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NC0003468_Renewal (Application)_20160713
DUKE Dan River Combined Cycle ®, ENERGY, Duke Energy Carolinas 864 South Edgewood Road Eden, NC 27288 July 13,2016 Mr.Jeff Poupart RECEIVED/NCDEQ/DWR NC Division of Water Resources JUL 15 2016 NPDES Wastewater Unit 1617 Mail Services Center Water Quality Raleigh,NC 27699-1617 Permitting Section Subject: Duke Energy Carolinas,LLC Dan River Combined Cycle Station NPDES Permit No.NC0003468 Rockingham County Permit Renewal Application Dear Mr. Poupart: Duke Energy Carolinas,LLC(herein after"Duke")requests the subject permit be renewed and reissued. The above referenced permit expires on April 30,2017. This request for renewal is in addition to the currently pending request for modification of the subject NPDES permit. As mandated by North Carolina Administrative Code 15A NCAC 2H.0105(e),this permit application is being submitted at least 180 days prior to expiration of the current permit. Please find enclosed in triplicate,the renewal application,which includes the following items: • EPA Form 1 • EPA Form 2C • Site Map showing the location of all outfalls(internal and final) • Waste Flow chart and description of waste flows through facility in accordance with EPA Form 2C Item II- A(Attachment 1) • Narrative description of sources of pollution and treatment technologies in accordance with EPA Form 2C Item II-B(Attachment 2) • List of Potential items not covered by analysis in accordance with EPA Form 2C Item VI(Attachment 3) • Alternate Schedule Request for 316(b)(Attachment 4) Condition A(11)of the current permit for the Dan River Combined Cycle Plant(DRCC)requires that Duke request a continuation of its 316(a) variance beyond the term of the present permit. Enclosed is an EPA guidance letter dated August 11, 1988 outlining the general procedure to be followed in requesting the continuance of a 316(a) variance. The following is Duke Energy's response to the pertinent factors contained in the EPA general procedure for the reissuance of the 316(a)variance: 1. The permittee must request the variance be continued. Response: Duke hereby requests continuation of the 316(a)variance reflected in the reissued Permit for the Dan River Combined Cycle Plant 2. Plant operating conditions and load factors are unchanged and are expected to remain so for the term of the reissued permit. Dan River Combined Cycle Plant NPDES Renewal Application NC0003468 Rockingham County Response: The Combined Cycle plant operating conditions and load factors are unchanged and are expected to remain so for the term of the reissued permit. 3. There are no changes to the permittee's knowledge to the plant discharges or other discharges in the plant area which could interact with thermal discharges. Response: There have been no changes to the combined cycle plant discharges since the current NPDES permit issuance in 2013. 4. There are no changes to permittee's knowledge to the biotic community of the receiving water body which could impact the previous 316(a)determinations. Response: As demonstrated by Duke's environmental monitoring,since issuance of the current NPDES permit there have been no changes to the biotic community of Dan River which would impact the previous 316(a)determinations. Condition A(12)of the current permit requires that DRCC comply with the Cooling Tower Intake Structure Rule per 40 CFR 125.95. As allowed under§125.95(a)(2), Duke requests an alternate schedule for the submission of the applicable 3 16(b)information for Dan River. DRCC requests explicit coverage in permit to dewater the interstitial water in Ash Settling Basin through NPDES Outfall 002. DRCC is scheduled to replace the current oil and water separator(OWS). The current OWS discharges to a sump designated as Outfall 001A prior to mixing with other low volume waste in the wastewater sump to be discharged to Outfall 001 The new OWS will discharge to the makeup water tank for the Cooling Towers and then to Outfall 001. The compliance sampling for the new OWS will be moved to an outlet on the discharge side of the OWS. With reissuance, Duke requests the following modifications: • Duke is requesting the removal of Condition A(9)of the current permit. Condition A(9)requires that there be no discharge of plant waste to the pond unless the permittee to determine and report to the Division that there is sufficient free water volume equivalent to the equivalent to the sum of the maximum 24-hour plant discharges plus all direct rainfall and all runoff flows to the pond resulting form a 10-year,24-hour rainfall event when using a coefficient of 1.0 before. Since the decommissioning of the coal-fired units in October 2012. DRCC no longer discharges ash transport water,and there is no risk of overfilling. As a result the calculation is unnecessary. • Duke is requesting a variance for Total Suspended Solids(TSS)at NPDES Outfall 001 to accommodate for TSS concentrations in the intake water. • Duke is requesting the reinstatement of Former NPDES Outfall 009. Former Outfall 009 has been identified to have basin seepage (S-4) and stormwater runoff from the switchyard. The stormwater is processed through an oil trap tank prior to discharge. • Duke is requesting designation of Effluent Channels for Areas of Wetness (AOW)S-1, S-2 and S-3. This request is based upon a site visit on June 8, 2016 by Sherri Knight and Shuying Wang from the Winston- Salem Regional Office. S-1 is an effluent channel discharging directly to Railroad Branch. Duke is requesting a waiver from sampling requirements for S-1 based upon the access to this area, which is precarious at best. • Duke is requesting addition of Effluent Channels for AOWs, S-2 and S-3. These AOWs are defined channels that stretch from outside the ash basin to Railroad Branch. Duke is requesting the entirety of the feature be designated as an effluent channel. Duke is requesting waiver of sampling requirements for S-2 as it flows into S-3 prior to entering Railroad Branch. Dan River Combined Cycle Plant NPDES Renewal Application NC0003468 Rockingham County • Duke has previously notified the Department of two other AOWs S-6 and S-7 which do not discharge to waters of the state. Duke is not requesting that they be added at reissuance of the permit.These AOWs are areas along the toe of the dike that intermittently appear damp. There is a significant floodplain lip between this point and the river. There is no flow from this area to waters of the State. These AOWs were reviewed by DEQ on June 8,2016. Duke requests confirmation that no permit coverage is needed for these areas. Duke requests notification that this application is complete. Should you have any questions regarding this submittal or require additional information,please contact Joyce Dishmon at 336-394-5524 or email Jo_lce.Dishmon a duke_enerrtz .com. I certity under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations inc rely, ence Sparks -446 M 11-Regulated Stations Dan River Combined Cycle Attachments Cc: NCDEQ cc: Sergei Chernikov Joyce Dishmon,Sr Env Specialist Dana Newcomb,Sr ERS Field Support t=j1 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY 4"4(mow REGION IV 3I9 couRrumo srncur ATLANTA. Co :.*GRG70is5 August 11, 1988 REF: 4W1!-FP Mr. Clyde Baldwin ' Division of Water KY Natural Resources & Environmental Protection Cabinet Ebrt Boone Plaza 18 Reilly Road Frankfort, KY 40601 • RE: 316 Q 4dance for Permit Reissuance Dear r ldefi n: ens have arisen as to what procedures and activities are necessary in ng a permit for .a facility which has thermal limitations based on a previous variance granted under Section 316(a) of the Clean water Act. The following is provided as a follow-up to information provided at the February 1988, E'A/State meeting in Destin, Florida. A thermal variance granted under S316(a) terminates on expiration of the NPDES permit of which it is a part (Attachment A). Procedures for a reissuance are virtually unchanged frau an initial determination. The amount of data necessary to support the variance at the time of reissuance will probably be minimal. tionBowever, if qu conditions have changed materially, a significant ntity of informa- maY needed. NOTE: Tb the extent that permitter are unaware of these requirements, should be notified of than expeditiously so that they can be prepared The general procedure is as follows: 1. The permittee must request that the variance be continued, preferably at the time of permit application. At that time, he should provide a basis for that continuance. The basis could be as simple as: (a) plant operating conditions and load factors are unchanged and are expected to remain so for the term of the reissued permit, (b) there are no changes (to his knowledge) discharges or other dischargesedge) interact ract with the thermal discharges, in the plant site area which could to the biotic cdisch roof , �receiving are no changes (to his knowledge) y ng water body which would imact the previous 316 determinations. 2. If the permitting authority agrees with the basis, appropriate permit condi- tions would be developed; otherwise, additional data would be requested as needed. Request for additional data must be made within 60 days of receipt of the application (Answer to Question 7, Attachment A). Additional studies can be made a permit requirement if needed (Answer to Question 7). Page 2 August 11, 1988 3. The Fact Sheet/Rationale should contain a summary of 316 variance activities from the-previous permits (dates, determinations, limitations, etc. ) and an indication of the pr6posed basis for continuing the 316 variance. Sample language is included in Attachment 8. 4. The Public notice requirements are contained in S124.75(a). is also included in Attachment B. Sample language Should you have have questions or need assistance, feel free to contact me at 404/347-3012. Sincerely yours, C .L Charles H. Kaplan, P.E. National Expert Steam Electric/Water Enclosures • cc: Mr. R. Bruce.Scott • Identical letters sent to all states in Region IV • • „•• • ••,, . . Tv•-_„,wimi -- •.47,... .1.,..pi ‘ . , .....:40 ` ii . •• •.', .i :iiipir. r . a ... ,.._ . .•..,..•. .. , ..• ..... , , 4 :7/. •-. . t: -- Virr--de=ff.__ . ... -•.1P• ?;•: 4ito .iiiiel— bk. ". . ' ,i• - ..„4/4i. , .. .T. 4010. r pool- .. It .1.6 \EDE,• :. ''' . . .____•._ ___ ••• ..2 all&F..1 14___ 4%74 1,- .. •- ,' „ " t ' „co - ,... . ,r• • • .1 "-Iv iiii �' Qp �, . 'I '.Si•nt•'� 1 ;l • .. �' -4 'rte �� ` � � ��- y. y t ._,,l_... :11+,.___ 1 syr' { ,.._� .. � ,.. ...�_ _ _ t'r. ► ice. _f'Courie "i ` _ v 5 • 3 ' y F " ,t, 4031 . ' , .;-?-/ -' '4" , 2,-, -kn-,`,,1 -•• ;EDEN vi,. ,jl�`,./' t +`� •Sl._ �ll_..E�-_ 5 .. • -.. Dan River Combined ' - _1'-i I' t h ' ,t, Ash Basin • ; 1 �,.'' Cycle Station }�.�rt.. • a i is .t . , •••- .U" • Ponds) eNr : fah I` /I 001A' - ,, '....1 1,.I( "�!t'�7. 7 • / ` )) :002 I .._... ::_ V f ti •' Rey' t { ? �• "�` „..2 ••Y! 1•� it ,,t. T. ` . �r M••" • j Y _. '__I Dan River v'" =` D a ( c. Steam Station f; �� , t• 002A ' _s o t� 'ti :,, •. r S,—. r . / `001 ce+n 4 t l(��✓ 1,J_ li `i -l' 1 .. 5 ,%i Com,., .}t f w, �_ .A. ' A......, , 1,,,i ,,,, „,, i r.v....4 I* jr li: A e„:14 , .‘,, qp . .1 '1/4,cik r, I 5: -,,,, , ,,,, y ► .........!*S1 r y ,rr �,�[ '+ � . 15. C-e -\ _ �r %it\ ...,;t:t: . •ice , ._ A - ‘43-•• : . .‘, ... s - - (11 • , , 1: tv..:,,x} ..-Nr.......i,..., ) yj Note: It L' ,. 1” f[-.\- 1\ t D)7. 1.USGS 1 24K Scale Quadrangles r '+i Northeast Eden and Southeast Eden(NC) 7. . 2 Property line provided by Duke Energy Is L', h , > *- -s , r +` 1 j �(((� approximate •. , t , SCALE(FEET) � , '. .. L it OP,..' ` n Feet 11' I - ',. `�,°' �0. :.� ! •��,f i r../ Y;l1„• 0 1,000 2.000 4,000 N _ _ VC �l DATE DISCHARGE LOCATION MAP DUKE ENERGY December 15,2014 tile%t�DUKE NPDES Permit No: NC0003468 DAN RIVER STEAM STATION ENERGY. ROCKINGHAM COUNTY FIGURE= I'� NORTH CAROLINA L Please print or type in the unshaded areas only (fill-in areas are spaced for elite type,i.e., 12 characters/inch). For Approved OMB No. 2040-0086. Approval expires 5-31-92 FORM U.S.ENVIRONMENTAL PROTECTION AGENCY I. EPA I.D. NUMBER 1ifti cDAGENERAL INFORMATION F NCD024668535 T`A o Consolidated Permits Program GENERAL (Read the "General Instructions"before starting.) 1 2 13 14 15 LABEL ITEMS GENERAL INSTRUCTIONS If a preprinted label has been provided, I. EPA I.D. NUMBER affix it in the designated space.Review the information carefully; if any of it is incorrect, cross through it and enter the III. FACILITY NAME correct data in the appropriate fill-in area below.Also,if any of the preprinted data is absent (the area to the left of the label V. FACILITY PLEASE PLACE LABEL IN THIS SPACE space lists the information that should appear),please provide it in the proper fill- MAILING LIST in area(s) below. If the label is complete and correct, you need not complete Items I, III,V, and VI(except Vl-8 which must be completed regardless). Complete all items VI. FACILITY if no label has beenroved. Refer to the LOCATION instructions for detailed item descriptions and for the legal authorization under which this data is collected. II. POLLUTANT CHARACTERISTICS INSTRUCTIONS: Complete A through J to determine whether you need to submit any permit application forms to the EPA. you answer"yes"to any questions,you must submit this form and the supplemental from listed in the parenthesis following the question.Mark"X"in the box in the third column if the supplemental form is attached. If you answer"no"to each question,you need not submit any of these forms. You may answer"no"if your activity is excluded from permit requirements;see Section C of the instructions.See also,Section D of the instructions for definitions of bold-faced terms. SPECIFIC QUESTIONS MARK"X" MARK"X" YES NO FORM SPECIFIC QUESTIONS FORM ATTACHED YES NO ATTACHED A. Is this facility a publicly owned treatment works B. Does or will this facility (either existing or which results in a discharge to waters of the ❑ ® Elproposed) include a concentrated animal ❑ ® CIU.S.?(FORM 2A) feeding operation or aquatic animal production facility which results in a discharge 16 17 18 to waters of the U.S.?(FORM 28) 19 20 21 C. Is this facility which currently results in ❑ ® D. Is this proposal facility(other than those described ❑ m Eldischarges to waters of the U.S. other than in A or B above)which will result in a discharge those described in A or B above?(FORM 2C) 22 23 24 to waters of the U.S.?(FORM 2D) 25 26 27 E Does or will this facility treat, store, or dispose of F. Do you or will you inject at this facility industrial or hazardous wastes?(FORM 3) ❑ ® ❑ municipal effluent below the lowermost stratum Li ® ❑ containing, within one quarter mile of the well bore, underground sources of drinking water? 28 29 30 (FORM 4) 31 32 33 G. Do you or will you inject at this facility any H Do you or will you inject at this facility fluids for produced water other fluids which are brought to special processes such as mining of suffer by the the surface in connection with conventional oil or ❑ ® ❑ Frasch process,solution mining of minerals,in ❑ ® ❑ natural gas production, inject fluids used for situ combustion of fossil fuel,or recovery of enhanced recovery of oil or natural gas, or inject geothermal energy?(FORM 4) fluids for storage of liquid hydrocarbons? (FORM 4) 34 35 36 37 38 39 I. Is this facility a proposed stationary source J. Is this facility a proposed stationary source which is one of the 28 industrial categories listedwhich is NOT one of the 28 industrial categories ❑ ® El the instructions and which will potentially emit ❑ ® ❑ listed in the instructions and which will potentially 100 tons per year of any air pollutant regulated emit 250 tons per year of any air pollutant under the Clean Air Act and may affect or be regulated under the Clean Air Act and may affect located in an attainment area? FORM 5 40 41 42 or be located in an attainment are? FORM 5 43 44 45 III. NAME OF FACILITY c SKIP Dan River Combined Cycle Station 1 15 16-29 30 69 IV. FACILITY CONTACT A.NAME&TITLE(last,first, &title) B.PHONE(area code&no.) 2 Lawrence Sparks, GM Il-Regulated Stations 336 635 3080 15 16 45 46 48 49 51 52 55 V. FACILITY MAILING ADDRESS A.STREET OR P.O.BOX _ s 864 South Edgewood Road 15 16 45 B.CITY OR TOWN C.STATE D.ZIP CODE c Eden NC 27288 4 15 16 40 41 42 47 51 VI. FACILITY LOCATION A.STREET,ROUTE NO.OR OTHER SPECIFIC IDENTIFIER 5 864 South Edgewood Road 15 16 45 B.COUNTY NAME Rockingham 46 70 C.CITY OR TOWN D.STATE E.ZIP CODE F.COUNTY CODE s Eden NC 27288 079 15 16 40 41 42 47 51 52 54 EPA FORM 3510-1(8-90) CONTINUED ON REVERSE CONTINUED FROM THE FRONT VII. SIC CODES 4-di.it, in order of.riori A.FIRST B.SECOND C 4911 (specify) 7 (specify) 6 16 17 Electric Services 5 16 19 C.THIRD D.FOURTH c (specify) 7 (specify) 15 16 17 _ _ 15 16 19 VIiI. OPERATOR INFORMATION A.NAME B.Is the name listed in Item c Duke Energy Carolinas, LLC VIII-A also the owner? 8 18 19 55 E YES E]NO C.STATUS OF OPERATOR(Enter the appropriate letter into the answer box;if"Other,"specify.) D.PHONE_(area code&no.) F=FEDERAL M=PUBLIC(other than federal or state) P (specify) C 336 623 0238 S=STATE 0=OTHER(specify) Electric Utility A P=PRIVATE 56 15 16 18 19 21 22 25 E.STREET OR PO BOX 864 South Edgewood Road 26 55 F.CITY OR TOWN G.STATE H.ZIP CODE IX. INDIAN LAND C Eden NC 27288 Is the facility located on Indian lands? B ❑YES ® NO 15 16 40 42 42 47 51 X. EXISTING ENVIRONMENTAL PERMITS A.NPDES(Discharges to Surface Water) D.PSD(Air Emissions from Proposed Sources) s N ' NC0003468 s 1= 8 03455T30 Title V Air 15 16 17 18 30 15 16 17 18 30 B.UIC(Underground Injection of Fluids E.OTHER(specify) (Specify) C T ' C T 8 NCS000572 Industrial Stormwater 9 U 9 Permit 15 16 17 18 30 15 16 17 18 30 C.RCRA(Hazardous Wastes) E.OTHER(specify) (Specify) s R ' NCD024668535 s T 8 IUP 1013 City of Eden -Industrial 15 16 17 18 — 30 15 16 17 18 30 User Permit XI. MAP Attach to this application a topographic map of the area extending to at least one mile beyond property boundaries. The map must show the outline of the facility, the location of each of its existing and proposed intake and discharge structures, each of its hazardous waste treatment, storage, or disposal facilities, and each well where it injects fluids underground. Include all springs, rivers and other surface water bodies in the ma. area. See instructions for •recise re•uirements. XII. NATURE OF BUSINESS .rovide a brief descri.tion Natural Gas Fired Electric Generation XIII. CERTIFICATION (see instructions) I certify under penalty of law that 1 have personally examined and am familiar with the Information submitted in this application and all attachments and that, based on my inquiry of those persons immediately responsible for obtaining the information contained in the application, I believe that the information is true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibilit of fine and imprisonment. A.NAME&OFFICIAL TITLE(type or print) S,00 ATURE C.DATE SI NED Lawrence Sparks, GM II-Regulated Stations (214' %xL 1-a; r7j13JZ-cLo COMMENTS FOR OFFICIAL USE ONLY c C 15 16 55 EPA FORM 3510-1(8-90) EPA I.D.NUMBER(copyfrom Item 1 of Form 1) Form Approved. Please print or type in the unshaded areas only. NCD 02466853 5 AMB v -3. Approval l expires 3-31-98. FORM U.S.ENVIRONMENTAL PROTECTION AGENCY APPLICATION FOR PERMIT TO DISCHARGE 2C 4-,EPAEXISTING MANUFATER ACTURING,COMMERCIAL,MINING AND SILVICULTURE OPERATIONS NPDES Consolidated Permits Program I.OUTFALL LOCATION For each outfall,list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A.OUTFALL NUMBER B.LATITUDE C.LONGITUDE (list) 1.DEG. 2 MIN. 3.SEC. 1.DEG. 2.MIN. 3.SEC. D.RECEIVING WATER(name) 001 36 29 7.9 79 43 13.9 Dan River 002 36 29 30.1 79 42 39.6 Dan River II.FLOWS,SOURCES OF POLLUTION,AND TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility.Indicate sources of intake water,operations contributing wastewater to the effluent,and treatment units labeled to correspond to the more detailed descriptions in Item B.Construct a water balance on the line drawing by showing average flows between intakes,operations, treatment units,and outfalls.If a water balance cannot be determined(e.g.,for certain mining activities),provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures. B. For each outfall,provide a description of (1)All operations contributing wastewater to the effluent,including process wastewater,sanitary wastewater,cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3)The treatment received by the wastewater. Continue on additional sheets if necessary. 1.OUT- 2.OPERATION(S)CONTRIBUTING FLOW 3.TREATMENT FALL b.AVERAGE FLOW b.LIST CODES FROM NO.(list) a.OPERATION(list) (include units) a.DESCRIPTION TABLE 2C-1 Ash Basin Discharge Settling 002 est 1.003 MOD 1 U Stormwater through yard Sumps Neutralization est 0.59 MGD 2 K Dry Ash Stack Stormwater Runoff Discharge to Surface Water est 0.418 MGD 4-A Cooling Slowdown Surface Water 001 est 1.33 MGD 4-A Cooling Tower Slowdown Reverse Osmosis eat 1.17 MGD 1-S Chiller Cooling Tower Slowdown Ion Exchange est 0.07 MGD 2 J CT Plant Sumps Neutralization est 0.07 MGD 2 K Sanitary Waste Water Dechlorination est 0.003 MGD 2_E OFFICIAL USE ONLY(effluent guidelines sub-categories) EPA Form 3510-2C(8-90) PAGE 1 of 4 CONTINUE ON REVERSE CONTINUED FROM THE FRONT C Except for storm runoff,leaks,or spills,are any of the discharges described in Items II-A or B intermittent or seasonal? ❑YES(complete the following table) 121 NO(go to Section III) 3 FREQUENCY 4 FLOW a DAYS PER B TOTAL VOLUME 2 OPERATION(s) WEEK b.MONTHS a.FLOW RATE(in nigd) (specify it oh units) 1.OUTFALL CONTRIBUTING FLOW (speafs PER YEAR 1 LONGTERM 2 MAXIMUM 1 LONGTERM 2 MAXIMUM C DURATION NUMBER (mm) average) (spee1 fm'erage) AVERAGE DAILY AVERAGE DAILY (`n days) III.PRODUCTION A.Does an effluent guideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facility? 1-0 YES(complete Item III-R) ❑NO(go to Section I[) B Are the limitations in the applicable effluent guideline expressed in terms of production(or other measure of operation)? ❑YES(complete Item 111-(') NO(go to Section IV) C. If you answered'yes"to Item III-B,list the quantity which represents an actual measurement of your level of production,expressed in the terms and units used in the applicable effluent guideline,and indicate the affected outfalls. 1 AVERAGE DAILY PRODUCTION 2.AFFECTED OUTFALLS (list e.OPERATION,PRODUCT,MATERIAL,ETCoutfall a.QUANTITY PER DAY b UNITS OF MEASURE numbers) (specify) IV IMPROVEMENTS A Are you now required by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operations of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application'?This includes,but is not limited to, permit conditions,administrative or enforcement orders,enforcement compliance schedule letters,stipulations,court orders,and grant or loan conditions YES(complete the following table) ❑NO(go to Item IV-H) 1 IDENTIFICATION OF CONDITION, 2 AFFECTED OUTFALLS 3.BRIEF DESCRIPTION OF PROJECT 4 FINAL COMPLIANCE DATE AGREEMENT,ETC. a NO b.SOURCE OF DISCHARGE a REQUIRED b.PROJECTED North Carolina Coal Ash 002 Ash Sluice The act requires excavation of ash. 8/1/2019 8/1/2019 Management Act of 2014 B. OPTIONAL: You may attach additional sheets describing any additional water pollution control programs (or other environmental projects which may affect your discharges)you now have underway or which you plan.Indicate whether each program is now underway or planned,and indicate your actual or planned schedules for construction. ❑MARK'X'IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAMS IS ATTACHED EPA Form 3510-2C(8-90) PAGE 2 of 4 CONTINUE ON PAGE 3 EPA I.D.NUMBER(copy from Item I of Form I) CONTINUED FROM PAGE 2 NCD024668535 V.INTAKE AND EFFLUENT CHARACTERISTICS A,B,&C: See instructions before proceeding-Complete one set of tables for each outfall-Annotate the outfall number in the space provided. NOTE:Tables V-A,V-B,and V-C are included on separate sheets numbered V-1 through V-9. D. Use the space below to list any of the pollutants listed in Table 2c-3 of the instructions,which you know or have reason to believe is discharged or may be discharged from any outfall.For every pollutant you list,briefly describe the reasons you believe it to be present and report any analytical data in your possession. 1.POLLUTANT 2.SOURCE 1.POLLUTANT 2.SOURCE Asbestos Trace amount in insulation, wire coatings, and harnesses. Trace amounts may be washed down drains in plant area during maintenance activities. Strontium Trace elements occasionally Uranium found in coal. Vanadium Zirconium VI.POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS Is any pollutant listed in Item V-C a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? m YES(list all such pollutants below) NO(go to Item VI-H) The following substances may be contained in coal: Antimony Arsenic Beryllium Cadmium Chromium Copper Lead Mercury Nickel Selenium Silver Thallium Zinc **See Attachment 3 - Potential Discharges Not Covered by Analysis EPA Form 3510-2C(8-90) PAGE 3 of 4 CONTINUE ON REVERSE CONTINUED FROM THE FRONT VII.BIOLOGICAL TOXICITY TESTING DATA Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? ©YES(idents the test(s)and describe their purposes below) NO(go to Section VIII) Toxicity testing is performed as required by the station's current NPDES permit. The acute toxicity test is conducted and reported quarterly for the ash basin discharge (Outfall 002) . VIII.CONTRACT ANALYSIS INFORMATION Were any of the analyses reported in Item V performed by a contract laboratory or consulting firm? YES(list the name,address,and telephone number of,and pollutants analyzed by, ❑NO(go to Section IX) each.such laboratory arftrm below) A.NAME B.ADDRESS C.TELEPHONE D.POLLUTANTS ANALYZED (area code&no.) (list) Duke Energy Analytical Lab 13339 Hagera Ferry Road 980-875-5245 Metasls, COD, Ammonia, TEN, NC# 248 Huntersville, NC 28078 Nitrate-nitrite, TP, Oil & Grease, TSS, TOC, Bromide, Sulfate, Flouride Shealy Lab 106 Vantage Point Dirve 803-791-9700 Color, Sulifide, Sulfite, NC# 329 West Columbia, Sc 29172 Surfactants, Cyanide, Phenol, Volatiles, Semi-volatiles Acid compounds, PCBs, Mercury GEL, Inc. 2040 Savage Road 843-556-8171 Radiology NC# 233 Charleston, SC 29417 Pace Analytical 9800 Kincey Avenue, Suite 100 704-875-9092 BOD, Fecal Coliform NC# 633 Huntersville, NC 28078 Cape Fear Analytical 3306 Kitty Hawk Road, Suite 120 910-795-0421 Dioxins and Furans an affiliate of The GEL Group Wilmington, NC 28405 NC# 065-1519-1 IX.CERTIFICATION I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief,true,accurate,and complete.I am aware that there are significant penalties for submitting false information,including the possibility of fine and imprisonment for knowing violations. A.NAME&OFFICIAL TITLE(type or print) B.PHONE NO.(area code&no.) Lawrence Sparks, GM II-Regulated Stations (336) 635-3080 A URE D.DATE SIGNED oaf-et ek4 7 15/r-016, EPA Form 3510-2C(8-90) PAGE 4 of 4 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY.You may report some or all of this information EPA I.D.NUMBER(ropy from Ileo,I of/arm!) on separate sheets(use the same format)instead of completing these pages. SEE INSTRUCTIONS. I'`r`` ; "F r' r 1111111i OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) PART A—You must provide the results of at least one analysis for every pollutant in this table.Complete c•,e too e'or coo-ou'fal See,rstructio-s'or adds;cnal dela is 3.UNITS 4.INTAKE 2.EFFLUENT (.aped)fblank) (optional) b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM a.MAXIMUM DAILY VALUE (farm/ahle) (if available) AVERAGE VALUE 1.POLLUTANT t1) (1) d.NO.OF a.CONCEN- 1) b.NO OF CONCENTRATION (2)MASS CONCENTRATION (2)MASS (1)CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES a.Biochemical Oxygen <2 <15 1 mg/1 lb/Day Demand(1300) b.Chemical Oxygen 22 165.2 1 m lb/Day(COD) 9/1 c.Total Organic Carbon 8.4 4 63.1 1 m 1 lb Da (rut) g/ lb/Day d.Total Suspended Solids(TV) 1.7 12.8 1 mg/1 lb/Day e.Ammonia(a‘11) 0.132 1.0 1 mg/1 lb/Day VALUE VALUE VALUE VALUE f.Flow 0.9 0.7 0.6 365 MGD N/A g.Temperature VALUE VALUE VALUE VALUE (arguer) 23.2 °C h.Temperature VALUE VALUE VALUE VALUE (summer) °C MINIMUM MAXIMUM MINIMUM MAXIMUM ,: ..), .: `-, .`a, i.pH 4-47 N STANDARD UNITS N PART B— Mark"X"in column 2-a for each pollutant you know or have reason to believe is present.Mark"X"in column 2-b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly, or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 2 MARK"X" 3.EFFLUENT 4.UNITS 5 INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM AVERAGE AND a b a.MAXIMUM DAILY VALUE (f available) (t/available) VALUE CAS NO. BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (if available) PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES a.Bromide (24959-67-9) X <0.10 <0.8 1 mg/1 lb/Da b.Chlorine,Total X/ <0.05 <0. m 4 1 1 Da Residual /\ g/ lb/ c.Color X 20.00 N/A N/A N/A 1 Std Unit N/A N/A d.Fecal Coliform X 11.00 N/A N/A N/A 1 CFU/100 N/A N/A e.Fluoride / \ (16984-48-8) X 0.28 2.1 1 mg/1 lb/Da f.(asitte-Nitrite X 2.00 15.0 1 mg/1 lb/Da EPA Form 3510-2C(8-90) PAGE V-1 CONTINUE ON REVERSE ITEM V-B CONTINUED FROM FRONT 2.MARK'X' 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM AND a b, a.MAXIMUM DAILY VALUE (if available) (j available) AVERAGE VALUE CAS NO. BEUEVED BEUEVED (1) (1) (1) d.NO.OF a.CONCEN- -- (1) b.NO.OF (lavmlable) PRESENT ABSENT CONCENTRATION (2)MAN SS CONCENTRATION RE )MASS CONCNTRATKkI (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES Total Organic(a: X 1.10 8.3 1 mg/1 lb/Da M / \ bh.OlandGrease X <5.00 <37.6 1 mg/1 lb/Da . I.Phosphorus `X(Ms P),Total 1.98 14.9 1 mg/1 lb/Da gra-1448 , I.Radk achity (1)Alpha,Total X <5.00 N/A N/A N/A 1 pCi/1 N/A N/A (2)Beta•Tod X 9.91 N/A N/A N/A 1 pCi/1 N/A N/A To Radium, X <1.00 N/A N/A N/A 1 pCi/1 N/A N/A Raaun228 X <1.00 N/A N/A N/A 1 pCi/1 N/A N/A Total k.SWMa X 140.00 1051.5 1 mg/1 lb/Da I.Sulfide X <1.00 <7.5 1 mg/1 lb/Da m.Wile 30.4 X <2.00 <15.0 1 mg/1 lb/Da (14285-45-3) n.Sudaclnta X 0.063 U.S 1 mg/1 lb/Da o.Nahum, X TOS 0.033 0.2 1 mg/1 lb/Da (1429-90.5) 0otal X 0.005 0.5 1 mg/1 lb/Da (� 2-8)) X 0.379 2.8 1 mg/1 lb/Da `.Cobalt.Total X <0.001 <0.008 1 mg/1 lb/Da (744648-4) a.Iron, g4.3041943)Total 0.386 2.9 1 mg/1 lb/Da LX Total 12.80 96.1 1 mg/1 lb/Da (7439-95-4) . T.Molybdenum, X Tod 0.00359 <0.03 1 mg/1 lb/Da (743698-7) T.Manprwtae, X Total <0.005 <0.04 1 mg/1 lb/Da (7439-865) Total (70- 4 X <0.01 <0.1 1 (1stns..Tot mg/1 lb/Da X Titanium. X Tots <0.005 <0.04 1 mg/1 lb/Da (7440-324) EPA Form 3510-2C(8-90) PAGE V-2 CONTINUE ON PAGE V4 EPA I.D.NUMBER(ropy from lien I ofForm I) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NCD024668535 001 PART C- R you area primary industry and this outsell contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark'X'in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toric metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries,nonprocess wastewater ouffals, and nonrequlred GCAt1S fractions),mirk IC in column 2-b for each pollutant you know or have reason to believe is present Mark"r in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant you must provide the results of at least one analysis for that pollutant If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it w0-be discharged In concentrations of 10 ppb or greater.If you mark column 2b for autleir,acrylonItrie,2,4 dinieophenol,or 2-mety1-4,6 dlnibophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greeter.Otherwise,for pollutants for vdch you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant Is expected to be discharged.Note that there are 7 pages to this part please review each carefully.Complete one table(ell 7 pages)for each ounall.See instructions for additional details and requirements. 2.MARK'X' 3.EFFLUENT 4.UNITS 5.INTAKE(apnoea° 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. - a.LONG TERM AND a. b. c a.MAXIMUM DAILY VALUE Of available) VALUE(fava;/able) AVERAGE VALUE CM NUMBER TESTING BELIEVED BEUEVEO (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF Of evadable) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES. TRATION b.MASS CONCENTRATION (2)MASS ANALYSES METALS,CYANIDE,AND TOTAL PHENOLS 1M.Antimony,Total 0440380) /�X/ 6.58 0.05 1 ug/1 lb/Da (72)'T0es X <1.0 <0.01 ' 1 ug/1 1 lb/Da �M �)m,TOW �/ <1.0 <0.01 1 ug/1 lb/Da 4M.Cadmium,,TOW /X <0.1 <0.001 1 ug/1 lb/Da (7440-43-9) /� TTotel Chromium-3) X <1.0 <0.01 1 ug/1 lb/Da BM.Copper,Total X <0.005 <.0001 1 ug/1 lb/Da (7440-509) (7439-92-1)� °W X <1.0 <0.01 1 ug/1 lb/Da (7(743 ) 9M. X 0.478 0.004 1 ug/1 lb/Da Nickel,Total (7440-02-0) X 4.7 0.04 1 ug/1 lb/Da 1011.Selenium, Total(7762-49-2) X <1.0 <0.01 1 ug/1 lb/Da (7440-M. i Total X <1.0 <0.01 1 ug/1 lb/Da 12M.Thallium, Tod(71402840) X <0.0002 <.0001 1 mg/1 lb/Da 13M. 7th.02464)Total X 0.023 0.17 1 mg/1 lb/Da 14M.Cyanide, Total(57-12-5) X <0.010 <008 1 . - m 1 lb 9/ Da/ Total ate X 0.0058 0.04 1 mg/1 lb/Da DIOXIN 2,3,7,8-7en. \ / DESCRIBE RESULTS DYomdas¢o-P- ,X\ Dbtln(1784-015) EPA Form 3510-2C(8-90) PAGE V-3 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2.MARK IX' 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE a LONG TERM AVRG. a.LONG TERM AND a. b. e. a.MAXIMUM DAILY VALUE ((available) VALUE(tfavadable) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (If available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS (107-00224)) X <5 <0.04 1 ug/1 lb/Da (107-16 X , <5 <0.04 1 ug/1 lb/Da ene (71-43-2) X <2 <0.02 1 ug/1 lb/Da 4V.BY(Chloro- "a0i+'0 EtherX 1 ug/1 lb/Da (542-061) 5V.Brom (26262) X <2 <0.02 1 ug/1 lb/Da BV.Crbon X Tide <2 <0.02 1 ug/1 lb/Da (56-23-5) N.CNrobenzene X <2 <0.02 3. ug/1 lb/Da (10640-7) 8V.CNro4F bronaneelane X <2 <0.02 1 ug/1 lb/Da (124461) _ _ . (N' aneX (25004) I <2 <0.02 1 ug/1 lb/Da 10V.2-Cbino- rhyMny1 Ether X <5 <0.04 1 ug/1 lb/Da (110-754) 11V.CMnablm X (5746-3) 4.3 0.03 1 ug/1 lb/Da - . 12V.Dknlaro- a°"a"ed1B"° X <2 <0.02 1 ug/1 lb/Da (75-274) 13V.Dkllro- ds1p1' 0 °a'B^e X <2 <0.02 1 ug/1 lb/Da (2671-B) 14V.w.waa(5-0I�g, X <2 <0.02 1 ug/1 lb/Da 15V. o- et ne(10-062) X <2 <0.02 1 ug/1 lb/Da 1W1 1'te(753 ) X <2 <0.02 1 ug/1 lb/Da 17V.1,2-OkNlao- 2 <0.02 1 u 1 lb/Da propane(76 < 87.5) _ X g/ 18V.1.3-DicMao- - . poPArle X <2 <0.02 1 ug/1 lb/Da (542-75-6) 18V.EMylbenzene X <2 <0.02 1 ug/1 lb/Da (100.414) 20VBrwSdeMethyl(74-83-9) X 1 <2 I <0.02 1 ug/1 lb/Da 21V.Methyl X <2 <0.02 1 ug/1 lb/Da L Chloride(74474) EPA Form 3510-2C(690) PAGE V-4 CONTINUE ON PAGE V5 CONTINUED FROM PAGE V-4 2.MARK'Ir 3.EFFLUENT 4.UNITS 5.INTAKE(optiona0 1.POLLUTANT b.MAXIMUM 30 DAY VALUE a.LONG TERM AVRG. a.LONG TERM AND a. b. a a.MAXIMUM DAILY VALUE (if available) VALUE(ifavoilable) AVERAGE VALUE CAS NUMBER TESTING BEUEVED BELIEVED d.NO.OF a.CONCEN- b.NO.OF (if available) REQUIRED, PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION ANALYSES TRATION b.MASS (1) ANALYSES R)M0.55 CONCENTRATION (2)MASS CONCENTRATION (2)MA55 GC/MS FRACTION-VOLATILE COMPOUNDS(continued) 22V.MeMe(/5ne X <2 <0.02 1 ug/1 lb/Da 23V.1a,22- TMvdYaoemne X <2 <0.02 1 ug/1 lb/Da (79-345) 24V.TeheWdo- X <2 <0.02 1 ug/1 lb/Da ethylene(127-144) 25V.Tdoane (10&88-3) X <2 <0.02 1 ug/1 lb/Da 28V.1,2-Trans 060-00-5)DMOmmIhylene X <2 <0.02 1 ug/1 lb/Da 2W 1,1,1 o- X <2 <0.02 1 ug/1 lb/Da ethane(1 M1-588)-55.8) 28V'1,1,2-Tnchloro- X <2 <0.02 1 ug/1 lb/Da ethane(7400.5) 2WTmMbro- stlnyNns(78-01-0) X <2 <0.02 1 ug/1 lb/Da 3W.TrMiawo- awranelharo X <2 <0.02 1 ug/1 lb/Da (15494) 31v.Vinyl Chloride X <2 <0.02 1 ug/1 lb/Da (75-014) GC/MS FRACTION-ACID COMPOUNDS 1A.2CMoropand X <10 <0.08 1 ug/1 lb/Da (95-574) M.2,4.Ordllao- X <10 <0.08 1 ug/1 lb/Da phenol(120442) 3A.2'4Dlmetly- X <10 <0.08 1 ug/1 lb/Da phenol(10547-9) 4A.4,4DY4so-0- X <10 <0.08 1 ug/1 lb/Da Cresol(53452-1) pA.henl(51-28- X <10 <0.08 1 ug/1 lb/Da phMnal(51-28-5) 8A 2-Mwphenol X <10 <0.08 1 ug/1 lb/Da (88-75-5) 7k4-wbap enol X <10 <0.08 1 ug/1 lb/Da (100-02-7) SA PClaoro-M X <10 <0.08 1 ug/1 - lb/Da Cresol(59-50-7) 9A Pentadauo- X <10 <0.08 1 ug/1 lb/Da phenol(87-86-5) (0-005-2) X 10*.Phenol h n <10 <0.08 1 ug/1 lb/Da _ HA 2,4,8-TridYao- X <10 <0.08 1 ug/l lb/Da petrol(88052) /� EPA Form 3510-2C(8-90) PAGE VS CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2.MARK IC _ 3.EFFLUENT 4.UNITS 5.INTAKE(apnaal) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c a.MAXIMUM DAILY VALUE (faiailable) VALUE Of available) AVERAGE VALUE CAS NUMBER TESTING BEUEVED BEUEVED (t) (1) (1) d.NO.OF a.CONCEN- -(1) b.NO.OF Of available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—BASE/NEUTRAL COMPOUNDS 1E.Aae aplltie e (8332-9) 213.Acenap4M4eiw (208-9&9) 35.Meracene (120-12-7) 48.Bemldne (92-87-5) 5B.Benzo(a) ( 5-3) BB.Benzo(a) Pyierr(50-32-8) 78.34-Bei¢o- 5uaenlMne (205-99-2) 8B.Baso We) Peiylene(191-242) 99.Benzo(k) Fluonmehene 108.Bit(2-Chloro- Stay)Methane (111-91-1) 118.Ma(2Cblaa- erhy0 Ether (111444) 128.BM(2- CAloronopropy8 Ether(102-80-1) 138.Ms(2-Ethyl- bet Phthalate (117-81-7) 148.4-Bramapheiyl Phenyl Ether (101-55-3) 158.Butyl Beazyi PhtnalMe(85.88-7) 168.2-Chloro-naphthalene (913&7) 178.4-Chloro- phenyl Phenyl Eller (7005-72-3) 188.CSyune (218-01-9) 198.Obenzo(a A) ( Mtlracene (5370.3) j I 208.1,2-Dichloro- benzene(95-50-1) 218.1,3-DI-dikm benzene(541-73-1) EPA Form 3510-2C(8-90) PAGE V3 CONTINUE ON PAGE V-7 CONTINUED FROM PAGE V-S 2.MARK IC 3.EFFLUENT 4.UNITS S.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a b. a a.MAXIMUM DAILY VALUE (f available) VALUE(11amiable) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVEDd.NO.OF S.CONCEN- b.NO.OF (iiavailable) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (1) ANALYSES TRATION b.MASS (1) ANALYSES (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS GCAIS FRACTION-BASE/NEUTRAL COMPOUNDS(cmmnaed) 229.1,40aLlary benzene(108-48-7) 238.3,3 DkNpo- hen:lane(91-94-1) 248.Diethyl Phthalate(8488-2) • 258.Dbaln4 Phthalate (131-11-3) • 284.DI-N-Butyl Phthalate(84-74-2) 278.2,4-DItto- tohane(121-14-2) 288.Z8-Dinitro- blame(80620-2) 298.DI-NOctyl Phthalate(11744-0) 308.1.2-DI henyl- hytrezMe(as Aro- benzene)(122-067) 318.Recrentlans 328.FMaene (8673-7) 338.Hslmdaoro- bamene(118-74-1) 348.Hbudibro- butadlene(87-88-3) 358.He a•dYao- cyclopentabene (77474) 388 HeucNao- ethane(87-72-1) 378.Inaenn (1,$3-cd)Pyrene (196365) 388.Ieoploone (76561) 398.Naphthalene (91-20-3) 408.Nbmbauene (96963) 418.N-Nlbe- — - — scdknethyY1Nne (82.754) 4213.N-Nlhowtll- N-PropyIan ne (821-047) EPA Fonn 3510-2C(690) PAGE V-7 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2.MARK'X' 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT ' b.MAXIMUM 30 DAY VALUE o.LONG TERM AVRG. a.LONG TERM AND a. b. a a.MAXIMUM DAILY VALUE (if available) VALUE(if available) AVERAGE VALUE CAS NUMBER TESTING BEUEVED BELIEVED CO (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF Of available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—BASE/NEUTRAL COMPOUNDS(aonnme4 43B.N-Nibn- ecelphanYlanila (8630-0) 44B.PYhahativaa — (65-014) 45B.Pyrene (129-00-0) 46B.1,2,4Trl- chlarobanzene (120.62-1) GC/PAS FRACTION—PESTICIDES 1P.Alddln �/ (308062) X 2P.a-BHC �/ (318-04-8) _ X 9P.5-BHC �/ . (31985-7) — /� , 4P.T-BHC �/ (58-89-9) X 5P.5-BHC �/ (319868) X OP.CMarda a v _ . (57-748) 7P.4,4'-DOT (50.293) 8P.4,4'-DOE X (72.55-8) 9P.4A'-DDD X (72-54-8) 10P.Deaden X (60.57-1) _ 11P.a-EnosuKan \/ (115267) X 12P.5-Endmultah 1 v (11529-7) /� 13P.EndmNM Sulfate • X (1031-07-8) 14P.Biotin �/ (72-268) X 15P.Endo Aldehyde (7421-93-4) . 18P.Heptachlor �/ I (76444) i /� EPA Form 3510-2C(8-90) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from hem I of FonnI) OUTFALL NUMBER NCD024668535 001 CONTINUED FROM PAGE V-8 2.MARK'X' 3.EFFLUENT _ 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND b. a a.MAXIMUM DAILY VALUE (Ifavailable) VALUE((1avadable) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (if available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION—PESTICIDES(continued) 17P.Heptachlor Epoxide X (1024-57-3) 42 (5348921-9)) X <0.25 <0.002 ug/1 lb/Day 254 (11097-89-1) X <0.25 <0.002 ug/1 lb/Day 2C41.PCB-1221 <0.25 <0.002 u /1 lb Da (11104-28-2) X 9 lb/Day 21P. 5) 4/1 lb/Day <0.25 <0.002 u ( X 22P.72-298)) X 9/1 lb/Day <0.25 <0.002 u (128672-28 (111196 2-5)� X <0.25 <0.002 ug/1 lb/Day 24P.PCB-1016 (1257411-2) X <0.25 <0.002 - I ug/1 lb/Day 25P.( 1T3Sa X <0.25 <0.002 eam ug/1 lb/Day EPA Form 3510.2C(8-90) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY.You may report some or all of this information EPA I.D.NUMBER(copy from Item I of Form I) on separate sheets(use the same format)instead of completing these pages. NCDO 24668535 SEE INSTRUCTIONS. OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 ofFoml2-C) 002 PART A—You must provide the results of at least one analysis for every pollutant in this table.Complete one table for each outfall.See instructions for additional details. 3.UNITS 4.INTAKE 2.EFFLUENT (sped'if blank) (optional) b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM a.MAXIMUM DAILY VALUE (ifavailahle) (if available) AVERAGE VALUE (1) (1) d.NO.OF a.CONCEN- (ll b.NO.OF 1.POLLUTANT CONCENTRATION (2)MASS CONCENTRATION (2)MASS (1)CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES a.Biochemical Oxygen 5.6 9.3 1 mg/1 lb/Day Demand(BOD) b.Chemical Oxygen <20 <30 1 mg/1 lb/Day Demand(('OD) c.Total Organic Carbon 2 3 3.8 1 mg/1 (TOO d.Total Suspended Solids(Th.S) 11 55 1 mg/1 lb/Day e.Ammonia(as N) 0.35 1.75 1 mg/1 VALUE VALUE VALUE VALUE f.Flow 0.2 0.6 0.2 3 MGD N/A g.Temperature VALUE VALUE VALUE °C VALUE (winter) h.Temperature VALUE VALUE VALUE VALUE (summer) 17.1 °C MINIMUM `MAXIMUM MINIMUM !MAXIMUM i.pH 7,95 I STANDARD UNITS PART B— Mark"X"in column 2-a for each pollutant you know or have reason to believe is present.Mark"X"in column 2-b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly,or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.VALUE a.LONG TERM AVERAGE AND a b. a.MAXIMUM DAILY VALUE (if available) 01-available) VALUE CAS NO. BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) -- b.NO.OF (1.1.available) PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES a.Bromide (24959-67-9) X <0.1 <0.5 1 mg/1 lb/Da b.Chlorine,Total X/ 0.03 0.15 1 mg/1 lb/Da Residual /� c.Color X 10 N/A N/A N/A 1 std unit N/A N/A d.Fecal Coliform X 333 N/A N/A N/A 1 CFU/100 N/A N/A e.Fluoride X (16984-48-8) 0.29 1.45 1 mg/1 lb/Da f. (asite Nitrite X <0.01 <0.05 1 mg/1 lb/Da EPA Form 3510-2C(8-90) PAGE V-1 CONTINUE ON REVERSE ITEM V-B CONTINUED FROM FRONT 2.MARK'X' 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT I I b.MAXIMUM 30 DAY VALUE 1 a LONG TERM AVRG.VALUE a.LONG TERM AND a. b. a.MAXIMUM DAILY VALUE (if available) (if available) AVERAGE VALUE CAS NO. BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) - b.NO.OF (ifavvilable) 'PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES g.Nitrogen, Tad ( X 0.38 1.94 1 mg/1 lb/Da M hGOl maed X <5 <25 1 mg/1 lb/Da i.Phosphorus ` , (as P).Total /�[\ 0.037 0.185 1 (772414-0) mg/1 lb/Da I.RRdbnaltal- (1)Ngla,Total X <3.8 <19.0 1 pCi/L N/A • (2)Bata,TOW X 15.6 78.1 1 pCi/L N/A Todd' X <0.242 <1.211 1 pCi/L N/A + (4 Ton 228. X 0.694 3.473 1 pCi/L N/A tol kSi e (as So.) X 65 325 1 mg/1 lb/D (14808-79-8) I.aS) X 1.0 5.0 1 mg/1 lb/D m.Sure ( X (cu <2.0 <10.0 1 mg/1 lb/D (14285453) . n.Surfactants X <0.05 <0.25 1 mg/1 lb/D o.Aluminum. X Total 0.296 1.481 1 mg/1 lb/Da (7429-90-5) . P.Bakim,Total (7440-39-3) X 0.167 0.836 1 mg/1 lb/Da (7� 2-88)) X 0.238 1.191 1 mg/1 lb/Da r.Cobalt,Tad X <1.0 <0.002 1 ug/1 lb/Da (7440-48-4) (743Bb9--8948) /�)1 (7 X 0.288 1.441 1 mg/1 lb/Da L Magnesium. X - Tod 7.87 39.38 1 mg/1 lb/Da (743495-4) u.Mr- tionum, X Tod 53.9 0.09 1 ug/1 lb/Da (7434847) v.Mrgrnre, X Tod 0.150 0.751 1 mg/1 lb/Da (7439-983) al (74 0-315) X <0.01 <0.05 1 mg/1 lb/Da - X Tltsrum, X Tod 0.013 0.065 1 mg/1 lb/Da (7440-32-8) EPA Form 3510.2C(8-90) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(ropy from Item I ofFonn I) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NCD024668535 002 PART C- If you area primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark'X"in column 2-a for all such GC/MS fractions that apply to your Industry and for ALL Mxic metals,cyanides,and total phenols. If you are not required to mark column 2-a(secondary industries,nonprocess wastewater Duffal's, and nonrequired GC/MS fractions),mark"X"In column 2-b for each pollutant you know or have reason to believe is present.Mark"X'in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant If you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for aaoleln,acrybnibie,2,4 dinibophend,or 2-metyl-4,6 dinibophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part please review each carefuly.Complete one table(all 7 pages)for each outfall. See instructions for additional details and requirements. 2.MARK le 3.EFFLUENT 4.UNITS 5.INTAKE(oprioeaO 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c a.MAXIMUM DAILY VALUE (ifavaiable) VALUE(ifawn/able) AVERAGE VALUE CAS NUMBER TESTING BEUEVED BELIEVED 0) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (iifavailable) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES METALS,CYANIDE,AND TOTAL PHENOLS 1M'""b"10ny'Tote/ X 13.2 0.02 1 ug/1 lb/Day (7440.38-0) CM�M8-2)'Total X/ 17.9 0.03 1 ug/1 lb/Day Vim,Total /X <1.0 <0.002 1 ug/1 lb/Day (7440-41- MA.Cadmium,Toni X <0.1 <.0001 1 ug/1 lb/Day (7440-43-9) SM.Chromium, 002 1 0 <0. Total(7440-47-3) X <1. mg/1 lb/Day OM.Copper,TOS X <0.005 <.0001 1 ug/1 lb/Day (7440-508) v (7499e'1)°o� X <1.0 <0.002 1 ug/1 lb/Day 'Taal X 0.939 <.0001 1 ng/1 lb/Day 9M(74.Nickel, TOS X 2.42 0.004 1 ug/1 lb/Day Toff.Selenium, X 4.38 0.007 1 ug/1 lb/Day Total(7782-49.2) 11M.Slyer,(744622-4)TOt°l X <1.0 <0.002 1 ug/1 lb/Day Total(440-28O) X 0.261 0.004 1 ug/1 lb/Day 13M.Zinc,(744046-6)TotalX 0.005 0.008 1 mg/1 lb/Day 14M.Cyanide, Total(57-12-5) X <0.01 <0.05 1 m 1 lb/Day Y 15M.Phenols,Phenols, X 0.016 0.080 1 mg/1 lb/Day DIOXIN 2,37,8-Tetra- DESCRIBE RESULTS Result- <10 pg/L - Procedure for preparation, analysis and reporting of analytical data are controleed by Cape Pear Analytical LLC rod dlbibenzo-P- �/ (CPA) Standard Operating Procedure (SOP). The data discussed has been analyzed with CR-QA-P-002 REVS 14. Raw data reports areprocessed and Oloxln(178401-6) ,/�` reviewed by analyst using the Targetbynx software package. EPA Form 3510-2C(8-90) PAGE V-3 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2.MARK'X' 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. c. a.MAXIMUM DAILY VALUE (if available) VALUE(Javailable) AVERAGE VALUE CAS NUMBER TESTING BEUEVED BEUEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF Of available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS (107@b8 X <5.0 <0.008 1 ug/1 lb/Day 2((107-1 yonivile X <5.0 <0.008 1 ug/1 lb/Day (71.-4 2a1)11a X <2.0 <0.003 1 ug/1 lb/Day 4V.BM(Chloro- want)- [\ ( 61) ,� (5421) (7 625-YB ) X <2.0 <0.003 1 ug/1 lb/Day eV.Carnal X - TetraalaaMs <2.0 <0.003 1 ug/1 lb/Day (5623-5) (10686 X <2.0 <0.003 1 ug/1 lb/Day _ - 8V.Chloradl- bmnomeelMM X <2.0 <0.003 1 ug/1 lb/Day (124461) (75-000-3C.hlo)��o X <2.0 <0.003 1 ug/1 lb/Day 1W.2CNato- - ' (11°6'75-a)Ether X <5.0 <0.008 1 ug/1 lb/Day (87Chloroform 48-3) X <2.0 <0.003 1 ug/1 lb/Day 12V.DkNao- bmnomelbane X <2.0 <0.003 1 ug/1 lb/Day (75-27-4) _ 13V.DiWao- lone X <2.0 <0.003 1 ug/1 lb/Day (75-71-8) . 14V.ethan (7 X <2.0 <0.003 1 ug/1 lb/Day 1 (70072) X <2.0 <0.003 1 ug/1 lb/Day 1 X <2.0 <0.003 1 ug/1 lb/Day 17V.t,z 7#974) �/ <2.0 <0.003 1 ug/1 lb/Day PtWale(7687s /� - 18V.1,3.00to- ProPNene X <2.0 <0.003 1 ug/1 lb/Day (542-758) . 19V.Emybenzene X <2.0 <0.003 1 ug/1 lb/Day (100414) 20V' X <2.0 <0.003 1 ug/1 lb/Day Bromide(74-83-9) 21V.Metu lX <2.0 <0.003 1 ug/1 lb/Day Chloride(74-87-3) EPA Form 3510-2C(8-00) PAGE V-4 CONTINUE ON PAGE V-5 CONTINUED FROM PAGE V-4 2.MARK'X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a, a e a.MAXIMUM DAILY VALUE ((Vavadoble) VALUE(ifawdable) AVERAGE VALUE CAS NUMBER ' TESTING BELIEVED BELIEVED (1) (I) (1) O.NO.OF a.CONCEN- (1) b.NO.OF (ffavallable) REDUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (1)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ALYSES GC/MS FRACTION-VOLATILE COMPOUNDS(continued) Cl�iaMeld'flhaoere z) X <2.0 <0.003 1 ug/1 lb/Day 23V.1.1.2.2- TMaaeNoe2ane X <2.0 <0.003 1 ug/1 lb/Day (79345) _ 24V.Tatrathlolo- <2.0 <0.003 1 u /1 lb/Day 25VX 4 'Tole X <2.0 <0.003 1 ug/1 lb/Day (108883) 24V.1.2-Trane- It�rre X <2.0 <0.003 1 ug/1 lb/Day � hioro- (71-55-8)) X <2.0 <0.003 1 ug/1 lb/Day 28V.1.7.2-Tidiono- X <2.0 <0.003 1 ug/1 lb/Day ethane(78085) - 29Vethylene(799--01-8) X <2.0 <0.003 1 ug/1 lb/Day . 30V.TrkNmo- Buwoai.mne X <2.0 <0.003 1 ug/1 lb/Day (75-081) 37v.Vinyl Chloride X <2.0 <0.003 1 ug/1 lb/Day (75-014) /� GC/MS FRACTION-ACID COMPOUNDS 15-574) ophend X (115572) <1.6 <0.002 1 ug/1 lb/Day - 2A 24Dkliaro- X <1.6 <0.002 1 ug/1 lb/Day phenol(720-032) - 3A2,4DYnelhyF X <1.6 <0.002 1 ug/1 lb/Day phenol(10547-9) aA 4.8-Mi-o-0. X <8.0 <0.01 1 ug/1 lb/Day Cresol(53452-1) - 5A2.1(DInlbo- phenol(51-285) X <6.0 <0.01 1 ug/1 lb/Day SA.2-Nitraphenol X <3.2 <0.005 1 ug/1 lb/Day (88-755) - 7A 4N8raphMnl X <8.0 <0.01 1 ug/1 lb/Day (10902-7) - BA.P-05bro-M) Crawl(59587) X <1.6 <0.002 1 ug/1 lb/Day 9A' D' X <8.0 <0.01 1 ug/1 lb/Day phenol(8748-5) - (0k Phenol )d 08 X <1.6 <0.002 1 ug/1 lb/Day 1 - 77A2(88.05311ao- X <1.6 <0.002 1 ug/1 lb/Day phenol(84082) EPA Form 3510-2C(8-90) PAGE VS CONTINUE ON REVERSE CONTINUED FROM THE FRONT - 2.MARK'X" 3.EFFLUENT 4.UNITS S.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE a LONG TERM AVRG. a.LONG TERM AND s. b. c. a.MAXIMUM DAILY VALUE Of available) VALUE((favailable) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) cl.NO.OF a.CONCEN- (1) - b.NO.OF (ifavailable) REQUIRED PRESENT( ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS 18.Acenaphthene (83-32-9) 213.Aornaphtylene (208-988) 3B.MBvacene (120-12-7) 48.Working - (92-87-5) 58.Benzo(a) - Nahracene (56-55-3) BB.Bono(a) - PyrMla(50328) 78.$4Benco- 205-9BRnle ( (20599.2) 88.Bane Wu) PayiNM(191-242) 96.Benzo(k) Fluoranthene (20788-91 10B.BM(1-Chlmo- etbaxy)Methane (111-91-1) 118.BM(2-Chloro- ethyl) 2-CMoroetbyl Ether (111444) 128.BM(2- Yl) Ether(102-80-1) 13B.BM(2-Ethyl- Hyl)Phthalate (11781.7) 148.4-Bromophenyl Phenyl Ether (101-55-3) . 158.Butyl Benzyl - - Phthalate(85-857) 168.2-Chloro- naphthalene (91-567) 178.4-Chlao- - phenyl Phenyl Ether (7005-72-3) 188.Chysene (21301-9) 1913.Dibenzo(ab) Anthracene (53703)70-3) 208.1,2-Dichloro- barwne(95-50-1) _ 21B.1,3-Di-chloro- benzene(541.73-1) _ EPA Form 3510-20(880) PAGE V-6 CONTINUE ON PAGE V-7 CONTINUED FROM PAGE V-S 2.MARK'X' 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT - b.MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a.LONG TERM AND a. b. a a.MAXIMUM DAILY VALUE (Ifavailable) VALUE(ifaeatlaNe) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (ifavailable) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GCAAS FRACTION—BASE/NEUTRAL COMPOUNDS(calibrated) 22B.1,4-Dldlloro- benzene(103-48-7) 238.3,3-Oldildo- bem ilne(91-841) 248.Diethyl Phthalate(84-88-2) 258.Dimethyl Phthalate (131-114) 28B DH4Butyl Phthalate(84-74-2) 27B.2,4-Dinlbo- toluene(121-14-2) 28B.2,11-petro- — Muene(806-20-2) • 298.DH4Octyl MINIM*(117-84-0) • 30B.1,2-Dlpheny4 hydrazine(aa Aw- bersane)(122-68-7) 318.FMomthee (20&44-0) 328.FMeene (88-73.7) • 338.Hendlbro- benzene(118-74-1) • 348.IleaetSo- butaaleoe(87-884) 358.Hexadeoro- _ - (yclopentadlene (77474) 388 He uddeo- Mane(87-72-1) 37B.Indeno (1,2,3-cm Pyrene (19339-5) 38B.laophorone (78.59-1) • 3998.Naphthalene (91-20-3) 409.Nitrobenzene (98-953) 41B.N-Nlbo- aodimethylamine (62-759) N-Propylmine (621-04.7) EPA Form 3510-2C(8-90) PAGE V-7 CONTINUE ON REVERSE CONTINUED FROM THE FRONT 2.MARK IC 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE a LONG TERM AVRG. a.LONG TERM MID a. b. a a.MAXIMUM DAILY VALUE Of available) VALUE(If available) AVERAGE VALUE CAS NUMBER TESTING BEUEVED BELIEVED (1) d.NO.OF a.CONCEN- b.NO.OF (/amiable) REQUIRED PRESENT ABSENT CONCERATION (2)MASS CONCENTRATION (1) ANALYSES TRATION b.MASS It) ANALYSES (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MARS GC/PAS FRACTION-BASE/NEUTRAL COMPOUNDS(commuted) 438.N-Nitro- eodpllen)WNre (88304) 448.Phenanthrene - (85-014) - 458.Pyrene (12800-0) - 488.1,2,4-Td- - - ddorabenzam (120-02-1) GC/MS FRACTION-PESTICIDES 1( 2) X <0.04 <.0001 1 ug/1 lb/Day 0ceBHC 1 ) X <0.04 <.0001 1 ug/1 lb/Day 0188887) X <0.04 <.0001 1 ug/1 lb/Day (5y9 X <0.04 <.0001 1 ug/1 lb/Day (3139468) X ' <0.04 <.0001 1 ug/1 lb/Day e5.Chlordane (5744-9) X <0.4 <.0007 1 ug/1 lb Da g/ lb/Day 70-.4.4-DDT X (5029.3) <0.04 <.0001 1 ug/1 lb/Day 8(0-Y 4,4c)DE X <0.04 <.0001 1 ug/1 lb/Day (72-54-8)911. X <0.04 <.0001 1 ug/1 lb/Day ( U1) X I <0.04 <.0001 1 ug/1 lb/Day (1152-7)°a8°n X <0.04 <.0001 1 ug/1 lb/Day (111 5-28.7 X <0.04 <.0001 1 ug/1 lb/Day, 13P.Endomdfan X Sulfate <0.04 c.0001 1 ug/1 lb/Day (1031-074) (7 2p�8)� X <0.04 <.0001 1 ug/1 lb/Day 151'.Endrin Aldehyde X <0.04 <.0001 1 ug/1 lb/Day (7421-934) - 18P.Haplachlor (7644-8) X <0.04 <.0001 1 ug/1 lb/Day EPA Form 3510-2C(8.90) PAGE V-S CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-e NW024668535 002 2.MARK sr 3.EFFLUENT 4.UNITS 5.INTAKE(optional) 1.POLLUTANT b.MAXIMUM 30 DAY VALUE C.LONG TERM AVRG. a.LONG TERM AND a. a a a.MAXIMUM DAILY VALUE (Ifavailable) VALUE(loyal/able) AVERAGE VALUE CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d.NO.OF a.CONCEN- (1) b.NO.OF (((available) REQUIRED PRESENT ABSENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS ANALYSES TRATION b.MASS CONCENTRATION (2)MASS ANALYSES GC/MS FRACTION-PESTICIDES(continued) 17P.HaptathI \ / Epoxlda X <0.04 <.0001 1 ug/1 lb/Day (10245X 73) - (5346921-9) X <0.4 <.0007 1 ug/1 lb/Day 1 (1109744411 54 X <0.4 <.0007 1 ug/1 lb/Day x0P.1104.2 2) X <0.4 <.0007 1 u /1 ` (11104.28-2) ^ 4 lb/Day 211232 <0.4 <.0007 1 u /1 lb/Day X9 22P.1 02672--296) X <0.4 <.0007 1 ug/1 lb/Day I 228 /� 23P.PCB-1260 (11096.82-5) X <0.4 <.0007 1 ug/1 lb/Day 24P.PCB-1016 (12674-11-2) X <0.4 <.0007 1 ug/1 lb/Day 2apbene <0.4 0007 1 (8001-35-2) X <. ug/1 lb/Da Y EPA Fan 3510-2C(8-90) PAGE V-9 Attachment 1 Form 2C—Item Il-A Description of Waste Flows Through Facility Evapowtw LOS '3247 31 Condenser e— 'Coding Tower wro _I111 — Water Supply Municipal0140 >I Potable Users >I Wastewalre terS t 1JI Sanitary 2 Closed Cooling W„" ing 2 CIPM 111 02 so Eveporame Low W'" W"' Blow Donn Sump < OM teppm Ev.pgretwlaW Chiller Coll Condnate A 18A '� " H D°min Cleaning West Neutralization Tank 60 PPM Chiller System K 20 I apm _ I A " ) Filtered Wear Storage app UltreFiltretion n Reverse Osmosis Storage Tank 35 JI HRSG cora Ms am ..., I I x 014m 70 Portable.Mixed. Bed 70 °°m IS Wm Damn Traria; I Wm V V V V weV a m Makeup Clarification Fire Protection bp%> Misc Uses >I Oil Separatordisharge Outing 001A)I Ws Pint Sumps A A ( m S I W turn °M° t° Sludge Thickener Filler 12 ° Orin CT Wash Water Press rpm Treat entDi Site WTreatment/Disposal A A 05 4MCD 4335 rpm own Intake Screen BackwashV Dan River Dry Basin Storm Water DRSS Plat Storm Water Outfall 001 o s 1 Chiller System Sumps Raps Runoff 6MDD OPII 0.411 0.007 VMS •D I e00� Ash Basin I(Mo0 Sumps V V I` Seeps Outfall 002 Outfall 002A vas* 1.0 MOD vatWeEmorpay Combs ---00 Separator(Outfall OO1A)Replacement Project - Current outfall discharges into Wastewater Sump to Outfall 001 - Replacement system will discharge into Cooling Tower Basin to be used as CCW makeup - Project projected to begin July 2015 with projected completion in October 2016 Attachment 2 Form 2C—Item Il-B Flows,Sources of Pollution,and Treatment Technology Introduction The Dan River Combined Cycle (CC) Station, located in Rockingham County, North Carolina, consists of two General Electric 7FA gas turbine generators with a General Electric D1 Steam Turbine. The nominal output for this facility is 620 MW. Prior to October 2012, the plant operated three coal—fired generating units and three Combustion Turbines. These units were retired once the CC block came online and are currently undergoing demolition. The CC Station operates separately and independently from the retired coal Plant. However, some auxiliary systems(water intake and NPDES Outfalls)are shared between the two plants. The CC Station pumps water from the Dan River via 3 raw water pumps to the Graver clarifier. Water is withdrawn from the Dan River, as required,. to makeup evaporative and blowdown losses. Coagulant(ferric sulfate), polymer (flocculant), sodium hydroxide (pH control), and sodium hypochlorite (disinfection) are added to the raw water. Water from the clarifier is further treated through gravity filters. Filtered water is stored in the Fire Water/Service Water Tank(approximately 350,000 gallons) for fire protection, used as makeup water to the heat recovery steam generator(HRSG), and/or various other plant functions and cooling tower basin(approximately 1 million gallons) for makeup of condenser cooling water. Chemical constituents contained in the discharge from the permitted outfalls will, in part, be representative of the naturally-occurring chemical quality and quantity of the intake water and will also have chemical constituents of such quality associated with similar discharges for fossil generating facilities of the size, type, and in this geographical location. Either all or part of the elements in the Periodic Table, either singularly on in any combination,may from time to time be contained in the discharge. All plant waste streams are directly or indirectly discharged to the Dan River or hauled off site for disposal. Each component of the discharges are described below. Outfall 001—Combined Cvcle Power Block Outfall 001 is the gravity flow discharge from the Combined Cycle Wastewater Sump (CCWS)to the Dan River. Various wastewater streams combine in the CCWS prior to discharge. These flows consist of cooling tower blowdown, oil and water separator discharge (Internal Outfall 001A), treated domestic sewage, Ultrafiltration backwash, reverse osmosis (RO)/Portable demineralizer trailer rinse down, RO cleaning waste, and fire (service) water/demineralizer tank overflow and drainage. Cooling Tower Blowdown Condenser cooling water(CCW) is supplied through filtered water sent to the ten cell cooling tower basin. This water is recirculated and cycled with approximately 5% makeup added hourly to account for blowdown and evaporation loss. Sodium hypochlorite is added to the CCW for disinfection/biological growth control, a dispersant/corrosion inhibitor is added for water chemistry parameter monitoring on the tower and corrosion inhibition,and a small amount of defaming agent is added to prevent foaming issues. A blowdown stream averaging around 400 gpm is used to maintain concentration of total dissolved solids in the cooling tower to within proper operating limits. Sodium bisulfite is added to the blowdown stream prior to discharge into the CCWS for chlorine removal. During cooling tower maintenance, the cooling tower basin may be drained to various levels, including emptied. Depending on the activity, the cooling tower basin water may be partially or fully routed through the blowdown line for dechlorination or through retention basins/tanks for dechlorination and discharge out Outfall 001. Oil and Water Separator(Internal Outfall 001A) All powerhouse building floor drains and all outside oil filled equipment drains are piped to an oil and water separator(OWS). These waste streams include small quantities of chemicals used for process water analyses and closed cooling water system. The closed cooling water system is approximately 21,000 gallons and contains propylene glycol as a coolant and a corrosion inhibitor. The powerhouse building floor drains can receive input from spillage/leakage of various chemical and equipment, floor wash water, and maintenance activities. The following are examples of materials that are stored/used inside the powerhouse: ammonium hydroxide, hydrazine, propylene glycol, new/used lube oil, kerosene, diesel fuel, phosphate, corrosion inhibitors, industrial cleaning products,and miscellaneous lab chemicals. The current OWS discharges to Internal Outfall 001A collection sump prior to gravity flow to CCWS. Compliance samples are collected from the Internal Outfall 00IA collection sump. The current OWS will be replaced beginning in July 2016 with completion of the project projected for October 2016. Upon completion, the new discharge of the new OWS will be to the cooling tower basin and will be used in CCW makeup water. Compliance sampling location for Outfall 001A will be on the discharge side of new OWS. Treated Domestic Sewage Sanitary wastes are treated by an aeration treatment package plant consisting of bar screen, aeration tank, clarifier, chlorine contact chamber, and a sludge holding tank. After chlorination via sodium hypochlorite tablets,treated water discharges to the CCWS. UF Backwash Portable demineralizer trailer backwash and RO rinse water During normal demineralized (demin) water demand periods, the RO system runs every 8 hours with a 4 hour break in-between. On initial startup the RO system has to rinse down to be in the optimum operating conductivity range. The rinse water produced during this initial startup is discharged to the CCWS. When the RO is operating,the UF system typically backwashes every 3040 minutes. This consists of about 135 gallons per minute (gpm) of backwash wastewater being discharged to the CCWS for approximately 2 minutes. During high demin water demand periods, portable demin trailers are brought in to supply additional demineralized water. These trailer have to be rinsed in. Approximately 70 gpm of rinse water is discharged to the CCWS during rinse in. When the portable demin trailer has been exhausted or is no longer needed,the trailer is drained to the CCWS. RO Cleaning Waste The RO system is normally cleaned once a quarter. This cleaning consist of an acid cleaning, a caustic cleaning,and treatment utilizing a biocide. The cleaning waste is sent to the neutralization tank and treated with acid/caustic for pH control. Upon neutralization,the waste is discharged to the CCWS. Service Water/Fire Water Storage Tank and Demineralizer Water Storage Tank Over/low/Drain Periodically,maintenance will need to be performed on the Service Water/Fire Water Storage Tank and the Demineralizer Water Tank. This maintenance will require the water from the storage tanks to be drained to the CCWS. Service Water/Fire Water has been treated via clarification, filtration and addition of ferric sulfate for coagulation, sodium hydroxide for pH control, sodium hypochlorite for disinfection, and polymer for flocculation. Demineralized water is service Service Water/Fire Water that has undergone ultrafiltration,reverse osmosis,and mixed bed demineralization. HRSG Slowdown HRSG makeup water is drawn directly from the Service Water/Fire Water tank. In addition to clarification and filtration, HRSG makeup water undergoes ultrafiltration, reverse osmosis, and mixed bed demineralization. UF uses citric acid and sodium hypochlorite. RO utilizes an antiscalant, sodium hydroxide for pH control, and sodium bisulfate for dechlorination. HRSG makeup water is treated with ammonium hydroxide for pH control, and oxygen scavenger, and phosphate for corrosion inhibition. Water in the HRSG blowdown sump is pumped to the cooling tower basin to be used for CCW makeup water. Other waste streams that flow to the HRSG blowdown sump via various drains throughout the station:auxiliary boiler blowdown,Ultrafiltration(UF)acid cleaning and bleach cleaning waste and reverse osmosis(RO)concentrate Chiller Blowdown The chiller system is utilized during the late spring and summer months to increase power output of the gas turbines by cooling the incoming air. The chilled water, which is a 33% mixture of propylene glycol and water has a system total capacity of approximately 65,000 gallons, is supplied by a chiller plant. The warmed water exiting the cooling tower is returned to the chiller plant to be recycled and cooled. 2,000 gallons of refrigerant is utilized in the chiller plant system. The cooled water exiting the chiller system consists of approximately 20,000 gallons of clarified and filtered water that is treated with sodium hypochlorite for biological control and a dispersant/corrosion inhibitor added for water chemistry parameter monitoring. The cooling water system side of the chiller tower has a blowdown stream(chiller blowdown)of approximately 32 gpm that is utilized to maintain water chemistry within the tower at proper operating limits and discharged into the cooling tower basin to be used in CCW makeup water. Prior to the winter months, the cooling water side of the chiller system is laid up utilizing approximately 150 gallons of a sodium hydroxide based layup chemical which is pumped into the cooling water side of the system consisting of approximately 20,000 gallons,circulated and drained to the cooling water tower basin. Combined Cycle Industrial Wastes for Offsite Disposal Clarifier Sludge Sludge is removed from the clarifier via sludge pumps and sent through a thickener tank where additional polymer is added. Once thickened,the sludge is sent through a plate and frame filter press for dewatering and to an industrial landfill for disposal. Potentially,this material may be used for beneficial use in brick making. Gas Turbine Compressor Wash Each combustion turbine unit is equipped with a 6,000 gallon compressor wash water sump. Periodically, the combustion turbines receive an on line or off line compressor wash. This activity involves injecting water with a mild detergent into the compressor section of the turbine and subsequent rinse cycles. The off line wash generates approximately 4,000-5,000 gallons of waste water per turbine. This activity occurs between 3-5 times per year per turbine. Wash water is pumped out by a certified third party waste disposal company for offsite disposal Chiller Sumps The chiller plant has two chiller sumps, where chilled water(propylene glycol/water mixture)drains from maintenance activities and normal operation. These sumps are monitored on a daily basis. Chiller sump is pumped out by a certified third party waste disposal company for offsite disposal. Outfall 002—Ash Basin Coal-Fired Units The coal-fired units were decommissioned in April 2012. Upon retirement of the coal fired units, waste streams from processes which historically went to the ash basins are no longer generated. Waste streams from closure activities may be sent to the secondary basin until April 2017. Per the Coal Combustion Residual Regulation,all discharges to the basins must be re-routed by April 2017. Stormwater Run0lf The secondary ash basin accommodates stormwater flows from the yard drainage sump and basin watershed area including the drainage area of the Dry Stacks (approximately 77 acres.). The average stormwater run-off flows are based on 44 inches of rain per year with 100%run-off from the basin surfaces and 50% run-off from other areas. The average run-off for the ash basin watershed area is 0.418 MGD. The coal yard drainage drains to the yard drainage sump and is then pumped to the ash basin. The coal yard has an average run-off of 0.007 MGD. This run-off is based on 44 inches of rain per year with 50% run-off. A filtration treatment skid will be installed at the yard drainage sump to remove Total Suspended Solids (TSS)from the stormwater. The installation is scheduled to begin in July and completed by October 2016 Upon completion, the treated stormwater will be pumped to Outfall SW009 under Industrial Stormwater Permit NCS000572. Stormwater from the basin drainage area will be re-routed for collection and discharge to the City of Eden under an Industrial User Permit #1013. The water re-direct project is scheduled to begin in August 2016 andbe completed in February 2017. Chemical Additions to the Ash Basin Small volumes of aluminum sulfate (alum), ferric sulfate, and miscellaneous polymers are infrequently added directly to the ash basin to encourage coagulation and flocculation, thus controlling suspended solids. Sulfuric acid, sodium hydroxide and CO2 injection are used for pH control. Some ongoing chemical additions may be required to manage waste streams from closure activities,including dewatering. Dewatering At the present time Duke Energy is expecting to discharge the wastewater generated from the removal of ash (including dewatering of ash basins to allow excavation and dewatering of excavated ash prior to loading onto trucks or rail cars) from the site through the current Outfall 002. It is anticipated that as dewatering proceeds some additional treatment may be needed to meet permit discharge limits at Outfall 002. Former Outfall 009 Area has been identified to have basin seepage and the switchyard stormwater runoff which is processed through an oil trap tank that is discharged through this outfall. During the review of NPDES stormwater permit application dated August 1, 2014, DEQ staff indicated that this outfall would be covered in the reissued NPDES wastewater permit. Attachment 3 Form 2C—Item VI Potential Discharges Not Covered by Analysis Location Chemical Quantity Frequency Purpose _ Water treatment 60%Ferric 5000 gal tank As needed Coagulant _ (Clarifier) Sulfate/Ferralyte 8130 Water Treatment 25%Sodium 3000 gal tank As Needed pH control (Clarifier) Hydroxide Water Treatment 12.5%Sodium 6000 gal tank As Needed disinfection (Clarifier) Hypochlorite Water Treatment Nalclear 7768 400 gal tote As Needed flocculant (Clarifier and Thickener Tank) Water Treatment PolyClean 7 5 gal pails As Needed Polymer pump (Polymer Pumps) cleaning solution Cooling Tower 3D Trasar 3DT187 2000 gals tank As needed Dispersant/corrosion (shared with Chiller inhibitor Tower) Cooling Tower 12.5%Sodium 6000 gals tank As needed Disinfection/biological (shared with Chiller Hypochlorite growth control Tower) Cooling Tower Trasar 3DT199 110 gal tote As needed Corrosion inhibitor (shared with Chiller Tower) Cooling Tower Nalco 7468 5 gal pails As needed Defoamer Chiller System DOWFROST HD 63000 gals Circulated, Cooling Agent (propylene glycol) (system) closed system Chiller System Dupont SUVA 123 2000 gals Circulate, Refrigerant closed system Chiller System NalPrep IV 200 gals 1/year Layup Chemical Closed Cooling Water 33%Propylene 21000 gals As needed Cooling Agent Glycol (system) Closed Cooling Water Nalco C-4710 5 gal pail As needed Corrosion Inhibitor Demineralizer Bldg 38%Sodium 330 gal tote As needed Dechlorination (RO and Cooling Tower bisufte Blow down) Demineralizer Bldg 25%Sodium 330 gal tote As needed pH control (RO system) hydroxide Demineralizer Bldg 50%Citric acid 350 gal tote As needed OF acid cleaning (UF system) Demineralizer Bldg(UF 12.5%sodium 330 gal tote As needed OF bleach cleaning system) hypochlorite Demineralizer Bldg AntiscalantPC- 110 gal tote As needed Corrosion inhibitor (RO system) 191T Demineralizer Bldg RoCide DB20 150 ml 1/quarter or as Biocide (RO cleaning biocide) needed Demineralizer Bldg RoClean P303 96 lbs 1/quarter or as RO acid cleaning (RO cleaning) needed Demineralizer Bldg RoClean P111 96 lbs 1/quarter or as RO caustic cleaning (RO cleaning) needed Aux Boiler Bldg 19%Aqueous 330 gal tote As needed pH control (HRSG Water) Ammonia Aux Boiler Bldg Eliminox 75 gal tote As needed Oxygen scavenger (HRSG Water) Unit 9 HRSG phosphate Trisodium 300 gal tank As needed Corrosion Inhibitor skid phosphate (HRSG Water) Unit 8 HRSG phosphate Trisodium 300 gal tank As needed Corrosion Inhibitor skid phosphate (HRSG water) Steam Turbine Bldg 19%Aqueous 350 gal tote As needed pH control (HRSG Water) ammonia Selective Catalytic 19%Aqueous 20000 gal tank As needed NOx emissions Reduction ammonia reduction Treated Domestic Bio-sanitizer 135 lbs As needed Disinfection/biological Sewage Tablets growth control (Calcium Hypochlorite) Ash Basin 25-50%Sodium 250 gal tote As needed pH control hydroxide _ _ Ash Basin Sulfuric Acid 250 gal tote As needed pH control Ash Basin Compressed CO2 Cylinders As needed pH control Attachment 4-Alternate Schedule Request§316(b)of the Clean Water Act Dan River Steam Station Final regulations to establish requirements for cooling water intake structures at existing facilities were published in the Federal Register on August 15, 2014 (i.e. regulations implementing§316(b) of the Clean Water Act)with an effective date of October 14, 2014. Per§125.91(a)(1)-(3)Applicability,the Dan River Steam Station is subject to the requirements at §125.94 through §125.99 (316(b) requirements) based on the following: — The facility is defined as an existing facility; — The facility has a point source discharge; — The facility uses a cooling water intake with a design intake flow (DIF) of greater than 2 million gallons(MGD)to withdraw water from waters of the U.S.;and — Twenty-five percent or more of the water withdraws on an actual intake flow basis are exclusively used for cooling purposes. Per §125.98(b) Permitting requirements, 316(b) requirements are implemented through the NPDES permit. The 316(b) application submittal timeframe for Dan River Steam Station is established under §125.95(a)(2),which states: "The owner or operator of a facility subject to this subpart whose currently effective permit expires prior to or on July 14, 2018, may request the Director to establish an alternate schedule for the submission of the information required in 40 CFR 122.21(r) when applying for a subsequent permit..." As allowed under §125.95(a)(2), Duke Energy requests an alternate schedule for the submission of the applicable 316(b) information for Dan River. Per§122.21(r)(1)(ii), the following information must be submitted for all existing facilities: §122.21(r)(2)Source Water Physical Data §122.21(r)(3)Cooling Water Intake Structure Data §122.21(r)(4)Source Water Baseline Biological Characterization Data §122.21(r)(5)Cooling Water System Data §122.21(r)(6)Chosen Method(s)of Compliance with Impingement Mortality Standard §122.21(r)(7) Entrainment Performance Studies §122.21(r)(8)Operational Status The actual intake flow (AIF), as well as the design intake flow (DIF), for Dan River Steam Station is less than 125 million gallons per day (MGD); therefore, the additional information requirements under §122.21(r)(1)(ii)(B) Existing facilities greater than 125 MGD AIF are not applicable to Dan River Steam Station. In the preamble to the rule, EPA states "... for many facilities, it may take as long as 39 months to plan, collect, compile the date and studies required to be submitted with the permit application.." and further states"This timeframe will be adequate for facilities under 125 MGD." Duke Energy,therefore, requests the 316(b) information for Dan River Steam Station to be submitted on or before December 27, 2017(i.e. 39 months from the effective date of the rule). Even though the station was subject to the remanded Phase II 316(b) Rule and prepared draft documents as required by the remanded rule, significant changes were made between the remanded Phase II Rule and the recently finalized 316(b) rule. In addition,significant modifications to the operation of the station have occurred since the remanded Phase II Rule. An alternate schedule, therefore, is justified. A summary of the changes are as follows: — Information requested in §122.21(r)(2), (3), and (5)was required under the remanded rule; however, these documents were not finalized due to the timing of the court ruling. In addition, the operations at Dan River Steam Station have substantially changed since the remanded rule. Units 1-3 have retired= and the generation was replaced with a 637 MW combined-cycle unit with closed-cycle cooling. — Additional Information is requested in §122.21(r)(4) that was not requested in the remanded rule.The additional information includes: o Identification of protective measures and stabilization activities that have been implemented, and a description of how these measures and activities affected the baseline water condition in the vicinity of the intake; and o A list of fragile species at the facility. — Information requested in §122.21(r)(6) – r(8) is new and data must be compiled and evaluated to complete these submittals. Duke Energy is not planning on collecting any new biological data on the source water, or conducting impingement or entrainment studies at the cooling water intake structure and has not been asked to do so by North Carolina Department of Environmental Quality(NCDEQ). Existing biological data will be used to complete §122.21(r)(2) Source Water Physical Data and §122.21(r)(4) Source Water Baseline Biological Characterization Data. Furthermore, with the station utilizing a closed-loop recirculating system, a design through-screen velocity of less than 0.5 feet per second (fps), and a DIF of less than 12 MGD, which equates to a small percentage of the annual mean flow of the Dan River, Duke Energy intends to demonstrate the existing technologies at Dan River Steam Station meet the best technology available (BTA)standard for both impingement and entrainment mortality. 1 Refer to Fed. Reg.Vol.29.No. 158,dated August 15,2014,p.48359 Units 1 and 2 were retired prior to the remanded Phase II 316(b)Rule.