WQ0003396_Monitoring - 11-2016_20161222

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
FACILITY INFORMATION rleasernnrclearryor type
Facility Name: —_ - Arauco Panels USA, LLC
Permit Name (if different):
Facility Address: 985 Corinth Road
County Chatham
tact Person: John Bird Telephone#: [phone]
I Location/Site Name Arauco Panels USA, LLC No. of wells to be sampled:._ 9+1
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
PERMIT Number: Expiration Date: 11/30/2016
Non -Discharge W00003396 _ UIC
NPDES Other
TYPE_ OF PERMITTED OPERATION BEING MONITORED
0 Lagoon ❑ Remediation: Infiltration Gallery
El Spray Field ❑ Remediation:
Cl Rotary Distributor ❑ Land Application of Sludge
El Water Source Heat Pump 11 Other:
WELL ID NUMBER (from Permit): SMW-3 Date sample collected: 1,1/812016__ _
Well Depth: 23 ft. Well Diameter: 2 in.
Depth to Water Level 82546: 17 - ft. below measuring point Screened Interval: ft. to ft.
Measuring Point is ft. above land surface Relative M.P. Elevation: ft.
Volume of water pumped/bailed before sampling: _ 3 gallons
Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO
Date sample analyzed: 1119, 11/10, 11/11, 11/15, 11/16, 11/21, Laboratory Name:
_
_ ENCO
PARAMETERS NOTE: Values_ should reflect dissolved and colloidal concentrations.
Temp. 000lc 19.4 °C
DRY at
COD 00335
mg/L
Nitrite (NO2) as N oo615
<0.017
mg/L
Coliform: MF Fecal 31616
/100mL
Nitrate (NO3) as N 00620
3.2
mg/L
Coliform: MF Total 31504
/100ml-
Phosphorus: Total as P00665
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
<0.16
mg/L
issolved Solids:Total 70300 <50
mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 0o403
units
Ba - Barium 01007
ug/L
TOC 00680 0.35'
mg/L
Ca - Calcium 00916
_
_mg/L_
Chloride 00940 _ _ 7.1
mg/L
Cd - Cadmium 01027
,_ ,
_ ug/L.
Arsenic 01002
ug/L
Chromium: Total 01034
Grease and Oils oo552
mg/L
Cu - Copper 01042
b
LU Rg/L
Phenol 32730 _ _
ug/L
Fe - Iron =45
= -
tag/L
Sulfate 00945
mg/L
Hg - Mercury 71900
`.
ug/L
pecific Conductance 00095
µMhos
K - Potassium 00937
_-
mg/L
Total Ammonia 00610 <0.045
mg/L
Mg - Magnesium 00927
mg/L
(Ammonia Nitrogen; NH,,as'N Ammonia Nitrogen, Total).
Mn -Manganese 01055
ug/L
TKN as N 00625
mg/L
Ni - Nickel 01067 _
_ _
ug/L
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
FIELD ANALYSES:
WAS
pH oo400: 5.2 units
Temp. 000lc 19.4 °C
DRY at
_
Spec. Cond.000.94:
0.063 µMhos
time i
Odor 00085:
NO ODOR
samplling,
check
Appearance
CLEAR
here: -
Certification No. NC591
Pb - Lead olo51 ug/L
Zn - Zinc 01092 — mg/L DEC 2 9 2m
Other (Specify Compounds and Concentration Units):
NITRATE/NITRITE = 3.2 mg/L
FORMALDEHYDE= BRL
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ❑ Yes (1) ❑ No (0)
VOC 7873 method # _ _ -
_. _- method #
method #
method #
mg/L Effluent Total VOCs:
mg/L VOC Removal%
Tom Quesenberry - Regional Manufacturing Director ~� _ 12/15/2016
Permittee (or Authorized Aqent) Name and Title - Please Print ortvpe Siqnature of P rmittee (or Authorize . q_eet) r == (Date)
GW -59 Rev. 8/2013

SUBMIT FORM ON YELLOW PAPER ONLY
For Remedlation Systems Only (Attach Lab Reports): Influent Total VOCs
Tom Quesenberry- Regional Manufacturing Director
Permittee (or Authorized Agent) Name and Title - Please print or type
GW -59 Rev. 8/2013
mg/L Effluent Total VOCs:
mg/L VOC Removal%
12/15/2016
Signature of Permittee (or Authorized Agerttj — _ _ -" (Date)
DEPARTMENT OF ENVIRONMENT $ NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:DIVISION
OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
_ SR:.: e e
n
1617 MAIL SERVICE CENTER, RALEIGH, NC 27 699-1 61 7 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 1.1/30/2016
Facility Name: _ _-
Arauco Panels USA, LLC . _- _
Non -Discharge W00003396 UIC
Permit Name (if different): _
.
NPDES Other
Facility Address: -_ _ _
98.5 Corinth Road _ _ _ _ _
TYPE OF PERMITTED OPERATION BEING MONITORED
_
County _ Chatham
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
Contact Person: _ -__ John Bird
_
- _ T_ elephone#- 919-642-6658
_
❑ Rotary Distributor Land Application of Sludge
Well Location/Site Name Arauco Panels LISA, LLC
No. of wells to be sampled: 9+1
❑ Water Source Heat Pump El Other' _
-- - - --
-- - --
- - from Permit
SAMPLING INFORMATION
-__--
_ - _ -
If WELL
WELL ID NUMBER (from Permit): _ SMW-4 _
Date sample collected: 1118/2016
FIELD ANALYSES:
WAS
Well Depth: 19 ft.
Well Diameter;_ 2 in.
pH oomo: 6.5 units Temp. 0001c 201 °C
DRY at
Depth to Water Level 82546: 7.9 ft. below measuring point
--- -
- -
Screened Interval:: ft. to
-
ft. Spec. Cond. 00094: 1.84 µMhos
- -- -
time of
sampling,
Measuring Point is ft. above land surface
Relative M.P. Elevation- ft.
Odor xoom: NO ODOR
- -- -- --
check
-
Volume of water pumped/bailed before sampling
6
-
gallons
CLEAR
Appearance _ -__ _- _
here: --
Samples for metals were collected u_nfi-Itered_: El YES d
NO and field acidified:. -Ej YES [I NO
LABORATORY INFORMATION
Date sample analyzed: 11/9,_11/10._11/11, 11/15, 11/16, 11/2.1
Laboratory Name;
ENCO _ Certification No. NG591
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations
COD 00335
mg/L
Nitrite (NO2) as N 00615 <0.017
Pb -Lead 01051
mg/Lug/L
Coliform: MFFecal 31616
/100mL
Nitrate (NO3) as N 00620 <0.025
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL Phosphorus: Total as P00665
mg/L
(Nate: use MPN method for Kghry turbid samples)
Orthophosphate 70507 <0.16__
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 1300_
mg/L
AI - Aluminum o1 -l05 _ _
mg/L _. _ _ _ NITRATE/NITRITE--= <0.041 mg/L
pH (Lab) oo4m --- - __.
units
Ba - Barium 01007
ug/L - FORMALDEHYDE =.BRL
TOC o068o - 4.7
mg/L
Ca - Calcium 00916 _ _ _. _ - -
mg/L-
Chloride oo940 580_
mg/L
Cd - Cadmium 01027
ug/L.
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L _
Grease. and Oils 00552
mg/L
Cu -Copper 01o42 _
ORGANICS; b GC, GC/MS, HPLC
mg/L { y )
Phenol 32730 _
ug/L
Fe - Iron oio45
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 _ _
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑ Yes (1) 0 No (0)
pecific Conductance 00095 _ _
µMhos
K - Potassium 00937
mg/L VOC 7873 _ method
Total Ammonia 00610 <0.045
mg/L
Mg - Magnesium 00927
mg/L , method #
(Ammonia Nitrogen: NH3as N; Ammonia Nitrogen; Total)
Mn - Manganese 01055
ug/L _ _-, , method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L - _ method #
For Remedlation Systems Only (Attach Lab Reports): Influent Total VOCs
Tom Quesenberry- Regional Manufacturing Director
Permittee (or Authorized Agent) Name and Title - Please print or type
GW -59 Rev. 8/2013
mg/L Effluent Total VOCs:
mg/L VOC Removal%
12/15/2016
Signature of Permittee (or Authorized Agerttj — _ _ -" (Date)

SUBMIT FORM ON YELLOW PAPER ONLY
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: _ mg/L Effluent Total VOCs: -_ mg/L VOC Removal%
Tom Quesenberry - Regional Manufacturing Director = - :r _ _ - _ 12/15/2016
Permittee (or Authorized Actent) Name and Title- Please print or type Signature of Permittee (or Authorized Apent _ '- (Date)
GW -59 Rev. 8/2013
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
►. � � s
�
DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT -
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
.FACILITY INFORMATION
Piease Print aearar ,oe
Tl �'
Y
PERMIT Number: Expiration Date: _11130/2016 _
Facility Name:Arauco
Panels USA, LLC _
Non -Discharge W00003396 — UIC
Permit Name (if different)_
NPDES Other
Facility Address: _
985 Corinth
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
County Chatham
D Lagoon D Remediation: Infiltration Gallery
D Spray Field D Remediation:
Contact Person: John Bird
Telephone#: [phone]
Q Rotary Distributor D Land Application of Sludge
Well Location/Site Name Arauco Panels USA, LLC_
No. of wells to be sampled: 9+1
[1 Water Source Heat Pump_ 0 Other:
-
SAMPLING INFORMATION
_
_.- _ -----
- -- ---
If WELL
WELL ID NUMBER (from Permit): SMW-5
Date sample collected° 11/8/2016
FIELD ANALYSES:
WAS
Well Depth: 20 ft.
Well Diameter: 2 in.
pH 00400: _-_ 7.1 units Temp. 000l[ 19.4 °C
DRY at
Depth to Water Level x2546: 8.9 ft. below measuring point
- Interval: ftto
Screened .
-
_ ft. Spec. Cond. 00094: 2 84 µMhos
--- — _-
time of
sampling,
Measuring Point is ft. above land surface
Relative M.P. Elevation: —ft.
Odor 00085: NO ODOR
check
Volume of water pumped/bailed before sampling:
6 _
gallons
Appearance CLEC
here:
Samples for metals were collected unfiltered: D YES D
NO and field acidified: D YES - _ D NO -
L.ABORATOR_Y. INFORMATION
Date sample analyzed: 11/9,11/10, 11111, 11115, 11/1.6. 11121,
Laboratory Name: _ _
ENCO- . . _ Certification No. N_C591_
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations..
COD 00335
mg/L
Nitrite (NO2) as N oo615 <0.017
mg/L Pb - Lead o1051 ug/L
Coliform: MF Fecal 31616
/100mL
Nitrate (NO3) as N 00620 0.18
mg/L Zn - Zine 01092 mg/L
Coliform: MF Total 31504 _ _ ..
/100mL Phosphorus: Total as P o0665
mg/L
(Note: Use MPN method for highly turbid samples) -
Orthophosphate 70507 <0.16
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 1700
mg/L
AI -Aluminum oilo5
mg/L NITRATEMITRATE_= 0.18 mg/L_
pH (Lab) 00403
units
_
Ba - Barium 01007_
ug/L FORMALDEHYDE = BRL
TOC 00680 5.9
mg/L
Ca -Calcium 00916 _ _ _
mg/L
Chloride oo94o 710
mg/L
Cd - Cadmium 01027 ._ _
ug/L
Arsenic 01002
ug/L
Chromium: Total oto34
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042 _
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron oio45 _ _ _ _ _
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate oo945 ._
mg/L
H9 - Mercury 71900
ug/L Lab Report Attached? D Yes (1) ❑ No (0)
pecific Conductance 00095
µMhos
K - Potassium 00937 _-
mg/L VOC 7873 method #
Total. Ammonia 00610 0.052 -
mg/L
Mg- Magnesium 00927 _
mg/L method #
(Ammonia Nitrogen; NH, as N, Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L method #
TKN as N 00625
mg/L
Ni = Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: _ mg/L Effluent Total VOCs: -_ mg/L VOC Removal%
Tom Quesenberry - Regional Manufacturing Director = - :r _ _ - _ 12/15/2016
Permittee (or Authorized Actent) Name and Title- Please print or type Signature of Permittee (or Authorized Apent _ '- (Date)
GW -59 Rev. 8/2013

SUBMIT FORM ON YELLOW PAPER ONLY
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Tom Quesenbeny - Regional Manufacturing Director
Permittee (or Authorized Aqent) Name and Title Please print or tvpe
GW -59 Rev. 8/2013
mg/L Effluent Total VOCs: - mg/L VOC Removal%
G
_ (Date)
12/15/2016
e o
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
o ®o
®
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT =
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 2 7699-1617 Phone: [phone]
- - Please Print cleaq or Type
FACILITY INFORMATION
PERMIT Number: Expiration Date: 11!30/2016._
Facility Name: Arauco Panels USA,_LLC. __- _
Non -Discharge _ _WQ0003396 UIC
NPDES _ _ Other _
Permit Name (if different): __- _ _ _
Facility Address: 985 Corinth Road
TYPE OF PERMITTED OPERATION BEING MONITORED
County Chatham
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑Spray Field 0 Remediation:
Contact Person: _- _._ John Bird
_ _ Telephone* -919-642-6658
Rotary Distributor ❑ Land Application of Sludge
Well'Location/Site Name _ Arauco Panels USA, LLC
No. of wells to be sampled:. 9+1 _
❑ Water Source Heat Pump Other:
_
(from Permit)—
- - - — -- -- --
SAMPLING INFORMATION
- - ----- — - - - - -
If'WELL
WELL ID NUMBER (from Permit): SMW=8 _ ,
Date sample collected: -1118/2016
_ FIELD ANALYSES:
WAS
Well Depth: 23 ft
Well Diameter: _ 2 in.
pH oo400: 72. units Temp. cook 17.3 °C
DRY at
_
Depth to Water Level x2546: 7 ft. below measuring point
—
Screened Interval: ft. to
__
ft. Spec, Cond. 00094: 1.268 hos
__ _ µM
time of
samplling,.
Measuring Point is ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085: NO ODOR
check
Volume of water pumped/bailed before sampling: 7.5
gallons
Appearance CLEAR
here;! -1
Samples for metals were collected unfiltered: ❑ YES ❑_NO - and field acidified: ❑ YES ❑ NO
-
LABORATORY INFORMATION
-- - - -- -
Date sample analyzed: 11/9. 11/10, 1.1/11, 11/15, 1.1/16-1112 1.
Laboratory Name:
ENCO Certification No. __ NC591
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations:
COD 00335 mg/L
Nitrite (NO2) as N 00615 <0.017
mg/L Pb - Lead oio5i ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NQ3) as N oo620 <0.025
mg/L Zn -Zinc 01092 mg/L
Coliform:, MF Total 31504 _ /1 OOmL Phosphorus: Total as P 00665
mg/L
(Note:. Use MPN method for highly tuft id samples)
Orthophosphate 70507 <0.16
mg/L Other (Specify Compounds and Concentration Units):
issolved SolidsTotal 70300 1.000 _ mg/L
AI -Aluminum 01105 __ _
mg/L NITRATE/NITR-ITE, ---<0.041 mg/L
pH (Lab) 00403 _ _ units
Ba - Barium 01007
ug/L- _ . _ FORMALDEHYDE = BRL
TOC oo68o 3.8 mg/L
Ca - Calcium oo916 _
mg/L _
Chloride oo940 420 _ mg/L
Cd - Cadmium o1027 _ _
ug/L
Arsenic oloo2 _ ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 - _ - ug/L
Fe - Iron 01045 _
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71 goo
ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0)
pecifie Conductance 00095 µMhos
K - Potassium 00937 _
mg/L VOC_7873 method #
Total Ammonia 00610 0.052 mg/L
Mg = Magnesium 00927 - _
mg/L _ , method #
(Ammonia Nitrogen;NH3as N; AmmoniaNitrogen, Total)
Mn -Manganese 01055
ug/L _ ,method #
TKN as N 00625 mg/L
Ni -Nickel olo67
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Tom Quesenbeny - Regional Manufacturing Director
Permittee (or Authorized Aqent) Name and Title Please print or tvpe
GW -59 Rev. 8/2013
mg/L Effluent Total VOCs: - mg/L VOC Removal%
G
_ (Date)
12/15/2016

SUBMIT FORM ON YELLOW PAPER ONLY
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
mg/L Effluent Total VOCs:
Tom Quesenberry - Regional Manufacturing Director_
Permittee (or Authorized Aqent) Name and Title - Please print or tvve Siqnature of Permittee (or Authorized
GW -59 Rev. 8/2013
mg/L VOC Removal%
0 o
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING',
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT `
COMPLIANCE REPORT FORM
a o 0
o
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number, Expiration Date: 11/30/2016_
Facility Name: -
Arauco Panels USA, LLC _.
Non -Discharge W00003396 UIC
Permit Name (if different):
__ _.
NPDES Other
Facility Address:
985 Corinth
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
D Lagoon Remediation: Infiltration Gallery
_ County Chatham
0 Spray Field D Remediation:
Contact Person: _ _ _- _ John Bird_
_ _
Telephone#: [phone]_58
❑ Rotary Distributor Q Land Application of Sludge
Well Location/Site Name Arauco Panels USA, LLC
No. of wells to be sampled: 9+1
El Water Source Heat Pump D Other:.
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): .__ _ SMW=9 -
Date sample collected: 1118/2.016
FIELD ANALYSES:
WAS
Well Depth:
Well Diameter: 2 in.
pH 00400: 7,1 units Temp. oco1C_ 17 °C
DRY at
_22 _ft.
Depth to Water Level 82546: 4.8 ft. below measuring point
Screened Interval: — fl. to
_ ft. Spec. Cond: 00094:_ _ -__ 0.6.15 µMhos
time of
sampling,
Measuring Point is ft. above land surface
Relative M.P. Elevation: ft:
Odor 000a5: NO ODOR
check
Volume of water pumped/bailed before sampling:
_ 8.41 -
gallons
Appearance CLEAR -
here:
Samples for metals were collected unfiltered: D
YES _E7-
NO and field acidified: -0 YES Q NO
LABORATORY INFORMATION --
- - - - - ---__- -_
Date sample analyzed: 11/9. 11/10, 11/11, 11/15, 11/16, 11/21_,
Laboratory Name:
ENCO _. _ Certification No. NC591
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N oo615 <0.017
mg/L Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31618
/100mL
Nitrate (NO3) as N 00620 <0.025
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL Phosphorus: Total as P oo665 _
mg/L
(Note: Use MPN method for highly turbid samples] -
Orthophosphate 70507 <0.16
mg/L Other (Specify Compounds and Concentration Units):.
issolved Solids:Total 70300 _ 490
mg/L
Al - Aluminum 01105 - _ _
mglL NITRATE/NITRITE = <0.041 mg/L
pH (Lab) oo403
units
Ba-Barium01007
uglL FORMALDEHYDE = BRL _
TOC oa68o 4.7 _ _ . _
mg/L
Ca - Calcium 00916
mg/L _-
Chloride 00940 _ 150
mg/L
Cd - Cadmium o1o27
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00,952 _-
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730.
ug/L
Fe - Iron 01045 _- _ _ -
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900 -
ug/L Lab Report Attached? C3 Yes (1) No (0)
peck Conductance 00095 - -
µMhos
K = Potassium 00937 _
mg/L VOC 787.3 _ method #
Total Ammonia o0610 <0.045 _
mg/L
Mg - Magnesium 00927 _ -_ .__
mg/L method #
(Ammonia Nitrogen;NH3as N; Ammonia Nitrogen, Total)
I
Mn - Manganese olom
ug/L method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L _ _ method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
mg/L Effluent Total VOCs:
Tom Quesenberry - Regional Manufacturing Director_
Permittee (or Authorized Aqent) Name and Title - Please print or tvve Siqnature of Permittee (or Authorized
GW -59 Rev. 8/2013
mg/L VOC Removal%

SU13MI I F-UKM UN YJ;LLUW F'At'LK ONLY
■ DEPARTMENT OF ENVIRONMENT a NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
��W617
COMPLIANCE REPORT FORM MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 11/30/2016
Facility Name: Arauco Panels USA, LLC - Non -Discharge W00003396 UIC
Permit Name (if different): NPOES Other
Facility Address: e 985 Corinth Road _ TYPE OF PERMITTED OPERATION BEING MONITORED
County Chatham ❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
Contact Person: John Bird Telephone#: [phone] ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name Arauco Panels USA, LLC No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other:
SAMPLING INFORMATION
72
mg/L
pH (Lab) 00403units
� -
R
If WELL
WELL ID NUMBER (from Permit): SMW-18R -_
Date sample collected: 11/8/_2.016
FIELD ANALYSES:
Chloride oo94o
12
WAS
Well Depth: 21 ft.
Well Diameter: 2 in.
pH oo40o: _5.3 units
Temp. 000lc 179 °C
Fe - Iron 01o45
DRY at
Depth to Water Level 82546;_ 9.5 ft. below measuring point Screened Interval: ft. to
ft. Spec. Cond. 00094:
0.052 µMhos
Sulfate 00945
time of
sampling,
Measuring Point is - ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085:
NO ODOR
Total Ammonia 00610
check
Volume of water pumped/bailed before sampling: 5.25
gallons
Appearance
CLEAR
here:
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES M NO
late sample analyzed: 11/9, 11/10, 11/11, 11/15, 1.1L16_11P21, Laboratory Name: ENCO Certification No. NC591
ARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD oo335 mg/L Nitrite (NO2) as N 00615 <0.017 mg/L Pb - Lead o1o51 ug/L
Coliform; MF Fecal 31616 �- /100mL Nitrate (NO3) as N 00620 0.31 mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL
(Note. Use MPN method for highly turbid samples)
Ived Solids:Total 70300
72
mg/L
pH (Lab) 00403units
� -
R
TOC oae8o
<0.34
mg/L
Chloride oo94o
12
mg/L
Arsenic 01002
ug/L
ug/L
Grease and Oils 00552 T
Fe - Iron 01o45
mg/L
Phenol 32730
ug/L
ug/L
Sulfate 00945
Mg - Magnesium 00927
mg/L
fic Conductance 00095
ug/L
µMhos
Total Ammonia 00610
<0.045
mg/L
(Ammonia Nitrogen: NH, as N; Ammonia Nitrogen, Total)
TKN as N 00625 mg/L
Phosphorus: Total as P 00665
- mg/L
Orthophosphate 70507
<0.16 mg/L
Al - Aluminum 01105
mg/L
Ba - Barium oloo7
ug/L
Ca - Calcium oo918
mg/L
Cd - Cadmium 01027
ug/L
Chromium: Total olo34
ug/L
Cu - Copper 01042
mg/L
Fe - Iron 01o45
ug/L
Hg - Mercury 71 goo
ug/L
K - Potassium 00937
mg/L
Mg - Magnesium 00927
mg/L
Mn - Manganese olo55
ug/L
Ni - Nickel 01067
ug/L
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Other (Specify Compounds and Concentration Units):
NITRATE/NITRITE = 0.31 mgA_
FORMALDEHYDE = BRL
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ❑ Yes (1) ❑ No (0)
VOC 7873 method #
method #
method #
method #
mg/L Effluent Total VOCs:
mg/L VOC Removal% _
Tom Quesenberry = Regional Manufacturing Director _ _ _ _ 12/15/2016
Permittee (or Authorized Agent) Name and'fitle - Please pnnt or tvpe Siqnature of Permittee for Authorized Abent) — - (Date)
GW -59 Rev. 8/?013

SUBMIT FORM ON YELLOW PAPER ONLY
For Remediation Systems Only (Attach Lab Reports): influent Total VOCs:
Tom Quesenberry - Regional Manufacturing Director
Perrmittee (or Autnonzed Agent) Name and Title -Please print or type
GW -59 Rev. 812013
mg/L Effluent Total VOCs:
mg/L VOC Removal%
12/29/2016
Signature of Permittee (or Authorized Agent),' - (Date) -
® ®
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
_
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
m m e
e
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number. Expiration Date: 11/30/2016_
Facility Name: _ _ _ _ - _ _
Arauco Panels -USA, LLC
Non -Discharge WQ0003396 UIC
Permit Name (if different): _
_ _ _ _ ..___ _
NPDES _ Other
Facility Address: _ _ —
___ 985 Corinth
Road _ _ _
TYPE OF PERMITTED OPERATION BEING MONITORED
.. z
County _ _Chatham
❑ Lagoon ❑Remediation: Infiltration
g Gallery
.70
El Spray Field ❑ Remedlation:
Contact Person: _ _ John Bird
-
- Telephone#: [phone]
Rotary Distributor Land Application of Sludge
Well Location/Site Name _ _ Arauco Panels USA, LLC
No. of wells to be sampled: 9+1
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION
If WELL
WELL- ID NUMBER (from Permit): _ SMW-19
Date sample collected: 11/8/2016
FIELD ANALYSES:
WAS
Well Depths 43 ft.
Well Diameter: 2_ in.
pH 00400: 6.5 units Temp. molc 17.4 °C
DRY at
Depth to Water Level 82546 9.5 ft. below measuring point
Screened Interval: ft. to
ft. Spec. Cond. 00094: 0.791 µMhos
time of
-—
Measuring Point is - ft. above land surface
Relative M.P. Elevation: ft.
- NO ODOR
Odor 00085: _
sampling,
check
Volume of water pumped/bailed before sampling:
_ 1.5. __
gallons
Appearance light brownlyellow (silty)
here:
Samples for metals were collected unfiltered: ❑
YES ❑
NO and field acidified: 0 YES 0 NO
LABORATORY INFORMATION
Date sample analyzed: 11/9, 1.1/10, 11/11-, 11/15; 1.1./16, '11/21.,
Laboratory Name:
ENCO _ _ Certification No. NC591__
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO,) as N oo6f5 0.019
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616
/100mL
Nitrate (NO3) as N 00620 0.033
Zn - Zinc 01092
mg/Lmg/L
Coliform: MF Total 31504
/100mL Phosphorus: Total as P oo665 _
mg/L
(Note: Use MPNmethod for rijohi wr5ids"pies) --
Orthophosphate 70507 _ <0.16_ __---_
mg/L Other (Specify Compounds and Concentration Units):
Issolved Solids:Total 70300 <500
mg/L
Al -Aluminum oiim
mg/L NITRATEINITRITE = 0.052 mg/L
PH (Lab) 00403 _ _ _ - _ _
units
Ba - Barium 01007
- -
ug/L FORMALDEHYDE_= 70 ug/L
- -
TOC 00680 _ 20. —
mg/L
Ca- Calcium 00916_ _
mg/L
Chloride 00940 150
mg/L
Cd - Cadmium 01027
ug/L 9.54
Arsenic 01002 _ _-.
ug/L
Chromium: Total o1o34 r
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042 :
rng/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe = Iron o1o45
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate oo945
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0)
pecific Conductance 00095
µMhos
K - Potassium oo937
mg/L VOC 7873 method #
Total Ammonia oo610 _ 0.29 _
mg/L
Mg - Magnesium 00927 _ _
mg/L _ _- _ _ , method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn -.Manganese 01056 _
ug/L ,method #
TKN as N oo625
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): influent Total VOCs:
Tom Quesenberry - Regional Manufacturing Director
Perrmittee (or Autnonzed Agent) Name and Title -Please print or type
GW -59 Rev. 812013
mg/L Effluent Total VOCs:
mg/L VOC Removal%
12/29/2016
Signature of Permittee (or Authorized Agent),' - (Date) -

SUBMIT FORM ON YELLOW PAPER ONLY
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Tom Quesenberry_- Regional Manufacturing Director
Permittee (or Authorized Aaent) Name and Title . please pent or tvpe
GW -59 Rev. 8/2013
mg/L Effluent Total VOCs:
mg/L VOC Removal%
12/15/2016
S]QnatUTe of Permittee !cr Authorized AaenTJ - _- -- - (Date)
DEPARTMENT OF ENVIRONMENT 8 NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
r
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Cie arfyorType
PERMIT Number: Expiration Date: 11/_30/2016
Facility Name:
Arauco Panels USA, LLC
NQn-Discharge W00003396 UIC
Permit Name (if different):
_
_ _ _ _
NPDES Other
Facility Address: �.
985 Corinth Road
TYPE OF PERMITTED OPERATION BEING MONITORED
-
County Chatham
❑ Lagoon ❑ Remediation: Infiltration Gallery
-
0 Spray Field ❑ Remediation:
Contact Person: John Bird
Telephone#: [phone]
❑ Rotary Distributor U1 Land Application of Sludge
Well Location/Site Name Arauco Panels USA, LLC No. of wells to be sampled: 9+1
❑ Water Source Heat Pump ❑ Other.
rim,, Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): SMW-20
Date sample collected: 11/8/2016
FIELD ANALYSES:
WAS
Well Depth: 43 ft.
Well Diameter: 2 in.
pH 00400: 7.1 units Temp. molc 161 0C
DRY at
Depth to Water Level 82546: 6.8 ft. below measuring point
Screened Interval: ft. to
ft. Spec. Cond. 00094: 0.259 fLMhos
time of
sampling.
Measuring Point is ft. above land surface
Relative M.P. Elevation: _ _ _ ft
Odor 00045: NO ODOR
check
Volume of water pumped/bailed before sampling-
18
gallons
Appearance _ CLQ _
here: �'j
E]
Samples for metals were collected unfiltered: U
YES
EJ NO and field acidified: 1:1 YES 1:1 NO
LABORATORY INFORMATION
Date sample analyzed 11/9. 11/10, 11/11. 11115,
1.1116, 11/2.1,
Laboratory Name:
ENCO Certification No. N_C_ _5.91 _
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615 <0.017
mg!L Pb - Lead olo51 ug/L
Coliform: MF Fecal 31616
/100ml-
Nitrate (NO3) as N om2o X0.025
mg/L Zn - Zlnc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus. Total as P 00665 _
mg/L
N-te Use MPN nemod For �,ghly `ura'd samples)
Orthophosphate 70507 X0.16
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 260
mg/L
AI - Aluminum o11o5
mg/L NITRATEINITRITE = X0.041 mg/L
pH (Lab) 00403
units
Ba - Barium 01007 _
ug/L FORMALDEHYDE = BRL
TOC 00680 7.7
mg/L
Ca - Calcium 00916
mg/L
Chloride 0os4o 79
mg/L
Cd - Cadmium 01027
ug/L
Arsenic olo02
ug/L
Chromium: Total c1o34
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042 _
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 _ _ _ _ _ _
ug/L
Fe - Iron o1o45
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑ Yes (1) © No (0)
pecific Conductance 00095
µMhos
K - Potassium 00935
mg/L VOC 7873 method #
Total Ammonia 00610 0.12
mg/L
Mg - Magnesium 0092.7
mg/L method # _
lAmmona Wrcges, NHS as N-. Ammonia Ni7ogBn, T0181:
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 _
mg,IL
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Tom Quesenberry_- Regional Manufacturing Director
Permittee (or Authorized Aaent) Name and Title . please pent or tvpe
GW -59 Rev. 8/2013
mg/L Effluent Total VOCs:
mg/L VOC Removal%
12/15/2016
S]QnatUTe of Permittee !cr Authorized AaenTJ - _- -- - (Date)

SUBMIT FORM ON YELLOW PAPER ONLY
For Remediation Systems Only (Attach Lab Reports): Influent. Total VOCs
Tom Quesenberry- Regional Manufacturing Director
Permittee (or Authorized Agent) Name and Title - Please print or tvpe
GW -59 Rev. 812013
mg/L Effluent Total VOCs:
mg/L VOC Removal%
12/15/2016'
m e
DEPARTMENT OF ENVIRONMENT 8 NA1 URAL RESOURCES
GROUNDWATER QUALITY MONITORING:
®®
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
®
'
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 11/30/2016
Facility Name:
Arauco Panels USA, LLC _
Non -Discharge WQ0003396 UIC '
Permit Name (if different):
NPDES Other
Facility Address: _
985 Corinth
Road _
TYPE OF PERMITTED OPERATION BEING MONITORED
— -
County Chatham
❑ Lagoon ❑ Remediation: Infiltration Gallery
- --
L1 Spray Field 11 Remediation: -
Contact Person: - _ John Bird
Telephone#: [phone]
- -
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name Arauco Panels USA, LLC
No. of wells to be sampled: 9+1 _
❑ Water Source Heat Pump 17 Other:.
from. Permit.
- - --
SAMPLING. INFORMATION -
-
_ _- -__-- --- -
If WELL
WELL ID NUMBER (from Permit): SMW-21
Date sample collected: 11/8/2016
FIELD ANALYSES:
WAS
Well Depth: 16- ft.
Well Diameter: 2
p_H 00400: 6.4 units Temp. 000lc -'$'_ °C
DRY at
Depth to Water Level 82546; 9.2ft. below measuring point
-
-in.
--
Screened Interval: ft. to
ft.
Spec. Cond. 00094: 0.444 µMhos
time of
sampling,
Measuring Point is ft. above land surface
Relative M.P. Elevation: _ __ ft.
Odor 00085: NO ODOR
_
check
Volume of water pumped/bailed before sampling:
2.5_
gallons
_
Appearance - CLEAR -
here: J
Samples for metals were collected unfiltered: ❑ YES ❑
NO and field acidified: ❑ YES ❑ NO -
- - -- --
-
LABORATORY INFORMATION
Date sample analyzed: 11/9. 11J10. 11/11, 1.1/15._11116,_1'1121._
Laboratory Name: _
ENCO
_ _- Certification No. N9591
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2.) as N 00615 0.057
mg/L
Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31616
/100mL
Nitrate (NO3) as N 00,620 X0.025
mg/L
Zn - Zinc 01092 mg/L
Coliform: MF Total 31.504
/100mL Phosphorus: Total as P oo665 _
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507 0,2_
mg/L
Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 380
mg/L
AI - Aluminum olto5
mg/L
NITRATE/NITRITE.:;: <0,041 mg/L _
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
_-_ _ _ FORMALDEHYDE =_BRL
TOC oos8o 4.2
mg/L
Ca - Calcium 00916
mg/L
--
Chloride 00940_ _ 84
mg/L
Cd - Cadmium 01027 _-
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper olo42
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 _ _
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900 - _ug/L
Lab Report Attached? Yes (1) ❑ No (0)
pecific Conductance 00035
µMhos
K = Potassium 00937
mg/L
VOC 7873 method #
Total Ammonia 00610 _ _ _ 0.081
mg/L
Mg_ - Magnesium 00927 _ _ _
mg/L
__ method #I
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn -Manganese 01055 --_ _ _
ug/L
_ _ ,method #
TKN as N 00625
mg/L
Ni - Nickel o1w
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent. Total VOCs
Tom Quesenberry- Regional Manufacturing Director
Permittee (or Authorized Agent) Name and Title - Please print or tvpe
GW -59 Rev. 812013
mg/L Effluent Total VOCs:
mg/L VOC Removal%
12/15/2016'

SUBMIT FORM ON YELLOW PAPER ONLY
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Tom Quesenberry_- Regional Manufacturing Director
Permittee (or Authonzed Aqent) Name and Title - Please print or tvoe
GW -59 Rev. a/2013
mg/L Effluent Total VOCs:
mg/L VOC Removal°
-` - 12/15/2016
Signature of Permrtiee (orquthonzed Agentl - (Date)
DEPARTMENT OF ENVIRONMENT 6 NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print cieariy or Type
PERMIT Number: Expiration Date: 11/30/2016
Facility Name: _ _ Arauco Panels _USA, LLC _ _
Non -Discharge WQ0003396 UIC
Permit Name (if different):
NPDES Other
Facility Address: _ 985 Corinth Road
TYPE OF PERMt7TED OPERATION BEING MONITORED
`
County Chatham
[j Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field Remediation:
Contact Person: John Bird
Telephone#: [phone]
❑ Rotary Distributor] Land Application of Sludge
Well Location/Site Name Arauco Panels USA, LLC
No. of wells to be sampled: 9+1
Water Source Heat Pump ❑ Other:
_ -from
Permit
--- -
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): CREEK (SCMS)
Date sample collected: 11/8/2016
FIELD ANALYSES:
WAS
_
Well Depth: ft.
Well Diameter. in.
pH omo: 6.6 units Temp. 0oo1c 10J 'C
DRY at
Depth to Water Level 82546: ft. below measuring point
Screened Interval: eft. to
ft. Spec. Cond. 00094: _ _ 0,201 µMhos
time of
sampling,
Measuring Point is _ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085: NO ODOR
check
Volume of water pumped/bailed before sampling:
gallons
Appearance STAIN, LOW LEVEL, LEAVES ANI
here:
Samples for metals were collected unfiltered: ❑ YES ❑
NO and field acidified: [] YES 0 NO
LABORATORY INFORMATION
Date sample analyzed 11/9 1111,0_1 11, 11/15,11/16,=11/211=
Laboratory Name:
ENCO Certification No.. NC591
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 rng/L
Nitrite (NO2) as N 00615 <0.017
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 0062o <0.025
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665
mg/L
(Note Use MPN method for highly turbid samples)
Orthophosphate 70507 <0.16 _
R�
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 170 mg/L
Al - Aluminum o11o5
mg/L NITRATE/NITRITI= t <0.041 mg/L.
pH (Lab) 00403 units
Ba -Barium 01007
ug/L FORMALDEHYDE = 210 ug/L
TOC 00680 48 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 14 _ mg/L
Cd - Cadmium 01027
ug/L
Arsenico1o02 ug/L
Chromium: Total o1o34
ug/L
Grease and Oils 00552 mg/L
Cu - Copper o1o42
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron o1o45
ug/L (Specify test and method #. ATTACH LAS REPORT.)
Sulfate 00945 mg/L
,
Hg - Mercury 71900
ug/L Lab Report Attached? M Yes (1) 0 No (0)
pecific Conductance 00095 µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia 00610_ 9.7 mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3as N[ Ammonia Dfitrogen. Total)
Mn -Manganese 01055.
ug/L _ ,method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Tom Quesenberry_- Regional Manufacturing Director
Permittee (or Authonzed Aqent) Name and Title - Please print or tvoe
GW -59 Rev. a/2013
mg/L Effluent Total VOCs:
mg/L VOC Removal°
-` - 12/15/2016
Signature of Permrtiee (orquthonzed Agentl - (Date)

CW -59A, COMPLIANCE. NCE. REPORT FORM Permit #
(Subinit one each monitoring period with C W-59 forms )
1
Enter date monitoring results were due.( V-1,511 b) Will this monitoring report (GW -59 andi,GW-59A)
YES
NO
I
'be submitted after the established due date?
2
Was any required information missing on the GW -59 report forms?
YES
NO
1F the answer to question i or 2 is 'YES, list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of'the monitor wells in need of repair, or maintenance (damaged casing; unlocked or missing cap,, missing
"Yes",
YES
"NO
identification plate, area overgrown, etc.)? If the ansiver is contact the Regional Office for guidance:
4
Are any monitored constituents equal to or above the established standards?
ES
NO
if the answer to question 4 is 'NO''; skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in. the space provided below:
I
: See
5
:I
For the constituents Identified in question 4 above, have standards been exceeded previously for the
same constituent(s) in the same well(s) In the fast two years?
YES
' NO
If the answer to question 5 is "NO", skip to section '8:
If the answer to question 5 is "YES". list in the space provided below, each well with constituent(s) exceeding
standards,, concentration(s) reported, and sample collection date for each occurrence (for the last two
ZX-++Ct Cil P
Are the monitoring wells listed in section:5 ilocated, at or beyond the review boundary?
YES
NO
If the answer Is "YES') a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE,IMMEDIATEL YFOR GUIDANCE. .If the, answer is "NO", monitoring wells maybe Improperly
located; contact the Regional Office.
ii
7
Is the permittee implementing previously approved actions required by the Division. Involving this
YES
NO
groundwater quality problem?
If the answer to question '7'is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO' contact the Regional Office within 90 days; an evaluation may, be
'I
required to determine the Impact the waste disposal system Is havin_a at the review and compliance
i
boundaries surrounding this facilitva Failure to do so may subject the permittee to a Notice of Violation,
fines, and/or penalties.
„ g;
The person completing. this portion (GW --59A) of the monitoring;report should sign below and submit this
fbrm with GW --59 forms for required wells to the address provided at the top of the, current GW -59 form.
I hereby acknowledge that the above information was evaluated and: the information submitted In this
report (Compliance :Report GW -59A) is true and complete to the best of my knowledge.
Signature of Perm ttee (or Authorized gent) Date
GW -'59A 112/8/2003

GW-59ai ATTACHMENT
1,411STORICAL EXCEEDANCE RESULTS - PREVIOUS Z YEARS
I Chlorldes"WRIL)
Well
Lim, it
11/6/201 3/23/2'015 7,/23./201,5
11/"17/2015' 3[8/2016 7/1312016
SIMW'-4
250
570 570 540
580 600 590"
SMW-5
850; 720 740
810 780: 760'
SMW4
550 .70 51',0
—
570 5801 '560
SMW-21
NE 330 NE
NE 450 400
TDS (mehl,
Well
Limit
11/6/2014
3/23,L/2015,7/23,/2015
11/17/2,015!
3/8/2016
7/13/2016
'SMW-4
k
1000
'11,00 1
13001
120,01
j 6.4 6.1 6.3 NE
13,0,0,
sM:W-5
-1300
1700 1700 1900 1700 1700
1700
1,200 1300 1300, .130,0 1306
1300
SMIW-9
560 630 640, 590, 640
640
SM49--
NT 3000 ;NT 430,0, 1100
870'
'SMW-21
NE NENE 85,0'
830!
TO'C'Imehl
Well,
Limit
11/6/2014 3,/23`/`20157/"23`/"2015,11/`­"`1�.7/"2015 3/$/2016 7/113/20116,1
SM -5
19
NE, NE' NE NE ;NE 4.9
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112
NT �NE INT 1 40 NE
Scims
62 18 42 21 NE 1 21
4.1
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6.2
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6.0
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NE
4.9 5,.,0: 4.7 4.9 5.1,
4.6,
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�9
_ENCO Laboratories
`62RKiU'
Accurate. Timely. Responsive. Innovative.
102-A Woodwinds Industrial Court
Cary NC, 27511
Phone: [phone] FAX: [phone]
Tuesday, November 22, 2016
Arauco USA, LLC (UN039)
Attn: John Bird
985 Corinth Road
Moncure, NC 27559
RE: Laboratory Results for
Project Number: GW/SW Monitoring, Project Name/Desc: GW/SW Monitoring -Annual
ENCO Workorder(s): CZ15249
Dear John Bird,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Wednesday, November 9, 2016.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative. This report shall not be reproduced except in full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Stephanie Franz
Project Manager
Enclosure(s)
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 1 of 40

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SAMPLE SUMMARY/ LABORATORY CHRONICLE
Client ID: SMW-3
Lab ID:
CZ15249-01
Sampled: 11/09/16 12:00 Received: 11/09/16 12:20
Parameter
Hold Date/Time(sl
Prep Date/Time(sl
Analysis Date/Time(s)
EPA 350.1
12/07/16
11/15/16
09:05
11/15/16 12:19
EPA 353.2
11/11/16
12:00
11/09/16
14:37
11/09/16 15:42
EPA 353.2
12/07/16
11/21/16
11:33
11/21/16 13:18
EPA 353.2
08/05/19
11/22/16
09:11
11/22/16 09:20
EPA 365.1
11/11/16
12:00
11/09/16
14:38
11/09/16 16:15
EPA 8260B/6230D
11/23/16
11/11/16
12:01
11/11/16 16:22
SM 254OC-1997
11/16/16
11/10/16
15:00
11/10/16 15:00
SM 4500CIE-1997
12/07/16
11/16/16
08:02
11/16/16 11:43
SM 531OB-2000
12/07/16
11/16/16
02:11
11/16/16 17:30
Client ID: SMW-4
Lab ID:
CZ15249-02
Sampled: 11/09/16 11:45 Received: 11/09/16 12:20
Parameter
Hold Date/Time(s)
Prep Date/Time(sl
Analysis Date/Time(s)
EPA 350.1
12/07/16
11/15/16
09:05
11/15/16 12:23
EPA 353.2
11/11/16
11:45
11/09/16
14:37
11/09/16 15:44
EPA 353.2
12/07/16
11/21/16
11:33
11/21/16 13:22
EPA 353.2
08/05/19
11/22/16
09:11
11/22/16 09:20
EPA 365.1
11/11/16
11:45
11/09/16
14:38
11/09/16 16:18
EPA 8260B/6230D
11/23/16
11/11/16
12:01
11/11/16 16:54
SM 254OC-1997
11/16/16
11/10/16
15:00
11/10/16 15:00
SM 4500CIE-1997
12/07/16
11/16/16
08:00
11/16/16 09:52
SM 531OB-2000
12/07/16
11/16/16
02:11
11/16/16 17:30
Client ID: SMW-5
Lab ID:
CZ15249-03
Sampled: 11/09/16 11:05 Received: 11/09/16 12:20
Parameter
Hold Date/Time(s)
Prep Date/Time(sl
Analysis Date/Time(s)
EPA 350.1
12/07/16
11/15/16
09:05
11/15/16 12:25
EPA 353.2
11/11/16
11:05
11/09/16
14:37
11/09/16 15:45
EPA 353.2
12/07/16
11/21/16
11:33
11/21/16 13:27
EPA 353.2
08/05/19
11/22/16
09:11
11/22/16 09:20
EPA 365.1
11/11/16
11:05
11/09/16
14:38
11/09/16 16:19
EPA 826013/62301)
11/23/16
11/11/16
12:01
11/11/16 17:22
SM 254OC-1997
11/16/16
11/10/16
15:00
11/10/16 15:00
SM 4500CIE-1997
12/07/16
11/16/16
08:00
11/16/16 09:55
SM 531OB-2000
12/07/16
11/16/16
02:11
11/16/16 17:30
Client ID: SMW-8
Lab ID:
CZ15249-04
Sampled: 11/09/16 11:20 Received: 11/09/16 12:20
Parameter
Hold Date/Time(s)
Prep Date/Time(s)
Analysis Date/Time(s)
EPA 350.1
12/07/16
11/15/16
09:05
11/15/16 12:27
EPA 353.2
11/11/16
11:20
11/09/16
14:37
11/09/16 15:46
EPA 353.2
12/07/16
11/18/16
08:21
11/18/16 11:49
EPA 353.2
08/05/19
11/21/16
10:17
11/21/16 11:03
EPA 365.1
11/11/16
11:20
11/09/16
14:38
11/09/16 16:21
EPA 826013/6230D
11/23/16
11/11/16
12:01
11/11/16 17:51
SM 2540C-1997
11/16/16
11/10/16
15:00
11/10/16 15:00
SM 4500CIE-1997
12/07/16
11/16/16
08:00
11/16/16 09:56
SM 53108-2000
12/07/16
11/16/16
02:11
11/16/16 17:30
Client ID: SMW-9
Lab ID:
CZ15249-05
Sampled: 11/09/16 11:35 Received: 11/09/16 12.20
Parameter
Hold Date/Timefs)
Prep Date/Time(sl
Analysis Date/Time(s)
EPA 350.1
12/07/16
11/15/16
09:03
11/15/16 10:47
EPA 353.2
11/11/16
11:35
11/09/16
14:37
11/09/16 15:50
EPA 353.2
12/07/16
11/18/16
08:21
11/18/16 11:53
EPA 353.2
08/05/19
11/21/16
10:17
11/21/16 11:03
EPA 365.1
11/11/16
11:35
11/09/16
14:38
11/09/16 16:22
EPA 826013/62301)
11/23/16
11/11/16
12:01
11/11/16 18:20
SM 25400-1997
11/16/16
11/10/16
15:00
11/10/16 15:00
SM 4500CIE-1997
12/07/16
11/16/16
08:00
11/16/16 09:56
SM 53108-2000
12/07/16
11/16/16
02:11
11/16/16 17:30
FINAL
This report relates only to the sample as
received by the laboratory,
and may only be reproduced in full. Page 2 Of 4O

CS eICO
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SAMPLE SUMMARY/ LABORATORY CHRONICLE
Client ID: SMW-18R
Lab ID:
CZ15249-06
Sampled:
11/09/16
09:35
Received:
11/09/16 12:20
Parameter
Hold Date/Timefs)
Prep Date/Time(s)
Analysis
Date/Timefsl
EPA 350.1
12/07/16
11/15/16
09:03
11/15/16
11:18
EPA 353.2
11/11/16
09:35
11/09/16
14:37
11/09/16
15:51
EPA 353.2
12/07/16
11/18/16
08:21
11/18/16
11:57
EPA 353.2
08/05/19
11/21/16
10:17
11/21/16
11:03
EPA 365.1
11/11/16
09:35
11/09/16
14:38
11/09/16
16:23
EPA 8260B/6230D
11/23/16
11/11/16
12:01
11/11/16
18:49
SM 254OC-1997
11/16/16
11/10/16
15:00
11/10/16
15:00
SM 4500CI E-1997
12/07/16
11/16/16
08:00
11/16/16
09:57
SM 531OB-2000
12/07/16
11/16/16
02:11
11/16/16
17:30
Client ID: SMW-19
Lab ID:
CZ15249-07
Sampled:
11/09/16
10:05
Received:
11/09/16 12:20
Parameter
Hold Date/Timefs)
Prep Date/Time(s)
Analysis
Date/Timefsl
EPA 350.1
12/07/16
11/15/16
09:03
11/15/16
11:22
EPA 353.2
11/11/16
10:05
11/09/16
14:37
11/09/16
15:52
EPA 353.2
12/07/16
11/18/16
08:21
11/18/16
11:59
EPA 353.2
08/05/19
11/21/16
10:17
11/21/16
11:03
EPA 365.1
11/11/16
10:05
11/09/16
14:38
11/09/16
16:25
EPA 82606/62301)
11/23/16
11/11/16
12:01
11/11/16
19:18
SM 254OC-1997
11/16/16
11/10/16
15:00
11/10/16
15:00
SM 4500CI E-1997
12/07/16
11/16/16
08:00
11/16/16
09:58
SM 53108-2000
12/07/16
11/16/16
02:11
11/16/16
17:30
Client ID: SMW-20
Lab ID:
CZ15249-08
Sampled:
11/09/16
10:15
Received:
11/09/16 12:20
Parameter
Hold Date/Timefsl
Prep Date/Time(s)
Analysis
Date/Time(sl
EPA 350.1
12/07/16
11/15/16
09:03
11/15/16
11:24
EPA 353.2
11/11/16
10:15
11/09/16
14:37
11/09/16
15:54
EPA 353.2
12/07/16
11/18/16
08:21
11/18/16
12:02
EPA 353.2
08/05/19
11/21/16
10:17
11/21/16
11:03
EPA 365.1
11/11/16
10:15
11/09/16
14:38
11/09/16
16:26
EPA 8260B/6230D
11/23/16
11/11/16
12:01
11/11/16
19:47
SM 2540C-1997
11/16/16
11/10/16
15:00
11/10/16
15:00
SM 4500CI E-1997
12/07/16
11/16/16
08:00
11/16/16
09:59
SM 531OB-2000
12/07/16
11/16/16
02:11
11/16/16
17:30
Client ID: SMW-21
Lab ID:
CZ15249-09
Sampled:
11/09/16
10:50
Received:
11/09/16 12:20
Parameter
Hold Date/Timefs)
Prep Date/Time(sl
Analysis
Date/Time(s)
EPA 350.1
12/07/16
11/15/16
09:03
11/15/16
11:27
EPA 353.2
11/11/16
10:50
11/09/16
14:37
11/09/16
15:55
EPA 353.2
12/07/16
11/18/16
08:21
11/18/16
12:04
EPA 353.2
08/05/19
11/21/16
10:17
11/21/16
11:03
EPA 365.1
11/11/16
10:50
11/09/16
14:38
11/09/16
16:27
EPA 8260B/6230D
11/23/16
11/11/16
12:01
11/11/16
20:16
SM 254OC-1997
11/16/16
11/10/16
15:00
11/10/16
15:00
SM 4500CI E-1997
12/07/16
11/16/16
08:00
11/16/16
09:59
SM 53108-2000
12/07/16
11/16/16
02:11
11/16/16
17:30
Client ID: SCMS
Lab ID:
CZ15249-10
Sampled:
11/09/16
10:35
Received:
11/09/16 12:20
Parameter
Hold Date/Time(s)
Prep Date/Timefs)
Analysis
Date/Time(s)
EPA 353.2
11/11/16
10:35
11/09/16
14:37
11/09/16
15:56
EPA 353.2
12/07/16
11/18/16
08:21
11/18/16
12:06
EPA 353.2
08/05/19
11/21/16
10:17
11/21/16
11:03
EPA 365.1
11/11/16
10:35
11/09/16
14:38
11/09/16
16:28
EPA 8260B/6230D
11/23/16
11/11/16
12:01
11/11/16
20:45
SM 254OC-1997
11/16/16
11/10/16
15:00
11/10/16
15:00
SM 45000E-1997
12/07/16
11/16/16
08:00
11/16/16
10:00
SM 53108-2000
12/07/16
11/16/16
02:11
11/16/16
17:30
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 3 0f 4O

CE
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SAMPLE SUMMARY/ LABORATORY CHRONICLE
Client ID: SCMS Lab ID: CZ15249-IOREI Sampled: 11/09/16 10:35 Received: 11/09/16 12:20
Parameter Hold Date/Time(s) Prep Date/T'ime(sl Analysis Date/Time(s)
EPA 350.1
12/07/16
11/15/16 09:03 11/15/16 13:19
Client ID: Trip Blank Lab ID: CZ15249-11 Sampled: 11/09/16 09:35 Received: 11/09/16 12:20
Parameter Hold Date/Time(s) Preo Date/Time(s) Analysis Date/Time(s)
EPA 826013/62301) 11/23/16
11/11/16 12:01 11/11/16 21:15
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 4 of 40

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Client ID: SMW-4
SAMPLE DETECTION SUMMARY
Lab ID:
CZ35249-02
Client ID: SMW-3
Lab ID: CZ15249-01
Angling
Results
Analyte
Results Flaq MDL
PPL
units
Method Notes
Chloride
7.1 1.9
5.0
mg/L
SM 4500CI E-1997
Nitrate as N
3.2 0.025
0.10
mg/L
EPA 353.2
Nitrate/Nitrite as N
3.2 0.082
0.20
mg/L
EPA 353.2
Total Oroanic Carbon
0.35 3 0.34
1.0
mQ/L
SM 53108-2000
Client ID: SMW-4
Lab ID:
CZ35249-02
Angling
Results
Flaq
MDL
PPL
units
Method
Notes
Chloride
580
9.5
25
mg/L
SM 4500CI E-1997
QB -01
Total Dissolved Solids
1300
50
50
mg/L
SM 2540C-1997
Total Organic Carbon
4.7
0.34
1.0
mg/L
SM 53108-2000
Client ID: SMW-5
72
Lab ID:
CZ15249-03
mg/L
SM 254OC-1997
Analyte
Results
Fig
MDL
PPL
Units
Method
Notes
Ammonia as N
0.052
3
0.045
0.10
mg/L
EPA 350.1
Notes
Chloride
710
D
19
50
mg/L
SM 4500C1 E-1997
QB -01
Nitrate as N
0.18
0.025
0.10
mg/L
EPA 353.2
QB -01
Nitrate/Nitrite as N
0.18
3
0.041
0.10
mg/L
EPA 353.2
Total Dissolved Solids
1700
3
50
50
mg/L
SM 254OC-1997
Total Organic Carbon
5.9
3
0.34
1.0
mg/L
SM 531OB-2000
Client ID: SMW-8
13
Lab ID:
CZ35249-04
ug/L
EPA 8260B/6230D
Analyte
Results
FlaaINDL
0.34
PQL
Units
Method
Notes
Ammonia as N
0.052
3
0.045
0.10
mg/L
EPA 350.1
Chloride
420
D
9.5
25
mg/L
SM 4500CI E-1997
QB -01
Total Dissolved Solids
1000
50
50
mg/L
SM 254OC-1997
Total Organic Carbon
3.8
0.34
1.0
mg/L
SM 531OB-2000
QB -01
Client ID: SMW-9
260
Lab ID:
CZ15249-05
mg/L
SM 254OC-1997
Analyte
Results
Flaa
MDL
POL
Units
Method
Notes
Chloride
150
D
3.8
10
mg/L
SM 4500CI E-1997
QB -01
Total Dissolved Solids
490
50
50
mg/L
SM 254OC-1997
Total Organic Carbon
4.7
0.34
1.0
mg/L
SM 531OB-2000
Client ID: SMW-18R
Lab ID:
CZ15249-06
Analyte
Results
Flaa
MDL
P L
Units
Method
Notes
Chloride
12
1.9
5.0
mg/L
SM 4500CI E-1997
3-01
Nitrate as N
0.31
0.025
0.10
mg/L
EPA 353.2
Nitrate/Nitrite as N
0.31
0.041
0.10
mg/L
EPA 353.2
Total Dissolved Solids
72
50
50
mg/L
SM 254OC-1997
Client ID: SMW-19
Lab ID:
CZ35249-07
Analyte
Results
Fig
MDL(PSL
Units
Method
Notes
Ammonia as N
0.29
0.045
0.10
mg/L
EPA 350.1
Chloride
150
1.9
5.0
mg/L
SM 4500CI E-1997
QB -01
Nitrate as N
0.033
3
0.025
0.10
mg/L
EPA 353.2
Nitrate/Nitrite as N
0.052
3
0.041
0.10
mg/L
EPA 353.2
Nitrite as N
0.019
3
0.017
0.10
mg/L
EPA 353.2
Toluene
13
0.053
0.50
ug/L
EPA 8260B/6230D
Total Organic Carbon
20
0.34
1.0
mg/L
SM 53108-2000
Client ID: SMW-20
Lab ID:
CZ15249-08
Anahtte
Results
Flaq
MDL
PPOL
Units
Method
Notes
Ammonia as N
0.12
0.045
0.10
mg/L
EPA 350.1
Chloride
79
1.9
5.0
mg/L
SM 4500CI E-1997
QB -01
Total Dissolved Solids
260
50
50
mg/L
SM 254OC-1997
Total Organic Carbon
7.7
0.34
1.0
mg/L
SM 531OB-2000
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 5 Of 40

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FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 6 Of 40
SAMPLE DETECTION SUMMARY
Client ID: SMW-21
Lab ID:
CZ15249-09
Analyte
Results
Flag
MDL
PSL
Units
Method
Notes
Ammonia as N
0.081
]
0.045
0.10
mg/L
EPA 350.1
Chloride
84
1.9
5.0
mg/L
SM 4500CI E-1997
QB -01
Nitrite as N
0.057
]
0.017
0.10
mg/L
EPA 353.2
Orthophosphate as P
0.20
J
0.16
0.50
mg/L
EPA 365.1
Total Dissolved Solids
380
50
50
mg/L
SM 254OC-1997
Total Organic Carbon
4.2
0.34
1.0
mg/L
SM 53108-2000
Client ID: SCMS
Lab ID:
CZ15249-10
AnalAte
Results
Flag
MDL
PSL,
Units
Method
Notes
4-Isopropyltoluene
2.1
0.066
0.50
ug/L
EPA 82606/62301)
Chloride
14
1.9
5.0
mg/L
SM 4500CI E-1997
3-01
Toluene
2.0
0.053
0.50
ug/L
EPA 826013/62301)
Total Dissolved Solids
170
50
50
mg/L
SM 2540C-1997
Total Organic Carbon
48
0.34
1.0
mg/L
SM 53108-2000
Client ID: SC MS
Lab ID:
CZ15249-IOREI
Analyte
Results
Man
MDL
Q
Units
Method
Notes
Ammonia as N
9.7
D
0.45
1.0
mg/L
EPA 350.1
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 6 Of 40

s
CcF. �60
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ANALYTICAL RESULTS
Description: SMW-3 Lab Sample ID: CZ15249-01 Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 12:00 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:John Sherrill
(Volatile Organic Compounds by GCMS
^ - ENCO Cary certfied analyte [NC 5911
Analyte rCAS Numberl
Results Flan
Units
DF
MDL
POLL
Batch
Method
Analyzed
Notes
1,1,1,2 -Tetrachloroethane [630-20-6]^
< 0.091
ug/L
1
0.091
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
1,1,1 -Trichloroethane [71-55-6]^
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
1,1,2,2 -Tetrachloroethane [79-34.5]^
< 0.085
ug/L
1
0.085
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
1,1,2 -Trichloroethane [79-00-5]^
< 0.068
ug/L
1
0.068
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
1,1-Dichloroethane [75-34-3]^
< 0.050
ug/L
1
0.050
0.50
61(11027
EPA 82606/62301)
11/11/16 16:22
MRK
1,1-Dichloroethene [75-35-41^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:22
MRK
1,1-Dichloropropene[563-58-61^
< 0.063
ug/L
1
0.063
0.50
61(11027
EPA 826013/62301)
11/11/16 16:22
MRK
1,2,3-Trichlorobenzene [87-61-6]^
< 0.25
ug/L
1
0.25
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:22
MRK
1,2,3-Trichloropropane [96-1814]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 826013/62301)
11/11/16 16:22
MRK
1,2,4-Trichlorobenzene[120-82-1]^
< 0.097
ug/L
1
0.097
0.50
6K11027
EPA 82606/62301)
11/11/16 16:22
MRK
1,2,4-Trimethylbenzene [95-63-6]^
< 0.067
ug/L
1
0.067
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
1,2-Dibromo-3-chloropropane [96-12-8]^
< 0.48
ug/L
1
0.48
0.50
6K11027
EPA 82606/62301)
11/11/16 16:22
MRK
1,2-Dibromoethane [106-93-4]^
< 0.27
ug/L
1
0.27
0.50
61(11027
EPA 82606/62301)
11/11/16 16:22
MRK
1,2 -Dichlorobenzene [95-50-1]A
< 0.062
ug/L
1
0.062
0.50
6K11027
EPA 82606/62301)
11/11/16 16:22
MRK
1,2-Dichloroethane[107-06-2]^
< 0.082
ug/L
1
0.082
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
1,2-Dichloropropane[78-87-5]^
< 0.098
ug/L
1
0.098
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:22
MRK
1,3,5-Trimethylbenzene [108-67-8]^
< 0.10
ug/L
1
0.10
0.50
6KII027
EPA 82606/62301)
11/11/16 16:22
MRK
1,3 -Dichlorobenzene [541-73-1]^
< 0.092
ug/L
1
0.092
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
1,3-Dichloropropane[142-28-9]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 82606/62301)
11/11/16 16:22
MRK
1,4 -Dichlorobenzene (106-46-7]A
< 0.10
ug/L
1
0.10
0.50
6KII027
EPA 8260B/6230D
11/11/16 16:22
MRK
2,2-Dichloropropane[594-20-7]^
< 0.12
ug/L
1
0.12
0.50
6K11027
EPA 82606/6230D
11/11/16 16:22
MRK
2-Chlorotoluene [95-49-8]^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 82606/62301)
11/11/16 16:22
MRK
4-Chlorotoluene [106-43-4]^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 82606/62301)
11/11/16 16:22
MRK
4-Isopropyltoluene [99-87-6]^
< 0.066
ug/L
1
0.066
0.50
61(11027
EPA 82606/62301)
11/11/16 16:22
MRK
Benzene [71-43-2]^
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 8260B16230D
11/11/16 16:22
MRK
Bromobenzene[108-86-1]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 826013/62301)
11/11/16 16:22
MRK
Bromochloromethane [74-97-5]^
< 0.11
ug/L
1
0.11
0.50
6K11027
EPA 82606/62301)
11/11/16 16:22
MRK
Bromodichloromethane [75-27-4]^
< 0.010
ug/L
1
0.010
0.50
6K11027
EPA 82606/6230D
11/11/16 16:22
MRK
Bromoform [75-25-2]^
< 0.20
ug/L
1
0.20
0.50
61(11027
EPA 82606/6230D
11/11/16 16:22
MRK
Bromomethane[74-83-9]^
< 0.28
ug/L
1
0.28
0.50
61<1 1027
EPA 8260B/6230D
11/11/16 16:22
MRK
Carbon Tetrachloride[56-23-5]^
< 0.082
ug/L
1
0.082
0.50
6K11027
EPA 82606/62301)
11/11/16 16:22
MRK
Chlorobenzene[108-90-7]^
< 0.069
ug/L
1
0.069
0.50
6K11027
EPA 82606/62301)
11/11/16 16:22
MRK
Chloroethane [75-00-3]^
< 0.18
ug/L
1
0.18
0.50
61<1 1027
EPA 82606/62301)
11/11/16 16:22
MRK
Chloroform [67-66-3]^
< 0.083
ug/L
1
0.083
0.50
61(11027
EPA 82606/62301)
11/11/16 16:22
MRK
Chloromethane [74-87-3]^
< 0.050
ug/L
1
0.050
0.50
61(11027
EPA 826013/6230D
11/11/16 16:22
MRK
cis-1,2-Dichloroethene[156-59-2]^
< 0.075
ug/L
1
0.075
0.50
6K11027
EPA 82606/62301)
11/11/16 16:22
MRK
cis-1,3-Dichloropropene [10061-01-5]^
< 0.073
ug/L
1
0.073
0.50
61(11027
EPA 82606/62301)
11/11/16 16:22
MRK
Dibromochloromethane [124-48-1]^
< 0.067
ug/L
1
0.067
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
Dibromomethane[74-95-3]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 82606/62301D
11/11/16 16:22
MRK
Dichlorodifluoromethane [75-71-8]^
< 0.091
ug/L
1
0.091
0.50
61(11027
EPA 82606/62301)
11/11/16 16:22
MRK
Ethylbenzene [100-41-4]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 82606/62301)
11/11/16 16:22
MRK
Hexachlorobutadiene[87-68-3]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 82606/62301)
11/11/16 16:22
MRK
Isopropyl Ether [108-20-3]^
< 0.20
ug/L
1
0.20
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
Isopropylbenzene [98-82-8]^
< 0.13
ug/L
1
0.13
0.50
61(11027
EPA 826013/62301)
11/11/16 16:22
MRK
m,p-Xylenes [108-38-3/106-42-3]^
< 0.18
ug/L
1
0.18
0.50
6KII027
EPA 82608/62301)
11/11/16 16:22
MRK
Methylene Chloride [75-09-21^
< 0.070
ug/L
1
0.070
0.50
6K11027
EPA 82606/62301)
11/11/16 16:22
MRK
Methyl-tert-Butyl Ether [1634-04-4]^
< 0.12
ug/L
1
0.12
0.50
61(11027
EPA 82606/62301)
11/11/16 16:22
MRK
FINAL
This report relates only to the sample as received
by the laboratory,
and may only be reproduced In full.
I Page 7 0f 4O

N
}
wvvwr.encolabs.com
ANALYTICAL RESULTS
Description: SMW-3 Lab Sample ID:CZ15249-01 Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 12:00 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:John Sherrill
Surrogates
(Volatile Organic Compounds by GCMS
OF
Spike Lv/
"/o Rec
% Rec Limits
Ba ch Method
Ana/ ed
ffy Notes
4-Bromofluorobenzene
^ - ENCO Cary certified analyte [NC 591]
1
50.0
96%
53-136
6K11027 EPA 8260816230L
1111111616.22
MRK
Dibromofluommethane
48
Analyte rCAS Numberl
Results Flag
Units
DF
MDL
PPL
Batch
Method
Analyzed
Ay Notes
Naphthalene [91-20-3]^
< 0.086
ug/L
1
0.086
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
n -Butyl Benzene [104-51-8]^
< 0.074
ug/L
1
0.074
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
n -Propyl Benzene [103-65-1]A
< 0.073
ug/L
1
0.073
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
o-Xylene[95-47-6]^
< 0.088
ug/L
1
0.088
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:22
MRK
sec-Butylbenzene[135-98-8]^
< 0.053
ug/L
1
0.053
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:22
MRK
Styrene [100 -42 -SIA
< 0.082
ug/L
1
0.082
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:22
MRK
tert-Butylbenzene [98-06-6]^
< 0.094
ug/L
1
0.094
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:22
MRK
Tetrachloroethene[127-18-4]^
< 0.099
ug/L
1
0.099
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:22
MRK
Toluene [108-88-3]A
< 0.053
ug/L
1
0.053
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:22
MRK
trans-l,2-Dichloroethene [156-60-5]^
< 0.11
ug/L
1
0.11
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
trans- l,3-Dichloropropene[10061-02-6]^
< 0.080
ug/L
1
0.080
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
Trichloroethene [79-01-6]^
< 0.13
ug/L
1
0.13
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
Trichlorofluoromethane [75-69-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:22
MRK
Vinyl chloride [75-01-4]A
< 0.083
ug/L
1
0.083
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:22
MRK
Xylenes (Total)[1330-20-7]^
< 0.22
ug/L
1
0.22
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:22
MRK
Surrogates
Resu/ts
OF
Spike Lv/
"/o Rec
% Rec Limits
Ba ch Method
Ana/ ed
ffy Notes
4-Bromofluorobenzene
48
1
50.0
96%
53-136
6K11027 EPA 8260816230L
1111111616.22
MRK
Dibromofluommethane
48
1
50.0
97%
67-129
6KII027 EPA 826OB16230L
11/11/1616.22
MRK
Toluene -d8
50
1
50.0
100%
59-134
6K11027 EPA 826OB16230L
1111111616:22
MRK
Classical Chemistry Parameters
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL P L
Batch Method
Analyzed
AM Notes
Ammonia as N [7664-41-7]^
< 0.045
mg/L
1
0.045 0.10
61(15007 EPA 350.1
11/15/16 12:19
JU
Chloride [16887-00-6]^
7.1
mg/L
1
1.9 5.0
61(16006 SM 4500CIE-1997
11/16/16 11:43
JU
Nitrate as N [14797-55-8]^
3.2
mg/L
1
0.025 0.10
61(22016 EPA 353.2
11/22/16 09:20
JU
Nitrate/Nitrite as N^
3.2
mg/L
2
0.082 0.20
6K21032 EPA 353.2
11/21/16 13:18
JU
Nitrite as N [14797-65-0]^
< 0.017
mg/L
1
0.017 0.10
6KO9041 EPA 353.2
11/09/16 15:42
JU
Orthophosphate as P [1426-54-42]^
< 0.16
mg/L
1
0.16 0.50
6KO9043 EPA 365.1
11/09/16 16:15
JU
Total Dissolved Solids^
< 50
mg/L
1
50 50
6K10004 SM 254OC-1997
11/10/16 15:00
MMR
Classical Chemistry Parameters
^ - ENCO Orlando certified analyte [NC 424]
Analyte KAS Numberl
Results
Flag
Units
DF
MDL Q
Batch Method
Analyzed
AM Notes
Total Organic Carbon
0.35
J
mg/L
1
0.34 1.0
61(16003 SM 531OB-2000
11/16/16 17:30
RSA
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 8 Of 4O

��
www.encolabs.com
ANALYTICAL RESULTS
Description: SMW-4 Lab Sample ID: CZ15249-02 Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 11:45 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By: John Sherrill
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 9 of 4O
(Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte KAS Numberl
Results Flaa
Units
DF
MDL
Q
Batch
Method
Analyzed
By Notes
1,1,1,2 -Tetrachloroethane [630-20-6]^
< 0.091
ug/L
1
0.091
0.50
6K11027
EPA 82606/62301)
11/11/16 16:54
MRK
1,1,1 -Trichloroethane [71-55-6]A
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
1,1,2,2 -Tetrachloroethane [79-34-5]^
< 0.085
ug/L
1
0.085
0.50
6K11027
EPA 826OB/6230D
11/11/16 16:54
MRK
1,1,2-Trichloroethane[79-00-5]^
< 0.068
ug/L
1
0.068
0.50
61<11027
EPA 8260B/6230D
11/11/16 16:54
MRK
1,1-Dichloroethane [75-34-3]^
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
1,1-Dichloroethene[75-35-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 82606/62301)
11/11/16 16:54
MRK
1,1-Dichloropropene[563-58-6]^
< 0.063
ug/L
1
0.063
0.50
6K11027
EPA 82606/62301)
11/11/16 16:54
MRK
1,2,3-Trichlorobenzene [87-61-6]^
< 0.25
ug/L
1
0.25
0.50
61<11027
EPA 8260B/6230D
11/11/16 16:54
MRK
1,2,3-Trichloropropane [96-18-4]^
< 0.15
ug/L
1
0.15
0.50
61<11027
EPA 8260B/6230D
11/11/16 16:54
MRK
1,2,4-Trichlorobenzene[120-82-1]^
< 0.097
ug/L
1
0.097
0.50
6K11027
EPA 82606/6230D
11/11/16 16:54
MRK
1,2,4-Trimethylbenzene [95-63-6]^
< 0.067
ug/L
1
0.067
0.50
61<11027
EPA 8260B/6230D
11/11/16 16:54
MRK
1,2-Dibromo-3-chloropropane [96-12-8]^
< 0.48
ug/L
1
0.48
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
1,2-Dibromoethane [106-93-41^
< 0.27
ug/L
1
0.27
0.50
6K11027
EPA 82606/62301)
11/11/16 16:54
MRK
1,2 -Dichlorobenzene [95-50-1]A
< 0.062
ug/L
1
0.062
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
1,2-Dichloroethane[107-06-2]^
< 0.082
ug/L
1
0.082
0.50
6K11027
EPA 826OB/6230D
11/11/16 16:54
MRK
1,2-Dichloropropane[78-87-5]^
< 0.098
ug/L
1
0.098
0.50
61<11027
EPA 8260B/6230D
11/11/16 16:54
MRK
1,3,5-Trimethylbenzene [108-67-8]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
1,3 -Dichlorobenzene [541-73-1]A
< 0.092
ug/L
1
0.092
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
1,3-Dichloropropane[142-28-9]^
< 0.15
ug/L
1
0.15
0.50
61<11027
EPA 8260B/6230D
11/11/16 16:54
MRK
1,4 -Dichlorobenzene (106-46-7]A
< 0.10
ug/L
1
0.10
0.50
61<11027
EPA 82608/62301)
11/11/16 16:54
MRK
2,2-Dichloropropane [594-20-7]^
< 0.12
ug/L
1
0.12
0.50
61<11027
EPA 8260B/6230D
11/11/16 16:54
MRK
2-Chlorotoluene[95-49-8]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 82606/62301)
11/11/16 16:54
MRK
4-Chlorotoluene [106-43-4]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 8260B/62301)
11/11/16 16:54
MRK
4-Isopropyltoluene[99-87-61^
< 0.066
ug/L
1
0.066
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Benzene [71-43-2]^
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Bromobenzene [lOB-86-1]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Bromochloromethane[74-97-5]^
< 0.11
ug/L
1
0.11
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Bromodichloromethane [75-27-4]^
< 0.010
ug/L
1
0.010
0.50
61<11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Bromoform [75-25-2]^
< 0.20
ug/L
1
0.20
0.50
6K11027
EPA 8260B16230D
11/11/16 16:54
MRK
Bromomethane [74-83-9]^
< 0.28
ug/L
1
0.28
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Carbon Tetrachloride [56-23-5]^
< 0.082
ug/L
1
0.082
0.50
6K11027
EPA 8260B/62301)
11/11/16 16:54
MRK
Chlorobenzene [108-90-7]^
< 0.069
ug/L
1
0.069
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Chloroethane [75-00-3]A
< 0.18
ug/L
1
0.18
0.50
6K11027
EPA 8260B/62301)
11/11/16 16:54
MRK
Chloroform [67-66-3]^
< 0.083
ug/L
1
0.083
0.50
61<11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Chloromethane [74-87-3]A
< 0.050
ug/L
1
0.050
0.50
61<11027
EPA 8260B/6230D
11/11/16 16:54
MRK
cis-1,2-Dichloroethene [156-59-2]^
< 0.075
ug/L
1
0.075
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
cis-1,3-Dichloropropene [10061-01-5]^
< 0.073
ug/L
1
0.073
0.50
61<11027
EPA 826OB/6230D
11/11/16 16:54
MRK
Dibromochloromethane [124-48-1]^
< 0.067
ug/L
1
0.067
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Dibromomethane [74-95-3]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 82606/62301)
11/11/16 16:54
MRK
Dichlorodifluoromethane [75-71-8]^
< 0.091
ug/L
1
0.091
0.50
61<11027
EPA 82606/62301)
11/11/16 16:54
MRK
Ethylbenzene [100-41-4]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Hexachlorobutadiene[87-68-3]^
< 0.15
ug/L
1
0.15
0.50
61<11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Isopropyl Ether [108-20-3]A
< 0.20
ug/L
1
0.20
0.50
6K11027
EPA 8260B/62301)
11/11/16 16:54
MRK
Isopropylbenzene [98-82-8]^
< 0.13
ug/L
1
0.13
0.50
61<11027
EPA 8260B/62301)
11/11/16 16:54
MRK
m,p-Xylenes [108-38-3/106-42-3]^
< 0.18
ug/L
1
0.18
0.50
6K11027
EPA 8260B/62301)
11/11/16 16:54
MRK
Methylene Chloride [75-09-2]^
< 0.070
ug/L
1
0.070
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Methyl-tert-Butyl Ether [1634-04-41A
< 0.12
ug/L
1
0.12
0.50
6K11027
EPA 82606/62301)
11/11/16 16:54
MRK
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 9 of 4O

r
CC-== �Go
www.encolabs.com
ANALYTICAL RESULTS
Description: SMW-4 Lab Sample ID:CZ15249-02 Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 11:45 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:John Sherrill
Surrogates Results
(Volatile Organic Compounds by GCMS
Soike L v/
% Rec
% Rec Limits
Balch Meth
A
RX Notes
4-Bromofluorobenzene 49
1
^ - ENCO Cary certified analyte [NC 591)
97%
53-136
6K11027 EPA 82608/62306
11/11/1616:54
MRK
Dibromofluoromethane 50
1
50.0
99%
Analyte KAS Numberl
Results Flag
Units
DF
MDL
PDL,
Batch
Method
Analyzed
By Notes
Naphthalene (91-20-3]^
< 0.086
ug/L
1
0.086
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
n -Butyl Benzene [104-51-8]A
< 0.074
ug/L
1
0.074
0.50
6K11027
EPA 82606/62301)
11/11/16 16:54
MRK
n -Propyl Benzene (103-65-1]A
< 0.073
ug/L
1
0.073
0.50
6K11027
EPA 826013/6230D
11/11/16 16:54
MRK
o-Xylene[95-47-6]^
< 0.088
ug/L
1
0.088
0.50
6K11027
EPA 826013/62301)
11/11/16 16:54
MRK
sec-Butylbenzene[135-98-8]^
< 0.053
ug/L
1
0.053
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Styrene[100-42-5]^
< 0.082
ug/L
1
0.082
0.50
61(11027
EPA 826013/62301)
11/11/16 16:54
MRK
tert-Butylbenzene [98-06-6]^
< 0.094
ug/L
1
0.094
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Tetrachloroethene [127-18-4]^
< 0.099
ug/L
1
0.099
0.50
61(11027
EPA 82606/62301)
11/11/16 16:54
MRK
Toluene [108-88-3]^
< 0.053
ug/L
1
0.053
0.50
61(11027
EPA 8260B/6230D
11/11/16 16:54
MRK
trans-1,2-Dichloroethene[156-60-5]^
< 0.11
ug/L
1
0.11
0.50
61(11027
EPA 826013/6230D
11/11/16 16:54
MRK
trans-1,3-Dichloropropene[10061-02-6]^
< 0.080
ug/L
1
0.080
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Trichloroethene [79-01-6]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/6230D
11/11/16 16:54
MRK
Trichlorofluoromethane [75-69-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 826013/62301)
11/11/16 16:54
MRK
Vinyl chloride [75-01-4]^
< 0.083
ug/L
1
0.083
0.50
6K11027
EPA 82606/62301)
11/11/16 16:54
MRK
Xylenes (Total) [1330-20-7]^
< 0.22
ug/L
1
0.22
0.50
61(11027
EPA 826013/6230D
11/11/16 16:54
MRK
Surrogates Results
OF
Soike L v/
% Rec
% Rec Limits
Balch Meth
A
RX Notes
4-Bromofluorobenzene 49
1
50.0
97%
53-136
6K11027 EPA 82608/62306
11/11/1616:54
MRK
Dibromofluoromethane 50
1
50.0
99%
67-129
6K11027 EPA 82608/62306
11/11/1616:54
MRK
Toluene -d8 50
1
50.0
100%
59-134
6K11027 EPA 82608/62306
1111111616:54
MRK
mg/L
Classical Chemistry Parameters
9.5
25
6K16004
SM 4500CIE-1997
11/16/16 09:52
JLI QB -01
Nitrate as N [14797-55-8]^
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results Flag
Units
DF
MDL
POL
Batch
Method
Analyzed
_By Notes
Ammonia as N [7664-41-7]^
< 0.045
mg/L
1
0.045
0.10
6K15007
EPA 350.1
11/15/16 12:23
JLJ
Chloride [16887-00-6]^
580
mg/L
5
9.5
25
6K16004
SM 4500CIE-1997
11/16/16 09:52
JLI QB -01
Nitrate as N [14797-55-8]^
< 0.025
mg/L
1
0.025
0.10
61(22016
EPA 353.2
11/22/16 09:20
JU
Nitrate/Nitrite as N^
< 0.041
mg/L
1
0.041
0.10
61(21032
EPA 353.2
11/21/16 13:22
JLI
Nitrite as N [14797-65-0]^
< 0.017
mg/L
1
0.017
0.10
6KO9041
EPA 353.2
11/09/16 15:44
JLI
Orthophosphate as P [1426-54-42]^
< 0.16
mg/L
1
0.16
0.50
6KO9043
EPA 365.1
11/09/16 16:18
JL)
Total Dissolved Solids^
1300
mg/L
1
50
50
6K10004
SM 254OC-1997
11/10/16 15:00
MMR
Classical Chemistry Parameters
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results Flag
Units
DF
MDL
PPL
Batch
Method
Analyzed
AM Notes
Total Organic Carbon^
4.7
mg/L
1
0.34
1.0
61(16003
SM 531OB-2000
11/16/16 17:30
RSA
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. I Page 10 Of 4O

www.encolabs.com
ANALYTICAL RESULTS
Description: SMW-5 Lab Sample ID:CZ15249-03 Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 11:05 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:John Sherrill
(Volatile Organic Compounds by GCMS
'
^ - ENCO Cary certified analyte [NC 5911
Analyte FCAS Numberl
Results Flag
Units
DF
MDL
POL
Batch
Method
Analyzed
By Notes
1,1,1,2 -Tetrachloroethane [630-20-6]A
< 0.091
ug/L
1
0.091
0.50
6K11027
EPA 82606/62301)
11/11/16 17:22
MRK
1,1,1-Trichloroethane[71-55-6]^
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:22
MRK
1,1,2,2 -Tetrachloroethane [79-34-5]A
< 0.085
ug/L
1
0.085
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
1,1,2 -Trichloroethane [79-00-5]^
< 0.068
ug/L
1
0.068
0.50
61(11027
EPA 82606/62301)
11/11/16 17:22
MRK
1,1-Dichloroethane[75-34-3]^
< 0.050
ug/L
1
0.050
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:22
MRK
1,1-Dichloroethene[75-35-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
1,1-Dichloropropene[563-58-6]^
< 0.063
ug/L
1
0.063
0.50
61(11027
EPA 826013/62301)
11/11/16 17:22
MRK
1,2,3-Trichlorobenzene[87-61-6]^
< 0.25
ug/L
1
0.25
0.50
6KII027
EPA 82606/62301)
11/11/16 17:22
MRK
1,2,3-Trichloropropane[96-18-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 82606/62301)
11/11/16 17:22
MRK
1,2,4-Trichlorobenzene[120-82-1]^
< 0.097
ug/L
1
0.097
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
1,2,4-Trimethylbenzene [95-63-6]^
< 0.067
ug/L
1
0.067
0.50
6K11027
EPA 82606/62301)
11/11/16 17:22
MRK
1,2-Dibromo-3-chloropropane [96-12-8]^
< 0.48
ug/L
1
0.48
0.50
6K11027
EPA 82606/62301)
11/11/16 17:22
MRK
1,2-Dibromoethane[106-93-4]^
< 0.27
ug/L
1
0.27
0.50
6K11027
EPA 826013/62301)
11/11/16 17:22
MRK
1,2 -Dichlorobenzene [95-50-1]A
< 0.062
ug/L
1
0.062
0.50
6K11027
EPA 82606/62301)
11/11/16 17:22
MRK
1,2-Dichloroethane[107-06-2]^
< 0.082
ug/L
1
0.082
0.50
61(11027
EPA 82606/62301)
11/11/16 17:22
MRK
1,2-Dichloropropane[78-87-5]^
< 0.098
ug/L
1
0.098
0.50
61(11027
EPA 82606/62301)
11/11/16 17:22
MRK
1,3,5-Trimethylbenzene [108-67-8]^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:22
MRK
1,3 -Dichlorobenzene [541-73-1]A
< 0.092
ug/L
1
0.092
0.50
6K11027
EPA 82606/62301)
11/11/16 17:22
MRK
1,3-Dichloropropane[142-28-9]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 82606/62301)
11/11/16 17:22
MRK
1,4 -Dichlorobenzene [106-46-7]A
< 0.10
ug/L
1
0.10
0.50
6KII027
EPA 8260B/6230D
11/11/16 17:22
MRK
2,2-Dichloropropane[594-20-7]^
< 0.12
ug/L
1
0.12
0.50
6K11027
EPA 82606/62301)
11/11/16 17:22
MRK
2-Chlorotoluene[95-49-8]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 826013/62301)
11/11/16 17:22
MRK
4-Chlorotoluene[106-43-4]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 82606/62301)
11/11/16 17:22
MRK
4-Isopropyltoluene[99-87-6]^
< 0.066
ug/L
1
0.066
0.50
6K11027
EPA 82606/62301)
11/11/16 17:22
MRK
Benzene [71-43-2]A
< 0.050
ug/L
1
0.050
0.50
6KII027
EPA 82606/62301)
11/11/16 17:22
MRK
Bromobenzene [108-86-1]^
< 0.13
ug/L
1
0.13
0.50
61(11027
EPA 82606/62301)
11/11/16 17:22
MRK
Bromochloromethane[74-97-5]^
< 0.11
ug/L
1
0.11
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:22
MRK
Bromodichloromethane [75-27-4]^
< 0.010
ug/L
1
0.010
0.50
6K11027
EPA 82606/62301)
11/11/16 17:22
MRK
Bromoform [75-25-2]^
< 0.20
ug/L
1
0.20
0.50
6K11027
EPA 82606/62301)
11/11/16 17:22
MRK
Bromomethane[74-83-9]^
< 0.28
ug/L
1
0.28
0.50
6K11027
EPA 826013/62301)
11/11/16 17:22
MRK
Carbon Tetrachloride [56-23-5]^
< 0.082
ug/L
1
0.082
0.50
61(11027
EPA 82606/62301)
11/11/16 17:22
MRK
Chlorobenzene[108-90-7]^
< 0.069
ug/L
1
0.069
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
Chloroethane [75-00-3]^
< 0.18
ug/L
1
0.18
0.50
6KII027
EPA 82606/62301)
11/11/16 17:22
MRK
Chloroform [67-66-3]^
< 0.083
ug/L
1
0.083
0.50
6K11027
EPA 82606/62301)
11/11/16 17:22
MRK
Chloromethane [74-87-31A
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
cis-1,2-Dichloroethene[156-59-2]^
< 0.075
ug/L
1
0.075
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
cis-1,3-Dichloropropene[10061-01-5]^
< 0.073
ug/L
1
0.073
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
Dibromochloromethane [124-48-1]^
< 0.067
ug/L
1
0.067
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:22
MRK
Dibromomethane[74-95-3]^
< 0.13
ug/L
1
0.13
0.50
61(11027
EPA 82606/62301)
11/11/16 17:22
MRK
Dichlorodifluoromethane [75-71-8]^
< 0.091
ug/L
1
0.091
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:22
MRK
Ethylbenzene[100-41-4]^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 82606/62301)
11/11/16 17:22
MRK
Hexachlorobutadiene [87-68-3]^
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 82606/62301)
11/11/16 17:22
MRK
Isopropyl Ether [108-20-3]A
< 0.20
ug/L
1
0.20
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:22
MRK
Isopropylbenzene[98-82-8]^
< 0.13
ug/L
1
0.13
0.50
61(11027
EPA 82606/62301)
11/11/16 17:22
MRK
m,p-Xylenes [108-38-3/106-42-3]^
< 0.18
ug/L
1
0.18
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
Methylene Chloride [75-09-2]^
< 0.070
ug/L
1
0.070
0.50
6K11027
EPA 82606/62301)
11/11/16 17:22
MRK
Methyl-tert-Butyl Ether [1634-04-4]^
< 0.12
ug/L
1
0.12
0.50
6K11027
EPA 82606/62301)
11/11/16 17:22
MRK
FINAL
This report relates only to the sample as received
by the laboratory,
and may only be reproduced In full.
Page 11 of 40

Description: SMW-5
ANALYTICAL RESULTS
Lab Sample ID:CZ15249-03
Matrix: Ground Water Sampled: 11/09/16 11:05
Project: GW/SW Monitoring -Annual Sampled By:John Sherrill
ENCO
www.encolabs.com
Received: 11/09/16 12:20
Work Order: CZ15249
Surrooates
IVolatile Organic Compounds by GCMS
DF
Spike L v/
% Rec
% Rec Limits
Batch Method
Ana/ ed
By
Notes
^ - ENCO Cary certified analyte [NC 5911
49
1
50.0
97%
53-136
6K11027 EPA 826OB16230L
11/11/16 17.22
MRK
Analyte FCAS Numberl
Results Flaa
Units
DF
MDL
Q
Batch
Method
Analyzed
AM Notes
Naphthalene [91-20-3]^
< 0.086
ug/L
1
0.086
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
n -Butyl Benzene [104-51-8]A
< 0.074
ug/L
1
0.074
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:22
MRK
n -Propyl Benzene [103-65-1]A
< 0.073
ug/L
1
0.073
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:22
MRK
o-Xylene[95-47-6]^
< 0.088
ug/L
1
0.088
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
sec-Butylbenzene[135-98-8]^
< 0.053
ug/L
1
0.053
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:22
MRK
Styrene [100-42-5]A
< 0.082
ug/L
1
0.082
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
tert-Butylbenzene [98-06-6]^
< 0.094
ug/L
1
0.094
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
Tetrachloroethene[127-18-4]^
< 0.099
ug/L
1
0.099
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:22
MRK
Toluene [108-88-3]^
< 0.053
ug/L
1
0.053
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
trans-1,2-Dichloroethene[156-60-5]^
< 0.11
ug/L
1
0.11
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
trans-1,3-Dichloropropene[10061-02-6]^
< 0.080
ug/L
1
0.080
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
Trichloroethene [79-01-6]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
Trichlorofluoromethane [75-69-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
Vinyl chloride [75-01-4]^
< 0.083
ug/L
1
0.083
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
Xylenes (Total) [1330-20-7]^
< 0.22
ug/L
1
0.22
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:22
MRK
Surrooates
Resu/(s
DF
Spike L v/
% Rec
% Rec Limits
Batch Method
Ana/ ed
By
Notes
4-Bromofluorobenzene
49
1
50.0
97%
53-136
6K11027 EPA 826OB16230L
11/11/16 17.22
MRK
Dibromofluoromethane
50
1
50.0
101%
67-129
6K11027 EPA 826OB16230L
11/11/1617.•22
MRK
Toluene -d8
50
1
50.0
100%
59-134
6K11027 EPA 8260816230L
1111111617:22
MRK
Classical Chemistry Parameters
^ - ENCO Cary certified analyte [NC 5911
Analvte 1CAS Numberl
Results
Flaa
Units
DF
MDL POLL
Batch Method
Analyzed
By
Notes
Ammonia as N [7664-41-7]^
0.052
1
mg/L
1
0.045 0.10
61(15007 EPA 350.1
11/15/16 12:25
Ili
Chloride [16887-00-6]^
710
D
mg/L
10
19 50
6K16004 SM 45000 E-1997
11/16/16 09:55
ILI
QB -01
Nitrate as N [14797-55-8]^
0.18
mg/L
1
0.025 0.10
6K22016 EPA 353.2
11/22/16 09:20
JU
Nitrate/Nitrite as N^
0.18
mg/L
1
0.041 0.10
6K21032 EPA 353.2
11/21/16 13:27
ILI
Nitrite as N [14797-65-0]^
< 0.017
mg/L
1
0.017 0.10
6KO9041 EPA 353.2
11/09/16 15:45
JL]
Orthophosphate as P [1426-54-42]^
< 0.16
mg/L
1
0.16 0.50
6KO9043 EPA 365.1
11/09/16 16:19
ILI
Total Dissolved solids^
1700
mg/L
1
50 50
6K10004 SM 2540C-1997
11/10/16 15:00
MMR
Classical Chemistry Parameters
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flaa
Units
DF
MDL Q
Batch Method
Analyzed
My
Notes
Total Organic Carbon'
5.9
mg/L
1
0.34 1.0
6K16003 SM 531OB-2000
11/16/16 17:30
RSA
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 12 Of 4O

�Eo
www.encolabs.com
ANALYTICAL RESULTS
Description: SMW-8 Lab Sample ID: CZ15249-04 Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 11:20 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By: John Sherrill
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 13 Of 4O
(Volatile Organic Compounds by GCMS
^ - ENCO Cary cetified analyte [NC 591]
Analyte TCAs Numberl
Results Flag
Units
DF
MDL
PPL
Batch
Method
Analyzed
By Notes
1,1,1,2 -Tetrachloroethane [630-20-61^
< 0.091
ug/L
1
0.091
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
1,1,1 -Trichloroethane [71-55-6]^
< 0.15
ug/L
1
0.15
0.50
61<11027
EPA 82606/62301)
11/11/16 17:51
MRK
1,1,2,2 -Tetrachloroethane [79-34-5]^
< 0.085
ug/L
1
0.085
0.50
6K11027
EPA 82606/62301)
11/11/16 17:51
MRK
1,1,2 -Trichloroethane [79-00-5]^
< 0.068
ug/L
1
0.068
0.50
61<11027
EPA 8260B/6230D
11/11/16 17:51
MRK
1,1-Dichloroethane[75-34-31^
< 0.050
ug/L
1
0.050
0.50
61<11027
EPA 8260B/62301)
11/11/16 17:51
MRK
1,1-Dichloroethene [75-35-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
1,1-Dichloropropene[563-58-6]^
< 0.063
ug/L
1
0.063
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
1,2,3-Trichlorobenzene[87-61-6]^
< 0.25
ug/L
1
0.25
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
1,2,3-Trichloropropane[96-18-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
1,2,4-Trichlorobenzene[120-82-1]^
< 0.097
ug/L
1
0.097
0.50
6K11027
EPA 82606/62301)
11/11/16 17:51
MRK
1,2,4-Trimethylbenzene [95-63-6]^
< 0.067
ug/L
1
0.067
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
1,2-Dibromo-3-chloropropane [96-12-8]^
< 0.48
ug/L
1
0.48
0.50
61<11027
EPA 8260B/6230D
11/11/16 17:51
MRK
1,2-Dibromoethane [106-93-4]^
< 0.27
ug/L
1
0.27
0.50
61<11027
EPA 8260B/62301)
11/11/16 17:51
MRK
1,2-Dichlorobenzene[95-50-1]^
< 0.062
ug/L
1
0.062
0.50
6K11027
EPA 82606/62301)
11/11/16 17:51
MRK
1,2-Dichloroethane [107-06-2]^
< 0.082
ug/L
1
0.082
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
1,2-Dichloropropane[78-87-5]^
< 0.098
ug/L
1
0.098
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
1,3,5-Trimethylbenzene [108-67-8]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
1,3 -Dichlorobenzene [541-73-1]A
< 0.092
ug/L
1
0.092
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
1,3-Dichloropropane[142-28-9]^
< 0.15
ug/L
1
0.15
0.50
61<11027
EPA 8260B/6230D
11/11/16 17:51
MRK
1,4 -Dichlorobenzene [106-46-7]A
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
2,2-Dichloropropane[594-20-71^
< 0.12
ug/L
1
0.12
0.50
61<11027
EPA 8260B/6230D
11/11/16 17:51
MRK
2-Chlorotoluene [95-49-8]^
< 0.10
ug/L
1
0.10
0.50
61<11027
EPA 82606/62301)
11/11/16 17:51
MRK
4-Chlorotoluene[106-43-4]^
< 0.10
ug/L
1
0.10
0.50
61<13027
EPA 82606/62301)
11/11/16 17:51
MRK
4-Isopropyltoluene [99-87-6]^
< 0.066
ug/L
1
0.066
0.50
6K11027
EPA 82606/62301)
11/11/16 17:51
MRK
Benzene [71-43-2]A
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 82606/62301)
11/11/16 17:51
MRK
Bromobenzene[108-86-1]^
< 0.13
ug/L
1
0.13
0.50
61<11027
EPA 82606/62301)
11/11/16 17:51
MRK
Bromochloromethane [74-97-5]^
< 0.11
ug/L
1
0.11
0.50
61<11027
EPA 82606/62301)
11/11/16 17:51
MRK
Bromodichloromethane [75-27-4]^
< 0.010
ug/L
1
0.010
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Bromoform [75-25-2]^
< 0.20
ug/L
1
0.20
0.50
61<11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Bromomethane[74-83-9]^
< 0.28
ug/1-
1
0.28
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Carbon Tetrachloride [56-23-5]^
< 0.082
ug/L
1
0.082
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Chlorobenzene[108-90-7]^
< 0.069
ug/L
1
0.069
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Chloroethane [75-00-3]^
< 0.18
ug/L
1
0.18
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Chloroform [67-66-3]^
< 0.083
ug/L
1
0.083
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Chloromethane [74-87-3]A
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
cis-1,2-Dichloroethene [156-59-2]^
< 0.075
ug/L
1
0.075
0.50
61<11027
EPA 8260B/6230D
11/11/16 17:51
MRK
cis-1,3-Dichloropropene[10061-01-5]^
< 0.073
ug/L
1
0.073
0.50
61<11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Dibromochloromethane [124-48-1]^
< 0.067
ug/L
1
0.067
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Dibromomethane [74-95-3]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Dichlorodifluoromethane [75-71-81^
< 0.091
ug/L
1
0.091
0.50
6K11027
EPA 82606/62301)
11/11/16 17:51
MRK
Ethylbenzene[100-41-4]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Hexachlorobutadiene[87-68-3]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Isopropyl Ether [108-20-3]A
< 0.20
ug/L
1
0.20
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Isopropylbenzene [98-82-8]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
m,p-Xylenes[108-38-3/106-42-3]^
< 0.18
ug/L
1
0.18
0.50
61<11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Methylene Chloride [75-09-2]^
< 0.070
ug/L
1
0.070
0.50
6K11027
EPA 8260B/62301)
11/11/16 17:51
MRK
Methyl-tert-Butyl Ether [1634-04-4]A
< 0.12
ug/L
1
0.12
0.50
6K11027
EPA 8260B/62301)
11/11/16 17:51
MRK
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 13 Of 4O

www.encolabs.com
ANALYTICAL RESULTS
Description: SMW-8 Lab Sample ID: CZ15249-04 Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 11:20 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:John Sherrill
Surrogates
(Volatile Organic Compounds by GCMS
DF
So/ke L v/
o Rec
% Rec Limits
Batch Method
Ana/vied
By
Notes
^ - ENCO Cary certified analyte [NC 5911
48
1
50.0
96%
53-136
6K11027 EPA 82608/62306
11/11/16 17.•51
MRK
Analyte fCAS Numberl
Results Flag
Units
DF
MDL
PPL
Batch
Method
Analyzed
By Notes
Naphthalene [91-20-3]^
< 0.086
ug/L
1
0.086
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:51
MRK
n -Butyl Benzene [104-51-8]A
< 0.074
ug/L
1
0.074
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:51
MRK
n -Propyl Benzene [103-65-1]A
< 0.073
ug/L
1
0.073
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:51
MRK
o-Xylene[95-47-6]^
< 0.088
ug/L
1
0.088
0.50
6K11027
EPA 8260B/62301)
11/11/16 17:51
MRK
sec-Butylbenzene[135-98-8]^
< 0.053
ug/L
1
0.053
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Styrene [100-42-5]A
< 0.082
ug/L
1
0.082
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
tent-Butylbenzene [98-06-6]^
< 0.094
ug/L
1
0.094
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Tetrachloroethene[127-18-4]^
< 0.099
ug/L
1
0.099
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Toluene [108-88-3]A
< 0.053
ug/L
1
0.053
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:51
MRK
trans-1,2-Dichloroethene [156-60-5]^
< 0.11
ug/L
1
0.11
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
trans-1,3-Dichloropropene[10061-02-6]^
< 0.080
ug/L
1
0.080
0.50
6K11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Trichloroethene [79-01-6]A
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 82606/62301)
11/11/16 17:51
MRK
Trichlorofluoromethane [75-69-4]^
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Vinyl chloride [75-01-4]^
< 0.083
ug/L
1
0.083
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Xylenes (Total) [1330-20-7]^
< 0.22
ug/L
1
0.22
0.50
61(11027
EPA 8260B/6230D
11/11/16 17:51
MRK
Surrogates
Resu/
DF
So/ke L v/
o Rec
% Rec Limits
Batch Method
Ana/vied
By
Notes
4-Bromofluorobenzene
48
1
50.0
96%
53-136
6K11027 EPA 82608/62306
11/11/16 17.•51
MRK
Dibromofluoromethane
51
1
50.0
101%
67-129
6K11027 EPA 82608/62306
11/11/1617.•51
MRK
Toluene -d8
50
1
50.0
100%
59-134
6K11027 EPA 82608/62306
11/11/16 17.•51
MRK
Classical Chemistry Parameters
^ - ENCO Cary certified analyte [NC 591]
Analyte CCAS Numberl
Results
Flag
Units
DF
MDL POL
Batch Method
Analyzed
AM
Notes
Ammonia as N [7664-41-7]^
0.052
J
mg/L
1
0.045 0.10
61(15007 EPA 350.1
11/15/16 12:27
JU
Chloride [16887-00-6]^
420
D
mg/L
5
9.5 25
61(16004 SM 4500CIE-1997
11/16/16 09:56
JU
QB -01
Nitrate as N [14797-55-8]^
< 0.025
mg/L
1
0.025 0.10
61(21022 EPA 353.2
11/21/16 11:03
JU
Nitrate/Nitrite as N^
< 0.041
mg/L
1
0.041 0.10
61(18005 EPA 353.2
11/18/16 11:49
JU
Nitrite as N [14797-65-0]^
< 0.017
mg/L
1
0.017 0.10
6KO9041 EPA 353.2
11/09/16 15:46
JU
Orthophosphate as P [1426-54-42]^
< 0.16
mg/L
1
0.16 0.50
6KO9043 EPA 365.1
11/09/16 16:21
JU
Total Dissolved Solids^
1000
mg/L
1
50 50
6K10004 SM 254OC-1997
11/10/16 15:00
MMR
Classical Chemistry Parameters
^ - ENCO Orlando certified analyte [NC 424]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL POLL
Batch Method
Analyzed
Ry
Notes
Total Organic Carbon^
3.8
mg/L
1
0.34 1.0
61(16003 SM 531OB-2000
11/16/16 17:30
RSA
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 14 Of 40

CICO
www.encolabs.com
ANALYTICAL RESULTS
Description: SMW-9 Lab Sample ID: CZ15249-05 Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 11:35 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:3ohn Sherrill
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 15 Of 40
(Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Number]
Results Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
AM Notes
1,1,1,2 -Tetrachloroethane [630-20-6]^
< 0.091
ug/L
1
0.091
0.50
61<11027
EPA 82608/62301)
11/11/16 18:20
MRK
1,1,1 -Trichloroethane [71-55-6]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 82606/62301)
11/11/16 18:20
MRK
1,1,2,2 -Tetrachloroethane [79-34-5]A
< 0.085
ug/L
1
0.085
0.50
61<11027
EPA 8260B/6230D
11/11/16 18:20
MRK
1,1,2-Trichloroethane[79-00-5]^
< 0.068
ug/L
1
0.068
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
1,1-Dichloroethane[75-34-3]^
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
1,1-Dichloroethene[75-35-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
1,1-Dichloropropene[563-58-6]^
< 0.063
ug/L
1
0.063
0.50
61<11027
EPA 8260B/62301)
11/11/16 18:20
MRK
1,2,3-Trichlorobenzene[87-61-6]^
< 0.25
ug/L
1
0.25
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
1,2,3-Trichloropropane [96-18-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 82608/62301)
11/11/16 18:20
MRK
1,2,4-Trichlorobenzene [120-82-1]^
< 0.097
ug/L
1
0.097
0.50
61<11027
EPA 8260B/6230D
11/11/16 18:20
MRK
1,2,4-Trimethylbenzene[95-63-6]^
< 0.067
ug/L
1
0.067
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
1,2-Dibromo-3-chloropropane [96-12-8]^
< 0.48
ug/L
1
0.48
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
1,2-Dibromoethane[106-93-4]^
< 0.27
ug/L
1
0.27
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
1,2 -Dichlorobenzene [95-50-11^
< 0.062
ug/L
1
0.062
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
1,2-Dichloroethane[107-06-2]^
< 0.082
ug/L
1
0.082
0.50
61<11027
EPA 8260B/6230D
11/11/16 18:20
MRK
1,2-Dichloropropane [78-87-5]^
< 0.098
ug/L
1
0.098
0.50
61<11027
EPA 8260B/6230D
11/11/16 18:20
MRK
1,3,5-Trimethylbenzene[108-67-8]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
1,3 -Dichlorobenzene [541-73-11A
< 0.092
ug/L
1
0.092
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
1,3-Dichloropropane[142-28-9]^
< 0.15
ug/L
1
0.15
0.50
61<11027
EPA 8260B/6230D
11/11/16 18:20
MRK
1,4 -Dichlorobenzene [106-46-7]^
< 0.10
ug/L
1
0.10
0.50
61<11027
EPA 8260B/6230D
11/11/16 18:20
MRK
2,2-Dichloropropane[594-20-7]^
< 0.12
ug/L
1
0.12
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
2-Chlorotoluene[95-49-8]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
4-Chlorotoluene [106-43-4]^
< 0.10
ug/L
1
0.10
0.50
61<11027
EPA 8260B/6230D
11/11/16 18:20
MRK
4-Isopropyltoluene[99-87-6]^
< 0.066
ug/L
1
0.066
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Benzene [71-43-2]^
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 82606/62301)
11/11/16 18:20
MRK
Bromobenzene[108-86-1]^
< 0.13
ug/L
1
0.13
0.50
61<11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Bromochloromethane [74-97-5]^
< 0.11
ug/L
1
0.11
0.50
61<11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Bromodichloromethane [75-27-4]^
< 0.010
ug/L
1
0.010
0.50
6K11027
EPA 82606/62301)
11/11/16 18:20
MRK
Bromoform [75-25-2]^
< 0.20
ug/L
1
0.20
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Bromomethane[74-83-9]^
< 0.28
ug/L
1
0.28
0.50
6K11027
EPA 8260B/62301)
11/11/16 18:20
MRK
Carbon Tetrachloride [56-23-5]^
< 0.082
ug/L
1
0.082
0.50
61<11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Chlorobenzene[108-90-7]^
< 0.069
ug/L
1
0.069
0.50
61<11027
EPA 8260B/62301)
11/11/16 18:20
MRK
Chloroethane [75-00-3]^
< 0.18
ug/L
1
0.18
0.50
61<11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Chloroform [67-66-3]^
< 0.083
ug/L
1
0.083
0.50
61<11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Chloromethane [74-87-3]A
< 0.050
ug/L
1
0.050
0.50
61<11027
EPA 8260B/62301)
11/11/16 18:20
MRK
cis-1,2-Dichloroethene[156-59-2]^
< 0.075
ug/L
1
0.075
0.50
61<11027
EPA 8260B/62301)
11/11/16 18:20
MRK
cis-1,3-Dichloropropene[10061-01-5]^
< 0.073
ug/L
1
0.073
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Dibromochloromethane [124-48-1]^
< 0.067
ug/L
1
0.067
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Dibromomethane [74-95-3]^
< 0.13
ug/L
1
0.13
0.50
61<11027
EPA 8260B/62301)
11/11/16 18:20
MRK
Dichlorodifluoromethane [75-71-8]^
< 0.091
ug/L
1
0.091
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Ethylbenzene[100-41-4]^
< 0.10
ug/L
1
0.10
0.50
61<11027
EPA 82606/62301)
11/11/16 18:20
MRK
Hexachlorobutadiene[87-68-3]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Isopropyl Ether [108-20-3]A
< 0.20
ug/L
1
0.20
0.50
61<11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Isopropylbenzene[98-82-8]^
< 0.13
ug/L
1
0.13
0.50
61<11027
EPA 8260B/62301)
11/11/16 18:20
MRK
m,p-Xylenes[108-38-3/106-42-3]^
< 0.18
ug/L
1
0.18
0.50
61<11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Methylene Chloride [75-09-2]^
< 0.070
ug/L
1
0.070
0.50
61<11027
EPA 8260B/62301)
11/11/16 18:20
MRK
Methyl-tert-Butyl Ether [1634-04-4]^
< 0.12
ug/L
1
0.12
0.50
61<11027
EPA 8260B/62301)
11/11/16 18:20
MRK
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 15 Of 40

C�
www.encolabs.com
ANALYTICAL RESULTS
Description: SMW-9 Lab Sample ID:CZ15249-05 Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 11:35 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:John Sherrill
Surrogates
(Volatile Organic Compounds by GCMS
DF
Spike Lv/
010 Rec
a Rec Limits
Batch Method
Anal ed
ffy Notes
4-Bromofluorobenzene
^ - ENCO Cary certified analyte [NC 591]
1
50.0
97%
53-136
6KII027 EPA 826OB16230B
1111111618:20
MRK
Dibromofluoromethane
51
Analyte rCAS Numberl
Results Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
BA Notes
Naphthalene [91-20-3]^
< 0.086
ug/L
1
0.086
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
n -Butyl Benzene [104-51-8]^
< 0.074
ug/L
1
0.074
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:20
MRK
n -Propyl Benzene [103-65-1]^
< 0.073
ug/L
1
0.073
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
o-Xylene[95-47-6]^
< 0.088
ug/L
1
0.088
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:20
MRK
sec-Butylbenzene[135-98-8]^
< 0.053
ug/L
1
0.053
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Styrene [100-42-5]A
< 0.082
ug/L
1
0.082
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:20
MRK
tert-Butylbenzene [98-06-6]^
< 0.094
ug/L
1
0.094
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Tetrachloroethene[127-18-4]^
< 0.099
ug/L
1
0.099
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Toluene [108-88-3]A
< 0.053
ug/L
1
0.053
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
trans-1,2-Dichloroethene [156-60-5]^
< 0.11
ug/L
1
0.11
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
trans-1,3-Dichloropropene[10061-02-6]^
< 0.080
ug/L
1
0.080
0.50
61(11027
EPA 8260B16230D
11/11/16 18:20
MRK
Trichloroethene [79-01-61^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Trichlorofluoromethane [75-691+]^
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Vinyl chloride [75-01-4]^
< 0.083
ug/L
1
0.083
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Xylenes (Total) (1330-20-7]A
< 0.22
ug/L
1
0.22
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:20
MRK
Surrogates
Results
DF
Spike Lv/
010 Rec
a Rec Limits
Batch Method
Anal ed
ffy Notes
4-Bromofluorobenzene
48
1
50.0
97%
53-136
6KII027 EPA 826OB16230B
1111111618:20
MRK
Dibromofluoromethane
51
1
50.0
102%
67-129
6K11027 EPA 826OB16230L
11/11/1618:20
MRK
Toluene -d8
50
1
50.0
100%
59-134
61(11027 EPA 826OB16230C
1111111618:20
MRK
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 16 Of 40
(Classical Chemistry Parameters
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results Flaq
Units
DF
MDL
POLL
Batch
Method
Analyzed
By Notes
Ammonia as N [7664-41-7]^
< 0.045
mg/L
1
0.045
0.10
6K15006
EPA 350.1
11/15/16 10:47
JU
Chloride [16887-00-6]^
150 D
mg/L
2
3.8
10
6K16004
SM 4500CI E-1997
11/16/16 09:56
JU QB -01
Nitrate as N [14797-55-8]^
< 0.025
mg/L
1
0.025
0.10
61(21022
EPA 353.2
11/21/16 11:03
JU
Nitrate/Nitrite as N^
< 0.041
mg/L
1
0.041
0.10
6K18005
EPA 353.2
11/18/16 11:53
JU
Nitrite as N [14797-65-0]^
< 0.017
mg/L
1
0.017
0.10
6KO9041
EPA 353.2
11/09/16 15:50
JU
Orthophosphate as P[1426-541+2]^
< 0.16
mg/L
1
0.16
0.50
6KO9043
EPA 365.1
11/09/16 16:22
JU
Total Dissolved Solids^
490
mg/L
1
50
50
61(10004
SM 2540C-1997'
11/10/16 15:00
MMR
Classical Chemistry Parameters
^ - ENCO Odando certified analyte [NC 424]
Analyte rCAS Numberl
Results Flag
Units
DF
MDL
l2
Batch
Method
Analyzed
By Notes
Total Organic Carbon^
4.7
mg/L
1
0.34
1.0
61(16003
SM 531OB-2000
11/16/16 17:30
RSA
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 16 Of 40

(� � �Go
www.encolabs.com
ANALYTICAL RESULTS
Description: SMW-18R Lab Sample ID:CZ15249-06
Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 09:35
Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:John Sherrill
(Volatile Organic Compounds by GCMS
'
^ - ENCO Cary ceriMed analyte [NC 591]
Analyte rCAS Numberl
Results Flaa
Units
DF
MDL
P L
Batch
Method
Analyzed
Notes
1,1,1,2 -Tetrachloroethane [630-20-6]^
< 0.091
ug/L
1
0.091
0.50
6K11027
EPA 82606/62301)
11/11/16 18:49
MRK
1,1,1 -Trichloroethane [71-55-6]A
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 82606/62301)
11/11/16 18:49
MRK
1,1,2,2 -Tetrachloroethane [79-345]^
< 0.085
ug/L
1
0.085
0.50
6KI1027
EPA 8260B/6230D
11/11/16 18:49
MRK
1,1,2 -Trichloroethane (79-00-5]A
< 0.068
ug/L
1
0.068
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:49
MRK
1,1-Dichloroethane [75-34-3]^
< 0.050
ug/L
1
0.050
0.50
61(11027
EPA 8260B/62301)
11/11/16 18:49
MRK
1,1-Dichloroethene [7S-35-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/62301)
11/11/16 18:49
MRK
1,1-Dichloropropene[563-58-6]^
< 0.063
ug/L
1
0.063
0.50
6K11027
EPA 82606/62301)
11/11/16 18:49
MRK
1,2,3-Trichlorobenzene [87-61-6]^
< 0.25
ug/L
1
0.25
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:49
MRK
1,2,3-Trichloropropane [96-18-4]^
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
1,2,4-Trichlorobenzene [120-82-1]^
< 0.097
ug/L
1
0.097
0.50
61(11027
EPA 8260B/62301)
11/11/16 18:49
MRK
1,2,4-Trimethylbenzene [95-63-6]^
< 0.067
ug/L
1
0.067
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
1,2-Dibromo-3-chloropropane [96-12-8]^
< 0.48
ug/L
1
0.48
0.50
61(11027
EPA 8260B/62301)
11/11/16 18:49
MRK
1,2-Dibromoethane[106-93-4]^
< 0.27
ug/L
1
0.27
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
1,2 -Dichlorobenzene [95-50-1]^
< 0.062
ug/L
1
0.062
0.50
61(11027
EPA 82606/62301)
11/11/16 18:49
MRK
1,2-Dichloroethane[107-06-2]^
< 0.082
ug/L
1
0.082
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
1,2-Dichloropropane [78-87-5]^
< 0.098
ug/L
1
0.098
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
1,3,5-Trimethylbenzene [108-67-8]^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
1,3 -Dichlorobenzene [541-73-1]^
< 0.092
ug/L
1
0.092
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
1,3-Dichloropropane [142-28-9]^
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
1,4 -Dichlorobenzene [106-46-7]^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 8260B/62301)
11/11/16 18:49
MRK
2,2-Dichloropropane[594-20-7]^
< 0.12
ug/L
1
0.12
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:49
MRK
2-Chlorotoluene [95-49-8]^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 8260B/62301)
11/11/16 18:49
MRK
4-Chlorotoluene [106-43-4]^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
4-Isopropyltoluene[99-87-6]^
< 0.066
ug/L
1
0.066
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Benzene [71-43-2]^
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Bromobenzene [108-86-1]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 82606/62301)
11/11/16 18:49
MRK
Bromochloromethane [74-97-5]^
< 0.11
ug/L
1
0.11
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Bromodichloromethane [75-27-4]^
< 0.010
ug/L
1
0.010
0.50
61(11027
EPA 8260B/62301)
11/11/16 18:49
MRK
Bromoform [75-25-2]^
< 0.20
ug/L
1
0.20
0.50
61(11027
EPA 82606/62301)
11/11/16 18:49
MRK
Bromomethane [74-83-9]^
< 0.28
ug/L
1
0.28
0.50
6KI1027
EPA 8260B/6230D
11/11/16 18:49
MRK
Carbon Tetrachloride [56-23-5]A
< 0.082
ug/L
1
0.082
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Chlorobenzene [108-90-7]^
< 0.069
ug/L
1
0.069
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Chloroethane [75-00-3]A
< 0.18
ug/L
1
0.18
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Chloroform [67-66-3]^
< 0.083
ug/L
1
0.083
0.50
6KI1027
EPA 8260B/6230D
11/11/16 18:49
MRK
Chloromethane (74-87-3]A
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:49
MRK
cis-1,2-Dichloroethene[156-59-2]^
< 0.075
ug/L
1
0.075
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:49
MRK
cis-1,3-Dichloropropene [10061-01-5]^
< 0.073
ug/L
1
0.073
0.50
6KII027
EPA 8260B/6230D
11/11/16 18:49
MRK
Dibromochloromethane [124-48-1]^
< 0.067
ug/L
1
0.067
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Dibromomethane [74-95-3]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/62301)
11/11/16 18:49
MRK
Dichlorodifluoromethane [75-71-8]^
< 0.091
ug/L
1
0.091
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Ethylbenzene[100-41-4]^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Hexachlorobutadiene [87-68-3]^
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Isopropyl Ether [108-20-3]A
< 0.20
ug/L
1
0.20
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Isopropylbenzene [98-82-8]^
< 0.13
ug/L
1
0.13
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
m,p-Xylenes[108-38-3/106-42-3]^
< 0.18
ug/L
1
0.18
0.50
61(11027
EPA 8260B/62301)
11/11/16 18:49
MRK
Methylene Chloride [75-09-2]^
< 0.070
ug/L
1
0.070
0.50
61(11027
EPA 82606/62301)
11/11/16 18:49
MRK
Methyl-tert-Butyl Ether [1634-04-4]^
< 0.12
ug/L
1
0.12
0.50
61(11027
EPA 82606/6230D
11/11/16 18:49
MRK
FINAL
This report relates only to the sample as received by the laboratory,
and may only be reproduced
in full.
I Page 17 of 40

www.encolabs.com
ANALYTICAL RESULTS
Description: SMW-18R Lab Sample ID:CZ15249-06 Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 09:35 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:3ohn Sherrill
Surrogates
Volatile Organic Compounds by GCMS
OF
Saike L v/
% Rec
% Rec Limits
Batch Method
A
§y
Notes
^ - ENCO Cary certified analyte [NC 5911
48
1
50.0
96%
53-136
6K11027 EPA 826OB16230L
1111111618:49
MRK
Analyte KAS Numberl
Results Flag
Units
DF
MDL
PPL
Batch
Method
Analyzed
AM Notes
Naphthalene [91-20-3]^
< 0.086
ug/L
1
0.086
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:49
MRK
n -Butyl Benzene [104-51-8]^
< 0.074
ug/L
1
0.074
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:49
MRK
n -Propyl Benzene[103-65-1]^
< 0.073
ug/L
1
0.073
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
o-Xylene[95-47-6]^
< 0.088
ug/L
1
0.088
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
sec-Butylbenzene[135-98-8]^
< 0.053
ug/L
1
0.053
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Styrene [100-42-5]^
< 0.062
ug/L
1
0.082
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:49
MRK
tert-Butylbenzene [98-06-6]^
< 0.094
ug/L
1
0.094
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Tetrachloroethene[127-18-4]^
< 0.099
ug/L
1
0.099
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Toluene [108-88-3]^
< 0.053
ug/L
1
0.053
0.50
6K11027
EPA 8260B/6230D
11/11/16 18:49
MRK
trans-1,2-Dichloroethene [156-60-51^
< 0.11
ug/L
1
0.11
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
trans-1,3-Dichloropropene[10061-02-6]^
< 0.080
ug/L
1
0.080
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Trichloroethene [79-01-6]A
< 0.13
ug/L
1
0.13
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Trichlorofluoromethane [75-69-4]^
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Vinyl chloride [75-01-4]^
< 0.083
ug/L
1
0.083
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Xylenes (Total)[1330-20-7]^
< 0.22
ug/L
1
0.22
0.50
61(11027
EPA 8260B/6230D
11/11/16 18:49
MRK
Surrogates
Resu/Ls
OF
Saike L v/
% Rec
% Rec Limits
Batch Method
A
§y
Notes
4-8romofluorobenzene
48
1
50.0
96%
53-136
6K11027 EPA 826OB16230L
1111111618:49
MRK
Dibromofluoromethane
51
1
50.0
102%
67-129
6K11027 EPA 826OB16230L
11/11/1618:49
MRK
Toluene -d8
50
1
50.0
100%
59-134
6K11027 EPA 826OB16230L
1111111618:49
MRK
Classical Chemistry Parameters
^ - ENCO Cary certified analyte [NC 591]
Analyte FCAS Numberl
Results
Flag
Units
DF
MDL POLL
Batch Method
Analyzed
_By
Notes
Ammonia as N [7664-41-7]^
< 0.045
mg/L
1
0.045 0.10
6K15006 EPA 350.1
11/15/16 11:18
JU
Chloride [16887-00-6]1
12
mg/L
1
1.9 5.0
61(16004 SM 45000E-1997
11/16/16 09:57
JLI
3-01
Nitrate as N [14797-55-8]^
0.31
mg/L
1
0.025 0.10
61(21022 EPA 353.2
11/21/16 11:03
30
Nitrate/Nitrite as N^
0.31
mg/L
1
0.041 0.10
6K18005 EPA 353.2
11/18/16 11:57
IL1
Nitrite as N [14797-65-0]^
< 0.017
mg/L
1
0.017 0.10
6KO9041 EPA 353.2
11/09/16 15:51
JU
Orthophosphate as P [1426-54-42]^
< 0.16
mg/L
1
0.16 0.50
6KO9043 EPA 365.1
11/09/16 16:23
JU
Total Dissolved Solids^
72
mg/L
1
50 50
6K10004 SM 254OC-1997
11/10/16 15:00
MMR
Classical Chemistry Parameters
^ - ENCO Orfando certified analyte [NC 4141
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL POL
Batch Method
Analyzed
By
Notes
Total Organic Carbon
< 0.34
mg/L
1
0.34 1.0
61(16003 SM 531OB-2000
11/16/16 17:30
RSA
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 18 of 40

Description: SMW-19
ANALYTICAL RESULTS
Lab Sample ID: CZ15249-07
Matrix: Ground Water Sampled: 11/09/16 10:05
Project: GW/SW Monitoring -Annual Sampled By:]ohn Sherrill
� ll�
1 � �Gjl
www.encolabs.com
Received: 11/09/16 12:20
Work Order: CZ15249
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 19 of 40
(Volatile Organic Compounds by GCMS
^ - ENCO Cary ceitfled analyte [NC 591]
Analyte KAS Numberl
Results Flaa
Units
DF
MDL
POLL
Batch
Method
Analyzed
Notes
1,1,1,2 -Tetrachloroethane [630-20-6]^
< 0.091
ug/L
1
0.091
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
1,1,1 -Trichloroethane [71-55-6]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 82606/62301)
11/11/16 19:18
MRK
1,1,2,2 -Tetrachloroethane [79-34-5]A
< 0.085
ug/L
1
0.085
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
1,1,2 -Trichloroethane [79-00-5]A
< 0.068
ug/L
1
0.068
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
1,1-Dichloroethane [75-34-3]^
< 0.050
ug/L
1
0.050
0.50
61(11027
EPA 8260B/62301)
11/11/16 19:18
MRK
1,1-Dichloroethene [75-35-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
1,1-Dichloropropene [563-58-6]^
< 0.063
ug/L
1
0.063
0.50
61(11027
EPA 82608/62301)
11/11/16 19:18
MRK
1,2,3-Trichlorobenzene[87-61-6]^
< 0.25
ug/L
1
0.25
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
1,2,3-Trichloropropane [96-18-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
1,2,4-Trichlorobenzene[120-82-1]^
< 0.097
ug/L
1
0.097
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
1,2,4-Trimethylbenzene [95-63-6]^
< 0.067
ug/L
1
0.067
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
1,2-Dibromo-3-chloropropane [96-12-8]^
< 0.48
ug/L
1
0.48
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
1,2-Dibromoethane[106-93-4]^
< 0.27
ug/L
1
0.27
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
1,2-Dichlorobenzene[95-50-1]^
< 0.062
ug/L
1
0.062
0.50
61(11027
EPA 82606/62301)
11/11/16 19:18
MRK
1,2-Dichloroethane [107-06-2]^
< 0.082
ug/L
1
0.082
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
1,2-Dichloropropane[78-87-5]^
< 0.098
ug/L
1
0.098
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
1,3,5-Trimethylbenzene [108-67-8]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
1,3 -Dichlorobenzene [541-73-1]A
< 0.092
ug/L
1
0.092
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
1,3-Dichloropropane [142-28-9]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
1,4 -Dichlorobenzene [106-46-7]^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
2,2-Dichloropropane [594-20-7]^
< 0.12
ug/L
1
0.12
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
2-Chlorotoluene [95-49-8]^
< 0.10
ug/L
1
0.10
0.50
6KII027
EPA 8260B/6230D
11/11/16 19:18
MRK
4-Chlorotoluene [106-43-4]^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
4-Isopropyltoluene[99-87-6]^
< 0.066
ug/L
1
0.066
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Benzene [71-43-2]A
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 82606/62301)
11/11/16 19:18
MRK
Bromobenzene[108-86-1]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Bromochloromethane [74-97-5]^
< 0.11
ug/L
1
0.11
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Bromodichloromethane [75-27-4]^
< 0.010
ug/L
1
0.010
0.50
6K11027
EPA 82606/62301)
11/11/16 19:18
MRK
Bromoform [75-25-2]^
< 0.20
ug/L
1
0.20
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Bromomethane [74-83-9]^
< 0.28
ug/L
1
0.28
0.50
6K11027
EPA 8260B/62301)
11/11/16 19:18
MRK
Carbon Tetrachloride [56-23-5]^
< 0.082
ug/L
1
0.082
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Chlorobenzene [108-90-7]^
< 0.069
ug/L
1
0.069
0.50
6K11027
EPA 8260B/62301)
11/11/16 19:18
MRK
Chloroethane [75-00-3]^
< 0.18
ug/L
1
0.18
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Chloroform [67-66-3]^
< 0.083
ug/L
1
0.083
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Chloromethane [74-87-3]^
< 0.050
ug/L
1
0.050
0.50
6KII027
EPA 8260B/6230D
11/11/16 19:18
MRK
cis-1,2-Dichloroethene[156-59-2]^
< 0.075
ug/L
1
0.075
0.50
6K11027
EPA 82606/62301)
11/11/16 19:18
MRK
cis-1,3-Dichloropropene[10061-01-5]^
< 0.073
ug/L
1
0.073
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Dibromochloromethane [124-48-1]^
< 0.067
ug/L
1
0.067
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Dibromomethane [74-95-3]^
< 0.13
ug/L
1
0.13
0.50
61(11027
EPA 8260B/62301)
11/11/16 19:18
MRK
Dichlorodifluoromethane [75-71-8]^
< 0.091
ug/L
1
0.091
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Ethylbenzene [100-41-41^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 82606/62301)
11/11/16 19:18
MRK
Hexachlorobutadiene[87-68-3]^
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Isopropyl Ether (108-20-3]^
< 0.20
ug/L
1
0.20
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Isopropylbenzene[98-82-8]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
m,p-Xylenes [108-38-3/106-42-3]^
< 0.18
ug/L
1
0.18
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Methylene Chloride [75-09-2]^
< 0.070
ug/L
1
0.070
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Methyl-tert-Butyl Ether [1634-04-4]^
< 0.12
ug/L
1
0.12
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 19 of 40

�a
www.encolabs.com
ANALYTICAL RESULTS
Description: SMW-19 Lab Sample ID: CZ15249-07 Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 10:05 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:John Sherrill
Surrogates
(Volatile Organic Compounds by GCMS
DF
Spike Lv/
% Rec
% Rec Limits
Batch Method
Ana/vied
By Notes
4-Bromofluorobenzene
^ - ENCO Cary certified analyte [NC 5911
1
50.0
97%
53-136
6K11027 EPA 82608/62306
1111111619:18
MRK
Dibromofluoromethane
52
Analyte fCAS Numberl
Results Flaa
Units
DF
MDL
POLL
Batch
Method
Analyzed
By Notes
Naphthalene[91-20-3]^
< 0.086
ug/L
1
0.086
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
n -Butyl Benzene [104-51-8]^
< 0.074
ug/L
1
0.074
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
n -Propyl Benzene [103-65-1]A
< 0.073
ug/L
1
0.073
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
o-Xylene[95-47-6]^
< 0.088
ug/L
1
0.088
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
sec-Butylbenzene[135-98-8]^
< 0.053
ug/L
1
0.053
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Styrene[100-42-S]^
< 0.082
ug/L
1
0.082
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
tert-Butylbenzene [98-06-6]^
< 0.094
ug/L
1
0.094
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Tetrachloroethene [127-18-4]^
< 0.099
ug/L
1
0.099
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Toluene [108-88-3]^
13
ug/L
1
0.053
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:18
MRK
trans-1,2-Dichloroethene [156-60-5]^
< 0.11
ug/L
1
0.11
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
trans-1,3-Dichloropropene[10061-02-6]^
< 0.080
ug/L
1
0.080
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Trichloroethene (79-01-6]A
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Trichlorofluoromethane [75-69-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Vinyl chloride [75-01-4]A
< 0.083
ug/L
1
0.083
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Xylenes (Total) [1330-20-7]^
< 0.22
ug/L
1
0.22
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:18
MRK
Surrogates
Resu/Gs
DF
Spike Lv/
% Rec
% Rec Limits
Batch Method
Ana/vied
By Notes
4-Bromofluorobenzene
49
1
50.0
97%
53-136
6K11027 EPA 82608/62306
1111111619:18
MRK
Dibromofluoromethane
52
1
50.0
103%
67-129
6K11027 EPA 82608/62306
11/11/1619:18
MRK
Toluene -d8
51
1
50.0
102%
59-134
6KII027 EPA 82606/62306
1111111619:18
MRK
Classical Chemistry Parameters
^ - ENCO Cary certified analyte [NC 5911
Analyte rCAS Numberl
Results
Flaa
Units
DF
MDL POLL
Batch Method
Analyzed
Ay Notes
Ammonia as N [7664-41-7]^
0.29
mg/L
1
0.045 0.10
6K15006 EPA 350.1
11/15/16 11:22
JU
Chloride [16887-00-6]^
150
mg/L
1
1.9 5.0
61(16004 SM 4500CIE-1997
11/16/16 09:58
JU QB -01
Nitrate as N [14797-55-8]^
0.033
J
mg/L
1
0.025 0.10
61(21022 EPA 353.2
11/21/16 11:03
JU
Nitrate/Nitrite as N^
0.052
J
mg/L
1
0.041 0.10
61(18005 EPA 353.2
11/18/16 11:59
JU
Nitrite as N [14797-65-0]^
0.019
J
mg/L
1
0.017 0.10
6KO9041 EPA 353.2
11/09/16 15:52
JLI
Orthophosphate as P[1426-54.42]^
< 0.16
mg/L
1
0.16 0.50
6KO9043 EPA 365.1
11/09/16 16:25
JU
Total Dissolved Solids^
< 500
mg/L
10
500 500
61(10004 SM 2540C-1997
11/10/16 15:00
MMR
Classical Chemistry Parameters
^ - ENCO Orlando certified analyte [NC 424]
Analyte fCAS Numberl Results Flaa Units DF MDL P L Batch Method Analyzed Ay Notes
Total Organic Carbon^ 20 mg/L 1 0.34 1.0 6K16003 SM 531OB-2000 11/16/16 17:30 RSA
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 20 Of 40

�G
www.encolabs.com
ANALYTICAL RESULTS
Description: SMW-20 Lab Sample ID: CZ15249-08 Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 10:15 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:John Sherrill
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 21 of 40
(Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 5911
Analyte (CAS Numberl
Results Flag
Units
DF
MDL
P L
Batch
Method
Analyzed
AM Notes
1,1,1,2 -Tetrachloroethane [630-20-61^
< 0.091
ug/L
1
0.091
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:47
MRK
1,1,1 -Trichloroethane [71-55-6]^
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 82606/62301)
11/11/16 19:47
MRK
1,1,2,2 -Tetrachloroethane [79-34-5]^
< 0.085
ug/L
1
0.085
0.50
6KII027
EPA 82606/62301)
11/11/16 19:47
MRK
1,1,2 -Trichloroethane [79-00-51^
< 0.068
ug/L
1
0.068
0.50
6KII027
EPA 8260B/6230D
11/11/16 19:47
MRK
1,1-Dichloroethane [75-34-3]^
< 0.050
ug/L
1
0.050
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:47
MRK
1,1-Dichloroethene [75-35-4]^
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:47
MRK
1,1-Dichloropropene[563-58-6]^
< 0.063
ug/L
1
0.063
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
1,2,3-Trichlorobenzene [87-61-6]^
< 0.25
ug/L
1
0.25
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
1,2,3-Trichloropropane [96-18-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
1,2,4-Trichlorobenzene [120-82-1]^
< 0.097
ug/L
1
0.097
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
1,2,4-Trimethylbenzene [95-63-6]^
< 0.067
ug/L
1
0.067
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
1,2-Dibromo-3-chloropropane [96-12-8]^
< 0.48
ug/L
1
0.48
0.50
6K11027
EPA 82606/62301)
11/11/16 19:47
MRK
1,2-Dibromoethane [106-93-4]^
< 0.27
ug/L
1
0.27
0.50
61(11027
EPA 8260B/62301)
11/11/16 19:47
MRK
1,2 -Dichlorobenzene [95-50-1]^
< 0.062
ug/L
1
0.062
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
1,2-Dichloroethane[107-06-2]^
< 0.082
ug/L
1
0.082
0.50
61(11027
EPA 82606/62301)
11/11/16 19:47
MRK
1,2-Dichloropropane [78-87-5]^
< 0.098
ug/L
1
0.098
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:47
MRK
1,3,5-Trimethylbenzene [108-67-8]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
1,3 -Dichlorobenzene [541-73-11A
< 0.092
ug/L
1
0.092
0.50
61(11027
EPA 8260B/62301)
11/11/16 19:47
MRK
1,3-Dichloropropane[142-28-9]^
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:47
MRK
1,4 -Dichlorobenzene [106-46-71A
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
2,2-Dichloropropane[594-20-7]^
< 0.12
ug/L
1
0.12
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
2-Chlorotoluene[95-49-8]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
4-Chlorotoluene [106-43-4]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
4-Isopropyltoluene[99-87-6]^
< 0.066
ug/L
1
0.066
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Benzene [71-43-2]A
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Bromobenzene[108-86-1]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Bromochloromethane [74-97-5]^
< 0.11
ug/L
1
0.11
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Bromodichloromethane [75-27-4]^
< 0.010
ug/L
1
0.010
0.50
6K11027
EPA 82606/62301)
11/11/16 19:47
MRK
Bromoform [75-25-2]^
< 0.20
ug/L
1
0.20
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Bromomethane[74-83-9]^
< 0.28
ug/L
1
0.28
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Carbon Tetrachloride [56-23-5]^
< 0.082
ug/L
1
0.082
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Chlorobenzene [108-90-7]^
< 0.069
ug/L
1
0.069
0.50
6K11027
EPA 82606/62301)
11/11/16 19:47
MRK
Chloroethane [75-00-3]^
< 0.18
ug/L
1
0.18
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Chloroform [67-66-3]^
< 0.083
ug/L
1
0.083
0.50
6KII027
EPA 82606/62301)
11/11/16 19:47
MRK
Chloromethane [74-87-31A
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
cis-1,2-Dichloroethene [156-59-2]^
< 0.075
ug/L
1
0.075
0.50
6KII027
EPA 8260B/6230D
11/11/16 19:47
MRK
cis-1,3-Dichloropropene [10061-01-5]^
< 0.073
ug/L
1
0.073
0.50
6K11027
EPA 82606/62301)
11/11/16 19:47
MRK
Dibromochloromethane [124-48-11^
< 0.067
ug/L
1
0.067
0.50
6K11027
EPA 8260B/62301)
11/11/16 19:47
MRK
Dibromomethane[74-95-3]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Dichlorodifluoromethane [75-71-8]^
< 0.091
ug/L
1
0.091
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Ethylbenzene [100-41-4]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 82606/62301)
11/11/16 19:47
MRK
Hexachlorobutadiene[87-68-3]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Isopropyl Ether [108-20-3]A
< 0.20
ug/L
1
0.20
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Isopropylbenzene[98-82-8]^
< 0.13
ug/L
1
0.13
0.50
61(11027
EPA 8260B/62301)
11/11/16 19:47
MRK
m,p-Xylenes [108-38-3/106-42-3]^
< 0.18
ug/L
1
0.18
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Methylene Chloride [75-09-2]^
< 0.070
ug/L
1
0.070
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Methyl-tert-Butyl Ether [1634-04-4]^
< 0.12
ug/L
1
0.12
0.50
61(11027
EPA 82606/62301)
11/11/16 19:47
MRK
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 21 of 40

CSNSCS
www.encolabs.com
ANALYTICAL RESULTS
Description: SMW-20 Lab Sample ID: CZ15249-08 Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 10:15 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:John Sherrill
Surrogates es /ts
(Volatile Organic Compounds by GCMS
Spike LH
°o Rec
o Rec Limits
Batch Me
Ana/ d
§ Notes
4-Bromofuorobenzene 49
1
^ - ENCO Cary certified analyte [NC 5911
98%
53-136
6K11017 EPA 82608/62306
1111111619:47
MRK
Dibromofluoromethane 52
1
50.0
105%
Analvte rCAS Numberl
Results Flaa
units
DF
MDL
PPL
Batch
Method
Analyzed
Notes
Naphthalene [91-20-3]^
< 0.086
ug/L
1
0.086
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:47
MRK
n -Butyl Benzene [10451-8]A
< 0.074
ug/L
1
0.074
0.50
61(11027
EPA 82606/62301)
11/11/16 19:47
MRK
n -Propyl Benzene [103-65-1]A
< 0.073
ug/L
1
0.073
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
o-Xylene[95-47-6]^
< 0.088
ug/L
1
0.088
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
sec-Butylbenzene [135-98-8]A
< 0.053
ug/L
1
0.053
0.50
61(11027
EPA 82606/62301)
11/11/16 19:47
MRK
Styrene[100-42-5]A
< 0.082
ug/L
1
0.082
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:47
MRK
tert-Butylbenzene [98-06-6]A
< 0.094
ug/L
1
0.094
0.50
61(11027
EPA 8260B/62301)
11/11/16 19:47
MRK
Tetrachloroethene [127-18-4]A
< 0.099
ug/L
1
0.099
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Toluene [108 -8B -3]A
< 0.053
ug/L
1
0.053
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:47
MRK
trans-1,2-Dichloroethene [156-60-5]A
< 0.11
ug/L
1
0.11
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
trans-1,3-Dichloropropene[10061-02-6]A
< 0.060
ug/L
1
0.080
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Trichloroethene [79-01-6]A
< 0.13
ug/L
1
0.13
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Trichlorofluoromethane [75-69-4]A
< 0.15
ug/L
1
0.15
0.50
61(13027
EPA 8260B/6230D
11/11/16 19:47
MRK
Vinyl chloride [75-01-4]^
< 0.063
ug/L
1
0.083
0.50
61(11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Xylenes (Total) [1330-20-7]A
< 0.22
ug/L
1
0.22
0.50
6K11027
EPA 8260B/6230D
11/11/16 19:47
MRK
Surrogates es /ts
OF
Spike LH
°o Rec
o Rec Limits
Batch Me
Ana/ d
§ Notes
4-Bromofuorobenzene 49
1
50.0
98%
53-136
6K11017 EPA 82608/62306
1111111619:47
MRK
Dibromofluoromethane 52
1
50.0
105%
67-119
6KII027 EPA 82608/62306
11/11/1619.•47
MRK
Toluene -d8 50
1
50.0
101%
59-134
6KII027 EPA 82608/6230L
1111111619:47
MRK
mg/L
Classical Chemistry Parameters
1.9
5.0
61(16004
SM 4500CIE-1997
11/16/16 09:59
]U QB -01
Nitrate as N [14797-55-8]A
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results Flaa
Units
DF
MDL
POL
Batch
Method
Analyzed
AM Notes
Ammonia as N [7664-41-7]A
0.12
mg/L
1
0.045
0.10
6K15006
EPA 350.1
11/15/16 11:24
JU
Chloride [16887-00-6]A
79
mg/L
1
1.9
5.0
61(16004
SM 4500CIE-1997
11/16/16 09:59
]U QB -01
Nitrate as N [14797-55-8]A
< 0.025
mg/L
1
0.025
0.10
61(21022
EPA 353.2
11/21/16 11:03
]U
Nitrate/Nitrite as NA
< 0.041
mg/L
1
0.041
0.10
6K18005
EPA 353.2
11/18/16 12:02
JU
Nitrite as N [14797-65-0]A
< 0.017
mg/L
1
0.017
0.10
6K09041
EPA 353.2
11/09/16 15:54
JU
Orthophosphate as P [1426-54-42]^
< 0.16
mg/L
1
0.16
0.50
6KO9043
EPA 365.1
11/09/16 16:26
JU
Total Dissolved SolidsA
260
mg/L
1
50
50
61(10004
SM 254OC-1997
11/10/16 15:00
MMR
Classical Chemistry Parameters
^ - ENCO Odando certified analyte [NC 4241
Analyte rCAS Numberl
Results Flaa
Units
DF
MDL
POLL
Batch
Method
Analyzed
By Notes
Total Organic Carbon'
7.7
mg/L
1
0.34
1.0
61(16003
SM 531OB-2000
11/16/16 17:30
RSA
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 22 Of 4O

Description: SMW-21
Matrix: Ground Water Sampled: 11/09/16 10:50
Project: GW/SW Monitoring -Annual Sampled By:John Sherrill
ANALYTICAL RESULTS
Lab Sample ID: CZ15249-09
(9 �Eo
www.encolabs.com
Received: 11/09/16 12:20
Work Order: CZ15249
L-
(Volatile Organic Compounds by GCMS
'
^ - ENCO Cary ceibfied analyte [NC 591]
Analyte (CAS Numberl
Results Flag
Units
DF
MDL
PPL
Batch
Method
Analyzed
By Notes
1,1,1,2 -Tetrachloroethane [630-20-6]^
< 0.091
ug/L
1
0.091
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:16
MRK
1,1,1 -Trichloroethane [71-55-6]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:16
MRK
1,1,2,2-Tetrachloroethane[79-34-5]^
< 0.085
ug/L
1
0.085
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
1,1,2 -Trichloroethane [79-00-5]^
< 0.068
ug/L
1
0.068
0.50
6KII027
EPA 8260B/6230D
11/11/16 20:16
MRK
1,1-Dichloroethane[75-34-3]^
< 0.050
ug/L
1
0.050
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
1,1-Dichloroethene [75-35-4]^
< 0.15
ug/L
1
0.15
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
1,1-Dichloropropene[563-58-6]^
< 0.063
ug/L
1
0.063
0.50
61<11027
EPA 8260B/62301)
11/11/16 20:16
MRK
1,2,3-Trichlorobenzene [87-61-6]^
< 0.25
ug/L
1
0.25
0.50
61<11027
EPA 82606/62301)
11/11/16 20:16
MRK
1,2,3-Trichloropropane [96-1814]^
< 0.15
ug/L
1
0.15
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
1,2,4-Trichlorobenzene[120-82-1]^
< 0.097
ug/L
1
0.097
0.50
61<11027
EPA 8260B/62301)
11/11/16 20:16
MRK
1,2,4-Trimethylbenzene[95-63-6]^
< 0.067
ug/L
1
0.067
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:16
MRK
1,2-Dibromo-3-chloropropane [96-12-8]^
< 0.48
ug/L
1
0.48
0.50
6KII027
EPA 8260B/6230D
11/11/16 20:16
MRK
1,2-Dibromoethane [106-93-4]^
< 0.27
ug/L
1
0.27
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
1,2-Dichlorobenzene[95-50-1]^
< 0.062
ug/L
1
0.062
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
1,2-Dichloroethane[107-06-2]^
< 0.082
ug/L
1
0.082
0.50
61<11027
EPA 82606/62301)
11/11/16 20:16
MRK
1,2-Dichloropropane[78-87-5]^
< 0.098
ug/L
1
0.098
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
1,3,5-Trimethylbenzene [108-67-8]^
< 0.10
ug/L
1
0.10
0.50
61<11027
EPA 8260B/62301)
11/11/16 20:16
MRK
1,3-Dichlorobenzene[541-73-1]^
< 0.092
ug/L
1
0.092
0.50
61<11027
EPA 8260B/62301)
11/11/16 20:16
MRK
1,3-Dichloropropane[142-28-9]^
< 0.15
ug/L
1
0.15
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
1,4 -Dichlorobenzene [106-46-7]^
< 0.10
ug/L
1
0.10
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
2,2-Dichloropropane[594-20-7]^
< 0.12
ug/L
1
0.12
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
2-Chlorotoluene [95-49-8]^
< 0.10
ug/L
1
0.10
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
4-Chlorotoluene [106-43-4]^
< 0.10
ug/L
1
0.10
0.50
61<11027
EPA 82606/62301)
11/11/16 20:16
MRK
4-Isopropyltoluene [99-87-6]^
< 0.066
ug/L
1
0.066
0.50
61<11027
EPA 82606/62301)
11/11/16 20:16
MRK
Benzene [71-43-2]A
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:16
MRK
Bromobenzene[108-86-1]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:16
MRK
Bromochloromethane [74-97-5]^
< 0.11
ug/L
1
0.11
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
Bromodichloromethane [75-27-4]^
< 0.010
ug/L
1
0.010
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
Bromoform [75-25-2]^
< 0.20
ug/L
1
0.20
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
Bromomethane[74-83-9]^
< 0.28
ug/L
1
0.28
0.50
6KII027
EPA 8260B/6230D
11/11/16 20:16
MRK
Carbon Tetrachloride [56-23-5]A
< 0.082
ug/L
1
0.082
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
Chlorobenzene[108-90-7]^
< 0.069
ug/L
1
0.069
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:16
MRK
Chloroethane [75-00-3]^
< 0.18
ug/L
1
0.18
0.50
6KII027
EPA 8260B/6230D
11/11/16 20:16
MRK
Chloroform [67-66-3]^
< 0.083
ug/L
1
0.083
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
Chloromethane [74-87-3]A
< 0.050
ug/L
1
0.050
0.50
61<11027
EPA 82606/62301)
11/11/16 20:16
MRK
cis-1,2-Dichloroethene[156-59-2]^
< 0.075
ug/L
1
0.075
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:16
MRK
cis-1,3-Dichloropropene [10061-01-5]^
< 0.073
ug/L
1
0.073
0.50
6K11027
EPA 82606/62301)
11/11/16 20:16
MRK
Dibromochloromethane [124-48-1]^
< 0.067
ug/L
1
0.067
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
Dibromomethane [74-95-3]^
< 0.13
ug/L
1
0.13
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
Dichlorodifluoromethane [75-71-8]^
< 0.091
ug/L
1
0.091
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:16
MRK
Ethylbenzene [100-41-4]^
< 0.10
ug/L
1
0.10
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
Hexachlorobutadiene[87-68-3]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 82608/62301)
11/11/16 20:16
MRK
Isopropyl Ether [108-20-3]A
< 0.20
ug/L
1
0.20
0.50
61<11027
EPA 8260B/6230D
11/11/16 20:16
MRK
Isopropylbenzene[98-82-8]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 82606/62301)
11/11/16 20:16
MRK
m,p-Xylenes [108-38-3/106-42-3]^
< 0.18
ug/L
1
0.18
0.50
61<11027
EPA 82606/62301)
11/11/16 20:16
MRK
Methylene Chloride [75-09-2]^
< 0.070
ug/L
1
0.070
0.50
61<11027
EPA 82606/62301)
11/11/16 20:16
MRK
Methyl-tert-Butyl Ether [1634-04-4]A
< 0.12
ug/L
1
0.12
0.50
6K11027
EPA 82606/62301)
11/11/16 20:16
MRK
FINAL
This report relates only to the sample as received by the laboratory,
and may only be reproduced
in full.
Page 23 Of 40
L-

cc==
www.encolabs.com
ANALYTICAL RESULTS
Description: SMW-21 Lab Sample ID: CZ15249-09 Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 10:50 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:John Sherrill
Surrogates
(Volatile Organic Compounds
by GCMS
Spike Lv/
o Rec
% Rec Limits
Batch Method
Ana/ ed
.9y
Notes
4-8romotluorobenzene
49
1
^ - ENCO Cary certified analyte [NC 5911
98%
53-136
6K11027 EPA 82608/62306
11/11/16 20:16
MRK
Dibromofluoromethane
52
1
50.0
104%
Analyte [CAS Numberl
Results Flag
Units
DF
MDL
POLL
Batch
1
Method
Analyzed
By Notes
Naphthalene [91-20-3]^
< 0.086
ug/L
1
0.086
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:16
MRK
n -Butyl Benzene [104-51-8]^
< 0.074
ug/L
1
0.074
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:16
MRK
n -Propyl Benzene (103-65-11A
< 0.073
ug/L
1
0.073
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:16
MRK
o-Xylene[95-47-6]^
< 0.088
ug/L
1
0.088
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:16
MRK
sec-Butylbenzene[135-98-8]^
< 0.053
ug/L
1
0.053
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:16
MRK
Styrene [100-42-5]^
< 0.082
ug/L
1
0.082
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:16
MRK
tert-Butylbenzene[98-06-6]^
< 0.094
ug/L
1
0.094
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:16
MRK
Tetrachlorcethene [127-18-4]^
< 0.099
ug/L
1
0.099
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:16
MRK
Toluene [108-88-3]A
< 0.053
ug/L
1
0.053
0.50
61<11027
EPA
8260B/6230D
11/11/16
20:16
MRK
trans-1,2-Dichloroethene[156-60-5]^
< 0.11
ug/L
1
0.11
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:16
MRK
trans-1,3-Dichloropropene [10061-02-6]^
< 0.080
ug/L
1
0.080
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:16
MRK
Trichloroethene [79-01-6]A
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:16
MRK
Trichlorofluoromethane [75-69-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:16
MRK
Vinyl chloride [75-01-4]^
< 0.083
ug/L
1
0.083
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:16
MRK
Xylenes (Total)[1330-20-7]^
< 0.22
ug/L
1
0.22
0.50
61<11027
EPA
8260B/6230D
11/11/16
20:16
MRK
Surrogates
Resu/
DF
Spike Lv/
o Rec
% Rec Limits
Batch Method
Ana/ ed
.9y
Notes
4-8romotluorobenzene
49
1
50.0
98%
53-136
6K11027 EPA 82608/62306
11/11/16 20:16
MRK
Dibromofluoromethane
52
1
50.0
104%
67-129
6KII027 EPA 82608/62306
1111111620:16
MRK
Toluene -d8
50
1
50.0
101%
59-134
6K11027 EPA 82608/62306
11/11/16 20:16
MRK
Classical Chemistry Parameters
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Numberl
Results
Flag
Units
DF
MDL POLL
Batch Method
Analyzed
By
Notes
Ammonia as N [7664-41-7]^
0.081
J
mg/L
1
0.045 0.10
61<15006 EPA 350.1
11/15/16 11:27
JU
Chloride [16887-00-6]^
84
mg/L
1
1.9 5.0
GK16004 SM 4500CIE-1997
11/16/16 09:59
JU
QB -01
Nitrate as N [14797-55-8]^
< 0.025
mg/L
1
0.025 0.10
61<21022 EPA 353.2
11/21/16 11:03
JU
Nitrate/Nitrite as N^
< 0.041
mg/L
1
0.041 0.10
61<18005 EPA 353.2
11/18/16 12:04
JU
Nitrite as N [14797-65-0]^
0.057
J
mg/L
1
0.017 0.10
6KO9041 EPA 353.2
11/09/16 15:55
JU
Orthophosphate as P [1426-54-42]^
0.20
J
mg/L
1
0.16 0.50
6KO9043 EPA 365.1
11/09/16 16:27
JU
Total Dissolved Solids^
380
mg/L
1
50 50
61<10004 SM 254OC-1997
11/10/16 15:00
MMR
Classical Chemistry Parameters
^ - ENCO Orlando certified analyte [NC 4241
Analyte (CAS Numberl
Results
Flag
Units
DF
MDL PPL
Batch Method
Analyzed
By
Notes
Total Organic Carbon^
4.2
mg/L
1
0.34 1.0
61<16003 SM 531OB-2000
11/16/16 17:30
RSA
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 24 Of 4O

Description: SCMS
ANALYTICAL RESULTS
Lab Sample ID: CZ15249-10
Matrix: Ground Water Sampled: 11/09/16 10:35
Project: GW/SW Monitoring -Annual Sampled By: John Sherrill
www.encolabs.com
Received: 11/09/16 12:20
Work Order: CZ15249
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 25 Of 40
(Volatile Organic Compounds by GCMS
^ - ENCO O wy certified analyte [NC 5911
Analyte FCAS Numberl
Results Flaa
Units
DF
MDL
POLL
Batch
Method
Analyzed
_By Notes
1,1,1,2 -Tetrachloroethane [630-20-6]^
< 0.091
ug/L
1
0.091
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,1,1 -Trichloroethane [71-55-6]A
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,1,2,2 -Tetrachloroethane [79-34-5]^
< 0.085
ug/L
1
0.085
0.50
6K11027
EPA 82606/62301)
11/11/16 20:45
MRK
1,1,2 -Trichloroethane [79-00-5]^
< 0.068
ug/L
1
0.068
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,1-Dichloroethane[75-34-3]^
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,1-Dichloroethene[75-35-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,1-Dichloropropene[563-58-61^
< 0.063
ug/L
1
0.063
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,2,3-Trichlorobenzene[87-61-6]^
< 0.25
ug/L
1
0.25
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,2,3-Trichloropropane [96-18-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,2,4-Trichlorobenzene[120-82-1]^
< 0.097
ug/L
1
0.097
0.50
61(11027
EPA 8260B/62301)
11/11/16 20:45
MRK
1,2,4-Trimethylbenzene [95-63-6]^
< 0.067
ug/L
1
0.067
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,2-Dibromo-3-chloropropane [96-12-81^
< 0.48
ug/L
1
0.48
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,2-Dibromoethane[106-93-4]^
< 0.27
ug/L
1
0.27
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,2 -Dichlorobenzene [95-50-1]A
< 0.062
ug/L
1
0.062
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,2-Dichloroethane[107-06-2]^
< 0.082
ug/L
1
0.082
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,2-Dichloropropane[78-87-5]^
< 0.098
ug/L
1
0.098
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,3,5-Trimethylbenzene [108-67-8]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 82606/62301)
11/11/16 20:45
MRK
1,3 -Dichlorobenzene [541-73-11A
< 0.092
ug/L
1
0.092
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,3-Dichloropropane[142-28-9]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
1,4 -Dichlorobenzene [106-46-7]A
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
2,2-Dichloropropane[594-20-7]^
< 0.12
ug/L
1
0.12
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
2-Chlorotoluene [95-49-8]^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
4-Chlorotoluene [106-43-4]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
4-Isopropyltoluene [99-87-6]^
2.1
ug/L
1
0.066
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
Benzene [71-43-2]A
< 0.050
ug/L
1
0.050
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
Bromobenzene[108-86-1]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
Bromochloromethane [74-97-5]^
< 0.11
ug/L
1
0.11
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
Bromodichloromethane [75-27-4]^
< 0.010
ug/L
1
0.010
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
Bromoform [75-25-2]^
< 0.20
ug/L
1
0.20
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
Bromomethane[74-83-9]^
< 0.28
ug/L
1
0.28
0.50
61(11027
EPA 8260B/62301)
11/11/16 20:45
MRK
Carbon Tetrachloride [56-23-51A
< 0.082
ug/L
1
0.082
0.50
6KII027
EPA 8260B/62301)
11/11/16 20:45
MRK
Chlorobenzene [108-90-7]^
< 0.069
ug/L
1
0.069
0.50
61(11027
EPA 82608/62301)
11/11/16 20:45
MRK
Chloroethane [75-00-3]1
< 0.18
ug/L
1
0.18
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
Chloroform [67-66-3]^
< 0.083
ug/L
1
0.083
0.50
6KII027
EPA 8260B/6230D
11/11/16 20:45
MRK
Chloromethane [74-87-3]A
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
cis-1,2-Dichloroethene[156-59-2]^
< 0.075
ug/L
1
0.075
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
cis-1,3-Dichloropropene[10061-01-5]^
< 0.073
ug/L
1
0.073
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
Dibromochloromethane [124-48-11^
< 0.067
ug/L
1
0.067
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
Dibromomethane[74-95-3]^
< 0.13
ug/L
1
0.13
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
Dichlorodifluoromethane [75-71-8]A
< 0.091
ug/L
1
0.091
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
Ethylbenzene[100-41-4]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
Hexachlorobutadiene [87-68-3]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
Isopropyl Ether [108-20-3]A
< 0.20
ug/L
1
0.20
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
Isopropylbenzene[98-82-8]^
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/6230D
11/11/16 20:45
MRK
m,p-Xylenes[108-38-3/106-42-3]^
< 0.18
ug/L
1
0.18
0.50
61(11027
EPA 82606/62301)
11/11/16 20:45
MRK
Methylene Chloride [75-09-2]^
< 0.070
ug/L
1
0.070
0.50
61(11027
EPA 8260B/6230D
11/11/16 20:45
MRK
Methyl-tert-Butyl Ether [1634-04-4]A
< 0.12
ug/L
1
0.12
0.50
6KII027
EPA 8260B/62301)
11/11/16 20:45
MRK
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 25 Of 40

www.encolabs.com
ANALYTICAL RESULTS
Description: SCMS Lab Sample ID:CZ15249-10 Received: 11/09/16 12:20
Matrix: Ground Water Sampled: 11/09/16 10:35 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:John Sherrill
Surrogates Resu/ts
Idolatile Organic Compounds
by GCMS
%Rec
% Rec Limits
Batch Meth
Anal ed
" Notes
4-Bromofluorobenzene 49
1
50.0
98%
53-136
^ - ENCO Cary certfied analyte [NC 591J
1111111620:45
MRK
Dibromofluoromethane 53
1
50.0
105%
67-129
6K11027 EPA 826OB16230L
1111111620:45
MRK
Toluene -d8 51
Analyte ICAS Numberl
Results Flaa
Units
DF
MDL
POLL
Batch
Ju
Method
Analyzed
Notes
Naphthalene [91-20-3]^
< 0.086
ug/L
1
0.086
0.50
61(11027
EPA
8260B/6230D
11/11/16
20:45
MRK
n -Butyl Benzene [104-51-8]^
< 0.074
ug/L
1
0.074
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:45
MRK
n -Propyl Benzene [103-65-1]A
< 0.073
ug/L
1
0.073
0.50
61(11027
EPA
8260B/6230D
11/11/16
20:45
MRK
o -Xylene [95-47-6]^
< 0.088
ug/L
1
0.088
0.50
61(11027
EPA
8260B/6230D
11/11/16
20:45
MRK
sec-Butylbenzene[135-98-S]^
< 0.053
ug/L
1
0.053
0.50
61(11027
EPA
8260B/6230D
11/11/16
20:45
MRK
Styrene[100-42-5]^
< 0.082
ug/L
1
0.082
0.50
61(11027
EPA
8260B/6230D
11/11/16
20:45
MRK
tert-Butylbenzene [98-06-6]^
< 0.094
ug/L
1
0.094
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:45
MRK
Tetrachloroethene[127-18-4]^
< 0.099
ug/L
1
0.099
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:45
MRK
Toluene [108-88-3]^
2.0
ug/L
1
0.053
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:45
MRK
trans-1,2-Dichloroethene [156-60-5]^
< 0.11
ug/L
1
0.11
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:45
MRK
trans-1,3-Dichloropropene[10061-02-6]^
< 0.080
ug/L
1
0.080
0.50
6K11027
EPA
8260B/6230D
11/11/16
20:45
MRK
Trichloroethene [79-01-61^
< 0.13
ug/L
1
0.13
0.50
61(11027
EPA
8260B/6230D
11/11/16
20:45
MRK
Trichlorofluoromethane [75-69-4]A
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA
8260B/6230D
11/11/16
20:45
MRK
Vinyl chloride [75-01-4]^
< 0.083
ug/L
1
0.083
0.50
61(11027
EPA
8260B/6230D
11/11/16
20:45
MRK
Xylenes (Total) [1330-20-7]^
< 0.22
ug/L
1
0.22
0.50
61(11027
EPA
8260B/6230D
11/11/16
20:45
MRK
Surrogates Resu/ts
DF
4Rzft L v/
%Rec
% Rec Limits
Batch Meth
Anal ed
" Notes
4-Bromofluorobenzene 49
1
50.0
98%
53-136
6K11027 EPA 826OB16230L
1111111620:45
MRK
Dibromofluoromethane 53
1
50.0
105%
67-129
6K11027 EPA 826OB16230L
1111111620:45
MRK
Toluene -d8 51
1
50.0
102 %
59-134
6K11027 EPA 826OB16230L
1111111620:45
MRK
Ju
Classical Chemistry Parameters
14
mg/L
1
1.9
5.0
6K16004
^ - ENCO Cary certified analyte [NC 591]
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
POL,
Batch
Method
Analyzed
py Notes
Ammonia as N [7664-41-7]1
9.7
D
mg/L
10
0.45
1.0
6K15006
EPA 350.1
11/15/16 13:19
Ju
Chloride [16887-00-6]^
14
mg/L
1
1.9
5.0
6K16004
SM 4500CIE-1997
11/16/16 10:00
Ju 3-01
Nitrate as N [14797-55-8]^
< 0.025
mg/L
1
0.025
0.10
61(21022
EPA 353.2
11/21/16 11:03
Ju
Nitrate/Nitrite as N^
< 0.041
mg/L
1
0.041
0.10
6K18005
EPA 353.2
11/18/16 12:06
Ju
Nitrite as N [14797-65-0]^
< 0.017
mg/L
1
0.017
0.10
6KO9041
EPA 353.2
11/09/16 15:56
Ju
Orthophosphate as P [1426-54-42]^
< 0.16
mg/L
1
0.16
0.50
6KO9043
EPA 365.1
11/09/16 16:28
Ju
Total Dissolved Solids^
170
mg/L
1
50
50
61(10004
SM 254OC-1997
11/10/16 15:00
MMR
Classical Chemistry Parameters
^ - ENCO Orlando certified analyte [NC 4241
Analyte rCAS Numberl
Results
Flag
Units
DF
MDL
PPL
Batch
Method
Analyzed
By Notes
Total Organic Carbon^
48
mg/L
1
0.34
1.0
6K16003
SM 53108-2000
11/16/16 17:30
RSA
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 26 Of 4O

eco
www.encolabs.com
ANALYTICAL RESULTS
Description: Trip Blank Lab Sample ID:CZ15249-11
Received: 11/09/16 12:20
Matrix: Surface Water Sampled: 11/09/16 09:35
Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:John Sherrill
^ - ENCO Cary certified analyte [NC 591]
(Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Analyte fCAS Numberl
Results Flan
Units
DF
MDL
P L
Batch
Method
Analyzed
AM Notes
1,1,1,2 -Tetrachloroethane (630-20-6]^
< 0.091
ug/L
1
0.091
0.50
6K11027
EPA 82606/62301)
11/11/16 21:15
MRK
1,1,1 -Trichloroethane [71-55-6]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 82606/62301)
11/11/16 21:15
MRK
1,1,2,2 -Tetrachloroethane [79-34-5]^
< 0.085
ug/L
1
0.085
0.50
6K11027
EPA 8260B/6230D
11/11/16 21:15
MRK
1,1,2 -Trichloroethane [79-00-5]^
< 0.068
ug/L
1
0.068
0.50
6K11027
EPA 82606/62301)
11/11/16 21:15
MRK
1,1-Dichloroethane [75-34-3]^
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 82606/62301)
11/11/16 21:15
MRK
1,1-Dichloroethene[75-35-4]^
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 8260B/62301)
11/11/16 21:15
MRK
1,1-Dichloropropene [563-58-6]^
< 0.063
ug/L
1
0.063
0.50
61(11027
EPA 82606/62301)
11/11/16 21:15
MRK
1,2,3-Trichlorobenzene [87-61-6]^
< 0.25
ug/L
1
0.25
0.50
6K11027
EPA 82606/62301)
11/11/16 21:15
MRK
1,2,3-Trichloropropane [96-18-4]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 82606/62301)
11/11/16 21:15
MRK
1,2,4-Trichlorobenzene[120-82-1]^
< 0.097
ug/L
1
0.097
0.50
6K11027
EPA 8260B/6230D
11/11/16 21:15
MRK
1,2,4-Trimethylbenzene [95-63-6]^
< 0.067
ug/L
1
0.067
0.50
6K11027
EPA 8260B/62301)
11/11/16 21:15
MRK
1,2-Dibromo-3-chloropropane [96-12-8]^
< 0.48
ug/L
1
0.48
0.50
61(11027
EPA 8260B/62301)
11/11/16 21:15
MRK
1,2-Dibromoethane [106-93-4]^
< 0.27
ug/L
1
0.27
0.50
61<1 1027
EPA 8260B/6230D
11/11/16 21:15
MRK
1,2 -Dichlorobenzene [95-50-1]^
< 0.062
ug/L
1
0.062
0.50
61<1 1027
EPA 8260B/6230D
11/11/16 21:15
MRK
1,2-Dichloroethane[107-06-2]^
< 0.082
ug/L
1
0.082
0.50
61(11027
EPA 8260B/6230D
11/11/16 21:15
MRK
1,2-Dichloropropane[78-87-5]^
< 0.098
ug/L
1
0.098
0.50
61(11027
EPA 8260B16230D
11/11/16 21:15
MRK
1,3,5-Trimethylbenzene [108-67-8]^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 8260B/6230D
11/11/16 21:15
MRK
1,3 -Dichlorobenzene [541-73-1]A
< 0.092
ug/L
1
0.092
0.50
61(11027
EPA 8260B/6230D
11/11/16 21:15
MRK
1,3-Dichloropropane[142-28-9]^
< 0.15
ug/L
1
0.15
0.50
6K11027
EPA 8260B/6230D
11/11/16 21:15
MRK
1,4 -Dichlorobenzene [106-46-7]^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 8260B/6230D
11/11/16 21:15
MRK
2,2-Dichloropropane[594-20-7]^
< 0.12
ug/L
1
0.12
0.50
6K11027
EPA 8260B/6230D
11/11/16 21:15
MRK
2-Chlorotoluene[95-49-8]^
< 0.10
ug/L
1
0.10
0.50
61(11027
EPA 82606/62301)
11/11/16 21:15
MRK
4-Chlorotoluene [106-43-4]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 82606/62301)
11/11/16 21:15
MRK
4-Isopropyltoluene [99-87-6]^
< 0.066
ug/L
1
0.066
0.50
6K11027
EPA 8260B/62301)
11/11/16 21:15
MRK
Benzene [71-43-2]^
< 0.050
ug/L
1
0.050
0.50
6K11027
EPA 82606/62301)
11/11/16 21:15
MRK
Bromobenzene[108-86-1]^
< 0.13
ug/L
1
0.13
0.50
61(11027
EPA 82606/62301)
11/11/16 21:15
MRK
Bromochloromethane [74-97-5]^
< 0.11
ug/L
1
0.11
0.50
61(11027
EPA 82606/62301)
11/11/16 21:15
MRK
Bromodichloromethane [75-27-4]^
< 0.010
ug/L
1
0.010
0.50
6K11027
EPA 82606/62301)
11/11/16 21:15
MRK
Bromoform [75-25-2]^
< 0.20
ug/L
1
0.20
0.50
6K11027
EPA 8260B/6230D
11/11/16 21:15
MRK
Bromomethane [74-83-9]^
< 0.28
ug/L
1
0.28
0.50
61(11027
EPA 8260B/62301)
11/11/16 21:15
MRK
Carbon Tetrachloride [56-23-5]^
< 0.082
ug/L
1
0.082
0.50
61(11027
EPA 8260B/62301)
11/11/16 21:15
MRK
Chlorobenzene[108-90-7]^
< 0.069
ug/L
1
0.069
0.50
61(11027
EPA 82608/62301)
11/11/16 21:15
MRK
Chloroethane [75-00-3]^
< 0.18
ug/L
1
0.18
0.50
61(11027
EPA 8260B/6230D
11/11/16 21:15
MRK
Chloroform [67-66-3]^
< 0.083
ug/L
1
0.083
0.50
61(11027
EPA 82606/62301)
11/11/16 21:15
MRK
Chloromethane (74-87-3]A
< 0.050
ug/L
1
0.050
0.50
61(11027
EPA 8260B/6230D
11/11/16 21:15
MRK
cis-1,2-Dichloroethene [156-59-2]^
< 0.075
ug/L
1
0.075
0.50
61(11027
EPA 82606/62301)
11/11/16 21:15
MRK
cis-1,3-Dichloropropene [10061-01-5]^
< 0.073
ug/L
1
0.073
0.50
61(11027
EPA 82606/62301)
11/11/16 21:15
MRK
Dibromochloromethane[124-48-1]^
< 0.067
ug/L
1
0.067
0.50
61(11027
EPA 8260B/6230D
11/11/16 21:15
MRK
Dibromomethane[74-95-3]^
< 0.13
ug/L
1
0.13
0.50
61(11027
EPA 8260B/6230D
11/11/16 21:15
MRK
Dichlorodifluoromethane [75-71-B]^
< 0.091
ug/L
1
0.091
0.50
61(11027
EPA 8260B/6230D
11/11/16 21:15
MRK
Ethylbenzene[100-41-4]^
< 0.10
ug/L
1
0.10
0.50
6K11027
EPA 82606/62301)
11/11/16 21:15
MRK
Hexachlorobutadiene[87-68-3]^
< 0.15
ug/L
1
0.15
0.50
61(11027
EPA 82606/62301)
11/11/16 21:15
MRK
Isopropyl Ether [108-20-3]^
< 0.20
ug/L
1
0.20
0.50
6K11027
EPA 8260B/6230D
11/11/16 21:15
MRK
Isopropylbenzene[98-82-8]^
< 0.13
ug/L
1
0.13
0.50
61(11027
EPA 8260B/6230D
11/11/16 21:15
MRK
m,p-Xylenes[108-38-3/106-42-3]^
< 0.18
ug/L
1
0.18
0.50
61(11027
EPA 8260B/62301)
11/11/16 21:15
MRK
Methylene Chloride [75-09-2]^
< 0.070
ug/L
1
0.070
0.50
6K11027
EPA 8260B/62301)
11/11/16 21:15
MRK
Methyl-tert-Butyl Ether [1634-04-4]A
< 0.12
ug/L
1
0.12
0.50
61(11027
EPA 8260B/62301)
11/11/16 21:15
MRK
FINAL
This report relates only to the sample as received by the laboratory,
and may only be reproduced in full.
I Page 27 Of 4O

CC -==co
www.encolabs.com
ANALYTICAL RESULTS
Description: Trip Blank Lab Sample ID: CZ15249-11 Received: 11/09/16 12:20
Matrix: Surface Water Sampled: 11/09/16 09:35 Work Order: CZ15249
Project: GW/SW Monitoring -Annual Sampled By:]ohn Sherrill
Surrogates
(Volatile Organic Compounds by GCMS
OF
Spike L v/
% Rec
% Rec Limits
Batch Meth
Ana/vied
By Notes
4-Bromofluorobenzene
^ - ENCO Cary certified analyte [NC 5911
1
50.0
98%
53-136
6K11027 EPA 8260B/6230G
11/11/16 21:15
MRK
Dibromofluoromethane
53
Analyte rCAS Numberl
Results Flag
Units
DF
MDL
PQL
Batch
Method
Analyzed
By Notes
Naphthalene [91-20-3]^
< 0.086
ug/L
1
0.086
0.50
6K11027
EPA 8260B/6230D
11/11/16 21:15
MRK
n -Butyl Benzene [104-51-8]^
< 0.074
ug/L
1
0.074
0.50
61<11027
EPA 8260B/6230D
11/11/16 21:15
MRK
n -Propyl Benzene [103-65-11A
< 0.073
ug/L
1
0.073
0.50
61<11027
EPA 8260B/6230D
11/11/16 21:15
MRK
o -Xylene [95-47-6]^
< 0.088
ug/L
1
0.088
0.50
61<11027
EPA 8260B/6230D
11/11/16 21:15
MRK
sec-Butylbenzene[135-98-8]^
< 0.053
ug/L
1
0.053
0.50
61<11027
EPA 8260B/6230D
11/11/16 21:15
MRK
Styrene [100-42-5]A
< 0.082
ug/L
1
0.082
0.50
6K11027
EPA 8260B/6230D
11/11/16 21:15
MRK
tert-Butylbenzene [98-06-6]^
< 0.094
ug/L
1
0.094
0.50
61<11027
EPA 8260B/6230D
11/11/16 21:15
MRK
Tetrachloroethene[127-18-4]^
< 0.099
ug/L
1
0.099
0.50
6K11027
EPA 8260B/6230D
11/11/16 21:15
MRK
Toluene [108-88-3]^
< 0.053
ug/L
1
0.053
0.50
6K11027
EPA 8260B/6230D
11/11/16 21:15
MRK
trans-1,2-Dichloroethene [156-60-5]^
< 0.11
ug/L
1
0.11
0.50
6K11027
EPA 8260B/6230D
11/11/16 21:15
MRK
trans-1,3-Dichloropropene [10061-02-6]^
< 0.080
ug/L
1
0.080
0.50
6K11027
EPA 8260B/6230D
11/11/16 21:15
MRK
Trichloroethene (79-01-6]A
< 0.13
ug/L
1
0.13
0.50
6K11027
EPA 8260B/6230D
11/11/16 21:15
MRK
Trichlorofluoromethane [75-69-4]^
< 0.15
ug/L
1
0.15
0.50
61<11027
EPA 8260B/6230D
11/11/16 21:15
MRK
Vinyl chloride [75-01-4]A
< 0.083
ug/L
1
0.083
0.50
6K11027
EPA 8260B/6230D
11/11/16 21:15
MRK
Xylenes (Total)[1330-20-7]^
< 0.22
ug/L
1
0.22
0.50
61<11027
EPA 8260B/6230D
11/11/16 21:15
MRK
Surrogates
Resu/ks
OF
Spike L v/
% Rec
% Rec Limits
Batch Meth
Ana/vied
By Notes
4-Bromofluorobenzene
49
1
50.0
98%
53-136
6K11027 EPA 8260B/6230G
11/11/16 21:15
MRK
Dibromofluoromethane
53
1
50.0
107%
67-129
6K11027 EPA 826OB16230C
11/11/16 21:15
MRK
Toluene -d8
50
1
50.0
101%
59-134
6K11027 EPA 826OB16230C
11/11/16 21:15
MRK
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 28 of 40

eco
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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 6K11027 - EPA 5030B MS
Blank (6](11027-BLK3) Prepared: 11/11/2016 12:01 Analyzed: 11/11/2016 15:53
Analyte
R sul
Flea
PPI
Units
1,1,1,2 -Tetrachloroethane
0.091
U
0.50
ug/L
1,1,1 -Trichloroethane
0.15
U
0.50
ug/L
1,1,2,2 -Tetrachloroethane
0.085
U
0.50
ug/L
1,1,2 -Trichloroethane
0.068
U
0.50
ug/L
1,1-Dichloroethane
0.050
U
0.50
ug/L
1,1-Dichloroethene
0.15
U
0.50
ug/L
1,1-Dichloropropene
0.063
U
0.50
ug/L
1,2,3-Trichlorobenzene
0.25
U
0.50
ug/L
1,2,3-Trichloropropane
0.15
U
0.50
ug/L
1,2,4-Trichlorobenzene
0.097
U
0.50
ug/L
1,2,4-Trimethylbenzene
0.067
U
0.50
ug/L
1,2-Dibromo-3-chloropropane
0.48
U
0.50
ug/L
1,2-Dibromoethane
0.27
U
0.50
ug/L
1,2 -Dichlorobenzene
0.062
U
0.50
ug/L
1,2-Dichloroethane
0.082
U
0.50
ug/L
1,2-Dichloropropane
0.098
U
0.50
ug/L
1,3,5-Trimethylbenzene
0.10
U
0.50
ug/L
1,3 -Dichlorobenzene
0.092
U
0.50
ug/L
1,3-Dichloropropane
0.15
U
0.50
ug/L
1,4 -Dichlorobenzene
0.10
U
0.50
ug/L
2,2-Dichloropropane
0.12
U
0.50
ug/L
2-Chlorotoluene
0.10
U
0.50
ug/L
4-Chlorotoluene
0.10
U
0.50
ug/L
4-Isopropyltoluene
0.066
U
0.50
ug/L
Benzene
0.050
U
0.50
ug/L
Bromobenzene
0.13
U
0.50
ug/L
Bromochloromethane
0.11
U
0.50
ug/L
Bromodichloromethane
0.010
U
0.50
ug/L
Bromoform
0.20
U
0.50
ug/L
Bromomethane
0.28
U
0.50
ug/L
Carbon Tetrachloride
0.082
U
0.50
ug/L
Chlorobenzene
0.069
U
0.50
ug/L
Chloroethane
0.18
U
0.50
ug/L
Chloroform
0.083
U
0.50
ug/L
Chloromethane
0.050
U
0.50
ug/L
cis-1,2-Dichloroethene
0.075
U
0.50
ug/L
cis-1,3-Dichloropropene
0.073
U
0.50
ug/L
Dibromochloromethane
0.067
U
0.50
ug/L
Dibromomethane
0.13
U
0.50
ug/L
Dichlorodifluoromethane
0.091
U
0.50
ug/L
Ethylbenzene
0.10
U
0.50
ug/L
Hexachlorobutadiene
0.15
U
0.50
ug/L
Isopropyl Ether
0.20
U
0.50
ug/L
Isopropylbenzene
0.13
U
0.50
ug/L
m,p-Xylenes
0.18
U
0.50
ug/L
Methylene Chloride
0.070
U
0.50
ug/L
Methyl-tert-Butyl Ether
0.12
U
0.50
ug/L
Naphthalene
0.086
U
0.50
ug/L
n -Butyl Benzene
0.074
U
0.50
ug/L
Spike Source %REC RPD
Level Result %REC Limits RPD Limit Notes
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 29 of 40

Ce N0 Eo
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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 6K11027 - EPA 5030B MS - Continued
Blank (6K11027-BLK1) Continued Prepared: 11/11/2016 12:01 Analyzed: 11/11/2016 15:53
Spike
Source
%REC
RPD
Anal
Resul
Flan
POI.
Units
Level
Resul
%REC
Limits RPD
Lima Notes
n -Propyl Benzene
0.073
U
0.50
ug/L
o -Xylene
0.088
U
0.50
ug/L
sec-Butylbenzene
0.053
U
0.50
ug/L
Styrene
0.082
U
0.50
ug/L
tert-Butylbenzene
0.094
U
0.50
ug/L
Tetrachloroethene
0.099
U
0.50
ug/L
Toluene
0.053
U
0.50
ug/L
trans-1,2-Dichloroethene
0.11
U
0.50
ug/L
trans-1,3-Dichloropropene
0.080
U
0.50
ug/L
Trichloroethene
0.13
U
0.50
ug/L
Trichlorofluoromethane
0.15
U
0.50
ug/L
Vinyl chloride
0.083
U
0.50
ug/L
Xylenes (Total)
0.22
U
0.50
ug/L
4-Bromofluorobenzene
48
ug/L
50.0
96
53-136
D/bromofluoromethane
48
WIL
50.0
96
67-129
Toluene -d8
49
u91L
50.0
98
59-134
LCS (6K11027-BS1)
Prepared: 11/11/2016 12:01 Analyzed: 11/11/2016 13:56
Spike
Source
%REC
RPD
Analyte
Result
Flag
P91,
Units
Level
Result
%REC
Limits RPD
Limit Notes
1,1-Dichloroethene
18
0.50
ug/L
20.0
92
75-133
Benzene
19
0.50
ug/L
20.0
93
81-134
Chlorobenzene
19
0.50
ug/L
20.0
94
83-117
Toluene
19
0.50
ug/L
20.0
93
71-118
Trichloroethene
19
0.50
ug/L
20.0
93
74-119
4-Bromofluorobenzene
49
u91L
50.0
97
53-136
Dibromofluoromethane
48
u91L
50.0
96
67-129
Toluene -d8
49
u91L
50.0
98
59-134
Matrix Spike (6K11027-MS1)
Prepared: 11/11/2016 12:01 Analyzed: 11/11/2016 14:25
Source:CZ16791-08
Spike
Source
%REC
RPD
Analyte
B4.s01L
Flan
POL
Units
Level
Result
%REC
Limits RPD
Lima Notes
1,1-Dichloroethene
21
0.50
ug/L
20.0
0.15 U
106
75-133
Benzene
21
0.50
ug/L
20.0
0.050 U
105
81-134
Chlorobenzene
21
0.50
ug/L
20.0
0.069 U
104
83-117
Toluene
21
0.50
ug/L
20.0
0.053 U
105
71-118
Trichloroethene
21
0.50
ug/L
20.0
0.13 U
107
74-119
4-8romoduorobenzene
46
u9/L
50.0
97
53-136
Dibromofluoromethane
48
u9/L
50.0
95
67-129
Toluene -d8
49
u91L
50.0
98
59-134
Matrix Spike Dup (6K11027-MSD1)
Prepared: 11/11/2016 12:01 Analyzed: 11/11/2016 14:55
Source:CZ16791-08
Spike
Source
%REC
RPD
Analyte
Result
FFaa
POL
Units
Level
Result
%REC
Limits RPD
Limit Notes
1,1-Dichloroethene
20
0.50
ug/L
20.0
0.15 U
100
75-133 6
20
Benzene
20
0.50
ug/L
20.0
0.050 U
99
81-134 6
17
Chlorobenzene
20
0.50
ug/L
20.0
0.069 U
100
83-117 3
16
FINAL
This report relates only to the sample as received by the laboratory, and may only be
reproduced in
Rill.
Page 30 Of 4O

Ce VCO
Source: CZ15249-01
Analyte
Nitrite as N
Batch 6KO9043 - NO PREP
Result fag POL
0.94
0.10
Spike Source %REC RPD
Units Level Resu %REC Limits RPD Lima Notes
mg/L 1.00 0.017 U 94 90-110 3 10
Blank (6K09043-BLK1) Prepared: 11/09/2016 14:38 Analyzed: 11/09/2016 16:13
Spike Source %REC RPD
Analyte Result Flan PAL units Level Result %REC Limits RPD Limit Notes
Orthophosphate as P 0.16 U 0.50 mg/L
LCS (6K09043 -BSI) Prepared: 11/09/2016 14:38 Analyzed: 11/09/2016 16:10
Spike Source %REC RPD
Analvile Result flag Q Units Level Resu %REC Limitfi RPD Limit Notes
Orthophosphate as P 4.8 0.50 mg/L 5.00 97 90-110
LCS (6K09043-BS2) Prepared: 11/09/2016 14:38 Analyzed: 11/09/2016 16:31
Spike Source %REC RPD
Anal Resul Flag POL Units Level Result %REC Limits RPD Lima Notes
Orthophosphate as P 4.9 0.50 mg/L 5.00 97 90-110
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I I Page 31 Of 40
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RPD
QUALITY CONTROL DATA
POL
Volatile Organic Compounds by GCMS - Quality Control
Level Re u %REC Limits RPD
Limit Notes
Nitrite as N 1.0
0.10
mg/L
Batch 6K11027 - EPA 5030B MS - Continued
Matrix Spike (6K09041-MS1)
Prepared: 11/09/2016 14:37 Analyzed: 11/09/2016 15:41
Matrix Spike Dup (6K11027-MSD1) Continued
Source: CZ15249-01
Prepared: 11/11/2016 12:01 Analyzed: 11/11/2016 14:55
Source: CZ16791-08
Spike Source %REC
RPD
Analyte Result Flan
POL
Units
Spike Source %REC
RPD
Analyte Result Flag
P91
Units
Level Resul %REC Limits RPD
Limit Notes
Toluene 20
0.50
ug/L
20.0 0.053 U 101 71-118 3
17
Trichloroethene 20
0.50
ug/L
20.0 0.13 U 102 74-119 5
22
4-Bromofluorobenzene 49
u91L
50.0 98 53-136
Dibromofluoromethane 48
u91L
50.0 97 67-129
Toluene -d8 48
u9/L
50.0 97 59-134
Classical Chemistry Parameters - Quality Control
Batch 6KO9041- NO PREP
Blank (6K09041-BLKI)
Prepared: 11/09/2016 14:37 Analyzed: 11/09/2016 15:39
Spike Source %REC
RPD
Analyte Result Flag
POL
Units
Level Re ul %REC Limits RPD
Limit Notes
Nitrite as N 0.017 U
0.10
mg/L
LCS (6K09041-BS1)
Prepared: 11/09/2016 14:37 Analyzed: 11/09/2016 15:34
Source: CZ15249-01
Analyte
Nitrite as N
Batch 6KO9043 - NO PREP
Result fag POL
0.94
0.10
Spike Source %REC RPD
Units Level Resu %REC Limits RPD Lima Notes
mg/L 1.00 0.017 U 94 90-110 3 10
Blank (6K09043-BLK1) Prepared: 11/09/2016 14:38 Analyzed: 11/09/2016 16:13
Spike Source %REC RPD
Analyte Result Flan PAL units Level Result %REC Limits RPD Limit Notes
Orthophosphate as P 0.16 U 0.50 mg/L
LCS (6K09043 -BSI) Prepared: 11/09/2016 14:38 Analyzed: 11/09/2016 16:10
Spike Source %REC RPD
Analvile Result flag Q Units Level Resu %REC Limitfi RPD Limit Notes
Orthophosphate as P 4.8 0.50 mg/L 5.00 97 90-110
LCS (6K09043-BS2) Prepared: 11/09/2016 14:38 Analyzed: 11/09/2016 16:31
Spike Source %REC RPD
Anal Resul Flag POL Units Level Result %REC Limits RPD Lima Notes
Orthophosphate as P 4.9 0.50 mg/L 5.00 97 90-110
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I I Page 31 Of 40
Spike Source %REC
RPD
Anal Rssul Flag
POL
its
Level Re u %REC Limits RPD
Limit Notes
Nitrite as N 1.0
0.10
mg/L
1.00 101 90-110
Matrix Spike (6K09041-MS1)
Prepared: 11/09/2016 14:37 Analyzed: 11/09/2016 15:41
Source: CZ15249-01
Spike Source %REC
RPD
Analyte Result Flan
POL
Units
Level R sul %REC Limits RPD
kimft Notes
Nitrite as N 0.97
0.10
mg/L
1.00 0.017 U 97 90-110
Matrix Spike Dup (6K09041-MSDI)
Prepared: 11/09/2016 14:37 Analyzed: 11/09/2016 15:43
Source: CZ15249-01
Analyte
Nitrite as N
Batch 6KO9043 - NO PREP
Result fag POL
0.94
0.10
Spike Source %REC RPD
Units Level Resu %REC Limits RPD Lima Notes
mg/L 1.00 0.017 U 94 90-110 3 10
Blank (6K09043-BLK1) Prepared: 11/09/2016 14:38 Analyzed: 11/09/2016 16:13
Spike Source %REC RPD
Analyte Result Flan PAL units Level Result %REC Limits RPD Limit Notes
Orthophosphate as P 0.16 U 0.50 mg/L
LCS (6K09043 -BSI) Prepared: 11/09/2016 14:38 Analyzed: 11/09/2016 16:10
Spike Source %REC RPD
Analvile Result flag Q Units Level Resu %REC Limitfi RPD Limit Notes
Orthophosphate as P 4.8 0.50 mg/L 5.00 97 90-110
LCS (6K09043-BS2) Prepared: 11/09/2016 14:38 Analyzed: 11/09/2016 16:31
Spike Source %REC RPD
Anal Resul Flag POL Units Level Result %REC Limits RPD Lima Notes
Orthophosphate as P 4.9 0.50 mg/L 5.00 97 90-110
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I I Page 31 Of 40

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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 6KO9043 - NO PREP - Continued
Matrix Spike (6KO9043-MSI)
Prepared: 11/09/2016 14:38 Analyzed: 11/09/2016 16:14
Source: CZ15249-01
Spike Source %REC
RPD
Analyte
Re ul
flag
M
Units
Level Result %REC Limits RPD
Limit
Notes
Orthophosphate as P
1.9
0.50
mg/L
2.00 0.16 U 96 90-110
Matrix Spike Dup (6K09043-MSD1)
Prepared: 11/09/2016 14:38 Analyzed: 11/09/2016 16:17
Source: CZ15249-01
Spike Source %REC
RPD
Analyte
Result
Flan
POL
Units
Level Re u %REC Limits RPD
Lima
Notes
Orthophosphate as P
1.9
0.50
mg/L
2.00 0.16 U 96 90-110 0.2
10
Batch 6K10004 - NO PREP
Blank (6K30004-BLK1)
Prepared & Analyzed: 11/10/2016 15:00
Spike Source %REC
RPD
Analyte
ResinIlr
ao
POL
Units
Level Result %REC Limits RPD
Limit
o es
Total Dissolved Solids
So
U
50
mg/L
LCS (6K10004-BS1)
Prepared & Analyzed: 11/10/2016 15:00
Spike Source %REC
RPD
Analyte
ResuS
Flan
_POL
Units
Level Resul %REC Limits RPD
Limit
Notes
Total Dissolved Solids
950
50
mg/L
1000 95 90-110
Duplicate (61(10004-DUP1)
Prepared & Analyzed: 11/10/2016 15:00
Source: CZ15249-01
Spike Source %REC
RPD
Analyte
ResulFlaq
POL
Units
Level Re u %REC Limits RPD
Limit
Notes
Total Dissolved Solids
50
U
50
mg/L
50 U
20
Duplicate (6K10004-DUP2)
Prepared & Analyzed: 11/10/2016 15:00
Source: CZ15249-02
Spike Source %REC
RPD
Analyte
Resin
Flaa
PPI,
Units
Level Re ul %REC Limits RPD
Limit
Notes
Total Dissolved Solids
1200
50
mg/L
1300 3
20
Batch 6KIS006 - NO PREP
Blank (61(15006-BLK1)
Prepared: 11/15/2016 09:03 Analyzed: 11/15/2016 10:41
Spike Source %REC
RPD
Analyte
Resul
Flag
POL
Units
Level Result %REC Limits RPD
Limit
Notes
Ammonia as N
0.045
U
0.10
mg/L
LCS (6K15006-BS3)
Prepared: 11/15/2016 09:03 Analyzed: 11/15/2016 10:43
Spike Source %REC
RPD
Analyte
Result
Flan
POL
Units
Level Result %REC Limits RPD
Limit
Notes
Ammonia as N
1.0
0.10
mg/L
0.989 104 90-110
Matrix Spike (6K15006-MS1)
Prepared: 11/15/2016 09:03 Analyzed: 11/15/2016 10:45
Source: CZ15249-05
Spike Source %REC
RPD
Analyte
Resul
FFla_q
POL
Units
Level Resu %REC Limits RPD
Lima
Notes
Ammonia as N
0.37
0.10
mg/L
0.385 0.045 U 95 90-110
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 32 Of 4O

0VCO
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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 6KI5006 - NO PREP - Continued
Matrix Spike (6K15006-MS2)
Prepared: 11/15/2016 09:03 Analyzed: 11/15/2016 11:20
Source: CZ15249-06
Spike Source %REC
RPD
Analyte Result
Flan POL
Units
Level Result %REC Limits RPD
Lima Notes
Ammonia as N 0.37
0.10
mg/L
0.385 0.045 U 97 90-110
Ammonia as N
Matrix Spike Dup (6K15006-MSD1)
U
0.10
Prepared: 11/15/2016 09:03 Analyzed: 11/15/2016 10:49
Source: CZ15249-05
LCS (6K35007 -BSI)
Prepared: 11/15/2016 09:05 Analyzed: 11/15/2016 12:10
Spike Source %REC
RPD
Analyte Result
Flag P2
Units
Level Result %REC Limits RPD
Limit Notes
Ammonia as N 0.38
0.10
mg/L
0.385 0.045 U 99 90-110 4
10
Batch 6K25007 - NO PREP
POL
Units
Level Resul %REC Limits RPD
Lima
Blank (6K15007-BLK3)
Prepared: 11/15/2016 09:05 Analyzed: 11/15/2016 12:08
Spike Source %REC
RPD
Analyte
Result
Flan
POL
Units
Level Result %REC Limits RPD
Limit
Notes
Ammonia as N
0.045
U
0.10
mg/L
LCS (6K35007 -BSI)
Prepared: 11/15/2016 09:05 Analyzed: 11/15/2016 12:10
Spike Source %REC
RPD
Anal
su
Flao
POL
Units
Level Resul %REC Limits RPD
Lima
Notes
Ammonia as N
1.1
0.10
mg/L
0.989 107 90-110
Matrix Spike (6K35007-MS1)
Prepared: 11/15/2016 09:05 Analyzed: 11/15/2016 12:12
Source: CZ15246-01
Spike Source %REC
RPD
Anal
Resul
Flag
POL
Units
Level Resul %REC Limits RPD
Lima
Notes
Ammonia as N
1.9
0.10
mg/L
0.385 1.5 105 90-110
Matrix Spike (6K15007-MS2)
Prepared: 11/15/2016 09:05 Analyzed: 11/15/2016 12:21
Source: CZ15249-01
Spike Source %REC
RPD
ASI de
R_esul
Fag
POL
Units
Level Result %REC Limits RPD
Lima
Notes
Ammonia as N
0.39
0.10
mg/L
0.385 0.045 U 101 90-110
Matrix Spike Dup (6KI5007-MSDI)
Prepared: 11/15/2016 09:05 Analyzed: 11/15/2016 12:16
Source: CZ15246-01
Spike Source %REC
RPD
Analyte
Res_ul
Elm
E"
Units
Level Resu %REC Limits RPD
Limit
Notes
Ammonia as N
1.8
0.10
mg/L
0.385 1.5 85 90-110 4
10
QM -07
Batch 6KI6004 - NO PREP
Blank (6K16004-BLK1)
Prepared: 11/16/2016 08:00 Analyzed: 11/16/2016 09:49
Spike Source %REC
RPD
Anal
Resull
FLao
P2
Units
Level Result %REC Limits RPD
Limit
Notes
Chloride
2.8
3
5.0
mg/L
LCS (6K16004-BS1)
Prepared: 11/16/2016 08:00 Analyzed: 11/16/2016 09:50
Spike Source %REC
RPD
Analyte
Result
flag
POL
Units
Level Resu %REC Limits RPD
Limit
Notes
Chloride
98
5.0
mg/L
100 98 80-120
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 33 of 4O

a 1 0
�e®
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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 6K16004 - NO PREP - Continued
Duplicate (61(16004-DUPi)
Prepared: 11/16/2016 08:00 Analyzed: 11/16/2016 09:54
RPD
Source: CZ15249-03
Analyte
Resul
Flag
PSL
Units
Level Re u %REC Limits RPD
Limit
Notes
Chloride
90
Spike Source %REC
RPD
Anal
Resul
Flaaa
POL
Units
Level Result %REC Limits RPD
Mmit LimitNotes
Chloride
720
D
50
mg/L
710 2
10
Matrix Spike (6K16004-MS1)
Prepared: 11/16/2016 08:00 Analyzed: 11/16/2016 09:51
Source: CZ15249-02
Spike Source %REC
RPD
Analyte
Result
178_9
PSL
Units
Level Result %REC Limits RPD
Spike Source %REC
RPD
Anal 1(Le
Result
IPla4
PSL
Units
Level Result %REC Limits RPD
Limi Notes
Chloride
750
25
mg/L
200 580 90 80-120
Prepared: 11/16/2016 08:02 Analyzed: 11/16/2016 11:40
Matrix Spike Dup (6Kl60G4-MSD1)
Source: CZ15246-01
Prepared: 11/16/2016 08:00 Analyzed: 11/16/2016 09:53
Source: CZ15249-02
Spike Source %REC
RPD
Anal
Spike Source %REC
RPD
Analyte
ResulFa
Level Re u %REC Limits RPD
Q
Units
Level Result %REC Limits RPD
Limit Notes
Chloride
740
mg/L
25
mg/L
200 580 83 80-120 2
25
Batch OK16006 - NO PREP
Prepared: 11/16/2016 08:02 Analyzed: 11/16/2016 11:41
Blank (6K16006-BLK1)
Prepared: 11/16/2016 08:02 Analyzed: 11/16/2016 11:39
Spike Source %REC RPD
Analyte Result Elan PSL Units Level Result %REC Limits RPD Lima Notes
Chloride 1.9 U 5.0 mg/L
LCS (6K16006-BS1) Prepared: 11/16/2016 08:02 Analyzed: 11/16/2016 11:39
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 34 Of 4O
Spike Source %REC
RPD
Analyte
Resul
Flag
PSL
Units
Level Re u %REC Limits RPD
Limit
Notes
Chloride
90
5.0
mg/L
100 90 80-120
Duplicate (61(16006-DUP1)
Prepared: 11/16/2016 08:02 Analyzed: 11/16/2016 11:41
Source: CZ15249-01
Spike Source %REC
RPD
Analyte
Result
178_9
PSL
Units
Level Result %REC Limits RPD
MM11
Notes
Chloride
6.6
5.0
mg/L
7.1 9
10
Matrix Spike (6K16006-MS1)
Prepared: 11/16/2016 08:02 Analyzed: 11/16/2016 11:40
Source: CZ15246-01
Spike Source %REC
RPD
Anal
Result
flag
PPL
Units
Level Re u %REC Limits RPD
MMA
Notes
Chloride
180
10
mg/L
80.0 110 91 80-120
Matrix Spike Dup (6K16006-MSD3)
Prepared: 11/16/2016 08:02 Analyzed: 11/16/2016 11:41
Source: CZ15246-01
Spike Source %REC
RPD
Analyte
Result
Flaa
PSL
Units
Level Result %REC Limits RPD
Lima
Notes
Chloride
180
10
mg/L
80.0 110 90 80-120 0.3
25
Batch 6K18005 - NO PREP
Blank (6K18005-BLK1)
Prepared: 11/18/2016 08:21 Analyzed: 11/18/2016 11:42
Spike Source %REC
RPD
Anal
Result
flag
PPL
Units
Level Resu %REC Limits RPD
Limit
Notes
Nitrate/Nitrite as N
0.041
U
0.10
mg/L
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 34 Of 4O

6 1 h
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Batch 6K16003 - NO PREP
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 35 Of 4O
QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 6K18005 - NO PREP - Continued
LCS (6K18005-BS3)
Prepared: 11/18/2016 08:21 Analyzed: 11/18/2016 11:44
Spike Source %REC
RPD
An
a ulIF
a Ic
PQL
Units
Level Result %REC Limits RPD
Limit
Notes
Nitrate/Nitrite as N
1.2
0.10
mg/L
1.25 93 90-110
Matrix Spike (61(18005-MS1)
Prepared: 11/18/2016 08:21 Analyzed: 11/18/2016 11:46
Source: CZ15249-04
Spike Source %REC
RPD
Analyte
Result
F1a9
POLL
Units
Level Resul %REC Limits RPD
Limit
Notes
Nitrate/Nitrite as N
0.52
0.10
mg/L
0.513 0.041 U 102 90-110
0
Matrix Spike (61(38005-MS2)
Prepared: 11/18/2016 08:21 Analyzed: 11/18/2016 11:55
Source: CZ15249-05
Spike Source %REC
RPD
Anal
Resul
Flaa
Q
Units
Level Result %REC Limits RPD
Limit
Notes
Nitrate/Nitrite as N
0.52
0.10
mg/L
0.513 0.041 U 101 90-110
Matrix Spike Dup (6K38005-MSD1)
Prepared: 11/18/2016 08:21 Analyzed: 11/18/2016 11:51
Source: CZ15249-04
Spike Source %REC
RPD
Anal
Resul
Flan
POL
Units
Level Resul %REC Limits RPD
Limit
Notes
Nitrate/Nitrite as N
0.53
0.10
mg/L
0.513 0.041 U 103 90-110 0.4
30
Batch 6K21032 - NO PREP
Blank (6K21032-BLK1)
Prepared: 11/21/2016 11:33 Analyzed: 11/21/2016 13:14
Spike Source %REC
RPD
Analyte
Result
flag
PPL
UJIM
Level Resul %REC Limits RPD
Limit
Notes
Nitrate/Nitrite as N
0.041
U
0.10
mg/L
LCS (6K23032-BS1)
Prepared: 11/21/2016 11:33 Analyzed: 11/21/2016 13:07
Spike Source %REC
RPD
Analyte
Result
Flag
POL
Units
Level Resul %REC Limits RPD
Limit
Notes
Nitrate/Nitrite as N
1.2
0.10
mg/L
1.25 96 90-110
Matrix Spike (6K21032 -MSS)
Prepared: 11/21/2016 11:33 Analyzed: 11/21/2016 13:16
Source.CZ15249-01
Spike Source %REC
RPD
Anal
Resul
Flan
PQ
Units
Level Resul %REC Limits RPD
Lima
Notes
Nitrate/Nitrite as N
4.5
0.20
mg/L
1.00 3.2 126 90-110
QM -07
Matrix Spike (6K21032-MS2)
Prepared: 11/21/2016 11:33 Analyzed: 11/21/2016 13:25
Source: CZ15249-02
Spike Source %REC
RPD
Analyte
Result
Flaa
POL
Units
Level Result %REC Limits RPD
Limit
Notes
Nitrate/Nitrite as N
0.56
0.10
mg/L
0.513 0.041 U 110 90-110
Matrix Spike Dup (6K21032-MSD1)
Prepared: 11/21/2016 11:33 Analyzed: 11/21/2016 13:20
Source: CZ15249-01
Spike Source %REC
RPD
Analyte
Resul
Flag
POL
Units
Level Resul %REC Limits RPD
Limit
Notes
Nitrate/Nitrite as N
4.0
0.20
mg/L
1.00 3.2 81 90-110 11
10
QM -07,
QM -11
Classical Chemistry Parameters - Quality Control
Batch 6K16003 - NO PREP
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 35 Of 4O

A
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QUALITY CONTROL DATA
Classical Chemistry Parameters - Quality Control
Batch 6K16003 - NO PREP - Continued
Blank (6K16003-BLK1) Prepared: 11/16/2016 02:11 Analyzed: 11/16/2016 17:30
Spike Source %REC RPD
Anala Resul Flaa Q2 Units Level Result %REC Limits RPD Mmft Notes
Total Organic Carbon 0.34 U 1.0 mg/L
LCS (6K16003-BS3) Prepared: 11/16/2016 02:11 Analyzed: 11/16/2016 17:30
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 36 Of 4O
Spike Source %REC
RPD
Analyte
Re501l
M9
P2
Sly
Level Resu %REC Limits RPD
Limit Notes
Total Organic Carbon
39
1.0
mg/L
40.0 97 85-115
Matrix Spike (6K16003 -MSI)
Prepared: 11/16/2016 02:11 Analyzed: 11/16/2016 17:30
Source: CZ15249-01
Spike Source %REC
RPD
Anal
Result
Flao
POL
Units
Level Result %REC Limits RPD
Limit Notes
Total Organic Carbon
40
1.0
mg/L
40.0 0.35 99 85-115
Matrix Spike Dup (6K16003-MSDI)
Prepared: 11/16/2016 02:11 Analyzed: 11/16/2016 17:30
Source: CZ15249-01
Spike Source %REC
RPD
Anal
Result
Flan
POL
units
Level Resul %REC Limits RPD
Limit Notes
Total Organic Carbon
39
1.0
mg/L
40.0 0.35 97 85-115 2
21
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 36 Of 4O

I all
FLAGS/NOTES AND DEFINITIONS
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B The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
7 The reported value is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQQ and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater
confidence) to make a "tentative identification".
Greater than 25% concentration difference was observed between the primary and secondary GC column.
The lower concentration is reported.
7-01 Result may be biased high due to positive results in the associated method blank.
QB -01 The method blank had a positive result for the analyte; however, the concentration in the
method blank is less than 10% of the sample result. There is minimal impact to the data.
QM -07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was
accepted based on acceptable LCS recovery.
QM -11 Precision between duplicate matrix spikes of the same sample was outside acceptance limits.
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 37 of 4O

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Note: All samples submitted to ENCO Labs are in accordance with the terms and conditions listed on the reverse of this form, unless prior written agreements exist

A
Sample Preservation Verification .
ENCO Cary
Work Order: CZ15249 Project: GW%SW Monitoring -Annual
Client: Arauco USA, LLC (UN039) Project #: GW/SW Monitoring
Logged In: 09 -Nov -16 14:19 Logged By: John C King
CZ15249-01
Cont
T e
YP
Pres (pH)
pH Checked /
Date/Time
PH Adjusted
Reagent,Used/.Comments
25bmLP+H2SO4
<2 / N / NA
Requirement
In Control
Adlusted:
B
250mLP+H2SO4
<2
/ N / NA
Y / / NA
CZ15249-02
ContT
YP e
Pres (pH) pH Checked /
Requirement -r In Control
Date/Time
PH Adjusted Adjusted
Reagent Used/Comments
B
25bmLP+H2SO4
<2 / N / NA
Y / / NA
/ N / NA
CZ15249-03
Cont
Type •
Pres (pH)
Requirement
"pH Checked /
In Control
pH Adjusted DateMme
Adlusted
Reagent Used/Comments
B
250mLP+H2SO4 .
<2
/ N / NA
Y / , % NA
CZ15249-04
Cont
T e
YP
Pres (pH)
Requirement
pH Checked !
In Control
DatelTime
PH Adjusted Adiusted
1
Reagent Used/Comments
B
250mLP+H2SO4
<2 .
! N / NA
Y / / NA
CZ15249-05
Cont
T e
YP
Pres (pH)
Requirement
pH Checked /
In" Control
Date�me
PH Adjusted Adiusted
Reagent Used/Comments
B
250mLP+H2SO4
<2/
N / NA
Y / / NA
CZ16249-06
Cont
YP
Type
Pres (pH).
Requirement
pH Checked /
In Control
pH Adjusted , DatelTime
•Adlusted
Reagent Used/Comments
B
250mLP+H2SO4
<2
/ N / NA
Y / / NA
CZ16249-07
Cont
YP
Type
Pres(pH)
Requirement
pH Checked /
In Control
Date/Tme
PH Adjusted Adjusted
Reagent Used/Comments
B
250rnLP+H2SO4
<2
/ N / NA
Y / ! NA
CZ15249-08 +v.
Cont
Type
Pres (pH)
Requirement
pH Checked /
f ' n Control
pHAdjusted , DateMme
Adiusted
Reagent Used/Comments
B
250mLP+H2SO4
<2
/ N / NA
Y In / NA
MA
CZ15249-09
Cont
YP
Type
Pres (pH)
Requirement.
pH Checked /
I Control
pH Adjusted DatelTime
Adiusted
Reagent Used/Comments
B
250mLP+H2SO4
<2
/ N / NA
I Y / / NA
Page 39 of 40
Page 1 o

Sample Preservation Verification
ENCO Cary
Work Order: CZ15249
Client: Arauco USA, LLC (UN039)
Logged In: 09 -Nov -16 14:19
CZ15249-10
.. -=ENCO
Project: GW/SW Monitoring -Annual
Project #: GW/SW Monitoring.
Logged By: John C King
Cont
Type
Pres (pH)
Requirement
pH Checked /
I In Control
pH Adjusted Date/Time
I Adlusted
Reagent Used/Comments
I
B
250mLP+H2SO4
<213/
N / NA
Y /(b7/ NA
Rea ent Name ID
1
2
Reacient Name ID
3
4
Rea ent Name ID
5
6
1 1 Page 40 of 40
Page 2 o