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HomeMy WebLinkAboutNC0001422_Mod of App_20150120 DUKE L.V.Sutton Energy Complex ENERGY® 801 Sutton Steam Plant R Wilmington,NC 284011 PROGRESS o:910.341.4750 f:910.341.4790 January 20, 2015 Mr. Jeffrey O. Poupart NCDENR-DWR, Wastewater Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: Duke Energy Progress, Inc. L. V. Sutton Energy Complex NPDES Permit NC0001422 Application Update in Response to NCDENR Notice of Modification Dear Mr. Poupart: Duke Energy Progress (DEP) hereby provides this update to the NPDES permit application, originally submitted on July 28, 2014 in response to DENR's Notice of Modification dated March 14, 2014. We have also included the Major NPDES Modification fee of$1032.00. This application update includes sample data for Outfall 001, as requested by your office, to complete EPA Form 2C, Section V. The cooling pond at Sutton Plant has not discharged through Outfall 001 since November 5, 2013. Therefore a representative sample was collected inside the outfall structure of the cooling pond. As you are aware, DEP is planning to remove coal combustion residuals (CCR) from the site in the near future. We plan to discharge the wastewater generated by the dewatering and removal of ash from the site through existing Outfall 004. We have characterized the wastewater to be generated by sampling free water and entrapped, or interstitial, water in the ash basins. The attached document provides an overview of our intended dewatering process and definitional language regarding the wastewaters to be generated through this process. We expect that the free water will meet current NPDES permit limits, but that additional treatment may be needed as dewatering proceeds. RECEIVEDIDENRIDWR JAN 2 3 2015 Water Quality Permitting Section L.V.Sutton Electric Plant NPDES Permit NC0001422 Update in Response to NCDENR Notice of Modification Page 2 Thank you, in advance for your consideration of the above-requested items. If there are any questions concerning this submittal, please contact either: • Ms. Toya Ogallo, Environmental Specialist at our North Carolina Regional Headquarters, phone (919) 546-6647 or email Letova.Opalloe-duke-energy.com, or • Mr. Kent Tyndall, Environmental Rrofessional for the L. V. Sutton Energy Complex Plant; phone (910) 341-4775 or e-mail Kent.TvndallCaD-duke-energy.com. /certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. /am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Sincerely, Allen A. Clare Station Manager Enclosures PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. EPA Facility Name SEE INSTRUCTIONS NCD000830646 L.V.Sutton Electric Plant OUTFALL NO V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 001 PART A-You must provide the results of at least one analysis for every pollutant In this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional) 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c LONGTERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) (If available) d.NO.OF a.Concen- b.Mass b.NO.OF (1)Concentrabon (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Blochenucal Oxygen `� 2 < 1 mgA Ib/Day Demand(BOD) b Chemical Oxygen 21 1, mgA Ib/Day Demand(COD) c Total Organic A 65 1 mgA Ib/Day Carbon(TOC) d.Total Suspended ,� 5 < 1 mgA Ib/Day Solids(TSS) e Ammonia(as N) 0.069 1 mgA Ib/Day Flow VALUE VALUE VALUE VALUE MGD N/A g.Temperature VALUE VALUE VALUE VALUE (winter) •?,'-`",f185 '=�; E, ? DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE (summer) .w.. iw " '`-' I �' trri - DEGREES CELSIUS I ' I pH MINIMUM MAXIMUM MINIMUM MAXIMUM '.1�c 7 -11 77 -` F-1.�'T7-3 STANDARD UNITS PART B-Mark"X"In column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which Is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the Instructions for additional details and requirements 1.POLLUTANT 2.MARK"X• 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (d available) a pre- b.ab- (if available) (if available) d.NO.OF a Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentrabon (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentrabon (2)Mass ANALYSES a Bromide X 0.18 1 mgA Ib/Day (24959-67-9) b Chlorine, X mgA Ib/Day Total Residual c.Color X i 30.00 N/A N/A NIA 1 Std.Units N/A N/A d.Fecal X 1000 N/A N/A N/A 1. Colonies N/A N/A Coliform /100 ml e Fluoride X 0.20 1 mgA Ib/Day J (1698448-8) Nitrate- X 0.024 1 mgA Ib/Day Nltrite(as N) F I I I EPA Form 3510-2C(Rev 2-85) PAGE V-1 CONTINUE ON PAGE V-2 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT 1.POLLUTANT 2.MARK•x 1 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. eeoeved a.MAXIMUM GAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- bab- (d available) (if available) d.NO.OF a Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration ](2)mass ANALYSES tration (1)Concentrahon (2)Mass ANALYSES .Nitrogen, Total organic X 0.40 1 mg/l Ib/Day (as N) h.Oil an Grease X 5.00 < 1 mg/I Ib/Day I.Phosphorous (as P),Total X 0.032 1 mgA Ib/Day (7723.14-0) 1. a loac rvl y (1)Alalia, Total X5.00 N/A N/A N/A 1 pCiA N/A N/A 2 Beta, Total X �. 5.00 N/A N/A N/A 1 pCiA N/A N/A (3Radium, Total X 100. N/A N/A N/A .1 pCiA N/A N/A (4)Radium 26,Total X 1.00 N/A N/A N/A 1 pCiA N/A N/A k.Sulfate (as SO4) X 34.00 11• mgA Ib/Day (14808-79-8) I.Sufficle (as S) X 100 < 1 mgA Ib/Day m.Su ite (as S03) X < 200 < I mgA Ib/Day (1426545.3) n Surfactants X 0.061 1;, mgA Ib/Day o.Aluminum, Total X 0.043 1 mgA Ib/Day (7429-90-5) p.Barium, Total X 0.041 4 mgA Ib/Day (7440-39-3) q Boron, Total X 0188 1 mgA Ib/Day (7440-42-8) r.Cobalt, Total X 0.001. < - 1 mgA Ib/Day (7440-48-4) s.Iron,Total (7439.89-6) X 0 158 1 mgA Ib/Day L Magnesium, Total X -4.43 1 mgA Ib/Day (7439-95-4) u Molyloclenum, Total X 00135 1 mgA Ib/Day (7439-98-7) v.Manganese, Total X 0.012 1 mgA Ib/Day (7439-96-5) w.Tin,Total (7440-31-5) X 001 < 1 mgA Ib/Day [70 Titanium, 005 < 1 mgAIb/Day 440-32-8) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3 EPA I D NUMBER(copytom Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NCD000830646 1 001 L.V. Sutton Electric Plant PART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre- cab- (d available) (if available) d.NO.OF a Concen- b.Mass d NO.OF ed sem sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES METALS,CYANIDE,AND TOTAL PHENOLS 1M Antimony, X 1.02 1 ugA Ib/Day Total(7440-36-0) 2M.Arsenic,Total X 417 1 ugA Ib/Day (7440-38-2) 3M.Beryllium, X <j 1 < 1 ugA Ib/Day Total(7440.41=7) 4M.Cadmium, X 01 < 1 ugA Ib/Day Total(744043-9) 5M.Chromium, X 1 < 1 ugA Ib/Day J Total(7440-47-3) 6M.Copper,Total X 0 009 1 mg/I Ib/Day (7440-50-8) 7M.Lead,Total X 1 < 1 ugA Ib/Day (7439-92-1) 8M.Mercury,Total X 0000845 1 ugA Ib/Day (7439-97-6) 9M.Nickel,Total X ^<� 1. < 1 ugA Ib/Dayr ._1 (7440-02-0) 10M Selenium, X 166 1" ugA Ib/Day f Total(778249-2) 11 M.Silver,Total X <'° 1 < 1 ugA Ib/Day (7440-224) 12M.Thallium, X .< 0 0002 < 1 mg/I Ib/Day otal(7440-28-0) 13M Zinc,Total X J 0.006 1 mgA Ib/Day (7440-66-6) 14M Cyanide, X ' -0010 < 1 mgA Ib/Day Total(57-12-5) 15M.Phenols, X 0.005 < 1 mgA Ib/Day Total DIOXIN 3,7,8 Tetra DESCRIBE RESULTS chlorodibenzo P X Diown(1764-01-6) EPA Form 3510-2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 I EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-3 NCD000830646 001 L.V. Sutton Electric Plant 1.POLLUTANT 2 MARK„X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONGTERM AVG VALUE a.LONG TERM AVG.VALUE (if available) quer- b.pre- c.ab- 1, (if available) I (if available) d.NO OF a.Concen- b.Mass d.NO.OF led sent Isent Imconcentration 1(2)mass (I)Concentration 1(2)mass (1)Concentration 1(2)mass JANAI YSES traUOn (1)Concentration 1(2)mass JANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS 1V Acrolein X < 5 < ,1 ugA Ib/Day (107-02-8) 2V.Acrybnitnte X 5 < 1 ugA Ib/Day (107-13-1) 3V.Benzene X 1 2 < 1 ugA Ib/Day (71-43-2) V.Bis(Chloro- methyl)Ether X (542-88-1) 5V Bromofo m X < 1 2 < 1 ugA Ib/Day (75-25.2) 6V.Carbon ,Tetrachloride X _<�, 2 < 1 ugA Ib/Day (56-23.5) 7V.Chlorobenzene X 5 2• < 1 ugA Ib/Day (108.90-7) 8V Chlorodi- bromomethane X I 2 < 1 ugA Ib/Day (124-48-1) 9V Chloroethane X J 2 < -1 ugA Ib/Day (75-00-3) 10V.2-Chloro- ethylvinyl Ether X 5 < 1 - ugA Ib/Day (110.75-8) 11V.Chloroform X ,� 2 < 1, ugA Ib/Day (67-66-3) 12V.Dichloro- bromomethane X 2' < 1 ugA Ib/Day (75.27-4) 13V.Dichloro- _ ddtuoromethane X 2 - < 1 ugA Ib/Day (75-71-8) 14V.1,1-Dichtoro- X c�.. ,2 < 1 ugA Ib/Day ethane(75-34-3) 15V.1,2-Dichbro- X J 2 < 1 ugA Ib/Day ethane(107-06.2) 16V.1,1-Dichbro- X < 2 < 1 ugA Ib/Day ethylene(75-35-4) 17V.12-Dichloro- X < 2 < .1 ugA Ib/Day J propane(78-87-5) 18V.1,3-Dichbro- X c 2 - < 1 ugA Ib/Day propylene(542-75-6) 19V.Ethylbenzene X < 2 < 1 ugA Ib/Day (100-41-4) OV.Methyl X 2 < 1 ugA Ib/Day Bromide(74-83-9) _ t V.Methyl 2 < 1 ugA Ib/Day Chloride(74-87-3) EPA Form 3510-2C(Rev.2-85) PAGE V4 CONTINUE ON PAGE V-5 U) LL w O } w Q a z z a LU LU �w z .+ m D z y o „ U > U W o c > N w G N Z w o ~ b L6 (7 C m Jin - nnlnnn i � � � -nen H O O 0 e Q Q e Q O R D ❑ D O e e O 0 U m a a a a a a a a n a a9 a a a a a a a n a Z a � c m c c c c c c c c c c c c c c c c c c c c c U Ol O OI O m O) O! 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J a LL O S. 5 m 0 .QS o 0 _ d v v L `o L 8' fccn ?_ ?_ .3 r c m v ^ d m m N Z d p > L t7 V p O 0 A N N p IL LL r S S O 2 0 S C - N,Z N Z 6 Z 6 Z Q LL O Z U m m@ m t m 5 m m m J m m 2 m m b m m s` m m m N A CO 6 m CO b CO m a a U m a t C7 N ' 8 rn N a a O a N S N 8 ° aL 8 M N �.m M 8 v °D m X C mn m M m C M ° o m H °� z ? w LL b \ c z e a < E \ ) \ CL § / . LU ] c &> ! . e . \0 _ ƒ / r z . ) f , 0 LLJ - zz / � < \ � ) R $ « 0 � k ) o ; � . k § ® � E R * E, / \ . 0 E � / k k '' # ( \ / \ $ ] ƒ LU LU a \ 2 & Zl § ) ;> k\ j �\ "k � o Go 2 q /ƒ x x x x § x x \ � x x x 4 x x x x x x x x � . | � . ate . & z Q 7fl30 . / . 0 a } z E F- LU S & k f 2 -j � ! \ �� �» -® o o ` w LL ED , § 0 � 7 \ \ ( § } i � � / § k } � ) § % ± ) { ( 5a � ( # 22 ) { 222 / { { / / � w £ t o ® a a - £ g « 2 t ƒo $ E 3 k E e $ 3 $ R # a: A » \ EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-8 NCD000830646 001 L.V. Sutton Electric Plant 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a re- M=7�� Y VALUE b.MAXIMUM 30 DAY VALUE C.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) qulr- if available)) (d available) d.NO OF a.Concen- 1b.Mass d.NO.OF ed 2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tr;;bnnConcentration 1 ( ) (z)Mass ANALYSES GC/MS FRACTION-PESTICIDES(continued) 17P.Heptachlor Epoxide X (1024-57-3) 18P.PCB-1242 X < 0.25 < (53469-21-9) 19P.PCB-1254 X < 0.25 < (11097-69-1) OP.PCB-1221 X < 025 < (11104-28-2) 21P.PCB-1232 X < 025 < (11141-16-5) 2P PCB-1248 X < 025 < (12672-29-6) 3P PCB-1260 X < 0.25 < (11096-82-5) 4P.PCB-1016 X < 025 < (12674-11-2) 5P.Toxaphene X (8001-35-2) EPA Form 3510-2C(Rev.2-85) PAGE V-9 M C) (D L too Q4 to, ^' Z o c-n 7 �7 Attachment to January 2015 NPDES Application Update Sutton Dewatering Plan Synopsis At the present time Duke Energy is expecting to discharge the wastewater generated from the removal of ash (including dewatering of ash basins to allow excavation and dewatering of excavated ash prior to being loaded onto trucks or rail cars)from the site through the current Outfall 004. It is anticipated that as dewatering proceeds, Duke may bring in additional treatment may be needed to meet permit discharge limits at Outfall 004. The following definitions may be useful as you consider these activities: Ash basin free water: Water in an ash basin located above the settled layer of ash. Ash basin free water has undergone treatment in the ash basin, has the same general characteristics as water discharged when the facility was active sluicing ash to the ash basing is largely devoid of Total Suspended Solids and meets all applicable NPDES permit limits. Ash basin interstitial water: Water in an ash basin that is located within the pore space of accumulated wastewater sludge or slurry. Ash basin interstitial water must be removed by some means such as trenching, well points, etc. and would likely require additional treatment before being�released to the environment. The process we envision for dewatering the ash basins to enable excavation and ash removal is as follows: The Sutton Plant has two Ash Basins on site, and they are referred to as the 1971 Basin and the 1984 Basin.The 1971 Basin contains a small storm water basin on the western side which we refer to herein as the Outer 1971 Basin.The 1984 Basin contains an Interior Containment Area (ICA)that was constructed in 2006. Based on data from July 2014, the 1971 Basin contains approximately 362 thousand gallons of free water and the 1984 Basin contains approximately 65 million gallons of free water. For the dewatering project,free water would be discharged only through existing Outfall 004 in the North 1984 Basin.There is an existing splitter structure at Outfall 004 which allows for the discharge to be routed directly to the cooling pond or bypassed to Outfall 001 (to the Cape Fear River). During dewatering,the bypass to Outfall 001 will remain closed. Water will be discharged only to the Cooling Pond from Outfall 004. Free water dewatering will occur simultaneously in the 1984 and 1971 Basins. Water from the Outer 1971 Basin will be pumped,into the Inner 1971 Basin at an initial design flow rate of 575 gallons per minute(gpm). Outer 1971 Basin free water will be pumped to the Inner 1971 Basin using a temporary diesel pump with a screened floating intake. The water level in the basin on September 9, 2014 was 20.6 ft and the basin bottom elevation (as shown in historic drawings) is 11.5 ft. Page 1 of 3 Attachment to January 2015 NPDES Application Update Sutton Dewatering Plan Synopsis There are currently two 12 in diameter ductile iron pipes that discharge to the southern tip of the 1971 Basin. These pipes convey stormwater collected from the West Retention Pond and the Fue'I Tank Containment Area to the basin. To reduce the impact of stormwater from these pipes saturating the dike walls in the narrow basin channel during the dewatering phase,the 12 in diameter pipes will be modified to extend into a culvert pipe. The culvert will extend from approximately the-outlet location of the 12 in pipes, along the narrow channel section of the Outer 1971 Basin and terminate into the main body of the Outer 1971 Basin. Free water from the Inner 1971 Basin'will be pumped directly to the North 1984 Basin at an initial-design flow rate of 785 gpm. Free water from the Inner 1971 Basin will be pumped to the North 1984 Basin using a temporary diesel pump with a screened floating intake. Water accumulated in the South 1984 Basin will be pumped to the Inner 1971 Basin or the area will be filled such that it will sheet flow to the Inner 1971 Basin. Similarly, water from the 2006 ICA will be pumped to the North 1984 Basin at an initial design flow rate of 500 gpm. Free water in the 2006 ICA will be pumped to the North 1984 Basin using a temporary diesel,pump with a'screened floating intake. The discharge hose will feed into the 2006 ICA discharge tower. The North 1984 Basin will be dewatered through,Outfall 004 via two temporary diesel pumps operated at a combined.1,400 gpm , each with screened floating intakes. The pumps will operate in parallel and discharge through a single hose to the North 1984 Basin discharge tower(Outfall 004). All,pumps will be controlled,to stop at a user-defined level,set point which is set manually every 7 days. The maximum free water drawdown rate will be one foot over seven days. If the free water level is drawn down below the set elevation in 7 days or�less,the pumps will stop. At the end of each 7 day period,the set point will be reset to 1 ft below the current water level. Following free water removal, accumulated storm-water will be removed at a maximum rate of 2 feet over 1 day. Historical discharge rates from.Outfall'004 were examined to ensure that dewatering discharge rates do not exceed historical discharge rates. The average Outfall 004 discharge rate from January 2012,through November 2013 is 4.05 million gallons per day(MGD),or 2,810 gpm . The design pumping rate from the duplex pumps in the North 1984 Basin to the,Outfall 004 discharge tower is 1,400 gpm. The maximum discharge rate of these pumps is 2,525 gpm at 2,200 rpm and 10 ft of suction lift. The North 1984 Basin pumps will be controlled with a real-time total suspended solids(TSS) meter.A real-time pH meter will control a carbon dioxide injection system to maintain pH between 6.0 and 9.0 standard units (SU). The sensors for the real-time TSS and pH meters will be inserted directly into the discharge piping. In addition to the real-time monitoring, handheld TSS and pH meters will be used daily for field measurement of samples taken from sample port located on the discharge piping manifold of the North 1984 Basin dewatering pumps. The handheld TSS meter will undergo laboratory validation and site- Page 2 of 3 Attachment to January 2015 NPDES Application Update Sutton Dewatering Plan Synopsis specific field verification. Daily pH monitoring will be conducted with a portable pH meter. Discharge flow rates will be monitored daily using an inline flow meter, a handheld flow meter,or a v-notch discharge weir. Staff gauges will be used to monitor daily water levels within the North 1984 Basin. Normal monitoring required by the N'PDES permit will continue uninterrupted during the dewatering process. As the dewatering process transitions from the free water phase to the interstitial,water phase it is anticipated that a filtration system will be used to maintain compliance with permit limits. Please include a provision in the modified permit to allow the use of a coagulant or flocculent from the state's approved list to facilitate the filtration process if,needed. We have included a process flow diagram and basin map as attachments,for your reference. Page 3 of 3 1 � Attachment to January 2015 NPDES Submittal Sutton Plant-Free and Entrapped Water-Field Measurements Depth Temperature Conductivity TDS ORP Sample ID (ft) (°C) (µS/cm) pH(SU) (PPM) (mv) FW-'1971-Outer-1 ft 1 26.2 398.9 7.38 264.2 69 FW-1984-North-1 ft 1 25.8 12.55 8.19 '30.3 55 FW-1984-North-5.5 ft 5.5 27.2 95:67 10.11 52.7 54 FW-2006-ICA-1 ft, 1 26.4 152.5 8A9 97.96 67 Free Water Average -- 26.4 164.9 8.44 111.29 61.3 EW-1971-Inner-I 5 25.4 .579.2 6.26 389.2 93 EW-1971-Inner-I1. 5 24.6 460:5 7.43_ 92.27 -65 EW-1971-Inner-111 5 24.6 460.5 7.43 92.27 -65 EW-PZ-INT 15 --. 1036 6:36 209.7 -67 EW-PZ-101 22 -- 619.3 6.21_ 125 125 EW-PZ-102=1 22 -- 562.2 6.54 113.4 218 EW-PZ-102-II 22 -- 562.2 6.54 113.4 219 EW-PZ-108D 30 -- 680.4 7.24 136.6 14 Entrapped Water Average -- 24.9 620.0 6.75 158.98 59 Attachment to January 2015 NPDES Submittal Sutton Plant-Summary of Free and Entrapped Water Analytical Data A Sb As Ba B Bromide Cd a Chloride Cr Cu Fluoride Pb Mg Mn Hg Method Hg Method Mo Ni Nitrite+ O&G Se Specific Conductance Sulfate TD TI TKN Co onmetric TSS Zn Sample ID Sample Description mg/L) L (µg/L) (mg/L) (mg/L) m L L (mg/ (mg/L) L L m L Fe m L L (mg/L) m /L 245.1 L 1631E L ( L) L Nitrate m /L H SU) P m /L L (µmhos/cm) (mg/L) (mg/L) L (mg-N/L) m /L m L FW-1971-Outer-1 ft Outer 1971 Basin Free Water 1'Depth 1.45 < 5 9.89 0.05 0.235 0.23 < 5 34.8 41 < 5 7.01 < 0.1 3.66 < 5 6.51 0.017 < 0.05 18.2 1 7.99 1 0.049 1 1 0.076 < 5 415 75 290 <1 5 1 0.56 20 P0018 FW-1984-North-1 ft North 1984 Basin Free Water 1'Depth 0.227 9.06 31.1 0.137 0 373 0.17 < 5 17.4 24 < 5 < S 0.34 0.034 H 5 4.66 < 0.005 < 0.05 132 5.51 < 001 < 5 < 0.02 54.3 272 75 180 < 5 0.23 < 5 < 0.005 North 1984 Basin Free Water 5.5' FW-1984-North-5.5 ft Depth 1.28 8.59 51.7 0.18 0.376 0.17 < 5 17.6 24 6.94 14.4 0.34 0.507 < 5 4.76 0.011 1< 0.05 135 8.12 < 0.01 < 5 0.048 55.3 272 74 180 < 5 1.1 27 0.007 2006 Interior Containment Area Free FW-2006-ICA-1 ft Water 1'Depth 1.65 < 5 50.7 0.184 0.174 < 0.1 < 5 7.83 4.8 5.25 9.68 0.16 0.688 < 5 1.62 0.006 1< 0.05 130 < 5 0.039 0.078 197 91.7 22 79 < 5 0.34 44 0.008 Inner 1971 Basin Entrapped Water EW-1971-Inner-I Screened 1'-5' 37.9 11.2 1S9 0.858 0.748 0.25 < 10 61 35 42.6 83.1 0.28 13.8 51.6 16.4 0.207 0.44 65 54.4 0.031 6.49 0.761 172 570 130 400 < 10 2.2 160 0.096 Inner 1971 Basin Entrapped Water EW-1971-Inner-I Total Screened 1'-5' Total 13.5 14.6 98.6 0.407 0.714 < 10 56.7 15.2 29.6 521 173 14.6 0.15 0.22 63.1 30.4 0.297 125 400 < 10 430 0.041 Inner 1971 Basin Entrapped Water EW-1971-Inner-I 350 Screened 1'-S',350 m 12.3 13.4 96.2 0.385 0.707 < 10 56.4 15.6 26.7 4.78 17.6 14.4 0.146 0.14 68.2 28 0.288 130 400 < 10 430 0.041 Inner 1971 Basin Entrapped Water EW-1971-Inner-I 105V Screened 1'-5',105 I.Lm 12.4 13.3 92.9 0.384 0.712 < 10 56.6 15.9 27.7 4.79 17.1 1 14.5 0.146 0.13 64.2 26.9 0.284 129 400 < 10 420 0.041 Inner 1971 Basin Entrapped Water EW-1971-Inner-1 53V Screened V-5' 53 larn 6.28 14.1 816 0.265 0.699 < 10 55.7 < 10 11.9 2.42 < 10 13.9 0.13 0.09 65.4 21.9 0.154 123 400 < 10 90 0.025 Inner 1971 Basin Entrapped Water EW-1971-Inner-I 10v Screened 1'-5' 10 pm 0 254 20.6 72.2 0.148 0.706 < 10 55.7 < 10 < 10 0.082 < 10 13.6 0.116 < 0.05 67.2 16.5 0.031 126 390 < 10 < 25 0.011 Inner 1971 Basin Entrapped Water EW-1971-Inner-I 0.45 Screened 1'-5' 0.45 m 0.048 179 72.3 0.141 0.7 < 10 55.1 < 10 < 10 < 0.01 < 10 13.3 0.113 < 0.05 65.2 15.1 0.023 124 400 < 10 < 25 0.011 Inner 1971 Basin Entrapped Water EW-1971-Inner-II Screened V-5' 0.0887 113001 Inner 1971 Basin Entrapped Water EW-1971-Inner-III Screened 1'-5' 0.093 1800 2006 Interior Containment Area EW-PZ-INT Entrapped Water Screened l3'-15' < 0.0031 43 2006 Interior Containment Area Dike EW-PZ-101 Entrapped Water Screened 17'-22' < 0.0031 6 2006 Interior Containment Area Dike EW-PZ-102-1 Entrapped Water Screened 17'-22' 0.0964 350 2006 Interior Containment Area Dike EW-PZ-102-11 Entrapped Water Screened 17'-22' 0.0404 220 Outer 1971 Basin Entrapped Water EW-PZ-108D Screened 25'-30' 0.212 3400 Field Blank < 0.0006 < 5 Tri Blank - < 0.0006 < 5 RECEIVEDIDENRIDWR JAN 2 3 MS Water Q Section Permitting