HomeMy WebLinkAboutWQ0004797_Monitoring - 11-2016_201612281 •
WE NG I N E E R i r.., a ii L�
231 HAYW000 STREET. ASHEVILLE. NC 28801
TEL.828.281.3350 FAC.828.281.3351
W W W.ALTAMONTENVIRONMKNTAL.COM
December 16, 2016
Mr. Blake Kehoe
Plant Engineer
Lassonde Pappas and Company, Inc.
125 Industrial Park Road
Hendersonville, North Carolina 28792
Subject: November 2016 Groundwater Sampling Event
Clement Pappas & Co., Inc. (Clement Pappas)
125 Industrial Park Road
Hendersonville, North Carolina
Dear Mr. Kehoe:
RF"'FI\/FD
0EC 2 8 2016
DWR SECTION
INFORMATION PROCESSING UNIT
Altamont Environmental, Inc. (Altamont) performed a groundwater sampling event at the subject facility on
November 9, 2016. A site location map is included as Figure 1. Altamont performed the groundwater
sampling event in accordance with the North Carolina Department of Environmental Quality (DEQ), formerly
known as the Department of Environment and Natural Resources (DENR), spray irrigation system permit
number WQ0004797 (permit most recently reissued on September 3, 2015). Altamont collected
groundwater samples from six monitoring wells: MW -4, MW -5, MW -6, MW -7R, MW -8, and MW -9. Monitoring
well MW -9 was installed on April 14, 2015 to replace the previously damaged monitoring well MW -2R. The
locations of the monitoring wells are shown on Figure 2 (attached). Altamont submitted the groundwater
samples to Pace Analytical Services, Inc. (Pace), a North Carolina -certified laboratory, for analysis of the
parameters specified in the permit.
Table 1 summarizes the current and historical laboratory analytical results for microbiology and wet
chemistry. All parameters analyzed, except total organic carbon (TOC) and nitrate, were below the permit
limits and North Carolina Administrative Code, Title 15A, Subchapter 21-.0202 Standards (21- standards).
The TOC concentrations can be summarized as follows:
• The permit limit for TOC is 10 milligrams per liter (mg/L).
• Similar to previous sampling events, the TOC concentration in the MW -7R sample collected during
this event (November 2016) was in excess of the permit limit.
• TOC concentrations in samples MW -4, MW -6, MW -8, and MW -9 collected during this event
(November 2016) were below the permit limit. TOC was not detected in the sample collected from
MW -5.
Nitrate concentrations can be summarized as follows:
• The permit limit for nitrate is 10 mg/L.
• Similar to the previous sampling event (May 2016), nitrate concentrations exceeded the permit limit
in the samples collected from monitoring wells MW -7R and MW -8.
• Nitrate was not detected in samples from monitoring wells MW -4 and MW -6. Nitrate concentrations
detected in samples from monitoring wells MW -5 and MW -9 were reported below the permit limit.
P:\Gement Pappas\Reports\2016 2081.01\November\Cover Letter_November 2016.Doc
Blake Kehoe
December 16, 2016
Page 2 of 3
Following the May 2016 sampling event, Clement Pappas requested that Altamont analyze the overall
effluent application rates for the irrigation system in an effort to determine if the effluent may have been
influencing groundwater results, specifically in regards to nitrate concentrations. As conveyed to the DEQ,
Altamont's analysis found that it was highly unlikely that nitrogen concentrations in the effluent were
influencing nitrate concentrations in groundwater. The more likely source of nitrate exceedances in
floodplain monitoring wells (monitoring wells MW -7R and MW -8), as identified by DEQ and Altamont, was the
continuous flooding of Mud Creek and its nutrient loading associated with runoff from agricultural fields
upstream of the facility.
In order to be proactive, Clement Pappas contracted Nutter and Associates to analyze the overall health and
performance of the land application system. This analysis resulted in a report that included
recommendations to improve the longevity of the system, while reducing the likelihood of impacts to
groundwater. Recommendations that have been implemented by Clement Pappas include the following.
In order to avoid introducing additional nitrogen to soils at the subject facility, Clement Pappas has
implemented the practice of bailing harvested fescue and removing it from the irrigation fields,
instead of mowing it and allowing it to decompose. Removing the harvested fescue should result in
improved vegetative growth, which will allow the fescue to uptake additional available nitrogen.
Additionally, it is expected that removal of the harvested fescue will result in greater assimilation of
nitrogen into facility soils and reduce the potential for nitrogen leaching.
• In an effort to correct calcium deficiencies in the irrigation fields, gypsum is applied. Gypsum was
applied to the irrigation fields at a rate of approximately 5 tons per acre during 2016. Correcting
calcium deficiencies allows the fescue to better uptake nutrients, thus reducing the available
nutrients in soils that could potentially leach to groundwater. Clement Pappas also applied foliar
manganese chelate to the fescue in an effort to increase nutrient uptake and further limit the
amount of nutrients available in soils that could potentially leach to groundwater.
Table 2 summarizes the current and historical laboratory analytical results for volatile organic compounds
(VOCs) analyzed by EPA Standard Method 6200. In accordance with permit requirements, samples are
analyzed for VOCs once annually, during the month of November. All VOCs analyzed, except
tetrachloroethene, trichloroethene, and cis-1,2-dichloroethene, were detected below the permit limits or 2L
standards.
VOC concentrations can be summarized as follows:
• Three VOCs (tetra ch lo roethe ne, trichloroethene, and cis-1,2-dichloroethene) were detected in the
sample collected from monitoring well MW -5. All three of these VOCs were detected at
concentrations above their 2L standards. These VOCs have been consistently detected at high
concentrations in samples collected from this monitoring well since 2002. Concentrations are
generally trending downward, with occasional spikes in the data.
• No VOCs were detected in the samples collected from monitoring wells MW -4, MW -6, MW -7R, MW -8,
and MW -9.
Table 3 summarizes the current and historical groundwater elevations. With the exception of monitoring well
MW -9, all of the monitoring well concrete pads and top -of -well casing elevations were surveyed by Wes Cole
Land Surveying, PA on November 21, 2012. Monitoring well MW -9 was surveyed by Wes Cole Land
Surveying, PA on May 29, 2015. The surveyed elevations are indicated on Table 3 and on Figure 2.
In accordance with the spray irrigation permit, Clement Pappas is required to submit the following by
December 31, 2016 (on or before the last working day of the month following the sampling month) to the
DEQ:
• Laboratory analytical report and chain -of -custody form (Attachment A); the well sampling logs and
equipment documentation and instrument calibration data sheet are also included (Attachment B)
P:\Clement Pappas\Reports\2016 2081.01\November\Cover Letter—November 2016.Doc
Blake Kehoe
December 16, 2016
Page 3 of 3
• DEQ GW-59A—Compliance Report Form (Attachment C)
• DEQ GW-59—Groundwater Quality Monitoring Compliance Report Form for each monitoring well
(Attachment D)
Altamont proposes to complete the next scheduled groundwater sampling event in May 2017.
If you have any questions or would like additional information, please do not hesitate to contact the
undersigned at 828.281.3350.
Sincerely,
ALTAMONT ENVIRONMENTAL, INC.
Brian Gant
Attachments:
Figure 1—Site Location Map
Figure 2—Site Plan Map
Table 1—Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry
Table 2—Current and Historical Groundwater Analytical Results for Volatile Organic Compounds
Table 3—Current and Historical Groundwater Elevation Measurements
Attachment A: Laboratory Analytical Report and Chain -of -Custody Form
Attachment B: Well Sampling Logs and Equipment Documentation and Instrument Calibration Data Sheet
Attachment C: DEQ GW-59A—Compliance Report Form
Attachment D: DEQ GW-59—Groundwater Quality Monitoring: Compliance Report Forms
R\Clement Pappas\Reports\2016 2081.01\November\Cover Letter_November 2016.Doc
COMPLIANCE xa t
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1. AGRI-WASTE TECHNOLOGY, INC. (AWY) MAY 4, 2001 IRRIGATION PLAN. SIR FIGURE
2. EARTH SYSTEMSASSOCIATES, LTD. FIGURE 3 LAND TREATMENT SYSTEMS, UNDATED. SITE PLAN MAP
3. HENDERSON COUNTY GIS WESSITEACCESSED JANUARY 30.2006. ENGINEERING & HYDROGEGLGC \�
4. AERIAL PHOTOGRAPHY DATED 2015 OBTAINED BY NC ONE MAP. 231 HAYINOIO STREET, ASHEVILLE, NC 28801 ///'''���
NOTES: TEL.B28.281.3350 FAC.828.281.3351 CLEMENT PAPPAS -
1. PROPERTY BOUNDARY LINES (PINK LINES) AND 2' CONTOUR LINES FROM HENDERSON COUNTYGIS. •♦• Al T AHe xiLxvlRoxxexT Al. a.. L
2. IRRIGATION FIELDS FROM AWT IRRIGATION PLAN (BLUE LINES). 125 INDUSTRIAL PARD ROAD
3. COMPLIANCE BOUNDARY DETERMINED PER I5A NCAC 02L. 0107 (YELLOW LINES). DRAWN BY: WYATT EDSEL SCALE (FEET) HENDERSONVILLE, NC
4, MONITORING WELL TOP -OF -CASING ELEVATIONS SURVEYED BY WES COLE LAND SURVEYING ON PROJECT MANAGER: BRIAN GANT
NOVEMBER 21, 2C 12. CLIENT: CLEMENT PAPPAS 250 0 200 Soo
5. MONITORING WALL TOP -OF -CASING ELEVATION FOR N1K0 SURVEYED BY WES COLE ON MAY 29, 2015 REY. DATE DESCRIPTION BY CNK APV DATE- 6/27/16 FILE PATH' P:,CLEHENr PAPPA5AFI60K5\CAD,ICI2M-SITE PLAN MAP. m,..
Table 1
Current and Historical Groundwater Analytical Results
for Microbiology and Wet Chemistry
Clement Pappas
Hendersonville, North Carolina
Sample Name
Sample Date _
O
a
CO
U
yaN
0
0
v
`o
U
r�
:
a
z
a�
w
'a
j
N
y
a
N
. o
E
E
v,
0
L
N
O
M.
m
(mm/dd/yyyy)
(mg/L)
(mg/L)
(CFU per 100 mL)
(mg/L)
(mg/L)
(mg/.L)
(mg/L)
, (mg/L)
05/24/2006
7.2
9.7
< 1.1
2
19
82
< 0.10
NA
11/09/2006
3.6
7.4
< 1.1
0.95
17
76
0.11
NA
05/18/2007
4.9
6.0
< 1.0
0.56
14
62
< 0.10
NA
11/13/2007
5.9
16.7
<1.1
2.9
6.9
82.0
< 0.10
NA
05/27/2008
10.2
9.0
<1.1
0.80
21.3
140
< 0.10
NA
11/18/2008
4.7
10.7
<1.1
1.9
8.5
32.0
< 0.10
NA
05/28/2009
14.4
7.1 1
< 4.0
0.46
24.2
104
< 0.10
NA
11/05/2009
13.5
5.9
< 2.0
0.31
23.5
80.0
< 0.10 1
NA
MW -2R
05/13/2010
8.7.
5.8
< 2.0
< 0.10
17.2
57.5
< 0.10
NA
11/08/2010
18.3
10.0
< 2.0
1.1
11.7
60.0
< 0.10
NA
05/17/2011
11.6
< 5.0
< 2.0
< 0.10
14.3
< 62.5
< 0.10
NA
11/15/2011
18.9
10.1
< 2.0
1.2
10.0
86.0
< 0.10
NA
05/17/2012
5.3
7.6
< 4.0
< 0.20
11.9
68.0
< 0.10
NA
11/07/2012
31.1
9.5
< 1.0
1.3
10.0
67.0
< 0.10'
NA
05/16/2013
13.5
1.2
< 1.0
< 0.02
13.2
64.0
< 0.10
NA
11/20/2013
6.1
7.6
< 1.0
0.97
9.3
66.0
< 0.10
NA
05/22/2014
8.0
4.1
< 1.0
0.72
8.4
52.0
< 0.10
NA
05/15/2002
8.9
45
< 1.1
< 0.10
9.3
180
< 0.10
NA
11/05/2002
5.5
48
< 1.1
< 0.1
14
230
< 0.10
NA
05/13/2003
3.3
32
< 1.1
0.051
20
110
0.21
NA
11/04/2003
41
31
< 1.1
< 5.0
66
210
< 0.10
NA
05/05/2004
6
29
< 1.1
< 5.0
45
240
0.11
NA
11/09/2004
8.4
13
3.6
< 0.10
52
200
< 0.10
NA
05/17/2005
8.5
10
< 1.1
< 0.10
37
220
< 0.10
NA
11/03/2005
16
1 14
< 1.1
< 0.10
29
220
0.14
NA
05/24/2006
19
11
< 1.1
< 0.10
28
180
< 0.10
NA
11/09/2006
8.8 .
6.9
< 1.1
< 0.10
26
180
< 0.10
NA •
05/18/2007
8.5
8.9
< 1.0
< 0.10
29
300
< 0.10
NA
11/13/2007
16.7
11.3
< 1.1
< 0.10
25.0
152
< 0.10
NA
05/27/2008
< 1.0
10.0
< 1.1
< 0.10
38.6
176
< 0.10
NA
11/18/2008
20.5
9.3
< 1.1
< 0.10
19.6
108
< 0.10
NA
MW
05/28/2009
8.6
13.6
< 4.0
< 0.10
35.5
156
< 0.10
NA
-4
11/05/2009
31.0
13.6
< 2.0
< 0.10
30.7
120
< 0.10
NA
05/13/2010
7.8
18.0
< 2.0
0.17
31.0
141
< 0.10
NA
11/08/2010
23.9
17.5
< 2.0
< 0.10
34.4
144
< 0.10
NA
05/17/2011
7.7
13.5
< 2.0
0.82
25.6
137
< 0.10.
NA
11/15/2011
7.3
14.4
< 2.0
< 0.20
27.8
157
< 0.10
NA
05/17/2012
6.7
12.1
2.0
< 0.20
22.3
117
< 0.10
NA
11/07/2012
10.6
14.5
2.0
< 0.020
26.2
150
< 0.10
NA
05/16/2013
31.8
10.2
2.0
0.28
19.1 1
108
< 0.10
NA
11/20/2013
8.0
14.7
< 1.0
0.026
22.1
157
< 0.10
NA
05/22/2014
8.7
10.8
< 2.0
0.14
22.5
146
< 0.10
NA
11/18/2014
28.7
-12.1
< 2.0
< 0.020
21.9
161
< 0.10
NA
05/13/2015
5.4
9.2
< 1.0
< 0.020
21.5
130
< 0.10
NA
11/04/2015
6.6
6.2
<2.0
< 0.020
NA
139
< 0.10
0.10
05/04/2016
5.5
8.4
< 4.0
< 0.020
NA
119
< 0.10
0.095
11/09/2016
4.3
12.2
< 4.0
< 0.020
NA
124
< 0.10
0.27
Standards
10
250
1
10
250
500
1.5
NL
P:\Clement Pappas\Reports\2016 2081.01\November\November 2016 -Historic Analytical Results Page 1 of 5
Table 1
Current and Historical Groundwater Analytical Results
for Microbiology and Wet Chemistry
Clement Pappas
Hendersonville, North Carolina
Sample Name
•
Sample Date
c
0
a
V
(0
�9N
.0.
-
20
v
o
w
O
0
m
LL
a�
m
Z
�,
_
U
O
N
Q y
- a
�
o
E
<
O
N
_
a
-
2
(mm/dd/yyyy)
(mg/L)
(mg/L)
(CFU per 100 mL)
(mg/L)
,(mg/L)
(mg/L)
(mg/L)
(mg/L)
05/15/2002
2.9
15
< 1.1
0.42
1.7
< 40
< 0.10
NA
11/05/2002
1.4
16
< 1.1
0.54
< 1.0
83
1.3
NA
05/13/2003
4.6
17
< 1.1
0.65
2
56
0.25
NA
11/04/2003
19
22
< 1.1
0.23
< 5.0
58
< 0.10
NA
05/05/2004
0.7
28
< 1.1
0.57
< 5.0
80
0.15
NA
11/09/2004
1.2
34
< 1.1
0.24
< 5.0
130
< 0.10
NA
05/17/2005
2.1
35
< 1.1
< 0.10
< 5.0
110
< 0.10
NA
11/03/2005
8.1
34
< 1.1
0.11
<5..0
82
< 0.10
NA
05/24/2006
7.8'
34
< 1.1
< 0.10
< 5.0
120
< 2.5
NA
11/09/2006
1.3
37
< 1.1
0.20
< 5.0
90
< 0.1
NA
05/18/2007
1.7
42
< 1.0
0.16
< 5.0
130
< 0.10
NA
11/13/2007
4.2
41.3.
< 1.1
0.25
< 5.0
112
< 0.10
NA
05/27/2008
6.7
14.3
< 1.1
0.21
< 5.0
168
0.17
NA
11118/2008
25.9
47.6
< 1.1
0.17
< 5.0
80.0
< 0.10
NA
MW -5
05/28/2009
16.1
29.0
4.0
0.11
< 5.0
188
< 0.10
NA
11/05/2009
4.7
39.1
2.0
0.15
< 5.0.
112
< 0.10
NA
05/13/2010
3.2
43.0
23
0.17
< 5.0
147
< 0.10
NA
11/08/2010
13.8
43.7
200
< 0.10
< 5.0
113
< 0.10
NA
05/17/2011
4.0
32.3
< 4.0
< 0.10
< 5.0
< 167
< 0.10
NA
11/15/2011
3.0
52.6
120
< 0.20
< 5.0
165
< 0.10
NA
05/17/2012
4.7
36.6 1
< 2.0
< 0.20
< 5.0
110
< 0.10
NA
11/07/2012
4.1
61.1
< 10.0
0.12
< 2.0
139
< 0.10
NA
05/16/2013
4.0
44.2
1.0
0.093
2.3
152
1 < 0.10
NA
11/20/2013
4.2
64.6
1.0
0.19
< 2.0
162
< 0.10
NA
05/22/2014
5.8
6.6
< 10.0
0.099
< 2.0
110
< 0.10
NA
11/18/2014
16.0
57.7
6.0
0.28
< 2.0
160
< 0.10
NA
05/13/2015
21.0
68.4
< 2.0
0.11
< 2.0
176
< 0.10
NA
11/0472015
7.3
20.3
7.0
< 0.020
NA
68.0
< 0.10
0.21
05/04/2016
8.6
41.5
< 10.0
0.042
NA
90.0
< 0.10
0.12
11/09/2016
1 <1.0
1 45.0
< 4.0
0.42
NA
109
< 0.10
0.47
Standards
1 10
1 250
1
10
250
500
1.5
NL
P:\Cleinent Pappas\Reports\2016 2081.01\November\November 2016_Historic Analytical Results Page 2 of.5
Table 1
Current and Historical Groundwater Analytical Results
for Microbiology and Wet Chemistry
Clement Pappas
Hendersonville, North Carolina
Sample Name
Sample Date
O
�
N
U
m
O
o
N
v_
o
0i
_
O
U
mm
LL
Y'
z
Y
=
�
'O
N
N
O m
v
o �,
N
o
E
a
N
�
O
L
a.
o
(mm/dd/yyyy)
(mg/L)
(mg/L)
(CFU per 100 mL)
(mg/L)
(rrig/L)
(mgJL)
(mg/L) I
(mg/L)
05/15/2002
6.8
9.9
5.1
< 0.10
11
< 40
< 0.10
NA
11/05/2002
3.9
4.6
< 1.1
0.49
9.8
51
2.5
NA
05/13/2003
4.4
7.3
> 23.0
0.075
14
52
0.14
NA
11/04/2003
26
6.8
9.2.
< 0.050
12
< 20
< 0.10
NA
05/05/2004
1.8
6.7
1.1
< 0.10
11
58
0.13
NA
11/09/2004
3.5
11
9.2
< 0.10
9.3
88
< 0.10
NA
05/17/2005
2.4
7.4
< 1.1
< 0.10
8.7
50
< 0.10
NA
11/03/2005
6.3
9.6
< 1.1
< 0.10
9.6
66
0.17
NA
05/24/2006
7.4
10
< 1.1
< 0.10
9
54
< 0.10
NA
11/09/2006
1.4
11
< 1.1
0.20
11
54
0.18
NA
05/18/2007
3.9
9.4
< 1.0
< 0.10
9.1
58
0.12
NA
11/13/2007
5.7
10.7
3.6
0.24
5.8
114
0.24
NA
05/27/2008
10.9
5.4
< 1.1
< 0.10
15.3
92.0
< 0.10
NA
11/18/2008
7.4
7.6
> 23
< 0.10
< 5.0
36.0
< 0.10
NA
MW
05/28/2009
6.4
6.2
276
0.39
8.8
104
< 0.10
NA
-6
11/05/2009
6.4
< 5.0
30
0.10
9.3
52.0
< 0.10
NA
05/13/2010
4.3
5.8
< 2.0
< 0.10
8.1
44.0 1
< 0.10
NA
11/08/2010
16.5
5.0
7.0
1.5
9.3
48.0
< 0.10
NA
05/17/2011
6.2
9.4
< 2.0
< 0.10
6.8
60.0
< 0.10
NA
11/15/2011
4.6
5.2
5.0
< 0.20
7.5
82.0
< 0.10
NA
05/17/2012
21.6
8.1
28.0
< 0.20
8.8
52.0
< 0.10
NA
11/07/2012
6.4
6.8
3.1
< 0.020
7.5
46.0
< 0.10
NA
05/16/2013
7.5
5.4 1
12.1
0.048
9.4
62.0
< 0.10
NA .
11/20/2013
4.4
7.3
< 1.0
< 0.020
8.6
56.0
< 0.10
NA
05/22/2014
4.6
4.5
1.0
< 0.0201
10.1
32.0
< 0.10
NA
11/18/2014
16.3
6.9
13.0
0.078
9.8
49.0 1
< 0.10
NA
05/13/2015
2.1
6.2
< 1.0
< 0.020
10.1
46.0
< 0.10
NA
11/04/2015
2.2
9.5
136
2.9
NA
58.0
< 0.10
0.12
05/04/2016
2.1
9.4
< 2.0
0.41
NA
58.0
< 0.10
0.079
11/09/2016
7.1 1
9.0 1
< 10.0
< 0.020
NA
64.0
0.11
0.70
Standards
10 1
250 1
1
1 10
250
500
1.5
NL
P:\Clement Pappas\Reports\2016 2081.01\November\November 2016 -Historic Analytical Results Page 3 of 5
W
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µ
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g
p
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[0
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N
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IZ
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(n
rn
rn
91
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01
Chloride
p
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0
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µ
0
µ
µ
0
O)
b
J
µ
µ
O
µ
Cit
O
A
c
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Z
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n n
µ N
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n
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µ-
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Fecal Coliform
0
D
D
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p
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0
0
0
0 0
p
b
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µ
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µ
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µ
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µ
µ
0
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v
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b
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00
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w CP
N
W
N
W
F-' N
µ
N
µ
µ
µ
µ
µ
P
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µ
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ppapp
Nitrate
O
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pW,7
(WJ
N
M
W
V
(WD
µp
0 µ
O
W
O M
N
N
A
W
A
3
Total Dissolved
O
J➢➢
O (D
(n
b
0
N
b
00
W
0 0
0
M
0 0
0
O
00
00
W
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N
N
p
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SOIIdS
n
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n
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n
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n n
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n
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n
O
n
O
n
O
p
n
0
n
0
n
0
n
0
p
F-
n
O
�-
µ
O
H µ
0 0
µ
0
µ
0
µ
0
µ
0
µ
0
µ
0
µ
0
µ
00
µ
µ µ
0 0
µ
0
µ
0
µ µ
0 0
µ
0
µ
0
µ
0
µ
0
µ
0
µ
O
O
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ppnn
r
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zzpwzzzzzzzzzzzzzzzzzzzzzzzzzzz3
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L11 �-h7
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R�
d
Table 1
Current and Historical Groundwater Analytical Results
for Microbiology and Wet Chemistry
Clement Pappas
Hendersonville, North Carolina
Sample Name
Sample Date
0
U
o
o
C
Gp
Q
m
LL
m
i
n
onF
m
o
9-6
o
an
0
C
E
E
2
a
O
8
I°-
(mm/dd/yyyy)
(mg/L)
(mg/L)
(CFU per 100 ml-)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
05/15/2002
6.8
8.7
< 1.1
< 0.10
9.1
64
'0.10
NA
11/05/2002
4.8
9.8
< 1.1
0.16
7
100
0.57
NA
05/13/2003
5.5
3.3
2.2
L4
9.4
64
0.41
NA
11/04/2003
27
8.1
6.9
<0.050
13
54
<0.10
NA
05/05/2004
3.0
7.4
< LS
0.24
9.8
140
< 0.10
NA
11/09/2004
3.7
6.7
> 23
0.79
6.8
120
< 0.10
NA
05/17/2005
3.8
8.3
< 1.1
0.61
6.4
88
< 0.10
NA
11/03/2005
7.1
11
< 1.1
0.95
8.4
100
< 0.10
NA
05/24/2006
Is
10
< 1.1
0.39
8.1
130
< 0.10
NA
11/09/2006
4.7
12
<1.1
0.97
7.7
96
<0.10
NA
05/18/2007
5.0
15
<1.0
3.0
13
290
<DAD
NA
11/13/2007
8.3
19.6
<1.1
0.97
26.6
154
<0.10
NA
05/27/2008
12.4
20.0
<LS
0.55
35.8
184
<0.10
NA
11/18/2008
14.4
17.2
2.2
<0.10
2L5
118
<DAD
NA
05/28/2009
6.2
24.9
240
0.74
24.9
192
<0.10
NA
11/05/2009
10.8
15.4
50
0.54
18.4
114
<0.10
NA
MW -8
05/13/2010
10.8
14.7
<2.0
LS
24.1
106
<0.10
NA
11/08/2010
23.2
24.3
200
< 0.10
26.3
173
< 0.10
NA
05/17/2011
30
16.9
10.0
12.2
16.1
232
<0.10
NA
11/L5/2011
8.0
26.6
<2.0
3.7
20.2
232
<DAD
NA
05/17/2012
14.4
24.8
12.0
8.0
22.9
356
<0.10
NA
11/07/2012
24.8
28.3
<100
L9
28.3
324
<0.10
NA
05/16/2013
15.8
8.8
10.9
6.8
13.4
248
< 0.10
NA
11/20/2013
21.0
15.4
< 1.0
1.3
24.3
342
< 0.10
NA
05/22/2014
17.6
14Z
< 10.0
0.61
17.8
352
< 0.10
NA
11/18/2014
54.0
16.4
< 4.0
1.1
13.2
421
< 0.10
NA
05/13/2015
19.7
18.3
< 2.0
9.7
12.2
454
< 0.10
NA
11/04/2015
15.0
21.6
4.0
3.0
NA
396
<0.10
0.82
05/04/2016
15.0
24.5
< 10.0
19.1
NA
398
< 0.10
0.62
6/9/2016 -Pace
NA
NA
NA
26.3
NA
NA
NA
NA
06/09/2016 Foam
NA
NA
NA
26.0
NA
NA
NA
NA
11/09/2016
9.7
12.0
<4.0
14.3
NA
333
<0.10
0.26
05/13/2015
2.2
12.4
<2.0
L0
5.5
94.0
<0.10
NA
11/04/2015
3.8
2.6
< 1.0
< 0.020
NA
58.0
< 0.10
0.45
MW -9
05/04/2016
15.0
5.3
< 10.0
0.64
NA
51.0
< 0.10
0.095
11/09/2016
1
9.3
10.7
<20.0
0.77
NA
69.0
<0.10
0.76
She deeds
10
250
1
10
250
500
1.5
NL
Notaa:
mg/L Milligrams per liter
CFO Coliform forming units
mL Milliliters
15.0 Indicates concentration equal to or above Me respective standard.
< 4.0 Indicates constituent concentration was not detected above Me laboratory reporting limit
Standards From North Carolina Administrative Code, Title 15A, Subchapter 2L April 1,2013, except total organic carbon and fecal coliform.
Total organic carbon standard from Spray Irrigation Permit Number W00004797. Fecal coliform standard is 2L standard for total
coliform.
Sulfate Removed from list of necessary analyses as of fall 2015 and replaced by total phosphorous.
NA Not analyzed
NL Indicates no standard limit is set
06032016 -Pace A resampling event was Performed on lune 9, 2016 to investigate nitrateeiceedances in MW -7R and MW -8. One set of samples
was analyzed by Pace Analytical Services, and a second set of samples was analyzed by Prism Laboratories.
P:\Clement Pappas\Reports\2016 2081.01\14ovember\November 2016j1istoric Analytical Results Page 5 of 5
Table 2
Current and Historical Groundwater Analytical Results
for Volatile Organic Compounds
Clement Pappas
Hendersonville, North Carolina
Sample Name
Sample Date
(mm/dd/Yyyy) .
C
OO
O
F
(pg/L)
y
O
L
U
i`-
(pg/L)
4)
C
O
a
c -I
N
(Ug/L)
iu
L
P
O
N
c
W
F
(pg/L)
0
L
S>
(pg/L)
L
O
0
L
ri
(pg/L)
MW -2R
11/09/2006
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/18/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/13/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2008
< 0.50
< 0.50
< 0.50
< 0.50
< 0.5
< 0.50
11/05/2009
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/08/2010
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/15/2011
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/07/2012
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/20/2013
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
MW -4
11/05/2002
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/04/2003
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2004
< 0.50
'< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/03/2005
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2006
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/18/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/13/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2008
< 0.50
< 0.50
< 0.50
< 0.50
< 0.5
< 0.50
11/05/2009
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/08/2010
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/15/2011
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/07/2012
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/20/2013
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2014
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/04/2015
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/09/2016
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
MW -5
11/05/2002
4,700
980
820
13
24
1.9
11/04/2003
3,500
570
510
< 50
<50
< 50
11/09/2004
580
62
38
< 10
< 10
< 10
11/03/2005
1,900
210
220
< 50
< 50
< 50
11/09/2006
350
74
67
0.61
1.2
< 0.50
05/18/2007
320
47
60
< 0.50
< 0.50
< 0.50
11/13/2007
1,150
217
209
2.0
3.4
1.0
11/18/2008
2,680
534
293
< 25.0
< 25.0
< 25.0
11/05/2009
872
106
125
0.92
< 1.0
< 0.50
11/08/2010
578
107
160
< 2.5
< 5.0
< 2.5
11/15/2011
1,450
124
141
< 2.5
< 5.0
< 2.5
11/07/2012
774
68.8
77.8
< 5.0
< 10.0
< 5.0
11/20/2013
332
65.1
80.5
< 1.2
< 2.5
< 1.2
11/18/2014
121
22.2
26.4
< 0.50
< 1.0
< 0.50
11/04/2015
26.1
2.6
2.9
< 0.50
< 1.0
< 0.50
11/09/2016
141
63.1
75.2
< 0.50
< 1.0
< 0.50
2L Standard
0.7
3
70
100
0.03
7
P:\Clement Pappas\Analytical Data\Water\November 2016_Historic Analytical Results Page 1 of 3
Table 2
Current and Historical Groundwater Analytical Results
for Volatile Organic Compounds
Clement Pappas
Hendersonville, North Carolina
P:\Clement Pappas\Analytical Data\Water\November 2016 -Historic Analytical Results Page 2 of 3
d)
iu
L
C
C
O
N
O
UI
d
U
O
O
N
L
O
N
U
O
O
O`
O
U
a
N
-Oc
`O
L
L
U
O
04
U
L
U
N
y
C
C
Q
cI
Sample Date
F
F
0
W
f
j
i
Sample Name
(mm/dd/yyyy)
(Ng/l)
(ug/I)
(ug/I)
(ug/I)
(pg/l)
W/O
MW -6
11/05/2002
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/04/2003
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50'
< 0.50
11/09/2004
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/03/2005
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2006
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/18/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/13/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2008
3.0
< 0.50
< 0.50
< 0.50
< 0.5
< 0.50
11/05/2009
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/08/2010
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0,50
11/15/2011
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/07/2012
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/20/2013
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2014
'< 0.50
< 0.50
< 0.50
<,0.50
< 1.0
< 0.50
11/04/2015
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/09/2016
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
MW -7
11/05/2002
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/04/2003
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2004
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/03/2005
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2006
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/18/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/13/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2008
0.79
< 0.50
< 0.50
< 0.50
< 0.5
< 0.50
11/05/2009
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/08/2010
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/15/2011
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
MW -7R
11/07/2012
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/20/2013
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2014
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/04/2015
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/09/2016
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
2L Standard
0.7
3
70
100
0.03
7
P:\Clement Pappas\Analytical Data\Water\November 2016 -Historic Analytical Results Page 2 of 3
Table 2
Current and Historical Groundwater Analytical Results
for Volatile Organic Compounds
Clement Pappas
Hendersonville, North Carolina
Notes:
Detections
This table only includes compounds that were detected above the laboratory method detection limits!nce the
sampling event in November 2002. The complete suite of compounds analyzed can be found in the individual
analytical reports. Only samples collected during November sampling events were analyzed for volatile organic
compounds, in accordance with Spray Irrigation Permit Number WQ0004797.
pg/L
CD (13
2L Standard
From North Carolina Administrative Code, Title 15A, Subchapter 2L, April 1, 2013.
4,700
Indicates an exceedance ofthe 2L standard.
O
In accordance with the Compliance Evaluation Inspection letter issued by Beverly Price of the DENR, Division
C Y
N N
Y 0
of Water Quality (DWQ) on April 27, 2007, volatile organic compounds and semivolatile organic compounds
C
were sampled duringthe May 2007 sampling event.
Naphthalene
C OC
C
O O
N
L
O
L
L D
O
O
0
0
o CV
o
0
cLi
N ci
U
;
0
Sample Date
F
i`-
U
Sample Name
(mm/dd/yyyy)
W/0
I (P9/1)
W/O (P9/l)
W/1)
(pg/0
MW -8
11/05/2002
< 0.50
< 0.50
< 0.50 < 0.50
< 0.50
< 0.50
11/04/2003
< 0.50
< 0.50
< 0.50 < 0.50
< 0.50
< 0.50
11/09/2004
< 0.50
< 0.50
< 0.50 < 0.50
< 0.50
< 0.50
11/03/2005
< 0.50
< 0.50
< 0.50 < 0.50
< 0.50
< 0.50
11/09/2006
< 0.50
< 0.50
< 0.50 < 0.50
< 1.0
< 0.50
05/18/2007
< 0.50
< 0.50
< 0.50 < 0.50
< 0.50
< 0.50
11/13/2007
< 0.50
< 0.50
< 0.50 < 0.50
< 1.0
< 0.50
11/18/2008
< 0.50
< 0.50
< 0.50 < 0.50
< 0.5
< 0.50 .
11/05/2009
< 0.50
< 0.50
< 0.50 < 0.50
< 1.0
< 0.50
11/08/2010
< 0.50
< 0.50
< 0.50 < 0.50
< 1.0
< 0.50
11/15/2011
< 0.50
< 0.50
< 0.50 < 0.50
< 1.0
< 0.50
11/07/2012
< 0.50
< 0.50
< 0.50 < 0.50
< 1.0
< 0.50
11/20/2013
< 0.50
< 0.50
< 0.50 < 0.50
< 1.0
< 0.50
11/18/2014
< 0.50
< 0.50
< 0.50 < 0.50
< 1.0
< 0.50
11/04/2015
< 0.50
< 0.50
< 0.50 < 0.50
< 1.0
< 0.50
11/09/2016
< 0.50
< 0.50
< 0.50 < 0.50
< 1.0
< 0.50
MW -9
11/04/2015
< 0.50
< 0.50
< 0.50 < 0.50
< 1.0
< 0.50
11/09/2016
< 0.50
< 0.50
< 0.50 < 0.50
< 1.0
< 0.50
2L Standard
0.7
3
70 100
0.03
7
Notes:
Detections
This table only includes compounds that were detected above the laboratory method detection limits!nce the
sampling event in November 2002. The complete suite of compounds analyzed can be found in the individual
analytical reports. Only samples collected during November sampling events were analyzed for volatile organic
compounds, in accordance with Spray Irrigation Permit Number WQ0004797.
pg/L
Micrograms per liter
2L Standard
From North Carolina Administrative Code, Title 15A, Subchapter 2L, April 1, 2013.
4,700
Indicates an exceedance ofthe 2L standard.
5/18/2007
In accordance with the Compliance Evaluation Inspection letter issued by Beverly Price of the DENR, Division
of Water Quality (DWQ) on April 27, 2007, volatile organic compounds and semivolatile organic compounds
were sampled duringthe May 2007 sampling event.
Naphthalene
Detected in MW -6 for the first time at a concentration of 2.2 pg/L (which is below the 2L standard of 6 pg/L)
duringthe November 5, 2002 sampling event.
1,1,2 -trichloroethane - Detected in MW -5 for the first time on November 20, 2010 at a concentration of 8.0 pg/L, which exceeds the
North Carolina Interim Maximum Allowable Concentration of 0.6 pg/L.
Chloroform Detected for the first time in MW -5 during the November 2011 sampling event at a concentration of 31.3
pg/L, which is below the 2L standard of 70 pg/L.
Toluene Detected for the first time in MW -4 during the November 2015 sampling event at a concentration of 0.75
pg/L, which is below the 2L standard of 600 pg/L.
P:\Clement Pappas\Analytical Data\Water\November 2016 -Historic Analytical Results Page 3 of 3
Table 3
Current and Historical Groundwater Elevation Measurements
Clement Pappas
Hendersonville, North Carolina
Well Identification
Date Measured
Depth to
Groundwater
Top -of -Casing
Elevation
Top -of -Casing
Height Above
Ground surface
Groundwater
Elevation
_
(mm/dd/yyM
(ft-BTOC)
(feet)
(feet)
(feet)
MW -2R
05/24/2006
9.29
2063.00
3.77
2053.71
11/09/2006
6.49
2063.00
3.77
2056.51
05/18/2007
7.94
2063.00
3.77
2055.06
11/13/2007
8.46
2063.00
3.77
2054.54
05/27/2008
8.48
2063.00
3.77
2054.52
11/18/2008
8.50
2063.00
3.77
2054.50
05/28/2009
5.43
2063.00
3.77
2057.57
11/05/2009
6.72
2063.00
3.77
2056.28
05/13/2010
7.36
2063.00
3.77
2055.64
11/08/2010
9.60
2063.00
3.77
2053.40
05/17/2011
7.25
2063.00
3.77
2055.75
11/15/2011
7.86
2063.00
3.77
2055.14
05/17/2012
5.19
2063.00
3.77
2057.81
11/07/2012
7.74
2062.36
3.77
2054.62
05/16/2013
6.86
2062.36
3.77
2055.50
11/20/2013
7.92
2062.36
3.77
2054.44
05/22/2014
7.56
2062.36 1
3.77
2054.80
11/18/2014
8.89
1 2062.36 1
3.77
2053.47
Well abandoned, replaced by MW -9
MW -4
05/15/2002
9.32
2064.60
2.43
2055.28
11/05/2002
9.49
2064.60
2.43
2055.11
05/13/2003
8.20
2064.60
2.43
2056.40
11/04/2003
9.23
2064.60
2.43
2055.37
05/05/2004
9.35
2064.60
2.43
2055.25
11/09/2004
8.61
2064.60
2.43
2055.99
05/17/2005
6.19
2064.60
2.43
2058.41
11/03/2005
9.57
2064.60
2.43
2055.03
05/24/2006
9.60
2064.60
2.43
2055.00
11/09/2006
8.41
2064.60 1
2.43
2056.19
05/18/2007
9.42
2064.60
2.43
2055.18
11/13/2007
9.89
2064.60
2.43
2054.71
05/27/2008
9.78
2064.60
2.43
2054.82
11/18/2008
9.76
2064.60
2.43
2054.84
05/28/2009
7.16
2064.60
2.43
2057.44
11/05/2009
8.53
2064.60
2.43
2056.07
05/13/2010
8.83
2064.60
2.43
2055.77
11/08/2010
9.30
2064.60
2.43
2055.30
05/17/2011
8.97
2064.60
2.43
2055.63
11/15/2011
9.48
2064.60
2.43
2055.12
05/17/2012
7.62
2064.60
2.43
2056.98
11/07/2012
9.32
2063.77
2.43
2054.45
05/16/2013
7.93
2063.77
2.43
2055.84
11/20/2013
8.87
2063.77
2.43
2054.90
05/22/2014
8.70
2063.77
2.43
2055.07
11/18/2014
8.54
2063.77
2.43
2055.23
05/13/2015
9.18
2063.77
2.43
2054.59
11/4/20156.93
2063.77
2.43
2056.84
05/04/2016
8.43
1 2063.77
2.43
2055.34
11/09/2016
9.63
1 2063.77
2.43
1 2054.14
P:\Clement Pappas\Reports\2016 2081.01\November\Table 2 Historic GW Elev Page 1 of 5
Table 3
Current and Historical Groundwater Elevation Measurements
Clement Pappas
Hendersonville, North Carolina
Well Identification
Date Measured
Depth to
Groundwater
Top -of -Casing .
Elevation
Top -of -Casing
Height Above
Ground Surface
Groundwater
Elevation
(mm/dd/yyyy)
(ft-BTOC)
(feet)
(feet)
(feet)
MW -5
05/15/2002
8.31
2086.40
3.00
2078.09
11/05/2002
10.20
2086.40
3.00
2076.20
05/13/2003
8.29
2086.40
3.00
2078.11
11/04/2003
9.92
2086.40
3.00
2076.48
05/05/2004
8.75
2086.40
3.00
2077.65
11/09/2004
8.50
2086.40
3.00
2077.90
05/17/2005
8.87
2086.40
3.00
2077.53
11/03/2005
9.70
2086.40
3.00
2076.70
05/24/2006
9.34
2086.40
3.00
2077.06
11/09/2006
8.39
2086.40
3.00
2078.01
05/18/2007
9.16
2086.40
3.00
2077.24
11/13/2007
11.00
2086.40
3.00
2075.40
05/27/2008
9.84
2086.40
3.00
2076.56
11/18/2008
11.59
2086.40
3.00
2074.81
05/28/2009
7.95
2086.40
3.00
2078.45
11/05/2009
8.63
2086.40
3.00
2077.77
05/13/2010
8.87
2086.40
3.00
2077.53
11/08/2010
10.24
2086.40
3.00
2076.16
05/17/2011
8.99
2086.40
3.00
2077.41
11/15/2011
10.58
2086.40
3.00
2075.82
05/17/2012
8.73
2086.40
3.00
2077.67
11/07/2012
9.65.
2085.60
3.00
2075.95
05/16/2013
8.14
2085.60
3.00
2077.46
11/20/2013
9.33
2085.60
3.00
2076.27
05/22/2014
8.57
2085.60
3.00
2077.03
11/18/2014
9.04
2085.60
3.00
2076.56
05/13/2015
8.92
2085.60
3.00
2076.68
11/4/2015
8.12
2085.60
3.00
2077.48
05/04/2016
8.54
2085.60
3.00
2077.06
11/09/2016
11.25
2085.60
3.00
1 2074.35
P:\Clement Pappas\Reports\2016 2081.01\November\Table 2 Historic GW Elev Page 2 of 5
Table 3
Current and Historical Groundwater Elevation Measurements
Clement Pappas
Hendersonville, North Carolina
Well Identification
Date Measured
Depth to
Groundwater
Top -of -Casing
Elevation
Top -of -casing
Height Above
Ground Surface
Groundwater
Elevation
(mm/dd1wM
(ft-BTOC)
(feet)
(feet)
(feet)
MW -6
05/15/2002
6.20
2061.90
3.00
2055.70
11/05/2002
6.15
2061.90
3.00
2055.75
05/13/2003
5.43
206L90
3.00
2056.47
11/04/2003
5.85
2061-90
3.00
2056.05
05/05/2004
6.00
2061.90
3.00
2055.90
11/09/2004
5.32
2061.90
3.00
2056.58
05/17/2005
6.10
2061.90
3.00
2055.80
11/03/2005
6.01
2061.90
3.00
2055.89
05/24/2006
6.48
2061.90
3.00
2055.42
11/09/2006
5.71
2061.90
3.00
2056.19
05/18/2007
6.50
2061.90
3.00
2055.40
11/13/2007
7.85
2061.90
3.00
2054.05
05/27/2008
7.01
2061.90
3.00
2054.89
11/18/2008
7.38
2061.90
3.00
2054.52
05/28/2009
5.63
2061.90
3.00
2056.27
11/05/2009
5.74
2061-90
3.00
2056.16
05/13/2010
5.90
2061-90
3.00
2056.00
11/08/2010
5.99
2061.90
3.00
2055.91
05/17/2011
5.85
2061.90
3.00
2056.05
11/15/2011
6.14
2061.90
3.00
2055.76
05/17/2012
5.87
2061.90
3.00
2056.03
11,/07/2012
6.05
2061.17
3.00
2055.12
05/16/2013
5.84
2061.17
3.00
2055.33
11/20/2013
5.96
2061.17
3.00
2055.21
05/22/2014
5.96
2061.17
3.00
2055.21
11,/1$/2014
5.82
2061-17
3.00
2055.35
05/13/2015
6.05
2061.17
3.00
2055.12
11./4/2015
5.18
2061.17
3.00
2055.99
05/04/2016
5.59
2061.17
3.00
2055.58
11/09/2016
7.42
2061.17
3.00
2053.75
R\Clement Pappas\Reports\2016 2081.01\November\Table 2 Historic GW Elev Page 3 of 5
Table 3
Current and Historical Groundwater Elevation Measurements
Clement Pappas
Hendersonville, North Carolina
Well Identification
Date Measured
Depth to
Groundwater
Top -of -Casing
Elevation
Top -of -Casing
Height Above
Ground Surface
Groundwater
Elevation
(mm/dd/yyyy)
(ft-BTOC)
(feet)
(feet)
(feet)
MW -7
05/15/2002
10.90
2062.70
3.00
2051.80
11/05/2002
11.35
2062.70
3.00
2051.35
05/13/2003
8.87
2062.70
3.00
2053.83
11/04/2003
10.78
2062.70
3.00
2051.92
05/05/2004
10.80
2062.70
3.00
2051.90
11/09/2004
9.70
2062.70
3.00
2053.00
05/17/2005
10.60
2062.70
3.00
2052.10
11/03/2005
11.09
2062.70
3.00
2051.61
05/24/2006
11.27
2062.70
3.00
2051.43
11/09/2006
9.71
2062.70
3.00
2052.99
05/18/2007
11.02
2062.70
3.00
2051.68
11/13/2007
11.76
2062.70
3.00
2050.94
05/27/2008
11.55
2062.70
3.00
2051.15
11/18/2008
11.63
2062.70
3.00
2051.07
05/28/2009
8.21
2062.70
3.00
2054.49
11/05/2009
9.89
2062.70
3.00
2052.81
05/13/2010
10.44
2062.70
3.00
2052.26
11/08/2010
11.12
2062.70
3.00
2051.58
05/17/2011
10.80
2062.70
3.00
2051.90
11/15/2011
11.43
2062.70
3.00
2051.27
05/17/2012
8.91
2062.70
3.00
2053.79
MW -7R
11/07/2012
12.02
2062.86
3.00
2050.84
05/16/2013
10.29
2062.86
3.00
2052.57
11/20/2013
11.69
2062.86
3.00
2051.17
05/22/2014
11.38
2062.86
3.00
2051.48
11/18/2014
11.25
2062.86
3.00
2051.61
05/13/2015
11.94
2062.86
3.00
2050.92
11/4/2015
8.43
2062.86
3.00
2054.43
05/04/2016
11.08
2062.86
3.00
2051.78
11/09/2016
12.63
2062.86
3.00
2050.23
P:\Clement Pappas\Reports\2016 2081.01\November\Table 2 Historic GW Elev Page 4. of 5
Table 3
Current and Historical Groundwater Elevation Measurements
Clement Pappas
Hendersonville, North Carolina
Well Identification
Date Measured
Depth to
Groundwater
Top -of -Casing
Elevation
Top -of -Casing
Height Above
Ground Surface
Groundwater
Elevation
elevations
(mm/dd/yyyy)
(ft-BTOC)
(feet)
(feet)
(feet)
MW -8
05/15/2002
10.25
2061.40
3.00
2051.15
11/05/2002
10.35
2061.40
3.00
2051.05
05/13/2003
8.16
2061.40
3.00
2053.24
11/04/2003
10.23
2061.40
3.00.
2051.17
05/05/2004
10.30
2061.40
3.00
2051.10
11/09/2004
8.90
2061.40
3.00
2052.50
05/17/2005
10.08
2061.40
3.00
2051.32
11/03/2005
10.61
2061.40
3.00
2050.79'
05/24/2006
10.60
2061.40
3.00
2050.80
11/09/2006
9.40
2061.40
3.00
2052.00
05/18/2007
10.31
2061.40
3.00
2051.09
11/13/2007
11.09
2061.40
3.00
2050.31
05/27/2008
10.83
2061.40
.3.00
2050.57
11/18/2008
11.11
2061.40
3.00
2050.29
05/28/2009
8.25
2061.40
3.00
2053.15
11/05/2009
.9.22
2061.40
3.00
2052.18
05/13/2010
9.88
2061.40
3.00
2051.52
11/08/2010
10.38
2061.40
3.00
2051.02
05/17/2011
10.27
2061.40
3.00
2051.13
11/15/2011
10.87
2061.40
3.00
2050.53
05/17/2012
8.03
2061.40
3.00
2053.37
11/07/2012
10.45
2060.80
3.00
2050.35
05/16/2013
8.58
2060.80
3.00
2052.22
11/20/2013
10.34
2060.80
3.00
2050.46
05/22/2014
9.79
2060.80
3.00
2051.01
11/18/2014
10.03
2060.80
3.00
2050.77
05/13/2015
10.34
2060.80
3.00
2050.46
11/4/2015
7.21
2060.80
3.00
2053.59
05/04/2016
9.84
2060.80
3.00
2050.96
11/09/2016
11.16
2060.80
3.00
2049.64
MW -9
05/13/2015
6.03
2060.23
1.44
2054.20
11/4/2015
2.89
2060.23
1.44
2057.34
05/04/2016
5.53
2060.23
1.44
2054.70
11/09/2016 1
6.55
1 2060.23
1.44
2053.68
Notes:
ft-BTOC
Feet below top -of -well casing
Top -of -casing
MW -5th rough MW -8 top -of -casing elevations based upon a survey by Hill and Associates Surveyors dated
elevations
January10, 2002 through May 2012. MW -2R and MW -4 top -of -casing elevations based upon differential level
measurements made by Altamont Environmental, Inc. on June 26, 2006 through May 2012. The tap -of -casing
elevations for the monitoring wells were resurveyed on November 21, 2012 by Wes Cole Land Surveying. The
top -of -casing elevations for MW -9 were surveyed on May 29, 2015 by Wes Cole Land Surveying.
Groundwater Top of casing minus depth to groundwater.
elevations
P:\Clement Pappas\Reports\2016 2081.01\November\Table 2 Historic GW Elev Page 5 of 5
2ceAna1j&a1
wxxpscebbs.com
November 18, 2016
Brian Gant
Altamont Environmental
231 Haywood Street
Asheville, NC 28804
RE: Project: Clement Pappas
Pace Project No.: 92319070
Dear Brian Gant:
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Enclosed are the analytical results for sample(s) received by the laboratory on November 09, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lord Patton
lorri.pafton@pacelabs.com
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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aceAnalXical
w»w.panleoa.mrri
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28a04
(828)264-7176
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 2 of 37
aceAnalytical
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SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)2547176
Project:
Clement Pappas
Pace Project No.:
92319070
Analytes
Lab ID
Sample ID
Method
Anti
Reported
Laboratory
92319070001
MW -4
SM 6200B
CAH
63
PASI-C
SM 2540C
MJS1
1
PASI-A
SM 9222D
KDF1
1
PASI-A
EPA 350.1 1993 Rev 2.0
BRJ
1
PASI-A
EPA 353.2
WRC
1
PASI-A
EPA 365.1
MDW
1
PASI-A
SM 4500 -CI -E
WRC
1
PASI-A
SM 53108
AES2
1
PASI-A
92319070002
MW -5
SM 62008
CAH
63
PASI-C
SM 2540C
MJS1
1
PASI-A
SM 9222D
KDF1
1
PAST -A
EPA 350.1 1993 Rev 2.0
BRJ
1
PASI-A
EPA 353.2
WRC
1
PASI-A
EPA 365.1
MDW
1
PASI-A
SM 4500 -CI -E
WRC
1
PASI-A
SM 5310B
AES2
1
PASI-A
92319070003
MW -6
SM 62008
CAH
63
PASI-C
SM 2540C
MJS1
1
PASI-A
SM 9222D
KDF1
1
PASI-A
EPA 350.1 1993 Rev 2.0
BRJ
1
PASI-A
EPA 353.2
WRC
1
PASI-A
EPA 365.1
MDW
1
PASI-A
SM 4500 -CI -E
WRC
1
PASI-A
SM 53108
AES2
1
PASI-A
92319070004
MW -7R
SM 6200B
CAH
63
PASI-C
SM 2540C
MJS1
1
PASI-A
SM 9222D
KDF1
1
PASI-A
EPA 350.1 1993 Rev 2.0
BRJ
1
PASI-A
EPA 353.2
WRC
1
PASI-A
EPA 365.1
MDW
1
PASI-A
SM 4500 -CI -E
WRC
1
PAST -A
SM 53108
AES2
1
PASI-A
92319070005
MW -8
SM 62006
CAH
63
PASI-C
SM 2540C
MJS1
1
PASI-A
SM 92220
KDF1
1
PASI-A
EPA 350.1 1993 Rev 2.0
BRJ
1
PASI-A
EPA 353.2
WRC
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 37
aceAnalytical'
wwwpacelabs.com
SAMPLE ANALYTE COUNT
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project:
Clement Pappas
Pace Project No.:
92319070
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
'EPA 365.1
MDW
1
PASI-A
SM 4500 -CI -E
WRC
1
PASI-A
SM 53108
AES2
1
PASI-A
92319070006
MW -9
SM 62008
CRH
63
PASI-C
SM 2540C
Mist
1
PASI-A
SM 9222D
KDF1
1
PASI-A
EPA 350.1 1993 Rev 2.0
BRJ
1
PASI-A
EPA 353.2
WRC
1
PASI-A
EPA 365.1
MDW
1
PASI-A
SM 4500 -CI -E
WRC
1
PASI-A
SM 53108
AES2
1
PASI-A
92319070007
Trip Blank
SM 62008
CAH
63
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in NII,
without the written consent of Pace Analytical Services, LLC. Page 4 of 37
-Pace Analytical m
..peceleb&=
ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Sample: MW4 Lab ID: 92319070001 Collected: 11/09/1613:00 Received: 11/09/1614:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method: SM 62008
Benzene
ND
ug/L
0.50
1
11112/16 10:08
7143-2
Bromobenzene
ND
ug/L
0.50
1
11/12/16 10:08
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/12116 10:08
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/12/1610:08
75-274
Bromoform
ND
ug/L
0.50
1
11/12/16 10:08
75-25-2
Bromomethane
NO
ug/L
5.0
1
11/12/1610:08
74-83-9
n-Butylbenzene
NO
ug/L
0.50
1
11/12/16 10:08
104-51-8
sec-Butylbenzene
NO
ug/L
0.50
1
11/12/16 10:08
135-98-8
tert-Butylbenzene
NO
ug/L
0.50
1
11/12/1610:08
98-06-6
Carbon tetrachloride
NO
ug/L
0.50
1
11/12/16 10:08
56-23-5
Chlorobenzene
NO
ug/L
0.50
1
11/12/16 10:08
108-90-7
Chloroethane
ND
ug/L
1.0
1
11112/1610:08
75-00-3
Chloroform
NO
ug/L
0.50
1
11/12/1610:08
67-66-3
Chloromethane
ND
ug/L
1.0
1
11112/1610:08
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/12/1610:08
9549-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/12/1610:08
106434
1,2-Dibromo-3-chloropropane
NO
ug/L
1.0
1
11/1211610:08
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/12/1610:08
12448-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/12/16 10:08
106-934
Dibromomethane
NO
ug/L
0.50
1
11/1211610:08
74-95-3
1,2 -Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 10:08
95-50-1
1,3 -Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 10:08
541-73-1
1,4 -Dichlorobenzene
NO
ug/L
0.50
1
11/12/16 10:08
106-46-7
Dichlorodifluoromethane
NO
ug/L
0.50
1
11112/1610:08
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/12/1610:08
75-343
1,2-Dichloroethane
ND
ug/L
0.50
1
11/12/1610:08
107-06-2
1,1-Dichloroethene
NO
ug/L
0.50
1
11/12/1610:08
75-354
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/12/1610:08
156-59-2
trans-1,2-Dichloroethene
NO
ug/L
0.50
1
11/12/16 10:08
156-60-5
1,2-Dichloropropane
NO
ug/L
0.50
1
11/12/16 10:08
78-87-5
1,3-Dichloropropane
NO
ug/L
0.50
1
11/12/16 10:08
142-28-9
2,2-Dichloropropane
NO
ug/L
0.50
1
11/12/1610:08
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/12/1610:08
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/12/1610:08
10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11/12/16 10:08
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/12/16 10:08
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/12/1610:08
100414
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/12/1610:08
87-68-3
Isopropylbenzene (Cumene)
NO
ug/L
0.50
1
11/12/16 10:08
98-82-8
Methylene Chloride
NO
ug/L
2.0
1
11/12/16 10:08
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/1211610:08
1634-044
Naphthalene
NO
ug/L
2.0
1
11/12/1610:08
91-20-3
n-Propylbenzene
NO
ug/L
0.50
1
11/12/16 10:08
103-65-1
Styrene
NO
ug/L
0.50
1
11/12/1610:08
10042-5
1,1,1,2 -Tetrachloroethane
ND
ug/L
0.50
1
11/1211610:08
630-20-6
1,1,2,2 -Tetrachloroethane
ND
ug/L
0.50
1
11/12/1610:08
79-345
Tetrachloroethene
NO
ug/L
0.50
1
11/12/1610:08
127-184
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 37
PaceAnalytical e
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ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Sample: MW -4 Lab ID: 92319070001 Collected: 11/09/1613:00 Received: 11/09/1614:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1 -Trichloroethane
1,1,2 -Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2, 3-Trichloropropane
1,2,4-Trimelhylbenzene
1,3, 5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o -Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8(S)
2640C Total Dissolved Solids
Total Dissolved Solids
MBIO 9222D Fetal Coliform AVL
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
53108 TOC
Total Organic Carbon
Date: 11/18/2016 10:59 AM
Analytical Method: SM 6200B
ND ug/L
0.50
ND ug/L
2.0
NO ug/L
2.0
NO ug/L
0.50
NO ug/L
0.50
NO ug/L
0.50
NO ug/L
1.0
NO ug/L
0.50
NO ug/L
0.50
NO ug/L
0.50
NO ug/L
1.0
NO ug/L
1.0
NO ug/L
0.50
93 %
70-130
96 %
70-130
100 %
70-130
Analytical Method: SM 2540C
124 mg/L
25.0
Analytical Method: SM 9222D
ND CFU/100 mL
4.0
Analytical Method: EPA 350.1 1993
Rev 2.0
NO mg/L
0.10
Analytical Method: EPA 353.2
NO mg/L
0.020
Analytical Method: EPA 365.1
0.27 mg/L
0.050
Analytical Method: SM 4500 -CI -E
12.2 mg/L
1.0
Analytical Method: SM 5310B
4.3 mg/l-
1.0
1 11/12116 10:08
108-88-3
1 11/12/1610:08
87-61-6
1 11/1211610:08
120-82-1
1 11/12/16 10:08
71-55.6
1 11/12/1610:08
79-00-5
1 11/12/1610:08
79-01-6
1 11/12/1610:08
75-69-4
1 11/1211610:08
96-184
1 11/12/1610:08
95-63-6
1 11/12/1610:08
108-67-8
1 11/12/1610:08
7"14
1 11/12/16 10:08
179601-23-1
1 11/12/16 10:08
95-47-6
1 11/12/16 10:08
17060-07-0
1 11/12/16 10:08
460-004
1 11/1211610:08
2037-26-5
1 11/11/16 14:53
4 11/09/16 15:39
1 11/17/1607:39 766441-7
1 11/11/16 00:00
1 11/11/1623:05 7723-14-0
1 11117/1617:01 16887-00-6
1 11/17/1611:05 744044-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 37
aceAnalj cal
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: Clement Pappas
Pace Project No.: 92319070
Sample: MW -5
Lab ID: 92319070002 Collected: 11/09/16 11:15 Received:
11/09/16 14:30 Matrix: Water
Parameters
Results
Units
Report Limit
DF Prepared
Analyzed
CAS No. Qua]
6200B MSV
Analytical Method: SM 62008
Benzene
ND'
ug/L
0.50
1
11/12/1610:25
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/12/1610:25
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/12/1610:25
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/12/1610:25
75-27-4
Bromoform
ND
ug/L
0.50
1
11/12/1610:25
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/12/1610:25
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/12/1610:25
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/12/1610:25
135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
11/12/1610:25
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/12/16 10:25
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/12/1610:25
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/12/1610:25
75-00-3
Chloroform
ND
ug/L
0.50
1
11/12/1610:25
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/12/1610:25
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/12/1610:25
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/12/1610:25
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/12/1610:25
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/12/1610:25
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/12/16 10:25
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/12/1610:25
74-95-3
1,2 -Dichlorobenzene
ND
ug/L
0.50
1
11/12/1610:25
95-50-1
1,3 -Dichlorobenzene
ND
ug/L
0.50
1
11/12/1610:25
541-73-1
1,4 -Dichlorobenzene
ND
ug/L
0.50
1
11/12/1610:25
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/12/1610:25
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/12/1610:25
75-34-3'
1,2-Dichloroethane
ND
ug/L
0.50
1
11112/1610:25
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11112/1610:25
75-35-4
cis-1,2-Dichloroethene
75.2
ug/L
0.50
1
11/12/1610:25
156-59-2
trans-1,2-Dich]oroethene
ND
ug/L
0.50
1
11/12/1610:25
156-60-5
1,2-Dich]oropropane
ND
ug/L
0.50
1
11/12/1610:25
78-87-5
1,3-Dich]oropropane
ND
ug/L
0.50
1
11112/1610:25
142-28-9
2,2-Dichloro propane
ND
ug/L
0.50
1
11/12/1610:25
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/12/1610:25
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/12/1610:25
10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11/12/1610:25
10061-02-6
Diisopropy] ether
ND
ug/L
0.50
1
11/12/16 10:25
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/12/1610:25
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/12/1610:25
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/12/16 10:25
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/12/16 10:25
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/12/16 10:25
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/12/1610:25
91-20-3
n-Propy]benzene
ND
ug/L
0.50
1
11/12/1610:25
103-65-1
Styrene
ND
ug/L
0.50
1
11/12/1610:25
100-42-5
1,1,1,2 -Tetrachloroethane
ND
ug/L
0.50
1
11/12/1610:25
630-20-6
1,1,2,2 -Tetrachloroethane
ND
ug/L
0.50
1
11/12/1610:25
79-34-5
Tetrachloroethene
141
ug/L
0.50
1
11/12/1610:25
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not
be reproduced, except in full,
Date: 11118/2016 10:59 AM
without
the written consent
of Pace Analytical Services, LLC.
Page 7 of 37
Pace Analytical Services, LLC
ice
2225 Riverside Dr.
Asheville, NC 28804
1vawPw8AEamal (828)2547176
ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Sample: MW -5 Lab ID: 92319070002 Collected: 11/09/1611:15 Received: 11/09/1614:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Toluene
NO ug/L
0.50
1
11/12/16 10:25
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/12/16 10:25
87-61-6
1,2,4-Tdchlorobenzene
NO ug/L
2.0
1
11/12/16 10:25
120-82-1
1,1,1 -Trichloroethane
ND ug/L
0.50
1
11/12/1610:25
71-55-6
1,1,2-Tdchloroethane
NO ug/L
0.50
1
11/12/1610:25
79-00-5
Trichloroethene
63.1 ug/L
0.50
1
11/12/16 10:25
79-01-6
Trichlorofluoromethane
NO ug/L
1.0
1
11/12/1610:25
75-694
1,2,3-Trichlompropane
NO ug/L
0.50
1
11/12/1610:25
96-184
1,2,4-Trimethylbenzene
NO ug/L
0.50
1
11/12/1610:25
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/12/1610:25
108-67-8
Vinyl chloride
NO ug/L
1.0
1
11/12/16 10:25
75-014
m&p-Xylene
ND ug/L
1.0
1
11/12/1610:25
179601-23-1
o -Xylene
NO ug/L
0.50
1
11/12/1610:25
9547-6
Surrogates
1,2-Dichloroethane-d4 (S)
89 %
70-130
1
11/12/16 10:25
17060-07-0
4-Bromofluorobenzene (S)
95 %
70-130
1
11/12/16 10:25
460-004
Toluene -d8 (S)
99 %
70-130
1
11/12/16 10:25
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
109 mg/L
25.0
1
-11/11/16 14:54
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D
Fecal Coliforms
NO CFU/100 mL
4.0
4
11/09/16 15:39
360.1 Ammonia
Analytical Method: EPA 350.1 1993
Rev 2.0
Nitrogen, Ammonia
NO mg/L
0.10
1
11/17/1607:41
766441-7
353.2 Nitrogen, NO2IN03 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
0.42 mg/L
0.020
1
11/10/1623:55
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0.47 mg/L
0.050
1
11/11/1623:06
7723-14-0
4500 Chloride
Analytical Method: SM 4500 -CI -E
Chloride
45.0 mg/L
4.0
4
11/17/16 17:36
16887-00-6
63108 TOC
Analytical Method: SM 53108
Total Organic Carbon
NO mg/L
1.0
1
11/17/16 11:36
744044-0
Date: 11/1812016 10:59 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 37
aceAnalytical e
wew.pecelab&=
ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Sample: Ill Lab ID: 92319070003 Collected: 11/09/1612:00 Received: 11/09/1614:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method: SM 6200B
Benzene
ND
ug/L
0.50
1
11/12/1610:42
7143-2
Bromobenzene
ND
ug/L
0.50
1
11/12/16 10:42
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/12/1610:42
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/12/1610:42
75-274
Bromoform
ND
ug/L
0.50
1
11/12/1610:42
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/12/1610:42
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/12/1610:42
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/12/1610:42
135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
11/12/16 10:42
98-06-6
Carbon tetrachloride
NO
ug/L
0.50
1
11/12/16 10:42
56-23-5
Chlorobenzene
NO
ug/L
0.50
1
11/12/16 10:42
108-90-7
Chloroethane
NO
ug/L
1.0
1
11/12/1610:42
75-00-3
Chloroform
NO
ug/L
0.50
1
11/12/1610:42
67-66-3
Chloromethane
NO
ug/L
1.0
1
11/12/1610:42
74-87-3
2-Chlorololuene
NO
ug/L
0.50
1
11/12/1610:42
9549-8
4-Chlorololuene
NO
ug/L
0.50
1
11/12/1610:42
106434
1,2-Dibromo-3-chloropropane
NO
ug/L
1.0
1
11/12/16 10:42
96-12-8
Dibromochloromethane
NO
ug/L
0.50
1
11/12/1610:42
12448-1
1,2-Dibromoethane(EDB)
NO
ug/L
0.50
1
11/12/1610:42
106-934
Dibromomelhane
NO
ug/L
0.50
1
11/12/16 10:42
74-95-3
1,2 -Dichlorobenzene
NO
ug/L
0.50
1
11/12/16 10:42
95-50-1
1,3 -Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 10:42
541-73-1
1,4 -Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 10:42
10646-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/12/1610:42
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/12/1610:42
75-343
1,2-Dichloroethane
ND
ug/L
0.50
1
11/12/16 10:42
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/12/1610:42
75-354
cis-1,2-Dichloroelhene
ND
ug/L
0.50
1
11/12/1610:42
156-59-2
Vans-1,2-Dichloroelhene
ND
ug/L
0.50
1
11/12/16 10:42
156-60-5
1,2-Dichloropropane
NO
ug/L
0.50
1
11/12/1610:42
78-87-5
1,3-Dichloropropane
NO
ug/L
0.50
1
11/12/1610:42
142-28-9
2,2-Dichloropropane
NO
ug/L
0.50
1
11/12/16 10:42
594-20-7
1,1-Dichlompropene
NO
ug/L
0.50
1
11/12/16 10:42
563-58-6
cis-1,3-Dichloropropene
NO
ug/L
0.50
1
11/12/16 10:42
10061-01-5
trans-1,3-Dichloropropene
NO
ug/L
0.50
1
11/12/16 10:42
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/12/16 10:42
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/12/16 10:42
100414
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/12/1610:42
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/12/16 10:42
98-82-8
Methylene Chloride
NO
ug/L
2.0
1
11/12/1610:42
75-09-2
Methyl-terl-butyl ether
NO
ug/L
0.50
1
11/12/1610:42
1634-044
Naphthalene
ND
ug/L
2.0
1
11/12/16 10:42
91-20-3
n-Propylbenzene
NO
ug/L
0.50
1 -
11/12/16 10:42
103-65-1
Styrene
NO
ug/L
0.50
1
11/12/16 10:42
10042-5
1,1,1,2 -Tetrachloroethane
NO
ug/L
0.50
1
11/12/1610:42
630-20-6
1,1,2,2 -Tetrachloroethane
ND
ug/L
0.50
1
11/12/1610:42
79-345
Tetrachloroethene
ND
ug/L
0.50
1
11/12/1610:42
127-184
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /18/201610:59 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 37
aceAnalytical
- www.paceleDa.wm
ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)2547178
Sample: MW -6 Lab ID: 92319070003 Collected: 11/09/1612:00 Received: 11/09/1614:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Toluene
1,2,3-Tdchlorobenzene
1,2,4-Trichlorobenzene
1,1,1 -Trichloroethane
1,1,2 -Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Tdmethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o -Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene -d8 (S)
2540C Total Dissolved Solids
Total Dissolved Solids
1111810 9222D Fecal Coliform AVL
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
53108 TOC
Total Organic Carbon
Date: 11/18/2016 10:59 AM
Analytical Method: SM 6200B
NO ug/L
0.50
NO ug/L
2.0
NO ug/L
2.0
NO ug/L
0.50
NO ug/L
0.50
NO ug/L
0.50
NO ug/L
1.0
NO ug/L
0.50
ND ug/L
0.50
ND ug/L
0.50
NO ug/L
1.0
ND ug/L
1.0
ND ug/L
0.50
92 %
70-130
97 %
70-130
100 %
70-130
Analytical Method: SM 2540C
64.0 mg/L
25.0
Analytical Method: SM 9222D
NO CFU/100 mL
10.0
Analytical Method: EPA 350.1 1993
Rev 2.0
0.11 mg/L
0.10
Analytical Method: EPA 353.2
NO mg/L
0.020
Analytical Method: EPA 365.1
0.70 mg/L
0.050
Analytical Method: SM 4500 -CI -E
9.0 mg/L
1.0
Analytical Method: SM 53108
7.1 mg/L
1.0
1 11/12/16 10:42
108-88-3
1 11/12/1610:42
87-61-0
1 11/12/16 10:42
120-82-1
1 11/12/16 10:42
71-55-6
1 11/12/1610:42
79-00-5
1 11/12/1610:42
79411-6
1 11/12/1610:42
75-694
1 11/12/1610:42
96-184
1 11/12/1610:42
95-63-6
1 11/12/16 10:42
108-67-8
1 11/12/1610:42
75-014
1 11/12/16 10:42
179601-23-1
1 11/12/1610:42
9547-6
1 11/12116 10:42
17060-07-0
1 11/12/1610:42
460-004
1 11/12/16 10:42
2037-26-5
1 11/11/16 14:55
10 11/09/16 15:39
1 11/17/1607:42 766441-7
1 11/10/16 23:59
1 - 11/1111623:06 7723-14-0
1 11/17/1617:08 16887-00-6
1 11/17/1611:49 7440440
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 37
`eAna//gy�pp /�����ra •
,ampsewa tam
Project: Clement Pappas
Pace Project No.: 92319070
Sam01e: MW -7R
Parameters
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)2547176
ANALYTICAL RESULTS
Lab ID: 92319070004 Collected: 11/09/1610:25 Received: 11/09/1614:30 Matrix: Water
Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method: SM 62008
Benzene
NO
ug/L
0.50
1
11/12/1610:59
7143-2
Bromobenzene
NO
ug/L
0.50
1
11/12/1610:59
108-86-1
Bromochloromethane
NO
ug/L
0.50
1
11/12/1610:59
74-97-5
Bromodichloromethane
NO
ug/L
0.50
1
11/12/1610:59
75-274
Bromoform
NO
ug/L
0.50
1
11/12/16 10:59
75-25-2
Bromomethane
NO
ug/L
5.0
1
11/12/1610:59
74-83-9
n-Butylbenzene
NO
ug/L
0.50
1
11/12/1610:59
10451-8
sec-Butylbenzene
NO
ug/L
0.50
1
11/12/1610:59
135-98-8
tert-Butylbenzene
NO
ug/L
0.50
1
11/12/1610:59
98-06-6
Carbon tetrachloride
NO
ug/L
0.50
1
11/12/1610:59
56-23-5
Chlorobenzene
NO
ug/L
0.50
1
11/12/16 10:59
108-90-7
Chloroethane
NO
ug/L
1.0
1
11/12/16 10:59
75-00-3
Chloroform
NO
ug/L
0.50
1
11/12/1610:59
67-66-3
Chloromethane
NO
ug/L
1.0
1
11/12/1610:59
74-87-3
2-Chlorotoluene
NO
ug/L
0.50
1
11/12/1610:59
9549-8
4-Chlorotoluene
NO
ug/L
0.50
1
11/12/1610:59
106434
1,2-Dibromo-3-chloropropane
NO
ug/L
1.0
1
11/12/1610:59
96-12-8
Dibromochloromethane
NO
ug/L
0.50
1
11/12/1610:59
12448-1
1,2-Dibromoethane (EDB)
NO
ug/L
0.50
1
11/12/1610:59
106-934
Dibromomethane
NO
ug/L
0.50
1
11/12/1610:59
74-95-3
1,2 -Dichlorobenzene
NO
ug/L
0.50
1
11/12/16 10:59
95-50-1
1,3 -Dichlorobenzene
NO
ug/L
0.50
1
11/12/16 10:59
541-73-1
1,4 -Dichlorobenzene
NO
ug/L
0.50
1
11/12/16 10:59
10646-7
Dichlorodifluoromethane
NO
ug/L
0.50
1
11/12/1610:59
75-71-8
1,1-Dichloroethane
NO
ug/L
0.50
1
11/12/16 10:59
75-34-3
1,2-Dichloroethane
NO
ug/L
0.50
1
11/12/16 10:59
107-06-2
1,1-Dichloroethene
NO
ug/L
0.50
1
11/12/1510:59
75-354
cis-1,2-Dichloroethene
NO
ug/L
0.50
1
11/12/1610:59
156-59-2
trans-1,2-Dichloroethene
NO
ug/L
0.50
1
11/12/1610:59
156-60-5
1,2-Dichloropropane
NO
ug/L
0.50
1
11/12/16 10:59
78-87-5
1,3-Dichloropropane
NO
ug/L
0.50
1
11/12/16 10:59
142-28-9
2,2-Dichloropropane
NO
ug/L
0.50
1
11/12/16 10:59
594-20-7
1,1-Dichloropropene
NO
ug/L
0.50
1
11/12/16 10:59
563-58-6
cis-1,3-Dichloropropene
NO
ug/L
0.50
1
11/12/16 10:59
10061-01-5
trans-1,3-Dichloropropene
NO
ug/L
0.50
1
11/12/16 10:59
10061-02-6
Diisopropyl ether
NO
ug/L
0.50
1
11/12/16 10:59
108-20-3
Ethylbenzene
NO
ug/L
0.50
1
11/12/1610:59
100414
Hexachloro-1,3butadiene
NO
ug/L
2.0
1
11/12/1610:59
87-68-3
Isopropylbenzene (Cumene)
NO
ug/L
0.50
1
11/12/1610:59
98-82-8
Methylene Chloride
NO
ug/L
2.0
1
11/12/1610:59
75-09-2
Methyl-tert-butyl ether
NO
ug/L
0.50
1
11/12/1610:59
1634-044
Naphthalene
NO
ug/L
2.0
1
11/12/1610:59
91-20-3
n-Propylbenzene
NO
ug/L
0.50
1
11/12/1610:59
103-65-1
Styrene
NO
ug/L
0.50
1
11/12/1610:59
10042-5
1,1,1,2 -Tetrachloroethane
NO
ug/L
0.50
1
11/12/1610:59
630-20-6
1,1,2,2 -Tetrachloroethane
NO
ug/L
0.50
1
11/12/1610:59
79-345
Tetrachloroethene
NO
ug/L
0.50
1
11/12/1610:59
127-184
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 37
^^' Pace Analytical Services, LLC
2225 R
de
C/I���l'V lytiM • Ashev Ile, NC 128804
oww0acablacom (828)2547176
ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Sample: MW -7R Lab ID: 92319070004 Collected: 11/09/1610:25 Received: 11/09/1614:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
62008 MSV
Analytical Method: SM 6200B
Toluene
NO ug/L
0.50
1
11/12/16 10:59
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/12/16 10:59
87-61-6
1,2,4-Tdchlorobenzene
ND ug/L
2.0
1
11/12/16 10:59
120-82-1
1,1,1 -Trichloroethane
ND ug/L
0.50
1
11/12/1610:59
71-55-6
1,1,2 -Trichloroethane
ND ug/l-
0.50
1
11/12/1610:59
79-00-5
Trichloroethene
NO ug/L
0.50
1
11/12/16 10:59
79-01-6
Trichlorofluoromethane
NO ug/L
1.0
1
11/12/1610:59
75-694
1,2,3-Trichloropropane
NO ug/L
0.50
1
11/12/1610:59
96-184
1,2,4-Trimethylbenzene
NO ug/L
0.50
1
11/12/1610:59
95-63-6
1,3,5-Trimethylbenzene
NO ug/L
0.50
1
11/12/1610:59
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/12/16 10:59
75-014
m&p-Xylene
NO ug/L
1.0
1
11/12/16 10:59
179601-23-1
o -Xylene
ND ug/L
0.50
1
11/12/1610:59
9547-6
Surrogates
1,2-Dichloroethane-d4 (S)
93 %
70-130
1
11/12/16 10:59
17060-07-0
4-Bromofluorobenzene (S)
96 %
70-130
1
11/12/16 10:59
460-004
Toluene -d8 (S)
101 %
70-130
1
11/12/16 10:59
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
147 mg/L
25.0
1
11/11/16 14:55
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D
Fecal Coliforms
ND CFU/100 mL
20.0
20
11/09/1615:39
360.1 Ammonia
Analytical Method: EPA 350.1 1993
Rev 2.0
Nitrogen, Ammonia
ND mg/L
0.10
1
11/17/1607:44
766441-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
12.5 mg/L
0.10
5
11/11/1600:42
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
1.0 mg/L
0.050
1
11/11/16 23:08
7723-14-0
4500 Chloride
Analytical Method: SM 4500 -CI -E
Chloride
22.7 mg/L
1.0
1
11/17/1617:09
16887-00-6
53108 TOC
Analytical Method: SM 5310B
Total Organic Carbon
13.0 mg/L
1.0
1
11/17/1612:05
744044-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 37
ceAnalyticat
www-0vsleftean
Project: Clement Pappas
Pace Project No.: 92319070
Sample: MW -8
Parameters
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)2547176
ANALYTICAL RESULTS
Lab ID: 92319070005 Collected: 11/09/1609:45 Received: 11/09/1614:30 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
62008 MSV Analytical Method: SM 62008
Benzene
ND
ug/L
0.50
1
11/12/16 11:15
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/12/16 11:15
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/12/16 11:15
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/12/1611:15
75-27-4
Bromofom
ND
ug/L
0.50
1
1111211611:15
75-25-2
Bromomethane
ND
ug/L
5.0
1
11112/1611:15
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/12/16 11:15
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/12/16 11:15
135-98-8
ter[-Butylbenzene
ND
ug/L
0.50
1
11/12/1611:15
98-06.6
Carbon tetrachloride
ND
ug/L
0.50
1
11/12/16 11:15
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/12/16 11:15
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/12/1611:15
75-00J
Chloroform
ND
ug/L
0.50
1
11/12/1611:15
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/12/1611:15
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/12/1611:15
9549-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/12/1611:15
106434
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/12/1611:15
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/12/1611:15
12448-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/12/1611:15
106-934
Dibromomethane
ND
ug/L
0.50
1
11/12/16 11:15
74-95-3
1,2 -Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 11:15
95-50-1
1,3 -Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 11:15
541-73-1
1,4 -Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 11:15
10646-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/12/16 11:15
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11112/1611:15
75-343
1,2-Dichloroethane
ND
ug/L
0.50
1
11/12/16 11:15
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/12/16 11:15
75-354
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/12/16 11:15
156-59-2
trans-1,2-Dichloroelhene
ND
ug/L
0.50
1
11/12/16 11:15
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/12/16 11:15
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/12/16 11:15
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/12/16 11:15
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/12/1611:15
563-5"
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/12/16 11:15
10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11/12/16 11:15
10061-02-6
Diisopropyl ether
ND
ug/L
0.50.
1
11/12/16 11:15
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/12/16 11:15
100414
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/12/1611:15
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/12/16 11:15
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/12/16 11:15
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1 -
11/12/16 11:15
1634-044
Naphthalene
ND
ug/L
2.0
1
11/12/1611:15
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/12/16 11:15
103-65-1
Styrene
ND
ug/L
0.50
1
11/12/1611:15
10042-5
1,1,1,2 -Tetrachloroethane
ND
ug/L
0.50
1
11/12/1611:15
630-20-6
1,1,2,2 -Tetrachloroethane
ND
ug/L
0.50
1
11/12/1611:15
79-345
Telrachloroethene
ND
ug/L
0.50
1
11/12/1611:15
127-184
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Dale: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 37
ceAnaVical a
nwrpKilmio as
ANALYTICAL RESULTS
Pace Ana lyticaI Seryices, LLC
2225 Riverside Dr.
Asheville, NC 28804
(628)254-7176
Project: Clement Pappas
Pace Project No.: 92319070
Sample: MW -8 Lab ID: 92319070005 Collected: 11/09/1609:45 Received: 11/09/161430 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
62008 MSV
Analytical Method: SM 6200B
Toluene
ND ug/L
0.50
1
11/12/16 11:15
108-88-3
1,2,3-Tdchlorobenzene
ND ug/L
2.0
1
11/12/16 11:15
87-61-6
1,2,4-Tdchlorobenzene
NO ug/L
2.0
1
11/12/16 11:15
120-82-1
1,1,1 -Trichloroethane
NO ug/L
0.50
1
11/12/1611:15
71-55-6
1,1,2 -Trichloroethane
ND ug/L
0.50
1
11/12/1611:15
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/12/16 11:15
79-01-0
Trichlorofluoromethane
ND ug/L
1.0
1
11/12/1611:15
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/12/16 11:15
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/12/1611:15
95-63-6
1,3,5-Trimethylbenzene
NO ug/L
0.50
1
11/12/1611:15
108-67-8
Vinyl chloride
NO ug/L
1.0
1
11/12/16 11:15
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/12/16 11:15
179601-23-1
c -Xylene
ND ug/L
0.50
1
11/12/1611:15
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
91 %
70-130
1
11/12/16 11:15
17060-07-0
4-13romofluorobenzene (S)
97 %
70-130
1
11/12/16 11:15
460-00-4
Toluene -d8 (S)
96 %
70-130
1
11/1211611:15
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
333 mg/L
25.0
1
11/11/16 14:55
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D
Fecal Coliforms
NO CFU/100 mL
4.0
4
11/09/1615:39
350.1 Ammonia
Analytical Method: EPA 350.1 1993
Rev 2.0
Nitrogen, Ammonia
NO mg/L
0.10
1
11/17/1607:45
766441-7
353.2 Nitrogen, NO2IN03 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
14.3 mg/L
0.020
1
11/10/1623:48
M6
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0.26 mg/L
0.050
1
11/11/16 23:11
7723-14-0
4600 Chloride
Analytical Method: SM 4500 -CI -E
Chloride
12.0 mg/L
1.0
1
11/17/1617:10
16887-00-6
5310B TOC
Analytical Method: SM 53108
Total Organic Carbon
9.7 mg/L
1.0
1
11/17/1612:36
744044-0
Date: 1111 M01 6 10:59 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 37
aceAnalytical
eww.Pacelebe.ove
Project: Clement Pappas
Pace Project No.: 92319070
Sample: MW -9
Parameters
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
ANALYTICAL RESULTS
Lab ID: 92319070006 Collected: 11/09/1613:20 Received: 11/09/1614:30 Matrix: Water
Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method: SM 6200B
Benzene
NO
ug/L
0.50
1
11/12/16 11:32
7143-2
Bromobenzene
NO
ug/L
0.50
1
11/12/16 11:32
108-86-1
Bromochloromethane
NO
ug/L
0.50
1
11/12/1611:32
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/12/1611:32
75-274
Bromofonn
ND
ug/L
0.50
1
11/12/16 11:32
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/12/1611:32
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/12/1611:32
10451-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/12/1611:32
135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
11/12/1611:32
98-06-6
Carbon tetrachloride
NO
ug/L
0.50
1
11/12/16 11:32
56-23-5
Chlorobenzene
NO
ug/L
0.50
1
11/12/16 11:32
108-90-7
Chloroethane
NO
ug/L
1.0
1
11/12/1611:32
75-00-3
Chloroform
NO
ug/L
0.50
1
11/12/16 11:32
67-66-3
Chloromethane
NO
ug/L
1.0
1
11/12/1611:32
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/12/1611:32
954941
4-Chlorotoluene
ND
ug/L
0.50
1
11/12/1611:32
106434
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/12/16 11:32
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/12/1611:32
12448-1
1,2-Dibromoethane(EDB)
ND
ug/L
0.50
1
11/12/1611:32
106-934
Dibromomethane
NO
ug/L
0.50
1
11/12/16 11:32
74-95-3
1,2 -Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 11:32
95-50-1
1,3 -Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 11:32
541-73-1
1,4 -Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 11:32
10646-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/12/1611:32
75-71-8 M1
1,1-Dichlorcethane
ND
ug/L
0.50
1
11/12/16 11:32
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/12/16 11:32
107-06-2
1,1-Dichloroelhene
NO
ug/L
0.50
1
11/12/1611:32
75-354
ds-1,2-Dichloroethene
ND
ug/L
0.50
1
11/12/1611:32
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/12/1611:32
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/12/16 11:32
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/12/16 11:32
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/12/16 11:32
59420-7
1,1-Dichloropropene
NO
ug/L
0.50
1
11/12/1611:32
563-58-6
cis-1,3-Dichloropropene
NO
ug/L
0.50
1
11/12/1611:32
10061-01-5
trans-1,3-Dichloropropene
NO
ug/L
0.50
1
11/12/16 11:32
10061-02-0
Diisopropyl ether
ND
ug/L
0.50
1
11/12/16 11:32
108-20-3
Ethylbenzene
NO
ug/L
0.50
1
11/12/1611:32
100414
Hexachloro-1,3-butadiene
NO
ug/L
2.0
1
11/12/1611:32
87-68-3
Isopropylbenzene (Cumene)
NO
ug/L
0.50
1
11/12/16 11:32
98-82-8
Methylene Chloride
NO
ug/L
2.0
1
11/12/1611:32
75-09-2
Methyl-tert-butyl ether
NO
ug/L
0.50
1
11/12/1611:32
1634-044
Naphthalene
NO
ug/L
2.0
1
11/12/1611:32
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/12/1611:32
103-051
Styrene
ND
ug/L
0.50
1
11/12/1611:32
10042-5
1,1,1,2 -Tetrachloroethane
ND
ug/L
0.50
1
11/12/16 11:32
630-20-6
1,1,2,2 -Tetrachloroethane
ND
ug/L
0.50
1
11/12/16 11:32
79-34-5
Tetrachloroethene
ND
ug/L
0.50
1
11/12/1611:32
127-184
REPORT OF LABORATORY ANALYSIS
This report shall not be reprotluced, except in full,
Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 37
aceAnalytical e
~..pscNeos.cwn
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: Clement Pappas
Pace Project No.: 92319070
Sample: MW -9
Lab ID: 92319070006 Collected:
11/09/1613:20
Received: 11/09/1614:30 Matrix: Water
Parameters
Results Units Report Limit
OF
Prepared Analyzed
CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Toluene
NO ug/L
0.50
1
11/12/1611:32
108-88-3
1,2,3-Trichlorobenzene
NO ug/L
2.0
1
11/12/1611:32
87616
1,2,4-Trichlorobenzene
NO ug/L
2.0
1
11/12/16 11:32
120-82-1
1,1,1 -Trichloroethane
NO ug/L
0.50
1
11/12/16 11:32
71-55-6
1,1,2 -Trichloroethane
NO ug/L
0.50
1
11/12/16 11:32
79-00-5
Trichloroethene
NO ug/L
0.50
1
11/12/16 11:32
79-016
Trichlorofluoromethane
NO ug/L
1.0
1
11/12/1611:32
7569-4
1,2,3-Trichloropropane
NO ug/L
0.50
1
11/12/16 11:32
96-184
1,2,4-Trimethylbenzene
NO ug/L
0.50
1
11/12/1611:32
9563-6
1,3,5-Trimethylbenzene
NO ug/L
0.50
1
11/12/16 11:32
108-67-8
Vinyl chloride
NO ug/L
1.0
1
11/12/1611:32
75-014
m&p-Xylene
NO ug/L
1.0
1
11/12/16 11:32
179601-23-1
o -Xylene
NO ug/L
0.50
1
11/12/1611:32
95476
Surrogates
1,2-Dichloroethane64 (S)
91 %
70-130
1
11/12/16 11:32
17060-07-0
4-Bromofluorobenzene (S)
96 %
70-130
1
11/12/1611:32
460-004
Toluene -08 (S)
102 %
70-130
1
11/12/16 11:32
2037-26-5
2640C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
69.0 mg/L
25.0
1
11/11/16 14:56
M1310 9222D Fecal Coliform AVL
Analytical Method: SM 9222D
Fecal Coliforms
NO CFU/100 mL
20.0
20
11/09/16 15:39
350.1 Ammonia
Analytical Method: EPA 350.1 1993 Rev 2.0
Nitrogen, Ammonia
NO mg/L
0.10
1
11/17/1607:50
766441-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
0.77 mg/L
0.020
1
11/11/1600:01
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0.76 mg/L
0.050
1
11/11/1623:13
7723-140
4500 Chloride
Analytical Method: SM 4500 -CI -E
Chloride
10.7 mg/L
1.0
1
11/17/1617:11
16887-006
53108 TOC
Analytical Method: SM 5310B
Total Organic Carbon
9.3 mg/L
1.0
1
11/17/1612:48
744044-0
Date: 1111812016 10:59 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 37
9PaceAnaly4ical m
wvrwpacelebscom
ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)2547176
Sample: Trip Blank Lab ID: 92319070007 Collected: 11/09/1600:00 Received: 11/09/1614:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
62008 MSV Analytical Method: SM 62006
Benzene
NO
ug/L
0.50
1
11/12/16 11:49
71-43-2
Bromobenzene
NO
ug/L
0.50
1
11/12/16 11:49
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/12/1611:49
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/12/1611:49
75-274
Bromoform
NO
ug/L
0.50
1
11/12/1611:49
75-25-2
Bromomethane
NO
ug/L
5.0
1
11/12/1611:49
74-83-9
n-Butylbenzene
NO
ug/L
0.50
1
11/12/16 11:49
104-51-8
sec-Butylbenzene
NO
ug/L
0.50
1
11/12/16 11:49
135-98-8
tert-Butyl benzene
NO
ug/L
0.50
1
11/12/1611:49
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/12/16 11:49
56-23-5
Chlorobenzene
NO
ug/L
0.50
1
11/12/16 11:49
108-90-7
Chloroethane
NO
ug/L
1.0
1
11/12/1611:49
75-00-3
Chloroform
ND
ug/L
0.50
1
11/12/16 11:49
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/12/1611:49
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/12/1611:49
9549-0
4-Chlorotoluene
ND
ug/L
0.50
1
11/12/16 11:49
106434
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/12/1611:49
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/12/1611:49
12448-1
1,2-Dibromoethane (EDB)
NO
ug/L
0.50
1
11/12/1611:49
106-934
Dibromomethane
NO
ug/L
0.50
1
11/12/1611:49
74-95-3
1,2 -Dichlorobenzene
NO
ug/L
0.50
1
11/12/16 11:49
95-50-1
1,3 -Dichlorobenzene
NO
ug/L
0.50
1
11/12/1611:49
541-73-1
1,4 -Dichlorobenzene
NO
ug/L
0.50
1
11/12/16 11:49
10646-7
Dichlorodifluoromethane
NO
ug/L
0.50
1
11/12/1611:49
75-71-8
1,1-Dichloroethane
NO
ug/L
0.50
1
11/12/1611:49
75-343
1,2-Dichloroethane
NO
ug/L
0.50
1
11/12/1611:49
107-06-2
1,1-Dichloroethene
NO
ug/L
0.50
1
11/12/1611:49
75-354
cis-1,2-Dichloroethene
NO
ug/L
0.50
1
11/12/1611:49
156-59-2
Vans-1,2-Dichloroethene
NO
ug/L
0.50
1
11/12/16 11:49
156-60-5
1,2-Dichloropropane
NO
ug/L
0.50
1
11/12/16 11:49
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/12/1611:49
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/12/16 11:49
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/12/1611:49
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/12/16 11:49
10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11/12/16 11:49
10061-02-0
Diisopropyl ether
ND
ug/L
0.50
1
11/12/16 11:49
108-20-3
Ethylbenzene
NO
ug/L
0.50
1
11/12/1611:49
100414
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/12/1611:49
87-08-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/12/16 11:49
98-82-8
Methylene Chloride
NO
ug/L
2.0
1
11/12/16 11:49
75-09-2
Methyl-tert-butyl ether
NO
ug/L
0.50
1
11/12/1611:49
1634-044
Naphthalene
NO
ug/L
2.0
1
11/12/1611:49
91-20-3
n-Propylbenzene
NO
ug/L
0.50
1
11/12/16 11:49
103-65-1
Styrene
NO
ug/L
0.50
1
11/12/1611:49
10042-5
1,1,1,2 -Tetrachloroethane
NO
ug/L
0.50
1
11/12/1611:49
630-20-6
1,1,2,2 -Tetrachloroethane
NO
ug/L
0.50
1
11/12/1611:49
79-345
Tetrachloroethene
NO
ug/L
0.50
1
11/12/1611:49
127-184
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical services, LLC. Page 17 of 37
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: Clement Pappas
Pace Project No.: 92319070
Sample: Trip Blank Lab ID: 92319070007 Collected: 11/09/16 00:00 Received: 11/09/1614:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Dual
62008 MSV Analytical Method: SM 6200B
Toluene
NO
ug/L
0.50
1
11/12/16 11:49
108-88-3
1,2,3-Trichlorobenzene
NO
ug/L
2.0
1
11/12/1611:49
87-61-6
1,2,4-Trichlorobenzene
NO
ug/L
2.0
1
11/12/16 11:49
120-82-1
1,1,1 -Trichloroethane
NO
ug/L
0.50
1
11/12/1611:49
71-55-6
1,1,2-Tdchloroethane
NO
ug/L
0.50
1
11/12/16 11:49
79-00-5
Trichloroethene
NO
ug/L
0.50
1
11/12/1611:49
79-01-6
Trichlorofluoromethane
NO
ug/L
1.0
1
11/12/1611:49
75-69-4
1,2,3-Trichloropropane
NO
ug/L
0.50
1
11/12/16 11:49
96-183
1,2,4-Trimethylbenzene
NO
ug/L
0.50
1
11/12/1611:49
95-63-6
1,3,5-Trimethylbenzene
NO
ug/L
0.50
1
11/12/1611:49
108-67-8
Vinyl chloride
NO
ug/L
1.0
1
11/12/1611:49
75-01-4
m&p-Xylene
NO
ug/L
1.0
1
11/12/16 11:49
179601-23-1
o -Xylene
NO
ug/L
0.50
1
11/12/1611:49
9537-6
Surrogates
1,2-Dichloroethane-04 (S)
90
%
70-130
1
11/12/16 11:49
17060-07-0
4-Bromofluorobenzene (S)
94
%
70-130
1
11/12/16 11:49
460-003
Toluene -d8 (S)
100
%
70-130
1
11/12/16 11:49
2037-26-5
Dale: 11/182016 10:59 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 37
aceAnalytical e
vrvm<pacelab,xc rn
QUALITY CONTROL DATA
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)2547176
QC Batch: 336667 Analysis Method: SM 62006
QC Batch Method: SM 6200B Analysis Description: 62008 MSV
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006, 92319070007
METHOD BLANK: 1866910 Matrix: Water
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006, 92319070007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1,2 -Tetrachloroethane
ug/L
ND
0.50
11/12/1609:34
1,1,1 -Trichloroethane
ug/L
NO
0.50
11/12/16 09:34
1,1,2,2 -Tetrachloroethane
ug/L
NO
0.50
11/12/16 09:34
1,1,2 -Trichloroethane
ug/L
NO
0.50
11/12/16 09:34
1,1-Dichlorcethane
ug/L
NO
0.50
11/12/1609:34
1,1-Dichloroethene
ug/L
NO
0.50
11/12/1609:34
1,1-Dichloropropene
ug/L
NO
0.50
11/12/1609:34
1,2,3-Trichlorobenzene
ug/L
NO
2.0
11/12/16 09:34
1,2,3-Trichloropropane
ug/L
NO
0.50
11/12/16 09:34
1,2,4-Trichlorobenzene
ug/L
ND
2.0
11/12/16 09:34
1,2,4-Trimethylbenzene
ug/L
ND
0.50
11/12/1609:34
1,2-Dibromo-3-chloropropane
ug/L
ND
1.0
11/12/1609:34
1,2-Dibromoethane(EDB)
ug/L
ND
0.50
11/12/1609:34
1,2 -Dichlorobenzene
ug/L
NO
0.50
11/12/16 09:34
1,2-Dichloroethane
ug/L
NO
0.50
11/12/1609:34
1,2-Dichloropropane
ug/L
NO
0.50
11/12/1609:34
1,3,5-Trimethylbenzene
ug/L
NO
0.50
11/12/16 09:34
1,3 -Dichlorobenzene
ug/L
NO
0.50
11/12/1609:34
1,3-Dichloropropane
ug/L
NO
0.50
11/12/16 09:34
1,4 -Dichlorobenzene
ug/L
NO
0.50
11/12/16 09:34
2,2-Dichloropropane
ug/L
NO
0.50
11/12/1609:34
2-Chlorotoluene
ug/L
NO
0.50
11/12/1609:34
4-Chlorotoluene
ug/L
NO
0.50
11/12/1609:34
Benzene
ug/L
NO
0.50
11/12/1609:34
Bromobenzene
ug/L
ND
0.50
11/12/16 09:34
Bromochloromethane
ug/L
ND
0.50
11/12/1609:34
Bromodichloromethane
ug/L
NO
0.50
11/12/1609:34
Bromoform
ug/L
NO
0.50
11/12/1609:34
Bromomethane
ug/L
NO
5.0
11/12/1609:34
Carbon tetrachloride
ug/L
NO
0.50
11/12/16 09:34
Chlombenzene
ug/L
ND
0.50
11/12/1609:34
Chloroethane
ug/L
NO
1.0
11/12/1609:34
Chloroform
ug/L
NO
0.50
11/12/1609:34
Chloromethane
ug/L
ND
1.0
11/12/1609:34
cis-1,2-Dichlorcethene
ug/L
ND
0.50
11/12/16 09:34
cis-1,3-Dichloropropene
ug/L
NO
0.50
11/12/16 09:34
Dibromochloromelhane
ug/L
NO
0.50
11/12/1609:34
Dibromomethane
ug/L
NO
0.50
11/12/1609:34
Dichlorodifluoromethane
ug/L
NO
0.50
11/12/1609:34
Diisopropyl ether
ug/L
NO
0.50
11/12/16 09:34
Ethylbenzene
ug/L
NO
0.50
11/12/1609:34
Results presented on MIs page are in the units indicated by the "Unita" column except v.Tere an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical services, LLC. Page 19 of 37
aceAnalyticale
aww.pecNabsarn
QUALITY CONTROL DATA
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
METHOD BLANK: 1866910 Matrix: Water
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006, 92319070007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Hexachloro-1,3-butadiene
ug/L
NO
2.0
11/12/1609:34
Isopropylbenzene(Cumene)
ug/L
ND
0.50
11/12/1609:34
m&p-Xylene
ug/L
NO
1.0
11/12/1609:34
Methyl-tert-butyl ether
ug/L
NO
0.50
11/12/1609:34
Methylene Chloride
ug/L
NO
2.0
11/12/1609:34
n-Butylbenzene
ug/L
NO
0.50
11/12/16 09:34
n-Propylbenzene
ug/L
NO
0.50
11/12/1609:34
Naphthalene
ug/L
ND
2.0
11/12/1609:34
o -Xylene
ug/L
ND
0.50
11/12/1609:34
sec-Butylbenzene
ug/L
NO
0.50
11/12/1609:34
Styrene
ug/L
NO
0.50
11/12/1609:34
tert-Butylbenzene
ug/L
NO
0.50
11/12/1609:34
Tetrachloroethene
ug/L
NO
0.50
11/12/1609:34
Toluene
ug/L
ND
0.50
11/12/16 09:34
trans-1,2-Dichloroethene
ug/L
ND
0.50
11/12/1609:34
trans-1,3-Dichloropropene
ug/L
ND
0.50
11/12/1609:34
Trichloroethene
ug/L
NO
0.50
11/12/1609:34
Trichlorofluoromethane
ug/L
NO
1.0
11/12/1609:34
Vinyl chloride
ug/L
NO
1.0
11/12/16 09:34
1,2-Dichloroethane-d4 (S)
%
89
70-130
11/12/16 09:34
4-Bromofluorobenzene (S)
%
96
70-130
11/12/16 09:34
Toluene-d8(S)
%
99
70-130
11/12/16 09:34
LABORATORY CONTROL SAMPLE:
Parameter
1866911
Units
Spike
Conc.
LCS
Result
LCS
%Rec
% Rec
Limits Qualifem
1,1,1,2 -Tetrachloroethane
ug/L
50
47.8
96
60-140
1,1,1 -Trichloroethane
ug/L
50
46.5
93
60-140
1,1,2,2 -Tetrachloroethane
ug/L
50
46.0
92
60-140
1,1,2 -Trichloroethane
ug/L
50
44.5
89
60-140
1,1-Dichloroethane
ug/L
50
47.2
94
60-140
1,1-Dichloroethene
ug/L
50
53.4
107
60-140
1,1-Dichloropropene
ug/L
50
47.5
95
60-140
1,2,3-Trichlorobenzene
ug/L
50
56.4
113
60-140
1,2,3-Trichloropropane
ug/L
50
43.3
87
60-140
1,2,4-Trichlorobenzene
ug/L
50
54.1
108
60-140
1,2,4-Trimethylbenzene
ug/L
50
49.4
99
60-140
1,2-Dibromo-3-chloropropane
ug/L
50
45.4
91
60-140
1,2-Dibromoethane(EDB)
ug/L
50
47.3
95
60-140
1,2 -Dichlorobenzene
ug/L
50
51.2
102
60-140
1,2-Dichloroethane
ug/L
50
40.1
80
60-140
1,2-Dichloropropane
ug/L
50
45.5
91
60-140
1,3,5-Trimethylbenzene
ug/L
50
48.5
97
60-140
1,3 -Dichlorobenzene
ug/L
50
49.7
99
60-140
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/182016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 37
ace Analytical
xxw.Gareko>cam
QUALITY CONTROL DATA
Project: Clement Pappas
Pace Project No.: 92319070
LABORATORY CONTROL SAMPLE:
Parameter
1866911
Units
Spike
Conc.
LCS
Result
-CS
%Rec
% Rec
Limits
1,3-Dichloropropane
ug/L
50
44.8
90
60-140
1,4 -Dichlorobenzene
ug/1-
50
48.1
96
60-140
2,2-Dichloropropane
ug/L
50
38.3
77
60-140
2-Chlorotoluene
ug/L
50
47.2
94
60-140
4-Chlorotoluene
ug/L
50
46.6
93
60-140
Benzene
ug/L
50
49.5
99
60-140
Bromobenzene
ug/L
50
46.8
94
60-140
Bromochloromethane
ug/L
50
46.7
93
60-140
Bromodichloromethane
ug/L
50
46.6
93
60-140
Bromoform
ug/L
50
45.5
91
60-140
Bromomethane
ug/L
50
40.0
80
60-140
Carbon tetrachloride
ug/L
50
49.5
99
60-140
Chlorobenzene
ug/L
50
46.4
93
60-140
Chloroethane
ug/L
50
45.4
91
60-140
Chloroform
ug/L
50
44.9
90
60-140
Chloromethane
ug/L
50
52.2
104
60-140
cis-1,2-Dichloroelhene
ug/L
50
46.4
93
60-140
cis-1,3-Dichloropropene
ug/L
50
44.2
88
60-140
Dibromochloromethane
ug/L
50
47.9
96
60-140
Dibromomethane
ug/L
50
44.9
90
60-140
Dichlorodifluoromethane
ug/L
50
53.1
106
60-140
Diisopropyl ether
ug/L
50
50.9
102
60-140
Ethylbenzene
ug/L
50
48.2
96
60-140
Hexachloro-1,3-butadiene
ug/L
50
51.2
102
60-140
Isopropylbenzene (Cumene)
ug/L
50
48.9
98
60-140
m&p-Xylene
ug/L
100
95.6
96
60-140
Methyl-tert-butyl ether
ug/L
50
48.6
97
60-140
Methylene Chloride
ug/L
50
53.3
107
60-140
n-Butylbenzene
ug/L
50
50.0
100
60-140
n-Propylbenzene
ug/L
50
48.9
98
60-140
Naphthalene
ug/L
50
53.0
106
60-140
o -Xylene
ug/L
50
46.9
94
60-140
sec-Butylbenzene
ug/L
50
50.6
101
60-140
Styrene
ug/L
50
48.4
97
60-140
tert-Butylbenzene
ug/L
50
43.0
86
60-140
Tetrachloroethene
ug/L
50
41.2
82
60-140
Toluene
ug/L
50
45.7
91
60-140
trans-1,2-Dichloroethene
ug/L
50
50.2
100
60-140
trans-1,3-Dichloropropene
ug/L
50
43.2
86
60-140
Trichloroethene
ug/L
50
46.3
93
60-140
Trichlorofluoromethane
ug/L
50
48.0
96
60-140
Vinyl chloride
ug/L
50
45.7
91
60-140
1,2-Dichloroelhane-d4 (S)
%
89
70-130
4-Bromotluorobenzene (S)
%
98
70-130
Toluene-d8(S)
%
96
70-130
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)2547776
Qualifiers
Results presented on this page are in the units indicated by the "Units' column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 37
aceAnalytical
.pacelabsxom
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
QUALITY CONTROL DATA
Project: Clement Pappas
Pace Project No.: 92319070
LriBIV:69VISX:IIGU:te69VIS21.1r194NLI94fe1-11*iP,
Parameter
92319070006
Units Result
1,1,1,2 -Tetrachloroethane
ug/L
NO
1,1,1 -Trichloroethane
ug/L
NO
1,1,2,2 -Tetrachloroethane
ug/L
NO
1,1,2 -Trichloroethane
ug/L
NO
1,1-Dichloroethane
ug/L
NO
1,1-Dichloroethene
ug/L
NO
1,1-Dichloropropene
ug/L
NO
1,2,3-Trichlorobenzene
ug/L
NO
1,2,3-Trichloropropane
ug/L
NO
1,2,4-Trichlorobenzene
ug/L
NO
1,2,4-Trimethylbenzene
ug/L
NO
1,2-Dibromo-3-chloropropane
ug/L
NO
1,2-Dibromoethane(EDB)
ug/L
NO
1,2 -Dichlorobenzene
ug/L
NO
1,2-Dichloroethane
ug/L
NO
1,2-Dichloropropane
ug/L
NO
1,3,5-Trimethylbenzene
ug/L
NO
1,3 -Dichlorobenzene
ug/L
NO
1,3-Dichloropropane
ug/L
NO
1,4 -Dichlorobenzene
ug/L
NO
2,2-Dichloropropane
ug/L
NO
2-Chlorotoluene
ug/L
NO
4-Chlorotoluene
ug/L
NO
Benzene
ug/L
NO
Bromobenzene
ug/L
NO
Bromochloromethane
ug/L
NO
Bromodichloromethane
ug/L
NO
Bromoform
ug/L
NO
Bromomethane
ug/L
NO
Carbon tetrachloride
ug/L
NO
Chlorobenzene
ug/L
NO
Chloroethane
ug/L
NO
Chloroform
ug/L
NO
Chloromethane
ug/L
NO
cis-1,2-Dichloroethene
ug/L
NO
cis-1,3-Dichloropropene
ug/L
NO
Dibromochloromethane
ug/L
NO
Dibromomethane
ug/L
NO
Dichlorodifluoromethane
ug/L
NO
Diisopropyl ether
ug/L
NO
Ethylbenzene
ug/L
NO
Hexachloro-1,3-butadiene
ug/L
NO
Isopropylbenzene (Cumene)
ug/L
NO
m&p-Xylene
ug/L
NO
Methyl-tert-butyl ether
ug/L
NO
Methylene Chloride
ug/L
NO
11I1-1*1111
MS
Spike
Conc.
MSD
Spike
Conc.
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Thal
20
20
20.2
19.9
101
100
60-140
1
20
20
19.9
19.7
99
98
60-140
1
20
20
19.5
19.6
98
98
60-140
0
20
20
19.6
19.3
98
97
60-140
1
20
20
20.0
19.9
100
100
60-140
0
20
20
21.4
21.8
107
109
60-140
2
20
20
20.2
20.7
101
103
60-140
2
20
20
21.8
20.8
109
104
60-140
5
20
20
18.6
18.1
93
90
60-140
3
20
20
20.9
20.4
104
102
60-140
2
20
20
20.5
20.8
103
104
60-140
1
20
20
18.7
18.7
94
94
60-140
0
20
20
19.9
19.3
100
97
60-140
3
20
20
21.1
21.2
105
106
60-140
1
20
20
17.0
17.1
84
85
60-140
0
20
20
19.6
19.5
98
98
60-140
0
20
20
20.7
20.7
104
104
60-140
0
20
20
20.6
20.7
103
103
60-140
0
20
20
19.0
18.9
95
95
60-140
0
20
20
20.0
20.0
100
100
60-140
0
20
20
16.2
15.8
81
79
60-140
2
20
20
20.5
20.7
103
104
60-140
1
20
20
19.8
20.0
99
100
60-140
1
20
20
20.8
20.7
104
103
60-140
1
20
20
20.2
20.1
101
100
60-140
0
20
20
19.9
20.1
100
101
60-140
1
20
20
20.0
19.7
100
98
60-140
1
20
20
18.5
18.0
93
90
60-140
3
20
20
15.8
14.8
79
74
60-140
6
20
20
21.2
21.5
106
107
60-140
1
20
20
19.8
19.7
99
98
60-140
1
20
20
15.8
16.5
79
82
60-140
4
20
20
19.4
19.3
97
97
60-140
0
20
20
14.3
13.7
71
69
60-140
4
20
20
19.6
19.8
98
99
60-140
1
20
20
18.5
18.7
93
94
60-140
1
20
20
20.1
19.6
100
98
60-140
2
20
20
18.9
19.1
95
96
60-140
1
20
20
8.3
7.9
41
40
60-140
5 M1
20
20
21.2
21.3
106
107
60-140
0
20
20
20.8
20.6
104
103
60-140
1
20
20
19.6
18.7
98
94
60-140
4
20
20
21.1
20.9
105
104
60-140
1
40
40
41.1
40.8
103
102
60-140
1
20
20
19.8
19.9
99
99
60-140
0
20
20
20.5
20.7
103
104
60-140
1
Results presented on this page are In the units Indicated by the "Units" column except where an aitemate ung is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/18/2016 10:59 AM without the wrihen consent of Pace Analytical Services, LLC. Page 22 of 37
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: Clement Pappas
Pace Project No.: 92319070
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
1866912
1866913
MS
MSD
92319070006
Spike
Spike
MS
MSD
MS
MSD
%Rec
Parameter
Units
Result
Conic.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
n-Butylbenzene
ug/L
ND
20
20
20.1
19.8
101
99
60-140
2
n-Propylbenzene
ug/L
ND
20
20
21.1
21.3
106
106
60-140
1
Naphthalene
ug/L
ND
20
20
21.2
20.5
106
103
60-140
3
o -Xylene
ug/L
ND
20
20
20.0
20.2
100
101
60-140
1
sec-Butylbenzene
ug/L
ND
20
20
20.9
20.8
104
104
60-140
0
Styrene
ug/L
ND
20
20
20.2
20.0
101
100
60-140
1
tert-Butylbenzene
ug/L
ND
20
20
18.5
18.2
92
91
60-140
1
Tetrachloroethene
ug/L
ND
20
20
17.3
17.4
86
87
60-140
1
Toluene
ug/L
ND
20
20
20.0
20.0
100
100
60-140
0
Vans-1,2-Dichloroethene
ug/L
ND
20
20
21.1
20.8
106
104
60-140
2
trans-1,3-Dichloropropene
ug/L
ND
20
20
18.3
17.8
92
89
60-140
3
Trichloroethene
ug/L
ND
20
20
19.6
19.8
98
99
60-140
1
Trichlorofluoromethane
ug/L
ND
20
20
19.0
19.4
95
97
60-140
2
Vinyl chloride
ug/L
ND
20
20
13.8
13.8
69
69
60-140
0
1,2-Dichloroethane-d4 (S)
%
91
91
70-130
4-Bromofluorobenzene (S)
%
101
99
70-130
Toluene-d8(S)
%
99
100
70-130
Results presented on this page are in the units Indicated by the "Units" column except v.Tere an ahemate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 1111812016 1 0:59 AM without the written consent of Pace Analytical Services, LLC. Page 23 of 37
lCeAnalyticale
axsepxeN6s xwar
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)2547176
Project: Clement Pappas
Pace Project No.: 92319070
QC Batch: 336499
Analysis Method: SM 2540C
QC Batch Method: SM 2540C
Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
METHOD BLANK: 1865998
Matrix: Water -
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers
Total Dissolved Solids
mg/L
ND 25.0 11/11/1614:32
LABORATORY CONTROL SAMPLE:
1865999
Spike LCS LCS % Rec
Parameter
Units
Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids
mg/L
250 264 106 90-110
SAMPLE DUPLICATE: 1866000
92318780051 Dup
Parameter
Units
Result Result RPD Qualifiers
Total Dissolved Solids
mg/L
183 191 4
SAMPLE DUPLICATE: 1866001
92319148004 Dup
Parameter
Units
Result Result RPD Qualifiers
Total Dissolved Solids
mg/L
1950 1460 29 D6
Results presented on this page are in the units Indicated by Me "Units' column except where an alternate unit is presentetl to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Page 24 of 37
aceAnalXical e
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QUALITY CONTROL DATA
Project: Clement Pappas
Pace Project No.: 92319070
QC Batch: 336424 Analysis Method: SM 9222D
QC Batch Method: SM 9222D Analysis Description: 9222D MBIO Fecal Coliform -AVL
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
METHOD BLANK: 1865520 Matrix: Water
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms CFU/100 mL NO 1.0 11/09/16 15:39
SAMPLE DUPLICATE: 1865521
92319070005 Dup
Parameter Units Result Result RPD Qualifiers
Fecal Coliforms CFU/100 mL NO NO
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Results presented on this page are in the units indicated by the"Units"column except vne an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/18/201610:59AM without the written consent of Pace Analytical Services,LLC.
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-PaceAnalytical®
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QUALITY CONTROL DATA
Project: Clement Pappas
Pace Project No.: 92319070
QC Batch: 337277 Analysis Method: EPA 350.1 1993 Rev 2.0
QC Batch Method: EPA 350.1 1993 Rev 2.0 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
METHOD BLANK: 1870478 Matrix: Water
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mglL ND 0.10 1111711607:32
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7178
LABORATORY CONTROL SAMPLE: 1870479
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 4.9 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1870480
1870481
MS
MSD
MSD
92319652001 Spike
Spike
MS
MSD MS MSD
°% Rec
Parameter Units Result Conc.
Conc.
Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Ammonia mg/L. NO 5
5
5.2
5.2 103 104
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1870482
1870483
MS
MSD
92318818002 Spike
Spike
MS
MSD
MS MSD
% Rec
Parameter Units Result Conc.
Conc,
Result
Result
% Rec % Rec
Limits RPD Qual
Nitrogen, Ammonia mg/L 13.1 5
5
19.7
19.2
132 121
90-110 3 M1
Results presented on this page are in the units indicated by Me "Unita" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/18/201610:59 AM without the written consent of Pace Analytical Services,LLC.
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aceAnalytical e
wwxpatelabsmm
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr
Asheville, NC 28804
(828)254-7176
Project: Clement Pappas
Pace Project No.: 92319070
QC Batch: 336471
Analysis Method: EPA 353.2
OC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92319070001,92319070002,92319070003,92319070004,92319070005,92319070006
METHOD BLANK: 1865760
Matrix: Water
Associated Lab Samples: 92319070001, 92319070002,
92319070003, 92319070004, 92319070005, 92319070006
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers;
Nitrogen, Nitrate mg/L
ND 0.020 11/10/1623:45
LABORATORY CONTROL SAMPLE: 1865761
Spike LCS LCS %Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5 2.6 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1865762 1865763
MS MSD
92319070005
Spike Spike MS MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 14.3
2.5 2.5 17.3 17.5 120 126 90-110 1 M6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1866056 1866057
MS MSD
92319338008 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L ND 2.5 2.5 2.3 2.3 91 91 90-110 1
Results presented on this page are in the units Indicated by Me 'Units" column except where an altemate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/201610:59AM without the written consent of Pace Analytical Services, 1-1-0.
Page 27 of 37
ceAnalXical`
tywx:paa�6xarortt
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: Clement Pappas
Pace Project No.: 92319070
QC Batch: 336486 Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004
METHOD BLANK: 1865898 Matrix: Water
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 11/11/16 22:46
LABORATORY CONTROL SAMPLE: 1865899
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.5 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1865900 1865901
MS MSD
92318583001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conic. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 20.6 2.5 2.5 24.5 23.9 155 132 90-110 2 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1865902
1865903
MS
MSD
92318901001 Spike
Spike
MS
MSD MS MSD
% Rec
Parameter Units Result Conc.
Conc.
Result
Result %Rec %Rec
Limits RPD Qual
Phosphorus mg/L 0.72 2.5
2.5
3.3
3.3 103 103
90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/201610:59 AM without the written consent of Pace Analytical Services, LLC.
Page 28 of 37
('!IaceAnalyticalo
wmvpacelabs.wm
QUALITY CONTROL DATA
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7178
Project: Clement Pappas
Pace Project No.: 92319070
QC Balch: 336488 Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 92319070005, 92319070006
METHOD BLANK: 1865913 Matrix: Water
Associated Lab Samples: 92319070005, 92319070006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 11/11/1623:09
LABORATORY CONTROL SAMPLE: 1865914
Spike LCS LCS % Rec
Parameter Units Cone. Result %Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.5 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1865915 1865916
MS MSD
92319070005 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.26 2.5 2.5 2.8 2.8 103 103 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1865917 1865918
MS MSD
92319199003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Phosphorus ni 1.8 2.5 2.5 4.3 4.4 103 103 90-110 0
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Page 29 of 37
PaceAnalytical
~..pealabs con
QUALITY CONTROL DATA
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: Clement Pappas
Pace Project No.: 92319070
QC Batch: 337161 _
Analysis Method: SM 4500 -CI -E
QC Batch Method: SM 4500 -CI -E
Analysis Description: 4500 Chloride
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
METHOD BLANK: 1869588
Matrix: Water
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Chloride mg/L
NO 1.0 11/17/1616:59
LABORATORY CONTROL SAMPLE: 1869589
Spike LCS LCS - % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Chloride mg/L
20 20.9 104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869590 1869591
MS MSD
92319070001
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits RPD Qual
Chloride mg/L 12.2
10 10 22.9 22.9 107 107
90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869592 1869593
MS MSD
92318783003
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits RPD Qual
Chloride mg/L 1.1
10 10 12.3 12.3 112 112
90-110 0 Mt
Resulls presented on this page are In the units Indicated by the "Units" column except where an altemate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/18/201610:59 AM without the written consent of Pace Analytical Services,LLC.
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0
aceAnalytical
~pecelneacom
QUALITY CONTROL DATA
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)2547176
Project: Clement Pappas
Pace Project No.: 92319070
QC Batch: 337165 Analysis Method: SM 53108
QC Batch Method: SM 53108 Analysis Description: 531OB TOC
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
METHOD BLANK: 1869646 Matrix: Water
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L. NO 1.0 11/17/1610:29
LABORATORY CONTROL SAMPLE: 1869647
Spike LCS LCS % Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Organic Carbon mg/L 25 23.1 92 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869648 1869649
MS MSD
92319070001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result e/ Rec % Rec Limits RPD Qual
Total Organic Carbon mg/1- 4.3 25 25 27.3 27.6 92 93 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869650 1869651
MS MSD
92319496009 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 0.56J 25 25 24.7 24.7 96 96 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an altemate unit Is presented to the lght or the result.
REPORT OF LABORATORY ANALYSIS
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ceAnalytical"
wsw.P�scnrr
QUALIFIERS
Project: Clement Pappas
Pace Project No.: 92319070
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL- Practical Quantitation Limit.
RL - Reporting Limit.
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unfounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chlomethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nilrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
REPORT OF LABORATORY ANALYSIS
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PaceAnalytical
.pacelahxcvn
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7178
Project:
Pace Project No.:
Clement Pappas
92319070
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method
Batch
92319070001
MW -4
SM 6200B
336667
92319070002
MW -5
SM 62006
336667
92319070003
MW -6
SM 62006
336667
92319070004
MW -7R
SM 62008
336667
92319070005
MW -8
SM 6200B
336667
92319070006
MW -9
SM 6200B
336667
92319070007
Trip Blank
SM 6200B
336667
92319070001
MW -4
SM 2540C
336499
92319070002
MW -5
SM 2540C
336499
92319070003
MW -6
SM 2540C
336499
92319070004
MW -7R
SM 2540C
336499
92319070005
MW -8
SM 2540C
336499
92319070006
MW -9
SM 2540C
336499
92319070001
MW -4
SM 9222D
336424
92319070002
MW -5
SM 9222D
336424
92319070003
MW -6
SM 9222D
336424
92319070004
MW -7R
SM 9222D
336424
92319070005
MW -8
SM 9222D
336424
92319070006
MW -9
SM 9222D
336424
92319070001
MW -4
EPA 350.1 1993 Rev 2.0
337277
92319070002
MW -5
EPA 350.1 1993 Rev 2.0
337277
92319070003
MW -6
EPA 350.11993 Rev 2.0
337277
92319070004
MW -7R
EPA 350.11993 Rev 2.0
337277
92319070005
MW -8
EPA 350.1 1993 Rev 2.0
337277
92319070006
MW -9
EPA 350.1 1993 Rev 2.0
337277
92319070001
MW -4
EPA 353.2
336471
92319070002
MW -5
EPA 353.2
336471
92319070003
MW -6
EPA 353.2
336471
92319070004
MW -7R
EPA 353.2
336471
92319070005
MW -8
EPA 353.2
336471
92319070006
MW -9
EPA 353.2
336471
92319070001
MW -4
EPA 365.1
336486
92319070002
MW -5
EPA 365.1
336486
92319070003
MW -6
EPA 365.1
336486
92319070004
MW -7R
EPA 365.1
336486
92319070005
MW -8
EPA 365.1
336488
92319070006
MW -9
EPA 365.1
336488
92319070001
MW -4
SM 4500 -CI -E
337161
92319070002
MW -5
SM 4500 -CI -E
337161
92319070003
MW -6
SM 4500 -CI -E
337161
92319070004
MW -7R
SM 4500 -CI -E
337161
92319070005
MW -8
SM 4500 -CI -E
337161
92319070006
MW -9
SM 4500 -CI -E
337161
92319070001
MW -4
SM 53108
337165
92319070002
MW -5
SM 5310B
337165
REPORT OF LABORATORY ANALYSIS
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Page 33 of 37
/ AceAnalytical e
.pacelabizcom
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7178
Project:
Pace Project No.:
Clement Pappas
92319070
Analytical
Lab ID
Sample ID
QC
Batch Method
QC Batch Analytical Method Batch
92319070003
MW -6
SM
53108
337165
92319070004
MW -7R
SM
5310B
337165
92319070005
MW -8
SM
5310B
337165
92319070006
MW -9
SM
53108
337165
REPORT OF LABORATORY ANALYSIS
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Laboratory receivingsa les:
Asheville Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑
ClientNa
Projec
i
Courier: ❑Fed Ex ❑UPS ❑USPS tient
❑ Commercial ❑Pace ❑Other:_
Custody Seal Present? ❑Yes 0 No Seals Intact? ❑Yes ❑No
Packing Material-, []Bubble Wrap [I B.06le Bags ❑None ❑Other:_
Thermometer•
IR Oun ID: Type? Ice: Wet ❑Blue
Correction Factor: 0 C oler Temp Corrected ('C): 0
Temp should be above fre ng to 6'C
USDA Regulated Soil ( N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)?
mv.. nN,.
WO# 92319070
11111111111111111
92319010
Date/Initials Person Examining
❑None ❑Samples on ice, cooling processhas be n
Biological Tissue Frozen? Dyes [-]No - /A
Did samples originate from a foreign source (inter nally,
Including Hawag and Puerto Rico)? ❑Yes No
Document Name:
Document Revised: Sept. 21, 2016
aceAnalytical`
Sample Condition Upon Recei t(SCUR)
Page 1 of 2
I
Document No.:
Issuing Authority:
❑N/A
F-CAR-CS-033-Rev.01
Pace Quality Office
Laboratory receivingsa les:
Asheville Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑
ClientNa
Projec
i
Courier: ❑Fed Ex ❑UPS ❑USPS tient
❑ Commercial ❑Pace ❑Other:_
Custody Seal Present? ❑Yes 0 No Seals Intact? ❑Yes ❑No
Packing Material-, []Bubble Wrap [I B.06le Bags ❑None ❑Other:_
Thermometer•
IR Oun ID: Type? Ice: Wet ❑Blue
Correction Factor: 0 C oler Temp Corrected ('C): 0
Temp should be above fre ng to 6'C
USDA Regulated Soil ( N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)?
mv.. nN,.
WO# 92319070
11111111111111111
92319010
Date/Initials Person Examining
❑None ❑Samples on ice, cooling processhas be n
Biological Tissue Frozen? Dyes [-]No - /A
Did samples originate from a foreign source (inter nally,
Including Hawag and Puerto Rico)? ❑Yes No
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Sample
Discrepancy:
Project Manager SCURF Review:
Project Manager SRF Review:
Field Data Required? ❑Yes /M No
Date/Time:
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, Incorrect containers)
Page 35 of 37
Comments/Discrepan :
Chain of Custody Present?
RfYe,
No
❑N/A
1.
Samples Arrived within Hold Time?
Ye,
ONO
❑N/A
2.
Short Hold Time Analysis (472 hr.)?
es
ONO
,❑N/A
3.A(Cl-
RushTurnAroundTlmeRequested?
❑Yes
o
❑N/A
4.
Sufficient Volume?04'
ONO
N/A
S.
Correct Containers Used?
-Pace Containers Used?
Ye y
Yes
ONO
ONO
❑N/A
N/A
6.
Containers intact?
QKes
ONO
❑ ltA
7.
Samples Field Filtered?
❑Yes
No
N/A
B. Note if sediment is visible In the dissolved container
Sample Labels Match COC?
-includes Date/Time/10/Analysis Matrix:
03fes
[IN.
❑N/A
9.
Heads ace in VOA Vials (>5-6mm)?
❑Yes
No
❑N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
Yes
ONO
[IN.
❑N/A
❑N/A
11.
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Sample
Discrepancy:
Project Manager SCURF Review:
Project Manager SRF Review:
Field Data Required? ❑Yes /M No
Date/Time:
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, Incorrect containers)
Page 35 of 37
*Check mark top half of box if pH and/or dechlorination
is verified and within the acceptance range for
preservation samples.
*"Bottom half of box is to list number of bottles
Projec1 l0#
:92319070
PWM: Lip Due Dale: 11/23/16
CLIENT: 83—ALTAMONT
Document Name:
Document Revised: Sept. 21, 2016
o
aceAnalytical
Sample Condition Up on Recei tjSCUR
Pae 2 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.01
Pace Qualit Office
*Check mark top half of box if pH and/or dechlorination
is verified and within the acceptance range for
preservation samples.
*"Bottom half of box is to list number of bottles
Projec1 l0#
:92319070
PWM: Lip Due Dale: 11/23/16
CLIENT: 83—ALTAMONT
pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot e
R
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2
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot e
Page 36 of 37
p CHAIN -OF -CUSTODY I Analytical Request Document
FaeeAnalytreal The Chai rof-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
•Ingvnant I av, siviv, nuv rpm I ac armgng Pxs:s NET 3001111-1, M aprt¢ng to I.., r i.. .., N 1 5%1--Ih ban, Oraxus rut Paid -don 30 don. F-ALL-0-Uzurevw. 1 S -May -LW
/ �
of Mmon
Section A
Section B
SectionG
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Requirad Gent Information: Required Protect Infarnation: Invoice Infarnlelion:
Dan P�y:A�+Q
Report To. r3 ; �jG1/J
Attention
G/I
2036974
Address:
Copy To:
ry'13�;G'✓1
Cier at Name;
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REGULATORY AGENCY
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NPDES GROUNDWATER
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ac`0"nI^
Email To: GAf ry �V rh ,P(!chase Order No.:
Phone' - "'o
Propd Name: C'I '> A
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Site LOCATED
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Requastad Due OaNrtAT: S'� _ /p/- Project Number � ' G � Pxc Pralno u.
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Requested Analysis Filtered (YIN)
Section O
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ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION
DATE
TIME
ACCEPTED BY I AFFIU.031M
DATE
TIME
SAMPLE CONDITIONS
ORIGINAL
SAMPLER NAME AND SIGNATURE
ti
`oz a =_
PRINT Name of SAMPLER:
I X
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SIGNATURE of SAMPLER:
GATE Sfenal
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•Ingvnant I av, siviv, nuv rpm I ac armgng Pxs:s NET 3001111-1, M aprt¢ng to I.., r i.. .., N 1 5%1--Ih ban, Oraxus rut Paid -don 30 don. F-ALL-0-Uzurevw. 1 S -May -LW
WWW.ALTA MOMTCMV rOOM MC MTAL.0 ON
Well Sampling Log
PROJECT NAVE: / _'rt t•{
W 0 " .Ty DATE: ( I Iqlj6_-
PROJECT NUMBER: ' GI r
WEATHER: $ds
SAMPLING PERSONNEL JLiKugw-
SAMPLETIME
WELL NUMBER: Mi���t-++
WELL DEPTH IN FEET (WD):
_
WELL DIAMETER:
WATER LEVEL IN FEET (WU:
TYPE OF CASING: VC
LENGTH OF WATER COLLMN N7 FEE -
MEASURING POIN
(WD) -(WL) - (LWC)
FLUSH MOUNT/ TICK -U
ONE CASING VOLUME: i. $ d? RJ $
GALLONS
COMMENTS:
(LWC) z (WCV)
THREE CASING VOLUMES: L.J, S7YT GALLONS
ACTUAL VOLU M E PURGED: �I �'7S^ GALLONS
WELL CASING VOLUMES (WCV)
i-0.041Ga t 2--0 (3al/Ft
3'-0.3SG8VFt &--0.66GaVF: 6"-1.50sVFt 8 -2.6 GO /Ft
11 -58 Gal/Ft
PURaE METHOD: LER-DI BAILER -TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER:
_
SAMPLE METHOC. PPAILERWSP. BAILER -TEFLON DEDICATED PUMP WHALEPUMP GRUNDFCS OTHER:
READING
TIME
bAtfONS
TEMP
SPECIFIC
DISSOLVED pH
OXIDATION
TURBIDITY
COMMENTS
PURGED
(°C)
COND.
OXYGEN IS.U.)
REDUCTION
(NTU)
(PS/cm)
(mvL) report to
POTENTIAL
0.1 S.U.
(mV)
li29
f�
Ii+
I TJ
9
3t 31, 7G
,GJ
2
i7.5-
IGI,SS
I
ff
Z
19 -'z.
Y{
a
7
'v
?.e-Iz 5,75-
`(
IIZJ
5
6
T
8
9
LO
SAMPLING CCN-AINER
NUMBER OF CONTAINERS REQUESTED ANALYSIS
500 mL PLASTIC
250 mL PLASTIC
125 mL PLASTIC
40 mL GLASS
1 L GLASS
OTHER
PROTECTIVE CASING: • PAD. 61;"
LOCK: I%. VEGETATI0fC- ACCESS:
Sampling Personnel Signature:
r
'�, _ - Date:
Notes: 'C - degrees Celsus
µ5/cm - rlc,o5iernen per centimeter
mg/L - mil igrams per lite
S.U. - Stehdarc Units
MV - mIII0N
NTU = nephelometric wrla dity, snits
Samples ere enahzei immediately upon collection.
.'sTamplatustGW Drilling Forms"Nell sampling Log_wh Page i of I
yG M; Its
F.1 OPV410161 LIN a
r�
ww x.n L'rw xu Nic-VI NPM M e nT A L.
Well Samplings Log
PROJECT NAM E: r f i- :qt
PROJECT NUMBER: (j (WEATHER:
SAMPLING PERSONNEL:
n;tul'rV,. DATE:
V s /
W LETIME: 1) 1 S
WELL NUMBER: /t,? fn, _ r1"
WELL DIAMETER: Q•t
TYPE OF CASING: P(JC
MEASURING POINT: T Q
FLUSH MOUNT/ TICK
COMMENTS:
WELL DEPTH IN FEET (WD): ;6,60_
WATER LEVEL . N FEET ML):_l '. Z S-
LENGTH OF WATER COLUMN : '7.35"
(WD)-(WL)-(1NC) _
ONE CASING VOLUME: �- S
(LWC) x (WCV)
THREE CASING VOLUMES: 3,75-
ACTUAL VOLUME PURGED: -fZ-Mr 3.7 g"
FEET
GALLONS
GALLONS
GALLONS
1'-0,041 GaVF 7-O. 7Gal/Ft
WELL CASING VOLUMES (DCV)
3-0.390AVPt 4 -O.66 GeVFt 6'-1.5 Gal/Ft 8 -2.6 Gal Ft
17'=5.83aVIFt
PURGE METHOD: ILER-DISP. BAILER -TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER:
SAMPLE METHOD: SZ&ILER- BAILER -TEFLON DEDICATEDPUMP 'W'HALEPUMP GRUNDFOS OTHER:
_
READIAG
TIME
GALLONS
PURGED
TEMP
(-C)
SPECIFIC
COND.
(NS/cm)
DISSOLVED
OXYGEN
(mg/!-)
pH
is. U.)
report to
O.SS.U.
OXIDATION
REDUCTION
POTENTIAL
(mV)
TURBIDITY
;NTUI
COMMENTS
1
IUSSr
(. 7h
z
s
I(Oq
I,.93
2ZI
i,6'G
4
IIS
1 75-
56
70
6
- -
7
8
10
SAMPLING CONTAINER
NUMBER OF CONTAINERS
REQUESTED ANALYS.S
500 mL PLASTIC
2ED mL PLASTIC
125 mL PLASTIC
40 mL GLASS
1 L GLASS
OTHER
PR07ECTIVE CASING: C; x PAD:--aLOCK: GIf VEGETATION:—O A ACCESS:
Sampling Personnel Signature:
Date: Il /(ff�
Notes: 'C= degrees Cels as
PS/cm - mlar051emen per Centimeter
MWL-M1111grema per IIter
S.U. -Standard Units
mV - miliNcIt
NTU - nepnelametrlc turbldl;y units
Samples are analyzed immediately L pon collealon.
P:%WplatcslGW Drilling FmmeSWell Sampling Log -)ds Page 1 011
•
F4,111 IN MITI, 18 low 0
tt- FendHl ?8`v5 !A•..9LC GCI.Jyel
WW WaLLT• MYNTe"InnoN M .........
Well Sampling Log
PROJECT NAME: Cjtmr FA f_DATE,
r'
I(jq
PROJECT NUMBER:
WEATHER
SAMPLING PERSONNEL: S
SAMPLE TIME:
WELL NUMBER: q,� („/-
WELL DEPTH IN FEET f WD): (1-4;)
WELL DIAMETER: "
WATER LEVEL IN FEET (WL):
TYPE OF CASING: Pyr
LENGTH OF WATER COLUMN : i/ I FEET
MEASURING POINT' ^t -k,
(WD) - (WL) _ (LWC)
FLUSH MOUNT/ TICK -UP
ONE CASING VOLUME: ri . 7G Z I
GALLONS
COMMENTS: ,ac.;Ifd dr,
6NOr -1,0 (LWC)R(WCV)
Crap n', Cofv II r
ck- 4LM THREE CASING VOLUMES: rbc3
GALLONS '
c 'F
ACTUAL VOLUME PURGED:
GAL
an
-ONS
WELL CASING VOLUMES (WCV)
1'M0.041Ge 2--0 Gal,/Ft
3'•O383aVFt d=0.66WVPI: 6'=1.5GsVFt 8 =2.6 GaVFt
12-=5.8 Ga1/P1
PURGE METHOD: ILER-DISP BAILER -TEFLON DEDICATED PUMP 'WHALE PUMP GRUNDFOS OTHER:
SAMPLE METHOD: BAILER -D BAILER -TEFLON DEDICATED PUMP 'WHALE PUMP GRUNDFOS OTHER:
READING
TIME
bAHnONS
TEMP
SPECIFIC
DISSOLVED
pH
OXIDATION
TURBIDITY
COMMENTS
PURGED
(TC)
COND.
OXYGEN
(S,U-)
REDUCTION
(NTU)
(PS/cm)
(mg/L)
report to
POTENTIAL
0.1 S.U.
(mV)
1
1 iLyo
7,6,,r
173
10. -7
is i, 1.5-
2
if -15- 7
—
S
wd rr bA,'
4
-
5
T
8
9
10
SAMPLING CONTAINER
NUMBER OF CONTAINERS
REQUESTED ANALYSIS
500 mL PLASTIC
250 mL PLASTIC
125 mL PLASTIC
aO mi. GLASS
1 L GLASS
OTHER
PROTECTIVE CASING: PAD:_ [ 2,,�- VEGETATION:r%,, ACCESS: C2({
J�LOCK.
Sampling Personnel Signature:,; ;f�\
Date:
Notes. 'C=deg-ees lelllUS /-�'-CMeGY, Prl L 4chrafr0f Cr) I15o
yS/cm - n• :roSiemen per centimeter /
me/L- m::ligrams per lite* P H '� by r^ir� Sl ob;r� cd a -I 6.71 , re-c4(4,Z c D
S,U - Stanlaid Unna
MV - rt iili4olt
NTU - morhelometm turbidity units
Samp os are aralyzed rnmedistely upon collection
PATemplatestGW Dri Ing FarmstWoll Sampling Leg xis Pago 1 M t
.1,9• HAywbpc Sra¢ir. AM Me al -L[. KC 2a SC I_.. _.__..
TC_. Saa.2e1.3311C ra G.aiB.>'RI:J3e1
'�'w ISTII IIOnT[Ny1POV M5 NTAL.Cox
Well Sampling Log
PRC•JECT NAME: ueclp
` yLI/^ �r: r -r,:n� DATE:
PROJECT NUMBER: ?
WEATHER: V ; Uear, w„
SAMPLING PERSONNEL: ,Cl
S F SAMPLETIME:
WELL NUMBER: M �
72- WELL DEPTH IN FEET (WD):—L; ,40
WELL DIAMETER: 2"
WATER LEVEL IN FEET It.vu, t Z • L i
TYPE OF CASING: hp
LEVGTH OF WATER COLUMN' zI. 7 7
FEET
MEASURING POINT: TOC
(WD)-(WL)I(LWC)
FLUSH MOUNT STICK•
ONE CASING VOLUME: O • E' �D 1 GAL -ONS
COVMENTS:
ILWC) x (WCV)
p
THREE CASING VOL•JMES: Z . al ! B
GALLONS
ACTUAL VOLUME PURGED: '� �. •S� GALLONS
WELL CASING VOLUMES (WCV)
1•-0.041Ga1(F 2•-0. 7GaVFt 3"=0.38GaVFt 4'-0.66GaVFl 6'-1.5Ge1/FI 8 e2.6Gai/Ft
12"-5,8 Ga(/Ft
PURGE METHOD- •DISP. BAILER -TEFLON DEDICATED PUMP WHALE PUMP GP.UNDFOS OTHER:
SAM'LEMETHOD: ILER-
BAILER -TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER:
READING
TIME
_LONE
TEMP
SPECIFIC
DISSOLVED
pH
OXIDATION
TURBIDITY
COMMENTS
PURGED
(•C)
COND.
OXYGEN
(S.U.)
REDUCTION
(NTU)
(IS/cm)
(mg/1.)
report to
POTENTIAL
0.1 S.U.
(mV)
1
I Gt 2
f ^.25-
5 YE
(� , ,i
"Ory
2
l
a1w I.0
1G.31t
3G
ti
S.G.
16c C
>II00
S
i-
2,0
6:�
8-
s. 21
15 9. S
4
'',S
5.3a
23R
S oo
S,o3
ru-7.1
6
7
S
9
SO
SAMPLING CONTAINER
NUMBEROFCONTAINERS
REOUESTEDANALYSIS
600 mL PLASTIC
250 mL PLASTIC
125 mL PLASTIC
40 mL GLASS
1 L G LASS
OTHER
PROTECTIVE CASING: UK PAID -._61 LOCK: Oji VEO ETATION:U/f AOCESS:
Sam lin Personnel 5i nature:
P g g
Date: /
Notes'. °C=degrees caw as
p5/cm - ml^ -o -semen per cerdmeter
mg/L • milligrams per Irer
S.J. _ Vendard Units
mV - mliltvol;
NTU - n aphel ometric turbidity mita
Samples are ana yzed Immediately upon oollecricn.
PATemplates`GW 0riping FormslWoll Sampling Lcg.xh
Pawl 0'
E p.'v l n t:c rx r .�a Ek r1-'.ir f; k c• c G'< -r —"a Y r- a_.
1a:IIAswOCL ::.r[c-. ,ic n.c d:1. s, n;, zn Eai
WW\Y.YLT�NONTPNYrwOXMc.X4 •L.EOM
Well Sampling Log
PROJECTNAME:--
PROJECTNUMBER:
WEATHER:
SAMPLING PERSONNEL L
S SAM PLE
WELL NUMBER:
WELL DEPTH IN FEET (WD): l i
WELL DIAMETER. .7
WATER LEVEL IN FEETIWL): l'•IE
TYPE OF CAS'NG: PVG
_ _
LENGTH OF WATER COLUMN . Z -1"
FEET
MEASURING POI. ,
(WD)• (WL,t X (LWC)
FLLSH MOUNT STICK-UP
ONE CASING VOLUME: iJ. H6 S GALLONS
COMMENTS:
(LWC)x(WCV)
3q 7
THREE CASING VOLUMES: I •
GALLONS
ACTUALVOLUMEPURGED:^'
GALLONS
WELL MING VOLUMES (WCV)
1,X0041 t 2'
O._ alit 3'-0.380aVFt 4--O.EGGz VFt 6'-1.5Ga/FL 8'-2.6GaVFt
_2-X5.8 GsVFt
PURGE METHOD: BAILER-DISP. DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER:
:;LER-TEFLON
SAMPLE METHOD: I BAILER•DISP. LER•TEFLON DEDICATED PUMP WHALE PUMP GRUNOFOS OTHER:
_
READING
TIME
TEMP
SPECIFIC
DISSOLVED
pH
OXIDATION
TURBIDITY
COMMENTS
PURGED
('C)
COND.
OXYGEN
(S.U.)
REDUCTION
INTO)
(p5/cm)
(mg/l.)
report to
POTENTIAL
0.1S.U.
(mV)
1
37
2
Us6
G.5
15.55
s; -v
z,qs
6.o3
1 '.�
Hqx 5`
a
ri3'f
I,
,�o
583
Z.23
5.8y
(i/.0
33.x.
a
iZts
5
(�.2,N
(�'-G
ZP39
5
G
T
—.
8
9
10
SAMPLING CONTAINER
NUMBER OF CONTAINERS
REQUESTED ANALYSIS
5CO mL PLASTIC
250 mL PLASTIC
125 mL PLASTIC
40 mL GLASS
ILGLASS
CT4ER
PROTECTIVE CASING U i PAD: U i LOCK:__CJt VEGETATION: /' ACCESS: (:f-
:f-Sampling
SamplingPersonnel Signature:,,,.
Date:
Notes: "C = degrees Celsius
p5/cm X microSlamen per eenLnreter
mg/L X millig-ems per liter
S.U. - Standard Unita
mV X millivo:t
NTU - nephelometric turblcfty units
TPles are analyzed immediately upor, CDIIediOn.
ro %GW Drilling FpmslWell Sampling Log.xb
PROJECT NU
WELL DIAMETER:
TYPE OF CASING:
MEASURING PON
FLUSH MOUNT(
COMMENTS:
KI I • 430 1 kwj IS lin
.T.. ,
i[L tlltl.�bi. tl J'vC 'AC d2H.:P 1 3:L1
W AW.OtT-IOM Ti1YYlY01..1-aT 1.L.COIY
Well Sampling Log
•iny DATE: I �
WEATHER:
WATER LEVEL IN FEET (WL): C. s z
PURGE METHOD: ILER-D1 .BAILER -TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER
SAMPLE METHOD: I ISP. BAILER -TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER.
LENGTH OF WATER COLUMN : I. SS
FEET
(WO) - (WL) - (L%VC)
TEMP SPECIFIC
(°C) GOND.
(pS/cm)
�. N
OXIDATION
REDUCTION
POTENTIAL
(ni
ONE CASINO VOLUME:
GALLONS
(LWC) x (WCV)
THREE CASING VOLUMES:
GALLONS
ACTUAL VOLUME PURGED. '" Z 5
GALLONS
i WELL CASING VOLUMES (WCV)
1--OD41 GaV/2-'0.17 aVFt 3' - :).38 GeVFt 4'•066 Cal/F: 6"'150aVFt B"-2.6Gr C2'-59Ga j"t
PURGE METHOD: ILER-D1 .BAILER -TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER
SAMPLE METHOD: I ISP. BAILER -TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER.
READ'.NG
TIME
GALLONS
PURGED
TEMP SPECIFIC
(°C) GOND.
(pS/cm)
DISSOLVED pH
OXYGEN (S. U.)
(mg/-) report M
0.1 S.tl.
OXIDATION
REDUCTION
POTENTIAL
(ni
TURBIDITY COMMENTS
(NTU)
M-23 `ls
2s ,pq
(za.Lr
lZql
2
ilF
3
iQ0
-2.257
1,= 7S 0)'
0i�,
4
B
6
7
8
9
10
SAMP_ING CONTAINER
NUMBER OF CONTAINERS REQUESTED ANALYSIS
500 mL PLASTIC
250 mL PLASTIC
_
125 mL PLASTIC
4U mL GLASS
PROTECTIVE
lSamplingPersonnel Signature: /���� ice.. Date: I I (,'/�/
Notes: "C - degrees Celsius
VS/cm - micioSlemen per centimeter
mg/L - millig-ams per liter
S.U.-SAndard Units
mY-m liivclt
NTU = naphalometrio turbid ;y mils
Samples are aoaA•red Immediately upor w ii=or.
P:1TunplateskGW Drilling FormslWcll Sampling Log.xls Page 1 of 1
Equipment Documentation & Instrument Calibration Data Sheet
Ca!lbreNon Documentallern
Protea Name: l I PN't Pnf +�Rnn.: < �'n- 1l'!are � /,'rrr. Person Conductlrg fsllbrauan: �L ¢ rj/PV/
project kumber. O. aGI _ n f Date at Cellbranon: 1!1r116
Equipment oocumentation
Equipment of meters used
Equlpmem Type
lotake measuremeri
Saba: Number
e4WterleYeI meters, survey
Brand Data of Use
150dt Water Lavel
21104
Soanbt
15041 Wmer LB•rel
22754
Sol nlst
15041 Water Love:
150
Te_stwell
150 -ft Drawdown
MP30.152 r
QED
Other
Tine r ❑me
("tial: r.�
equipment, etc.):
Select Turbidimeter. =
Hach 2100Q (3/n 15100604 5207)
HF Scientific MicroTPW (s/n 200601045)
Calibration Standards
Instrument Reading
Inslvnent Reading
Upiratan Delo
-._-_ (Hash 2100-1)
(HF Sclenhf:c Ail-rOTPW)
20 NTU 100'JU SOO NTU
0.02 NTU 1 10.0 N' 11 1000NTU
Cellbrotlon
Cab 'Cal: Cal;
Cal Jag
Cal Ca'. _ _
�
Tme: Time: Tim¢
Time:
Tine r ❑me
("tial: r.�
Cilf
VenficetlOn (10 NTUrVeHflceOon:
Vedficatbq: u n 1,,:,
NA
0 06
yE
Time:
-_
Time:
Time: li
Nates.
L Electronic equ pmenl calibrated according Whe manufamumr's oFemllon menual.
2. Spec fie Conductivity shouts be calibrated aoaordirg to values represertative of h'srode range.
3. Order of Ca''.bmtlon Is as follows: Specilla Cana umr iy, pH 7, 0114, oft 10, O0, ORP, QC checks.
4. QC Aceeptoi Ranges: r,i'/-0.1 Su. and Speche Conductivity 1" of the true velue. If QC readln3s 8e out or range. the Instrument notes
to be recalibrated.
5- - Indicates Iran 0 QC check most be performed In the morning, ererhoon, and the end of the day. or every few hours.
6.1e ndicares to choaae a Speoft Condu/cutiv,ity buffer of 1413, 447, 84, or 23 mS which Is dowst Ic historical readings from the proem iocatlan.
4 Re
atTaTdawa\OrvuMnba1e lwltdne FQ'hrViom4w w6xrlce wmnr\Gtlxalon Cela 6�roo1 ^SI eSB aev9 Pegs lof'.
YSI 556 MUItlparometer Meter (s/n 12L101057)
Instru nlRNOings
Cellbrotlon
,d1 :eLt
Expiration Dale
nissmvmt ox)ger
("tial: r.�
Cilf
mmHg7616Q Time: Ci' 7ri
NA
PH 7 SX. repo:' Ic C.1
,ilial;
pHmV:Cal:
pHmV
T'me:
PH 4 S.U. report 1a Q.
Initial:
Initial:
'
pHmV:
pHmV:
-_— -
Cal: pHmV:
i�L
Cal: Gf pHmV:
91
ITme,,,
PH 10 S.U. report to
Tme:
0.15.U. 9,
AM AM Time:
Mesa!
MIG Day TIN; (Teck:
PM Time: Chauk:
aii
QC PH 7 S.U. Pon
Spec. Caird.
lnalai:
Cal:
Time:
- 4S/ar_•-.
q 6 3
_�S,Ls_.
QC:
_.__
M
AM Time:
Meas:
— --
Mid D6Y me: _ Chedc
PN TImn:h.
16m --k:-
--------
n✓���Q4
1.�LJ iS/cm
Sr) 31
q�
OPP 240 mV
Initial: 3N
I
(Cal; 0E2.
Time: mo
Nates.
L Electronic equ pmenl calibrated according Whe manufamumr's oFemllon menual.
2. Spec fie Conductivity shouts be calibrated aoaordirg to values represertative of h'srode range.
3. Order of Ca''.bmtlon Is as follows: Specilla Cana umr iy, pH 7, 0114, oft 10, O0, ORP, QC checks.
4. QC Aceeptoi Ranges: r,i'/-0.1 Su. and Speche Conductivity 1" of the true velue. If QC readln3s 8e out or range. the Instrument notes
to be recalibrated.
5- - Indicates Iran 0 QC check most be performed In the morning, ererhoon, and the end of the day. or every few hours.
6.1e ndicares to choaae a Speoft Condu/cutiv,ity buffer of 1413, 447, 84, or 23 mS which Is dowst Ic historical readings from the proem iocatlan.
4 Re
atTaTdawa\OrvuMnba1e lwltdne FQ'hrViom4w w6xrlce wmnr\Gtlxalon Cela 6�roo1 ^SI eSB aev9 Pegs lof'.
GW -59A COMPLIANCE REPORT FORM Permit # WQ0004797
(.Vulandt ). re each manitaring period Irhh GO' -Sy fanru.)
I
Enter date monitoring results were due. (12/31/2016) Will this monitoring report (GW -59 and GW -59A)
YES
NO
be submitted after the established due date?
YES
X
NO
2
Was any required information missing on the CW -59 report forms? -
IF the answer to question 1 or 2 is "YES', list in the space provided below the well identification number)'s) and
explain the problems encountered in obtaining tho required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
Identification plate, wren overgrown, eta.)? (%the answer is "Yes", contacl the Regional Ofcejor guidmrre.
X
4
Are any monitored constituents equal to or above the established standards?
V
NO
If the answer to question 4 is 'NO', skip to section 8.
If the answer to question 4 I "YES" list the affected wells individually with constifuenf(s) and concentrations)
exceeding standards in the space provided below:
MW -8: Nitrate -14.3 mg/L: MW8 Tetrachlorethene = 141 ug/l, Trichloroethene = 63.I yell, as-12-0Ichbraethene - 752 pelt;
MW -7R: Total Organic Carbon - no melt, Nitrate -12.5 mg/L
Total Organic Carbon Limit- 10 mg/0 Nitrate limn - to melt; Tetrdchlomethene limit - 0.7 ug/q trichloroethene limit = 3 ug/LI Cis-1,2-dichloroethene limn - 70 per
5
For the constituents Identified In question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) In the same well(s) In the last two years?
X
If the answer to question 5 is "NO" skip to section 8.
If the answer to question 5/s "YES", list in the space provided below, each well with constiluent(s) exceeding
standards, concentrations) reported, and sample collection date for each occurrence (for the last two years).
Total Organic Carbon (emit - 30 mg/q-5/13/2015: MW -5 =1e] melt,11/18/2014: MW$ -54.0 melt; 5/22/2014: MW -8-17.6 ani
5/4/2016: MW -7R-13.5 mg/l, 11/15/14: MW -711-19.1 mg/L
Tetrachloroethene (limit- 0.7 ug/q-11/35/2014: MWS - 121 ug/L; 11/4/2015: MW -5" 261 ug/L
Trichloroethene (Ilmd-3 pg/IT-11/18/2014: Mws - 22.2 ug/1-
gJLNitrate
Nitrate(limit = SO mg/q-5/4/2016: MW -7R -112 melt MW -8 = 19.1 mg/LI 6/9/2038: MW -7R -10.9 mgr4 MW a • 26.3 me/L.
6
Are the monitoring wells listed in section 6 located at or beyond the review boundary?
YES
NO
If the answer Is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer Is "NO", monitoring wells maybe Improperly
located; contact the Regional Office.
MW -5 is upgradlent and outside of the review boundary. MW -7R and MW -8 are beyond and downgradient
of the review boundary.
7
is the permittee implementing previously approved actions required by the Division Involving this
YES
NO
groundwater quality problem?
_
If the answer to question 7 is "YES" describe those actions in the space provided below.
X
If the answer to question 7 I "NO", contact the Realonal Office within 90 days: an evaluation may be
ralaoired to determine the impact the waste disposal system Is having at the review and corrijbilainic
boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation,
fines, and/or penalties.
TotMehlomethen , trlchloorthene, and cis-1,2-dicboroetbene have been defected in MW -5 during almost every November sampling event since November 2002.
The conten rations of these VOCs have been treating downward since Me initial detection In 2002, with occasional minor spikes in dab.
Total Organic Carbon (TOC), voc. and SVOC analyses were completed for all samples during Me May 2007 groundwater sampling event TOC concenlre0ons are not
attributable to voca or svocs and are possibly naturally occurring.
Nitrate concentrations twiddled the groundwater standard in MW -7R and MW -8 for We first time In May, 2016. The high concentrations of nitrate are likely
attributable to occasional flooding from the stream adjacent to these monitoring wells and/or W an adjacent property.
g
The person completing this portion (GW -59A) of the monitoring report should sign below and submit this
form with GW -59 forms for required wells to the address provided at the top of the current G W-59 form.
I hereby acknowle a that the abov formatio s evaluated and the Information submitted in this
report (Complia a -69 I true a co plate to the best of my knowledge.
2
AP"M
utb zed. Agent) Data
GW -59A 1218/2003
SUBMIT FORM ON YELLOW PAPER ONLY
=R QUALITY MONITORING:
REPORT FORM
TY INFORMATION Please Print Clearly or Type
Name: Clement Pappas
Name (if different):
Address: 125 Industrial Park
dersonville s'a NC 28792 County Henderson
act Person: Mr. Blake Kehoe Telephone#: 828-693-0711
Location/Site Name: Irrigation Area No. of wells to be sampled: 6
YA1tTMENT OF ENVIRONMENT a NATURAL RESOURCES
'ISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
7 MAIL SERVICE CENTER, RALEIGH, NO 27699-1617 Phone: 919-807-6306
!RMIT Number: Expiration Date: 8/31/202
n -Discharge WQ0004797 UIC
IDES Other
PE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
IN Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
- - -(--- )
WELL ID NUMBER (from Permit : MW -4
sample collected: 11/9/2016
FIELD ANALYSES:
mg/L
If WELLDate
WAS
Well Depth: 18 -2 -aft.
Well Diameter: 2 in.
pH o0400: 5. 76 units Temp. 000to: 16 . 72 °C
Coliform: MF Total 31504
DRY at
Depth to Water Level 82546: 9 , 6 3ft. below measuring point
Screened Interval: 8*ft. tc!L6_1*ft.
Spec. Cond. 00094: 186 µMhos
WrsleSamples)
time of
Measuring Point is 2 . 43 ft. above land surface
Relative M.P. Elevation: 2063.77 ft.
Odor none
AI - Aluminumoilos
sampling,
Volume of water pumped/bailed before sampling: 4.75 gallonsa`zaenea incerval to relac," to land surface
Appearance
units
check
Samples for metals were collected unfiltered: El YES El NO
and field acidified: ❑YES El NO
4.3 mg/L
Ca - Calcium 00916
here:
❑
Its sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services
IRAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L
Coliform: MF Fecal 31616
<4 0 /100mL
Nitrate (NOS) as N 00620
<0 . 020 Till
Coliform: MF Total 31504
/100ml-
Phosphorus: Total as P ooses
0.27 mg/L
(Note: Use MPNmethod for highly
WrsleSamples)
Orthophosphate 70507
mg/L
solved Solids:TotaI70300
124 mg/L
AI - Aluminumoilos
mg/L
pH (Lab) 00403
units
Be - Barium 01007
ug/L
TOC ooseo
4.3 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940
1 2 - 2 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
ecific Conductance 000gs
µMhos
K - Potassium 00937
mg/L
Total Ammonia ooslo
<0-10 mg/L
Mg - Magnesium 00927
mg/L
g
(Ammonia Nitrogen; NH, as N;
Ammonia Nitrogen, Tale)
Mn -Manganese 01055
ug/L
TKN as N 00625
rl
Ni - Nickel 01067
ug/L
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Pb - Lead olo51
Zn - Zinc 01092
Certification No. 3 7 712
ug/L
mg/L
49FC
419
Other (Specify Compounds and Concentration Units):
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ® Yes (1) ❑ No (0)
VOC 7873 , method # 5200
method #
method #
method #
mg/L Effluent Total
imee (or Autnonzed Agent) Name and Tale - Please print or type✓ Signator ennittee ulho reed Agent)
GW -59 Rev. 8/2013
mg/L VOC Removal
SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
Facility Name: Clement Pappas
Permit Name (if different):
Facility Address: 125 Industrial Park
Hendersonville Ismao NC 28792 county Henderson
Contact Person: Mr. Blake Kehoe Telephone#: 828 - 693 - 0711
Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6
PARTMENT OF ENVIRONMENT & NATURAL RESOURCES
1SION OF WATER RESOURCES- INFORMATION PROCESSING UNIT
7 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-907-6306
.RMIT Number: Expiration Date: 8/31/202
n -Discharge WQ0004797 UIC
-DES Other
'PE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
12 Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
- -- ----from-
WELL ID NUMBER (from Permit): MW -5
Date sample collected: 11/9/2016
FIELD ANALYSES:
units
KWELL
WAS
Well Depth: 18 r oft•
Well Diameter: 2 in.
pH 00400: 4 . 79 units Temp. 000lo: 15 . 72 eC
Arsenic 01002
DRY at
Depth to Water Level 82546: ft, below measuring point
�??� 9 P
Screened Interval: 9 * 19 *
_ft. to ft.
Spec. Cond. 00094: 185 µMhos
ug/L
time of
Measuring Point is 3 . 0 0 ft. above land surface
Relative M.P. Elevation: 2085.60 ft.
Odor 000ee: none
Total Ammonia oo6lo
sampling,
Volume of water pumped/bailed before sampling: 3.75 gallons
•acreened interval ie relative to land surface
Appearance
Mg - Magnesium 00927
check
Sam -les for metals were collected unfiltered: ❑ YES ❑ NO
and field acidified: ❑ YES ❑ NO
Ni- Nickel 01067
un/1
here: ❑
Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite (NOJ as N 00615 mg/L
Coliform: MF Fecal 31616 <4 . 0 /1OOmL Nitrate (NO3) as N oo62o 0.42 mg/L
Coliform: MF Total 31504 /10OmL
(Nola: Use MPN memod for highly wrEid samples)
Ived Solids:Total 70300
109 mg/L
pH (Lab) 00403
units
TOC 00680
<1 . 0 mg/L
Chloride 00940
45.0 mg/L
Arsenic 01002
ug/L
Grease and Oils 00552
mg/L
Phenol 32730
ug/L
Sulfate 00945
mg/L
ific Conductance 00095
µMhos
Total Ammonia oo6lo
<0 - 10 mg/L
(Ammonia Niavg,,m NH,.. W. Am nia Nitrogen, Tom9
TKN as N 00625 mg/L
For Remediation Systems Only (Attach Lab Reports):
Phosphorus: Total as P 00665
0.47 mg/L
Orthophosphate 70507
mg/L
Al - Aluminum 01105
mg/L
Ba - Barium 01007
ug/L
Ca - Calcium 00916
mg/L
Cd - Cadmium 01027
ug/L
Chromium: Total 01034
ug/L
Cu - Copper 01042
mg/L
Fe - Iron 01045
ug/L
Hg - Mercury 71900
ug/L
K - Potassium 00937
mg/L
Mg - Magnesium 00927
mg/L
Mn - Manganese oloss
ug/L
Ni- Nickel 01067
un/1
Influent Total VOCs:
ma/L
Pb - Lead o1oe1
Zn - Zinc 01092
Certification No. 37712
ug/L
mg/L
Other (Specify Compounds and Concentration Units):
fC 9 e2016
C
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ® Yes (1) ❑ No (0)
VOC7873 ,method# Fsnn
method #
method #
method #
Effluent Tntal Vr1Cr,
VOC Removal%
GW -59
Rev. 812013
SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
as : :
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
.,
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
.
1617 MAIL SERVICE CENTER, RALEIGH. NC 27699-1617 Phone: 919-907-6306
FACILITY INFORMATION Please Pnnt Cleady or Type
PERMIT Number: Expiration Date: 8/31/2020
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
NPDES Other
Permit Name (if different):
Facility Address: 125 Industrial Park
TYPE OF PERMITTED OPERATION BEING MONITORED
❑Lagoon EJ Remediation: Infiltration Gallery
Hendersonville (stroW NC 28792 count Henderson
(cny) (stael (Zip)y
® Spray Field ❑ Remediation:
Contact Person:. Mr. Blake Kehoe
Telephone#: 828 -693 - 0 711
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled:
6
❑ Water Source Heat Pump ❑ Other:
(from Perot)
SAMPLING INFORMATION MW -6
If WELL
WELL ID NUMBER (from Permit):
Date sample collected: 11/9/2016 FIELD ANALYSES:
WAS
Well Depth: 11 _ 5aft. -
Well Diameter:. 2 in.
pH 00400: 5 . 31 units Temp. 000to: 17 . 05 °C
DRY at
Depth to Water Level 92546: 7 - 42 ft. below measuring point Screened Interval: 5" ft.
to 10 * ft. Spec. Cond. 00094: 88 µMhos
time of
Measuring Point is 3 . 0 0 ft. above land surface
Relative M.P. Elevation: 2061. 17 ft. Odor 00045: none
sampling,check
Volume of water um ed/bailed before sampling: 1 . D
P P9
allon5ecreened interval is relative to land surface
Appearance
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES
❑ NO
x
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report LaboratoryName:-Pace Analytical Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved
and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead oiosl /L
u /L
ug
Coliform: MF Fecal 31616 . 0/100mL
Nitrate (NOS) as N 00620 <0.
020 mg/L Zn mg/L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P00665 0.70
mg/L
(Nore: Use MPN nathod for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 64.0 mg/L
AI - Aluminum 01105
mg/L
PH (Lab) 00403 units
Be - Barium 01007
ug/L
TOC o0690 7.1 mg/L
Ca - Calcium 00916
mg/L19 2��u
Chloride 00940 9.0 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L E
Grease and Oils 00552 mg/L
- Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900 _
ug/L Lab Report Attached? ® Yes (1) ❑ No (0)
pecific Conductance D0095 µMhos
K - Potassium 00937
mg/L VOC 7973 , method # 6200
Total Ammonia 00610 0.11 mg/L
Mg - Magnesium 00927
mg/L , method #
(Anrronie Nitrogen; NH3 as N; Ammonia Nitrogen, TOMO
Mn - Manganese 01o55
ug/L method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L , method #
ror Remediation Systems Only (Attach Lab Reports)
GW -59 Rev. B/2013
Influent Total VOCs: mg/L Effluent Total
mg/L VOC Removal%
6
SUBMIT FORM ON YELLOW PAPER ONLY
7 a a , DEPARTMENT OF ENVIRONMENT 9, NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING: a as a DIVISION OF WATER RESOURCES- INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone:919-807-6306
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 8/3172u2u
Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC
Permit Name (if different): - NPDES Other
Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville (shore" NC 28792 County Henderson ❑ Lagoon 9 ❑ Remediation: Infiltration Gallery
(cry) (state) (zip) IR Spray Field ❑ Remediation:
Contact Person: Mr. Blake Kehoe Telephone#: B28-693 -0711 ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other:
_. .....-...-...- _. ., MW -7R
WELL ID NUMBER (from Permit):
Date sample collected: 11/9/2016
FIELD ANALYSES:
mg/L
If WELL
WAS
Well Depth: 17 _ 7 nft.
Well Diameter: 2 in.
pH 00400: 5_03 units Temp. 000lo: 15.34'C
Coliform: MF Total 31504
DRY at
Depth to Water Level 92546: 1 2 - F 3 ft. below measuring point
Screened Interval: 5 ft.* to 1511L*
Spec. Cond. 00094: 239 µMhos
time of
Measuring Point is 3 . 0 0 R. above land surface
Relative M.P. Elevation: 2062.86 R.
Odor 000es: none
AI - Aluminum 01105
sampling,
Volume of water um ed/bailed before sampling: 2 . 5 gallon
P P P 9� 9
a`=eenea interval ie retec�ve to land surface
Appearance
ug/L
check
here:
Samples for metals were collected unfiltered: ❑ YES ❑ NO
and field acidified: F1 YES F-1 No
mg/L
Chloride 00940 22.7
mg/L
ite sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services
\RAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L
Coliform: MF Fecal 31616 <20.0
/100mL
Nitrate (NO3) as N oo6m
12.5 mg1L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665
1.0 mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
solved Solids:Total 70300 147
mg/L
AI - Aluminum 01105
ni
pH (Lab) 00403
units
Be - Barium 01007
ug/L
TOC oomo 13 .0
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 22.7
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
ni
Cu - Copper 01042
mg/L
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
eciFic Conductance 00095
µMhos
K - Potassium 00937
mg/L
Total Ammonia oo6lo <0-10 mg/L
Mg - Magnesium 00927
mg/L
(Aovnonie Nitrogen: NH3 as N: Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Pb - Lead o1o51
Zn - Zinc olo92
Certification No. 37712
ug/L
mg/L
Other (Specify Compounds and Concentration Units):
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ❑ Yes (1) ® No (0)
VOC 7873 , method # 020o
method #
method #
method #
mg/L Effluent Total VOCs:
ma/L VOC RPrnnVal%
GW -59 Rev. 8/2013
SUBMIT FORM ON YELLOW PAPER ONLY
r � e e , utPAKI MENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING: as a DIVISION OF WATER RESOURCES- INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-007-6306
FACILITY INFORMATION PleasePriintClearly-Type PERMIT Number: Expiration Date: 8/31/2(J20
Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC
Permit Name (if different): NPDES Other
Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville (SaeeU NC 28792 County Henderson ❑ Lagoon
(cayl I..) (tip)g El Remediation: Infiltration Gallery
® Spray Field ❑ Remediation:
Contact Person: Mr. Blake Kehoe Telephone#: 828 — 693 — 0711 ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation area No. of wells to be sampled: 1. 6 ❑ Water Source Heat Pump ❑ Other:
_. .. _. _..-_.-._.............
WELL ID NUMBER (from Permit): MW -8
Dale sample collected: 11/9/2016
FIELD ANALYSES:
Nitrite (NOO as N 00615
If WELL
WAS
Well Depth: 13_9-4
Well Diameter: 2 in,
pH 00400: 6.12 units Temp. 000lo: 14.66'C
Nitrate (NO,) as N oo6zo
DRY at
Depth to Water Level 82546: 11 . l Eft. below measuring point
Screened Interval: 3 ft- to 13 ft*
Spec. Cond. 00094: 626 µMhos
Phosphorus: Total as P oo66e
time of
Measuring Point is 3 . 0 0 ft. above land surface
Relative M.P. Elevation: 2060. ao ft.
Odor 000ss none
Orthophosphate 70507
sampling,
Volume of water pumped bailed before sampling: 1 .5 0
*eereened interval is relative to land surface
gallons
Appearance
Al - Aluminum o11o5
check
Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO
units
here:❑
tte sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services
\RAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NOO as N 00615
mg/L
Coliform: MF Fecal 31616
<4 . 0
/10OmL
Nitrate (NO,) as N oo6zo
14.3 mg/L
Coliform: MF Total 31504
/10OmL
Phosphorus: Total as P oo66e
0.26 mg/L
(Nore: Use MPN mthod Por highly mrsid
samples)
Orthophosphate 70507
mg/L
solved Solids:Total 70300
333
mg/L
Al - Aluminum o11o5
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00660
9.7
mg/L
Ca - Calcium oo916
mg/L
Chloride 00940
12.0
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L
Phenol 32730
ug/L
Fe - Iron 01o45
ug/L
Sulfate 00945
mg/L
Hg - Mercury 71 goo
ug/L
ecific Conductance 0009s
µMhos
K - Potassium 00937
mg/L
Total Ammonia 00610
<0-10 mg/L
Mg - Magnesium 00927
mg/L
(Ammonia Nlvagen; NH,.. N; Ammonia Nitrogen, Tota6
Mn - Manganese 01o55
u9 /L
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
For Remediation Systems Only (Attach Lab Reports):
Influent Total VOCs:
Pb - Lead olos1
Zn - Zinc 111092
Certification No. 37712
ug/L
mg/L
Other (Specify Compounds and Concentration Units):
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ® Yes (1) ❑ No (0)
VOC 7873 , method # 6200
method #
method #
method #
Effluent Trial VOCs
VOC Removal%
GW -59 Rev. 8/2013
SUBMIT FORM ON YELLOW PAPER ONLY
:. oo ; : DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-907-6306
FACILITY INFORMATION Please Print Fla -Type PERMIT Number: Expiration Date: 8 31 ZU2U
Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC
Permit Name (if different): NPDES Other
Facility Address: 125. Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville S'ee NC 28792 Coun Henderson
ry ❑Lagoon EJ Remediation: Infiltration Gallery
(CRY) (5taw) (Zip) ® Spray Field ❑ Remediation:
Contact Person: Mr. Blake Kehoe Telephone#: 8 2 8 - 6 93 - 0 711 ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other:
WELL ID NUMBER (from Permit): MW -9
sample collected: 11/9/2016
FIELD ANALYSES:
If VYLLLDate
WAS
Well Depth: 18.1 oft.
Well Diameter: 2 in.
pH 00400: 4- 42 units Temp. 0001o: 16.750C
DRY at
Depth to Water Level 82546: 6 . 5 5 ft. below measuring point
Screened Interval: 6 *ft. to 16 * ft.
Spec. Cond. 00094: 90 µMhos
time of
MeasuringPoint is 1 . 44 ft. above land surface
Relative M.P. Elevation: 2060.23 ft.
Odor 9ooe5: none
sampling,
Volume of water um ed/balled before sampling: 2.25 afDns screened iatexval ie relative to lana surface
P P P 9� 9 Appearance
check
here:
Al - Aluminum 01105
mg/L
pH (Lab) 00403
units
Samples for metals were collected unfiltered: ❑ YES ❑ NO
and field acidified: ❑ YES ❑ NO
TOC oo6Bo
IK
Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L
Coliform: MF Fecal 31616
<20.0 /100mL
Nitrate (NOs as N 00620
0.77 mg/L
Coliform: MF Total 31504
/10OmL
Phosphorus: Total as P00665
0 .76 mg/L
(Nolo: Use MPN method for highly twbitl
samples)
Orthophosphate 70507
mg/L
)issolved Solids:Total 70300
G9.0 mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403
units
Be - Barium 01007
ug/L
TOC oo6Bo
9.3 mg/L
Ca - Calcium Dots
mg/L
Chloride 00940
10.7 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01D42
_mg/L
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L
Total Ammonia 0o610
<0 . 10 mg/L
Mg - Magnesium 00927
mg/L
(Ammonia Nitrogen; NH,as N: Ammonia Nitrogen, Teta9
Mn - Manganese 01055
ug/L
TKN as N oo625
mg/L
Ni - Nickel 01067
ug/L
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Pb - Lead olos1
Zn - Zinc 01092
Certification No. 37712
ug/L
mg/L
Other (Specify Compounds and Concentration Units):
DEG 2 6
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ® Yes (1) ❑ No (0)
VOC 7873 , method # _ 62nn
method #
method #
method #
mq/L Effluent Total VOCs:
mall l/nr, Rern v" l
GW -59 Rev. 812013