Pump Note: Values should ,reflect dissolved and If WELL WAS colloidal concentrations DRY at time Date sample collected: 11/2812016 of sampling, Date sample analyzed-: 11/28/2016 to 12/16/2016- check ry Name: PCS PHOSPHATE ion No(s) 330 10 and field acidified HYes uNo) Nitrite (NO2 as N) N/A mg /L Nitrate (NO3 as N) N/A mg/L Phosphorus: Total as P 8:750 mg/L Orthophosphate N_ /A mg/L Al - Aluminum _ _ N/A mg/L Ba - Barium N/A ug/L Ca - Calcium N/A mgLL Cd- Cadmium <1.0 ug/L 'Chromium: Total <.5.0 ug/L Cu - Copper _ N/A mg/L Fe - Iron N/A ug/i, Hg - Mercury N/A ug/L K- Potassium _ N/A_ mgLL Mg - Magnesium N/A mg/L Mn -'Manganese _ . N/A ugLL Ni - Nickel <10:0 ug/L Pb -- Lead <5.0 ug/,L Zn - Zine _ N/A ugLL Ammonia Nitrogen mg/L Other (Specify Compounds and Concentration units) Fluoride, 4.18 mg/L MIBK N/A ug/L Ag - Silver _ N/A ug/L Se- Selenium <10:0 ugLL Sodium, 56940 ug/L Organics: (GC,, GC/MS, HPLC) ,(Specify test.method #'. Attach lab report.) Report attached? Yes X (1) No. __ ___ (2) VOC BDL method# 6200C method# method# P 'it of Authorized Agent) Name and. Title - Pleasje type or print y Facilty Name, PCSPHOSPHATE CO., INC. -Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South_ Aurora, NC 27806 County:. Beaufort Contact -Person: Danny Winstead Telephone: (252)322-8283 Well Locations/Site Name: #2 Cooling Pond No. of Wells to be Sampled ill Identification Number (from Permit):: MW2 9 BR- For Groundwater rreatme ph Depth: 43.00 ft. Well Diamter: 2 inch systems cheek ore: ---- reened Interval: 39.90 ft. to 42.40 ft. Influent(98) th to Water Level: 18.68' ft. below measuring g point. Effluent (99) osuring, Point is 2.70 ft above land surface. LILITERS of water pumped/bailed before sampling 2600 dd Analysis: pH 6.5 , Specific Conductance 3890 uMhos Temp. 19.7 oC, Odor NONE Appearance: CLEAR ERMIT'#: W000011051_ on -Discharge X PDES EXPIRATION DATE:_ _ UIC OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field _ Remediation: Rotary Distributor Land. Application of Sludge C Other _ Water Source Heat Pump Values should reflect dissolved and If WELL WAS colloidal concentrations DRY at time sample collected: 11/28/2016 of sampling, sample analyzed: 11/28/2016 to 12/16/2016 check ratory Name: PCS PHOSPHATE here; fication No(s) 330 10 PARAMETERS: (Samples for metals were collected unfiltered ❑X Yes 0 No and field acidified []Yes X❑No ) COD N/A mgLL Nitrite :(NO2 as N) - _ N!A mg/L Ni'- Nickel _ - _ <10.0 ug/L Coliform: MF Fecal N/A /100mL Nitrate (NO3 as N) N/A_ mgLL Pb - Lead <5.0 ug/L Coliform; 'MF Total NLA /100mL Phosphorus: Total as P 5.400 mg/L Zn - Zinc NIA ug/L (Note: use MPN method for highly turbid samples) Orthophosphate NIA mg/L Ammonia Nitrogen mgLL. Dissolved Solids: Total 3250_ mg/L Al - Aluminum N/A _ , mg/L other (Specify Compounds and Concentration Units)' pH (when analyzed) 6.5 units Ba - Barium N/A ugLL Fluoride <0.3 mg/L TOC 5.2 mg/L Ca - Calcium N/A mg/L MIBK N/A ug/L Chloride - 114.0 mg/L Cd- Cadmium <1.0 ug/L Ag --Silver N/A ug/L Arsenic N/A_ ug/L Chromium: Total - X5.0 ug/L Se- Selenium <10.0 .41- ugLLGrease Greaseand Oils, NLA, mg/L Cu - Copper N/A mgLL Sodium 242600 ug/L Phenol N/A mg/L Fe - Iron N/A ug/L Organics: (GC, GC/MS, HPLC) Sulfate 16410 mg/L Hg - Mercury N/A ugLL (Specify test, method #. Attach lab report:). Specific Conductance N/A uMhos K- Potassium NLA mg%L Report attached? Yes X (1) No (2,) Total Ammonia N/A mg/L Mg - Magnesium N/A mg/L VOC BDL_ :. method# 62000 _ TKN as N NLA. mg/L Mn - Manganese N/A ug/L method# method# NOTE: Mark D. Johnson General Manager - - - 'I U P i e (of Authorized AA ent) Name and Title - Please type or print 2 e RA I t7JL t -'+!e IL ?. e7JtAN.;ge+ GW -59 Rev 4198 Signature of Permittee (or Authorized Agent) (Date) r • • ..:[3WvI51"N�1= LIANCE REP. O Facilty Name:, PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility_ Addres ss- 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Danny Winstead Telephone (252)322-8283 Well Locations/Site Name- #2 Cooling Pond, No. of Wells to be Sampled 11 IUCIILIIIVQUVI1IYu111UC1 klivil.l rcnruy:: nlvrz-.w For Groundwater Treatment 11 Depth: 43.50 ft. Well'Diamter: 2 inch systems Check one: eened Interval: 40.34 ft. to 42.34 ft. Influent (98) 3th to Water Level-. NIA ft. below measuring .point. Effluent (99) asuring Point is 3.23ft above land surface. .ILITERS of water pumpedibailed before sampling" NIA Id Analysis: pH' NIA, , Specific Conductance NIA _uMhos Temp. NIA oC Odor NONEAppearance: CLEAR .. . 617 m. _:tEeVte eEty i ALe[H,:Nc zzsas 117 Phony fatal 80� ssos #: WQ0001105 EXPIRATION DATE charge X UIC OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation- Infiltration Gallery Spray Field Remediation :. Rotary Distributor Land Application of Sludge .Water Source Heat Pump: Values should reflect dissolved an colloidal concentrations sample collected: sample analyzed: ratory Name.- F 11/21/2016 11/2112016' to 11121/2016 NELL WAS tY at time sampling, here. PARAMETERS: (Samples for metals were collected unfiltered Yes n/a. No and field acidified Yes n/a No ) COD _ N/A mg/L Nitrite (NO2 as N) NIA mg/L Ni - Nickel N/A ug/L Coliform: MF Fecal NIA /100mL Nitrate (NO3 as N) N/A mg/L. Pb - Lead N/A ug/L Coliform: MF Total N/A /100mL Phosphorus: Total as P N/A mg/L Zn - Zinc N/A uglL, (Note; use MPN method forhighly turbid samples) Dissolved Solids: 'Total 3 L.:nML Orthophosphate _ N/A mg/L Ammonia Nitrogen of Sp " C ou n x �ncentration Units) mg/L pH (when analyzed) I i 7 L! I e N/A mg/L TOC N/A ug/L Chloride N/A. mg/L Cd- Cad um, N/A __ ug/L Ag - Silver NIA ug/L Arsenic _ NIA. ug/L Chromium: Total N/A ug/L Se- Selenium N/A ug/L Grease and Oils N/A mg/L Cu - Copper _ N/A _ mg/L Sodium N/A ug/L Phenol N/A_ mg%L Fe - Iron -_ N/A ug/L Organics: (GC, GUMS, HPLC) Sulfate • N/A mg/L Hg - Mercury N/A_ ug/L (Specify test method #. Attach lab report.) Specific Conductance N/A uMhos K- Potassium N/A mg/L Report attached? Yes (1) No Total Ammonia N/A mg/L Mg - Magnesium - - N/A mg/L VOC method# TKN as N _ N/A mg/L Mn = Manganese N/A ug/L : method# method# ;NOTE: GW -59 Rev 4/98 Permitte (of Authorized Agent Name and Title -Please type or print y —" Signature of Permittee (or Authorized Agent) (Date) :....E :.:.:. DEFIt - FEFtIFtiR : t T &LVATIIRA Rir .:..P.. . ....... ...:.:.:.:.:.:.:.:.:.:.:.:.:. RT.MENt 0 . DR111lEE SOUR GR:: ..( ::Mf� t,`7t.:.:.:::::..........::::::.......::.:::::.:.:.:.:.:.:.::.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.::::::. • • _ ::::DIFFISIOI� OF.INA7Etd:RE50lJRCES-INFQRNfAT OVNDWA IQN:P.K�..-. F``SfAWUNIT `. • •• • COMP�I�kf�+ty:RSP'T.FCIRM..:.::..:.......:::.........::.::..................... iGZ:IVIAILSE#2)FiGEGENTEti::::E :.N. .. fi 6: :Ei EEP 9 9 6306 ::::::::::::::::::::::::t�AL6tGH Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division Permit Name (if different): Facility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort Contact Person: Danny Winstead Telephone: (252)322-8283 Well Locations/Site Name: #2 Cooling Pond No. of Wells to be Sampled I Identification Number (from Permit): MW2-4A For Groundwater Treatment I Depth: 17.50 ft. Well Diamter: 2 inch Systems check one: coned Interval: 14.96 ft. to 16.96 ft. Influent (98) 3th to Water Level: 5.26 ft. below measuring point. Effluent (99) asuring Point is 3.05 ft above land surface. .ILITERS of water pumped/bailed before sampling: 2600 Id Analysis: pH 4.7 , Specific Conductance 771 uMhos Temp. 20.4 oC, Odor NONE Appearance: CLEAR MIT M W00001105 EXPIRATION DATE: 06/30/19 -Discharge X UIC iES - E OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field Remediation : Rotary Distributor Land Application of Sludge Water Source Heat Pump Values should reflect dissolved and If WELL WAS colloidal concentrations DRY at time sample collected: 11/28/2016 of sampling, sample analyzed: 11/28/2016 to 1211612016 check ratory Name: PCS PHOSPHATE here: F fication No(s) 330 16 - 11-- ug/L PARAMETERS: (Samples for metals were collected unfiltered NX Yes E_1 No and field acidified ElYes XD No ) COD N/A mg/L Nitrite (NO2 as N) N/A mg/L Ni - Nickel 45 ug/L Coliform: MF Fecal N/A /100mL Nitrate (NO3 as N) N/A mg/L Pb - Lead <5.0 ug/L Coliform: MF Total N/A /100mL Phosphorus: Total as P 0.060 mg/L Zn -Zinc N/A ug/L (Note: Use MPN method for highly turbid samples) Orthophosphate N/A mg/L Ammonia Nitrogen mg/L Dissolved Solids: Total 592 mg/L Al - Aluminum N/A mg/L Other (Specify Compounds and Concentration Units) pH (when analyzed) 4.9 units Ba - Barium N/A ug/L Fluoride <0.3 mg/L TOC 2.8 mg/L Ca - Calcium N/A mg/L MIBK N/A ug/L Chloride 10.0 mg/L Cd- Cadmium <1.0 ug/L Ag - Silver N/A ug/L Arsenic N/A ug/L Chromium: Total <5.0 ug/L Se- Selenium <10.0 ug/L Grease and Oils N/A mg/L Cu - Copper N/A mg/L Sodium 21870 ug/L Phenol N/A mg/L Fe - Iron N/A ug/L Organics: (GC, GC/MS, HPLC) Sulfate 362.0 mg/L Hg - Mercury N/A ug/L (Specify test method #. Attach lab report.). Specific Conductance N/A uMhos K- Potassium N/A mg/L Report attached? Yes X (1) No -_ (2) Total Ammonia N/A mg/L Mg - Magnesium N/A mg/L VOC BDL method# 6200C TKN as N N/A mg/L Mn - Manganese N/A ug/L method# method# NOTE: GW -59 Rev 4/98 Mark D. Johnson, General Manager &pDittee (of Authorized Agent) Name and Title - Please type or print Signature of Permittee (or Authorized Agent) (Date) DEP G €UNDVA �LaLI'Y MC1ltd• vlsl N o w>•Ea RESOURCEs INFORMATIQN PROCaFSs +ICS liNlr GPLI1IE REPQRTCEtiYl and ..�nm�l> sEl�v�c eENrElx. I2AL Eft) I, ItfC 2x626 1si1 3�hQne (9 49) -acilty Name: PCS PHOSPHATE CO., INC. - Aurora Division 3ermit Name (if different): acilityAddresss 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort 'ontact Person: Danny. Winstead Telephone (252)322-8283 _ Well Locations/Site Name: #2 Cooling Pond. No. of Wells to be Sampled Depth 26.00 ft., Well Interval: 21.80 ft. to '23.80 ft: Groundwater Treatment teras Check One: Influent (98) pth to Water Level:. 5.59 ft. below measuring point. _- Effluent (! asuring Point is 3.33: ft above land surface. _ILITERS of water pumped/bailed before sampling 2700 ild Analysis: pH 4.9 ; Specific Conductance 802 _uMhos Temp. 19.4 oC, Odor NONE ,Appearance: CLEAR M. W00001106 EXPIRATION_ DATE harge X Vic OF PERMITTED OPERATION BEING MONITORED' _ Lagoon Remediation: Infiltration Gallery Spray Field Remediation: Rotary Distributor Land Application of Sludge Water Source Heat. Pump Values should reflect dissolved and If WELL WAS colloidal concentrations DRY at time sample collected: 111281201.6' of sampling, sample analyzed, 11/28/2016 to 12/16/2016 check ratory Name: PCS PHOSPHATE' here:. fication No(s) 330 10 Ni - Nickel PARAMETERS: (Samples for metals were collected unfiltered 0 Yes F-1 No and field acidified' E]Yes KNo CO'D. _ _ N/A mg/L Nitrite (NO2 as N) N/A mg/L Ni - Nickel X10:0 ug/L Coliform: MF Fecal N/A. /100mL Nitrate (NO3 as N) N/A mg/L Pb - Lead <5.0 ug/L Coliform: MF Total N/A, /100mL Phosphorus: Total as .P 0.112 mg/L Zn - Zinc N/A ug/L (Note: Use MPN method for highly turbid samples) Orthophosphate N/A mg/L Ammonia Nitrogen m.g/L Dissolved Solids-.. Total 616 mg/L Al - Aluminum N/A mg/L Other (Specify Compounds and Concentration Units) pH (when analyzed) 5.1 units Ba - Barium N/A • - ug/L Fluoride <0.3 _ mg/L TOC 2.1 mg/L Ca - Calcium _ _ N/A mg/L MIBK N/A ug/L_ Chloride _ _ 13.0 mg/L Cd- Cadmium <1.0 ug/L Ag - Silver NIA ug/L Arsenic N/A ug/L Chromium: Total <5.0 ug1L Se- Selenium <10.0' ug/L - Grease and Oils N/A mg/L Cu - Copper N/A mg/L Sodium 18500 ug/L Phenol N/A mg/L Fe - Iron N/A ug/L Organics: (GC, GUMS, HPLC) Sulfate 383.0 mg/L Hg - Mercury N/A ug/L (Specify test method #. Attach lab report.) Specific Conductance N/A uMhos K- Potassium _. NLA mg/L Report attached? Yes X (1) No {2) Total Ammonia, _ _ N/A mg/L Mg - Magnesium N/A mg/L VOC BDL method# 6200.0 TKN as N N/A mg/L Mn - Manganese N/A ug/L method# method# NOTE: GW -59 Rev 4198 Permittee (of Authorized Agent) Name and Title - Please'type or print 3.4 Signature of Permittee(or Authorized Agent) (Date] ": 3EPA€tTN1ENTflF E1 VIRQNIVIENT&-NK.T.0 . Alm tESOEIR %6. GROUNDWATER QPALITY MONITIQRih1 • DI1l151QN OF wATI;Ri2ESQt3RCES INI EiFtINATIflN PRflGESSINGt1NIT GQN[P);1�4NCE #�l~R R aRM .. 1fr$ iIAAIL S I�VIC� daji#t; . �eLEIGIi PIC 29626 1617 P#Qne (37SJ 807;6306 Facilty Name! PCS PHOSPHATE CO., INC. -_Aurora Division Permit Name (if different): Facility_ Addresss 1530 NC Hwy 306 South Aurora, NC 27806 County- Beaufort Contact Person; Danny _Winstead Telephone: (252)322-8283 Well Locations/Site Name: #2 Cooling Pond No. of Wells to be Sampled - 9 u IYG1161114QLIVIJ runwep�v�u rc�una/= �•••�-�� For Groundwater Treatment II Depth; 42.00 - ft. Well Diamter: ____2 inch systems Check one. ,eened Interval: 3.8.95 ft. to 40.95 ft. Influent(98) pth to Water Level:' 5.74 ft. below measuring point. Effluent (99) asuring Point is 2.92._ ft above, land surface. -ILITERS of water pumped/bailed before sampling: 2600 Id Analysis: pH 6.6 , Specific Conductance 1500 uMhos. Temp. 19x6 oC, Odor NONE Appearance: CLEAR - W00001105 EXPIRATION DATE- X UIC ,OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray. Field Remediation Rotary Distributor Land Application of Sludge Water Source Heat Pump Values should reflect dissolved and If WELL, WA: colloidal concentrations DRY at time sample collected 111281201.6 of sampling, sample analyzed: 11/28/2016 to 12/16/2016 check ratory Name: PCS PHOSPHATE - . here: fication No(s) 330 10 PARAMETERS: (Samples for metals were collected unfiltered 0 YesL1 No and field acidifieduYes uNo ) COD N/A mg/L Nitrite (NO2 as. N) N/A mg/L Ni - Nickel <10.0 ug/L Coliform,: MF Fecal N/A /100mL Nitrate (NO3 as N) NTA mg/L Pb,- Lead. -- <5:0 _ ug/L Coliform: MF Total N/A /100ml- Phosphorus: Total as:'P 0.422_ mg/L Zn - Zinc N/A_ ug/L (Note: Use MPN method for Highly turbid samples), Orthophosphate N/A. mg/L Ammonia. Nitrogen _ _ _ -_ mg/L Dissolved' Solids: Total 1120_ nig/L Al = Aluminum N/A mg/L Other (Specify Compounds and Concentration Units). pH'. (when analyzed) 6.8 units Ba - Barium _ N/A ug/L Fluoride <-0.3 mg/L TOC 3.8 mg/L Ca - Calcium - N/A mg/L MIRK N/A ug/L Chloride 18.0 mg/L Cd- Cadmium 0:0- ug /L Ag - Silver N/A ug/L Arsenic N/A ug/L Chromium: Total <5.0 ug/L Se- Selenium <%o ug/L. Grease and Oils N/A mg/L Cu - Copper NTA mg[L Sodium 45360 ug/L Phenol N/A mg/L. Fe - Iron _ N/A ug/L Organics: (GC, GC/MS, HPLC;) Sulfate _ - 443.0 mg/L Hg- Mercury N/A ug/L (Specify test method #. Attach lab report.) Specific Conductance N/A uMhos K- Potassium __ N/A mg/L Report,attached? Yes X (1) No (2) Total Ammonia _ N/A mg/L Mg - Magnesium N/A mg/L VOC HIT method# 6200C TKN as.N N/A mg/L Mn - Manganese N/A ug/L method# method#' NOTE: GW -59 Rev 4198 Mark D Johnson General Manager_ - Permittee (of Authorized Agent) Name and Title - Please type or print _1354— 2, ,. _ F2 iAAXI< To 29 b Signature of Permittee (or Authorized Agent) (Date) .... . [iEPARTMENT OP F.f+IViROt�llEENFi' StJA7U�lAE RE504lRCES €}U1VDilV 1T Fi i L aLITY :M ?Allltiyl*II C�' • �lvislpN E) -WATER RE50L1RCE�S INFOI�NF/IFIQKi Pic �s sN l3Nlr COIMPLIkIe(EE REPT I.F.#FtM _ • •s�7 tulnt :sEveevstvt. ......; C z s23�1#i 17 Phor (919} 8a� 6 3Q6 acilty Name: PCS PHOSPHATE CO., INC. - Aurora Division 'ermit Name (if different) acility Addresss: 1530 NC Hwy 306 South Aurora, NC 2780.6 County: Beaufort ;ontact'Person Danny Winstead - Telephone: (252)322=8283 Well Locations/Site Name: #2 Cooling Pond No. of Wells to be Sampled. - _For Groundwater Trea_ tment II Depth: 43..80 ft. Well Diamte"r: 2 inch systems check one: -eened Intervals 39.50 ft. to 41.50 ft. Influent (98) pth to. Water Level: 18.76ft: below measuring point. Effluent (99) asuring Point is 2.50 ft above land surface. -ILITERS, of water pumped/bailed before sampling: 2400 Id Analysis: pH 7.0 Specific Conductance 2430 uMhos Temp., 18.0 oC, Odor NONE Appearance: CLEAR WQ_ 0001105 EXPIRATION DATE: rge X UIC OF PERMITTED OPERATION BEING MONITORED _ Lagoon Remediation: Infiltration Gallery Spray Field Remediation Rotary Distributor Land Application of Sludge Water Source Heat Pump Values should reflect dissolved and If WELL WAS colloidal concentrations DRY at time sample collected: 11/28/2016 of sampling, sample analyzed: 11/28/2016 to 121161201.6 check gyratory Name: PCS PHOSPHATE -__ _ here' fication No(s) 330 10 PARAMETERS: (Samples for metals were collected unfiltered NX YesE_1 No and field acidified 0Yes X❑No ) COD N/A mg/L Nitrite (NO2. as N) N/A mg/L Ni - Nickel <10.0 ug/L Coliform: MF Fecal' N/A . /100mL Nitrate (NO3 as N) N/A mg/L Pb - Lead - _ _ _ <5.0 ug/L Coliform: MF Total N/A /100mL Phosphorus: Total as P 0:440 mg/L Zn - Zinc N/A ug/L (Note: use MPN method for highly turbid samples) Orthophosphate _- _ N/A, mg/L Ammonia Nitrogen - mg/L Dissolved Solids: Total _ 1640 mg/L Al - Aluminum N/A mg/L ather(Specify Compounds and Concentration units) pH (when analyzed)_ 6.7_ units Ba - Barium N/A ug/L Fluoride - <03 mg/L TOC 2.3 ' mg/L Ca - Calcium N/A _ mg/L MIBK - N/A. ug/L Chloride _ 300.0 mg/L Cd- Cadmium <1.0 _ ug/L. Ag - Silver - _ _ N/A ug/L Arsenic ___ N/A ug/L Chromium: Total _ <5.0 ug/L Se- Selenium <10.0 ug/L Grease and Oils _. __ _ N/A mg/L Cu - Copper N/A _ mg/L Sodium _ _ _ 116100 ug/L Phenol N/A mg/L 5e- Iron _ N/A ug/L Organics: (GC, GC/MS, HPLC) Sulfate 432:0 mg/L Hg - Mercury N/A ug/L (Specify test method #. Attach lab report.) Specific Conductance p N/A. uMhos - K- Potassium N/A m /L Repo attached? Yes X (1) No P �metho (Z) Ammonia _ g g- Magnesium g VOC BDL 62000 TKNTotaI s N. N/A m /L 9 Mn - Manganese 9 N/A u /L g method'# # method# NOTE: Permittee of Authorized Agent) Name and Ttle - Please type or prrht ° cud � ��PL- �� ale �, �u$►.�s�� �) GW -59 Rev 4/98 =acilty Name: PCS PHOSPHATE CO., INC. - Aurora Division 3ermit Name (if different): °acility Addresss: 1530 NC Hwy 306 South Aurora, NC 27806 County: Beaufort :ontact Person: Danny Winstead Telephone: (252).322-8283 Well Locations/Site Name: #2 Cooling Pond No. of Wells to be Sampled 9 fell Identification Number (from Permit): MW2-5C For Groundwater Treatment fell Depth: 29.00 ft. Well Diamter: 2 inch systems check one: creened Interval: 25.93 ft. to 27.93 ft. Influent (98) epth to Water Level: 19.19 ft. below measuring point. Effluent (99) leasuring Point is 3.08 ft above land surface. IILILITERS of water pumped/bailed before sampling: 2500 ield Analysis: pH 6.8 , Specific Conductance 1770 uMhos Temp. 17.8 oC, Odor NONE Appearance: CLEAR `OF1A1f1iEi i2E5111CS-INFQRNFQfIQISEPRC lL*SFRVICE CE(V rEf% EEE f �;Nt27626fIB1Z` PfiQti?r:(9�918Qy���i)6�`' #: W00001105 EXPIRATION DATE: :harge X UIC OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field Remediation: Rotary Distributor Land Application of Sludge Water Source Heat Pump Values should reflect dissolved and lIf WELL WAS colloidal concentrations DRY at time Date sample collected: 11/28/2016 of sampling, Date sample analyzed: 11/28/2016 to 12/16/2016 check Name: PCS PHOSPHATE n No(s) 330 10 PARAMETERS: (Samples for metals were collected unfiltered ❑X Yes E--1 No and field acidified []Yes LINO) COD N/A mg/L Nitrite (NO2 as N) N/A mg/L Ni - Nickel <10.0 ug/L Coliform: MF Fecal N/A /100ml- Nitrate (NO3 as N) N/A mg/L Pb - Lead 7 ug/L Coliform: MF Total N/A /100mL Phosphorus: Total as P 2.330 mg/L Zn - Zinc N/A ug/L (Note: Use MPN method for highly_ turbid samples) Orthophosphate N/A mg/L Ammonia Nitrogen mg/L Dissolved Solids: Total 1140 mg/L Al - Aluminum N/A mg/L Other (Specify Compounds and Concentration Units) pH (when analyzed) 6.3 units Ba - Barium N/A ug/L Fluoride 1.55 mg/L TOC 3.9 mg/L Ca - Calcium N/A mg/L MIBK N/A ug/L Chloride 139.0 mg/L Cd- Cadmium <1.0 ug/L Ag - Silver N/A ug/L Arsenic N/A ug/L Chromium: Total X5.0 ug/L Se- Selenium <10.0 ug/L Grease and Oils N/A mg/L Cu - Copper N/A mg/L Sodium 90085 ug/L Phenol N/A mg/L Fe - Iron N/A ug/L Organics: (GC, GC/MS, HPLC) Sulfate 407.0 mg/L Hg - Mercury N/A ug/L (Specify test method #. Attach lab report.) Specific Conductance N/A uMhos K- Potassium N/A mg/L Report attached? Yes X (1) No (2) Total Ammonia N/A mg/L Mg - Magnesium N/A mg/L VOC BDL method# 6200C TKN as N N/A mg/L Mn - Manganese N/A ug/L method# method# NOTE: GW -59 Rev 4/98 Mark D. Johnson, General Manager Peopiltee (of Authorized Agent) Name and Title - Please type or print �a� l" ?/t :P, T�bw ✓ 28 ��er'r, •z f i' Signature of Permittee (or Authorized Agent) (Date) GW -59A COMPLIANCE REPORT FORM Permit (Submit one each monitoring period with GW -59 forms.) WQ 0001105 1 Enter date monitoring results were due. (12-31-2016) -willthis monitoring report -59 and G 9 be YES NO submitted after the established due date? X 2 Was any required information missing on the GW -59 report forms? YES NO X IF e answer to question 1 or 2 is ism the space provided e ow the well identification num er s an exp ain the problems encountered in obtaining the required information. No access to wells MW1-4A, MW1-4B, MW1-5A, MW1-5B, MW2-3A and MW2-36. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, YES NO X missing identification plate, area overgrown, etc.)? If the answer is "Yes" contact the Regional Office for guidance. 4 Are any monitored constituents equal to or above the established standards? YES X NO it e answer to question 4 is ,sip to section d. if the answer to question 4 is "YES", list the affected wells individually with constituent(s) and concentrations(s) exceeding standards in the space provided below. See attached spreadsheet for details. 5 ort the constituents identified in question 4 above, have standards been exceeded previous fort the same YES NO constituent(s) in the same well(s) X If the answer to question 5 is "NO , skip to section 8. if the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). See attached spreadsheet. 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES X NO It e answer is YES , a groundwater quality problem may be occurring. IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. Contacted the WaRO on 12/28/2016 7 Is the permittee implementing previously approved actions required by the Division involving this groundwater quality YES NO problem? X If the answer to question 7 is "YES" describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation fines and/or penalties The Cooling Pond Remedial Action System Design Report was submitted to NCDENR on September 27, 1990 and approved by NCDENR January 7, 1991. The system was installed by PCS Phosphate between July 8, 1991 and April 9, 1992. In 2008 the cut-off wall was extended on the south perimeter of CPA. This action was taken due to the location of the active mine pit. 8 e person comp etmg t is po ion of the monitoring report sho uld sign below and sub mit this form with GW -59 forms for required wells to be address provided at the top of the current GW -59 form. } Ftarat�jr kribvii)edge:#Ijat:ttie atibYB:iitifoFttiiatibri:W4s:0-i4tuat0it.1nd tai ii�f ttii�i ti9 $4 tk�i#t p......... . iCorKipliaticu::124port:0wN .,$ : s:4rue:aril:coria;plete:to:ths:best:tif:iri• k...... t e : .............. ........................................ Signature of Permittee (or Authorized Agent) Date Cooling Pond Number One Wells Well Location (Feet from CP) 40 Well Location (Feet from CP) 40 Well Location (Feet from CP) 40 MW1-3A Date Dissolved Solids pH Sulfate Fluoride Nickel (500.0) (6.5-8.5) (250.0) (2.0) (100) 25 -Nov -14 2250.0 5.6 1414.0 5.6 28 -May -15 2030.0 5.5 1383.0 4.8 28 -Nov -15 2370.0 923.0 4.3 26 -May -16 2200.0 5.3 1320.0 4.7 21 -Nov -16 2110.0 5.5 1206.0 4.5 MW1-313 Date Dissolved Solids pH Sulfate Fluoride (500.0) (6.5-8.5) (250.0) (2.0) 25 -Nov -14 4030.0 6.2 1755.0 28 -May -15 4350.0 6.4 1335.0 28 -May -15 3350.0 1020.0 26 -May -16 3290.0 6.2 1770.0 21 -Nov -16 3060.0 6.4 1723.0 MW1-4A Date Dissolved Solids pH Sulfate Fluoride Nickel (500.0) (6.5-8.5) (250.0) (2.0) (100) 30 -Nov -14 No Access No Access No Access No Access 28 -May -15 No Access No Access No Access No Access 28 -Nov -15 No Access No Access No Access No Access 26 -May -16 No Access No Access No Access No Access 21 -Nov -16 No Access No Access No Access No Access Well Location (Feet from CP) 40 Well Location (Feet from CP) 40 Well Location (Feet from CP) 40 Date 30 -Nov -14 28 -May -15 28 -Nov -15 26 -May -16 21 -Nov -16 Date 30 -Nov -14 29 -May -15 28 -Nov -15 26 -May -16 21 -Nov -16 Date 30 -Nov -14 29 -May -15 28 -Nov -15 26 -May -16 21 -Nov -16 Dissolved Solids (500.0) No Access No Access No Access No Access No Access Dissolved Solids (500.0) 4190.0 4380.0 No Access No Access No Access Dissolved Solids (500.0) 4510.0 3640.0 No Access No Access No Access Cooling Pond Number One Wells Cadmium (2.0) Chromium (10.0) 11 Cadmium Chromium (2.0) (10.0) Well Location (Feet from CP) 40 Well Location (Feet from CP) 50 Well Location (Feet from CP) 50 MW1-5A MW1-4B pH Sulfate pH Sulfate Fluoride (6.5-8.5) (250.0) (2.0) No Access No Access No Access No Access No Access No Access No Access No Access No Access No Access No Access No Access No Access No Access No Access Cadmium (2.0) Chromium (10.0) 11 Cadmium Chromium (2.0) (10.0) Well Location (Feet from CP) 40 Well Location (Feet from CP) 50 Well Location (Feet from CP) 50 MW1-5A pH Sulfate Fluoride (6.5-8.5) (250.0) (2.0) 3.8 1515.0 41.4 4.5 1479.0 47.2 No Access No Access No Access No Access No Access No Access No Access No Access No Access MW1-5B pH Sulfate Fluoride (6.5-8.5) (250.0) (2.0) 6.4 1664.0 5.9 1748.0 No Access No Access No Access No Access No Access No Access No Access No Access No Access Cadmium (2.0) Chromium (10.0) 11 Cadmium Chromium (2.0) (10.0) Well Location (Feet from CP) 40 Well Location (Feet from CP) 50 Well Location (Feet from CP) 50 Cooling Pond Number One Wells Well Location (Feet from CP) 2120 Well Location (Feet from CP) 2120 MW1-6AR Date Dissolved Solids pH Sulfate Fluoride (500.0) (6.5-8.5) (250.0) (2.0) 24 -Nov -14 1030.0 6.3 356.0 28 -May -15 1050.0 6.4 29 -Nov -15 1200.0 6.3 542.0 25 -May -16 1130.0 6.3 592.0 21 -Nov -16 1170.0 6.1 460.0 MW1-6BR Date Dissolved Solids pH Sulfate Fluoride (500.0) (6.5-8.5) (250.0) (2.0) 24 -Nov -14 2800.0 1314.0 28 -May -15 2900.0 1635.0 29 -Nov -15 2770.0 6.4 909.0 25 -May -16 2660.0 1500.0 21 -Nov -16 2640.0 6.4 1461.0 Well Location (Feet from CP) 2120 Well Location (Feet from CP) 2120 Date 24 -Nov -14 28 -May -15 28 -Nov -15 25 -May -16 21 -Nov -16 Date 24 -Nov -14 5 -May -15 28 -Nov -15 25 -May -16 21 -Nov -16 Date 25 -Nov -14 28 -May -15 28 -Nov -15 25 -May -16 21 -Nov -16 Dissolved Solids (500.0) 2810.0 2940.0 2300.0 1280.0 861.0 Dissolved Solids (500.0) 1080.0 1090.0 1180.0 1060.0 1450.0 Dissolved Solids (500.0) 1930.0 1880.0 1870.0 1840.0 1950.0 MW1-8A pH (6.5-8.5) 4.5 4.5 4.4 4.5 4.6 374.0 Sulfate (250.0) 1886.0 993.0 894.0 1100.0 1207.0 Fluoride (2.0) 18.3 17.7 20.6 22.7 26.0 Cadmium Chromium (2.0) (10.0) Well Location (Feet from CP) Well Location (Feet from CP) 250 Well Location (Feet from CP) 250 Cooling Pond Number One Wells MW1-7A pH Sulfate Fluoride Nickel (6.5-8.5) (250.0) (2.0) (100) 5.7 1503.0 5.6 261 6.0 1527.0 6.9 5.7 978.0 6.7 105 5.4 838.0 20.8 5.3 435.0 11.4 MW1-7B pH Sulfate Fluoride (6.5-8.5) (250.0) (2.0) MW1-8A pH (6.5-8.5) 4.5 4.5 4.4 4.5 4.6 374.0 Sulfate (250.0) 1886.0 993.0 894.0 1100.0 1207.0 Fluoride (2.0) 18.3 17.7 20.6 22.7 26.0 Cadmium Chromium (2.0) (10.0) Well Location (Feet from CP) Well Location (Feet from CP) 250 Well Location (Feet from CP) 250 Cooling Pond Number One Wells MW1-8B Date Dissolved Solids pH Sulfate Fluoride Well Location (500.0) (6.5-8.5) (250.0) (2.0) (Feet from CP) 25 -Nov -14 2990.0 2446.0 250 5 -May -15 3720.0 2209.0 28 -Nov -15 4620.0 1899.0 25 -May -16 5400.0 6.4 2680.0 21 -Nov -16 5390.0 6.2 2893.0 Cooling Pond Number Two Wells MW2-1AR Date Dissolved Solids pH Sulfate Fluoride Well Location (500.0) (6.5-8.5) (250.0) (2.0) (Feet from CP) 18 -Nov -14 5.0 4.4 30 6 -May -15 502.0 5.1 4.9 27 -Nov -15 5.1 4.4 24 -May -16 634.0 5.1 791.0 4.5 21 -Nov -16 683.0 5.2 296.0 4.2 Well Location (Feet from CP) 30 Well Location (Feet from CP) 40 Well Location (Feet from CP) 40 Cooling Pond Number Two Wells MW2-1 BR Date Dissolved Solids pH Sulfate Fluoride Cadmium Chromium (500.0) (6.5-8.5) (250.0) (2.0) (2.0) (10.0) 18 -Nov -14 2860.0 6.2 2301.0 6 -May -15 3340.0 6.1 1029.0 27 -Nov -15 3290.0 6.3 1401.0 24 -May -16 3440.0 6.4 1660.0 21 -Nov -16 3250.0 1643.0 MW2-3A Date Dissolved Solids pH Sulfate Fluoride (500.0) (6.5-8.5) (250.0) (2.0) 17 -Nov -14 Well Dry Well Dry Well Dry Well Dry 6 -May -15 Well Dry Well Dry Well Dry Well Dry 27 -Nov -15 No Access No Access No Access No Access 24 -May -16 No Access No Access No Access No Access 21 -Nov -16 No Access No Access No Access No Access MW2-3B Date Dissolved Solids pH Sulfate Fluoride (500.0) (6.5-8.5) (250.0) (2.0) 18 -Nov -14 6.3 6 -May -15 27 -Nov -15 No Access No Access No Access No Access 24 -May -16 No Access No Access No Access No Access 21 -Nov -16 No Access No Access No Access No Access Well Location (Feet from CP) 30 Well Location (Feet from CP) 40 Well Location (Feet from CP) 40 Date 18 -Nov -14 26 -May -15 27 -Nov -15 24 -May -16 21 -Nov -16 Date 18 -Nov -14 26 -May -15 27 -Nov -15 24 -May -16 21 -Nov -16 Date 18 -Nov -14 26 -May -15 27 -Nov -15 24 -May -16 21 -Nov -16 Dissolved Solids (500.0) 570.0 652.0 580.0 649.0 592.0 Dissolved Solids (500.0) 648.0 688.0 611.0 655.0 616.0 Dissolved Solids (500.0) 1060.0 1120.0 1050.0 908.0 1120.0 Cooling Pond Number Two Wells Cadmium Chromium (2.0) (10.0) Well Location (Feet from CP) 70 Well Location (Feet from CP) 70 Well Location (Feet from CP) 70 r MW2-4A pH Sulfate Fluoride (6.5-8.5) (250.0) (2.0) 4.6 342.0 4.3 4.8 5.2 336.0 4.8 387.0 4.7 362.0 Cadmium Chromium (2.0) (10.0) Well Location (Feet from CP) 70 Well Location (Feet from CP) 70 Well Location (Feet from CP) 70 r MW2-4B pH Sulfate Fluoride (6.5-8.5) (250.0) (2.0) 4.8 321.0 3.7 344.0 4.8 327.0 4.9 430.0 4.9 383.0 MW2-4C pH Sulfate Fluoride (6.5-8.5) (250.0) (2.0) 389.0 336.0 360.0 6.7 441.0 443.0 Cadmium Chromium (2.0) (10.0) Well Location (Feet from CP) 70 Well Location (Feet from CP) 70 Well Location (Feet from CP) 70 r Date Dissolved Solids pH (500.0) (6.5-8.5) 18 -Nov -14 1650.0 6.5 6 -May -15 1690.0 6.4 27 -Nov -15 1700.0 6.1 24 -May -16 1860.0 21 -Nov -16 1640.0 Date Dissolved Solids pH (500.0) (6.5-8.5) 18 -Nov -14 Well Dry Well Dry 6 -May -15 Well Dry Well Dry 27 -Nov -15 1260.0 6.1 24 -May -16 1190.0 21 -Nov -16 1140.0 Cooling Pond Number Two Wells MW2-513 Sulfate Fluoride Chloride (250.0) (2.0) (250.0) 327.0 387.0 534.0 432.0 MW2-5C Sulfate (250.0) Well Dry Well Dry 483.0 456.0 407.0 Fluoride (2.0) Well Dry Well Dry 2.1 273.0 302.0 284.0 284.0 300.0 Well Location (Feet from CP) 560 Well Location (Feet from CP) 560 1 PCS PHOSPHATE CO Aurora Division PHOSPHATE OPERATIONS WELL MEASUREMENTS TOC TOC TOC TOC Elevation Stc Wtr Wtr Lvl Elevation Stc Wtr Wtr Lvl .-W.ell-0-_.._._MSL- ..__-.Level ' ___-Rel_to-MSL--Well._ID __ _.___MSL _... __.__Level __ Rel to MSL ............ ::::::::::::::::::....::::::::::::::::::::: PZ1 - 1A 22.51 (p,s PZ2 - 1A 22.57 8 Q 1 B 22.75 // 1 B 22.46 is 22.58 16- Z/9 is 22.43ez PZ2 - 2A 21.11 F5-21- 2A 21.89 �. / 2B 21.85 _ 2B 21.12 2S 21.92 - 2S 21.09 ..................................................... ...............:.:.............................................. ... .. PZ2 - 3A 21.70 , PZ1 - 3 17.42 * 3B 21.72 PZ1 - 4 16.00 * 3S 21.81 PZ2-4A 22.05 Q, PZ1 - 5 15.61 46 21.95 PZ1-9A-I 21.89 9 /15' 4S 21.95 9491 21.99 �W13-1 9S -I 22.06 < �� :: PZ2 -7A 21.82 '° ... . PZ2-8A.... 21.92...x` PZ1-9A-0 22.52::: , 1�5s �;!9 913-0 22.49 .....l ............. :.......:::.: MW2 2A 1. 289 �• MW1-1A.... 18.26::::::::: MW2-2B 22.06 �. MW1- 1B 18.26 MW1 2A 15.84 5 MW1-2B 15.98 CP # 2 := Plezoierx:::::: Piezometers could not be located. 19+50 PZA 50.36 - -- PZ -B- 33.-24 - - :.:.:.:.:.: --------*--------- - - ------------- ------ _ __._ _..-._.._ ... 27+50 PZA 52.15 PZB 34.19 * ::::: Tech: Dater9' 40+00 PZA 53.30.:::::. *` --- --PZB_-3589 F -------------*--------- - - ---------------- -------- _ __-------- - dAforms\piezometer Measurements.As I EmkomM Flo hmpudid Dr.�nk:Lag�Water IAi�3e7,7i1�$ P.O. BOX 7085, 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27835.7085 y _ _ � FAX (252) 756-0633 CLIENT: PCS PHOSPHATE CO., INC. CLIENT ID: 1603 MR. BRAD LEE 1530 NC HWY. 306 SOUTH ANALYST: MAO AURORA, NC 27806 DATE COLLECTED: 11/21/16 Page: 1 DATE ANALYZED: 12/05/16 DATE REPORTED: 12/16/16 REVIEWED BY: ��/ v VOLATILE ORGANICS STD. METHODS 6200C (97) PARAMETERS, ug/l MW1-3A MW1-3B NMI -7A MW1-7B MW1-8A 1. Benzene <0.50 <0.50 <0.50 <0.50 <0.50 2. Bromobenzene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 3. Bromochloromethane <0.50 <0.50 <0.50 <0.50 <0.50 4. Bromodichloromethane <0.50 <0.50 <0.50 <0.50 <0.50 5. Bromoform <0.50 < 0.50 < 0.50 < 0.50 < 0.50 6. Bromomethane < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 7. N-Butylbenzene <0.50 < 0.50 < 0.50 <0.50 < 0.50 8. Sec-Butylbenzene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 9. Tert-Butylbenzene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 10. Carbon Tetrachloride < 0.50 < 0.50 < 0.50 < 0.50 <0.50 11. Chlorobenzene <0.50 <0.50 <0.50 <0.50 <0.50 12. Chloroethane <0.50 <0.50 <0.50 <0.50 <0.50 13. Chloroform <0.50 <0.50 <0.50 <0.50 <0.50 14. Chloromethane <0.50 <0.50 <0.50 <0.50 <0.50 15. 2-Chlorotoluene <0.50 <0.50 <0.50 <0.50 <0.50 16. 4-Chlorotoluene <0.50 <0.50 <0.50 <0.50 <0.50 17. Dibromochloromethane < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 18. 1,2-Dibromo-3-Chloropropane <0.50 <0.50 <0.50 <0.50 <0.50 19. 1,2-Dibromoethane < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 20. Dibromomethane <0.50 <0.50 <0.50 <0.50 <0.50 21. 1,2 -Dichlorobenzene <0.50 <0.50 <0.50 <0.50 <0.50 22. 1,3 -Dichlorobenzene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 23. 1,4 -Dichlorobenzene <0.50 <0.50 <0.50 <0.50 <0.50 24. Dichlorodifluoromethane <0.50 <0.50 <0.50 <0.50 <0.50 25. 1,1-Dichloroethane <0.50 <0.50 <0.50 <0.50 <0.50 26. 1,2-Dichloroethane <0.50 <0.50 <0.50 <0.50 <0.50 27. 1,1-Dichloroethene <0.50 <0.50 <0.50 <0.50 <0.50 28. Cis-1,2-Dichloroethene <0.50 <0.50 <0.50 <0.50 <0.50 29. trans-1,2-Dichloroethene <0.50 <0.50 <0.50 <0.50 <0.50 30. 1,2-Dichloropropane < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 31. 1,3-Dichloropropane <0.50 <0.50 <0.50 <0.50 <0.50 32. 2,2-Dichloropropane <0.50 <0.50 <0.50 <0.50 <0.50 33. 1,1-Dichloropropene <0.50 <0.50 <0.50 <0.50 <0.50 34. Cis-1,3-Dichloropropene <0.50 <0.50 <0.50 <0.50 <0.50 35. trans-1,3-Dichloropropene <0.50 <0.50 <0.50 <0.50 <0.50 36. Ethylbenzene <0.50 < 0.50 < 0.50 < 0.50 <0.50 37. Hexachlorobutadiene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 38. Isopropylbenzene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 39. 4-Isopropyltoluene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 40. Methylene Chloride <0.50 <0.50 <0.50 <0.50 <0.50 41. Naphthalene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 42. Propylbenzene <0.50 <0.50 <0.50 <0.50 <0.50 43. Styrene <0.50 <0.50 < 0.50 < 0.50 < 0.50 44. 1,1,1,2 -Tetrachloroethane < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 45. 1,1,2,2 -Tetrachloroethane <0.50 <0.50 <0.50 <0.50 <0.50 46. Tetrachloroethene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 47. Toluene <0.50 <0.50 <0.50 <0.50 <0.50 48. 1,2,3-Trichlorobenzene <0.50 <0.50 <0.50 <0.50 <0.50 Emikmu(M P.O. BOX 7085, 114 OAKMONT DRIVE GREENVILLE, N.C. 27835-7085_ CLIENT: PCS PHOSPHATE CO., INC. MR. BRAD LEE 1530 NC HWY. 306 SOUTH AURORA, NC 27806 REVIEWED BY: VOLATILE ORGANICS STD. METHODS 6200C (97) PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 1603 ANALYST: MAO DATE COLLECTED: 11/21/16 Page: 2 DATE ANALYZED: 12/05/16 DATE REPORTED: 12/16/16 PARAMETERS, ug/l MW1-3A MW1-313 NMI -7A MW1-713 MW1-8A 49. 1,2,4-Trichlorobenzene <0.50 <0.50 <0.50 <0.50 <0.50 50. 1,1,1 -Trichloroethane <0.50 <0.50 <0.50 <0.50 <0.50 51. 1,1,2 -Trichloroethane <0.50 <0.50 <0.50 <0.50 <0.50 52. Trichloroethene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 53. Trichlorofluoromethane <0.50 <0.50 <0.50 <0.50 <0.50 54. 1,2,3-Trichloropropane <0.50 <0.50 <0.50 <0.50 <0.50 55. 1,2,4-Trimethylbenzene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 56. 1,3,5-Trimethylbenzene <0.50 <0.50 <0.50 <0.50 <0.50 57. Vinyl Chloride <0.50 <0.50 <0.50 <0.50 <0.50 58. Total Xylenes < 1.00 < 1.00 < 1.00 < 1.00 < 1.00 59. Methyl Tert Butyl Ether < 1.00 < 1.00 < 1.00 < 1.00 < 1.00 P.O. BOX 7085, 114 OAKMONT GREENVILLE, N.C. 27835-7085 CLIENT: PCS PHOSPHATE CO., INC. MR. BRAD LEE 1530 NC HWY. 306 SOUTH AURORA, NC 27806 � J � a REVIEWED BY: ,C ✓ " "- a VOLATILE ORGANICS STD. METHODS 6200C (97) PHONE (252) 756-6208 FAX 252 756-0633 CLIENT ID: 1603 ANALYST: MAO DATE COLLECTED: 11/21/16 DATE ANALYZED: 12/05/16 DATE REPORTED: 12/16/16 Page: 3 PARAMETERS, ug/l MW1-8B 1. Benzene <0.50 2. Bromobenzene <0.50 3. Bromochloromethane < 0.50 4. Bromodichloromethane < 0.50 5. Bromoform < 0.50 6. Bromomethane <0.50 7. N-Butylbenzene < 0.50 S. Sec-Butylbenzene < 0.50 9. Tert-Butylbenzene < 0.50 10. Carbon Tetrachloride <0.50 11. Chlorobenzene <0.50 12. Chloroethane <0.50 13. Chloroform <0.50 14. Chloromethane < 0.50 15. 2-Chlorotoluene < 0.50 16. 4-Chlorotoluene < 0.50 17. Dibromochloromethane <0.50 18. 1,2-Dibromo-3-Chloropropane < 0.50 19. 1,2-Dibromoethane <0.50 20. Dibromomethane < 0.50 21. 1,2 -Dichlorobenzene < 0.50 22. 1,3 -Dichlorobenzene < 0.50 23. 1,4 -Dichlorobenzene < 0.50 24. Dichlorodifluoromethane <0.50 25. 1,1-Dichloroethane < 0.50 26. 1,2-Dichloroethane < 0.50 27. 1,1-Dichloroethene < 0.50 28. Cis-1,2-Dichloroethene <0.50 29. trans-1,2-Dichloroethene < 0.50 30. 1,2-Dichloropropane < 0.50 31. 1,3-Dichloropropane < 0.50 32. 2,2-Dichloropropane < 0.50 33. 1,1-Dichloropropene < 0.50 34. Cis-1,3-Dichloropropene <0.50 35. trans-1,3-Dichloropropene <0.50 36. Ethylbenzene < 0.50 37. Hexachlorobutadiene < 0.50 38. Isopropylbenzene < 0.50 39. 4-Isopropyltoluene < 0.50 40. Methylene Chloride <0.50 41. Naphthalene <0.50 42. Propylbenzene < 0.50 43. Styrene < 0.50 44. 1,1,1,2 -Tetrachloroethane < 0.50 45. 1,1,2,2 -Tetrachloroethane < 0.50 46. Tetrachloroethene < 0.50 47. Toluene <0.50 48. 1,2,3-Trichlorobenzene < 0.50 Page: 3 �in xinnfp�nlrmnnl(olfnl 1� �rh P(—n) @Tmq@d CLIENT: PCS PHOSPHATE CO., INC. MR. BRAD LEE 1530 NC HWY. 306 SOUTH AURORA, NC 27806 J REVIEWED BY: AA VOLATILE ORGANICS STD. METHODS 6200C (97) CLIENT ID: 1603 ANALYST: MAO DATE COLLECTED: 11/21/16 DATE ANALYZED: 12/05/16 DATE REPORTED: 12/16/16 Page: 4 PARAMETERS, ug/l MW1-8B 49. 1,2,4-Trichlorobenzene < 0.50 50. 1,1,1 -Trichloroethane < 0.50 51. 1,1,2 -Trichloroethane < 0.50 52. Trichloroethene < 0.50 53. Trichlorofluoromethane < 0.50 54. 1,2,3-Trichloropropane < 0.50 55. 1,2,4-Trimethylbenzene < 0.50 56. 1,3,5-Trimethylbenzene < 0.50 57. Vinyl Chloride <0.50 58. Total Xylenes < 1.00 59. Methyl Tert Butyl Ether < 1.00 Page: 4 9wommu(110 Flo hw P.O. BOX 7085, 114 GREENVILLE, N.C. Woo CLIENT: PCS PHOSPHATE CO., INC. MR. BRAD LEE 1530 NC HWY. 306 SOUTH AURORA, NC 27806 REVIEWED BY: VOLATILE ORGANICS STD. METHODS 6200C (97) CLIENT ID: 1603 ANALYST: MAO DATE COLLECTED: 11/22/16 Page: 1 DATE ANALYZED: 12/05/16 DATE REPORTED: 12/16/16 PARAMETERS, ug/l NMI -6A MW1-6B 1. Benzene < 0.50 < 0.50 2. Bromobenzene < 0.50 < 0.50 3. Bromochloromethane <0.50 <0.50 4. Bromodichloromethane <0.50 <0.50 5. Bromoform <0.50 <0.50 6. Bromomethane <0.50 <0.50 7. N-Butylbenzene <0.50 <0.50 8. Sec-Butylbenzene < 0.50 < 0.50 9. Tert-Butylbenzene <0.50 <0.50 10. Carbon Tetrachloride <0.50 <0.50 11. Chlorobenzene <0.50 <0.50 12. Chloroethane <0.50 <0.50 13. Chloroform <0.50 <0.50 14. Chloromethane <0.50 <0.50 15. 2-Chlorotoluene <0.50 <0.50 16. 4-Chlorotoluene < 0.50 < 0.50 17. Dibromochloromethane <0.50 <0.50 18. 1,2-Dibromo-3-Chloropropane <0.50 <0.50 19. 1,2-Dibromoethane <0.50 <0.50 20. Dibromomethane <0.50 <0.50 21. 1,2 -Dichlorobenzene <0.50 < 0.50 22. 1,3 -Dichlorobenzene <0.50 <0.50 23. 1,4 -Dichlorobenzene <0.50 <0.50 24. Dichlorodifluoromethane <0.50 <0.50 25. 1,1-Dichloroethane <0.50 <0.50 26. 1,2-Dichloroethane <0.50 <0.50 27. 1,1-Dichloroethene <0.50 <0.50 28. Cis-1,2-Dichloroethene < 0.50 < 0.50 29. trans-1,2-Dichloroethene < 0.50 < 0.50 30. 1,2-Dichloropropane < 0.50 < 0.50 31. 1,3-Dichloropropane < 0.50 < 0.50 32. 2,2-Dichloropropane <0.50 <0.50 33. 1,1-Dichloropropene <0.50 <0.50 34. Cis-1,3-Dichloropropene <0.50 <0.50 35. trans-1,3-Dichloropropene <0.50 <0.50 36. Ethylbenzene <0.50 <0.50 37. Hexachlorobutadiene <0.50 <0.50 38. Isopropylbenzene < 0.50 < 0.50 39. 4-Isopropyltoluene <0.50 <0.50 40. Methylene Chloride < 0.50 < 0.50 41. Naphthalene <0.50 <0.50 42. Propylbenzene <0.50 <0.50 43. Styrene <0.50 <0.50 44. 1,1,1,2 -Tetrachloroethane <0.50 <0.50 45. 1,1,2,2 -Tetrachloroethane <0.50 <0.50 46. Tetrachloroethene < 0.50 < 0.50 47. Toluene < 0.50 < 0.50 48. 1,2,3-Trichlorobenzene <0.50 <0.50 91mummW % hmpumbd P.O. BOX 7085, 114 OAKMONT DRIVE GREENVILLE, N.C. 27835-7085 CLIENT: PCS PHOSPHATE CO., INC. MR. BRAD LEE 1530 NC HWY. 306 SOUTH AURORA, NC 27806 7� /v REVIEWED BY: ✓--I VOLATILE ORGANICS STD. METHODS 6200C (97) JNE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 1603 ANALYST: MAO DATE COLLECTED: 11/22/16 DATE ANALYZED: 12/05/16 DATE REPORTED: 12/16/16 PARAMETERS, ug/l NMI -6A MM1-613 49. 1,2,4-Trichlorobenzene <0.50 <0.50 50. 1,1,1 -Trichloroethane <0.50 <0.50 51. 1,1,2 -Trichloroethane <0.50 <0.50 52. Trichloroethene <0.50 <0.50 53. Trichlorofluoromethane < 0.50 < 0.50 54. 1,2,3-Trichloropropane <0.50 <0.50 55. 1,2,4-Trimethylbenzene <0.50 <0.50 56. 1,3,5-Trimethylbenzene <0.50 <0.50 57. Vinyl Chloride <0.50 <0.50 58. Total Xylenes < 1.00 < 1.00 59. Methyl Tert Butyl Ether < 1.00 < 1.00 Page: 2 P.O. BOX 7085, 114 OAKMONT DRI' _ GREENVILLE, N.C. 27835-7085 _ CLIENT: PCS PHOSPHATE CO., INC. MR. BRAD LEE 1530 NC HWY. 306 SOUTH AURORA, NC 27806 J REVIEWED BY: VOLATILE ORGANICS STD. METHODS 6200C (97) FAX (252) 756-0633 CLIENT ID: 1603 ANALYST: MAO DATE COLLECTED: 11/28/16 Page: 1 DATE ANALYZED: 12/06/16 DATE REPORTED: 12/16/16 PARAMETERS, ug/1 MW2-1A MW2-1BR 1. Benzene <0.50 <0.50 2. Bromobenzene <0.50 <0.50 3. Bromochloromethane <0.50 <0.50 4. Bromodichloromethane <0.50 <0.50 5. Bromoform <0.50 <0.50 6. Bromomethane <0.50 <0.50 7. N-Butylbenzene <0.50 <0.50 8. Sec-Butylbenzene < 0.50 < 0.50 9. Tert-Butylbenzene < 0.50 < 0.50 10. Carbon Tetrachloride <0.50 <0.50 11. Chlorobenzene <0.50 <0.50 12. Chloroethane <0.50 <0.50 13. Chloroform <0.50 <0.50 14. Chloromethane <0.50 <0.50 15. 2-Chlorotoluene < 0.50 < 0.50 16. 4-Chlorotoluene <0.50 <0.50 17. Dibromochloromethane <0.50 <0.50 18. 1,2-Dibromo-3-Chloropropane <0.50 <0.50 19. 1,2-Dibromoethane <0.50 <0.50 20. Dibromomethane < 0.50 < 0.50 21. 1,2 -Dichlorobenzene < 0.50 < 0.50 22. 1,3 -Dichlorobenzene <0.50 <0.50 23. 1,4 -Dichlorobenzene < 0.50 < 0.50 24. Dichlorodifluoromethane <0.50 <0.50 25. 1,1-Dichloroethane <0.50 <0.50 26. 1,2-Dichloroethane <0.50 <0.50 27. 1,1-Dichloroethene <0.50 <0.50 28. Cis-1,2-Dichloroethene <0.50 <0.50 29. trans-1,2-Dichloroethene <0.50 <0.50 30. 1,2-Dichloropropane <0.50 <0.50 31. 1,3-Dichloropropane <0.50 <0.50 32. 2,2-Dichloropropane <0.50 <0.50 33. 1,1-Dichloropropene <0.50 <0.50 34. Cis-1,3-Dichloropropene <0.50 <0.50 35. trans-1,3-Dichloropropene <0.50 <0.50 36. Ethylbenzene <0.50 <0.50 37. Hexachlorobutadiene <0.50 <0.50 38. Isopropylbenzene <0.50 <0.50 39. 4-Isopropyltoluene <0.50 <0.50 40. Methylene Chloride <0.50 <0.50 41. Naphthalene <0.50 <0.50 42. Propylbenzene < 0.50 < 0.50 43. Styrene < 0.50 < 0.50 44. 1,1,1,2 -Tetrachloroethane <0.50 <0.50 45. 1,1,2,2 -Tetrachloroethane <0.50 <0.50 46. Tetrachloroethene < 0.50 < 0.50 47. Toluene < 0.50 < 0.50 48. 1,2,3-Trichlorobenzene < 0.50 <0.50 GREENVILLE, N.C. 27835-7085 CLIENT: PCS PHOSPHATE CO., INC. MR. BRAD LEE 1530 NC HWY. 306 SOUTH AURORA, NC 27806 v REVIEWED BY: ILAN VOLATILE ORGANICS STD. METHODS 6200C (97) PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 1603 ANALYST: MAO DATE COLLECTED: 11/28/16 Page: 2 DATE ANALYZED: 12/06/16 DATE REPORTED: 12/16/16 PARAMETERS, ug/1 MM2 -1A MW2-IBR 49. 1,2,4-Trichlorobenzene < 0.50 < 0.50 50. 1,1,1 -Trichloroethane <0.50 <0.50 51. 1,1,2 -Trichloroethane <0.50 <0.50 52. Trichloroethene <0.50 <0.50 53. Trichlorofluoromethane <0.50 <0.50 54. 1,2,3-Trichloropropane <0.50 <0.50 55. 1,2,4-Trimethylbenzene <0.50 <0.50 56. 1,3,5-Tritnethylbenzene <0.50 <0.50 57. Vinyl Chloride < 0.50 < 0.50 58. Total Xylenes < 1.00 < 1.00 59. Methyl Tert Butyl Ether < 1.00 < 1.00 13 � ilwram i.1W Flo hmpo mho ZEN, P.O. BOX 7085, 114 OAKMONT DRIVE GREENVILLE, N.C. 27835-7085 CLIENT: PCS PHOSPHATE CO., INC. MR. BRAD LEE 1530 NC HWY. 306 SOUTH AURORA, NCS 27806 REVIEWED BY: VOLATILE ORGANICS STD. METHODS 6200C (97) PHONE (252) 756-6208 FAX 252 756-0633 CLIENT ID: 1604 ANALYST: MAO DATE COLLECTED: 11/28/16 Page: 1 DATE REPORTED: 12/16/16 Date Analyzed: PARAMETERS, ug/l 12/05/16 MW24A 12/06/16 MW24B 12/06/16 MM24C 12/06/16 MM2 -5B 12/06/16 MW2-5C 1. Benzene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 2. Bromobenzene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 3. Bromochloromethane <0.50 <0.50 <0.50 <0.50 <0.50 4. Bromodichloromethane <0.50 <0.50 <0.50 <0.50 <0.50 5. Bromoform <0.50 <0.50 <0.50 <0.50 <0.50 6. Bromomethane <0.50 <0.50 <0.50 <0.50 <0.50 7. N-Butylbenzene <0.50 <0.50 <0.50 <0.50 <0.50 8. Sec-Butylbenzene <0.50 <0.50 <0.50 <0.50 <0.50 9. Tert-Butylbenzene <0.50 <0.50 <0.50 <0.50 <0.50 10. Carbon Tetrachloride <0.50 <0.50 <0.50 <0.50 <0.50 11. Chlorobenzene < 0.50 < 0.50 < 0.50 < 0.50 <0.50 12. Chloroethane <0.50 <0.50 <0.50 <0.50 <0.50 13. Chloroform <0.50 <0.50 <0.50 <0.50 <0.50 14. Chloromethane <0.50 <0.50 <0.50 <0.50 <0.50 15. 2-Chlorotoluene <0.50 <0.50 <0.50 <0.50 <0.50 16. 4-Chlorotoluene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 17. Dibromochloromethane < 0.50 < 0.50 <0.50 < 0.50 < 0.50 18. 1,2-Dibromo-3-Chloropropane < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 19. 1,2-Dibromoethane <0.50 <0.50 <0.50 <0.50 <0.50 20. Dibromomethane <0.50 <0.50 <0.50 <0.50 <0.50 21. 1,2 -Dichlorobenzene <0.50 <0.50 <0.50 <0.50 <0.50 22. 1,3 -Dichlorobenzene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 23. 1,4 -Dichlorobenzene <0.50 <0.50 <0.50 <0.50 <0.50 24. Dichlorodifluoromethane <0.50 <0.50 <0.50 <0.50 <0.50 25. 1,1-Dichloroethane < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 26. 1,2-Dichloroethane <0.50 <0.50 <0.50 <0.50 <0.50 27. 1,1-Dichloroethene <0.50 <0.50 <0.50 <0.50 <0.50 28. Cis-1,2-Dichloroethene <0.50 <0.50 2.60 <0.50 <0.50 29. trans-1,2-Dichloroethene < 0.50 < 0.50 <0.50 < 0.50 < 0.50 30. 1,2-Dichloropropane <0.50 <0.50 <0.50 <0.50 <0.50 31. 1,3-Dichloropropane <0.50 <0.50 <0.50 <0.50 <0.50 32. 2,2-Dichloropropane <0.50 <0.50 <0.50 <0.50 <0.50 33. 1,1-Dichloropropene <0.50 <0.50 <0.50 <0.50 <0.50 34. Cis-1,3-Dichloropropene <0.50 <0.50 <0.50 <0.50 <0.50 35. trans-1,3-Dichloropropene <0.50 <0.50 <0.50 <0.50 <0.50 36. Ethylbenzene <0.50 <0.50 <0.50 <0.50 <0.50 37. Hexachlorobutadiene <0.50 <0.50 <0.50 <0.50 <0.50 38. Isopropylbenzene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 39. 4-Isopropyltoluene <0.50 <0.50 <0.50 <0.50 <0.50 40. Methylene Chloride < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 41. Naphthalene < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 42. Propylbenzene <0.50 <0.50 <0.50 <0.50 <0.50 43. Styrene <0.50 <0.50 <0.50 <0.50 <0.50 44. 1,1,1,2 -Tetrachloroethane <0.50 <0.50 <0.50 <0.50 <0.50 45. 1,1,2,2 -Tetrachloroethane < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 46. Tetrachloroethene <0.50 <0.50 <0.50 <0.50 <0.50 47. Toluene < 0.50 < 0.50 <0.50 < 0.50 < 0.50 .i 1 � E['mw'0T@mH(@M Flo hmpumbd P.O. BOX 7085, 114 OAKMONT DRIVE rriuivc <<oe) ion-oeuo _q GREENVILLE, N.C. 27835-7085 _ _ _ FAX (252) 756-0633 CLIENT: PCS PHOSPHATE CO., INC. MR. BRAD LEE 1530 NC HWY. 306 SOUTH AURORA, NC 27806 � 1 REVIEWED BY: VOLATILE ORGANICS STD. METHODS 6200C (97) CLIENT ID: 1604 ANALYST: MAO DATE COLLECTED: 11/28/16 Page: 2 DATE REPORTED: 12/16/16 Date Analyzed: PARAMETERS, ug/l 12/05/16 MM2 -4A 12/06/16 MW2-4B 12/06/16 MW24C 12/06/16 MW2-5B 12/06/16 MM2 -5C 48. 1,2,3-Trichlorobenzene <0.50 <0.50 <0.50 <0.50 <0.50 49. 1,2,4-Trichlorobenzene <0.50 <0.50 <0.50 <0.50 <0.50 50. 1,1,1 -Trichloroethane <0.50 <0.50 <0.50 <0.50 <0.50 51. 1,1,2 -Trichloroethane < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 52. Trichloroethene <0.50 <0.50 <0.50 <0.50 <0.50 53. Trichlorofluoromethane <0.50 <0.50 <0.50 <0.50 <0.50 54. 1,2,3-Trichloropropane <0.50 <0.50 <0.50 <0.50 <0.50 55. 1,2,4-Trimethylbenzene <0.50 <0.50 <0.50 <0.50 <0.50 56. 1,3,5-Trimethylbenzene <0.50 <0.50 <0.50 <0.50 <0.50 57. Vinyl Chloride <0.50 <0.50 <0.50 <0.50 <0.50 58. Total Xylenes < 1.00 < 1.00 < 1.00 < 1.00 < 1.00 59. Methyl Tert Butyl Ether < 1.00 < 1.00 < 1.00 < 1.00 < 1.00