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HomeMy WebLinkAboutNC0022406_30 Percent Basis of Design Report_20161228526 South Church St. n NC 28202 tDUKECharlotte, ENERGY, P.O. Box 1006 Mail Code EC13K Charlotte, NC 28201-1006 336-445.0610 December 21, 2016 State of North Carolina Department of Environmental Quality Division of Water Resources Winston Salem Regional Office Attn: Shuying Wang, P.G., Hydrogeologist 450 Hanes Mill Road, Suite 300 Winston-Salem, NC 27105 Subject:: Belews Creek Steam Station Interim Action Plan Basis of Design Report Dear Ms. Wang: Enclosed you will find the first submittal of the Interim Action Plan Basis of Design Report for the Belews Creek Steam Station. This submittal incorporates the 30% design and pumping test report. If you have any questions on the enclosed information, please contact me at (336) 445-0610 or Melonie.Martin@duke-energy.com at your convenience. Respectfully submitted, �- l Melonie Martin Lead Environmental Specialist Waste and Groundwater Programs Attachment: Belews Creek Steam Station - Interim Action Plan Basis of Design Report NCDEQ Cc : Steve Lanter NCDEQ DWR 1636 Mail Service Center Raleigh, NC 27699-1636 Duke Cc (electronic): Henry Taylor Kevin Kirkley Melonie Martin Jeremy Pruett Ed Sullivan Page 1 of 1 4clp synTerra BASIS OF DESIGN REPORT (30% SUBMITTAL) ACCELERATED REMEDIATION INTERIM ACTION PLAN BELEWS CREEK STEAM STATION 3195 PINE HILL ROAD BELEWS CREEKF NORTH CAROLINA 27009 DECEMBER 2016 PREPARED FOR DUKE ENERGY CAROLINAS, LLC. 526 SOUTH CHURCH STREET CHARLOTTES NORTH CAROLINA 28202 • DUKE ENERGY, William Lantz, C PE 44301 Senior Proj ct Engineer Cr 'g Eady, NC LG 1 39 Project Ma ger Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page i P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx TABLE OF CONTENTS (GRAY HIGHLIGHTS INDICATE WORK THAT WILL BE INCLUDED IN FINAL BASIS OF DESIGN REPORT) SECTION PAGE 1.0 INTRODUCTION AND BACKGROUND .............................................................. 1-1 1.1 Project Background ................................................................................................... 1-1 1.1.1 Settlement Agreement ........................................................................................ 1-1 1.1.2 Interim Action Plan ............................................................................................. 1-2 1.1.3 Purpose of Basis of Design ................................................................................ 1-2 1.1.4 Scope and Objectives of Interim Action .......................................................... 1-2 1.2 Interim Action Alternatives Evaluation ................................................................ 1-3 1.3 Report Organization ................................................................................................. 1-3 2.0 REFINED SITE CONCEPTUAL MODEL ................................................................ 2-1 2.1 Geology and Hydrogeology .................................................................................... 2-1 2.2 Summary of Baseline Site Conditions .................................................................... 2-2 2.2.1 Summary of HDR Field Investigation ............................................................. 2-2 2.2.2 Summary of HDR Recent Groundwater Quality Results ............................. 2-4 2.3 Summary of Aquifer Characteristics ...................................................................... 2-4 3.0 INTERIM ACTION DESIGN CONSIDERATIONS ............................................. 3-1 3.1 Preliminary Design Criteria and Layout ............................................................... 3-1 3.2 Evaluation of Alternative Technologies ................................................................ 3-2 3.3 Groundwater Flow Modeling ................................................................................. 3-3 3.3.1 Groundwater Flow Model Conceptualization................................................ 3-3 3.3.2 Groundwater Flow Model Calibration ............................................................ 3-3 3.4 Groundwater Extraction System Design ............................................................... 3-4 3.4.1 Current Conditions ............................................................................................. 3-4 3.4.2 Post-Basin Closure Conditions .......................................................................... 3-4 3.5 Groundwater Fate and Transport Modeling ........................................................ 3-4 3.5.1 Groundwater Fate and Transport Model Calibration ................................... 3-5 3.5.2 Predictive Results ................................................................................................ 3-5 3.5.3 Implications of Remedy on Geochemical Conditions and Plume Stability 3-5 Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page ii P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx 3.6 Groundwater Extraction System Design Limitations .......................................... 3-5 4.0 WELL DESIGN .............................................................................................................. 4-1 4.1 Overview of Extraction Well Network .................................................................. 4-1 4.2 Well Construction ..................................................................................................... 4-1 4.3 Groundwater Extraction Rates ................................................................................ 4-1 5.0 EXTRACTION SYSTEM PUMP AND PIPELINE DESIGN ................................. 5-1 5.1 Overall Pipeline Design Basis ................................................................................. 5-1 5.1.1 Design Basis and Assumptions ......................................................................... 5-1 5.1.2 Calculation Method ............................................................................................ 5-1 5.1.3 Well Head Configuration................................................................................... 5-1 5.2 Extraction Well Pipeline ........................................................................................... 5-2 5.2.1 Pipe Pressure ....................................................................................................... 5-2 5.2.2 Pipe Flow .............................................................................................................. 5-3 5.2.3 Pipe Expansion/Contraction .............................................................................. 5-4 5.2.4 Pipe Trenching..................................................................................................... 5-4 6.0 ELECTRICAL AND INSTRUMENTATION DESIGN ......................................... 6-1 6.1 Piping and Instrumentation Diagram .................................................................... 6-1 6.2 Pump Controls .......................................................................................................... 6-1 6.3 Emergency System Shutdown ................................................................................ 6-1 7.0 DESIGN DOCUMENTS .............................................................................................. 7-1 7.1 Design Drawings ....................................................................................................... 7-1 7.2 Specifications ............................................................................................................. 7-1 8.0 GROUNDWATER EXTRACTION SYSTEM OPERATION ................................ 8-1 8.1 System Performance Metrics ................................................................................... 8-1 8.2 Permits ........................................................................................................................ 8-1 8.3 Institutional Controls ................................................................................................ 8-1 8.4 Contingency Plans .................................................................................................... 8-1 8.5 Construction and Monitoring Schedules ............................................................... 8-1 9.0 REFERENCES ................................................................................................................ 9-1 Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page iii P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx LIST OF FIGURES Figure 1-1 Site Location Map Figure 1-2 Site Layout Figure 2-1 Boron in Surficial Zone Figure 2-2 Boron in Transition Zone Figure 2-3 Boron in Bedrock Zone Figure 2-4 Chloride in Surficial Zone Figure 2-5 Chloride in Transition Zone Figure 2-6 Chloride in Bedrock Zone Figure 2-7 Selenium in Surficial Zone Figure 2-8 Selenium in Transition Zone Figure 2-9 Selenium in Bedrock Zone Figure 2-10 Total Dissolved Solids (TDS) in Surficial Zone Figure 2-11 Total Dissolved Solids (TDS) in Transition Zone Figure 2-12 Total Dissolved Solids (TDS) in Bedrock Zone Figure 3-1 Phase I Remediation System Layout Figure 3-2 Extraction Well Schematic Figure 5-1 Typical Below Grade Vault Figure 5-2 Piping Plan Profile LIST OF TABLES Table 1-1 Summary of Select Constituent Analytical Data in Area of Interest LIST OF APPENDICES Appendix A Aquifer Testing Analysis (HDR Field Investigation and Pumping Test Report, October 6, 2016) Appendix B Evaluation of Alternative Remedial Technologies Appendix C Groundwater Flow Model Report Appendix D Geochemical Model Report Appendix E Pipe and Pump Selection Package Appendix F Design Drawings Appendix G Technical Specifications Appendix H Permits Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page iv P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx LIST OF ACRONYMS 2L DEQ/Division of Water Resources Title 15, Subchapter 2L. Groundwater Quality Standards AOI BCSS BGS Area of Interest Belews Creek Steam Station Below Ground Surface CAMA Coal Ash Management Act CAP Corrective Action Plan (Parts 1 and 2) CCR Coal Combustion Residuals CSA DEQ FGD FPS Comprehensive Site Assessment North Carolina Department of Environmental Quality Flue Gas Desulfurization Feet per Second GPM HDPE HMI HP IAP Gallons per Minute High Density Polyethylene Human Machine Interface Horsepower Interim Action Plan IMAC Interim Maximum Allowable Concentrations NPDES National Pollution Discharge Elimination System O&M P&ID Operations and Maintenance Piping and Instrumentation Diagram PPBTVs Proposed Provisional Background Threshold Values PSI PVC SCM Pounds per Square-Inch Polyvinyl Chloride Site Conceptual Model TDS Total Dissolved Solids VFD Variable Frequency Drive Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 1-1 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx 1.0 INTRODUCTION AND BACKGROUND Duke Energy Carolinas, LLC (Duke Energy) owns and operates the Belews Creek Steam Station (BCSS), located on Belews Lake in Stokes County, North Carolina (Figure 1-1). BCSS began operation in 1974 and operates two coal-fired units. Coal combustion residuals (CCR) and other liquid discharges from the coal combustion process have been disposed in the ash basin since its construction. In 1983, BCSS converted to dry handling of fly ash with disposal in on-site landfills with bottom ash sluiced to the ash basin and fly ash sluiced to the ash basin on plant start-up and in emergency situations. Water discharge from the ash basin is permitted by the North Carolina Department of Environmental Quality (DEQ) Division of Water Resources (DWR) under the National Pollutant Discharge Elimination System (NPDES) Permit NC0024406. 1.1 Project Background In order to satisfy requirements of the North Carolina Coal Ash Management Act (CAMA), a Comprehensive Site Assessment (CSA) and Corrective Action Plan (CAP) Parts 1 and 2 were prepared and submitted to the DEQ by HDR Engineering, Inc. of the Carolinas (HDR). The CAP (Parts 1 and 2) describes means to restore groundwater quality to the level of the standards, or as close as is economically and technologically feasible in accordance with T15A NCAC 02L .0106. Exceedances of numerical values contained in Subchapter 2L and Appendix 1 Subchapter 02L (IMACs) at or beyond the compliance boundary were determined to be the basis for corrective action with the exception of parameters for which naturally occurring background concentrations are greater than the standards. A CSA Supplement 1, prepared by HDR, was submitted to DEQ on February 18, 2016 as an appendix to the CAP Part 2 and provided information to address information requested by DEQ subsequent to submittal of the CSA report, additional data validation reporting, and a response to site-specific DEQ comments obtained during in-person meetings. A CSA Supplement 2, prepared by HDR, was submitted to DEQ on August 11, 2016. 1.1.1 Settlement Agreement A Settlement Agreement between DEQ and Duke Energy signed on September 29, 2015, requires accelerated remediation to be implemented at sites that demonstrate off-site groundwater impacts. Historical and CSA assessment information indicates the potential for off-site groundwater impact northwest of the ash basin in the area of the 2.23-acre parcel (hereafter Parcel A) not owned by Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 1-2 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx Duke Energy. Figure 1-2 illustrates Parcel A with pertinent features and shows the general area to be addressed for accelerated remediation. Duke Energy provided an Accelerated Remediation Summary report to DEQ on February 17, 2016 which supplemented and updated information included with the CAP Part 2. In correspondence dated March 28, 2016, DEQ acknowledged receipt of the Remediation Summary and requested additional information. DEQ conditionally approved the Interim Action Plan (IAP) in a letter dated July 22, 2016 with the condition (among others) that a Basis of Design (BOD) Report be submitted for review. Duke Energy provided a response to the conditional approval letter on September 9, 2016. In follow-up, the Table of Contents for the Basis of Design report was adjusted by DEQ in a letter dated September 27, 2016. 1.1.2 Interim Action Plan Interim action activities associated with Parcel A consisted of pilot testing with the potential of installing a groundwater extraction system along the northwest corner of the ash basin. Specific objectives outlined in the Interim Action Plan (HDR, April 2016) were: Acquire Parcel A. This activity is no longer being pursued by Duke Energy. Conduct initial aquifer tests to evaluate feasibility and aid in the preliminary design of a groundwater extraction system and/or subsurface barrier wall. Recently completed aquifer tests indicate groundwater extraction is a viable remedial alternative at BCSS. Initiate preliminary design of a groundwater extraction system. Initiate permitting for a groundwater extraction system. 1.1.3 Purpose of Basis of Design The purpose of this Basis of Design Report is to provide a system layout and sizing of system components including wells, piping, pumps, and discharge system. It also serves to provide control system capabilities and power requirements. Due to the preliminary nature of this 30% Basis of Design report, the actual design criteria, calculation and assumptions are unknown or in the preliminary development stages as this time. 1.1.4 Scope and Objectives of Interim Action Constituents associated with coal ash pore water have been identified within groundwater in shallow (saprolite) and deep (transition zone between saprolite Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 1-3 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx and competent bedrock) flow layers between the ash basin and Parcel A and downgradient of Parcel A. Groundwater in shallow and deep layers near Parcel A flows north and northwest toward the Dan River. Groundwater monitoring wells delineating concentrations in this area are located on Duke Energy property. Implementation of a groundwater extraction system located between the ash basin and the southeast side of Parcel A will be used to capture groundwater flow toward Parcel A. The compliance boundary coincides with the southeast property line of Parcel A. 1.2 Interim Action Alternatives Evaluation In a letter from DEQ to Duke Energy dated July 22, 2016, evaluation of alternative technologies to achieve Agreement objectives related to potential off-site groundwater impacts must be considered as part of the implementation of the Interim Action Plan. Options incorporated in the IAP included groundwater extraction and/or a low permeability barrier wall. A detailed evaluation of the alternatives is presented in Section 3.2. 1.3 Report Organization The initial 30% design submittal provides sufficient detail of the groundwater extraction design to conceptualize system components, performance, and initiate evaluation of site specific considerations. Provided herein are conceptual layout drawings, preliminary pump and piping specifications and findings from the aquifer pumping tests. This design report will be updated and incorporated into the final (100%) Basis of Design report. Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 2-1 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx 2.0 REFINED SITE CONCEPTUAL MODEL The site conceptual model (SCM) is an interpretation of processes and characteristics associated with hydrogeologic conditions and constituent interactions at the BCSS ash basin. The purpose of the SCM is to evaluate areal distribution and flow pattern of constituents with regard to site-specific geological/ hydrogeological and geochemical properties at the BCSS ash basin relative to the source, potential receptors and natural control mechanisms. The SCM was developed using data and analysis from the CSA (HDR, September, 2015) and further refined in the CAP Part 2 (HDR, March 2016) and recent field investigations related to Parcel A. Key components of the SCM are as follows: The hydraulic head of the ash basin, coupled with the significant topographic relief from the ash basin to the Dan River, drives groundwater flow through the system. This concept is further described in the Groundwater Flow and Transport Modeling Report for the BCSS (CAP Part 1). Partition coefficient (Kd) values were developed for major constituents at the BCSS. Boron has a Kd determined to facilitate high mobility across the site. Analysis of site specific Kd values is provided in the Soil Sorption Evaluation Belews Creek Steam Station (CAP Part 1, Appendix D). Groundwater flow within the Area of Interest (AOI), incorporating Parcel A and the northwest corner of the ash basin, is generally to the northwest from the ash basin toward the Dan River. The topographic grade between the basin and the river averages approximately 6 percent (southeast to northwest). It is likely that the water table exhibits a similar trend. The water table is typically 20 to 30 feet below ground surface in the topographic high areas near the ash basin and decreases nearer the river. The water table is in the upper portions of the saprolite; however, the transition zone has a greater transmissivity (by a factor of approximately 100) and thus the bulk of groundwater flow and constituent transport is in this zone (HDR Field Investigation and Pumping Test Report, October 6, 2016). 2.1 Geology and Hydrogeology The BCSS site is located in the Milton terrane of the Piedmont Physiographic Provence; the Dan River Basin is located approximately 2,500 to 3,000 feet north/northwest of the Site. Geologic units mapped in the vicinity of the site include alluvium, terrace deposits, sedimentary rocks of the Dan River Basin, a diabase dike, and felsic gneisses Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 2-2 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx and schists with interlayered hornblende gneiss and schist. Alluvial and terrace deposits have not been encountered in boreholes advanced in the area of the BCSS ash basin, but alluvial deposits have been mapped along the unnamed stream north of the ash basin main dam and along the Dan River. The hydrogeologic regime at BCSS is characterized by residual soil/saprolite and weathered rock overlying fractured crystalline rock separated by a transition zone (TZ). The BCSS groundwater system is divided into three layers referred to as shallow, deep (TZ), and bedrock to distinguish the flow layers within the connected aquifer. This system is similar to that described by LeGrand (2004) in that groundwater flow in not confined within these units. In keeping with LeGrand model, groundwater flow and transport at the BCSS site can be approximated from surface topography. A topographic divide along Pine Hall Road separates the ash basin and Pine Hall Road landfill, both located north of the road, from the ash structural fill, coal pile, and power plant, located south of the road (Figure 1-1). Groundwater flow north of the road is to the north-northwest toward the Dan River, while groundwater flow south of the road is to the south-southeast towards Belews Lake. Additional topographic divides are located west and north of the ash basin approximately near Middleton Loop Road. These divides separate the surface drainage area containing the ash basin from adjacent drainage areas. While the topographic divides generally function as groundwater divides, groundwater flow across topographic divides may occur based on head conditions from the ash basin or preferential flow paths within the shallow and/or deep flow layers. In the area of Parcel A, groundwater flows across the topographic divide of Middleton Loop Road to the northwest toward Parcel A and the Dan River. 2.2 Summary of Baseline Site Conditions 2.2.1 Summary of HDR Field Investigation The following summarizes results from a HDR report (October 2016). The HDR field investigation and pumping test activities included the advancement of four soil borings (SB-1, SB-2, SB-4, and SB-5) along the property boundary and Middleton Loop Road, and installation of two extraction wells (EW-1 and EW-2) and four observation wells (TW-1 through TW-4) (Figure 1-2). The activities were conducted in August/September 2016. The soil borings were advanced to evaluate geologic conditions within the estimated extent of impacted groundwater in the AOI and evaluate target depths for Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 2-3 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx potential groundwater extraction wells. The results of the HDR field investigation activities are included in Appendix A. Lithology encountered during installation of the four soil borings (SB-1, SB-2, SB-4, and SB-5) along the western property boundary primarily included low-plasticity silt from approximately 0 to 55 feet below ground surface (ft bgs) with relict foliation and structure identified with increasing depth. Lenses of sandy silt and sandy silt with gravel were identified within the range of 25 to 55 ft bgs in soil borings SB-2, SB-4 and SB-5. Partially weathered and fractured rock was encountered in SB-1 at 54 ft bgs, in SB-2 at 59 ft bgs, at 60 ft bgs in SB-4, and at 45 ft bgs in SB-5. Competent (sound) bedrock was encountered at 59 ft bgs in SB-1 and 53 ft bgs in SB-5. Observation well TW-1 was installed along the western property boundary, immediately downgradient from extraction well EW-1. Silt, sandy silt, and sandy silt with gravel were encountered from 0 to 42 ft bgs during installation and weathered/fractured rock was encountered from 42 to 58 ft bgs. An additional observation well (TW-4) was installed with a fully penetrating screen in the shallow flow layer adjacent to TW-1. Conditions encountered in TW-4 were similar to those encountered during installation of TW-1. During installation of extraction well EW-1, low-plasticity silt and lenses of silty sand were encountered from 0 to 46 ft bgs. Weathered and fractured rock was encountered at 46 ft bgs and sound rock was encountered at 63 ft bgs. An additional extraction well (EW-2) was installed approximately 15 ft south of EW-1 and screened within the shallow flow layer from approximately 15 to 45 ft bgs. Conditions encountered in EW-2 were similar to those encountered during installation of EW-1. Conditions encountered during installation of two observation wells (TW-2 and TW-3) located between the extraction well EW-1 and the ash basin were generally similar to those encountered with the other soil borings and extraction wells. Low-plasticity silt with lenses of silty sand with gravel was encountered from 0 to 48 ft bgs. Slightly weathered and fractured rock was encountered at 48 ft bgs and sound bedrock was encountered at 58 ft bgs. The water table was encountered from approximately 20 to 28 ft bgs in shallow extraction and observation wells installed for the pumping test. Water levels in the deep (TZ) extraction and observation wells ranged from 21 to 29 ft bgs. The saturated thickness within the soil/saprolite zone (above weathered and fractured rock) ranged Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 2-4 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx from approximately 11 to 29 ft at the pumping test site. Other than the sound rock beneath the transition zone there is no unit identified that will impede vertical migration of groundwater flow and contaminant transport. 2.2.2 Summary of HDR Recent Groundwater Quality Results The most recent groundwater analytical data available (May/June 2016) as provided by HDR were used to develop isoconcentration maps for the three flow layers (shallow (surficial), deep/transition zone, and bedrock) for select constituents as depicted in Figures 2-1 through 2-12. The constituents: boron, chloride, selenium and total dissolved solids (TDS) were chosen based on exceedances above 2L in the AOI and to represent constituent behavior in subsurface media. A summary of the analytical data provided by HDR is presented in Table 1. A brief summary of results follows: Concentrations of boron in the shallow and transitions zones have been defined and are shown on Figures 2-1 and 2-2. No 2L exceedances were observed in bedrock (Figure 2-3). Chloride concentrations are shown on Figures 2-4 to 2-6. Exceedances of 2L exist in the shallow and transition zones in small areas and no exceedances are found in bedrock. Selenium concentrations are shown on Figures 2-7 to 2-9. The transition and bedrock zones have no exceedances of 2L, while the shallow zone has an exceedance. Total dissolved solids concentrations are shown on Figures 2-10 to 2-12. Exceedances of 2L are present in the shallow and transition zones but not in bedrock. Exceedances of 2L are confined to the upper two zones and not present in bedrock. It is likely that these concentrations represent near stable conditions (that is concentrations are not changing with time) because of the age of the system and the velocity of groundwater. 2.3 Summary of Aquifer Characteristics HDR conducted pumping test activities within the AOI which included step draw down tests on EW-1 and EW-2; a 24-hour pumping test on EW-2 and single well pumps tests on TW-1 and TW-3. Drawdown and recovery information was obtained using downhole pressure transducers. The pumping test activities were performed from Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 2-5 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx September 7 to 9, 2016. The results of the HDR pumping test activities are included in Appendix A. Transmissivity and hydraulic conductivity values were calculated for both the shallow and deep flow layers. Using graphical calculation methods and AQTESOLV, the transmissivity in the shallow flow layer based on the drawdown and recovery test results was 6.78 to 13.2 gallons per day/foot (0.9 to 1.8 feet2/day), respectively. These transmissivity values equate to hydraulic conductivities of 0.08 feet per day (2.8 x 10-5 centimeters/second) and 0.04 feet/day (1.41 x 10-5 centimeters/second), respectively. These values are representative of silt and sandy silt (Freeze and Cherry, 1979). Hydraulic communication was observed between the shallow and deep flow layers during the pumping test activities. Using graphical calculation methods, the average transmissivity in the deep flow layer based on the TW-1 single pumping test results was 570 gallons per day/foot (76.1 feet2/day), which equates to a hydraulic conductivity of 217 feet/day (7.68 x 10-4 centimeters/second). Based on drawdown observed in shallow and deep wells during the constant rate test at TW-1, the shallow and deep flow layers are connected and pumping from the deep layer will draw groundwater from the shallow layer. The radius of influence calculations for the deep flow layer indicate that a well spacing of 45 feet may be needed to provide hydraulic control for impacted groundwater migrating offsite in the deep flow layer for wells pumping at 2 gpm. Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 3-1 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx 3.0 INTERIM ACTION DESIGN CONSIDERATIONS This section addresses the identification and evaluation of corrective measures applicable to the capture of groundwater flow between the ash basin and Parcel A. 3.1 Preliminary Design Criteria and Layout A series of extraction wells upgradient of the southeastern perimeter of Parcel A will be installed to capture groundwater and create hydraulic control by minimizing the flow of groundwater passing from the ash basin through Parcel A. Results from the pumping test (HDR, October 2016) suggest that it is appropriate to plan for several phases of well installation given the highly variable nature of the transition zone (in terms of thickness and hydraulic conductivity). Note that the methods for determining capture are based on assumptions of homogeneity and isotropy. Due to local variations in hydrogeologic properties along the proposed alignment, well spacing (to provide capture) may need to be varied throughout the 700 foot length of the line of extraction wells. Experience with other capture well systems in similar geologic environments suggests a 45 foot well spacing (HDR, October 2016) is overly conservative and that a larger spacing is more apt to be appropriate. In Phase 1, five extraction wells will be installed as shown on Figure 3-1. These locations were chosen to determine probable extremes in site conditions (i.e., transition zone thickness, transmissivity) and resultant range in well spacing. As part of the first phase, a monitoring period will be initiated after system startup where water level and water quality data will be collected from the extraction wells and nearby existing and proposed monitoring wells for a period no longer than three months. These data will be used to determine well spacing for the balance of the system. Extraction wells will be screened across the depth of the transition zone at each location (Figure 3-2). Reduced heads in the transition zone will cause flow from the shallow zone to migrate to the transition zone, which will result in further reduction of mass transport. Based on the pumping test results, the flow rate from each well is estimated at 2 gpm; however, increased flow rates may be encountered depending on the transmissive nature of the transition zone at an extraction well location. Existing and proposed monitoring wells will be used to measure the effectiveness of the system in controlling groundwater flow in the area. Extracted groundwater would be pumped through discharge piping to the nearby permitted outfall conveyance system via the ash basin discharge tower. Pending final Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 3-2 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx permit modification issuance, it is anticipated that the groundwater may require pH adjustment prior to discharge. 3.2 Evaluation of Alternative Technologies Options incorporated in the IAP included groundwater extraction and/or a low permeability barrier wall. A low permeability barrier wall as a method of alternative remediation has been evaluated and is not considered technically feasible for the following reasons: Constituent concentrations greater than 2L are observed within the shallow and transition zone flow systems. The fractures inherit within the transition zone formation preclude the suitability for the installation of slurry walls or permeable reactive barriers. Boron treatment via a reactive barrier is not a proven technology. Increased hydraulic heads behind a barrier wall and localized leaks could result in accelerated flow through areas of the transition zone. Site conditions indicate that it is infeasible to ensure that a barrier wall is hydraulically sealed at the interface with bedrock. The surface of the competent bedrock beneath the transition zone is uneven, the thickness of the transition zone is variable, the surface of the transition zone is uneven, the rock comprising the transition zone is fractured, and the depth to competent bedrock is significant. A barrier wall would have to extend significant distances to the northeast and southwest beyond Parcel A property boundaries to prevent impacted groundwater from flowing around the wall and into the property. The area where a barrier wall is most apt to be located consists of major topographic relief southeast to northwest, from the crest of the ash basin dam to the Dan River. The topography, along with an irregular bedrock surface, renders the implementation of a slurry trench technically infeasible and would not benefit the off-site parcel. Another option considered was a combination of extraction wells and a low permeability barrier. This option was also rejected because of the technical infeasibility to ensure an effective hydraulic seal between the barrier wall and the bedrock interface. Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 3-3 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx The pumping tests conducted by HDR in September 2016 confirmed the feasibility of implementation of extraction wells northwest of the ash basin. As indicated in the pumping test report, soils and pumping test data indicate that extraction from the deeper, more permeable transition zone is a viable approach to limiting plume migration. Review of the boring logs for wells in this area indicates that the shallow zone and the transition zone are connected hydraulically. This means that extraction from the transition zone will result in lowering the water level in the shallow zone and creation of a hydraulic barrier to down gradient migration throughout the water column. Several additional monitoring wells will be added to monitor the shallow zone as part of Phase 1. Once steady state conditions are reached, a hydraulic barrier can be maintained with a sustainable, relatively constant, extraction flow rate from the transition zone. Note that the groundwater extraction system operation may not be necessary once the ash basin is dewatered and closed (as groundwater levels are anticipated to drop below the transition zone). The future water levels following basin closure will be predicted through groundwater modeling currently underway. Groundwater modeling of the final extraction system under closure condition simulations will be provided in the final Basis of Design report. 3.3 Groundwater Flow Modeling A Groundwater Flow and Transport Modeling Report has been developed and submitted with the CAP Part 1 (December 8, 2015) and the CAP Part 2 (March 4, 2016). This model is being updated with information obtained from the installation of data gap wells and the recently completed aquifer pumping tests and the domain expanded to include a larger area. The updated groundwater flow model will be included in a final Basis of Design report. 3.3.1 Groundwater Flow Model Conceptualization Discussion of Groundwater Flow Model Conceptualization will be included in the final Basis of Design Report submittal. 3.3.2 Groundwater Flow Model Calibration Discussion of Groundwater Flow Model Calibration will be included in the final Basis of Design Report submittal. Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 3-4 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx 3.4 Groundwater Extraction System Design The groundwater extraction system design is based on effective and efficient capture and conveyance of groundwater for treatment and discharge. Based on the HDR pumping test results, up to twenty 6-inch diameter extraction wells may ultimately be installed along the southeastern side of Middleton Loop Road (Figure 3-1), between the ash basin and Parcel A based upon a spacing of 45 feet as suggested from the pumping test report. However, flow rates are likely to vary significantly throughout the transition zone and spatially along the proposed well alignment. The phased installation approach will allow refinement of the well spacing and flow rates. The flow rate achieved from the transition zone of 2 gallons per minute (gpm) during the test of well TW-1 resulted in a sustained drawdown of approximately 16 feet. If all proposed groundwater extraction wells achieve a similar flowrate, the total flow rate for the extraction system could be 40 gpm. Extraction wells will be completed to depths expected to be 55 to 65 feet below grade to encounter the fractured rock constituting the transition zone/deep flow layer. Pump controls will allow operation based on speed, flow rate, or water level. An ideal pumping scenario will create a constant drawdown with continuous pumping after steady state conditions are reached. During initial dewatering of the shallow zone soil, pump cycling will likely occur. High level and low level float switches may be used as an alternative method for pump cycling should conditions warrant. Thermal and electrical current load protection (shut-off) is built into the pump motor. 3.4.1 Current Conditions The area of the proposed extraction well network is between the ash basin and Middleton Loop Road. The southern portion of the area is slightly wooded, while the northern area is an open area associated with maintenance of the ash basin discharge structure. 3.4.2 Post-Basin Closure Conditions Plans for basin closure are not complete at this time. Groundwater modeling of post-closure groundwater levels with and without system operation will also be used in the final design of the system. 3.5 Groundwater Fate and Transport Modeling An initial Groundwater Flow and Transport Modeling Report was submitted with the CAP Part 1 on November 20, 2015. This model will be updated with information obtained from the installation of data gap wells and the recently completed aquifer pumping tests and groundwater analysis. The updated groundwater fate and transport model Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 3-5 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx will predict how long boron concentrations will remain above the 2L at the offsite property boundary (compliance boundary), and through the year 2117. Modelling results will be submitted in the final Basis of Design report. 3.5.1 Groundwater Fate and Transport Model Calibration Discussion of Groundwater Fate and Transport Model Calibration will be included in the final Basis of Design Report submittal. 3.5.2 Predictive Results Discussion of Predictive Results will be included in the final Basis of Design Report submittal. 3.5.3 Implications of Remedy on Geochemical Conditions and Plume Stability This discussion will be included in the final Basis of Design report. 3.6 Groundwater Extraction System Design Limitations Discussion of Groundwater Extraction System Design Limitations will be included in the final Basis of Design Report submittal. Because of variable hydrogeologic conditions it is necessary to have a phased approach for system design and installation. This process is included in this design. A second factor that will affect the final design is the closure plan for the ash basin. When the design and implementation schedule are known, the layout of the extraction well system will be amended as necessary. Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 4-1 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx 4.0 WELL DESIGN The extraction well system will be designed to capture groundwater flow between the ash basin and Parcel A to provide mass removal of constituents of concern to accelerate groundwater remediation at the property boundary. 4.1 Overview of Extraction Well Network Based on this objective, the Phase I preliminary design spacing between extraction wells is estimated at 200 feet along Middleton Loop Road, adjacent to the subject property. Additional extraction wells may be needed depending of site conditions. Based on the HDR pump test results, with the assumption of 2 gpm per well, the total flow rate for the extraction system would be 40 gpm. Following the Phase I implementation, greater pumping rates and drawdown levels may be needed so a design flow rate of 80 gpm is currently anticipated. 4.2 Well Construction The extraction wells will be installed by a North Carolina licensed well driller in accordance with North Carolina Administrative Code Title 15A, Subchapter 2C – Well Construction Standards, Rule 108 Standards of Construction: Wells Other Than Water Supply (15A NCAC 02C .0108). The wells will be drilled and installed to depths of between about 55 and 65 feet, corresponding to the depth of competent bedrock. The exact depths will be determined during drilling. The extraction wells will be 6-inch diameter wells with casings and screens. The well screens will be installed near the bottom of the transition zone to provide capture across the depth of this layer. 4.3 Groundwater Extraction Rates Groundwater extraction rates will be fully discussed in the final Basis of Design report. Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 5-1 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx 5.0 EXTRACTION SYSTEM PUMP AND PIPELINE DESIGN 5.1 Overall Pipeline Design Basis The anticipated flow rate for the system is 40 to 80 gpm. The pipeline design basis is 80 gpm to allow for the higher end of the anticipated pumping rate range. The piping system will be constructed below grade with high density polyethylene (HDPE). 5.1.1 Design Basis and Assumptions The extraction wells will be equipped with variable frequency drive (VFD) motor control and electrical and thermal motor protection. 5.1.2 Calculation Method Assuming similar conditions and flow rates as indicated by the pumping test, the proposed submersible pumps provide 270 feet of nominal head, operate on 230 volt single phase power and have a 0.75 horsepower (hp) submersible electric motor (e.g., Grundfos SQE Smart Flo 10SQE07-240 or equivalent). The pump diameter is 3 inches with a 1-inch discharge. At both 2 and 4 gpm, the pump provides between 40 and 360 feet of head based on the motor drive frequency. The expected head requirement assumes 65 feet from the well water column, 20 feet for surface elevation changes, 50 feet for piping losses, 20 feet for fittings loss, and an estimated 20 feet for treatment system requirements. This pump provides the greatest efficiency over the design flow rate range. Use of a VFD will provide the capability to operate the pump at lower flow rates, if necessary, while not significantly sacrificing efficiency or subjecting the pump to unnecessary working pressure. The control system will include water level and flow monitoring feedback to the VFD providing effective operation of the pumps. It is anticipated that the well pump will discharge through 1-inch diameter discharge pipe to the surface. The pipe will be secured in the center of the well casing with Simmons (or equal) top guides. 5.1.3 Well Head Configuration Well vaults will be finished below grade with insulated covers to simplify O&M (Figure 5-1) and utilize the following design parameters. o Well vault piping and fittings may be 304 stainless steel to reduce risk of damage due to O&M. The piping will transition to high density polyethylene (HDPE) fusion-welded pipe. Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 5-2 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx o The well seal will be Simmons Model 316 (or equal) cast solid plate, 4-bolt seal with threaded openings for the pump power cable, level monitor and well vent. o The piping will be fitted with a Simmons Model 516SS (or equal) check valve. o Flow monitoring at the well head will be accomplished with a Sparling Tigermag EP FM656 (or equal) electromagnetic flow meter with direct read and transmitter. o Well water level will be monitored with a Solinst Levelogger (or equal) transducer. High level and low level floats may be incorporated into the design to provide pump on and off control. o The piping will be fitted with a one-half inch sampling port ball valve. o The well head piping train will include a ball valve for isolation of the well head from the header and pipe unions for maintenance access. 5.2 Extraction Well Pipeline The extraction well header pipe will connect all of the well discharges to the treatment system. It will be constructed of 2-inch diameter DR-11 HDPE. 5.2.1 Pipe Pressure The maximum pressure of the system is anticipated to be less than 150 psi. Manufacturers’ pressure rating for DR-11 HDPE pipe is 200 psi. DR-11 pipe also meets long term pressure performance criteria. PR =2(HDS) 𝑓𝑓𝐸𝐸 𝑓𝑓𝑇𝑇𝐷𝐷𝐷𝐷−1 Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 5-3 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx where: PR: pressure rating, psi HDS: hydrostatic design stress, psi; 800 @ 73 degrees Fahrenheit (oF) fE: environmental design factor; 1.00 for water fT; operating temperature multiplier; 1.11 @ 73 oF DR: pipe dimension ratio, DR=D/t; D: diameter, t: thickness 150 =2(800)(1.00)(1.11)𝐷𝐷𝐷𝐷−1 DR = 11.8; 11.8 > 11, so DR-11 is acceptable 5.2.2 Pipe Flow Flow velocities for the extraction well and header piping were estimated using the Hazen Williams formula with US units. S = 𝑃𝑃𝑑𝑑𝐿𝐿=4.52 𝑄𝑄1.852 𝐶𝐶1.852 𝑑𝑑4.8704 where: S = frictional resistance (pressure drop per foot of pipe) in psig/ft (psi gauge pressure per foot) Pd = pressure drop over the length of pipe in psig L = length of pipe in feet Q = flow, gpm C = pipe roughness coefficient d = inside pipe diameter, in At the assumed header pipe operating flow rate of 40 gpm, the water velocity in the pipe would be 4.08 feet per second (fps) and the head loss would be 0.03 feet of water per foot of pipe length (ft/ft). At the design flow rate of 80 gpm, the velocity will be 8.17 fps and the head loss will be 0.12 ft/ft (Appendix E). Piping from the well boxes to the header is anticipated to be 1-inch diameter DR- 11 HDPE. At the expected well line operating flow rate of 2 gpm, the water velocity in the pipe will be 0.82 fps and the head loss will be 0.004 ft/ft. At the design flow rate of 4 gpm, the velocity will be 1.63 fps and the head loss will be 0.014 ft/ft (Appendix E). Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 5-4 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx The fluid velocities and head losses are within acceptable ranges given the fluid and piping material characteristics. Installation of the pipe will be completed with heat fused joints and all piping connections will be pressure tested prior to burial. 5.2.3 Pipe Expansion/Contraction HDPE pipe has a thermal expansion coefficient of 67.0 ×10-6 in/in. Using a conservative groundwater temperature variation of 20 °F, the linear dimension change per 100 feet of pipe length is estimated to be: ∆𝑇𝑇=20 ℉ ∆𝐿𝐿=100 𝑓𝑓𝑓𝑓 × 12 𝑖𝑖𝑖𝑖𝑓𝑓𝑓𝑓× 67.0 × 10−6 in℉ in × 20 ℉.=1.6 𝑖𝑖𝑖𝑖 Pipe expansion loops or curvature will be included in the detailed pipe layout to accommodate this expansion/contraction. Due to the thermal capacity of the pipe contents and soil matrix, this will be a conservative approach. 5.2.4 Pipe Trenching The extraction piping system will be installed in trenches constructed with granular bedding material, backfilled with excavated native soil and compacted. The pipe trenching will be designed to accommodate vehicle loading. Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 6-1 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx 6.0 ELECTRICAL AND INSTRUMENTATION DESIGN It is anticipated that single-phase, 230-Volt, 200-Amp electrical service will be provided to the system from a power drop initiated from a transformer on Middleton Loop Road and terminated inside the fenced area at the current ash basin discharge structure location. The control panel for the system will be located in the same location. It is also assumed that power to the well pumps, through the VFDs, as well as the pumping system controls will be provided from this panel. 6.1 Piping and Instrumentation Diagram The Piping and Instrumentation Diagram (P&ID) will be completed as part of the Final Basis for Design package once the conceptual design and complete design objectives are determined. 6.2 Pump Controls The pumps will be controlled with individual Grundfos CUE (or equal) VFDs which adjust the power frequency to vary the motor speed to control the pumping rate. The pumping rate can be adjusted manually or based on set points for flow rate or water level in the well from flow or level sensor signals. The VFDs allow for soft starts of the motor and allow the motors to operate efficiently by only drawing the necessary amperage to provide the desired pumping rate. It is assumed control of the system will be accomplished through a Human Machine Interface (HMI) screen for ease of operation. 6.3 Emergency System Shutdown The pump motors have internal shutdown systems if the motors start to draw excessive power indicative of pump problems. The motors also have internal shutdown systems for motor overheating. In addition to these safeguards, high pressure conditions or other treatment system malfunctions can also trigger complete system shutdown. These safeguards can be programmed into the pumping control system once the treatment system design is completed. The control system can also be equipped with an auto-dialer to notify operations staff immediately of a system shutdown condition. Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 7-1 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx 7.0 DESIGN DOCUMENTS This 30% design package includes preliminary site layout drawings and conceptual details for the wells and well head configurations. Additional details and specifications will be finalized in the Final Basis of Design package. 7.1 Design Drawings The complete design package will include site layout plans and profiles, process flow diagrams, P&ID diagrams, construction details, electrical and control drawings, and indices and notes. 7.2 Specifications Complete equipment, materials and construction specifications will be incorporated into the final design package. Supporting equipment performance data, calculations, and significant equipment and materials cut-sheets will also be included. This 30% design package includes supporting documentation for the significant elements necessary to evaluate the conceptual design. Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 8-1 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx 8.0 GROUNDWATER EXTRACTION SYSTEM OPERATION 8.1 System Performance Metrics 8.2 Permits 8.3 Institutional Controls 8.4 Contingency Plans 8.5 Construction and Monitoring Schedules These sections will be provided in the Final Basis of Design report. Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra Page 9-1 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx 9.0 REFERENCES HDR Engineering, Inc. of the Carolinas, September 9, 2015. Comprehensive Site Assessment Report – Belews Creek Steam Station Ash Basin. HDR Engineering, Inc. of the Carolinas, December 8, 2015. Corrective Action Plan – Part 1: Belews Creek Steam Station Ash Basin. HDR Engineering, Inc. of the Carolinas, March 4, 2016. Corrective Action Plan – Part 2: Belews Creek Steam Station Ash Basin. HDR Engineering, Inc. of the Carolinas, August 11, 2016. Comprehensive Site Assessment – Supplement 2 – Belews Creek Steam Station Ash Basin. HDR Engineering, Inc. of the Carolinas, October 6, 2016. Field Investigation and Pumping Test Report. Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx FIGURES v �? u L 15111 ARC �� 'Elks RO J0E AY Riverview ( Goff Course Y Vl ^L plpE P71 : PARCEL LINE (APPROXIMATE) AREA OF INTERESTi�` COMPLIANCE BOUNDARY M/DD< PTON (OOP PARCEL A (2.23 ACRES) L _ _ _ I ASH easlN ' BELEWS LAKE ' ( WE LAN DCTED - I 1 WASTE BOUNDARY c +ao0 ,I Jr COAL PILE 800 .o I PINE HALL ROAD ASH LANDFILL 0 STRUCTURAL FILL / _ PINE NPVL ROW J. POWER PLANT O A 800 a - co FGD LANDFILL _ S f k SOURCE: J^ USGS TOPOGRAPHIC MAP OBTAINED FROM THE USGS STORE AT�/} 1 h Ltp://store.usgs.gov/b2c_usgs/b2c/start/%%%28xcm=r3standardpitrex_prd%%%29/.do NOTE: \ } PARCEL LINE, WASTE BOUNDARY AND COMPLIANCE BOUNDARY BASED ON INFORMATION OBTAINED FROM AN HDR DRAWING TITLED "BELEWS CREEK STEAM STATION GW FLOW DIRECTION" BELEWS CREEK STEAM STATION FIGURE 1-1 STOKES COUNTY SITE LOCATION MAP WINSTON-SALEM. DUKE ENERGY CAROLINAS - .RALErGH BELEWS CREEK STEAM STATION GREENVILLE• 3195 PINE HILL RD � erra •CMARLO7iE . FAYETrEV"`E BELEWS CREEK, NORTH CAROLINA 148 RIVER STREET, SUITE 220 BELEWS LAKE NC QUADRANGLE GREENVI LLE, SOUTH CAROLINA w LMIlG 101 DRAWN BY: JOHV CHASTAIN DATE: 12/27/2016 GRAPHIC SCALE PHONE 864-421-9999 PRaECT MANAGER: C. EADY CONTOUR INTERVAL: zo FEET 1000 0 1000 2000 www.synterracorp.com [LAYOUT: USGSTOPO MAP DATE: 2013 P.\Duke Ener Pro ress.1026\20. BELEWS CREEK\04. CUP Accelera Led Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN \dw \DE BELEWS CK FIG 1-1 USGSTOPO.d,g IN FEET GWA- V i ° MIDDLETON LOOP ROAD SB5� I NS]\ mum mom ;i m SB 4 IC OUTLET I I EW 2 ITW 4; �i� b0_ / STRUCTURE T TW-2 T GWA-20SA ��'"��' TW-3\V Viso — — GWA-20D GWA-20BR 4 .r `�`�\ wA z/„sB-2 LEGEND COMPLIANCE BOUNDARY vv A r; vv !' — — — — COMPLAINCE BOUNDARY COINCIDENT WITH PROPERTY LINE ASH BASIN WASTE BOUNDARY 0,//,,,.�r APPROX.ROAD RIGHT OF WAY — — — — DUKE ENERGY CAROLINAS PROPERTY LINE �-� ----- PARCEL A BOUNDARY \\ EXISTING CONCRETE MONUMENT SB-1 4, v 10 �a°mv�v T r .r ��� �r ASH BASIN Ill AMW 17S CSA MONITORING WELL ELEVATION: APPROX. 750' 0 EW-1 EXTRACTION WELL FOR HDR PUMP TEST 770` / n TW-1 TEMPORARY WELL FOR HDR PUMP TEST \\ -.'so. \\ \\ i \' • � SB-1 HDR SOIL BORING G EXISTING AXLE i - \ - / O S-2 AOW -AREA OF WETNESS \ BO NOTES: 1. THE DUKE ENERGY CAROLII PROPERTY LINE, COMPLIANCE BOUNDARY AND WASTE BOUNDARY SHOWN ARE FROM THE HDR SCSA SUPPLEMENT 2. DUKE IS ANTICIPATING COMMENTS FROM DEQ \\ CONCERNING THE COMPLIANCE BOUNDARY. 2. PARCEL A (2.23 ACRES) PROPERTY LINE IS BASED ON A PLAT PREPARED BY LDSI TITLED "EXHIBIT MAP \\ / FOR DUKE ENERGY CORPORATION", DATED 09-28-2016, PROJECT NUMBER 4115187, FILE NAME 4115198.DWG. 3. SITE FEATURES AND TOPOGRAPHY OBTAINED FROM MAP PREPARED BY WSP TITLED "MONITORING WELL / LOCATION SURVEY BELEWS CREEK STEAM STATION', JOB NUMBER 1188313A, DATED JULY 22, 2015, FILE NAME "BELEWS GWA FINAL 07-22-15.DWG". \ 4. THE COMPLIANCE BOUNDARY, WASTE BOUNDARY, DUKE ENERGY CAROLINAS PROPERTY LINE, \\ ,' TEMPORARY WELLS, SOIL BORINGS, AND AOW LOCATIONS ARE APPROXIMATE. \ MIDDLETON GRAPH IC SCALE LOOP ROAD 100 0 100 200 FIGURE 1-2 IN FEET SITE LAYOUT 148 RIVER STREET, SUITE 220 DUKE ENERGY CAROLINAS GREEN/ PHONE 64-421-9999LLE, SOUTH ROLINA29601 BELEWS CREEK STEAM STATION / PHONE 864-421-9999 www.synte"aco'p.com 3195 PINE HALL RD Terra PROJECT MANAGIGLER* DATE: PRINTED* BELEWS CREEK, NORTH CAROLINA O F PROJECT MANAGER: E LADY DATE PRINTED: / CHECKED BY: B. MILLER 12/27/2016 2:14 PM P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\dwg\DE BELEWS CK FIG 1.2 SITE LAYOUT.dwg NOTES ) \ l � o 1. CONCENTRATIONS SHOWN ARE FROM APRIL 27, 2016 TO OCTOBER 18, 2016. \o 2. THE 2L FOR BORON IS 700 ug/L. \ S5o 3. J =INDICATES CONCENTRATION REPORTED BELOW PRACTICAL QUANTITATION LIMIT (PQL), BUT ABOVE -� cc z- /i METHOD DETECTION LIMIT (MDL) AND THEREFORE CONCENTRATION IS ESTIMATED. o , /(<, \/ </ \\' m \ m s Ull 60 \ GWA 30S \ J j § \ \ T00 o. \ MIDDLETONop LOOP ROAD A Ole A\ __ 74 �� � OUTLET STRUCTURE �gg ° \\ GWA-27S �, PIPE DISCHARGE I 0 EXTRACTION W — LEGEND ALIGNMENT — NCENTRATION CONTOUR (ug/L) PARCEL A — — — ?o PROPOSED PHASE 1 EXTRACTION WELL (APPROXIMATE) ASH BASIN GMW-18S CSA MONITORING WELL 28 J CONCENTRATION IN ug/L EXISTING CONCRETE MONUMEN )q / , o Z°SF\\ ��� � S-2 SEEP/AREA OF WETNESS (AOW) LOCATION v �% FEW-1 EXTRACTION WELL FOR PUMP TEST "° O 4) TW-1 TEMPORARY WELL FOR PUMP TEST GRAPHIC SCALE r =m 240 0 240 480 FIGURE 2-1 GWA-2os �� ' �� BORON IN SURFICIAL ZONE 84,� \\. / � HORIZONTAL SCALE 1" 240 ° \ GWA-18S 148 STREET, SUITE 220 GREENVILE, SOUTH CARD INA 29601 28J DUKE ENERGY CAROLINAS \\ / PHONE 864-421-9999 LOOP J> BELEWS CREEK STEAM STATION t00P ROAD ) wwwsynterraoorp.Com \ 777 ���� PRO ECTMANAGER DATE: RINTE 2016 BELEWS CREEK, NORTH CAROLINA PROJEC BY. FEIGL C. LADY DATE PRINTED: CHECKED BY: B. WICKER 12/27/2016 2:29 PM P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plar - Design & Dev\30 PERCENT DESIGN\dwg\OE BELEWS CK FIG 2-1 To 2-12 ISOCONTOL NOTES 1. CONCENTRATIONS SHOWN ARE FROM APRIL 27, 2016 TO OCTOBER 18, 201f-1 u~\ 2. THE 2L FOR BORON IS 700 ug/L. 3. J = INDICATES CONCENTRATION REPORTED BELOW PRACTICAL QUANTITATION LIMIT (PQL), BUT ABOVE X� METHOD DETECTION LIMIT (MDL) AND THEREFORE WIl I / CONCENTRATION IS ESTIMATED. � f e) Aso �9 j �- GWA-30D � J GWA-21D IDDI FTON 69..4 Ex STING AXLE \ v \ r / „ - OUTLET TW � Tw-z. STRUCTURE w-3 I \ GW 5301D o ' o I TC- I DISCHARGE �— -.. PIPE ,60 � �s°m�\ ' ! iI � ��� ♦ LEGEND �o vv .�lI // ; EXTRACTION WELL � BORON ISOCONCENTRATION CONTOUR (ug/L) r ALIGNMENT � � � PARCEL A v - // PROPOSED PHASE 1 EXTRACTION WELL (APPROXIMATE) 3D GWA-19D 9 ion �i��t ASH BASIN GMW-18D CSA MONITORING WELL EXISTING CTE MONUMENT <50 CONCENTRATION IN ug/L ONC SEEP/AREA OF WETNESS (AOW) LOCATION EW-1 EXTRACTION WELL FOR PUMP TEST �� FT—W-11 TEMPORARY WELL FOR PUMP TEST z o A\ GRAPHIC SCALE P �m VV asp / / 240 HORIZONTAL SCALE 1'40 40 480 '� > , .GWA-1oD vv / � FIGURE 2-2 BORON IN TRANSITION ZONE GREE VERSTSOUTHCAR LIN DUKE ENERGY CAROLINAS GWA-18D GREENVILLE, SOUTH CAROLINA 29601 <50 PHONE 864-421-9999 LooPROAD N ) wwwsVIP ynterraoorp.Com BELEWS CREEK STEAM STATION [a DRAWN BY: A. FEIGL DATE:12/14/2016 BELEWS CREEK, NORTH CAROLINA PRO J ECT MANAGER: C. LADY DATE PRINTED WTe r CHECKED BY: B. WILKER 12/27/2016 2:29 PM P:\Duke Energy Progress.1026\20, BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plar - Design & Dev\30 PERCENT DESIGN\dwg\OE BELEWS CK FIG 2-1 To 2-12 ISOCONTOL NOTES 1. CONCENTRATIONS SHOWN ARE FROM APRIL 27, 2016 TO OCTOBER 18, 2016. 2. THE 2L FOR BORON IS 700 ug/L. 3. NO BORON EXCEEDANCES OF 2L IN BEDROCK ZONE. 4. J = INDICATES CONCENTRATION REPORTED BELOW PRACTICAL QUANTITATION LIMIT (PQL), BUT ABOVE METHOD DETECTION LIMIT (MDL) AND THEREFORE CONCENTRATION IS ESTIMATED. \ 660 rn osm t la8° v �v\ I EXIST osm \\\\\ 1a i r T 7,_. WA-19BR 28.6J \ % EXISTING CONCRETE MONUMENT —770 _ a �6° wsosm �\ e! a MIDDLETON „„ y'LOOP ROAD 11 0 r MIDDL�ON \ LOOP ROAD j DISCHARGE PI PE 0 \\ a LEGEND PARCEL A PROPOSED PHASE 1 EXTRACTION WELL (APPROXIMATE) ASH BASIN GMW-20BR CSA MONITORING WELL 51 CONCENTRATION IN ug/L S-2 SEEP/AREA OF WETNESS (AOW) LOCATION E-W 1 EXTRACTION WELL FOR PUMP TEST TW-1 TEMPORARY WELL FOR PUMP TEST GRAPHIC SCALE 240 0 240 480 FIGURE 2-3 HORIZONTAL=24 BORON IN BEDROCK ZONE 148 RIVER STREET,,SUITE 220 GREENVILLE,SOUTH CAROLINA296O1 DUKE ENERGY CAROLINAS PHONE s6,,,c,r .com BELEWS CREEK STEAM STATION 999 ww w. syn to r ra c o r p. c o m Terra PRO ECT MANAGER DATE PRINTED* 2016 BELEWS CREEK, NORTH CAROLINA S� PROJECT BY: B. ILK LADY DATE 12/27/ 0162 CHECKED BY: B. WICKER 12/27/2016 2:29 PM P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\dwg\DE BELEWS CK FIG 2-1 To 2-12 ISOCONTOUR: (EXTRACTION WELL ALIGNMENT NOTES 1. CONCENTRATIONS SHOWN ARE FROM APRIL 27, 2016 TO OCTOBER 18, 2016. D I 0 2. THE 2L FOR CHLORIDE IS 250 mg/L. \ 0 345 3. J = INDICATES CONCENTRATION REPORTED BELOW PRACTICAL QUANTITATION LIMIT (PQL), BUT ABOVE METHOD DETECTION LIMITON IS ( ED.) AND THEREFORECONCEN s 1f 1� I "b VQ \\ MIDDLETON LOOP ROAD �jn5P '._�'eo' EXISTING AXLE , Ir V\�V�� EW-2 Twn ii STIR CTURE ,TW-2- /I I o. 1\ A DISCHARGE GWA-27S — - PIPE 3 LEGEND EXTRACTION WELL _ _ _ _ CHLORIDE ISOCONCENTRATION CONTOUR (mg/L) ALIGNMENT PARCEL A PROPOSED PHASE 1 EXTRACTION WELL (APPROXIMATE) 3p GWA sss'� \ � - ASH aaslN GMW 18S CSA MONITORING WELL 157 �\, : , / 21.5 CONCENTRATION IN mg/L EXISTING CONCRETE MONUMENT -- vv SEEP/AREA OF WETNESS (AOW) LOCATION �sn " FEW-1 EXTRACTION WELL FOR PUMP TEST ,� \v "°- �0 0TW-1 TEMPORARY WELL FOR PUMP TEST A GRAPHIC SCALE 240 0 240 480 G2i5 FIGURE -� HORIZONTAL SCALE I"=240� ys\\ 148RIVERSTREET,SUITE220 CHLORIDE IN SURFICIAL ZONE mV"\ GREENVILLE,SOUTHCAROLINA29601 DUKE ENERGY CAROLINAS so \ L ODLETDu 864-421-9999BELEWS CREEK STEAM STATION PHO ���� synterracorp.ComLOOP ROADCIDRABY A FEIGL DATE 12/14/2D16 BELEWS CREEK, NORTH CAROLINA S� PROJECT MANAGER. C. LADY DATE PRINTED: ik�t� CHECKED BY: B. WICKER 12/27/2016 2:29 PM -- - �' - - P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plar - Design & Dev\30 PERCENT DESIGN\dwg\OE BELEWS CK FIG 2-1 To 2-12 ISOCONTOL NOTES 1. CONCENTRATIONS SHOWN ARE FROM APRIL 27, 2016 TO OCTOBER 18, 2016.o 2. THE 2L FOR CHLORIDE IS 250 mg/L. 3. J = INDICATES CONCENTRATION REPORTED BELOW PRACTICAL QUANTITATION LIMIT (PQL), BUT ABOVE METHOD DETECTION LIMIT (MDL) AND THEREFORE �- CONCENTRATION IS ESTIMATED. I 0 0 S_03 Aso �9 GWA 30D J LIDDI OOP- �voft.I � V. 740EXISTING AXLE 1 .4TW-1 0 / OUTLET -'-��MEN U I Tw-4�T w-2 STRUCTURE �2 GWA-31D y 9 1.9 PIPE DISCHARGE LEGEND i EXTRACTION WELL ALIGNMENT m L) _ _ _ _ CHLORIDE ISOCONCENTRATION CONTOUR ( � 1 (/ � � • �a �v �; /y — PARCEL A Nx� PROPOSED PHASE 1 EXTRACTION WELL APPROXIMATE GWA19D 9 �\v ASH BASIN GMW-18D CSA MONITORING WELL �v , 7.9 CONCENTRATION IN mg/L EXISTING GONER ErEnnoN 2 SEEP/AREA OF WETNESS (AOW) LOCATION EW-1 EXTRACTION WELL FOR PUMP TEST "° / �0 �. 4) TW-1 TEMPORARY WELL FOR PUMP TEST vv� of GRAPHIC SCALE 240 NORrzoNrALSCALE r404o4so FIGURE 2-5 CHLORIDE IN TRANSITION ZONE \>o o\ 148RIVER STREET, SUITE 22o so�m\\ � GW7.9 GREENV61- SOUTH9999 OLINA29601 DUKE ENERGY CAROLINAS vEss4421-99s9 BELEWS CREEK STEAM STATION \ J> PHONE LOOP ROAD ) wwwsynterracorp.com NTED ���� DRAWN BY A FEIGL DATE:12/14/2016 BELEWS CREEK, NORTH CAROLINA PROJECT MANAGER B.WICKER 12/27/DATE 0162 CHECKED BY: B. WICKER 12/27/2016 2:29 PM P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan -Design & Dev\30 PERCENT DESIGN\dwg\OE BELEWS CK FIG 2-1 To 2-12 ISOCONTOL oMOM � NOTES l~^ 1. CONCENTRATIONS SHOWN ARE FROM APRIL 27, 2016 TO OCTOBER 18, 2016.o� 2. THE 2L FOR CHLORIDE IS 250 mg/L. 3. NO CHLORIDE EXCEEDANCES OF 2L IN BEDROCK ZONE. 4. J =INDICATES CONCENTRATION REPORTED BELOW PRACTICAL QUANTITATION LIMIT (PQL), BUT ABOVE METHOD DETECTION LIMIT (MDL) AND THEREFORE CONCENTRATION IS ESTIMATED. _ 1 f� A k iI OS03 GW2.9BR v WH ��� ��.A__ �•` �, �� 'i; MIDDLETON LOOP ROAD V \. \\ --- EXISTING TW_1 / OUTLET 0-2 W�1 STRUCTURE 77 EW 2 i T\N_2 C,I t WA2 BR ! =� PIPEHARGE �10 IGWA-27BR } 0 I 0 0 EXTRACTION WELL LEGEND ALIGNMENT _ PARCEL A rD �o ® PROPOSED PHASE 1 EXTRACTION WELL (APPROXIMATE) \ L 9 19BR �\ 3 5.ASH aaslN GMW-20BR CSA MONITORING WELL 26.4 CONCENTRATION IN mg/L EXISTING CONCRETE MONUMENT-- vv SEEP/AREA OF WETNESS (AOW) LOCATION FEW-1 EXTRACTION WELL FOR PUMP TEST "°- �-0 0 �.0 FTW--ll TEMPORARY WELL FOR PUMP TEST o - m GRAPHIC SCALE I 240 0 240 480 148RIVERIZSUSCALE1_ FIGURE2'6 HORIZONTAL SCALE 1' - 240' CHLORIDE IN BEDROCK ZONE % s \\ MI GREENVILLE SOUTH CAROLINA 29601 o=m !' ) STREET, DUKE ENERGY CAROLINAS OP ROAN 1 PHONE864421-9999 BELEWS CREEK STEAM STATION /,✓/ _\\ / ' LOOPI ROAD 7i wwwsynterracorp.Com _/ - �\ _ / _ \\ / I ) ���� BRAWNBVAFUGL DATE'12/14/2016 BELEWS CREEK, NORTH CAROLINA -�'� ,� PROJECT MANAGER WI CER DATE PRINTED 12/27/0162 CHECKED BY. B. WICKER 12/27/2016 2:29 PM -- - - - - P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCPAccelerated Rem, Interim Action Plar - Design & Dev\30 PERCENT DESIGN\dwg\OE BELEWS CK FIG 2-1 To 2-121SOCONTOURS.dwg NOTES X��~� o w 1. CONCENTRATIONS SHOWN ARE FROM APRIL 27, 2016 TO OCTOBER 18, 2016. ; 2. THE 2L FOR SELENIUM IS 20 ug/L. 3. J = INDICATES CONCENTRATION REPORTED BELOW PRACTICAL QUANTITATION LIMIT (PQL), BUT ABOVE \ I 1 METHOD DETECTION LIMIT (MDL) AND THEREFORE CONCENTRATION IS ESTIMATED. � a 0.41J MIDDL�ON OOP _�. LROAD ���, V\ '�o I — — \ \\\ 74o EXISTING AXLE ws m\\ I I Tw-1 EW o \V / „ / OUTLET �- EW 2 nv a� 2 STRUCTURE / \A GWA-20SA 3 „rws WA- 1:S ° I % -�/ DISCHARGE <0. �m - GWA-27S PIPE 0 a y� LEGEND /� t EXTRACTION WELL ALIGNMENT — SELENIUM ISOCONCENTRATION CONTOUR (ug/L) '. EXISTING CONCRETE MONUMENT � \ \ ° o GWA-10S s\\ GWA-18S 31.8 �. / 0.53 a ° !\ \\ / MIDDLETON ROAD r — PARCEL A PROPOSED PHASE 1 EXTRACTION WELL (APPROXIMATE) ASH BASIN GMW 18S M CSA MONITORING WELL CONCENTRATION IN ug/L S-2 SEEP/AREA OF WETNESS (AOW) LOCATION EW 1 EXTRACTION WELL FOR PUMP TEST TW 1 TEMPORARY WELL FOR PUMP TEST GRAPHIC SCALE 240 0 240 480 FIGURE 2-7 HORIZONTAL SELENIUM IN SURFICIAL ZONE ,SUITE220=24° 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 DUKE ENERGY CAROLINAS 999 PHONE s6rracor .com ww w. syn to r ra c o r p. c o m BELEWS CREEK STEAM STATION Terra DRAWN DATE 2016 BELEWS CREEK, NORTH CAROLINA PROJECT MANAGER LADY DATE PRINTED* CHECKED BY: B. WICKER 12/27/2016 2:29 PM BY: B. ILK 12/27/ 0162 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan -Design & Dev\30 PERCENT DESIGN\dwg\DE BELEWS CK FIG 2-1 To 2-12 ISOCONTOURS.tlwg 1� ��� NOTES l~^�- 1. CONCENTRATIONS SHOWN ARE FROM APRIL 27, 2016 TO OCTOBER 18, 2016.o �— 2. THE 2L FOR SELENIUM IS 20 ug/L.Al 3. NO SELENIUM EXCEEDANCES OF 2L IN TRANSITION ZONE. 4. J =INDICATES CONCENTRATION REPORTED BELOW �. PRACTICAL QUANTITATION LIMIT (PQL), BUT ABOVE METHOD DETECTION LIMIT (MDL) AND THEREFORE CONCENTRATION IS ESTIMATED. NM� J AV 's°gym 'I��� s '�1!� � 'oo jjl MIDDLETON -\�\ LOOP ROAD V \. 1'- - 74 EXISTING AXLE \ a r som\V II /TW-�/ OUTLET - -��/� V A\ C I - EW-2 TW-4 STRUCTURE C, GWA 1 r � 0.83 GW051D,& �1 PIPEHARGE 7 0 I °mv� EXTRACTION WELL LEGEND ALIGNMENT _ PARCEL A PROPOSED PHASE 1 EXTRACTION WELL (APPROXIMATE) J ,asH aaslN � GMW-18D CSA MONITORING WELL <0.5 CONCENTRATION IN ug/L EXISTING CONCRETE MONUMENT /.. -- °� SEEP/AREA OF WETNESS (AOW) LOCATION FEW-1 EXTRACTION WELL FOR PUMP TEST "°- �0 0 �.0 TW-1 TEMPORARY WELL FOR PUMP TEST v o GRAPHIC SCALE 240 0 240 480 HORIZONTAL SCALE I 240 FIGURE 2-8 SELENIUM IN TRANSITION ZONE ° 148 RIVER STREET, SUITE 220 s m \f GWA-18D GREENVILLE SOUTH CAROLINA 29601 DUKE ENERGY CAROLINAS <0.5 � PHONE 864 421-9999 lv� LOOP Rono wwwsynterracorp.Com BELEWS CREEK STEAM STATION Lo �� DRAWN BY: A. FEIGL DATE:12/14/2016 BELEWS CREEK, NORTH CAROLINA PROJECT MANAGER: C. EADY DATE PRINTED: CHECKED BY: B. WICKER 12/27/2016 2:29 PM V / P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan -Design & Dev\30 PERCENT DESIGN\dwg\OE BELEWS CK FIG 2-1 To 2-12 ISOCONTOL NOTES l~^�- 1. CONCENTRATIONS SHOWN ARE FROM APRIL 27, 2016 TO OCTOBER 18, 2016.o� 0 2. THE 2L FOR SELENIUM IS 20 ug/L.px" ,� `~ 3. NO SELENIUM EXCEEDANCES OF 2L IN BEDROCK ZONE. ;I', °°m X - \ �� 4. J = INDICATES CONCENTRATION REPORTED BELOW V ��°'Wij PRACTICAL QUANTITATION LIMIT (PQL), BUT ABOVE METHOD DETECTION LIMIT (MDL) AND THEREFORE CONCENTRATION IS ESTIMATED. _ go T 0S03 jjl ,jN �°i',\._. \•` �, \ �� 'i, n MIDDLETON -� LOOP ROAD740- \ \. VA ms mVV �' � „o I TW 1 EW-1 STRUCTOUTLET URE - �� C EW 2 i Tw_2 /=; TW-3 ° 1 — DISCHARGE PIPE /760 I EXTRACTION WELL LEGEND ALIGNMENT — PARCEL A z° OO PROPOSED PHASE 1 EXTRACTION WELL (APPROXIMATE) �. WA-19BR� �\ a° 0.52 \ v - ASH aaslN GMW-20BR CSA MONITORING WELL y�v, 0.59 CONCENTRATION IN ug/L EXISTING CONCRETE MONUMENT /.. - vv SEEP/AREA OF WETNESS (AOW) LOCATION 0 EW-1 EXTRACTION WELL FOR PUMP TEST "°- �0 0 �.0 TW 1 TEMPORARY WELL FOR PUMP TEST o - m GRAPHIC SCALE I 240 0 240 480 148RIVERSTREIZ SUSCALE1_ FIGURE2'9 HORIZONTAL SCALE 1' - 240' ITE 220 SELENIUM IN BEDROCK ZONE MI GREENVILLE SOUTH CAROLINA 29601 =m ) DUKE ENERGY CAROLINAS OP ROAN 1 wHONE864421p.com BELEWS CREEK STEAM STATION /,✓/ _\\ / ' LOOPI ROAD 7i wwwsynterracorp.Com BRAWNBYAFEIGL DATE'12/14/2016 BELEWS CREEK, NORTH CAROLINA 4 ier� PROJECT MANAGER C. EA BY DATE PRIMED' CHECKED BY. B. WILKER 12/27/2016 2:29 PM -- - — - P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCPAccelerated Rem, Interim Action Plar - Design & Dev\30 PERCENT DESIGN\dwg\OE BELEWS CK FIG 2-1 To 2-121SOCONTOURS.dwg NOTES 1. CONCENTRATIONS SHOWN ARE FROM APRIL 27, 2016 TO OCTOBER 18, 2016. 2. THE 2L FOR TDS IS 500 mg/L. 3. J -INDICATES CONCENTRATION REPORTED BELOW PRACTICAL QUANTITATION LIMIT (PQL), BUT ABOVE ��� j �,� METHOD DETECTION LIMIT (MDL) AND THEREFORE CONCENTRATION IS ESTIMATED. I e) k ill ` 0723 �OAD A \ „o - IXISTING AXLE741 OUTLET ° �VV EW-2 nv 4 na-2 0 1 2osn _ c t GWA-27S � 7 � � • DISCHARGE- �\ 108 w PIPE LEGEND o= EXTRACTION WELL — — — — TDS ISOCONCENTRATION CONTOUR (mg/L) v ` « ALIGNMENT PARCEL A PROPOSED PHASE 1 EXTRACTION WELL (APPROXIMATE) 3D G 29ASH BASIN GMW-18S CSA MONITORING WELL 019S , 21.5 CONCENTRATION IN mg/L EXISTING CONCRETE MONUMENT � ��.. - SEEP/AREA OF WETNESS (AOW) LOCATION \ OFEW-11 EXTRACTION WELL FOR PUMP TEST 770 o o 4) TW-1 TEMPORARY WELL FOR PUMP TEST GRAPHIC SCALE 240 0 240 480 FIGURE 2-10 Gw53 s� ��y / Gwn1 HORIZGNTALSCALET"=240� TOTAL DISSOLVED SOLIDS (TDS) ° \� 148 RIVER STREET, SUITE 220 ` yyzm\ GREENVILLE,SOUTHCAROLINA29601 IN SURFICIAL ZONE \ ° MIDDLETON PHONE864421-9999 DUKE ENERGY CAROLINAS LOOP ROAD wwwsynterra.o'com g / / synTerra BELEWS CREEK STEAM STATION DRAWN BY A FEIGL DATE: 12/14/2016 PROTECT MANAGER: C. LADY DATE PRINTED: BELEWS CREEK NORTH CAROLINA \\ CHECKED BY: B. WILKER 12/27/2016 2:29 PM P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan -Design & Dev\30 PERCENT DESIGN\dwg\OE BELEWS CK FIG 2-1 To 2-121SOCONTOL NOTES 1. CONCENTRATIONS SHOWN ARE FROM APRIL 27, 2016 TO OCTOBER 18, 2016.o 2. THE 2L FOR TDS IS 500 mg/L.� 3. J = INDICATES CONCENTRATION REPORTED BELOW °m X,—�; PRACTICAL QUANTITATION LIMIT (PQL), BUT ABOVE METHOD DETECTION LIMIT (MDL) AND THEREFORE CONCENTRATION IS ESTIMATED. O g_p3 �O� i GWgD1D :If VV X.� MIDDLETON ! LOOP ROAD i �o n"o V\ EXI SIINGAXLE i ---------------- / , OU�C 1� C, �lqi i GW 120 D ��rw� Jam• r T y �\ GW971D PIPEHARGE — ---�� LEGEND EXTRACTION WELL — — — — TDS ISOCONCENTRATION CONTOUR m L v I ALIGNMENT ( ) PARCEL A PROPOSED PHASE 1 EXTRACTION WELL (APPROXIMATE) ASH BASIN GMW-18D CSA MONITORING WELL c so v �vA 94 CONCENTRATION IN mg/L o\' ExISTINGcoNCR MONUMENT SEEP AREA OF WETNESS (AOW) LOCATION *FEW 1 EXTRACTION WELL FOR PUMP TEST v 70_ 00 4) TW-1 TEMPORARY WELL FOR PUMP TEST s 24o GROAPHIC SCALE 40 480 FIGURE 2-11 HORIZONTAL SCALE I°=24G TOTAL DISSOLVED SOLIDS (TDS) a 148 RIVER STREET, SUITE 220 IN TRANSITION ZONE som\f GWA-18DN GREENV64- SOUTH9999 OLINA29601 DUKE ENERGY CAROLINAS \� \\/) �\ / � 94 PHONE 864 4219999 �% �\ �< Loop ROAD WWW,synterracorp.com BELEWS CREEK STEAM STATION Tura DRAWN BY A PEER DATE PRINTED 2016 BELEWS CREEK, NORTH CAROLINA oynPROJECT MANAGER C. LADY DATE PRINTED: / CHECKED BY: B. WILKER 12/27/2016 2:29 PM PADuke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & 0ev\30 PERCENT DESIGN\dwg\DE BELEWS CK FIG 2-1 To 2-12 ISOCONTOL lj NOTES 1. CONCENTRATIONS SHOWN ARE FROM APRIL 27, 2016 TO OCTOBER 18, 2016. 2. THE 2L FOR TDS IS 500 mg/L. l 3. NO TDS EXCEEDANCES OF 2L IN BEDROCK ZONE. 4. J = INDICATES CONCENTRATION REPORTED BELOW PRACTICAL QUANTITATION LIMIT (PQL), BUT ABOVE METHOD DETECTION LIMIT (MDL) AND THEREFORE CONCENTRATION IS ESTIMATED. \\ Tao-- sm \\\\\ AAa I 3p 83 \ \� \\ EXISTING CONCRETE MONUMENT `'�--7,o _ a Aso wZ0s,n we a „„MIDDLETON i\\'LOOP ROAD D s 0 0 o � \III. r LO PRDA LOOP ROAD I I - i JR, rw4 \ • DISCHARGE \ PI PE (EXTRACTION WELL ALIGNMENT a LEGEND PARCEL A PROPOSED PHASE 1 EXTRACTION WELL (APPROXIMATE) ASH BASIN GMW-20BR CSA MONITORING WELL 191 CONCENTRATION IN mg/L S-2 SEEP/AREA OF WETNESS (AOW) LOCATION FEW-1 EXTRACTION WELL FOR PUMP TEST TW 1 TEMPORARY WELL FOR PUMP TEST GRAPHIC SCALE 240 40480 FIGURE 2-12 HORIZONTAL SCALE 140 TOTAL DISSOLVED SOLIDS (TDS) IN BEDROCK ZONE 148RIVER STREET, SUITE 22O GREENVILLE, SOUTH CAROLINA 29601 PHONE864-421-9999 DUKE ENERGY CAROLINAS w.syRAWNBnt.FEIGLrp.com BELEWS CREEK STEAM STATION DRAWNBMANAGER DDATE ATE:12/14/2016 PROJECT LADY Terra S4n BELEWS CREEK, NORTH CAROLINA CHECKED BY: B. WICKER 12/27/2016 2:29 PM BY: B. ILK 12/27/ 0162 P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\dwg\DE BELEWS CK FIG 2-1 To 2-12 ISOCONTOUR: PROPEF I I- � 1 I 760.- II II I II II II II II I II PARCEL A I I 'Y LINE T I I 11 rr �o j O l (YIJJ,/ APPROXIMATE ROAD RIGHT OF WAY / r r;' r / /r C J / rL o=� o 0 synTerra ;160 / CONTROL /PANEL POWER POLE / TW-1 �+ _FENCE/ =S) i TW //-4 EW 1 pH ADJUSTMENT J /� EQUIPMENT EW-2 ' �� TW-2 DISCHARGE GWA-20SA �� /t) TW-3 PIPE l` GWA-20D GWA-20BR Q i O i i O t° GATE ov i� I 1 7 fi -\ /o \� ^^ EXTRACTION WELL ALIGNMENT ASH BASIN LEGEND DUKE ENERGY CAROLINAS PROPERTY LINE (SURVEYED) ® PROPOSED PHASE 1 EXTRACTION WELL (APPROXIMATE) PROPOSED INTERIM ACTION MONITORING WELL (APPROXIMATE) 9 FAMW-17S CSA MONITORING WELL Lo EW-1 EXTRACTION WELL FOR HDR PUMP TEST 4) TW-1 TEMPORARY WELL FOR HDR PUMP TEST SITE FEATURES AND TOPOGRAPHY OBTAINED FROM MAP PREPARED BY WSP TITLED r "MONITORING WELL LOCATION SURVEY BELEWS CREEK STEAM STATION', JOB NUMBER 1188313A, TrY DATED JULY 22, 2015, FILE NAME "BELEWS GWA FINAL 07-22-15.DWG". PARCEL A (2.23 ACRES) PROPERTY LINE IS BASED ON A PLAT PREPARED BY LDSI TITLED "EXHIBIT MAP FOR DUKE ENERGY CORPORATION', DATED 09-28-2016, PROJECT NUMBER 4115187, FILE NAME 4115198.DWG 50 GRAPHIC O50100 FIGURE 3-1 IN FEET PHASE 1 REMEDIATION SYSTEM LAYOUT 148 RIVER STREET, SUITE 220 DUKE ENERGY CAROLINAS GREENPHONE 64-421-9999LLE, SOUTH ROLINA29601 BELEWS CREEK STEAM STATION PHONE 864-421-9999 www.bynterracurp.com 3195 PINE HALL RD PROJECT RAWN OJECTM MANAGER DATE: PRINTED BELEWS CREEK, NORTH CAROLINA PROJECT MANAGER: C. FADY DATE PRINTED: LAYOUT: FIG 3-1 REMEDIATION SYSTEM 12/27/20162:30 PM CONCRETE VAULT SEE FIGURE 5-1 FOR MORE DETAILS ,I WELL SEAL j CASING CENTRALIZER/ (MINIMUM OF 2) n ROXIMATE WATER TABLE HIGH LEVEL LOW MPETENT BEDR( 5555' BGS r r////////ELECTRIC"N D / INSTRUMENTATION CONDUIT / -�__ II I I / I, I, I DISCHARGE PIPE/ I j a CONCRETE GROUT TO SEAL VAULT I I I II I a WELL PIPE GUIDES (MINIMUM OF 2) r I I < CEMENT WITH 5 % SENTONITE I j a 10" BOREHOLE REGOLITH II I� 6" WELL CASING II II TOP OF TRANSITION ZONE APPROXIMATELY45' BGS I II , II , II , II TRANSITION ZONE -APPROXIMATELY 10' L� RESSURE TRANSDUCER CABLE_ =LL PUMP POWER CABLE WELL PUMP 1 FEET NOT TO SCALE FIGURE 3-2 EXTRACTION WELL SCHEMATIC 148 RIVER STREET, SUITE 220 BELEWS CREEK STEAM STATION GREENVILLE, SOUTH CAROLINA 29601 PHONE864-421-9999 DUKE ENERGY CAROLINAS, LLC www.synterracorp.com 3195 PINE HALL RD Terra DRAWN BY NAG R C. EAIN DATE PRINTED 2016 !� PROJECTMANAGERCHE 1DATE 2/27/ 016 BELEWS CREEK NORTH CAROLINA LAYOUT: FIG 3-2 WELL SCHEMATIC 12/27/2016 2:23 PM P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\dwg\DE BELEWS CK FIG 3-2 (WELL SCH EMATIC).dwg WELL SEAL WELL CASIN NG VAULT LID SAMPLE PORT ELECTROMAGNETIC FLOW METER CHECK VALVE \ FLOW y /PRESSURE GAUGE THREADED UNION (TYP.) BALL VALVE ETE VAULT GRAVEL SURFACE ELECTRICAL AND -- DISCHARGE PIPE INSTRUMENTATION CONDUIT CONTROL SENSOR CABLES ----------- — -- ----- ------ --------------------- WELL PUMP POWER CABLE I II j DRAIN OPENING IN VAULT I I kA II II II I l NOT TO SCALE 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 www.synterracorp.co m Term DRAWN BY : NAGOHN CHAR:C. EAIN DATE PRINTED INTE 2016 PROJECT FIG 5-1 VAULT EADY DATE 12/27/ 016 2 LAYOUT: FIG 5-1 VAULT 12/27/2016 2:27 PM ))m P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Acceler ISCHARGE PIPE SUMP FIGURE 5-1 TYPICAL BELOW GRADE VAULT BELEWS CREEK STEAM STATION 3195 PINE HALL RD BELEWS CREEK, NORTH CAROLINA Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx TABLES Table 1-1 Summary of Select Constituent Analytical Data in Area of Interest Belews Creek Steam Station Duke Energy Carolinas, LLC, Belews Creek, NC Boron Selenium Chloride TDS ug/L ug/L mg/L mg/L 700 20 250 500 Sample ID Sample Collection Date GWA-1BR 9/28/2016 <50 <0.5 2.9 113 GWA-1D 9/22/2016 26.9 J 0.5 50.7 190 GWA-1S 9/21/2016 428 0.41 J 51.5 94 GWA-10D 9/21/2016 <50 <0.5 21.7 228 GWA-10S 9/21/2016 84.2 31.8 66.1 153 GWA-11D 9/21/2016 69.4 <0.5 203 576 GWA-11S 9/21/2016 379 7.3 157 441 GWA-18D 9/21/2016 <50 <0.5 7.9 94 GWA-18S 4/27/2016 28 J 0.53 21.5 125 GWA-18SA 6/8/2016 112 0.71 56.6 169 GWA-19BR 9/26/2016 28.6 J 0.52 5.9 83 GWA-19SA 9/21/2016 1880 36.8 202 379 GWA-19D 4/28/2016 <50 0.31 J 3 90 GWA-19S 5/11/2016 1320 30.9 157 299 GWA-20SA 9/21/2016 11300 3 486 1240 GWA-20BR 6/20/2016 51 0.59 26.4 191 GWA-20D 9/21/2016 8700 0.83 471 1120 GWA-21D 9/21/2016 125 <0.5 190 545 GWA-21S 9/21/2016 126 6.3 150 267 GWA-27BR 6/16/2016 <50 <5 6 145 GWA-27D 6/16/2016 5420 <5 393 990 GWA-27S 6/17/2016 155 5.8 51.9 108 GWA-30D 9/22/2016 <50 <0.5 3.6 146 GWA-30S 9/22/2016 <50 <0.5 3.9 48 GWA-31D 9/22/2016 <50 <0.5 1.9 97 GWA-31S 9/22/2016 <50 <0.5 2.5 <25 S-2 10/18/2016 236 <1 74 220 S-3 10/18/2016 <50 <1 4.9 120 S-4 10/18/2016 <50 <1 82 270 S-5 10/18/2016 <50 <1 3.4 120 Notes:Prepared by: BDW Checked: CDE * Analytical data provided by HDR, Inc. < = Concentration not detected at or above the reporting limit mg/L = Milligram per liter ug/L = Microgram per liter Analytical Results Analytical Parameter 15A NCAC 02L Standard Reporting Units j = Indicates concentration reported below Practical Quantitation Limit (PQL), but above Method Detection Limit (MDL) and therefore concentration is estimated. - Bold highlighted concentration indicates exceedance of the 15A NCAC 02L Standard. P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\Table 1-1 Data Summary AOI Page 1 of 1 Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx APPENDIX A AQUIFER TESTING ANALYSIS (HDR FIELD INVESTIGATION AND PUMPING TEST REPORT, OCTOBER 6, 2016) Belews Creek Steam Station Ash Basin Accelerated Remediation Interim Action Field Investigation and Pumping Test Report October 6, 2016 Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report TABLE OF CONTENTS i Table of Contents Section Page 1.0 Introduction ....................................................................................................................... 1 2.0 Geology and Hydrogeology ............................................................................................... 2 2.1 Site Geology and Hydrogeology ............................................................................ 2 3.0 Field Investigation and Pumping Test Activities ................................................................ 3 3.1 Soil Borings and Well Installation .......................................................................... 3 3.2 Conditions Encountered During Field Investigation............................................... 3 3.3 Pumping Test Implementation ............................................................................... 4 3.4 Interpretation of Pumping Test Data...................................................................... 6 24-Hour Pumping Test (EW-2) .................................................................. 6 Single Well Pumping Tests (TW-1 and TW-3) ........................................... 7 Overall Pumping Test Activities ................................................................. 7 4.0 Summary of Findings ........................................................................................................ 9 4.1 Findings ................................................................................................................. 9 5.0 References ...................................................................................................................... 11 Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report LIST OF FIGURES, TABLES, AND APPENDICES ii Figures Figure 1 Site Layout Map Figure 2 Interim Action Soil Boring and Well Location Map Figure 3 Cross-Section A-A’ Figure 4 Cross-Section B-B’ Figure 5 Background vs. Time Prior to Pumping Test in Shallow Groundwater Zone Figure 6 Drawdown vs. Time at EW-2 Figure 7 Drawdown vs. Time at TW-1 Figure 8 Drawdown vs. Time at TW-3 Figure 9 Drawdown vs. Time at TW-4 Figure 10 Drawdown vs. Time at GWA-20SA Figure 11 Drawdown vs. Time at GWA-20D Figure 12 Recovery vs. Time at EW-2 Figure 13 Recovery vs. Time at TW-1 Figure 14 Recovery vs. Time at TW-3 Figure 15 Recovery vs. Time at TW-4 Figure 16 Recovery vs. Time at GWA-20SA Figure 17 Recovery vs. Time at GWA-20D Figure 18 Manual Drawdown Measurements at TW-1 Figure 19 Interpretation of EW-2 Recovery Data Figure 20 Interpretation of GWA-20D Drawdown Data Figure 21 Interpretation of TW-2 Drawdown Data Figure 22 Interpretation of EW-1 Drawdown Data Tables Table 1 Well Information Table 2 Pumping Rates and Manual Water Level Measurements at EW-2 Table 3 Range of Water Level and Groundwater Temperature Measurements at EW-2 Table 4 Pumping Rates and Manual Water Level Measurements at TW-3 Table 5 Manual Water Level Measurements at TW-1 (Pumping Rate = 2 gpm) Table 6 Calculated Transmissivity and Hydraulic Conductivity Table 7 Preliminary Well Spacing and Produced Water Volume Table 8 EW-2 Sustained Pumping Sample Results Appendices Appendix A Boring Logs Appendix B Laboratory Analytical Report (EW-2 Sustained Pumping Sample) Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report INTRODUCTION 1 1.0 Introduction This report provides a description of the activities and findings from an interim action field investigation and pumping test performed at the Duke Energy Carolinas, LLC (Duke Energy) Belews Creek Steam Station (BCSS) site located in Belews Creek, North Carolina. The Settlement Agreement (Agreement) between the North Carolina Department of Environmental Quality (NCDEQ) and Duke Energy dated September 29, 2015 required Duke Energy to implement accelerated remediation at BCSS to address off-site groundwater impacts. The Area of Interest (AOI), where groundwater has been impacted by ash basin-related constituents and migrated off-site, is northwest of the ash basin in the area of a 2.23-acre parcel not owned by Duke Energy (Figure 1). In a letter dated March 28, 2016, NCDEQ provided technical direction for accelerated remediation and requested a response from Duke Energy. The BCSS Accelerated Remediation Interim Action Plan (Plan), dated April 30, 2016, was developed and submitted to NCDEQ to provide those responses. The proposed Plan was approved by NCDEQ via the Interim Action Plans Conditional Approval Letter dated July 22, 2016. As proposed in the Plan, the field investigation and pumping test were performed to allow for evaluation of the viability of three potential groundwater remediation approaches to address impacted groundwater within the AOI. The potential options in the Plan were proposed to provide hydraulic control for impacted groundwater migrating toward the 2.23-acre parcel, and are included below. 1. Installation of a groundwater extraction system between the parcel and ash basin. 2. Installation of a subsurface barrier wall (e.g., slurry trench barrier wall, grout curtain, sheet pile barrier wall, or deep soil mixing barrier wall) between the parcel and ash basin. 3. A combination of options 1 and 2. The optimal configuration of a barrier wall and/or location and number of extraction wells will be evaluated through the incorporation of newly acquired data into the groundwater flow model that was constructed for the BCSS Corrective Action Plan (CAP2 model). Further evaluation of the remediation alternatives should be provided in the Basis of Design Report, as requested in the July 22, 2016 Conditional Approval Letter from NCDEQ. The remaining sections of this report provide descriptions of site geology and hydrogeology; the interim action field investigation and pumping test activities; interpretation of the pumping test data; findings; and recommendations for moving forward with accelerated remediation in the AOI at BCSS. Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report GEOLOGY AND HYDROGEOLOGY 2 2.0 Geology and Hydrogeology 2.1 Site Geology and Hydrogeology The BCSS site is located in the Milton terrane of the Piedmont Physiographic Provence; the Dan River Triassic Basin is located approximately 3,000 feet north of the site. Geologic units mapped in the vicinity of the site include alluvium, terrace deposits, sedimentary rocks of the Dan River Basin, a diabase dike, and felsic gneisses and schists with interlayered hornblende gneiss and schist. Alluvial and terrace deposits have not been encountered in boreholes advanced in the area of the BCSS ash basin, but alluvial deposits have been mapped along the unnamed stream north of the ash basin main dam and along the Dan River. The hydrogeologic regime at BCSS is characterized by residual soil/saprolite and weathered rock overlying fractured crystalline rock separated by the transition zone (TZ). Based on the site investigation completed for the Comprehensive Site Assessment (CSA; HDR, 2015), the groundwater system in the natural materials (soil, soil/saprolite, and bedrock) at BCSS is consistent with the regolith-fractured rock system and is an unconfined, connected aquifer system. The BCSS groundwater system is divided into three layers referred to as shallow, deep (TZ), and bedrock to distinguish the flow layers within the connected aquifer. Groundwater flow and transport at the BCSS site can be approximated from the surface topography. A topographic divide along Pine Hall Road separates the ash basin and Pine Hall Road landfill, both located north of the road, from the ash structural fill, coal pile, and power plant, located south of the road. Groundwater flow north of the road is to the north-northwest toward the Dan River, while groundwater flow south of the road is to the south-southeast towards Belews Lake. Additional topographic divides are located west and north of the ash basin approximately near Middleton Loop Road. These divides separate the surface drainage area containing the ash basin from adjacent drainage areas. While the topographic divides generally function as groundwater divides, groundwater flow across topographic divides may occur based on driving head conditions from the ash basin or preferential flow paths within the shallow and/or deep flow layers. In the accelerated remediation AOI, groundwater flows across the topographic divide of Middleton Loop Road to the northwest toward the 2.23-acre parcel and eventually to the Dan River. Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report FIELD INVESTIGATION AND PUMPING TEST ACTIVITIES 3 3.0 Field Investigation and Pumping Test Activities The field investigation and pumping test activities included advancement of four soil borings (SB-1, SB-2, SB-4, and SB-5) along the property boundary and Middleton Loop Road, and installation of two extraction wells (EW-1 and EW-2) and four observation wells (TW-1 through TW-4). The soil borings were advanced to evaluate geologic conditions within the estimated extent of impacted groundwater in the AOI and evaluate target depths for potential groundwater extraction wells. Soil boring and well installation activities were conducted between August 1 and August 30, 2016. The pumping test activities were performed from September 7 to 9, 2016. 3.1 Soil Borings and Well Installation EW-1, TW-1 and TW-2 were installed and screened within the deep (TZ) flow layer. EW-2, TW- 3 and TW-4 were installed with fully-penetrating screens in the shallow flow layer, immediately above the deep flow layer. The soil boring and well locations are depicted on Figure 2 and a summary of well construction details are included in Table 1. Lithologic descriptions are provided on the boring logs in Appendix A. EW-1 was installed with a 6-inch diameter poly-vinyl chloride (PVC) casing and a 10-ft 10-slot screen in the deep flow layer. EW-2 was installed with a 6-inch diameter PVC casing and 30-ft 10-slot screen across the shallow flow layer (i.e., the saturated thickness of soil/saprolite above the deep flow layer). TW-1 and TW-2 were installed with 2-inch diameter PVC casings and 10-ft 10-slot screens in the deep flow layer. TW-3 and TW-4 were installed with 2-inch diameter PVC casings and 20-ft 10-slot screens in the shallow flow layer. A sand filter pack (#2) was installed around the extraction and observation well screens and a hydrated bentonite seal was placed prior to grouting the borehole annulus to the ground surface. Note that existing monitoring wells GWA-20SA and GWA-20D were utilized during the pumping test. Following well installation, and no sooner than 24 hours after installation, development of the observation wells and extraction wells were performed using surging techniques and a submersible pump to remove fines that may have been introduced into the sand pack and to establish communication of the wells with the aquifer. The extraction and observation wells were developed until the extracted water was visibly clear throughout the screened interval, and the water level meter indicated a “hard” (sediment-free) bottom. Pumping test details are provided in the section below. 3.2 Conditions Encountered During Field Investigation Lithology encountered during installation of four soil borings along the western property boundary primarily included low-plasticity silt from approximately 0 to 55 feet below ground surface (ft bgs) with relict foliation and structure identified with increasing depth. Lenses of sandy silt and sandy silt with gravel were identified within the range of 25 to 55 ft bgs in soil borings SB-2, SB-4 and SB-5. Partially weathered and fractured rock was encountered at 54 ft bgs and sound rock was encountered at 59 ft bgs in SB-1. Slightly weathered sound rock was Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report FIELD INVESTIGATION AND PUMPING TEST ACTIVITIES 4 encountered at 59 ft bgs in SB-2 and at 60 ft bgs in SB-4. Partially weathered and fractured rock was encountered at 45 ft bgs in SB-5 and sound rock was encountered at 53 ft bgs. Observation well TW-1 was installed along the western property boundary, immediately downgradient from extraction well EW-1. Silt, sandy silt, and sandy silt with gravel were encountered from 0 to 42 ft bgs during installation of TW-1 and weathered and fractured rock was encountered from 42 to 58 ft bgs. An additional observation well (TW-4) was installed with a fully penetrating screen in the shallow flow layer adjacent to TW-1. Conditions encountered in TW-4 were similar to those encountered during installation of TW-1. During installation of extraction well EW-1, low-plasticity silt and lenses of silty sand were encountered from 0 to 46 ft bgs. Weathered and fractured rock was encountered at 46 ft bgs and sound rock was encountered at 63 ft bgs. Note that the rock was intensely fractured from 50 to 54.5 ft bgs in the boring and the screen was installed at approximately 50 to 60 ft bgs for extraction well EW-1. An additional extraction well (EW-2) was installed approximately 15 ft south of EW-1 and screened within the shallow flow layer from approximately 15 to 45 ft bgs. Conditions encountered in EW-2 were similar to those encountered during installation of EW-1. Conditions encountered during installation of two observation wells (TW-2 and TW-3) located between the extraction well EW-1 and the ash basin were generally similar to those encountered with the other soil borings and extraction wells. Low-plasticity silt with lenses of silty sand with gravel were encountered from 0 to 48 ft bgs. Slightly weathered and fractured rock was encountered at 48 ft bgs and sound rock was encountered at 58 ft bgs. The water table was encountered from approximately 20 to 28 ft bgs in shallow extraction and observation wells installed for the pumping test, and approximately 21 to 29 ft bgs in the deep (TZ) extraction and observation wells. The saturated thickness within the soil/saprolite zone above weathered and fractured rock ranged from approximately 11 to 29 ft at the pumping test site. Other than the sound rock beneath the weathered and fractured rock zone (i.e., the TZ/deep flow layer), there was no unit identified that would impede vertical migration of groundwater flow and contaminant transport. Conditions observed during the interim action field investigation and existing data from the 2015 Comprehensive Site Assessment (CSA) activities (including post-CSA additional assessment activities) were interpreted and geologic cross sections were developed for the transects shown on Figure 2. Section A-A’ shows lithology from the ash basin dam to the southwest across the 2.23-acre parcel and beyond to existing monitoring wells GWA-19S/D/BR (Figure 3). Section B- B’ shows lithology along the alignment of soil borings advanced during the interim action field investigation (Figure 4) between the ash basin and the 2.23-acre parcel. The cross sections indicate a thicker transition in the vicinity of the pumping test area and GWA-20SA/D/BR compared to the north and south ends of the soil boring alignment (i.e., SB-1, SB-3, SB-4 and SB-5), which indicates there may be a preferential flow pathway via the thicker transition zone. This condition corresponds with the direction of the approximate plume shown on Figure 2. 3.3 Pumping Test Implementation Following development of EW-1 and TW-1 through TW-3, a step drawdown test was performed at EW-1. The purpose was to evaluate drawdown in the extraction well to determine a sufficient Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report FIELD INVESTIGATION AND PUMPING TEST ACTIVITIES 5 pumping rate for the constant rate pumping test. The initial pumping rate for the step drawdown test was set to 1 gallon per minute (gpm) and caused significant drawdown. Therefore, the pumping rate was decreased to approximately 0.5 gpm after 45 minutes of pumping. The water level in EW-1 did not stabilize following the drop in pumping rate and eventually was pumped dry after 80 minutes. Following the step drawdown test at EW-1, which indicated a constant rate pumping test would not be suitable using EW-1, shallow observation TW-3 was pumped at approximately 1.25 gpm to evaluate the potential for conducting a pumping test in the shallow flow layer. There was minimal drawdown (approximately 0.3 feet) when pumping from TW-3 at a rate of approximately 1.25 gpm for 45 minutes. Due to the significant drawdown in EW-1 when pumping at only 1 gpm and the minimal drawdown in TW-3 when pumping at 1.25 gpm, EW-2 and TW-4 were installed in the shallow flow layer to perform the pumping test in the shallow flow layer. Subsequently, a step drawdown test was performed at EW-2 starting with a pumping rate of 1 gpm. After approximately 1 hour of pumping at 1 gpm, the drawdown in EW-2 was approximately 4 feet and the water level was generally stable for another 30 minutes. The pumping rate was then increased to approximately 1.5 gpm, the water level continued to drop, and the well was pumped dry after 1 hour. Therefore, the target rate for the constant rate pumping test at EW-2 was determined to be 1 gpm or less such that the target drawdown during the test would be less than 25% of the shallow aquifer thickness. Due to the limited flow observed during the step drawdown test, the pumping test at EW-2 consisted of a 24-hour drawdown period and a recovery period after pumping ceased. The drawdown period began on Wednesday, September 7, 2016, at 1409 hours and ended on Thursday, September 8, 2016, at 1413 hours. The duration of the recovery period was 2 hours and 14 minutes. Drawdown in the extraction well recovered more than 95% during the recovery test period. Head pressure and depth to water readings were collected in extraction wells EW-2 and EW-1 and in observation wells TW-1, TW-3, TW-4, GWA-20SA, and GWA-20D during the pumping test using Level TROLL 700 pressure transducers (15 PSIG). The transducers were placed approximately 2 to 2.5 feet above the bottom of the observation wells and at least 1 foot above the pump intake in EW-2. The hydraulic head in each well was within the pressure range of the transducers. The data were managed using the In-Situ Virtual Hermit net hub and Win-Situ v.5 software installed on a laptop computer. Note that vented pressure transducer cables were used to eliminate barometric pressure effects on head data. The weather was clear and there were no rainfall events before the pumping test, or during the drawdown and recovery periods of the test. The 24-hour pumping test began with a pumping rate of 1.1 gpm based on the step drawdown test results. Shortly following start of the test, drawdown in the well reached and exceeded the “stabilized level” observed during the step drawdown and the pumping rate was decreased to 0.75 gpm and then 0.5 gpm. The pumping rate remained at approximately 0.5 gpm for the remainder of the test and the water level in EW-2 was generally stabilized. The pumping rate was measured using a calibrated bucket and stopwatch. Manual water level measurements were also recorded during the 24-hour pumping test and are provided in Table 2 along with the Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report FIELD INVESTIGATION AND PUMPING TEST ACTIVITIES 6 measured pumping rates throughout the test. The range of water level and groundwater temperature measurements recorded with the Level TROLL pressure transducers during the drawdown and recovery periods of the 24-hour pumping test are provided in Table 3. Prior to stopping the 24-hour pumping test, one water sample was collected from the discharge tubing on Thursday, September 8, 2016, to be analyzed by a North Carolina-certified laboratory. The purpose of collecting the water sample was to obtain concentration data during sustained pumping conditions to aid in design of a water treatment system, if needed. The analytical results are summarized in Table 8 and the laboratory report is provided in Appendix B. In addition to the 24-hour pumping test, single well pumping tests were performed at TW-3 and TW-1 on Friday, September 9, 2016. Due to the greater well yield observed in TW-3 during well development, a single well pumping test was performed at TW-3 to evaluate hydraulic properties in the shallow flow layer between EW-1/EW-2 and the ash basin. The single well pumping test at TW-1 was performed to evaluate hydraulic properties in the deep flow layer along the property boundary and Middleton Loop Road downgradient of EW-1 and EW-2. The single well pumping test at TW-3 was performed as a step drawdown test while manually measuring depth to water in TW-3. The step test reached a maximum pumping rate of 4.25 gpm, which was the capacity of the pump under the present conditions. The pumping rates and measured drawdown for the single well pumping test at TW-3 are provided in Table 4. The single well pumping test at TW-1 was performed as a constant rate test while manually measuring depth to water in TW-1 and surrounding observation wells (EW-1, EW-2, TW-2, TW- 3, TW-4, GWA-20SA, GWA-20D, and GWA-20BR). Water was pumped from TW-1 at a rate of approximately 2 gpm for 3 hours and 33 minutes. The water level measurements for the single- well pumping test at TW-1 are provided in Table 5. 3.4 Interpretation of Pumping Test Data 24-Hour Pumping Test (EW-2) Depth to water measurements were recorded in the extraction and observation wells over a 83 minute period prior to the start of pumping EW-2 on September 7, 2016 and are depicted on Figure 5. The water levels were steady in EW-2, TW-1, TW-3, TW-4, GWA-20D, and GWA- 20SA before the pumping test. During the drawdown period, the pumping rate was manually adjusted to maintain a constant pumping rate of 0.5 gpm in EW-2. Slight fluctuations in the pumping rate are evident in the drawdown data presented in Figure 6. The slight variability in the pumping rate is likely due to the low flow rate used for the pumping test. The transducers in extraction well EW-2 and observation wells TW-1, TW-3, TW-4, GWA-20SA, and GWA-20D were programmed to collect data in the logarithmic mode with a greater density of readings during the early stages of the drawdown test. The transducers were “stepped” when the pump was turned off and the recovery period began to repeat collecting readings at a higher density. Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report FIELD INVESTIGATION AND PUMPING TEST ACTIVITIES 7 The drawdown data collected by transducers in TW-1, TW-3, TW-4, GWA-20SA and GWA-20D are presented in Figures 7 to 11. These figures show that minimal drawdown occurred in observation wells during the test (shallow and deep flow layers). The water level data from the recovery period in Figures 12 to 17 show that significant recovery occurred at EW-2, but again the recovery is considered minimal in the observation wells. An exception was TW-4 (Figure 15) where a significant change in water level occurred between 10 and 20 minutes. This was produced by the transducer slipping several feet in the well. The range of water level measurements in observation wells was on the order of several tenths of a foot while pumping and several hundredths of a foot during recovery. The groundwater temperatures recorded were similar in most of the wells, except that a lower temperature was observed in TW-3 during the background, drawdown, and recovery periods. This may indicate that groundwater in the shallow zone near TW-3 flows at a higher rate and is recharged quicker than other surrounding observation wells. Single Well Pumping Tests (TW-1 and TW-3) The maximum pumping rate (4.25 gpm) during the step drawdown test at TW-3 resulted in 4.89 feet of drawdown in the well. The specific capacity of TW-3 was calculated at 0.87 gpm/foot, which is significantly higher than the conditions observed during the 24-hour pumping test at EW-2, which is located approximately 40 feet downgradient of TW-3. Observations made during installation of TW-3 indicate that there is more sand and gravel in the soil/saprolite layer in this area compared to the soil borings and extraction and other observation wells installed closer to Middleton Loop Road. During the constant rate test at TW-1, drawdown remained generally stable in TW-1 while increasing drawdown was observed in all observation wells used (EW-2, TW-2, TW-3, TW-4, GWA-20SA, and GWA-20D). More drawdown was observed in deep wells EW-1, GWA-20D, and TW-2 compared to the shallow observation wells. However, the observed drawdown in all wells indicates that the shallow and deep flow layers are connected and pumping from the deep layer will draw groundwater from the shallow layer. The water level measurements collected during the TW-1 pumping test are plotted on Figure 18. Overall Pumping Test Activities The Cooper and Jacob (1946) straight-line method (also referred to as modified non-equilibrium equation) was applied to recovery data from the EW-2 shallow flow layer test (Figure 19) and drawdown data from GWA-20D, TW-2 and EW-1 during the TW-1 deep flow layer test (Figures 20 to 22). Since unconfined aquifers behave in a similar manner as confined aquifers, except when delayed yield effects are observed, confined solutions were applied to the late-time pumping test data. The time-drawdown curve for data collected during pumping and recovery periods becomes a straight line on a semi-log diagram. The slope of the line on the semi-log diagram can be used to calculate transmissivity; this is a graphical method used to estimate the hydraulic parameters. The assumptions for applying the Cooper and Jacob method include: o All layers are horizontal and extend infinitely in the radial direction. o The aquifer is homogeneous and isotropic. Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report FIELD INVESTIGATION AND PUMPING TEST ACTIVITIES 8 o Groundwater flow can be described by Darcy’s Law. o Groundwater density and viscosity are constant. o Groundwater flow is horizontal and directed radially towards the well. o The pumping rate is constant. o The extraction well and observation wells are screened over 80% of the Surficial Aquifer thickness. o Drawdown is small compared to the aquifer saturated thickness (<25%). o Head losses through the well screen and pump intake are negligible. The slope of the line applied in the transmissivity equations is from late-time data, as this is when the unconfined aquifer was behaving similarly to a confined aquifer (u<0.05 which is normally satisfied at large time or short distance from the pumping well). Transmissivity and hydraulic conductivity values were calculated for both the shallow and deep flow layers, and are provided in Table 6. The shallow flow layer calculations were verified using AQTESOLV v4.5 (Duffield 2007). Note that the deep flow layer calculations were not verified due to the low number of data points defining the curves. The Neuman (1974) solution was used in AQTESOLV. As shown in Table 6, the calculated transmissivity of the deep flow layer is more than an order of magnitude higher than the transmissivity of the shallow flow layer. The transmissivity of the sand and gravel layers such as those observed at TW-3 in the shallow flow layer were not quantified, but are likely similar to deep flow layer results. Radius of influence for wells screened in the shallow and deep flow layers were calculated using the transmissivity values from the EW-2 and TW-1 pumping tests, and are provided in Table 7. Based on the calculated values, the number of wells required to control impacted groundwater migrating northwest from the ash basin beneath the 2.23-acre parcel not owned by Duke Energy was estimated for the shallow and deep flow layers. As shown in Table 7, it is estimated that 150 extraction wells would be needed to contain the plume in the shallow flow layer, while 20 wells would be needed to contain the plume within the deep flow layer. The estimated volume of extracted water is 108,000 gallons per day for 150 shallow pumping wells (pumping at 0.5 gpm) and 57,600 gallons per day for 20 deep pumping wells (pumping at 2 gpm). Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report SUMMARY OF FINDINGS 9 4.0 Summary of Findings 4.1 Findings Findings of the field investigation and pumping test are summarized below: • Mostly low-plasticity silt with lenses of sandy silt and sandy silt with gravel were observed in the shallow flow layer along Middleton Loop Road between the ash basin and the 2.23-acre parcel. The thickness of the aquifer in the shallow flow layer ranged from 11 to 29 feet. • The thickness of the deep flow layer (i.e., transition zone/partially weathered rock) ranged from approximately 0 to 10 feet in the field investigation and pumping test area. The deep flow layer is thicker is in the vicinity of EW-1, EW-2, GWA-20SA/D, TW-1, and TW-2. The soil borings located to the south and north of the pumping test area indicate the deep flow layer is less thick and there may be a preferential flow pathway that corresponds with the direction of the approximate plume shown on Figure 2. • Hydraulic communication was observed between the shallow and deep flow layers during the pumping test activities. • Using graphical calculation methods and AQTESOLV, the transmissivity in the shallow flow layer based on the drawdown and recovery test results was 6.78 to 13.2 gallons per day/foot (0.9 to 1.8 feet2/day), respectively. These transmissivity values equate to hydraulic conductivities of 0.08 feet per day (2.8 x 10-5 centimeters/second) and 0.04 feet/day (1.41 x 10-5 centimeters/second), respectively. These values are representative of silt and sandy silt (Freeze and Cherry, 1979). • Using graphical calculation methods, the average transmissivity in the deep flow layer based on the TW-1 single pumping test results was 570 gallons per day/foot (76.1 feet2/day), which equates to a hydraulic conductivity of 217 feet/day (7.68 x 10-4 centimeters/second). • Based on drawdown observed in shallow and deep wells during the constant rate test at TW-1, the shallow and deep flow layers are connected and pumping from the deep layer will draw groundwater from the shallow layer. The radius of influence calculations for the deep flow layer indicate that a well spacing of 45 feet would be needed to provide hydraulic control for impacted groundwater migrating offsite in the deep flow layer if pumping at 2 gpm. • Groundwater extraction from the deep flow layer may be a suitable option for controlling impacted groundwater migrating offsite. Options #2 and #3 included in the Interim Action Plan included a subsurface barrier wall. Based on the results of this field investigation and pumping test, its likely extraction wells would be required if a barrier wall option was implemented. Therefore, Options #2 or #3 may not be as feasible as groundwater extraction only. • Given the variability of the hydrogeologic environment, implementation of an extraction system could be performed in phases to further assess conditions in the area. For example, Phase 1 would consist of a well spacing of 180 feet (every 5th extraction well) to further characterize the variability in the flow system. The Phase 1 wells would then Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report SUMMARY OF FINDINGS 10 be pumped for a duration such as four to six months to allow for refinement of extraction well spacing prior to installing additional wells (in Phase 2). To monitor conditions in the AOI, existing monitoring wells could be used along with additional wells as needed. Further evaluation can be performed during Phase 1 to determine if extraction wells screened in the shallow flow layer are needed. Note that due to the shallow and deep flow layers being connected, it is anticipated that as the deep flow layer is dewatered the shallow flow layer will recharge the deep layer and potentially reduce the need for additional extraction wells. Additional extraction wells would be installed and connected to the collection and treatment system during Phase 2. Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report REFERENCES 11 5.0 References Cooper, H.H., Jr. and C.E. Jacob. 1946. A Generalized Graphical Method for Evaluating Formation Constants and Summarizing Well-Field History. Transaction, American Geophysical Union, Vol. 27, No. 4, pp. 526-534. Driscoll, F.G. 1986. Groundwater and Wells. Second Edition. Johnson Division, St. Paul, MN. Duffield, G.M. 2007. AQTESOLV for Windows Version 4.5 User’s Guide. HydroSOLVE, Inc., Reston, VA. HDR. 2015. Comprehensive Site Assessment Report. Belews Creek Steam Station Ash Basin. September 9, 2015. Freeze, R.A. and J.A. Cherry. 1979. Groundwater. Prentice-Hall, Inc. Englewood Cliffs, NJ. Kruseman, G.P. and N.A. deRidder. 1994. Analysis and Evaluation of Pumping Test Data. Second Edition. Publication 47. International Institute for Land Reclamation and Improvement, Wageningen, The Netherlands. Neuman, S.P., 1974. Effect of partial penetration on flow in unconfined aquifers considering delayed gravity response, Water Resources Research, vol. 10, no. 2, pp. 303-312. Figures LLM • mm 41 LEGEND: — — DUKE ENERGY PROPERTY BOUNDARY • ASH BASIN WASTE BOUNDARY .- ... -+--- .. -� _ _ - .. LANDFILL/STRUCTURAL FILL BOUNDARY r �' • ASH BASIN COMPLIANCE BOUNDARY PINE HALL ROAD ASH LANDFILL COMPLIANCE r BOUNDARY J,� f ASH BASIN COMPLIANCE BOUNDARY COINCIDENT WITH DUKE PROPERTY BOUNDARY �' . } ci`r� �;° �T l�' y 4 . : • ,�► '�i i Ohm ;? STREAM • �� ���' y TOPOGRAPHIC CONTOUR NCDEQ SAMPLE LOCATIONS 22 i ASH BASIN VOLUNTARY GROUNDWATER •r 14 MONITORING WELL - • 4g `r h, ,.' ASH BASIN COMPLIANCE GROUNDWATER • MONITORINGWELL •20 2915 E, 1 y r CSA GROUNDWATER MONITORING WELL LOCATION so �, :, .. a�� ` POST CSA GROUNDWATER MONITORING WELL LO•�R - � ' F � � _►- � "'' �'�`'� '���=:��. � a CSA SURFACE WATER AN D/OR SEDIMENT SAMPLE LOCATION CSA AREA OF WETNESS SAMPLE LOCATION -- e- � `_ '-""• - � PUBLIC WATER SUPPLY WELL FIELD IDENTIFIED PRIVATE WATER SUPPLY WELL - a:a RECORDED PRIVATE WATER SUPPLY WELL • �, �t' ASSUMED PRIVATE WATER SUPPLY WELL REPORTED PRIVATE WATER SUPPLY WELL NOTES: 1. PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE. 2. WASTE BOUNDARY IS APPROXIMATE. 3. AS -BUILT MONITORING WELL LOCATIONS PROVIDED BY DUKE ENERGYANDWSP. 4. COMPLIANCE SHALLOW MONITORING WELLS (S) ARE SCREENED ACROSS THE SHALLOW FLOW LAYER. 5. COMPLIANCE DEEP MONITORING WELLS (D)ARE SCREENED IN THE DEEP FLOW LAYER. 6. TOPOGRAPHY DATA FOR THE SITE WAS OBTAINED FROM NCDOTWEB SITE (DATED 2010). 7. AERIAL PHOTOGRAPHY WAS OBTAINED FROM WSP(DATED 2014). S. THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCACO2L.0107 [a}. 9. THE COMPLIANCE BOUNDARY SHOWN ON THIS FIGURE IS FROM THE 2015 COMPREHENSIVE SITE ASSESSMENT REPORTSUBMITTEDTO DEQON SEPTEMBER 9,2015, AND IS NOT REPRESENTATIVE OF RECENT PROPERTY LINE REVISIONS ALONG MIDDLETON LOOP ROAD. 10. PARCEL DATA FOR THE 2.23-ACRE PROPERTY NORTHWEST OF THE ASH BASIN WAS OBTAINED FROM LDSI, INC. (SURVEY DATED SEPTEMBER29,2016). 11. PROPERTY RESEARCH CONDUCTED BY DUKE ENERGY IN AUGUST 2016 INDICATES THAT DUKE ENERGY'S PROPERTYALONG MIDDLETON LOOP ROAD EXTENDSTOTHE2.23-ACRE PARCEL AND INCLUDES THE ROADWAY WHERE DUKE ENERGY PROPERTY EXISTS ON BOTH SIDES OF MIDDLETON LOOP ROAD(i.e.,THE PROPERTY EXTENDSTOAPPROXIMATELY THE CENTER OF THE ROADWAY). SCALE (FEET) 600' 0 600' 1,200' SITE LAYOUT MAP ACCELERATED REMEDIATION AOI DUKE ENERGY CAROLINAS, LLC BELEWS CREEK STEAM STATION ASH BASIN STOKES COUNTY, NORTH CAROB NA DATE 10/06/2016 FIGURE ASH BASIN ELEVATION 750 FT (APPROXIMATE) DUKE ENERGY PROPERTY DUKE ENERGY PROPERTY GWA-18S/D GWA-21S/D GWA-20SA/D/BR GWA-27S/D/BR GWA-30S/D LEGEND: DUKE ENERGY PROPERTY BOUNDARY ASH BASIN WASTE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY ASH BASIN COMPLIANCE BOUNDARY COINCIDENT WITH DUKE PROPERTY BOUNDARY CROSS-SECTION TRANSECT CSA GROUNDWATER MONITORING WELL POST-CSA ADDITIONAL ASSESSMENT GROUNDWATER MONITORING WELL EXTRACTION WELL (INTERIM ACTION) SOIL BORING (INTERIM ACTION) OBSERVATION WELL (INTERIM ACTION) P APPROX. EXTENT OF BORON, CHLORIDE, SELENIUM, OR TDS EXCEEDANCES (FROM ROUND 5 RESULTS) 2.23-ACRE PARCEL NOT OWNED BY DUKE ENERGY NOTES: 1. PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE. 2. SHALLOW MONITORING WELLS (S) ARE SCREENED ACROSS THE SHALLOW FLOW LAYER. 3. DEEP MONITORING WELLS (D) ARE SCREENED IN THE DEEP FLOW LAYER. 4. TOPOGRAPHY DATA FOR THE SITE WAS OBTAINED FROM WSP (DATED 2015). 5. AERIAL PHOTOGRAPHY WAS OBTAINED FROM NCONEMAP (DATED 2014). 6. THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L .0107 (a). 7. THE COMPLIANCE BOUNDARY SHOWN ON THIS FIGURE IS FROM THE 2015 COMPREHENSIVE SITE ASSESSMENT REPORT SUBMITTED TO DEQ ON SEPTEMBER 9, 2015, AND IS NOT REPRESENTATIVE OF RECENT PROPERTY LINE REVISIONS ALONG MIDDLETON LOOP ROAD. 8. PARCEL DATA FOR THE 2.23-ACRE PROPERTY NORTHWEST OF THE ASH BASIN WAS OBTAINED FROM LDSI, INC. (SURVEY DATED SEPTEMBER 29, 2016). 9. PROPERTY RESEARCH CONDUCTED BY DUKE ENERGY IN AUGUST 2016 INDICATES THAT DUKE ENERGY'S PROPERTY ALONG MIDDLETON LOOP ROAD EXTENDS TO THE 2.23-ACRE PARCEL AND INCLUDES THE ROADWAY WHERE DUKE ENERGY PROPERTY EXISTS ON BOTH SIDES OF MIDDLETON LOOP ROAD (i.e., THE PROPERTY EXTENDS TO APPROXIMATELY THE CENTER OF THE ROADWAY). 10/06/2016 INTERIM ACTION SOIL BORING AND WELL LOCATION MAP ACCELERATED REMEDIATION AOI DUKE ENERGY CAROLINAS, LLC BELEWS CREEK STEAM STATION ASH BASIN STOKES COUNTY, NORTH CAROLINA DATE FIGURE 5%#.' 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     C:\pwworking\tpa\d0991874\BCSS_B-B'_Section.dwg, Layout1, 9/30/2016 11:20:30 AM, CHEARN Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report FIGURES       Figure 5. Background vs. Time Prior to Pumping Test in Shallow Groundwater Zone      Figure 6. Drawdown vs. Time at EW‐2  0 5 10 15 20 25 30 35 0 10 20 30 40 50 60 70 80 90 Background (feet) vs. Time (minutes) EW‐2 TW‐1 TW‐3 TW‐4 GWA‐20D GWA‐20SA 0 2 4 6 8 10 12 14 16 0 20 0 40 0 60 0 80 0 1, 0 0 0 1, 2 0 0 1, 4 0 0 1, 6 0 0 Drawdown (feet)  at EW‐2 vs. Time (minutes) Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report FIGURES        Figure 7. Drawdown vs. Time at TW‐1       Figure 8. Drawdown vs. Time at TW‐3   0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 20 0 40 0 60 0 80 0 1, 0 0 0 1, 2 0 0 1, 4 0 0 1, 6 0 0 Drawdown (feet) at TW‐1 vs. Time (minutes) 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 20 0 40 0 60 0 80 0 1, 0 0 0 1, 2 0 0 1, 4 0 0 1, 6 0 0 Drawdown (feet) at TW‐3 vs. Time (minutes) Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report FIGURES        Figure 9. Drawdown vs. Time at TW‐4       Figure 10. Drawdown vs. Time at GWA‐20SA   0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 20 0 40 0 60 0 80 0 1, 0 0 0 1, 2 0 0 1, 4 0 0 1, 6 0 0 Drawdown (feet) at TW‐4 vs. Time (minutes) 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 20 0 40 0 60 0 80 0 1, 0 0 0 1, 2 0 0 1, 4 0 0 1, 6 0 0 Drawdown (feet) at GWA‐20SA vs. Time (minutes) Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report FIGURES        Figure 11. Drawdown vs. Time at GWA‐20D      Figure 12. Recovery vs. Time at EW‐2  0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 20 0 40 0 60 0 80 0 1, 0 0 0 1, 2 0 0 1, 4 0 0 1, 6 0 0 Drawdown (feet) at GWA‐20D vs. Time (minutes) 0 2 4 6 8 10 12 14 0 20 40 60 80 10 0 12 0 Recovery (feet) at EW‐2 vs. Time (minutes) Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report FIGURES        Figure 13. Recovery vs. Time at TW‐1       Figure 14. Recovery vs. Time at TW‐3   0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18 0.2 0 20 40 60 80 10 0 12 0 Recovery (feet) at TW‐1 vs. Time (minutes) 0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18 0.2 0 20 40 60 80 10 0 12 0 Recovery (feet) at TW‐3 vs. Time (minutes) Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report FIGURES        Figure 15. Recovery vs. Time at TW‐4       Figure 16. Recovery vs. Time at GWA‐20SA   0 0.5 1 1.5 2 2.5 0 20 40 60 80 10 0 12 0 Recovery (feet) at TW‐4 vs. Time (minutes) 0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18 0.2 0 20 40 60 80 10 0 12 0 Recovery (feet) at GWA‐20SA vs. Time (minutes) Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report FIGURES        Figure 17. Recovery vs. Time at GWA‐20D      Figure 18. Manual Drawdown Measurements at TW‐1   0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18 0.2 0 20 40 60 80 10 0 12 0 Recovery (feet) at GWA‐20D vs. Time (minutes) 0 2 4 6 8 10 12 14 16 18 0 50 10 0 15 0 20 0 Drawdown (feet) vs. Time (minutes) ‐Pumping TW‐1 TW‐1 GWA‐20D TW‐2 EW‐1 Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report FIGURES         Figure 19. Interpretation of EW‐2 Recovery Data      Figure 20. Interpretation of GWA‐20D Drawdown Data  0 2 4 6 8 10 12 14 0. 0 1 0. 1 1 10 10 0 Recovery (feet)  at EW‐2 vs. Log Time (minutes) EW‐2 Recovery between 13 and 130  minutes (estimated) = 10 ft ܶൌ ଶ଺ସ ௫ ଴.ହ ௚௣௠ ଵ଴ ௙௧ = 13.2 gpd/ft 0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2 0. 0 0 1 0. 0 1 0. 1 1 10 10 0 Drawdown (feet)  at GWA‐20D vs. Log Time (minutes) GWA‐20D Drawdown between 20 and  200 minutes = 0.77 feet ܶൌ ଶ଺ସ ௫ ଶ ௚௣௠ ଴.଻଻ ௙௧ = 685 gpd/ft Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report FIGURES       Figure 21. Interpretation of TW‐2 Drawdown Data      Figure 22. Interpretation of EW‐1 Drawdown Data  0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2 0. 0 0 1 0. 0 1 0. 1 1 10 10 0 Drawdown (feet)  at TW‐2 vs. Log Time (minutes) TW‐2 ܶൌ ଶ଺ସ ௫ ଶ ௚௣௠ ଴.଼ହ ௙௧ = 621 gpd/ft Drawdown between 20 and  200 minutes = 0.85 feet 0 0.2 0.4 0.6 0.8 1 1.2 1.4 0. 0 0 1 0. 0 1 0. 1 1 10 10 0 Drawdown (feet)  at EW‐1 vs. Log Time (minutes) EW‐1 ܶൌ ଶ଺ସ ௫ ଶ ௚௣௠ ଴.଻଻ ௙௧ = 406 gpd/ft Drawdown between 20 and 200  minutes (estimated) = 1.3 feet Tables Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report LIST OF TABLES   1  Table 1. Well Information  Well Groundwater  Flow Layer  Flush  Mount or  Stick‐up  Dia.  (inches)  Distance  to EW‐2  (feet)  Time  (hours)  Static Depth  to Water  (feet‐TOC)  TD  (feet‐ TOC)  Static Water  Column  Height (feet)  EW‐1 deep flush  6 NM 1022 22.53 59.85 37.32  EW‐2 shallow stick‐up 6 NM 1026 25.00 47.72 22.72  TW‐1 deep flush 2 43.9 1036 28.70 56.98 28.28  TW‐2 deep flush 2 NM 1024 20.90 62.40 41.50  TW‐3 shallow flush 2 34.8 1025 19.80 42.30 22.50  TW‐4 shallow stick‐up 2 38.1 1035 30.45 41.10 10.65  GWA‐20SA shallow stick‐up 2 NM 1028 26.00 ‐  ‐  GWA‐20D deep stick‐up 2 20.2 1029 26.72 ‐  ‐  GWA‐20BR bedrock stick‐up 2 26.5 1033 31.60 ‐  ‐  GWA‐20S shallow stick‐up 2 NM 1028 dry ‐  ‐  1‐ not measured           Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report LIST OF TABLES   2  Table 2. Pumping Rates and Manual Water Level Measurements at EW‐2  Time (hours) Pumping Rate  (gpm)  Manual WLs  Measured in EW‐2  (feet‐TOC)  9/7/16 ‐ 1409 1.125 NM  1443 0.75 35.35  1520 0.5 37.90  1600 0.375 38.40  1627 0.35 38.75  1748 0.45 38.95  1900 0.5 39.59  1940 0.4 39.61  2045 0.5 39.53  2200 0.45 39.50  2300 0.5 39.85  2350 0.5 39.95  9/8/16 ‐ 0300 0.4 39.55  0400 0.5 39.58  0545 0.5 39.33  0730 0.5 39.70  1100 0.55 39.29       Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report LIST OF TABLES   3  Table 3. Range of Water Level and Groundwater Temperature Measurements at EW‐2  Well  Maximum  Water Level  Measurement  Recorded   (feet)  Minimum  Water Level  Measurement   Recorded  (feet)  Difference in  Water Level  Measurement   (feet)  Maximum  Groundwater  Temperature  Recorded   (°C)  Minimum  Groundwater  Temperature  Recorded   (°C)  Difference in  Temperature  (°C)  Background Data (83 minutes)  EW‐2 24.972 24.866 0.106 16.356 16.247 0.109  TW‐3 19.810 19.782 0.028 15.373 15.273 0.100  TW‐4 20.467 20.431 0.036 16.415 16.336 0.079  TW‐1 28.724 28.687 0.037 16.120 16.023 0.097  GWA‐20D 26.736 26.704 0.032 16.043 15.957 0.086  GWA‐20SA 26.018 25.975 0.043 16.124 16.008 0.116  Drawdown Test (1,440 minutes)  EW‐2 39.284 24.717 14.567 16.276 16.130 0.146  TW‐3 19.999 19.791 0.199 15.353 15.284 0.069  TW‐4 20.678 20.424 0.254 16.364 16.292 0.072  TW‐1 28.901 28.700 0.201 16.053 16.002 0.051  GWA‐20D 26.913 26.713 0.200 16.002 15.949 0.053  GWA‐20SA 26.403 25.997 0.406 16.082 16.016 0.066  Recovery Test (118 minutes)  EW‐2 36.819 25.728 11.541 16.196 16.121 0.075  TW‐3 20.001 19.918 0.083 15.383 15.285 0.098  TW‐4 20.619 18.126 2.493 16.370 16.215 0.155  TW‐1 28.904 28.854 0.05 16.075 16.001 0.074  GWA‐20D 26.914 26.851 0.063 16.014 15.941 0.073  GWA‐20SA 26.398 26.196 0.202 16.100 15.993 0.107           Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report LIST OF TABLES   4  Table 4. Pumping Rates and Manual Water Level Measurements at TW‐3  DTW  (ft‐TOC)  DD  (ft)  Pumping Rate  (gpm)  19.96 ‐ Initial, 0  20.13 0.17 0.8  21.81 1.85 1.1  22.10 2.14 1.8  22.85 2.89 2.3  24.85 4.89 4.251  1Maximum pumping rate with equipment Du k e E n e r g y C a r o l i n a s , L L C | Be l e w s C r e e k S t e a m S t a t i o n A s h B a s i n A c c e l e r a t e d R e m e d i a t i o n Fi e l d I n v e s t i g a t i o n a n d P u m p i n g T e s t R e p o r t LIST OF TABLES   5   Ta b l e  5.  Ma n u a l  Wa t e r  Le v e l  Me a s u r e m e n t s  at  TW ‐1  ‐   Pu m p i n g  Ra t e  = 2  gp m   We l l   St a t i c   WL   (f e e t ‐ TO C )   Ti m e   (h o u r s )   DT W   (f e e t ‐ TO C ) 1   DD   (f e e t )   Ti m e   (h o u r s )   DT W   (f e e t ‐ TO C )   DD   (f e e t )   Ti m e   (h o u r s )   DT W   (f e e t ‐ TO C )   DD   (f e e t )   Ti m e   (h o u r s )   DT W   (f e e t ‐ TO C )   DD   (f e e t )   Ti m e   (h o u rs )   DT W   (f e e t ‐ TO C )   DD   (f e e t )  Time  (hours) DTW  (feet ‐TOC) DD  (feet)  Me a s u r e m e n t  1   Me a s u r e m e n t  2   Me a s u r e m e n t  3   Me a s u r e m e n t  4   Me a s u r e m e n t  5  Measurement  6   EW ‐1   22 . 5 3   11 2 4   22 . 9 8   0. 4 5  ‐  ‐   ‐   ‐   ‐   ‐   ‐   23 . 5 9   1. 0 6  ‐   23 . 7 2   1.19  ‐  ‐   ‐   EW ‐2   25 . 0 0   11 2 7   25 . 4 0   0. 4  ‐  ‐   ‐   ‐   ‐   ‐   ‐   25 . 4 7   0. 4 7  ‐   25 . 4 8   0.48  ‐  ‐   ‐   TW ‐1   28 . 7 0   11 5 7   45 . 1 5   16 . 4 5   12 5 3   44 . 7 4   16 . 0 4   13 0 7   45 . 2 5   16 . 5 5   13 2 0   45 . 2 5   16 . 5 5   13 5 0   45 . 5 5   16 . 8 5  1409  45.51  16.81   TW ‐2   20 . 9 0   11 3 7   21 . 8 0   0. 9  ‐  ‐   ‐   ‐   ‐   ‐   ‐   22 . 4 5   1. 5 5  ‐   22 . 5   1.6  ‐  ‐   ‐   TW ‐3   19 . 8 0   11 4 2   20 . 0 5   0. 2 5  ‐  ‐   ‐   ‐   ‐   ‐   ‐   20 . 1   0. 3  ‐   20 . 1   0.3  ‐  ‐   ‐   TW ‐4   30 . 4 5   11 5 4   31 . 3 2   0. 8 7  ‐  ‐   ‐   ‐   ‐   ‐   ‐   31 . 0 5   0. 6  ‐   31 . 1   0.65  ‐  ‐   ‐   GW A ‐ 20 S A   26 . 0 0   11 3 1   26 . 3 7   0. 3 7  ‐  ‐   ‐   ‐   ‐   ‐   ‐   25 . 3 4  ‐ 0. 6 6 2  ‐   26 . 4 5   0.45  ‐  ‐   ‐   GW A ‐ 20 D   26 . 7 2   11 2 9   28 . 0 5   1. 3 3  ‐  ‐   ‐   ‐   ‐   ‐   ‐   28 . 4 4   1. 7 2  ‐   28 . 4 9   1.77  ‐  ‐   ‐   GW A ‐ 20 B R   31 . 6 0   11 3 3   31 . 6 5   0. 0 5  ‐  ‐   ‐   ‐   ‐   ‐   ‐   31 . 6 3   0. 0 3  ‐   31 . 6 1   0.01  ‐  ‐   ‐   1 Ma n u a l  Re a d i n g s  wh i l e  pu m p i n g  2. 0  gp m  at  TW ‐1  (d e e p ) ,  10 3 6  ‐   14 0 9  ho u r s  (2 1 3  mi n u t e s )   2 Ba d  da t a  po i n t     Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report LIST OF TABLES   6  Table 6. Calculated Transmissivity and Hydraulic Conductivity  Well  Transmissivity  gpd/ft  (feet2/day)  Hydraulic Conductivity  feet/day  (cm/sec)  Transmissivity  gpd/ft  (feet2/day)  Hydraulic Conductivity  feet/day  (cm/sec)   Shallow Flow Layer – Recovery Test at EW‐2  Graphical Method AQTESOLV1  EW‐2 13.2  (1.8)  0.08  (2.80E‐05)  6.78  (0.9)  0.04  (1.41E‐05)   Deep Flow Layer – Drawdown Test at TW‐1  Graphical Method AQTESOLV  GWA‐20D 685  (91.5)  2.61  (9.23E‐04) ‐‐‐  ‐‐‐  TW‐2 621  (83.0)  2.37  (8.37E‐04) ‐‐‐  ‐‐‐  EW‐1 406  (54.0)  1.54  (5.44E‐04) ‐‐‐  ‐‐‐  Average for   Transition Zone  570  (76.1)  217  (7.68E‐04) ‐‐‐  ‐‐‐  1Neuman (1974) solution for unsteady flow to a fully or partially penetrating well in a homogeneous, anisotropic  unconfined aquifer with delayed gravity response. The Neuman solution is used to analyze both pumping and  recovery data from constant‐rate or variable‐rate pumping tests.       Duke Energy Carolinas, LLC | Belews Creek Steam Station Ash Basin Accelerated Remediation Field Investigation and Pumping Test Report LIST OF TABLES   7  Table 7. Preliminary Well Spacing and Produced Water Volume  Well Spacing1 Number of Wells Required for   Plume Control2  Volume of Produced Water  (gallons per day)3  Shallow Flow Layer – pumping rate = 0.5 gpm  6 feet 150 108,000  Deep Flow Layer – pumping rate = 2 gpm  45 feet 20 57,600  1The radius of influence, r (diameter = well spacing) was calculated as follows (Cooper and Jacob 1946):  ݎൌඨ0.3 ܶݐ ܵ   where:  T = transmissivity (from Table 6.)  t = time, based on pumping test results, it is assumed that steady‐state conditions are reached after pumping one  day in both shallow and deep flow layers  S = storage coefficient, in this case the specific yield (assigned by lithology type). A specific yield of 0.21 was used  for silt (observed in the shallow flow layer), and 0.23 for silt with sand (deep flow layer).    2The number of wells is based on the length of the boron, chloride, selenium or TDS plume in groundwater along  Middleton Loop Road southeast of the parcel of land that is not owned by Duke Energy. In this case, plume control  refers to recovering contaminants that are migrating from the ash basin towards the parcel of land. Note that the  contaminant plume that already exists beyond Middleton Loop Road and beneath the parcel would not be  recovered.      3The volume of produced water = number of wells x pumping rate x time (one day).  Table 8 - EW-2 Sustained Pumping Sample Results (Sample Collected on September 8, 2016) Belews Creek Interim Action Field Investigation and Pumping Test Analyte Method Result (µg/L) Antimony EPA 200.8 < 0.50 Alkalinity SM 2320 B < 5000 Aluminum EPA 200.7 228 Arsenic EPA 200.8 1.7 Barium EPA 200.7 424 Beryllium EPA 200.8 11.5 Boron EPA 200.7 8460 Cadmium EPA 200.8 1.5 Calcium EPA 200.7 141000 Chloride SM 4500 Cl E 496000 Chromium EPA 200.8 0.82 Cobalt EPA 200.8 9.5 Copper EPA 200.8 0.56 Hexavalent Chromium EPA 218.7 < 0.03 Iron EPA 200.7 1560 Lead EPA 200.7 < 5.00 Magnesium EPA 200.7 52700 Manganese EPA 200.7 3720 Mercury EPA 245.1 < 0.20 Methane RSK 175 < 10.00 Molybdenum EPA 200.8 0.83 Nickel EPA 200.8 6.9 Potassium EPA 200.7 7380 Selenium EPA 200.8 6.5 Sodium EPA 200.7 16000 Strontium EPA 200.7 751 Sulfate EPA 300.0 43900 Sulfide SM 4500 S D < 100 Thallium EPA 200.8 0.47 Vanadium EPA 200.8 < 0.30 Zinc EPA 200.7 13 U Ammonia Nitrogen EPA 350.1 < 100 Nitrogen, Nitrate EPA 353.2 92 Total Dissolved Solids (TDS) SM 2540 C 1060000 Residue Suspended (TSS) SM 2540 D < 2500 Total Organic Carbon (TOC) SM 5310 B < 1000 Notes: 1. µg/L indicates micrograms per liter. 2. Analytical results provided by Pace Analytical on September 20, 2016. 3. < indicates constituent not detected at or above the laboratory reporting limit. Page 1 of 1 Appendix A Boring Logs 15-24-28 (52) 7-20-50/4" 17-21-27 (48) 4-23-37 (60) 12-40- 50/2" SS - 1 SS - 2 SS - 3 SS - 4 SS - 5 4.5' Sharp contact 24' Split spoon shoe broke in hole; Shoe drilled out, no recovery 18 12 15 18 0 (ML) SILT, hard, yellowish red (5YR 5/8) to red (10R 4/8), dry, non-plastic, cohesive, sparse fine sand, trace construction gravel (FILL) (SM) SILTY SAND, brown (7.5YR 4/4) to pinkish gray (7.5YR 7/2), dry, non-plastic, non-cohesive, becoming sandier with depth (FILL) Continued: red (2.5YR 5/8) grading to very pale brown (10YR 7/3) (ML) SILT, very stiff, red (2.5YR 5/8) to very pale brown (10YR 7/3), non-plastic, cohesive, relict foliation, micaceous (SAPROLITE) (ML) SILT WITH SAND, light yellowish brown (10YR 6/4) to dark yellowish brown (10YR 4/6), dry, non-plastic, cohesive, trace mica (SAPROLITE) NOTES LOGGED BY T. Campbell CHECKED BY DATE STARTED 8/1/16 COMPLETED 8/3/16 GROUND WATER LEVELS:DRILLING METHOD Hollow Stem Auger, HQ Core DRILLING CONTRACTOR Geologic Exploration, Inc. HOLE SIZE(S)9, 4 inches DATE/TIME --- DATE/TIME --- GROUND ELEVATION TBD NORTHING TBD EASTING TBD DE P T H (f t ) 0 5 10 15 20 25 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 1 OF 3 BORING NUMBER EW-1 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us 15-50/3" 50/6" 12-25-35 (60) 50/2" 50/0" SS - 6 SS - 7 SS - 8 SS - 9 SS - 10 46' SPT Refusal 11 11 16 9 0 (ML) SILT WITH SAND, light yellowish brown (10YR 6/4) to dark yellowish brown (10YR 4/6), dry, non-plastic, cohesive, trace mica (SAPROLITE) (continued) (ML) SILT, hard, yellowish brown (10YR 5/6), dry, non-plastic, cohesive, trace fine sand, trace coarse gravel sized gneiss fragments, gray (N6) to dark gray (N4), thinly foliated (SAPROLITE) Continued: wet Continued: dark olive brown (2.5Y 3/3) to very pale brown (10YR 8/4), moist, non-plastic, cohesive, micaceous, relict foliation, trace intensely weathered gravel-sized gneiss fragments (SAPROLITE) GNEISS, moderate strength, light brown (7.5YR 6/4) and gray (7.5YR 5/1), gneissic to schistose, intensely foliated, moderately weathered (WEATHERED/FRACTURED ROCK) DE P T H (f t ) 25 30 35 40 45 50 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 2 OF 3 BORING NUMBER EW-1 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us RC - 1 RC - 2 50' Begin HQ core 50'-54.5' Intensely fractured, Fe stained 54.5'-58.5' Moderately fractured, fracture surfaces Fe and Mn stained 56.5'-56.7' Quartz band 58.5'-60' Intensely fractured 60'-68' Unfractured 62'-64' Gradational contact Boring terminated at 68', screened interval set at 50.4'-60.4', extraction well installed 8/3/16 90 98 GNEISS, moderate strength, light brown (7.5YR 6/4) and gray (7.5YR 5/1), gneissic to schistose, intensely foliated, moderately weathered (WEATHERED/FRACTURED ROCK) (continued) Continued: slightly weathered Continued: gray (N5) to very dark gray (N3) MICA SCHIST, gray (N5) to very dark gray (N3), trace augens, fresh to slightly weathered (SOUND ROCK) Bottom of borehole at 68.0 feet. 30 84 DE P T H (f t ) 50 55 60 65 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 3 OF 3 BORING NUMBER EW-1 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us SD - 1 SD - 2 Hand auger first 5' 7.0' - color change to red (10R 4/8) Very fine grained sand, well sorted, rounded 60 103 (CL) SILTY CLAY, reddish brown (2.5yr 4/4) and yellowish brown (10yr 5/6), dry, low plasticity, non-cohesive (saprolite) (ML) SILT, medium, yellowish red (5YR 4/6), dry, non-plastic, non-cohesive (soil) SILTY SAND, dense, gray (10YR 6/1), moist, non-plastic, non-cohesive (soil) (ML) SILT, dense, dark yellowish brown (10YR 4/4), non-plastic, non-cohesive (ML) SILT, dense, yellowish brown (10YR 4/4), non-plastic, non-cohesive NOTES LOGGED BY J. Pendleton CHECKED BY DATE STARTED 8/30/16 COMPLETED 8/30/16 GROUND WATER LEVELS:DRILLING METHOD Sonic DRILLING CONTRACTOR Cascade Drilling, L.P. HOLE SIZE(S)9 inches DATE/TIME --- DATE/TIME 8/31/2016 7:50:00 AM 22.40 ft GROUND ELEVATION TBD NORTHING TBD EASTING TBD DE P T H (f t ) 0 5 10 15 20 25 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 1 OF 2 BORING NUMBER EW-2 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us SD - 3 SD - 4 SD - 5 SD - 6 Laminae bedding plane structural components (foliation bedding planes) Relic mica schist present with laminae bedding plane structure 112 120 60 36 (ML) SILT WITH SAND, medium dense, brownish yellow (10YR 6/6), non-plastic, non-cohesive (soil) (continued) (ML) SILT, dense, gray (10YR 6/1) and white (9/4), non-plastic, non-cohesive (saprolite) (ML) SILT, very dense, light yellowish brown (10YR 6/4), non-plastic, non-cohesive (saprolite) (SW-SM) WELL GRADED SAND WITH SILT, dense, very pale brown (10YR 7/3), non-plastic, non-cohesive (saprolite) (ML) SANDY SILT, very dense, grayish brown (10YR 5/2), non-plastic , non-cohesive (ML) SILT, very dense, very dark grayish black (10YR 3/2), non-plastic, non-cohesive (saprolite) Bottom of borehole at 48.0 feet. DE P T H (f t ) 25 30 35 40 45 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 2 OF 2 BORING NUMBER EW-2 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us 5-12-17 (29) 12-17-21 (38) 6-7-16 (23) 9-9-17 (26) 13-50/6" SS - 1 SS - 2 SS - 3 SS - 4 SS - 5 18 18 18 18 15 (ML) SILT, stiff, strong brown (7.5YR 5/6), dry, non-plastic, cohesive, few consolidated nodules, trace roots (SOIL) (ML) SILT, stiff, red (10R 4/6) and pink (5YR 7/6), non-plastic, cohesive, relict foliation, micaceous, trace Mn (SAPROLITE) Continued: very stiff Continued: strong brown (7.5YR 5/6), dry, with trace fine sand, Mn absent (ML) SILT, hard, pale brown (10YR 6/3), dry, non-plastic, cohesive, thinly laminated, micaceous, with Fe and Mn staining, relict structure evident, friable (SAPROLITE) NOTES LOGGED BY T. Campbell CHECKED BY DATE STARTED 8/4/16 COMPLETED 8/4/16 GROUND WATER LEVELS:DRILLING METHOD Hollow Stem Auger, HQ Core DRILLING CONTRACTOR Geologic Exploration, Inc. HOLE SIZE(S)9, 4 inches DATE/TIME --- DATE/TIME 8/9/2016 1:35:00 PM 22.50 ft GROUND ELEVATION TBD NORTHING TBD EASTING TBD DE P T H (f t ) 0 5 10 15 20 25 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 1 OF 3 BORING NUMBER SB-1 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us 14-23-26 (49) 26-50/5" 18-36-47 (83) 16-28-50 (78) 7-19-36 SS - 6 SS - 7 SS - 8 SS - 9 SS - (ML) SILT, hard, pale brown (10YR 6/3), dry, non-plastic, cohesive, thinly laminated, micaceous, with Fe and Mn staining, relict structure evident, friable (SAPROLITE) (continued) Continued: very stiff Continued: light yellowish brown (10YR 6/4) and very pale brown (10YR 7/4), moist, trace dark yellowish brown (10YR 3/4), lamination less distinct Continued: with Mn veins (ML) SILT, hard, light olive brown (2.5Y 5/3), smaller amounts of reddish yellow (5YR 6/8) and pale brown (10YR 6/3), non-plastic, cohesive, micaceous, common Fe staining and Mn veins, relict foliation (SAPROLITE) DE P T H (f t ) 25 30 35 40 45 50 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 2 OF 3 BORING NUMBER SB-1 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us (55) 50/0" 10 SS - 11 RC - 1 54' SPT refusal; Begin HQ core at 54.7' 54.7' -56.3' Intensely fractured 54.7'-59.2' Fractures Fe and Mn stained 56.3'-59' Intensely to moderately fractured 57.4'-57.5' Intensely weathered 57.8', 58', 58.6', Fractures, subhorizontal, open, Fe stained 59'-64.7' Slightly to moderately fractured 59'-59.2' Zone of residual soil, Fe stained 61' Fracture, 50º, open, angular, Fe stained 62', 62.6', 62.9', Fractures, subhorizontal, open, minor Fe staining Boring terminated at 64.7' on 8/4/16 and grouted to surface on 8/9/16 100 (ML) SILT, hard, light olive brown (2.5Y 5/3), smaller amounts of reddish yellow (5YR 6/8) and pale brown (10YR 6/3), non-plastic, cohesive, micaceous, common Fe staining and Mn veins, relict foliation (SAPROLITE) (continued) MICA SCHIST, weak to strong, very dark gray (N3) to gray (N5), trace light brown (7.5YR 6/4), fine to coarse grained, schistose, undulatory, intensely foliated, slightly weathered, common pinhead garnets, Fe and Mn staining on fractured surfaces (WEATHERED/FRACTURED ROCK) MICA SCHIST, strong, very dark gray (N3) to gray (N5), trace light brown (7.5YR 6/4), fine to coarse grained, schistose, undulatory, intensely foliated, slightly weathered, common pinhead garnets, Fe and Mn staining on fractured surfaces (SOUND ROCK) Bottom of borehole at 64.7 feet. 59 DE P T H (f t ) 50 55 60 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 3 OF 3 BORING NUMBER SB-1 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us 4-5-5 (10) 4-4-5 (9) 4-6-7 (13) 5-8-14 (22) 50/2" SS - 1 SS - 2 SS - 3 SS - 4 SS - 5 9.3' Sharp contact 15 18 17 18 9 (CL) CLAY, medium stiff, red (2.5YR 4/8), dry, low plasticity, cohesive, massive texture, trace mica (SOIL) (ML) SILT, medium stiff, pink (7.5YR 7/4) to reddish yellow ( (7.5YR 6/6), dry, non-plastic, cohesive, indistinct laminae, kaolinitic below 10' (SAPROLITE) Continued: relict foliation becoming more distinct, decreasing kaolin content, with Mn veins (ML) SILT, stiff, red (2.5YR 5/6) to light red (2.5YR 7/6), dry, non-plastic, cohesive, relict foliation, trace Mn nodules and veins, friable, trace quartzite (SAPROLITE) (ML) GRAVELLY SILT, hard, very pale brown (10YR 7/4) and grayish brown (10YR 5/2), dry, non-plastic, silt component is cohesive, indistinctly foliated with Fe staining and Mn nodules, trace fine to coarse sand (SAPROLITE) NOTES LOGGED BY T. Campbell CHECKED BY DATE STARTED 8/4/16 COMPLETED 8/5/16 GROUND WATER LEVELS:DRILLING METHOD Hollow Stem Auger, HQ Core DRILLING CONTRACTOR Geologic Exploration, Inc. HOLE SIZE(S)9, 4 inches DATE/TIME --- DATE/TIME 8/9/2016 1:30:00 PM 24.20 ft GROUND ELEVATION TBD NORTHING TBD EASTING TBD DE P T H (f t ) 0 5 10 15 20 25 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 1 OF 3 BORING NUMBER SB-2 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us 50/2" 16-24-26 (50) 18-26- 50/3" 26-50/4" 50/4" SS - 6 SS - 7 SS - 8 SS - 9 SS - 10 3 9 13 10 4 (SW-SM) SILTY SAND WITH GRAVEL, hard, very pale brown (10YR 7/4), moist, non-plastic, non-cohesive (SAPROLITE) (ML) SILT, hard, olive brown (2.5Y 4/3) to dark grayish brown (2.5Y 4/2), moist, non-plastic, cohesive, micaceous, slightly sandy, relict foliation, Mn veins, Fe stained (SAPROLITE) (ML) SILT, hard, black (2.5Y 2.5/1), trace yellowish red (5YR 5/6), Mn stained throughout, large mica flakes, relict schistose structure, trace rock fragments (SAPROLITE) DE P T H (f t ) 25 30 35 40 45 50 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 2 OF 3 BORING NUMBER SB-2 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us 36-50/1" 50/0" SS - 11 SS - 12 RC - 1 56' SPT Refusal 58.9' Begin HQ core 58.9'-66.9' Hole losing water; 8' cored in 25 minutes, ~50 gallons of water lost 58.9'-62' Moderately to intensely fractured 59.2'-64' Fractures subhorizontal, open, Fe stained, trace Mn stained 62'-64' Slightly fractured 64'-64.5' Intensely fractured 64.5'-68.9' Slightly fractured 67'-68.9' Rig chattering Boring terminated at 68.9' on 8/5/16 and grouted to surface on 8/9/16 98 6 0 (ML) SILT, hard, black (2.5Y 2.5/1), trace yellowish red (5YR 5/6), Mn stained throughout, large mica flakes, relict schistose structure, trace rock fragments (SAPROLITE) (continued) (ML) SANDY SILT WITH GRAVEL, hard, light brownish gray (10YR 6/2) to dark grayish brown (10YR 4/2), dry, non-plastic, silt competent is cohesive, micaceous, few thin mica schist fragments (SAPROLITE) MICA SCHIST, strong, very dark gray (N3) to bluish gray (5PB 6/1), schistose to gneissic, intensely crenulated, slightly weathered, with pinhead garnets (WEATHERED/FRACTURED ROCK) Continued: (SOUND ROCK) Bottom of borehole at 68.9 feet. 83 DE P T H (f t ) 50 55 60 65 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 3 OF 3 BORING NUMBER SB-2 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us 8-36-38 (74) 30-50/3" 16-50/4" 20-50/5" 19-50/5" SS - 1 SS - 2 SS - 3 SS - 4 SS - 5 18 0 9 12 12 (ML) SILT, hard, reddish brown (5YR 5/4), light brown (7.5YR 5/3), and trace red (10R 5/6), moist, trace fine sand, non-plastic, cohesive, slightly micaceous, relict foliation common, Fe and Mn staining (SAPROLITE Continued: few cemented nodules, dry, increasing mica content Continued: grading to brown (7.5YR 5/4), dry, friable NOTES LOGGED BY T. Campbell CHECKED BY DATE STARTED 8/5/16 COMPLETED 8/8/16 GROUND WATER LEVELS:DRILLING METHOD Hollow Stem Auger, HQ Core DRILLING CONTRACTOR Geologic Exploration, Inc. HOLE SIZE(S)9, 4 inches DATE/TIME --- DATE/TIME 8/9/2016 1:40:00 PM --- GROUND ELEVATION TBD NORTHING TBD EASTING TBD DE P T H (f t ) 0 5 10 15 20 25 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 1 OF 3 BORING NUMBER SB-4 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us 50/6" 49-50/5" 50/4" 13-48- 50/5" 50/2" SS - 6 SS - 7 SS - 8 SS - 9 SS - 10 45' Sharp contact 6 11 4 18 2 (ML) SILT, hard, brown (7.5YR 5/4), dry, trace fine sand, non-plastic, cohesive, slightly micaceous, friable, Fe and Mn staining (SAPROLITE) (continued) Continued: light brown (7.5YR 6/4) to dark brown (7.5YR 3/2) Continued: less friable with depth (ML) SANDY SILT, hard, gray (10YR 6/1) to light yellowish brown (10YR 6/4), dry, non-plastic, cohesive, fine sand, trace mica (SAPROLITE) DE P T H (f t ) 25 30 35 40 45 50 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 2 OF 3 BORING NUMBER SB-4 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us 50/1" 50/0" SS - 11 SS - 12 RC - 1 58' SPT refusal 59.8' Begin HQ core 59.8'-66.8 Moderately fractured 60.3'-60.6' Fracture zone, open, Fe and Mn staining 61' Fracture, open, subhorizontal, Fe staining 61.3' Fracture, 40º, open, Fe and Mn staining 61.7', 62.7' Fractures, 0º-20º, open, Fe and Mn staining 64.1'-64.4' Fracture zone, open, Fe and Mn staining throughout 65.1', 65.5', 65.8' Fractures, open, subhorizontal, Fe and Mn staining 66.1' Fracture zone in quartz lens, Fe and Mn staining 66.8'-69.8' Slightly fractured Boring terminated at 69.8' on 8/8/16 and grouted to surface on 8/9/16 98 1 0 (ML) SANDY SILT, hard, gray (10YR 6/1) to light yellowish brown (10YR 6/4), dry, non-plastic, cohesive, fine sand, trace mica (SAPROLITE) (continued) (ML) SILT WITH SAND, hard, gray (10YR 6/1), dry, non-plastic, cohesive, fine sand, micaceous, few cemented lenses (SAPROLITE) SCHISTOSE MICA GNEISS, moderate to strong, dark gray (N3) to bluish gray (5PB 6/1), gneissic, intensely foliated, slightly weathered, pinhead garnets (WEATHERED/FRACTURED ROCK) Continued: strong, gray (N5) to dark gray (N4), fresh to slightly weathered, trace augens Bottom of borehole at 69.8 feet. 93 DE P T H (f t ) 50 55 60 65 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 3 OF 3 BORING NUMBER SB-4 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us 4-7-9 (16) 10-29-39 (68) 7-9-8 (17) 12-50/5" 4-4-5 SS - 1 SS - 2 SS - 3 SS - 4 SS - 5 18 18 18 13 (CL) CLAY, stiff, red (10R 4/6), dry, low plasticity, cohesive, trace roots, massive (SOIL) (ML) SILT, stiff, red (10R 4/6) to yellowish red (5YR 5/6), dry, non-plastic, cohesive, trace kaolina, micaceous, Fe staining, trace Mn staining, relict foliation (SAPROLITE) (ML) SILT, hard, mottled light yellowish brown (2.5Y 6/4) and red (2.5YR 5/6), dry, non-plastic, cohesive, micaceous, common Fe staining, trace Mn staining, relict foliation (SAPROLITE) Continued: increased Mn, decreased mica and relict foliation (ML) SILT, medium stiff, grading from light reddish brown (2.5YR 6/4) to red (2.5YR 4/6), moist, non-plastic, slightly kaolinitic, Fe and Mn staining (SAPROLITE) NOTES LOGGED BY T. Campbell CHECKED BY DATE STARTED 8/8/16 COMPLETED 8/9/16 GROUND WATER LEVELS:DRILLING METHOD Hollow Stem Auger, HQ Core DRILLING CONTRACTOR Geologic Exploration, Inc. HOLE SIZE(S)9, 4 inches DATE/TIME --- DATE/TIME 8/9/2016 1:45:00 PM 27.30 ft GROUND ELEVATION TBD NORTHING TBD EASTING TBD DE P T H (f t ) 0 5 10 15 20 25 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 1 OF 3 BORING NUMBER SB-5 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us (9) 27-50/6" 20-7-9 (16) 5-7-9 (16) 20-50/3" 50/0" SS - 6 SS - 7 SS - 8 SS - 9 SS - 10 RC - 1 35.5' Sharp contact 44.4' Sharp contact 45' SPT refusal 45.7' Begin HQ core 45.7'-49.5' Moderately to intensely fractured, 20º-80º, open, heavy Mn mineralization, Fe staining of fracture surfaces 49.5'-52.3' Intensely fractured, Fe stained 100 18 12 14 18 9 0 (SM) SILTY SAND, dark gray (N4), non-plastic, non-cohesive, fine sand, with quartzite rock fragments (SAPROLITE) (ML) SILT, stiff, yellow (10YR 7/6) to reddish yellow (10YR 6/8), moist, non-plastic, cohesive, few Mn veins, trace Kaolin, indistinct relict structure (SAPROLITE) (ML) SILT, stiff, light yellowish brown (10YR 6/4), moist, non-plastic, cohesive, generally massive with few Mn veins (SAPROLITE) (SM) SILTY SAND, hard, grayish brown (10YR 5/2), dry, non-plastic, non-cohesive, lightly cemented, fine grained (SAPROLITE) SCHISTOSE MICA GNEISS, moderate, gray (N5), indistinct foliation, moderately weathered (WEATHERED/FRACTURED ROCK) Continued: weak, reddish yellow (7.5YR 6/6) to brown (7.5YR 5/4) 16 DE P T H (f t ) 25 30 35 40 45 50 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 2 OF 3 BORING NUMBER SB-5 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us RC - 2 RC - 3 throughout, Mn staining and mineralization on fracture surfaces 52.3'-53' Intensely fractured 53'-60.7' Unfractured Boring terminated at 60.7' and grouted to surface on 8/9/16 95 100 SCHISTOSE MICA GNEISS, weak, very dark gray (7.5YR 3/1) and brown (7.5YR 4/4), schistose to gneissic, intensely foliated, moderately weathered (WEATHERED/FRACTURED ROCK) MICA SCHIST, strong, gray (N6) to dark gray (N3) with bluish gray (5PB 5/1) crenulations, intensely foliated, fresh (SOUND ROCK) Bottom of borehole at 60.7 feet. 50 100 DE P T H (f t ) 50 55 60 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 3 OF 3 BORING NUMBER SB-5 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us 6-20-27 (47) 7-50/6" 10-50/6" 18-24-48 (72) 15-16-14 SS - 1 SS - 2 SS - 3 SS - 4 SS - 5 18 9 12 15 (ML) SANDY SILT, very stiff, red (2.5YR 5/6), grading to reddish yellow (7.5YR 7/4), dry, fine to coarse, non-plastic, silt fraction cohesive, relict foliation, large mica flakes, Fe staining, Mn veins (SAPROLITE) (ML) SANDY SILT WITH GRAVEL, hard, pale brown (10YR 6/2) to gray (N5) with red (2.5YR 4/6) nodules, dry, non-plastic, silt fraction cohesive, few quartzitic fragments broken into thin horizontal disks, Fe staining (SAPROLITE) (SW-SM) SAND WITH SILT AND GRAVEL, very stiff, very pale brown (10YR 7/3) to brownish yellow (10YR 6/6), moist, fine grained, fine to coarse gravel, non-plastic, non-cohesive, micaceous, kaolinitic, Mn veins (SAPROLITE) NOTES LOGGED BY T. Campbell CHECKED BY DATE STARTED 8/9/16 COMPLETED 8/10/16 GROUND WATER LEVELS:DRILLING METHOD Hollow Stem Auger, HQ Core DRILLING CONTRACTOR Geologic Exploration, Inc. HOLE SIZE(S)9, 4 inches DATE/TIME --- DATE/TIME 8/11/2016 9:55:00 AM 23.40 ft GROUND ELEVATION TBD NORTHING TBD EASTING TBD DE P T H (f t ) 0 5 10 15 20 25 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 1 OF 3 BORING NUMBER TW-1 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us (30) 7-9-17 (26) 9-13-18 (31) 9-34-50/3" 50/0" SS - 6 SS - 7 SS - 8 SS - 9 RC - 1 42' SPT refusal 42.9' Begin HQ core 42.9'-53.1' Moderately fractured 43'-44' Rig chattering 43.3', 43.5' Fractures, open, 0º-20º, Fe and Mn staining, Mn mineralization 43.9'-44.2' Fractures, open, 40º, Fe and Mn staining 44.7', 45' Fractures, open, subhorizontal, Fe and Mn staining 45' Driller reports fracture (slight rod drop) 45.2'-45.4' Intensely weathered 45.8'-47.9' Multiple fractures, tight, subhorizontal, Fe and Mn staining 46'-47.5' Losing water (~25 gallons) 48.5'-49.1' Fracture zone, horizontal to 80º, moderately to intensely weathered 79 14 18 18 16 0 (ML) SILT, light brownish gray (10YR 6/2) to brown (10YR 4/3), moist, non-plastic, cohesive, relict foliation, abundant large mica flakes, Fe staining, Mn nodules and veins, friable (SAPROLITE) Continued: brown (10YR 4/3) and bluish gray (5PB 5/1) MICA SCHIST, strong, very dark gray (N3) and bluish gray (5PB 6/1), schistose texture, intensely foliated, crenulated, slightly weathered with pinhead garnets, few quartz bands, trace augens 28 DE P T H (f t ) 25 30 35 40 45 50 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 2 OF 3 BORING NUMBER TW-1 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us RC - 2 49.4', 49.6' Fractures, open, subhorizontal, Fe and Mn staining 49.8'-50.1' Fracture zone, open to tight, Fe and Mn staining 50'-52' Losing water (~20 gallons) 50.1'-53' Fractures at 0.3'-0.5' intervals, open, minor Fe staining 53.1'-54.8' unfractured, abundant healed fractures 54.8'-55.3' Fracture zone, open to tight, Fe and Mn staining 55.3'-58.2' Moderately fractured, fractures at 0.4' average intervals, open, Fe and Mn staining Boring terminated at 58.2', screened interval set at 46.8'-56.8', well installed 8/10/16 92 MICA SCHIST, strong, very dark gray (N3) and bluish gray (5PB 6/1), schistose texture, intensely foliated, crenulated, slightly weathered with pinhead garnets, few quartz bands, trace augens (continued) Bottom of borehole at 58.2 feet. 45 DE P T H (f t ) 50 55 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 3 OF 3 BORING NUMBER TW-1 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us 5-8-12 (20) 21-50/4" 18-50/6" 40-50/5" 20-40-37 SS - 1 SS - 2 SS - 3 SS - 4 SS - 5 18 9 12 9 (ML) SILT, stiff, red (10R 4/6) to yellowish red (5YR 4/6), dry, non-plastic, cohesive, trace mica (SAPROLITE) Continued: hard, brown (7.5YR 5/4), friable, micaceous, trace fine sand, trace kaolin Continued: reddish brown (10YR 5/4), dry to moist, relict foliation, Fe staining, Mn veins NOTES LOGGED BY T. Campbell CHECKED BY DATE STARTED 8/10/16 COMPLETED 8/10/16 GROUND WATER LEVELS:DRILLING METHOD Hollow Stem Auger, HQ Core DRILLING CONTRACTOR Geologic Exploration, Inc. HOLE SIZE(S)9, 4 inches DATE/TIME --- DATE/TIME 8/11/2016 8:05:00 AM 21.30 ft GROUND ELEVATION TBD NORTHING TBD EASTING TBD DE P T H (f t ) 0 5 10 15 20 25 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 1 OF 3 BORING NUMBER TW-2 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us (77) 50/4" 12-15- 50/5" 17-25-45 (70) 50/3" 50/0" SS - 6 SS - 7 SS - 8 SS - 9 SS - 10 48' SPT refusal 49.2' Begin HQ core 49.2'-59.2' Moderately fractured, Fe and Mn 4 15 18 3 0 (ML) SILT, hard, reddish brown (10YR 5/4), dry to moist, non-plastic, cohesive, micaceous, trace fine sand, trace kaolin, relict foliation, Fe staining, Mn veins (SAPROLITE) (continued) (SW-SC) SAND WITH SILT AND GRAVEL, hard, light greenish gray (10Y 7/1) to gray (N5), dry, non-plastic, non-cohesive, sand fine to coarse, gravel fine to coarse, trace Fe staining (SAPROLITE) (ML) SILT, hard, light brown (7.5YR 6/4) to pinkish gray (7.5YR 6/2), moist, non-plastic, cohesive, massive to intensely foliated, Mn veins and nodules, trace mica and kaolin, slightly sandy (SAPROLITE) (ML) SILT, hard, gray (7.5YR 6/1), thinly laminated with white (N9.5), moist, non-plastic, cohesive, with Mn veins, Fe staining on relict fractures, original gneissic structure preserved, micaceous at base of spoon (SAPROLITE) (SW-SM) SAND WITH SILT AND GRAVEL, hard, grayish brown (10YR 5/2), trace light yellowish brown (10YR 6/4), sand fine to coarse, fine gravel, non-plastic, non-cohesive, trace kaolin, trace mica (SAPROLITE) SCHISTOSE MICA GNEISS, strong, dark gray (N4) with white (N9.5) foliation, fresh to slightly weathered, button plagioclase, trace garnet, few augens (SOUND ROCK) DE P T H (f t ) 25 30 35 40 45 50 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 2 OF 3 BORING NUMBER TW-2 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us RC - 1 RC - 2 staining on open fractures, mostly subhorizontal, few fractures to 60º 49.6'-50' Fracture zone, open, subhorizontal to 70º, Fe and Mn staining 50.5' Fracture, open, subhorizontal, Fe and Mn staining 50.9', 51' Fractures, open, subhorizontal, Fe and Mn staining 53.2'-53.9' Intensely fractured 53.2'-53.9' Fracture, 80º, open, Mn mineralization 54.2'-54.8' Fracture, 80º, open, Mn mineralization 56'-56.2' Fracture, subhorizontal 56.8'-57.3' Fracture, open, 80º, Fe and Mn staining 57.3'-58' Abundant healed fractures 58.6'-59.2' Fracture, open, 80º, minor Fe staining, heavy Mn mineralization 59.2'-62.5' Drilled out (not sampled) to allow for screen length Boring terminated at 62.5', screened interval set at 52.1'-62.1', well installed 8/10/16 100 SCHISTOSE MICA GNEISS, strong, dark gray (N4) with white (N9.5) foliation, fresh to slightly weathered, button plagioclase, trace garnet, few augens (SOUND ROCK) (continued) QUARTZ FELDSPAR GNEISS, strong, white (7.5YR 9.5/1) and brown (10YR 4/3), fresh, common pinhead garnet (SOUND ROCK) SCHISTOSE MICA GNEISS, strong, dark gray (N4) with white (N9.5) foliation, fresh to slightly weathered, button plagioclase, trace garnet, few augens (SOUND ROCK) Bottom of borehole at 62.5 feet. 62 DE P T H (f t ) 50 55 60 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 3 OF 3 BORING NUMBER TW-2 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us See TW-2 for lithology NOTES LOGGED BY T. Campbell CHECKED BY DATE STARTED 8/11/16 COMPLETED 8/11/16 GROUND WATER LEVELS:DRILLING METHOD Hollow Stem Auger DRILLING CONTRACTOR Geologic Exploration, Inc. HOLE SIZE(S)9 inches DATE/TIME --- DATE/TIME 8/12/2016 7:45:00 AM 21.20 ft GROUND ELEVATION TBD NORTHING TBD EASTING TBD DE P T H (f t ) 0 5 10 15 20 25 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 1 OF 2 BORING NUMBER TW-3 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us Boring terminated at 44', screened interval set at 23.5'-43.5', well installed 8/11/16 Bottom of borehole at 44.0 feet. DE P T H (f t ) 25 30 35 40 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 2 OF 2 BORING NUMBER TW-3 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us SD - 1 SD - 2 Hand auger first 5' Mica flakes present throughout Relic laminae/bedding planes present (structure or saprolite) Laminae bedding planes with residual relic structure Color change to greater amount of light yellowish brown, saprolite characteristics increase Wet/saturated 60 102 (CL) SILTY CLAY, medium red (2.5YR 4/6), low plasticity, cohesive (soil) (ML) SANDY SILT, hard, red (2.5YR 4/8), gray (10YR 5/1) and white (9.5N), moist, non-plastic , non-cohesive (saprolite) (CL) SILTY CLAY, very stiff, red (2.5YR 4/8), moist, non-plastic, non-cohesive (saprolite) (ML) SILT, stiff, red (2.5YR 5/6) and light yellowish brown (10YR 6/4), moist, non-plastic, non-cohesive (saprolite) (ML) SILT, stiff, pale brown (10YR 6/3), non-plastic, non-cohesive (saprolite) NOTES LOGGED BY J. Pendleton CHECKED BY DATE STARTED 8/31/16 COMPLETED 8/31/16 GROUND WATER LEVELS:DRILLING METHOD Sonic DRILLING CONTRACTOR Cascade Drilling, L.P. HOLE SIZE(S)6 inches DATE/TIME --- DATE/TIME --- GROUND ELEVATION TBD NORTHING TBD EASTING TBD DE P T H (f t ) 0 5 10 15 20 25 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 1 OF 2 BORING NUMBER TW-4 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us SD - 3 Very weathered mica schist and mica flakes present throughout (sand fine-medium) Weathered mica schist decomposition with laminae and structural makeup Fragmented mica schist present throughout most of 37-40 interval Weathered mica schist with saprolite structure Beginning of transition zone located at 40' bgs 98 (ML) SILT, stiff, pale brown (10YR 6/3), non-plastic, non-cohesive (saprolite) (continued) (ML) SILT WITH SOME SAND, medium, light yellowish brown (10YR 6/4), dry, non-plastic (ML) SILT, stiff, yellowish brown (10YR 5/4), red (10R 4/6) and black (5YR 2.5/1), moist, non-plastic, non-cohesive (saprolite) (ML) SILT WITH GRAVEL, very stiff, dark gray (5Y 4/1), dry, non-plastic, non-cohesive (ML) SILT WITH GRAVEL, hard, very dark gray (10YR 3/1),moist, non-plastic, non-cohesive (saprolite) Bottom of borehole at 42.0 feet. DE P T H (f t ) 25 30 35 40 BL O W CO U N T S (N V A L U E ) MONITORING WELL SA M P L E T Y P E / NO . / C O R E R U N REMARKS RO C K RE C O V E R Y % SO I L RE C O V E R Y ( i n ) DESCRIPTION RO C K R Q D % PAGE 2 OF 2 BORING NUMBER TW-4 CLIENT Duke Energy Carolinas PROJECT NUMBER 10030143 PROJECT NAME Belews Creek - Accelerated Remediation PROJECT LOCATION Stokes County, NC NO R T H C A R O L I N A B O R I N G L O G - G I N T S T D U S L A B . G D T - 9 / 1 6 / 1 6 0 8 : 4 9 - C : \ P W W O R K I N G \ T P A \ D 0 9 7 9 9 3 7 \ B E L E W S C R E E K A C C E L E R A T E D R E M E D I A T I O N . G P J 440 S. Church Street, Suite 900 Charlotte, NC 28202-2075 Phone: 704-338-6700 hdrinc.com/follow-us Appendix B Analytical Report #=CL# September 20, 2016 LIMS USE: FR - CHAD HEARN LIMS OBJECT ID: 92311854 92311854 Project: Pace Project No.: RE: Chad Hearn HDR 440 S. Church Street Suite 1000 Charlotte, NC 28202 BCSS Accelerated Remediation Dear Chad Hearn: Enclosed are the analytical results for sample(s) received by the laboratory on September 09, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 40 #=CP# CERTIFICATIONS Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Wyoming Certification: FL NELAC Reciprocity West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 40 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92311854001 BCSS EW-2 RSK 175 Modified 1 PASI-CWDV EPA 200.7 12 PASI-ASH1 EPA 200.8 Rev 5.4 13 PASI-ACDF EPA 245.1 1 PASI-AWAB SM 2320B 1 PASI-AKDF SM 2540C 1 PASI-AMJS SM 2540D 1 PASI-AMJP SM 4500-S2D 1 PASI-AMDW EPA 218.7 1 PASI-OAEM EPA 300.0 1 PASI-AMDW EPA 350.1 1993 Rev 2.0 1 PASI-ASER EPA 353.2 2 PASI-ASER SM 4500-Cl-E 1 PASI-AWRC SM 5310B 1 PASI-AMDW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 40 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Method: Client:HDR Engineering RSK 175 Modified Date:September 20, 2016 Description:RSK 175 Headspace General Information: 1 sample was analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Surrogates: All surrogates were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 40 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Method: Client:HDR Engineering EPA 200.7 Date:September 20, 2016 Description:200.7 MET ICP General Information: 1 sample was analyzed for EPA 200.7. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 200.7 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: 328187 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92311647004,92311847001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1818789) • Aluminum • MSD (Lab ID: 1818790) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 40 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Method: Client:HDR Engineering EPA 200.8 Rev 5.4 Date:September 20, 2016 Description:200.8 MET ICPMS General Information: 1 sample was analyzed for EPA 200.8 Rev 5.4. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 200.8 Rev 5.4 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 40 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Method: Client:HDR Engineering EPA 245.1 Date:September 20, 2016 Description:245.1 Mercury General Information: 1 sample was analyzed for EPA 245.1. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 245.1 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 40 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Method: Client:HDR Engineering SM 2320B Date:September 20, 2016 Description:2320B Alkalinity General Information: 1 sample was analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 40 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Method: Client:HDR Engineering SM 2540C Date:September 20, 2016 Description:2540C Total Dissolved Solids General Information: 1 sample was analyzed for SM 2540C. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 40 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Method: Client:HDR Engineering SM 2540D Date:September 20, 2016 Description:2540D Total Suspended Solids General Information: 1 sample was analyzed for SM 2540D. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: 328583 D6: The precision between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1821350) • Total Suspended Solids Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 40 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Method: Client:HDR Engineering SM 4500-S2D Date:September 20, 2016 Description:4500S2D Sulfide Water General Information: 1 sample was analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 40 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Method: Client:HDR Engineering EPA 218.7 Date:September 20, 2016 Description:Hexavalent Chromium by IC General Information: 1 sample was analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 40 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Method: Client:HDR Engineering EPA 300.0 Date:September 20, 2016 Description:300.0 IC Anions 28 Days General Information: 1 sample was analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 40 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Method: Client:HDR Engineering EPA 350.1 1993 Rev 2.0 Date:September 20, 2016 Description:350.1 Ammonia General Information: 1 sample was analyzed for EPA 350.1 1993 Rev 2.0. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: 328388 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92311266001,92311331001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1820052) • Nitrogen, Ammonia • MSD (Lab ID: 1820053) • Nitrogen, Ammonia Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 40 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Method: Client:HDR Engineering EPA 353.2 Date:September 20, 2016 Description:353.2 Nitrogen, NO2/NO3 unpres General Information: 1 sample was analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: 328072 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92311854001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1818066) • Nitrogen, Nitrite • MSD (Lab ID: 1818067) • Nitrogen, Nitrite Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 40 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Method: Client:HDR Engineering SM 4500-Cl-E Date:September 20, 2016 Description:4500 Chloride General Information: 1 sample was analyzed for SM 4500-Cl-E. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: 328523 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92311363001,92311971001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1820943) • Chloride • MSD (Lab ID: 1820944) • Chloride M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1820941) • Chloride • MSD (Lab ID: 1820942) • Chloride Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 40 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Method: Client:HDR Engineering SM 5310B Date:September 20, 2016 Description:5310B TOC General Information: 1 sample was analyzed for SM 5310B. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 40 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Sample:BCSS EW-2 Lab ID:92311854001 Collected:09/08/16 13:45 Received:09/09/16 16:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: RSK 175 ModifiedRSK 175 Headspace Methane ND ug/L 09/12/16 13:54 74-82-8 N210.0 1 Analytical Method: EPA 200.7 Preparation Method: EPA 200.7200.7 MET ICP Aluminum 228 ug/L 09/13/16 20:05 7429-90-509/12/16 21:301001 Barium 424 ug/L 09/13/16 20:05 7440-39-309/12/16 21:305.0 1 Boron 8460 ug/L 09/13/16 20:05 7440-42-809/12/16 21:3050.0 1 Calcium 141000 ug/L 09/14/16 14:48 7440-70-209/12/16 21:305005 Iron 1560 ug/L 09/13/16 20:05 7439-89-609/12/16 21:3050.0 1 Lead ND ug/L 09/13/16 20:05 7439-92-109/12/16 21:305.0 1 Magnesium 52700 ug/L 09/13/16 20:05 7439-95-409/12/16 21:301001 Manganese 3720 ug/L 09/13/16 20:05 7439-96-509/12/16 21:305.0 1 Potassium 7380 ug/L 09/13/16 20:05 7440-09-709/12/16 21:3050001 Sodium 16000 ug/L 09/13/16 20:05 7440-23-509/12/16 21:3050001 Strontium 751 ug/L 09/13/16 20:05 7440-24-609/12/16 21:305.0 1 Zinc 13.0 ug/L 09/13/16 20:05 7440-66-609/12/16 21:3010.0 1 Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4200.8 MET ICPMS Antimony ND ug/L 09/14/16 20:05 7440-36-009/13/16 18:450.50 1 Arsenic 1.7 ug/L 09/14/16 20:05 7440-38-209/13/16 18:450.10 1 Beryllium 11.5 ug/L 09/14/16 20:05 7440-41-709/13/16 18:450.10 1 Cadmium 1.5 ug/L 09/14/16 20:05 7440-43-909/13/16 18:450.080 1 Chromium 0.82 ug/L 09/14/16 20:05 7440-47-309/13/16 18:450.50 1 Cobalt 9.5 ug/L 09/14/16 20:05 7440-48-409/13/16 18:450.10 1 Copper 0.56 ug/L 09/14/16 20:05 7440-50-809/13/16 18:450.50 1 Lead 0.35 ug/L 09/14/16 20:05 7439-92-109/13/16 18:450.10 1 Molybdenum 0.83 ug/L 09/14/16 20:05 7439-98-709/13/16 18:450.50 1 Nickel 6.9 ug/L 09/14/16 20:05 7440-02-009/13/16 18:450.50 1 Selenium 6.5 ug/L 09/14/16 20:05 7782-49-209/13/16 18:450.50 1 Thallium 0.47 ug/L 09/14/16 20:05 7440-28-009/13/16 18:450.10 1 Vanadium ND ug/L 09/14/16 20:05 7440-62-209/13/16 18:450.30 1 Analytical Method: EPA 245.1 Preparation Method: EPA 245.1245.1 Mercury Mercury ND ug/L 09/20/16 13:37 7439-97-609/17/16 05:500.20 1 Analytical Method: SM 2320B2320B Alkalinity Alkalinity, Total as CaCO3 ND mg/L 09/14/16 15:585.0 1 Analytical Method: SM 2540C2540C Total Dissolved Solids Total Dissolved Solids 1060 mg/L 09/14/16 17:3050.0 1 Analytical Method: SM 2540D2540D Total Suspended Solids Total Suspended Solids ND mg/L 09/14/16 23:302.5 1 Analytical Method: SM 4500-S2D4500S2D Sulfide Water Sulfide ND mg/L 09/14/16 01:26 18496-25-80.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 40 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Sample:BCSS EW-2 Lab ID:92311854001 Collected:09/08/16 13:45 Received:09/09/16 16:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent ND ug/L 09/19/16 15:23 18540-29-90.030 1 Analytical Method: EPA 300.0300.0 IC Anions 28 Days Sulfate 43.9 mg/L 09/11/16 18:40 14808-79-86.0 3 Analytical Method: EPA 350.1 1993 Rev 2.0350.1 Ammonia Nitrogen, Ammonia ND mg/L 09/14/16 03:18 7664-41-70.10 1 Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 0.092 mg/L 09/10/16 05:340.020 1 Nitrogen, Nitrite ND mg/L 09/10/16 05:34 M10.020 1 Analytical Method: SM 4500-Cl-E4500 Chloride Chloride 496 mg/L 09/15/16 23:26 16887-00-650.0 50 Analytical Method: SM 5310B5310B TOC Total Organic Carbon ND mg/L 09/16/16 09:33 7440-44-01.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 328132 RSK 175 Modified RSK 175 Modified RSK 175 HEADSPACE Associated Lab Samples:92311854001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1818353 Associated Lab Samples:92311854001 Matrix:Water Analyzed Methane ug/L ND 10.0 N209/12/16 10:21 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1818354LABORATORY CONTROL SAMPLE & LCSD: LCSSpike LCSD % Rec RPD Max RPD LCSD Result 1818355 Methane ug/L 412 N239610470-13098389 6 20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 328143 EPA 245.1 EPA 245.1 245.1 Mercury Associated Lab Samples:92311854001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1818475 Associated Lab Samples:92311854001 Matrix:Water Analyzed Mercury ug/L ND 0.20 09/20/16 13:37 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1818476LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 2.72.5 107 85-115 Parameter Units MS Result % Rec Limits Qual% RecConc. 1818477MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311423005 1818478 MSD Result MSD % Rec RPD MSDMS Spike Conc. Mercury ug/L 2.5 79 70-13095 82.52.6 4.6 5.0 Parameter Units MS Result % Rec Limits Qual% RecConc. 1818479MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311693006 1818480 MSD Result MSD % Rec RPD MSDMS Spike Conc. Mercury ug/L 2.5 99 70-130100 22.5ND 2.6 2.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 328187 EPA 200.7 EPA 200.7 200.7 MET Associated Lab Samples:92311854001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1818785 Associated Lab Samples:92311854001 Matrix:Water Analyzed Aluminum ug/L ND 100 09/13/16 19:32 Barium ug/L ND 5.0 09/13/16 19:32 Boron ug/L ND 50.0 09/13/16 19:32 Calcium ug/L ND 100 09/14/16 14:44 Iron ug/L ND 50.0 09/13/16 19:32 Lead ug/L ND 5.0 09/13/16 19:32 Magnesium ug/L ND 100 09/13/16 19:32 Manganese ug/L ND 5.0 09/13/16 19:32 Potassium ug/L ND 5000 09/13/16 19:32 Sodium ug/L ND 5000 09/13/16 19:32 Strontium ug/L ND 5.0 09/13/16 19:32 Zinc ug/L ND 10.0 09/13/16 19:32 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1818786LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 50405000 101 85-115 Barium ug/L 517500 103 85-115 Boron ug/L 491500 98 85-115 Calcium ug/L 52905000 106 85-115 Iron ug/L 47705000 95 85-115 Lead ug/L 478500 96 85-115 Magnesium ug/L 49005000 98 85-115 Manganese ug/L 493500 99 85-115 Potassium ug/L 4800J5000 96 85-115 Sodium ug/L 4860J5000 97 85-115 Strontium ug/L 493500 99 85-115 Zinc ug/L 486500 97 85-115 Parameter Units MS Result % Rec Limits Qual% RecConc. 1818787MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311847001 1818788 MSD Result MSD % Rec RPD MSDMS Spike Conc. Aluminum ug/L 5000 97 70-13099 2500016350005120 Barium ug/L 500 100 70-130102 250013.5 512 522 Boron ug/L 500 97 70-130100 3500185668686 Calcium ug/L 5000 96 70-13098 15000150001980019900 Iron ug/L 5000 90 70-13093 3500057350905240 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1818787MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311847001 1818788 MSD Result MSD % Rec RPD MSDMS Spike Conc. Lead ug/L 500 89 70-13091 3500ND446458 Magnesium ug/L 5000 91 70-13095 25000343079808170 Manganese ug/L 500 93 70-13096 350039.8 504 519 Potassium ug/L 5000 93 70-13095 05000180002260022700 Sodium ug/L 5000 82 70-13088 05000104000108000108000 Strontium ug/L 500 95 70-13096 250054.9 528 537 Zinc ug/L 500 92 70-13095 350094.0 553 567 Parameter Units MS Result % Rec Limits Qual% RecConc. 1818789MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311647004 1818790 MSD Result MSD % Rec RPD MSDMS Spike Conc. Aluminum ug/L M1500013670-130138 15000304098709930 Barium ug/L 500 102 70-130102 050093.9 603 605 Boron ug/L 500 97 70-13097 050052.7 536 536 Calcium ug/L 5000 105 70-130108 05000231002830028500 Iron ug/L 5000 101 70-130101 05000400090309060 Lead ug/L 500 91 70-13091 1500ND460457 Magnesium ug/L 5000 99 70-13099 0500065001150011400 Manganese ug/L 500 96 70-13096 050080.7 562 560 Potassium ug/L 5000 99 70-130101 15000118001670016800 Sodium ug/L 5000 96 70-13096 05000ND90409060 Strontium ug/L 500 96 70-13096 050084.8 566 566 Zinc ug/L 500 92 70-13092 150042.1 503 500 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 328336 EPA 200.8 Rev 5.4 EPA 200.8 Rev 5.4 200.8 MET Associated Lab Samples:92311854001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1819664 Associated Lab Samples:92311854001 Matrix:Water Analyzed Antimony ug/L ND 0.50 09/14/16 18:39 Arsenic ug/L ND 0.10 09/14/16 18:39 Beryllium ug/L ND 0.10 09/14/16 18:39 Cadmium ug/L ND 0.080 09/14/16 18:39 Chromium ug/L ND 0.50 09/14/16 18:39 Cobalt ug/L ND 0.10 09/14/16 18:39 Copper ug/L ND 0.50 09/14/16 18:39 Lead ug/L ND 0.10 09/14/16 18:39 Molybdenum ug/L ND 0.50 09/14/16 18:39 Nickel ug/L ND 0.50 09/14/16 18:39 Selenium ug/L ND 0.50 09/14/16 18:39 Thallium ug/L ND 0.10 09/14/16 18:39 Vanadium ug/L ND 0.30 09/14/16 18:39 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1819665LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 93.1100 93 85-115 Arsenic ug/L 93.9100 94 85-115 Beryllium ug/L 98.0100 98 85-115 Cadmium ug/L 94.1100 94 85-115 Chromium ug/L 97.7100 98 85-115 Cobalt ug/L 98.4100 98 85-115 Copper ug/L 99.2100 99 85-115 Lead ug/L 96.3100 96 85-115 Molybdenum ug/L 95.2100 95 85-115 Nickel ug/L 97.3100 97 85-115 Selenium ug/L 91.8100 92 85-115 Thallium ug/L 96.5100 96 85-115 Vanadium ug/L 96.6100 97 85-115 Parameter Units MS Result % Rec Limits Qual% RecConc. 1819666MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311888001 1819667 MSD Result MSD % Rec RPD MSDMS Spike Conc. Antimony ug/L 100 97 70-13097 01004.0 101 101 Arsenic ug/L 100 96 70-13095 110028.9 125 123 Beryllium ug/L 100 98 70-13099 11000.038J 98.2 99.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1819666MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311888001 1819667 MSD Result MSD % Rec RPD MSDMS Spike Conc. Cadmium ug/L 100 96 70-13096 0100ND96.0 96.2 Chromium ug/L 100 97 70-13097 01000.51 97.7 97.8 Cobalt ug/L 100 98 70-13099 11001.0 99.1 100 Copper ug/L 100 97 70-13097 01002.8 99.6 99.6 Lead ug/L 100 95 70-13095 01000.54 96.0 95.8 Molybdenum ug/L 100 98 70-13098 010010.6 109 109 Nickel ug/L 100 95 70-13095 01004.4 99.1 99.4 Selenium ug/L 100 93 70-13094 01001.5 95.0 95.3 Thallium ug/L 100 96 70-13095 11000.060J 95.7 95.2 Vanadium ug/L 100 99 70-13098 010022.6 121 121 Parameter Units MS Result % Rec Limits Qual% RecConc. 1819668MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311904006 1819669 MSD Result MSD % Rec RPD MSDMS Spike Conc. Antimony ug/L 100 95 70-13096 11000.66 96.0 96.7 Arsenic ug/L 100 96 70-13097 11000.81 97.2 98.1 Beryllium ug/L 100 102 70-130102 0100ND102102 Cadmium ug/L 100 96 70-13097 2100ND95.6 97.1 Chromium ug/L 100 99 70-130100 01000.54 99.9 100 Cobalt ug/L 100 102 70-130103 11000.087J 102 103 Copper ug/L 100 103 70-130103 01002.1 105 105 Lead ug/L 100 97 70-13098 1100ND97.1 98.1 Molybdenum ug/L 100 96 70-13097 11004.7 101 102 Nickel ug/L 100 100 70-130100 01001.3 101 101 Selenium ug/L 100 94 70-13094 01000.38J 94.5 94.9 Thallium ug/L 100 97 70-13098 2100ND96.7 98.2 Vanadium ug/L 100 99 70-130100 01009.3 109 109 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 328234 SM 2320B SM 2320B 2320B Alkalinity Associated Lab Samples:92311854001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1818913 Associated Lab Samples:92311854001 Matrix:Water Analyzed Alkalinity, Total as CaCO3 mg/L ND 5.0 09/14/16 11:40 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1818914LABORATORY CONTROL SAMPLE: LCSSpike Alkalinity, Total as CaCO3 mg/L 48.250 96 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1818915MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311888004 1818916 MSD Result MSD % Rec RPD MSDMS Spike Conc. Alkalinity, Total as CaCO3 mg/L 50 102 80-120100 150135186185 Parameter Units MS Result % Rec Limits Qual% RecConc. 1818917MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311904009 1818918 MSD Result MSD % Rec RPD MSDMS Spike Conc. Alkalinity, Total as CaCO3 mg/L 50 96 80-12096 050ND48.2 48.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 328443 SM 2540C SM 2540C 2540C Total Dissolved Solids Associated Lab Samples:92311854001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1820306 Associated Lab Samples:92311854001 Matrix:Water Analyzed Total Dissolved Solids mg/L ND 25.0 09/14/16 17:30 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1820307LABORATORY CONTROL SAMPLE: LCSSpike Total Dissolved Solids mg/L 250250 100 90-110 Parameter Units Dup Result QualifiersRPDResult 92311295041 1820308SAMPLE DUPLICATE: Total Dissolved Solids mg/L NDND Parameter Units Dup Result QualifiersRPDResult 92311295049 1820309SAMPLE DUPLICATE: Total Dissolved Solids mg/L NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 328583 SM 2540D SM 2540D 2540D Total Suspended Solids Associated Lab Samples:92311854001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1821348 Associated Lab Samples:92311854001 Matrix:Water Analyzed Total Suspended Solids mg/L ND 2.5 09/14/16 23:30 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1821349LABORATORY CONTROL SAMPLE: LCSSpike Total Suspended Solids mg/L 248250 99 90-110 Parameter Units Dup Result QualifiersRPDResult 92311864002 1821350SAMPLE DUPLICATE: Total Suspended Solids mg/L 6.5 D6105.9 Parameter Units Dup Result QualifiersRPDResult 92311674001 1821351SAMPLE DUPLICATE: Total Suspended Solids mg/L NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 328350 SM 4500-S2D SM 4500-S2D 4500S2D Sulfide Water Associated Lab Samples:92311854001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1819817 Associated Lab Samples:92311854001 Matrix:Water Analyzed Sulfide mg/L ND 0.10 09/14/16 01:26 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1819818LABORATORY CONTROL SAMPLE: LCSSpike Sulfide mg/L 0.53.5 106 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1819819MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311840006 1819820 MSD Result MSD % Rec RPD MSDMS Spike Conc. Sulfide mg/L .5 102 80-120103 1.5ND 0.51 0.51 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 320989 EPA 218.7 EPA 218.7 Chromium, Hexavalent IC Associated Lab Samples:92311854001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1707753 Associated Lab Samples:92311854001 Matrix:Water Analyzed Chromium, Hexavalent ug/L ND 0.030 09/19/16 11:15 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1707754LABORATORY CONTROL SAMPLE: LCSSpike Chromium, Hexavalent ug/L 0.072.075 97 85-115 Parameter Units MS Result % Rec Limits Qual% RecConc. 1707757MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92312085003 1707758 MSD Result MSD % Rec RPD MSDMS Spike Conc. Chromium, Hexavalent ug/L .025 90 85-11598 1.0250.24 0.26 0.26 Parameter Units MS Result % Rec Limits Qual% RecConc. 1710138MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311904011 1710139 MSD Result MSD % Rec RPD MSDMS Spike Conc. Chromium, Hexavalent ug/L .075 105 85-115106 0.075ND 0.079 0.079 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 328087 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92311854001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1818103 Associated Lab Samples:92311854001 Matrix:Water Analyzed Sulfate mg/L ND 2.0 09/11/16 16:22 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1818104LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 19.220 96 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1818105MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311291001 1818106 MSD Result MSD % Rec RPD MSDMS Spike Conc. Sulfate mg/L 20 105 90-110106 02018.5 39.5 39.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 328388 EPA 350.1 1993 Rev 2.0 EPA 350.1 1993 Rev 2.0 350.1 Ammonia Associated Lab Samples:92311854001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1820050 Associated Lab Samples:92311854001 Matrix:Water Analyzed Nitrogen, Ammonia mg/L ND 0.10 09/14/16 03:04 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1820051LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Ammonia mg/L 5.45 107 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1820052MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311266001 1820053 MSD Result MSD % Rec RPD MSDMS Spike Conc. Nitrogen, Ammonia mg/L M1511190-110112 154.9 10.5 10.5 Parameter Units MS Result % Rec Limits Qual% RecConc. 1820054MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311331001 1820055 MSD Result MSD % Rec RPD MSDMS Spike Conc. Nitrogen, Ammonia mg/L 5 107 90-110107 050.14 5.5 5.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 328072 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92311854001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1818064 Associated Lab Samples:92311854001 Matrix:Water Analyzed Nitrogen, Nitrate mg/L ND 0.020 09/10/16 05:30 Nitrogen, Nitrite mg/L ND 0.020 09/10/16 05:30 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1818065LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.52.5 99 90-110 Nitrogen, Nitrite mg/L 1.01 103 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1818066MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311854001 1818067 MSD Result MSD % Rec RPD MSDMS Spike Conc. Nitrogen, Nitrate mg/L 2.5 98 90-11098 02.50.092 2.5 2.5 Nitrogen, Nitrite mg/L M1111390-110113 01ND1.1 1.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 328523 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92311854001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1820939 Associated Lab Samples:92311854001 Matrix:Water Analyzed Chloride mg/L ND 1.0 09/15/16 22:41 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1820940LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 20.620 103 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1820941MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311363001 1820942 MSD Result MSD % Rec RPD MSDMS Spike Conc. Chloride mg/L M61021190-110208 11020.6 41.7 41.4 Parameter Units MS Result % Rec Limits Qual% RecConc. 1820943MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92311971001 1820944 MSD Result MSD % Rec RPD MSDMS Spike Conc. Chloride mg/L M11011290-110112 0104.0 15.1 15.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 40 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 328802 SM 5310B SM 5310B 5310B TOC Associated Lab Samples:92311854001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1822465 Associated Lab Samples:92311854001 Matrix:Water Analyzed Total Organic Carbon mg/L ND 1.0 09/16/16 04:49 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1822466LABORATORY CONTROL SAMPLE: LCSSpike Total Organic Carbon mg/L 23.625 95 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1822467MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92312241001 1822468 MSD Result MSD % Rec RPD MSDMS Spike Conc. Total Organic Carbon mg/L 25 97 90-11096 125ND24.5 24.2 Parameter Units MS Result % Rec Limits Qual% RecConc. 1822469MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92312401006 1822470 MSD Result MSD % Rec RPD MSDMS Spike Conc. Total Organic Carbon mg/L 25 94 90-11094 0255.8 29.3 29.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 40 #=QL# QUALIFIERS Pace Project No.: Project: 92311854 BCSS Accelerated Remediation DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C Pace Analytical Services - Ormond BeachPASI-O ANALYTE QUALIFIERS The precision between the sample and sample duplicate exceeded laboratory control limits.D6 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 40 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92311854 BCSS Accelerated Remediation Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92311854001 328132BCSS EW-2 RSK 175 Modified 92311854001 328187 328217BCSS EW-2 EPA 200.7 EPA 200.7 92311854001 328336 328400BCSS EW-2 EPA 200.8 Rev 5.4 EPA 200.8 Rev 5.4 92311854001 328143 328224BCSS EW-2 EPA 245.1 EPA 245.1 92311854001 328234BCSS EW-2 SM 2320B 92311854001 328443BCSS EW-2 SM 2540C 92311854001 328583BCSS EW-2 SM 2540D 92311854001 328350BCSS EW-2 SM 4500-S2D 92311854001 320989BCSS EW-2 EPA 218.7 92311854001 328087BCSS EW-2 EPA 300.0 92311854001 328388BCSS EW-2 EPA 350.1 1993 Rev 2.0 92311854001 328072BCSS EW-2 EPA 353.2 92311854001 328523BCSS EW-2 SM 4500-Cl-E 92311854001 328802BCSS EW-2 SM 5310B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 09/20/2016 05:31 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 40 Page 38 of 40 Page 39 of 40 Page 40 of 40 Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx APPENDIX B EVALUATION OF ALTERNATIVE REMEDIAL TECHNOLOGIES Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx APPENDIX C UPDATED GROUNDWATER FLOW MODEL REPORT Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx APPENDIX D UPDATED GEOCHEMICAL MODEL REPORT Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx APPENDIX E PIPE AND PUMP SELECTION PACKAGE Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx APPENDIX F DESIGN DRAWINGS Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx APPENDIX G TECHNICAL SPECIFICATIONS Basis of Design Report (30% Submittal) December 2016 Belews Creek Steam Station SynTerra P:\Duke Energy Progress.1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\PDF\2016-12-27 KWW DRAFT\30 Percent Basis of Design Report,122816, Belews Creek text.docx APPENDIX H PERMITS