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HomeMy WebLinkAboutWQ0004797_Monitoring - 11-2016_201612281 • WE NG I N E E R i r.., a ii L� 231 HAYW000 STREET. ASHEVILLE. NC 28801 TEL.828.281.3350 FAC.828.281.3351 W W W.ALTAMONTENVIRONMKNTAL.COM December 16, 2016 Mr. Blake Kehoe Plant Engineer Lassonde Pappas and Company, Inc. 125 Industrial Park Road Hendersonville, North Carolina 28792 Subject: November 2016 Groundwater Sampling Event Clement Pappas & Co., Inc. (Clement Pappas) 125 Industrial Park Road Hendersonville, North Carolina Dear Mr. Kehoe: RF"'FI\/FD 0EC 2 8 2016 DWR SECTION INFORMATION PROCESSING UNIT Altamont Environmental, Inc. (Altamont) performed a groundwater sampling event at the subject facility on November 9, 2016. A site location map is included as Figure 1. Altamont performed the groundwater sampling event in accordance with the North Carolina Department of Environmental Quality (DEQ), formerly known as the Department of Environment and Natural Resources (DENR), spray irrigation system permit number WQ0004797 (permit most recently reissued on September 3, 2015). Altamont collected groundwater samples from six monitoring wells: MW -4, MW -5, MW -6, MW -7R, MW -8, and MW -9. Monitoring well MW -9 was installed on April 14, 2015 to replace the previously damaged monitoring well MW -2R. The locations of the monitoring wells are shown on Figure 2 (attached). Altamont submitted the groundwater samples to Pace Analytical Services, Inc. (Pace), a North Carolina -certified laboratory, for analysis of the parameters specified in the permit. Table 1 summarizes the current and historical laboratory analytical results for microbiology and wet chemistry. All parameters analyzed, except total organic carbon (TOC) and nitrate, were below the permit limits and North Carolina Administrative Code, Title 15A, Subchapter 21-.0202 Standards (21- standards). The TOC concentrations can be summarized as follows: • The permit limit for TOC is 10 milligrams per liter (mg/L). • Similar to previous sampling events, the TOC concentration in the MW -7R sample collected during this event (November 2016) was in excess of the permit limit. • TOC concentrations in samples MW -4, MW -6, MW -8, and MW -9 collected during this event (November 2016) were below the permit limit. TOC was not detected in the sample collected from MW -5. Nitrate concentrations can be summarized as follows: • The permit limit for nitrate is 10 mg/L. • Similar to the previous sampling event (May 2016), nitrate concentrations exceeded the permit limit in the samples collected from monitoring wells MW -7R and MW -8. • Nitrate was not detected in samples from monitoring wells MW -4 and MW -6. Nitrate concentrations detected in samples from monitoring wells MW -5 and MW -9 were reported below the permit limit. P:\Gement Pappas\Reports\2016 2081.01\November\Cover Letter_November 2016.Doc Blake Kehoe December 16, 2016 Page 2 of 3 Following the May 2016 sampling event, Clement Pappas requested that Altamont analyze the overall effluent application rates for the irrigation system in an effort to determine if the effluent may have been influencing groundwater results, specifically in regards to nitrate concentrations. As conveyed to the DEQ, Altamont's analysis found that it was highly unlikely that nitrogen concentrations in the effluent were influencing nitrate concentrations in groundwater. The more likely source of nitrate exceedances in floodplain monitoring wells (monitoring wells MW -7R and MW -8), as identified by DEQ and Altamont, was the continuous flooding of Mud Creek and its nutrient loading associated with runoff from agricultural fields upstream of the facility. In order to be proactive, Clement Pappas contracted Nutter and Associates to analyze the overall health and performance of the land application system. This analysis resulted in a report that included recommendations to improve the longevity of the system, while reducing the likelihood of impacts to groundwater. Recommendations that have been implemented by Clement Pappas include the following. In order to avoid introducing additional nitrogen to soils at the subject facility, Clement Pappas has implemented the practice of bailing harvested fescue and removing it from the irrigation fields, instead of mowing it and allowing it to decompose. Removing the harvested fescue should result in improved vegetative growth, which will allow the fescue to uptake additional available nitrogen. Additionally, it is expected that removal of the harvested fescue will result in greater assimilation of nitrogen into facility soils and reduce the potential for nitrogen leaching. • In an effort to correct calcium deficiencies in the irrigation fields, gypsum is applied. Gypsum was applied to the irrigation fields at a rate of approximately 5 tons per acre during 2016. Correcting calcium deficiencies allows the fescue to better uptake nutrients, thus reducing the available nutrients in soils that could potentially leach to groundwater. Clement Pappas also applied foliar manganese chelate to the fescue in an effort to increase nutrient uptake and further limit the amount of nutrients available in soils that could potentially leach to groundwater. Table 2 summarizes the current and historical laboratory analytical results for volatile organic compounds (VOCs) analyzed by EPA Standard Method 6200. In accordance with permit requirements, samples are analyzed for VOCs once annually, during the month of November. All VOCs analyzed, except tetrachloroethene, trichloroethene, and cis-1,2-dichloroethene, were detected below the permit limits or 2L standards. VOC concentrations can be summarized as follows: • Three VOCs (tetra ch lo roethe ne, trichloroethene, and cis-1,2-dichloroethene) were detected in the sample collected from monitoring well MW -5. All three of these VOCs were detected at concentrations above their 2L standards. These VOCs have been consistently detected at high concentrations in samples collected from this monitoring well since 2002. Concentrations are generally trending downward, with occasional spikes in the data. • No VOCs were detected in the samples collected from monitoring wells MW -4, MW -6, MW -7R, MW -8, and MW -9. Table 3 summarizes the current and historical groundwater elevations. With the exception of monitoring well MW -9, all of the monitoring well concrete pads and top -of -well casing elevations were surveyed by Wes Cole Land Surveying, PA on November 21, 2012. Monitoring well MW -9 was surveyed by Wes Cole Land Surveying, PA on May 29, 2015. The surveyed elevations are indicated on Table 3 and on Figure 2. In accordance with the spray irrigation permit, Clement Pappas is required to submit the following by December 31, 2016 (on or before the last working day of the month following the sampling month) to the DEQ: • Laboratory analytical report and chain -of -custody form (Attachment A); the well sampling logs and equipment documentation and instrument calibration data sheet are also included (Attachment B) P:\Clement Pappas\Reports\2016 2081.01\November\Cover Letter—November 2016.Doc Blake Kehoe December 16, 2016 Page 3 of 3 • DEQ GW-59A—Compliance Report Form (Attachment C) • DEQ GW-59—Groundwater Quality Monitoring Compliance Report Form for each monitoring well (Attachment D) Altamont proposes to complete the next scheduled groundwater sampling event in May 2017. If you have any questions or would like additional information, please do not hesitate to contact the undersigned at 828.281.3350. Sincerely, ALTAMONT ENVIRONMENTAL, INC. Brian Gant Attachments: Figure 1—Site Location Map Figure 2—Site Plan Map Table 1—Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Table 2—Current and Historical Groundwater Analytical Results for Volatile Organic Compounds Table 3—Current and Historical Groundwater Elevation Measurements Attachment A: Laboratory Analytical Report and Chain -of -Custody Form Attachment B: Well Sampling Logs and Equipment Documentation and Instrument Calibration Data Sheet Attachment C: DEQ GW-59A—Compliance Report Form Attachment D: DEQ GW-59—Groundwater Quality Monitoring: Compliance Report Forms R\Clement Pappas\Reports\2016 2081.01\November\Cover Letter_November 2016.Doc COMPLIANCE xa t BOUNDARY i T (2060.64 Flr�;c; ;. - #�`.: 0}..a...,.:. REVIEW BOUNDARY'T MW -8 Field #3 2060.80 PZ 1 Field #2' n 206 1. 1 MW -7R , - �. 2062.#6 WAOMW i MW -6 sr PROPERTY 2061.17 M of . Y BOUNDAR Old Field 2060.23 2064.18 jjjjyy t E r,` j LEGEND; # r MONITORING WELL R >A T MW -4 ® (IN USE) t41<; . 2063.77 OLD OR FORMER ® MONITORING WELL 41'a1� ✓�. u, O PIEZOMETERi (2060.64) TOP-OF-CASING:II ' +. ELEVATION '�' ' k \ .� , 4. —t' , Y\'�'^,Z.; r 4 -T:' ' •��' � 1:x a +• CrJ 2q 1• .I.I M11 IN �.> SOURCE: 1. AGRI-WASTE TECHNOLOGY, INC. (AWY) MAY 4, 2001 IRRIGATION PLAN. SIR FIGURE 2. EARTH SYSTEMSASSOCIATES, LTD. FIGURE 3 LAND TREATMENT SYSTEMS, UNDATED. SITE PLAN MAP 3. HENDERSON COUNTY GIS WESSITEACCESSED JANUARY 30.2006. ENGINEERING & HYDROGEGLGC \� 4. AERIAL PHOTOGRAPHY DATED 2015 OBTAINED BY NC ONE MAP. 231 HAYINOIO STREET, ASHEVILLE, NC 28801 ///'''��� NOTES: TEL.B28.281.3350 FAC.828.281.3351 CLEMENT PAPPAS - 1. PROPERTY BOUNDARY LINES (PINK LINES) AND 2' CONTOUR LINES FROM HENDERSON COUNTYGIS. •♦• Al T AHe xiLxvlRoxxexT Al. a.. L 2. IRRIGATION FIELDS FROM AWT IRRIGATION PLAN (BLUE LINES). 125 INDUSTRIAL PARD ROAD 3. COMPLIANCE BOUNDARY DETERMINED PER I5A NCAC 02L. 0107 (YELLOW LINES). DRAWN BY: WYATT EDSEL SCALE (FEET) HENDERSONVILLE, NC 4, MONITORING WELL TOP -OF -CASING ELEVATIONS SURVEYED BY WES COLE LAND SURVEYING ON PROJECT MANAGER: BRIAN GANT NOVEMBER 21, 2C 12. CLIENT: CLEMENT PAPPAS 250 0 200 Soo 5. MONITORING WALL TOP -OF -CASING ELEVATION FOR N1K0 SURVEYED BY WES COLE ON MAY 29, 2015 REY. DATE DESCRIPTION BY CNK APV DATE- 6/27/16 FILE PATH' P:,CLEHENr PAPPA5AFI60K5\CAD,ICI2M-SITE PLAN MAP. m,.. Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Clement Pappas Hendersonville, North Carolina Sample Name Sample Date _ O a CO U yaN 0 0 v `o U r� : a z a� w 'a j N y a N . o E E v, 0 L N O M. m (mm/dd/yyyy) (mg/L) (mg/L) (CFU per 100 mL) (mg/L) (mg/L) (mg/.L) (mg/L) , (mg/L) 05/24/2006 7.2 9.7 < 1.1 2 19 82 < 0.10 NA 11/09/2006 3.6 7.4 < 1.1 0.95 17 76 0.11 NA 05/18/2007 4.9 6.0 < 1.0 0.56 14 62 < 0.10 NA 11/13/2007 5.9 16.7 <1.1 2.9 6.9 82.0 < 0.10 NA 05/27/2008 10.2 9.0 <1.1 0.80 21.3 140 < 0.10 NA 11/18/2008 4.7 10.7 <1.1 1.9 8.5 32.0 < 0.10 NA 05/28/2009 14.4 7.1 1 < 4.0 0.46 24.2 104 < 0.10 NA 11/05/2009 13.5 5.9 < 2.0 0.31 23.5 80.0 < 0.10 1 NA MW -2R 05/13/2010 8.7. 5.8 < 2.0 < 0.10 17.2 57.5 < 0.10 NA 11/08/2010 18.3 10.0 < 2.0 1.1 11.7 60.0 < 0.10 NA 05/17/2011 11.6 < 5.0 < 2.0 < 0.10 14.3 < 62.5 < 0.10 NA 11/15/2011 18.9 10.1 < 2.0 1.2 10.0 86.0 < 0.10 NA 05/17/2012 5.3 7.6 < 4.0 < 0.20 11.9 68.0 < 0.10 NA 11/07/2012 31.1 9.5 < 1.0 1.3 10.0 67.0 < 0.10' NA 05/16/2013 13.5 1.2 < 1.0 < 0.02 13.2 64.0 < 0.10 NA 11/20/2013 6.1 7.6 < 1.0 0.97 9.3 66.0 < 0.10 NA 05/22/2014 8.0 4.1 < 1.0 0.72 8.4 52.0 < 0.10 NA 05/15/2002 8.9 45 < 1.1 < 0.10 9.3 180 < 0.10 NA 11/05/2002 5.5 48 < 1.1 < 0.1 14 230 < 0.10 NA 05/13/2003 3.3 32 < 1.1 0.051 20 110 0.21 NA 11/04/2003 41 31 < 1.1 < 5.0 66 210 < 0.10 NA 05/05/2004 6 29 < 1.1 < 5.0 45 240 0.11 NA 11/09/2004 8.4 13 3.6 < 0.10 52 200 < 0.10 NA 05/17/2005 8.5 10 < 1.1 < 0.10 37 220 < 0.10 NA 11/03/2005 16 1 14 < 1.1 < 0.10 29 220 0.14 NA 05/24/2006 19 11 < 1.1 < 0.10 28 180 < 0.10 NA 11/09/2006 8.8 . 6.9 < 1.1 < 0.10 26 180 < 0.10 NA • 05/18/2007 8.5 8.9 < 1.0 < 0.10 29 300 < 0.10 NA 11/13/2007 16.7 11.3 < 1.1 < 0.10 25.0 152 < 0.10 NA 05/27/2008 < 1.0 10.0 < 1.1 < 0.10 38.6 176 < 0.10 NA 11/18/2008 20.5 9.3 < 1.1 < 0.10 19.6 108 < 0.10 NA MW 05/28/2009 8.6 13.6 < 4.0 < 0.10 35.5 156 < 0.10 NA -4 11/05/2009 31.0 13.6 < 2.0 < 0.10 30.7 120 < 0.10 NA 05/13/2010 7.8 18.0 < 2.0 0.17 31.0 141 < 0.10 NA 11/08/2010 23.9 17.5 < 2.0 < 0.10 34.4 144 < 0.10 NA 05/17/2011 7.7 13.5 < 2.0 0.82 25.6 137 < 0.10. NA 11/15/2011 7.3 14.4 < 2.0 < 0.20 27.8 157 < 0.10 NA 05/17/2012 6.7 12.1 2.0 < 0.20 22.3 117 < 0.10 NA 11/07/2012 10.6 14.5 2.0 < 0.020 26.2 150 < 0.10 NA 05/16/2013 31.8 10.2 2.0 0.28 19.1 1 108 < 0.10 NA 11/20/2013 8.0 14.7 < 1.0 0.026 22.1 157 < 0.10 NA 05/22/2014 8.7 10.8 < 2.0 0.14 22.5 146 < 0.10 NA 11/18/2014 28.7 -12.1 < 2.0 < 0.020 21.9 161 < 0.10 NA 05/13/2015 5.4 9.2 < 1.0 < 0.020 21.5 130 < 0.10 NA 11/04/2015 6.6 6.2 <2.0 < 0.020 NA 139 < 0.10 0.10 05/04/2016 5.5 8.4 < 4.0 < 0.020 NA 119 < 0.10 0.095 11/09/2016 4.3 12.2 < 4.0 < 0.020 NA 124 < 0.10 0.27 Standards 10 250 1 10 250 500 1.5 NL P:\Clement Pappas\Reports\2016 2081.01\November\November 2016 -Historic Analytical Results Page 1 of 5 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Clement Pappas Hendersonville, North Carolina Sample Name • Sample Date c 0 a V (0 �9N .0. - 20 v o w O 0 m LL a� m Z �, _ U O N Q y - a � o E < O N _ a - 2 (mm/dd/yyyy) (mg/L) (mg/L) (CFU per 100 mL) (mg/L) ,(mg/L) (mg/L) (mg/L) (mg/L) 05/15/2002 2.9 15 < 1.1 0.42 1.7 < 40 < 0.10 NA 11/05/2002 1.4 16 < 1.1 0.54 < 1.0 83 1.3 NA 05/13/2003 4.6 17 < 1.1 0.65 2 56 0.25 NA 11/04/2003 19 22 < 1.1 0.23 < 5.0 58 < 0.10 NA 05/05/2004 0.7 28 < 1.1 0.57 < 5.0 80 0.15 NA 11/09/2004 1.2 34 < 1.1 0.24 < 5.0 130 < 0.10 NA 05/17/2005 2.1 35 < 1.1 < 0.10 < 5.0 110 < 0.10 NA 11/03/2005 8.1 34 < 1.1 0.11 <5..0 82 < 0.10 NA 05/24/2006 7.8' 34 < 1.1 < 0.10 < 5.0 120 < 2.5 NA 11/09/2006 1.3 37 < 1.1 0.20 < 5.0 90 < 0.1 NA 05/18/2007 1.7 42 < 1.0 0.16 < 5.0 130 < 0.10 NA 11/13/2007 4.2 41.3. < 1.1 0.25 < 5.0 112 < 0.10 NA 05/27/2008 6.7 14.3 < 1.1 0.21 < 5.0 168 0.17 NA 11118/2008 25.9 47.6 < 1.1 0.17 < 5.0 80.0 < 0.10 NA MW -5 05/28/2009 16.1 29.0 4.0 0.11 < 5.0 188 < 0.10 NA 11/05/2009 4.7 39.1 2.0 0.15 < 5.0. 112 < 0.10 NA 05/13/2010 3.2 43.0 23 0.17 < 5.0 147 < 0.10 NA 11/08/2010 13.8 43.7 200 < 0.10 < 5.0 113 < 0.10 NA 05/17/2011 4.0 32.3 < 4.0 < 0.10 < 5.0 < 167 < 0.10 NA 11/15/2011 3.0 52.6 120 < 0.20 < 5.0 165 < 0.10 NA 05/17/2012 4.7 36.6 1 < 2.0 < 0.20 < 5.0 110 < 0.10 NA 11/07/2012 4.1 61.1 < 10.0 0.12 < 2.0 139 < 0.10 NA 05/16/2013 4.0 44.2 1.0 0.093 2.3 152 1 < 0.10 NA 11/20/2013 4.2 64.6 1.0 0.19 < 2.0 162 < 0.10 NA 05/22/2014 5.8 6.6 < 10.0 0.099 < 2.0 110 < 0.10 NA 11/18/2014 16.0 57.7 6.0 0.28 < 2.0 160 < 0.10 NA 05/13/2015 21.0 68.4 < 2.0 0.11 < 2.0 176 < 0.10 NA 11/0472015 7.3 20.3 7.0 < 0.020 NA 68.0 < 0.10 0.21 05/04/2016 8.6 41.5 < 10.0 0.042 NA 90.0 < 0.10 0.12 11/09/2016 1 <1.0 1 45.0 < 4.0 0.42 NA 109 < 0.10 0.47 Standards 1 10 1 250 1 10 250 500 1.5 NL P:\Cleinent Pappas\Reports\2016 2081.01\November\November 2016_Historic Analytical Results Page 2 of.5 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Clement Pappas Hendersonville, North Carolina Sample Name Sample Date O � N U m O o N v_ o 0i _ O U mm LL Y' z Y = � 'O N N O m v o �, N o E a N � O L a. o (mm/dd/yyyy) (mg/L) (mg/L) (CFU per 100 mL) (mg/L) (rrig/L) (mgJL) (mg/L) I (mg/L) 05/15/2002 6.8 9.9 5.1 < 0.10 11 < 40 < 0.10 NA 11/05/2002 3.9 4.6 < 1.1 0.49 9.8 51 2.5 NA 05/13/2003 4.4 7.3 > 23.0 0.075 14 52 0.14 NA 11/04/2003 26 6.8 9.2. < 0.050 12 < 20 < 0.10 NA 05/05/2004 1.8 6.7 1.1 < 0.10 11 58 0.13 NA 11/09/2004 3.5 11 9.2 < 0.10 9.3 88 < 0.10 NA 05/17/2005 2.4 7.4 < 1.1 < 0.10 8.7 50 < 0.10 NA 11/03/2005 6.3 9.6 < 1.1 < 0.10 9.6 66 0.17 NA 05/24/2006 7.4 10 < 1.1 < 0.10 9 54 < 0.10 NA 11/09/2006 1.4 11 < 1.1 0.20 11 54 0.18 NA 05/18/2007 3.9 9.4 < 1.0 < 0.10 9.1 58 0.12 NA 11/13/2007 5.7 10.7 3.6 0.24 5.8 114 0.24 NA 05/27/2008 10.9 5.4 < 1.1 < 0.10 15.3 92.0 < 0.10 NA 11/18/2008 7.4 7.6 > 23 < 0.10 < 5.0 36.0 < 0.10 NA MW 05/28/2009 6.4 6.2 276 0.39 8.8 104 < 0.10 NA -6 11/05/2009 6.4 < 5.0 30 0.10 9.3 52.0 < 0.10 NA 05/13/2010 4.3 5.8 < 2.0 < 0.10 8.1 44.0 1 < 0.10 NA 11/08/2010 16.5 5.0 7.0 1.5 9.3 48.0 < 0.10 NA 05/17/2011 6.2 9.4 < 2.0 < 0.10 6.8 60.0 < 0.10 NA 11/15/2011 4.6 5.2 5.0 < 0.20 7.5 82.0 < 0.10 NA 05/17/2012 21.6 8.1 28.0 < 0.20 8.8 52.0 < 0.10 NA 11/07/2012 6.4 6.8 3.1 < 0.020 7.5 46.0 < 0.10 NA 05/16/2013 7.5 5.4 1 12.1 0.048 9.4 62.0 < 0.10 NA . 11/20/2013 4.4 7.3 < 1.0 < 0.020 8.6 56.0 < 0.10 NA 05/22/2014 4.6 4.5 1.0 < 0.0201 10.1 32.0 < 0.10 NA 11/18/2014 16.3 6.9 13.0 0.078 9.8 49.0 1 < 0.10 NA 05/13/2015 2.1 6.2 < 1.0 < 0.020 10.1 46.0 < 0.10 NA 11/04/2015 2.2 9.5 136 2.9 NA 58.0 < 0.10 0.12 05/04/2016 2.1 9.4 < 2.0 0.41 NA 58.0 < 0.10 0.079 11/09/2016 7.1 1 9.0 1 < 10.0 < 0.020 NA 64.0 0.11 0.70 Standards 10 1 250 1 1 1 10 250 500 1.5 NL P:\Clement Pappas\Reports\2016 2081.01\November\November 2016 -Historic Analytical Results Page 3 of 5 W J v . d CD z M 3 . 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Fecal Coliform 0 D D O O O 0 p O O 0p 0 0 0 0 0 p b µ µ µ 0 µ µ µ F. µ µ 1--* N µ µ 0 , O O r µ0 NOON OD W (D W J Ut v Cn (P D A b W 00 W U1 Cn N N w CP N W N W F-' N µ N µ µ µ µ µ P LI7 I--` Lb µ (il Cn ppapp Nitrate O (0 N F' 0n (P W N O W N N\ .r. z D z D z D z z D➢ W J A A A O W (P A '.b J 01 Cn L N Cn Ul to W Cq Ul p W AAAAAA (0 I-' N 0 ppsn Sulfate p fU (D O O O N O O O J 0 0 0 0 0 b W µ U1 A Z z w N N pW,7 (WJ N M W V (WD µp 0 µ O W O M N N A W A 3 Total Dissolved O J➢➢ O (D (n b 0 N b 00 W 0 0 0 M 0 0 0 O 00 00 W O N N p O SOIIdS n O Z➢ ZD n n O O n O n O n O n O n O A O n O n O n 00 n n O n O n O n n O O n O n O n O n O p n 0 n 0 n 0 n 0 p F- n O �- µ O H µ 0 0 µ 0 µ 0 µ 0 µ 0 µ 0 µ 0 µ 0 µ 00 µ µ µ 0 0 µ 0 µ 0 µ µ 0 0 µ 0 µ 0 µ 0 µ 0 µ 0 µ O O O J ppnn r Ammonia O O zFbA zzpwzzzzzzzzzzzzzzzzzzzzzzzzzzz3 D➢ D D a➢ TotalPhos Phosphorus � r O m 7 (D O a3 O W W O_ O C' � rte+ ty z m CL a n N n 1 3 O (D 7 3. L11 �-h7 "C R� d Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Clement Pappas Hendersonville, North Carolina Sample Name Sample Date 0 U o o C Gp Q m LL m i n onF m o 9-6 o an 0 C E E 2 a O 8 I°- (mm/dd/yyyy) (mg/L) (mg/L) (CFU per 100 ml-) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) 05/15/2002 6.8 8.7 < 1.1 < 0.10 9.1 64 '0.10 NA 11/05/2002 4.8 9.8 < 1.1 0.16 7 100 0.57 NA 05/13/2003 5.5 3.3 2.2 L4 9.4 64 0.41 NA 11/04/2003 27 8.1 6.9 <0.050 13 54 <0.10 NA 05/05/2004 3.0 7.4 < LS 0.24 9.8 140 < 0.10 NA 11/09/2004 3.7 6.7 > 23 0.79 6.8 120 < 0.10 NA 05/17/2005 3.8 8.3 < 1.1 0.61 6.4 88 < 0.10 NA 11/03/2005 7.1 11 < 1.1 0.95 8.4 100 < 0.10 NA 05/24/2006 Is 10 < 1.1 0.39 8.1 130 < 0.10 NA 11/09/2006 4.7 12 <1.1 0.97 7.7 96 <0.10 NA 05/18/2007 5.0 15 <1.0 3.0 13 290 <DAD NA 11/13/2007 8.3 19.6 <1.1 0.97 26.6 154 <0.10 NA 05/27/2008 12.4 20.0 <LS 0.55 35.8 184 <0.10 NA 11/18/2008 14.4 17.2 2.2 <0.10 2L5 118 <DAD NA 05/28/2009 6.2 24.9 240 0.74 24.9 192 <0.10 NA 11/05/2009 10.8 15.4 50 0.54 18.4 114 <0.10 NA MW -8 05/13/2010 10.8 14.7 <2.0 LS 24.1 106 <0.10 NA 11/08/2010 23.2 24.3 200 < 0.10 26.3 173 < 0.10 NA 05/17/2011 30 16.9 10.0 12.2 16.1 232 <0.10 NA 11/L5/2011 8.0 26.6 <2.0 3.7 20.2 232 <DAD NA 05/17/2012 14.4 24.8 12.0 8.0 22.9 356 <0.10 NA 11/07/2012 24.8 28.3 <100 L9 28.3 324 <0.10 NA 05/16/2013 15.8 8.8 10.9 6.8 13.4 248 < 0.10 NA 11/20/2013 21.0 15.4 < 1.0 1.3 24.3 342 < 0.10 NA 05/22/2014 17.6 14Z < 10.0 0.61 17.8 352 < 0.10 NA 11/18/2014 54.0 16.4 < 4.0 1.1 13.2 421 < 0.10 NA 05/13/2015 19.7 18.3 < 2.0 9.7 12.2 454 < 0.10 NA 11/04/2015 15.0 21.6 4.0 3.0 NA 396 <0.10 0.82 05/04/2016 15.0 24.5 < 10.0 19.1 NA 398 < 0.10 0.62 6/9/2016 -Pace NA NA NA 26.3 NA NA NA NA 06/09/2016 Foam NA NA NA 26.0 NA NA NA NA 11/09/2016 9.7 12.0 <4.0 14.3 NA 333 <0.10 0.26 05/13/2015 2.2 12.4 <2.0 L0 5.5 94.0 <0.10 NA 11/04/2015 3.8 2.6 < 1.0 < 0.020 NA 58.0 < 0.10 0.45 MW -9 05/04/2016 15.0 5.3 < 10.0 0.64 NA 51.0 < 0.10 0.095 11/09/2016 1 9.3 10.7 <20.0 0.77 NA 69.0 <0.10 0.76 She deeds 10 250 1 10 250 500 1.5 NL Notaa: mg/L Milligrams per liter CFO Coliform forming units mL Milliliters 15.0 Indicates concentration equal to or above Me respective standard. < 4.0 Indicates constituent concentration was not detected above Me laboratory reporting limit Standards From North Carolina Administrative Code, Title 15A, Subchapter 2L April 1,2013, except total organic carbon and fecal coliform. Total organic carbon standard from Spray Irrigation Permit Number W00004797. Fecal coliform standard is 2L standard for total coliform. Sulfate Removed from list of necessary analyses as of fall 2015 and replaced by total phosphorous. NA Not analyzed NL Indicates no standard limit is set 06032016 -Pace A resampling event was Performed on lune 9, 2016 to investigate nitrateeiceedances in MW -7R and MW -8. One set of samples was analyzed by Pace Analytical Services, and a second set of samples was analyzed by Prism Laboratories. P:\Clement Pappas\Reports\2016 2081.01\14ovember\November 2016j1istoric Analytical Results Page 5 of 5 Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic Compounds Clement Pappas Hendersonville, North Carolina Sample Name Sample Date (mm/dd/Yyyy) . C OO O F (pg/L) y O L U i`- (pg/L) 4) C O a c -I N (Ug/L) iu L P O N c W F (pg/L) 0 L S> (pg/L) L O 0 L ri (pg/L) MW -2R 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 < 0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW -4 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 '< 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 < 0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/09/2016 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW -5 11/05/2002 4,700 980 820 13 24 1.9 11/04/2003 3,500 570 510 < 50 <50 < 50 11/09/2004 580 62 38 < 10 < 10 < 10 11/03/2005 1,900 210 220 < 50 < 50 < 50 11/09/2006 350 74 67 0.61 1.2 < 0.50 05/18/2007 320 47 60 < 0.50 < 0.50 < 0.50 11/13/2007 1,150 217 209 2.0 3.4 1.0 11/18/2008 2,680 534 293 < 25.0 < 25.0 < 25.0 11/05/2009 872 106 125 0.92 < 1.0 < 0.50 11/08/2010 578 107 160 < 2.5 < 5.0 < 2.5 11/15/2011 1,450 124 141 < 2.5 < 5.0 < 2.5 11/07/2012 774 68.8 77.8 < 5.0 < 10.0 < 5.0 11/20/2013 332 65.1 80.5 < 1.2 < 2.5 < 1.2 11/18/2014 121 22.2 26.4 < 0.50 < 1.0 < 0.50 11/04/2015 26.1 2.6 2.9 < 0.50 < 1.0 < 0.50 11/09/2016 141 63.1 75.2 < 0.50 < 1.0 < 0.50 2L Standard 0.7 3 70 100 0.03 7 P:\Clement Pappas\Analytical Data\Water\November 2016_Historic Analytical Results Page 1 of 3 Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic Compounds Clement Pappas Hendersonville, North Carolina P:\Clement Pappas\Analytical Data\Water\November 2016 -Historic Analytical Results Page 2 of 3 d) iu L C C O N O UI d U O O N L O N U O O O` O U a N -Oc `O L L U O 04 U L U N y C C Q cI Sample Date F F 0 W f j i Sample Name (mm/dd/yyyy) (Ng/l) (ug/I) (ug/I) (ug/I) (pg/l) W/O MW -6 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50' < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 3.0 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0,50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 '< 0.50 < 0.50 < 0.50 <,0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/09/2016 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW -7 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 0.79 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW -7R 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/09/2016 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 2L Standard 0.7 3 70 100 0.03 7 P:\Clement Pappas\Analytical Data\Water\November 2016 -Historic Analytical Results Page 2 of 3 Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic Compounds Clement Pappas Hendersonville, North Carolina Notes: Detections This table only includes compounds that were detected above the laboratory method detection limits!nce the sampling event in November 2002. The complete suite of compounds analyzed can be found in the individual analytical reports. Only samples collected during November sampling events were analyzed for volatile organic compounds, in accordance with Spray Irrigation Permit Number WQ0004797. pg/L CD (13 2L Standard From North Carolina Administrative Code, Title 15A, Subchapter 2L, April 1, 2013. 4,700 Indicates an exceedance ofthe 2L standard. O In accordance with the Compliance Evaluation Inspection letter issued by Beverly Price of the DENR, Division C Y N N Y 0 of Water Quality (DWQ) on April 27, 2007, volatile organic compounds and semivolatile organic compounds C were sampled duringthe May 2007 sampling event. Naphthalene C OC C O O N L O L L D O O 0 0 o CV o 0 cLi N ci U ; 0 Sample Date F i`- U Sample Name (mm/dd/yyyy) W/0 I (P9/1) W/O (P9/l) W/1) (pg/0 MW -8 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 < 0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 . 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/09/2016 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW -9 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/09/2016 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 2L Standard 0.7 3 70 100 0.03 7 Notes: Detections This table only includes compounds that were detected above the laboratory method detection limits!nce the sampling event in November 2002. The complete suite of compounds analyzed can be found in the individual analytical reports. Only samples collected during November sampling events were analyzed for volatile organic compounds, in accordance with Spray Irrigation Permit Number WQ0004797. pg/L Micrograms per liter 2L Standard From North Carolina Administrative Code, Title 15A, Subchapter 2L, April 1, 2013. 4,700 Indicates an exceedance ofthe 2L standard. 5/18/2007 In accordance with the Compliance Evaluation Inspection letter issued by Beverly Price of the DENR, Division of Water Quality (DWQ) on April 27, 2007, volatile organic compounds and semivolatile organic compounds were sampled duringthe May 2007 sampling event. Naphthalene Detected in MW -6 for the first time at a concentration of 2.2 pg/L (which is below the 2L standard of 6 pg/L) duringthe November 5, 2002 sampling event. 1,1,2 -trichloroethane - Detected in MW -5 for the first time on November 20, 2010 at a concentration of 8.0 pg/L, which exceeds the North Carolina Interim Maximum Allowable Concentration of 0.6 pg/L. Chloroform Detected for the first time in MW -5 during the November 2011 sampling event at a concentration of 31.3 pg/L, which is below the 2L standard of 70 pg/L. Toluene Detected for the first time in MW -4 during the November 2015 sampling event at a concentration of 0.75 pg/L, which is below the 2L standard of 600 pg/L. P:\Clement Pappas\Analytical Data\Water\November 2016 -Historic Analytical Results Page 3 of 3 Table 3 Current and Historical Groundwater Elevation Measurements Clement Pappas Hendersonville, North Carolina Well Identification Date Measured Depth to Groundwater Top -of -Casing Elevation Top -of -Casing Height Above Ground surface Groundwater Elevation _ (mm/dd/yyM (ft-BTOC) (feet) (feet) (feet) MW -2R 05/24/2006 9.29 2063.00 3.77 2053.71 11/09/2006 6.49 2063.00 3.77 2056.51 05/18/2007 7.94 2063.00 3.77 2055.06 11/13/2007 8.46 2063.00 3.77 2054.54 05/27/2008 8.48 2063.00 3.77 2054.52 11/18/2008 8.50 2063.00 3.77 2054.50 05/28/2009 5.43 2063.00 3.77 2057.57 11/05/2009 6.72 2063.00 3.77 2056.28 05/13/2010 7.36 2063.00 3.77 2055.64 11/08/2010 9.60 2063.00 3.77 2053.40 05/17/2011 7.25 2063.00 3.77 2055.75 11/15/2011 7.86 2063.00 3.77 2055.14 05/17/2012 5.19 2063.00 3.77 2057.81 11/07/2012 7.74 2062.36 3.77 2054.62 05/16/2013 6.86 2062.36 3.77 2055.50 11/20/2013 7.92 2062.36 3.77 2054.44 05/22/2014 7.56 2062.36 1 3.77 2054.80 11/18/2014 8.89 1 2062.36 1 3.77 2053.47 Well abandoned, replaced by MW -9 MW -4 05/15/2002 9.32 2064.60 2.43 2055.28 11/05/2002 9.49 2064.60 2.43 2055.11 05/13/2003 8.20 2064.60 2.43 2056.40 11/04/2003 9.23 2064.60 2.43 2055.37 05/05/2004 9.35 2064.60 2.43 2055.25 11/09/2004 8.61 2064.60 2.43 2055.99 05/17/2005 6.19 2064.60 2.43 2058.41 11/03/2005 9.57 2064.60 2.43 2055.03 05/24/2006 9.60 2064.60 2.43 2055.00 11/09/2006 8.41 2064.60 1 2.43 2056.19 05/18/2007 9.42 2064.60 2.43 2055.18 11/13/2007 9.89 2064.60 2.43 2054.71 05/27/2008 9.78 2064.60 2.43 2054.82 11/18/2008 9.76 2064.60 2.43 2054.84 05/28/2009 7.16 2064.60 2.43 2057.44 11/05/2009 8.53 2064.60 2.43 2056.07 05/13/2010 8.83 2064.60 2.43 2055.77 11/08/2010 9.30 2064.60 2.43 2055.30 05/17/2011 8.97 2064.60 2.43 2055.63 11/15/2011 9.48 2064.60 2.43 2055.12 05/17/2012 7.62 2064.60 2.43 2056.98 11/07/2012 9.32 2063.77 2.43 2054.45 05/16/2013 7.93 2063.77 2.43 2055.84 11/20/2013 8.87 2063.77 2.43 2054.90 05/22/2014 8.70 2063.77 2.43 2055.07 11/18/2014 8.54 2063.77 2.43 2055.23 05/13/2015 9.18 2063.77 2.43 2054.59 11/4/20156.93 2063.77 2.43 2056.84 05/04/2016 8.43 1 2063.77 2.43 2055.34 11/09/2016 9.63 1 2063.77 2.43 1 2054.14 P:\Clement Pappas\Reports\2016 2081.01\November\Table 2 Historic GW Elev Page 1 of 5 Table 3 Current and Historical Groundwater Elevation Measurements Clement Pappas Hendersonville, North Carolina Well Identification Date Measured Depth to Groundwater Top -of -Casing . Elevation Top -of -Casing Height Above Ground Surface Groundwater Elevation (mm/dd/yyyy) (ft-BTOC) (feet) (feet) (feet) MW -5 05/15/2002 8.31 2086.40 3.00 2078.09 11/05/2002 10.20 2086.40 3.00 2076.20 05/13/2003 8.29 2086.40 3.00 2078.11 11/04/2003 9.92 2086.40 3.00 2076.48 05/05/2004 8.75 2086.40 3.00 2077.65 11/09/2004 8.50 2086.40 3.00 2077.90 05/17/2005 8.87 2086.40 3.00 2077.53 11/03/2005 9.70 2086.40 3.00 2076.70 05/24/2006 9.34 2086.40 3.00 2077.06 11/09/2006 8.39 2086.40 3.00 2078.01 05/18/2007 9.16 2086.40 3.00 2077.24 11/13/2007 11.00 2086.40 3.00 2075.40 05/27/2008 9.84 2086.40 3.00 2076.56 11/18/2008 11.59 2086.40 3.00 2074.81 05/28/2009 7.95 2086.40 3.00 2078.45 11/05/2009 8.63 2086.40 3.00 2077.77 05/13/2010 8.87 2086.40 3.00 2077.53 11/08/2010 10.24 2086.40 3.00 2076.16 05/17/2011 8.99 2086.40 3.00 2077.41 11/15/2011 10.58 2086.40 3.00 2075.82 05/17/2012 8.73 2086.40 3.00 2077.67 11/07/2012 9.65. 2085.60 3.00 2075.95 05/16/2013 8.14 2085.60 3.00 2077.46 11/20/2013 9.33 2085.60 3.00 2076.27 05/22/2014 8.57 2085.60 3.00 2077.03 11/18/2014 9.04 2085.60 3.00 2076.56 05/13/2015 8.92 2085.60 3.00 2076.68 11/4/2015 8.12 2085.60 3.00 2077.48 05/04/2016 8.54 2085.60 3.00 2077.06 11/09/2016 11.25 2085.60 3.00 1 2074.35 P:\Clement Pappas\Reports\2016 2081.01\November\Table 2 Historic GW Elev Page 2 of 5 Table 3 Current and Historical Groundwater Elevation Measurements Clement Pappas Hendersonville, North Carolina Well Identification Date Measured Depth to Groundwater Top -of -Casing Elevation Top -of -casing Height Above Ground Surface Groundwater Elevation (mm/dd1wM (ft-BTOC) (feet) (feet) (feet) MW -6 05/15/2002 6.20 2061.90 3.00 2055.70 11/05/2002 6.15 2061.90 3.00 2055.75 05/13/2003 5.43 206L90 3.00 2056.47 11/04/2003 5.85 2061-90 3.00 2056.05 05/05/2004 6.00 2061.90 3.00 2055.90 11/09/2004 5.32 2061.90 3.00 2056.58 05/17/2005 6.10 2061.90 3.00 2055.80 11/03/2005 6.01 2061.90 3.00 2055.89 05/24/2006 6.48 2061.90 3.00 2055.42 11/09/2006 5.71 2061.90 3.00 2056.19 05/18/2007 6.50 2061.90 3.00 2055.40 11/13/2007 7.85 2061.90 3.00 2054.05 05/27/2008 7.01 2061.90 3.00 2054.89 11/18/2008 7.38 2061.90 3.00 2054.52 05/28/2009 5.63 2061.90 3.00 2056.27 11/05/2009 5.74 2061-90 3.00 2056.16 05/13/2010 5.90 2061-90 3.00 2056.00 11/08/2010 5.99 2061.90 3.00 2055.91 05/17/2011 5.85 2061.90 3.00 2056.05 11/15/2011 6.14 2061.90 3.00 2055.76 05/17/2012 5.87 2061.90 3.00 2056.03 11,/07/2012 6.05 2061.17 3.00 2055.12 05/16/2013 5.84 2061.17 3.00 2055.33 11/20/2013 5.96 2061.17 3.00 2055.21 05/22/2014 5.96 2061.17 3.00 2055.21 11,/1$/2014 5.82 2061-17 3.00 2055.35 05/13/2015 6.05 2061.17 3.00 2055.12 11./4/2015 5.18 2061.17 3.00 2055.99 05/04/2016 5.59 2061.17 3.00 2055.58 11/09/2016 7.42 2061.17 3.00 2053.75 R\Clement Pappas\Reports\2016 2081.01\November\Table 2 Historic GW Elev Page 3 of 5 Table 3 Current and Historical Groundwater Elevation Measurements Clement Pappas Hendersonville, North Carolina Well Identification Date Measured Depth to Groundwater Top -of -Casing Elevation Top -of -Casing Height Above Ground Surface Groundwater Elevation (mm/dd/yyyy) (ft-BTOC) (feet) (feet) (feet) MW -7 05/15/2002 10.90 2062.70 3.00 2051.80 11/05/2002 11.35 2062.70 3.00 2051.35 05/13/2003 8.87 2062.70 3.00 2053.83 11/04/2003 10.78 2062.70 3.00 2051.92 05/05/2004 10.80 2062.70 3.00 2051.90 11/09/2004 9.70 2062.70 3.00 2053.00 05/17/2005 10.60 2062.70 3.00 2052.10 11/03/2005 11.09 2062.70 3.00 2051.61 05/24/2006 11.27 2062.70 3.00 2051.43 11/09/2006 9.71 2062.70 3.00 2052.99 05/18/2007 11.02 2062.70 3.00 2051.68 11/13/2007 11.76 2062.70 3.00 2050.94 05/27/2008 11.55 2062.70 3.00 2051.15 11/18/2008 11.63 2062.70 3.00 2051.07 05/28/2009 8.21 2062.70 3.00 2054.49 11/05/2009 9.89 2062.70 3.00 2052.81 05/13/2010 10.44 2062.70 3.00 2052.26 11/08/2010 11.12 2062.70 3.00 2051.58 05/17/2011 10.80 2062.70 3.00 2051.90 11/15/2011 11.43 2062.70 3.00 2051.27 05/17/2012 8.91 2062.70 3.00 2053.79 MW -7R 11/07/2012 12.02 2062.86 3.00 2050.84 05/16/2013 10.29 2062.86 3.00 2052.57 11/20/2013 11.69 2062.86 3.00 2051.17 05/22/2014 11.38 2062.86 3.00 2051.48 11/18/2014 11.25 2062.86 3.00 2051.61 05/13/2015 11.94 2062.86 3.00 2050.92 11/4/2015 8.43 2062.86 3.00 2054.43 05/04/2016 11.08 2062.86 3.00 2051.78 11/09/2016 12.63 2062.86 3.00 2050.23 P:\Clement Pappas\Reports\2016 2081.01\November\Table 2 Historic GW Elev Page 4. of 5 Table 3 Current and Historical Groundwater Elevation Measurements Clement Pappas Hendersonville, North Carolina Well Identification Date Measured Depth to Groundwater Top -of -Casing Elevation Top -of -Casing Height Above Ground Surface Groundwater Elevation elevations (mm/dd/yyyy) (ft-BTOC) (feet) (feet) (feet) MW -8 05/15/2002 10.25 2061.40 3.00 2051.15 11/05/2002 10.35 2061.40 3.00 2051.05 05/13/2003 8.16 2061.40 3.00 2053.24 11/04/2003 10.23 2061.40 3.00. 2051.17 05/05/2004 10.30 2061.40 3.00 2051.10 11/09/2004 8.90 2061.40 3.00 2052.50 05/17/2005 10.08 2061.40 3.00 2051.32 11/03/2005 10.61 2061.40 3.00 2050.79' 05/24/2006 10.60 2061.40 3.00 2050.80 11/09/2006 9.40 2061.40 3.00 2052.00 05/18/2007 10.31 2061.40 3.00 2051.09 11/13/2007 11.09 2061.40 3.00 2050.31 05/27/2008 10.83 2061.40 .3.00 2050.57 11/18/2008 11.11 2061.40 3.00 2050.29 05/28/2009 8.25 2061.40 3.00 2053.15 11/05/2009 .9.22 2061.40 3.00 2052.18 05/13/2010 9.88 2061.40 3.00 2051.52 11/08/2010 10.38 2061.40 3.00 2051.02 05/17/2011 10.27 2061.40 3.00 2051.13 11/15/2011 10.87 2061.40 3.00 2050.53 05/17/2012 8.03 2061.40 3.00 2053.37 11/07/2012 10.45 2060.80 3.00 2050.35 05/16/2013 8.58 2060.80 3.00 2052.22 11/20/2013 10.34 2060.80 3.00 2050.46 05/22/2014 9.79 2060.80 3.00 2051.01 11/18/2014 10.03 2060.80 3.00 2050.77 05/13/2015 10.34 2060.80 3.00 2050.46 11/4/2015 7.21 2060.80 3.00 2053.59 05/04/2016 9.84 2060.80 3.00 2050.96 11/09/2016 11.16 2060.80 3.00 2049.64 MW -9 05/13/2015 6.03 2060.23 1.44 2054.20 11/4/2015 2.89 2060.23 1.44 2057.34 05/04/2016 5.53 2060.23 1.44 2054.70 11/09/2016 1 6.55 1 2060.23 1.44 2053.68 Notes: ft-BTOC Feet below top -of -well casing Top -of -casing MW -5th rough MW -8 top -of -casing elevations based upon a survey by Hill and Associates Surveyors dated elevations January10, 2002 through May 2012. MW -2R and MW -4 top -of -casing elevations based upon differential level measurements made by Altamont Environmental, Inc. on June 26, 2006 through May 2012. The tap -of -casing elevations for the monitoring wells were resurveyed on November 21, 2012 by Wes Cole Land Surveying. The top -of -casing elevations for MW -9 were surveyed on May 29, 2015 by Wes Cole Land Surveying. Groundwater Top of casing minus depth to groundwater. elevations P:\Clement Pappas\Reports\2016 2081.01\November\Table 2 Historic GW Elev Page 5 of 5 2ceAna1j&a1 wxxpscebbs.com November 18, 2016 Brian Gant Altamont Environmental 231 Haywood Street Asheville, NC 28804 RE: Project: Clement Pappas Pace Project No.: 92319070 Dear Brian Gant: Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Enclosed are the analytical results for sample(s) received by the laboratory on November 09, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Lord Patton lorri.pafton@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page t of 37 0 aceAnalXical w»w.panleoa.mrri Project: Clement Pappas Pace Project No.: 92319070 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28a04 (828)264-7176 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 37 aceAnalytical www.pdcelehiroM SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)2547176 Project: Clement Pappas Pace Project No.: 92319070 Analytes Lab ID Sample ID Method Anti Reported Laboratory 92319070001 MW -4 SM 6200B CAH 63 PASI-C SM 2540C MJS1 1 PASI-A SM 9222D KDF1 1 PASI-A EPA 350.1 1993 Rev 2.0 BRJ 1 PASI-A EPA 353.2 WRC 1 PASI-A EPA 365.1 MDW 1 PASI-A SM 4500 -CI -E WRC 1 PASI-A SM 53108 AES2 1 PASI-A 92319070002 MW -5 SM 62008 CAH 63 PASI-C SM 2540C MJS1 1 PASI-A SM 9222D KDF1 1 PAST -A EPA 350.1 1993 Rev 2.0 BRJ 1 PASI-A EPA 353.2 WRC 1 PASI-A EPA 365.1 MDW 1 PASI-A SM 4500 -CI -E WRC 1 PASI-A SM 5310B AES2 1 PASI-A 92319070003 MW -6 SM 62008 CAH 63 PASI-C SM 2540C MJS1 1 PASI-A SM 9222D KDF1 1 PASI-A EPA 350.1 1993 Rev 2.0 BRJ 1 PASI-A EPA 353.2 WRC 1 PASI-A EPA 365.1 MDW 1 PASI-A SM 4500 -CI -E WRC 1 PASI-A SM 53108 AES2 1 PASI-A 92319070004 MW -7R SM 6200B CAH 63 PASI-C SM 2540C MJS1 1 PASI-A SM 9222D KDF1 1 PASI-A EPA 350.1 1993 Rev 2.0 BRJ 1 PASI-A EPA 353.2 WRC 1 PASI-A EPA 365.1 MDW 1 PASI-A SM 4500 -CI -E WRC 1 PAST -A SM 53108 AES2 1 PASI-A 92319070005 MW -8 SM 62006 CAH 63 PASI-C SM 2540C MJS1 1 PASI-A SM 92220 KDF1 1 PASI-A EPA 350.1 1993 Rev 2.0 BRJ 1 PASI-A EPA 353.2 WRC 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 37 aceAnalytical' wwwpacelabs.com SAMPLE ANALYTE COUNT Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Clement Pappas Pace Project No.: 92319070 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 'EPA 365.1 MDW 1 PASI-A SM 4500 -CI -E WRC 1 PASI-A SM 53108 AES2 1 PASI-A 92319070006 MW -9 SM 62008 CRH 63 PASI-C SM 2540C Mist 1 PASI-A SM 9222D KDF1 1 PASI-A EPA 350.1 1993 Rev 2.0 BRJ 1 PASI-A EPA 353.2 WRC 1 PASI-A EPA 365.1 MDW 1 PASI-A SM 4500 -CI -E WRC 1 PASI-A SM 53108 AES2 1 PASI-A 92319070007 Trip Blank SM 62008 CAH 63 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in NII, without the written consent of Pace Analytical Services, LLC. Page 4 of 37 -Pace Analytical m ..peceleb&= ANALYTICAL RESULTS Project: Clement Pappas Pace Project No.: 92319070 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW4 Lab ID: 92319070001 Collected: 11/09/1613:00 Received: 11/09/1614:30 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 62008 Benzene ND ug/L 0.50 1 11112/16 10:08 7143-2 Bromobenzene ND ug/L 0.50 1 11/12/16 10:08 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/12116 10:08 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/12/1610:08 75-274 Bromoform ND ug/L 0.50 1 11/12/16 10:08 75-25-2 Bromomethane NO ug/L 5.0 1 11/12/1610:08 74-83-9 n-Butylbenzene NO ug/L 0.50 1 11/12/16 10:08 104-51-8 sec-Butylbenzene NO ug/L 0.50 1 11/12/16 10:08 135-98-8 tert-Butylbenzene NO ug/L 0.50 1 11/12/1610:08 98-06-6 Carbon tetrachloride NO ug/L 0.50 1 11/12/16 10:08 56-23-5 Chlorobenzene NO ug/L 0.50 1 11/12/16 10:08 108-90-7 Chloroethane ND ug/L 1.0 1 11112/1610:08 75-00-3 Chloroform NO ug/L 0.50 1 11/12/1610:08 67-66-3 Chloromethane ND ug/L 1.0 1 11112/1610:08 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/12/1610:08 9549-8 4-Chlorotoluene ND ug/L 0.50 1 11/12/1610:08 106434 1,2-Dibromo-3-chloropropane NO ug/L 1.0 1 11/1211610:08 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/12/1610:08 12448-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/12/16 10:08 106-934 Dibromomethane NO ug/L 0.50 1 11/1211610:08 74-95-3 1,2 -Dichlorobenzene ND ug/L 0.50 1 11/12/16 10:08 95-50-1 1,3 -Dichlorobenzene ND ug/L 0.50 1 11/12/16 10:08 541-73-1 1,4 -Dichlorobenzene NO ug/L 0.50 1 11/12/16 10:08 106-46-7 Dichlorodifluoromethane NO ug/L 0.50 1 11112/1610:08 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/12/1610:08 75-343 1,2-Dichloroethane ND ug/L 0.50 1 11/12/1610:08 107-06-2 1,1-Dichloroethene NO ug/L 0.50 1 11/12/1610:08 75-354 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/12/1610:08 156-59-2 trans-1,2-Dichloroethene NO ug/L 0.50 1 11/12/16 10:08 156-60-5 1,2-Dichloropropane NO ug/L 0.50 1 11/12/16 10:08 78-87-5 1,3-Dichloropropane NO ug/L 0.50 1 11/12/16 10:08 142-28-9 2,2-Dichloropropane NO ug/L 0.50 1 11/12/1610:08 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/12/1610:08 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/12/1610:08 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/12/16 10:08 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/12/16 10:08 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/12/1610:08 100414 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/12/1610:08 87-68-3 Isopropylbenzene (Cumene) NO ug/L 0.50 1 11/12/16 10:08 98-82-8 Methylene Chloride NO ug/L 2.0 1 11/12/16 10:08 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/1211610:08 1634-044 Naphthalene NO ug/L 2.0 1 11/12/1610:08 91-20-3 n-Propylbenzene NO ug/L 0.50 1 11/12/16 10:08 103-65-1 Styrene NO ug/L 0.50 1 11/12/1610:08 10042-5 1,1,1,2 -Tetrachloroethane ND ug/L 0.50 1 11/1211610:08 630-20-6 1,1,2,2 -Tetrachloroethane ND ug/L 0.50 1 11/12/1610:08 79-345 Tetrachloroethene NO ug/L 0.50 1 11/12/1610:08 127-184 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 37 PaceAnalytical e wwwpacelebccam ANALYTICAL RESULTS Project: Clement Pappas Pace Project No.: 92319070 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW -4 Lab ID: 92319070001 Collected: 11/09/1613:00 Received: 11/09/1614:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1 -Trichloroethane 1,1,2 -Trichloroethane Trichloroethene Trichlorofluoromethane 1,2, 3-Trichloropropane 1,2,4-Trimelhylbenzene 1,3, 5-Trimethylbenzene Vinyl chloride m&p-Xylene o -Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8(S) 2640C Total Dissolved Solids Total Dissolved Solids MBIO 9222D Fetal Coliform AVL Fecal Coliforms 350.1 Ammonia Nitrogen, Ammonia 353.2 Nitrogen, N021NO3 unpres Nitrogen, Nitrate 365.1 Phosphorus, Total Phosphorus 4500 Chloride Chloride 53108 TOC Total Organic Carbon Date: 11/18/2016 10:59 AM Analytical Method: SM 6200B ND ug/L 0.50 ND ug/L 2.0 NO ug/L 2.0 NO ug/L 0.50 NO ug/L 0.50 NO ug/L 0.50 NO ug/L 1.0 NO ug/L 0.50 NO ug/L 0.50 NO ug/L 0.50 NO ug/L 1.0 NO ug/L 1.0 NO ug/L 0.50 93 % 70-130 96 % 70-130 100 % 70-130 Analytical Method: SM 2540C 124 mg/L 25.0 Analytical Method: SM 9222D ND CFU/100 mL 4.0 Analytical Method: EPA 350.1 1993 Rev 2.0 NO mg/L 0.10 Analytical Method: EPA 353.2 NO mg/L 0.020 Analytical Method: EPA 365.1 0.27 mg/L 0.050 Analytical Method: SM 4500 -CI -E 12.2 mg/L 1.0 Analytical Method: SM 5310B 4.3 mg/l- 1.0 1 11/12116 10:08 108-88-3 1 11/12/1610:08 87-61-6 1 11/1211610:08 120-82-1 1 11/12/16 10:08 71-55.6 1 11/12/1610:08 79-00-5 1 11/12/1610:08 79-01-6 1 11/12/1610:08 75-69-4 1 11/1211610:08 96-184 1 11/12/1610:08 95-63-6 1 11/12/1610:08 108-67-8 1 11/12/1610:08 7"14 1 11/12/16 10:08 179601-23-1 1 11/12/16 10:08 95-47-6 1 11/12/16 10:08 17060-07-0 1 11/12/16 10:08 460-004 1 11/1211610:08 2037-26-5 1 11/11/16 14:53 4 11/09/16 15:39 1 11/17/1607:39 766441-7 1 11/11/16 00:00 1 11/11/1623:05 7723-14-0 1 11117/1617:01 16887-00-6 1 11/17/1611:05 744044-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 37 aceAnalj cal wwwpacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Clement Pappas Pace Project No.: 92319070 Sample: MW -5 Lab ID: 92319070002 Collected: 11/09/16 11:15 Received: 11/09/16 14:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua] 6200B MSV Analytical Method: SM 62008 Benzene ND' ug/L 0.50 1 11/12/1610:25 71-43-2 Bromobenzene ND ug/L 0.50 1 11/12/1610:25 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/12/1610:25 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/12/1610:25 75-27-4 Bromoform ND ug/L 0.50 1 11/12/1610:25 75-25-2 Bromomethane ND ug/L 5.0 1 11/12/1610:25 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/12/1610:25 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/12/1610:25 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/12/1610:25 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/12/16 10:25 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/12/1610:25 108-90-7 Chloroethane ND ug/L 1.0 1 11/12/1610:25 75-00-3 Chloroform ND ug/L 0.50 1 11/12/1610:25 67-66-3 Chloromethane ND ug/L 1.0 1 11/12/1610:25 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/12/1610:25 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/12/1610:25 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/12/1610:25 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/12/1610:25 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/12/16 10:25 106-93-4 Dibromomethane ND ug/L 0.50 1 11/12/1610:25 74-95-3 1,2 -Dichlorobenzene ND ug/L 0.50 1 11/12/1610:25 95-50-1 1,3 -Dichlorobenzene ND ug/L 0.50 1 11/12/1610:25 541-73-1 1,4 -Dichlorobenzene ND ug/L 0.50 1 11/12/1610:25 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/12/1610:25 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/12/1610:25 75-34-3' 1,2-Dichloroethane ND ug/L 0.50 1 11112/1610:25 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11112/1610:25 75-35-4 cis-1,2-Dichloroethene 75.2 ug/L 0.50 1 11/12/1610:25 156-59-2 trans-1,2-Dich]oroethene ND ug/L 0.50 1 11/12/1610:25 156-60-5 1,2-Dich]oropropane ND ug/L 0.50 1 11/12/1610:25 78-87-5 1,3-Dich]oropropane ND ug/L 0.50 1 11112/1610:25 142-28-9 2,2-Dichloro propane ND ug/L 0.50 1 11/12/1610:25 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/12/1610:25 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/12/1610:25 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/12/1610:25 10061-02-6 Diisopropy] ether ND ug/L 0.50 1 11/12/16 10:25 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/12/1610:25 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/12/1610:25 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/12/16 10:25 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/12/16 10:25 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/12/16 10:25 1634-04-4 Naphthalene ND ug/L 2.0 1 11/12/1610:25 91-20-3 n-Propy]benzene ND ug/L 0.50 1 11/12/1610:25 103-65-1 Styrene ND ug/L 0.50 1 11/12/1610:25 100-42-5 1,1,1,2 -Tetrachloroethane ND ug/L 0.50 1 11/12/1610:25 630-20-6 1,1,2,2 -Tetrachloroethane ND ug/L 0.50 1 11/12/1610:25 79-34-5 Tetrachloroethene 141 ug/L 0.50 1 11/12/1610:25 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11118/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 37 Pace Analytical Services, LLC ice 2225 Riverside Dr. Asheville, NC 28804 1vawPw8AEamal (828)2547176 ANALYTICAL RESULTS Project: Clement Pappas Pace Project No.: 92319070 Sample: MW -5 Lab ID: 92319070002 Collected: 11/09/1611:15 Received: 11/09/1614:30 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Toluene NO ug/L 0.50 1 11/12/16 10:25 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/12/16 10:25 87-61-6 1,2,4-Tdchlorobenzene NO ug/L 2.0 1 11/12/16 10:25 120-82-1 1,1,1 -Trichloroethane ND ug/L 0.50 1 11/12/1610:25 71-55-6 1,1,2-Tdchloroethane NO ug/L 0.50 1 11/12/1610:25 79-00-5 Trichloroethene 63.1 ug/L 0.50 1 11/12/16 10:25 79-01-6 Trichlorofluoromethane NO ug/L 1.0 1 11/12/1610:25 75-694 1,2,3-Trichlompropane NO ug/L 0.50 1 11/12/1610:25 96-184 1,2,4-Trimethylbenzene NO ug/L 0.50 1 11/12/1610:25 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/12/1610:25 108-67-8 Vinyl chloride NO ug/L 1.0 1 11/12/16 10:25 75-014 m&p-Xylene ND ug/L 1.0 1 11/12/1610:25 179601-23-1 o -Xylene NO ug/L 0.50 1 11/12/1610:25 9547-6 Surrogates 1,2-Dichloroethane-d4 (S) 89 % 70-130 1 11/12/16 10:25 17060-07-0 4-Bromofluorobenzene (S) 95 % 70-130 1 11/12/16 10:25 460-004 Toluene -d8 (S) 99 % 70-130 1 11/12/16 10:25 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 109 mg/L 25.0 1 -11/11/16 14:54 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms NO CFU/100 mL 4.0 4 11/09/16 15:39 360.1 Ammonia Analytical Method: EPA 350.1 1993 Rev 2.0 Nitrogen, Ammonia NO mg/L 0.10 1 11/17/1607:41 766441-7 353.2 Nitrogen, NO2IN03 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 0.42 mg/L 0.020 1 11/10/1623:55 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Phosphorus 0.47 mg/L 0.050 1 11/11/1623:06 7723-14-0 4500 Chloride Analytical Method: SM 4500 -CI -E Chloride 45.0 mg/L 4.0 4 11/17/16 17:36 16887-00-6 63108 TOC Analytical Method: SM 53108 Total Organic Carbon NO mg/L 1.0 1 11/17/16 11:36 744044-0 Date: 11/1812016 10:59 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 37 aceAnalytical e wew.pecelab&= ANALYTICAL RESULTS Project: Clement Pappas Pace Project No.: 92319070 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: Ill Lab ID: 92319070003 Collected: 11/09/1612:00 Received: 11/09/1614:30 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 11/12/1610:42 7143-2 Bromobenzene ND ug/L 0.50 1 11/12/16 10:42 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/12/1610:42 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/12/1610:42 75-274 Bromoform ND ug/L 0.50 1 11/12/1610:42 75-25-2 Bromomethane ND ug/L 5.0 1 11/12/1610:42 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/12/1610:42 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/12/1610:42 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/12/16 10:42 98-06-6 Carbon tetrachloride NO ug/L 0.50 1 11/12/16 10:42 56-23-5 Chlorobenzene NO ug/L 0.50 1 11/12/16 10:42 108-90-7 Chloroethane NO ug/L 1.0 1 11/12/1610:42 75-00-3 Chloroform NO ug/L 0.50 1 11/12/1610:42 67-66-3 Chloromethane NO ug/L 1.0 1 11/12/1610:42 74-87-3 2-Chlorololuene NO ug/L 0.50 1 11/12/1610:42 9549-8 4-Chlorololuene NO ug/L 0.50 1 11/12/1610:42 106434 1,2-Dibromo-3-chloropropane NO ug/L 1.0 1 11/12/16 10:42 96-12-8 Dibromochloromethane NO ug/L 0.50 1 11/12/1610:42 12448-1 1,2-Dibromoethane(EDB) NO ug/L 0.50 1 11/12/1610:42 106-934 Dibromomelhane NO ug/L 0.50 1 11/12/16 10:42 74-95-3 1,2 -Dichlorobenzene NO ug/L 0.50 1 11/12/16 10:42 95-50-1 1,3 -Dichlorobenzene ND ug/L 0.50 1 11/12/16 10:42 541-73-1 1,4 -Dichlorobenzene ND ug/L 0.50 1 11/12/16 10:42 10646-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/12/1610:42 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/12/1610:42 75-343 1,2-Dichloroethane ND ug/L 0.50 1 11/12/16 10:42 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/12/1610:42 75-354 cis-1,2-Dichloroelhene ND ug/L 0.50 1 11/12/1610:42 156-59-2 Vans-1,2-Dichloroelhene ND ug/L 0.50 1 11/12/16 10:42 156-60-5 1,2-Dichloropropane NO ug/L 0.50 1 11/12/1610:42 78-87-5 1,3-Dichloropropane NO ug/L 0.50 1 11/12/1610:42 142-28-9 2,2-Dichloropropane NO ug/L 0.50 1 11/12/16 10:42 594-20-7 1,1-Dichlompropene NO ug/L 0.50 1 11/12/16 10:42 563-58-6 cis-1,3-Dichloropropene NO ug/L 0.50 1 11/12/16 10:42 10061-01-5 trans-1,3-Dichloropropene NO ug/L 0.50 1 11/12/16 10:42 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/12/16 10:42 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/12/16 10:42 100414 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/12/1610:42 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/12/16 10:42 98-82-8 Methylene Chloride NO ug/L 2.0 1 11/12/1610:42 75-09-2 Methyl-terl-butyl ether NO ug/L 0.50 1 11/12/1610:42 1634-044 Naphthalene ND ug/L 2.0 1 11/12/16 10:42 91-20-3 n-Propylbenzene NO ug/L 0.50 1 - 11/12/16 10:42 103-65-1 Styrene NO ug/L 0.50 1 11/12/16 10:42 10042-5 1,1,1,2 -Tetrachloroethane NO ug/L 0.50 1 11/12/1610:42 630-20-6 1,1,2,2 -Tetrachloroethane ND ug/L 0.50 1 11/12/1610:42 79-345 Tetrachloroethene ND ug/L 0.50 1 11/12/1610:42 127-184 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/201610:59 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 37 aceAnalytical - www.paceleDa.wm ANALYTICAL RESULTS Project: Clement Pappas Pace Project No.: 92319070 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)2547178 Sample: MW -6 Lab ID: 92319070003 Collected: 11/09/1612:00 Received: 11/09/1614:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Toluene 1,2,3-Tdchlorobenzene 1,2,4-Trichlorobenzene 1,1,1 -Trichloroethane 1,1,2 -Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Tdmethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o -Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene -d8 (S) 2540C Total Dissolved Solids Total Dissolved Solids 1111810 9222D Fecal Coliform AVL Fecal Coliforms 350.1 Ammonia Nitrogen, Ammonia 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 365.1 Phosphorus, Total Phosphorus 4500 Chloride Chloride 53108 TOC Total Organic Carbon Date: 11/18/2016 10:59 AM Analytical Method: SM 6200B NO ug/L 0.50 NO ug/L 2.0 NO ug/L 2.0 NO ug/L 0.50 NO ug/L 0.50 NO ug/L 0.50 NO ug/L 1.0 NO ug/L 0.50 ND ug/L 0.50 ND ug/L 0.50 NO ug/L 1.0 ND ug/L 1.0 ND ug/L 0.50 92 % 70-130 97 % 70-130 100 % 70-130 Analytical Method: SM 2540C 64.0 mg/L 25.0 Analytical Method: SM 9222D NO CFU/100 mL 10.0 Analytical Method: EPA 350.1 1993 Rev 2.0 0.11 mg/L 0.10 Analytical Method: EPA 353.2 NO mg/L 0.020 Analytical Method: EPA 365.1 0.70 mg/L 0.050 Analytical Method: SM 4500 -CI -E 9.0 mg/L 1.0 Analytical Method: SM 53108 7.1 mg/L 1.0 1 11/12/16 10:42 108-88-3 1 11/12/1610:42 87-61-0 1 11/12/16 10:42 120-82-1 1 11/12/16 10:42 71-55-6 1 11/12/1610:42 79-00-5 1 11/12/1610:42 79411-6 1 11/12/1610:42 75-694 1 11/12/1610:42 96-184 1 11/12/1610:42 95-63-6 1 11/12/16 10:42 108-67-8 1 11/12/1610:42 75-014 1 11/12/16 10:42 179601-23-1 1 11/12/1610:42 9547-6 1 11/12116 10:42 17060-07-0 1 11/12/1610:42 460-004 1 11/12/16 10:42 2037-26-5 1 11/11/16 14:55 10 11/09/16 15:39 1 11/17/1607:42 766441-7 1 11/10/16 23:59 1 - 11/1111623:06 7723-14-0 1 11/17/1617:08 16887-00-6 1 11/17/1611:49 7440440 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 37 `eAna//gy�pp /�����ra • ,ampsewa tam Project: Clement Pappas Pace Project No.: 92319070 Sam01e: MW -7R Parameters Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)2547176 ANALYTICAL RESULTS Lab ID: 92319070004 Collected: 11/09/1610:25 Received: 11/09/1614:30 Matrix: Water Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 62008 Benzene NO ug/L 0.50 1 11/12/1610:59 7143-2 Bromobenzene NO ug/L 0.50 1 11/12/1610:59 108-86-1 Bromochloromethane NO ug/L 0.50 1 11/12/1610:59 74-97-5 Bromodichloromethane NO ug/L 0.50 1 11/12/1610:59 75-274 Bromoform NO ug/L 0.50 1 11/12/16 10:59 75-25-2 Bromomethane NO ug/L 5.0 1 11/12/1610:59 74-83-9 n-Butylbenzene NO ug/L 0.50 1 11/12/1610:59 10451-8 sec-Butylbenzene NO ug/L 0.50 1 11/12/1610:59 135-98-8 tert-Butylbenzene NO ug/L 0.50 1 11/12/1610:59 98-06-6 Carbon tetrachloride NO ug/L 0.50 1 11/12/1610:59 56-23-5 Chlorobenzene NO ug/L 0.50 1 11/12/16 10:59 108-90-7 Chloroethane NO ug/L 1.0 1 11/12/16 10:59 75-00-3 Chloroform NO ug/L 0.50 1 11/12/1610:59 67-66-3 Chloromethane NO ug/L 1.0 1 11/12/1610:59 74-87-3 2-Chlorotoluene NO ug/L 0.50 1 11/12/1610:59 9549-8 4-Chlorotoluene NO ug/L 0.50 1 11/12/1610:59 106434 1,2-Dibromo-3-chloropropane NO ug/L 1.0 1 11/12/1610:59 96-12-8 Dibromochloromethane NO ug/L 0.50 1 11/12/1610:59 12448-1 1,2-Dibromoethane (EDB) NO ug/L 0.50 1 11/12/1610:59 106-934 Dibromomethane NO ug/L 0.50 1 11/12/1610:59 74-95-3 1,2 -Dichlorobenzene NO ug/L 0.50 1 11/12/16 10:59 95-50-1 1,3 -Dichlorobenzene NO ug/L 0.50 1 11/12/16 10:59 541-73-1 1,4 -Dichlorobenzene NO ug/L 0.50 1 11/12/16 10:59 10646-7 Dichlorodifluoromethane NO ug/L 0.50 1 11/12/1610:59 75-71-8 1,1-Dichloroethane NO ug/L 0.50 1 11/12/16 10:59 75-34-3 1,2-Dichloroethane NO ug/L 0.50 1 11/12/16 10:59 107-06-2 1,1-Dichloroethene NO ug/L 0.50 1 11/12/1510:59 75-354 cis-1,2-Dichloroethene NO ug/L 0.50 1 11/12/1610:59 156-59-2 trans-1,2-Dichloroethene NO ug/L 0.50 1 11/12/1610:59 156-60-5 1,2-Dichloropropane NO ug/L 0.50 1 11/12/16 10:59 78-87-5 1,3-Dichloropropane NO ug/L 0.50 1 11/12/16 10:59 142-28-9 2,2-Dichloropropane NO ug/L 0.50 1 11/12/16 10:59 594-20-7 1,1-Dichloropropene NO ug/L 0.50 1 11/12/16 10:59 563-58-6 cis-1,3-Dichloropropene NO ug/L 0.50 1 11/12/16 10:59 10061-01-5 trans-1,3-Dichloropropene NO ug/L 0.50 1 11/12/16 10:59 10061-02-6 Diisopropyl ether NO ug/L 0.50 1 11/12/16 10:59 108-20-3 Ethylbenzene NO ug/L 0.50 1 11/12/1610:59 100414 Hexachloro-1,3butadiene NO ug/L 2.0 1 11/12/1610:59 87-68-3 Isopropylbenzene (Cumene) NO ug/L 0.50 1 11/12/1610:59 98-82-8 Methylene Chloride NO ug/L 2.0 1 11/12/1610:59 75-09-2 Methyl-tert-butyl ether NO ug/L 0.50 1 11/12/1610:59 1634-044 Naphthalene NO ug/L 2.0 1 11/12/1610:59 91-20-3 n-Propylbenzene NO ug/L 0.50 1 11/12/1610:59 103-65-1 Styrene NO ug/L 0.50 1 11/12/1610:59 10042-5 1,1,1,2 -Tetrachloroethane NO ug/L 0.50 1 11/12/1610:59 630-20-6 1,1,2,2 -Tetrachloroethane NO ug/L 0.50 1 11/12/1610:59 79-345 Tetrachloroethene NO ug/L 0.50 1 11/12/1610:59 127-184 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 37 ^^' Pace Analytical Services, LLC 2225 R de C/I���l'V lytiM • Ashev Ile, NC 128804 oww0acablacom (828)2547176 ANALYTICAL RESULTS Project: Clement Pappas Pace Project No.: 92319070 Sample: MW -7R Lab ID: 92319070004 Collected: 11/09/1610:25 Received: 11/09/1614:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 62008 MSV Analytical Method: SM 6200B Toluene NO ug/L 0.50 1 11/12/16 10:59 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/12/16 10:59 87-61-6 1,2,4-Tdchlorobenzene ND ug/L 2.0 1 11/12/16 10:59 120-82-1 1,1,1 -Trichloroethane ND ug/L 0.50 1 11/12/1610:59 71-55-6 1,1,2 -Trichloroethane ND ug/l- 0.50 1 11/12/1610:59 79-00-5 Trichloroethene NO ug/L 0.50 1 11/12/16 10:59 79-01-6 Trichlorofluoromethane NO ug/L 1.0 1 11/12/1610:59 75-694 1,2,3-Trichloropropane NO ug/L 0.50 1 11/12/1610:59 96-184 1,2,4-Trimethylbenzene NO ug/L 0.50 1 11/12/1610:59 95-63-6 1,3,5-Trimethylbenzene NO ug/L 0.50 1 11/12/1610:59 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/12/16 10:59 75-014 m&p-Xylene NO ug/L 1.0 1 11/12/16 10:59 179601-23-1 o -Xylene ND ug/L 0.50 1 11/12/1610:59 9547-6 Surrogates 1,2-Dichloroethane-d4 (S) 93 % 70-130 1 11/12/16 10:59 17060-07-0 4-Bromofluorobenzene (S) 96 % 70-130 1 11/12/16 10:59 460-004 Toluene -d8 (S) 101 % 70-130 1 11/12/16 10:59 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 147 mg/L 25.0 1 11/11/16 14:55 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL 20.0 20 11/09/1615:39 360.1 Ammonia Analytical Method: EPA 350.1 1993 Rev 2.0 Nitrogen, Ammonia ND mg/L 0.10 1 11/17/1607:44 766441-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 12.5 mg/L 0.10 5 11/11/1600:42 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Phosphorus 1.0 mg/L 0.050 1 11/11/16 23:08 7723-14-0 4500 Chloride Analytical Method: SM 4500 -CI -E Chloride 22.7 mg/L 1.0 1 11/17/1617:09 16887-00-6 53108 TOC Analytical Method: SM 5310B Total Organic Carbon 13.0 mg/L 1.0 1 11/17/1612:05 744044-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 37 ceAnalyticat www-0vsleftean Project: Clement Pappas Pace Project No.: 92319070 Sample: MW -8 Parameters Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)2547176 ANALYTICAL RESULTS Lab ID: 92319070005 Collected: 11/09/1609:45 Received: 11/09/1614:30 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual 62008 MSV Analytical Method: SM 62008 Benzene ND ug/L 0.50 1 11/12/16 11:15 71-43-2 Bromobenzene ND ug/L 0.50 1 11/12/16 11:15 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/12/16 11:15 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/12/1611:15 75-27-4 Bromofom ND ug/L 0.50 1 1111211611:15 75-25-2 Bromomethane ND ug/L 5.0 1 11112/1611:15 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/12/16 11:15 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/12/16 11:15 135-98-8 ter[-Butylbenzene ND ug/L 0.50 1 11/12/1611:15 98-06.6 Carbon tetrachloride ND ug/L 0.50 1 11/12/16 11:15 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/12/16 11:15 108-90-7 Chloroethane ND ug/L 1.0 1 11/12/1611:15 75-00J Chloroform ND ug/L 0.50 1 11/12/1611:15 67-66-3 Chloromethane ND ug/L 1.0 1 11/12/1611:15 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/12/1611:15 9549-8 4-Chlorotoluene ND ug/L 0.50 1 11/12/1611:15 106434 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/12/1611:15 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/12/1611:15 12448-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/12/1611:15 106-934 Dibromomethane ND ug/L 0.50 1 11/12/16 11:15 74-95-3 1,2 -Dichlorobenzene ND ug/L 0.50 1 11/12/16 11:15 95-50-1 1,3 -Dichlorobenzene ND ug/L 0.50 1 11/12/16 11:15 541-73-1 1,4 -Dichlorobenzene ND ug/L 0.50 1 11/12/16 11:15 10646-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/12/16 11:15 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11112/1611:15 75-343 1,2-Dichloroethane ND ug/L 0.50 1 11/12/16 11:15 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/12/16 11:15 75-354 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/12/16 11:15 156-59-2 trans-1,2-Dichloroelhene ND ug/L 0.50 1 11/12/16 11:15 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/12/16 11:15 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/12/16 11:15 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/12/16 11:15 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/12/1611:15 563-5" cis-1,3-Dichloropropene ND ug/L 0.50 1 11/12/16 11:15 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/12/16 11:15 10061-02-6 Diisopropyl ether ND ug/L 0.50. 1 11/12/16 11:15 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/12/16 11:15 100414 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/12/1611:15 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/12/16 11:15 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/12/16 11:15 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 - 11/12/16 11:15 1634-044 Naphthalene ND ug/L 2.0 1 11/12/1611:15 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/12/16 11:15 103-65-1 Styrene ND ug/L 0.50 1 11/12/1611:15 10042-5 1,1,1,2 -Tetrachloroethane ND ug/L 0.50 1 11/12/1611:15 630-20-6 1,1,2,2 -Tetrachloroethane ND ug/L 0.50 1 11/12/1611:15 79-345 Telrachloroethene ND ug/L 0.50 1 11/12/1611:15 127-184 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 37 ceAnaVical a nwrpKilmio as ANALYTICAL RESULTS Pace Ana lyticaI Seryices, LLC 2225 Riverside Dr. Asheville, NC 28804 (628)254-7176 Project: Clement Pappas Pace Project No.: 92319070 Sample: MW -8 Lab ID: 92319070005 Collected: 11/09/1609:45 Received: 11/09/161430 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 62008 MSV Analytical Method: SM 6200B Toluene ND ug/L 0.50 1 11/12/16 11:15 108-88-3 1,2,3-Tdchlorobenzene ND ug/L 2.0 1 11/12/16 11:15 87-61-6 1,2,4-Tdchlorobenzene NO ug/L 2.0 1 11/12/16 11:15 120-82-1 1,1,1 -Trichloroethane NO ug/L 0.50 1 11/12/1611:15 71-55-6 1,1,2 -Trichloroethane ND ug/L 0.50 1 11/12/1611:15 79-00-5 Trichloroethene ND ug/L 0.50 1 11/12/16 11:15 79-01-0 Trichlorofluoromethane ND ug/L 1.0 1 11/12/1611:15 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/12/16 11:15 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/12/1611:15 95-63-6 1,3,5-Trimethylbenzene NO ug/L 0.50 1 11/12/1611:15 108-67-8 Vinyl chloride NO ug/L 1.0 1 11/12/16 11:15 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/12/16 11:15 179601-23-1 c -Xylene ND ug/L 0.50 1 11/12/1611:15 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 91 % 70-130 1 11/12/16 11:15 17060-07-0 4-13romofluorobenzene (S) 97 % 70-130 1 11/12/16 11:15 460-00-4 Toluene -d8 (S) 96 % 70-130 1 11/1211611:15 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 333 mg/L 25.0 1 11/11/16 14:55 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms NO CFU/100 mL 4.0 4 11/09/1615:39 350.1 Ammonia Analytical Method: EPA 350.1 1993 Rev 2.0 Nitrogen, Ammonia NO mg/L 0.10 1 11/17/1607:45 766441-7 353.2 Nitrogen, NO2IN03 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 14.3 mg/L 0.020 1 11/10/1623:48 M6 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Phosphorus 0.26 mg/L 0.050 1 11/11/16 23:11 7723-14-0 4600 Chloride Analytical Method: SM 4500 -CI -E Chloride 12.0 mg/L 1.0 1 11/17/1617:10 16887-00-6 5310B TOC Analytical Method: SM 53108 Total Organic Carbon 9.7 mg/L 1.0 1 11/17/1612:36 744044-0 Date: 1111 M01 6 10:59 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 37 aceAnalytical eww.Pacelebe.ove Project: Clement Pappas Pace Project No.: 92319070 Sample: MW -9 Parameters Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Lab ID: 92319070006 Collected: 11/09/1613:20 Received: 11/09/1614:30 Matrix: Water Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene NO ug/L 0.50 1 11/12/16 11:32 7143-2 Bromobenzene NO ug/L 0.50 1 11/12/16 11:32 108-86-1 Bromochloromethane NO ug/L 0.50 1 11/12/1611:32 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/12/1611:32 75-274 Bromofonn ND ug/L 0.50 1 11/12/16 11:32 75-25-2 Bromomethane ND ug/L 5.0 1 11/12/1611:32 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/12/1611:32 10451-8 sec-Butylbenzene ND ug/L 0.50 1 11/12/1611:32 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/12/1611:32 98-06-6 Carbon tetrachloride NO ug/L 0.50 1 11/12/16 11:32 56-23-5 Chlorobenzene NO ug/L 0.50 1 11/12/16 11:32 108-90-7 Chloroethane NO ug/L 1.0 1 11/12/1611:32 75-00-3 Chloroform NO ug/L 0.50 1 11/12/16 11:32 67-66-3 Chloromethane NO ug/L 1.0 1 11/12/1611:32 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/12/1611:32 954941 4-Chlorotoluene ND ug/L 0.50 1 11/12/1611:32 106434 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/12/16 11:32 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/12/1611:32 12448-1 1,2-Dibromoethane(EDB) ND ug/L 0.50 1 11/12/1611:32 106-934 Dibromomethane NO ug/L 0.50 1 11/12/16 11:32 74-95-3 1,2 -Dichlorobenzene ND ug/L 0.50 1 11/12/16 11:32 95-50-1 1,3 -Dichlorobenzene ND ug/L 0.50 1 11/12/16 11:32 541-73-1 1,4 -Dichlorobenzene ND ug/L 0.50 1 11/12/16 11:32 10646-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/12/1611:32 75-71-8 M1 1,1-Dichlorcethane ND ug/L 0.50 1 11/12/16 11:32 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/12/16 11:32 107-06-2 1,1-Dichloroelhene NO ug/L 0.50 1 11/12/1611:32 75-354 ds-1,2-Dichloroethene ND ug/L 0.50 1 11/12/1611:32 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/12/1611:32 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/12/16 11:32 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/12/16 11:32 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/12/16 11:32 59420-7 1,1-Dichloropropene NO ug/L 0.50 1 11/12/1611:32 563-58-6 cis-1,3-Dichloropropene NO ug/L 0.50 1 11/12/1611:32 10061-01-5 trans-1,3-Dichloropropene NO ug/L 0.50 1 11/12/16 11:32 10061-02-0 Diisopropyl ether ND ug/L 0.50 1 11/12/16 11:32 108-20-3 Ethylbenzene NO ug/L 0.50 1 11/12/1611:32 100414 Hexachloro-1,3-butadiene NO ug/L 2.0 1 11/12/1611:32 87-68-3 Isopropylbenzene (Cumene) NO ug/L 0.50 1 11/12/16 11:32 98-82-8 Methylene Chloride NO ug/L 2.0 1 11/12/1611:32 75-09-2 Methyl-tert-butyl ether NO ug/L 0.50 1 11/12/1611:32 1634-044 Naphthalene NO ug/L 2.0 1 11/12/1611:32 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/12/1611:32 103-051 Styrene ND ug/L 0.50 1 11/12/1611:32 10042-5 1,1,1,2 -Tetrachloroethane ND ug/L 0.50 1 11/12/16 11:32 630-20-6 1,1,2,2 -Tetrachloroethane ND ug/L 0.50 1 11/12/16 11:32 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/12/1611:32 127-184 REPORT OF LABORATORY ANALYSIS This report shall not be reprotluced, except in full, Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 37 aceAnalytical e ~..pscNeos.cwn ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Clement Pappas Pace Project No.: 92319070 Sample: MW -9 Lab ID: 92319070006 Collected: 11/09/1613:20 Received: 11/09/1614:30 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Toluene NO ug/L 0.50 1 11/12/1611:32 108-88-3 1,2,3-Trichlorobenzene NO ug/L 2.0 1 11/12/1611:32 87616 1,2,4-Trichlorobenzene NO ug/L 2.0 1 11/12/16 11:32 120-82-1 1,1,1 -Trichloroethane NO ug/L 0.50 1 11/12/16 11:32 71-55-6 1,1,2 -Trichloroethane NO ug/L 0.50 1 11/12/16 11:32 79-00-5 Trichloroethene NO ug/L 0.50 1 11/12/16 11:32 79-016 Trichlorofluoromethane NO ug/L 1.0 1 11/12/1611:32 7569-4 1,2,3-Trichloropropane NO ug/L 0.50 1 11/12/16 11:32 96-184 1,2,4-Trimethylbenzene NO ug/L 0.50 1 11/12/1611:32 9563-6 1,3,5-Trimethylbenzene NO ug/L 0.50 1 11/12/16 11:32 108-67-8 Vinyl chloride NO ug/L 1.0 1 11/12/1611:32 75-014 m&p-Xylene NO ug/L 1.0 1 11/12/16 11:32 179601-23-1 o -Xylene NO ug/L 0.50 1 11/12/1611:32 95476 Surrogates 1,2-Dichloroethane64 (S) 91 % 70-130 1 11/12/16 11:32 17060-07-0 4-Bromofluorobenzene (S) 96 % 70-130 1 11/12/1611:32 460-004 Toluene -08 (S) 102 % 70-130 1 11/12/16 11:32 2037-26-5 2640C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 69.0 mg/L 25.0 1 11/11/16 14:56 M1310 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms NO CFU/100 mL 20.0 20 11/09/16 15:39 350.1 Ammonia Analytical Method: EPA 350.1 1993 Rev 2.0 Nitrogen, Ammonia NO mg/L 0.10 1 11/17/1607:50 766441-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 0.77 mg/L 0.020 1 11/11/1600:01 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Phosphorus 0.76 mg/L 0.050 1 11/11/1623:13 7723-140 4500 Chloride Analytical Method: SM 4500 -CI -E Chloride 10.7 mg/L 1.0 1 11/17/1617:11 16887-006 53108 TOC Analytical Method: SM 5310B Total Organic Carbon 9.3 mg/L 1.0 1 11/17/1612:48 744044-0 Date: 1111812016 10:59 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 37 9PaceAnaly4ical m wvrwpacelebscom ANALYTICAL RESULTS Project: Clement Pappas Pace Project No.: 92319070 Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)2547176 Sample: Trip Blank Lab ID: 92319070007 Collected: 11/09/1600:00 Received: 11/09/1614:30 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 62008 MSV Analytical Method: SM 62006 Benzene NO ug/L 0.50 1 11/12/16 11:49 71-43-2 Bromobenzene NO ug/L 0.50 1 11/12/16 11:49 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/12/1611:49 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/12/1611:49 75-274 Bromoform NO ug/L 0.50 1 11/12/1611:49 75-25-2 Bromomethane NO ug/L 5.0 1 11/12/1611:49 74-83-9 n-Butylbenzene NO ug/L 0.50 1 11/12/16 11:49 104-51-8 sec-Butylbenzene NO ug/L 0.50 1 11/12/16 11:49 135-98-8 tert-Butyl benzene NO ug/L 0.50 1 11/12/1611:49 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/12/16 11:49 56-23-5 Chlorobenzene NO ug/L 0.50 1 11/12/16 11:49 108-90-7 Chloroethane NO ug/L 1.0 1 11/12/1611:49 75-00-3 Chloroform ND ug/L 0.50 1 11/12/16 11:49 67-66-3 Chloromethane ND ug/L 1.0 1 11/12/1611:49 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/12/1611:49 9549-0 4-Chlorotoluene ND ug/L 0.50 1 11/12/16 11:49 106434 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/12/1611:49 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/12/1611:49 12448-1 1,2-Dibromoethane (EDB) NO ug/L 0.50 1 11/12/1611:49 106-934 Dibromomethane NO ug/L 0.50 1 11/12/1611:49 74-95-3 1,2 -Dichlorobenzene NO ug/L 0.50 1 11/12/16 11:49 95-50-1 1,3 -Dichlorobenzene NO ug/L 0.50 1 11/12/1611:49 541-73-1 1,4 -Dichlorobenzene NO ug/L 0.50 1 11/12/16 11:49 10646-7 Dichlorodifluoromethane NO ug/L 0.50 1 11/12/1611:49 75-71-8 1,1-Dichloroethane NO ug/L 0.50 1 11/12/1611:49 75-343 1,2-Dichloroethane NO ug/L 0.50 1 11/12/1611:49 107-06-2 1,1-Dichloroethene NO ug/L 0.50 1 11/12/1611:49 75-354 cis-1,2-Dichloroethene NO ug/L 0.50 1 11/12/1611:49 156-59-2 Vans-1,2-Dichloroethene NO ug/L 0.50 1 11/12/16 11:49 156-60-5 1,2-Dichloropropane NO ug/L 0.50 1 11/12/16 11:49 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/12/1611:49 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/12/16 11:49 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/12/1611:49 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/12/16 11:49 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/12/16 11:49 10061-02-0 Diisopropyl ether ND ug/L 0.50 1 11/12/16 11:49 108-20-3 Ethylbenzene NO ug/L 0.50 1 11/12/1611:49 100414 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/12/1611:49 87-08-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/12/16 11:49 98-82-8 Methylene Chloride NO ug/L 2.0 1 11/12/16 11:49 75-09-2 Methyl-tert-butyl ether NO ug/L 0.50 1 11/12/1611:49 1634-044 Naphthalene NO ug/L 2.0 1 11/12/1611:49 91-20-3 n-Propylbenzene NO ug/L 0.50 1 11/12/16 11:49 103-65-1 Styrene NO ug/L 0.50 1 11/12/1611:49 10042-5 1,1,1,2 -Tetrachloroethane NO ug/L 0.50 1 11/12/1611:49 630-20-6 1,1,2,2 -Tetrachloroethane NO ug/L 0.50 1 11/12/1611:49 79-345 Tetrachloroethene NO ug/L 0.50 1 11/12/1611:49 127-184 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical services, LLC. Page 17 of 37 aceAnalytical www.pscabbs.can ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Clement Pappas Pace Project No.: 92319070 Sample: Trip Blank Lab ID: 92319070007 Collected: 11/09/16 00:00 Received: 11/09/1614:30 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Dual 62008 MSV Analytical Method: SM 6200B Toluene NO ug/L 0.50 1 11/12/16 11:49 108-88-3 1,2,3-Trichlorobenzene NO ug/L 2.0 1 11/12/1611:49 87-61-6 1,2,4-Trichlorobenzene NO ug/L 2.0 1 11/12/16 11:49 120-82-1 1,1,1 -Trichloroethane NO ug/L 0.50 1 11/12/1611:49 71-55-6 1,1,2-Tdchloroethane NO ug/L 0.50 1 11/12/16 11:49 79-00-5 Trichloroethene NO ug/L 0.50 1 11/12/1611:49 79-01-6 Trichlorofluoromethane NO ug/L 1.0 1 11/12/1611:49 75-69-4 1,2,3-Trichloropropane NO ug/L 0.50 1 11/12/16 11:49 96-183 1,2,4-Trimethylbenzene NO ug/L 0.50 1 11/12/1611:49 95-63-6 1,3,5-Trimethylbenzene NO ug/L 0.50 1 11/12/1611:49 108-67-8 Vinyl chloride NO ug/L 1.0 1 11/12/1611:49 75-01-4 m&p-Xylene NO ug/L 1.0 1 11/12/16 11:49 179601-23-1 o -Xylene NO ug/L 0.50 1 11/12/1611:49 9537-6 Surrogates 1,2-Dichloroethane-04 (S) 90 % 70-130 1 11/12/16 11:49 17060-07-0 4-Bromofluorobenzene (S) 94 % 70-130 1 11/12/16 11:49 460-003 Toluene -d8 (S) 100 % 70-130 1 11/12/16 11:49 2037-26-5 Dale: 11/182016 10:59 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 37 aceAnalytical e vrvm<pacelab,xc rn QUALITY CONTROL DATA Project: Clement Pappas Pace Project No.: 92319070 Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)2547176 QC Batch: 336667 Analysis Method: SM 62006 QC Batch Method: SM 6200B Analysis Description: 62008 MSV Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006, 92319070007 METHOD BLANK: 1866910 Matrix: Water Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006, 92319070007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1,2 -Tetrachloroethane ug/L ND 0.50 11/12/1609:34 1,1,1 -Trichloroethane ug/L NO 0.50 11/12/16 09:34 1,1,2,2 -Tetrachloroethane ug/L NO 0.50 11/12/16 09:34 1,1,2 -Trichloroethane ug/L NO 0.50 11/12/16 09:34 1,1-Dichlorcethane ug/L NO 0.50 11/12/1609:34 1,1-Dichloroethene ug/L NO 0.50 11/12/1609:34 1,1-Dichloropropene ug/L NO 0.50 11/12/1609:34 1,2,3-Trichlorobenzene ug/L NO 2.0 11/12/16 09:34 1,2,3-Trichloropropane ug/L NO 0.50 11/12/16 09:34 1,2,4-Trichlorobenzene ug/L ND 2.0 11/12/16 09:34 1,2,4-Trimethylbenzene ug/L ND 0.50 11/12/1609:34 1,2-Dibromo-3-chloropropane ug/L ND 1.0 11/12/1609:34 1,2-Dibromoethane(EDB) ug/L ND 0.50 11/12/1609:34 1,2 -Dichlorobenzene ug/L NO 0.50 11/12/16 09:34 1,2-Dichloroethane ug/L NO 0.50 11/12/1609:34 1,2-Dichloropropane ug/L NO 0.50 11/12/1609:34 1,3,5-Trimethylbenzene ug/L NO 0.50 11/12/16 09:34 1,3 -Dichlorobenzene ug/L NO 0.50 11/12/1609:34 1,3-Dichloropropane ug/L NO 0.50 11/12/16 09:34 1,4 -Dichlorobenzene ug/L NO 0.50 11/12/16 09:34 2,2-Dichloropropane ug/L NO 0.50 11/12/1609:34 2-Chlorotoluene ug/L NO 0.50 11/12/1609:34 4-Chlorotoluene ug/L NO 0.50 11/12/1609:34 Benzene ug/L NO 0.50 11/12/1609:34 Bromobenzene ug/L ND 0.50 11/12/16 09:34 Bromochloromethane ug/L ND 0.50 11/12/1609:34 Bromodichloromethane ug/L NO 0.50 11/12/1609:34 Bromoform ug/L NO 0.50 11/12/1609:34 Bromomethane ug/L NO 5.0 11/12/1609:34 Carbon tetrachloride ug/L NO 0.50 11/12/16 09:34 Chlombenzene ug/L ND 0.50 11/12/1609:34 Chloroethane ug/L NO 1.0 11/12/1609:34 Chloroform ug/L NO 0.50 11/12/1609:34 Chloromethane ug/L ND 1.0 11/12/1609:34 cis-1,2-Dichlorcethene ug/L ND 0.50 11/12/16 09:34 cis-1,3-Dichloropropene ug/L NO 0.50 11/12/16 09:34 Dibromochloromelhane ug/L NO 0.50 11/12/1609:34 Dibromomethane ug/L NO 0.50 11/12/1609:34 Dichlorodifluoromethane ug/L NO 0.50 11/12/1609:34 Diisopropyl ether ug/L NO 0.50 11/12/16 09:34 Ethylbenzene ug/L NO 0.50 11/12/1609:34 Results presented on MIs page are in the units indicated by the "Unita" column except v.Tere an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical services, LLC. Page 19 of 37 aceAnalyticale aww.pecNabsarn QUALITY CONTROL DATA Project: Clement Pappas Pace Project No.: 92319070 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 METHOD BLANK: 1866910 Matrix: Water Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006, 92319070007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Hexachloro-1,3-butadiene ug/L NO 2.0 11/12/1609:34 Isopropylbenzene(Cumene) ug/L ND 0.50 11/12/1609:34 m&p-Xylene ug/L NO 1.0 11/12/1609:34 Methyl-tert-butyl ether ug/L NO 0.50 11/12/1609:34 Methylene Chloride ug/L NO 2.0 11/12/1609:34 n-Butylbenzene ug/L NO 0.50 11/12/16 09:34 n-Propylbenzene ug/L NO 0.50 11/12/1609:34 Naphthalene ug/L ND 2.0 11/12/1609:34 o -Xylene ug/L ND 0.50 11/12/1609:34 sec-Butylbenzene ug/L NO 0.50 11/12/1609:34 Styrene ug/L NO 0.50 11/12/1609:34 tert-Butylbenzene ug/L NO 0.50 11/12/1609:34 Tetrachloroethene ug/L NO 0.50 11/12/1609:34 Toluene ug/L ND 0.50 11/12/16 09:34 trans-1,2-Dichloroethene ug/L ND 0.50 11/12/1609:34 trans-1,3-Dichloropropene ug/L ND 0.50 11/12/1609:34 Trichloroethene ug/L NO 0.50 11/12/1609:34 Trichlorofluoromethane ug/L NO 1.0 11/12/1609:34 Vinyl chloride ug/L NO 1.0 11/12/16 09:34 1,2-Dichloroethane-d4 (S) % 89 70-130 11/12/16 09:34 4-Bromofluorobenzene (S) % 96 70-130 11/12/16 09:34 Toluene-d8(S) % 99 70-130 11/12/16 09:34 LABORATORY CONTROL SAMPLE: Parameter 1866911 Units Spike Conc. LCS Result LCS %Rec % Rec Limits Qualifem 1,1,1,2 -Tetrachloroethane ug/L 50 47.8 96 60-140 1,1,1 -Trichloroethane ug/L 50 46.5 93 60-140 1,1,2,2 -Tetrachloroethane ug/L 50 46.0 92 60-140 1,1,2 -Trichloroethane ug/L 50 44.5 89 60-140 1,1-Dichloroethane ug/L 50 47.2 94 60-140 1,1-Dichloroethene ug/L 50 53.4 107 60-140 1,1-Dichloropropene ug/L 50 47.5 95 60-140 1,2,3-Trichlorobenzene ug/L 50 56.4 113 60-140 1,2,3-Trichloropropane ug/L 50 43.3 87 60-140 1,2,4-Trichlorobenzene ug/L 50 54.1 108 60-140 1,2,4-Trimethylbenzene ug/L 50 49.4 99 60-140 1,2-Dibromo-3-chloropropane ug/L 50 45.4 91 60-140 1,2-Dibromoethane(EDB) ug/L 50 47.3 95 60-140 1,2 -Dichlorobenzene ug/L 50 51.2 102 60-140 1,2-Dichloroethane ug/L 50 40.1 80 60-140 1,2-Dichloropropane ug/L 50 45.5 91 60-140 1,3,5-Trimethylbenzene ug/L 50 48.5 97 60-140 1,3 -Dichlorobenzene ug/L 50 49.7 99 60-140 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/182016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 37 ace Analytical xxw.Gareko>cam QUALITY CONTROL DATA Project: Clement Pappas Pace Project No.: 92319070 LABORATORY CONTROL SAMPLE: Parameter 1866911 Units Spike Conc. LCS Result -CS %Rec % Rec Limits 1,3-Dichloropropane ug/L 50 44.8 90 60-140 1,4 -Dichlorobenzene ug/1- 50 48.1 96 60-140 2,2-Dichloropropane ug/L 50 38.3 77 60-140 2-Chlorotoluene ug/L 50 47.2 94 60-140 4-Chlorotoluene ug/L 50 46.6 93 60-140 Benzene ug/L 50 49.5 99 60-140 Bromobenzene ug/L 50 46.8 94 60-140 Bromochloromethane ug/L 50 46.7 93 60-140 Bromodichloromethane ug/L 50 46.6 93 60-140 Bromoform ug/L 50 45.5 91 60-140 Bromomethane ug/L 50 40.0 80 60-140 Carbon tetrachloride ug/L 50 49.5 99 60-140 Chlorobenzene ug/L 50 46.4 93 60-140 Chloroethane ug/L 50 45.4 91 60-140 Chloroform ug/L 50 44.9 90 60-140 Chloromethane ug/L 50 52.2 104 60-140 cis-1,2-Dichloroelhene ug/L 50 46.4 93 60-140 cis-1,3-Dichloropropene ug/L 50 44.2 88 60-140 Dibromochloromethane ug/L 50 47.9 96 60-140 Dibromomethane ug/L 50 44.9 90 60-140 Dichlorodifluoromethane ug/L 50 53.1 106 60-140 Diisopropyl ether ug/L 50 50.9 102 60-140 Ethylbenzene ug/L 50 48.2 96 60-140 Hexachloro-1,3-butadiene ug/L 50 51.2 102 60-140 Isopropylbenzene (Cumene) ug/L 50 48.9 98 60-140 m&p-Xylene ug/L 100 95.6 96 60-140 Methyl-tert-butyl ether ug/L 50 48.6 97 60-140 Methylene Chloride ug/L 50 53.3 107 60-140 n-Butylbenzene ug/L 50 50.0 100 60-140 n-Propylbenzene ug/L 50 48.9 98 60-140 Naphthalene ug/L 50 53.0 106 60-140 o -Xylene ug/L 50 46.9 94 60-140 sec-Butylbenzene ug/L 50 50.6 101 60-140 Styrene ug/L 50 48.4 97 60-140 tert-Butylbenzene ug/L 50 43.0 86 60-140 Tetrachloroethene ug/L 50 41.2 82 60-140 Toluene ug/L 50 45.7 91 60-140 trans-1,2-Dichloroethene ug/L 50 50.2 100 60-140 trans-1,3-Dichloropropene ug/L 50 43.2 86 60-140 Trichloroethene ug/L 50 46.3 93 60-140 Trichlorofluoromethane ug/L 50 48.0 96 60-140 Vinyl chloride ug/L 50 45.7 91 60-140 1,2-Dichloroelhane-d4 (S) % 89 70-130 4-Bromotluorobenzene (S) % 98 70-130 Toluene-d8(S) % 96 70-130 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)2547776 Qualifiers Results presented on this page are in the units indicated by the "Units' column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 37 aceAnalytical .pacelabsxom Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Clement Pappas Pace Project No.: 92319070 LriBIV:69VISX:IIGU:te69VIS21.1r194NLI94fe1-11*iP, Parameter 92319070006 Units Result 1,1,1,2 -Tetrachloroethane ug/L NO 1,1,1 -Trichloroethane ug/L NO 1,1,2,2 -Tetrachloroethane ug/L NO 1,1,2 -Trichloroethane ug/L NO 1,1-Dichloroethane ug/L NO 1,1-Dichloroethene ug/L NO 1,1-Dichloropropene ug/L NO 1,2,3-Trichlorobenzene ug/L NO 1,2,3-Trichloropropane ug/L NO 1,2,4-Trichlorobenzene ug/L NO 1,2,4-Trimethylbenzene ug/L NO 1,2-Dibromo-3-chloropropane ug/L NO 1,2-Dibromoethane(EDB) ug/L NO 1,2 -Dichlorobenzene ug/L NO 1,2-Dichloroethane ug/L NO 1,2-Dichloropropane ug/L NO 1,3,5-Trimethylbenzene ug/L NO 1,3 -Dichlorobenzene ug/L NO 1,3-Dichloropropane ug/L NO 1,4 -Dichlorobenzene ug/L NO 2,2-Dichloropropane ug/L NO 2-Chlorotoluene ug/L NO 4-Chlorotoluene ug/L NO Benzene ug/L NO Bromobenzene ug/L NO Bromochloromethane ug/L NO Bromodichloromethane ug/L NO Bromoform ug/L NO Bromomethane ug/L NO Carbon tetrachloride ug/L NO Chlorobenzene ug/L NO Chloroethane ug/L NO Chloroform ug/L NO Chloromethane ug/L NO cis-1,2-Dichloroethene ug/L NO cis-1,3-Dichloropropene ug/L NO Dibromochloromethane ug/L NO Dibromomethane ug/L NO Dichlorodifluoromethane ug/L NO Diisopropyl ether ug/L NO Ethylbenzene ug/L NO Hexachloro-1,3-butadiene ug/L NO Isopropylbenzene (Cumene) ug/L NO m&p-Xylene ug/L NO Methyl-tert-butyl ether ug/L NO Methylene Chloride ug/L NO 11I1-1*1111 MS Spike Conc. MSD Spike Conc. MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Thal 20 20 20.2 19.9 101 100 60-140 1 20 20 19.9 19.7 99 98 60-140 1 20 20 19.5 19.6 98 98 60-140 0 20 20 19.6 19.3 98 97 60-140 1 20 20 20.0 19.9 100 100 60-140 0 20 20 21.4 21.8 107 109 60-140 2 20 20 20.2 20.7 101 103 60-140 2 20 20 21.8 20.8 109 104 60-140 5 20 20 18.6 18.1 93 90 60-140 3 20 20 20.9 20.4 104 102 60-140 2 20 20 20.5 20.8 103 104 60-140 1 20 20 18.7 18.7 94 94 60-140 0 20 20 19.9 19.3 100 97 60-140 3 20 20 21.1 21.2 105 106 60-140 1 20 20 17.0 17.1 84 85 60-140 0 20 20 19.6 19.5 98 98 60-140 0 20 20 20.7 20.7 104 104 60-140 0 20 20 20.6 20.7 103 103 60-140 0 20 20 19.0 18.9 95 95 60-140 0 20 20 20.0 20.0 100 100 60-140 0 20 20 16.2 15.8 81 79 60-140 2 20 20 20.5 20.7 103 104 60-140 1 20 20 19.8 20.0 99 100 60-140 1 20 20 20.8 20.7 104 103 60-140 1 20 20 20.2 20.1 101 100 60-140 0 20 20 19.9 20.1 100 101 60-140 1 20 20 20.0 19.7 100 98 60-140 1 20 20 18.5 18.0 93 90 60-140 3 20 20 15.8 14.8 79 74 60-140 6 20 20 21.2 21.5 106 107 60-140 1 20 20 19.8 19.7 99 98 60-140 1 20 20 15.8 16.5 79 82 60-140 4 20 20 19.4 19.3 97 97 60-140 0 20 20 14.3 13.7 71 69 60-140 4 20 20 19.6 19.8 98 99 60-140 1 20 20 18.5 18.7 93 94 60-140 1 20 20 20.1 19.6 100 98 60-140 2 20 20 18.9 19.1 95 96 60-140 1 20 20 8.3 7.9 41 40 60-140 5 M1 20 20 21.2 21.3 106 107 60-140 0 20 20 20.8 20.6 104 103 60-140 1 20 20 19.6 18.7 98 94 60-140 4 20 20 21.1 20.9 105 104 60-140 1 40 40 41.1 40.8 103 102 60-140 1 20 20 19.8 19.9 99 99 60-140 0 20 20 20.5 20.7 103 104 60-140 1 Results presented on this page are In the units Indicated by the "Units" column except where an aitemate ung is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/18/2016 10:59 AM without the wrihen consent of Pace Analytical Services, LLC. Page 22 of 37 (-�2cekwa* MN1Lpac111DS.tAm QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Clement Pappas Pace Project No.: 92319070 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1866912 1866913 MS MSD 92319070006 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conic. Conc. Result Result % Rec % Rec Limits RPD Qual n-Butylbenzene ug/L ND 20 20 20.1 19.8 101 99 60-140 2 n-Propylbenzene ug/L ND 20 20 21.1 21.3 106 106 60-140 1 Naphthalene ug/L ND 20 20 21.2 20.5 106 103 60-140 3 o -Xylene ug/L ND 20 20 20.0 20.2 100 101 60-140 1 sec-Butylbenzene ug/L ND 20 20 20.9 20.8 104 104 60-140 0 Styrene ug/L ND 20 20 20.2 20.0 101 100 60-140 1 tert-Butylbenzene ug/L ND 20 20 18.5 18.2 92 91 60-140 1 Tetrachloroethene ug/L ND 20 20 17.3 17.4 86 87 60-140 1 Toluene ug/L ND 20 20 20.0 20.0 100 100 60-140 0 Vans-1,2-Dichloroethene ug/L ND 20 20 21.1 20.8 106 104 60-140 2 trans-1,3-Dichloropropene ug/L ND 20 20 18.3 17.8 92 89 60-140 3 Trichloroethene ug/L ND 20 20 19.6 19.8 98 99 60-140 1 Trichlorofluoromethane ug/L ND 20 20 19.0 19.4 95 97 60-140 2 Vinyl chloride ug/L ND 20 20 13.8 13.8 69 69 60-140 0 1,2-Dichloroethane-d4 (S) % 91 91 70-130 4-Bromofluorobenzene (S) % 101 99 70-130 Toluene-d8(S) % 99 100 70-130 Results presented on this page are in the units Indicated by the "Units" column except v.Tere an ahemate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 1111812016 1 0:59 AM without the written consent of Pace Analytical Services, LLC. Page 23 of 37 lCeAnalyticale axsepxeN6s xwar QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)2547176 Project: Clement Pappas Pace Project No.: 92319070 QC Batch: 336499 Analysis Method: SM 2540C QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006 METHOD BLANK: 1865998 Matrix: Water - Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 11/11/1614:32 LABORATORY CONTROL SAMPLE: 1865999 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 250 264 106 90-110 SAMPLE DUPLICATE: 1866000 92318780051 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 183 191 4 SAMPLE DUPLICATE: 1866001 92319148004 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 1950 1460 29 D6 Results presented on this page are in the units Indicated by Me "Units' column except where an alternate unit is presentetl to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 11/18/201610:59AM without the written consent of Pace Analytical Services,LLC. Page 24 of 37 aceAnalXical e wwwpacelabs.com QUALITY CONTROL DATA Project: Clement Pappas Pace Project No.: 92319070 QC Batch: 336424 Analysis Method: SM 9222D QC Batch Method: SM 9222D Analysis Description: 9222D MBIO Fecal Coliform -AVL Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006 METHOD BLANK: 1865520 Matrix: Water Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL NO 1.0 11/09/16 15:39 SAMPLE DUPLICATE: 1865521 92319070005 Dup Parameter Units Result Result RPD Qualifiers Fecal Coliforms CFU/100 mL NO NO Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are in the units indicated by the"Units"column except vne an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/18/201610:59AM without the written consent of Pace Analytical Services,LLC. Page 25 of 37 -PaceAnalytical® www pacelabs.cvh QUALITY CONTROL DATA Project: Clement Pappas Pace Project No.: 92319070 QC Batch: 337277 Analysis Method: EPA 350.1 1993 Rev 2.0 QC Batch Method: EPA 350.1 1993 Rev 2.0 Analysis Description: 350.1 Ammonia Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006 METHOD BLANK: 1870478 Matrix: Water Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mglL ND 0.10 1111711607:32 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7178 LABORATORY CONTROL SAMPLE: 1870479 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 4.9 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1870480 1870481 MS MSD MSD 92319652001 Spike Spike MS MSD MS MSD °% Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L. NO 5 5 5.2 5.2 103 104 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1870482 1870483 MS MSD 92318818002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc, Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 13.1 5 5 19.7 19.2 132 121 90-110 3 M1 Results presented on this page are in the units indicated by Me "Unita" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/18/201610:59 AM without the written consent of Pace Analytical Services,LLC. Page 26 of 37 aceAnalytical e wwxpatelabsmm QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr Asheville, NC 28804 (828)254-7176 Project: Clement Pappas Pace Project No.: 92319070 QC Batch: 336471 Analysis Method: EPA 353.2 OC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92319070001,92319070002,92319070003,92319070004,92319070005,92319070006 METHOD BLANK: 1865760 Matrix: Water Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers; Nitrogen, Nitrate mg/L ND 0.020 11/10/1623:45 LABORATORY CONTROL SAMPLE: 1865761 Spike LCS LCS %Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.6 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1865762 1865763 MS MSD 92319070005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 14.3 2.5 2.5 17.3 17.5 120 126 90-110 1 M6 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1866056 1866057 MS MSD 92319338008 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L ND 2.5 2.5 2.3 2.3 91 91 90-110 1 Results presented on this page are in the units Indicated by Me 'Units" column except where an altemate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/18/201610:59AM without the written consent of Pace Analytical Services, 1-1-0. Page 27 of 37 ceAnalXical` tywx:paa�6xarortt QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Clement Pappas Pace Project No.: 92319070 QC Batch: 336486 Analysis Method: EPA 365.1 QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004 METHOD BLANK: 1865898 Matrix: Water Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus mg/L ND 0.050 11/11/16 22:46 LABORATORY CONTROL SAMPLE: 1865899 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Phosphorus mg/L 2.5 2.5 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1865900 1865901 MS MSD 92318583001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conic. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 20.6 2.5 2.5 24.5 23.9 155 132 90-110 2 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1865902 1865903 MS MSD 92318901001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Phosphorus mg/L 0.72 2.5 2.5 3.3 3.3 103 103 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/18/201610:59 AM without the written consent of Pace Analytical Services, LLC. Page 28 of 37 ('!IaceAnalyticalo wmvpacelabs.wm QUALITY CONTROL DATA Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7178 Project: Clement Pappas Pace Project No.: 92319070 QC Balch: 336488 Analysis Method: EPA 365.1 QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total Associated Lab Samples: 92319070005, 92319070006 METHOD BLANK: 1865913 Matrix: Water Associated Lab Samples: 92319070005, 92319070006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus mg/L ND 0.050 11/11/1623:09 LABORATORY CONTROL SAMPLE: 1865914 Spike LCS LCS % Rec Parameter Units Cone. Result %Rec Limits Qualifiers Phosphorus mg/L 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1865915 1865916 MS MSD 92319070005 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 0.26 2.5 2.5 2.8 2.8 103 103 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1865917 1865918 MS MSD 92319199003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Phosphorus ni 1.8 2.5 2.5 4.3 4.4 103 103 90-110 0 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 29 of 37 PaceAnalytical ~..pealabs con QUALITY CONTROL DATA Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Clement Pappas Pace Project No.: 92319070 QC Batch: 337161 _ Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006 METHOD BLANK: 1869588 Matrix: Water Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L NO 1.0 11/17/1616:59 LABORATORY CONTROL SAMPLE: 1869589 Spike LCS LCS - % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.9 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869590 1869591 MS MSD 92319070001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 12.2 10 10 22.9 22.9 107 107 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869592 1869593 MS MSD 92318783003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 1.1 10 10 12.3 12.3 112 112 90-110 0 Mt Resulls presented on this page are In the units Indicated by the "Units" column except where an altemate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/18/201610:59 AM without the written consent of Pace Analytical Services,LLC. Page 30 of 37 0 aceAnalytical ~pecelneacom QUALITY CONTROL DATA Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)2547176 Project: Clement Pappas Pace Project No.: 92319070 QC Batch: 337165 Analysis Method: SM 53108 QC Batch Method: SM 53108 Analysis Description: 531OB TOC Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006 METHOD BLANK: 1869646 Matrix: Water Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L. NO 1.0 11/17/1610:29 LABORATORY CONTROL SAMPLE: 1869647 Spike LCS LCS % Rec Parameter Units Conc. Result %Rec Limits Qualifiers Total Organic Carbon mg/L 25 23.1 92 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869648 1869649 MS MSD 92319070001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result e/ Rec % Rec Limits RPD Qual Total Organic Carbon mg/1- 4.3 25 25 27.3 27.6 92 93 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869650 1869651 MS MSD 92319496009 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L 0.56J 25 25 24.7 24.7 96 96 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit Is presented to the lght or the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 11/18/2016 10:59 AM without the written consent of Pace Analytical services,LLC. Page 31 of 37 ceAnalytical" wsw.P�scnrr QUALIFIERS Project: Clement Pappas Pace Project No.: 92319070 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL- Practical Quantitation Limit. RL - Reporting Limit. Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unfounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chlomethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA Method 8260. N-Nilrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11118/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 32 of 37 PaceAnalytical .pacelahxcvn QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7178 Project: Pace Project No.: Clement Pappas 92319070 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92319070001 MW -4 SM 6200B 336667 92319070002 MW -5 SM 62006 336667 92319070003 MW -6 SM 62006 336667 92319070004 MW -7R SM 62008 336667 92319070005 MW -8 SM 6200B 336667 92319070006 MW -9 SM 6200B 336667 92319070007 Trip Blank SM 6200B 336667 92319070001 MW -4 SM 2540C 336499 92319070002 MW -5 SM 2540C 336499 92319070003 MW -6 SM 2540C 336499 92319070004 MW -7R SM 2540C 336499 92319070005 MW -8 SM 2540C 336499 92319070006 MW -9 SM 2540C 336499 92319070001 MW -4 SM 9222D 336424 92319070002 MW -5 SM 9222D 336424 92319070003 MW -6 SM 9222D 336424 92319070004 MW -7R SM 9222D 336424 92319070005 MW -8 SM 9222D 336424 92319070006 MW -9 SM 9222D 336424 92319070001 MW -4 EPA 350.1 1993 Rev 2.0 337277 92319070002 MW -5 EPA 350.1 1993 Rev 2.0 337277 92319070003 MW -6 EPA 350.11993 Rev 2.0 337277 92319070004 MW -7R EPA 350.11993 Rev 2.0 337277 92319070005 MW -8 EPA 350.1 1993 Rev 2.0 337277 92319070006 MW -9 EPA 350.1 1993 Rev 2.0 337277 92319070001 MW -4 EPA 353.2 336471 92319070002 MW -5 EPA 353.2 336471 92319070003 MW -6 EPA 353.2 336471 92319070004 MW -7R EPA 353.2 336471 92319070005 MW -8 EPA 353.2 336471 92319070006 MW -9 EPA 353.2 336471 92319070001 MW -4 EPA 365.1 336486 92319070002 MW -5 EPA 365.1 336486 92319070003 MW -6 EPA 365.1 336486 92319070004 MW -7R EPA 365.1 336486 92319070005 MW -8 EPA 365.1 336488 92319070006 MW -9 EPA 365.1 336488 92319070001 MW -4 SM 4500 -CI -E 337161 92319070002 MW -5 SM 4500 -CI -E 337161 92319070003 MW -6 SM 4500 -CI -E 337161 92319070004 MW -7R SM 4500 -CI -E 337161 92319070005 MW -8 SM 4500 -CI -E 337161 92319070006 MW -9 SM 4500 -CI -E 337161 92319070001 MW -4 SM 53108 337165 92319070002 MW -5 SM 5310B 337165 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 1111 W01610:59 AM without the written consent of Pace Analytical Services, I.I.G. Page 33 of 37 / AceAnalytical e .pacelabizcom QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7178 Project: Pace Project No.: Clement Pappas 92319070 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92319070003 MW -6 SM 53108 337165 92319070004 MW -7R SM 5310B 337165 92319070005 MW -8 SM 5310B 337165 92319070006 MW -9 SM 53108 337165 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 34 of 37 Laboratory receivingsa les: Asheville Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ ClientNa Projec i Courier: ❑Fed Ex ❑UPS ❑USPS tient ❑ Commercial ❑Pace ❑Other:_ Custody Seal Present? ❑Yes 0 No Seals Intact? ❑Yes ❑No Packing Material-, []Bubble Wrap [I B.06le Bags ❑None ❑Other:_ Thermometer• IR Oun ID: Type? Ice: Wet ❑Blue Correction Factor: 0 C oler Temp Corrected ('C): 0 Temp should be above fre ng to 6'C USDA Regulated Soil ( N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? mv.. nN,. WO# 92319070 11111111111111111 92319010 Date/Initials Person Examining ❑None ❑Samples on ice, cooling processhas be n Biological Tissue Frozen? Dyes [-]No - /A Did samples originate from a foreign source (inter nally, Including Hawag and Puerto Rico)? ❑Yes No Document Name: Document Revised: Sept. 21, 2016 aceAnalytical` Sample Condition Upon Recei t(SCUR) Page 1 of 2 I Document No.: Issuing Authority: ❑N/A F-CAR-CS-033-Rev.01 Pace Quality Office Laboratory receivingsa les: Asheville Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ ClientNa Projec i Courier: ❑Fed Ex ❑UPS ❑USPS tient ❑ Commercial ❑Pace ❑Other:_ Custody Seal Present? ❑Yes 0 No Seals Intact? ❑Yes ❑No Packing Material-, []Bubble Wrap [I B.06le Bags ❑None ❑Other:_ Thermometer• IR Oun ID: Type? Ice: Wet ❑Blue Correction Factor: 0 C oler Temp Corrected ('C): 0 Temp should be above fre ng to 6'C USDA Regulated Soil ( N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? mv.. nN,. WO# 92319070 11111111111111111 92319010 Date/Initials Person Examining ❑None ❑Samples on ice, cooling processhas be n Biological Tissue Frozen? Dyes [-]No - /A Did samples originate from a foreign source (inter nally, Including Hawag and Puerto Rico)? ❑Yes No CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Sample Discrepancy: Project Manager SCURF Review: Project Manager SRF Review: Field Data Required? ❑Yes /M No Date/Time: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, Incorrect containers) Page 35 of 37 Comments/Discrepan : Chain of Custody Present? RfYe, No ❑N/A 1. Samples Arrived within Hold Time? Ye, ONO ❑N/A 2. Short Hold Time Analysis (472 hr.)? es ONO ,❑N/A 3.A(Cl- RushTurnAroundTlmeRequested? ❑Yes o ❑N/A 4. Sufficient Volume?04' ONO N/A S. Correct Containers Used? -Pace Containers Used? Ye y Yes ONO ONO ❑N/A N/A 6. Containers intact? QKes ONO ❑ ltA 7. Samples Field Filtered? ❑Yes No N/A B. Note if sediment is visible In the dissolved container Sample Labels Match COC? -includes Date/Time/10/Analysis Matrix: 03fes [IN. ❑N/A 9. Heads ace in VOA Vials (>5-6mm)? ❑Yes No ❑N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? Yes ONO [IN. ❑N/A ❑N/A 11. CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Sample Discrepancy: Project Manager SCURF Review: Project Manager SRF Review: Field Data Required? ❑Yes /M No Date/Time: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, Incorrect containers) Page 35 of 37 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. *"Bottom half of box is to list number of bottles Projec1 l0# :92319070 PWM: Lip Due Dale: 11/23/16 CLIENT: 83—ALTAMONT Document Name: Document Revised: Sept. 21, 2016 o aceAnalytical Sample Condition Up on Recei tjSCUR Pae 2 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.01 Pace Qualit Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. *"Bottom half of box is to list number of bottles Projec1 l0# :92319070 PWM: Lip Due Dale: 11/23/16 CLIENT: 83—ALTAMONT pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot e R E 2 z E J OM M 2 e 7 of m Z z E J N m < Z d c m 5 J M m Nd V x Z of JI m m yN x S n E 2 III m Z to d N n cE2 N m N `� Z Z o In m n J 9 E v l7 3 z d j E ¢ M a N 9 t E ¢ „`ar, N U' a Y z n J d o III I:1 a x aN IV E d -`u, ei l9 Q n O x E a o T U' a s 4 iJ e� I ll ¢ <¢ Dj E al \ 0 ,� Z o > E lJ > n J ¢ Dj E O1 l9 > z Z d t j E T ly --• 3 a u a y « x u VI i a n w in vEi N Z n o ry N t) ? n d m d L V 'A of l� Lam' ti 1 1 1, iN 2 i u H3 3 4 3 I 1 I i4 3 i 5 q 3 I I 6 I 3 7 I a a 9 SO 11 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot e Page 36 of 37 p CHAIN -OF -CUSTODY I Analytical Request Document FaeeAnalytreal The Chai rof-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. •Ingvnant I av, siviv, nuv rpm I ac armgng Pxs:s NET 3001111-1, M aprt¢ng to I.., r i.. .., N 1 5%1--Ih ban, Oraxus rut Paid -don 30 don. F-ALL-0-Uzurevw. 1 S -May -LW / � of Mmon Section A Section B SectionG i m d Requirad Gent Information: Required Protect Infarnation: Invoice Infarnlelion: Dan P�y:A�+Q Report To. r3 ; �jG1/J Attention G/I 2036974 Address: Copy To: ry'13�;G'✓1 Cier at Name; X11 REGULATORY AGENCY U C �'� l II 1'I /IiF( I _ r c r �. 0 mess' yl F& ./ She I� N NPDES GROUNDWATER - UST RCRA DRINKING WATER OTHER ac`0"nI^ Email To: GAf ry �V rh ,P(!chase Order No.: Phone' - "'o Propd Name: C'I '> A P-v<I Site LOCATED ,t l_ - - S eTne& NS Ma „ ,r� STATE: 1 VEL Requastad Due OaNrtAT: S'� _ /p/- Project Number � ' G � Pxc Pralno u. /f / Requested Analysis Filtered (YIN) Section O 111111 Codes t�' RepalroeImanm a.m nau z+nTR z r coos s = COLLECTED Preservatives > P• Dnnxiry WaMr Dw a u o - WT Water 8 Waste Water WW "� U m L pIPPSnE c. COMPOSITE Eroraaa V . Z Product P j SAMPLE ID SoillSolid SL f wipe r�j O y w y m C o -np7� JA Z. D -9l; 1 AWIPR e Air AR p. a ,n " Sample lDs MUST BE UNIQUE TNsue TS O Z w w r 2 M U s Other OT O X w R Z O U Y 2 O A n N D toz 53 on R i t W DATE TIME MTE TIME _ _ = Is 2 Z E O y R Pate Project No✓ Lab I.D. - WT (> I i 14100 I( X ), X It, VK D Mhr-6 4116 1Z60 ii ' x x A z Y x X' :C X XVI a M w- -1 II R1 102 -Lx I I X 4 K X s Mw- II/Y 16 q`15, it x X XXXXxx I no 15 s M w -A I/9 t3 o II AIX X >< X X 0 U) S 9 t0 1 ism 11 13 ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME ACCEPTED BY I AFFIU.031M DATE TIME SAMPLE CONDITIONS ORIGINAL SAMPLER NAME AND SIGNATURE ti `oz a =_ PRINT Name of SAMPLER: I X E m} i U 2 2 m u mr my - " E rc u m in SIGNATURE of SAMPLER: GATE Sfenal + ( (MWDDIYYtt •Ingvnant I av, siviv, nuv rpm I ac armgng Pxs:s NET 3001111-1, M aprt¢ng to I.., r i.. .., N 1 5%1--Ih ban, Oraxus rut Paid -don 30 don. F-ALL-0-Uzurevw. 1 S -May -LW WWW.ALTA MOMTCMV rOOM MC MTAL.0 ON Well Sampling Log PROJECT NAVE: / _'rt t•{ W 0 " .Ty DATE: ( I Iqlj6_- PROJECT NUMBER: ' GI r WEATHER: $ds SAMPLING PERSONNEL JLiKugw- SAMPLETIME WELL NUMBER: Mi���t-++ WELL DEPTH IN FEET (WD): _ WELL DIAMETER: WATER LEVEL IN FEET (WU: TYPE OF CASING: VC LENGTH OF WATER COLLMN N7 FEE - MEASURING POIN (WD) -(WL) - (LWC) FLUSH MOUNT/ TICK -U ONE CASING VOLUME: i. $ d? RJ $ GALLONS COMMENTS: (LWC) z (WCV) THREE CASING VOLUMES: L.J, S7YT GALLONS ACTUAL VOLU M E PURGED: �I �'7S^ GALLONS WELL CASING VOLUMES (WCV) i-0.041Ga t 2--0 (3al/Ft 3'-0.3SG8VFt &--0.66GaVF: 6"-1.50sVFt 8 -2.6 GO /Ft 11 -58 Gal/Ft PURaE METHOD: LER-DI BAILER -TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: _ SAMPLE METHOC. PPAILERWSP. BAILER -TEFLON DEDICATED PUMP WHALEPUMP GRUNDFCS OTHER: READING TIME bAtfONS TEMP SPECIFIC DISSOLVED pH OXIDATION TURBIDITY COMMENTS PURGED (°C) COND. OXYGEN IS.U.) REDUCTION (NTU) (PS/cm) (mvL) report to POTENTIAL 0.1 S.U. (mV) li29 f� Ii+ I TJ 9 3t 31, 7G ,GJ 2 i7.5- IGI,SS I ff Z 19 -'z. Y{ a 7 'v ?.e-Iz 5,75- `( IIZJ 5 6 T 8 9 LO SAMPLING CCN-AINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 500 mL PLASTIC 250 mL PLASTIC 125 mL PLASTIC 40 mL GLASS 1 L GLASS OTHER PROTECTIVE CASING: • PAD. 61;" LOCK: I%. VEGETATI0fC- ACCESS: Sampling Personnel Signature: r '�, _ - Date: Notes: 'C - degrees Celsus µ5/cm - rlc,o5iernen per centimeter mg/L - mil igrams per lite S.U. - Stehdarc Units MV - mIII0N NTU = nephelometric wrla dity, snits Samples ere enahzei immediately upon collection. .'sTamplatustGW Drilling Forms"Nell sampling Log_wh Page i of I yG M; Its F.1 OPV410161 LIN a r� ww x.n L'rw xu Nic-VI NPM M e nT A L. Well Samplings Log PROJECT NAM E: r f i- :qt PROJECT NUMBER: (j (WEATHER: SAMPLING PERSONNEL: n;tul'rV,. DATE: V s / W LETIME: 1) 1 S WELL NUMBER: /t,? fn, _ r1" WELL DIAMETER: Q•t TYPE OF CASING: P(JC MEASURING POINT: T Q FLUSH MOUNT/ TICK COMMENTS: WELL DEPTH IN FEET (WD): ;6,60_ WATER LEVEL . N FEET ML):_l '. Z S- LENGTH OF WATER COLUMN : '7.35" (WD)-(WL)-(1NC) _ ONE CASING VOLUME: �- S (LWC) x (WCV) THREE CASING VOLUMES: 3,75- ACTUAL VOLUME PURGED: -fZ-Mr 3.7 g" FEET GALLONS GALLONS GALLONS 1'-0,041 GaVF 7-O. 7Gal/Ft WELL CASING VOLUMES (DCV) 3-0.390AVPt 4 -O.66 GeVFt 6'-1.5 Gal/Ft 8 -2.6 Gal Ft 17'=5.83aVIFt PURGE METHOD: ILER-DISP. BAILER -TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: SZ&ILER- BAILER -TEFLON DEDICATEDPUMP 'W'HALEPUMP GRUNDFOS OTHER: _ READIAG TIME GALLONS PURGED TEMP (-C) SPECIFIC COND. (NS/cm) DISSOLVED OXYGEN (mg/!-) pH is. U.) report to O.SS.U. OXIDATION REDUCTION POTENTIAL (mV) TURBIDITY ;NTUI COMMENTS 1 IUSSr (. 7h z s I(Oq I,.93 2ZI i,6'G 4 IIS 1 75- 56 70 6 - - 7 8 10 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYS.S 500 mL PLASTIC 2ED mL PLASTIC 125 mL PLASTIC 40 mL GLASS 1 L GLASS OTHER PR07ECTIVE CASING: C; x PAD:--aLOCK: GIf VEGETATION:—O A ACCESS: Sampling Personnel Signature: Date: Il /(ff� Notes: 'C= degrees Cels as PS/cm - mlar051emen per Centimeter MWL-M1111grema per IIter S.U. -Standard Units mV - miliNcIt NTU - nepnelametrlc turbldl;y units Samples are analyzed immediately L pon collealon. P:%WplatcslGW Drilling FmmeSWell Sampling Log -)ds Page 1 011 • F4,111 IN MITI, 18 low 0 tt- FendHl ?8`v5 !A•..9LC GCI.Jyel WW WaLLT• MYNTe"InnoN M ......... Well Sampling Log PROJECT NAME: Cjtmr FA f_DATE, r' I(jq PROJECT NUMBER: WEATHER SAMPLING PERSONNEL: S SAMPLE TIME: WELL NUMBER: q,� („/- WELL DEPTH IN FEET f WD): (1-4;) WELL DIAMETER: " WATER LEVEL IN FEET (WL): TYPE OF CASING: Pyr LENGTH OF WATER COLUMN : i/ I FEET MEASURING POINT' ^t -k, (WD) - (WL) _ (LWC) FLUSH MOUNT/ TICK -UP ONE CASING VOLUME: ri . 7G Z I GALLONS COMMENTS: ,ac.;Ifd dr, 6NOr -1,0 (LWC)R(WCV) Crap n', Cofv II r ck- 4LM THREE CASING VOLUMES: rbc3 GALLONS ' c 'F ACTUAL VOLUME PURGED: GAL an -ONS WELL CASING VOLUMES (WCV) 1'M0.041Ge 2--0 Gal,/Ft 3'•O383aVFt d=0.66WVPI: 6'=1.5GsVFt 8 =2.6 GaVFt 12-=5.8 Ga1/P1 PURGE METHOD: ILER-DISP BAILER -TEFLON DEDICATED PUMP 'WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: BAILER -D BAILER -TEFLON DEDICATED PUMP 'WHALE PUMP GRUNDFOS OTHER: READING TIME bAHnONS TEMP SPECIFIC DISSOLVED pH OXIDATION TURBIDITY COMMENTS PURGED (TC) COND. OXYGEN (S,U-) REDUCTION (NTU) (PS/cm) (mg/L) report to POTENTIAL 0.1 S.U. (mV) 1 1 iLyo 7,6,,r 173 10. -7 is i, 1.5- 2 if -15- 7 — S wd rr bA,' 4 - 5 T 8 9 10 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 500 mL PLASTIC 250 mL PLASTIC 125 mL PLASTIC aO mi. GLASS 1 L GLASS OTHER PROTECTIVE CASING: PAD:_ [ 2,,�- VEGETATION:r%,, ACCESS: C2({ J�LOCK. Sampling Personnel Signature:,; ;f�\ Date: Notes. 'C=deg-ees lelllUS /-�'-CMeGY, Prl L 4chrafr0f Cr) I15o yS/cm - n• :roSiemen per centimeter / me/L- m::ligrams per lite* P H '� by r^ir� Sl ob;r� cd a -I 6.71 , re-c4(4,Z c D S,U - Stanlaid Unna MV - rt iili4olt NTU - morhelometm turbidity units Samp os are aralyzed rnmedistely upon collection PATemplatestGW Dri Ing FarmstWoll Sampling Leg xis Pago 1 M t .1,9• HAywbpc Sra¢ir. AM Me al -L[. KC 2a SC I_.. _.__.. TC_. Saa.2e1.3311C ra G.aiB.>'RI:J3e1 '�'w ISTII IIOnT[Ny1POV M5 NTAL.Cox Well Sampling Log PRC•JECT NAME: ueclp ` yLI/^ �r: r -r,:n� DATE: PROJECT NUMBER: ? WEATHER: V ; Uear, w„ SAMPLING PERSONNEL: ,Cl S F SAMPLETIME: WELL NUMBER: M � 72- WELL DEPTH IN FEET (WD):—L; ,40 WELL DIAMETER: 2" WATER LEVEL IN FEET It.vu, t Z • L i TYPE OF CASING: hp LEVGTH OF WATER COLUMN' zI. 7 7 FEET MEASURING POINT: TOC (WD)-(WL)I(LWC) FLUSH MOUNT STICK• ONE CASING VOLUME: O • E' �D 1 GAL -ONS COVMENTS: ILWC) x (WCV) p THREE CASING VOL•JMES: Z . al ! B GALLONS ACTUAL VOLUME PURGED: '� �. •S� GALLONS WELL CASING VOLUMES (WCV) 1•-0.041Ga1(F 2•-0. 7GaVFt 3"=0.38GaVFt 4'-0.66GaVFl 6'-1.5Ge1/FI 8 e2.6Gai/Ft 12"-5,8 Ga(/Ft PURGE METHOD- •DISP. BAILER -TEFLON DEDICATED PUMP WHALE PUMP GP.UNDFOS OTHER: SAM'LEMETHOD: ILER- BAILER -TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING TIME _LONE TEMP SPECIFIC DISSOLVED pH OXIDATION TURBIDITY COMMENTS PURGED (•C) COND. OXYGEN (S.U.) REDUCTION (NTU) (IS/cm) (mg/1.) report to POTENTIAL 0.1 S.U. (mV) 1 I Gt 2 f ^.25- 5 YE (� , ,i "Ory 2 l a1w I.0 1G.31t 3G ti S.G. 16c C >II00 S i- 2,0 6:� 8- s. 21 15 9. S 4 '',S 5.3a 23R S oo S,o3 ru-7.1 6 7 S 9 SO SAMPLING CONTAINER NUMBEROFCONTAINERS REOUESTEDANALYSIS 600 mL PLASTIC 250 mL PLASTIC 125 mL PLASTIC 40 mL GLASS 1 L G LASS OTHER PROTECTIVE CASING: UK PAID -._61 LOCK: Oji VEO ETATION:U/f AOCESS: Sam lin Personnel 5i nature: P g g Date: / Notes'. °C=degrees caw as p5/cm - ml^ -o -semen per cerdmeter mg/L • milligrams per Irer S.J. _ Vendard Units mV - mliltvol; NTU - n aphel ometric turbidity mita Samples are ana yzed Immediately upon oollecricn. PATemplates`GW 0riping FormslWoll Sampling Lcg.xh Pawl 0' E p.'v l n t:c rx r .�a Ek r1-'.ir f; k c• c G'< -r —"a Y r- a_. 1a:IIAswOCL ::.r[c-. ,ic n.c d:1. s, n;, zn Eai WW\Y.YLT�NONTPNYrwOXMc.X4 •L.EOM Well Sampling Log PROJECTNAME:-- PROJECTNUMBER: WEATHER: SAMPLING PERSONNEL L S SAM PLE WELL NUMBER: WELL DEPTH IN FEET (WD): l i WELL DIAMETER. .7 WATER LEVEL IN FEETIWL): l'•IE TYPE OF CAS'NG: PVG _ _ LENGTH OF WATER COLUMN . Z -1" FEET MEASURING POI. , (WD)• (WL,t X (LWC) FLLSH MOUNT STICK-UP ONE CASING VOLUME: iJ. H6 S GALLONS COMMENTS: (LWC)x(WCV) 3q 7 THREE CASING VOLUMES: I • GALLONS ACTUALVOLUMEPURGED:^' GALLONS WELL MING VOLUMES (WCV) 1,X0041 t 2' O._ alit 3'-0.380aVFt 4--O.EGGz VFt 6'-1.5Ga/FL 8'-2.6GaVFt _2-X5.8 GsVFt PURGE METHOD: BAILER-DISP. DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: :;LER-TEFLON SAMPLE METHOD: I BAILER•DISP. LER•TEFLON DEDICATED PUMP WHALE PUMP GRUNOFOS OTHER: _ READING TIME TEMP SPECIFIC DISSOLVED pH OXIDATION TURBIDITY COMMENTS PURGED ('C) COND. OXYGEN (S.U.) REDUCTION INTO) (p5/cm) (mg/l.) report to POTENTIAL 0.1S.U. (mV) 1 37 2 Us6 G.5 15.55 s; -v z,qs 6.o3 1 '.� Hqx 5` a ri3'f I, ,�o 583 Z.23 5.8y (i/.0 33.x. a iZts 5 (�.2,N (�'-G ZP39 5 G T —. 8 9 10 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 5CO mL PLASTIC 250 mL PLASTIC 125 mL PLASTIC 40 mL GLASS ILGLASS CT4ER PROTECTIVE CASING U i PAD: U i LOCK:__CJt VEGETATION: /' ACCESS: (:f- :f-Sampling SamplingPersonnel Signature:,,,. Date: Notes: "C = degrees Celsius p5/cm X microSlamen per eenLnreter mg/L X millig-ems per liter S.U. - Standard Unita mV X millivo:t NTU - nephelometric turblcfty units TPles are analyzed immediately upor, CDIIediOn. ro %GW Drilling FpmslWell Sampling Log.xb PROJECT NU WELL DIAMETER: TYPE OF CASING: MEASURING PON FLUSH MOUNT( COMMENTS: KI I • 430 1 kwj IS lin .T.. , i[L tlltl.�bi. tl J'vC 'AC d2H.:P 1 3:L1 W AW.OtT-IOM Ti1YYlY01..1-aT 1.L.COIY Well Sampling Log •iny DATE: I � WEATHER: WATER LEVEL IN FEET (WL): C. s z PURGE METHOD: ILER-D1 .BAILER -TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER SAMPLE METHOD: I ISP. BAILER -TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER. LENGTH OF WATER COLUMN : I. SS FEET (WO) - (WL) - (L%VC) TEMP SPECIFIC (°C) GOND. (pS/cm) �. N OXIDATION REDUCTION POTENTIAL (ni ONE CASINO VOLUME: GALLONS (LWC) x (WCV) THREE CASING VOLUMES: GALLONS ACTUAL VOLUME PURGED. '" Z 5 GALLONS i WELL CASING VOLUMES (WCV) 1--OD41 GaV/2-'0.17 aVFt 3' - :).38 GeVFt 4'•066 Cal/F: 6"'150aVFt B"-2.6Gr C2'-59Ga j"t PURGE METHOD: ILER-D1 .BAILER -TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER SAMPLE METHOD: I ISP. BAILER -TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER. READ'.NG TIME GALLONS PURGED TEMP SPECIFIC (°C) GOND. (pS/cm) DISSOLVED pH OXYGEN (S. U.) (mg/-) report M 0.1 S.tl. OXIDATION REDUCTION POTENTIAL (ni TURBIDITY COMMENTS (NTU) M-23 `ls 2s ,pq (za.Lr lZql 2 ilF 3 iQ0 -2.257 1,= 7S 0)' 0i�, 4 B 6 7 8 9 10 SAMP_ING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 500 mL PLASTIC 250 mL PLASTIC _ 125 mL PLASTIC 4U mL GLASS PROTECTIVE lSamplingPersonnel Signature: /���� ice.. Date: I I (,'/�/ Notes: "C - degrees Celsius VS/cm - micioSlemen per centimeter mg/L - millig-ams per liter S.U.-SAndard Units mY-m liivclt NTU = naphalometrio turbid ;y mils Samples are aoaA•red Immediately upor w ii=or. P:1TunplateskGW Drilling FormslWcll Sampling Log.xls Page 1 of 1 Equipment Documentation & Instrument Calibration Data Sheet Ca!lbreNon Documentallern Protea Name: l I PN't Pnf +�Rnn.: < �'n- 1l'!are � /,'rrr. Person Conductlrg fsllbrauan: �L ¢ rj/PV/ project kumber. O. aGI _ n f Date at Cellbranon: 1!1r116 Equipment oocumentation Equipment of meters used Equlpmem Type lotake measuremeri Saba: Number e4WterleYeI meters, survey Brand Data of Use 150dt Water Lavel 21104 Soanbt 15041 Wmer LB•rel 22754 Sol nlst 15041 Water Love: 150 Te_stwell 150 -ft Drawdown MP30.152 r QED Other Tine r ❑me ("tial: r.� equipment, etc.): Select Turbidimeter. = Hach 2100Q (3/n 15100604 5207) HF Scientific MicroTPW (s/n 200601045) Calibration Standards Instrument Reading Inslvnent Reading Upiratan Delo -._-_ (Hash 2100-1) (HF Sclenhf:c Ail-rOTPW) 20 NTU 100'JU SOO NTU 0.02 NTU 1 10.0 N' 11 1000NTU Cellbrotlon Cab 'Cal: Cal; Cal Jag Cal Ca'. _ _ � Tme: Time: Tim¢ Time: Tine r ❑me ("tial: r.� Cilf VenficetlOn (10 NTUrVeHflceOon: Vedficatbq: u n 1,,:, NA 0 06 yE Time: -_ Time: Time: li Nates. L Electronic equ pmenl calibrated according Whe manufamumr's oFemllon menual. 2. Spec fie Conductivity shouts be calibrated aoaordirg to values represertative of h'srode range. 3. Order of Ca''.bmtlon Is as follows: Specilla Cana umr iy, pH 7, 0114, oft 10, O0, ORP, QC checks. 4. QC Aceeptoi Ranges: r,i'/-0.1 Su. and Speche Conductivity 1" of the true velue. If QC readln3s 8e out or range. the Instrument notes to be recalibrated. 5- - Indicates Iran 0 QC check most be performed In the morning, ererhoon, and the end of the day. or every few hours. 6.1e ndicares to choaae a Speoft Condu/cutiv,ity buffer of 1413, 447, 84, or 23 mS which Is dowst Ic historical readings from the proem iocatlan. 4 Re atTaTdawa\OrvuMnba1e lwltdne FQ'hrViom4w w6xrlce wmnr\Gtlxalon Cela 6�roo1 ^SI eSB aev9 Pegs lof'. YSI 556 MUItlparometer Meter (s/n 12L101057) Instru nlRNOings Cellbrotlon ,d1 :eLt Expiration Dale nissmvmt ox)ger ("tial: r.� Cilf mmHg7616Q Time: Ci' 7ri NA PH 7 SX. repo:' Ic C.1 ,ilial; pHmV:Cal: pHmV T'me: PH 4 S.U. report 1a Q. Initial: Initial: ' pHmV: pHmV: -_— - Cal: pHmV: i�L Cal: Gf pHmV: 91 ITme,,, PH 10 S.U. report to Tme: 0.15.U. 9, AM AM Time: Mesa! MIG Day TIN; (Teck: PM Time: Chauk: aii QC PH 7 S.U. Pon Spec. Caird. lnalai: Cal: Time: - 4S/ar_•-. q 6 3 _�S,Ls_. QC: _.__ M AM Time: Meas: — -- Mid D6Y me: _ Chedc PN TImn:h. 16m --k:- -------- n✓���Q4 1.�LJ iS/cm Sr) 31 q� OPP 240 mV Initial: 3N I (Cal; 0E2. Time: mo Nates. L Electronic equ pmenl calibrated according Whe manufamumr's oFemllon menual. 2. Spec fie Conductivity shouts be calibrated aoaordirg to values represertative of h'srode range. 3. Order of Ca''.bmtlon Is as follows: Specilla Cana umr iy, pH 7, 0114, oft 10, O0, ORP, QC checks. 4. QC Aceeptoi Ranges: r,i'/-0.1 Su. and Speche Conductivity 1" of the true velue. If QC readln3s 8e out or range. the Instrument notes to be recalibrated. 5- - Indicates Iran 0 QC check most be performed In the morning, ererhoon, and the end of the day. or every few hours. 6.1e ndicares to choaae a Speoft Condu/cutiv,ity buffer of 1413, 447, 84, or 23 mS which Is dowst Ic historical readings from the proem iocatlan. 4 Re atTaTdawa\OrvuMnba1e lwltdne FQ'hrViom4w w6xrlce wmnr\Gtlxalon Cela 6�roo1 ^SI eSB aev9 Pegs lof'. GW -59A COMPLIANCE REPORT FORM Permit # WQ0004797 (.Vulandt ). re each manitaring period Irhh GO' -Sy fanru.) I Enter date monitoring results were due. (12/31/2016) Will this monitoring report (GW -59 and GW -59A) YES NO be submitted after the established due date? YES X NO 2 Was any required information missing on the CW -59 report forms? - IF the answer to question 1 or 2 is "YES', list in the space provided below the well identification number)'s) and explain the problems encountered in obtaining tho required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO Identification plate, wren overgrown, eta.)? (%the answer is "Yes", contacl the Regional Ofcejor guidmrre. X 4 Are any monitored constituents equal to or above the established standards? V NO If the answer to question 4 is 'NO', skip to section 8. If the answer to question 4 I "YES" list the affected wells individually with constifuenf(s) and concentrations) exceeding standards in the space provided below: MW -8: Nitrate -14.3 mg/L: MW8 Tetrachlorethene = 141 ug/l, Trichloroethene = 63.I yell, as-12-0Ichbraethene - 752 pelt; MW -7R: Total Organic Carbon - no melt, Nitrate -12.5 mg/L Total Organic Carbon Limit- 10 mg/0 Nitrate limn - to melt; Tetrdchlomethene limit - 0.7 ug/q trichloroethene limit = 3 ug/LI Cis-1,2-dichloroethene limn - 70 per 5 For the constituents Identified In question 4 above, have standards been exceeded previously for the YES NO same constituent(s) In the same well(s) In the last two years? X If the answer to question 5 is "NO" skip to section 8. If the answer to question 5/s "YES", list in the space provided below, each well with constiluent(s) exceeding standards, concentrations) reported, and sample collection date for each occurrence (for the last two years). Total Organic Carbon (emit - 30 mg/q-5/13/2015: MW -5 =1e] melt,11/18/2014: MW$ -54.0 melt; 5/22/2014: MW -8-17.6 ani 5/4/2016: MW -7R-13.5 mg/l, 11/15/14: MW -711-19.1 mg/L Tetrachloroethene (limit- 0.7 ug/q-11/35/2014: MWS - 121 ug/L; 11/4/2015: MW -5" 261 ug/L Trichloroethene (Ilmd-3 pg/IT-11/18/2014: Mws - 22.2 ug/1- gJLNitrate Nitrate(limit = SO mg/q-5/4/2016: MW -7R -112 melt MW -8 = 19.1 mg/LI 6/9/2038: MW -7R -10.9 mgr4 MW a • 26.3 me/L. 6 Are the monitoring wells listed in section 6 located at or beyond the review boundary? YES NO If the answer Is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer Is "NO", monitoring wells maybe Improperly located; contact the Regional Office. MW -5 is upgradlent and outside of the review boundary. MW -7R and MW -8 are beyond and downgradient of the review boundary. 7 is the permittee implementing previously approved actions required by the Division Involving this YES NO groundwater quality problem? _ If the answer to question 7 is "YES" describe those actions in the space provided below. X If the answer to question 7 I "NO", contact the Realonal Office within 90 days: an evaluation may be ralaoired to determine the impact the waste disposal system Is having at the review and corrijbilainic boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation, fines, and/or penalties. TotMehlomethen , trlchloorthene, and cis-1,2-dicboroetbene have been defected in MW -5 during almost every November sampling event since November 2002. The conten rations of these VOCs have been treating downward since Me initial detection In 2002, with occasional minor spikes in dab. Total Organic Carbon (TOC), voc. and SVOC analyses were completed for all samples during Me May 2007 groundwater sampling event TOC concenlre0ons are not attributable to voca or svocs and are possibly naturally occurring. Nitrate concentrations twiddled the groundwater standard in MW -7R and MW -8 for We first time In May, 2016. The high concentrations of nitrate are likely attributable to occasional flooding from the stream adjacent to these monitoring wells and/or W an adjacent property. g The person completing this portion (GW -59A) of the monitoring report should sign below and submit this form with GW -59 forms for required wells to the address provided at the top of the current G W-59 form. I hereby acknowle a that the abov formatio s evaluated and the Information submitted in this report (Complia a -69 I true a co plate to the best of my knowledge. 2 AP"M utb zed. Agent) Data GW -59A 1218/2003 SUBMIT FORM ON YELLOW PAPER ONLY =R QUALITY MONITORING: REPORT FORM TY INFORMATION Please Print Clearly or Type Name: Clement Pappas Name (if different): Address: 125 Industrial Park dersonville s'a NC 28792 County Henderson act Person: Mr. Blake Kehoe Telephone#: 828-693-0711 Location/Site Name: Irrigation Area No. of wells to be sampled: 6 YA1tTMENT OF ENVIRONMENT a NATURAL RESOURCES 'ISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT 7 MAIL SERVICE CENTER, RALEIGH, NO 27699-1617 Phone: 919-807-6306 !RMIT Number: Expiration Date: 8/31/202 n -Discharge WQ0004797 UIC IDES Other PE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery IN Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: - - -(--- ) WELL ID NUMBER (from Permit : MW -4 sample collected: 11/9/2016 FIELD ANALYSES: mg/L If WELLDate WAS Well Depth: 18 -2 -aft. Well Diameter: 2 in. pH o0400: 5. 76 units Temp. 000to: 16 . 72 °C Coliform: MF Total 31504 DRY at Depth to Water Level 82546: 9 , 6 3ft. below measuring point Screened Interval: 8*ft. tc!L6_1*ft. Spec. Cond. 00094: 186 µMhos WrsleSamples) time of Measuring Point is 2 . 43 ft. above land surface Relative M.P. Elevation: 2063.77 ft. Odor none AI - Aluminumoilos sampling, Volume of water pumped/bailed before sampling: 4.75 gallonsa`zaenea incerval to relac," to land surface Appearance units check Samples for metals were collected unfiltered: El YES El NO and field acidified: ❑YES El NO 4.3 mg/L Ca - Calcium 00916 here: ❑ Its sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services IRAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Coliform: MF Fecal 31616 <4 0 /100mL Nitrate (NOS) as N 00620 <0 . 020 Till Coliform: MF Total 31504 /100ml- Phosphorus: Total as P ooses 0.27 mg/L (Note: Use MPNmethod for highly WrsleSamples) Orthophosphate 70507 mg/L solved Solids:TotaI70300 124 mg/L AI - Aluminumoilos mg/L pH (Lab) 00403 units Be - Barium 01007 ug/L TOC ooseo 4.3 mg/L Ca - Calcium 00916 mg/L Chloride 00940 1 2 - 2 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L Phenol 32730 ug/L Fe - Iron 01045 ug/L Sulfate 00945 mg/L Hg - Mercury 71900 ug/L ecific Conductance 000gs µMhos K - Potassium 00937 mg/L Total Ammonia ooslo <0-10 mg/L Mg - Magnesium 00927 mg/L g (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Tale) Mn -Manganese 01055 ug/L TKN as N 00625 rl Ni - Nickel 01067 ug/L For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: Pb - Lead olo51 Zn - Zinc 01092 Certification No. 3 7 712 ug/L mg/L 49FC 419 Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? ® Yes (1) ❑ No (0) VOC 7873 , method # 5200 method # method # method # mg/L Effluent Total imee (or Autnonzed Agent) Name and Tale - Please print or type✓ Signator ennittee ulho reed Agent) GW -59 Rev. 8/2013 mg/L VOC Removal SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Facility Name: Clement Pappas Permit Name (if different): Facility Address: 125 Industrial Park Hendersonville Ismao NC 28792 county Henderson Contact Person: Mr. Blake Kehoe Telephone#: 828 - 693 - 0711 Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 PARTMENT OF ENVIRONMENT & NATURAL RESOURCES 1SION OF WATER RESOURCES- INFORMATION PROCESSING UNIT 7 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-907-6306 .RMIT Number: Expiration Date: 8/31/202 n -Discharge WQ0004797 UIC -DES Other 'PE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery 12 Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: - -- ----from- WELL ID NUMBER (from Permit): MW -5 Date sample collected: 11/9/2016 FIELD ANALYSES: units KWELL WAS Well Depth: 18 r oft• Well Diameter: 2 in. pH 00400: 4 . 79 units Temp. 000lo: 15 . 72 eC Arsenic 01002 DRY at Depth to Water Level 82546: ft, below measuring point �??� 9 P Screened Interval: 9 * 19 * _ft. to ft. Spec. Cond. 00094: 185 µMhos ug/L time of Measuring Point is 3 . 0 0 ft. above land surface Relative M.P. Elevation: 2085.60 ft. Odor 000ee: none Total Ammonia oo6lo sampling, Volume of water pumped/bailed before sampling: 3.75 gallons •acreened interval ie relative to land surface Appearance Mg - Magnesium 00927 check Sam -les for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO Ni- Nickel 01067 un/1 here: ❑ Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NOJ as N 00615 mg/L Coliform: MF Fecal 31616 <4 . 0 /1OOmL Nitrate (NO3) as N oo62o 0.42 mg/L Coliform: MF Total 31504 /10OmL (Nola: Use MPN memod for highly wrEid samples) Ived Solids:Total 70300 109 mg/L pH (Lab) 00403 units TOC 00680 <1 . 0 mg/L Chloride 00940 45.0 mg/L Arsenic 01002 ug/L Grease and Oils 00552 mg/L Phenol 32730 ug/L Sulfate 00945 mg/L ific Conductance 00095 µMhos Total Ammonia oo6lo <0 - 10 mg/L (Ammonia Niavg,,m NH,.. W. Am nia Nitrogen, Tom9 TKN as N 00625 mg/L For Remediation Systems Only (Attach Lab Reports): Phosphorus: Total as P 00665 0.47 mg/L Orthophosphate 70507 mg/L Al - Aluminum 01105 mg/L Ba - Barium 01007 ug/L Ca - Calcium 00916 mg/L Cd - Cadmium 01027 ug/L Chromium: Total 01034 ug/L Cu - Copper 01042 mg/L Fe - Iron 01045 ug/L Hg - Mercury 71900 ug/L K - Potassium 00937 mg/L Mg - Magnesium 00927 mg/L Mn - Manganese oloss ug/L Ni- Nickel 01067 un/1 Influent Total VOCs: ma/L Pb - Lead o1oe1 Zn - Zinc 01092 Certification No. 37712 ug/L mg/L Other (Specify Compounds and Concentration Units): fC 9 e2016 C ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? ® Yes (1) ❑ No (0) VOC7873 ,method# Fsnn method # method # method # Effluent Tntal Vr1Cr, VOC Removal% GW -59 Rev. 812013 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: as : : DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES ., DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM . 1617 MAIL SERVICE CENTER, RALEIGH. NC 27699-1617 Phone: 919-907-6306 FACILITY INFORMATION Please Pnnt Cleady or Type PERMIT Number: Expiration Date: 8/31/2020 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC NPDES Other Permit Name (if different): Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED ❑Lagoon EJ Remediation: Infiltration Gallery Hendersonville (stroW NC 28792 count Henderson (cny) (stael (Zip)y ® Spray Field ❑ Remediation: Contact Person:. Mr. Blake Kehoe Telephone#: 828 -693 - 0 711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Perot) SAMPLING INFORMATION MW -6 If WELL WELL ID NUMBER (from Permit): Date sample collected: 11/9/2016 FIELD ANALYSES: WAS Well Depth: 11 _ 5aft. - Well Diameter:. 2 in. pH 00400: 5 . 31 units Temp. 000to: 17 . 05 °C DRY at Depth to Water Level 92546: 7 - 42 ft. below measuring point Screened Interval: 5" ft. to 10 * ft. Spec. Cond. 00094: 88 µMhos time of Measuring Point is 3 . 0 0 ft. above land surface Relative M.P. Elevation: 2061. 17 ft. Odor 00045: none sampling,check Volume of water um ed/bailed before sampling: 1 . D P P9 allon5ecreened interval is relative to land surface Appearance here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO x LABORATORY INFORMATION Date sample analyzed: varies; see analytical report LaboratoryName:-Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead oiosl /L u /L ug Coliform: MF Fecal 31616 . 0/100mL Nitrate (NOS) as N 00620 <0. 020 mg/L Zn mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P00665 0.70 mg/L (Nore: Use MPN nathod for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 64.0 mg/L AI - Aluminum 01105 mg/L PH (Lab) 00403 units Be - Barium 01007 ug/L TOC o0690 7.1 mg/L Ca - Calcium 00916 mg/L19 2��u Chloride 00940 9.0 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L E Grease and Oils 00552 mg/L - Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 _ ug/L Lab Report Attached? ® Yes (1) ❑ No (0) pecific Conductance D0095 µMhos K - Potassium 00937 mg/L VOC 7973 , method # 6200 Total Ammonia 00610 0.11 mg/L Mg - Magnesium 00927 mg/L , method # (Anrronie Nitrogen; NH3 as N; Ammonia Nitrogen, TOMO Mn - Manganese 01o55 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L , method # ror Remediation Systems Only (Attach Lab Reports) GW -59 Rev. B/2013 Influent Total VOCs: mg/L Effluent Total mg/L VOC Removal% 6 SUBMIT FORM ON YELLOW PAPER ONLY 7 a a , DEPARTMENT OF ENVIRONMENT 9, NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: a as a DIVISION OF WATER RESOURCES- INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone:919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 8/3172u2u Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): - NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (shore" NC 28792 County Henderson ❑ Lagoon 9 ❑ Remediation: Infiltration Gallery (cry) (state) (zip) IR Spray Field ❑ Remediation: Contact Person: Mr. Blake Kehoe Telephone#: B28-693 -0711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: _. .....-...-...- _. ., MW -7R WELL ID NUMBER (from Permit): Date sample collected: 11/9/2016 FIELD ANALYSES: mg/L If WELL WAS Well Depth: 17 _ 7 nft. Well Diameter: 2 in. pH 00400: 5_03 units Temp. 000lo: 15.34'C Coliform: MF Total 31504 DRY at Depth to Water Level 92546: 1 2 - F 3 ft. below measuring point Screened Interval: 5 ft.* to 1511L* Spec. Cond. 00094: 239 µMhos time of Measuring Point is 3 . 0 0 R. above land surface Relative M.P. Elevation: 2062.86 R. Odor 000es: none AI - Aluminum 01105 sampling, Volume of water um ed/bailed before sampling: 2 . 5 gallon P P P 9� 9 a`=eenea interval ie retec�ve to land surface Appearance ug/L check here: Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: F1 YES F-1 No mg/L Chloride 00940 22.7 mg/L ite sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services \RAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Coliform: MF Fecal 31616 <20.0 /100mL Nitrate (NO3) as N oo6m 12.5 mg1L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 1.0 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L solved Solids:Total 70300 147 mg/L AI - Aluminum 01105 ni pH (Lab) 00403 units Be - Barium 01007 ug/L TOC oomo 13 .0 mg/L Ca - Calcium 00916 mg/L Chloride 00940 22.7 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 ni Cu - Copper 01042 mg/L Phenol 32730 ug/L Fe - Iron 01045 ug/L Sulfate 00945 mg/L Hg - Mercury 71900 ug/L eciFic Conductance 00095 µMhos K - Potassium 00937 mg/L Total Ammonia oo6lo <0-10 mg/L Mg - Magnesium 00927 mg/L (Aovnonie Nitrogen: NH3 as N: Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L TKN as N 00625 mg/L Ni - Nickel 01067 ug/L For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: Pb - Lead o1o51 Zn - Zinc olo92 Certification No. 37712 ug/L mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? ❑ Yes (1) ® No (0) VOC 7873 , method # 020o method # method # method # mg/L Effluent Total VOCs: ma/L VOC RPrnnVal% GW -59 Rev. 8/2013 SUBMIT FORM ON YELLOW PAPER ONLY r � e e , utPAKI MENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: as a DIVISION OF WATER RESOURCES- INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-007-6306 FACILITY INFORMATION PleasePriintClearly-Type PERMIT Number: Expiration Date: 8/31/2(J20 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (SaeeU NC 28792 County Henderson ❑ Lagoon (cayl I..) (tip)g El Remediation: Infiltration Gallery ® Spray Field ❑ Remediation: Contact Person: Mr. Blake Kehoe Telephone#: 828 — 693 — 0711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation area No. of wells to be sampled: 1. 6 ❑ Water Source Heat Pump ❑ Other: _. .. _. _..-_.-._............. WELL ID NUMBER (from Permit): MW -8 Dale sample collected: 11/9/2016 FIELD ANALYSES: Nitrite (NOO as N 00615 If WELL WAS Well Depth: 13_9-4 Well Diameter: 2 in, pH 00400: 6.12 units Temp. 000lo: 14.66'C Nitrate (NO,) as N oo6zo DRY at Depth to Water Level 82546: 11 . l Eft. below measuring point Screened Interval: 3 ft- to 13 ft* Spec. Cond. 00094: 626 µMhos Phosphorus: Total as P oo66e time of Measuring Point is 3 . 0 0 ft. above land surface Relative M.P. Elevation: 2060. ao ft. Odor 000ss none Orthophosphate 70507 sampling, Volume of water pumped bailed before sampling: 1 .5 0 *eereened interval is relative to land surface gallons Appearance Al - Aluminum o11o5 check Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO units here:❑ tte sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services \RAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NOO as N 00615 mg/L Coliform: MF Fecal 31616 <4 . 0 /10OmL Nitrate (NO,) as N oo6zo 14.3 mg/L Coliform: MF Total 31504 /10OmL Phosphorus: Total as P oo66e 0.26 mg/L (Nore: Use MPN mthod Por highly mrsid samples) Orthophosphate 70507 mg/L solved Solids:Total 70300 333 mg/L Al - Aluminum o11o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00660 9.7 mg/L Ca - Calcium oo916 mg/L Chloride 00940 12.0 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L Phenol 32730 ug/L Fe - Iron 01o45 ug/L Sulfate 00945 mg/L Hg - Mercury 71 goo ug/L ecific Conductance 0009s µMhos K - Potassium 00937 mg/L Total Ammonia 00610 <0-10 mg/L Mg - Magnesium 00927 mg/L (Ammonia Nlvagen; NH,.. N; Ammonia Nitrogen, Tota6 Mn - Manganese 01o55 u9 /L TKN as N 00625 mg/L Ni - Nickel 01067 ug/L For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: Pb - Lead olos1 Zn - Zinc 111092 Certification No. 37712 ug/L mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? ® Yes (1) ❑ No (0) VOC 7873 , method # 6200 method # method # method # Effluent Trial VOCs VOC Removal% GW -59 Rev. 8/2013 SUBMIT FORM ON YELLOW PAPER ONLY :. oo ; : DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-907-6306 FACILITY INFORMATION Please Print Fla -Type PERMIT Number: Expiration Date: 8 31 ZU2U Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125. Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville S'ee NC 28792 Coun Henderson ry ❑Lagoon EJ Remediation: Infiltration Gallery (CRY) (5taw) (Zip) ® Spray Field ❑ Remediation: Contact Person: Mr. Blake Kehoe Telephone#: 8 2 8 - 6 93 - 0 711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: WELL ID NUMBER (from Permit): MW -9 sample collected: 11/9/2016 FIELD ANALYSES: If VYLLLDate WAS Well Depth: 18.1 oft. Well Diameter: 2 in. pH 00400: 4- 42 units Temp. 0001o: 16.750C DRY at Depth to Water Level 82546: 6 . 5 5 ft. below measuring point Screened Interval: 6 *ft. to 16 * ft. Spec. Cond. 00094: 90 µMhos time of MeasuringPoint is 1 . 44 ft. above land surface Relative M.P. Elevation: 2060.23 ft. Odor 9ooe5: none sampling, Volume of water um ed/balled before sampling: 2.25 afDns screened iatexval ie relative to lana surface P P P 9� 9 Appearance check here: Al - Aluminum 01105 mg/L pH (Lab) 00403 units Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO TOC oo6Bo IK Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Coliform: MF Fecal 31616 <20.0 /100mL Nitrate (NOs as N 00620 0.77 mg/L Coliform: MF Total 31504 /10OmL Phosphorus: Total as P00665 0 .76 mg/L (Nolo: Use MPN method for highly twbitl samples) Orthophosphate 70507 mg/L )issolved Solids:Total 70300 G9.0 mg/L Al - Aluminum 01105 mg/L pH (Lab) 00403 units Be - Barium 01007 ug/L TOC oo6Bo 9.3 mg/L Ca - Calcium Dots mg/L Chloride 00940 10.7 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01D42 _mg/L Phenol 32730 ug/L Fe - Iron 01045 ug/L Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Specific Conductance 00095 µMhos K - Potassium 00937 mg/L Total Ammonia 0o610 <0 . 10 mg/L Mg - Magnesium 00927 mg/L (Ammonia Nitrogen; NH,as N: Ammonia Nitrogen, Teta9 Mn - Manganese 01055 ug/L TKN as N oo625 mg/L Ni - Nickel 01067 ug/L For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: Pb - Lead olos1 Zn - Zinc 01092 Certification No. 37712 ug/L mg/L Other (Specify Compounds and Concentration Units): DEG 2 6 ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? ® Yes (1) ❑ No (0) VOC 7873 , method # _ 62nn method # method # method # mq/L Effluent Total VOCs: mall l/nr, Rern v" l GW -59 Rev. 812013