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HomeMy WebLinkAboutNC0004308_Comments_20150713 Franklin E. Hill, Director of Superfund Division United States Environmental Protection Agency, Region 4 Sam Nunn Atlanta Federal Center 61 Forsyth Street, SW Atlanta, GA 30303 Request for Preliminary Assessment for Areas Surrounding Alcoa Badin Works Facility in Badin, North Carolina x.. W. pod j5&M(J,�5:lJndeFgmundConveyanc Line to 4PDESOutf&llGG9 '&L". .,head Cir—Rebuiid Strutwire kv lit- wfoqle earth :1 t lmi rti I/ 4!Mir t `� �- '�„ �� —� i'r'�,'��� '�►`�.. �' �t��r ' #.�.+f.i�+r � �.o'``ff` �� 1'� 1 Table of Contents BACKGROUND..................................................................................................................... 5 A History of Environmental Injustice.............................................................................. 5 Spent Potliner Regulatory History.................................................................................. 6 Badin Works RCRA Permitting....................................................................................... 7 CorrectiveAction............................................................................................................ 7 AREA 1-LITTLE MOUNTAIN CREEK,ADJACENT TO SWMU 2....................................... 9 Alcoa-Badin Landfill Geology and Hydrology............................................................. 10 Little Mountain Creek Sampling and Testing............................................................... 11 Bioclassification and Impairment of Little Mountain Creek......................................... 18 NPDES Permit, Expiration and Continuation.............................................................. 20 AREA 2-THE BALL FIELD............................................................................................... 21 RockSamples................................................................................................................. 21 TCLPAnalysis............................................................................................................... 23 FURTHER CONSIDERATIONS............................................................................................ 26 Preliminary Assessment New Monitoring Wells: SWMU 2........................................ 26 CONCLUSION AND REQUEST............................................................................................ 27 APPENDIX ......................................................................................................................... 29 Table A-1. Summary of Previous K088 Rulemakings &Recent Litigation and Petitions ....................................................................................................................................... 29 Table A-2. Weather Conditions in Badin, NC 28009 before June 2014 Little Mountain CreekSampling............................................................................................................. 30 Table A-3. SWMU 2 Monitoring Well and Piezometer Construction Details .............. 31 Figure A-1. Groundwater Hydrographs for SWMU 2/Badin Municipal Landfill........ 32 Figure A-2. Map of Alcoa Badin Works and NPDES Permit Discharge Locations..... 34 Figure A-3. SWMU 2 Soil and Groundwater Conductivity.......................................... 35 INDEX FOR ELECTRONIC APPENDIX................................................................................ 36 2 Director Hill, Under the authority of CERCLA Section 105(d), as amended, the Duke Environmental Law and Policy Clinic (the Clinic), on behalf of the petitioner, Yadkin Riverkeeper, Inc.,' hereby requests that Region 4 of the United States Environmental Protection Agency(EPA) conduct a Preliminary Assessment of the suspected presence and release of hazardous substances in two areas in the immediate vicinity of the former Alcoa Badin Works2 aluminum smelting facility in Badin,North Carolina.' The Alcoa Badin Works facility has a long history of environmental degradation and the two sites addressed in this petition are only two of many possible contaminated sites in and around Badin Works. Area 1 abuts the Alcoa-Badin Landfill (SWMU 2) and includes, but is not limited to, portions of Little Mountain Creek (Figure 1). Initial testing results from Area 1 indicate that the Creek has been contaminated with fluoride, sulfate, and a number of other chemicals associated with industrial processes conducted at the nearby facility. Fluoride and sulfate are indicator compounds of hazardous waste contamination associated with spent potliner, a listed hazardous waste also known as K088. Evidence suggests that hazardous potliner has leached from the Alcoa-Badin Landfill and contaminated the adjacent Little Mountain Creek, an impaired water of the United States. Area 2, referred to as the Ball Field, is the large field east of Alcoa's smelting plant and adjacent to Badin Lake (Figure 1). Preliminary testing by the Clinic has produced results suggesting that this site also has been contaminated with industrial solid wastes. The Badin Works facility is currently undergoing the Corrective Action approval process pursuant to the Resource Conservation and Recovery Act (RCRA) for a number of identified areas within the facility's boundaries; however, the Corrective Action plan does not address the sites of interest in this petition. Alcoa and the Corrective Action plan have not assessed the environmental contamination and degradation of the area around the Alcoa Badin Works facility. Since Alcoa's corrective measures and investigation have not evaluated the areas we identified, we respectfully request that EPA conduct a preliminary assessment of the two sites identified in this petition, as well as any other site with suspected hazardous contamination. Both of these areas are down-gradient of Alcoa Badin Works. 'Yadkin Riverkeeper Inc.,308 Patterson Avenue,Winston-Salem,NC 27101,(336)722-4949, gayle@ggtuchlaw.com. 2 Alcoa Badin Works,EPA/Handler ID:NCD003162542,FRS ID: 110017425614. s See 42 U.S.C. § 9605(d)(2012)(permitting any person to petition for a preliminary assessment and requiring a response within twelve months). 3 Area 2: The Ball Field r Area 1: Little Mountain Creek i r MV :. Y�� +gar .. �r trt►. d� •. � 5 ,� �r. " r 5 }I a Figure 1:Aerial photograph of Alcoa Badin Works Facility in Badin,NC. The location of Areas 1 and 2 are highlighted in relation to the Facility and Badin Lake4 4 U.S.Geological Survey,EarthExplorer.High Resolution Orthoimagery(Jan.27,2010).Images patched and prepared with ArcGIS. GPS coordinates of the approximate center of the Ball Field are 35.406757,- 80.114336. Google Maps, https://www.google.com/maps/place/3 5%C2%B024%2724.3%22N+80%C2%B006%2751.6%22W/@3 5. 406757,-80.114336,17z/data=!3m1!4bl!4m2!3ml!1sOx0:Ox0(last visited Oct. 8,2014).GPS coordinates of the approximate region of Little Mountain Creek where sampling was performed are 35.403470, -80.126345. Google Maps, https://www.google.com/maps/place/3 5%C2%B024%2712.5%22N+80%C2%B007%2734.8%22W/@3 5. 4034717,-80.1263333,15z/data=!3ml!4bl!4m2!3ml!ISOXO:OXO (last visited Oct. 8,2014). 4 BACKGROUND A History of Environmental Injustice Badin,North Carolina, began as a company town established by L'Aluminium Frangaise, which constructed a hydroelectric dam in the narrows of the Yadkin River, circa 1913, to power an aluminum smelter.5 The Aluminum Company of America (Alcoa)bought the partially-finished company town and dam in 1915 and began smelting operations in 1916.6 Since its founding, Badin has been starkly segregated down its geographic center, with a primarily poor, African-American population residing in West Badin, and a more affluent population—at least historically—residing in the eastern part of town. TO"Fdo "Ptff*&M rJ Za7rl5µr54a lnf�a *y FAuw 010-2C. =40- 100 0 r W Figure 2:EJ View Map of the Alcoa Badin RCRA Site. While in operation,Alcoa Badin Works used the Hall-Heroult industrial aluminum smelting process to produce aluminum and had an annual production capacity of 115 thousand metric tons.7 The primary aluminum smelting process requires large volumes of chemical and electrical inputs, and generates a substantial number of hazardous wastes, including but not limited to fluoride,benzo(a)pyrene, mercury, s Town of Badin,A Brief History of Badin(Sept.25,2014),available at http://www.badin.org/about badin.html. 6 Id. 7 DPRA INC.,ECONOMIC ASSESSMENT OF THE REVISED LDR TREATMENT STANDARDS FOR SPENT ALUMINUM POTLINER(K088),at 8 (2000),available at http://www.epa.gov/epawaste/hazard/tsd/ldr/kO88/economic.pdf(prepared for EPA,Office of Solid Waste and Emergency Response,Economics,Methods and Risk Analysis Division). 5 cyanide, lead, polycyclic aromatic hydrocarbons (PAHs), and spent potliner.8 Of particular concern due to production volume is spent potliner, which contains leachable cyanide and fluoride compounds.' Cyanide is well known for its toxicity and can cause health problems with long-term, low-concentration exposure. Fluoride, while considered safe and even beneficial at low doses, can lead to an increased likelihood of bone fractures and skeletal fluorosis with elevated exposure.10 Alcoa has been disposing of hazardous wastes in Badin since the plant began operations in 1917, and for the nearly sixty years before the passage of RCRA, this waste disposal was largely unregulated. It was not until EPA finalized its rule for spent potliner disposal in September of 1988 that the large amounts of spent potliner generated at Badin Works finally were covered by the federal regulatory umbrella. Following this action by EPA, Alcoa sought coverage for damages and cleanup response costs from its insurers. In December of 1992, Alcoa filed a declaratory judgment action in the King County Superior Court in Washington against 167 insurers, seeking coverage for the cost of pollution damage, investigation, and remediation at thirty-five of its sites around the United States.l I Based on the evidence presented, the trial judge held that multiple Alcoa sites may need environmental remediation. Three sites specifically were highlighted as warranting particularly high cleanup costs, exceeding $50 million. The sites were Massena,New York; Point Comfort, Texas; and Badin,North Carolina. While the New York and Texas sites have already been cleaned up under both RCRA and CERCLA, the Badin Works RCRA cleanup has languished. A CERCLA preliminary analysis is needed to protect the Badin community and speed the RCRA cleanup process along. Spent Potliner Regulatory History RCRA was enacted in 1976,12 but Alcoa's handling, transportation, and disposal of hazardous wastes did not fall under EPA's RCRA guidelines until 1980. On May 19, 1980, the first RCRA regulations, "Hazardous Waste and Consolidated Permit Regulations,"were published in the Federal Register and established the basic "cradle to 'See EPA,PROPOSED BEST DEMONSTRATED AVAILABLE TECHNOLOGY(BDAT)BACKGROUND DOCUMENT FOR SPENT ALUMINUM POTLINERS-K088,at iii(2000), http://www.epa.gov/osw/hazard/tsd/ldr/kO88/kO88back.pdf-,EPA ECHO,DETAILED FACILITY REPORT (2013),available at http://echo.epa.gov/detailed_facility_report?fid=110017425614;see also, e.g., EPA, TOXICS RELEASE INVENTORY REPORTING, http://oaspub.epa.gov/enviro/trisquery.dcn_details?tris_id=28009LMNMCHW'Y74(last visited Oct. 3, 2014). 9Id. "CDC, Community Water Fluoridation FAQs(Dec. 6,2013),available at http://www.cdc.gov/fluoridation/faqs/#overexposurel. 11 See Aluminum Co. ofAm. v.Aetna, 998 P.2d 856,30 Envtl.L.Rep.20,536(2000);Aug. 6,2003 Order of Hon. Sharon Armstrong in Alcoa,Inc. v.Accident&Casualty Company, Case No. 92-2-28065-SEA (Sup.Ct.Wash.King Cnty. 2003). 12 Resource Conversation and Recovery Act,Pub.L.No. 94-580,90 Stat.2795 (1976). 6 grave" approach to hazardous waste management that exists today.13 On October 21, 1980, Congress enacted the Solid Waste Disposal Act Amendments of 1980,14 which added, among other amendments, an exemption from RCRA regulation for"[s]olid waste from the extraction, beneficiation, and processing of ores and minerals, including phosphate rock and overburden from the mining of uranium ore. ,15 The aluminum smelting process involves the beneficiation and processing of aluminum ore. EPA subsequently modified its hazardous waste regulations to reflect the October 1980 "mining waste exclusion," and issued a preliminary interpretation of the scope of the exclusion.16 To be consistent with this interpretation, EPA suspended the listings of "solid waste from the exploration, mining, milling, smelting and refining of ores and minerals," including spent potliner.17 On September 13, 1988, EPA published the final rule promulgating the hazardous listing for spent potliner(see Appendix, Table A-1).18 Badin Works RCRA Permitting On November 19, 1980, Alcoa Badin Works submitted a RCRA Part A permit application which indicated that it was storing spent potliner in waste piles, with an estimated annual generation of 4800 tons of waste.19 Immediately following the relisting of spent potliner, Alcoa Badin Works submitted a Notification of Hazardous Waste Activity and a RCRA Part A permit application indicating the generation of spent potliner.20 Alcoa buried spent potliner as a means of disposal long before the submission of its Part B RCRA application in March 1990. A 1989 site assessment report prepared by Law Environmental for Alcoa stated that the burying of[spent] potliner began in the early 1900s and continued until the late 1970s. The disposal area locations are not precisely known, although several areas are identified and others are suspected.21 Corrective Action In 1989, cleanup of the Badin Works site was handed over to Alcoa, which would manage the remediation under RCRA's Corrective Action process. On December 23, 1996, CERCLA enforcement staff noted that further CERCLA activities at the site were 1145 Fed.Reg. 33066,33066-72(May 19, 1980);see also EPA,History ofRCRA,available at http://www.epa.gov/osw/laws-regs/rcrahistory.htm. 14 Pub.L.No. 96-482,94 Stat.2334(Oct.21, 1980). 15 42 U.S.C. § 6921(b)(3)(A)(ii)(2012). 16 45 Fed.Reg. 76618,76618(Nov. 19, 1980);see also EPA,supra note 8. 17 45 Fed.Reg. 76618,76619(Nov. 19, 1980);see also EPA,supra note 8,at A-1. "53 Fed.Reg. 35412,35414 tbl.I (Sept. 13, 1988);see also EPA,supra note 16,at A-3. 19 A.T.KEARNEY,INC.&DPRA,INC.,INTERIM RCRA FACILITY ASSESSMENT REPORT,at II-11 (1990) (prepared for Ms. Rowena Sheffield of EPA Region 4). 20 Id.at II-12. 21 LAW ENVTL.,PHASE II GROUND-WATER ASSESSMENT NORTHWEST VALLEY,ALCOA-BADIN WORKS, BADIN,NORTH CAROLINA 1-1 (1990). 7 "[d]eferred to RCRA."22 EPA's online Superfund database lists the site as having completed a Preliminary Assessment on November 20, 1985,23 after which no further actions were taken. This 1985 Preliminary Assessment was conducted by an employee of North Carolina's Division of Health Services who relied only on files already available at his Raleigh,North Carolina office, and on a single day's communications with one employee each from the Department of Environment and Natural Resources (DENR) and from Alcoa.24 North Carolina conducted no sampling or testing.25 This 1985 Preliminary Assessment does not meet the standard for a Preliminary Assessment and did not address the issues we bring forward in this petition. The RCRA Corrective Action procedures are implemented by the North Carolina Department of Environment and Natural Resources Division of Waste Management and consist of five phases. Phases 4 and 5 are currently ongoing. Phase 1: RCRA Facility Assessment Phase 2: RCRA Facility Investigation Phase 3: Corrective Measures Study Phase 4: Corrective Measures Implementation Phase 5: Corrective Action Completed. Areas 1 and 2 identified in this petition show evidence indicative of past disposal and ongoing contamination with hazardous substances,but have not been identified as SWMUs or AOCs under the ongoing RCRA work. Because these areas are not being addressed by Alcoa or DENR under RCRA, the unclaimed contamination near Areas 1 and 2 qualifies for consideration under Superfund. EPA should conduct a Preliminary Assessment that includes actual sampling of potentially-contaminated areas surrounding Alcoa's facility, and should proceed under CERCLA according to the results of that assessment. The following sections provide a detailed summation of field sampling, testing, and lab results for the two areas, and identify various concerns for human and ecosystem health. 22 EPA,Superfund Site Information—Actions(Sept. 30,2014),available at http://cumulis.epa.gov/supercpad/cursites/cactinfo.cfm?id=0402612;EPA,Superfund Site Information- Site Info(Sept.30,2014),available at http://cumulis.epa.gov/supercpad/cursites/csitinfo.cfin?id=0402612. 23 EPA,Superfund Site Information—Actions(Sept. 30,2014),available at http://cumulis.epa.gov/supercpad/cursites/cactinfo.cfm?id=0402612. 24 See Cover Letter for 1985 RCRA Final Preliminary Assessment Report,infra note 26,at 2. 25 Id. 8 AREA 1 - LITTLE MOUNTAIN CREEK,ADIACENT TO SWMU 2 The Alcoa-Badin Landfill (SWMU 2) is an unlined landfill that was in operation since the early twentieth century, long before the existence of RCRA. It occupies an area roughly 1000 feet by 950 feet and is located southwest of the facility on the opposite side of Wood Street, outside of the former plant's fence. From the early 1900s into the 1970s, both municipal and industrial wastes were disposed of in this landfill. During this time, unknown quantities of spent potliner were placed in the landfill, especially during the renovation of the smelting facility, circa 1965.26 Use of SWMU 2 was discontinued in the mid-I970s.27 Since then, a cap was placed on the landfill to reduce surface water infiltration and monitoring wells were installed. However, the landfill is unlined and therefore offers no protection against groundwater contamination from hazardous constituents such as spent potliner. It lies about 300 feet north and hydraulically up- gradient of Little Mountain Creek, creating the potential for the flow of contaminants down-gradient and into the creek; this relationship is discussed in more detail below.28 Nonetheless, the source of this pollution, despite a 2004 recommendation to do so by HDR Engineering in a report addressing Little Mountain Creek's impairment for aquatic life.29 The HDR report, commissioned by the North Carolina Ecosystem Enhancement Program under DENR, also recommended a monitoring plan under which multiple points in the stream would be regularly monitored through chemical, physical, benthos, and fish tests. Instead, the Division of Water Quality disregarded the HDR report. The HDR report identified activities associated with Badin Works as likely having contributed to the impairment of Little Mountain Creek, based on reports that the facility continued to discharge into the Little Mountain Creek hydrologic unit(HU)with NPDES permit violations, even though Alcoa's smelting facility closed in 2007.30 The report concludes that further investigation into the water quality impacts from Alcoa Badin Works should be conducted, yet none was undertaken by DWR. 26 N.C.DIV.OF HEALTH SERVS.,FINAL PRELIMINARY ASSESSMENT REPORT(1985). 27 NUS CORP.,PRELIMINARY REASSESSMENT 7(1989);MFG,INC.,RCRA FACILITY INVESTIGATION REPORT,VOLUME I OF II,at 103 (200 1)(prepared for Alcoa,Inc.). 28 Little Mountain Creek is a tributary of Mountain Creek, which in turn empties into Lake Tillery on the Yadkin-Pee Dee River(south and downriver of Badin and the Yadkin Project). 29 HDR ENG'G,INC.,PRELIMINARY FINDINGS&RECOMMENDATIONS REPORT-MOUNTAIN CREEK AND LITTLE MOUNTAIN CREEK AND JACOBS CREEK 2-47(2004)(prepared for the North Carolina Ecosystems Enhancement Program). 301d. 9 Alcoa-Badin Landfill Geology and Hydrology SOUTH NORTH �Ew A A' .F r _ Fr+rzman IJ � FfFnassm uFaza 3 J J / BEOROCK� w ✓ /r ea A i � ESVL FMA I'IOE ®M"FE waaMi X- Q 5 ryoeia RE FMCF aei. Fberms /r GERAGHTY FIGURE n 3-1�rn�I1.I.ER. INC. Concepluaf She Madel Mb:omemir �Wnr-l°wi Ebveelan In.msilE AbFbwn�wmpanv uCOa e.an wvmc seen,xebn G.d°4 5w°eneE MnvN 4ninW J°rvnv t],18Ei 0®M1W Figure 3: Cross-Sectional Diagram of Alcoa-Badin Landfill(SWMU 2).31 As shown in Figure 3, the elevation of SWMU 2 ranges from approximately 540 feet above mean sea level (ft-msl) at the north-central end of the landfill to approximately 460 ft-msl at the south end leading towards Little Mountain Creek. Geologically, SWMU 2 overlies a natural ravine, which extends from the Badin Works plant south to Little Mountain Creek.32 The bedrock below the landfill, shown in Figure 3, consists of argillite/green slate; weathering has altered the uppermost portion of the slate into a silty clay saprolite.33 In general, the flow of groundwater through the Alcoa-Badin Landfill follows topography. Groundwater flows from north to south through the Alcoa-Badin Landfill, towards Little Mountain Creek. The water table in this area is relatively close to the surface—in several places it is merely a few feet from the surface. Along the southwestern side of the landfill, groundwater actually intersects with some of the waste material (Figure 3). Notably, at the western tip of the landfill (ABL-MW-3), the water table elevation occasionally rises to just inches below the ground surface. This results in 31 GERAGHTY&MILLER,INC.,GROUNDWATER FLUX DETERMINATION ALUMINUM COMPANY OF AMERICA BADIN LANDFILL BADIN WORKS FACILITY BADIN,NORTH CAROLINA 28(1997)(included as Appendix A-4 Of ALCOA,INTERIM MEASURES WORKPLAN,ALCOA-BADIN LANDFILL(SWMU#2),REGRADING AND COVER SYSTEM INSTALLATION(1997)). 32 MFG,INC.,supra note 27,at 105. 33 Id. 10 an area of deep mud and some standing water. The average hydraulic gradient throughout SWMU 2 is 0.05ft/ft.34 Hydraulic conductivity throughout the landfill is quite high due to the presence of unconsolidated fill material underneath the compacted soil. Little Mountain Creek Sampling and Testing Given the proximity of Little Mountain Creek(LMC)to the unlined landfill, a sampling team led by Dr. Shea Tuberty35 collected samples and performed field testing on April 4, 2014, to determine the presence and concentration of hazardous compounds that might be traced back to the landfill. The sampling team collected water samples from six locations to undergo Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES) and Ion Chromatography(IC) chemical analysis. April 2014: Sampling and Testing of Little Mountain Creek near Small creek feeding into Little Outfall 0 18.36 Mountain Creek from direction of Landfill 34Id. at 106. 3s Dr. Shea Tuberty.Associate Professor,Aquatic Ecophysiology and Toxicology Lab,Department of Biology,Appalachian State University.Boone,N.C. 36 GPS Coordinates of Little Mountain Creek Sampling: 35.403470, -80.126345. Google Maps,supra note 4. 11 Concentrations(m /L Water Sample Aluminum Arsenic Barium Cadmium Chromium Copper Result Averages Badin Lake Drain 0.286944 0.0014082 0.029054 0.000225 0.002908 LMC Below 0.3065658 0.0024042 0.011425 0.0001626 0.009875 TestBox 1.0524966 0.0018228 0.051422 0.0002226 0.0372807 0.008452 Feeder Cr 1 0.2808324 0.0024966 0.016009 0.0001986 0.002187 Feeder Cr 2 0.2344536 0.0015666 0.013398 0.0002688 0.003965 Cracked Pipe 74.3754444 0.08505 1.060296 0.0057426 0.1723191 0.24975 (continued) Concentrations(m /L Water Sample Iron Manganese Nickel Lead Selenium Strontium Zinc Result Averages Badin Lake Drain 0.5994216 0.1797822 0.000907 0.005154 0.0262183 0.07043 0.0176776 LMC Below 0.429819 0.013662 0.000504 0.0059376 0.0257718 0.041786 0.0228747 TestBox 1.9112814 2.644722 0.004477 0.0058764 0.0310118 0.194459 0.0636306 Feeder Cr 1 0.4618314 0.3400248 0.001129 0.0015906 0.0282870 0.154477 0.0128333 Feeder Cr 2 0.589473 0.0456246 0.000734 0.0011334 0.0254446 0.047106 0.0138634 Cracked Pie 169.581825 70.563141 0.100614 0.1684452 0.0599751 0.51028 0.5592018 Table 1:Presence and concentration of analytes found in water samples from six study sites. Data prepared by Dr. Shea Tuberty, average metals analysis results by ICP-OES. While sampling, the team identified a poorly-constructed pipe running along a man-made ditch from the Alcoa-Badin Landfill to a test box near Little Mountain Creek. The pipe was discharging considerable amounts of an unknown fluid through an apparent leak(see below). The team collected samples of the leaking discharge for lab tests.37 37 Dr. Shea Tuberty,ICP Chemical Analysis Results(Apr.2014)(laboratory results are on file with the Duke Environmental Law&Policy Clinic). 12 f � AW Ap AF v t a.s •r... �I ! h , } Cf �:°�':{ 'tib �I �, �• a 1,- ��'.'. •�` rm r� Y Ir April 2014: Leaking Pipe near Little Mountain Creek." The IC results indicated significantly higher levels of fluoride and sulfate downstream of the landfill than upstream. Many of the results of this analysis have analyte levels which far exceed North Carolina's water quality criteria. For example, the cracked pipe observed near Little Mountain Creek had fluoride levels at nearly four times the State's surface water quality criterion, and the test box it connected to the pipe had levels almost fourteen times that criterion. High fluoride levels in particular may be indicative of leaching spent potliner buried nearby. Although there are no State criteria for sulfate, the pipe, drainage ditches, and other areas surrounding the creek had sulfate levels ten times higher than the reference site upstream in Little Mountain Creek. 38 Id. 13 Sample Site Fluoride Chloride Sulfate Nitrate (mg/L) (mg/L) (mg/L) (mg/L) NC Water Criteria 1.8 230 LD 10 LMC1 (downstream) 0.37 7.76 13.84 0.76 LMC3 (upstream ref) 0.09 10.93 11.02 0.76 Drainage Ditch 1 16.14 15.7 102.28 0.87 Drainage Ditch 2 0.6 8.68 13 0.4 Test Box 25.08 20.02 113.21 0.2 Cracked Pipe 7.09 19 131.84 0.2 Unnamed Feeder Creek 2.83 9.71 77.97 11.11 Ball Field Drainage 0.62 20.56 58.15 4.56 Table 2:Dr. Shea Tuberty sampling results and analysis by IC from Alcoa-Badin site visit. After reviewing the lab results from prior sampling and site visits, our team again collected samples from Little Mountain Creek on June 27, 2014. The sampling team collected both water and sediment samples from Little Mountain Creek, which underwent a full panel of chemical analyses. The samples were taken from the same approximate location as the April 2014 sampling event. y �r _ � 9 June 2014: LMC sampling location,showing Outfall 018. 14 The lab results for the Little Mountain Creek surface water samples and the State's criteria are listed in the table below (Table 3). None of the listed results exceeded North Carolina's surface water quality criteria. 15A NCAC 2B Method Analyte Concentration Surface Water (ug/L) Criteria (ug/L) EPA 300.0 Fluoride 0.0488 mg/1 1.8 mg/L Aluminum 79.4 87 Calcium 8900 Cyanide 2.64 5 EPA 6010C Iron 144 1.0 mg/L Magnesium 3840 Manganese 56.6 Sodium 8380 EPA 5030B Acetone 1.5 2.0 mg/L Toluene 0.035 11 Table 3:Water sample test results from Little Mountain Creek,June 2014. The lab results for the Little Mountain Creek sediment samples are listed in the table below (Table 4); however,North Carolina does not have sediment or soil criteria by which to compare the results. While Dr. Tuberty's Little Mountain Creek sampling results differed slightly from the Clinic's results, each set of results is based on different testing conditions. A water sample falling below the State criteria on one day may exceed the standard on another day, for example, depending on changes in the weather. 15 Method Analyte Concentration (mg/kg dry) Aluminum 11700 Antimony 1.65 Arsenic 31.2 Barium 40.1 Beryllium 1.65 Calcium 534 Chromium 156 Cobalt 17.1 Copper 13.4 EPA 6010C Iron 45200 Lead 1.08 Magnesium 1760 Manganese 1170 Nickel 18.4 Potassium 278 Sodium 140 Thallium 13.6 Vanadium 80.3 Zinc 59.5 EPA 7471B Mercury 0.00685 Table 4: Sediment sample results from Little Mountain Creek,June 2014. In the process of collecting the Little Mountain Creek samples, the team noticed a small body of standing water between Little Mountain Creek and the landfill that was presumably groundwater. The water had a peculiar orange/brown tinge, so the team collected a sample for chemical analysis. 16 � I _ t _ June 2014: Standing water between Little Mountain Creek and landfill. Unlike the Little Mountain Creek samples, the water sample collected from the standing pool was only tested for fluoride. In this instance, the Clinic chose fluoride to serve as the "canary in the coal mine," as elevated levels of fluoride in the sample would likely indicate ongoing hazardous waste material discharges from the unlined landfill (SWMU 2), into the groundwater, and ultimately into Little Mountain Creek. 15A NCAC 2L Method Analyte Concentration Groundwater (mg/L) Standard (mg/L) EPA 300.0 Fluoride 19.9 2 Table 5:Water sample test results from standing puddle between LMC and Landfill, June 2014. As there had not been rainfall of more than 0.03 inches for two weeks prior to the June 27th sampling event(see Appendix, Table A-2), our team concluded that the source of this puddle was groundwater intersecting with the land surface. The puddle was located in the alluvium between the landfill and Little Mountain Creek, where the water table occasionally rises to within a few inches of the ground. Due to the unusually high fluoride concentration in the sample and its location hydraulically down-gradient from SWMU 2, the team suspects that hazardous waste materials within the landfill may be leaching into the groundwater. 17 The presence and extent of SWMU 2 groundwater contamination may be influenced by the amount of rainfall in a given timeframe and the subsequent groundwater elevation. We have seen that the groundwater level is capable of intersecting landfill waste material (Figure 3); however, it is unclear the degree to which rainfall increases the exposure of landfill waste materials to groundwater. Alcoa's Phase 3 Corrective Measures Study included groundwater hydrographs showing the correlation between precipitation and groundwater elevation for SWMU 2 piezometers (PZ) and monitoring wells (MW) over a two-year period (see Appendix, Figure A-1).39 MW-3, MW-4, and MW-5 are located near Little Mountain Creek in the alluvium and show separate fluctuations in groundwater elevation resulting from precipitation(see Appendix, Figure A-1).40 Groundwater elevations measured at MW-4 rose over two feet with nearly three inches of rainfall.41 Groundwater elevations measured at MW-3 and MW-5 generally exhibited fluctuations of lower magnitude compared to those of MW-4.42 However, the average groundwater elevations were highest in MW-3 and lowest in MW-5,presumably due to the subterranean geology and landfill composition.43 PZ-2S and PZ-2D are located up-gradient from MW-3, -4, and-5 and due north of MW-5 (Figures 3 and 5). The hydrograph for these piezometers indicates a potential intersection of the groundwater level and landfill waste material following moderate to substantial rainfall (see Appendix, Table A-3, Figure A-3).44 The evidence of contamination in Little Mountain Creek provided below further supports this possibility. Bioclassification and Impairment of Little Mountain Creek The North Carolina Division of Water Quality(now the Division of Water Resources or DWR)has listed Little Mountain Creek as impaired on the Clean Water Act 303(d) list since 1998, yet the source of impairment is still listed as unknown.45 Though agriculture is listed as a potential source of impairment in the 2002 Integrated 305(b) and 303(d)report,46 Alcoa's activities have likely exacerbated the creek's impairment. 39 TESTAMERICA,TESTAMERICA JOB ID:680-71611-1,Appendix I(2011)(included as Appendix H of ENvIRONEERING,INC.,PHASE 3—ENGINEERING DATA COLLECTION FOR THE CORRECTIVE MEASURES STUDY BADIN WORKS FACILITY BADIN,NORTH CAROLINA(2012)). 4o Id. 41 Id.Precipitation event occurred between June 16,2010 and September 24,2010. 42 Id. 43 Id. 44 Id. 45 HDR ENG'G,INC.,supra note 29,at 2-25. 46 N.C.DEPT.OF ENV'T&NATURAL RES.,WATER QUALITY ASSESSMENT AND IMPAIRED WATERS LIST (2002 INTEGRATED 305(B)AND 303(D)REPORT)Appendix VI,at 99 of 101(2003),available at http://portal.ncdenr.org/c/document_library/get_file?uuid=7cfeOf8a-bde3-4523-9e3 e- cdc44e323123&groupld=38364. 18 A 2013 report by the DWR listed a bioclassification of"Fair" for the creek based on a sample from 2011, a meager improvement from a"Poor"bioclassification from 2004.47 When the 2011 sample was taken, the water had"a milky tint" and heightened specific conductance.48 Water quality data collected from the creek between 1998 and 2002 reflected elevated nitrogen and fecal coliform bacteria levels and high conductivity, but adequate dissolved oxygen levels.49 DWR did not investigate further. A recent 2014 study by Professor Shea Tuberty of the fish and invertebrate species found in Little Mountain Creek revealed the ecological impact of the creek's impairment. Although the testing was not conducted in accordance with State testing procedures, the test results provided strong evidence of anthropogenic degradation of the stream which requires further investigation. The table below presents the Index of Biotic Integrity(IBI) data taken both upstream and downstream from the landfill (Table 6). A score of five on a particular metric indicates that the metric was similar to that expected for a habitat with little human interference, whereas a score of one indicates a large deviation from the expected condition, and a score of three is intermediate. The integrity classification is calculated by summing the twelve component metrics, and accordingly can range from twelve to sixty. Reference Site Contaminated Site Metric (Upstream) (Downstream) # Metric Criteria Score Score 1 Number of Species 5 3 2 Number of Fish 5 3 3 Number of Darter Species 5 1 4 Number of Centrachids and Trout 5 5 5 Number of Sucker Species 5 5 6 Number of intolerant Species 1 1 7 %Tolerant 3 1 8 %Omnivore and Herbivore 1 5 9 %Insectivores 1 5 10 %Piscivores 1 1 11 %Diseased Fish 5 1 12 %of Species with Multiple Age Groups 5 5 Total: 42 36 Good/Fair Fair Integrity Classification: (42-46) (36 to 40) Table 6:Fish IBI Scores from Sampling of Little Mountain Creek(Badin,NC),Dr. Shea Tuberty. 47 N.C.DEPT.OF WATER RES.,BASINWIDE ASSESSMENT REPORT:YADKIN RIVER BASIN 114(2013), available athttp://portal.ncdenr.org/c/document—library/get file?uuid=43a70651-e85f-4330-915f- fl3aafbfa99d&groupld=38364. 4s Id. 49 HDR ENG'G,INC.,supra note 29,at Appendix C,at 4. 19 The scores for the upstream portion are generally good, showing a large, diverse population of species with little disease. The downstream site, however, received an integrity classification at the low end of the "Fair" designation, due to small, less diverse populations and higher rates of disease; all of these factors indicate stream degradation. In particular, a portion of the fish tested at the downstream site had obvious erosion on the fins and fungal infections on the skin, neither of which were apparent at the upstream site, which received a five for percentage of diseased fish. These results are highly indicative of stream degradation downstream of the Alcoa-Badin Landfill. In addition, the low score for the number of darter species indicates decreased oxygen levels and increased silt, as these species are especially susceptible to both conditions.50 These results indicate some form of contamination or impairment down-gradient from the plant site. NPDES Permit, Expiration and Continuation Alcoa has previously held a National Pollutant Discharge Elimination System (NPDES)permit for numerous Outfalls across the Alcoa Badin Works site, including the "stormwater" discharge from the Alcoa-Badin Landfill into Little Mountain Creek, known as Outfall 018 (see Appendix, Figure A-2). The NPDES permit expired on February 28, 2013;51 however, the facility must comply with the requirements of the expired permit until a new permit is issued. The standing permit does not have any effluent limitations for discharges from Outfall 018 into Little Mountain Creek.52 so LYCOMING COLLEGE,CLEAN WATER INSTITUTE,IBI METRICS DESCRIPTIONS(2004),available at https://www.lycoming.edu/cwi/pdfs/limestoneRun/ibiMetrics.pdf "N.C.Div.of Water Quality,NPDES Permit No.NC0004308 (Feb.22,2008). 52 Id. 20 AREA 2 - THE BALL FIELD Area 2's nickname, the Ball Field, is attributed to historic aerial photographs showing what appears to be a baseball diamond in the center of the field (Figure 4), though the baseball diamond disappeared from aerial photographs around 1960. The Ball Field abuts the south end of Badin Lake and is across from the Alcoa Badin Works facility. „d JU ' Baseball Diamond Ball Field Alcoa-Badin Landfill Figure 4: Comparison of Ball Field and SWMU 2, 1956 and 2010.13 The Ball Field is not a listed SWMU under the RCRA Corrective Action plan, but given its proximity to Alcoa's smelting facility, other SWMUs, lakebed PCB remediation activity, and first-hand citizen accounts, the Clinic decided to visit the site to determine if further investigation was merited. This determination is especially important given that the Town of Badin has been planning on accepting this land as a gift and using it to construct a waterfront park, with design provided by Alcoa.54 Rock Samples In September 2012, the Clinic's sampling team visited Badin to collect field samples for lab testing from the Ball Field and Badin Lake Boat Access adjacent to the Ball Field. The sampling team found several unusual rocks, one of which was suspected to be a fragment of spent potliner(Sample A, see below). A Powder X-Ray Diffraction (XRD)test was performed on the samples to determine their chemical compositions. 13 N.C.Geological Survey(NCGS),Badin, NC(1956), in North Carolina Historical Aerial Photography Collection;U.S. Geological Survey,supra note 4.For more information on accessing NCGS's Historical Aerial Photography Collection,please see http://portal.ncdenr.org/web/lr/geologic-maps-of-north- carolina#atalog_listing. 14 Visit Badin,Master Plan,http://visitbadin.com/wp-content/uploads/2011/12Badin-Park-Plan- 11_08_2011 l Jpg(last visited Oct. 11,2014). 21 September 2012: Sample A,found near Badin Lake Sample B,found in the Ball Field." Boat Access. Constituent Composition Mullite((Al2O3)x(SiO2),) 69.70% Spinel(MgFe2O4) 4.10% Quartz(SiO2) 2.70% Sample A Cristobalite(SiO2) 6.50% Tridymite(SiO2) 2.00% Rutile(TiO2) 0.20% Amorphous 14.80% Graphite(C) 98.60% Nephaline(Na,K)A1SiO4) 0.80% Sample B Quartz(SiO2) 0.30% Corundum(Al2O3) 0.20% Hematite(Fe2O3) 0.10% Table 7:X-Ray Diffraction test results for Samples A and B from the Ball Field The XRD test results revealed that Sample A was comprised of 69.7%mullite [(A1203),(Si02)y] (Table 7). Mullite is used as a refractory material in several high-heat applications, such as metal, glass, and ceramics manufacturing. Potliner produced during aluminum smelting operations has characteristically high mullite concentrations.56 There are no other industrial facilities in the vicinity of Badin that would be expected to use or produce mullite, and the compound does not occur naturally in the region. Given the sample's proximity to the Alcoa Badin Works facility, we concluded that Sample A likely 5s Approximate GPS Coordinates of Samples A and B: 35.407758, -80.114432. Google Maps, https://www.google.com/maps/place/35%C2%B024%2727.9%22N+80%C2%B006%2752.0%22W/@3 5.4 07758,-80.114432,17z/data=!3ml!4bl!4m2!3ml!1SOXO:OXO(last visited Oct. 8,2014). 16 K.Tsch6pe et al.,Chemical Degradation Map for Sodium Attack in Refractory Linings,LIGHT METALS 871,871 (2010), available at www.material.ntnu.no/ceramics/0871.pdf. 22 is a fragment of spent potliner from the nearby smelting plant. The XRD analysis showed that Sample B was composed of 98.6% graphite [C] (Table 7). Like mullite, graphite has numerous industrial applications, especially as a refractory material in the metals, glass, and ceramics industries.57 Apart from Alcoa Badin Works, however,there are no nearby facilities that we would expect to be a source of this graphite sample, and pure graphite does not naturally occur in the region. Based on the sample's composition and the geographic factors surrounding the sample's location, we believe that Sample B is a carbon anode fragment. Carbon anode is a common waste product in smelting operations. Neither Sample A nor Sample B is associated with the current use of the field. As such, the two rock samples may be evidence of past solid waste dumping. None of these items would be associated with baseball or fishing activities. TCLP Analysis After reviewing the XRD results from the rock samples, the Clinic determined that more advanced chemical analyses were necessary to determine the presence and degree of contamination at the Ball Field. In November 2013, our sampling team returned to the Ball Field to collect water, soil, and rock samples for Toxicity Characteristic Leaching Procedure (TCLP) analysis. A0 � -A 71140'. Ar P WWI ZL �.A-1 017. November 2013: Water Sampling from Ball Field "Rock"Sample from Ball Field.58 Drainage 57 Graphite Applications,MEGA GRAPHITE INC., www.megagraphite.com/products/byapplication/industrialapplications_(last visited Oct. 8,2014). "GPS Coordinates of Ball Field Drainage: 35.407646, -80.114606. Google Maps, https://www.google.com/maps/place/35%C2%B024%2727.5%22N+80%C2%B006%2752.6%22W/@35.4 07646,-80.114606,17z/data=!3ml!4bl!4m2!3ml!ISOXO:OXO(last visited Oct. 8,2014). 23 The TCLP analyses of the Ball Field drainage water sample revealed the presence of a number of hazardous compounds associated with industrial processes, rather than baseball and fishing(Table 8). 15A NCAC 2L Method Analyte Sample Groundwater (ug/L) Standard (ug/L) 2-Fluorophenol 58 Phenol-d5 34 30 Nitrobenzene-d5 81 2-Fluorobiphenyl 77 2,4,6 Tribromophenol 86 SVOC Terphenyl-d14 83 8270D 1,4-Dicholorobenzene-d4 158 6 Napthalene-d8 164 6 Acenaphthene-d10 182 80 Phenanthrene-d10 183 200 Chrysene-d 12 176 5 Perylene-d 12 182 Bibromofluoromethane 123 1,2 Dicholoroethane-d4 138 0.4 Toluene-d8 106 600 VOA Bromofluorobenzene 105 8260B Fluorobenzene 82 Chlorobenzene-d5 83 50 1,4-Dicholorobenzene-d4 78 6 EPA Fluoride 0.0796 mg/1 2 mg/l 300.0 Aluminum 119 Calcium 5600 EPA Iron 83.6 300 6010C Magnesium 2070 Manganese 27.7 50 Potassium 2880 gamma-Chlordane 0.454 Methoxychlor 15.64 Table 8: TCLP test results for water sample from Ball Field drainage unit,November 2013. We used State groundwater quality standards for this comparison although the samples were taken from a surface drainage unit. We are aware that the content of this sample might not accurately mirror the content of the groundwater; however, it serves as 24 an example of the constituents that are capable of leaching into groundwater. The TCLP analysis of the rock and soil samples detected a number of hazardous compounds, some of which are known carcinogens associated with the aluminum smelting process (Table 9). Concentration Analyte (ug/L) Soil "Rock" Arsenic 7.81 11.8 Barium 264 224 Cadmium 3.1 Chromium 16 Lead 82.4 11.3 Selenium 7.71 5.12 Mercury 0.058 0.075 2-Fluorophenol 58 61 Phenol-d5 39 43 Nitrobenzene-d5 68 71 2-Fluorobiphenyl 75 73 2,4,6-Tribromophenol 80 75 Terphenyl-d14 87 83 1,4-Dichlorobenzene-d4 89 110 Naphthalene-d8 90 115 Acenaphthene-d10 85 115 Phenanthrene-d10 81 105 Chrysene-d12 81 103 Perylene-d12 76 99 Table 9: TCLP test results for soil and"rock"samples from the Ball Field. All of the analytes fell below EPA's maximum concentration of contaminants for TCLP.59 However, the presence of carcinogenic and otherwise toxic substances, as well as rock fragments which are likely byproducts of industrial processes, indicates a need for further investigation of the site. These compounds did not come from recreational boating and fishing activities or kids playing baseball. 5940 C.F.R. § 261.24(2011). 25 FURTHER CONSIDERATIONS Due to limited testing site access and resources, only the two sites identified in this petition were examined by the Clinic. Nonetheless, other sites within and around the Badin Works site may also be contaminated. Alcoa and DENR records both suggest that environmental contamination may be present in other areas not identified in the RCRA Corrective Action plan or in this petition. Members of the Badin community have likewise mentioned that waste from the plant had been deposited outside of the areas identified by Alcoa for a number of years dating back to the early 1950s. We believe that a number of sites beyond those identified in this petition warrant inclusion in the requested Preliminary Assessment. Preliminary Assessment—New Monitoring Wells: SWMU 2 As part of the Preliminary Assessment, we recommend that EPA locate, install, and monitor three additional monitoring wells to be placed south of the landfill (in the alluvium) to determine whether the unlined landfill may be a source of the contamination in Little Mountain Creek. Approximately forty wells actively monitor the groundwater flowing into Badin Lake. However, we believe that the groundwater in the southern part of the plant, flowing from beneath SWMU 2 into Little Mountain Creek, is insufficiently monitored. Of the six monitoring wells around the perimeter of the landfill, only three (ABL-MW03, ABL-MW04, and ABL-MW05) are located in positions that allow for monitoring of water leaving the landfill (Figure 5). 26 R I 4 l ' L-MPdWO1 IIABL'Z1S ., ABL PZ-1IP, ±.- wt , i AJ31.-PZ13 :, 01BL MVS C13 . 'c ABL-PZ15 ABL-P ABL-PZ16 ABL-MA'04 ABL-Pz1 ,ABL-PZ7$� Legend O Fe eter i hianiicr 4Ve- - _ ENVIR€)NEERING, INC. FIGURE 3-1 ALCOA BADIN MUNICIPAL LANDILL hMONITORNG WELL AND SOIL BORING LOCATION MAP w-a;ta�m a tia7dcsFhcartr �Ire,tafedri caaoi:ke, FiEure 5:Locations of piezometers and monitoring wells in and around the Alcoa-Badin� Landfill.60 CONCLUSION AND REQUEST Having conducted several rounds of testing, we believe that the two areas discussed in this petition warrant further investigation by EPA. Additional areas around the Badin Works site may also warrant investigation and should be sampled during the Preliminary Assessment. Numerous Alcoa Badin sites are already being investigated under RCRA; however the Ball Field has not been previously identified as a potential disposal site, and though Little Mountain Creek has been listed as "impaired" in the past, it still shows signs of degradation downstream of Outfall 018. 60 ENVIRONEERING,INC.,PHASE 3—ENGINEERING DATA COLLECTION FOR THE CORRECTIVE MEASURES STUDY BADIN WORKS FACILITY BADIN,NORTH CAROLINA 11 (2012). 27 NC DENR has a history of dismissing the concerns of West Badin's environmental justice community and the Yadkin Riverkeeper without independent investigation. Alcoa has a history of improperly disposing of hazardous wastes around its facility. For these reasons, we request that EPA further investigate the areas discussed in this petition in order to determine the presence, extent, and impact of hazardous materials, and the eligibility of the areas to be listed as Superfund sites. Because Alcoa and North Carolina have not investigated or addressed the presence of hazardous wastes in surrounding areas during the RCRA process, EPA should now conduct a Preliminary Assessment of the contamination under CERCLA. Please contact us if you have any questions about this request. Thank you again for your attention. Sincerely, /s/ Ryke Longest, Director Duke Environmental Law&Policy Clinic (919) 613-7207 longest@law.duke.edu /s/ Shannon Arata, Legal Fellow Duke Environmental Law&Policy Clinic (919) 613-7251 shannon.arata@lawnet.duke.edu cc: Gina McCarthy, Administrator United States Environmental Protection Agency 1200 Pennsylvania Avenue,N.W. Washington, DC 20460 Heather McTeer Toney, Regional Administrator United States Environmental Protection Agency, Region 4 Sam Nunn Atlanta Federal Center 61 Forsyth Street, SW Atlanta, GA 30303 Mathy Stanislaus, Assistant Administrator United States Environmental Protection Agency Office of Solid Waste and Emergency Response EPA West Building 1301 Constitution Avenue,NW Washington, DC 20004 28 Appendix Table A-1. Summary of Previous KO88 Rulemakings & Recent Litigation and Petitions Regulatory Event Federal Register Notice Date Listed as a hazardous waste 45 FR 47832 July 16, 1980 Listing suspended 46 FR 4615 January 16, 1981 Environmental group challenged EPA's failure to complete the required studies under Sections N/A 1984 8002(f)and(p) Proposed relist 50 FR 40292 October 2, 1985 Withdrawal of proposal of relist 51 FR 36233 October 9, 1986 Court removed suspension of K088 listing(EDF vs. N/A July 1988 EPA) Re-enact original listing of K088 53 FR 35412 September 13, 1988 Proposed LDR for K088 60 FR 11702 March 2, 1995 Final LDR for K088 61 FR 15566 April 8, 1996 Reynolds challenged EPA's decision of nine months of national capacity variance and sought the N/A May 1996 court's expedited review of the case Generators from Northwest region petitioned for a N/A July 9, 1996 two-year national capacity variance EPA extended the national capacity variance for an 62 FR 1992 January 14, 1997 additional six months until July 8, 1997 LDR became effective with three months of 62 FR 37693 July 14, 1997 capacity variance Court decision to vacate land disposal prohibition and treatment standards for two constituents N/A April 1998 (fluoride and arsenic) EPA gained four months to stay its mandate after filing a motion to move the court for a stay in May 63 FR 51254 September 24, 1998 1998 and promulgated an interim final rule Source: EPA,Land Disposal Restrictions—Background Document to Establish Effective Date for Amended Treatment Standards for Spent Aluminum Potliners(Proposed Rule) (2000),available at http://www.epa.gov/osw/hazard/tsd/ldr/kO88/landdisp.pdf. 29 Table A-2. Weather Conditions in Badin, NC 28009 before June 2014 Little Mountain Creek Sampling High Low Precip Snow Avg.Hi Avg.Lo Thu 910 710 0 in 0 in 850 660 6/19/2014 Fri 890 670 0 in 0 in 860 660 6/20/2014 Sat 870 690 0 in 0 in 860 660 6/21/2014 Sun 840 690 0 in 0 in 860 660 6/22/2014 Mon 830 670 0 in 0 in 860 670 6/23/2014 Tue 820 690 0 in 0 in 860 670 6/24/2014 Wed 880 710 0.01 in 0 in 860 670 6/25/2014 Thu 890 670 0 in 0 in 860 670 6/26/2014 Fri 870 690 0.02 in 0 in 870 670 6/27/2014 Source:ACCUWEATHEx.Com,Badin,NC Local Weather for June 2014, http://www.accuweather.com/en/usibadin-nc/28009/driving june- weather/2132788?monyr=6/1/2014&view=table. 30 Table A-3. SWMU 2 Monitoring Well and Piezometer Construction Details Table 3-2. Monitor-Well Construction Details ALCOA Sadin Warks Badin,Worth Carolina Well Elevation Casing Depth to Screened Depth sof Identification Ground Surface Elevadoa(TOC) interval from TOC Screened Interval M nasi) (t.m91) (ft) A mall ABL-MW-1 539.40 541.46 35-45 504.40-494.40 ABL-MW-2 538.73 541.04 37-47 501.73491.73 ABL-MW-3 476.52 478.46 4-14 472.52-462.52 ABL-MW-4 470.41 472.11 4-14 466.41-456.41 ABL-MW-5 467.08 468.75 4-14 463.08-453.08 ABL-MW-6 536.20 538.03 25-35 511.20-501.20 ABL-PZ-1S 537.00* 539.10 8-18 529.00-519.00 ABL-PZ-1I 537.00* 538.98 30-40 507.00-497.00 ABL-PZ-1D 537.00* 539.03 46-56 491.00-481.00 ABL-PZ-2S 532.00* 534.68 24-34 508.00-498.00 ABL-PZ-2I 532.00* 534.81 43-53 489.00-479.00 A13L-PZ-D 532.00* 534.93 60-70 472.00-462.00 ABL-PZ-3S 468.00* 470.37 3-8 465.00460.00 ABL-PZ-3I 467.00* 469.81 15-25 452.00-442.00 ABL-PZ-3D 4-67.00* 469.82 40-50 427.00417.00 ABL-PZ-4 477.13 479.63 5-15 472.13-462.13 ABL-PZ-5 512.24 515.50 37-47 475.24-465.24 ABL-PZ-6 525.24 529.37 45.8-55.8 479.44-469.44 ABL-PZ-10 481.35 484.12 10-20 471.35461.35 ABL-PZ-11 500.27 503.25 25-35 475.27465.27 ABL-PZ-12 526.14 530.24 42-52 484.14474.14 ft-fed md-meso sea kvd TGC-top of casing -approXMwe Source: GERAGHTY&MILLER,INC.,GROUNDWATER FLUX DETERMINATION ALUMINUM COMPANY OF AMERICA BADIN LANDFILL BADIN WORKS FACILITY BADIN,NORTH CAROLINA 22(1997)(included as Appendix A-4 of ALCOA,INTERIM MEASURES WORKPLAN,ALCOR-BADIN LANDFILL(SWMU#2), REGRADING AND COVER SYSTEM INSTALLATION(1997)). 31 Figure A-1. Groundwater Hydrographs for SWMU 2/13adin Municipal Landfill i R.o =Precipitation —MW-3 GW Elevation W en s M ENVIRCNEERINO,INC. m 3 n S GRDUND'NATERURE RYDPOGRAPN5 BADIx MUWCIPAL LANDFILL aw�x.xmmx cumuxn 174 1 3jp a Precipitation s —MW 1GWElevatian � s ENVIRCNEERINO,INC. e n IIBURE a7 �9�3 UROmWAHR HYPRWRAFNS BABIN MUNICIPAL LANDFILL I+NM�,HRNE FNGNn' RMIN.NRR1H CMOLINA 32 xss z _Precipitation z —MW-5 GW Elevation IWAIP IN A�mI a.�Iamn..Y,Q ns® ENVIRONEERINO,INC. S CRDUNDWAIERUHYDROGRkINS BADIN MUNICIPAL LANDFILL �GYNn BABiN.NBR1H tMOLINA a`mo Precipitation s —PZ-25 GW Elevation —PZ-2D GW Elevation res R 2ENVI PIONEERING,INC. 5 a FIGURE CRDUND BADIN MUNICIPAL LANDFILL BNMM"A- Source: TESTAMERICA,TESTAMERICA JOB ID:680-71611-1,Appendix I(2011)(included as Appendix H within ENVIRONEERING,INC.,PHASE 3—ENGINEERING DATA COLLECTION FOR THE CORRECTIVE MEASURES STUDY BADIN WORKS FACILITY BADIN,NORTH CAROLINA(2012)). 33 Figure A-2. Map of Alcoa Badin Works and NPDES Permit Discharge Locations h_ ! outfa114'k3 ` outrarfa R17JS12&tl1fISf1 ��_%.� �- l ,,yy r �kL Oudfall il2n J f t i` autrr Doxrsoz I,i�'r 5 n !>' •outfall OO+IIS44 l F ,��r n �� ' .�_ � i •;t ueeadfr _-. I! �1 r I r S f II r 1r I fi �'' •1 A/ f r �/ ,0`•, r/� VICINITY NAP Alcoa,Inc.-8adin Works /�/ N0004308/y Pummiv^ng Stream: 8adin Lake(Yadkin Ri"r)and SCALE UT to little Mountain Geek 1'24,000 Stream paSSifwat n: WS-Tv CA&B;and C 115G5 Quad�:FiBNE,F18NW P,wBarn: VadkenlPac Dee 8adin&New London,NC W-` SulrBasin 43-6708 iii Source:NPDES Permit No.NC0004308,originally issued Oct.25, 1995. Subsequent permit issued Feb.22,2008.Modified in 2010. 34 Figure A-3. SWMU 2 Soil and Groundwater Conductivity 4 • i / 4 A T LEG EIJC 604206 _ 604060 IUBD' Irlir, ri'Ll, r��' 6a3sa0 t SUM OF mSW L I RESULTS OF SUM OF } CONDUCTIVITY EM DATA 643660 - ?f. � SOIL AND GROUNDWATER -tri JIA: CONDUCTIVITY rt- SEE FIGURE 5B MULTIFRFQUENCYEM ` GEFOR RESULTS BAND IN LAANLDSFI L 603406 BADIN,NORTH CAROLINA SITE PLAN '.h''LE IJ -- 6U3200- 166'400 1664600 1664800 1665006 1665200 1665400 1665640 FIGURE 'MC STATE P LANAR C( R©NATES IS URYEY FEET) Geo4aluEions Ltd. Source: GEO SOLUTIONS LTD.,INC.,GEOPHYSICAL EVALUATION AT THE ALCOA POWER GENERATING,INC.YADKIN DIVISION SWITCHYARD AND THE SWMU No.2,ALCOA/BADIN LANDFILL,BADIN,NORTH CAROLINA 10(2008)(included as Appendix A within ENVIRONEERING, INC.,PHASE 3—ENGINEERING DATA COLLECTION FOR THE CORRECTIVE MEASURES STUDY BADIN WORKS FACILITY BADIN,NORTH CAROLINA(2012)). 35 Index for Electronic Appendix 1. Cover Letter&Report, N.C. Div. of Health Servs., Final Preliminary Assessment Report (1985). 2. NUS Corp., Preliminary Reassessment (1989). 3. A.T. Kearney, Inc. &DPRA, Inc., Interim RCRA Facility Assessment Report (1990). 4. Law Envtl., Phase II Ground-water Assessment Northwest Valley, Alcoa-Badin Works, Badin,North Carolina(1990). 5. Alcoa, Interim Measures Workplan, Alcoa-Badin Landfill (SWMU#2), Regrading and Cover System Installation (1997). 6. MFG, Inc., RCRA Facility Investigation Report, Volume I of II (2001). 7. Order of Hon. Sharon Armstrong in Alcoa, Inc. v. Accident& Casualty Company, Case No. 92-2-28065-SEA(Sup. Ct. Wash. King Cnty. 2003). 8. HDR Eng'g, Inc., Preliminary Findings &Recommendations Report- Mountain Creek and Little Mountain Creek and Jacobs Creek(2004). 9. Environeering, Inc., Phase 3—Engineering Data Collection for the Corrective Measures Study Badin Works Facility Badin,North Carolina (2012). 36