NC0001422_LVSuttonSARP_Rev0_AppendixF_20161201

Appendix F
Chemical Characterization Report

CHEMICAL CHARACTERIZATION
REPORT
L.V. SUTTON ENERGY COMPLEX
SITE ANALYSIS AND REMOVAL PLAN
December 2016
Revision 0
Prepared for

Duke Energy Progress, LLC
526 South Church Street
Charlotte, North Carolina 28202
Prepared by

Geosyntec Consultants of NC, PC
1300 South Mint Street, Suite 300
Charlotte, North Carolina 28203
License No. C-3500

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TABLE OF CONTENTS
1. INTRODUCTION ............................................................................................................... 1
1.1 Overview .................................................................................................................. 1
1.2 Site Background ....................................................................................................... 1
1.3 Report Organization ................................................................................................. 2
2. CHEMICAL CHARACTERISTICS OF CCR AND SOIL ................................................... 3
2.1 Overview .................................................................................................................. 3
2.2 Coal Combustion Residuals ..................................................................................... 4
2.2.1 1984 Basin .................................................................................................. 4
2.2.2 1971 Basin .................................................................................................. 4
2.2.3 CCR Results ................................................................................................ 5
2.3 Soils ......................................................................................................................... 6
2.3.1 Background Soils ........................................................................................ 6
2.3.2 Site Soils ..................................................................................................... 6
2.4 Soil and CCR Mixture at LOLA ................................................................................. 7
2.4.1 Previous Investigation of LOLA ................................................................... 7
2.4.2 Supplemental Investigation of LOLA ........................................................... 7
3. GROUNDWATER AND CCR INTERSTITIAL WATER QUALITY ................................... 9
3.1 Overview .................................................................................................................. 9
3.2 Historical Investigations and NPDES Sampling Results .......................................... 9
3.3. Supplemental Monitoring Well and Piezometer Installations ................................. 11
3.3.1 Groundwater Monitoring Wells .................................................................. 11
3.3.2. CCR Piezometers ...................................................................................... 12
3.4 Supplemental Groundwater Monitoring and CCR Interstitial Water Sampling ....... 13
3.4.1 Overview ................................................................................................... 13
3.4.2 CCR Interstitial Water and Groundwater Sampling and Testing ............... 13
3.5 Groundwater Monitoring at LOLA........................................................................... 16
3.6 Summary of Groundwater Impacts ......................................................................... 17
3.7 Geochemical Conceptual Site Model ..................................................................... 18
3.8 Conclusions ............................................................................................................ 19
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4. REFERENCES ................................................................................................................ 20

Tables
Table 1. Soil and CCR Analytical Data
Table 2. SPLP Analytical Data
Table 3. 1971 Borrow Area Investigation – CCR Analytical Data
Table 4. 1971 Borrow Area Investigation – SPLP Analytical Data
Table 5. LOLA Investigation – Soil and CCR Analytical Data
Table 6. LOLA Investigation – SPLP Analytical Data
Table 7. Historical Groundwater Analytical Results - Metals
Table 8. Historical Groundwater Analytical Results - Non-Metals
Table 9. Groundwater and CCR Interstitial Water Field Parameters
Table 10. Groundwater and CCR Interstitial Water Analytical Data
Table 11. LOLA Investigation – Groundwater Field Parameters
Table 12. LOLA Investigation – Groundwater Analytical Data

Figures
Figure 1. Soil and CCR Sampling Locations May 2014
Figure 2. Historical and Conceptual Closure Geotechnical Investigation
Figure 3. DPT Investigation and Monitoring Well Locations
Figure 4. Bottom Elevations of CCR in LOLA
Figure 5. Isopach Thickness of CCR in LOLA
Figure 6. Newly Installed and Existing Monitoring Wells, Piezometers, and Staff Gages
Figure 7. Groundwater and Surface Water Monitoring May 2014
Figure 8. Cross Section Locations
Figure 9. Lithologic Cross Sections A to A′ and B to B′
Figure 10. Lithologic Cross Section C to C′

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Appendices
Appendix A1 Laboratory Analytical Reports – Supplemental Investigation
Appendix A2 Laboratory Analytical Reports – LOLA and 1971 Borrow Area

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1. INTRODUCTION
1.1 Overview
Geosyntec Consultants of North Carolina PC (Geosyntec) has prepared this Chemical
Characterization Report (Report) as part of the Site Analysis and Removal Plan (Removal Plan)
in support of the proposed closure of the Coal Combustion Residuals (CCR) Basins at the L.V.
Sutton Energy Complex (Sutton) located near Wilmington, North Carolina. Sutton is located on
property owned by Duke Energy Progress, LLC (DEP). This Report is required in accordance
with NC Senate Bill SB729 (§ 130A-309.212) and was prepared to fulfill the requirements
outlined under § 130A-309.212 (c)(5 through 9).
During the review of historical information in the spring of 2014, Geosyntec identified certain
data gaps and proposed a field program to fill these data gaps for the purpose of preparing this
report. The field work was subsequently implemented between May and July 2014, and the
results were presented in a number of submittals, including (i) the Preliminary Site Investigation
Data Report [Geosyntec, 2014a], (ii) the Preliminary Site Investigation Data Report Addendum
No. 1 [Geosyntec, 2014b], (iii) the Data Interpretation and Analysis Report [Geosyntec, 2014c],
and (iv) the Data Interpretation and Analysis Report Addendum No. 1 [Geosyntec, 2014d].
The information presented and summarized in the current document has been extracted and
edited from the above-referenced reports. Note that additional data were collected by SynTerra
during 2015, which were summarized and interpreted in the Comprehensive Site Assessment
(CSA) Report and CSA Supplement 1 [2015a, 2016b] and the Corrective Action Plan (CAP, Part
1) [2015b], but were not included in this data summary. These additional data were consistent
with historical data and the data collected during Geosyntec’s preliminary site investigation and
did not change the overall conclusions presented in this Report and the Removal Plan.
1.2 Site Background
Sutton is located in New Hanover County, near Wilmington, North Carolina, situated between
the Cape Fear River to the west and the Northeast Cape Fear River to the east. Sutton
operated as a three-unit, 575-megawatt (MW) coal-fired power plant. Sutton operated from
1954 until the retirement of the coal-fired units in November 2013. Upon the retirement of the
coal-fired units a new, 625-MW gas-fired unit began operating.
Notable features at Sutton related to the scope of this Report include two CCR basins and the
Lay of Land Area (LOLA).
Sutton has two CCR basins, and they are referred to as: (i) the 1971 Basin; and (ii) the 1984
Basin. The 1971 Basin was operated from 1971 to 1985, and since then was used alternatively
as needed to allow maintenance for the 1984 Basin until the coal units were shut down in
November 2013. The 1984 Basin was operated from 1984 to November 2013. Both basins
contain fly ash, bottom ash, boiler slag, storm water, ash sluice water, coal pile runoff, and low
volume wastewater.
The LOLA is located between the discharge canal and the coal pile. Based on a previous
investigation conducted by Geosyntec, the LOLA contains approximately 2 to 15 ft of CCR and
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soil mixtures [Geosyntec, 2014b and 2014d]. More details about this area and its
characterization are summarized in Section 2 below.
1.3 Report Organization
The remaining sections of this Report are organized as follows:
• Section 2 summarizes the chemical characteristics of CCR and CCR/soil mixtures
analyzed at Sutton;
• Section 3 presents the historical and current groundwater quality at Sutton; and
• Section 4 contains the cited references.

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2. CHEMICAL CHARACTERISTICS OF CCR AND SOIL
2.1 Overview
As part of the evaluation of closure options for the CCR basins at Sutton, Geosyntec performed
hydrogeologic and environmental site assessment activities to supplement historical
assessment data collected by other consultants. The supplemental field work to collect the data
reported herein was implemented between May 5th and May 29th, 2014, with an additional
investigation within the LOLA and the 1971 Basin conducted between June 30th and July 2nd,
2014.
Soil and CCR samples were collected to evaluate background concentrations of constituents of
interest (COIs), COI concentrations within the CCR basins, and concentrations of COIs in
vadose zone soils located outside of the CCR basins. Note that the term COI has been used in
this Report to include all constituents analyzed during this investigation, while SynTerra [2015a
and b] subsequently defined the term to only include constituents detected in CCR interstitial
water in excess of a North Carolina Groundwater Quality Standard found in the North Carolina
Administrative Code (NCAC) Title 15A, Subchapter 2L.0202 (2L or 2L Standards) and the
Interim Maximum Allowable Concentrations (IMAC) established by the NCDEQ pursuant to 15A
NCAC 02L.0202(c). CCR interstitial water within a basin may not be representative of
groundwater conditions outside of a basin and the results were compared to 2L Standards
solely to provide a frame of reference.
Soil and CCR samples were collected according to the EPA Region 4 Soil Sampling SOP [EPA
2011a]. The samples were properly preserved, labeled, logged onto a chain-of-custody form,
and placed into an iced cooler prior to shipment. The samples were submitted to Lancaster
Laboratories located in Lancaster, PA, for analysis of:
• The North Carolina (NC) Hazardous Substance List metals (antimony [Sb], arsenic [As],
beryllium [Be], cadmium [Cd], chromium [Cr], copper [Cu], lead [Pb], manganese [Mn],
mercury [Hg], nickel [Ni], selenium [Se], silver [Ag], thallium [Tl], zinc [Zn]) using Method
SW 846-7471B (Hg) and Method SW 846-6010C (all other metals);
• Major cations (calcium [Ca], magnesium [Mg], sodium [Na], and potassium [K]) using
Method SW 846-6010C;
• Major anions (chloride [Cl], bromide [Br], and sulfate [SO4] using EPA Method 300.0;
• Strontium [Sr], boron [B], barium [Ba], molybdenum [Mo], and iron [Fe] using Method
SW 846-6010C; and
• pH using Method SW 846-9045D modified.
Leachability of metals was also evaluated using the Synthetic Precipitation Leaching Procedure
(SPLP; EPA Method 1312) for CCR and background soils.
In addition to investigating the CCR within and the soils around and below the CCR basins, the
LOLA was investigated between June 30th and July 2nd, 2014 to supplement the historical
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investigation data, delineate the vertical boundaries of the CCR and collect groundwater quality
information in the area. Note that groundwater data from this area are summarized in Section 3.
2.2 Coal Combustion Residuals
2.2.1 1984 Basin
Two CCR samples from representative locations and depth increments [SS-SPT9(12.0-14.0
feet) from PZ-Int, and SS-SPT7(4.0-6.0) from the southern portion of the 1984 Basin] were
collected from geotechnical cores at a depth corresponding to high CCR content based on
visual inspection and professional judgment. The referenced sections of borings were collected
into a stainless steel bowl, mixed manually using a stainless steel spoon, and then filled into
laboratory-supplied sample containers. The soil and CCR sampling locations are presented on
Figure 1. Boring logs are included as an appendix in the Removal Plan.
2.2.2 1971 Basin
During the geotechnical investigation of the 1971 Basin, samples were collected at depths
corresponding to high CCR content based on visual observation [SS-SPT3(10.0-12.0), which is
the same location as PZ-1971, and SS-GP3(24.0-28.0)], and from soil below the CCR based on
visual observations [SS-GP5(20.0-24.0) and SS-GP6(24.0-28.0)]. Furthermore, samples were
collected from materials where uncertainty existed in the field whether they should be classified
as CCR or soil [SS-GP3 (32.0-36.0), SS-G3 (76.0-80.0), SS-GP3 (80.0-84.0), SS-GP3(72.0-
76.0), SS-GP2(72.0-76.0), and SS-GP2(52.0-56.0)]. The soil and CCR sampling locations are
presented on Figure 1. Boring logs are included as an appendix in the Removal Plan.
Based on the uncertainty related to the bottom of the CCR within portions of the 1971 Basin, an
additional investigation was implemented within the boundaries of the 1971 Basin, but below the
design bottom elevation of the 1971 Basin between June 25th and July 2nd, 2014. This deeper
area has been termed the 1971 Borrow Area. The additional investigation consisted of
geoprobe borings and laboratory tests to delineate the horizontal and vertical extent of CCR
within the Borrow Area. Samples were continuously collected during the geoprobe borings.
Selected samples were transported for laboratory testing to characterize geotechnical and
environmental properties. These laboratory testing results were used to verify the bottom of
CCR estimated based on a visual assessment in the field.
Fourteen geoprobe borings were advanced within the 1971 Borrow Area and on the 1971 Basin
dike. Two borings were located in a soft ground area covered by vegetation. Access to those
two locations was facilitated by DEP by building a temporary access road. Mid-Atlantic Drilling
of Wilmington, NC was subcontracted to conduct the geoprobe borings using a track-mounted
6600 rig. The locations of those borings are presented on Figure 2 together with other historical
and current boring locations within the CCR basins. In the geoprobe borings, a hollow rod
interior lined with a clear plastic sleeve was pushed into the ground. During the borings,
samples were continuously collected in 4-ft-long increments. The collected samples were
visually classified and logged. Boring logs are included as an appendix in the Removal Plan.
Selected samples were then bagged or stored in laboratory-supplied containers, and sent under
chain-of-custody protocol for laboratory testing of:
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• The North Carolina (NC) Hazardous Substance List metals (antimony [Sb], arsenic [As],
beryllium [Be], cadmium [Cd], chromium [Cr], copper [Cu], lead [Pb], manganese [Mn],
mercury [Hg], nickel [Ni], selenium [Se], silver [Ag], thallium [Tl], zinc [Zn]) using Method
SW 846-7471B (Hg) and Method SW 846-6010C (all other metals);
• Strontium [Sr], boron [B], barium [Ba], molybdenum [Mo] and iron [Fe] using Method SW
846-6010C;
• pH using Method SW 846-9045D modified; and
• Leachability of metals using the Synthetic Precipitation Leaching Procedure (SPLP; EPA
Method 1312).
Note that SynTerra collected additional samples for physical and chemical characterization
during the 2015 investigation. Refer to the CSA [SynTerra, 2015a, 2016b] and CAP [SynTerra,
2015b, 2016a] for a summary of these results.
2.2.3 CCR Results
Table 1 summarizes the analytical results for CCR samples and soil samples, and the SPLP
results are summarized in Table 2. Hard copies of the laboratory analytical reports are included
in Appendix A1.
As can be seen in Table 1, with the exception of antimony, cadmium, mercury, molybdenum,
silver, and thallium (which were all basically non-detect), all metallic COIs were higher in CCR
compared to soil samples. Furthermore, sulfate and pH levels were also higher in CCR
compared to levels in the soil. It is further noted that COI levels appeared to be higher in CCR
samples from the 1971 Basin as compared to the 1984 Basin.
This apparent trend generally also holds true for leachable levels of COIs as measured using
the SPLP approach. Arsenic still appeared to be leaching at elevated levels from CCR, while
boron, iron, manganese, and selenium levels were low to non-detect (Table 2).
As summarized above, a follow-up investigation was conducted within the limits of the 1971
Basin. In order to supplement the visual and geotechnical characterization of the CCR within
the 1971 Borrow Area, samples were collected for chemical analysis. Both total concentrations
of COIs and SPLP concentrations were analyzed in nine CCR samples and the results are
summarized in Table 3 (total concentrations) and Table 4 (SPLP). Hard copies of the laboratory
analytical reports are included in Appendix A2.
Total concentrations of many COIs indicate that the tested samples are CCR and not soils,
which is consistent with the visual and geotechnical characterization of these samples.
Consistent with the results from the May 2014 investigation, the samples exhibited elevated
concentrations of arsenic and iron, which appear to be the most important “CCR indicator
parameters” of the materials found within the 1971 Borrow Area. Arsenic concentrations ranged
up to 155 mg/kg, a result obtained from the deepest sample submitted (MB2 at 76-80 ft bgs),
and iron concentrations ranged up to 43,400 mg/kg. In comparison, site-specific soil samples
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exhibited non-detect results for arsenic (i.e., <1 mg/kg), and iron concentrations that were
generally below 1,000 mg/kg.
Leaching tests using the SPLP method indicated that the CCR located within the 1971 Borrow
Area have the potential to leach arsenic at elevated concentrations. Arsenic concentrations of
up to 316 µg/L were measured in SPLP extracts, and there was a good apparent correlation
between total arsenic and SPLP arsenic concentrations. Other “typical” CCR indicator
parameters such as boron, iron, chromium, manganese, and selenium did not leach at elevated
concentrations from the CCR submitted for analysis.
2.3 Soils
2.3.1 Background Soils
Background soil samples were collected from locations on the property that have not received
CCR to establish metals concentrations naturally occurring in Sutton soils. Two discrete
background soil samples were collected using a hand auger from 2.5 ft to 3.0 ft below ground
surface (bgs) to avoid sampling soils that could potentially be affected by surface deposition of
CCR-related dust.
Table 1 summarizes the soil and CCR analytical data, including the results from the background
soil samples, and Table 2 summarizes the SPLP leaching data.
Background soils indicated low to non-detect levels of most constituents analyzed. However,
iron was detected at a slightly elevated level at location SB-2, which is located close to
monitoring well MW-7. Both background soil samples exhibited acidic pH levels at around 4.6
and 4.7 standard units (s.u.), indicating naturally acidic soil conditions at Sutton.
SPLP results showed some leachable levels of iron and calcium, and to a lesser degree barium,
silver, and thallium at background soil location SB-2. All other COIs were not detected above
the practical quantitation limit (PQL).
2.3.2 Site Soils
Soil samples were collected during the installation of monitoring wells MW-34C and MW-36C
and from the soil below the CCR in the 1971 Basin based on visual observations from borings
GP-5 and GP-6. Boring logs are included as an appendix in the Removal Plan.
As can be seen in Table 1, results were generally consistent with background soil conditions,
except for location GP-5, which exhibited elevated concentrations of most COIs that may
indicate leaching from the overlying CCR and/or a mix of soil and CCR at the sampled depth
(i.e., 20-24 ft bgs). Furthermore, pH levels were higher than background conditions (i.e.,
circumneutral to slightly alkaline), but lower than in CCR.
SPLP results summarized in Table 2 indicate leachable levels of barium, calcium, magnesium,
and sodium above background levels in soil samples collected from below the CCR in the 1971
Basin. However, these levels were lower than leachable results from CCR (see Section 2.2).
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2.4 Soil and CCR Mixture at LOLA
2.4.1 Previous Investigation of LOLA
Environmental assessments were conducted periodically in the LOLA from 2001 through 2012
to assess potential CCR impacts. In June 2001, Law Environmental, subsequently Blasland,
Bouck, and Lee, Inc (BBL), conducted soil and groundwater assessments following the release
of white liquor from one of the above ground storage tanks leased to International Paper. The
release was remediated, but additional investigations were conducted by BBL when Duke
Energy entered the North Carolina Registered Environmental Consultant (REC) voluntary
remediation program under the Inactive Hazardous Sites Branch of the North Carolina
Department of Environmental Quality (NCDEQ) to assess potential impacts from CCR and
petroleum in soil and groundwater. A Remedial Investigation report was submitted to NCDEQ
in May 2005 [BBL, 2005]. Soil borings using hand augers and larger test pits were used to
delineate the extent of CCR in soil within LOLA to determine the soil impacts. Groundwater
monitoring wells were also installed as part of this investigation to assess groundwater quality in
the LOLA. In many cases, the test pits and soil borings were terminated near the top of the
water table, before reaching the native soil. A Remedial Action Plan was submitted by BBL in
March 2006 [BBL, 2006]. The proposed remedy was monitored natural attenuation of arsenic in
groundwater along with administrative controls and land use restrictions to address soil and
CCR impacts above unrestricted use remedial goals. Limited groundwater sampling was
performed within LOLA during the Phase II Groundwater Quality Assessment conducted by
Catlin [2012].
2.4.2 Supplemental Investigation of LOLA
Geosyntec implemented a screening-level assessment of the soils and CCR in the LOLA was
conducted using Geoprobe® investigation techniques to (i) visually assess materials to evaluate
composition as either soil, CCR, or a mixture, (ii) verify native soil had been reached, and (iii)
collect soil and/or CCR samples from impacted locations. Geosyntec subcontracted
SAEDACCO of Fort Mill, SC, to provide direct push technology (DPT) boring services. The
sample locations are shown on Figure 3. Boring logs are included as an appendix in the
Removal Plan.
A subset of soil and/or CCR samples was collected from the borings. When CCR were present
above the groundwater table, a sample was collected from the unsaturated zone approximately
1 ft above the water table. When CCR were present below the groundwater table, a sample
was collected from an area of the saturated zone with the greatest visual impacts based on
professional judgment. In cases where the transition to native soil was not visually evident,
samples were collected in order to verify that native soil had been reached. The solid samples
were mixed manually using a stainless steel spoon in a stainless steel bowl and packed into
laboratory-supplied containers and zip lock bags. Following the assessment, 12 soil samples
from six locations that were judged to be representative of CCR and CCR/soil mixtures were
selected along with two additional samples for native soil verification and transferred to
laboratory-supplied containers. The selected samples were sent under chain-of-custody
protocol to Lancaster Laboratories located in Lancaster, PA, for analysis of:
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• The North Carolina (NC) Hazardous Substance List metals (antimony [Sb], arsenic [As],
beryllium [Be], cadmium [Cd], chromium [Cr], copper [Cu], lead [Pb], manganese [Mn],
mercury [Hg], nickel [Ni], selenium [Se], silver [Ag], thallium [Tl], zinc [Zn]) using Method
SW 846-7471B (Hg) and Method SW 846-6010C (all other metals);
• Strontium [Sr], boron [B], barium [Ba], molybdenum [Mo], and iron [Fe] using Method SW
846-6010C;
• pH using Method SW 846-9045D modified, and
• Leachability of metals using the Synthetic Precipitation Leaching Procedure (SPLP; EPA
Method 1312).
The samples were properly preserved, labeled, logged onto a chain-of-custody form, and placed
into an iced cooler prior to shipment. Note that SynTerra collected additional samples from the
LOLA for chemical characterization during the 2015 investigation. Refer to the CSA [SynTerra,
2015a, 2016b] and CAP [SynTerra, 2015b, 2016a] for a summary of these results.
The analytical results are presented in Table 5 (total metals, pH, and % moisture) and Table 6
(SPLP). Hard copies of the laboratory analytical reports are included in Appendix A2.
The analytical results were used to evaluate levels of constituents of interest (COI), assess the
current leachability potential, and supplement the visual identification of CCR to confirm that the
vertical extent of CCR has been reached.
Figure 3 includes descriptions of the depth increments that appeared to contain CCR. Based on
visual identification, the observed CCR appeared to include a range of grain sizes, which might
indicate a minor presence of fly ash mixed in with mostly bottom ash within the LOLA.
The main purpose of this investigation was to evaluate the vertical extent of CCR. The
elevations (NAVD 88) for the bottom of CCR are presented on Figure 4, while Figure 5 depicts
isopach contours of the thickness of CCR within the LOLA. Note that the horizontal extent of
the LOLA has changed from previously depicted delineations, but may be subject to further
adjustments pending additional investigations within this area. SynTerra’s depiction of the
waste boundary of the LOLA in the CSA Report [2015a, 2016b] accounts for the updated
delineation based on Geosyntec’s and SynTerra’s 2014 and 2015 investigation results. As can
be seen on Figure 5, the thickness of CCR varies considerably across the LOLA but appears to
be thickest within the northwestern corner of the LOLA and thinnest within the southeastern
corner.
The chemical characterization summarized in Table 5 indicated relatively low concentrations of
arsenic (up to a maximum of 42 mg/kg), boron (up to 25 mg/kg), chromium (up to 25 mg/kg),
and iron (up to 16,200 mg/kg) compared to the CCR characterized in the 1971 and 1984
Basins. The chemical signatures did indicate a contribution of CCR when arsenic, iron, and
chromium were detected at elevated concentrations compared to native soils, but the levels
were more consistent with a CCR/soil mixture than pure CCR.
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The SPLP data summarized in Table 6 indicated that this CCR/soil mixture within the LOLA did
not leach COIs at elevated concentrations. Again, this is in contrast to the CCR characterized
within the 1971 and 1984 Basins, and it may be another indication that the CCR present within
the LOLA is mostly bottom ash.
3. GROUNDWATER AND CCR INTERSTITIAL WATER QUALITY
3.1 Overview
As part of the evaluation of closure options for the CCR basins, Geosyntec performed
groundwater and CCR interstitial water investigation activities to supplement historical
groundwater assessment data collected by other consultants and to fill certain data gaps. The
field work was implemented between 5 May and 29 May 2014.
Prior to Geosyntec’s involvement at Sutton, monitoring wells and piezometers were installed
around Sutton beginning in 1984.
For this supplemental investigation, Geosyntec performed the following groundwater and CCR
interstitial water investigation activities to fill data gaps identified during the review of historical
information to evaluate potentially applicable CCR basin closure options:
• Piezometers were installed within the CCR basins and around the toe of the dike
surrounding the CCR basins;
• Intermediate-depth (22-27 feet below ground surface [ft bgs]), and deeper depth
monitoring wells (40-45 ft bgs), intervals consistent with the depths of existing monitoring
wells designated as “B-” and “C-” wells, were installed to supplement existing information
on potential impacts to ground water in the surficial aquifer at Sutton;
• Groundwater and CCR interstitial water samples were collected from certain existing and
newly installed monitoring wells and piezometers located throughout Sutton, but not
included in the National Pollutant Discharge Elimination System (NPDES) compliance
sampling plan.
Note that SynTerra installed additional wells and collected additional groundwater samples
during the 2015 investigation. Refer to the CSA [SynTerra, 2015a, 2016b] and CAP [SynTerra,
2015b, 2016a] for a summary of these results.
3.2 Historical Investigations and NPDES Sampling Results
Existing monitoring wells were installed by Blasland, Bouck & Lee [2004-2005], Catlin Engineers
and Scientists [2011], and Synterra [2013]. Existing piezometers were installed by Golder
Associates [2008]. Monitoring wells were also installed in 1984, 1986, and 1990, but either well
logs were not available for these wells or well logs did not specify the entity who installed the
wells. However, these wells were used during various investigations and some are still in use
as part of the NPDES sampling program.
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Historical and current groundwater analytical data and field parameters are provided in Table 7
(metals) and Table 8 (non-metals and field parameters) for sampling events through June 2015.
Note that these sampling events are conducted under the requirements of the NPDES permit for
Sutton and that hard copies of laboratory analytical reports are being submitted under separate
cover consistent with the requirements of the NPDES permit. Further note that there may be
new permit parameters included for upcoming compliance sampling, some of which may
already have been sampled for during June 2015. However, Tables 7 and 8 do not include any
new parameters and the discussion in this Report is limited to the parameters routinely
monitored until recently.
Background well MW-4B on the southeastern side of Sutton has exhibited consistent
exceedances of the iron groundwater standard [NCDENR, 2013] of 300 µg/L (1,280 µg/L in
June 2015) and occasional exceedances of the 50 µg/L manganese standard (59 µg/L in June
2015), while background well MW-5C on the northeastern side of the property has shown
exceedances of the manganese standard (441 µg/L in June 2015) and naturally acidic pH
conditions (pH 5.5 s.u. versus the pH groundwater standard of 6.5 s.u to 8.5 s.u.). This
indicates that background geochemical conditions are likely contributing to the increased
solubility of iron and manganese. The negative oxidation-reduction potential (ORP) measured
in MW-4B likely contributes to the higher solubility of iron, while manganese is expected to be
soluble under the acidic groundwater conditions in MW-5C.
Monitoring wells within the vicinity of the eastern and southeastern side of the 1971 Basin,
including MW-2C, MW-17, and MW-18 have historically exhibited elevated concentrations of
arsenic, boron, iron, and manganese. Occasionally, other metals and TDS were detected at
slightly elevated concentrations and the groundwater pH was slightly acidic. While elevated
manganese and iron concentrations and acidic groundwater conditions can be partially
explained by background conditions, arsenic and boron concentrations are likely attributable to
the presence of the CCR basins. Monitoring well MW-6C, which is located to the east of the
Interior Containment Area within the 1984 Basin, has historically shown elevated concentrations
of boron, iron, and manganese as well as acidic groundwater conditions, but only the boron
levels appear to have been elevated when compared to background conditions. This suggests
that the clay liner within the 1984 Basin may provide increased groundwater protection and that
arsenic has either been contained within the 1984 Basin or quickly attenuates within a relatively
short distance from the waste boundary.
Attenuation of arsenic has also been observed within the area outside of the 1971 Basin; MW-
21C, which serves as a compliance monitoring well within this area, is the only well at or beyond
the compliance boundary that has shown occasional exceedances of the 10 µg/L arsenic
groundwater standard. However, arsenic concentrations appear to be increasing in this well
with a current concentration of 53.8 µg/L measured during the June 2015 sampling event.
Nevertheless, given that MW-21C is the only well in this area exceeding the arsenic standard,
this suggests that arsenic is not very mobile in groundwater and is expected to be present as
the less mobile arsenate (i.e., As5+) form as opposed to the more mobile arsenite (i.e., As3+)
form in groundwater at a certain distance away from the basins. This has been confirmed using
Eh-pH stability diagrams for arsenic under site-specific conditions presented in the Data
Interpretation and Analysis Report [Geosyntec, 2014c]. Similarly, with the exception of
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monitoring well MW-27B along the northern side of the 1984 Basin, which had a detection of
28.4 µg/L during the June 2015 sampling event, selenium has not been consistently detected
above its groundwater standard of 20 µg/L. Monitoring well MW-24B along the eastern
compliance boundary outside of the Interior Containment Area within the 1984 Basin had
historically shown detections above the selenium groundwater standard but has been non-
detect during the past nine sampling events.
On the other hand, boron, which basically acts as a conservative ion that does not get
attenuated via sorption or precipitation, has historically shown concentrations above its
groundwater standard of 700 µg/L in multiple monitoring wells at or beyond the compliance
boundary. This includes compliance boundary wells MW-21C (2,120 µg/L in June 2015), MW-
22C (2,560 µg/L in June 2015), MW-23B (currently at 137 µg/L and therefore, below the
standard), MW-23C (2,050 µg/L in June 2015), MW-24B (currently at 409 µg/L and therefore,
below the standard), and MW-24C (1,040 µg/L in June 2015). Furthermore, several wells
beyond the compliance boundary have historically shown exceedances of the boron
groundwater standard. These wells include MW-12 (along the property boundary next to S.T.
Wooten Corporation; 1,470 µg/L in June 2015), MW-19 (downgradient of MW-21C; 2,080 µg/L
in June 2015), and MW-31C (along the property boundary next to S.T. Wooten Corporation;
currently at 381 µg/L and therefore, below the standard).
Given that MW-12 and MW-31C are approximately 1,300 feet and 1,200 feet, respectively, east
of the waste boundary suggests that groundwater extraction at the S.T. Wooten Site may
influence groundwater flow pattern at Sutton. Furthermore, it is noted that the deeper C-wells
(screened at about 40 ft to 45 ft bgs) generally exhibit higher concentrations of most COIs as
compared to the B-wells, which are screened around 22 ft to 27 ft bgs.
During the Phase II Groundwater Quality Assessment [Catlin, 2012], two temporary piezometers
were installed within the CCR along the western end of the 1971 Basin. Results indicated
elevated levels of arsenic, iron, and manganese, and slightly elevated levels of boron. These
levels were generally consistent with the results reported in groundwater immediately outside
the eastern and southeastern side of the 1971 Basin discussed above.
3.3. Supplemental Monitoring Well and Piezometer Installations
3.3.1 Groundwater Monitoring Wells
Three intermediate-depth monitoring wells (MW-34B, MW-35B, and MW-36B) and four deep
monitoring wells (MW-27C, MW-34C, MW-35C, and MW-36C) were installed at Sutton using
hollow stem auger (HSA) drilling methods. The monitoring wells were constructed with 2-inch
diameter, Schedule 40 PVC well casings and 5-ft screens with 0.010-inch slot openings. A filter
pack of 20/30 silica sand was placed around each screen and extended to at least one foot
above the top of the screen. A minimum one-foot thick seal of bentonite chips was placed
directly above and in contact with the filter pack. The bentonite seal was allowed to hydrate for
at least 30 minutes before bentonite grout was placed into the annular space between the
casing and the borehole to ground surface.
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Furthermore, eight groundwater piezometers (GWPZ-1A/B through GWPZ-4A/B) were installed
to monitor groundwater elevation at the toe of the dike around the CCR basins using HSA
drilling methods. Piezometers were constructed with 1-inch diameter, Schedule 40 PVC well
casings and 5-ft screens with 0.010-inch slot openings. Piezometers designated with an “A”
suffix were installed from 10-15 ft bgs, and piezometers with a “B” suffix were installed from 22-
27 ft bgs, which is consistent with the depths and the “A” and “B” designations of the previously
installed wells and piezometers. These piezometers were not sampled for chemical
characterization and are therefore not further discussed in this Report. However, some of the
borings for these piezometers were used to construct cross-sections discussed below.
All wells and piezometers were completed with at least 12 inches of four-inch by four-inch above
ground outer protective steel casing set in a two-foot by two-foot concrete pad. The wells were
secured with DEP-provided locks. Figure 6 shows the locations of the monitoring wells. Boring
logs are included as an appendix in the Removal Plan.
Monitoring wells were developed to establish a hydrologic connection with the surrounding
aquifer and to remove residual solids from the wells prior to sampling. Well development was
not initiated until the grout was allowed to set for a minimum of 24 hours following installation of
the surface completion. Well development was performed by pumping with a submersible pump
or peristaltic pump to remove turbid water and sediments. Well development was considered
completed when (i) turbidity measured less than or equal to 10 Nephelometric Turbidity Units
(NTUs), (ii) turbidity did not improve over the previous hour of well development or (iii) well was
purged for three hours.
As indicated above, SynTerra installed additional wells and collected additional groundwater
and CCR interstitial water samples during the 2015 investigation. Refer to the CSA [SynTerra,
2015a, 2016b] and CAP [SynTerra, 2015b, 2016a] for a summary of these results.
3.3.2. CCR Piezometers
Two CCR piezometers (PZ-1971 and PZ-Int) were installed using mud rotary drilling methods to
monitor water elevations within the CCR basins and collect interstitial water samples for
laboratory analyses. Piezometers were constructed with 2-inch diameter, Schedule 40 PVC
well casings and 5-ft screens with 0.010-inch slot openings. Piezometers were installed such
that the screened interval was located entirely within CCR; PZ-1971 was screened from 17-22 ft
bgs, and PZ-Int was screened from 13-18 ft bgs.
A filter pack of 20/30 silica sand was placed around the screen and extended to at least one foot
above the top of the screen of the piezometers. A seal of bentonite chips was placed directly
above and in contact with the filter pack to the ground surface. The bentonite seal was allowed
to hydrate for at least 30 minutes before the above ground completion was installed.
Piezometers were completed with at least 12 inches of outer protective steel casing set in a two-
foot by the two-foot concrete pad. The piezometers were secured with DEP-provided locks.
Figure 6 shows the locations of the piezometers. Boring logs are included as an appendix in the
Removal Plan.
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CCR piezometer development was initiated after the grout was allowed to set for a minimum of
24 hours following the installation of the surface completion. CCR piezometer development in
PZ-1971 was initiated using a peristaltic pump but was stopped immediately because the
piezometer was pumped dry. CCR piezometer development in PZ-Int was conducted using a
submersible pump for approximately two hours, after which turbidity readings were not
improving and development was stopped.
3.4 Supplemental Groundwater Monitoring and CCR Interstitial Water Sampling
3.4.1 Overview
Depth-to-water measurements, CCR interstitial water samples, and groundwater samples were
collected from the newly installed monitoring wells and piezometers after they had been allowed
to stabilize for approximately one week after installation. Unfiltered groundwater samples were
collected using low-flow sampling methods as described in EPA Region 4 Groundwater
Sampling Standard Operating Procedure (SOP) [EPA, 2011b].
3.4.2 CCR Interstitial Water and Groundwater Sampling and Testing
A CCR interstitial water sample was collected from piezometer PZ-Int, but no sample could be
collected from PZ-1971 since the piezometer was dry. Groundwater samples were collected
from monitoring wells installed by Geosyntec and from select existing monitoring wells and
piezometers (Figure 7). Sampled wells and piezometers were purged using a low-flow
peristaltic pump with the tubing intake located in the middle portion of the screened interval of
the wells and piezometers. To the extent practical, the purge rate was set to minimize
drawdown and avoid agitation of the sample. The groundwater or CCR interstitial water was
purged through a flow-through cell equipped with temperature, pH, conductivity, redox potential
and dissolved oxygen (DO) sensors to monitor variations in these parameters. Turbidity was
measured using a separate turbidity meter.
The wells were considered sufficiently purged when the following water quality parameters had
stabilized for three consecutive readings as follows:
• pH: ±0.2 SU;
• Specific Conductance: ±5%; and
• Turbidity: <10 NTUs or stable within 10%
If the designated water quality parameters had not stabilized after five well volumes had been
purged, then purging stopped at that time and a note of explanation was recorded in the field log
forms. Table 9 presents the final measured field parameters.
Samples were sent under chain-of-custody protocol to Lancaster Laboratories located in
Lancaster, PA, for analysis of:
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• The NC Hazardous Substance List metals (antimony, arsenic, beryllium, cadmium,
chromium, copper, lead, manganese, mercury, nickel, selenium, silver, thallium, zinc)
using Method SW 846-7471B (mercury) and Method SW 846-6010C (all other metals);
• Major cations (calcium [Ca], magnesium [Mg], sodium [Na], and potassium [K]) using
Method SW 846-6010C;
• Major anions (chloride [Cl], bromide [Br], sulfate [SO4], alkalinity [HCO3], and nitrate/
nitrite [NO3/NO2]) using EPA Method 300.0 (Cl, Br, SO4, NO3/NO2) and EPA Method
310.1 (HCO3);
• Strontium [Sr], boron [B], barium [Ba], molybdenum [Mo], iron [Fe], vanadium [V] using
Method SW 846-6010C; and
• Total dissolved solids [TDS] using Standard Method 2540 C-1997.
The samples were properly preserved, labeled, logged onto a chain-of-custody form, and placed
into an iced cooler prior to shipment.
The analytical results are presented in Table 10. Hard copies of the laboratory analytical
reports are included in Appendix A1.
3.4.2.1 CCR Interstitial Water
As can be seen from Table 9 and Table 10, CCR interstitial water conditions were anaerobic
(ORP of -267 mV) and pH conditions were circumneutral (pH 7.43). In addition, elevated levels
of arsenic, boron, iron, and manganese were detected in CCR interstitial water at this location
(i.e., PZ-Int) compared to groundwater outside the basins. Note that the elevated
concentrations of various constituents detected in groundwater well MW-2C are discussed in
Section 3.4.2.2 below. In general, these interstitial water results were consistent with the
interstitial water results from the 1971 Basin reported in the Phase II Groundwater Quality
Assessment Report [Catlin, 2012], although PZ-Int exhibited higher boron concentrations and
lower manganese concentrations compared to the two temporary piezometers sampled during
the Phase II Groundwater Quality Assessment.
3.4.2.2 Site Groundwater
As discussed above, three intermediate-depth monitoring wells (MW-34B, MW-35B, and MW-
36B) and four deep monitoring wells (MW-27C, MW-34C, MW-35C, and MW-36C) were
installed as part of the additional site investigation. These wells were installed to supplement
the existing monitoring network, especially with respect to the areas northeast and north of the
1984 Basin.
In addition, certain existing monitoring wells that do not serve as routine compliance monitoring
wells were selected and sampled to evaluate groundwater quality conditions along several
transects away from the CCR basins. These transects included MW-2B/2C and MW-3B (near
the 1971 Basin), MW-6B/6C and PZ-25 (near the Interior Containment Area within the 1984
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Basin), MW-34B/34C and MW-35B/35C (northeast of the 1984 Basin), and MW-36B/36C and
MW-27C to the north of the 1984 Basin. Well MW-5B was included as a background well.
These wells and transects are shown on Figure 7 and the results are summarized in Table 9
(Field Parameters) and Table 10 (Analytical Results).
3.4.2.2.1 Background Conditions
Consistent with results from historical sampling events of other background wells (i.e., MW-4B
and MW-5C), background well MW-5B indicated low to non-detect results for most COIs.
However, iron was detected at 700 µg/L, which is above its groundwater standard (300 µg/L),
indicating that geochemical background conditions contribute to elevated levels of iron in
groundwater. Manganese was not detected above its groundwater standard of 50 µg/L despite
fairly acidic conditions within this well (pH 3.94), while the deeper compliance background well
(MW-5C) has historically exhibited elevated levels of manganese (but not iron).
Both the historical investigations including background wells MW-4B and MW-5C as well as the
supplemental investigation including background well MW-5B have indicated that the
groundwater at Sutton has exhibited naturally acidic conditions. Furthermore, the historical data
for MW-4B and MW-5C have also established naturally elevated concentrations of iron and
manganese above their respective groundwater standards. It is noted, however, that the
shallower background well MW-5B sampled during the supplemental investigation did not
exhibit elevated levels of these constituents above groundwater standards.
3.4.2.2.2 Site Groundwater Conditions
While well MW-2B exhibited low concentrations of COIs, the deeper well MW-2C indicated
elevated concentrations of several COIs, including arsenic (278 µg/L), boron (3,020 µg/L), iron
(9,510 µg/L), manganese (375 µg/L), and TDS (542 mg/L). The levels were consistent with
historical results from this well. Well MW-3B downgradient of the MW-2B/2C well pair exhibited
low COI concentrations. However, it is likely that this well is screened too shallow to evaluate
whether the elevated concentrations found in MW-2C were attenuated along the groundwater
flow path.
With the exception of boron and manganese, the well pair MW-6B/6C exhibited low
concentrations of COIs. The boron levels were approximately consistent with each other, while
manganese levels were higher in MW-6C as compared to MW-6B. Overall, these
concentrations were lower than the levels detected in MW-2C, indicating that the clay liner
within the 1984 Basin provides a level of groundwater protection that is not found within the
unlined 1971 Basin. The downgradient piezometer PZ-25, which is screened at the same depth
as MW-6B but is located beyond the compliance boundary, did exhibit low levels of COIs and
indicated attenuation of these constituents away from the basins.
Similarly, the newly installed well pair MW-34B/34C indicated low levels of COIs. However, the
deeper well MW-34C exhibited somewhat elevated levels of manganese (303 µg/L) and iron
(613 µg/L), even though these levels were consistent with background conditions. The
downgradient newly installed well pair MW-35B/35C (located approximately coinciding with the
compliance boundary) exhibited similar concentrations of COIs as wells MW-34B/34C, even
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though iron (2,810 µg/L) and manganese (345 µg/L) concentrations were somewhat higher in
MW-35C and were above their respective groundwater standards. Again, this can likely be
attributed to background conditions, and other CCR indicator parameters such as arsenic and
boron were non-detect or low at these locations. This is further evidence that the clay liner is
fairly effective in protecting groundwater from CCR leaching. It is noted, however, that well MW-
35C did exhibit a selenium detection of 55 µg/L, which is above its groundwater standard of 20
µg/L. The wells closer to the basin boundary (i.e., MW-34B/34C) exhibited levels below the
PQL of 40 µg/L, suggesting that the 1984 Basin is unlikely to be a continuing source of selenium
and that this elevated detection in MW-35C may be the result of historical leaching.
The northern transect formed by the newly installed well pair MW-36B/36C and the newly
installed well MW-27C indicated a very similar pattern of generally low concentrations of COIs,
but elevated levels of iron and manganese in the deeper wells MW-36C and MW-27C. Again,
well MW-27C indicated an elevated selenium concentration of 55 µg/L, while the well pair closer
to the basin boundary (i.e. MW-36B/36C) exhibited levels below the PQL.
One well (i.e., MW-31B) was sampled along the property boundary with the S.T. Wooten
Corporation Site. Elevated levels of iron (1,390 µg/L) were detected in this well, but this is likely
attributable to background conditions. The deeper compliance well MW-31C (not sampled for
this investigation) has historically shown elevated levels of iron (about twice the levels found in
MW-31B), manganese, and boron.
3.5 Groundwater Monitoring at LOLA
Unfiltered water samples were collected from the nine existing wells using low-flow sampling
methods as described above. Samples were sent under chain-of-custody protocol to Lancaster
Laboratories located in Lancaster, PA, for analysis of the same parameters as outlined above
for the wells and piezometers around the CCR basins.
Figure 3 depicts the monitoring well locations (as well as the boring locations for the soil and
CCR samples described in Section 2.4) within the LOLA.
Water quality samples were collected from all existing monitoring wells within the LOLA,
including MW-13, MW-13D, MW-14, MW-15, MW-15D, MW-16, MW-16D, MW-20 and MW-20D.
During purging of the wells, field parameters were collected and the readings are summarized in
Table 11. As can be seen from this table, pH conditions were relatively uniform and
circumneutral to slightly acidic and redox conditions were generally mildly reducing. This is
consistent with other monitoring locations throughout Sutton (including background conditions),
even though many locations across Sutton appear to have somewhat more oxidizing conditions.
The difference might be related to the input from natural organic matter (e.g., decaying leaf litter
within the densely vegetated areas in the northern part of the LOLA) and/or potential historical
impacts of petroleum hydrocarbons around the former aboveground storage tank (AST) area
within the southern part of the LOLA.
The analytical results are presented in Table 12 and hard copies of the laboratory analytical
reports are included in Appendix A2. Consistent with historical sampling results, the arsenic
concentration in MW-13 (shallow well) was elevated (218 µg/L), but the boron concentration
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was only slightly elevated (935 µg/L). On the other hand, the deep well at this location (MW-
13D) indicated a low arsenic concentration (9.6 µg/L), but an elevated boron concentration
(2,350 µg/L), which likely did not originate within the LOLA, but from the upgradient deeper
zones within the 1971 Borrow Area. Note that the MW-13 well cluster is located within the
compliance boundary. Shallow monitoring well MW-15, which appears to be located at the
previously established compliance boundary around the LOLA, indicated an arsenic
concentration of 31.2 µg/L, exceeding the groundwater standard of 10 µg/L. Manganese and
iron concentrations were elevated throughout the LOLA, which is consistent with conditions
across Sutton (including background conditions).
3.6 Summary of Groundwater Impacts
In order to summarize and graphically depict groundwater impacts at Sutton, cross-sections
were developed. These cross-sections are depicted on Figures 8 through 10. Figure 8 depicts
the locations of the cross-sections. Figure 9 depicts cross-section A-A’, which was cut from
west to east along the northern boundary of the 1984 Basin, and cross-section B-B’, which was
cut from west to east along the southern end of the 1971 Basin, including a small part of the
northwestern corner of the LOLA and across the Discharge Canal. Figure 10 depicts cross-
section C-C’, which was cut from north to south across both the 1984 and 1971 Basins and
towards the southern extent of the LOLA. Note that the cross-sections were limited to the areas
within the compliance boundaries of the 1971 and 1984 Basins as well as the LOLA. Therefore,
they do not delineate the horizontal or vertical extent of groundwater exceedances across
Sutton, which would be impractical to do given the widespread occurrences of elevated levels of
iron, manganese, and acidic pH conditions, much of which can be attributed to natural
background conditions. Furthermore, boron concentrations are elevated at multiple monitoring
locations outside the compliance boundary. Additional cross-sections, including monitoring
wells showing exceedances of groundwater standards, can be found in the CSA [Synterra,
2015a, 2016b].
These cross-sections include the monitoring wells, piezometers, and other borings used to
construct the cross-sections. Where applicable, wells and piezometers indicate groundwater
detections found to be in excess of groundwater standards established by Subchapter L of
Chapter 2 of Title 15A of the North Carolina Administrative Code. Note that CCR interstitial
water concentrations are not depicted given that these results do not represent groundwater
conditions.
As can be seen on cross-section A-A’, the shallower (i.e., B-wells) do not indicate any
exceedances of groundwater standards, while the deeper (i.e., C-wells) do indicate
exceedances of groundwater standards for iron, manganese, and in the case of MW-35C, for
selenium. Given the relative protectiveness of the clay liner within the 1984 Basin as well as the
naturally elevated concentrations of iron and manganese, the iron and manganese
exceedances are likely to mainly attributable to background conditions. The selenium
exceedance is likely attributable to historical leaching from CCR.
Cross-section B-B’ illustrates exceedances of the groundwater standards within the
northwestern corner of the LOLA (i.e., the MW-13 well cluster) and outside the southeastern
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corner of the 1971 Basin. These exceedances include iron, manganese, boron, and arsenic.
As previously discussed, the exceedances of iron and manganese are partially attributable to
background conditions, while the boron and arsenic exceedances are linked to the CCR within
the 1971 Basin.
Cross-section C-C’ depicts conditions from the compliance boundary north of the 1984 Basin to
the southern extent of the LOLA. As can be seen, groundwater standards for iron, manganese
and arsenic are exceeded at the southern extent of the compliance boundary for the LOLA (i.e,
MW-15 well cluster), while groundwater standards for manganese and selenium are exceeded
within the shallow and deep wells of the MW-27 cluster and standards for iron are exceeded
within the deeper well of the MW-27 well cluster at the northern compliance boundary.
3.7 Geochemical Conceptual Site Model
A geochemical evaluation was implemented during the conceptual closure investigation, which
was presented in the Data Interpretation and Analysis Report [Geosyntec, 2014c]. Based on
this evaluation, a geochemical Conceptual Site Model (CSM) was developed that can be
summarized as follows:
• CCR within the basins contain most of the analyzed constituents at levels greater than
the natural soil samples around and below the CCR basins. This is especially apparent
for constituents that are typically indicative of CCR, including arsenic, boron, and iron,
and to a lesser degree, manganese, chromium, and selenium. Furthermore, the major
cations calcium, magnesium, potassium, and sodium also exhibit concentrations above
the surrounding soil concentrations.
• Leaching tests using the SPLP procedure indicate that arsenic and most of the major
cations still leach from CCR at elevated levels. However, boron, chromium, iron, and
manganese do not leach at elevated levels, which indicates that these constituents are
either already leached out of CCR (e.g., boron) and/or are more affected by redox
reactions (e.g., iron and manganese) than by desorption and/or dissolution.
• Groundwater in the immediate vicinity of the 1971 Basin appears to show an impact from
CCR contained within this basin. This is likely further pronounced due to the presence
of CCR at considerable depths (i.e., in the 1971 Borrow Area) within the boundaries of
the 1971 Basin. Monitoring points further away (i.e., north) show a diminishing impact,
suggesting that the clay liner within the 1984 Basin provides some protection of the
surrounding groundwater.
• The ionic compositions indicate that groundwater in the vicinity of the 1971 Basin has a
geochemical signature consistent with the CCR interstitial water sample. However,
groundwater further to the north and outside of the 1984 Basin indicates a geochemical
signature different from CCR interstitial water, which also suggests that the clay liner
within the 1984 Basin provides some protection of the surrounding groundwater not
found within the unlined 1971 Basin.
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• Elevated boron concentrations in groundwater are likely a historical artifact of leaching of
the CCR since the SPLP results indicate only minor leaching potential for boron from
recently obtained samples. Boron is not attenuated by sorption or precipitation
reactions; therefore, it has the potential to migrate over longer distances, and its
distribution may also be somewhat affected by groundwater pumping activities along the
eastern property boundary.
• The Eh-pH conditions in groundwater affect the distribution of iron, manganese, arsenic,
and selenium. Iron and manganese are found at elevated concentrations across much
of Sutton, including background locations. Based on their respective Eh-pH diagrams
and using site-specific data, arsenic and selenium are likely present in their less mobile
forms in Sutton groundwater at certain distances away from the basins, which is
consistent with their low-level to non-detect results along the compliance boundary.
Furthermore, the conditions within CCR interstitial water are conducive to precipitating
selenium with iron, as predicted in the Eh-pH diagram, which appears to immobilize
selenium within the CCR basins. However, the selenium detections in wells MW-27C
and MW-35C are not consistent with this explanation, and the elevated detections at
these locations remain unclear at this point. Note that the Eh-pH diagrams are included
and discussed in the Data Interpretation and Analysis Report.
• Excavation of the CCR will remove the source for potential additional groundwater
impacts. However, some residual impacts from historical leaching are expected to
remain, especially with respect to boron as well as the elevated levels of iron and
manganese and the naturally acidic groundwater conditions across Sutton (including
background conditions). Some of these residual impacts are expected to decrease over
time through natural attenuation (e.g., boron), but elevated levels of iron, manganese,
and acidic groundwater conditions will likely remain due to background conditions, even
though levels may also slightly decrease over time due to source removal efforts.
3.8 Conclusions
The geochemical conceptual site model presented above, and the supporting information
presented in this Report and other referenced reports fulfill the requirements outlined under §
130A-309.212 (c)(5 through 9) for Sutton. Additional horizontal and vertical delineation results
for constituents exceeding groundwater standards are presented in SynTerra’s CSA Report
[2015a, 2016b] and CAP [2015b].

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4. REFERENCES
Catlin (2012). Phase II Groundwater Quality Assessment for Ash Pond Impacts at the L.V.
Sutton Electric Plant, Wilmington, North Carolina; July 2012.
EPA Region 4 (2011a). Soil Sampling Operating Procedure. Science and Ecosystem Support
Division. Athens, Georgia.
EPA Region 4 (2011b). Groundwater Sampling Operating Procedure. Science and Ecosystem
Support Division. Athens, Georgia.
Geosyntec Consultants. (2014a). Preliminary Site Investigation Data Report – Conceptual
Closure Plan – L.V. Sutton Plant, September 2014.
Geosyntec Consultants. (2014b). Preliminary Site Investigation Data Report, Addendum No.1 –
Conceptual Closure Plan – L.V. Sutton Plant, September 2014.
Geosyntec Consultants. (2014c). Data Interpretation and Analysis Report – Conceptual Closure
Plan – L.V. Sutton Plant, September 2014.
Geosyntec Consultants. (2014d). Data Interpretation and Analysis Report, Addendum No.1 –
Conceptual Closure Plan – L.V. Sutton Plant, September 2014.
North Carolina Department of Environment and Natural Resources (NCDENR) (2013). “North
Carolina Administrative Code – Title 15A, Subchapter 2L – Classifications and Water Quality
Standards Applicable to the Groundwaters of North Carolina”
SynTerra Corporation (2015a), “Comprehensive Site Assessment Report, Duke Energy L.V.
Sutton Energy Complex, New Hannover County, North Carolina”, August 5, 2015.
SynTerra Corporation (2015b), “Corrective Action Plan, Part 1, Duke Energy L.V. Sutton Energy
Complex, New Hannover County North Carolina”, November 2, 2015.
SynTerra Corporation (2016a), “Corrective Action Plan, Part 2, Duke Energy L.V. Sutton Energy
Complex, New Hannover County North Carolina”, February 1, 2016.
SynTerra Corporation (2016b), “Comprehensive Site Assessment Report, Supplement 1, Duke
Energy L.V. Sutton Energy Complex”, August 31, 2016.

TABLES
1 of 2

Table 1. Soil and CCR Analytical Data
Location
Sample
Interval
(ft BGS)
Sample
Date
Concentration (mg/kg)
Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Total Chromium Copper Iron Lead Magnesium Manganese Mercury Molybdenum Nickel
CCR SAMPLES
GP2 52-56 5/16/2014 < 5.45 119 954 6.99 54.3 0.103 U 3,710 54.2 72.7 33,900 34.9 2,890 127 < 0.267 < 2.72 40.8
72-76 5/19/2014 < 5.5 136 632 5.28 66.4 0.105 U 5,210 62.5 74.9 36,300 32.2 2,580 126 < 0.282 27.3 85.2
GP3
24-28 5/20/2014 < 5.49 60.4 384 7.55 36.4 0.104 U 2,890 41.3 74.7 15,300 32.4 1,700 64.7 < 0.261 5.92 39.7
72-76 5/20/2014 < 5.64 104 785 5.68 58.5 0.107 U 3,670 44.3 68.5 23,700 28.4 2,350 103 < 0.272 < 2.82 49.1
76-80 5/20/2014 < 5.64 115 599 5.28 57.1 0.107 U 3,270 49.9 76.4 23,500 32.8 2,260 107 < 0.285 < 2.82 46
80-84 5/20/2014 < 4.9 58.9 477 3.62 41.1 0.0931 U 3,000 38.7 49.6 30,800 20.1 1,650 105 < 0.235 < 2.45 33.1
SPT-3 10-12 5/9/2014 0.955 U 19.6 214 2.71 < 12.9 < 1.29 1,700 27.4 38.8 20,100 16.8 842 88.3 < 0.247 < 2.58 26.4
SPT-7 4-6 5/7/2014 0.959 U 49.1 430 5.81 31.3 < 1.3 3,560 42.3 58.1 13,900 28.6 1,510 67.4 < 0.266 < 2.59 30.5
PZ-INT 12-14 5/7/2014 1.27 U 38.1 304 4.15 31 < 1.71 2,390 19.3 70.7 7,610 21.2 809 40.8 < 0.337 < 3.42 28.5
SOIL SAMPLES
MW34C 4-6 5/13/2014 0.749 U 0.709 U 1.29 0.0679 U 0.851 U 0.077 U < 40.5 < 3.04 < 2.03 342 < 3.04 < 20.3 2.42 0.0099 U < 2.03 < 2.03
MW36C 4-6 5/9/2014 0.778 U 0.736 U 1.42 0.0705 U 0.884 U 0.0799 U 224 < 3.16 < 2.1 835 < 3.16 36.1 5.05 0.0106 U 0.179 U < 2.1
SB1 2.5-3 5/13/2014 0.783 U 0.74 U < 1.06 0.0709 U 0.888 U 0.0804 U < 42.3 < 3.17 0.307 U < 42.3 0.529 U 1.77 U 1.22 0.0106 U 0.18 U < 2.12
SB2 2.5-3 5/13/2014 0.729 U 0.69 U 1.5 0.066 U 0.828 U 0.0749 U < 39.4 < 2.96 < 1.97 1,620 < 2.96 32.2 1.93 0.0099 U 0.167 U < 1.97
GP5 20-24 5/21/2014 0.868 U 50.2 18 2.97 25.1 < 1.17 242 24.6 27.7 216 14.1 1,290 56.1 0.0113 U < 2.35 17.3
GP6 24-28 5/21/2014 0.837 U < 4.52 1.92 0.0758 U < 11.3 0.0859 U 65 < 3.39 0.328 U 424 - 37.1 2.45 0.0115 U 0.192 U < 2.26
Note(s):
[1] U indicates results below the method detection limit (MDL) and < indicates results below the practical quantitation limit (PQL).
[2] mg/kg indicates milligrams per kilogram.
[3] ft BGS indicates feet below ground surface.
[4] Sample IDs for these locations were a combination of location, depth, and sampling date, i.e. SS-MW-24C(4-6)-20140513
[5] Geotechnical boring SPT9 was collected during installation of PZ-INT. The CCR sample was collected from SPT-9.
[6] * indicates moisture is reported as a percent.
[7] ** indicates pH is reported in standard units.

2 of 2

Table 1. Soil and CCR Analytical Data (Continued)
Location
Sample
Interval
(ft BGS)
Sample Date Concentration (mg/kg)
Potassium Selenium Silver Sodium Strontium Thallium Vanadium Zinc Bromide Chloride Sulfate Moisture* pH (Lab)**
CCR SAMPLES
GP2 52-56 5/16/2014 7,690 7.99 0.231 U 920 493 < 8.17 - 57.9 5.5 U 27.7 41.5 28.7 8.23
72-76 5/19/2014 5,720 6.44 0.234 U 822 564 0.715 U - 66.3 5.6 U 18.4 85.5 29.4 7.56
GP3
24-28 5/20/2014 3,610 14.6 0.233 U 551 327 0.714 U - 51.9 5.6 U < 13.9 39.1 27.9 7.81
72-76 5/20/2014 6,410 8.73 0.24 U 765 426 < 8.46 - 48.2 5.7 U < 14.3 34.5 29.8 8.5
76-80 5/20/2014 5,720 7.34 0.24 U 699 418 < 8.47 - 55.9 5.8 U 15.4 53.4 31.2 8.58
80-84 5/20/2014 3,860 < 4.9 0.208 U 475 317 < 7.35 - 35.9 5 U < 12.6 22.3 20 8.49
SPT-3 10-12 5/9/2014 1,370 14.9 0.219 U < 258 148 0.671 U - 24.1 5.2 U 6.5 U < 19.6 23.3 6.53
SPT-7 4-6 5/7/2014 2,820 5.39 0.22 U 499 420 < 7.77 - 58 5.4 U 6.8 U 24.6 26.5 8.35
PZ-INT 12-14 5/7/2014 1,890 < 6.84 0.291 U < 342 290 0.889 U - 29.2 6.8 U 32.5 74.8 42.1 8.02
SOIL SAMPLES
MW34C 4-6 5/13/2014 < 101 0.81 U 0.172 U 16.9 U < 1.01 0.527 U - < 4.05 4.1 U < 10.2 74.4 3.2 6.27
MW36C 4-6 5/9/2014 < 105 0.842 U 0.179 U 17.6 U 1.26 0.547 U - < 4.21 4.3 U 5.3 U 5.3 U 6.8 7.9
SB1 2.5-3 5/13/2014 8.82 U 0.846 U 0.18 U 17.7 U < 1.06 0.55 U < 1.06 < 4.23 4.3 U 5.4 U < 16.1 8.2 4.68
SB2 2.5-3 5/13/2014 < 98.5 0.788 U 0.167 U 16.5 U < 0.985 0.512 U 3.95 < 3.94 4 U 5 U < 15.1 2.4 4.55
GP5 20-24 5/21/2014 < 117 0.938 U < 1.17 415 11.3 < 7.04 - 25.8 4.8 U 35.6 < 17.8 15.6 7.58
GP6 24-28 5/21/2014 < 113 0.905 U 0.192 U 18.9 U 2.12 0.588 U - < 4.52 4.7 U 17 18.2 13.3 7.87
Note(s):
[1] U indicates results below the method detection limit (MDL) and < indicates results below the practical quantitation limit (PQL).
[2] mg/kg indicates milligrams per kilogram.
[3] ft BGS indicates feet below ground surface.
[4] Sample IDs for these locations were a combination of location, depth, and sampling date, i.e. SS-MW-24C(4-6)-20140513
[5] Geotechnical boring SPT9 was collected during installation of PZ-INT. The CCR sample was collected from SPT-9.
[6] * indicates moisture is reported as a percent.
[7] ** indicates pH is reported in standard units.

1 of 2

Table 2. SPLP Analytical Data
Location
Sample
Interval
(ft
BGS)
Sample
Date
Concentration (µg/L)
Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Total Chromium Copper Iron Lead Magnesium Manganese Mercury Molybdenum Nickel
CCR SAMPLES
GP2 52-56 5/16/2014 5.3 U 188 172 0.67 U < 100 0.76 U 4,690 < 30 2.7 U < 400 4.7 U 584 < 10 0.06 U < 20 1.5 U
72-76 5/19/2014 < 40 258 146 0.67 U 340 0.76 U 8,240 < 30 < 20 4,950 < 30 1,660 17.7 0.06 U 688 < 20
GP3
24-28 5/20/2014 < 40 56.1 95.7 0.67 U < 100 0.76 U 5,870 1.6 U 2.7 U 43 U 4.7 U 836 < 10 0.06 U 153 1.5 U
72-76 5/20/2014 < 40 208 76.6 0.67 U 120 0.76 U 4,100 < 30 2.7 U < 400 4.7 U 1,020 < 10 0.06 U < 20 1.5 U
76-80 5/20/2014 < 40 192 44.4 0.67 U 113 0.76 U 3,970 < 30 < 20 < 400 4.7 U 1,330 < 10 0.06 U < 20 1.5 U
80-84 5/20/2014 5.3 U 151 54.7 0.67 U 125 0.76 U 3,550 < 30 < 20 546 4.7 U 1,170 < 10 0.06 U < 20 < 20
SPT3 10-12 5/9/2014 5.3 U 6.8 U 64.2 0.67 U < 100 0.76 U 1,870 1.6 U 2.7 U < 400 4.7 U 582 < 10 0.06 U < 20 < 20
SPT7 4-6 5/7/2014 5.3 U 73.4 72.7 0.67 U < 100 0.76 U 6,380 < 30 2.7 U 43 U 4.7 U 1,460 0.83 U 0.06 U < 20 1.5 U
SPT9 12-14 5/7/2014 5.3 U 69.9 143 0.67 U < 100 0.76 U 4,870 < 30 < 20 < 400 4.7 U 531 < 10 0.06 U < 20 < 20
SOIL SAMPLES
GP5 20-24 5/21/2014 5.3 U < 40 36.6 0.67 U < 100 0.76 U 1,880 < 30 2.7 U < 400 4.7 U 536 < 10 0.06 U < 20 1.5 U
GP6 24-28 5/21/2014 5.3 U < 40 32.7 0.67 U < 100 0.76 U 1,230 1.6 U 2.7 U 552 4.7 U 487 < 10 0.06 U 1.7 U 1.5 U
SB1 2.5-3 5/13/2014 5.3 U 6.8 U < 10 0.67 U < 100 0.76 U < 400 1.6 U 2.7 U 43 U 4.7 U < 200 < 10 0.06 U 1.7 U 1.5 U
SB2 2.5-3 5/13/2014 5.3 U 6.8 U 16.4 0.67 U < 100 0.76 U 496 < 30 2.7 U 3,870 4.7 U < 200 < 10 0.06 U 1.7 U 1.5 U
Note(s):
[1] U indicates results below the method detection limit (MDL) and < indicates results below the practical quantitation limit (PQL).
[2] µg/L indicates micrograms per liter.
[3] SPLP indicates synthetic precipitation leaching procedure.
[4] ft BGS indicates feet below ground surface.
[5] Sample IDs for these locations were a combination of location, depth, and sampling date, i.e. SS-GP2(52-56)-20140516

2 of 2

Table 2. SPLP Analytical Data (Continued)
Location
Sample
Interval
(ft BGS)
Sample
Date
Concentration (µg/L)
Potassium Selenium Silver Sodium Strontium Thallium Vanadium Zinc
CCR SAMPLES
GP2 52-56 5/16/2014 <1,000 < 40 2.1 U 3,020 194 5.4 U - < 40
72-76 5/19/2014 <1,000 8.4 U 2.1 U 15,100 228 5.4 U - < 40
GP3
24-28 5/20/2014 <1,000 < 40 2.1 U 3,620 179 5.4 U - < 40
72-76 5/20/2014 <1,000 < 40 2.1 U 4,650 277 5.4 U - < 40
76-80 5/20/2014 <1,000 < 40 2.1 U 4,640 241 5.4 U - < 40
80-84 5/20/2014 <1,000 < 40 2.1 U 5,560 175 5.4 U - < 40
SPT3 10-12 5/9/2014 <1,000 < 40 2.1 U 2,590 81.1 5.4 U - 2 U
SPT7 4-6 5/7/2014 98 U 42.8 2.1 U < 2,000 224 5.4 U - 2 U
SPT9 12-14 5/7/2014 <1,000 8.4 U 2.1 U < 2,000 265 5.4 U - 2 U
SOIL SAMPLES
GP5 20-24 5/21/2014 <1,000 8.4 U 2.1 U 6,620 32.3 5.4 U - < 40
GP6 24-28 5/21/2014 <1,000 8.4 U 2.1 U 3,400 25.5 5.4 U - < 40
SB1 2.5-3 5/13/2014 98 U 8.4 U 2.1 U < 2,000 < 10 5.4 U < 10 < 40
SB2 2.5-3 5/13/2014 <1,000 8.4 U 2.1 U 5,170 < 10 5.4 U 10.6 < 40
Note(s):
[1] U indicates results below the method detection limit (MDL) and < indicates results below the practical quantitation limit (PQL).
[2] µg/L indicates micrograms per liter.
[3] SPLP indicates synthetic precipitation leaching procedure.
[4] ft BGS indicates feet below ground surface.
[5] Sample IDs for these locations were a combination of location, depth, and sampling date, i.e. SS-GP2(52-56)-20140516

1 of 2

Table 3. 1971 Borrow Area Investigation – CCR Analytical Data
Location
Sample
Interval
(ft BGS)
Sample Date
Concentration (mg/kg)
Antimony Arsenic Barium Beryllium Boron Cadmium Total
Chromium Copper Iron Lead Manganese Mercury Molybdenum Nickel
GP12 28-32 7/2/2014 < 6.17 67.6 467 5.99 41.2 < 1.54 46.8 76.8 13200 30.8 64.1 < 0.31 4.39 35.9
GP13 64-68 7/1/2014 0.464 U 129 865 6.56 52.2 < 1.41 49 64 19,600 32.9 95.1 < 0.274 < 2.81 34.3
68-72 0.45 U 127 591 5.1 52.3 < 1.36 47.4 64.8 19,500 31.4 101 < 0.269 2.91 40.8
GP14 60-62 7/2/2014 0.502 U 137 562 3.82 34.3 < 1.52 31.9 58.8 13,500 24.2 72.8 < 0.289 < 3.04 26.5
68-72 0.459 U 144 661 5.45 45.5 < 1.39 55.8 66.5 29,500 29.6 114 < 0.269 < 2.78 41
GP15 60-64 7/1/2014 0.432 U 125 493 4.89 66.7 0.0432 U 65.1 64.5 43,400 24.6 160 < 0.249 2.68 47.3
68.7-70.7 0.453 U 35.6 265 3 30.2 0.0453 U 22.3 28.9 22,400 15.2 63.4 < 0.28 < 2.75 112
MB2 64-68 6/25/2014 0.452 U 87.3 502 3.92 42.3 0.0452 U 43.8 59.1 14,500 26.1 87.6 < 0.255 < 2.74 29.8
76-80 0.457 U 155 735 5.7 55.3 0.0457 U 54.5 83.8 31,500 28.9 128 < 0.275 3.01 43.6
Note(s):
[1] U indicates results below the method detection limit (MDL).
[2] < indicates results below the practical quantitation limit (PQL).
[3] mg/kg represents milligrams per kilogram.
[4] ft BGS indicates feet below ground surface.
[5] S.U. represents standard units.

2 of 2

Table 3. 1971 Borrow Area Investigation – CCR Analytical Data (Continued)
Location Sample Interval (ft BGS) Sample Date Concentration (mg/kg) Moisture
(%)
pH (Lab)
(S.U.) Selenium Silver Strontium Thallium Zinc
GP12 28-32 7/2/2014 < 6.17 0.293 U 322 < 9.26 51.4 37.7 7.62
GP13 64-68 7/1/2014 6.68 0.267 U 491 < 8.44 53.3 32.3 8.69
68-72 5.71 0.259 U 388 < 8.17 53.4 30.1 8.61
GP14 60-62 7/2/2014 < 6.08 0.289 U 295 < 9.12 36.3 34.2 8.65
68-72 6.04 0.264 U 598 < 8.34 55.4 29.5 8.63
GP15 60-64 7/1/2014 < 5.24 0.249 U 561 9.28 55.8 25.9 8.28
68.7-70.7 < 5.49 0.261 U 237 62.5 27.5 29.3 7.89
MB2 64-68 6/25/2014 < 5.48 0.26 U 318 1.1 U 43.6 27 8.23
76-80 6.74 0.263 U 587 1.11 U 57.6 27.8 8.41
Note(s):
[1] U indicates results below the method detection limit (MDL).
[2] < indicates results below the practical quantitation limit (PQL).
[3] mg/kg represents milligrams per kilogram.
[4] ft BGS indicates feet below ground surface.
[5] S.U. represents standard units.
1 of 2

Table 4. 1971 Borrow Area Investigation – SPLP Analytical Data
Location
Sample
Interval
(ft BGS)
Sample
Date
Concentration (µg/L)
Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Total Chromium Copper Iron Lead Magnesium Manganese
GP12 28-32 7/2/2014 < 40 71.6 135 0.67 U < 100 0.33 U 3,240 1.3 U 28.1 33.4 U 4.7 U 529 < 10
GP13 64-68 7/1/2014 5.1 U 251 67.6 0.67 U 137 0.33 U 4,420 < 30 2.8 U < 400 4.7 U 1230 < 10
68-72 < 40 254 32.1 0.67 U 177 0.33 U 3,730 < 30 2.8 U < 400 4.7 U 1180 < 10
GP14 60-62 7/2/2014 5.1 U 247 90.1 0.67 U < 100 0.33 U 2,990 < 30 2.8 U < 400 4.7 U 603 < 10
68-72 < 40 263 28.1 0.67 U < 100 0.33 U 4,830 < 30 2.8 U < 400 4.7 U 560 < 10
GP15 60-64 7/1/2014 5.1 U 208 17.8 0.67 U 100 0.33 U 6,350 < 30 2.8 U < 400 4.7 U 678 < 10
68.7-70.7 5.1 U 91.4 33.2 0.67 U < 100 0.33 U 6,440 1.3 U 2.8 U < 400 4.7 U 960 < 10
MB2 64-68 6/25/2014 5.1 U 184 124 0.67 U < 100 0.33 U 4,320 < 30 2.8 U < 400 4.7 U 751 < 10
76-80 5.1 U 316 54.3 0.67 U 105 0.33 U 4,900 < 30 2.8 U < 400 4.7 U 849 < 10
Note(s):
[1] U indicates results below the method detection limit (MDL).
[2] < indicates results below the practical quantitation limit (PQL).
[3] µg/L represents micrograms per liter.
[4] SPLP represents synthetic precipitation leaching procedure.
[5] ft BGS indicates feet below ground surface.

2 of 2

Table 4. 1971 Borrow Area Investigation – SPLP Analytical Data (Continued)
Location Sample Interval (ft BGS) Sample Date Concentration (µg/L)
Mercury Molybdenum Nickel Potassium Selenium Silver Sodium Strontium Thallium Zinc
GP12 28-32 7/2/2014 0.06 U 141 < 20 <1,000 < 40 18 U 2,200 191 5.1 U < 40
GP13 64-68 7/1/2014 0.06 U < 20 1.6 U <1,000 < 40 18 U 3060 249 5.1 U < 40
68-72 0.06 U < 20 1.6 U 133 U < 40 < 100 3,950 183 5.1 U < 40
GP14 60-62 7/2/2014 0.06 U < 20 < 20 <1,000 < 40 18 U 3,870 102 5.1 U < 40
68-72 0.06 U < 20 1.6 U 133 U < 40 18 U 3,240 163 5.1 U < 40
GP15 60-64 7/1/2014 0.06 U < 20 1.6 U 133 U < 40 18 U 9,010 197 5.1 U < 40
68.7-70.7 0.06 U < 20 < 20 <1,000 < 40 18 U 3450 240 5.1 U < 40
MB2 64-68 6/25/2014 0.06 U < 20 1.6 U <1,000 < 40 1.8 U <2,000 281 5.1 U 2 U
76-80 0.06 U < 20 1.6 U <1,000 < 40 1.8 U 2,060 185 5.1 U < 40
Note(s):
[1] U indicates results below the method detection limit (MDL).
[2] < indicates results below the practical quantitation limit (PQL).
[3] µg/L represents micrograms per liter.
[4] SPLP represents synthetic precipitation leaching procedure.
[5] ft BGS indicates feet below ground surface.
1 of 2

Table 5. LOLA Investigation – CCR Analytical Data
Location
Sample
Interval (ft
BGS)
Sample Date
Concentration (mg/kg)
Antimony Arsenic Barium Beryllium Boron Cadmium Total
Chromium Copper Iron Lead Manganese Mercury Molybdenum Nickel
F-DPT1 3-4 6/30/2014 0.317 U < 3.84 3.28 0.0643 U < 9.59 0.0317 U < 2.88 < 1.92 348 < 2.88 3.12 0.0096 U < 1.92 < 1.92
7-8 0.47 U 26.5 452 3.54 24.6 0.047 U 18.8 42.8 12,600 13.9 44.9 < 0.296 < 2.85 54.8
F-DPT3 1.5-2.5 6/30/2014 0.337 U < 4.09 5.57 0.0685 U < 10.2 0.0337 U < 3.07 < 2.04 833 < 3.07 7.45 0.0103 U 0.174 U 2.1
5-6 0.567 U 28.1 314 2.73 22.8 0.0567 U 20.4 34.8 11,700 9.56 58.6 < 0.341 < 3.43 17.4
F-DPT4 18-20* 7/1/2014 < 8.47 < 8.47 34.2 0.142 U < 21.2 < 2.12 6.51 < 4.24 1,610 < 6.36 15.6 0.0209 U < 4.24 < 4.24
F-DPT5 2-4 7/1/2014 0.41 U 18.5 340 2.76 < 12.4 0.041 U 11.8 27 11,400 8.63 81.1 < 0.251 < 2.48 18.6
6-8 0.517 U 42.2 708 7.84 19 0.0517 U 25.4 66.4 13,500 18.8 85.7 < 0.311 < 3.13 34.9
F-DPT7
3-4
7/1/2014
0.394 U < 4.78 31.8 < 1.19 < 11.9 0.0394 U < 3.58 5.03 2,180 < 3.58 8.22 0.0117 U < 2.39 3.27
7-8 0.546 U 31.1 543 5.79 < 16.5 0.0546 U 22.2 58.2 8,130 17.7 43.5 < 0.315 < 3.31 27
15-16* 0.377 U < 4.57 7.41 0.0766 U < 11.4 0.0377 U < 3.43 0.377 U 267 < 3.43 2.52 0.0118 U 0.194 U < 2.29
F-DPT11 7-8 7/2/2014 0.345 U 6.44 38.8 < 1.04 < 10.4 0.0345 U 4.16 7.55 2,080 3.52 10.9 0.0108 U < 2.09 3.93
11-12 0.383 U 7.54 261 1.59 < 11.6 0.0383 U 6.59 14.7 9,420 3.6 46.9 0.0117 U < 2.32 8.38
F-DPT14 3-4 7/2/2014 0.537 U 35.1 447 5.15 < 16.3 0.0537 U 21.1 56.1 13,400 14.6 152 < 0.312 < 3.25 29.9
7-8 0.526 U 39 443 2.64 < 15.9 0.0526 U 17.1 34.9 16,200 9.93 72.7 < 0.308 < 3.19 16.6
Note(s):
[1] DPT locations were surveyed by WSP on July 7-8, 2014.
[2] U indicates results below the method detection limit (MDL) and < indicates results below the practical quantitation limit (PQL).
[3] mg/kg indicates milligrams per kilogram.
[4] ft BGS indicates feet below ground surface.
[5] Sample IDs for these locations were a combination of location, depth, and sampling date, i.e. SS-F-DPT-1(3-4)-20140630.
[6] * indicates sample was collected to verify that native soil had been reached.
[7] S.U. indicates standard units.

2 of 2

Table 5. LOLA Investigation – CCR Analytical Data (Continued)
Location Sample Interval (ft BGS) Sample Date Concentration (mg/kg) Moisture
(%)
pH (Lab)
(S.U.) Selenium Silver Strontium Thallium Zinc
F-DPT1 3-4 6/30/2014 0.422 U 0.182 U 1.74 0.767 U < 3.84 0.7 6.65
7-8 < 5.7 0.271 U 337 1.14 U 31.3 33.2 6.55
F-DPT3 1.5-2.5 6/30/2014 0.45 U 0.194 U 11.4 0.818 U < 4.09 5 8.28
5-6 < 6.87 0.326 U 201 1.37 U 14 44 7.71
F-DPT4 18-20* 7/1/2014 0.932 U 0.403 U 21 1.69 U 9.63 52.8 5.54
F-DPT5 2-4 7/1/2014 < 4.96 0.236 U 184 0.993 U 16.6 21 7.53
6-8 6.86 0.298 U 475 1.25 U 28 37.4 7.8
F-DPT7
3-4
7/1/2014
0.525 U 0.227 U 11.8 0.955 U 5.99 18.7 6.1
7-8 < 6.61 0.314 U 336 1.32 U 22.4 40.7 7.21
15-16* 0.503 U 0.217 U 3.43 0.915 U < 4.57 16.7 7.16
F-DPT11 7-8 7/2/2014 0.459 U 0.198 U 21.3 0.835 U < 4.18 8.8 6.43
11-12 < 4.65 0.221 U 83.7 0.929 U 6.3 16.4 6.69
F-DPT14 3-4 7/2/2014 < 6.5 0.309 U 235 1.3 U 20.5 38.5 6.32
7-8 < 6.38 0.303 U 195 1.28 U 15 39.1 5.9
Note(s):
[1] DPT locations were surveyed by WSP on July 7-8, 2014.
[2] U indicates results below the method detection limit (MDL) and < indicates results below the practical quantitation limit (PQL).
[3] mg/kg indicates milligrams per kilogram.
[4] ft BGS indicates feet below ground surface.
[5] Sample IDs for these locations were a combination of location, depth, and sampling date, i.e. SS-F-DPT-1(3-4)-20140630.
[6] * indicates sample was collected to verify that native soil had been reached.
[7] S.U. indicates standard units.

1 of 2

Table 6. LOLA Investigation – SPLP Analytical Data
Location
Sample
Interval
(ft BGS)
Sample Date Concentration (µg/L)
Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Total Chromium Copper Iron Lead Magnesium Manganese
F-DPT1 3-4 6/30/2014 5.1 U 7.2 U 29.9 0.67 U < 100 0.33 U 1,840 1.3 U 2.8 U < 400 4.7 U 259 < 10
7-8 5.1 U < 40 104 0.67 U < 100 0.33 U 1,550 < 30 2.8 U < 400 4.7 U < 200 < 10
F-DPT3 1.5-2.5 6/30/2014 5.1 U 7.2 U 61.2 0.67 U < 100 0.33 U 10,200 < 30 2.8 U 473 4.7 U 391 < 10
5-6 5.1 U < 40 22.3 0.67 U < 100 0.33 U 4,340 1.3 U 2.8 U 33.4 U 4.7 U 204 < 10
F-DPT4 18-20* 7/1/2014 5.1 U 7.2 U 42.4 0.67 U < 100 0.33 U 1,080 1.3 U < 20 < 400 4.7 U < 200 < 10
F-DPT5 2-4 7/1/2014 < 40 < 40 105 0.67 U < 100 0.33 U 5,400 < 30 < 20 < 400 4.7 U 323 < 10
6-8 < 40 41.5 221 0.67 U < 100 0.33 U 12,000 1.3 U 2.8 U 33.4 U 4.7 U 214 < 10
F-DPT7
3-4
7/1/2014
5.1 U 7.2 U 17.3 0.67 U < 100 0.33 U 1,470 1.3 U 2.8 U < 400 4.7 U 211 < 10
7-8 < 40 < 40 295 0.67 U < 100 0.33 U 5,600 1.3 U 2.8 U 33.4 U 4.7 U 306 < 10
15-16* 5.1 U 7.2 U 44.7 0.67 U < 100 0.33 U 1,860 < 30 2.8 U 821 4.7 U 364 < 10
F-DPT11 7-8 7/2/2014 5.1 U 7.2 U < 10 0.67 U < 100 0.33 U 791 1.3 U 2.8 U < 400 4.7 U 278 0.83 U
11-12 5.1 U 7.2 U 57.1 0.67 U < 100 0.33 U 1,300 < 30 2.8 U 426 4.7 U 500 < 10
F-DPT14 3-4 7/2/2014 5.1 U 7.2 U 35.2 0.67 U < 100 0.33 U 1,110 1.3 U 2.8 U < 400 4.7 U 515 < 10
7-8 5.1 U 7.2 U 87 0.67 U < 100 0.33 U 1,710 1.3 U 2.8 U 33.4 U 4.7 U 320 0.83 U
Note(s):
[1] U indicates results below the method detection limit (MDL) and < indicates results below the practical quantitation limit (PQL).
[2] µg/L indicates micrograms per liter.
[3] SPLP indicates synthetic precipitation leaching procedure.
[4] ft BGS indicates feet below ground surface.
[5] Sample IDs for these locations were a combination of location, depth, and sampling date, i.e. SS-F-DPT-1(3-4)-20140630.
[6] * indicates sample was collected to verify that native soil had been reached.

2 of 2

Table 6. LOLA Investigation – SPLP Analytical Data (Continued)
Location Sample Interval (ft BGS) Sample Date Concentration (µg/L)
Mercury Molybdenum Nickel Potassium Selenium Silver Sodium Strontium Thallium Zinc
F-DPT1 3-4 6/30/2014 0.06 U < 20 < 20 133 U 4.8 U 1.8 U 4,810 < 10 5.1 U < 40
7-8 0.06 U < 20 < 20 <1,000 < 40 1.8 U <2,000 79.4 5.1 U < 40
F-DPT3 1.5-2.5 6/30/2014 0.06 U 1.7 U < 20 133 U 4.8 U 1.8 U 6,220 20.1 5.1 U < 40
5-6 0.06 U < 20 1.6 U 133 U < 40 1.8 U 2,760 43.6 5.1 U 2 U
F-DPT4 18-20* 7/1/2014 0.06 U 1.7 U 1.6 U 133 U 4.8 U 1.8 U 12,600 < 10 5.1 U < 40
F-DPT5 2-4 7/1/2014 0.06 U < 20 1.6 U 133 U 4.8 U 1.8 U 3,580 122 5.1 U < 40
6-8 0.06 U < 20 1.6 U <1,000 < 40 1.8 U <2,000 247 5.1 U < 40
F-DPT7
3-4
7/1/2014
0.06 U 1.7 U 1.6 U 133 U 4.8 U 1.8 U 6,090 10.1 5.1 U < 40
7-8 0.06 U 26.1 1.6 U 133 U < 40 1.8 U 2,710 139 5.1 U 2 U
15-16* 0.06 U < 20 1.6 U <1,000 4.8 U 1.8 U 5,740 25 5.1 U < 40
F-DPT11 7-8 7/2/2014 0.06 U 1.7 U 1.6 U 133 U 4.8 U 1.8 U 2,550 20.2 5.1 U 2 U
11-12 0.06 U < 20 1.6 U 133 U 4.8 U 1.8 U 4,410 37.5 5.1 U < 40
F-DPT14 3-4 7/2/2014 0.06 U < 20 1.6 U 133 U 4.8 U 1.8 U 5,530 21 5.1 U < 40
7-8 0.06 U < 20 < 20 <1,000 < 40 1.8 U 2,760 129 5.1 U 2 U
Note(s):
[1] U indicates results below the method detection limit (MDL) and < indicates results below the practical quantitation limit (PQL).
[2] µg/L indicates micrograms per liter.
[3] SPLP indicates synthetic precipitation leaching procedure.
[4] ft BGS indicates feet below ground surface.
[5] Sample IDs for these locations were a combination of location, depth, and sampling date, i.e. SS-F-DPT-1(3-4)-20140630.
[6] * indicates sample was collected to verify that native soil had been reached.
Table 7. Historical Groundwater Analytical Results – Metals
Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
MW-2-C 40-45
3/1/1990 - <1 - - - - - 120 - - - - 1 - - -
7/1/1990 - <1 - - - - - 130 - - - - 2 - - -
11/13/1990 - <1 - - - - - 50 - - - - 1 - - -
3/6/1991 - <1 - - - - - 130 - - - - 1 - - -
7/22/1991 - <1 - - - - - 90 - - - - <1 - - -
11/6/1991 - <1 - - - - - 2,200 - - - - 18 - - -
3/25/1992 - <1 - - - - - 1,000 - - - - 2 - - -
7/15/1992 - <1 - - - - - 900 - - - - <1 - - -
11/24/1992 - <1 - - - - - 1,700 - - - - <1 - - -
3/22/1993 - <1 - - - - - 2,300 - - - - 10 - - -
7/19/1993 - <1 - - - - - 1,800 - - - - 1 - - -
11/4/1993 - <1 - - - - - 900 - - - - 1 - - -
3/7/1994 - <1 - - - - - 930 - - - - 2 - - -
7/11/1994 - <1 - - - - - 770 - - - - <1 - - -
11/2/1994 - <1 - - - - - 730 - - - - 5 - - -
3/8/1995 - <1 - - - - - 1,200 - - - - 3 - - -
3/6/1996 - <1 - - - - - 430 - - - - <1 - - -
3/17/1997 - 5.5 - - - - - 1,500 - - - - 3 - - -
3/16/1998 - 55 - - - - - 3,360 - - - - <5 - - -
3/17/1999 - 66 - - - - - 3,970 - - - - 35 - - -
3/6/2000 - 35 - - - - - 1,870 - - - - <5 - - -
3/16/2001 - <5 - - - - - 2,810 - - - - <5 - - -
3/6/2002 - 104 - - - - - 3,230 - - - - <5 - - -
3/18/2003 - 102 - - - - - 5,310 - - - - <5 - - -
3/9/2004 - 47 - - - - - 3,330 - - - - <5 - - -
3/7/2005 - 104 - - - - - 4,600 - - - - <5 - - -
3/2/2006 - 126 - - - - - 3,220 - - - - <5 - - -
12/12/2006 0.75 280 41.9 2,100 0.068 0.18 0.0038 4,750 0.33 159 <0.1 0.58 0.58 <0.017 0.71 0.036
3/6/2007 <3 290 42 2,690 <1 <5 0.006 3,420 <3 146 <0.2 <5 <5 <5 <1 0.015
11/7/2007 <2.5 239 50 2,160 <1 <5 <0.005 3,460 <5 255 <0.2 <5 <5 <5 <1 0.009
3/11/2008 <2.5 134 46 2,200 23 <5 <0.005 3,060 <5 154 <0.2 <5 <5 <5 <1 0.006
11/6/2008 <2 186 44 2,160 <1 <5 <0.005 3,320 <5 65 <0.2 <5 <5 <5 <1 0.044
3/10/2009 <40 193 <100 1,600 <10 11 <0.01 2,880 <10 90 <0.2 39 <20 <10 <10 0.038
10/6/2009 <5 114 45 1,670 <5 <5 <0.005 3,910 <5 153 <0.2 <5 <5 <5 <5 0.006
3/10/2010 <1 148 41 1,910 <1 3 0.001 2,550 <1 141 <0.2 3 4 <1 <1 0.003
Table 7. Historical Groundwater Analytical Results – Metals (Continued)
2 of 16

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
11/11/2010 <0.5 196 45 2,150 <0.08 <5 <0.005 3,750 <5 120 <0.2 <5 <10 <5 0.58 <0.010
3/2/2011 <0.5 267 48.1 B 1,990 <0.08 <5 <0.005 5,740 <5 203 <0.2 <5 <10 - 0.56 <0.01
10/4/2011 <0.5 85.6 33.7 2,270 <0.08 <5 <0.005 3,140 <5 259 <0.2 <5 <10 - 0.57 0.0143
3/6/2012 <0.5 232 74.6 2,790 <0.08 <5 <0.005 7,170 <5 350 <0.2 <5 <10 - 0.6 <0.010
6/5/2012 <0.5 260 76.7 2,640 <0.08 <5 <0.005 8,050 <5 265 <0.2 <5 <10 - 0.11 <0.010
MW-4-B* 22-27
3/1/1990 - 7 - - - - - 6,500 - - - - 3 - - -
7/1/1990 - 7 - - - - - 4,800 - - - - 2 - - -
11/13/1990 - 1 - - - - - 810 - - - - <1 - - -
3/6/1991 - 1 - - - - - 700 - - - - <1 - - -
7/22/1991 - 1 - - - - - 890 - - - - <1 - - -
11/6/1991 - 1 - - - - - 720 - - - - <1 - - -
3/25/1992 - 1 - - - - - 840 - - - - 1 - - -
7/15/1992 - 1 - - - - - 650 - - - - <1 - - -
11/24/1992 - <1 - - - - - 50 - - - - <1 - - -
3/22/1993 - 1 - - - - - 610 - - - - <1 - - -
7/19/1993 - 1 - - - - - 620 - - - - <1 - - -
11/4/1993 - 1 - - - - - 610 - - - - <1 - - -
3/7/1994 - 1 - - - - - 550 - - - - <1 - - -
7/11/1994 - 1 - - - - - 500 - - - - <1 - - -
11/2/1994 - <1 - - - - - 600 - - - - <1 - - -
3/8/1995 - 9.8 - - - - - 9,700 - - - - 8 - - -
3/6/1996 - 4.2 - - - - - 5,700 - - - - <1 - - -
3/17/1997 - 3.4 - - - - - 3,200 - - - - 2 - - -
3/16/1998 - <5 - - - - - 907 - - - - <5 - - -
3/17/1999 - <5 - - - - - 1,470 - - - - 17 - - -
3/6/2000 - <5 - - - - - 1,070 - - - - <5 - - -
3/16/2001 - <5 - - - - - 536 - - - - <5 - - -
3/6/2002 - <5 - - - - - 755 - - - - <5 - - -
3/18/2003 - <5 - - - - - 989 - - - - <5 - - -
3/9/2004 - <5 - - - - - 627 - - - - <5 - - -
3/7/2005 - <5 - - - - - 741 - - - - <5 - - -
3/2/2006 - <5 - - - - - 588 - - - - <5 - - -
12/12/2006 0.14 0.28 28.7 12.5 <0.24 0.61 0.0276 597 0.24 23 <0.1 1.3 <0.14 <0.017 <0.014 0.0033
3/6/2007 <3 2 30 10 <1 <5 <0.005 607 <3 22 <0.2 <5 <5 <5 <1 0.007
11/7/2007 <2.5 <1 34 17 <1 <5 <0.005 623 <5 18 <0.2 <5 <5 <5 <1 0.011
3/11/2008 <2.5 2 24 19 <1 <5 <0.005 486 <5 16 <0.2 <5 <5 <5 <1 <0.005
11/6/2008 <2 <2 26 <5 <1 <5 <0.005 405 <5 14 <0.2 <5 <5 <5 <1 0.019
Table 7. Historical Groundwater Analytical Results – Metals (Continued)
3 of 16

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
3/10/2009 <40 <2 <100 30 <10 <10 <0.01 751 <10 29 <0.2 <10 <20 <10 <10 <0.02
10/6/2009 <5 <5 32 <20 <5 <5 <0.005 517 <5 20 <0.2 <5 <5 <5 <5 0.008
3/10/2010 <1 <1 25 10 <1 3 <0.001 516 <1 18 0.2 2 <1 4 <1 0.002
11/11/2010 <0.5 <5 27.7 <50 <0.080 <5 <0.005 417 <5 25.6 <0.2 <5 <10 <5 <0.1 <0.010
3/2/2011 <0.5 <5 35.4 B <50 <0.08 <5 <0.005 763 <5 33 <0.2 <5 <10 - <0.1 <0.010
10/4/2011 <0.5 <5 42.7 <50 <0.08 <5 <0.005 1,250 <5 42.5 <0.2 <5 <10 - <0.1 <0.010
3/6/2012 <0.5 <5 51.8 <50 <0.08 <5 <0.005 1,460 <5 44.3 <0.2 <5 <10 - <0.1 <0.010
6/5/2012 <0.5 <5 44.2 <50 <0.08 <5 <0.005 1,100 <5 52.3 <0.2 <5 <10 - <0.1 <0.010
10/2/2012 <0.5 <5 47.4 <50 <0.08 <5 <0.005 1,470 <5 49.1 <0.2 <5 <10 - <0.1 <0.010
3/12/2013 <1 <1 47 <50 <1 <5 <0.005 1,650 <1 46 <0.05 <5 <1 - <0.2 <0.005
6/12/2013 <1 <1 47 <50 <1 <5 <0.005 570 <1 16 <0.05 <5 <1 - <0.2 0.006
10/2/2013 <1 <1 53 <50 <1 <5 <0.005 1,720 <1 62 <0.05 <5 <1 - <0.2 <0.005
3/4/2014 <1 <1 61 <50 <1 <5 <0.005 2,020 <1 62 <0.05 <5 <1 - <0.2 0.005
6/2/2014 <1 <1 59 <50 <1 <5 <0.005 891 <1 29 <0.05 <5 <1 - <0.2 <0.005
10/1/2014 <1 <1 70 <50 <1 <5 <0.005 2840 <1 80 <0.05 <5 <1 - <0.2 <0.005
3/11/2015 <1 <1 80 <50 <1 <5 <0.005 2940 <1 81 <0.05 <5 <1 - <0.2 <0.005
6/1/2015 <1 <1 68 <50 <1 <5 <0.005 1280 <1 59 <0.05 <5 <1 - <0.2 <0.005
MW-5-C* 40-45
3/1/1990 - 1 - - - - - 630 - - - - <1 - - -
7/1/1990 - 1 - - - - - 430 - - - - <1 - - -
11/13/1990 - <1 - - - - - 110 - - - - <1 - - -
3/6/1991 - <1 - - - - - <50 - - - - <1 - - -
7/22/1991 - <1 - - - - - 90 - - - - <1 - - -
11/6/1991 - 1 - - - - - 120 - - - - <1 - - -
3/25/1992 - <1 - - - - - 50 - - - - <1 - - -
7/15/1992 - <1 - - - - - 110 - - - - <1 - - -
11/24/1992 - <1 - - - - - 50 - - - - <1 - - -
3/22/1993 - <1 - - - - - 70 - - - - <1 - - -
7/19/1993 - <1 - - - - - 110 - - - - <1 - - -
11/4/1993 - <1 - - - - - 90 - - - - <1 - - -
3/7/1994 - <1 - - - - - 70 - - - - <1 - - -
7/11/1994 - <1 - - - - - 60 - - - - <1 - - -
11/2/1994 - <1 - - - - - 90 - - - - <1 - - -
3/8/1995 - <1 - - - - - 1,200 - - - - <1 - - -
3/6/1996 - <1 - - - - - <100 - - - - <1 - - -
3/17/1997 - <1 - - - - - 350 - - - - <1 - - -
3/16/1998 - <5 - - - - - 11 - - - - <5 - - -
3/17/1999 - <5 - - - - - 159 - - - - <5 - - -
Table 7. Historical Groundwater Analytical Results – Metals (Continued)
4 of 16

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
3/6/2000 - <5 - - - - - 46 - - - - <5 - - -
3/16/2001 - <5 - - - - - 285 - - - - <5 - - -
3/6/2002 - <5 - - - - - 127 - - - - <5 - - -
3/18/2003 - <5 - - - - - 14 - - - - <5 - - -
3/9/2004 - <5 - - - - - 373 - - - - <5 - - -
3/7/2005 - <5 - - - - - 122 - - - - <5 - - -
3/2/2006 - <5 - - - - - 115 - - - - <5 - - -
3/6/2007 - <1 - - - - - 129 - - - - <5 - - -
3/11/2008 - <2 - - - - - 2,210 - - - - <5 - - -
3/10/2009 - <2 - - - - - <100 - - - - <20 - - -
3/10/2010 - <5 - - - - - 12 - - - - <10 - - -
3/2/2011 - <5 - - - - - 72 - - - - <10 - - -
3/7/2012 <0.5 <5 39.8 <50 <0.08 <5 <0.005 57 <5 336 <0.2 <5 <10 - <0.1 <0.010
6/6/2012 <0.5 <5 34.3 <50 <0.08 <5 <0.005 <50 <5 193 <0.2 <5 <10 - <0.1 <0.010
10/2/2012 <0.5 <5 42.1 <50 0.1 <5 <0.005 <50 <5 447 <0.2 <5 <10 - <0.1 <0.010
3/13/2013 <1 <1 28 <50 <1 <5 <0.005 26 <1 222 <0.05 <5 <1 - <0.2 <0.005
6/13/2013 <1 <1 32 <50 <1 <5 <0.005 28 <1 130 <0.05 <5 <1 - <0.2 <0.005
10/3/2013 <1 <1 33 <50 <1 <5 <0.005 26 <1 602 <0.05 <5 <1 - <0.2 <0.005
3/5/2014 <1 <1 17 <50 <1 <5 <0.005 21 <1 111 <0.05 <5 <1 - <0.2 0.01
6/3/2014 <1 <1 28 <50 <1 <5 <0.005 34 <1 441 <0.05 <5 <1 - <0.2 <0.005
10/2/2014 <1 <1 27 <50 <1 <5 <0.005 23 <1 554 <0.05 <5 <1 - <0.2 <0.005
3/10/2015 <1 <1 29 <50 <1 <5 <0.005 13 <1 535 <0.05 <5 <1 - <0.2 <0.005
6/1/2015 <1 <1 27 <50 <1 <5 <0.005 <10 <1 441 <0.05 <5 <1 - <0.2 <0.005
MW-6-C 40-45
3/1/1990 - <1 - - - - - 7,140 - - - - <1 - - -
7/1/1990 - <1 - - - - - 610 - - - - <1 - - -
11/13/1990 - <1 - - - - - 170 - - - - <1 - - -
3/6/1991 - <1 - - - - - 150 - - - - <1 - - -
7/22/1991 - <1 - - - - - 130 - - - - <1 - - -
11/6/1991 - <1 - - - - - 170 - - - - <1 - - -
3/25/1992 - <1 - - - - - 160 - - - - <1 - - -
7/15/1992 - <1 - - - - - 200 - - - - <1 - - -
11/24/1992 - <1 - - - - - 300 - - - - <1 - - -
3/22/1993 - <1 - - - - - 180 - - - - <1 - - -
7/19/1993 - <1 - - - - - 190 - - - - <1 - - -
11/4/1993 - 1 - - - - - 210 - - - - <1 - - -
3/7/1994 - <1 - - - - - 180 - - - - <1 - - -
7/11/1994 - <1 - - - - - 180 - - - - <1 - - -
Table 7. Historical Groundwater Analytical Results – Metals (Continued)
5 of 16

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
11/2/1994 - <1 - - - - - 230 - - - - <1 - - -
3/8/1995 - <1 - - - - - 1,500 - - - - <1 - - -
3/6/1996 - <1 - - - - - 2,500 - - - - <1 - - -
3/17/1997 - <1 - - - - - 1,200 - - - - <1 - - -
3/16/1998 - <5 - - - - - 102 - - - - <5 - - -
3/17/1999 - <5 - - - - - 193 - - - - 25 - - -
3/6/2000 - <5 - - - - - 106 - - - - <5 - - -
3/16/2001 - <5 - - - - - 150 - - - - <5 - - -
3/6/2002 - <5 - - - - - 120 - - - - <5 - - -
3/18/2003 - <5 - - - - - 489 - - - - <5 - - -
3/9/2004 - <5 - - - - - 1,340 - - - - <5 - - -
3/7/2005 - <5 - - - - - 284 - - - - <5 - - -
3/2/2006 - <5 - - - - - 195 - - - - <5 - - -
12/12/2006 3 0.22 45.5 739 0.46 0.18 2 157 0.54 930 <0.1 1.3 1.2 <0.017 0.1 0.0098
3/6/2007 <3 <1 37 770 <1 <5 <5 331 <3 711 <0.2 <5 <5 <5 <1 0.013
11/7/2007 <2.5 <1 41 1,140 <1 <5 <5 1,040 6 1,090 <0.2 <5 <5 <5 <1 0.044
3/11/2008 <2.5 <2 34 925 <1 7 <5 275 <5 889 <0.2 <5 <5 <5 <1 0.045
11/6/2008 <2 <2 35 940 <1 <5 <5 236 <5 644 <0.2 <5 <5 <5 <1 0.042
3/10/2009 <40 <2 <100 896 <10 <10 <10 138 <10 929 <0.2 <10 <20 <10 <10 0.026
10/6/2009 <5 <5 47 1,510 <5 <5 <5 153 <5 1,260 <0.2 <5 <5 <5 <5 0.014
3/10/2010 <1 <1 35 1,490 <1 3 2 424 <1 1,130 <0.2 3 5 <1 <1 0.014
11/11/2010 <0.5 <5 33.4 1,350 0.26 <5 <0.005 219 <5 1,060 <0.2 <5 <10 <5 <0.1 <0.01
3/2/2011 <0.5 <5 30 B 943 0.17 <5 <0.005 636 <5 301 <0.2 <5 <10 - <0.1 0.0154 B
10/4/2011 <0.5 <5 41.6 1,690 0.3 <5 <0.005 780 <5 1,180 <0.2 <5 <10 - <0.1 0.016
3/6/2012 <0.5 <5 42.4 1,680 0.23 <5 <0.005 407 <5 1,280 <0.2 <5 <10 - <0.1 0.0193
6/5/2012 <0.5 <5 41.1 1,320 0.2 <5 <0.005 591 <5 1,150 <0.2 <5 <10 - 0.1 0.0169
MW-7-C* 40-45
3/1/1990 - <1 - - - - - 3,400 - - - - <1 - - -
7/1/1990 - <1 - - - - - 1,600 - - - - <1 - - -
11/13/1990 - <1 - - - - - 250 - - - - <1 - - -
3/6/1991 - <1 - - - - - 160 - - - - 1 - - -
7/22/1991 - <1 - - - - - 120 - - - - <1 - - -
11/6/1991 - <1 - - - - - 90 - - - - 1 - - -
3/25/1992 - <1 - - - - - 60 - - - - <1 - - -
7/15/1992 - <1 - - - - - 110 - - - - <1 - - -
11/24/1992 - <1 - - - - - 110 - - - - <1 - - -
3/22/1993 - <1 - - - - - 120 - - - - <1 - - -
7/19/1993 - 1 - - - - - 170 - - - - <1 - - -
Table 7. Historical Groundwater Analytical Results – Metals (Continued)
6 of 16

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
11/4/1993 - <1 - - - - - 90 - - - - <1 - - -
3/7/1994 - <1 - - - - - <50 - - - - 2 - - -
7/11/1994 - <1 - - - - - 70 - - - - 1 - - -
11/2/1994 - <1 - - - - - 60 - - - - 1 - - -
3/8/1995 - 1.4 - - - - - 2,800 - - - - 2 - - -
3/6/1996 - 2.5 - - - - - 4,900 - - - - <1 - - -
3/17/1997 - 2 - - - - - 5,200 - - - - <1 - - -
3/16/1998 - <5 - - - - - 117 - - - - <5 - - -
3/17/1999 - <5 - - - - - 696 - - - - 27 - - -
3/6/2000 - <5 - - - - - 464 - - - - <5 - - -
3/16/2001 - <5 - - - - - 914 - - - - <5 - - -
3/6/2002 - <5 - - - - - 1,330 - - - - <5 - - -
3/18/2003 - <5 - - - - - 861 - - - - <5 - - -
3/9/2004 - <5 - - - - - 502 - - - - <5 - - -
3/7/2005 - <5 - - - - - 103 - - - - <5 - - -
3/2/2006 - <5 - - - - - <5 - - - - <5 - - -
3/6/2007 - <1 - - - - - 72 - - - - <5 - - -
3/11/2008 - <2 - - - - - 123 - - - - <5 - - -
3/10/2009 - <2 - - - - - <100 - - - - <20 - - -
3/10/2010 - <5 - - - - - 45 - - - - <10 - - -
3/2/2011 - <5 - - - - - 190 - - - - <10 - - -
3/6/2012 <0.5 <5 134 709 0.083 <5 <0.005 561 <5 320 <0.2 <5 <10 - <0.1 <0.010
6/5/2012 <0.5 <5 126 767 0.1 <5 <0.005 707 <5 458 <0.2 <5 <10 - <0.1 <0.010
10/2/2012 <0.5 <5 97.7 157 <0.08 <5 <0.005 273 <5 60 <0.2 <5 <10 - <0.1 <0.010
3/12/2013 <1 <1 68 164 <1 <5 <0.005 222 <1 108 <0.05 <5 <1 - <0.2 0.006
6/12/2013 <1 <1 67 185 3.34 <5 <0.005 282 <1 148 <0.05 <5 <1 - <0.2 <0.005
10/3/2013 <1 <1 103 312 <1 <5 <0.005 266 <1 101 <0.05 <5 <1 - <0.2 <0.005
3/4/2014 <1 <1 70 330 <1 <5 <0.005 128 <1 142 <0.05 <5 <1 - <0.2 0.008
6/2/2014 <1 <1 84 391 <1 <5 <0.005 316 <1 131 <0.05 <5 <1 - <0.2 0.006
10/2/2014 <1 <1 48 386 <1 <5 <0.005 381 <1 136 <0.05 <5 <1 - <0.2 <0.005
3/10/2015 <1 <1 58 490 <1 <5 <0.005 50 <1 202 <0.05 <5 <1 - <0.2 <0.005
6/2/2015 <1 <1 75 560 <1 <5 <0.005 166 <1 368 <0.05 <5 <1 - 0.405 <0.005
MW-8 40-50
3/1/1990 - <1 - - - - - 4,800 - - - - <1 - - -
7/1/1990 - <1 - - - - - 3,200 - - - - <1 - - -
11/13/1990 - <1 - - - - - 300 - - - - <1 - - -
3/6/1991 - <1 - - - - - 150 - - - - <1 - - -
7/22/1991 - <1 - - - - - 320 - - - - <1 - - -
Table 7. Historical Groundwater Analytical Results – Metals (Continued)
7 of 16

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
11/6/1991 - <1 - - - - - 180 - - - - <1 - - -
3/25/1992 - <1 - - - - - 80 - - - - <1 - - -
7/15/1992 - <1 - - - - - 380 - - - - <1 - - -
11/24/1992 - <1 - - - - - 50 - - - - <1 - - -
3/22/1993 - <1 - - - - - 620 - - - - <1 - - -
7/19/1993 - <1 - - - - - 500 - - - - <1 - - -
11/4/1993 - <1 - - - - - 360 - - - - <1 - - -
3/7/1994 - <1 - - - - - 280 - - - - <1 - - -
7/11/1994 - <1 - - - - - 100 - - - - <1 - - -
11/2/1994 - <1 - - - - - 510 - - - - <1 - - -
3/8/1995 - 2.4 - - - - - 13,000 - - - - <1 - - -
3/6/1996 - <1 - - - - - 250 - - - - <1 - - -
3/17/1997 - <1 - - - - - 190 - - - - <1 - - -
3/16/1998 - <5 - - - - - 60 - - - - <5 - - -
3/17/1999 - <5 - - - - - 175 - - - - 19 - - -
3/6/2000 - <5 - - - - - 147 - - - - <5 - - -
3/16/2001 - <5 - - - - - 298 - - - - <5 - - -
3/6/2002 - <5 - - - - - 81 - - - - <5 - - -
3/18/2003 - <5 - - - - - 64 - - - - <5 - - -
3/9/2004 - <5 - - - - - 671 - - - - <5 - - -
3/7/2005 - <5 - - - - - 450 - - - - <5 - - -
3/2/2006 - <5 - - - - - 97 - - - - <5 - - -
3/6/2007 - <1 - - - - - 103 - - - - <5 - - -
3/11/2008 - <2 - - - - - 64 - - - - <5 - - -
3/10/2009 - <2 - - - - - 196 - - - - <20 - - -
3/10/2010 - <5 - - - - - <10 - - - - <10 - - -
3/2/2011 - <5 - - - - - <50 - - - - <10 - - -
3/7/2012 <0.5 <5 60.4 <50 <0.08 <5 <0.005 64 <5 376 <0.2 <5 <10 - <0.1 <0.010
6/6/2012 <0.5 <5 68.1 <50 <0.08 <5 <0.005 <50 <5 344 <0.2 <5 <10 - <0.1 <0.010
3/5/2014 <1 <1 47 <50 <1 <5 <0.005 <10 <1 270 - <5 <1 - <0.2 0.006
MW-9 40-50
3/1/1990 - <1 - - - - - 360 - - - - <1 - - -
7/1/1990 - <1 - - - - - 320 - - - - <1 - - -
11/13/1990 - <1 - - - - - 220 - - - - <1 - - -
3/6/1991 - <1 - - - - - 90 - - - - <1 - - -
7/22/1991 - <1 - - - - - 150 - - - - <1 - - -
11/6/1991 - 1 - - - - - 100 - - - - <1 - - -
3/25/1992 - <1 - - - - - 60 - - - - <1 - - -
Table 7. Historical Groundwater Analytical Results – Metals (Continued)
8 of 16

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
7/15/1992 - <1 - - - - - 90 - - - - <1 - - -
11/24/1992 - <1 - - - - - 120 - - - - <1 - - -
3/22/1993 - <1 - - - - - 140 - - - - <1 - - -
7/19/1993 - <1 - - - - - 280 - - - - <1 - - -
11/4/1993 - <1 - - - - - 180 - - - - <1 - - -
3/7/1994 - <1 - - - - - 110 - - - - <1 - - -
7/11/1994 - <1 - - - - - 60 - - - - <1 - - -
11/2/1994 - <1 - - - - - 160 - - - - <1 - - -
3/8/1995 - <1 - - - - - 1,400 - - - - <1 - - -
3/6/1996 - 3 - - - - - 4,300 - - - - <1 - - -
3/17/1997 - <1 - - - - - 600 - - - - <1 - - -
3/16/1998 - <5 - - - - - 35 - - - - <5 - - -
3/17/1999 - <5 - - - - - 489 - - - - 10 - - -
3/6/2000 - <5 - - - - - 203 - - - - <5 - - -
3/16/2001 - <5 - - - - - 586 - - - - <5 - - -
3/6/2002 - <5 - - - - - 316 - - - - <5 - - -
3/18/2003 - <5 - - - - - 471 - - - - <5 - - -
3/9/2004 - <5 - - - - - 398 - - - - <5 - - -
3/7/2005 - <5 - - - - - 127 - - - - <5 - - -
3/2/2006 - <5 - - - - - 58 - - - - <5 - - -
3/6/2007 - <1 - - - - - 88 - - - - <5 - - -
3/11/2008 - <2 - - - - - 39 - - - - <5 - - -
3/10/2009 - <2 - - - - - 207 - - - - <20 - - -
3/10/2010 - <5 - - - - - 16 - - - - <10 - - -
3/2/2011 - <5 - - - - - 133 - - - - <10 - - -
3/7/2012 <0.5 <5 20.2 <50 <0.08 <5 <0.005 <50 <5 6.8 <0.2 <5 <10 - <0.1 <0.010
6/6/2012 <0.5 <5 21.2 <50 <0.08 <5 <0.005 <50 <5 6.6 <0.2 <5 <10 - <0.1 <0.010
MW-10 40-50
3/1/1990 - 2 - - - - - 3,800 - - - - <1 - - -
7/1/1990 - <1 - - - - - 770 - - - - <1 - - -
11/13/1990 - <1 - - - - - 210 - - - - <1 - - -
3/6/1991 - <1 - - - - - 80 - - - - <1 - - -
7/22/1991 - <1 - - - - - 120 - - - - <1 - - -
11/6/1991 - <1 - - - - - 80 - - - - <1 - - -
3/25/1992 - <1 - - - - - 90 - - - - <1 - - -
7/15/1992 - <1 - - - - - 80 - - - - <1 - - -
11/24/1992 - <1 - - - - - 120 - - - - <1 - - -
3/22/1993 - <1 - - - - - 150 - - - - <1 - - -
Table 7. Historical Groundwater Analytical Results – Metals (Continued)
9 of 16

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
7/19/1993 - <1 - - - - - 490 - - - - <1 - - -
11/4/1993 - <1 - - - - - 120 - - - - <1 - - -
3/7/1994 - <1 - - - - - 100 - - - - <1 - - -
7/11/1994 - <1 - - - - - 100 - - - - <1 - - -
11/2/1994 - <1 - - - - - 140 - - - - <1 - - -
3/8/1995 - <1 - - - - - 1,300 - - - - <1 - - -
3/6/1996 - <1 - - - - - 230 - - - - <1 - - -
3/17/1997 - <1 - - - - - 200 - - - - <1 - - -
3/16/1998 - <5 - - - - - 63 - - - - <5 - - -
3/17/1999 - <5 - - - - - 556 - - - - 11 - - -
3/6/2000 - <5 - - - - - 75 - - - - <5 - - -
3/16/2001 - <5 - - - - - 222 - - - - <5 - - -
3/6/2002 - <5 - - - - - 168 - - - - <5 - - -
3/18/2003 - <5 - - - - - 234 - - - - <5 - - -
3/9/2004 - <5 - - - - - 485 - - - - <5 - - -
3/7/2005 - <5 - - - - - 188 - - - - <5 - - -
3/2/2006 - <5 - - - - - 123 - - - - <5 - - -
3/6/2007 - 1 - - - - - 106 - - - - <5 - - -
3/11/2008 - 2 - - - - - 174 - - - - <5 - - -
3/10/2009 - <2 - - - - - <100 - - - - <20 - - -
3/10/2010 - <5 - - - - - 41 - - - - <10 - - -
3/2/2011 - <5 - - - - - <50 - - - - <10 - - -
3/7/2012 <0.5 <5 65.2 53.3 <0.08 <5 <0.005 105 <5 86.7 <0.2 <5 <10 - <0.1 <0.010
6/5/2012 <0.5 <5 53.5 73 <0.08 <5 <0.005 156 <5 84 <0.2 <5 <10 - <0.1 <0.010
MW-11* 40-50
3/1/1990 - <1 - - - - - 4,900 - - - - <1 - - -
7/1/1990 - <1 - - - - - 3,400 - - - - <1 - - -
11/13/1990 - <1 - - - - - 4,800 - - - - <1 - - -
3/6/1991 - <1 - - - - - 1,800 - - - - <1 - - -
7/22/1991 - <1 - - - - - 1,400 - - - - <1 - - -
11/6/1991 - <1 - - - - - 890 - - - - <1 - - -
3/25/1992 - <1 - - - - - 1,000 - - - - <1 - - -
7/15/1992 - <1 - - - - - 640 - - - - <1 - - -
11/24/1992 - <1 - - - - - 110 - - - - <1 - - -
3/22/1993 - <1 - - - - - 250 - - - - 1 - - -
7/19/1993 - <1 - - - - - 490 - - - - <1 - - -
11/4/1993 - <1 - - - - - 440 - - - - <1 - - -
3/7/1994 - <1 - - - - - 210 - - - - <1 - - -
Table 7. Historical Groundwater Analytical Results – Metals (Continued)
10 of 16

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
7/11/1994 - <1 - - - - - 230 - - - - <1 - - -
11/2/1994 - <1 - - - - - 230 - - - - <1 - - -
3/8/1995 - <1 - - - - - 150 - - - - <1 - - -
3/6/1996 - <1 - - - - - 250 - - - - <1 - - -
3/17/1997 - <1 - - - - - <100 - - - - <1 - - -
3/16/1998 - <5 - - - - - 17 - - - - <5 - - -
3/17/1999 - <5 - - - - - 379 - - - - 11 - - -
3/6/2000 - <5 - - - - - 138 - - - - <5 - - -
3/16/2001 - <5 - - - - - 106 - - - - <5 - - -
3/6/2002 - <5 - - - - - 107 - - - - <5 - - -
3/18/2003 - <5 - - - - - 1,010 - - - - <5 - - -
3/9/2004 - <5 - - - - - 138 - - - - <5 - - -
3/7/2005 - <5 - - - - - <5 - - - - <5 - - -
3/2/2006 - <5 - - - - - <5 - - - - <5 - - -
3/6/2007 - 1 - - - - - 50 - - - - <5 - - -
3/11/2008 - <2 - - - - - 330 - - - - <5 - - -
3/10/2009 - <2 - - - - - <100 - - - - <20 - - -
3/10/2010 - <5 - - - - - <10 - - - - <10 - - -
3/2/2011 - <5 - - - - - 420 - - - - <10 - - -
3/7/2012 <0.5 <5 79.6 <50 <0.08 <5 <0.005 174 <5 91.4 <0.2 <5 <10 - <0.1 <0.010
6/6/2012 <0.5 <5 78.8 <50 0.081 <5 <0.005 245 <5 88.3 <0.2 <5 <10 - <0.1 <0.010
10/2/2012 <0.5 <5 75.8 <50 0.11 <5 <0.005 181 <5 99.6 <0.2 <5 <10 - <0.1 <0.010
3/13/2013 <1 <1 85 <50 <1 <5 <0.005 142 <1 90 <0.05 <5 <1 - <0.2 <0.005
6/13/2013 <1 <1 83 <50 <1 <5 <0.005 219 <1 115 <0.05 <5 <1 - <0.2 <0.005
10/3/2013 <1 <1 96 <50 <1 <5 <0.005 130 <1 117 <0.05 <5 <1 - <0.2 <0.005
3/5/2014 <1 <1 82 <50 <1 <5 <0.005 295 <1 86 <0.05 <5 <1 - <0.2 <0.005
6/3/2014 <1 <1 93 <50 <1 <5 <0.005 140 <1 60 <0.05 <5 <1 - <0.2 <0.005
10/2/2014 <1 <1 87 <50 <1 <5 <0.005 124 <1 49 <0.05 <5 <1 - <0.2 <0.005
3/10/2015 <1 <1 85 <50 <1 <5 <0.005 119 <1 33 <0.05 <5 <1 - <0.2 <0.005
6/1/2015 <1 <1 82 <50 <1 <5 <0.005 48 <1 30 <0.05 <5 <1 - <0.2 <0.005
MW-12* 40-50
3/1/1990 - <1 - - - - - 8,000 - - - - <1 - - -
7/1/1990 - 4 - - - - - 4,000 - - - - <1 - - -
11/13/1990 - 1 - - - - - 1,400 - - - - 1 - - -
3/6/1991 - <1 - - - - - 370 - - - - 1 - - -
7/22/1991 - <1 - - - - - 440 - - - - <1 - - -
11/6/1991 - <1 - - - - - 290 - - - - 1 - - -
3/25/1992 - <1 - - - - - 240 - - - - 1 - - -
Table 7. Historical Groundwater Analytical Results – Metals (Continued)
11 of 16

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
7/15/1992 - <1 - - - - - 380 - - - - <1 - - -
11/24/1992 - <1 - - - - - 280 - - - - 1 - - -
3/22/1993 - <1 - - - - - 440 - - - - 1 - - -
7/19/1993 - <1 - - - - - 420 - - - - <1 - - -
11/4/1993 - <1 - - - - - 410 - - - - <1 - - -
3/7/1994 - <1 - - - - - 340 - - - - 1 - - -
7/11/1994 - 1 - - - - - 310 - - - - <1 - - -
11/2/1994 - <1 - - - - - 370 - - - - <1 - - -
3/8/1995 - <1 - - - - - 1,300 - - - - <1 - - -
3/6/1996 - 2.6 - - - - - 3,900 - - - - <1 - - -
3/17/1997 - <1 - - - - - 1,000 - - - - <1 - - -
3/16/1998 - <5 - - - - - 896 - - - - <5 - - -
3/17/1999 - <5 - - - - - 988 - - - - 34 - - -
3/6/2000 - <5 - - - - - 1,020 - - - - <5 - - -
3/16/2001 - <5 - - - - - 552 - - - - <5 - - -
3/6/2002 - <5 - - - - - 1,570 - - - - <5 - - -
3/18/2003 - <5 - - - - - 1,480 - - - - <5 - - -
3/9/2004 - <5 - - - - - 649 - - - - <5 - - -
3/7/2005 - <5 - - - - - 581 - - - - <5 - - -
3/2/2006 - <5 - - - - - 733 - - - - <5 - - -
3/6/2007 - 1 - - - - - 3,560 - - - - <5 - - -
3/11/2008 - <5 - - - - - 78 - - - - <5 - - -
3/10/2009 - <2 - - - - - 194 - - - - <20 - - -
3/10/2010 - <5 - - - - - 47 - - - - <10 - - -
3/2/2011 - <5 - - - - - 316 - - - - <10 - - -
3/7/2012 <0.5 <5 39.6 1,450 0.092 <5 <0.005 1,490 17.3 281 <0.2 <5 <10 - <0.1 <0.010
6/6/2012 <0.5 <5 53.1 1,260 <0.08 <5 <0.005 317 <5 221 <0.2 <5 <10 - <0.1 <0.010
10/2/2012 <0.5 <5 54.8 1,290 <0.08 <5 <0.005 753 5.3 204 <0.2 <5 <10 - <0.1 <0.010
3/13/2013 <1 <1 30 1,510 <1 <5 <0.005 255 3.17 280 <0.05 <5 <1 - <0.2 <0.005
6/13/2013 <1 <1 27 1,360 <1 <5 <0.005 411 4.82 211 <0.05 <5 <1 - <0.2 <0.005
10/3/2013 <1 <1 26 1,560 <1 <5 <0.005 110 1.32 236 <0.05 <5 <1 - <0.2 <0.005
3/5/2014 <1 <1 19 928 <1 <5 <0.005 97 <1 55 <0.05 <5 <1 - <0.2 <0.005
6/3/2014 <1 <1 21 1,050 <1 <5 <0.005 79 <1 142 <0.05 <5 <1 - <0.2 <0.005
10/2/2014 <1 <1 25 1,300 <1 <5 <0.005 93 <1 196 <0.05 <5 <1 - <0.2 <0.005
3/10/2015 <1 <1 36 1,500 <1 <5 <0.005 112 <1 316 <0.05 <5 <1 - <0.2 <0.005
6/2/2015 <1 <1 29 1,470 <1 <5 <0.005 5,690 <1 691 <0.05 <5 <1 - <0.2 <0.005
MW-17 45-50 3/2/2006 - 41 - - - - - 2,450 - - - - <5 - - -
Table 7. Historical Groundwater Analytical Results – Metals (Continued)
12 of 16

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
12/12/2006 0.33 18.8 162 2,180 0.046 0.19 0.0018 2,240 0.2 455 <0.1 3.7 0.68 <0.017 0.21 0.0133
3/6/2007 4 22 161 2,900 <1 6 0.009 2,840 <3 441 <0.2 <5 <5 <5 <1 0.022
11/7/2007 <2.5 25 143 2,720 <1 <5 <0.005 1,220 <5 353 <0.2 <5 <5 <5 <1 0.023
3/11/2008 <2.5 20 119 2,440 <1 <5 <0.005 886 <5 276 <0.2 <5 <5 <5 <1 0.02
11/6/2008 <2 29 87 3,060 <1 <5 <0.005 982 <5 162 <0.2 <5 <5 <5 <1 0.025
3/10/2009 <40 27 120 2,000 <10 <10 <0.01 1,110 <10 274 <0.2 <10 <20 <10 <10 0.03
10/6/2009 <5 34 140 2,110 <5 <5 <0.005 1,200 <5 259 0.2 <5 <5 <5 <5 0.019
3/10/2010 <1 29 112 2,140 <1 3 <0.001 1,560 <1 262 <0.2 4 4 <1 <1 0.009
11/11/2010 <0.5 35.2 102 2,140 <0.08 <5 <0.005 1,570 <5 284 <0.2 <5 <10 <5 <0.1 <0.010
3/2/2011 <0.5 7.1 126 2,220 <0.08 <5 <0.005 386 <5 386 <0.2 <5 <10 - 0.11 0.0102 B
10/4/2011 <0.5 7.1 135 2,090 <0.08 <5 <0.005 636 <5 305 <0.2 <5 <10 - 0.14 <0.01
3/6/2012 <0.5 17 153 2,230 <0.08 <5 <0.005 2,040 <5 401 <0.2 <5 <10 - <0.1 0.012
6/5/2012 <0.5 16.1 162 2,120 <0.08 <5 <0.005 1,890 <5 382 <0.2 <5 <10 - 0.38 0.012
MW-18 45-50
3/2/2006 - 39 - - - - - 2,940 - - - - <5 - - -
3/6/2007 - 113 - - - - - 2,000 - - - - <5 - - -
3/11/2008 - 67 - - - - - 4,140 - - - - <5 - - -
3/10/2009 - 110 - - - - - 6,160 - - - - <20 - - -
3/10/2010 - 80 - - - - - 6,910 - - - - 10 - - -
3/2/2011 - 26.9 - - - - - 420 - - - - <10 - - -
3/6/2012 <0.5 169 126 1,550 <0.08 <5 <0.005 6,510 <5 266 <0.2 <5 <10 - <0.1 <0.010
6/5/2012 <0.5 159 88.3 1,150 <0.08 <5 <0.005 4,920 <5 215 <0.2 <5 <10 - <0.1 <0.010
MW-19* 45-50
3/2/2006 - 10 - - - - - 150 - - - - <5 - - -
12/12/2006 0.49 0.63 101 850 0.19 0.2 0.0046 25 0.18 356 <0.1 3.6 1 <0.017 0.33 0.0541
3/6/2007 <3 1 87 1,180 <1 <5 0.006 84 <3 358 <0.2 <5 <5 <5 <1 0.031
11/7/2007 <2.5 <1 96 1,280 <1 <5 <0.005 74 <5 339 <0.2 <5 <5 <5 <1 0.022
3/11/2008 <2.5 <2 99 1,620 <1 <5 <0.005 121 <5 354 <0.2 <5 <5 <5 <1 0.025
11/6/2008 <2 <2 60 1,760 <1 <5 <0.005 142 <5 182 <0.2 <5 <5 <5 <1 0.036
3/10/2009 <40 2 <100 2,020 <10 <10 <0.01 200 <10 311 <0.2 <10 <20 <10 11 0.023
10/6/2009 <5 <5 87 1,960 <5 <5 <0.005 215 <5 337 <0.2 <5 <5 <5 <5 0.015
3/10/2010 <1 <1 61 1,920 <1 5 0.001 322 <1 267 <0.2 4 3 <1 <1 0.013
11/11/2010 <0.5 <5 61 1,830 <0.08 <5 <0.005 296 <5 249 <0.2 <5 <10 <5 0.31 <0.010
3/2/2011 <0.5 <5 71.6 B 1,960 <0.08 <5 <0.005 61 <5 347 <0.2 <5 <10 - 0.3 0.0159
10/4/2011 <0.5 <5 69.6 1,710 <0.08 <5 <0.005 113 <5 366 <0.2 <5 <10 - 0.28 0.0114
3/6/2012 <0.5 <5 64.6 1,920 <0.08 <5 <0.005 <50 <5 14.6 <0.2 <5 <10 - 0.23 <0.010
6/5/2012 <0.5 <5 77.1 1,940 <0.08 <5 <0.005 74 <5 436 <0.2 <5 <10 - 0.38 0.0111
10/3/2012 <0.5 <5 55.1 1,680 <0.08 <5 <0.005 <50 <5 14.3 <0.2 <5 <10 - <0.1 <0.010
3/12/2013 <1 <1 98 1,830 <1 <5 <0.005 117 <1 508 <0.05 <5 <1 - 0.62 0.022
6/12/2013 <1 <1 98 1,710 <1 <5 <0.005 504 <1 539 <0.05 <5 <1 - 0.311 0.013
Table 7. Historical Groundwater Analytical Results – Metals (Continued)
13 of 16

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
10/2/2013 <1 <1 103 1,990 <1 <5 <0.005 528 <1 531 <0.05 <5 <1 - 0.43 0.013
3/4/2014 <1 <1 94 2,020 <1 <5 <0.005 646 <1 475 <0.05 <5 <1 - 0.32 0.013
6/3/2014 <1 <1 94 2,110 <1 <5 <0.005 725 <1 497 <0.05 <5 <1 - 0.299 0.015
10/2/2014 <1 2.23 91 2,190 <1 <5 <0.005 1,080 <1 489 <0.05 <5 <1 - 0.464 0.014
3/11/2015 <1 2.22 85 2,270 <1 <5 <0.005 1,380 <1 444 <0.05 <5 <1 - 0.405 0.013
6/1/2015 <1 2.62 73 2,080 <1 <5 <0.005 914 <1 386 <0.05 <5 <1 - 0.458 0.009
MW-21-C* 40-45
10/3/2011 - 6.2 - 1,640 - - - 947 - 1,200 - - <10 - - -
1/18/2012 - <5 - 1,490 - - - 1,730 - 1,520 - - <10 - - -
10/3/2012 <0.5 5.8 53.2 1,720 <0.08 <5 <0.005 6,430 <5 1,460 <0.2 14.6 <10 - <0.1 <0.010
3/12/2013 <1 15 65 1,660 <1 <5 <0.005 7,680 <1 1,350 <0.05 20 <1 - <0.2 0.008
6/12/2013 <1 1.25 51 1,730 <1 <5 <0.005 727 <1 764 <0.05 16 <1 - <0.2 <0.005
10/2/2013 <1 22.8 67 1,510 <1 <5 <0.005 4,910 <1 874 <0.05 13 <1 - <0.2 <0.005
3/4/2014 <1 27.6 66 1,830 <1 <5 <0.005 6,600 <1 808 <0.05 13 <1 - <0.2 0.007
6/3/2014 <1 28.5 69 2,000 <1 <5 <0.005 5,310 <1 805 <0.05 18 <1 - <0.2 0.006
10/2/2014 <1 45 70 2,210 <1 <5 <0.005 6,160 <1 652 <0.05 15 <1 - <0.2 0.01
3/11/2015 <1 55.4 66 2,020 <1 <5 <0.005 5,550 <1 493 <0.05 9 <1 - <0.2 <0.005
6/1/2015 <1 53.8 66 2,120 <1 <5 <0.005 5,110 <1 430 <0.05 9 <1 - <0.2 <0.005
MW-22-B* 22-27
10/3/2011 - <5 - <50 - - - <50 - 88.7 - - <10 - - -
1/17/2012 - <5 - 175 - - - 460 - 85.5 - - <10 - - -
10/3/2012 <0.5 <5 44.1 180 <0.08 <5 <0.005 <50 <5 116 <0.2 <5 <10 - <0.1 <0.010
3/12/2013 <1 <1 36 106 <1 <5 <0.005 13 <1 29 <0.05 <5 <1 - <0.2 <0.005
6/12/2013 <1 <1 57 532 <1 <5 <0.005 <10 <1 48 <0.05 <5 <1 - <0.2 <0.005
10/2/2013 <1 <1 22 <50 <1 <5 <0.005 <10 <1 16 <0.05 <5 <1 - <0.2 0.01
3/4/2014 <1 <1 24 <50 <1 <5 <0.005 68 <1 16 <0.05 <5 <1 - <0.2 0.009
6/2/2014 <1 <1 17 <50 <1 <5 <0.005 <10 <1 <5 <0.05 <5 <1 - <0.2 <0.005
10/2/2014 <1 <1 13 <50 <1 <5 <0.005 17 <1 8 <0.05 <5 <1 - <0.2 0.005
3/11/2015 <1 <1 10 <50 <1 <5 <0.005 <10 <1 6 <0.05 <5 <1 - <0.2 <0.005
6/1/2015 <1 <1 9 <50 <1 <5 <0.005 <10 <1 <5 <0.05 <5 <1 - <0.2 <0.005
MW-22-C* 39.5-44.5
10/3/2011 - <5 - 1,680 - - - 171 - 737 - - <10 - - -
1/17/2012 - <5 - 1,650 - - - 256 - 814 - - <10 - - -
10/3/2012 <0.5 <5 86.2 2,100 <0.08 <5 <0.005 286 <5 780 <0.2 <5 <10 - 0.35 <0.010
3/12/2013 <1 <1 71 1,840 <1 <5 <0.005 431 <1 798 <0.05 <5 <1 - 0.296 <0.005
6/12/2013 <1 <1 102 2,250 <1 <5 <0.005 262 <1 828 <0.05 <5 <1 - 0.251 <0.005
10/2/2013 <1 <1 98 2,290 <1 <5 <0.005 230 <1 1,330 <0.05 <5 <1 - 0.25 0.017
3/4/2014 <1 <1 63 1,950 <1 <5 <0.005 <10 <1 18 <0.05 <5 <1 - <0.2 <0.005
6/2/2014 <1 <1 108 2,500 <1 <5 <0.005 628 <1 1,360 <0.05 <5 <1 - 0.226 0.007
10/2/2014 <1 <1 113 2,660 <1 <5 <0.005 608 <1 1,710 <0.05 <5 <1 - 0.422 0.006
3/11/2015 <1 <1 108 2,690 <1 <5 <0.005 499 <1 986 <0.05 <5 <1 - 0.506 <0.005
Table 7. Historical Groundwater Analytical Results – Metals (Continued)
14 of 16

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
6/1/2015 <1 <1 95 2,560 <1 <5 <0.005 141 <1 732 <0.05 <5 <1 - 0.398 <0.005
MW-23-B* 21.5-26.5
10/3/2011 - <5 - 394 - - - <50 - 277 - - <10 - - -
1/16/2012 - <5 - 468 - - - 168 - 349 - - <10 - - -
10/2/2012 <0.5 <5 35.2 1,330 <0.4 <5 <0.005 <50 <5 348 <0.2 <5 <10 - <0.1 <0.010
3/12/2013 <1 <1 35 1,100 <1 <5 <0.005 16 <1 157 <0.05 <5 2.36 - <0.2 <0.005
6/12/2013 <1 <1 49 1,830 <1 <5 <0.005 15 <1 133 <0.05 <5 1.9 - <0.2 <0.005
10/2/2013 <1 <1 36 1,140 <1 <5 <0.005 <10 <1 59 <0.05 <5 3.13 - <0.2 <0.005
3/4/2014 <1 <1 32 1,020 <1 <5 <0.005 133 <1 49 <0.05 <5 5.84 - <0.2 <0.005
6/2/2014 <1 <1 28 758 <1 <5 <0.005 13 <1 13 <0.05 <5 7.98 - <0.2 <0.005
10/1/2014 <1 <1 31 403 <1 <5 <0.005 80 <1 35 <0.05 <5 10.1 - <0.2 0.006
3/10/2015 <1 <1 39 245 <1 <5 <0.005 26 <1 11 <0.05 <5 7.43 - <0.2 <0.005
6/3/2015 <1 <1 39 137 <1 <1 <0.001 20 <1 9 <0.05 <1 4.88 - <0.2 <0.005
MW-23-C* 40-45
10/3/2011 - <5 - 1,640 - - - 311 - 970 - - <10 - - -
1/16/2012 - <5 - 1,780 - - - 53 - 1,190 - - <10 - - -
10/2/2012 <0.5 <5 45.1 2,580 <0.08 <5 <0.005 176 <5 1,050 <0.2 <5 <10 - <0.1 <0.010
3/12/2013 <1 <1 42 2,400 <1 <5 <0.005 187 <1 1,150 <0.05 <5 <1 - <0.2 <0.005
6/12/2013 <1 <1 49 2,710 <1 <5 <0.005 370 <1 1,300 <0.05 <5 <1 - <0.2 <0.005
10/2/2013 <1 <1 52 3,000 <1 <5 <0.005 395 <1 1,500 <0.05 <5 <1 - <0.2 <0.005
3/4/2014 <1 <1 53 3,000 <1 <5 0.01 364 <1 1,590 <0.05 <5 <1 - <0.2 0.008
6/2/2014 <1 <1 50 2,970 <1 <5 <0.005 340 <1 1,630 <0.05 <5 <1 - <0.2 <0.005
10/1/2014 <1 <1 54 3,600 <1 <5 <0.005 445 <1 1,520 <0.05 <5 <1 - 0.212 <0.005
3/10/2015 <1 <1 38 3,060 <1 <5 <0.005 147 <1 384 <0.05 <5 <1 - <0.2 <0.005
6/2/2015 <1 <1 36 2,050 <1 <5 <0.005 88 <1 309 <0.05 <5 <1 - 0.21 <0.005
MW-24-B* 22-27
10/4/2011 - <5 - 1,350 - - - <50 - 377 - - 43.3 - - -
1/17/2012 - <5 - 1,500 - - - <50 - 725 - - 21.6 - - -
10/3/2012 1.1 <5 43.4 1,420 <0.08 <5 <0.005 117 <5 805 <0.2 <5 <10 - 0.42 <0.010
3/13/2013 1.07 <1 54 1,270 <1 <5 <0.005 11 <1 396 <0.05 <5 <1 - 0.586 0.005
6/12/2013 <1 <1 42 1,190 <1 <5 <0.005 55 <1 388 <0.05 <5 <1 - 0.468 0.006
10/2/2013 <1 <1 40 1,130 <1 <5 <0.005 38 <1 464 <0.05 <5 <1 - 0.57 <0.005
3/5/2014 <1 <1 41 1,180 <1 <5 <0.005 11 <1 55 <0.05 <5 <1 - 0.23 <0.005
6/3/2014 <1 <1 41 1,140 <1 <5 <0.005 12 <1 19 <0.05 <5 <1 - <0.2 <0.005
10/1/2014 <1 <1 37 1,050 <1 <5 <0.005 23 <1 183 <0.05 <5 <1 - 0.445 0.011
3/10/2015 <1 <1 49 609 <1 <5 <0.005 16 <1 40 <0.05 <5 <1 - <0.2 <0.005
6/2/2015 <1 <1 47 409 <1 <5 <0.005 <10 <1 35 <0.05 <5 <1 - <0.2 <0.005
MW-24-C* 40-45
10/4/2011 - <5 - 1,240 - - - 583 - 852 - - <10 - - -
1/17/2012 - <5 - 1,240 - - - 515 - 891 - - <10 - - -
10/3/2012 <0.5 <5 50.2 1,160 0.083 <5 <0.005 2,860 <5 2,360 <0.2 <5 <10 - <0.1 0.0399
3/13/2013 <1 7.37 46 1,030 <1 <5 <0.005 6,230 <1 2,250 <0.05 6 <1 - <0.2 0.049
Table 7. Historical Groundwater Analytical Results – Metals (Continued)
15 of 16

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
6/12/2013 <1 3.33 47 999 <1 <5 <0.005 2,580 <1 2,280 <0.05 6 <1 - <0.2 0.046
10/2/2013 <1 2.81 46 988 <1 <5 <0.005 2,290 <1 2,150 <0.05 7 <1 - 0.23 0.058
3/5/2014 <1 5.81 47 1,030 <1 <5 <0.005 7,450 <1 2,060 <0.05 8 <1 - <0.2 0.075
6/3/2014 <1 3.02 42 1,090 <1 <5 <0.005 3,600 <1 1,110 <0.05 <5 <1 - <0.2 0.051
10/1/2014 <1 1.54 43 1,130 <1 <5 <0.005 1,990 <1 1,180 <0.05 7 <1 - <0.2 0.068
3/10/2015 <1 3.56 43 1,150 <1 <5 <0.005 5,600 <1 1,470 <0.05 6 <1 - <0.2 0.068
6/2/2015 <1 3.42 39 1,040 <1 <5 <0.005 4,180 <1 1,120 <0.05 5 <1 - <0.2 0.06
MW-27-B* 22-27
10/3/2011 - <5 - 404 - - - <50 - 391 - - 22.7 - - -
1/18/2012 - <5 - 412 - - - <50 - 406 - - 25.3 - - -
10/2/2012 <0.5 <5 49.3 466 0.16 <5 <0.005 <50 <5 229 <0.2 <5 27.3 - <0.1 0.0101
3/13/2013 <1 <1 52 395 <1 <5 <0.005 10 <1 219 <0.05 <5 37.1 - <0.2 0.011
6/13/2013 <1 <1 49 403 <1 <5 <0.005 38 <1 168 <0.05 <5 34.6 - <0.2 0.013
10/2/2013 <1 <1 53 401 <1 <5 <0.005 21 <1 261 <0.05 <5 48.2 - <0.2 0.037
3/5/2014 <1 <1 48 414 <1 <5 <0.005 14 <1 237 <0.05 <5 61.7 - <0.2 0.015
6/2/2014 <1 <1 47 403 <1 <5 <0.005 23 <1 153 <0.05 <5 56.7 - <0.2 0.01
10/1/2014 <1 <1 44 388 <1 <5 <0.005 <10 <1 150 <0.05 <5 59.9 - <0.2 0.009
3/10/2015 <1 <1 38 241 <1 <5 <0.005 <10 <1 78 <0.05 <5 36.2 - <0.2 <0.005
6/2/2015 <1 <1 42 195 <1 <1 <0.001 <10 <1 55 <0.05 <1 28.4 - <0.2 <0.005
MW-28-B* 25-30
10/3/2011 - <5 - <50 - - - <50 - 73.2 - - <10 - - -
1/17/2012 - <5 - <50 - - - <50 - 89.4 - - <10 - - -
10/3/2012 <0.5 <5 35.2 <50 <0.08 <5 <0.005 <50 <5 40.7 <0.2 <5 <10 - <0.1 <0.010
3/12/2013 <1 <1 41 <50 <1 <5 <0.005 <10 <1 18 <0.05 <5 <1 - <0.2 <0.005
6/12/2013 <1 <1 39 <50 <1 <5 <0.005 <10 <1 16 <0.05 <5 <1 - <0.2 0.01
10/2/2013 <1 <1 35 <50 <1 <5 <0.005 <10 <1 <5 <0.05 <5 <1 - <0.2 <0.005
3/4/2014 <1 <1 33 <50 <1 <5 <0.005 15 <1 14 <0.05 <5 <1 - <0.2 0.008
6/2/2014 <1 <1 32 <50 <1 <5 <0.005 <10 <1 <5 <0.05 <5 <1 - <0.2 <0.005
10/2/2014 <1 <1 30 <50 <1 <5 <0.005 17 <1 13 <0.05 <5 <1 - <0.2 0.005
3/11/2015 <1 <1 32 <50 <1 <5 <0.005 <10 <1 10 <0.05 <5 <1 - <0.2 <0.005
6/1/2015 <1 <1 28 <50 <1 <5 <0.005 10 <1 10 <0.05 <5 <1 - <0.2 <0.005
MW-28-C* 40-45
10/3/2011 - <5 - 94.9 - - - 59 - 58.1 - - <10 - - -
1/17/2012 - <5 - 193 - - - <50 - 59.9 - - <10 - - -
10/3/2012 <0.5 <5 75.1 652 <0.08 <5 <0.005 <50 <5 245 <0.2 <5 <10 - <0.1 0.082
3/12/2013 <1 <1 91 1,030 <1 <5 <0.005 20 <1 367 <0.05 <5 <1 - <0.2 <0.005
6/12/2013 <1 <1 102 1,260 <1 <5 <0.005 32 <1 409 <0.05 <5 <1 - <0.2 <0.005
10/2/2013 <1 <1 37 263 <1 <5 <0.005 11 <1 46 <0.05 <5 <1 - <0.2 <0.005
3/4/2014 <1 <1 70 711 <1 <5 <0.005 21 <1 166 <0.05 <5 1.51 - <0.2 0.007
6/2/2014 <1 <1 48 330 <1 <5 <0.005 26 <1 17 <0.05 <5 1.67 - <0.2 <0.005
10/2/2014 <1 <1 46 83 <1 <5 <0.005 12 <1 11 <0.05 <5 <1 - <0.2 0.006
Table 7. Historical Groundwater Analytical Results – Metals (Continued)
16 of 16

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Antimony Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Selenium Silver Thallium Zinc
µg/L µg/L µg/L µg/L µg/L µg/L mg/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/l
Groundwater Standards NC 10 700 700 2 10 1 300 15 50 1 100 20 20 NC 1
IMAC 1 NC NC NC NC NC NC NC NC NC NC NC NC NC 0.2 NC
3/11/2015 <1 <1 52 <50 <1 <5 <0.005 15 <1 14 <0.05 <5 <1 - <0.2 <0.005
6/1/2015 <1 <1 51 <50 <1 <5 <0.005 <10 <1 8 <0.05 <5 <1 - <0.2 <0.005
MW-31-C* 40-45
10/4/2011 - <5 - 1,020 - - - 1,220 - 1,470 - - <10 - - -
1/17/2012 - <5 - 1,130 - - - 2,330 - 2,000 - - <10 - - -
10/2/2012 <0.5 <5 48.6 1,120 <0.08 <5 <0.005 2,700 <5 1,790 <0.2 <5 <10 - <0.1 0.0411
3/13/2013 <1 1.55 45 1,030 <1 <5 <0.005 2,820 <1 1,800 <0.05 <5 <1 - <0.2 0.044
6/13/2013 <1 1.25 48 985 <1 <5 <0.005 2,760 <1 1,760 <0.05 <5 <1 - <0.2 0.052
10/3/2013 <1 <1 54 1,020 <1 <5 <0.005 2,550 <1 1,910 <0.05 <5 <1 - <0.2 0.046
3/5/2014 <1 <1 40 1,030 <1 <5 <0.005 232 <1 220 <0.05 <5 <1 - <0.2 0.016
6/3/2014 <1 <1 75 1,410 <1 <5 <0.005 3,420 <1 2,390 <0.05 <5 <1 - <0.2 0.053
10/2/2014 <1 <1 58 1,200 <1 <5 <0.005 2,850 <1 1,870 <0.05 <5 <1 - <0.2 0.049
3/10/2015 <1 <1 57 1,190 <1 <5 <0.005 3,440 <1 1,840 <0.05 <5 <1 - <0.2 0.049
6/2/2015 <1 <1 55 1,180 <1 <5 <0.005 2,850 <1 1,680 <0.05 <5 <1 - <0.2 0.05
MW-32-C 45-50
11/20/2013 <1 <1 41 381 <1 <5 <0.005 89 <1 28 <0.05 <5 <1 - <0.2 <0.005
3/4/2014 <1 <1 28 115 <1 <5 <0.005 47 <1 12 <0.05 <5 <1 - <0.2 0.008
6/3/2014 <1 1.36 38 248 <1 <5 <0.005 424 <1 24 <0.05 <5 <1 - <0.2 0.006
10/2/2014 <1 <1 25 <50 <1 <5 <0.005 132 <1 32 <0.05 <5 <1 - <0.2 <0.005
3/11/2015 <1 <1 30 120 <1 <5 <0.005 74 <1 22 <0.05 <5 <1 - <0.2 <0.005
6/1/2015 <1 <1 27 115 <1 <5 <0.005 30 <1 30 <0.05 <5 <1 - <0.2 0.011
MW-33-C 40-45
11/20/2013 <1 <1 32 60 <1 <5 <0.005 99 <1 29 <0.05 <5 <1 - <0.2 <0.005
3/4/2014 <1 <1 27 52 <1 <5 <0.005 35 <1 31 <0.05 <5 <1 - <0.2 0.007
6/3/2014 <1 <1 28 68 <1 <5 <0.005 109 <1 35 <0.05 <5 <1 - <0.2 <0.005
10/2/2014 <1 <1 36 106 <1 <5 <0.005 96 <1 18 <0.05 <5 <1 9.7 <0.2 <0.005
3/11/2015 <1 <1 24 <50 <1 <5 <0.005 25 <1 33 <0.05 <5 <1 11 <0.2 <0.005
6/1/2015 <1 <1 21 <50 <1 <5 <0.005 20 <1 30 <0.05 <5 <1 - <0.2 <0.005
Note(s):
[1] µg/L indicates micrograms per liter.
[2] IMAC indicates Interim Maximum Allowable Concentrations
[3] Groundwater Standards and IMAC values are from Classifications and Water Quality Standards Applicable to
the Groundwaters of North Carolina (NCDENR, Division of Water Quality, April 2013).
[4] NC indicates no criteria.
[5] Bold values indicate concentrations exceeding groundwater standards at or beyond compliance boundary.
[6] "<" indicates the sample was nondetect. The value right of the < symbol is the method detection limit (MDL).
[7] ft BGS indicates feet below ground surface.
[8] B indicates there was a detection in the field blank.
[9] NS indicates not sampled.
[10] Historical results are reported to the same significant figures reported in tables by previous consultants.
[11] * indicates monitoring well is part of the National Pollutant Discharge Elimination System sampling plan.
[12] - indicates analyte was not previously reported.
[13] Historical data received from Duke.

Table 8. Historical Groundwater Analytical Results – Non-Metals
Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
MW-2-C 40-45
3/1/1990 100 - - - 368 - 5.63 9.36 - - - - -
7/1/1990 78.6 - - - 336 - 4.96 9.91 - - - - -
11/13/1990 60 - - - 336 - 5.58 9.92 - - - - -
3/6/1991 37 - - - 88 - 6.30 10.40 - - - - -
7/22/1991 44.5 - - - 160 - 6.35 9.56 - - - - -
11/6/1991 56.1 - - - 296 - 5.90 9.69 - - - - -
3/25/1992 40.5 - - - 200 - 6.43 9.52 - - - - -
7/15/1992 42 - - - 184 - 6.24 10.81 - - - - -
11/24/1992 39.5 - - - 200 - 6.20 10.74 - - - - -
3/22/1993 52.6 - - - 384 - 6.12 11.63 - - - - -
7/19/1993 52.6 - - - 448 - 6.17 10.49 - - - - -
11/4/1993 44 - - - 184 - 6.27 10.74 - - - - -
3/7/1994 48.1 - - - 316 - 6.30 11.86 - - - - -
7/11/1994 53.1 - - - 440 - 6.29 10.23 - - - - -
11/2/1994 50 - - - 337 - 6.17 10.86 - - - - -
3/8/1995 47 - - - 340 - 6.47 14.00 - - - - -
3/6/1996 53 - - - 438 - 6.52 13.96 - - - - -
3/17/1997 51 - - - 412 - 6.40 12.75 - - - - -
3/16/1998 35.3 - - - 399 - 6.42 12.40 - - - - -
3/17/1999 38.5 - - - 355 - 6.91 13.93 - - - - -
3/6/2000 16.7 - - - 178 - 6.48 13.14 - - - - -
3/16/2001 37.2 - - - 392 - 6.71 14.80 - - - - -
3/6/2002 33.5 - - - 397 - 6.86 14.66 - - - - -
3/18/2003 51 - - - 427 - 6.47 14.42 - - - - -
3/9/2004 106 - - - 511 - 6.40 12.35 - - - - -
3/7/2005 55.6 - - - 443 - 6.39 14.45 - - - - -
3/2/2006 58.4 - - - 439 - 6.68 11.87 - - - - -
12/12/2006 23.1 0.05 0.05 146 320 2.99 6.75 12.18 19.80 481 - - -
3/6/2007 26.6 <0.02 <0.02 178 325 4.3 6.67 13.66 19.50 - - -
11/7/2007 31 <0.02 <0.02 184 328 2.7 6.41 15.34 567 - - -
3/11/2008 32 <0.04 <0.02 132 357 2.9 6.34 15.12 20.00 582 - - -
11/6/2008 29 <0.02 <0.02 141 359 3.4 6.79 15.25 20.30 603 - - -
3/10/2009 34 <0.02 <0.02 148 348 3 6.81 14.71 20.40 591 - - -
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
2 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
10/6/2009 36 <0.02 <0.02 140 359 2.9 6.75 13.44 20.30 592 - - -
3/10/2010 37 0.04 <0.02 162 413 3.2 6.84 13.21 19.30 618 - - -
11/11/2010 30.7 <0.1 <0.1 142 376 6.1 6.85 12.33 19.80 631 - - -
3/2/2011 31.1 B <0.1 - 148 390 B - 6.70 13.94 18.58 573 - - 9.90
10/4/2011 33.3 <0.2 - 144 352 - 6.44 13.69 21.06 607 - - 5.73
3/6/2012 36.3 <0.2 - 142 457 - 6.5 15.48 18.91 679 - - 7.89
6/5/2012 55.4 <0.02 - 143 526 - 6.6 15.09 20.54 855 - - 6.97
MW-4-B* 22-27
3/1/1990 4.91 - - - 140 - 7.00 7.03 - - - - -
7/1/1990 3.7 - - - 76 - 6.76 6.82 - - - - -
11/13/1990 3.8 - - - 128 - 6.77 6.37 - - - - -
3/6/1991 5 - - - 8 - 6.80 8.01 - - - - -
7/22/1991 3.6 - - - 82 - 5.97 6.26 - - - - -
11/6/1991 4.1 - - - 86 - 6.58 7.17 - - - - -
3/25/1992 3.9 - - - 172 - 7.10 6.01 - - - - -
7/15/1992 3.9 - - - 78 - 6.70 7.59 - - - - -
11/24/1992 3.7 - - - 68 - 6.74 7.62 - - - - -
3/22/1993 3.8 - - - 70 - 6.30 8.57 - - - - -
7/19/1993 3.8 - - - 80 - 6.62 6.69 - - - - -
11/4/1993 3.55 - - - 46 - 6.57 7.86 - - - - -
3/7/1994 3.75 - - - 80 - 6.66 9.18 - - - - -
7/11/1994 3.55 - - - 64 - 6.62 5.93 - - - - -
11/2/1994 3.3 - - - 65 - 6.33 8.00 - - - - -
3/8/1995 3.2 - - - 86 - 7.06 8.29 - - - - -
3/6/1996 4.5 - - - 115 - 7.42 9.76 - - - - -
3/17/1997 3.8 - - - 94 - 6.40 7.98 - - - - -
3/16/1998 4.42 - - - 70 - 6.79 6.93 - - - - -
3/17/1999 7.6 - - - 81.5 - 6.70 9.75 - - - - -
3/6/2000 6.75 - - - 78 - 6.55 8.77 - - - - -
3/16/2001 11.8 - - - 75 - 6.70 9.73 - - - - -
3/6/2002 6.65 - - - 67 - 7.22 10.78 - - - - -
3/18/2003 8.68 - - - 70 - 6.19 10.20 - - - - -
3/9/2004 4.8 - - - 77 - 6.80 8.15 - - - - -
3/7/2005 5.2 - - - 72 - 6.91 10.06 - - - - -
3/2/2006 5.7 - - - 74 - 6.08 8.00 - - - - -
12/12/2006 3.28 0.05 0.05 7.75 53 5 7.07 8.10 18.30 124 - - -
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
3 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
3/6/2007 5 <0.02 <0.02 8 80 2 6.68 8.59 18.90 - - - -
11/7/2007 7 <0.02 <0.02 12 62 <0.5 6.36 11.32 - 108 - - -
3/11/2008 7 <0.04 <0.02 7 93 <0.5 6.44 10.80 19.50 117 - - -
11/6/2008 5 <0.02 <0.02 <10.0 74 <0.5 6.74 10.16 19.60 115 - - -
3/10/2009 5 <0.02 <0.02 8 61 <0.5 6.70 10.35 19.20 120 - - -
10/6/2009 5 <0.02 <0.02 9 72 <0.5 6.63 9.05 19.70 122 - - -
3/10/2010 6 <0.02 <0.02 9 87 <0.5 6.79 8.54 19.50 131.7 - - -
11/11/2010 6.2 <0.1 <0.1 9.3 68 1.3 6.74 7.93 19.50 129.1 - - -
3/2/2011 29.6 B <0.1 - 7.9 B 116 B - 7.01 9.10 14.99 197 0.3 -67.7 1.64
10/4/2011 8.8 <0.2 - 7.1 105 - 6.94 10.81 19.00 224 0.51 -90.4 2.21
3/6/2012 12.7 <0.2 - 6.9 168 - 6.8 13.96 17.66 246 1.43 -113.1 0.55
6/5/2012 11.8 <0.02 - 8.9 153 - 6.8 12.33 18.80 274 1.16 -74.5 3.97
10/2/2012 10.8 <0.02 - 8.5 145 - 7.20 11.40 21.10 286 0.6 -105.1 0.94
3/12/2013 8.7 <0.023 - 8.1 140 - 7.00 10.74 17.90 235.6 0.36 -89.7 4.9
6/12/2013 9 <0.023 - 8.8 130 - 6.90 10.23 20.40 244.3 1 40.4 2.6
10/2/2013 11 <0.023 - 8.1 180 - 7.40 9.72 20.60 323.1 0.33 -147.6 1
3/4/2014 11 <0.023 - 8.8 180 - 7.10 10.42 15.10 250.9 0.39 26.3 1.2
6/2/2014 10 <0.023 - 8.6 170 - 7.30 9.62 22.00 309 - 12.1 6
10/1/2014 12 <0.023 - 9.4 210 - 6.80 8.21 23.10 375.2 0.42 -122.3 2.7
3/11/2015 12 <0.023 - 9.3 180 - 7.00 8.46 18.00 367.7 0.2 -85.9 5.3
6/1/2015 13 0.05 - 10 210 - 6.80 8.79 22.00 385 0.6 -43 9.98
MW-5-C* 40-45
3/1/1990 295 - - - 500 - 5.64 8.69 - - - - -
7/1/1990 270 - - - 464 - 5.44 9.29 - - - - -
11/13/1990 205 - - - 472 - 5.56 9.03 - - - - -
3/6/1991 190 - - - 336 - 5.7 9.23 - - - - -
7/22/1991 176.7 - - - 308 - 5.37 8.64 - - - - -
11/6/1991 184.2 - - - 340 - 5.44 8.53 - - - - -
3/25/1992 170.2 - - - 384 - 5.62 8.23 - - - - -
7/15/1992 175 - - - 332 - 5.3 9.53 - - - - -
11/24/1992 169.7 - - - 328 - 5.36 9.49 - - - - -
3/22/1993 141.7 - - - 252 - 5.42 10.35 - - - - -
7/19/1993 116.6 - - - 260 - 5.35 9.66 - - - - -
11/4/1993 114.1 - - - 120 - 5.51 9.77 - - - - -
3/7/1994 124.1 - - - 272 - 5.47 10.34 - - - - -
7/11/1994 120.6 - - - 284 - 5.5 9.26 - - - - -
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
4 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
11/2/1994 130 - - - 249 - 5.46 10.08 - - - - -
3/8/1995 140 - - - 297 - 5.65 4.36 - - - - -
3/6/1996 130 - - - 267 - 5.74 5.05 - - - - -
3/17/1997 93 - - - 162 - 5.82 4.10 - - - - -
3/16/1998 82 - - - 198 - 5.73 4.83 - - - - -
3/17/1999 81.7 - - - 224 - 5.75 4.60 - - - - -
3/6/2000 40.2 - - - 114 - 5.86 4.39 - - - - -
3/16/2001 47.3 - - - 111 - 5.9 5.43 - - - - -
3/6/2002 39.7 - - - 253 - 5.82 5.54 - - - - -
3/18/2003 34.9 - - - 81 - 5.83 4.96 - - - - -
3/9/2004 22.3 - - - 70 - 5.76 3.74 - - - - -
3/7/2005 16.2 - - - 52 - 5.65 4.25 - - - - -
3/2/2006 29.9 - - - 105 - 5.73 3.62 - - - - -
3/6/2007 32 - - - 88 - 5.57 3.94 - - - - -
3/11/2008 24 - - - 74 - 5.08 4.45 - - - - -
3/10/2009 21 - - - 78 - 5.44 4.24 - - - - -
3/10/2010 23 - - - 93 - 5.67 6.25 - - - - -
3/2/2011 23 B - - - 78 B - 5.13 3.99 17.75 88 1.28 189 1.47
3/7/2012 16.2 <0.2 - 7.8 59 - 5.4 4.19 19.00 156 0.96 -91.8 2.03
6/6/2012 14.2 0.1 B - 8.8 52 - 5.5 4.23 19.55 102 1.66 -71.9 1.13
10/2/2012 22.4 0.037 B - 11.9 59 - 5.7 4.43 22.4 158 0.63 169.3 0.77
3/13/2013 12 0.11 - 9.6 47 - 5.5 4.42 16.7 80.1 0.87 195 1.18
6/13/2013 74 0.02 - 74 56 - 4.9 4.16 21.9 85.3 0.74 252.6 0.8
10/3/2013 18 <0.023 - 13 72 - 5.7 3.91 22.5 127 0.31 251 0.72
3/5/2014 12 0.17 - 8.8 50 - 6 4.62 14.5 85.2 6.06 236 1.08
6/3/2014 16 0.05 - 11 65 - 5.8 4.4 21 114.7 - 211.2 3
10/2/2014 18 0.03 - 12 63 - 5.5 3.66 24 123.7 0.41 237.3 0.93
3/10/2015 18 0.03 - 12 57 - 5.6 3.69 18.1 130.5 0.31 212.2 1.07
6/1/2015 21 0.03 - 14 69 - 5.5 4 21 135 0.97 212 1.03
MW-6-C 40-45
3/1/1990 115 - - - 228 - 4.71 10.13 - - - - -
7/1/1990 103.6 - - - 228 - 4.71 10.09 - - - - -
11/13/1990 90 - - - 240 - 5.04 10.11 - - - - -
3/6/1991 77 - - - 116 - 5.64 10.65 - - - - -
7/22/1991 70.1 - - - 136 - 5.49 9.76 - - - - -
11/6/1991 65.1 - - - 140 - 4.82 10.42 - - - - -
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
5 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
3/25/1992 57.6 - - - 176 - 5.14 10.00 - - - - -
7/15/1992 68.6 - - - 156 - 4.76 9.83 - - - - -
11/24/1992 54.6 - - - 152 - 4.82 10.48 - - - - -
3/22/1993 69.6 - - - 212 - 4.72 11.98 - - - - -
7/19/1993 73.6 - - - 208 - 4.62 10.16 - - - - -
11/4/1993 91.6 - - - 132 - 4.69 10.60 - - - - -
3/7/1994 86.1 - - - 208 - 4.77 11.66 - - - - -
7/11/1994 86.1 - - - 260 - 4.71 10.08 - - - - -
11/2/1994 90 - - - 274 - 4.67 10.84 - - - - -
3/8/1995 79 - - - 202 - 4.79 5.72 - - - - -
3/6/1996 83 - - - 260 - 4.92 5.12 - - - - -
3/17/1997 47 - - - 311 - 5.53 3.72 - - - - -
3/16/1998 57.4 - - - 321 - 4.70 2.74 - - - - -
3/17/1999 43.2 - - - 270 - 4.61 4.66 - - - - -
3/6/2000 23 - - - 138 - 4.77 4.74 - - - - -
3/16/2001 31.6 - - - 150 - 4.73 5.74 - - - - -
3/6/2002 38.7 - - - 239 - 4.95 4.95 - - - - -
3/18/2003 74.7 - - - 323 - 4.81 4.84 - - - - -
3/9/2004 42.3 - - - 220 - 4.74 1.11 - - - - -
3/7/2005 64.6 - - - 332 - 4.64 5.17 - - - - -
3/2/2006 67.9 - - - 340 - 4.07 2.25 - - - - -
12/12/2006 83 0.05 0.05 142 311 5 7.12 2.51 19.5 534 - - -
3/6/2007 72.2 <0.02 <0.02 177 340 3.7 4.87 3.68 19.5 - - - -
11/7/2007 78 0.04 <0.02 190 330 0.6 4.62 6.28 - 591 - - -
3/11/2008 86 <0.04 <0.02 136 345 0.6 4.33 6.10 19.6 591 - - -
11/6/2008 95 <0.02 <0.02 142 381 0.6 4.65 5.62 20.2 651 - - -
3/10/2009 72 <0.02 <0.02 130 332 <0.5 4.57 5.13 19.4 561 - - -
10/6/2009 102 <0.02 <0.02 139 382 <0.5 4.67 3.39 20.3 659 - - -
3/10/2010 113 <0.02 <0.02 141 429 <0.5 4.65 3.48 18.9 682 - - -
11/11/2010 105 <0.1 <0.1 132 360 3.2 4.66 2.30 20.2 640 - - -
3/2/2011 6.5 B 0.24 - 103 304 B - 5.00 3.91 18.4 492 - - 4.76
10/4/2011 153 <0.2 - 130 456 - 4.57 3.91 22.16 798 - - 2.79
3/6/2012 163 <0.2 - 121 798 - 4.9 5.82 17.08 703 - - 2.05
6/5/2012 146 <0.02* - 135 437 - 4.6 5.49 21.17 799 - - 5.71
MW-7-C* 40-45 3/1/1990 210 - - - 468 - 5.02 8.49 - - - - -
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
6 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
7/1/1990 175 - - - 384 - 5.78 8.84 - - - - -
11/13/1990 150 - - - 380 - 5.37 8.68 - - - - -
3/6/1991 94 - - - 152 - 6.29 9.33 - - - - -
7/22/1991 98.6 - - - 236 - 5.78 8.24 - - - - -
11/6/1991 82.6 - - - 196 - 5.67 8.64 - - - - -
3/25/1992 91.1 - - - 272 - 5.73 8.45 - - - - -
7/15/1992 112 - - - 292 - 5.47 9.44 - - - - -
11/24/1992 110.5 - - - 268 - 4.59 8.10 - - - - -
3/22/1993 151.7 - - - 352 - 5.47 10.04 - - - - -
7/19/1993 105.1 - - - 328 - 5.51 8.35 - - - - -
11/4/1993 79.1 - - - 148 - 5.54 9.47 - - - - -
3/7/1994 46.6 - - - 144 - 5.74 10.32 - - - - -
7/11/1994 55.1 - - - 176 - 5.55 8.42 - - - - -
11/2/1994 65 - - - 212 - 5.54 9.63 - - - - -
3/8/1995 30 - - - 106 - 6.07 7.34 - - - - -
3/6/1996 85 - - - 299 - 5.51 8.19 - - - - -
3/17/1997 61 - - - 186 - 5.81 6.78 - - - - -
3/16/1998 75.1 - - - 265 - 5.97 6.21 - - - - -
3/17/1999 87.4 - - - 283 - 6.18 7.71 - - - - -
3/6/2000 39.5 - - - 136 - 5.27 7.12 - - - - -
3/16/2001 61.4 - - - 191 - 5.19 8.31 - - - - -
3/6/2002 48.2 - - - 527 - 5.54 8.44 - - - - -
3/18/2003 45.8 - - - 191 - 5.82 8.07 - - - - -
3/9/2004 20.4 - - - 104 - 5.15 6.54 - - - - -
3/7/2005 43.7 - - - 211 - 5.03 7.73 - - - - -
3/2/2006 10.9 - - - 64 - 4.96 6.40 - - - - -
3/6/2007 26.5 - - - 132 - 4.97 6.83 - - - - -
3/11/2008 16 - - - 112 - 4.86 7.95 - - - - -
3/10/2009 446 - - - 897 - 4.84 7.78 - - - - -
3/10/2010 163 - - - 421 - 5.06 6.58 - - - - -
3/2/2011 22.3 B - - - 118 B - 4.92 7.23 17.17 144 3.11 239.5 1.63
3/6/2012 49.2 0.28 - 92 228 - 5.1 10.56 19.01 391 0.75 -88 3.97
6/5/2012 78.6 0.15 B - 94.5 298 - 4.9 9.11 19.56 518 2.31 -51.3 8.06
10/2/2012 77.7 0.26 B - 85.8 225 - 4.9 9.69 22.27 457 1.53 194.9 6.81
3/12/2013 68 0.02 - 68 230 - 5 8.20 19 408.7 0.27 239 4.05
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
7 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
6/12/2013 14 0.06 - 9.1 230 - 5 7.72 22 422.1 0.58 244.4 4.33
10/3/2013 71 0.04 - 75 250 - 5.3 7.51 25.7 455 0.34 271.8 5.29
3/4/2014 83 0.18 - 73 250 - 5.6 8.24 17.1 387.4 0.29 147.7 1.68
6/2/2014 71 0.31 - 67 240 - 5.5 7.71 22 420 - 214 4.3
10/2/2014 27 1.4 - 48 130 - 5.2 6.46 23 193.2 3.44 231.5 3.79
3/10/2015 30 0.76 - 67 140 - 5.3 6.68 18.6 248 1.46 232.2 2.13
6/2/2015 38 0.457 - 83 200 0.748 5.0 7 21 299 1.23 256 1.86
MW-8 40-50
3/1/1990 260 - - - 444 - 6.09 8.06 - - - - -
7/1/1990 255 - - - 488 - 6.05 8.37 - - - - -
11/13/1990 225 - - - 476 - 5.53 7.98 - - - - -
3/6/1991 181 - - - 360 - 6.18 8.64 - - - - -
7/22/1991 164.7 - - - 304 - 5.40 7.32 - - - - -
11/6/1991 153.7 - - - 296 - 5.57 7.92 - - - - -
3/25/1992 120.1 - - - 236 - 5.87 7.50 - - - - -
7/15/1992 130 - - - 276 - 5.58 8.70 - - - - -
11/24/1992 117.6 - - - 260 - 5.57 9.51 - - - - -
3/22/1993 117.6 - - - 260 - 5.59 10.82 - - - - -
7/19/1993 119.1 - - - 312 - 5.71 9.41 - - - - -
11/4/1993 127.6 - - - 184 - 5.69 9.91 - - - - -
3/7/1994 127.6 - - - 296 - 5.64 10.93 - - - - -
7/11/1994 134.1 - - - 288 - 5.61 8.93 - - - - -
11/2/1994 130 - - - 290 - 5.69 10.21 - - - - -
3/8/1995 120 - - - 280 - 5.92 7.35 - - - - -
3/6/1996 130 - - - 324 - 5.80 8.45 - - - - -
3/17/1997 60 - - - 139 - 5.91 7.47 - - - - -
3/16/1998 102 - - - 275 - 5.45 5.97 - - - - -
3/17/1999 65.5 - - - 172 - 5.50 8.06 - - - - -
3/6/2000 39.2 - - - 63 - 5.85 7.36 - - - - -
3/16/2001 51.3 - - - 115 - 5.83 8.67 - - - - -
3/6/2002 35.9 - - - 79 - 5.85 9.22 - - - - -
3/18/2003 45.7 - - - 103 - 5.80 6.76 - - - - -
3/9/2004 24.7 - - - 85 - 5.63 6.42 - - - - -
3/7/2005 32.3 - - - 116 - 5.71 7.70 - - - - -
3/2/2006 24.2 - - - 99 - 5.45 6.37 - - - - -
3/6/2007 30.5 - - - 94 - 5.44 6.62 - - - - -
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
8 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
3/11/2008 39 - - - 127 - 5.41 8.19 - - - - -
3/10/2009 31 - - - 105 - 5.70 7.78 - - - - -
3/10/2010 20 - - - 108 - 5.66 6.25 - - - - -
3/2/2011 7.2 B - - - 62 B - 5.13 6.89 17.59 79 - - 0.38
3/7/2012 23.6 <0.2 - 19.2 102 - 5.7 7.72 18.80 299 - - 0.52
6/6/2012 28.3 <0.02 - 21.5 101 - 5.6 7.79 19.19 170 - - 0.65
3/5/2014 - - - - 52 - 5.5 7.93 15 82 0.9 272 0.9
MW-9 40-50
3/1/1990 11.5 - - - 20 - 5.52 6.91 - - - - -
7/1/1990 9 - - - 0 - 6.68 7.01 - - - - -
11/13/1990 10 - - - 46 - 5.49 6.15 - - - - -
3/6/1991 22 - - - 76 - 5.65 7.16 - - - - -
7/22/1991 22.5 - - - 32 - 5.26 5.93 - - - - -
11/6/1991 12.5 - - - 28 - 5.45 6.46 - - - - -
3/25/1992 5 - - - 60 - 5.78 6.06 - - - - -
7/15/1992 6.51 - - - 24 - 5.51 7.30 - - - - -
11/24/1992 6 - - - 30 - 5.33 8.29 - - - - -
3/22/1993 7.11 - - - 24 - 5.30 9.76 - - - - -
7/19/1993 11.6 - - - 50 - 5.29 8.01 - - - - -
11/4/1993 16.3 - - - 10 - 5.25 8.46 - - - - -
3/7/1994 26 - - - 88 - 5.17 10.28 - - - - -
7/11/1994 39.5 - - - 100 - 5.13 7.93 - - - - -
11/2/1994 29 - - - 68 - 5.23 9.67 - - - - -
3/8/1995 32 - - - 78 - 5.49 17.97 - - - - -
3/6/1996 28 - - - 185 - 5.57 19.44 - - - - -
3/17/1997 34 - - - 60 - 5.36 17.73 - - - - -
3/16/1998 30.3 - - - 77.5 - 5.05 15.54 - - - - -
3/17/1999 22.3 - - - 50 - 5.27 17.64 - - - - -
3/6/2000 10.5 - - - 25 - 5.18 16.96 - - - - -
3/16/2001 23.1 - - - 69 - 5.28 18.60 - - - - -
3/6/2002 8.99 - - - 35 - 5.83 19.35 - - - - -
3/18/2003 22.7 - - - 73 - 5.59 18.26 - - - - -
3/9/2004 5.7 - - - 35 - 5.10 15.64 - - - - -
3/7/2005 11.4 - - - 50 - 5.16 17.32 - - - - -
3/2/2006 5.9 - - - 30 - 4.85 15.58 - - - - -
3/6/2007 6.5 - - - 24 - 4.76 15.84 - - - - -
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
9 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
3/11/2008 9 - - - 41 - 4.66 17.80 - - - - -
3/10/2009 9 - - - 37 - 5.08 17.15 - - - - -
3/10/2010 5 - - - 55 - 4.95 15.28 - - - - -
3/2/2011 <5 - - - 50 B - 4.94 15.90 18.06 52 - - 1.30
3/7/2012 <5 <0.2 - 9.8 44 - 5.1 17.46 19.07 105 - - 0.34
6/6/2012 5.2 0.33 - 9.3 33 - 5.1 17.41 19.14 59 - - 0.61
MW-10 40-50
3/1/1990 8.51 - - - 156 - 6.24 8.65 - - - - -
7/1/1990 7.01 - - - 0 - 5.26 8.77 - - - - -
11/13/1990 6.5 - - - 62 - 5.28 8.75 - - - - -
3/6/1991 11 - - - 34 - 6.02 9.33 - - - - -
7/22/1991 11.5 - - - 26 - 5.10 8.63 - - - - -
11/6/1991 16.5 - - - 40 - 5.10 9.16 - - - - -
3/25/1992 17 - - - 36 - 5.31 7.83 - - - - -
7/15/1992 17.5 - - - 56 - 4.98 9.33 - - - - -
11/24/1992 15 - - - 32 - 5.01 9.76 - - - - -
3/22/1993 20 - - - 54 - 4.97 11.08 - - - - -
7/19/1993 47.6 - - - 124 - 4.75 9.70 - - - - -
11/4/1993 12.5 - - - 6 - 5.01 9.95 - - - - -
3/7/1994 7.01 - - - 72 - 5.09 11.18 - - - - -
7/11/1994 31.2 - - - 92 - 4.99 9.47 - - - - -
11/2/1994 6.6 - - - 25 - 5.08 10.54 - - - - -
3/8/1995 5.4 - - - 34 - 5.36 16.18 - - - - -
3/6/1996 42 - - - 117 - 5.13 8.45 - - - - -
3/17/1997 61 - - - 153 - 5.18 15.66 - - - - -
3/16/1998 51.1 - - - 140 - 4.98 14.62 - - - - -
3/17/1999 34.7 - - - 130 - 4.71 16.11 - - - - -
3/6/2000 25.7 - - - 17 - 4.86 15.53 - - - - -
3/16/2001 22.5 - - - 63 - 4.78 16.65 - - - - -
3/6/2002 18.2 - - - 73 - 5.04 17.09 - - - - -
3/18/2003 20.9 - - - 71 - 5.22 16.61 - - - - -
3/9/2004 13.3 - - - 68 - 4.80 14.16 - - - - -
3/7/2005 13.8 - - - 61 - 4.81 17.13 - - - - -
3/2/2006 11.9 - - - 57 - 5.86 15.96 - - - - -
3/6/2007 14 - - - 44 - 4.71 14.88 - - - - -
3/11/2008 9 - - - 33 - 4.54 17.53 - - - - -
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
10 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
3/10/2009 6 - - - 37 - 4.90 16.82 - - - - -
3/10/2010 11 - - - 52 - 4.77 15.58 - - - - -
3/2/2011 12 B - - - 64 B - 4.78 15.96 19.42 86 - - 0.35
3/7/2012 12.2 <0.2 - 16.2 72 - 5.0 16.80 19.80 177 - - 0.53
6/5/2012 11.6 0.083 B - 19.3 53 - 5.2 16.98 20.11 103 - - 1.19
MW-11* 40-50
3/1/1990 170 - - - 400 - 5.15 8.51 - - - - -
7/1/1990 150 - - - 408 - 5.15 8.33 - - - - -
11/13/1990 110 - - - 424 - 4.88 8.13 - - - - -
3/6/1991 99 - - - 344 - 5.00 9.02 - - - - -
7/22/1991 94.6 - - - 320 - 4.71 8.00 - - - - -
11/6/1991 85.1 - - - 300 - 4.77 9.26 - - - - -
3/25/1992 70.1 - - - 308 - 5.07 8.82 - - - - -
7/15/1992 45.6 - - - 220 - 4.68 8.13 - - - - -
11/24/1992 70.1 - - - 252 - 4.76 9.69 - - - - -
3/22/1993 74.1 - - - 272 - 4.68 10.95 - - - - -
7/19/1993 79.6 - - - 348 - 4.62 8.84 - - - - -
11/4/1993 79.6 - - - 168 - 4.63 9.09 - - - - -
3/7/1994 44.1 - - - 200 - 4.69 10.89 - - - - -
7/11/1994 50.6 - - - 228 - 4.62 8.87 - - - - -
11/2/1994 27 - - - 110 - 4.61 10.02 - - - - -
3/8/1995 32 - - - 142 - 4.78 15.15 - - - - -
3/6/1996 21 - - - 126 - 5.07 14.64 - - - - -
3/17/1997 12 - - - 57 - 5.02 12.92 - - - - -
3/16/1998 11.9 - - - 58 - 5.09 12.11 - - - - -
3/17/1999 11.4 - - - 51.5 - 4.94 14.02 - - - - -
3/6/2000 9 - - - 31 - 5.02 13.11 - - - - -
3/16/2001 14.7 - - - 4 - 5.03 14.81 - - - - -
3/6/2002 6.9 - - - 41 - 5.06 16.19 - - - - -
3/18/2003 13.3 - - - 33 - 5.00 15.41 - - - - -
3/9/2004 5.7 - - - 38 - 4.75 11.76 - - - - -
3/7/2005 9 - - - 30 - 4.75 15.10 - - - - -
3/2/2006 6.9 - - - 29 - 4.31 12.45 - - - - -
3/6/2007 8 - - - 14 - 4.49 12.95 - - - - -
3/11/2008 8 - - - 29 - 4.35 16.00 - - - - -
3/10/2009 5 - - - 31 - 4.57 14.82 - - - - -
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
11 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
3/10/2010 5 - - - 46 - 4.62 12.69 - - - - -
3/2/2011 <5 - - - <50 - 4.50 13.11 18.04 49 5.16 226 3.36
3/7/2012 7.3 0.49 - 8.8 48 - 5.0 15.41 17.58 126 2.87 -63.1 3.13
6/6/2012 7.1 0.5 - 10.6 39 - 4.6 15.46 19.09 65 2.27 -55.9 2.97
10/2/2012 8 0.47 - 10.7 <25 - 4.50 14.26 22.09 70 1.86 296.7 3.50
3/13/2013 9 0.42 - 13 37 - 4.60 14.69 17.4 70.7 1.38 322.7 2.33
6/13/2013 10 0.42 - 13 46 - 4.00 14.81 21.7 82.2 1.79 281.1 2.61
10/3/2013 11 0.39 - 14 58 - 4.50 13.04 22.3 85.6 1.5 371.9 2.15
3/5/2014 9.4 0.47 - 12 42 - 4.70 15.04 14.1 76.4 2.36 322.6 5.04
6/3/2014 6.8 0.52 - 10 41 - 4.70 14.19 23 63.1 - 334.8 2.00
10/2/2014 5.6 0.57 - 10 30 - 4.40 12.34 22 59.2 3.77 295.9 2.46
3/10/2015 3.9 0.52 - 13 <25 - 4.50 12.67 19.3 49.3 4.73 306.8 3.82
6/1/2015 4.0 0.51 - 12 <25 - 4.50 13.51 21.00 48 4.48 323 3.69
MW-12* 40-50
3/1/1990 185 - - - 428 - 5.84 9.76 - - - - -
7/1/1990 170 - - - 436 - 5.59 9.55 - - - - -
11/13/1990 160 - - - 524 - 5.06 9.55 - - - - -
3/6/1991 161 - - - 476 - 5.04 10.32 - - - - -
7/22/1991 164.2 - - - 448 - 4.99 9.11 - - - - -
11/6/1991 158.2 - - - 460 - 4.89 10.16 - - - - -
3/25/1992 134.7 - - - 464 - 5.33 9.84 - - - - -
7/15/1992 150 - - - 488 - 4.81 9.47 - - - - -
11/24/1992 120.1 - - - 468 - 4.83 10.22 - - - - -
3/22/1993 95.1 - - - 432 - 4.87 11.30 - - - - -
7/19/1993 83.1 - - - 448 - 4.87 9.37 - - - - -
11/4/1993 84.6 - - - 248 - 4.87 10.07 - - - - -
3/7/1994 90 - - - 408 - 4.86 11.85 - - - - -
7/11/1994 82.1 - - - 384 - 4.87 9.42 - - - - -
11/2/1994 88 - - - 361 - 4.86 10.61 - - - - -
3/8/1995 82 - - - 367 - 4.89 10.76 - - - - -
3/6/1996 82 - - - 369 - 5.04 10.50 - - - - -
3/17/1997 69 - - - 341 - 5.05 8.74 - - - - -
3/16/1998 56.2 - - - 366 - 5.12 7.36 - - - - -
3/17/1999 57.5 - - - 364 - 4.86 10.16 - - - - -
3/6/2000 48.2 - - - 326 - 5.01 8.64 - - - - -
3/16/2001 58.6 - - - 337 - 5.19 10.79 - - - - -
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
12 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
3/6/2002 46.5 - - - 313 - 5.07 11.56 - - - - -
3/18/2003 52.1 - - - 335 - 4.91 10.87 - - - - -
3/9/2004 14.7 - - - 177 - 5.14 7.88 - - - - -
3/7/2005 36.6 - - - 304 - 5.14 10.31 - - - - -
3/2/2006 46.6 - - - 315 - 4.72 7.19 - - - - -
3/6/2007 59.2 - - - 302 - 4.99 8.22 - - - - -
3/11/2008 82 - - - 330 - 4.65 11.04 - - - - -
3/10/2009 74 - - - 365 - 4.99 10.37 - - - - -
3/10/2010 47 - - - 327 - 5.39 8.09 - - - - -
3/2/2011 36.6 B - - - 286 B - 5.36 8.73 16.25 400 1.07 176.5 1.09
3/7/2012 26.9 <0.2 - 98 274 - 6.3 11.29 15.37 693 0.86 -73.7 8.96
6/6/2012 33.7 0.04 B - 130 312 - 6.6 11.10 19.23 306 4.07 -52.3 2.07
10/2/2012 26.2 0.18 B - 159 260 - 5.60 10.16 23.4 447 0.72 99.4 8.26
3/13/2013 24 0.05 - 130 260 - 5.60 10.47 17.5 414.7 0.39 220.9 2.79
6/13/2013 18 0.03 - 110 220 - 5.20 10.50 22.9 360 0.29 3.76
10/3/2013 24 0.07 - 110 270 - 5.90 8.79 20.6 428.3 0.42 213.8 1.35
3/5/2014 17 0.17 - 78 200 - 6.50 10.79 14.6 322.5 3.85 291.5 2.11
6/3/2014 16 0.13 - 64 170 - 6.10 10.08 24 276 - 181.5 1.40
10/2/2014 39 <0.023 - 110 230 - 5.70 7.73 21 287.3 0.27 272.9 0.48
3/10/2015 110 <0.023 - 160 430 - 6.70 8.06 19.8 341 0.44 265.2 2.26
6/2/2015 100 0.018 - 130 410 2.5 8.50 8.79 22 264 5.52 156 4.33
MW-17 45-50
3/2/2006 48 - - - 398 - 6.09 19.03 - - - - -
12/12/2006 37.4 0.05 0.05 195 377 2.24 6.38 20.08 19.7 570 - - -
3/6/2007 35.6 <0.02 <0.02 188 387 6.6 6.30 19.96 19.5 - - - -
11/7/2007 34 <0.02 <0.02 234 367 3 6.25 20.42 - 610 - - -
3/11/2008 37 <0.04 <0.02 172 396 3.1 6.23 20.44 20 622 - - -
11/6/2008 31 <0.02 <0.02 163 393 3.1 6.53 21.16 20.4 630 - - -
3/10/2009 38 <0.02 <0.02 152 373 3 6.52 20.31 20.3 614 - - -
10/6/2009 84 <0.02 <0.02 149 471 3.3 6.59 19.59 20.2 796 - - -
3/10/2010 44 <0.02 <0.02 155 412 3.1 6.59 19.50 19.5 645 - - -
11/11/2010 37.7 <0.1 <0.1 144 342 4.8 6.58 19.23 19.7 581 - - -
3/2/2011 77.3 <0.1 - 146 368 - 6.20 20.12 18.38 585 - - 2.18
10/4/2011 51.3 <0.2 - 134 360 - 6.32 20.01 22.49 594 - - 2.44
3/6/2012 101 <0.2 - 130 377 - 6.3 20.82 19.24 686 - - 1.74
6/5/2012 134 <0.02 - 148 574 - 6.3 20.53 19.50 983 - - 3.47
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
13 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
MW-18 45-50
3/2/2006 35.2 - - - 389 - 6.47 9.94 - - - - -
3/6/2007 53 - - - 398 - 6.53 10.58 - - - - -
3/11/2008 48 - - - 358 - 6.47 11.48 - - - - -
3/10/2009 73 - - - 447 - 6.62 11.23 - - - - -
3/10/2010 407 - - - 1040 - 6.69 10.08 - - - - -
3/2/2011 162 - - - 570 - 6.69 10.83 18.43 705 - - 1.06
3/6/2012 88.6 <0.2 - 81.6 505 - 6.7 11.89 17.88 753 - - 9.69
6/5/2012 77.3 <0.02 - 69.4 415 - 6.7 11.45 20.33 738 - - 8.73
MW-19* 45-50
3/2/2006 105 - - - 440 - 6.26 19.38 - - - - -
12/12/2006 71.6 0.05 0.05 126 334 2.08 6.34 20.43 20 685 - - -
3/6/2007 54.6 <0.02 <0.02 160 294 4.2 6.24 20.24 20.1 - - - -
11/7/2007 46 <0.02 <0.02 156 336 2.3 6.17 21.48 - 583 - - -
3/11/2008 36 <0.04 <0.02 141 360 2.6 6.25 21.37 20.9 566 - - -
11/6/2008 32 <0.02 <0.02 148 314 2.7 6.50 21.70 20.8 581 - - -
3/10/2009 35 <0.02 <0.02 161 354 2.2 6.43 21.14 20.8 585 - - -
10/6/2009 36 <0.02 <0.02 155 359 2.4 6.50 19.91 20.8 582 - - -
3/10/2010 33 <0.02 <0.02 142 361 2.4 6.56 19.88 20.2 542 - - -
11/11/2010 28.8 <0.1 <0.1 124 293 4.5 6.47 19.28 20.6 504 - - -
3/2/2011 39.2 B 0.14 - 126 334 B - 6.26 20.54 17.93 520 0.54 124.8 0.70
10/4/2011 28.3 <0.2 - 111 311 - 6.34 20.45 22.55 488 0.57 -18.4 0.60
3/6/2012 28.8 <0.2 - 109 329 - 6.7 22.07 18.87 454 1.1 -118 0.28
6/5/2012 52.2 <0.02 - 151 404 - 6.3 21.66 20.11 646 1.94 -43.9 1.34
10/3/2012 30.5 0.2 B - 148 304 - 6.70 21.61 21.9 540 3.81 132.2 1.06
3/12/2013 73 0.03 - 130 470 - 6.50 21.54 19.8 684 0.34 52.2 1.22
6/12/2013 69 <0.023 - 110 480 - 6.20 21.20 23 819 0.46 - 1.64
10/2/2013 51 <0.023 - 120 500 - 6.40 20.51 22.7 845 0.43 30.9 1.50
3/4/2014 53 <0.023 - 130 490 - 6.60 22.70 16.9 677 0.31 215.6 1.00
6/3/2014 43 <0.023 - 130 480 - 6.50 21.18 20 781 - 43.6 0.97
10/2/2014 44 <0.023 - 140 470 - 6.30 19.90 22 735 0.28 20.4 0.91
3/11/2015 28 <0.023 - 150 400 - 6.40 20.10 20.3 679 0.31 186.6 1.12
6/1/2015 28 0.02 - 140 380 - 6.40 20.50 22 630 0.39 42 5.44
MW-21-C* 40-45
10/3/2011 - - - 117 511 - 6.98 20.20 21.30 610 - -10.2 0.2
1/18/2012 - - - 138 404 - 6.70 21.63 17.99 452 0.2 -34.8 1.4
10/3/2012 76.2 0.027 B - 814 447 - 6.60 21.42 22.63 796 1.38 -59.3 9.38
3/12/2013 79 <0.023 - 120 500 - 6.50 21.18 19.90 803 0.43 -26.2 3.24
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
14 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
6/12/2013 67 0.48 - 140 450 - 6.40 20.96 21.40 746 1.57 - 7.29
10/2/2013 68 <0.023 - 96 500 - 6.50 20.35 23.90 873 0.46 -42 9.39
3/4/2014 63 <0.023 - 120 480 - 6.80 21.47 15.80 691 0.39 9.4 9.92
6/3/2014 60 <0.023 - 110 490 - 6.60 21.00 20.00 804 - -25.4 7.24
10/2/2014 53 <0.023 - 130 490 - 6.40 19.80 23.00 769 0.3 -52 7.14
3/11/2015 32 <0.023 - 130 420 - 6.60 19.99 21.20 728 0.27 -34.5 8.06
6/1/2015 34 0.08 - 140 420 - 6.50 20.35 21.00 697 0.2 -42 15.9
6/1/2015 34 0.08 - 140 420 - 6.50 20.35 21.00 697 0.2 -42 15.9
MW-22-B* 22-27
10/3/2011 - - - 13.6 54 - 7.26 8.52 22.04 113 - 98.8 0.42
1/17/2012 - - - 15 35 - 5.77 10.48 20.38 93 1.78 160.6 1.1
10/3/2012 5.5 0.55 - 12.6 40 - 6.20 9.93 24.37 82 2.57 115.8 1.88
3/12/2013 3.2 0.27 - 7.4 34 - 6.00 9.94 18.20 85.5 4.71 150.1 0.57
6/12/2013 8.4 0.35 - 32 110 - 6.00 9.71 22.30 188.1 0.78 91.7 0.52
10/2/2013 2.6 0.08 - 4.2 <25 - 5.10 8.74 24.60 39.3 3.24 251.8 0.31
3/4/2014 2.4 0.27 - 6.2 27 - 7.10 10.28 15.70 32 5.39 111.4 0.94
6/2/2014 1.8 0.11 - 4.5 <25 - 5.90 9.63 21.00 32 - 161.3 0.66
10/2/2014 3.8 0.12 - 3.3 <25 - 5.30 8.06 23.00 31.2 8.41 255 0.75
3/11/2015 2.2 0.38 - 4.4 <25 - 5.80 8.32 19.70 26.1 7.05 212.8 1.17
6/1/2015 2.7 0.2 - 4.8 <25 - 5.70 8.77 20.00 31 5.68 85 0.28
MW-22-C* 39.5-44.5
10/3/2011 - - - 122 400 - 6.90 8.58 23.88 641 6.3 -52.9 0.41
1/17/2012 - - - 125 341 - 6.77 10.56 20.26 516 11.83 37.9 1.4
10/3/2012 36 <0.02 - 172 380 - 6.30 10.02 23.61 652 0.78 13.9 1.2
3/12/2013 34 <0.023 - 160 390 - 6.40 9.99 18.50 602 0.43 66.1 1
6/12/2013 39 <0.023 - 160 480 - 6.20 9.81 23.30 763 0.3 86 1.86
10/2/2013 32 <0.023 - 150 460 - 6.30 8.82 24.50 764 0.42 95.8 2.16
3/4/2014 35 0.46 - 160 390 - 7.00 10.37 15.30 526.4 5.55 197.3 0.65
6/2/2014 37 0.05 - 160 490 - 6.50 9.73 22.00 755 - 45.1 4.1
10/2/2014 33 <0.023 - 160 470 - 6.20 8.12 23.00 710 0.37 163 2.23
3/11/2015 34 0.36 - 160 430 - 6.40 8.43 20.30 733 0.22 128.3 2.93
6/1/2015 41 0.13 - 160 440 - 6.40 8.87 22.00 684 0.4 23 0.51
MW-23-B* 21.5-26.5
10/3/2011 - - - 29.1 1,990 - 6.92 5.00 22.47 247 - 54.7 0.4
1/16/2012 - - - 34.8 148 - 6.92 7.37 17.48 216 5.86 23.5 1.6
10/2/2012 18.7 0.2 B - 74.9 186 - 6.20 6.44 23.45 339 0.59 39.6 2.07
3/12/2013 17 0.35 - 78 210 - 6.60 6.65 18.10 297.3 4.57 120.1 1.1
6/12/2013 28 0.22 - 160 330 - 6.20 6.50 22.80 497.5 0.69 81.4 0.63
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
15 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
10/2/2013 17 0.37 - 90 220 - 6.10 5.23 23.10 331.7 1.09 167.5 0.63
3/4/2014 18 0.43 - 69 170 - 6.90 7.10 14.80 231.5 4.73 186.1 5.69
6/2/2014 11 0.44 - 45 140 - 6.50 6.40 21.00 237 - 127 1.4
10/1/2014 4.3 0.46 - 24 83 - 6.00 4.46 23.00 146.1 2.23 214.6 3.62
3/10/2015 3 0.25 - 15 55 - 6.40 4.81 17.40 108.8 5.07 299.5 2.29
6/3/2015 2.3 0.123 - 9.8 55 1 6.30 4.71 19.00 90 2.21 34 0.88
MW-23-C* 40-45
10/3/2011 - - - 131 460 - 6.56 5.46 22.66 618 6.8 -50.3 1.41
1/16/2012 - - - 134 335 - 6.44 7.67 18.92 413 0.24 136.4 0.9
10/2/2012 71.1 0.024 B - 200 456 - 6.10 6.93 23.30 766 0.67 44 1.37
3/12/2013 76 <0.023 - 180 470 - 6.20 7.14 18.60 758 0.28 85.2 0.92
6/12/2013 90 0.03 - 200 530 - 6.00 7.00 23.10 842 0.31 65 1.58
10/2/2013 74 <0.023 - 210 540 - 6.10 5.72 24.70 878 0.41 94.4 1.66
3/4/2014 98 <0.023 - 190 540 - 6.60 7.58 14.90 677 0.51 206.2 3.46
6/2/2014 89 0.06 - 190 540 - 6.30 7.76 22.00 850 - 82.7 2.8
10/1/2014 76 <0.023 - 240 580 - 6.00 4.95 22.00 856 0.3 185.6 2.16
3/10/2015 32 0.04 - 120 380 - 6.40 5.30 18.30 636 0.16 301.4 4.59
6/2/2015 29 <0.01 - 69 280 2.7 6.60 5.94 22.00 454 0.33 16 1.27
MW-24-B* 22-27
10/4/2011 - - - 74.2 328 - 6.82 3.83 20.42 561 12.7 -10.4 0.2
1/17/2012 - - - 68.7 331 - 6.28 5.90 19.26 506 0.55 123.9 1.1
10/3/2012 73.6 0.021 B - 124 391 - 6.20 5.01 23.76 727 0.72 39.4 5.57
3/13/2013 62 0.02 - 99 360 - 6.50 5.49 16.90 610 3.67 100.7 0.59
6/12/2013 69 <0.023 - 100 380 - 6.30 5.41 22.20 638 0.31 96.9 2.58
10/2/2013 65 <0.023 - 100 380 - 6.30 3.93 22.20 668 0.28 126.2 1.43
3/5/2014 64 <0.023 - 100 370 - 6.80 5.94 13.90 680 4.02 166.9 1.01
6/3/2014 56 <0.023 - 94 350 - 6.60 5.30 22.00 604 - 150.1 0.92
10/1/2014 46 <0.023 - 86 320 - 6.10 3.25 23.00 542 0.35 233.9 1.44
3/10/2015 18 0.07 - 38 180 - 6.60 3.53 17.00 337 3.5 283.2 3.1
6/2/2015 11 0.015 - 28 140 1.2 6.60 4.40 19.00 265 0.97 26 0.67
MW-24-C* 40-45
10/4/2011 - - - 137 560 - 5.75 3.52 20.07 1003 - 77.6 3.84
1/17/2012 - - - 145 597 - 5.99 5.71 19.02 909 13.03 66 2.1
10/3/2012 164 <0.02 - 163 579 - 5.90 4.69 25.25 1027 0.87 31.8 4.62
3/13/2013 160 <0.023 - 150 530 - 5.80 5.15 17.30 919 0.29 67.1 3.11
6/12/2013 170 0.03 - 150 550 - 5.80 5.07 22.30 951 1.22 83.9 4.63
10/2/2013 170 <0.023 - 150 560 - 5.60 3.44 23.70 967 0.34 134.9 4.07
3/5/2014 190 <0.023 - 160 610 - 6.10 5.59 14.30 1070 0.56 196.2 5.83
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
16 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
6/3/2014 170 <0.023 - 150 550 - 5.80 4.97 26.00 943 - 138 8.1
10/1/2014 170 <0.023 - 160 560 - 5.00 2.87 23.00 904 0.39 238.8 4.94
3/10/2015 160 <0.023 - 160 500 - 5.40 3.16 17.60 899 0.27 293.8 5.32
6/2/2015 150 0.066 - 150 500 1.7 5.50 4.00 22.00 858 1.48 77 0.69
MW-27-B* 22-27
10/3/2011 - - - 83 309 - 6.52 4.30 19.95 579 - 95.2 0.8
1/18/2012 - - - 77.9 292 - 6.25 4.86 17.48 424 2.84 137.7 1.4
10/2/2012 58.7 1.6 - 92.7 240 - 5.60 4.60 22.33 459 1.07 112.4 2.32
3/13/2013 63 1.9 - 90 250 - 5.50 4.88 15.50 443.7 2.79 245.2 0.67
6/13/2013 56 2.1 - 91 250 - 5.00 4.45 21.90 432.4 0.5 184.5 2.74
10/2/2013 50 1.5 - 96 240 - 4.50 4.11 21.30 427.1 1.16 355.2 1.48
3/5/2014 50 1.5 - 97 260 - 5.20 4.95 13.10 455.4 1.97 227.6 1.17
6/2/2014 51 1.2 - 96 250 - 4.70 4.82 20.00 419 - 320 0.39
10/1/2014 42 1.3 - 95 230 - 4.30 3.88 22.00 381.7 1.97 230.7 0.81
3/10/2015 19 1.5 - 75 120 - 4.50 4.01 16.40 231.1 4.16 320.5 1.21
6/2/2015 14 1.3 - 62 110 0.45 4.70 4.39 21.00 196 4.81 151 2.67
MW-28-B* 25-30
10/3/2011 - - - 27.5 236 - 7.56 22.50 22.10 254 - 87.9 0.62
1/17/2012 - - - 16.5 112 - 7.21 24.03 19.53 175 2.95 104.2 1.3
10/3/2012 3.3 0.56 - 11.7 94 - 7.20 23.66 23.71 191 1.47 51.6 1.29
3/12/2013 2.8 0.39 - 13 88 - 7.20 23.21 19.40 142.3 5.02 83.1 0.57
6/12/2013 2.8 0.41 - 12 78 - 6.60 22.96 24.50 130.4 3.42 94.3 1.54
10/2/2013 2.2 0.26 - 11 67 - 6.80 22.42 23.70 113.3 3.36 140.9 0.47
3/4/2014 2.9 0.31 - 11 60 - 6.90 23.40 16.10 81.5 6.19 211.4 0.67
6/2/2014 2.9 0.27 - 11 63 - 6.90 22.91 22.00 90.2 - 135 1
10/2/2014 4 0.4 - 11 44 - 6.50 21.66 23.00 81.3 4.76 149.4 0.72
3/11/2015 4.3 0.28 - 11 46 - 6.50 21.89 20.00 70.1 6.2 238.1 1.46
6/1/2015 4.8 0.27 - 10 40 - 6.30 22.21 25.00 69 4.88 33 0.61
MW-28-C* 40-45
10/3/2011 - - - 17.6 1,240 - 6.34 21.69 22.28 121 11.1 -26.3 1.58
1/17/2012 - - - 18 69 - 5.97 23.22 19.45 106 2.43 160.1 1.9
10/3/2012 37.7 0.18 B - 47.2 177 - 6.20 22.84 22.85 370 0.93 96.1 2.1
3/12/2013 18 0.11 - 78 210 - 6.20 22.39 19.80 342 0.28 96.1 1.01
6/12/2013 30 0.07 - 100 250 - 6.00 22.23 22.60 430.8 0.34 55.9 1.29
10/2/2013 9.5 0.45 - 30 89 - 6.00 21.58 22.00 131.7 3.49 194.2 0.88
3/4/2014 17 0.16 - 57 150 - 6.20 22.58 16.00 210.9 0.33 202.5 0.75
6/2/2014 9.1 0.34 - 28 85 - 6.50 22.09 23.00 143 - 145.3 1.3
Table 8. Historical Groundwater Analytical Results – Non-Metals (Continued)
17 of 17

Sample ID
Screen
Interval
(ft BGS)
Sample Date
Concentration
Chloride Nitrate Nitrite Sulfate TDS TOC pH
Water
Level Temp. Cond. DO ORP Turbidity
mg/l mg/l mg/l mg/l mg/l mg/l SU feet ˚C µmhos/cm mg/l mV NTU
Groundwater Standards 250 10 1 250 500 NC 6.5-8.5 NC NC NC NC NC NC
IMAC NC NC NC NC NC NC NC NC NC NC NC NC NC
10/2/2014 4.1 0.71 - 11 34 - 5.70 20.87 22.00 61.7 5.62 208 0.88
3/11/2015 2.7 0.81 - 7.4 33 - 5.60 21.08 20.50 48.9 5.47 269.3 1.82
6/1/2015 2.6 0.6 - 10 26 - 5.60 21.42 22.00 55 5.26 77 1.09
MW-31-C* 40-45
10/4/2011 - - - 131 349 - 5.46 6.55 21.78 620 7.6 -3.7 0.72
1/17/2012 - - - 136 386 - 5.28 8.63 18.17 518 0.26 149.5 0.9
10/2/2012 114 0.14 B - 174 407 - 5.10 7.64 22.70 737 0.69 69.8 9.78
3/13/2013 110 <0.023 - 150 400 - 5.30 8.06 16.40 679 0.4 131.4 6.15
6/13/2013 110 <0.023 - 150 420 - 5.10 8.20 22.60 691 0.35 147.4 4.09
10/3/2013 140 <0.023 - 150 490 - 5.20 6.27 22.70 828 0.34 167.3 1.5
3/5/2014 150 0.11 - 150 490 - 5.80 8.42 14.50 690 2.56 312 3.23
6/3/2014 170 <0.023 - 150 570 - 5.20 7.68 24.00 941 - 141.5 2.8
10/2/2014 180 <0.023 - 150 550 - 5.00 5.46 23.00 905 0.3 260.2 1.39
3/10/2015 170 <0.023 - 160 510 - 5.20 5.70 18.00 907 0.26 250.3 1.57
6/5/2015 170 0.024 - 160 540 0.63 5.40 5.93 20.00 877 0.61 82 3.83
MW-32-C 45-50
11/20/2013 7.9 0.14 - 35 120 - 9.20 26.16 19.50 236 2.21 102.2 <10
3/4/2014 3.8 0.21 - 13 32 - 5.80 26.37 17.00 54 4.2 342 3.3
6/3/2014 5.8 0.18 - 24 57 - 5.50 25.65 22.00 128.1 - 244.4 9.2
10/2/2014 4.4 0.36 - 15 29 - 4.60 23.76 20.00 60.9 5.14 291.9 5.82
3/11/2015 4 0.39 - 18 26 - 4.80 24.18 21.00 65.1 3.98 311.2 6.69
6/1/2015 4.2 0.36 - 16 31 - 5.00 24.64 22.00 70 3.97 121 2.37
MW-33-C 40-45
11/20/2013 5.3 0.76 - 21 83 - 9.70 16.32 18.30 156 2.97 124.2 <10
3/4/2014 5.2 0.91 - 10 36 - 5.20 16.50 16.00 49 3.3 363 2.6
6/3/2014 6 0.72 - 13 42 - 5.20 15.75 21.00 64 - 194.3 9.2
10/2/2014 4.9 0.94 - 9.7 28 - 4.70 13.65 21.00 57.2 3.7 253.1 5.85
3/11/2015 4.3 0.92 - 11 <25 - 4.80 14.15 21.20 53.2 1.5 265.7 2.25
6/1/2015 4.5 0.66 - 12 30 - 4.60 14.61 23.00 55 1.06 134 0.96
Note(s):
[1] U indicates results below the method detection limit (MDL) and < indicates results below the practical
quantitation limit (PQL).
[2] µg/L indicates micrograms per liter.
[3] SPLP indicates synthetic precipitation leaching procedure.
[4] ft BGS indicates feet below ground surface.
[5] Sample IDs for these locations were a combination of location, depth, and sampling date, i.e. SS-F-DPT-1(3-
4)-20140630.
[6] * indicates sample was collected to verify that native soil had been reached.

1 of 1

Table 9. Groundwater and CCR Interstitial Water Field Parameters
Location Screen Interval
(ft BGS) Sample Date Drawdown pH Conductivity Temperature Turbidity ORP DO
(ft) (S.U.) (µS/cm) (˚C) (NTU) (mV) (mg/L)
MW-2B 22-27 5/23/2014 0.00 5.91 51.8 19.60 2.61 159 4.14
MW-2C 40-45 5/23/2014 0.02 6.66 807 22.08 28.7 4.0 0.50
MW-3B 22-27 5/27/2014 0.01 5.61 91 19.24 0.71 161 0.95
MW-5B 22-27 5/23/2014 0.01 3.94 32 20.42 7.51 163 4.40
MW-6B 22-27 5/21/2014 1.03 6.66 629 22.35 2.53 80.1 0.39
MW-6C 40-45 5/21/2014 0.05 4.82 577 21.93 4.92 100.3 0.60
MW-27C 40-45 5/22/2014 0.12 5.38 358 19.79 37.9 104 1.06
MW-31B 22-27 5/27/2014 0.05 5.65 109 21.17 9.95 74.3 0.44
MW-34B 22-27 5/27/2014 0.00 5.33 324.4 21.10 9.20 116 0.34
MW-34C 40-45 5/28/2014 0.03 5.91 465 22.07 7.85 75.4 0.15
MW-35B 22-27 5/28/2014 0.02 5.47 112 20.16 5.78 87.6 4.16
MW-35C 40-45 5/28/2014 0.09 6.91 620 23.40 81.3 66.2 0.54
MW-36B 22-27 5/21/2014 0.02 6.52 513 19.80 5.86 0.61 81.2
MW-36C 40-45 5/21/2014 NM 6.35 5.32 20.77 9.44 71.1 0.23
PZ-25 22-27 5/27/2014 0.03 4.58 22 19.33 6.44 131 8.60
PZ-INT 13-18 5/20/2014 0.59 7.43 997 19.84 >1,000 -267 0.07
Note(s):
[1] ft indicates feet.
[2] ft BGS indicates feet below ground surface.
[3] SU indicates standard units.
[4] µS/cm indicates microsiemens per centimeter.
[5] ˚C indicates degrees Celsius.
[6] NTU indicates Nephelometric turbidity units.
[7] ORP indicates oxidation reduction potential.
[8] mV indicates millivolts.
[9] DO indicates dissolved oxygen.
[10] mg/L indicates milligrams per liter.
[11] NM means not measured.
[12] Bold values mean an exceedance at or beyond the compliance boundary.

1 of 2

Table 10. Groundwater and CCR Interstitial Water Analytical Data
Location
Screen
Interval
(ft
BGS)
Sample
Date
Concentration (µg/L)
Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Total Chromium Copper Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Potassium
Groundwater Standards NC 10 700 NC 700 2 NC 10 1,000 300 15 NC 50 1 NC 100 NC
IMAC 1 NC NC 4 NC NC NC NC NC NC NC NC NC NC NC NC NC
MW-2B 22-27 5/23/2014 5.3 U 6.8 U < 10 0.67 U < 100 0.76 U 2,870 1.6 U 2.7 U < 400 4.7 U 574 < 10 0.06 U < 20 1.5 U <1,000
MW-2C 40-45 5/23/2014 5.3 U 278 80.6 0.67 U 3,020 0.76 U 109,000 1.6 U 2.7 U 9,510 4.7 U 28,500 375 0.06 U 294 1.5 U 19,500
MW-3B 22-27 5/27/2014 5.3 U 6.8 U < 10 0.67 U 446 0.76 U 12,000 1.6 U 2.7 U 43 U 4.7 U 2,270 18.5 0.06 U 329 1.5 U 3,580
MW-5B 22-27 5/23/2014 5.3 U 6.8 U 44.5 0.67 U < 100 0.76 U 948 1.6 U 2.7 U 700 4.7 U 444 32 0.06 U 1.7 U 1.5 U 1,020
MW-6B 22-27 5/21/2014 5.3 U 6.8 U 34.9 0.67 U 1,130 0.76 U 53,900 1.6 U 2.7 U < 400 < 30 13,400 68.2 0.06 U 256 1.5 U 11,700
MW-6C 40-45 5/21/2014 5.3 U 6.8 U 28.2 0.67 U 1,270 0.76 U 30,100 1.6 U 2.7 U 514 4.7 U 8,920 857 0.06 U 1.7 U 1.5 U 6,160
MW-27C 40-45 5/22/2014 5.3 U 6.8 U 45.6 0.67 U 517 0.76 U 25,200 < 30 2.7 U 1,090 4.7 U 5,050 342 0.06 U 1.7 U < 20 8,440
MW-31B 22-27 5/27/2014 5.3 U 6.8 U 33.6 0.67 U 268 0.76 U 11,800 1.6 U 2.7 U 1,390 4.7 U 2,350 46.1 0.06 U < 20 1.5 U 2,500
MW-34B 22-27 5/27/2014 5.3 U 6.8 U 17.3 0.67 U 223 0.76 U 25,900 1.6 U 2.7 U < 400 4.7 U 2,940 < 10 0.06 U 37.6 1.5 U 5,250
MW-34C 40-45 5/28/2014 5.3 U 6.8 U 47.1 0.67 U 491 0.76 U 29,400 1.6 U 2.7 U 613 4.7 U 5,340 303 0.06 U < 20 < 20 8,160
MW-35B 22-27 5/28/2014 5.3 U 6.8 U 42 0.67 U < 100 0.76 U 4,110 1.6 U 2.7 U < 400 4.7 U 450 24.7 0.06 U 1.7 U 1.5 U 1,030
MW-35C 40-45 5/28/2014 5.3 U 6.8 U 31.7 0.67 U 412 0.76 U 35,900 < 30 < 20 2,810 4.7 U 4,500 345 0.06 U < 20 < 20 4,530
MW-36B 22-27 5/21/2014 5.3 U 6.8 U 153 0.67 U 528 0.76 U 44,100 1.6 U 2.7 U < 400 4.7 U 6,830 < 10 0.06 U 132 1.5 U 10,900
MW-36C 40-45 5/21/2014 5.3 U 6.8 U 33.7 0.67 U 522 0.76 U 32,100 < 30 2.7 U 877 4.7 U 5,820 558 0.06 U < 20 1.5 U 10,800
PZ-25 22-27 5/27/2014 5.3 U 6.8 U 11.5 0.67 U < 100 0.76 U 1,180 1.6 U 2.7 U < 400 4.7 U 324 11.2 0.06 U 1.7 U 1.5 U <1,000
PZ-INT 13-18 5/20/2014 5.3 U 275 925 < 10 4,260 < 10 122,000 < 30 91.3 9,570 < 30 38,600 184 0.06 U 70.3 63.7 18,600
Note(s):
[1] U indicates results below the method detection limit (MDL) and < indicates results below the practical quantitation limit (PQL).
[2] µg/L indicates micrograms per liter.
[3] IMAC indicates Interim Maximum Allowable Concentrations
[4] Groundwater Standards and IMAC values are from Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina (NCDENR, Division of Water Quality, April 2013).
[5] NC indicates no criteria.
[6] Bold values indicate concentrations exceeding groundwater standards at or beyond compliance boundary.
[7] TDS indicates total dissolved solids.
[8] ft BGS indicates feet below ground surface.
[9] Sample IDs for these locations were a combination of location and sampling date, i.e. GW-MW-2B-20140523

2 of 2

Table 10. Groundwater and CCR Interstitial Water Analytical Data (Continued)
Location
Screen
Interval (ft
BGS)
Sample Date Concentration (µg/L)
Selenium Silver Sodium Strontium Thallium Vanadium Zinc Bromide Chloride Nitrate (as N) Nitrite (as N) Sulfate Alkalinity as CaCO3 TDS
Groundwater Standards 20 20 NC NC NC NC 1,000 NC 250,000 10,000 1,000 250,000 NC 500,000
IMAC NC NC NC NC 0.2 0.3 NC NC NC NC NC NC NC NC
MW-2B 22-27 5/23/2014 8.4 U 2.1 U 2,580 52.6 5.4 U 2 U < 40 2,000 U 4,200 < 500 400 U <5,000 5,300 <30,000
MW-2C 40-45 5/23/2014 8.4 U 2.1 U 36,600 3,100 5.4 U 2 U < 40 2,000 U 42,100 250 U 400 U 130,000 269,000 542,000
MW-3B 22-27 5/27/2014 8.4 U 2.1 U 3,060 346 5.4 U 2 U 2 U 2,000 U 3,900 770 400 U 16,000 27,300 61,000
MW-5B 22-27 5/23/2014 8.4 U 2.1 U 2,020 < 10 5.4 U 2 U < 40 2,000 U 3,700 250 U 400 U 5,400 700 U <30,000
MW-6B 22-27 5/21/2014 8.4 U 2.1 U 52,300 1,930 5.4 U 2 U < 40 2,000 U 71,500 250 U 400 U 91,800 105,000 374,000
MW-6C 40-45 5/21/2014 8.4 U 2.1 U 67,200 431 5.4 U 2 U < 40 2,000 U 85,100 250 U 400 U 112,000 2,800 338,000
MW-27C 40-45 5/22/2014 55 2.1 U 50,200 294 5.4 U < 10 < 40 2,000 U 52,300 740 400 U 96,900 8,100 258,000
MW-31B 22-27 5/27/2014 8.4 U 2.1 U 8,840 243 5.4 U 2 U < 40 2,000 U 15,600 250 U 400 U 19,500 15,900 81,500
MW-34B 22-27 5/27/2014 < 40 2.1 U 28,100 230 5.4 U 2 U < 40 2,000 U 34,700 1,100 400 U 62,300 24,300 164,000
MW-34C 40-45 5/28/2014 < 40 2.1 U 72,200 311 5.4 U 2 U < 40 2,000 U 61,300 250 U 400 U 122,000 28,800 339,000
MW-35B 22-27 5/28/2014 8.4 U 2.1 U 17,500 15.2 5.4 U 2 U < 40 2,000 U 6,400 250 U 400 U 31,800 5,700 88,500
MW-35C 40-45 5/28/2014 55 2.1 U 89,400 299 5.4 U < 10 < 40 2,000 U 58,400 < 500 400 U 131,000 57,300 419,000
MW-36B 22-27 5/21/2014 < 40 2.1 U 46,300 546 5.4 U < 10 < 40 2,000 U 51,900 630 400 U 90,400 72,400 316,000
MW-36C 40-45 5/21/2014 < 40 2.1 U 61,600 324 5.4 U < 10 < 40 2,000 U 54,800 < 500 400 U 117,000 41,000 327,000
PZ-25 22-27 5/27/2014 8.4 U 2.1 U < 2,000 < 10 5.4 U 2 U < 40 2,000 U 3,200 250 U 400 U 5,900 700 U <30,000
PZ-INT 13-18 5/20/2014 < 40 2.1 U 41,100 7,240 5.4 U 129 72.3 2,000 U 83,400 250 U 400 U 73,200 335,000 631,000
Note(s):
[1] U indicates results below the method detection limit (MDL) and < indicates results below the practical quantitation limit (PQL).
[2] µg/L indicates micrograms per liter.
[3] IMAC indicates Interim Maximum Allowable Concentrations
[4] Groundwater Standards and IMAC values are from Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina (NCDENR, Division of Water Quality, April 2013).
[5] NC indicates no criteria.
[6] Bold values indicate concentrations exceeding groundwater standards at or beyond compliance boundary.
[7] TDS indicates total dissolved solids.
[8] ft BGS indicates feet below ground surface.
[9] Sample IDs for these locations were a combination of location and sampling date, i.e. GW-MW-2B-20140523

1 of 1

Table 11. LOLA Investigation – Groundwater Field Parameters
Location Screen Interval
(ft BGS) Sample Date Drawdown pH Conductivity Temperature Turbidity ORP DO
(ft) (S.U.) (µS/cm) (˚C) (NTU) (mV) (mg/L)
MW-13 8-18 7/2/2014 0.02 6.85 510.5 21.3 9.95 -75.4 0.69
MW-13D 33.5-38.5 7/2/2014 0.20 7.04 773 21.9 6.98 #### 1.51
MW-14 1-11 6/30/2014 0.05 6.50 151.4 26.8 16.1 4.4 1.85
MW-15 1-11 7/2/2014 0.01 6.73 583 21.5 2.38 -83.8 1.35
MW-15D 40-45 7/2/2014 0.10 6.43 626 23.0 8.18 52.8 1.26
MW-16 2-12 7/1/2014 0.01 6.30 193 23.3 28.4 -18.9 1.67
MW-16D 42-47 7/1/2014 0.15 4.82 539 22.3 7.30 95.4 1.04
MW-20 4-14 7/1/2014 -0.02 6.32 471.2 21.7 1.54 -60.5 2.38
MW-20D 43-48 7/1/2014 0.32 7.08 544 22.0 12.5 -48.5 0.84
Note(s):
[1] ft indicates feet.
[2] ft BGS indicates feet below ground surface.
[3] S.U. indicates standard units.
[4] µS/cm indicates microsiemens per centimeter.
[5] ˚C indicates degrees Celsius.
[6] NTU indicates Nephelometric turbidity units.
[7] ORP indicates oxidation reduction potential.
[8] mV indicates millivolts.
[9] DO indicates dissolved oxygen.
[10] mg/L indicates milligrams per liter.
[11] Bold value indicates exceedance of groundwater standard at or beyond the Compliance Boundary.

1 of 2

Table 12. LOLA Investigation – Groundwater Analytical Data
Location
Screen
Interval
(ft BGS)
Sample
Date
Concentration (µg/L)
Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Total
Chromium Copper Iron Lead Magnesiu
m
Manganes
e Mercury Molybdenu
m Nickel Potassiu
m
Groundwater Standards NC 10 700 NC 700 2 NC 10 1,000 300 15 NC 50 1 NC 100 NC
IMAC 1 NC NC 4 NC NC NC NC NC NC NC NC NC NC NC NC NC
MW-13 8-18 7/2/2014 5.1 U 218 367 0.67 U 935 0.33 U 45,300 0.5 U 2.8 U 5,500 4.7 U 15,700 145 0.06 U 140 1.6 U 13,000
MW-13D 33.5-38.5 7/2/2014 5.1 U 9.7 144 0.67 U 2,350 0.33 U 89,400 0.5 U 2.8 U 4,720 4.7 U 25,100 459 0.06 U 319 1.6 U 14,700
MW-14 1-11 6/30/2014 5.1 U 6.1 441 0.67 U 104 0.33 U 47,300 < 4.0 2.8 U 1,170 4.7 U 3,030 27.5 0.06 U < 20 1.6 U 5,360
MW-15 1-11 7/2/2014 5.1 U 31.2 36.5 0.67 U < 100 0.33 U 114,000 0.5 U 2.8 U 5,720 4.7 U 5,200 109 0.06 U < 20 1.6 U 3,500
MW-15D 40-45 7/2/2014 5.1 U < 4.0 53.3 0.67 U 550 0.33 U 61,500 0.5 U 2.8 U 724 4.7 U 8,180 1,620 0.06 U 1.7 U 1.6 U 7,610
MW-16 2-12 7/1/2014 5.1 U < 4.0 26.3 0.67 U 143 0.33 U 8,660 < 4.0 2.8 U 781 4.7 U 3,860 20.4 0.06 U < 20 1.6 U 5,460
MW-16D 42-47 7/1/2014 5.1 U < 4.0 34.3 0.67 U 432 0.33 U 24,500 0.5 U 2.8 U 1,820 4.7 U 5,970 269 0.06 U 1.7 U < 20 4,820
MW-20 4-14 7/1/2014 5.1 U 7.2 U 126 0.67 U 129 0.33 U 85,500 0.5 U 2.8 U 2,610 4.7 U 8,940 413 0.06 U 1.7 U < 20 6,710
MW-20D 43-48 7/1/2014 5.1 U 7.2 U 58.7 0.67 U 227 0.33 U 69,900 0.5 U 2.8 U 2,310 4.7 U 5,620 190 0.06 U < 20 1.6 U 2,720
Note(s):
[1] U indicates results below the method detection limit (MDL) and < indicates results below the practical quantitation limit (PQL).
[2] µg/L indicates micrograms per liter.
[3] IMAC indicates Interim Maximum Allowable Concentrations.
[4] Groundwater Standards and IMAC values are from Classifications and Water Quality Applicable to the Groundwaters of North Carolina (NCDENR, Division of Water Quality, April 2013).
[5] NC indicates no criteria.
[6] Bold values indicate concentrations exceeding groundwater standards at or beyond Compliance Boundary.
[7] TDS indicates total dissolved solids.
[8] ft BGS indicates feet below ground surface.
[9] Sample IDs for these locations were a combination of location and sampling date, i.e. GW-MW-16-20140701 or 20140630 - MW14.

2 of 2

Table 12. LOLA Investigation – Groundwater Analytical Data (Continued)
Location
Screen
Interval
(ft BGS)
Sample Date
Concentration (µg/L)
Selenium Silver Sodium Strontium Thallium Vanadium Zinc Bromide Chloride Nitrate (as
N)
Nitrite (as
NO2-) Sulfate Alkalinity
(as CaCO3) TDS
Groundwater Standards 20 20 NC NC NC NC 1,000 NC 250,000 10,000 1,000 250,000 NC 500,000
IMAC NC NC NC NC 0.2 0.3 NC NC NC NC NC NC NC NC
MW-13 8-18 7/2/2014 4.8 U 1.8 U 44,800 1,400 5.1 U 1.9 U < 40 2,000U 47,200 250 U 400 U 128,000 86,900 370,000
MW-13D 33.5-38.5 7/2/2014 4.8 U 1.8 U 52,100 3,200 5.1 U 1.9 U < 40 2,000U 59,600 250 U 400 U 96,900 235,000 516,000
MW-14 1-11 6/30/2014 4.8 U 1.8 U 19,200 398 5.1 U 11.4 < 40 2,000U 22,700 < 500 400 U 6,500 125,000 200,000
MW-15 1-11 7/2/2014 4.8 U 1.8 U 18,300 553 5.1 U 1.9 U < 40 2,000U 45,100 250 U 400 U 42,000 211,000 398,000
MW-15D 40-45 7/2/2014 4.8 U 1.8 U 66,500 615 5.1 U 1.9 U < 40 2,000U 131,000 250 U 400 U 75,700 70,100 435,000
MW-16 2-12 7/1/2014 4.8 U 1.8 U 26,900 105 5.1 U 3.0 < 40 2,000U 28,000 250 U 400 U 31,800 23,800 140,000
MW-16D 42-47 7/1/2014 4.8 U 1.8 U 80,700 154 5.1 U 6.0 < 40 2,000U 114,000 250 U 400 U 89,000 2,700 345,000
MW-20 4-14 7/1/2014 4.8 U 1.8 U 16,300 785 5.1 U 41.3 < 40 2,000U 18,800 250 U 400 U 53,700 207,000 334,000
MW-20D 43-48 7/1/2014 4.8 U 1.8 U 51,700 186 5.1 U 1.9 U < 40 2,000U 83,500 250 U 400 U 69,600 118,000 365,000
Note(s):
[1] U indicates results below the method detection limit (MDL) and < indicates results below the practical quantitation limit (PQL).
[2] µg/L indicates micrograms per liter.
[3] IMAC indicates Interim Maximum Allowable Concentrations.
[4] Groundwater Standards and IMAC values are from Classifications and Water Quality Applicable to the Groundwaters of North Carolina (NCDENR, Division of Water Quality, April 2013).
[5] NC indicates no criteria.
[6] Bold values indicate concentrations exceeding groundwater standards at or beyond Compliance Boundary.
[7] TDS indicates total dissolved solids.
[8] ft BGS indicates feet below ground surface.
[9] Sample IDs for these locations were a combination of location and sampling date, i.e. GW-MW-16-20140701 or 20140630 - MW14.

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L.V. SUTTON PLANT
HISTORICAL AND CONCEPTUAL
CLOSURE GEOTECHNICAL INVESTIGATION
PROJECT NO:
FIGURE
OCTOBER 2015
3.F1
GC5770
0 600'1200'
SCALE IN FEET
N
LEGEND
GEOSYNTEC CONE PENETRATION TEST
GEOSYNTEC GEOPROBE (MAY 2014)
GEOSYNTEC GEOPROBE (JUNE-JULY 2014)
GEOSYNTEC MARSH BORINGS (JUNE-JULY 2014)
GEOSYNTEC PIEZOMETER
GEOSYNTEC SEISMIC CONE PENETRATION TEST
GEOSYNTEC STANDARD PENETRATION TEST
HISTORICAL HAND-AUGER
HISTORICAL PIEZOMETER
HISTORICAL STANDARD PENETRATION TEST
NOTES:
1. B-SERIES, HA-SERIES, AND PZ-B-SERIES POINTS ARE
SHOWN AT APPROXIMATE LOCATIONS.
2. POST-FIX 'A' FOR GEOSYNTEC INVESTIGATION POINTS
INDICATES A POINT ON THE DIKE OF 2006 INTERIOR
CONTAINMENT AREA.
3. THE LOCATIONS OF THE GEOSYNTEC BORINGS WERE
SURVEYED BY WSP SELLS, INC., IN MAY AND JULY 2014.
COOLING
POND
CANAL
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L.V. Sutton Plant
Figure
2.F3
Project No. GC5770
October 2015
Notes:
1.LOLA indicates Lay-of-Land Area
2.FDPT indicates direct-push technology boring location
3.Bottom elevations are in feet relative to North American Vertical Datum of 1988 (NAVD88)
4.Horizontal coordinate system North American Datum 1983 (NAD83)
Pa
t
h
:

Isopach Thickness of CCR in LOLA
L.V. Sutton Plant
Figure
2.F4
Project No. GC5770
October 2015
Notes:
1.LOLA indicates Lay-of-Land Area
2.FDPT indicates direct-push technology boring location
3.Isopach thickness is denoted in feet
4.Elevations are in feet relative to North American Vertical Datum of 1988 (NAVD88)
5.Horizontal coordinate system North American Datum 1983 (NAD83)



































































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AREA WITHIN THIS LIMIT IS FROM
AN AERIAL SURVEY FLOWN 17
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2015 (AREA OUTSIDE IS FROM
NCDOT LIDAR, DATED APRIL 2007)
1984 ASH BASIN
1971 ASH BASIN
LAY OF LAND AREA (LOLA)
DIS
C
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C
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W
COOLING POND
B-1
B-2
B-3
LA-SPT-1
LA-SPT-2
LA-SPT-3
LA-SPT-4
LA-SPT-5
LA-SPT-6
LA-SPT-7
SPT- 10
SPT- 8
SPT-1
SPT-11
SPT-12
SPT-13
SPT-14
SPT-2
SPT-3
SPT-4
SPT-5
SPT-6
SPT-7
SPT-9/PZ-INT
CPT-1
CPT-2
CPT-3
CPT-4
CPT-5
CPT-6A
CPT-7A
CPT-8
GP-1
GP-10GP-11
GP-12
GP-13
GP-14 GP-15
GP-16
GP-16A
GP-17
GP-2
GP-3
GP-4
GP-5
GP-6
GP-7
GP-8
GP-9
HA-004-B-1
HA-004-B-2
HA-004-B-3
HA-004-PZ-105
HA-004-PZ-106
HA-004-PZ-107
HA-005-PZ-103
HA-005-PZ-104
HA-1-1HA-1-2
HA-2-1HA-2-2
HA-3-1
HA-3-2
MB-1
MB-2
MW 1B
MW 2A
MW 3A
MW 3B
MW-10
MW-11
MW-12
MW-13
MW-13D
MW-14
MW-15
MW-15D
MW-16MW-16D
MW-17MW-18
MW-19
MW-1A
MW-1B
MW-20
MW-20D
MW-22B
MW-22C
MW-23B
MW-23C
MW-24B
MW-24C
MW-27B
MW-28B
MW-28CMW-2A
MW-2B
MW-2C
MW-31B
MW-31C
MW-32C
MW-33C
MW-34B
MW-34C
MW-35B
MW-35C
MW-36B
MW-36C
MW-3A
MW-3BMW-6A
MW-6BMW-6C MW-7AMW-7B
MW-7C
MW-9
GWPZ-1A
GWPZ-1B
GWPZ-2AGWPZ-2B
GWPZ-3AGWPZ-3B GWPZ-4AGWPZ-4B
LA-PZ-1
LA-PZ-2
LA-PZ-3
LA-PZ-4
LA-PZ-5
PZ-1
PZ-101
PZ-102
PZ-103
PZ-104
PZ-105
PZ-106
PZ-107
PZ-108D
PZ-108S
PZ-10DPZ-10S
PZ-11
PZ-12
PZ-13
PZ-14
PZ-15
PZ-16
PZ-17
PZ-18
PZ-19
PZ1971
PZ-1A
PZ-1B
PZ-1X
PZ-2
PZ-20
PZ-21
PZ-22
PZ-23
PZ-24
PZ-25
PZ-26
PZ-27
PZ-28
PZ-29
PZ-2A
PZ-2B
PZ-2X
PZ-3PZ-3APZ-3B
PZ-3X
PZ-4PZ-4A
PZ-4B
PZ-4X
PZ-5PZ-5APZ-5B
PZ-5X
PZ-6PZ-6A
PZ-6B
PZ-6D
PZ-6S
PZ-7
PZ-8
PZ-9
PZ-INT
SCPT-1
SCPT-2
SCPT-3A
SCPT-4
SCPT-5A
SCPT-6
SG - 1
SG - 2
SG - 3
SG - 4
DW-1
DW-2 DW-3 DW-4 DW-5
DW-6
DW-12
PRW-5
EDR-3
EDR-5
EDR-11
NHC-SW2
PLANT LOCATION
LO-SPT-3
0 300'600'
SCALE IN FEET
NNOTES:
1. FLOOD ZONE INFORMATION OBTAINED FROM NEW HANOVER
COUNTY GIS WEBSITE AND ARE SHOWN IN REFERENCE TO FEMA
FIRM MAP PANELS 3109 AND 3200, LAST REVISED 2 JUNE 2006.
2. NATIONAL WETLAND INVENTORY INFORMATION SHOWN WAS
OBTAINED FROM THE US FISH AND WILDLIFE SERVICE WEBSITE.
3. WETLANDS WERE OBTAINED FROM FIELD DELINEATION BY
GEOSYNTEC AND PROVIDED IN A DRAWING DATED 4 MARCH 2015
BASED ON FIELD SURVEY BY WSP.
PROPERTY BOUNDARY
EXISTING GROUND ELEVATION
CONTOURS IN OBSCURED AREAS
EXISTING GROUND ELEVATION
CONTOURS IN OPEN AREAS
AERIAL MAPPING LIMIT
DRAINAGE CENTERLINE
FENCE LINE
GRAVEL / DIRT PATH
SPOT ELEVATION
SPOT ELEVATION ESTIMATED
IN OBSCURED AREAS
500 FT COMPLIANCE BOUNDARY
X X X X X X X X
LEGEND
TREE / BRUSH LINE
UNIDENTIFIED UTILITIES / STRUCTURES /
OBJECTS
UTILITY POLE
WET AREA
FEMA FLOOD ZONE AE (NOTE 1)
FEMA FLOOD ZONE X (NOTE 1)
WETLANDS - NATIONAL WETLAND INVENTORY
(NOTE 2)
WETLANDS - SURVEYED (NOTE 3)
W W
A
9
A
B'
9
B
C
C'
PROJECT NO:
FIGURE
CROSS-SECTION LOCATIONS
L.V. SUTTON STEAM STATION
WILMINGTON, NORTH CAROLINA 28401
OCTOBER 2015
8
GC5770
HAND AUGER
CONE PENETRATION TEST
SEISMIC CONE PENETRATION TEST
GEO-PROBE
BORING
PIEZOMETER
MONITORING WELL
WATER SUPPLY WELL
ABANDONED WATER SUPPLY WELL
STAFF GAUGE
HYDROGEOLOGIC CROSS SECTION LOCATIONC
10
C
10
9
9
10
10
PROJECT NO:
FIGURE
CROSS-SECTIONS A AND B
L.V. SUTTON STEAM STATION
WILMINGTON, NORTH CAROLINA 28401
OCTOBER 2015
9
GC5770
A
SCALE AS SHOWN
SECTION
HYDROGEOLOGICAL CROSS SECTION8
B
SCALE AS SHOWN
SECTION
HYDROGEOLOGICAL CROSS SECTION8
NOTES:
1. ALL CONCENTRATIONS ARE REPORTED IN MICROGRAMS PER LITER.
2. ONLY RESULTS ABOVE NCDENR'S 2L STANDARDS ARE SHOWN.
3. SCREEN INTERVALS ARE REPORTED IN FEET BELOW GROUND SURFACE.
LEGEND
NOTES:
1. ALL CONCENTRATIONS ARE REPORTED IN MICROGRAMS PER LITER.
2. ONLY RESULTS ABOVE NCDENR'S 2L STANDARDS ARE SHOWN.
3. SCREEN INTERVALS ARE REPORTED IN FEET BELOW GROUND SURFACE.
LEGEND
PROJECT NO:
FIGURE
CROSS-SECTION C
L.V. SUTTON STEAM STATION
WILMINGTON, NORTH CAROLINA 28401
OCTOBER 2015
10
GC5770
C
SCALE AS SHOWN
SECTION
HYDROGEOLOGICAL CROSS SECTION8

APPENDICES

Appendix A1
Laboratory Analytical Report Supplemental
Investigation
REVISED

ANALYTICAL RESULTS

Prepared by:

Eurofins Lancaster Laboratories Environmental
2425 New Holland Pike
Lancaster, PA 17601
Prepared for:

GeoSyntec Consultants
4601 Six Forks Road
Suite 340
Raleigh NC 27609

June 16, 2014

Project: Duke Sutton, NC

Submittal Date: 05/10/2014
Group Number: 1473465
SDG: DUK25
PO Number: GC5592
State of Sample Origin: NC

Client Sample Description Lancaster Labs (LL) #
SS-SPT9(12-14)-20140507 Solid Sample 7459366
SS-SPT9(12-14)-20140507 Solid Sample 7459367
SS-SPT7(4-6)-20140507 Solid Sample 7459368
SS-SPT7(4-6)-20140507 Solid Sample 7459369
SS-MW36C(4-6)-20140509 Solid Sample 7459370

The specific methodologies used in obtaining the enclosed analytical results are indicated on the
Laboratory Sample Analysis Record.

ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Lauren Wellborn
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Beau Hodge
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Rachel Donahue
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Herwig Goldemund

Page 1 of 18
REVISED

Respectfully Submitted,

[phone]

Page 2 of 18
REVISED

LL Sample # SW 7459366
LL Group # 1473465
Account # 10634
Sample Description: SS-SPT9(12-14)-20140507 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/07/2014 11:25
Submitted: 05/10/2014 09:35
GeoSyntec Consultants
Reported: 06/16/2014 14:30
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DUK01 SDG#: DUK25-01
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 1.27 6.84 Antimony
38.1 17440-38-2 06935 1.20 6.84 Arsenic
304 57440-39-3 06946 0.282 8.55 Barium
4.15 17440-41-7 06947 0.115 1.71 Beryllium
31.0 17440-42-8 07914 1.44 17.1 Boron
0.328 J 17440-43-9 06949 0.130 1.71 Cadmium
2,390 17440-70-2 01650 5.71 68.4 Calcium
19.3 17440-47-3 06951 0.274 5.13 Chromium
70.7 17440-50-8 06953 0.496 3.42 Copper
7,610 17439-89-6 01654 6.19 68.4 Iron
21.2 17439-92-1 06955 0.855 5.13 Lead
809 17439-95-4 01657 2.86 34.2 Magnesium
40.8 17439-96-5 06958 0.142 1.71 Manganese
2.44 J 17439-98-7 06960 0.291 3.42 Molybdenum
28.5 17440-02-0 06961 0.222 3.42 Nickel
1,890 17440-09-7 01662 14.3 171 Potassium
1.55 J 17782-49-2 06936 1.37 6.84 Selenium
N.D.17440-22-4 06966 0.291 1.71 Silver
334 J 17440-23-5 01667 28.6 342 Sodium
290 57440-24-6 07968 0.282 8.55 Strontium
N.D.17440-28-0 06925 0.889 10.3 Thallium
29.2 17440-66-6 06972 0.342 6.84 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.0362 J 17439-97-6 00159 0.0169 0.337 Mercury
mg/kg mg/kgmg/kgWet Chemistry EPA 300.0
N.D.124959-67-907335 6.8 8.5 Bromide by IC (solid)
32.5 116887-00-607333 8.5 17.0 Chloride by IC (solid)
74.8 114808-79-807338 8.5 25.4 Sulfate by IC (solid)
Std. Units Std. UnitsStd. UnitsSW-846 9045D modified
8.02 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 21.5 C.
% %%Wet Chemistry SM 2540 G-1997
42.1 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 3 of 18
REVISED

LL Sample # SW 7459366
LL Group # 1473465
Account # 10634
Sample Description: SS-SPT9(12-14)-20140507 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/07/2014 11:25
Submitted: 05/10/2014 09:35
GeoSyntec Consultants
Reported: 06/16/2014 14:30
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DUK01 SDG#: DUK25-01
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Antimony 06944
1Tara L Snyder05/15/2014 06:15 1413306370011SW-846 6010C Arsenic 06935
5Tara L Snyder05/15/2014 06:27 1413306370011SW-846 6010C Barium 06946
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Beryllium 06947
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Boron 07914
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Cadmium 06949
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Calcium 01650
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Chromium 06951
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Copper 06953
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Iron 01654
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Lead 06955
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Magnesium 01657
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Manganese 06958
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Molybdenum 06960
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Nickel 06961
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Potassium 01662
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Selenium 06936
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Silver 06966
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Sodium 01667
5Tara L Snyder05/15/2014 06:27 1413306370011SW-846 6010C Strontium 07968
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Thallium 06925
1Maria A Orrs05/14/2014 18:40 1413306370011SW-846 6010C Zinc 06972
1Damary Valentin05/14/2014 11:19 1413206380021SW-846 7471B Mercury 00159
1James L Mertz05/14/2014 08:14 1413306370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1Denise K Conners05/13/2014 13:20 1413206380021SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Sandra J Miller05/20/2014 18:41 14140140201A1EPA 300.0 Bromide by IC (solid) 07335
1Sandra J Miller05/20/2014 18:41 14140140201A1EPA 300.0 Chloride by IC (solid) 07333
1Sandra J Miller05/20/2014 18:41 14140140201A1EPA 300.0 Sulfate by IC (solid) 07338
1Nancy J Shoop05/20/2014 08:15 14140140201A1EPA 300.0 Deionized Water
Extraction
01352
1Luz M Groff05/13/2014 21:25 14133039401A1SW-846 9045D
modified
pH 00394
1Scott W Freisher05/19/2014 19:01 14139820003A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 4 of 18
REVISED

LL Sample # TL 7459367
LL Group # 1473465
Account # 10634
Sample Description: SS-SPT9(12-14)-20140507 Solid Sample
SPLP NVE
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/07/2014 11:25
Submitted: 05/10/2014 09:35
GeoSyntec Consultants
Reported: 06/16/2014 14:30
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DUK02 SDG#: DUK25-02
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
0.0699 17440-38-2 07035 0.0068 0.0400 Arsenic
0.143 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0644 J 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
4.87 17440-70-2 01750 0.0334 0.400 Calcium
0.0032 J 17440-47-3 07051 0.0016 0.0300 Chromium
0.0028 J 17440-50-8 07053 0.0027 0.0200 Copper
0.0983 J 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.531 17439-95-4 01757 0.0167 0.200 Magnesium
0.0061 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0189 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0038 J 17440-02-0 07061 0.0015 0.0200 Nickel
0.460 J 17440-09-7 01762 0.0980 1.00 Potassium
N.D.17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
1.83 J 17440-23-5 01767 0.167 2.00 Sodium
0.265 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
N.D.17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Antimony 07044
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Arsenic 07035
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Barium 07046
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Beryllium 07047
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Boron 08014
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Cadmium 07049
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Calcium 01750
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 5 of 18
REVISED

LL Sample # TL 7459367
LL Group # 1473465
Account # 10634
Sample Description: SS-SPT9(12-14)-20140507 Solid Sample
SPLP NVE
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/07/2014 11:25
Submitted: 05/10/2014 09:35
GeoSyntec Consultants
Reported: 06/16/2014 14:30
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DUK02 SDG#: DUK25-02
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Copper 07053
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Iron 01754
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Lead 07055
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Magnesium 01757
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Manganese 07058
1Katlin N Cataldi05/19/2014 16:06 1413606360021SW-846 6010C Molybdenum 07060
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Nickel 07061
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Potassium 01762
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Selenium 07036
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Silver 07066
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Sodium 01767
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Strontium 08068
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Thallium 07022
1Joanne M Gates05/19/2014 06:32 1413606360021SW-846 6010C Zinc 07072
1Damary Valentin05/19/2014 10:45 1413657130031SW-846 7470A Mercury 00259
1Annamaria Kuhns05/18/2014 23:00 1413606360021SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Annamaria Kuhns05/19/2014 01:00 1413657130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Darin P Wagner05/15/2014 14:30 14135-482-
1567A
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 6 of 18
REVISED

LL Sample # SW 7459368
LL Group # 1473465
Account # 10634
Sample Description: SS-SPT7(4-6)-20140507 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/07/2014 14:15
Submitted: 05/10/2014 09:35
GeoSyntec Consultants
Reported: 06/16/2014 14:30
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DUK03 SDG#: DUK25-03
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.959 5.18 Antimony
49.1 17440-38-2 06935 0.907 5.18 Arsenic
430 107440-39-3 06946 0.428 13.0 Barium
5.81 17440-41-7 06947 0.0868 1.30 Beryllium
31.3 17440-42-8 07914 1.09 13.0 Boron
0.540 J 17440-43-9 06949 0.0985 1.30 Cadmium
3,560 17440-70-2 01650 4.33 51.8 Calcium
42.3 17440-47-3 06951 0.207 3.89 Chromium
58.1 17440-50-8 06953 0.376 2.59 Copper
13,900 17439-89-6 01654 4.69 51.8 Iron
28.6 17439-92-1 06955 0.648 3.89 Lead
1,510 17439-95-4 01657 2.16 25.9 Magnesium
67.4 17439-96-5 06958 0.108 1.30 Manganese
1.33 J 17439-98-7 06960 0.220 2.59 Molybdenum
30.5 17440-02-0 06961 0.168 2.59 Nickel
2,820 17440-09-7 01662 10.8 130 Potassium
5.39 17782-49-2 06936 1.04 5.18 Selenium
N.D.17440-22-4 06966 0.220 1.30 Silver
499 17440-23-5 01667 21.6 259 Sodium
420 107440-24-6 07968 0.428 13.0 Strontium
1.68 J 17440-28-0 06925 0.674 7.77 Thallium
58.0 17440-66-6 06972 0.259 5.18 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.262 J 17439-97-6 00159 0.0133 0.266 Mercury
mg/kg mg/kgmg/kgWet Chemistry EPA 300.0
N.D.124959-67-907335 5.4 6.8 Bromide by IC (solid)
N.D.116887-00-607333 6.8 13.5 Chloride by IC (solid)
24.6 114808-79-807338 6.8 20.3 Sulfate by IC (solid)
Std. Units Std. UnitsStd. UnitsSW-846 9045D modified
8.35 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 21.8 C.
% %%Wet Chemistry SM 2540 G-1997
26.5 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 7 of 18
REVISED

LL Sample # SW 7459368
LL Group # 1473465
Account # 10634
Sample Description: SS-SPT7(4-6)-20140507 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/07/2014 14:15
Submitted: 05/10/2014 09:35
GeoSyntec Consultants
Reported: 06/16/2014 14:30
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DUK03 SDG#: DUK25-03
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Antimony 06944
1Tara L Snyder05/15/2014 06:19 1413306370011SW-846 6010C Arsenic 06935
10Tara L Snyder05/15/2014 06:31 1413306370011SW-846 6010C Barium 06946
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Beryllium 06947
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Boron 07914
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Cadmium 06949
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Calcium 01650
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Chromium 06951
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Copper 06953
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Iron 01654
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Lead 06955
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Magnesium 01657
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Manganese 06958
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Molybdenum 06960
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Nickel 06961
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Potassium 01662
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Selenium 06936
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Silver 06966
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Sodium 01667
10Tara L Snyder05/15/2014 06:31 1413306370011SW-846 6010C Strontium 07968
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Thallium 06925
1Maria A Orrs05/14/2014 18:44 1413306370011SW-846 6010C Zinc 06972
1Damary Valentin05/14/2014 11:21 1413206380021SW-846 7471B Mercury 00159
1James L Mertz05/14/2014 08:14 1413306370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1Denise K Conners05/13/2014 13:20 1413206380021SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Sandra J Miller05/20/2014 19:30 14140140201A1EPA 300.0 Bromide by IC (solid) 07335
1Sandra J Miller05/20/2014 19:30 14140140201A1EPA 300.0 Chloride by IC (solid) 07333
1Sandra J Miller05/20/2014 19:30 14140140201A1EPA 300.0 Sulfate by IC (solid) 07338
1Nancy J Shoop05/20/2014 08:15 14140140201A1EPA 300.0 Deionized Water
Extraction
01352
1Luz M Groff05/13/2014 21:25 14133039401A1SW-846 9045D
modified
pH 00394
1Scott W Freisher05/19/2014 19:01 14139820003A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 8 of 18
REVISED

LL Sample # TL 7459369
LL Group # 1473465
Account # 10634
Sample Description: SS-SPT7(4-6)-20140507 Solid Sample
SPLP NVE
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/07/2014 14:15
Submitted: 05/10/2014 09:35
GeoSyntec Consultants
Reported: 06/16/2014 14:30
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DUK04 SDG#: DUK25-04
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
0.0734 17440-38-2 07035 0.0068 0.0400 Arsenic
0.0727 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0734 J 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
6.38 17440-70-2 01750 0.0334 0.400 Calcium
0.0051 J 17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
N.D.17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
1.46 17439-95-4 01757 0.0167 0.200 Magnesium
N.D.17439-96-5 07058 0.00083 0.0100 Manganese
0.0086 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
N.D.17440-09-7 01762 0.0980 1.00 Potassium
0.0428 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
1.74 J 17440-23-5 01767 0.167 2.00 Sodium
0.224 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
N.D.17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Antimony 07044
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Arsenic 07035
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Barium 07046
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Beryllium 07047
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Boron 08014
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Cadmium 07049
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Calcium 01750
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 9 of 18
REVISED

LL Sample # TL 7459369
LL Group # 1473465
Account # 10634
Sample Description: SS-SPT7(4-6)-20140507 Solid Sample
SPLP NVE
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/07/2014 14:15
Submitted: 05/10/2014 09:35
GeoSyntec Consultants
Reported: 06/16/2014 14:30
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DUK04 SDG#: DUK25-04
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Copper 07053
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Iron 01754
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Lead 07055
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Magnesium 01757
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Manganese 07058
1Katlin N Cataldi05/19/2014 16:30 1413606360021SW-846 6010C Molybdenum 07060
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Nickel 07061
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Potassium 01762
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Selenium 07036
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Silver 07066
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Sodium 01767
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Strontium 08068
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Thallium 07022
1Joanne M Gates05/19/2014 07:11 1413606360021SW-846 6010C Zinc 07072
1Damary Valentin05/19/2014 10:53 1413657130031SW-846 7470A Mercury 00259
1Annamaria Kuhns05/18/2014 23:00 1413606360021SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Annamaria Kuhns05/19/2014 01:00 1413657130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Darin P Wagner05/15/2014 14:30 14135-482-
1567A
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 10 of 18
REVISED

LL Sample # SW 7459370
LL Group # 1473465
Account # 10634
Sample Description: SS-MW36C(4-6)-20140509 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/09/2014 08:05
Submitted: 05/10/2014 09:35
GeoSyntec Consultants
Reported: 06/16/2014 14:30
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DUK05 SDG#: DUK25-05*
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.778 4.21 Antimony
N.D.17440-38-2 06935 0.736 4.21 Arsenic
1.42 17440-39-3 06946 0.0347 1.05 Barium
N.D.17440-41-7 06947 0.0705 1.05 Beryllium
N.D.17440-42-8 07914 0.884 10.5 Boron
N.D.17440-43-9 06949 0.0799 1.05 Cadmium
224 17440-70-2 01650 3.51 42.1 Calcium
1.20 J 17440-47-3 06951 0.168 3.16 Chromium
0.315 J 17440-50-8 06953 0.305 2.10 Copper
835 17439-89-6 01654 3.81 42.1 Iron
0.865 J 17439-92-1 06955 0.526 3.16 Lead
36.1 17439-95-4 01657 1.76 21.0 Magnesium
5.05 17439-96-5 06958 0.0873 1.05 Manganese
N.D.17439-98-7 06960 0.179 2.10 Molybdenum
0.512 J 17440-02-0 06961 0.137 2.10 Nickel
34.6 J 17440-09-7 01662 8.77 105 Potassium
N.D.17782-49-2 06936 0.842 4.21 Selenium
N.D.17440-22-4 06966 0.179 1.05 Silver
N.D.17440-23-5 01667 17.6 210 Sodium
1.26 17440-24-6 07968 0.0347 1.05 Strontium
N.D.17440-28-0 06925 0.547 6.31 Thallium
1.70 J 17440-66-6 06972 0.210 4.21 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
N.D.17439-97-6 00159 0.0106 0.212 Mercury
mg/kg mg/kgmg/kgWet Chemistry EPA 300.0
N.D.124959-67-907335 4.3 5.3 Bromide by IC (solid)
N.D.116887-00-607333 5.3 10.6 Chloride by IC (solid)
N.D.114808-79-807338 5.3 16.0 Sulfate by IC (solid)
Std. Units Std. UnitsStd. UnitsSW-846 9045D modified
7.90 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 21.7 C.
% %%Wet Chemistry SM 2540 G-1997
6.8 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 11 of 18
REVISED

LL Sample # SW 7459370
LL Group # 1473465
Account # 10634
Sample Description: SS-MW36C(4-6)-20140509 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/09/2014 08:05
Submitted: 05/10/2014 09:35
GeoSyntec Consultants
Reported: 06/16/2014 14:30
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DUK05 SDG#: DUK25-05*
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Antimony 06944
1Tara L Snyder05/15/2014 06:23 1413306370011SW-846 6010C Arsenic 06935
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Barium 06946
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Beryllium 06947
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Boron 07914
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Cadmium 06949
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Calcium 01650
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Chromium 06951
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Copper 06953
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Iron 01654
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Lead 06955
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Magnesium 01657
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Manganese 06958
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Molybdenum 06960
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Nickel 06961
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Potassium 01662
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Selenium 06936
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Silver 06966
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Sodium 01667
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Strontium 07968
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Thallium 06925
1Maria A Orrs05/14/2014 18:48 1413306370011SW-846 6010C Zinc 06972
1Damary Valentin05/14/2014 11:23 1413206380021SW-846 7471B Mercury 00159
1James L Mertz05/14/2014 08:14 1413306370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1Denise K Conners05/13/2014 13:20 1413206380021SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Sandra J Miller05/20/2014 19:46 14140140201A1EPA 300.0 Bromide by IC (solid) 07335
1Sandra J Miller05/20/2014 19:46 14140140201A1EPA 300.0 Chloride by IC (solid) 07333
1Sandra J Miller05/20/2014 19:46 14140140201A1EPA 300.0 Sulfate by IC (solid) 07338
1Nancy J Shoop05/20/2014 08:15 14140140201A1EPA 300.0 Deionized Water
Extraction
01352
1Luz M Groff05/13/2014 21:25 14133039401B1SW-846 9045D
modified
pH 00394
1Scott W Freisher05/19/2014 19:01 14139820003A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 12 of 18

Page 1 of 4
REVISED
Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1473465
Reported: 06/16/14 at 02:30 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Matrix QC may not be reported if insufficient sample or site-specific QC samples were not submitted. In these
situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise
specified in the method.

All Inorganic Initial Calibration and Continuing Calibration Blanks met acceptable method criteria unless
otherwise noted on the Analysis Report.

Laboratory Compliance Quality Control

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Batch number: 141320638002 Sample number(s): 7459366,7459368,7459370
Mercury N.D. 0.0100 0.200 mg/kg 90 80-120

Batch number: 141330637001 Sample number(s): 7459366,7459368,7459370
Antimony N.D. 0.740 4.00 mg/kg 107 80-120
Arsenic N.D. 0.700 4.00 mg/kg 106 80-120
Barium N.D. 0.0330 1.00 mg/kg 103 80-120
Beryllium N.D. 0.0670 1.00 mg/kg 103 80-120
Boron N.D. 0.840 10.0 mg/kg 101 80-120
Cadmium N.D. 0.0760 1.00 mg/kg 106 80-120
Calcium 10.8 J 3.34 40.0 mg/kg 102 80-120
Chromium N.D. 0.160 3.00 mg/kg 103 80-120
Copper N.D. 0.290 2.00 mg/kg 106 80-120
Iron N.D. 3.62 40.0 mg/kg 102 80-120
Lead N.D. 0.500 3.00 mg/kg 108 80-120
Magnesium N.D. 1.67 20.0 mg/kg 100 80-120
Manganese 0.0880 J 0.0830 1.00 mg/kg 103 80-120
Molybdenum N.D. 0.170 2.00 mg/kg 104 80-120
Nickel N.D. 0.130 2.00 mg/kg 109 80-120
Potassium N.D. 8.34 100 mg/kg 98 80-120
Selenium N.D. 0.800 4.00 mg/kg 102 80-120
Silver N.D. 0.170 1.00 mg/kg 86 80-120
Sodium N.D. 16.7 200 mg/kg 100 80-120
Strontium 0.0630 J 0.0330 1.00 mg/kg 105 80-120
Thallium N.D. 0.520 6.00 mg/kg 109 80-120
Zinc 0.691 J 0.200 4.00 mg/kg 105 80-120

Batch number: 141360636002 Sample number(s): 7459367,7459369
Antimony N.D. 0.0053 0.0400 mg/l 107 80-120
Arsenic N.D. 0.0068 0.0400 mg/l 103 80-120
Barium N.D. 0.00033 0.0100 mg/l 105 80-120
Beryllium N.D. 0.00067 0.0100 mg/l 102 80-120
Boron N.D. 0.0084 0.100 mg/l 102 80-120
Cadmium N.D. 0.00076 0.0100 mg/l 106 80-120
Calcium 0.0388 J 0.0334 0.400 mg/l 107 80-120
Chromium N.D. 0.0016 0.0300 mg/l 104 80-120
Copper N.D. 0.0027 0.0200 mg/l 108 80-120
Iron N.D. 0.0430 0.400 mg/l 108 80-120
Lead N.D. 0.0047 0.0300 mg/l 105 80-120
Magnesium N.D. 0.0167 0.200 mg/l 104 80-120
Manganese N.D. 0.00083 0.0100 mg/l 107 80-120
Molybdenum N.D. 0.0017 0.0200 mg/l 108 80-120
Nickel N.D. 0.0015 0.0200 mg/l 110 80-120
Potassium N.D. 0.0980 1.00 mg/l 105 80-120
Page 13 of 18

Page 2 of 4
REVISED
Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1473465
Reported: 06/16/14 at 02:30 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max
Selenium N.D. 0.0084 0.0400 mg/l 106 80-120
Silver N.D. 0.0021 0.0100 mg/l 105 80-120
Sodium N.D. 0.167 2.00 mg/l 105 80-120
Strontium N.D. 0.00033 0.0100 mg/l 108 80-120
Thallium N.D. 0.0054 0.0600 mg/l 107 80-120
Zinc N.D. 0.0020 0.0400 mg/l 104 80-120

Batch number: 141365713003 Sample number(s): 7459367,7459369
Mercury N.D. 0.00006
0
0.00020 mg/l 97 80-120

Batch number: 14140140201A Sample number(s): 7459366,7459368,7459370
Bromide by IC (solid) N.D. 4.0 5.0 mg/kg 97 90-110
Chloride by IC (solid) N.D. 5.0 10.0 mg/kg 101 90-110
Sulfate by IC (solid) N.D. 5.0 15.0 mg/kg 99 90-110

Batch number: 14133039401A Sample number(s): 7459366,7459368
pH 100 90-110

Batch number: 14133039401B Sample number(s): 7459370
pH 100 90-110

Batch number: 14139820003A Sample number(s): 7459366,7459368,7459370
Moisture 100 99-101

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 141320638002 Sample number(s): 7459366,7459368,7459370 UNSPK: P459349 BKG: P459349
Mercury 173* 111 80-120 19 20 0.285 0.537 61* (1) 20

Batch number: 141330637001 Sample number(s): 7459366,7459368,7459370 UNSPK: P459333 BKG: P459333
Antimony 84 87 75-125 5 20 3.19 J N.D. 200* (1) 20
Arsenic 93 97 75-125 4 20 5.63 4.63 19 (1) 20
Barium 85 85 75-125 2 20 129 110 17 20
Beryllium 100 103 83-119 4 20 0.252 J 0.241 J 4 (1) 20
Boron 97 100 84-110 5 20 16.2 10.4 43* (1) 20
Cadmium 95 113 75-120 14 20 1.44 1.44 0 (1) 20
Calcium 1 (2) 85 (2) 75-125 4 20 8,180 8,250 1 20
Chromium 119 110 75-125 4 20 11.8 12.1 2 (1) 20
Copper 89 100 75-125 4 20 48.7 45.7 6 20
Iron -303
(2)
507 (2) 75-125 9 20 8,650 10,300 18 20
Lead -576
(2)
-533
(2)
75-125 2 20 389 300 26* 20
Magnesium 112 (2) 115 (2) 75-125 1 20 1,260 1,120 11 20
Manganese 75 (2) 83 (2) 75-125 2 20 198 187 6 20
Molybdenum 96 101 82-110 6 20 1.03 J 0.951 J 8 (1) 20
Nickel 99 109 75-125 9 20 14.7 15.5 5 20
Page 14 of 18

Page 3 of 4
REVISED
Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1473465
Reported: 06/16/14 at 02:30 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___
Potassium 163* 160* 75-125 0 20 769 761 1 20
Selenium 102 107 75-125 6 20 1.91 J 2.07 J 8 (1) 20
Silver 87 87 75-125 2 20 N.D. N.D. 0 (1) 20
Sodium 97 101 75-125 6 20 69.0 J 51.7 J 29* (1) 20
Strontium 97 101 81-125 5 20 35.5 35.4 0 20
Thallium 91 97 78-119 8 20 N.D. N.D. 0 (1) 20
Zinc 63 (2) 95 (2) 75-125 6 20 247 241 3 20

Batch number: 141360636002 Sample number(s): 7459367,7459369 UNSPK: 7459367 BKG: 7459367
Antimony 95 96 75-125 1 20 N.D. N.D. 0 (1) 20
Arsenic 96 97 75-125 1 20 0.0699 0.0702 0 (1) 20
Barium 92 94 75-125 2 20 0.143 0.144 1 20
Beryllium 90 91 75-125 2 20 N.D. N.D. 0 (1) 20
Boron 94 96 75-125 2 20 0.0644 J 0.0635 J 1 (1) 20
Cadmium 92 92 75-125 0 20 N.D. N.D. 0 (1) 20
Calcium 94 94 75-125 1 20 4.87 4.94 1 20
Chromium 92 93 75-125 2 20 0.0032 J 0.0036 J 11 (1) 20
Copper 95 97 75-125 2 20 0.0028 J 0.0029 J 2 (1) 20
Iron 93 94 75-125 1 20 0.0983 J 0.107 J 8 (1) 20
Lead 90 91 75-125 0 20 N.D. N.D. 0 (1) 20
Magnesium 93 94 75-125 1 20 0.531 0.541 2 (1) 20
Manganese 93 94 75-125 2 20 0.0061 J 0.0062 J 1 (1) 20
Molybdenum 93 94 75-125 1 20 0.0189 J 0.0161 J 16 (1) 20
Nickel 91 91 75-125 0 20 0.0038 J 0.0037 J 5 (1) 20
Potassium 95 96 75-125 1 20 0.460 J 0.497 J 8 (1) 20
Selenium 95 96 75-125 1 20 N.D. 0.0092 J 200* (1) 20
Silver 65* 79 75-125 20 20 N.D. N.D. 0 (1) 20
Sodium 94 94 75-125 0 20 1.83 J 1.83 J 0 (1) 20
Strontium 93 94 75-125 1 20 0.265 0.269 1 20
Thallium 91 91 75-125 1 20 N.D. N.D. 0 (1) 20
Zinc 93 93 75-125 1 20 N.D. N.D. 0 (1) 20

Batch number: 141365713003 Sample number(s): 7459367,7459369 UNSPK: 7459367 BKG: 7459367
Mercury 79* 80 80-120 1 20 N.D. N.D. 0 (1) 20

Batch number: 14140140201A Sample number(s): 7459366,7459368,7459370 UNSPK: 7459366 BKG: 7459366
Bromide by IC (solid) 91 90-110 N.D. N.D. 0 (1) 20
Chloride by IC (solid) 84* 90-110 18.8 18.5 2 (1) 20
Sulfate by IC (solid) 87* 90-110 43.3 42.6 2 (1) 20

Batch number: 14133039401A Sample number(s): 7459366,7459368 BKG: P459212
pH 7.29 7.33 1 3

Batch number: 14133039401B Sample number(s): 7459370 BKG: 7459370
pH 7.90 7.94 1 3

Batch number: 14139820003A Sample number(s): 7459366,7459368,7459370 BKG: 7459370
Moisture 6.8 7.1 4 5

Page 15 of 18

Page 4 of 4
REVISED
Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1473465
Reported: 06/16/14 at 02:30 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Page 16 of 18
Page 17 of 18
Explanation of Symbols and Abbreviations

3768 0713
The following defines common symbols and abbreviations used in reporting technical data:
RL Reporting Limit BMQL Below Minimum Quantitation Level
N.D. none detected MPN Most Probable Number
TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units
IU International Units NTU nephelometric turbidity units
umhos/cm micromhos/cm ng nanogram(s)
C degrees Celsius F degrees Fahrenheit
meq milliequivalents lb. pound(s)
g gram(s) kg kilogram(s)
µg microgram(s) mg milligram(s)
mL milliliter(s) L liter(s)
m3 cubic meter(s) µL microliter(s)
pg/L picogram/liter
< less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be
reliably determined using this specific test.
> greater than
ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For
aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/l), because one liter of water has a
weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter per liter of gas.
ppb parts per billion
Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight
basis concentration to approximate the value present in a similar sample without moisture. All other results are reported
on an as-received basis.
Data Qualifiers:
C – result confirmed by reanalysis.
J - estimated value – The result is ≥ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ).
U.S. EPA CLP Data Qualifiers:
Organic Qualifiers Inorganic Qualifiers
A TIC is a possible aldol-condensation product B Value is <CRDL, but ≥IDL
B Analyte was also detected in the blank E Estimated due to interference
C Pesticide result confirmed by GC/MS M Duplicate injection precision not met
D Compound quantitated on a diluted sample N Spike sample not within control limits
E Concentration exceeds the calibration range of S Method of standard additions (MSA) used
the instrument for calculation
N Presumptive evidence of a compound (TICs only) U Compound was not detected
P Concentration difference between primary and W Post digestion spike out of control limits
confirmation columns >25% * Duplicate analysis not within control limits
U Compound was not detected + Correlation coefficient for MSA <0.995
X,Y,Z Defined in case narrative
Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.
Measurement uncertainty values, as applicable, are available upon request.
Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the
test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact
us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our
staff. This report shall not be reproduced except in full, without the written approval of the laboratory.
Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as “analyze immediately” are not
performed within 15 minutes.

WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE
FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM
ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF
MERCHANTABILITY. IN NO EVENT SHALL EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL, LLC BE LIABLE FOR INDIRECT, SPECIAL,
CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS
OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL AND (B) WHETHER
EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal
responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Eurofins Lancaster
Laboratories Environmental which includes any conditions that vary from the Standard Terms and Conditions, and Eurofins Lancaster Laboratories
Environmental hereby objects to any conflicting terms contained in any acceptance or order submitted by client.
Page 18 of 18
REVISED

ANALYTICAL RESULTS

Prepared by:

Eurofins Lancaster Laboratories Environmental
2425 New Holland Pike
Lancaster, PA 17601
Prepared for:

GeoSyntec Consultants
4601 Six Forks Road
Suite 340
Raleigh NC 27609

June 16, 2014

Project: Duke Sutton, NC

Submittal Date: 05/14/2014
Group Number: 1474124
SDG: DUK26
PO Number: GC5592
State of Sample Origin: NC

Client Sample Description Lancaster Labs (LL) #
SS-SPT3(10-12)20140509 Solid Sample 7462436
SS-SPT3(10-12)20140509 Solid Sample 7462437
SS-MW34C(4-6)20140513 Solid Sample 7462438
SS-SB1(2.5-3.0)20140513 Solid Sample 7462440
SS-SB1(2.5-3.0)20140513 Solid Sample 7462441
SS-SB2(2.5-3.0)20140513 Solid Sample 7462442
SS-SB2(2.5-3.0)20140513 Solid Sample 7462443

The specific methodologies used in obtaining the enclosed analytical results are indicated on the
Laboratory Sample Analysis Record.

ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Lauren Wellborn
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Beau Hodge
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Rachel Donahue
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Herwig Goldemund

Page 1 of 24
REVISED

Respectfully Submitted,

[phone]

Page 2 of 24
REVISED

LL Sample # SW 7462436
LL Group # 1474124
Account # 10634
Sample Description: SS-SPT3(10-12)20140509 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/09/2014 10:40
Submitted: 05/14/2014 09:50
GeoSyntec Consultants
Reported: 06/16/2014 14:28
4601 Six Forks Road
Suite 340
Raleigh NC 27609
SPT3- SDG#: DUK26-01
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.955 5.16 Antimony
19.6 17440-38-2 06935 0.904 5.16 Arsenic
214 27440-39-3 06946 0.0852 2.58 Barium
2.71 17440-41-7 06947 0.0865 1.29 Beryllium
12.4 J 17440-42-8 07914 1.08 12.9 Boron
0.111 J 17440-43-9 06949 0.0981 1.29 Cadmium
1,700 17440-70-2 01650 4.31 51.6 Calcium
27.4 17440-47-3 06951 0.207 3.87 Chromium
38.8 17440-50-8 06953 0.374 2.58 Copper
20,100 17439-89-6 01654 4.67 51.6 Iron
16.8 17439-92-1 06955 0.645 3.87 Lead
842 17439-95-4 01657 2.16 25.8 Magnesium
88.3 17439-96-5 06958 0.107 1.29 Manganese
2.52 J 17439-98-7 06960 0.219 2.58 Molybdenum
26.4 17440-02-0 06961 0.168 2.58 Nickel
1,370 17440-09-7 01662 10.8 129 Potassium
14.9 17782-49-2 06936 1.03 5.16 Selenium
N.D.17440-22-4 06966 0.219 1.29 Silver
221 J 17440-23-5 01667 21.6 258 Sodium
148 27440-24-6 07968 0.0852 2.58 Strontium
N.D.17440-28-0 06925 0.671 7.75 Thallium
24.1 17440-66-6 06972 0.258 5.16 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.170 J 17439-97-6 00159 0.0124 0.247 Mercury
mg/kg mg/kgmg/kgWet Chemistry EPA 300.0
N.D.124959-67-907335 5.2 6.5 Bromide by IC (solid)
N.D.116887-00-607333 6.5 13.0 Chloride by IC (solid)
9.2 J 114808-79-807338 6.5 19.6 Sulfate by IC (solid)
Std. Units Std. UnitsStd. UnitsSW-846 9045D modified
6.53 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 21.2 C.
% %%Wet Chemistry SM 2540 G-1997
23.3 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 3 of 24
REVISED

LL Sample # SW 7462436
LL Group # 1474124
Account # 10634
Sample Description: SS-SPT3(10-12)20140509 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/09/2014 10:40
Submitted: 05/14/2014 09:50
GeoSyntec Consultants
Reported: 06/16/2014 14:28
4601 Six Forks Road
Suite 340
Raleigh NC 27609
SPT3- SDG#: DUK26-01
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Antimony 06944
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Arsenic 06935
2Eric L Eby05/15/2014 13:27 1413406370011SW-846 6010C Barium 06946
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Beryllium 06947
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Boron 07914
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Cadmium 06949
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Calcium 01650
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Chromium 06951
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Copper 06953
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Iron 01654
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Lead 06955
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Magnesium 01657
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Manganese 06958
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Molybdenum 06960
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Nickel 06961
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Potassium 01662
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Selenium 06936
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Silver 06966
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Sodium 01667
2Eric L Eby05/15/2014 13:27 1413406370011SW-846 6010C Strontium 07968
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Thallium 06925
1Joanne M Gates05/15/2014 07:31 1413406370011SW-846 6010C Zinc 06972
1Damary Valentin05/16/2014 07:34 1413406380021SW-846 7471B Mercury 00159
1Annamaria Kuhns05/14/2014 22:24 1413406370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1Annamaria Kuhns05/15/2014 01:20 1413406380021SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Sandra J Miller05/20/2014 20:02 14140140201A1EPA 300.0 Bromide by IC (solid) 07335
1Sandra J Miller05/20/2014 20:02 14140140201A1EPA 300.0 Chloride by IC (solid) 07333
1Sandra J Miller05/20/2014 20:02 14140140201A1EPA 300.0 Sulfate by IC (solid) 07338
1Nancy J Shoop05/20/2014 08:15 14140140201A1EPA 300.0 Deionized Water
Extraction
01352
1Luz M Groff05/17/2014 13:10 14137039401A1SW-846 9045D
modified
pH 00394
1Scott W Freisher05/19/2014 19:33 14139820005A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 4 of 24
REVISED

LL Sample # TL 7462437
LL Group # 1474124
Account # 10634
Sample Description: SS-SPT3(10-12)20140509 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/09/2014 10:40
Submitted: 05/14/2014 09:50
GeoSyntec Consultants
Reported: 06/16/2014 14:28
4601 Six Forks Road
Suite 340
Raleigh NC 27609
SPT3S SDG#: DUK26-02
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0642 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0571 J 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
1.87 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.0494 J 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.582 17439-95-4 01757 0.0167 0.200 Magnesium
0.00084 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0060 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0018 J 17440-02-0 07061 0.0015 0.0200 Nickel
0.297 J 17440-09-7 01762 0.0980 1.00 Potassium
0.0339 J 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
2.59 17440-23-5 01767 0.167 2.00 Sodium
0.0811 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
N.D.17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Antimony 07044
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Arsenic 07035
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Barium 07046
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Beryllium 07047
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Boron 08014
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Cadmium 07049
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Calcium 01750
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 5 of 24
REVISED

LL Sample # TL 7462437
LL Group # 1474124
Account # 10634
Sample Description: SS-SPT3(10-12)20140509 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/09/2014 10:40
Submitted: 05/14/2014 09:50
GeoSyntec Consultants
Reported: 06/16/2014 14:28
4601 Six Forks Road
Suite 340
Raleigh NC 27609
SPT3S SDG#: DUK26-02
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Copper 07053
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Iron 01754
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Lead 07055
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Magnesium 01757
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Manganese 07058
1Katlin N Cataldi05/19/2014 16:34 1413606360021SW-846 6010C Molybdenum 07060
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Nickel 07061
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Potassium 01762
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Selenium 07036
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Silver 07066
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Sodium 01767
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Strontium 08068
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Thallium 07022
1Joanne M Gates05/19/2014 07:14 1413606360021SW-846 6010C Zinc 07072
1Damary Valentin05/19/2014 10:59 1413657130031SW-846 7470A Mercury 00259
1Annamaria Kuhns05/18/2014 23:00 1413606360021SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Annamaria Kuhns05/19/2014 01:00 1413657130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Darin P Wagner05/15/2014 14:30 14135-482-
1567A
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 6 of 24
REVISED

LL Sample # SW 7462438
LL Group # 1474124
Account # 10634
Sample Description: SS-MW34C(4-6)20140513 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/13/2014 08:45
Submitted: 05/14/2014 09:50
GeoSyntec Consultants
Reported: 06/16/2014 14:28
4601 Six Forks Road
Suite 340
Raleigh NC 27609
W36C- SDG#: DUK26-03
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.749 4.05 Antimony
N.D.17440-38-2 06935 0.709 4.05 Arsenic
1.29 17440-39-3 06946 0.0334 1.01 Barium
N.D.17440-41-7 06947 0.0679 1.01 Beryllium
N.D.17440-42-8 07914 0.851 10.1 Boron
N.D.17440-43-9 06949 0.0770 1.01 Cadmium
27.0 J 17440-70-2 01650 3.38 40.5 Calcium
0.870 J 17440-47-3 06951 0.162 3.04 Chromium
0.450 J 17440-50-8 06953 0.294 2.03 Copper
342 17439-89-6 01654 3.67 40.5 Iron
0.953 J 17439-92-1 06955 0.506 3.04 Lead
10.3 J 17439-95-4 01657 1.69 20.3 Magnesium
2.42 17439-96-5 06958 0.0841 1.01 Manganese
0.176 J 17439-98-7 06960 0.172 2.03 Molybdenum
0.418 J 17440-02-0 06961 0.132 2.03 Nickel
20.7 J 17440-09-7 01662 8.45 101 Potassium
N.D.17782-49-2 06936 0.810 4.05 Selenium
N.D.17440-22-4 06966 0.172 1.01 Silver
N.D.17440-23-5 01667 16.9 203 Sodium
0.515 J 17440-24-6 07968 0.0334 1.01 Strontium
N.D.17440-28-0 06925 0.527 6.08 Thallium
0.699 J 17440-66-6 06972 0.203 4.05 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
N.D.17439-97-6 00159 0.0099 0.198 Mercury
mg/kg mg/kgmg/kgWet Chemistry EPA 300.0
N.D.124959-67-907335 4.1 5.1 Bromide by IC (solid)
6.8 J 116887-00-607333 5.1 10.2 Chloride by IC (solid)
74.4 114808-79-807338 5.1 15.3 Sulfate by IC (solid)
Std. Units Std. UnitsStd. UnitsSW-846 9045D modified
6.27 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 21.4 C.
% %%Wet Chemistry SM 2540 G-1997
3.2 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 7 of 24
REVISED

LL Sample # SW 7462438
LL Group # 1474124
Account # 10634
Sample Description: SS-MW34C(4-6)20140513 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/13/2014 08:45
Submitted: 05/14/2014 09:50
GeoSyntec Consultants
Reported: 06/16/2014 14:28
4601 Six Forks Road
Suite 340
Raleigh NC 27609
W36C- SDG#: DUK26-03
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Antimony 06944
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Arsenic 06935
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Barium 06946
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Beryllium 06947
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Boron 07914
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Cadmium 06949
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Calcium 01650
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Chromium 06951
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Copper 06953
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Iron 01654
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Lead 06955
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Magnesium 01657
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Manganese 06958
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Molybdenum 06960
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Nickel 06961
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Potassium 01662
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Selenium 06936
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Silver 06966
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Sodium 01667
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Strontium 07968
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Thallium 06925
1Joanne M Gates05/15/2014 07:35 1413406370011SW-846 6010C Zinc 06972
1Damary Valentin05/16/2014 07:36 1413406380021SW-846 7471B Mercury 00159
1Annamaria Kuhns05/14/2014 22:24 1413406370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1Annamaria Kuhns05/15/2014 01:20 1413406380021SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Sandra J Miller05/20/2014 20:51 14140140201A1EPA 300.0 Bromide by IC (solid) 07335
1Sandra J Miller05/20/2014 20:51 14140140201A1EPA 300.0 Chloride by IC (solid) 07333
1Sandra J Miller05/20/2014 20:51 14140140201A1EPA 300.0 Sulfate by IC (solid) 07338
1Nancy J Shoop05/20/2014 08:15 14140140201A1EPA 300.0 Deionized Water
Extraction
01352
1Luz M Groff05/17/2014 13:10 14137039401A1SW-846 9045D
modified
pH 00394
1Scott W Freisher05/19/2014 19:33 14139820005A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 8 of 24
REVISED

LL Sample # SW 7462440
LL Group # 1474124
Account # 10634
Sample Description: SS-SB1(2.5-3.0)20140513 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/13/2014 11:30
Submitted: 05/14/2014 09:50
GeoSyntec Consultants
Reported: 06/16/2014 14:28
4601 Six Forks Road
Suite 340
Raleigh NC 27609
SB1-- SDG#: DUK26-05
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.783 4.23 Antimony
N.D.17440-38-2 06935 0.740 4.23 Arsenic
0.500 J 17440-39-3 06946 0.0349 1.06 Barium
N.D.17440-41-7 06947 0.0709 1.06 Beryllium
N.D.17440-42-8 07914 0.888 10.6 Boron
N.D.17440-43-9 06949 0.0804 1.06 Cadmium
8.61 J 17440-70-2 01650 3.53 42.3 Calcium
0.383 J 17440-47-3 06951 0.169 3.17 Chromium
N.D.17440-50-8 06953 0.307 2.12 Copper
32.5 J 17439-89-6 01654 3.83 42.3 Iron
N.D.17439-92-1 06955 0.529 3.17 Lead
N.D.17439-95-4 01657 1.77 21.2 Magnesium
1.22 17439-96-5 06958 0.0878 1.06 Manganese
N.D.17439-98-7 06960 0.180 2.12 Molybdenum
0.172 J 17440-02-0 06961 0.137 2.12 Nickel
N.D.17440-09-7 01662 8.82 106 Potassium
N.D.17782-49-2 06936 0.846 4.23 Selenium
N.D.17440-22-4 06966 0.180 1.06 Silver
N.D.17440-23-5 01667 17.7 212 Sodium
0.249 J 17440-24-6 07968 0.0349 1.06 Strontium
N.D.17440-28-0 06925 0.550 6.35 Thallium
0.420 J 17440-62-2 06971 0.137 1.06 Vanadium
0.219 J 17440-66-6 06972 0.212 4.23 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
N.D.17439-97-6 00159 0.0106 0.212 Mercury
mg/kg mg/kgmg/kgWet Chemistry EPA 300.0
N.D.124959-67-907335 4.3 5.4 Bromide by IC (solid)
N.D.116887-00-607333 5.4 10.7 Chloride by IC (solid)
5.4 J 114808-79-807338 5.4 16.1 Sulfate by IC (solid)
Std. Units Std. UnitsStd. UnitsSW-846 9045D modified
4.68 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 21.2 C.
% %%Wet Chemistry SM 2540 G-1997
8.2 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 9 of 24
REVISED

LL Sample # SW 7462440
LL Group # 1474124
Account # 10634
Sample Description: SS-SB1(2.5-3.0)20140513 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/13/2014 11:30
Submitted: 05/14/2014 09:50
GeoSyntec Consultants
Reported: 06/16/2014 14:28
4601 Six Forks Road
Suite 340
Raleigh NC 27609
SB1-- SDG#: DUK26-05
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Antimony 06944
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Arsenic 06935
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Barium 06946
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Beryllium 06947
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Boron 07914
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Cadmium 06949
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Calcium 01650
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Chromium 06951
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Copper 06953
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Iron 01654
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Lead 06955
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Magnesium 01657
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Manganese 06958
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Molybdenum 06960
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Nickel 06961
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Potassium 01662
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Selenium 06936
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Silver 06966
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Sodium 01667
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Strontium 07968
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Thallium 06925
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Vanadium 06971
1Joanne M Gates05/15/2014 07:39 1413406370011SW-846 6010C Zinc 06972
1Damary Valentin05/16/2014 07:50 1413406380021SW-846 7471B Mercury 00159
1Annamaria Kuhns05/14/2014 22:24 1413406370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1Annamaria Kuhns05/15/2014 01:20 1413406380021SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Sandra J Miller05/20/2014 21:07 14140140201A1EPA 300.0 Bromide by IC (solid) 07335
1Sandra J Miller05/20/2014 21:07 14140140201A1EPA 300.0 Chloride by IC (solid) 07333
1Sandra J Miller05/20/2014 21:07 14140140201A1EPA 300.0 Sulfate by IC (solid) 07338
1Nancy J Shoop05/20/2014 08:15 14140140201A1EPA 300.0 Deionized Water
Extraction
01352
1Luz M Groff05/17/2014 13:10 14137039401A1SW-846 9045D
modified
pH 00394
1Scott W Freisher05/19/2014 19:33 14139820005A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 10 of 24
REVISED

LL Sample # TL 7462441
LL Group # 1474124
Account # 10634
Sample Description: SS-SB1(2.5-3.0)20140513 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/13/2014 11:30
Submitted: 05/14/2014 09:50
GeoSyntec Consultants
Reported: 06/16/2014 14:28
4601 Six Forks Road
Suite 340
Raleigh NC 27609
SB1-S SDG#: DUK26-06
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0056 J 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0180 J 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
0.199 J 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
N.D.17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.0366 J 17439-95-4 01757 0.0167 0.200 Magnesium
0.0014 J 17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
N.D.17440-09-7 01762 0.0980 1.00 Potassium
N.D.17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
1.36 J 17440-23-5 01767 0.167 2.00 Sodium
0.00083 J 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0028 J 17440-62-2 07071 0.0020 0.0100 Vanadium
0.0063 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Antimony 07044
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Arsenic 07035
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Barium 07046
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Beryllium 07047
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Boron 08014
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Cadmium 07049
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Calcium 01750
*=This limit was used in the evaluation of the final result
Page 11 of 24
REVISED

LL Sample # TL 7462441
LL Group # 1474124
Account # 10634
Sample Description: SS-SB1(2.5-3.0)20140513 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/13/2014 11:30
Submitted: 05/14/2014 09:50
GeoSyntec Consultants
Reported: 06/16/2014 14:28
4601 Six Forks Road
Suite 340
Raleigh NC 27609
SB1-S SDG#: DUK26-06
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Chromium 07051
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Copper 07053
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Iron 01754
1John W Yanzuk II06/04/2014 01:08 1415006360021SW-846 6010C Lead 07055
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Magnesium 01757
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Manganese 07058
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Molybdenum 07060
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Nickel 07061
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Potassium 01762
1John W Yanzuk II06/04/2014 01:08 1415006360021SW-846 6010C Selenium 07036
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Silver 07066
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Sodium 01767
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Strontium 08068
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Thallium 07022
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Vanadium 07071
1John W Yanzuk II06/02/2014 21:31 1415006360021SW-846 6010C Zinc 07072
1Parker D Lindstrom06/03/2014 17:07 1415057130071SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 09:08 1415006360021SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong06/02/2014 11:37 1415057130071SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber05/29/2014 12:00 14149-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 12 of 24
REVISED

LL Sample # SW 7462442
LL Group # 1474124
Account # 10634
Sample Description: SS-SB2(2.5-3.0)20140513 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/13/2014 15:00
Submitted: 05/14/2014 09:50
GeoSyntec Consultants
Reported: 06/16/2014 14:28
4601 Six Forks Road
Suite 340
Raleigh NC 27609
SB2-- SDG#: DUK26-07
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.729 3.94 Antimony
N.D.17440-38-2 06935 0.690 3.94 Arsenic
1.50 17440-39-3 06946 0.0325 0.985 Barium
N.D.17440-41-7 06947 0.0660 0.985 Beryllium
N.D.17440-42-8 07914 0.828 9.85 Boron
N.D.17440-43-9 06949 0.0749 0.985 Cadmium
11.9 J 17440-70-2 01650 3.29 39.4 Calcium
2.09 J 17440-47-3 06951 0.158 2.96 Chromium
0.446 J 17440-50-8 06953 0.286 1.97 Copper
1,620 17439-89-6 01654 3.57 39.4 Iron
1.71 J 17439-92-1 06955 0.493 2.96 Lead
32.2 17439-95-4 01657 1.65 19.7 Magnesium
1.93 17439-96-5 06958 0.0818 0.985 Manganese
N.D.17439-98-7 06960 0.167 1.97 Molybdenum
0.411 J 17440-02-0 06961 0.128 1.97 Nickel
30.0 J 17440-09-7 01662 8.22 98.5 Potassium
N.D.17782-49-2 06936 0.788 3.94 Selenium
N.D.17440-22-4 06966 0.167 0.985 Silver
N.D.17440-23-5 01667 16.5 197 Sodium
0.604 J 17440-24-6 07968 0.0325 0.985 Strontium
N.D.17440-28-0 06925 0.512 5.91 Thallium
3.95 17440-62-2 06971 0.128 0.985 Vanadium
1.13 J 17440-66-6 06972 0.197 3.94 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
N.D.17439-97-6 00159 0.0099 0.197 Mercury
mg/kg mg/kgmg/kgWet Chemistry EPA 300.0
N.D.124959-67-907335 4.0 5.0 Bromide by IC (solid)
N.D.116887-00-607333 5.0 10.1 Chloride by IC (solid)
9.1 J 114808-79-807338 5.0 15.1 Sulfate by IC (solid)
Std. Units Std. UnitsStd. UnitsSW-846 9045D modified
4.55 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 21.3 C.
% %%Wet Chemistry SM 2540 G-1997
2.4 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 13 of 24
REVISED

LL Sample # SW 7462442
LL Group # 1474124
Account # 10634
Sample Description: SS-SB2(2.5-3.0)20140513 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/13/2014 15:00
Submitted: 05/14/2014 09:50
GeoSyntec Consultants
Reported: 06/16/2014 14:28
4601 Six Forks Road
Suite 340
Raleigh NC 27609
SB2-- SDG#: DUK26-07
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Antimony 06944
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Arsenic 06935
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Barium 06946
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Beryllium 06947
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Boron 07914
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Cadmium 06949
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Calcium 01650
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Chromium 06951
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Copper 06953
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Iron 01654
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Lead 06955
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Magnesium 01657
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Manganese 06958
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Molybdenum 06960
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Nickel 06961
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Potassium 01662
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Selenium 06936
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Silver 06966
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Sodium 01667
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Strontium 07968
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Thallium 06925
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Vanadium 06971
1Joanne M Gates05/15/2014 07:43 1413406370011SW-846 6010C Zinc 06972
1Damary Valentin05/16/2014 07:52 1413406380021SW-846 7471B Mercury 00159
1Annamaria Kuhns05/14/2014 22:24 1413406370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1Annamaria Kuhns05/15/2014 01:20 1413406380021SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Sandra J Miller05/20/2014 21:23 14140140201A1EPA 300.0 Bromide by IC (solid) 07335
1Sandra J Miller05/20/2014 21:23 14140140201A1EPA 300.0 Chloride by IC (solid) 07333
1Sandra J Miller05/20/2014 21:23 14140140201A1EPA 300.0 Sulfate by IC (solid) 07338
1Nancy J Shoop05/20/2014 08:15 14140140201A1EPA 300.0 Deionized Water
Extraction
01352
1Luz M Groff05/17/2014 13:10 14137039401A1SW-846 9045D
modified
pH 00394
1Scott W Freisher05/19/2014 19:33 14139820005A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 14 of 24
REVISED

LL Sample # TL 7462443
LL Group # 1474124
Account # 10634
Sample Description: SS-SB2(2.5-3.0)20140513 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/13/2014 15:00
Submitted: 05/14/2014 09:50
GeoSyntec Consultants
Reported: 06/16/2014 14:28
4601 Six Forks Road
Suite 340
Raleigh NC 27609
SB2-S SDG#: DUK26-08*
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0164 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0441 J 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
0.496 17440-70-2 01750 0.0334 0.400 Calcium
0.0053 J 17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
3.87 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.183 J 17439-95-4 01757 0.0167 0.200 Magnesium
0.0036 J 17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
0.169 J 17440-09-7 01762 0.0980 1.00 Potassium
N.D.17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
5.17 17440-23-5 01767 0.167 2.00 Sodium
0.0032 J 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0106 17440-62-2 07071 0.0020 0.0100 Vanadium
0.0088 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Antimony 07044
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Arsenic 07035
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Barium 07046
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Beryllium 07047
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Boron 08014
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Cadmium 07049
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Calcium 01750
*=This limit was used in the evaluation of the final result
Page 15 of 24
REVISED

LL Sample # TL 7462443
LL Group # 1474124
Account # 10634
Sample Description: SS-SB2(2.5-3.0)20140513 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/13/2014 15:00
Submitted: 05/14/2014 09:50
GeoSyntec Consultants
Reported: 06/16/2014 14:28
4601 Six Forks Road
Suite 340
Raleigh NC 27609
SB2-S SDG#: DUK26-08*
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Chromium 07051
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Copper 07053
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Iron 01754
1John W Yanzuk II06/04/2014 01:30 1415006360021SW-846 6010C Lead 07055
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Magnesium 01757
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Manganese 07058
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Molybdenum 07060
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Nickel 07061
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Potassium 01762
1John W Yanzuk II06/04/2014 01:30 1415006360021SW-846 6010C Selenium 07036
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Silver 07066
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Sodium 01767
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Strontium 08068
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Thallium 07022
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Vanadium 07071
1John W Yanzuk II06/02/2014 22:09 1415006360021SW-846 6010C Zinc 07072
1Parker D Lindstrom06/03/2014 17:16 1415057130071SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 09:08 1415006360021SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong06/02/2014 11:37 1415057130071SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber05/29/2014 12:00 14149-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 16 of 24

Page 1 of 4
REVISED
Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1474124
Reported: 06/16/14 at 02:28 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Matrix QC may not be reported if insufficient sample or site-specific QC samples were not submitted. In these
situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise
specified in the method.

All Inorganic Initial Calibration and Continuing Calibration Blanks met acceptable method criteria unless
otherwise noted on the Analysis Report.

Laboratory Compliance Quality Control

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Batch number: 141340637001 Sample number(s): 7462436,7462438,7462440,7462442
Antimony N.D. 0.740 4.00 mg/kg 105 80-120
Arsenic N.D. 0.700 4.00 mg/kg 107 80-120
Barium N.D. 0.0330 1.00 mg/kg 101 80-120
Beryllium N.D. 0.0670 1.00 mg/kg 97 80-120
Boron N.D. 0.840 10.0 mg/kg 96 80-120
Cadmium N.D. 0.0760 1.00 mg/kg 102 80-120
Calcium 5.40 J 3.34 40.0 mg/kg 101 80-120
Chromium N.D. 0.160 3.00 mg/kg 101 80-120
Copper N.D. 0.290 2.00 mg/kg 104 80-120
Iron N.D. 3.62 40.0 mg/kg 101 80-120
Lead N.D. 0.500 3.00 mg/kg 105 80-120
Magnesium N.D. 1.67 20.0 mg/kg 99 80-120
Manganese N.D. 0.0830 1.00 mg/kg 101 80-120
Molybdenum N.D. 0.170 2.00 mg/kg 102 80-120
Nickel N.D. 0.130 2.00 mg/kg 106 80-120
Potassium N.D. 8.34 100 mg/kg 97 80-120
Selenium N.D. 0.800 4.00 mg/kg 100 80-120
Silver N.D. 0.170 1.00 mg/kg 82 80-120
Sodium N.D. 16.7 200 mg/kg 98 80-120
Strontium 0.0330 J 0.0330 1.00 mg/kg 103 80-120
Thallium N.D. 0.520 6.00 mg/kg 105 80-120
Vanadium N.D. 0.130 1.00 mg/kg 101 80-120
Zinc N.D. 0.200 4.00 mg/kg 101 80-120

Batch number: 141340638002 Sample number(s): 7462436,7462438,7462440,7462442
Mercury N.D. 0.0100 0.200 mg/kg 105 80-120

Batch number: 141360636002 Sample number(s): 7462437
Antimony N.D. 0.0053 0.0400 mg/l 107 80-120
Arsenic N.D. 0.0068 0.0400 mg/l 103 80-120
Barium N.D. 0.00033 0.0100 mg/l 105 80-120
Beryllium N.D. 0.00067 0.0100 mg/l 102 80-120
Boron N.D. 0.0084 0.100 mg/l 102 80-120
Cadmium N.D. 0.00076 0.0100 mg/l 106 80-120
Calcium 0.0388 J 0.0334 0.400 mg/l 107 80-120
Chromium N.D. 0.0016 0.0300 mg/l 104 80-120
Copper N.D. 0.0027 0.0200 mg/l 108 80-120
Iron N.D. 0.0430 0.400 mg/l 108 80-120
Lead N.D. 0.0047 0.0300 mg/l 105 80-120
Magnesium N.D. 0.0167 0.200 mg/l 104 80-120
Manganese N.D. 0.00083 0.0100 mg/l 107 80-120
Molybdenum N.D. 0.0017 0.0200 mg/l 108 80-120
Nickel N.D. 0.0015 0.0200 mg/l 110 80-120
Page 17 of 24

Page 2 of 4
REVISED
Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1474124
Reported: 06/16/14 at 02:28 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max
Potassium N.D. 0.0980 1.00 mg/l 105 80-120
Selenium N.D. 0.0084 0.0400 mg/l 106 80-120
Silver N.D. 0.0021 0.0100 mg/l 105 80-120
Sodium N.D. 0.167 2.00 mg/l 105 80-120
Strontium N.D. 0.00033 0.0100 mg/l 108 80-120
Thallium N.D. 0.0054 0.0600 mg/l 107 80-120
Zinc N.D. 0.0020 0.0400 mg/l 104 80-120

Batch number: 141365713003 Sample number(s): 7462437
Mercury N.D. 0.00006
0
0.00020 mg/l 97 80-120

Batch number: 141500636002 Sample number(s): 7462441,7462443
Antimony N.D. 0.0053 0.0400 mg/l 104 80-120
Arsenic N.D. 0.0068 0.0400 mg/l 103 80-120
Barium N.D. 0.00033 0.0100 mg/l 99 80-120
Beryllium N.D. 0.00067 0.0100 mg/l 99 80-120
Boron N.D. 0.0084 0.100 mg/l 94 80-120
Cadmium N.D. 0.00076 0.0100 mg/l 102 80-120
Calcium N.D. 0.0334 0.400 mg/l 103 80-120
Chromium N.D. 0.0016 0.0300 mg/l 100 80-120
Copper N.D. 0.0027 0.0200 mg/l 102 80-120
Iron N.D. 0.0430 0.400 mg/l 102 80-120
Lead N.D. 0.0047 0.0300 mg/l 109 80-120
Magnesium N.D. 0.0167 0.200 mg/l 100 80-120
Manganese N.D. 0.00083 0.0100 mg/l 100 80-120
Molybdenum N.D. 0.0017 0.0200 mg/l 103 80-120
Nickel N.D. 0.0015 0.0200 mg/l 106 80-120
Potassium N.D. 0.0980 1.00 mg/l 102 80-120
Selenium N.D. 0.0084 0.0400 mg/l 98 80-120
Silver N.D. 0.0021 0.0100 mg/l 104 80-120
Sodium 0.479 J 0.167 2.00 mg/l 105 80-120
Strontium N.D. 0.00033 0.0100 mg/l 101 80-120
Thallium N.D. 0.0054 0.0600 mg/l 104 80-120
Vanadium N.D. 0.0020 0.0100 mg/l 102 80-120
Zinc N.D. 0.0020 0.0400 mg/l 101 80-120

Batch number: 141505713007 Sample number(s): 7462441,7462443
Mercury N.D. 0.00006
0
0.00020 mg/l 106 80-120

Batch number: 14140140201A Sample number(s): 7462436,7462438,7462440,7462442
Bromide by IC (solid) N.D. 4.0 5.0 mg/kg 97 90-110
Chloride by IC (solid) N.D. 5.0 10.0 mg/kg 101 90-110
Sulfate by IC (solid) N.D. 5.0 15.0 mg/kg 99 90-110

Batch number: 14137039401A Sample number(s): 7462436,7462438,7462440,7462442
pH 99 90-110

Batch number: 14139820005A Sample number(s): 7462436,7462438,7462440,7462442
Moisture 100 99-101

Sample Matrix Quality Control
Page 18 of 24

Page 3 of 4
REVISED
Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1474124
Reported: 06/16/14 at 02:28 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 141340637001 Sample number(s): 7462436,7462438,7462440,7462442 UNSPK: P462380 BKG: P462380
Antimony 98 83 75-125 17 20 N.D. N.D. 0 (1) 20
Arsenic 94 60* 75-125 32* 20 4.23 0.955 J 126* (1) 20
Barium 98 109 75-125 9 20 31.6 41.6 27* 20
Beryllium 95 102 83-119 6 20 0.370 J 0.419 J 12 (1) 20
Boron 105 101 84-110 4 20 1.33 J 6.53 J 132* (1) 20
Cadmium 90 69* 75-120 23* 20 0.603 J 0.651 J 8 (1) 20
Calcium 7248
(2)
2566
(2)
75-125 13 20 120,000 138,000 14 20
Chromium 248* 1226* 75-125 91* 20 66.4 168 87* 20
Copper 35* 91 75-125 24* 20 43.3 33.3 26* 20
Iron -6213
(2)
26837
(2)
75-125 104* 20 21,400 25,100 16 20
Lead -89 (2) 480 (2) 75-125 71* 20 90.1 131 37* 20
Magnesium 7920
(2)
-4467
(2)
75-125 35* 20 66,500 64,700 3 20
Manganese 326 (2) 6223
(2)
75-125 114* 20 950 2,230 81* 20
Molybdenum 98 101 82-110 2 20 1.43 J 1.76 J 21* (1) 20
Nickel 79 85 75-125 5 20 13.5 11.4 17 20
Potassium 139* 141* 75-125 1 20 876 1,040 17 20
Selenium 106 134* 75-125 22* 20 1.25 J 1.01 J 22* (1) 20
Silver 72* 40* 75-125 58* 20 N.D. N.D. 0 (1) 20
Sodium 107 114 75-125 5 20 119 J 148 J 22* (1) 20
Strontium 94 118 81-125 15 20 48.4 63.2 26* 20
Thallium 75* 60* 78-119 23* 20 N.D. N.D. 0 (1) 20
Vanadium 161* 487* 75-125 81* 20 39.2 125 105* 20
Zinc 54* 192* 75-125 35* 20 134 173 25* 20

Batch number: 141340638002 Sample number(s): 7462436,7462438,7462440,7462442 UNSPK: 7462438 BKG: 7462438
Mercury 110 105 80-120 5 20 N.D. N.D. 0 (1) 20

Batch number: 141360636002 Sample number(s): 7462437 UNSPK: P459367 BKG: P459367
Antimony 95 96 75-125 1 20 N.D. N.D. 0 (1) 20
Arsenic 96 97 75-125 1 20 0.0699 0.0702 0 (1) 20
Barium 92 94 75-125 2 20 0.143 0.144 1 20
Beryllium 90 91 75-125 2 20 N.D. N.D. 0 (1) 20
Boron 94 96 75-125 2 20 0.0644 J 0.0635 J 1 (1) 20
Cadmium 92 92 75-125 0 20 N.D. N.D. 0 (1) 20
Calcium 94 94 75-125 1 20 4.87 4.94 1 20
Chromium 92 93 75-125 2 20 0.0032 J 0.0036 J 11 (1) 20
Copper 95 97 75-125 2 20 0.0028 J 0.0029 J 2 (1) 20
Iron 93 94 75-125 1 20 0.0983 J 0.107 J 8 (1) 20
Lead 90 91 75-125 0 20 N.D. N.D. 0 (1) 20
Magnesium 93 94 75-125 1 20 0.531 0.541 2 (1) 20
Manganese 93 94 75-125 2 20 0.0061 J 0.0062 J 1 (1) 20
Molybdenum 93 94 75-125 1 20 0.0189 J 0.0161 J 16 (1) 20
Nickel 91 91 75-125 0 20 0.0038 J 0.0037 J 5 (1) 20
Potassium 95 96 75-125 1 20 0.460 J 0.497 J 8 (1) 20
Selenium 95 96 75-125 1 20 N.D. 0.0092 J 200* (1) 20
Silver 65* 79 75-125 20 20 N.D. N.D. 0 (1) 20
Sodium 94 94 75-125 0 20 1.83 J 1.83 J 0 (1) 20
Page 19 of 24

Page 4 of 4
REVISED
Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1474124
Reported: 06/16/14 at 02:28 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___
Strontium 93 94 75-125 1 20 0.265 0.269 1 20
Thallium 91 91 75-125 1 20 N.D. N.D. 0 (1) 20
Zinc 93 93 75-125 1 20 N.D. N.D. 0 (1) 20

Batch number: 141365713003 Sample number(s): 7462437 UNSPK: P459367 BKG: P459367
Mercury 79* 80 80-120 1 20 N.D. N.D. 0 (1) 20

Batch number: 141500636002 Sample number(s): 7462441,7462443 UNSPK: 7462441 BKG: 7462441
Antimony 90 91 75-125 1 20 N.D. N.D. 0 (1) 20
Arsenic 90 91 75-125 1 20 N.D. N.D. 0 (1) 20
Barium 87 96 75-125 9 20 0.0056 J 0.0055 J 0 (1) 20
Beryllium 87 86 75-125 0 20 N.D. N.D. 0 (1) 20
Boron 86 87 75-125 1 20 0.0180 J 0.0145 J 21* (1) 20
Cadmium 87 88 75-125 1 20 N.D. N.D. 0 (1) 20
Calcium 91 92 75-125 1 20 0.199 J 0.177 J 12 (1) 20
Chromium 87 88 75-125 1 20 N.D. N.D. 0 (1) 20
Copper 89 89 75-125 0 20 N.D. N.D. 0 (1) 20
Iron 89 89 75-125 0 20 N.D. N.D. 0 (1) 20
Lead 85 86 75-125 0 20 N.D. N.D. 0 (1) 20
Magnesium 89 90 75-125 1 20 0.0366 J 0.0374 J 2 (1) 20
Manganese 87 88 75-125 1 20 0.0014 J 0.0013 J 8 (1) 20
Molybdenum 89 90 75-125 1 20 N.D. N.D. 0 (1) 20
Nickel 86 87 75-125 1 20 N.D. N.D. 0 (1) 20
Potassium 93 94 75-125 1 20 N.D. N.D. 0 (1) 20
Selenium 88 88 75-125 1 20 N.D. N.D. 0 (1) 20
Silver 76 77 75-125 1 20 N.D. N.D. 0 (1) 20
Sodium 91 91 75-125 1 20 1.36 J 1.37 J 0 (1) 20
Strontium 84 84 75-125 0 20 0.00083 J 0.00074 J 11 (1) 20
Thallium 83 84 75-125 1 20 N.D. N.D. 0 (1) 20
Vanadium 90 90 75-125 0 20 0.0028 J 0.0030 J 8 (1) 20
Zinc 87 88 75-125 1 20 0.0063 J 0.0050 J 23* (1) 20

Batch number: 141505713007 Sample number(s): 7462441,7462443 UNSPK: 7462441 BKG: 7462441
Mercury 82 82 80-120 0 20 N.D. N.D. 0 (1) 20

Batch number: 14140140201A Sample number(s): 7462436,7462438,7462440,7462442 UNSPK: P459366 BKG: P459366
Bromide by IC (solid) 91 90-110 N.D. N.D. 0 (1) 20
Chloride by IC (solid) 84* 90-110 18.8 18.5 2 (1) 20
Sulfate by IC (solid) 87* 90-110 43.3 42.6 2 (1) 20

Batch number: 14137039401A Sample number(s): 7462436,7462438,7462440,7462442 BKG: P464348
pH 5.59 5.64 1 3

Batch number: 14139820005A Sample number(s): 7462436,7462438,7462440,7462442 BKG: P463166
Moisture 24.1 25.5 6* 5

Page 20 of 24
Page 21 of 24
Page 22 of 24
Page 23 of 24
Explanation of Symbols and Abbreviations

3768 0713
The following defines common symbols and abbreviations used in reporting technical data:
RL Reporting Limit BMQL Below Minimum Quantitation Level
N.D. none detected MPN Most Probable Number
TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units
IU International Units NTU nephelometric turbidity units
umhos/cm micromhos/cm ng nanogram(s)
C degrees Celsius F degrees Fahrenheit
meq milliequivalents lb. pound(s)
g gram(s) kg kilogram(s)
µg microgram(s) mg milligram(s)
mL milliliter(s) L liter(s)
m3 cubic meter(s) µL microliter(s)
pg/L picogram/liter
< less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be
reliably determined using this specific test.
> greater than
ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For
aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/l), because one liter of water has a
weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter per liter of gas.
ppb parts per billion
Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight
basis concentration to approximate the value present in a similar sample without moisture. All other results are reported
on an as-received basis.
Data Qualifiers:
C – result confirmed by reanalysis.
J - estimated value – The result is ≥ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ).
U.S. EPA CLP Data Qualifiers:
Organic Qualifiers Inorganic Qualifiers
A TIC is a possible aldol-condensation product B Value is <CRDL, but ≥IDL
B Analyte was also detected in the blank E Estimated due to interference
C Pesticide result confirmed by GC/MS M Duplicate injection precision not met
D Compound quantitated on a diluted sample N Spike sample not within control limits
E Concentration exceeds the calibration range of S Method of standard additions (MSA) used
the instrument for calculation
N Presumptive evidence of a compound (TICs only) U Compound was not detected
P Concentration difference between primary and W Post digestion spike out of control limits
confirmation columns >25% * Duplicate analysis not within control limits
U Compound was not detected + Correlation coefficient for MSA <0.995
X,Y,Z Defined in case narrative
Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.
Measurement uncertainty values, as applicable, are available upon request.
Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the
test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact
us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our
staff. This report shall not be reproduced except in full, without the written approval of the laboratory.
Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as “analyze immediately” are not
performed within 15 minutes.

WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE
FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM
ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF
MERCHANTABILITY. IN NO EVENT SHALL EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL, LLC BE LIABLE FOR INDIRECT, SPECIAL,
CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS
OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL AND (B) WHETHER
EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal
responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Eurofins Lancaster
Laboratories Environmental which includes any conditions that vary from the Standard Terms and Conditions, and Eurofins Lancaster Laboratories
Environmental hereby objects to any conflicting terms contained in any acceptance or order submitted by client.
Page 24 of 24

ANALYTICAL RESULTS

Prepared by:

Eurofins Lancaster Laboratories Environmental
2425 New Holland Pike
Lancaster, PA 17601
Prepared for:

GeoSyntec Consultants
4601 Six Forks Road
Suite 340
Raleigh NC 27609

June 03, 2014

Project: Duke Sutton, NC

Submittal Date: 05/21/2014
Group Number: 1475873
SDG: DUK27
PO Number: GC5592
State of Sample Origin: NC

Client Sample Description Lancaster Labs (LL) #
PZ-INT-20140520 Water Sample 7471432

The specific methodologies used in obtaining the enclosed analytical results are indicated on the
Laboratory Sample Analysis Record.

ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Lauren Wellborn
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Beau Hodge
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Rachel Donahue
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Herwig Goldemund

Respectfully Submitted,

[phone]

Page 1 of 9

Page 2 of 9

LL Sample # WW 7471432
LL Group # 1475873
Account # 10634
Sample Description: PZ-INT-20140520 Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 15:35
Submitted: 05/21/2014 09:50
GeoSyntec Consultants
Reported: 06/03/2014 06:20
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSPZI SDG#: DUK27-01*
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
0.275 17440-38-2 07035 0.0068 0.0400 Arsenic
0.925 17440-39-3 07046 0.00033 0.0100 Barium
0.0069 J 17440-41-7 07047 0.00067 0.0100 Beryllium
4.26 107440-42-8 08014 0.0840 1.00 Boron
0.00080 J 17440-43-9 07049 0.00076 0.0100 Cadmium
122 17440-70-2 01750 0.0334 0.400 Calcium
0.0256 J 17440-47-3 07051 0.0016 0.0300 Chromium
0.0913 17440-50-8 07053 0.0027 0.0200 Copper
9.57 17439-89-6 01754 0.0430 0.400 Iron
0.0294 J 17439-92-1 07055 0.0047 0.0300 Lead
38.6 17439-95-4 01757 0.0167 0.200 Magnesium
0.184 17439-96-5 07058 0.00083 0.0100 Manganese
0.0703 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0637 17440-02-0 07061 0.0015 0.0200 Nickel
18.6 17440-09-7 01762 0.0980 1.00 Potassium
0.0134 J 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
41.1 17440-23-5 01767 0.167 2.00 Sodium
7.24 107440-24-6 08068 0.0033 0.100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.129 17440-62-2 07071 0.0020 0.0100 Vanadium
0.0723 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
83.4 2016887-00-600224 4.0 8.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
73.2 514808-79-800228 1.5 5.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
335 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
631 1n.a. 00212 19.4 60.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 3 of 9

LL Sample # WW 7471432
LL Group # 1475873
Account # 10634
Sample Description: PZ-INT-20140520 Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 15:35
Submitted: 05/21/2014 09:50
GeoSyntec Consultants
Reported: 06/03/2014 06:20
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSPZI SDG#: DUK27-01*
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Antimony 07044
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Arsenic 07035
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Barium 07046
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Beryllium 07047
10Eric L Eby05/30/2014 08:47 1414706350011SW-846 6010C Boron 08014
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Cadmium 07049
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Calcium 01750
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Chromium 07051
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Copper 07053
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Iron 01754
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Lead 07055
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Magnesium 01757
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Manganese 07058
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Molybdenum 07060
1Katlin N Cataldi06/02/2014 19:46 1415106350011SW-846 6010C Nickel 07061
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Potassium 01762
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Selenium 07036
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Silver 07066
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Sodium 01767
10Eric L Eby05/30/2014 08:47 1414706350011SW-846 6010C Strontium 08068
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Thallium 07022
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Vanadium 07071
1Eric L Eby05/29/2014 13:00 1414706350011SW-846 6010C Zinc 07072
1Damary Valentin05/23/2014 10:29 1414157130021SW-846 7470A Mercury 00259
1Micaela L Dishong05/28/2014 10:00 1414706350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong06/02/2014 10:04 1415106350012SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong05/22/2014 12:58 1414157130021SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/22/2014 00:42 14141373601A1EPA 300.0 Bromide 01505
20Sandra J Miller05/22/2014 09:07 14141373601A1EPA 300.0 Chloride 00224
5Sandra J Miller05/22/2014 00:42 14141373601A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/22/2014 00:42 14141373601A1EPA 300.0 Nitrite Nitrogen 01506
5Sandra J Miller05/22/2014 00:42 14141373601A1EPA 300.0 Sulfate 00228
1Michele L Graham05/22/2014 18:28 14142002103A1EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch05/23/2014 08:43 14143021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 4 of 9

Page 1 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1475873
Reported: 06/03/14 at 06:20 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Matrix QC may not be reported if insufficient sample or site-specific QC samples were not submitted. In these
situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise
specified in the method.

All Inorganic Initial Calibration and Continuing Calibration Blanks met acceptable method criteria unless
otherwise noted on the Analysis Report.

Laboratory Compliance Quality Control

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Batch number: 141415713002 Sample number(s): 7471432
Mercury N.D. 0.00006
0
0.00020 mg/l 98 80-120

Batch number: 141470635001 Sample number(s): 7471432
Antimony N.D. 0.0053 0.0400 mg/l 107 88-111
Arsenic N.D. 0.0068 0.0400 mg/l 108 90-113
Barium N.D. 0.00033 0.0100 mg/l 106 90-110
Beryllium N.D. 0.00067 0.0100 mg/l 104 90-111
Boron N.D. 0.0084 0.100 mg/l 98 90-110
Cadmium N.D. 0.00076 0.0100 mg/l 110 90-112
Calcium N.D. 0.0334 0.400 mg/l 107 90-112
Chromium N.D. 0.0016 0.0300 mg/l 104 90-110
Copper N.D. 0.0027 0.0200 mg/l 108 90-112
Iron N.D. 0.0430 0.400 mg/l 108 90-112
Lead N.D. 0.0047 0.0300 mg/l 115 88-116
Magnesium N.D. 0.0167 0.200 mg/l 105 89-110
Manganese N.D. 0.00083 0.0100 mg/l 107 90-110
Molybdenum N.D. 0.0017 0.0200 mg/l 108 90-110
Potassium N.D. 0.0980 1.00 mg/l 103 90-110
Selenium N.D. 0.0084 0.0400 mg/l 110 89-113
Silver N.D. 0.0021 0.0100 mg/l 114 80-120
Sodium N.D. 0.167 2.00 mg/l 105 87-114
Strontium N.D. 0.00033 0.0100 mg/l 107 90-110
Thallium N.D. 0.0054 0.0600 mg/l 112 90-118
Vanadium N.D. 0.0020 0.0100 mg/l 106 90-110
Zinc 0.0024 J 0.0020 0.0400 mg/l 110 90-110

Batch number: 141510635001 Sample number(s): 7471432
Nickel N.D. 0.0015 0.0200 mg/l 110 90-111

Batch number: 14141373601A Sample number(s): 7471432
Bromide N.D. 0.40 0.50 mg/l 96 96 90-110 0 20
Chloride N.D. 0.20 0.40 mg/l 103 98 90-110 5 20
Nitrate Nitrogen N.D. 0.050 0.10 mg/l 99 99 90-110 0 20
Nitrite Nitrogen N.D. 0.080 0.10 mg/l 96 95 90-110 1 20
Sulfate N.D. 0.30 1.0 mg/l 100 97 90-110 3 20

Batch number: 14142002103A Sample number(s): 7471432
Total Alkalinity N.D. 0.70 2.0 mg/l as
CaCO3
96 90-110

Batch number: 14143021201A Sample number(s): 7471432
Total Dissolved Solids N.D. 9.7 30.0 mg/l 105 80-120
Page 5 of 9

Page 2 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1475873
Reported: 06/03/14 at 06:20 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 141415713002 Sample number(s): 7471432 UNSPK: P470904 BKG: P470904
Mercury 119 103 80-120 15 20 N.D. N.D. 0 (1) 20

Batch number: 141470635001 Sample number(s): 7471432 UNSPK: P473019 BKG: P473019
Antimony 105 108 76-122 3 20 N.D. N.D. 0 (1) 20
Arsenic 107 110 81-123 3 20 N.D. N.D. 0 (1) 20
Barium 100 104 78-125 4 20 0.153 0.167 9 20
Beryllium 101 104 87-114 3 20 N.D. N.D. 0 (1) 20
Boron 96 99 87-111 3 20 0.528 0.574 8 20
Cadmium 105 108 75-122 2 20 N.D. N.D. 0 (1) 20
Calcium 78 (2) 113 (2) 75-125 3 20 44.1 43.8 1 20
Chromium 100 103 76-120 3 20 N.D. N.D. 0 (1) 20
Copper 103 107 86-122 3 20 N.D. N.D. 0 (1) 20
Iron 104 110 75-125 4 20 0.276 J 0.287 J 4 (1) 20
Lead 109 112 75-125 3 20 N.D. N.D. 0 (1) 20
Magnesium 90 105 81-118 3 20 6.83 6.75 1 20
Manganese 101 105 75-125 4 20 0.0016 J 0.0019 J 13 (1) 20
Molybdenum 104 108 89-117 3 20 0.132 0.129 2 20
Potassium 100 107 77-128 3 20 10.9 10.8 0 20
Selenium 99 103 75-125 3 20 0.0268 J 0.0261 J 2 (1) 20
Silver 107 111 75-125 4 20 N.D. N.D. 0 (1) 20
Sodium 94 (2) 107 (2) 84-117 2 20 46.3 45.8 1 20
Strontium 100 104 88-117 3 20 0.546 0.597 9 20
Thallium 104 107 75-125 3 20 N.D. N.D. 0 (1) 20
Vanadium 103 106 90-117 3 20 0.0023 J 0.0025 J 9 (1) 20
Zinc 105 108 85-117 3 20 0.0077 J 0.0059 J 27* (1) 20

Batch number: 141510635001 Sample number(s): 7471432 UNSPK: P479329 BKG: P479329
Nickel 108 107 79-123 2 20 N.D. N.D. 0 (1) 20

Batch number: 14141373601A Sample number(s): 7471432 UNSPK: P471371 BKG: P471371
Bromide 86* 90-110 N.D. N.D. 0 (1) 20
Chloride 85* 90-110 5.1 4.3 19 (1) 20
Nitrate Nitrogen 87* 90-110 1.0 1.1 7 (1) 20
Nitrite Nitrogen 85* 90-110 N.D. N.D. 0 (1) 20
Sulfate 90 90-110 15.7 16.6 6 (1) 20

Batch number: 14142002103A Sample number(s): 7471432 UNSPK: P466063 BKG: P466063
Total Alkalinity 94 95 17-146 1 5 20.7 20.9 1 5

Batch number: 14143021201A Sample number(s): 7471432 UNSPK: P473019 BKG: P473019
Total Dissolved Solids 98 66-131 316 311 2 5

Page 6 of 9

Page 3 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1475873
Reported: 06/03/14 at 06:20 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Page 7 of 9
Page 8 of 9
Explanation of Symbols and Abbreviations

3768 0713
The following defines common symbols and abbreviations used in reporting technical data:
RL Reporting Limit BMQL Below Minimum Quantitation Level
N.D. none detected MPN Most Probable Number
TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units
IU International Units NTU nephelometric turbidity units
umhos/cm micromhos/cm ng nanogram(s)
C degrees Celsius F degrees Fahrenheit
meq milliequivalents lb. pound(s)
g gram(s) kg kilogram(s)
µg microgram(s) mg milligram(s)
mL milliliter(s) L liter(s)
m3 cubic meter(s) µL microliter(s)
pg/L picogram/liter
< less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be
reliably determined using this specific test.
> greater than
ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For
aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/l), because one liter of water has a
weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter per liter of gas.
ppb parts per billion
Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight
basis concentration to approximate the value present in a similar sample without moisture. All other results are reported
on an as-received basis.
Data Qualifiers:
C – result confirmed by reanalysis.
J - estimated value – The result is ≥ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ).
U.S. EPA CLP Data Qualifiers:
Organic Qualifiers Inorganic Qualifiers
A TIC is a possible aldol-condensation product B Value is <CRDL, but ≥IDL
B Analyte was also detected in the blank E Estimated due to interference
C Pesticide result confirmed by GC/MS M Duplicate injection precision not met
D Compound quantitated on a diluted sample N Spike sample not within control limits
E Concentration exceeds the calibration range of S Method of standard additions (MSA) used
the instrument for calculation
N Presumptive evidence of a compound (TICs only) U Compound was not detected
P Concentration difference between primary and W Post digestion spike out of control limits
confirmation columns >25% * Duplicate analysis not within control limits
U Compound was not detected + Correlation coefficient for MSA <0.995
X,Y,Z Defined in case narrative
Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.
Measurement uncertainty values, as applicable, are available upon request.
Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the
test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact
us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our
staff. This report shall not be reproduced except in full, without the written approval of the laboratory.
Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as “analyze immediately” are not
performed within 15 minutes.

WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE
FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM
ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF
MERCHANTABILITY. IN NO EVENT SHALL EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL, LLC BE LIABLE FOR INDIRECT, SPECIAL,
CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS
OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL AND (B) WHETHER
EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal
responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Eurofins Lancaster
Laboratories Environmental which includes any conditions that vary from the Standard Terms and Conditions, and Eurofins Lancaster Laboratories
Environmental hereby objects to any conflicting terms contained in any acceptance or order submitted by client.
Page 9 of 9

ANALYTICAL RESULTS

Prepared by:

Eurofins Lancaster Laboratories Environmental
2425 New Holland Pike
Lancaster, PA 17601
Prepared for:

GeoSyntec Consultants
4601 Six Forks Road
Suite 340
Raleigh NC 27609

June 01, 2014

Project: Duke Sutton, NC

Submittal Date: 05/22/2014
Group Number: 1476292
SDG: DUK28
PO Number: GC5592
State of Sample Origin: NC

Client Sample Description Lancaster Labs (LL) #
MW-36C-20140521 Water Sample 7473017
MW-936C-20140521 Water Sample 7473018
MW-36B-20140521 Water Sample 7473019
MW-36B-20140521MS Water Sample 7473020
MW-36B-20140521MSD Water Sample 7473021
MW-36B-20140521DUP Water Sample 7473022
MW-6B-20140521 Water Sample 7473023
MW-6C-20140521 Water Sample 7473024

The specific methodologies used in obtaining the enclosed analytical results are indicated on the
Laboratory Sample Analysis Record.

ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Lauren Wellborn
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Beau Hodge
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Rachel Donahue
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Herwig Goldemund

Page 1 of 23

Respectfully Submitted,

[phone]

Page 2 of 23

LL Sample # WW 7473017
LL Group # 1476292
Account # 10634
Sample Description: MW-36C-20140521 Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 12:30
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS36C SDG#: DUK28-01
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0337 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.522 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
32.1 17440-70-2 01750 0.0334 0.400 Calcium
0.0019 J 17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.877 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
5.82 17439-95-4 01757 0.0167 0.200 Magnesium
0.558 17439-96-5 07058 0.00083 0.0100 Manganese
0.0133 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
10.8 17440-09-7 01762 0.0980 1.00 Potassium
0.0357 J 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
61.6 57440-23-5 01767 0.835 10.0 Sodium
0.324 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0039 J 17440-62-2 07071 0.0020 0.0100 Vanadium
0.0135 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
54.8 2016887-00-600224 4.0 8.0 Chloride
0.35 J 514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
117 2014808-79-800228 6.0 20.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
41.0 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
327 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 3 of 23

LL Sample # WW 7473017
LL Group # 1476292
Account # 10634
Sample Description: MW-36C-20140521 Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 12:30
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS36C SDG#: DUK28-01
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Antimony 07044
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Arsenic 07035
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Barium 07046
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Beryllium 07047
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Boron 08014
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Cadmium 07049
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Calcium 01750
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Chromium 07051
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Copper 07053
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Iron 01754
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Lead 07055
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Magnesium 01757
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Manganese 07058
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Molybdenum 07060
1Eric L Eby05/30/2014 08:54 1414706350011SW-846 6010C Nickel 07061
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Potassium 01762
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Selenium 07036
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Silver 07066
5Katlin N Cataldi05/30/2014 17:46 1414706350011SW-846 6010C Sodium 01767
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Strontium 08068
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Thallium 07022
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Vanadium 07071
1Eric L Eby05/29/2014 13:05 1414706350011SW-846 6010C Zinc 07072
1Damary Valentin05/29/2014 08:46 1414757130021SW-846 7470A Mercury 00259
1Micaela L Dishong05/28/2014 10:00 1414706350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong05/28/2014 11:32 1414757130021SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/23/2014 03:10 14142347602A1EPA 300.0 Bromide 01505
20Sandra J Miller05/23/2014 20:08 14142347602A1EPA 300.0 Chloride 00224
5Sandra J Miller05/23/2014 03:10 14142347602A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/23/2014 03:10 14142347602A1EPA 300.0 Nitrite Nitrogen 01506
20Sandra J Miller05/23/2014 20:08 14142347602A1EPA 300.0 Sulfate 00228
1Kenneth A Bell05/24/2014 15:18 14144002102A1EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch05/23/2014 08:43 14143021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 4 of 23

LL Sample # WW 7473018
LL Group # 1476292
Account # 10634
Sample Description: MW-936C-20140521 Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 12:30
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS936 SDG#: DUK28-02
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0336 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.519 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
32.0 17440-70-2 01750 0.0334 0.400 Calcium
0.0024 J 17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.765 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
5.82 17439-95-4 01757 0.0167 0.200 Magnesium
0.559 17439-96-5 07058 0.00083 0.0100 Manganese
0.0130 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0016 J 17440-02-0 07061 0.0015 0.0200 Nickel
10.6 17440-09-7 01762 0.0980 1.00 Potassium
0.0363 J 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
61.0 57440-23-5 01767 0.835 10.0 Sodium
0.325 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0035 J 17440-62-2 07071 0.0020 0.0100 Vanadium
0.0117 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
54.5 2016887-00-600224 4.0 8.0 Chloride
0.31 J 514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
115 2014808-79-800228 6.0 20.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
40.5 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
324 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 5 of 23

LL Sample # WW 7473018
LL Group # 1476292
Account # 10634
Sample Description: MW-936C-20140521 Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 12:30
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS936 SDG#: DUK28-02
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Antimony 07044
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Arsenic 07035
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Barium 07046
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Beryllium 07047
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Boron 08014
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Cadmium 07049
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Calcium 01750
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Chromium 07051
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Copper 07053
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Iron 01754
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Lead 07055
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Magnesium 01757
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Manganese 07058
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Molybdenum 07060
1Katlin N Cataldi05/30/2014 17:50 1414706350012SW-846 6010C Nickel 07061
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Potassium 01762
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Selenium 07036
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Silver 07066
5Katlin N Cataldi05/30/2014 17:54 1414706350011SW-846 6010C Sodium 01767
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Strontium 08068
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Thallium 07022
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Vanadium 07071
1Eric L Eby05/29/2014 13:17 1414706350011SW-846 6010C Zinc 07072
1Damary Valentin05/29/2014 08:49 1414757130021SW-846 7470A Mercury 00259
1Micaela L Dishong05/28/2014 10:00 1414706350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong05/28/2014 11:32 1414757130021SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/23/2014 03:26 14142347602A1EPA 300.0 Bromide 01505
20Sandra J Miller05/23/2014 20:24 14142347602A1EPA 300.0 Chloride 00224
5Sandra J Miller05/23/2014 03:26 14142347602A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/23/2014 03:26 14142347602A1EPA 300.0 Nitrite Nitrogen 01506
20Sandra J Miller05/23/2014 20:24 14142347602A1EPA 300.0 Sulfate 00228
1Kenneth A Bell05/24/2014 15:50 14144002102B2EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch05/23/2014 08:43 14143021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 6 of 23

LL Sample # WW 7473019
LL Group # 1476292
Account # 10634
Sample Description: MW-36B-20140521 Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 13:47
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS36B SDG#: DUK28-03BKG
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.153 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.528 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
44.1 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.276 J 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
6.83 17439-95-4 01757 0.0167 0.200 Magnesium
0.0016 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.132 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
10.9 17440-09-7 01762 0.0980 1.00 Potassium
0.0268 J 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
46.3 17440-23-5 01767 0.167 2.00 Sodium
0.546 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0023 J 17440-62-2 07071 0.0020 0.0100 Vanadium
0.0077 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
51.9 2016887-00-600224 4.0 8.0 Chloride
0.63 514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
90.4 2014808-79-800228 6.0 20.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
72.4 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
316 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 7 of 23

LL Sample # WW 7473019
LL Group # 1476292
Account # 10634
Sample Description: MW-36B-20140521 Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 13:47
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS36B SDG#: DUK28-03BKG
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Antimony 07044
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Arsenic 07035
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Barium 07046
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Beryllium 07047
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Boron 08014
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Cadmium 07049
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Calcium 01750
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Chromium 07051
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Copper 07053
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Iron 01754
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Lead 07055
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Magnesium 01757
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Manganese 07058
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Molybdenum 07060
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Nickel 07061
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Potassium 01762
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Selenium 07036
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Silver 07066
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Sodium 01767
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Strontium 08068
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Thallium 07022
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Vanadium 07071
1Eric L Eby05/29/2014 11:45 1414706350011SW-846 6010C Zinc 07072
1Damary Valentin05/29/2014 08:51 1414757130021SW-846 7470A Mercury 00259
1Micaela L Dishong05/28/2014 10:00 1414706350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong05/28/2014 11:32 1414757130021SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/23/2014 01:49 14142347602A1EPA 300.0 Bromide 01505
20Sandra J Miller05/23/2014 18:47 14142347602A1EPA 300.0 Chloride 00224
5Sandra J Miller05/23/2014 01:49 14142347602A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/23/2014 01:49 14142347602A1EPA 300.0 Nitrite Nitrogen 01506
20Sandra J Miller05/23/2014 18:47 14142347602A1EPA 300.0 Sulfate 00228
1Kenneth A Bell05/24/2014 13:39 14144002102A1EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch05/23/2014 08:43 14143021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 8 of 23

LL Sample # WW 7473020
LL Group # 1476292
Account # 10634
Sample Description: MW-36B-20140521MS Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 13:47
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS36B SDG#: DUK28-03MS
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.524 17440-36-0 07044 0.0053 0.0400 Antimony
0.160 17440-38-2 07035 0.0068 0.0400 Arsenic
2.15 17440-39-3 07046 0.00033 0.0100 Barium
0.0504 17440-41-7 07047 0.00067 0.0100 Beryllium
2.45 17440-42-8 08014 0.0084 0.100 Boron
0.0526 17440-43-9 07049 0.00076 0.0100 Cadmium
47.3 17440-70-2 01750 0.0334 0.400 Calcium
0.200 17440-47-3 07051 0.0016 0.0300 Chromium
0.259 17440-50-8 07053 0.0027 0.0200 Copper
1.32 17439-89-6 01754 0.0430 0.400 Iron
0.163 17439-92-1 07055 0.0047 0.0300 Lead
8.63 17439-95-4 01757 0.0167 0.200 Magnesium
0.509 17439-96-5 07058 0.00083 0.0100 Manganese
2.22 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.545 17440-02-0 07061 0.0015 0.0200 Nickel
20.9 17440-09-7 01762 0.0980 1.00 Potassium
0.176 17782-49-2 07036 0.0084 0.0400 Selenium
0.0537 17440-22-4 07066 0.0021 0.0100 Silver
55.7 17440-23-5 01767 0.167 2.00 Sodium
1.55 17440-24-6 08068 0.00033 0.0100 Strontium
0.155 17440-28-0 07022 0.0054 0.0600 Thallium
0.519 17440-62-2 07071 0.0020 0.0100 Vanadium
0.530 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
0.00094 17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
52.0 1024959-67-901505 4.0 5.0 Bromide
145 5016887-00-600224 10.0 20.0 Chloride
11.1 1014797-55-800368 0.50 1.0 Nitrate Nitrogen
9.9 1014797-65-001506 0.80 1.0 Nitrite Nitrogen
148 1014808-79-800228 3.0 10.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
215 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
511 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 9 of 23

LL Sample # WW 7473020
LL Group # 1476292
Account # 10634
Sample Description: MW-36B-20140521MS Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 13:47
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS36B SDG#: DUK28-03MS
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Antimony 07044
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Arsenic 07035
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Barium 07046
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Beryllium 07047
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Boron 08014
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Cadmium 07049
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Calcium 01750
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Chromium 07051
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Copper 07053
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Iron 01754
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Lead 07055
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Magnesium 01757
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Manganese 07058
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Molybdenum 07060
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Nickel 07061
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Potassium 01762
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Selenium 07036
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Silver 07066
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Sodium 01767
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Strontium 08068
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Thallium 07022
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Vanadium 07071
1Eric L Eby05/29/2014 11:57 1414706350011SW-846 6010C Zinc 07072
1Damary Valentin05/29/2014 08:55 1414757130021SW-846 7470A Mercury 00259
1Micaela L Dishong05/28/2014 10:00 1414706350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong05/28/2014 11:32 1414757130021SW-846 7470A WW SW846 Hg Digest 05713
10Sandra J Miller05/23/2014 02:54 14142347602A1EPA 300.0 Bromide 01505
50Sandra J Miller05/23/2014 19:20 14142347602A1EPA 300.0 Chloride 00224
10Sandra J Miller05/23/2014 02:54 14142347602A1EPA 300.0 Nitrate Nitrogen 00368
10Sandra J Miller05/23/2014 02:54 14142347602A1EPA 300.0 Nitrite Nitrogen 01506
10Sandra J Miller05/23/2014 02:54 14142347602A1EPA 300.0 Sulfate 00228
1Kenneth A Bell05/24/2014 13:45 14144002102A1EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch05/23/2014 08:43 14143021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 10 of 23

LL Sample # WW 7473021
LL Group # 1476292
Account # 10634
Sample Description: MW-36B-20140521MSD Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 13:47
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS36B SDG#: DUK28-03MSD
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.539 17440-36-0 07044 0.0053 0.0400 Antimony
0.165 17440-38-2 07035 0.0068 0.0400 Arsenic
2.23 17440-39-3 07046 0.00033 0.0100 Barium
0.0520 17440-41-7 07047 0.00067 0.0100 Beryllium
2.51 17440-42-8 08014 0.0084 0.100 Boron
0.0538 17440-43-9 07049 0.00076 0.0100 Cadmium
48.6 17440-70-2 01750 0.0334 0.400 Calcium
0.206 17440-47-3 07051 0.0016 0.0300 Chromium
0.267 17440-50-8 07053 0.0027 0.0200 Copper
1.37 17439-89-6 01754 0.0430 0.400 Iron
0.168 17439-92-1 07055 0.0047 0.0300 Lead
8.93 17439-95-4 01757 0.0167 0.200 Magnesium
0.527 17439-96-5 07058 0.00083 0.0100 Manganese
2.29 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.562 17440-02-0 07061 0.0015 0.0200 Nickel
21.6 17440-09-7 01762 0.0980 1.00 Potassium
0.181 17782-49-2 07036 0.0084 0.0400 Selenium
0.0556 17440-22-4 07066 0.0021 0.0100 Silver
57.0 17440-23-5 01767 0.167 2.00 Sodium
1.59 17440-24-6 08068 0.00033 0.0100 Strontium
0.160 17440-28-0 07022 0.0054 0.0600 Thallium
0.534 17440-62-2 07071 0.0020 0.0100 Vanadium
0.546 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
0.00092 17439-97-6 00259 0.000060 0.00020 Mercury
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3Wet Chemistry EPA 310.1
212 1n.a. 12150 0.70 2.0 Total Alkalinity
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Antimony 07044
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Arsenic 07035
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Barium 07046
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Beryllium 07047
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Boron 08014
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Cadmium 07049
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Calcium 01750
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 11 of 23

LL Sample # WW 7473021
LL Group # 1476292
Account # 10634
Sample Description: MW-36B-20140521MSD Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 13:47
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS36B SDG#: DUK28-03MSD
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Copper 07053
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Iron 01754
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Lead 07055
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Magnesium 01757
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Manganese 07058
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Molybdenum 07060
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Nickel 07061
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Potassium 01762
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Selenium 07036
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Silver 07066
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Sodium 01767
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Strontium 08068
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Thallium 07022
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Vanadium 07071
1Eric L Eby05/29/2014 12:01 1414706350011SW-846 6010C Zinc 07072
1Damary Valentin05/29/2014 08:57 1414757130021SW-846 7470A Mercury 00259
1Micaela L Dishong05/28/2014 10:00 1414706350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong05/28/2014 11:32 1414757130021SW-846 7470A WW SW846 Hg Digest 05713
1Kenneth A Bell05/24/2014 13:53 14144002102A1EPA 310.1 Total Alkalinity 12150
*=This limit was used in the evaluation of the final result
Page 12 of 23

LL Sample # WW 7473022
LL Group # 1476292
Account # 10634
Sample Description: MW-36B-20140521DUP Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 13:47
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS36B SDG#: DUK28-03DUP
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.167 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.574 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
43.8 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.287 J 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
6.75 17439-95-4 01757 0.0167 0.200 Magnesium
0.0019 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.129 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
10.8 17440-09-7 01762 0.0980 1.00 Potassium
0.0261 J 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
45.8 17440-23-5 01767 0.167 2.00 Sodium
0.597 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0025 J 17440-62-2 07071 0.0020 0.0100 Vanadium
0.0059 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
54.1 2016887-00-600224 4.0 8.0 Chloride
0.59 514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
97.1 2014808-79-800228 6.0 20.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
73.0 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
311 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 13 of 23

LL Sample # WW 7473022
LL Group # 1476292
Account # 10634
Sample Description: MW-36B-20140521DUP Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 13:47
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS36B SDG#: DUK28-03DUP
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Antimony 07044
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Arsenic 07035
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Barium 07046
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Beryllium 07047
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Boron 08014
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Cadmium 07049
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Calcium 01750
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Chromium 07051
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Copper 07053
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Iron 01754
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Lead 07055
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Magnesium 01757
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Manganese 07058
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Molybdenum 07060
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Nickel 07061
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Potassium 01762
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Selenium 07036
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Silver 07066
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Sodium 01767
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Strontium 08068
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Thallium 07022
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Vanadium 07071
1Eric L Eby05/29/2014 11:53 1414706350011SW-846 6010C Zinc 07072
1Damary Valentin05/29/2014 08:53 1414757130021SW-846 7470A Mercury 00259
1Micaela L Dishong05/28/2014 10:00 1414706350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong05/28/2014 11:32 1414757130021SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/23/2014 02:05 14142347602A1EPA 300.0 Bromide 01505
20Sandra J Miller05/23/2014 19:04 14142347602A1EPA 300.0 Chloride 00224
5Sandra J Miller05/23/2014 02:05 14142347602A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/23/2014 02:05 14142347602A1EPA 300.0 Nitrite Nitrogen 01506
20Sandra J Miller05/23/2014 19:04 14142347602A1EPA 300.0 Sulfate 00228
1Kenneth A Bell05/24/2014 13:59 14144002102A1EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch05/23/2014 08:43 14143021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 14 of 23

LL Sample # WW 7473023
LL Group # 1476292
Account # 10634
Sample Description: MW-6B-20140521 Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 15:08
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSM6C SDG#: DUK28-04
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0349 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
1.13 57440-42-8 08014 0.0420 0.500 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
53.9 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.121 J 17439-89-6 01754 0.0430 0.400 Iron
0.0057 J 17439-92-1 07055 0.0047 0.0300 Lead
13.4 17439-95-4 01757 0.0167 0.200 Magnesium
0.0682 17439-96-5 07058 0.00083 0.0100 Manganese
0.256 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
11.7 17440-09-7 01762 0.0980 1.00 Potassium
N.D.17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
52.3 57440-23-5 01767 0.835 10.0 Sodium
1.93 57440-24-6 08068 0.0017 0.0500 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
N.D.17440-62-2 07071 0.0020 0.0100 Vanadium
0.0026 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
71.5 2016887-00-600224 4.0 8.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
91.8 2014808-79-800228 6.0 20.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
105 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
374 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 15 of 23

LL Sample # WW 7473023
LL Group # 1476292
Account # 10634
Sample Description: MW-6B-20140521 Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 15:08
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSM6C SDG#: DUK28-04
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Antimony 07044
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Arsenic 07035
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Barium 07046
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Beryllium 07047
5Eric L Eby05/30/2014 09:05 1414706350011SW-846 6010C Boron 08014
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Cadmium 07049
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Calcium 01750
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Chromium 07051
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Copper 07053
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Iron 01754
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Lead 07055
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Magnesium 01757
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Manganese 07058
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Molybdenum 07060
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Nickel 07061
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Potassium 01762
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Selenium 07036
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Silver 07066
5Katlin N Cataldi05/30/2014 17:58 1414706350011SW-846 6010C Sodium 01767
5Eric L Eby05/30/2014 09:05 1414706350011SW-846 6010C Strontium 08068
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Thallium 07022
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Vanadium 07071
1Eric L Eby05/29/2014 13:20 1414706350011SW-846 6010C Zinc 07072
1Damary Valentin05/29/2014 08:59 1414757130021SW-846 7470A Mercury 00259
1Micaela L Dishong05/28/2014 10:00 1414706350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong05/28/2014 11:32 1414757130021SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/23/2014 03:42 14142347602A1EPA 300.0 Bromide 01505
20Sandra J Miller05/23/2014 20:41 14142347602A1EPA 300.0 Chloride 00224
5Sandra J Miller05/23/2014 03:42 14142347602A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/23/2014 03:42 14142347602A1EPA 300.0 Nitrite Nitrogen 01506
20Sandra J Miller05/23/2014 20:41 14142347602A1EPA 300.0 Sulfate 00228
1Kenneth A Bell05/24/2014 14:05 14144002102A1EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch05/23/2014 08:43 14143021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 16 of 23

LL Sample # WW 7473024
LL Group # 1476292
Account # 10634
Sample Description: MW-6C-20140521 Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 15:52
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSM6B SDG#: DUK28-05*
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0282 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
1.27 57440-42-8 08014 0.0420 0.500 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
30.1 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.514 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
8.92 17439-95-4 01757 0.0167 0.200 Magnesium
0.857 17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
6.16 17440-09-7 01762 0.0980 1.00 Potassium
N.D.17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
67.2 57440-23-5 01767 0.835 10.0 Sodium
0.431 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
N.D.17440-62-2 07071 0.0020 0.0100 Vanadium
0.0135 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
85.1 2516887-00-600224 5.0 10.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
112 2514808-79-800228 7.5 25.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
2.8 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
338 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 17 of 23

LL Sample # WW 7473024
LL Group # 1476292
Account # 10634
Sample Description: MW-6C-20140521 Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 15:52
Submitted: 05/22/2014 09:25
GeoSyntec Consultants
Reported: 06/01/2014 11:56
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSM6B SDG#: DUK28-05*
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Antimony 07044
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Arsenic 07035
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Barium 07046
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Beryllium 07047
5Eric L Eby05/30/2014 09:09 1414706350011SW-846 6010C Boron 08014
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Cadmium 07049
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Calcium 01750
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Chromium 07051
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Copper 07053
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Iron 01754
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Lead 07055
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Magnesium 01757
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Manganese 07058
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Molybdenum 07060
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Nickel 07061
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Potassium 01762
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Selenium 07036
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Silver 07066
5Katlin N Cataldi05/30/2014 18:02 1414706350011SW-846 6010C Sodium 01767
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Strontium 08068
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Thallium 07022
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Vanadium 07071
1Eric L Eby05/29/2014 13:24 1414706350011SW-846 6010C Zinc 07072
1Damary Valentin05/29/2014 09:05 1414757130021SW-846 7470A Mercury 00259
1Micaela L Dishong05/28/2014 10:00 1414706350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong05/28/2014 11:32 1414757130021SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/23/2014 03:59 14142347602A1EPA 300.0 Bromide 01505
25Sandra J Miller05/23/2014 20:57 14142347602A1EPA 300.0 Chloride 00224
5Sandra J Miller05/23/2014 03:59 14142347602A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/23/2014 03:59 14142347602A1EPA 300.0 Nitrite Nitrogen 01506
25Sandra J Miller05/23/2014 20:57 14142347602A1EPA 300.0 Sulfate 00228
1Kenneth A Bell05/24/2014 14:20 14144002102A1EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch05/23/2014 08:43 14143021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 18 of 23

Page 1 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1476292
Reported: 06/01/14 at 11:56 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Matrix QC may not be reported if insufficient sample or site-specific QC samples were not submitted. In these
situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise
specified in the method.

All Inorganic Initial Calibration and Continuing Calibration Blanks met acceptable method criteria unless
otherwise noted on the Analysis Report.

Laboratory Compliance Quality Control

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Batch number: 141470635001 Sample number(s): 7473017-7473024
Antimony N.D. 0.0053 0.0400 mg/l 107 88-111
Arsenic N.D. 0.0068 0.0400 mg/l 108 90-113
Barium N.D. 0.00033 0.0100 mg/l 106 90-110
Beryllium N.D. 0.00067 0.0100 mg/l 104 90-111
Boron N.D. 0.0084 0.100 mg/l 98 90-110
Cadmium N.D. 0.00076 0.0100 mg/l 110 90-112
Calcium N.D. 0.0334 0.400 mg/l 107 90-112
Chromium N.D. 0.0016 0.0300 mg/l 104 90-110
Copper N.D. 0.0027 0.0200 mg/l 108 90-112
Iron N.D. 0.0430 0.400 mg/l 108 90-112
Lead N.D. 0.0047 0.0300 mg/l 115 88-116
Magnesium N.D. 0.0167 0.200 mg/l 105 89-110
Manganese N.D. 0.00083 0.0100 mg/l 107 90-110
Molybdenum N.D. 0.0017 0.0200 mg/l 108 90-110
Nickel N.D. 0.0015 0.0200 mg/l 116* 90-111
Potassium N.D. 0.0980 1.00 mg/l 103 90-110
Selenium N.D. 0.0084 0.0400 mg/l 110 89-113
Silver N.D. 0.0021 0.0100 mg/l 114 80-120
Sodium N.D. 0.167 2.00 mg/l 105 87-114
Strontium N.D. 0.00033 0.0100 mg/l 107 90-110
Thallium N.D. 0.0054 0.0600 mg/l 112 90-118
Vanadium N.D. 0.0020 0.0100 mg/l 106 90-110
Zinc 0.0024 J 0.0020 0.0400 mg/l 110 90-110

Batch number: 141475713002 Sample number(s): 7473017-7473024
Mercury N.D. 0.00006
0
0.00020 mg/l 94 80-120

Batch number: 14142347602A Sample number(s): 7473017-7473020,7473022-7473024
Bromide N.D. 0.40 0.50 mg/l 96 96 90-110 0 20
Chloride N.D. 0.20 0.40 mg/l 98 98 90-110 0 20
Nitrate Nitrogen N.D. 0.050 0.10 mg/l 98 98 90-110 0 20
Nitrite Nitrogen N.D. 0.080 0.10 mg/l 95 95 90-110 0 20
Sulfate N.D. 0.30 1.0 mg/l 98 97 90-110 0 20

Batch number: 14143021201A Sample number(s): 7473017-7473020,7473022-7473024
Total Dissolved Solids N.D. 9.7 30.0 mg/l 105 80-120

Batch number: 14144002102A Sample number(s): 7473017,7473019-7473024
Total Alkalinity N.D. 0.70 2.0 mg/l as
CaCO3
97 90-110

Batch number: 14144002102B Sample number(s): 7473018
Page 19 of 23

Page 2 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1476292
Reported: 06/01/14 at 11:56 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max
Total Alkalinity N.D. 0.70 2.0 mg/l as
CaCO3
97 90-110

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 141470635001 Sample number(s): 7473017-7473024 UNSPK: 7473019 BKG: 7473019
Antimony 105 108 76-122 3 20 N.D. N.D. 0 (1) 20
Arsenic 107 110 81-123 3 20 N.D. N.D. 0 (1) 20
Barium 100 104 78-125 4 20 0.153 0.167 9 20
Beryllium 101 104 87-114 3 20 N.D. N.D. 0 (1) 20
Boron 96 99 87-111 3 20 0.528 0.574 8 20
Cadmium 105 108 75-122 2 20 N.D. N.D. 0 (1) 20
Calcium 78 (2) 113 (2) 75-125 3 20 44.1 43.8 1 20
Chromium 100 103 76-120 3 20 N.D. N.D. 0 (1) 20
Copper 103 107 86-122 3 20 N.D. N.D. 0 (1) 20
Iron 104 110 75-125 4 20 0.276 J 0.287 J 4 (1) 20
Lead 109 112 75-125 3 20 N.D. N.D. 0 (1) 20
Magnesium 90 105 81-118 3 20 6.83 6.75 1 20
Manganese 101 105 75-125 4 20 0.0016 J 0.0019 J 13 (1) 20
Molybdenum 104 108 89-117 3 20 0.132 0.129 2 20
Nickel 109 112 79-123 3 20 N.D. N.D. 0 (1) 20
Potassium 100 107 77-128 3 20 10.9 10.8 0 20
Selenium 99 103 75-125 3 20 0.0268 J 0.0261 J 2 (1) 20
Silver 107 111 75-125 4 20 N.D. N.D. 0 (1) 20
Sodium 94 (2) 107 (2) 84-117 2 20 46.3 45.8 1 20
Strontium 100 104 88-117 3 20 0.546 0.597 9 20
Thallium 104 107 75-125 3 20 N.D. N.D. 0 (1) 20
Vanadium 103 106 90-117 3 20 0.0023 J 0.0025 J 9 (1) 20
Zinc 105 108 85-117 3 20 0.0077 J 0.0059 J 27* (1) 20

Batch number: 141475713002 Sample number(s): 7473017-7473024 UNSPK: 7473019 BKG: 7473019
Mercury 94 92 80-120 2 20 N.D. N.D. 0 (1) 20

Batch number: 14142347602A Sample number(s): 7473017-7473020,7473022-7473024 UNSPK: 7473019 BKG: 7473019
Bromide 104 90-110 N.D. N.D. 0 (1) 20
Chloride 93 90-110 51.9 54.1 4 20
Nitrate Nitrogen 104 90-110 0.63 0.59 7 (1) 20
Nitrite Nitrogen 99 90-110 N.D. N.D. 0 (1) 20
Sulfate 115* 90-110 90.4 97.1 7 (1) 20

Batch number: 14143021201A Sample number(s): 7473017-7473020,7473022-7473024 UNSPK: 7473019 BKG: 7473019
Total Dissolved Solids 98 66-131 316 311 2 5

Batch number: 14144002102A Sample number(s): 7473017,7473019-7473024 UNSPK: 7473019 BKG: 7473019
Total Alkalinity 76 75 17-146 1 5 72.4 73.0 1 5

Batch number: 14144002102B Sample number(s): 7473018 UNSPK: 7473019 BKG: 7473018
Total Alkalinity 76 75 17-146 1 5 40.5 41.1 2 5
Page 20 of 23

Page 3 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1476292
Reported: 06/01/14 at 11:56 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Page 21 of 23
Page 22 of 23
Explanation of Symbols and Abbreviations

3768 0713
The following defines common symbols and abbreviations used in reporting technical data:
RL Reporting Limit BMQL Below Minimum Quantitation Level
N.D. none detected MPN Most Probable Number
TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units
IU International Units NTU nephelometric turbidity units
umhos/cm micromhos/cm ng nanogram(s)
C degrees Celsius F degrees Fahrenheit
meq milliequivalents lb. pound(s)
g gram(s) kg kilogram(s)
µg microgram(s) mg milligram(s)
mL milliliter(s) L liter(s)
m3 cubic meter(s) µL microliter(s)
pg/L picogram/liter
< less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be
reliably determined using this specific test.
> greater than
ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For
aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/l), because one liter of water has a
weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter per liter of gas.
ppb parts per billion
Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight
basis concentration to approximate the value present in a similar sample without moisture. All other results are reported
on an as-received basis.
Data Qualifiers:
C – result confirmed by reanalysis.
J - estimated value – The result is ≥ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ).
U.S. EPA CLP Data Qualifiers:
Organic Qualifiers Inorganic Qualifiers
A TIC is a possible aldol-condensation product B Value is <CRDL, but ≥IDL
B Analyte was also detected in the blank E Estimated due to interference
C Pesticide result confirmed by GC/MS M Duplicate injection precision not met
D Compound quantitated on a diluted sample N Spike sample not within control limits
E Concentration exceeds the calibration range of S Method of standard additions (MSA) used
the instrument for calculation
N Presumptive evidence of a compound (TICs only) U Compound was not detected
P Concentration difference between primary and W Post digestion spike out of control limits
confirmation columns >25% * Duplicate analysis not within control limits
U Compound was not detected + Correlation coefficient for MSA <0.995
X,Y,Z Defined in case narrative
Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.
Measurement uncertainty values, as applicable, are available upon request.
Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the
test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact
us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our
staff. This report shall not be reproduced except in full, without the written approval of the laboratory.
Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as “analyze immediately” are not
performed within 15 minutes.

WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE
FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM
ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF
MERCHANTABILITY. IN NO EVENT SHALL EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL, LLC BE LIABLE FOR INDIRECT, SPECIAL,
CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS
OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL AND (B) WHETHER
EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal
responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Eurofins Lancaster
Laboratories Environmental which includes any conditions that vary from the Standard Terms and Conditions, and Eurofins Lancaster Laboratories
Environmental hereby objects to any conflicting terms contained in any acceptance or order submitted by client.
Page 23 of 23

ANALYTICAL RESULTS

Prepared by:

Eurofins Lancaster Laboratories Environmental
2425 New Holland Pike
Lancaster, PA 17601
Prepared for:

GeoSyntec Consultants
4601 Six Forks Road
Suite 340
Raleigh NC 27609

June 05, 2014

Project: Duke Sutton, NC

Submittal Date: 05/23/2014
Group Number: 1476634
SDG: DUK29
PO Number: GC5592
State of Sample Origin: NC

Client Sample Description Lancaster Labs (LL) #
MW-27C-20140522 Groundwater Sample 7474661

The specific methodologies used in obtaining the enclosed analytical results are indicated on the
Laboratory Sample Analysis Record.

ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Lauren Wellborn
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Beau Hodge
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Rachel Donahue
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Herwig Goldemund

Respectfully Submitted,

[phone]

Page 1 of 9

Page 2 of 9

LL Sample # WW 7474661
LL Group # 1476634
Account # 10634
Sample Description: MW-27C-20140522 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/22/2014 17:25
Submitted: 05/23/2014 09:50
GeoSyntec Consultants
Reported: 06/05/2014 12:40
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS27C SDG#: DUK29-01*
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0456 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.517 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
25.2 17440-70-2 01750 0.0334 0.400 Calcium
0.0022 J 17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
1.09 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
5.05 17439-95-4 01757 0.0167 0.200 Magnesium
0.342 17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0019 J 17440-02-0 07061 0.0015 0.0200 Nickel
8.44 17440-09-7 01762 0.0980 1.00 Potassium
0.0550 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
50.2 57440-23-5 01767 0.835 10.0 Sodium
0.294 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0039 J 17440-62-2 07071 0.0020 0.0100 Vanadium
0.0174 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
52.3 2016887-00-600224 4.0 8.0 Chloride
0.74 514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
96.9 2014808-79-800228 6.0 20.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
8.1 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
258 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 3 of 9

LL Sample # WW 7474661
LL Group # 1476634
Account # 10634
Sample Description: MW-27C-20140522 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/22/2014 17:25
Submitted: 05/23/2014 09:50
GeoSyntec Consultants
Reported: 06/05/2014 12:40
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS27C SDG#: DUK29-01*
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Antimony 07044
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Arsenic 07035
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Barium 07046
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Beryllium 07047
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Boron 08014
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Cadmium 07049
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Calcium 01750
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Chromium 07051
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Copper 07053
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Iron 01754
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Lead 07055
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Magnesium 01757
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Manganese 07058
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Molybdenum 07060
1Joanne M Gates06/04/2014 13:04 1415406350033SW-846 6010C Nickel 07061
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Potassium 01762
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Selenium 07036
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Silver 07066
5Katlin N Cataldi05/30/2014 18:14 1414706350011SW-846 6010C Sodium 01767
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Strontium 08068
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Thallium 07022
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Vanadium 07071
1Eric L Eby05/29/2014 13:29 1414706350011SW-846 6010C Zinc 07072
1Damary Valentin05/29/2014 09:07 1414757130021SW-846 7470A Mercury 00259
1Micaela L Dishong05/28/2014 10:00 1414706350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz06/04/2014 07:00 1415406350032SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong05/28/2014 11:32 1414757130021SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/23/2014 22:34 14143347602A1EPA 300.0 Bromide 01505
20Sandra J Miller05/24/2014 23:28 14143347602A1EPA 300.0 Chloride 00224
5Sandra J Miller05/23/2014 22:34 14143347602A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/23/2014 22:34 14143347602A1EPA 300.0 Nitrite Nitrogen 01506
20Sandra J Miller05/24/2014 23:28 14143347602A1EPA 300.0 Sulfate 00228
1Michele L Graham05/27/2014 16:39 14147002102B1EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch05/27/2014 08:54 14147021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 4 of 9

Page 1 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1476634
Reported: 06/05/14 at 12:40 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Matrix QC may not be reported if insufficient sample or site-specific QC samples were not submitted. In these
situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise
specified in the method.

All Inorganic Initial Calibration and Continuing Calibration Blanks met acceptable method criteria unless
otherwise noted on the Analysis Report.

Laboratory Compliance Quality Control

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Batch number: 141470635001 Sample number(s): 7474661
Antimony N.D. 0.0053 0.0400 mg/l 107 88-111
Arsenic N.D. 0.0068 0.0400 mg/l 108 90-113
Barium N.D. 0.00033 0.0100 mg/l 106 90-110
Beryllium N.D. 0.00067 0.0100 mg/l 104 90-111
Boron N.D. 0.0084 0.100 mg/l 98 90-110
Cadmium N.D. 0.00076 0.0100 mg/l 110 90-112
Calcium N.D. 0.0334 0.400 mg/l 107 90-112
Chromium N.D. 0.0016 0.0300 mg/l 104 90-110
Copper N.D. 0.0027 0.0200 mg/l 108 90-112
Iron N.D. 0.0430 0.400 mg/l 108 90-112
Lead N.D. 0.0047 0.0300 mg/l 115 88-116
Magnesium N.D. 0.0167 0.200 mg/l 105 89-110
Manganese N.D. 0.00083 0.0100 mg/l 107 90-110
Molybdenum N.D. 0.0017 0.0200 mg/l 108 90-110
Potassium N.D. 0.0980 1.00 mg/l 103 90-110
Selenium N.D. 0.0084 0.0400 mg/l 110 89-113
Silver N.D. 0.0021 0.0100 mg/l 114 80-120
Sodium N.D. 0.167 2.00 mg/l 105 87-114
Strontium N.D. 0.00033 0.0100 mg/l 107 90-110
Thallium N.D. 0.0054 0.0600 mg/l 112 90-118
Vanadium N.D. 0.0020 0.0100 mg/l 106 90-110
Zinc 0.0024 J 0.0020 0.0400 mg/l 110 90-110

Batch number: 141475713002 Sample number(s): 7474661
Mercury N.D. 0.00006
0
0.00020 mg/l 94 80-120

Batch number: 141540635003 Sample number(s): 7474661
Nickel N.D. 0.0015 0.0200 mg/l 103 90-111

Batch number: 14143347602A Sample number(s): 7474661
Bromide N.D. 0.40 0.50 mg/l 96 90-110
Chloride N.D. 0.20 0.40 mg/l 96 90-110
Nitrate Nitrogen N.D. 0.050 0.10 mg/l 97 90-110
Nitrite Nitrogen N.D. 0.080 0.10 mg/l 97 90-110
Sulfate N.D. 0.30 1.0 mg/l 97 90-110

Batch number: 14147002102B Sample number(s): 7474661
Total Alkalinity 0.73 J 0.70 2.0 mg/l as
CaCO3
97 90-110

Batch number: 14147021201A Sample number(s): 7474661
Total Dissolved Solids N.D. 9.7 30.0 mg/l 93 80-120
Page 5 of 9

Page 2 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1476634
Reported: 06/05/14 at 12:40 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 141470635001 Sample number(s): 7474661 UNSPK: P473019 BKG: P473019
Antimony 105 108 76-122 3 20 N.D. N.D. 0 (1) 20
Arsenic 107 110 81-123 3 20 N.D. N.D. 0 (1) 20
Barium 100 104 78-125 4 20 0.153 0.167 9 20
Beryllium 101 104 87-114 3 20 N.D. N.D. 0 (1) 20
Boron 96 99 87-111 3 20 0.528 0.574 8 20
Cadmium 105 108 75-122 2 20 N.D. N.D. 0 (1) 20
Calcium 78 (2) 113 (2) 75-125 3 20 44.1 43.8 1 20
Chromium 100 103 76-120 3 20 N.D. N.D. 0 (1) 20
Copper 103 107 86-122 3 20 N.D. N.D. 0 (1) 20
Iron 104 110 75-125 4 20 0.276 J 0.287 J 4 (1) 20
Lead 109 112 75-125 3 20 N.D. N.D. 0 (1) 20
Magnesium 90 105 81-118 3 20 6.83 6.75 1 20
Manganese 101 105 75-125 4 20 0.0016 J 0.0019 J 13 (1) 20
Molybdenum 104 108 89-117 3 20 0.132 0.129 2 20
Potassium 100 107 77-128 3 20 10.9 10.8 0 20
Selenium 99 103 75-125 3 20 0.0268 J 0.0261 J 2 (1) 20
Silver 107 111 75-125 4 20 N.D. N.D. 0 (1) 20
Sodium 94 (2) 107 (2) 84-117 2 20 46.3 45.8 1 20
Strontium 100 104 88-117 3 20 0.546 0.597 9 20
Thallium 104 107 75-125 3 20 N.D. N.D. 0 (1) 20
Vanadium 103 106 90-117 3 20 0.0023 J 0.0025 J 9 (1) 20
Zinc 105 108 85-117 3 20 0.0077 J 0.0059 J 27* (1) 20

Batch number: 141475713002 Sample number(s): 7474661 UNSPK: P473019 BKG: P473019
Mercury 94 92 80-120 2 20 N.D. N.D. 0 (1) 20

Batch number: 141540635003 Sample number(s): 7474661 UNSPK: 7474661 BKG: 7474661
Nickel 99 102 79-123 2 20 0.0019 J 0.0025 J 27* (1) 20

Batch number: 14143347602A Sample number(s): 7474661 UNSPK: P474569 BKG: P474569
Bromide 97 90-110 N.D. N.D. 0 (1) 20
Chloride 90 90-110 290 292 1 20
Nitrate Nitrogen 98 90-110 N.D. N.D. 0 (1) 20
Nitrite Nitrogen 91 90-110 N.D. N.D. 0 (1) 20
Sulfate 92 90-110 219 216 1 (1) 20

Batch number: 14147002102B Sample number(s): 7474661 UNSPK: P474252 BKG: 7474661
Total Alkalinity 46 42 17-146 5 5 8.1 8.4 3 (1) 5

Batch number: 14147021201A Sample number(s): 7474661 UNSPK: P474252 BKG: P474252
Total Dissolved Solids 80 66-131 547 573 5 5

Page 6 of 9

Page 3 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1476634
Reported: 06/05/14 at 12:40 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Page 7 of 9
Page 8 of 9
Explanation of Symbols and Abbreviations

3768 0713
The following defines common symbols and abbreviations used in reporting technical data:
RL Reporting Limit BMQL Below Minimum Quantitation Level
N.D. none detected MPN Most Probable Number
TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units
IU International Units NTU nephelometric turbidity units
umhos/cm micromhos/cm ng nanogram(s)
C degrees Celsius F degrees Fahrenheit
meq milliequivalents lb. pound(s)
g gram(s) kg kilogram(s)
µg microgram(s) mg milligram(s)
mL milliliter(s) L liter(s)
m3 cubic meter(s) µL microliter(s)
pg/L picogram/liter
< less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be
reliably determined using this specific test.
> greater than
ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For
aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/l), because one liter of water has a
weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter per liter of gas.
ppb parts per billion
Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight
basis concentration to approximate the value present in a similar sample without moisture. All other results are reported
on an as-received basis.
Data Qualifiers:
C – result confirmed by reanalysis.
J - estimated value – The result is ≥ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ).
U.S. EPA CLP Data Qualifiers:
Organic Qualifiers Inorganic Qualifiers
A TIC is a possible aldol-condensation product B Value is <CRDL, but ≥IDL
B Analyte was also detected in the blank E Estimated due to interference
C Pesticide result confirmed by GC/MS M Duplicate injection precision not met
D Compound quantitated on a diluted sample N Spike sample not within control limits
E Concentration exceeds the calibration range of S Method of standard additions (MSA) used
the instrument for calculation
N Presumptive evidence of a compound (TICs only) U Compound was not detected
P Concentration difference between primary and W Post digestion spike out of control limits
confirmation columns >25% * Duplicate analysis not within control limits
U Compound was not detected + Correlation coefficient for MSA <0.995
X,Y,Z Defined in case narrative
Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.
Measurement uncertainty values, as applicable, are available upon request.
Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the
test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact
us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our
staff. This report shall not be reproduced except in full, without the written approval of the laboratory.
Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as “analyze immediately” are not
performed within 15 minutes.

WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE
FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM
ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF
MERCHANTABILITY. IN NO EVENT SHALL EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL, LLC BE LIABLE FOR INDIRECT, SPECIAL,
CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS
OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL AND (B) WHETHER
EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal
responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Eurofins Lancaster
Laboratories Environmental which includes any conditions that vary from the Standard Terms and Conditions, and Eurofins Lancaster Laboratories
Environmental hereby objects to any conflicting terms contained in any acceptance or order submitted by client.
Page 9 of 9

ANALYTICAL RESULTS

Prepared by:

Eurofins Lancaster Laboratories Environmental
2425 New Holland Pike
Lancaster, PA 17601
Prepared for:

GeoSyntec Consultants
4601 Six Forks Road
Suite 340
Raleigh NC 27609

May 30, 2014

Project: Duke Sutton, NC

Submittal Date: 05/24/2014
Group Number: 1476947
SDG: DUK30
PO Number: GC5592
State of Sample Origin: NC

Client Sample Description Lancaster Labs (LL) #
MW-5B-20140523 Groundwater Sample 7476605
MW-2B-20140523 Groundwater Sample 7476606
MW-2C-20140523 Groundwater Sample 7476607

The specific methodologies used in obtaining the enclosed analytical results are indicated on the
Laboratory Sample Analysis Record.

ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Lauren Wellborn
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Beau Hodge
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Rachel Donahue
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Herwig Goldemund

Page 1 of 12

Respectfully Submitted,

[phone]

Page 2 of 12

LL Sample # WW 7476605
LL Group # 1476947
Account # 10634
Sample Description: MW-5B-20140523 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/23/2014 12:12
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 05/30/2014 18:07
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSM5B SDG#: DUK30-01
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0445 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0134 J 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
0.948 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.700 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.444 17439-95-4 01757 0.0167 0.200 Magnesium
0.0320 17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
1.02 17440-09-7 01762 0.0980 1.00 Potassium
N.D.17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
2.02 17440-23-5 01767 0.167 2.00 Sodium
0.0099 J 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
N.D.17440-62-2 07071 0.0020 0.0100 Vanadium
0.0087 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
3.7 516887-00-600224 1.0 2.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
5.4 514808-79-800228 1.5 5.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
N.D.1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
10.0 J 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 3 of 12

LL Sample # WW 7476605
LL Group # 1476947
Account # 10634
Sample Description: MW-5B-20140523 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/23/2014 12:12
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 05/30/2014 18:07
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSM5B SDG#: DUK30-01
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Antimony 07044
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Arsenic 07035
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Barium 07046
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Beryllium 07047
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Boron 08014
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Cadmium 07049
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Calcium 01750
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Chromium 07051
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Copper 07053
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Iron 01754
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Lead 07055
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Magnesium 01757
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Manganese 07058
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Molybdenum 07060
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Nickel 07061
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Potassium 01762
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Selenium 07036
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Silver 07066
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Sodium 01767
1Eric L Eby05/30/2014 09:16 1414706350011SW-846 6010C Strontium 08068
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Thallium 07022
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Vanadium 07071
1Eric L Eby05/29/2014 13:32 1414706350011SW-846 6010C Zinc 07072
1Damary Valentin05/29/2014 09:09 1414757130021SW-846 7470A Mercury 00259
1Micaela L Dishong05/28/2014 10:00 1414706350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong05/28/2014 11:32 1414757130021SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/24/2014 21:02 14144987601A1EPA 300.0 Bromide 01505
5Sandra J Miller05/24/2014 21:02 14144987601A1EPA 300.0 Chloride 00224
5Sandra J Miller05/24/2014 21:02 14144987601A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/24/2014 21:02 14144987601A1EPA 300.0 Nitrite Nitrogen 01506
5Sandra J Miller05/24/2014 21:02 14144987601A1EPA 300.0 Sulfate 00228
1Michele L Graham05/27/2014 17:05 14147002102A1EPA 310.1 Total Alkalinity 12150
1Noah M Rainbow05/29/2014 11:47 14149021202B1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 4 of 12

LL Sample # WW 7476606
LL Group # 1476947
Account # 10634
Sample Description: MW-2B-20140523 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/23/2014 11:30
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 05/30/2014 18:07
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSM2B SDG#: DUK30-02
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0026 J 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0185 J 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
2.87 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.0781 J 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.574 17439-95-4 01757 0.0167 0.200 Magnesium
0.0080 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0080 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
0.851 J 17440-09-7 01762 0.0980 1.00 Potassium
N.D.17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
2.58 17440-23-5 01767 0.167 2.00 Sodium
0.0526 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
N.D.17440-62-2 07071 0.0020 0.0100 Vanadium
0.0021 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
4.2 516887-00-600224 1.0 2.0 Chloride
0.41 J 514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
3.6 J 514808-79-800228 1.5 5.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
5.3 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
18.0 J 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 5 of 12

LL Sample # WW 7476606
LL Group # 1476947
Account # 10634
Sample Description: MW-2B-20140523 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/23/2014 11:30
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 05/30/2014 18:07
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSM2B SDG#: DUK30-02
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Antimony 07044
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Arsenic 07035
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Barium 07046
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Beryllium 07047
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Boron 08014
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Cadmium 07049
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Calcium 01750
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Chromium 07051
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Copper 07053
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Iron 01754
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Lead 07055
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Magnesium 01757
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Manganese 07058
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Molybdenum 07060
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Nickel 07061
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Potassium 01762
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Selenium 07036
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Silver 07066
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Sodium 01767
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Strontium 08068
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Thallium 07022
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Vanadium 07071
1Eric L Eby05/29/2014 13:36 1414706350011SW-846 6010C Zinc 07072
1Damary Valentin05/29/2014 09:11 1414757130021SW-846 7470A Mercury 00259
1Micaela L Dishong05/28/2014 10:00 1414706350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong05/28/2014 11:32 1414757130021SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/24/2014 20:14 14144987601A1EPA 300.0 Bromide 01505
5Sandra J Miller05/24/2014 20:14 14144987601A1EPA 300.0 Chloride 00224
5Sandra J Miller05/24/2014 20:14 14144987601A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/24/2014 20:14 14144987601A1EPA 300.0 Nitrite Nitrogen 01506
5Sandra J Miller05/24/2014 20:14 14144987601A1EPA 300.0 Sulfate 00228
1Michele L Graham05/27/2014 17:12 14147002102A1EPA 310.1 Total Alkalinity 12150
1Noah M Rainbow05/29/2014 11:47 14149021202B1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 6 of 12

LL Sample # WW 7476607
LL Group # 1476947
Account # 10634
Sample Description: MW-2C-20140523 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/23/2014 11:22
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 05/30/2014 18:07
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSM2C SDG#: DUK30-03*
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
0.278 17440-38-2 07035 0.0068 0.0400 Arsenic
0.0806 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
3.02 57440-42-8 08014 0.0420 0.500 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
109 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
9.51 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
28.5 17439-95-4 01757 0.0167 0.200 Magnesium
0.375 17439-96-5 07058 0.00083 0.0100 Manganese
0.294 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
19.5 17440-09-7 01762 0.0980 1.00 Potassium
N.D.17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
36.6 17440-23-5 01767 0.167 2.00 Sodium
3.10 57440-24-6 08068 0.0017 0.0500 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
N.D.17440-62-2 07071 0.0020 0.0100 Vanadium
0.0087 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
42.1 2016887-00-600224 4.0 8.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
130 2014808-79-800228 6.0 20.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
269 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
542 1n.a. 00212 19.4 60.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 7 of 12

LL Sample # WW 7476607
LL Group # 1476947
Account # 10634
Sample Description: MW-2C-20140523 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/23/2014 11:22
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 05/30/2014 18:07
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSM2C SDG#: DUK30-03*
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Antimony 07044
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Arsenic 07035
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Barium 07046
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Beryllium 07047
5Eric L Eby05/30/2014 09:28 1414706350011SW-846 6010C Boron 08014
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Cadmium 07049
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Calcium 01750
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Chromium 07051
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Copper 07053
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Iron 01754
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Lead 07055
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Magnesium 01757
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Manganese 07058
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Molybdenum 07060
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Nickel 07061
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Potassium 01762
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Selenium 07036
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Silver 07066
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Sodium 01767
5Eric L Eby05/30/2014 09:28 1414706350011SW-846 6010C Strontium 08068
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Thallium 07022
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Vanadium 07071
1Eric L Eby05/29/2014 13:40 1414706350011SW-846 6010C Zinc 07072
1Damary Valentin05/29/2014 09:13 1414757130021SW-846 7470A Mercury 00259
1Micaela L Dishong05/28/2014 10:00 1414706350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong05/28/2014 11:32 1414757130021SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/24/2014 21:18 14144987601A1EPA 300.0 Bromide 01505
20Sandra J Miller05/27/2014 19:31 14144987601A1EPA 300.0 Chloride 00224
5Sandra J Miller05/24/2014 21:18 14144987601A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/24/2014 21:18 14144987601A1EPA 300.0 Nitrite Nitrogen 01506
20Sandra J Miller05/27/2014 19:31 14144987601A1EPA 300.0 Sulfate 00228
1Michele L Graham05/27/2014 15:37 14147002102A1EPA 310.1 Total Alkalinity 12150
1Noah M Rainbow05/29/2014 11:47 14149021202B1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 8 of 12

Page 1 of 2

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1476947
Reported: 05/30/14 at 06:07 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Matrix QC may not be reported if insufficient sample or site-specific QC samples were not submitted. In these
situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise
specified in the method.

All Inorganic Initial Calibration and Continuing Calibration Blanks met acceptable method criteria unless
otherwise noted on the Analysis Report.

Laboratory Compliance Quality Control

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Batch number: 141470635001 Sample number(s): 7476605-7476607
Antimony N.D. 0.0053 0.0400 mg/l 107 88-111
Arsenic N.D. 0.0068 0.0400 mg/l 108 90-113
Barium N.D. 0.00033 0.0100 mg/l 106 90-110
Beryllium N.D. 0.00067 0.0100 mg/l 104 90-111
Boron N.D. 0.0084 0.100 mg/l 98 90-110
Cadmium N.D. 0.00076 0.0100 mg/l 110 90-112
Calcium N.D. 0.0334 0.400 mg/l 107 90-112
Chromium N.D. 0.0016 0.0300 mg/l 104 90-110
Copper N.D. 0.0027 0.0200 mg/l 108 90-112
Iron N.D. 0.0430 0.400 mg/l 108 90-112
Lead N.D. 0.0047 0.0300 mg/l 115 88-116
Magnesium N.D. 0.0167 0.200 mg/l 105 89-110
Manganese N.D. 0.00083 0.0100 mg/l 107 90-110
Molybdenum N.D. 0.0017 0.0200 mg/l 108 90-110
Nickel N.D. 0.0015 0.0200 mg/l 116* 90-111
Potassium N.D. 0.0980 1.00 mg/l 103 90-110
Selenium N.D. 0.0084 0.0400 mg/l 110 89-113
Silver N.D. 0.0021 0.0100 mg/l 114 80-120
Sodium N.D. 0.167 2.00 mg/l 105 87-114
Strontium N.D. 0.00033 0.0100 mg/l 107 90-110
Thallium N.D. 0.0054 0.0600 mg/l 112 90-118
Vanadium N.D. 0.0020 0.0100 mg/l 106 90-110
Zinc 0.0024 J 0.0020 0.0400 mg/l 110 90-110

Batch number: 141475713002 Sample number(s): 7476605-7476607
Mercury N.D. 0.00006
0
0.00020 mg/l 94 80-120

Batch number: 14144987601A Sample number(s): 7476605-7476607
Bromide N.D. 0.40 0.50 mg/l 96 96 90-110 0 20
Chloride N.D. 0.20 0.40 mg/l 97 97 90-110 0 20
Nitrate Nitrogen N.D. 0.050 0.10 mg/l 99 99 90-110 0 20
Nitrite Nitrogen N.D. 0.080 0.10 mg/l 96 96 90-110 0 20
Sulfate N.D. 0.30 1.0 mg/l 98 97 90-110 1 20

Batch number: 14147002102A Sample number(s): 7476605-7476607
Total Alkalinity 0.73 J 0.70 2.0 mg/l as
CaCO3
97 90-110

Batch number: 14149021202B Sample number(s): 7476605-7476607
Total Dissolved Solids N.D. 9.7 30.0 mg/l 95 80-120

Page 9 of 12

Page 2 of 2

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1476947
Reported: 05/30/14 at 06:07 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 141470635001 Sample number(s): 7476605-7476607 UNSPK: P473019 BKG: P473019
Antimony 105 108 76-122 3 20 N.D. N.D. 0 (1) 20
Arsenic 107 110 81-123 3 20 N.D. N.D. 0 (1) 20
Barium 100 104 78-125 4 20 0.153 0.167 9 20
Beryllium 101 104 87-114 3 20 N.D. N.D. 0 (1) 20
Boron 96 99 87-111 3 20 0.528 0.574 8 20
Cadmium 105 108 75-122 2 20 N.D. N.D. 0 (1) 20
Calcium 78 (2) 113 (2) 75-125 3 20 44.1 43.8 1 20
Chromium 100 103 76-120 3 20 N.D. N.D. 0 (1) 20
Copper 103 107 86-122 3 20 N.D. N.D. 0 (1) 20
Iron 104 110 75-125 4 20 0.276 J 0.287 J 4 (1) 20
Lead 109 112 75-125 3 20 N.D. N.D. 0 (1) 20
Magnesium 90 105 81-118 3 20 6.83 6.75 1 20
Manganese 101 105 75-125 4 20 0.0016 J 0.0019 J 13 (1) 20
Molybdenum 104 108 89-117 3 20 0.132 0.129 2 20
Nickel 109 112 79-123 3 20 N.D. N.D. 0 (1) 20
Potassium 100 107 77-128 3 20 10.9 10.8 0 20
Selenium 99 103 75-125 3 20 0.0268 J 0.0261 J 2 (1) 20
Silver 107 111 75-125 4 20 N.D. N.D. 0 (1) 20
Sodium 94 (2) 107 (2) 84-117 2 20 46.3 45.8 1 20
Strontium 100 104 88-117 3 20 0.546 0.597 9 20
Thallium 104 107 75-125 3 20 N.D. N.D. 0 (1) 20
Vanadium 103 106 90-117 3 20 0.0023 J 0.0025 J 9 (1) 20
Zinc 105 108 85-117 3 20 0.0077 J 0.0059 J 27* (1) 20

Batch number: 141475713002 Sample number(s): 7476605-7476607 UNSPK: P473019 BKG: P473019
Mercury 94 92 80-120 2 20 N.D. N.D. 0 (1) 20

Batch number: 14144987601A Sample number(s): 7476605-7476607 UNSPK: 7476606 BKG: 7476606
Bromide 90 90-110 N.D. N.D. 0 (1) 20
Chloride 89* 90-110 4.2 4.1 2 (1) 20
Nitrate Nitrogen 90 90-110 0.41 J 0.39 J 5 (1) 20
Nitrite Nitrogen 92 90-110 N.D. N.D. 0 (1) 20
Sulfate 90 90-110 3.6 J 3.6 J 1 (1) 20

Batch number: 14147002102A Sample number(s): 7476605-7476607 UNSPK: P474252 BKG: P474252
Total Alkalinity 46 42 17-146 5 5 38.9 39.3 1 5

Batch number: 14149021202B Sample number(s): 7476605-7476607 UNSPK: P476603 BKG: 7476607
Total Dissolved Solids 98 66-131 542 543 0 5

Page 10 of 12
Page 11 of 12
Explanation of Symbols and Abbreviations

3768 0713
The following defines common symbols and abbreviations used in reporting technical data:
RL Reporting Limit BMQL Below Minimum Quantitation Level
N.D. none detected MPN Most Probable Number
TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units
IU International Units NTU nephelometric turbidity units
umhos/cm micromhos/cm ng nanogram(s)
C degrees Celsius F degrees Fahrenheit
meq milliequivalents lb. pound(s)
g gram(s) kg kilogram(s)
µg microgram(s) mg milligram(s)
mL milliliter(s) L liter(s)
m3 cubic meter(s) µL microliter(s)
pg/L picogram/liter
< less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be
reliably determined using this specific test.
> greater than
ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For
aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/l), because one liter of water has a
weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter per liter of gas.
ppb parts per billion
Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight
basis concentration to approximate the value present in a similar sample without moisture. All other results are reported
on an as-received basis.
Data Qualifiers:
C – result confirmed by reanalysis.
J - estimated value – The result is ≥ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ).
U.S. EPA CLP Data Qualifiers:
Organic Qualifiers Inorganic Qualifiers
A TIC is a possible aldol-condensation product B Value is <CRDL, but ≥IDL
B Analyte was also detected in the blank E Estimated due to interference
C Pesticide result confirmed by GC/MS M Duplicate injection precision not met
D Compound quantitated on a diluted sample N Spike sample not within control limits
E Concentration exceeds the calibration range of S Method of standard additions (MSA) used
the instrument for calculation
N Presumptive evidence of a compound (TICs only) U Compound was not detected
P Concentration difference between primary and W Post digestion spike out of control limits
confirmation columns >25% * Duplicate analysis not within control limits
U Compound was not detected + Correlation coefficient for MSA <0.995
X,Y,Z Defined in case narrative
Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.
Measurement uncertainty values, as applicable, are available upon request.
Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the
test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact
us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our
staff. This report shall not be reproduced except in full, without the written approval of the laboratory.
Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as “analyze immediately” are not
performed within 15 minutes.

WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE
FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM
ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF
MERCHANTABILITY. IN NO EVENT SHALL EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL, LLC BE LIABLE FOR INDIRECT, SPECIAL,
CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS
OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL AND (B) WHETHER
EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal
responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Eurofins Lancaster
Laboratories Environmental which includes any conditions that vary from the Standard Terms and Conditions, and Eurofins Lancaster Laboratories
Environmental hereby objects to any conflicting terms contained in any acceptance or order submitted by client.
Page 12 of 12

ANALYTICAL RESULTS

Prepared by:

Eurofins Lancaster Laboratories Environmental
2425 New Holland Pike
Lancaster, PA 17601
Prepared for:

GeoSyntec Consultants
4601 Six Forks Road
Suite 340
Raleigh NC 27609

June 04, 2014

Project: Duke Sutton, NC

Submittal Date: 05/24/2014
Group Number: 1476968
SDG: DUK31
PO Number: GC5592
State of Sample Origin: NC

Client Sample Description Lancaster Labs (LL) #
SS-GP3(76.0-80.0)-20140520 Grab Solid Sample 7476720
SS-GP3(76.0-80.0)-20140520 Grab Solid Sample 7476721
SS-GP3(80.0-84.0)-20140520 Grab Solid Sample 7476722
SS-GP3(80.0-84.0)-20140520 Grab Solid Sample 7476723
SS-GP3(72.0-76.0)-20140520 Grab Solid Sample 7476724
SS-GP3(72.0-76.0)-20140520 Grab Solid Sample 7476725
SS-GP3(24.0-28.0)-20140520 Grab Solid Sample 7476726
SS-GP3(24.0-28.0)-20140520 Grab Solid Sample 7476727
SS-GP2(72.0-76.0)-20140519 Grab Solid Sample 7476728
SS-GP2(72.0-76.0)-20140519 Grab Solid Sample 7476729
SS-GP2(52.0-56.0)-20140516 Grab Solid Sample 7476730
SS-GP2(52.0-56.0)-20140516 Grab Solid Sample 7476731
SS-GP5(20.0-24.0)-20140521 Grab Solid Sample 7476732
SS-GP5(20.0-24.0)-20140521 Grab Solid Sample 7476733
SS-GP6(24.0-28.0)-20140521 Grab Solid Sample 7476734
SS-GP6(24.0-28.0)-20140521 Grab Solid Sample 7476735

The specific methodologies used in obtaining the enclosed analytical results are indicated on the
Laboratory Sample Analysis Record.

ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Lauren Wellborn
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Beau Hodge
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Rachel Donahue
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Herwig Goldemund
Page 1 of 41

Respectfully Submitted,

[phone]

Page 2 of 41

LL Sample # SW 7476720
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(76.0-80.0)-20140520 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 10:00 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3101 SDG#: DUK31-01
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
1.07 J 17440-36-0 06944 1.04 5.64 Antimony
115 17440-38-2 06935 0.988 5.64 Arsenic
599 57440-39-3 06946 0.233 7.06 Barium
5.28 17440-41-7 06947 0.0945 1.41 Beryllium
57.1 17440-42-8 07914 1.19 14.1 Boron
N.D.17440-43-9 06949 0.107 1.41 Cadmium
3,270 17440-70-2 01650 4.62 55.4 Calcium
49.9 17440-47-3 06951 0.226 4.23 Chromium
76.4 17440-50-8 06953 0.409 2.82 Copper
23,500 17439-89-6 01654 5.11 56.4 Iron
32.8 17439-92-1 06955 0.706 4.23 Lead
2,260 17439-95-4 01657 2.36 28.2 Magnesium
107 17439-96-5 06958 0.117 1.41 Manganese
2.61 J 17439-98-7 06960 0.240 2.82 Molybdenum
46.0 17440-02-0 06961 0.183 2.82 Nickel
5,720 17440-09-7 01662 11.8 141 Potassium
7.34 17782-49-2 06936 1.13 5.64 Selenium
N.D.17440-22-4 06966 0.240 1.41 Silver
699 17440-23-5 01667 23.6 282 Sodium
418 57440-24-6 07968 0.233 7.06 Strontium
1.58 J 17440-28-0 06925 0.734 8.47 Thallium
55.9 17440-66-6 06972 0.282 5.64 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.230 J 17439-97-6 00159 0.0143 0.285 Mercury
mg/kg mg/kgmg/kgWet Chemistry EPA 300.0
N.D.124959-67-907335 5.8 7.3 Bromide by IC (solid)
15.4 116887-00-607333 7.3 14.5 Chloride by IC (solid)
53.4 114808-79-807338 7.3 21.8 Sulfate by IC (solid)
Std. Units Std. UnitsStd. UnitsSW-846 9045D modified
8.58 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 22.2 C.
% %%Wet Chemistry SM 2540 G-1997
31.2 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 3 of 41

LL Sample # SW 7476720
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(76.0-80.0)-20140520 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 10:00 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3101 SDG#: DUK31-01
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Antimony 06944
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Arsenic 06935
5Joanne M Gates05/30/2014 10:24 1414806370011SW-846 6010C Barium 06946
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Beryllium 06947
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Boron 07914
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Cadmium 06949
1Maria A Orrs06/02/2014 15:50 1415106370011SW-846 6010C Calcium 01650
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Chromium 06951
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Copper 06953
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Iron 01654
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Lead 06955
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Magnesium 01657
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Manganese 06958
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Molybdenum 06960
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Nickel 06961
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Potassium 01662
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Selenium 06936
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Silver 06966
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Sodium 01667
5Joanne M Gates05/30/2014 10:24 1414806370011SW-846 6010C Strontium 07968
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Thallium 06925
1Maria A Orrs05/29/2014 16:57 1414806370011SW-846 6010C Zinc 06972
1Damary Valentin05/29/2014 10:14 1414706380021SW-846 7471B Mercury 00159
1Annamaria Kuhns05/28/2014 22:42 1414806370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz06/02/2014 07:56 1415106370012SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1Denise K Conners05/28/2014 11:05 1414706380021SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Sandra J Miller05/30/2014 08:04 14149149202A1EPA 300.0 Bromide by IC (solid) 07335
1Sandra J Miller05/30/2014 08:04 14149149202A1EPA 300.0 Chloride by IC (solid) 07333
1Sandra J Miller05/30/2014 08:04 14149149202A1EPA 300.0 Sulfate by IC (solid) 07338
1James S Mathiot05/29/2014 20:45 14149149202A1EPA 300.0 Deionized Water
Extraction
01352
1Luz M Groff05/28/2014 21:10 14148039401B1SW-846 9045D
modified
pH 00394
1Scott W Freisher05/29/2014 18:33 14149820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 4 of 41

LL Sample # TL 7476721
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(76.0-80.0)-20140520 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 10:00 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3102 SDG#: DUK31-02
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.0053 J 17440-36-0 07044 0.0053 0.0400 Antimony
0.192 17440-38-2 07035 0.0068 0.0400 Arsenic
0.0444 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.113 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
3.97 17440-70-2 01750 0.0334 0.400 Calcium
0.0026 J 17440-47-3 07051 0.0016 0.0300 Chromium
0.0031 J 17440-50-8 07053 0.0027 0.0200 Copper
0.117 J 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
1.33 17439-95-4 01757 0.0167 0.200 Magnesium
0.0050 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0054 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
0.278 J 17440-09-7 01762 0.0980 1.00 Potassium
0.0340 J 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
4.64 17440-23-5 01767 0.167 2.00 Sodium
0.241 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0044 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Antimony 07044
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Arsenic 07035
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Barium 07046
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Beryllium 07047
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Boron 08014
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Cadmium 07049
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Calcium 01750
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 5 of 41

LL Sample # TL 7476721
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(76.0-80.0)-20140520 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 10:00 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3102 SDG#: DUK31-02
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Copper 07053
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Iron 01754
1John W Yanzuk II06/04/2014 01:34 1415006360021SW-846 6010C Lead 07055
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Magnesium 01757
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Manganese 07058
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Molybdenum 07060
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Nickel 07061
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Potassium 01762
1John W Yanzuk II06/04/2014 01:34 1415006360021SW-846 6010C Selenium 07036
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Silver 07066
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Sodium 01767
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Strontium 08068
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Thallium 07022
1John W Yanzuk II06/02/2014 22:13 1415006360021SW-846 6010C Zinc 07072
1Parker D Lindstrom06/03/2014 17:18 1415057130071SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 09:08 1415006360021SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong06/02/2014 11:37 1415057130071SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber05/29/2014 12:00 14149-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 6 of 41

LL Sample # SW 7476722
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(80.0-84.0)-20140520 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 10:20 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3103 SDG#: DUK31-03
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
1.15 J 17440-36-0 06944 0.907 4.90 Antimony
58.9 17440-38-2 06935 0.858 4.90 Arsenic
477 107440-39-3 06946 0.404 12.3 Barium
3.62 17440-41-7 06947 0.0821 1.23 Beryllium
41.1 17440-42-8 07914 1.03 12.3 Boron
N.D.17440-43-9 06949 0.0931 1.23 Cadmium
3,000 17440-70-2 01650 4.05 48.5 Calcium
38.7 17440-47-3 06951 0.196 3.68 Chromium
49.6 17440-50-8 06953 0.355 2.45 Copper
30,800 107439-89-6 01654 44.4 490 Iron
20.1 17439-92-1 06955 0.613 3.68 Lead
1,650 17439-95-4 01657 2.05 24.5 Magnesium
105 17439-96-5 06958 0.102 1.23 Manganese
1.58 J 17439-98-7 06960 0.208 2.45 Molybdenum
33.1 17440-02-0 06961 0.159 2.45 Nickel
3,860 17440-09-7 01662 10.2 123 Potassium
3.89 J 17782-49-2 06936 0.980 4.90 Selenium
N.D.17440-22-4 06966 0.208 1.23 Silver
475 17440-23-5 01667 20.5 245 Sodium
317 107440-24-6 07968 0.404 12.3 Strontium
1.22 J 17440-28-0 06925 0.637 7.35 Thallium
35.9 17440-66-6 06972 0.245 4.90 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.101 J 17439-97-6 00159 0.0118 0.235 Mercury
mg/kg mg/kgmg/kgWet Chemistry EPA 300.0
N.D.124959-67-907335 5.0 6.3 Bromide by IC (solid)
7.0 J 116887-00-607333 6.3 12.6 Chloride by IC (solid)
22.3 114808-79-807338 6.3 18.9 Sulfate by IC (solid)
Std. Units Std. UnitsStd. UnitsSW-846 9045D modified
8.49 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 22.2 C.
% %%Wet Chemistry SM 2540 G-1997
20.0 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 7 of 41

LL Sample # SW 7476722
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(80.0-84.0)-20140520 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 10:20 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3103 SDG#: DUK31-03
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Antimony 06944
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Arsenic 06935
10Joanne M Gates05/30/2014 10:36 1414806370011SW-846 6010C Barium 06946
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Beryllium 06947
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Boron 07914
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Cadmium 06949
1Maria A Orrs06/02/2014 16:35 1415106370011SW-846 6010C Calcium 01650
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Chromium 06951
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Copper 06953
10Joanne M Gates05/30/2014 10:36 1414806370011SW-846 6010C Iron 01654
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Lead 06955
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Magnesium 01657
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Manganese 06958
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Molybdenum 06960
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Nickel 06961
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Potassium 01662
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Selenium 06936
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Silver 06966
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Sodium 01667
10Joanne M Gates05/30/2014 10:36 1414806370011SW-846 6010C Strontium 07968
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Thallium 06925
1Maria A Orrs05/29/2014 17:01 1414806370011SW-846 6010C Zinc 06972
1Damary Valentin05/29/2014 10:32 1414706380021SW-846 7471B Mercury 00159
1Annamaria Kuhns05/28/2014 22:42 1414806370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz06/02/2014 07:56 1415106370012SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1Denise K Conners05/28/2014 11:05 1414706380021SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Sandra J Miller05/30/2014 08:20 14149149202A1EPA 300.0 Bromide by IC (solid) 07335
1Sandra J Miller05/30/2014 08:20 14149149202A1EPA 300.0 Chloride by IC (solid) 07333
1Sandra J Miller05/30/2014 08:20 14149149202A1EPA 300.0 Sulfate by IC (solid) 07338
1James S Mathiot05/29/2014 20:45 14149149202A1EPA 300.0 Deionized Water
Extraction
01352
1Luz M Groff05/28/2014 21:10 14148039401B1SW-846 9045D
modified
pH 00394
1Scott W Freisher05/29/2014 18:33 14149820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 8 of 41

LL Sample # TL 7476723
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(80.0-84.0)-20140520 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 10:20 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3104 SDG#: DUK31-04
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
0.151 17440-38-2 07035 0.0068 0.0400 Arsenic
0.0547 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.125 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
3.55 17440-70-2 01750 0.0334 0.400 Calcium
0.0055 J 17440-47-3 07051 0.0016 0.0300 Chromium
0.0074 J 17440-50-8 07053 0.0027 0.0200 Copper
0.546 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
1.17 17439-95-4 01757 0.0167 0.200 Magnesium
0.0039 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0098 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0017 J 17440-02-0 07061 0.0015 0.0200 Nickel
0.123 J 17440-09-7 01762 0.0980 1.00 Potassium
0.0187 J 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
5.56 17440-23-5 01767 0.167 2.00 Sodium
0.175 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0077 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Antimony 07044
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Arsenic 07035
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Barium 07046
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Beryllium 07047
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Boron 08014
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Cadmium 07049
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Calcium 01750
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 9 of 41

LL Sample # TL 7476723
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(80.0-84.0)-20140520 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 10:20 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3104 SDG#: DUK31-04
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Copper 07053
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Iron 01754
1John W Yanzuk II06/04/2014 01:45 1415006360021SW-846 6010C Lead 07055
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Magnesium 01757
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Manganese 07058
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Molybdenum 07060
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Nickel 07061
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Potassium 01762
1John W Yanzuk II06/04/2014 01:45 1415006360021SW-846 6010C Selenium 07036
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Silver 07066
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Sodium 01767
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Strontium 08068
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Thallium 07022
1John W Yanzuk II06/02/2014 22:16 1415006360021SW-846 6010C Zinc 07072
1Parker D Lindstrom06/03/2014 17:20 1415057130071SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 09:08 1415006360021SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong06/02/2014 11:37 1415057130071SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber05/29/2014 12:00 14149-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 10 of 41

LL Sample # SW 7476724
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(72.0-76.0)-20140520 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 09:50 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3105 SDG#: DUK31-05
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
1.19 J 17440-36-0 06944 1.04 5.64 Antimony
104 17440-38-2 06935 0.987 5.64 Arsenic
785 107440-39-3 06946 0.465 14.1 Barium
5.68 17440-41-7 06947 0.0945 1.41 Beryllium
58.5 17440-42-8 07914 1.18 14.1 Boron
N.D.17440-43-9 06949 0.107 1.41 Cadmium
3,670 17440-70-2 01650 4.76 57.0 Calcium
44.3 17440-47-3 06951 0.226 4.23 Chromium
68.5 17440-50-8 06953 0.409 2.82 Copper
23,700 17439-89-6 01654 5.11 56.4 Iron
28.4 17439-92-1 06955 0.705 4.23 Lead
2,350 17439-95-4 01657 2.36 28.2 Magnesium
103 17439-96-5 06958 0.117 1.41 Manganese
2.24 J 17439-98-7 06960 0.240 2.82 Molybdenum
49.1 17440-02-0 06961 0.183 2.82 Nickel
6,410 17440-09-7 01662 11.8 141 Potassium
8.73 17782-49-2 06936 1.13 5.64 Selenium
N.D.17440-22-4 06966 0.240 1.41 Silver
765 17440-23-5 01667 23.6 282 Sodium
426 57440-24-6 07968 0.233 7.05 Strontium
1.31 J 17440-28-0 06925 0.733 8.46 Thallium
48.2 17440-66-6 06972 0.282 5.64 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.173 J 17439-97-6 00159 0.0136 0.272 Mercury
mg/kg mg/kgmg/kgWet Chemistry EPA 300.0
N.D.124959-67-907335 5.7 7.2 Bromide by IC (solid)
14.2 J 116887-00-607333 7.2 14.3 Chloride by IC (solid)
34.5 114808-79-807338 7.2 21.5 Sulfate by IC (solid)
Std. Units Std. UnitsStd. UnitsSW-846 9045D modified
8.50 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 22.3 C.
% %%Wet Chemistry SM 2540 G-1997
29.8 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 11 of 41

LL Sample # SW 7476724
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(72.0-76.0)-20140520 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 09:50 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3105 SDG#: DUK31-05
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Antimony 06944
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Arsenic 06935
10Joanne M Gates05/30/2014 11:01 1414806370011SW-846 6010C Barium 06946
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Beryllium 06947
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Boron 07914
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Cadmium 06949
1Maria A Orrs06/02/2014 16:39 1415106370011SW-846 6010C Calcium 01650
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Chromium 06951
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Copper 06953
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Iron 01654
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Lead 06955
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Magnesium 01657
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Manganese 06958
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Molybdenum 06960
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Nickel 06961
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Potassium 01662
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Selenium 06936
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Silver 06966
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Sodium 01667
5Joanne M Gates05/30/2014 10:49 1414806370011SW-846 6010C Strontium 07968
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Thallium 06925
1Maria A Orrs05/29/2014 17:06 1414806370011SW-846 6010C Zinc 06972
1Damary Valentin05/29/2014 10:34 1414706380021SW-846 7471B Mercury 00159
1Annamaria Kuhns05/28/2014 22:42 1414806370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz06/02/2014 07:56 1415106370012SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1Denise K Conners05/28/2014 11:05 1414706380021SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Sandra J Miller05/30/2014 08:36 14149149202A1EPA 300.0 Bromide by IC (solid) 07335
1Sandra J Miller05/30/2014 08:36 14149149202A1EPA 300.0 Chloride by IC (solid) 07333
1Sandra J Miller05/30/2014 08:36 14149149202A1EPA 300.0 Sulfate by IC (solid) 07338
1James S Mathiot05/29/2014 20:45 14149149202A1EPA 300.0 Deionized Water
Extraction
01352
1Luz M Groff05/28/2014 21:10 14148039401B1SW-846 9045D
modified
pH 00394
1Scott W Freisher05/29/2014 18:33 14149820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 12 of 41

LL Sample # TL 7476725
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(72.0-76.0)-20140520 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 09:50 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3106 SDG#: DUK31-06
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.0072 J 17440-36-0 07044 0.0053 0.0400 Antimony
0.208 17440-38-2 07035 0.0068 0.0400 Arsenic
0.0766 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.120 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
4.10 17440-70-2 01750 0.0334 0.400 Calcium
0.0026 J 17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.0891 J 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
1.02 17439-95-4 01757 0.0167 0.200 Magnesium
0.0012 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0034 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
0.197 J 17440-09-7 01762 0.0980 1.00 Potassium
0.0333 J 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
4.65 17440-23-5 01767 0.167 2.00 Sodium
0.277 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0025 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Antimony 07044
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Arsenic 07035
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Barium 07046
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Beryllium 07047
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Boron 08014
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Cadmium 07049
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Calcium 01750
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 13 of 41

LL Sample # TL 7476725
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(72.0-76.0)-20140520 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 09:50 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3106 SDG#: DUK31-06
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Copper 07053
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Iron 01754
1John W Yanzuk II06/04/2014 01:49 1415006360021SW-846 6010C Lead 07055
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Magnesium 01757
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Manganese 07058
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Molybdenum 07060
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Nickel 07061
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Potassium 01762
1John W Yanzuk II06/04/2014 01:49 1415006360021SW-846 6010C Selenium 07036
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Silver 07066
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Sodium 01767
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Strontium 08068
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Thallium 07022
1John W Yanzuk II06/02/2014 22:20 1415006360021SW-846 6010C Zinc 07072
1Parker D Lindstrom06/03/2014 17:22 1415057130071SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 09:08 1415006360021SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong06/02/2014 11:37 1415057130071SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber05/29/2014 12:00 14149-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 14 of 41

LL Sample # SW 7476726
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(24.0-28.0)-20140520 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 08:30 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3107 SDG#: DUK31-07
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
1.54 J 17440-36-0 06944 1.02 5.49 Antimony
60.4 17440-38-2 06935 0.961 5.49 Arsenic
384 57440-39-3 06946 0.227 6.87 Barium
7.55 17440-41-7 06947 0.0920 1.37 Beryllium
36.4 17440-42-8 07914 1.15 13.7 Boron
N.D.17440-43-9 06949 0.104 1.37 Cadmium
2,890 17440-70-2 01650 4.41 52.8 Calcium
41.3 17440-47-3 06951 0.220 4.12 Chromium
74.7 17440-50-8 06953 0.398 2.75 Copper
15,300 17439-89-6 01654 4.97 54.9 Iron
32.4 17439-92-1 06955 0.687 4.12 Lead
1,700 17439-95-4 01657 2.29 27.5 Magnesium
64.7 17439-96-5 06958 0.114 1.37 Manganese
5.92 17439-98-7 06960 0.233 2.75 Molybdenum
39.7 17440-02-0 06961 0.179 2.75 Nickel
3,610 17440-09-7 01662 11.5 137 Potassium
14.6 17782-49-2 06936 1.10 5.49 Selenium
N.D.17440-22-4 06966 0.233 1.37 Silver
551 17440-23-5 01667 22.9 275 Sodium
327 57440-24-6 07968 0.227 6.87 Strontium
N.D.17440-28-0 06925 0.714 8.24 Thallium
51.9 17440-66-6 06972 0.275 5.49 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.175 J 17439-97-6 00159 0.0130 0.261 Mercury
mg/kg mg/kgmg/kgWet Chemistry EPA 300.0
N.D.124959-67-907335 5.6 7.0 Bromide by IC (solid)
13.9 J 116887-00-607333 7.0 13.9 Chloride by IC (solid)
39.1 114808-79-807338 7.0 20.9 Sulfate by IC (solid)
Std. Units Std. UnitsStd. UnitsSW-846 9045D modified
7.81 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 22.4 C.
% %%Wet Chemistry SM 2540 G-1997
27.9 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 15 of 41

LL Sample # SW 7476726
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(24.0-28.0)-20140520 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 08:30 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3107 SDG#: DUK31-07
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Antimony 06944
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Arsenic 06935
5Joanne M Gates05/30/2014 11:09 1414806370011SW-846 6010C Barium 06946
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Beryllium 06947
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Boron 07914
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Cadmium 06949
1Maria A Orrs06/02/2014 16:43 1415106370011SW-846 6010C Calcium 01650
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Chromium 06951
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Copper 06953
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Iron 01654
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Lead 06955
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Magnesium 01657
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Manganese 06958
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Molybdenum 06960
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Nickel 06961
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Potassium 01662
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Selenium 06936
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Silver 06966
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Sodium 01667
5Joanne M Gates05/30/2014 11:09 1414806370011SW-846 6010C Strontium 07968
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Thallium 06925
1Maria A Orrs05/29/2014 17:10 1414806370011SW-846 6010C Zinc 06972
1Damary Valentin05/29/2014 10:36 1414706380021SW-846 7471B Mercury 00159
1Annamaria Kuhns05/28/2014 22:42 1414806370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz06/02/2014 07:56 1415106370012SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1Denise K Conners05/28/2014 11:05 1414706380021SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Sandra J Miller05/30/2014 08:52 14149149202A1EPA 300.0 Bromide by IC (solid) 07335
1Sandra J Miller05/30/2014 08:52 14149149202A1EPA 300.0 Chloride by IC (solid) 07333
1Sandra J Miller05/30/2014 08:52 14149149202A1EPA 300.0 Sulfate by IC (solid) 07338
1James S Mathiot05/29/2014 20:45 14149149202A1EPA 300.0 Deionized Water
Extraction
01352
1Luz M Groff05/28/2014 21:10 14148039401B1SW-846 9045D
modified
pH 00394
1Scott W Freisher05/29/2014 18:33 14149820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 16 of 41

LL Sample # TL 7476727
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(24.0-28.0)-20140520 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 08:30 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3108 SDG#: DUK31-08
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.0140 J 17440-36-0 07044 0.0053 0.0400 Antimony
0.0561 17440-38-2 07035 0.0068 0.0400 Arsenic
0.0957 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0704 J 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
5.87 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
N.D.17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.836 17439-95-4 01757 0.0167 0.200 Magnesium
0.0011 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.153 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
0.319 J 17440-09-7 01762 0.0980 1.00 Potassium
0.0172 J 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
3.62 17440-23-5 01767 0.167 2.00 Sodium
0.179 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0021 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Antimony 07044
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Arsenic 07035
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Barium 07046
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Beryllium 07047
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Boron 08014
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Cadmium 07049
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Calcium 01750
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 17 of 41

LL Sample # TL 7476727
LL Group # 1476968
Account # 10634
Sample Description: SS-GP3(24.0-28.0)-20140520 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/20/2014 08:30 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3108 SDG#: DUK31-08
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Copper 07053
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Iron 01754
1John W Yanzuk II06/04/2014 01:53 1415006360021SW-846 6010C Lead 07055
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Magnesium 01757
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Manganese 07058
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Molybdenum 07060
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Nickel 07061
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Potassium 01762
1John W Yanzuk II06/04/2014 01:53 1415006360021SW-846 6010C Selenium 07036
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Silver 07066
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Sodium 01767
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Strontium 08068
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Thallium 07022
1John W Yanzuk II06/02/2014 22:24 1415006360021SW-846 6010C Zinc 07072
1Parker D Lindstrom06/03/2014 17:24 1415057130071SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 09:08 1415006360021SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong06/02/2014 11:37 1415057130071SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber05/29/2014 12:00 14149-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 18 of 41

LL Sample # SW 7476728
LL Group # 1476968
Account # 10634
Sample Description: SS-GP2(72.0-76.0)-20140519 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/19/2014 09:30 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3109 SDG#: DUK31-09
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
1.37 J 17440-36-0 06944 1.02 5.50 Antimony
136 17440-38-2 06935 0.963 5.50 Arsenic
632 107440-39-3 06946 0.454 13.8 Barium
5.28 17440-41-7 06947 0.0921 1.38 Beryllium
66.4 17440-42-8 07914 1.16 13.8 Boron
N.D.17440-43-9 06949 0.105 1.38 Cadmium
5,210 17440-70-2 01650 4.68 56.1 Calcium
62.5 17440-47-3 06951 0.220 4.13 Chromium
74.9 17440-50-8 06953 0.399 2.75 Copper
36,300 107439-89-6 01654 49.8 550 Iron
32.2 17439-92-1 06955 0.688 4.13 Lead
2,580 17439-95-4 01657 2.30 27.5 Magnesium
126 17439-96-5 06958 0.114 1.38 Manganese
27.3 17439-98-7 06960 0.234 2.75 Molybdenum
85.2 17440-02-0 06961 0.179 2.75 Nickel
5,720 17440-09-7 01662 11.5 138 Potassium
6.44 17782-49-2 06936 1.10 5.50 Selenium
N.D.17440-22-4 06966 0.234 1.38 Silver
822 17440-23-5 01667 23.0 275 Sodium
564 107440-24-6 07968 0.454 13.8 Strontium
N.D.17440-28-0 06925 0.715 8.25 Thallium
66.3 17440-66-6 06972 0.275 5.50 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.109 J 17439-97-6 00159 0.0141 0.282 Mercury
mg/kg mg/kgmg/kgWet Chemistry EPA 300.0
N.D.124959-67-907335 5.6 7.0 Bromide by IC (solid)
18.4 116887-00-607333 7.0 14.1 Chloride by IC (solid)
85.5 114808-79-807338 7.0 21.1 Sulfate by IC (solid)
Std. Units Std. UnitsStd. UnitsSW-846 9045D modified
7.56 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 22.3 C.
% %%Wet Chemistry SM 2540 G-1997
29.4 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 19 of 41

LL Sample # SW 7476728
LL Group # 1476968
Account # 10634
Sample Description: SS-GP2(72.0-76.0)-20140519 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/19/2014 09:30 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3109 SDG#: DUK31-09
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Antimony 06944
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Arsenic 06935
10Joanne M Gates05/30/2014 11:26 1414806370011SW-846 6010C Barium 06946
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Beryllium 06947
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Boron 07914
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Cadmium 06949
1Maria A Orrs06/02/2014 16:47 1415106370011SW-846 6010C Calcium 01650
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Chromium 06951
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Copper 06953
10Joanne M Gates05/30/2014 11:26 1414806370011SW-846 6010C Iron 01654
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Lead 06955
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Magnesium 01657
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Manganese 06958
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Molybdenum 06960
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Nickel 06961
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Potassium 01662
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Selenium 06936
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Silver 06966
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Sodium 01667
10Joanne M Gates05/30/2014 11:26 1414806370011SW-846 6010C Strontium 07968
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Thallium 06925
1Maria A Orrs05/29/2014 17:14 1414806370011SW-846 6010C Zinc 06972
1Damary Valentin05/29/2014 10:38 1414706380021SW-846 7471B Mercury 00159
1Annamaria Kuhns05/28/2014 22:42 1414806370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz06/02/2014 07:56 1415106370012SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1Denise K Conners05/28/2014 11:05 1414706380021SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Sandra J Miller05/30/2014 09:08 14149149202A1EPA 300.0 Bromide by IC (solid) 07335
1Sandra J Miller05/30/2014 09:08 14149149202A1EPA 300.0 Chloride by IC (solid) 07333
1Sandra J Miller05/30/2014 09:08 14149149202A1EPA 300.0 Sulfate by IC (solid) 07338
1James S Mathiot05/29/2014 20:45 14149149202A1EPA 300.0 Deionized Water
Extraction
01352
1Luz M Groff05/28/2014 21:10 14148039401B1SW-846 9045D
modified
pH 00394
1Scott W Freisher05/29/2014 18:33 14149820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 20 of 41

LL Sample # TL 7476729
LL Group # 1476968
Account # 10634
Sample Description: SS-GP2(72.0-76.0)-20140519 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/19/2014 09:30 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3110 SDG#: DUK31-10
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.0060 J 17440-36-0 07044 0.0053 0.0400 Antimony
0.258 17440-38-2 07035 0.0068 0.0400 Arsenic
0.146 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.340 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
8.24 17440-70-2 01750 0.0334 0.400 Calcium
0.0204 J 17440-47-3 07051 0.0016 0.0300 Chromium
0.0146 J 17440-50-8 07053 0.0027 0.0200 Copper
4.95 17439-89-6 01754 0.0430 0.400 Iron
0.0069 J 17439-92-1 07055 0.0047 0.0300 Lead
1.66 17439-95-4 01757 0.0167 0.200 Magnesium
0.0177 17439-96-5 07058 0.00083 0.0100 Manganese
0.688 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0185 J 17440-02-0 07061 0.0015 0.0200 Nickel
0.796 J 17440-09-7 01762 0.0980 1.00 Potassium
N.D.17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
15.1 17440-23-5 01767 0.167 2.00 Sodium
0.228 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0307 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Antimony 07044
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Arsenic 07035
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Barium 07046
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Beryllium 07047
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Boron 08014
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Cadmium 07049
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Calcium 01750
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 21 of 41

LL Sample # TL 7476729
LL Group # 1476968
Account # 10634
Sample Description: SS-GP2(72.0-76.0)-20140519 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/19/2014 09:30 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3110 SDG#: DUK31-10
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Copper 07053
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Iron 01754
1John W Yanzuk II06/04/2014 01:56 1415006360021SW-846 6010C Lead 07055
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Magnesium 01757
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Manganese 07058
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Molybdenum 07060
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Nickel 07061
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Potassium 01762
1John W Yanzuk II06/04/2014 01:56 1415006360021SW-846 6010C Selenium 07036
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Silver 07066
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Sodium 01767
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Strontium 08068
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Thallium 07022
1John W Yanzuk II06/02/2014 22:27 1415006360021SW-846 6010C Zinc 07072
1Parker D Lindstrom06/03/2014 17:26 1415057130071SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 09:08 1415006360021SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong06/02/2014 11:37 1415057130071SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber05/29/2014 12:00 14149-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 22 of 41

LL Sample # SW 7476730
LL Group # 1476968
Account # 10634
Sample Description: SS-GP2(52.0-56.0)-20140516 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/16/2014 15:30 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3111 SDG#: DUK31-11
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
1.16 J 17440-36-0 06944 1.01 5.45 Antimony
119 17440-38-2 06935 0.953 5.45 Arsenic
954 107440-39-3 06946 0.449 13.6 Barium
6.99 17440-41-7 06947 0.0912 1.36 Beryllium
54.3 17440-42-8 07914 1.14 13.6 Boron
N.D.17440-43-9 06949 0.103 1.36 Cadmium
3,710 17440-70-2 01650 4.50 53.9 Calcium
54.2 17440-47-3 06951 0.218 4.09 Chromium
72.7 17440-50-8 06953 0.395 2.72 Copper
33,900 57439-89-6 01654 24.6 272 Iron
34.9 17439-92-1 06955 0.681 4.09 Lead
2,890 17439-95-4 01657 2.27 27.2 Magnesium
127 17439-96-5 06958 0.113 1.36 Manganese
1.85 J 17439-98-7 06960 0.231 2.72 Molybdenum
40.8 17440-02-0 06961 0.177 2.72 Nickel
7,690 57440-09-7 01662 56.8 681 Potassium
7.99 17782-49-2 06936 1.09 5.45 Selenium
N.D.17440-22-4 06966 0.231 1.36 Silver
920 17440-23-5 01667 22.7 272 Sodium
493 57440-24-6 07968 0.225 6.81 Strontium
1.88 J 17440-28-0 06925 0.708 8.17 Thallium
57.9 17440-66-6 06972 0.272 5.45 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.110 J 17439-97-6 00159 0.0134 0.267 Mercury
mg/kg mg/kgmg/kgWet Chemistry EPA 300.0
N.D.124959-67-907335 5.5 6.9 Bromide by IC (solid)
27.7 116887-00-607333 6.9 13.8 Chloride by IC (solid)
41.5 114808-79-807338 6.9 20.6 Sulfate by IC (solid)
Std. Units Std. UnitsStd. UnitsSW-846 9045D modified
8.23 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 22.3 C.
% %%Wet Chemistry SM 2540 G-1997
28.7 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 23 of 41

LL Sample # SW 7476730
LL Group # 1476968
Account # 10634
Sample Description: SS-GP2(52.0-56.0)-20140516 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/16/2014 15:30 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3111 SDG#: DUK31-11
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Antimony 06944
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Arsenic 06935
10Joanne M Gates05/30/2014 11:50 1414806370011SW-846 6010C Barium 06946
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Beryllium 06947
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Boron 07914
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Cadmium 06949
1Maria A Orrs06/02/2014 16:51 1415106370011SW-846 6010C Calcium 01650
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Chromium 06951
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Copper 06953
5Joanne M Gates05/30/2014 11:38 1414806370011SW-846 6010C Iron 01654
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Lead 06955
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Magnesium 01657
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Manganese 06958
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Molybdenum 06960
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Nickel 06961
5Joanne M Gates05/30/2014 11:38 1414806370011SW-846 6010C Potassium 01662
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Selenium 06936
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Silver 06966
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Sodium 01667
5Joanne M Gates05/30/2014 11:38 1414806370011SW-846 6010C Strontium 07968
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Thallium 06925
1Maria A Orrs05/29/2014 17:18 1414806370011SW-846 6010C Zinc 06972
1Damary Valentin05/29/2014 10:40 1414706380021SW-846 7471B Mercury 00159
1Annamaria Kuhns05/28/2014 22:42 1414806370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz06/02/2014 07:56 1415106370012SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1Denise K Conners05/28/2014 11:05 1414706380021SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Sandra J Miller05/30/2014 09:57 14149149202A1EPA 300.0 Bromide by IC (solid) 07335
1Sandra J Miller05/30/2014 09:57 14149149202A1EPA 300.0 Chloride by IC (solid) 07333
1Sandra J Miller05/30/2014 09:57 14149149202A1EPA 300.0 Sulfate by IC (solid) 07338
1James S Mathiot05/29/2014 20:45 14149149202A1EPA 300.0 Deionized Water
Extraction
01352
1Luz M Groff05/28/2014 21:10 14148039401B1SW-846 9045D
modified
pH 00394
1Scott W Freisher05/29/2014 18:33 14149820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 24 of 41

LL Sample # TL 7476731
LL Group # 1476968
Account # 10634
Sample Description: SS-GP2(52.0-56.0)-20140516 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/16/2014 15:30 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3112 SDG#: DUK31-12
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
0.188 17440-38-2 07035 0.0068 0.0400 Arsenic
0.172 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0708 J 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
4.69 17440-70-2 01750 0.0334 0.400 Calcium
0.0036 J 17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.0492 J 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.584 17439-95-4 01757 0.0167 0.200 Magnesium
0.0021 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0039 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
0.680 J 17440-09-7 01762 0.0980 1.00 Potassium
0.0327 J 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
3.02 17440-23-5 01767 0.167 2.00 Sodium
0.194 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0034 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Antimony 07044
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Arsenic 07035
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Barium 07046
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Beryllium 07047
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Boron 08014
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Cadmium 07049
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Calcium 01750
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 25 of 41

LL Sample # TL 7476731
LL Group # 1476968
Account # 10634
Sample Description: SS-GP2(52.0-56.0)-20140516 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/16/2014 15:30 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3112 SDG#: DUK31-12
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Copper 07053
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Iron 01754
1John W Yanzuk II06/04/2014 02:00 1415006360021SW-846 6010C Lead 07055
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Magnesium 01757
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Manganese 07058
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Molybdenum 07060
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Nickel 07061
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Potassium 01762
1John W Yanzuk II06/04/2014 02:00 1415006360021SW-846 6010C Selenium 07036
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Silver 07066
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Sodium 01767
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Strontium 08068
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Thallium 07022
1John W Yanzuk II06/02/2014 22:31 1415006360021SW-846 6010C Zinc 07072
1Parker D Lindstrom06/03/2014 18:40 1415057130071SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 09:08 1415006360021SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong06/02/2014 11:37 1415057130071SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber05/29/2014 12:00 14149-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 26 of 41

LL Sample # SW 7476732
LL Group # 1476968
Account # 10634
Sample Description: SS-GP5(20.0-24.0)-20140521 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 11:50 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3113 SDG#: DUK31-13
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.868 4.69 Antimony
50.2 17440-38-2 06935 0.821 4.69 Arsenic
18.0 17440-39-3 06946 0.0387 1.17 Barium
2.97 17440-41-7 06947 0.0786 1.17 Beryllium
25.1 17440-42-8 07914 0.985 11.7 Boron
0.366 J 17440-43-9 06949 0.0892 1.17 Cadmium
242 17440-70-2 01650 3.88 46.5 Calcium
24.6 17440-47-3 06951 0.188 3.52 Chromium
27.7 17440-50-8 06953 0.340 2.35 Copper
216 17439-89-6 01654 4.25 46.9 Iron
14.1 17439-92-1 06955 0.587 3.52 Lead
1,290 17439-95-4 01657 1.96 23.5 Magnesium
56.1 17439-96-5 06958 0.0974 1.17 Manganese
0.704 J 17439-98-7 06960 0.199 2.35 Molybdenum
17.3 17440-02-0 06961 0.153 2.35 Nickel
57.0 J 17440-09-7 01662 9.78 117 Potassium
N.D.17782-49-2 06936 0.938 4.69 Selenium
0.377 J 17440-22-4 06966 0.199 1.17 Silver
415 17440-23-5 01667 19.6 235 Sodium
11.3 17440-24-6 07968 0.0387 1.17 Strontium
1.88 J 17440-28-0 06925 0.610 7.04 Thallium
25.8 17440-66-6 06972 0.235 4.69 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
N.D.17439-97-6 00159 0.0113 0.226 Mercury
mg/kg mg/kgmg/kgWet Chemistry EPA 300.0
N.D.124959-67-907335 4.8 5.9 Bromide by IC (solid)
35.6 116887-00-607333 5.9 11.9 Chloride by IC (solid)
6.0 J 114808-79-807338 5.9 17.8 Sulfate by IC (solid)
Std. Units Std. UnitsStd. UnitsSW-846 9045D modified
7.58 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 22.3 C.
% %%Wet Chemistry SM 2540 G-1997
15.6 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 27 of 41

LL Sample # SW 7476732
LL Group # 1476968
Account # 10634
Sample Description: SS-GP5(20.0-24.0)-20140521 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 11:50 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3113 SDG#: DUK31-13
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Antimony 06944
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Arsenic 06935
1Katlin N Cataldi05/31/2014 09:19 1414806370012SW-846 6010C Barium 06946
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Beryllium 06947
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Boron 07914
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Cadmium 06949
1Eric L Eby06/03/2014 11:06 1415106370011SW-846 6010C Calcium 01650
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Chromium 06951
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Copper 06953
1Katlin N Cataldi05/31/2014 09:19 1414806370012SW-846 6010C Iron 01654
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Lead 06955
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Magnesium 01657
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Manganese 06958
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Molybdenum 06960
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Nickel 06961
1Katlin N Cataldi05/31/2014 09:19 1414806370012SW-846 6010C Potassium 01662
1Katlin N Cataldi05/31/2014 09:19 1414806370012SW-846 6010C Selenium 06936
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Silver 06966
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Sodium 01667
1Katlin N Cataldi05/31/2014 09:19 1414806370012SW-846 6010C Strontium 07968
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Thallium 06925
1Joanne M Gates05/30/2014 11:58 1414806370012SW-846 6010C Zinc 06972
1Damary Valentin05/29/2014 10:42 1414706380021SW-846 7471B Mercury 00159
1Annamaria Kuhns05/28/2014 22:42 1414806370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz06/02/2014 07:56 1415106370012SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1Denise K Conners05/28/2014 11:05 1414706380021SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Sandra J Miller05/30/2014 10:13 14149149202A1EPA 300.0 Bromide by IC (solid) 07335
1Sandra J Miller05/30/2014 10:13 14149149202A1EPA 300.0 Chloride by IC (solid) 07333
1Sandra J Miller05/30/2014 10:13 14149149202A1EPA 300.0 Sulfate by IC (solid) 07338
1James S Mathiot05/29/2014 20:45 14149149202A1EPA 300.0 Deionized Water
Extraction
01352
1Luz M Groff05/28/2014 21:10 14148039401B1SW-846 9045D
modified
pH 00394
1Scott W Freisher05/29/2014 18:33 14149820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 28 of 41

LL Sample # TL 7476733
LL Group # 1476968
Account # 10634
Sample Description: SS-GP5(20.0-24.0)-20140521 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 11:50 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3114 SDG#: DUK31-14
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
0.0120 J 17440-38-2 07035 0.0068 0.0400 Arsenic
0.0366 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0699 J 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
1.88 17440-70-2 01750 0.0334 0.400 Calcium
0.0019 J 17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.227 J 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.536 17439-95-4 01757 0.0167 0.200 Magnesium
0.0040 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0084 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
0.136 J 17440-09-7 01762 0.0980 1.00 Potassium
N.D.17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
6.62 17440-23-5 01767 0.167 2.00 Sodium
0.0323 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0064 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Antimony 07044
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Arsenic 07035
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Barium 07046
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Beryllium 07047
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Boron 08014
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Cadmium 07049
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Calcium 01750
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 29 of 41

LL Sample # TL 7476733
LL Group # 1476968
Account # 10634
Sample Description: SS-GP5(20.0-24.0)-20140521 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 11:50 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3114 SDG#: DUK31-14
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Copper 07053
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Iron 01754
1John W Yanzuk II06/04/2014 02:04 1415006360021SW-846 6010C Lead 07055
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Magnesium 01757
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Manganese 07058
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Molybdenum 07060
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Nickel 07061
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Potassium 01762
1John W Yanzuk II06/04/2014 02:04 1415006360021SW-846 6010C Selenium 07036
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Silver 07066
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Sodium 01767
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Strontium 08068
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Thallium 07022
1John W Yanzuk II06/02/2014 22:35 1415006360021SW-846 6010C Zinc 07072
1Parker D Lindstrom06/03/2014 18:42 1415057130071SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 09:08 1415006360021SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong06/02/2014 11:37 1415057130071SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber05/29/2014 12:00 14149-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 30 of 41

LL Sample # SW 7476734
LL Group # 1476968
Account # 10634
Sample Description: SS-GP6(24.0-28.0)-20140521 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 14:00 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3115 SDG#: DUK31-15
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.837 4.52 Antimony
2.06 J 17440-38-2 06935 0.792 4.52 Arsenic
1.92 17440-39-3 06946 0.0373 1.13 Barium
N.D.17440-41-7 06947 0.0758 1.13 Beryllium
7.79 J 17440-42-8 07914 0.950 11.3 Boron
N.D.17440-43-9 06949 0.0859 1.13 Cadmium
64.7 17440-70-2 01650 3.67 43.9 Calcium
0.727 J 17440-47-3 06951 0.181 3.39 Chromium
N.D.17440-50-8 06953 0.328 2.26 Copper
424 17439-89-6 01654 4.09 45.2 Iron
37.1 17439-95-4 01657 1.89 22.6 Magnesium
2.45 17439-96-5 06958 0.0939 1.13 Manganese
N.D.17439-98-7 06960 0.192 2.26 Molybdenum
0.401 J 17440-02-0 06961 0.147 2.26 Nickel
42.9 J 17440-09-7 01662 9.43 113 Potassium
N.D.17782-49-2 06936 0.905 4.52 Selenium
N.D.17440-22-4 06966 0.192 1.13 Silver
N.D.17440-23-5 01667 18.9 226 Sodium
2.12 17440-24-6 07968 0.0362 1.10 Strontium
N.D.17440-28-0 06925 0.588 6.78 Thallium
1.10 J 17440-66-6 06972 0.226 4.52 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
N.D.17439-97-6 00159 0.0115 0.230 Mercury
mg/kg mg/kgmg/kgWet Chemistry EPA 300.0
N.D.124959-67-907335 4.7 5.8 Bromide by IC (solid)
17.0 116887-00-607333 5.8 11.7 Chloride by IC (solid)
18.2 114808-79-807338 5.8 17.5 Sulfate by IC (solid)
Std. Units Std. UnitsStd. UnitsSW-846 9045D modified
7.87 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 21.9 C.
% %%Wet Chemistry SM 2540 G-1997
13.3 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 31 of 41

LL Sample # SW 7476734
LL Group # 1476968
Account # 10634
Sample Description: SS-GP6(24.0-28.0)-20140521 Grab Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 14:00 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3115 SDG#: DUK31-15
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Antimony 06944
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Arsenic 06935
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Barium 06946
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Beryllium 06947
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Boron 07914
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Cadmium 06949
1Eric L Eby06/03/2014 11:10 1415106370011SW-846 6010C Calcium 01650
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Chromium 06951
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Copper 06953
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Iron 01654
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Magnesium 01657
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Manganese 06958
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Molybdenum 06960
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Nickel 06961
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Potassium 01662
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Selenium 06936
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Silver 06966
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Sodium 01667
1Maria A Orrs06/02/2014 16:59 1415106370011SW-846 6010C Strontium 07968
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Thallium 06925
1Maria A Orrs05/29/2014 17:27 1414806370011SW-846 6010C Zinc 06972
1Damary Valentin05/29/2014 10:44 1414706380021SW-846 7471B Mercury 00159
1Annamaria Kuhns05/28/2014 22:42 1414806370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz06/02/2014 07:56 1415106370012SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1Denise K Conners05/28/2014 11:05 1414706380021SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Sandra J Miller05/30/2014 07:15 14149149202A1EPA 300.0 Bromide by IC (solid) 07335
1Sandra J Miller05/30/2014 07:15 14149149202A1EPA 300.0 Chloride by IC (solid) 07333
1Sandra J Miller05/30/2014 07:15 14149149202A1EPA 300.0 Sulfate by IC (solid) 07338
1James S Mathiot05/29/2014 20:45 14149149202A1EPA 300.0 Deionized Water
Extraction
01352
1Luz M Groff05/28/2014 22:00 14148039402A1SW-846 9045D
modified
pH 00394
1Scott W Freisher05/29/2014 18:33 14149820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 32 of 41

LL Sample # TL 7476735
LL Group # 1476968
Account # 10634
Sample Description: SS-GP6(24.0-28.0)-20140521 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 14:00 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3116 SDG#: DUK31-16*
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
0.0102 J 17440-38-2 07035 0.0068 0.0400 Arsenic
0.0327 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0498 J 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
1.23 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.552 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.487 17439-95-4 01757 0.0167 0.200 Magnesium
0.0018 J 17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
0.124 J 17440-09-7 01762 0.0980 1.00 Potassium
N.D.17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
3.40 17440-23-5 01767 0.167 2.00 Sodium
0.0255 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0062 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Antimony 07044
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Arsenic 07035
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Barium 07046
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Beryllium 07047
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Boron 08014
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Cadmium 07049
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Calcium 01750
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 33 of 41

LL Sample # TL 7476735
LL Group # 1476968
Account # 10634
Sample Description: SS-GP6(24.0-28.0)-20140521 Grab Solid Sample
SPLP Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/21/2014 14:00 by WS
Submitted: 05/24/2014 09:30
GeoSyntec Consultants
Reported: 06/04/2014 13:01
4601 Six Forks Road
Suite 340
Raleigh NC 27609
D3116 SDG#: DUK31-16*
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Copper 07053
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Iron 01754
1John W Yanzuk II06/04/2014 02:07 1415006360021SW-846 6010C Lead 07055
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Magnesium 01757
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Manganese 07058
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Molybdenum 07060
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Nickel 07061
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Potassium 01762
1John W Yanzuk II06/04/2014 02:07 1415006360021SW-846 6010C Selenium 07036
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Silver 07066
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Sodium 01767
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Strontium 08068
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Thallium 07022
1John W Yanzuk II06/02/2014 22:38 1415006360021SW-846 6010C Zinc 07072
1Parker D Lindstrom06/03/2014 18:44 1415057130071SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 09:08 1415006360021SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong06/02/2014 11:37 1415057130071SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber05/29/2014 12:00 14149-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 34 of 41

Page 1 of 4

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1476968
Reported: 06/04/14 at 01:01 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Matrix QC may not be reported if insufficient sample or site-specific QC samples were not submitted. In these
situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise
specified in the method.

All Inorganic Initial Calibration and Continuing Calibration Blanks met acceptable method criteria unless
otherwise noted on the Analysis Report.

Laboratory Compliance Quality Control

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Batch number: 141470638002 Sample number(s):
7476720,7476722,7476724,7476726,7476728,7476730,7476732,7476734

Mercury N.D. 0.0100 0.200 mg/kg 92 80-120

Batch number: 141480637001 Sample number(s):
7476720,7476722,7476724,7476726,7476728,7476730,7476732,7476734

Antimony N.D. 0.740 4.00 mg/kg 106 80-120
Arsenic N.D. 0.700 4.00 mg/kg 106 80-120
Barium 0.0830 J 0.0330 1.00 mg/kg 102 80-120
Beryllium N.D. 0.0670 1.00 mg/kg 102 80-120
Boron 4.92 J 0.840 10.0 mg/kg 101 80-120
Cadmium N.D. 0.0760 1.00 mg/kg 105 80-120
Chromium N.D. 0.160 3.00 mg/kg 101 80-120
Copper N.D. 0.290 2.00 mg/kg 106 80-120
Iron N.D. 3.62 40.0 mg/kg 106 80-120
Lead N.D. 0.500 3.00 mg/kg 111 80-120
Magnesium N.D. 1.67 20.0 mg/kg 100 80-120
Manganese N.D. 0.0830 1.00 mg/kg 105 80-120
Molybdenum N.D. 0.170 2.00 mg/kg 104 80-120
Nickel N.D. 0.130 2.00 mg/kg 110 80-120
Potassium N.D. 8.34 100 mg/kg 99 80-120
Selenium N.D. 0.800 4.00 mg/kg 102 80-120
Silver N.D. 0.170 1.00 mg/kg 110 80-120
Sodium N.D. 16.7 200 mg/kg 99 80-120
Strontium 0.593 J 0.0330 1.00 mg/kg 105 80-120
Thallium N.D. 0.520 6.00 mg/kg 107 80-120
Zinc N.D. 0.200 4.00 mg/kg 104 80-120

Batch number: 141500636002 Sample number(s):
7476721,7476723,7476725,7476727,7476729,7476731,7476733,7476735

Antimony N.D. 0.0053 0.0400 mg/l 104 80-120
Arsenic N.D. 0.0068 0.0400 mg/l 103 80-120
Barium N.D. 0.00033 0.0100 mg/l 99 80-120
Beryllium N.D. 0.00067 0.0100 mg/l 99 80-120
Boron N.D. 0.0084 0.100 mg/l 94 80-120
Cadmium N.D. 0.00076 0.0100 mg/l 102 80-120
Calcium N.D. 0.0334 0.400 mg/l 103 80-120
Chromium N.D. 0.0016 0.0300 mg/l 100 80-120
Copper N.D. 0.0027 0.0200 mg/l 102 80-120
Iron N.D. 0.0430 0.400 mg/l 102 80-120
Lead N.D. 0.0047 0.0300 mg/l 109 80-120
Magnesium N.D. 0.0167 0.200 mg/l 100 80-120
Manganese N.D. 0.00083 0.0100 mg/l 100 80-120
Molybdenum N.D. 0.0017 0.0200 mg/l 103 80-120
Page 35 of 41

Page 2 of 4

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1476968
Reported: 06/04/14 at 01:01 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max
Nickel N.D. 0.0015 0.0200 mg/l 106 80-120
Potassium N.D. 0.0980 1.00 mg/l 102 80-120
Selenium N.D. 0.0084 0.0400 mg/l 98 80-120
Silver N.D. 0.0021 0.0100 mg/l 104 80-120
Sodium 0.479 J 0.167 2.00 mg/l 105 80-120
Strontium N.D. 0.00033 0.0100 mg/l 101 80-120
Thallium N.D. 0.0054 0.0600 mg/l 104 80-120
Zinc N.D. 0.0020 0.0400 mg/l 101 80-120

Batch number: 141505713007 Sample number(s):
7476721,7476723,7476725,7476727,7476729,7476731,7476733,7476735

Mercury N.D. 0.00006
0
0.00020 mg/l 106 80-120

Batch number: 141510637001 Sample number(s):
7476720,7476722,7476724,7476726,7476728,7476730,7476732,7476734

Calcium 8.72 J 3.34 40.0 mg/kg 110 80-120
Strontium 0.0440 J 0.0330 1.00 mg/kg 103 80-120

Batch number: 14149149202A Sample number(s):
7476720,7476722,7476724,7476726,7476728,7476730,7476732,7476734

Bromide by IC (solid) N.D. 4.0 5.0 mg/kg 94 90-110
Chloride by IC (solid) N.D. 5.0 10.0 mg/kg 93 90-110
Sulfate by IC (solid) N.D. 5.0 15.0 mg/kg 96 90-110

Batch number: 14148039401B Sample number(s): 7476720,7476722,7476724,7476726,7476728,7476730,7476732
pH 100 90-110

Batch number: 14148039402A Sample number(s): 7476734
pH 100 90-110

Batch number: 14149820002B Sample number(s):
7476720,7476722,7476724,7476726,7476728,7476730,7476732,7476734

Moisture 100 99-101

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 141470638002 Sample number(s):
7476720,7476722,7476724,7476726,7476728,7476730,7476732,7476734 UNSPK: P473954
BKG: P473954
Mercury 97 97 80-120 5 20 0.0367 J 0.0309 J 17 (1) 20

Batch number: 141480637001 Sample number(s):
7476720,7476722,7476724,7476726,7476728,7476730,7476732,7476734 UNSPK: P473954
BKG: P473954
Antimony 99 98 75-125 1 20 N.D. N.D. 0 (1) 20
Arsenic 94 95 75-125 1 20 8.18 10.9 29* (1) 20
Barium 104 106 75-125 2 20 22.8 38.0 50* 20
Page 36 of 41

Page 3 of 4

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1476968
Reported: 06/04/14 at 01:01 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___
Beryllium 105 102 83-119 3 20 0.178 J 0.229 J 25* (1) 20
Boron 97 96 84-110 0 20 9.11 J 7.18 J 24* (1) 20
Cadmium 101 101 75-120 0 20 N.D. N.D. 0 (1) 20
Chromium 105 111 75-125 4 20 5.18 5.81 11 (1) 20
Copper 92 119 75-125 13 20 27.4 27.4 0 20
Iron -13104
(2)
-12352
(2)
75-125 10 20 20,500 10,900 61* 20
Lead 70* 117 75-125 13 20 40.3 53.7 28* 20
Magnesium 81 13* 75-125 16 20 769 608 23* 20
Manganese -82* -108* 75-125 9 20 187 108 54* 20
Molybdenum 100 99 82-110 1 20 0.892 J 1.07 J 18 (1) 20
Nickel 107 112 75-125 4 20 12.2 14.0 14 20
Potassium 121 119 75-125 2 20 265 360 31* (1) 20
Selenium 101 102 75-125 1 20 1.30 J 2.89 J 76* (1) 20
Silver 107 107 75-125 0 20 N.D. N.D. 0 (1) 20
Sodium 117 104 75-125 10 20 239 264 10 (1) 20
Strontium 111 108 81-125 3 20 17.4 20.3 15 20
Thallium 93 96 78-119 3 20 0.881 J N.D. 200* (1) 20
Zinc 122 108 75-125 8 20 29.3 50.4 53* 20

Batch number: 141500636002 Sample number(s):
7476721,7476723,7476725,7476727,7476729,7476731,7476733,7476735 UNSPK: P462441
BKG: P462441
Antimony 90 91 75-125 1 20 N.D. N.D. 0 (1) 20
Arsenic 90 91 75-125 1 20 N.D. N.D. 0 (1) 20
Barium 87 96 75-125 9 20 0.0056 J 0.0055 J 0 (1) 20
Beryllium 87 86 75-125 0 20 N.D. N.D. 0 (1) 20
Boron 86 87 75-125 1 20 0.0180 J 0.0145 J 21* (1) 20
Cadmium 87 88 75-125 1 20 N.D. N.D. 0 (1) 20
Calcium 91 92 75-125 1 20 0.199 J 0.177 J 12 (1) 20
Chromium 87 88 75-125 1 20 N.D. N.D. 0 (1) 20
Copper 89 89 75-125 0 20 N.D. N.D. 0 (1) 20
Iron 89 89 75-125 0 20 N.D. N.D. 0 (1) 20
Lead 85 86 75-125 0 20 N.D. N.D. 0 (1) 20
Magnesium 89 90 75-125 1 20 0.0366 J 0.0374 J 2 (1) 20
Manganese 87 88 75-125 1 20 0.0014 J 0.0013 J 8 (1) 20
Molybdenum 89 90 75-125 1 20 N.D. N.D. 0 (1) 20
Nickel 86 87 75-125 1 20 N.D. N.D. 0 (1) 20
Potassium 93 94 75-125 1 20 N.D. N.D. 0 (1) 20
Selenium 88 88 75-125 1 20 N.D. N.D. 0 (1) 20
Silver 76 77 75-125 1 20 N.D. N.D. 0 (1) 20
Sodium 91 91 75-125 1 20 1.36 J 1.37 J 0 (1) 20
Strontium 84 84 75-125 0 20 0.00083 J 0.00074 J 11 (1) 20
Thallium 83 84 75-125 1 20 N.D. N.D. 0 (1) 20
Zinc 87 88 75-125 1 20 0.0063 J 0.0050 J 23* (1) 20

Batch number: 141505713007 Sample number(s):
7476721,7476723,7476725,7476727,7476729,7476731,7476733,7476735 UNSPK: P462441
BKG: P462441
Mercury 82 82 80-120 0 20 N.D. N.D. 0 (1) 20

Batch number: 141510637001 Sample number(s):
Page 37 of 41

Page 4 of 4

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1476968
Reported: 06/04/14 at 01:01 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___
7476720,7476722,7476724,7476726,7476728,7476730,7476732,7476734 UNSPK: 7476720
BKG: 7476720
Calcium 255 (2) 251 (2) 75-125 0 20 2,250 2,690 18 20
Strontium 148* 150* 81-125 1 20 221 264 17 20

Batch number: 14149149202A Sample number(s):
7476720,7476722,7476724,7476726,7476728,7476730,7476732,7476734 UNSPK: 7476734
BKG: 7476734
Bromide by IC (solid) 92 90-110 N.D. N.D. 0 (1) 20
Chloride by IC (solid) 72* 90-110 14.8 12.4 18 (1) 20
Sulfate by IC (solid) 86* 90-110 15.7 13.2 J 17 (1) 20

Batch number: 14148039401B Sample number(s): 7476720,7476722,7476724,7476726,7476728,7476730,7476732 BKG:
P470803
pH 7.13 7.15 0 3

Batch number: 14148039402A Sample number(s): 7476734 BKG: 7476734
pH 7.87 7.90 0 3

Batch number: 14149820002B Sample number(s):
7476720,7476722,7476724,7476726,7476728,7476730,7476732,7476734 BKG: P476574
Moisture 17.9 17.1 5 5

Page 38 of 41
Page 39 of 41
Page 40 of 41
Explanation of Symbols and Abbreviations

3768 0713
The following defines common symbols and abbreviations used in reporting technical data:
RL Reporting Limit BMQL Below Minimum Quantitation Level
N.D. none detected MPN Most Probable Number
TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units
IU International Units NTU nephelometric turbidity units
umhos/cm micromhos/cm ng nanogram(s)
C degrees Celsius F degrees Fahrenheit
meq milliequivalents lb. pound(s)
g gram(s) kg kilogram(s)
µg microgram(s) mg milligram(s)
mL milliliter(s) L liter(s)
m3 cubic meter(s) µL microliter(s)
pg/L picogram/liter
< less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be
reliably determined using this specific test.
> greater than
ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For
aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/l), because one liter of water has a
weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter per liter of gas.
ppb parts per billion
Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight
basis concentration to approximate the value present in a similar sample without moisture. All other results are reported
on an as-received basis.
Data Qualifiers:
C – result confirmed by reanalysis.
J - estimated value – The result is ≥ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ).
U.S. EPA CLP Data Qualifiers:
Organic Qualifiers Inorganic Qualifiers
A TIC is a possible aldol-condensation product B Value is <CRDL, but ≥IDL
B Analyte was also detected in the blank E Estimated due to interference
C Pesticide result confirmed by GC/MS M Duplicate injection precision not met
D Compound quantitated on a diluted sample N Spike sample not within control limits
E Concentration exceeds the calibration range of S Method of standard additions (MSA) used
the instrument for calculation
N Presumptive evidence of a compound (TICs only) U Compound was not detected
P Concentration difference between primary and W Post digestion spike out of control limits
confirmation columns >25% * Duplicate analysis not within control limits
U Compound was not detected + Correlation coefficient for MSA <0.995
X,Y,Z Defined in case narrative
Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.
Measurement uncertainty values, as applicable, are available upon request.
Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the
test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact
us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our
staff. This report shall not be reproduced except in full, without the written approval of the laboratory.
Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as “analyze immediately” are not
performed within 15 minutes.

WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE
FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM
ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF
MERCHANTABILITY. IN NO EVENT SHALL EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL, LLC BE LIABLE FOR INDIRECT, SPECIAL,
CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS
OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL AND (B) WHETHER
EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal
responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Eurofins Lancaster
Laboratories Environmental which includes any conditions that vary from the Standard Terms and Conditions, and Eurofins Lancaster Laboratories
Environmental hereby objects to any conflicting terms contained in any acceptance or order submitted by client.
Page 41 of 41

ANALYTICAL RESULTS

Prepared by:

Eurofins Lancaster Laboratories Environmental
2425 New Holland Pike
Lancaster, PA 17601
Prepared for:

GeoSyntec Consultants
4601 Six Forks Road
Suite 340
Raleigh NC 27609

June 04, 2014

Project: Duke Sutton, NC

Submittal Date: 05/28/2014
Group Number: 1477503
SDG: DUK32
PO Number: GC5592
State of Sample Origin: NC

Client Sample Description Lancaster Labs (LL) #
MW-3B-20140527 Groundwater Sample 7479328
MW-31B-20140527 Groundwater Sample 7479329
PZ-25-20140527 Groundwater Sample 7479330
MW-34B-20140527 Groundwater Sample 7479331

The specific methodologies used in obtaining the enclosed analytical results are indicated on the
Laboratory Sample Analysis Record.

ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Lauren Wellborn
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Beau Hodge
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Rachel Donahue
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Herwig Goldemund

Page 1 of 15

Respectfully Submitted,

[phone]

Page 2 of 15

LL Sample # WW 7479328
LL Group # 1477503
Account # 10634
Sample Description: MW-3B-20140527 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/27/2014 10:14
Submitted: 05/28/2014 11:15
GeoSyntec Consultants
Reported: 06/04/2014 09:45
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSM3B SDG#: DUK32-01
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0058 J 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.446 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
12.0 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
N.D.17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
2.27 17439-95-4 01757 0.0167 0.200 Magnesium
0.0185 17439-96-5 07058 0.00083 0.0100 Manganese
0.329 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
3.58 17440-09-7 01762 0.0980 1.00 Potassium
N.D.17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
3.06 17440-23-5 01767 0.167 2.00 Sodium
0.346 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
N.D.17440-62-2 07071 0.0020 0.0100 Vanadium
N.D.17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
3.9 516887-00-600224 1.0 2.0 Chloride
0.77 514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
16.0 514808-79-800228 1.5 5.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
27.3 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
61.0 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 3 of 15

LL Sample # WW 7479328
LL Group # 1477503
Account # 10634
Sample Description: MW-3B-20140527 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/27/2014 10:14
Submitted: 05/28/2014 11:15
GeoSyntec Consultants
Reported: 06/04/2014 09:45
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSM3B SDG#: DUK32-01
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Antimony 07044
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Arsenic 07035
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Barium 07046
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Beryllium 07047
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Boron 08014
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Cadmium 07049
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Calcium 01750
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Chromium 07051
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Copper 07053
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Iron 01754
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Lead 07055
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Magnesium 01757
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Manganese 07058
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Molybdenum 07060
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Nickel 07061
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Potassium 01762
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Selenium 07036
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Silver 07066
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Sodium 01767
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Strontium 08068
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Thallium 07022
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Vanadium 07071
1Katlin N Cataldi06/02/2014 19:50 1415106350011SW-846 6010C Zinc 07072
1Parker D Lindstrom06/03/2014 19:21 1415057130121SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 10:04 1415106350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong06/02/2014 14:13 1415057130121SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/29/2014 07:16 14149347601A1EPA 300.0 Bromide 01505
5Sandra J Miller05/29/2014 07:16 14149347601A1EPA 300.0 Chloride 00224
5Sandra J Miller05/29/2014 07:16 14149347601A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/29/2014 07:16 14149347601A1EPA 300.0 Nitrite Nitrogen 01506
5Sandra J Miller05/29/2014 07:16 14149347601A1EPA 300.0 Sulfate 00228
1Michele L Graham05/30/2014 22:06 14150002104A1EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch05/30/2014 09:14 14150021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 4 of 15

LL Sample # WW 7479329
LL Group # 1477503
Account # 10634
Sample Description: MW-31B-20140527 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/27/2014 14:20
Submitted: 05/28/2014 11:15
GeoSyntec Consultants
Reported: 06/04/2014 09:45
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS31B SDG#: DUK32-02
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0336 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.268 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
11.8 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
1.39 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
2.35 17439-95-4 01757 0.0167 0.200 Magnesium
0.0461 17439-96-5 07058 0.00083 0.0100 Manganese
0.0047 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
2.50 17440-09-7 01762 0.0980 1.00 Potassium
N.D.17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
8.84 17440-23-5 01767 0.167 2.00 Sodium
0.243 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
N.D.17440-62-2 07071 0.0020 0.0100 Vanadium
0.0042 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
15.6 516887-00-600224 1.0 2.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
19.5 514808-79-800228 1.5 5.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
15.9 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
81.5 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 5 of 15

LL Sample # WW 7479329
LL Group # 1477503
Account # 10634
Sample Description: MW-31B-20140527 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/27/2014 14:20
Submitted: 05/28/2014 11:15
GeoSyntec Consultants
Reported: 06/04/2014 09:45
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS31B SDG#: DUK32-02
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Antimony 07044
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Arsenic 07035
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Barium 07046
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Beryllium 07047
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Boron 08014
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Cadmium 07049
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Calcium 01750
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Chromium 07051
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Copper 07053
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Iron 01754
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Lead 07055
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Magnesium 01757
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Manganese 07058
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Molybdenum 07060
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Nickel 07061
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Potassium 01762
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Selenium 07036
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Silver 07066
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Sodium 01767
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Strontium 08068
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Thallium 07022
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Vanadium 07071
1Katlin N Cataldi06/02/2014 19:24 1415106350011SW-846 6010C Zinc 07072
1Parker D Lindstrom06/03/2014 19:33 1415057130121SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 10:04 1415106350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong06/02/2014 14:13 1415057130121SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/29/2014 08:04 14149347601A1EPA 300.0 Bromide 01505
5Sandra J Miller05/29/2014 08:04 14149347601A1EPA 300.0 Chloride 00224
5Sandra J Miller05/29/2014 08:04 14149347601A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/29/2014 08:04 14149347601A1EPA 300.0 Nitrite Nitrogen 01506
5Sandra J Miller05/29/2014 08:04 14149347601A1EPA 300.0 Sulfate 00228
1Michele L Graham05/31/2014 00:35 14150002104A1EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch05/30/2014 09:14 14150021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 6 of 15

LL Sample # WW 7479330
LL Group # 1477503
Account # 10634
Sample Description: PZ-25-20140527 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/27/2014 15:36
Submitted: 05/28/2014 11:15
GeoSyntec Consultants
Reported: 06/04/2014 09:45
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSP25 SDG#: DUK32-03
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0115 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0093 J 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
1.18 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.0572 J 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.324 17439-95-4 01757 0.0167 0.200 Magnesium
0.0112 17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
0.493 J 17440-09-7 01762 0.0980 1.00 Potassium
N.D.17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
1.33 J 17440-23-5 01767 0.167 2.00 Sodium
0.0082 J 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
N.D.17440-62-2 07071 0.0020 0.0100 Vanadium
0.0026 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
3.2 516887-00-600224 1.0 2.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
5.9 514808-79-800228 1.5 5.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
N.D.1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
10.0 J 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 7 of 15

LL Sample # WW 7479330
LL Group # 1477503
Account # 10634
Sample Description: PZ-25-20140527 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/27/2014 15:36
Submitted: 05/28/2014 11:15
GeoSyntec Consultants
Reported: 06/04/2014 09:45
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DSP25 SDG#: DUK32-03
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Antimony 07044
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Arsenic 07035
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Barium 07046
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Beryllium 07047
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Boron 08014
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Cadmium 07049
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Calcium 01750
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Chromium 07051
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Copper 07053
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Iron 01754
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Lead 07055
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Magnesium 01757
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Manganese 07058
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Molybdenum 07060
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Nickel 07061
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Potassium 01762
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Selenium 07036
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Silver 07066
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Sodium 01767
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Strontium 08068
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Thallium 07022
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Vanadium 07071
1Katlin N Cataldi06/02/2014 20:01 1415106350011SW-846 6010C Zinc 07072
1Parker D Lindstrom06/03/2014 19:35 1415057130121SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 10:04 1415106350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong06/02/2014 14:13 1415057130121SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/29/2014 08:20 14149347601A1EPA 300.0 Bromide 01505
5Sandra J Miller05/29/2014 08:20 14149347601A1EPA 300.0 Chloride 00224
5Sandra J Miller05/29/2014 08:20 14149347601A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/29/2014 08:20 14149347601A1EPA 300.0 Nitrite Nitrogen 01506
5Sandra J Miller05/29/2014 08:20 14149347601A1EPA 300.0 Sulfate 00228
1Michele L Graham05/30/2014 21:20 14150002103A1EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch05/30/2014 09:14 14150021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 8 of 15

LL Sample # WW 7479331
LL Group # 1477503
Account # 10634
Sample Description: MW-34B-20140527 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/27/2014 17:50
Submitted: 05/28/2014 11:15
GeoSyntec Consultants
Reported: 06/04/2014 09:45
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS34B SDG#: DUK32-04*
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0173 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.223 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
25.9 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.115 J 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
2.94 17439-95-4 01757 0.0167 0.200 Magnesium
0.0085 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0376 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
5.25 17440-09-7 01762 0.0980 1.00 Potassium
0.0359 J 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
28.1 17440-23-5 01767 0.167 2.00 Sodium
0.230 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
N.D.17440-62-2 07071 0.0020 0.0100 Vanadium
0.0043 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
34.7 1016887-00-600224 2.0 4.0 Chloride
1.1 514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
62.3 514808-79-800228 1.5 5.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
24.3 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
164 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 9 of 15

LL Sample # WW 7479331
LL Group # 1477503
Account # 10634
Sample Description: MW-34B-20140527 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/27/2014 17:50
Submitted: 05/28/2014 11:15
GeoSyntec Consultants
Reported: 06/04/2014 09:45
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS34B SDG#: DUK32-04*
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Antimony 07044
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Arsenic 07035
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Barium 07046
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Beryllium 07047
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Boron 08014
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Cadmium 07049
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Calcium 01750
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Chromium 07051
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Copper 07053
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Iron 01754
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Lead 07055
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Magnesium 01757
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Manganese 07058
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Molybdenum 07060
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Nickel 07061
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Potassium 01762
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Selenium 07036
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Silver 07066
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Sodium 01767
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Strontium 08068
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Thallium 07022
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Vanadium 07071
1Katlin N Cataldi06/02/2014 20:04 1415106350011SW-846 6010C Zinc 07072
1Parker D Lindstrom06/03/2014 19:37 1415057130121SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 10:04 1415106350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong06/02/2014 14:13 1415057130121SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/29/2014 08:36 14149347601A1EPA 300.0 Bromide 01505
10Sandra J Miller05/29/2014 18:02 14149347601A1EPA 300.0 Chloride 00224
5Sandra J Miller05/29/2014 08:36 14149347601A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/29/2014 08:36 14149347601A1EPA 300.0 Nitrite Nitrogen 01506
5Sandra J Miller05/29/2014 08:36 14149347601A1EPA 300.0 Sulfate 00228
1Michele L Graham05/30/2014 21:26 14150002103A1EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch05/30/2014 09:14 14150021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 10 of 15

Page 1 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1477503
Reported: 06/04/14 at 09:45 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Matrix QC may not be reported if insufficient sample or site-specific QC samples were not submitted. In these
situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise
specified in the method.

All Inorganic Initial Calibration and Continuing Calibration Blanks met acceptable method criteria unless
otherwise noted on the Analysis Report.

Laboratory Compliance Quality Control

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Batch number: 141505713012 Sample number(s): 7479328-7479331
Mercury N.D. 0.00006
0
0.00020 mg/l 111 80-120

Batch number: 141510635001 Sample number(s): 7479328-7479331
Antimony N.D. 0.0053 0.0400 mg/l 107 88-111
Arsenic N.D. 0.0068 0.0400 mg/l 112 90-113
Barium N.D. 0.00033 0.0100 mg/l 105 90-110
Beryllium N.D. 0.00067 0.0100 mg/l 103 90-111
Boron N.D. 0.0084 0.100 mg/l 100 90-110
Cadmium N.D. 0.00076 0.0100 mg/l 106 90-112
Calcium N.D. 0.0334 0.400 mg/l 105 90-112
Chromium N.D. 0.0016 0.0300 mg/l 104 90-110
Copper N.D. 0.0027 0.0200 mg/l 106 90-112
Iron N.D. 0.0430 0.400 mg/l 106 90-112
Lead N.D. 0.0047 0.0300 mg/l 109 88-116
Magnesium N.D. 0.0167 0.200 mg/l 105 89-110
Manganese N.D. 0.00083 0.0100 mg/l 106 90-110
Molybdenum N.D. 0.0017 0.0200 mg/l 108 90-110
Nickel N.D. 0.0015 0.0200 mg/l 110 90-111
Potassium N.D. 0.0980 1.00 mg/l 106 90-110
Selenium N.D. 0.0084 0.0400 mg/l 104 89-113
Silver N.D. 0.0021 0.0100 mg/l 85 80-120
Sodium N.D. 0.167 2.00 mg/l 106 87-114
Strontium N.D. 0.00033 0.0100 mg/l 106 90-110
Thallium N.D. 0.0054 0.0600 mg/l 109 90-118
Vanadium N.D. 0.0020 0.0100 mg/l 105 90-110
Zinc N.D. 0.0020 0.0400 mg/l 105 90-110

Batch number: 14149347601A Sample number(s): 7479328-7479331
Bromide N.D. 0.40 0.50 mg/l 96 90-110
Chloride N.D. 0.20 0.40 mg/l 94 90-110
Nitrate Nitrogen N.D. 0.050 0.10 mg/l 98 90-110
Nitrite Nitrogen N.D. 0.080 0.10 mg/l 98 90-110
Sulfate N.D. 0.30 1.0 mg/l 98 90-110

Batch number: 14150002103A Sample number(s): 7479330-7479331
Total Alkalinity N.D. 0.70 2.0 mg/l as
CaCO3
97 90-110

Batch number: 14150002104A Sample number(s): 7479328-7479329
Total Alkalinity N.D. 0.70 2.0 mg/l as
CaCO3
97 90-110

Page 11 of 15

Page 2 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1477503
Reported: 06/04/14 at 09:45 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max
Batch number: 14150021201A Sample number(s): 7479328-7479331
Total Dissolved Solids N.D. 9.7 30.0 mg/l 93 80-120

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 141505713012 Sample number(s): 7479328-7479331 UNSPK: 7479328 BKG: 7479328
Mercury 103 101 80-120 2 20 N.D. N.D. 0 (1) 20

Batch number: 141510635001 Sample number(s): 7479328-7479331 UNSPK: 7479329 BKG: 7479329
Antimony 107 107 76-122 1 20 N.D. N.D. 0 (1) 20
Arsenic 111 107 81-123 3 20 N.D. N.D. 0 (1) 20
Barium 105 102 78-125 2 20 0.0336 0.0325 3 (1) 20
Beryllium 103 100 87-114 2 20 N.D. N.D. 0 (1) 20
Boron 99 98 87-111 1 20 0.268 0.261 3 (1) 20
Cadmium 106 104 75-122 2 20 N.D. N.D. 0 (1) 20
Calcium 100 98 75-125 0 20 11.8 11.7 1 20
Chromium 104 102 76-120 2 20 N.D. N.D. 0 (1) 20
Copper 106 105 86-122 1 20 N.D. N.D. 0 (1) 20
Iron 99 99 75-125 0 20 1.39 1.36 2 (1) 20
Lead 105 105 75-125 0 20 N.D. N.D. 0 (1) 20
Magnesium 99 99 81-118 0 20 2.35 2.30 2 20
Manganese 105 103 75-125 2 20 0.0461 0.0451 2 (1) 20
Molybdenum 108 108 89-117 0 20 0.0047 J 0.0018 J 88* (1) 20
Nickel 108 107 79-123 2 20 N.D. N.D. 0 (1) 20
Potassium 104 102 77-128 2 20 2.50 2.45 2 (1) 20
Selenium 107 103 75-125 4 20 N.D. N.D. 0 (1) 20
Silver 85 85 75-125 0 20 N.D. N.D. 0 (1) 20
Sodium 101 99 84-117 1 20 8.84 8.68 2 (1) 20
Strontium 106 103 88-117 2 20 0.243 0.235 3 20
Thallium 107 106 75-125 1 20 N.D. N.D. 0 (1) 20
Vanadium 105 103 90-117 2 20 N.D. N.D. 0 (1) 20
Zinc 103 102 85-117 1 20 0.0042 J 0.0047 J 11 (1) 20

Batch number: 14149347601A Sample number(s): 7479328-7479331 UNSPK: 7479328 BKG: 7479328
Bromide 98 90-110 N.D. N.D. 0 (1) 20
Chloride 91 90-110 3.9 3.6 8 (1) 20
Nitrate Nitrogen 97 90-110 0.77 0.71 8 (1) 20
Nitrite Nitrogen 95 90-110 N.D. N.D. 0 (1) 20
Sulfate 212* 90-110 16.0 16.0 0 (1) 20

Batch number: 14150002103A Sample number(s): 7479330-7479331 UNSPK: P478089 BKG: P478089
Total Alkalinity 91 93 17-146 1 5 228 234 3 5

Batch number: 14150002104A Sample number(s): 7479328-7479329 UNSPK: 7479328 BKG: 7479328
Total Alkalinity 90 17-146 27.3 28.3 3 5

Batch number: 14150021201A Sample number(s): 7479328-7479331 UNSPK: P478983 BKG: P478983
Total Dissolved Solids 11* 66-131 112 406 114* (1) 5
Page 12 of 15

Page 3 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1477503
Reported: 06/04/14 at 09:45 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Page 13 of 15
Page 14 of 15
Explanation of Symbols and Abbreviations

3768 0713
The following defines common symbols and abbreviations used in reporting technical data:
RL Reporting Limit BMQL Below Minimum Quantitation Level
N.D. none detected MPN Most Probable Number
TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units
IU International Units NTU nephelometric turbidity units
umhos/cm micromhos/cm ng nanogram(s)
C degrees Celsius F degrees Fahrenheit
meq milliequivalents lb. pound(s)
g gram(s) kg kilogram(s)
µg microgram(s) mg milligram(s)
mL milliliter(s) L liter(s)
m3 cubic meter(s) µL microliter(s)
pg/L picogram/liter
< less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be
reliably determined using this specific test.
> greater than
ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For
aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/l), because one liter of water has a
weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter per liter of gas.
ppb parts per billion
Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight
basis concentration to approximate the value present in a similar sample without moisture. All other results are reported
on an as-received basis.
Data Qualifiers:
C – result confirmed by reanalysis.
J - estimated value – The result is ≥ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ).
U.S. EPA CLP Data Qualifiers:
Organic Qualifiers Inorganic Qualifiers
A TIC is a possible aldol-condensation product B Value is <CRDL, but ≥IDL
B Analyte was also detected in the blank E Estimated due to interference
C Pesticide result confirmed by GC/MS M Duplicate injection precision not met
D Compound quantitated on a diluted sample N Spike sample not within control limits
E Concentration exceeds the calibration range of S Method of standard additions (MSA) used
the instrument for calculation
N Presumptive evidence of a compound (TICs only) U Compound was not detected
P Concentration difference between primary and W Post digestion spike out of control limits
confirmation columns >25% * Duplicate analysis not within control limits
U Compound was not detected + Correlation coefficient for MSA <0.995
X,Y,Z Defined in case narrative
Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.
Measurement uncertainty values, as applicable, are available upon request.
Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the
test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact
us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our
staff. This report shall not be reproduced except in full, without the written approval of the laboratory.
Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as “analyze immediately” are not
performed within 15 minutes.

WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE
FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM
ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF
MERCHANTABILITY. IN NO EVENT SHALL EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL, LLC BE LIABLE FOR INDIRECT, SPECIAL,
CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS
OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL AND (B) WHETHER
EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal
responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Eurofins Lancaster
Laboratories Environmental which includes any conditions that vary from the Standard Terms and Conditions, and Eurofins Lancaster Laboratories
Environmental hereby objects to any conflicting terms contained in any acceptance or order submitted by client.
Page 15 of 15

ANALYTICAL RESULTS

Prepared by:

Eurofins Lancaster Laboratories Environmental
2425 New Holland Pike
Lancaster, PA 17601
Prepared for:

GeoSyntec Consultants
4601 Six Forks Road
Suite 340
Raleigh NC 27609

June 06, 2014

Project: Duke Sutton, NC

Submittal Date: 05/30/2014
Group Number: 1478138
SDG: DUK33
PO Number: GC5592
State of Sample Origin: NC

Client Sample Description Lancaster Labs (LL) #
MW-35B-201405028 Groundwater Sample 7481909
MW-35C-201405028 Groundwater Sample 7481910
MW-34C-201405028 Groundwater Sample 7481911

The specific methodologies used in obtaining the enclosed analytical results are indicated on the
Laboratory Sample Analysis Record.

ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Lauren Wellborn
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Beau Hodge
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Rachel Donahue
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Herwig Goldemund

Page 1 of 12

Respectfully Submitted,

[phone]

Page 2 of 12

LL Sample # WW 7481909
LL Group # 1478138
Account # 10634
Sample Description: MW-35B-201405028 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/28/2014 10:40
Submitted: 05/30/2014 09:45
GeoSyntec Consultants
Reported: 06/06/2014 08:04
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS35B SDG#: DUK33-01
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0420 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0163 J 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
4.11 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.0739 J 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.450 17439-95-4 01757 0.0167 0.200 Magnesium
0.0247 17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0015 0.0200 Nickel
1.03 17440-09-7 01762 0.0980 1.00 Potassium
N.D.17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
17.5 17440-23-5 01767 0.167 2.00 Sodium
0.0152 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
N.D.17440-62-2 07071 0.0020 0.0100 Vanadium
0.0031 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
6.4 516887-00-600224 1.0 2.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
31.8 514808-79-800228 1.5 5.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
5.7 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
88.5 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 3 of 12

LL Sample # WW 7481909
LL Group # 1478138
Account # 10634
Sample Description: MW-35B-201405028 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/28/2014 10:40
Submitted: 05/30/2014 09:45
GeoSyntec Consultants
Reported: 06/06/2014 08:04
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS35B SDG#: DUK33-01
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Antimony 07044
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Arsenic 07035
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Barium 07046
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Beryllium 07047
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Boron 08014
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Cadmium 07049
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Calcium 01750
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Chromium 07051
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Copper 07053
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Iron 01754
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Lead 07055
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Magnesium 01757
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Manganese 07058
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Molybdenum 07060
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Nickel 07061
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Potassium 01762
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Selenium 07036
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Silver 07066
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Sodium 01767
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Strontium 08068
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Thallium 07022
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Vanadium 07071
1Katlin N Cataldi06/02/2014 20:08 1415106350011SW-846 6010C Zinc 07072
1Parker D Lindstrom06/05/2014 16:36 1415457130021SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 10:04 1415106350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong06/04/2014 10:57 1415457130021SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/30/2014 10:34 14150347902A1EPA 300.0 Bromide 01505
5Sandra J Miller05/30/2014 10:34 14150347902A1EPA 300.0 Chloride 00224
5Sandra J Miller05/30/2014 10:34 14150347902A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/30/2014 10:34 14150347902A1EPA 300.0 Nitrite Nitrogen 01506
5Sandra J Miller05/30/2014 10:34 14150347902A1EPA 300.0 Sulfate 00228
1Michele L Graham06/03/2014 13:54 14154002103A1EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch06/02/2014 11:20 14153021202A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 4 of 12

LL Sample # WW 7481910
LL Group # 1478138
Account # 10634
Sample Description: MW-35C-201405028 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/28/2014 11:45
Submitted: 05/30/2014 09:45
GeoSyntec Consultants
Reported: 06/06/2014 08:04
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS35C SDG#: DUK33-02
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0317 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.412 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
35.9 17440-70-2 01750 0.0334 0.400 Calcium
0.0046 J 17440-47-3 07051 0.0016 0.0300 Chromium
0.0034 J 17440-50-8 07053 0.0027 0.0200 Copper
2.81 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
4.50 17439-95-4 01757 0.0167 0.200 Magnesium
0.345 17439-96-5 07058 0.00083 0.0100 Manganese
0.0075 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0019 J 17440-02-0 07061 0.0015 0.0200 Nickel
4.53 17440-09-7 01762 0.0980 1.00 Potassium
0.0550 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
89.4 57440-23-5 01767 0.835 10.0 Sodium
0.299 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
0.0074 J 17440-62-2 07071 0.0020 0.0100 Vanadium
0.0172 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
58.4 2016887-00-600224 4.0 8.0 Chloride
0.29 J 514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
131 2014808-79-800228 6.0 20.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
57.3 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
419 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 5 of 12

LL Sample # WW 7481910
LL Group # 1478138
Account # 10634
Sample Description: MW-35C-201405028 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/28/2014 11:45
Submitted: 05/30/2014 09:45
GeoSyntec Consultants
Reported: 06/06/2014 08:04
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS35C SDG#: DUK33-02
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Antimony 07044
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Arsenic 07035
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Barium 07046
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Beryllium 07047
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Boron 08014
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Cadmium 07049
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Calcium 01750
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Chromium 07051
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Copper 07053
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Iron 01754
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Lead 07055
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Magnesium 01757
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Manganese 07058
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Molybdenum 07060
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Nickel 07061
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Potassium 01762
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Selenium 07036
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Silver 07066
5Joanne M Gates06/03/2014 08:33 1415106350011SW-846 6010C Sodium 01767
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Strontium 08068
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Thallium 07022
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Vanadium 07071
1Katlin N Cataldi06/02/2014 20:12 1415106350011SW-846 6010C Zinc 07072
1Parker D Lindstrom06/05/2014 16:38 1415457130021SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 10:04 1415106350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong06/04/2014 10:57 1415457130021SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/30/2014 11:06 14150347902A1EPA 300.0 Bromide 01505
20Sandra J Miller05/31/2014 02:30 14150347902A1EPA 300.0 Chloride 00224
5Sandra J Miller05/30/2014 11:06 14150347902A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/30/2014 11:06 14150347902A1EPA 300.0 Nitrite Nitrogen 01506
20Sandra J Miller05/31/2014 02:30 14150347902A1EPA 300.0 Sulfate 00228
1Michele L Graham06/03/2014 14:45 14154002103A1EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch06/02/2014 11:20 14153021202A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 6 of 12

LL Sample # WW 7481911
LL Group # 1478138
Account # 10634
Sample Description: MW-34C-201405028 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/28/2014 15:54
Submitted: 05/30/2014 09:45
GeoSyntec Consultants
Reported: 06/06/2014 08:04
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS34C SDG#: DUK33-03*
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0053 0.0400 Antimony
N.D.17440-38-2 07035 0.0068 0.0400 Arsenic
0.0471 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.491 17440-42-8 08014 0.0084 0.100 Boron
N.D.17440-43-9 07049 0.00076 0.0100 Cadmium
29.4 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0016 0.0300 Chromium
N.D.17440-50-8 07053 0.0027 0.0200 Copper
0.613 17439-89-6 01754 0.0430 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
5.34 17439-95-4 01757 0.0167 0.200 Magnesium
0.303 17439-96-5 07058 0.00083 0.0100 Manganese
0.0031 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0026 J 17440-02-0 07061 0.0015 0.0200 Nickel
8.16 17440-09-7 01762 0.0980 1.00 Potassium
0.0104 J 17782-49-2 07036 0.0084 0.0400 Selenium
N.D.17440-22-4 07066 0.0021 0.0100 Silver
72.2 27440-23-5 01767 0.334 4.00 Sodium
0.311 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0054 0.0600 Thallium
N.D.17440-62-2 07071 0.0020 0.0100 Vanadium
0.0076 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
61.3 2016887-00-600224 4.0 8.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
122 2014808-79-800228 6.0 20.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
28.8 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
339 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 7 of 12

LL Sample # WW 7481911
LL Group # 1478138
Account # 10634
Sample Description: MW-34C-201405028 Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 05/28/2014 15:54
Submitted: 05/30/2014 09:45
GeoSyntec Consultants
Reported: 06/06/2014 08:04
4601 Six Forks Road
Suite 340
Raleigh NC 27609
DS34C SDG#: DUK33-03*
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Antimony 07044
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Arsenic 07035
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Barium 07046
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Beryllium 07047
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Boron 08014
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Cadmium 07049
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Calcium 01750
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Chromium 07051
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Copper 07053
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Iron 01754
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Lead 07055
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Magnesium 01757
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Manganese 07058
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Molybdenum 07060
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Nickel 07061
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Potassium 01762
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Selenium 07036
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Silver 07066
2Joanne M Gates06/03/2014 08:37 1415106350011SW-846 6010C Sodium 01767
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Strontium 08068
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Thallium 07022
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Vanadium 07071
1Katlin N Cataldi06/02/2014 20:15 1415106350011SW-846 6010C Zinc 07072
1Parker D Lindstrom06/05/2014 16:40 1415457130021SW-846 7470A Mercury 00259
1Micaela L Dishong06/02/2014 10:04 1415106350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1Micaela L Dishong06/04/2014 10:57 1415457130021SW-846 7470A WW SW846 Hg Digest 05713
5Sandra J Miller05/30/2014 11:23 14150347902A1EPA 300.0 Bromide 01505
20Sandra J Miller05/31/2014 02:46 14150347902A1EPA 300.0 Chloride 00224
5Sandra J Miller05/30/2014 11:23 14150347902A1EPA 300.0 Nitrate Nitrogen 00368
5Sandra J Miller05/30/2014 11:23 14150347902A1EPA 300.0 Nitrite Nitrogen 01506
20Sandra J Miller05/31/2014 02:46 14150347902A1EPA 300.0 Sulfate 00228
1Michele L Graham06/03/2014 14:12 14154002103A1EPA 310.1 Total Alkalinity 12150
1Yolunder Y Bunch06/02/2014 11:20 14153021202A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 8 of 12

Page 1 of 2

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1478138
Reported: 06/06/14 at 08:04 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Matrix QC may not be reported if insufficient sample or site-specific QC samples were not submitted. In these
situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise
specified in the method.

All Inorganic Initial Calibration and Continuing Calibration Blanks met acceptable method criteria unless
otherwise noted on the Analysis Report.

Laboratory Compliance Quality Control

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Batch number: 141510635001 Sample number(s): 7481909-7481911
Antimony N.D. 0.0053 0.0400 mg/l 107 88-111
Arsenic N.D. 0.0068 0.0400 mg/l 112 90-113
Barium N.D. 0.00033 0.0100 mg/l 105 90-110
Beryllium N.D. 0.00067 0.0100 mg/l 103 90-111
Boron N.D. 0.0084 0.100 mg/l 100 90-110
Cadmium N.D. 0.00076 0.0100 mg/l 106 90-112
Calcium N.D. 0.0334 0.400 mg/l 105 90-112
Chromium N.D. 0.0016 0.0300 mg/l 104 90-110
Copper N.D. 0.0027 0.0200 mg/l 106 90-112
Iron N.D. 0.0430 0.400 mg/l 106 90-112
Lead N.D. 0.0047 0.0300 mg/l 109 88-116
Magnesium N.D. 0.0167 0.200 mg/l 105 89-110
Manganese N.D. 0.00083 0.0100 mg/l 106 90-110
Molybdenum N.D. 0.0017 0.0200 mg/l 108 90-110
Nickel N.D. 0.0015 0.0200 mg/l 110 90-111
Potassium N.D. 0.0980 1.00 mg/l 106 90-110
Selenium N.D. 0.0084 0.0400 mg/l 104 89-113
Silver N.D. 0.0021 0.0100 mg/l 85 80-120
Sodium N.D. 0.167 2.00 mg/l 106 87-114
Strontium N.D. 0.00033 0.0100 mg/l 106 90-110
Thallium N.D. 0.0054 0.0600 mg/l 109 90-118
Vanadium N.D. 0.0020 0.0100 mg/l 105 90-110
Zinc N.D. 0.0020 0.0400 mg/l 105 90-110

Batch number: 141545713002 Sample number(s): 7481909-7481911
Mercury N.D. 0.00006
0
0.00020 mg/l 99 80-120

Batch number: 14150347902A Sample number(s): 7481909-7481911
Bromide N.D. 0.40 0.50 mg/l 96 90-110
Chloride N.D. 0.20 0.40 mg/l 95 90-110
Nitrate Nitrogen N.D. 0.050 0.10 mg/l 98 90-110
Nitrite Nitrogen N.D. 0.080 0.10 mg/l 97 90-110
Sulfate N.D. 0.30 1.0 mg/l 97 90-110

Batch number: 14153021202A Sample number(s): 7481909-7481911
Total Dissolved Solids N.D. 9.7 30.0 mg/l 99 80-120

Batch number: 14154002103A Sample number(s): 7481909-7481911
Total Alkalinity 1.2 J 0.70 2.0 mg/l as
CaCO3
97 90-110

Page 9 of 12

Page 2 of 2

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1478138
Reported: 06/06/14 at 08:04 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 141510635001 Sample number(s): 7481909-7481911 UNSPK: P479329 BKG: P479329
Antimony 107 107 76-122 1 20 N.D. N.D. 0 (1) 20
Arsenic 111 107 81-123 3 20 N.D. N.D. 0 (1) 20
Barium 105 102 78-125 2 20 0.0336 0.0325 3 (1) 20
Beryllium 103 100 87-114 2 20 N.D. N.D. 0 (1) 20
Boron 99 98 87-111 1 20 0.268 0.261 3 (1) 20
Cadmium 106 104 75-122 2 20 N.D. N.D. 0 (1) 20
Calcium 100 98 75-125 0 20 11.8 11.7 1 20
Chromium 104 102 76-120 2 20 N.D. N.D. 0 (1) 20
Copper 106 105 86-122 1 20 N.D. N.D. 0 (1) 20
Iron 99 99 75-125 0 20 1.39 1.36 2 (1) 20
Lead 105 105 75-125 0 20 N.D. N.D. 0 (1) 20
Magnesium 99 99 81-118 0 20 2.35 2.30 2 20
Manganese 105 103 75-125 2 20 0.0461 0.0451 2 (1) 20
Molybdenum 108 108 89-117 0 20 0.0047 J 0.0018 J 88* (1) 20
Nickel 108 107 79-123 2 20 N.D. N.D. 0 (1) 20
Potassium 104 102 77-128 2 20 2.50 2.45 2 (1) 20
Selenium 107 103 75-125 4 20 N.D. N.D. 0 (1) 20
Silver 85 85 75-125 0 20 N.D. N.D. 0 (1) 20
Sodium 101 99 84-117 1 20 8.84 8.68 2 (1) 20
Strontium 106 103 88-117 2 20 0.243 0.235 3 20
Thallium 107 106 75-125 1 20 N.D. N.D. 0 (1) 20
Vanadium 105 103 90-117 2 20 N.D. N.D. 0 (1) 20
Zinc 103 102 85-117 1 20 0.0042 J 0.0047 J 11 (1) 20

Batch number: 141545713002 Sample number(s): 7481909-7481911 UNSPK: 7481911 BKG: 7481911
Mercury 106 104 80-120 2 20 N.D. N.D. 0 (1) 20

Batch number: 14150347902A Sample number(s): 7481909-7481911 UNSPK: 7481909 BKG: 7481909
Bromide 103 90-110 N.D. N.D. 0 (1) 20
Chloride 103 90-110 6.4 6.5 2 (1) 20
Nitrate Nitrogen 107 90-110 N.D. N.D. 200* (1) 20
Nitrite Nitrogen 100 90-110 N.D. N.D. 0 (1) 20
Sulfate 107 90-110 31.8 31.9 0 20

Batch number: 14153021202A Sample number(s): 7481909-7481911 UNSPK: P481570 BKG: P481570
Total Dissolved Solids 96 92 66-131 2 23 24,000 21,500 11* (1) 5

Batch number: 14154002103A Sample number(s): 7481909-7481911 UNSPK: P483205 BKG: P483205
Total Alkalinity 90 17-146 181 183 1 5

Page 10 of 12
Page 11 of 12
Explanation of Symbols and Abbreviations

3768 0713
The following defines common symbols and abbreviations used in reporting technical data:
RL Reporting Limit BMQL Below Minimum Quantitation Level
N.D. none detected MPN Most Probable Number
TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units
IU International Units NTU nephelometric turbidity units
umhos/cm micromhos/cm ng nanogram(s)
C degrees Celsius F degrees Fahrenheit
meq milliequivalents lb. pound(s)
g gram(s) kg kilogram(s)
µg microgram(s) mg milligram(s)
mL milliliter(s) L liter(s)
m3 cubic meter(s) µL microliter(s)
pg/L picogram/liter
< less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be
reliably determined using this specific test.
> greater than
ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For
aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/l), because one liter of water has a
weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter per liter of gas.
ppb parts per billion
Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight
basis concentration to approximate the value present in a similar sample without moisture. All other results are reported
on an as-received basis.
Data Qualifiers:
C – result confirmed by reanalysis.
J - estimated value – The result is ≥ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ).
U.S. EPA CLP Data Qualifiers:
Organic Qualifiers Inorganic Qualifiers
A TIC is a possible aldol-condensation product B Value is <CRDL, but ≥IDL
B Analyte was also detected in the blank E Estimated due to interference
C Pesticide result confirmed by GC/MS M Duplicate injection precision not met
D Compound quantitated on a diluted sample N Spike sample not within control limits
E Concentration exceeds the calibration range of S Method of standard additions (MSA) used
the instrument for calculation
N Presumptive evidence of a compound (TICs only) U Compound was not detected
P Concentration difference between primary and W Post digestion spike out of control limits
confirmation columns >25% * Duplicate analysis not within control limits
U Compound was not detected + Correlation coefficient for MSA <0.995
X,Y,Z Defined in case narrative
Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.
Measurement uncertainty values, as applicable, are available upon request.
Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the
test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact
us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our
staff. This report shall not be reproduced except in full, without the written approval of the laboratory.
Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as “analyze immediately” are not
performed within 15 minutes.

WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE
FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM
ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF
MERCHANTABILITY. IN NO EVENT SHALL EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL, LLC BE LIABLE FOR INDIRECT, SPECIAL,
CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS
OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL AND (B) WHETHER
EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal
responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Eurofins Lancaster
Laboratories Environmental which includes any conditions that vary from the Standard Terms and Conditions, and Eurofins Lancaster Laboratories
Environmental hereby objects to any conflicting terms contained in any acceptance or order submitted by client.
Page 12 of 12

Appendix A2
Laboratory Analytical Reports LOLA and
1971 Borrow Area

ANALYTICAL RESULTS

Prepared by:

Eurofins Lancaster Laboratories Environmental
2425 New Holland Pike
Lancaster, PA 17601
Prepared for:

GeoSyntec Consultants
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607

July 16, 2014

Project: Duke Sutton, NC

Submittal Date: 07/01/2014
Group Number: 1485674
SDG: DUK34
PO Number: GC5592
State of Sample Origin: NC

Client Sample Description Lancaster Labs (LL) #
20140630-MW14 Grab Groundwater Sample 7516890

The specific methodologies used in obtaining the enclosed analytical results are indicated on the
Laboratory Sample Analysis Record.

ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Lauren Wellborn
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Beau Hodge
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Rachel Donahue
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Herwig Goldemund

Respectfully Submitted,

[phone]

Page 1 of 8

Page 2 of 8

LL Sample # WW 7516890
LL Group # 1485674
Account # 10634
Sample Description: 20140630-MW14 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 17:00 by MP
Submitted: 07/01/2014 09:30
GeoSyntec Consultants
Reported: 07/16/2014 13:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DSMT4 SDG#: DUK34-01*
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.0097 J 17440-38-2 07035 0.0072 0.0400 Arsenic
0.441 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.104 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
47.3 17440-70-2 01750 0.0334 0.400 Calcium
0.0016 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
1.17 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
3.03 17439-95-4 01757 0.0167 0.200 Magnesium
0.0275 17439-96-5 07058 0.00083 0.0100 Manganese
0.0064 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
5.36 17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
19.2 17440-23-5 01767 0.167 2.00 Sodium
0.398 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0114 17440-62-2 07071 0.0019 0.0100 Vanadium
0.0021 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
22.7 516887-00-600224 1.0 2.0 Chloride
0.27 J 514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
6.5 514808-79-800228 1.5 5.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
125 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
200 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 3 of 8

LL Sample # WW 7516890
LL Group # 1485674
Account # 10634
Sample Description: 20140630-MW14 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 17:00 by MP
Submitted: 07/01/2014 09:30
GeoSyntec Consultants
Reported: 07/16/2014 13:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DSMT4 SDG#: DUK34-01*
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 04:09 1418806350011SW-846 6010C Barium 07046
1Tara L Snyder07/09/2014 04:09 1418806350011SW-846 6010C Beryllium 07047
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Boron 08014
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Cadmium 07049
1Tara L Snyder07/09/2014 04:09 1418806350011SW-846 6010C Calcium 01750
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Copper 07053
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Iron 01754
1Joanne M Gates07/09/2014 13:35 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Magnesium 01757
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Molybdenum 07060
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Nickel 07061
1Tara L Snyder07/09/2014 04:09 1418806350011SW-846 6010C Potassium 01762
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Silver 07066
1Tara L Snyder07/09/2014 04:09 1418806350011SW-846 6010C Sodium 01767
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Strontium 08068
1Tara L Snyder07/09/2014 04:09 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 22:05 1418806350011SW-846 6010C Zinc 07072
1Damary Valentin07/16/2014 07:36 1419557130041SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/08/2014 11:00 1418857130011SW-846 7470A WW SW846 Hg Digest 05713
1Micaela L Dishong07/11/2014 09:34 1419157130022SW-846 7470A WW SW846 Hg Digest 05713
1James L Mertz07/15/2014 09:08 1419557130043SW-846 7470A WW SW846 Hg Digest 05713
5Clinton M Wilson07/01/2014 14:15 14182347901B1EPA 300.0 Bromide 01505
5Clinton M Wilson07/01/2014 14:15 14182347901B1EPA 300.0 Chloride 00224
5Clinton M Wilson07/01/2014 14:15 14182347901B1EPA 300.0 Nitrate Nitrogen 00368
5Clinton M Wilson07/01/2014 14:15 14182347901B1EPA 300.0 Nitrite Nitrogen 01506
5Clinton M Wilson07/01/2014 14:15 14182347901B1EPA 300.0 Sulfate 00228
1Yolunder Y Bunch07/02/2014 20:38 14183011102A1EPA 310.1 Total Alkalinity 12150
1Sarah E Thompson07/01/2014 11:40 14182021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 4 of 8

Page 1 of 2

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1485674
Reported: 07/16/14 at 01:40 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Matrix QC may not be reported if insufficient sample or site-specific QC samples were not submitted. In these
situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise
specified in the method.

All Inorganic Initial Calibration and Continuing Calibration Blanks met acceptable method criteria unless
otherwise noted on the Analysis Report.

Laboratory Compliance Quality Control

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Batch number: 141880635001 Sample number(s): 7516890
Antimony N.D. 0.0051 0.0400 mg/l 109 88-111
Arsenic N.D. 0.0072 0.0400 mg/l 111 90-113
Barium N.D. 0.00033 0.0100 mg/l 108 90-110
Beryllium N.D. 0.00067 0.0100 mg/l 106 90-111
Boron N.D. 0.0046 0.100 mg/l 100 90-110
Cadmium N.D. 0.00033 0.0100 mg/l 105 90-112
Calcium N.D. 0.0334 0.400 mg/l 109 90-112
Chromium N.D. 0.0013 0.0300 mg/l 102 90-110
Copper N.D. 0.0028 0.0200 mg/l 108 90-112
Iron N.D. 0.0334 0.400 mg/l 112 90-112
Lead N.D. 0.0047 0.0300 mg/l 114 88-116
Magnesium N.D. 0.0167 0.200 mg/l 107 89-110
Manganese 0.0013 J 0.00083 0.0100 mg/l 108 90-110
Molybdenum N.D. 0.0017 0.0200 mg/l 106 90-110
Nickel N.D. 0.0016 0.0200 mg/l 111 90-117
Potassium N.D. 0.133 1.00 mg/l 104 90-110
Selenium N.D. 0.0048 0.0400 mg/l 103 89-113
Silver N.D. 0.0018 0.0100 mg/l 94 80-120
Sodium N.D. 0.167 2.00 mg/l 106 87-114
Strontium N.D. 0.00033 0.0100 mg/l 108 90-110
Thallium N.D. 0.0051 0.0600 mg/l 101 90-118
Vanadium N.D. 0.0019 0.0100 mg/l 102 90-110
Zinc N.D. 0.0020 0.0400 mg/l 104 90-110

Batch number: 141955713004 Sample number(s): 7516890
Mercury N.D. 0.00006
0
0.00020 mg/l 100 80-120

Batch number: 14182347901B Sample number(s): 7516890
Bromide N.D. 0.40 0.50 mg/l 99 90-110
Chloride N.D. 0.20 0.40 mg/l 98 90-110
Nitrate Nitrogen N.D. 0.050 0.10 mg/l 102 90-110
Nitrite Nitrogen N.D. 0.080 0.10 mg/l 101 90-110
Sulfate N.D. 0.30 1.0 mg/l 101 90-110

Batch number: 14182021201A Sample number(s): 7516890
Total Dissolved Solids N.D. 9.7 30.0 mg/l 105 80-120

Batch number: 14183011102A Sample number(s): 7516890
Total Alkalinity N.D. 0.70 2.0 mg/l as
CaCO3
97 90-110

Page 5 of 8

Page 2 of 2

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1485674
Reported: 07/16/14 at 01:40 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 141880635001 Sample number(s): 7516890 UNSPK: P520777 BKG: P520777
Antimony 108 106 76-122 2 20 N.D. N.D. 0 (1) 20
Arsenic 104 108 81-123 3 20 0.0199 J 0.0133 J 39* (1) 20
Barium 102 101 78-125 1 20 0.144 0.136 6 20
Beryllium 102 101 87-114 1 20 N.D. N.D. 0 (1) 20
Boron 74* 87 87-111 6 20 2.35 2.10 11 (1) 20
Cadmium 99 99 75-122 0 20 N.D. N.D. 0 (1) 20
Calcium 7 (2) -1 (2) 75-125 0 20 89.4 84.3 6 20
Chromium 98 95 76-120 2 20 0.0017 J 0.0019 J 11 (1) 20
Copper 106 106 86-122 0 20 N.D. N.D. 0 (1) 20
Iron 72 (2) 112 (2) 75-125 7 20 4.72 4.44 6 20
Lead 101 100 75-125 1 20 N.D. N.D. 0 (1) 20
Magnesium 20 (2) 10 (2) 81-118 1 20 25.1 23.6 6 20
Manganese 98 94 75-125 2 20 0.459 0.430 7 20
Molybdenum 102 102 89-117 0 20 0.319 0.293 9 20
Nickel 104 103 79-123 1 20 N.D. N.D. 0 (1) 20
Potassium 100 98 77-128 1 20 14.7 13.8 6 20
Selenium 100 101 75-125 1 20 N.D. N.D. 0 (1) 20
Silver 93 91 75-125 2 20 N.D. N.D. 0 (1) 20
Sodium 21 (2) 51 (2) 84-117 3 20 52.1 47.3 10 (1) 20
Strontium 49* 72* 88-117 6 20 3.20 2.88 11 20
Thallium 95 94 75-125 0 20 N.D. N.D. 0 (1) 20
Vanadium 97 97 90-117 0 20 N.D. N.D. 0 (1) 20
Zinc 100 99 85-117 0 20 0.0041 J 0.0038 J 8 (1) 20

Batch number: 141955713004 Sample number(s): 7516890 UNSPK: P514111 BKG: P514111
Mercury 94 97 80-120 2 20 N.D. N.D. 0 (1) 20

Batch number: 14182347901B Sample number(s): 7516890 UNSPK: 7516890 BKG: 7516890
Bromide 99 90-110 N.D. N.D. 0 (1) 20
Chloride 102 90-110 22.7 23.0 1 20
Nitrate Nitrogen 102 90-110 0.27 J 0.28 J 5 (1) 20
Nitrite Nitrogen 99 90-110 N.D. N.D. 0 (1) 20
Sulfate 104 90-110 6.5 6.6 3 (1) 20

Batch number: 14182021201A Sample number(s): 7516890 UNSPK: P515584 BKG: P515584
Total Dissolved Solids 384* 66-131 4,080 4,080 0 5

Batch number: 14183011102A Sample number(s): 7516890 UNSPK: P518803 BKG: P518803
Total Alkalinity 39 17-146 199 200 1 5

Page 6 of 8
Page 7 of 8
Explanation of Symbols and Abbreviations

3768 0713
The following defines common symbols and abbreviations used in reporting technical data:
RL Reporting Limit BMQL Below Minimum Quantitation Level
N.D. none detected MPN Most Probable Number
TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units
IU International Units NTU nephelometric turbidity units
umhos/cm micromhos/cm ng nanogram(s)
C degrees Celsius F degrees Fahrenheit
meq milliequivalents lb. pound(s)
g gram(s) kg kilogram(s)
µg microgram(s) mg milligram(s)
mL milliliter(s) L liter(s)
m3 cubic meter(s) µL microliter(s)
pg/L picogram/liter
< less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be
reliably determined using this specific test.
> greater than
ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For
aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/l), because one liter of water has a
weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter per liter of gas.
ppb parts per billion
Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight
basis concentration to approximate the value present in a similar sample without moisture. All other results are reported
on an as-received basis.
Data Qualifiers:
C – result confirmed by reanalysis.
J - estimated value – The result is ≥ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ).
U.S. EPA CLP Data Qualifiers:
Organic Qualifiers Inorganic Qualifiers
A TIC is a possible aldol-condensation product B Value is <CRDL, but ≥IDL
B Analyte was also detected in the blank E Estimated due to interference
C Pesticide result confirmed by GC/MS M Duplicate injection precision not met
D Compound quantitated on a diluted sample N Spike sample not within control limits
E Concentration exceeds the calibration range of S Method of standard additions (MSA) used
the instrument for calculation
N Presumptive evidence of a compound (TICs only) U Compound was not detected
P Concentration difference between primary and W Post digestion spike out of control limits
confirmation columns >25% * Duplicate analysis not within control limits
U Compound was not detected + Correlation coefficient for MSA <0.995
X,Y,Z Defined in case narrative
Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.
Measurement uncertainty values, as applicable, are available upon request.
Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the
test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact
us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our
staff. This report shall not be reproduced except in full, without the written approval of the laboratory.
Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as “analyze immediately” are not
performed within 15 minutes.

WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE
FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM
ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF
MERCHANTABILITY. IN NO EVENT SHALL EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL, LLC BE LIABLE FOR INDIRECT, SPECIAL,
CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS
OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL AND (B) WHETHER
EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal
responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Eurofins Lancaster
Laboratories Environmental which includes any conditions that vary from the Standard Terms and Conditions, and Eurofins Lancaster Laboratories
Environmental hereby objects to any conflicting terms contained in any acceptance or order submitted by client.
Page 8 of 8

ANALYTICAL RESULTS

Prepared by:

Eurofins Lancaster Laboratories Environmental
2425 New Holland Pike
Lancaster, PA 17601
Prepared for:

GeoSyntec Consultants
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607

July 16, 2014

Project: Duke Sutton, NC

Submittal Date: 07/02/2014
Group Number: 1486078
SDG: DUK35
PO Number: GC5592
State of Sample Origin: NC

Client Sample Description Lancaster Labs (LL) #
SS-MB2(64.0-68.0)-20140625 Grab Soil Sample 7519007
SS-MB2(64.0-68.0)-20140625 Grab Soil Sample 7519008
SS-MB2(76.0-80.0)-20140625 Grab Soil Sample 7519009
SS-MB2(76.0-80.0)-20140625 Grab Soil Sample 7519010
GW-MW16-20140701 Grab Groundwater Sample 7519011
GW-MW16D-20140701 Grab Groundwater Sample 7519012
EB-02-20140701 Grab Water Sample 7519013
SB-02-20140701 Grab Water Sample 7519014
GW-MW20-20140701 Grab Groundwater Sample 7519015
GW-MW20D-20140701 Grab Groundwater Sample 7519016

The specific methodologies used in obtaining the enclosed analytical results are indicated on the
Laboratory Sample Analysis Record.

ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Lauren Wellborn
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Beau Hodge
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Rachel Donahue
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Herwig Goldemund

Page 1 of 28

ANALYTICAL RESULTS

Prepared by:

Eurofins Lancaster Laboratories Environmental
2425 New Holland Pike
Lancaster, PA 17601
Prepared for:

GeoSyntec Consultants
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607

July 14, 2014

Project: Duke Sutton, NC

Submittal Date: 07/03/2014
Group Number: 1486445
SDG: DUK36
PO Number: GC5592
State of Sample Origin: NC

Client Sample Description Lancaster Labs (LL) #
SS-F-DPT-1(3-4)-20140630 Solid Sample 7520693
SS-F-DPT-1(3-4)-20140630 Solid Sample 7520694
SS-F-DPT-1(7-8)-20140630 Solid Sample 7520695
SS-F-DPT-1(7-8)-20140630 Solid Sample 7520696
SS-F-DPT-3(1.5-2.5)-20140630 Solid Sample 7520697
SS-F-DPT-3(1.5-2.5)-20140630 Solid Sample 7520698
SS-F-DPT-3(5-6)-20140630 Solid Sample 7520699
SS-F-DPT-3(5-6)-20140630 Solid Sample 7520700
SS-F-DPT-5(2-4)-20140701 Solid Sample 7520701
SS-F-DPT-5(2-4)-20140701 MS Solid Sample 7520702
SS-F-DPT-5(2-4)-20140701 MSD Solid Sample 7520703
SS-F-DPT-5(2-4)-20140701 DUP Solid Sample 7520704
SS-F-DPT-5(2-4)-20140701 Solid Sample 7520705
SS-F-DPT-5(2-4)-20140701 MS Solid Sample 7520706
SS-F-DPT-5(2-4)-20140701 MSD Solid Sample 7520707
SS-F-DPT-5(2-4)-20140701 DUP Solid Sample 7520708
SS-F-DPT-5(6-8)-20140701 Solid Sample 7520709
SS-F-DPT-5(6-8)-20140701 Solid Sample 7520710
SS-F-DPT-95(7-8)-20140701 Solid Sample 7520711
SS-F-DPT-95(7-8)-20140701 Solid Sample 7520712
SS-F-DPT-7(3-4)-20140701 Solid Sample 7520713
SS-F-DPT-7(3-4)-20140701 Solid Sample 7520714
SS-F-DPT-7(7-8)-20140701 Solid Sample 7520715
SS-F-DPT-7(7-8)-20140701 Solid Sample 7520716
SS-F-DPT-4(18-20)-20140701 Solid Sample 7520717
SS-F-DPT-4(18-20)-20140701 Solid Sample 7520718
SS-F-DPT-11(7-8)-20140702 Solid Sample 7520719
SS-F-DPT-11(7-8)-20140702 Solid Sample 7520720
SS-F-DPT-11(11-12)-20140702 Solid Sample 7520721
SS-F-DPT-11(11-12)-20140702 Solid Sample 7520722
SS-F-DPT-7(15-16)-20140701 Solid Sample 7520723
Page 1 of 81

SS-F-DPT-7(15-16)-20140701 Solid Sample 7520724
SS-F-DPT-14(3-4)-20140702 Solid Sample 7520725
SS-F-DPT-14(3-4)-20140702 Solid Sample 7520726
SS-F-DPT-14(7-8)-20140702 Solid Sample 7520727
SS-F-DPT-14(7-8)-20140702 Solid Sample 7520728

The specific methodologies used in obtaining the enclosed analytical results are indicated on the
Laboratory Sample Analysis Record.

ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Lauren Wellborn
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Beau Hodge
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Rachel Donahue
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Herwig Goldemund

Respectfully Submitted,

[phone]

Page 2 of 81

LL Sample # SW 7520693
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-1(3-4)-20140630 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 14:15 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS13T SDG#: DUK36-01
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.317 3.84 Antimony
0.715 J 17440-38-2 06935 0.614 3.84 Arsenic
3.28 17440-39-3 06946 0.0317 0.959 Barium
N.D.17440-41-7 06947 0.0643 0.959 Beryllium
3.98 J 17440-42-8 07914 0.806 9.59 Boron
N.D.17440-43-9 06949 0.0317 0.959 Cadmium
0.815 J 17440-47-3 06951 0.106 2.88 Chromium
0.598 J 17440-50-8 06953 0.317 1.92 Copper
348 17439-89-6 01654 3.20 38.4 Iron
1.52 J 17439-92-1 06955 0.480 2.88 Lead
3.12 17439-96-5 06958 0.0796 0.959 Manganese
0.164 J 17439-98-7 06960 0.163 1.92 Molybdenum
0.516 J 17440-02-0 06961 0.144 1.92 Nickel
N.D.17782-49-2 06936 0.422 3.84 Selenium
N.D.17440-22-4 06966 0.182 0.959 Silver
1.74 17440-24-6 07968 0.0317 0.959 Strontium
N.D.17440-28-0 06925 0.767 5.75 Thallium
1.69 J 17440-66-6 06972 0.249 3.84 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
N.D.17439-97-6 00159 0.0096 0.191 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
6.65 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 22.8 C.
% %%Wet Chemistry SM 2540 G-1997
0.70 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Arsenic 06935
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 3 of 81

LL Sample # SW 7520693
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-1(3-4)-20140630 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 14:15 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS13T SDG#: DUK36-01
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Iron 01654
1John P Hook07/09/2014 19:46 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Silver 06966
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 15:09 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:02 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402A1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 4 of 81

LL Sample # TL 7520694
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-1(3-4)-20140630 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 14:15 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS13S SDG#: DUK36-02
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
N.D.17440-38-2 07035 0.0072 0.0400 Arsenic
0.0299 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0295 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
1.84 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.345 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.259 17439-95-4 01757 0.0167 0.200 Magnesium
0.0026 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0032 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0117 J 17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
4.81 17440-23-5 01767 0.167 2.00 Sodium
0.0052 J 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0066 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Beryllium 07047
1Joanne M Gates07/11/2014 08:15 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 5 of 81

LL Sample # TL 7520694
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-1(3-4)-20140630 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 14:15 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS13S SDG#: DUK36-02
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 02:34 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:16 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 6 of 81

LL Sample # SW 7520695
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-1(7-8)-20140630 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 14:20 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS17T SDG#: DUK36-03
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.470 5.70 Antimony
26.5 17440-38-2 06935 0.912 5.70 Arsenic
452 57440-39-3 06946 0.235 7.13 Barium
3.54 17440-41-7 06947 0.0955 1.43 Beryllium
24.6 17440-42-8 07914 1.20 14.3 Boron
N.D.17440-43-9 06949 0.0470 1.43 Cadmium
18.8 17440-47-3 06951 0.157 4.28 Chromium
42.8 17440-50-8 06953 0.470 2.85 Copper
12,600 17439-89-6 01654 4.76 57.0 Iron
13.9 17439-92-1 06955 0.713 4.28 Lead
44.9 17439-96-5 06958 0.118 1.43 Manganese
1.06 J 17439-98-7 06960 0.242 2.85 Molybdenum
54.8 17440-02-0 06961 0.214 2.85 Nickel
5.23 J 17782-49-2 06936 0.627 5.70 Selenium
N.D.17440-22-4 06966 0.271 1.43 Silver
337 57440-24-6 07968 0.235 7.13 Strontium
N.D.17440-28-0 06925 1.14 8.55 Thallium
31.3 17440-66-6 06972 0.371 5.70 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.154 J 17439-97-6 00159 0.0148 0.296 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
6.55 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23.1 C.
% %%Wet Chemistry SM 2540 G-1997
33.2 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:13 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 15:13 1418806370021SW-846 6010C Arsenic 06935
5John P Hook07/09/2014 19:54 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 15:13 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 7 of 81

LL Sample # SW 7520695
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-1(7-8)-20140630 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 14:20 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS17T SDG#: DUK36-03
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:13 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 15:13 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 15:13 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 15:13 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 15:13 1418806370021SW-846 6010C Iron 01654
1John P Hook07/09/2014 19:50 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 15:13 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 15:13 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 15:13 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 15:13 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 15:13 1418806370021SW-846 6010C Silver 06966
5John P Hook07/09/2014 19:54 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 15:13 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 15:13 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:04 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402A1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 8 of 81

LL Sample # TL 7520696
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-1(7-8)-20140630 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 14:20 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS17S SDG#: DUK36-04
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.0109 J 17440-38-2 07035 0.0072 0.0400 Arsenic
0.104 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0195 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
1.55 17440-70-2 01750 0.0334 0.400 Calcium
0.0016 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.197 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.151 J 17439-95-4 01757 0.0167 0.200 Magnesium
0.0030 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0019 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0075 J 17440-02-0 07061 0.0016 0.0200 Nickel
0.151 J 17440-09-7 01762 0.133 1.00 Potassium
0.0108 J 17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
1.97 J 17440-23-5 01767 0.167 2.00 Sodium
0.0794 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0060 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Beryllium 07047
1Joanne M Gates07/11/2014 08:19 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 9 of 81

LL Sample # TL 7520696
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-1(7-8)-20140630 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 14:20 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS17S SDG#: DUK36-04
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 02:37 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:18 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 10 of 81

LL Sample # SW 7520697
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-3(1.5-2.5)-20140630 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 16:02 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS31T SDG#: DUK36-05
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.337 4.09 Antimony
1.28 J 17440-38-2 06935 0.654 4.09 Arsenic
5.57 17440-39-3 06946 0.0337 1.02 Barium
N.D.17440-41-7 06947 0.0685 1.02 Beryllium
2.68 J 17440-42-8 07914 0.858 10.2 Boron
N.D.17440-43-9 06949 0.0337 1.02 Cadmium
2.34 J 17440-47-3 06951 0.112 3.07 Chromium
1.83 J 17440-50-8 06953 0.337 2.04 Copper
833 17439-89-6 01654 3.41 40.9 Iron
2.31 J 17439-92-1 06955 0.511 3.07 Lead
7.45 17439-96-5 06958 0.0848 1.02 Manganese
N.D.17439-98-7 06960 0.174 2.04 Molybdenum
2.10 17440-02-0 06961 0.153 2.04 Nickel
N.D.17782-49-2 06936 0.450 4.09 Selenium
N.D.17440-22-4 06966 0.194 1.02 Silver
11.4 17440-24-6 07968 0.0337 1.02 Strontium
N.D.17440-28-0 06925 0.818 6.13 Thallium
3.06 J 17440-66-6 06972 0.266 4.09 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
N.D.17439-97-6 00159 0.0103 0.207 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
8.28 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23.3 C.
% %%Wet Chemistry SM 2540 G-1997
5.0 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Arsenic 06935
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 11 of 81

LL Sample # SW 7520697
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-3(1.5-2.5)-20140630 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 16:02 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS31T SDG#: DUK36-05
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Iron 01654
1John P Hook07/09/2014 19:58 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Silver 06966
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 15:17 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:06 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402A1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 12 of 81

LL Sample # TL 7520698
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-3(1.5-2.5)-20140630 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 16:02 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS31S SDG#: DUK36-06
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
N.D.17440-38-2 07035 0.0072 0.0400 Arsenic
0.0612 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0438 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
10.2 17440-70-2 01750 0.0334 0.400 Calcium
0.0019 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.473 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.391 17439-95-4 01757 0.0167 0.200 Magnesium
0.0044 J 17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0020 J 17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
6.22 17440-23-5 01767 0.167 2.00 Sodium
0.0201 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0099 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Beryllium 07047
1Joanne M Gates07/11/2014 08:23 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 13 of 81

LL Sample # TL 7520698
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-3(1.5-2.5)-20140630 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 16:02 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS31S SDG#: DUK36-06
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 02:41 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:20 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 14 of 81

LL Sample # SW 7520699
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-3(5-6)-20140630 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 16:12 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS35T SDG#: DUK36-07
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.567 6.87 Antimony
28.1 17440-38-2 06935 1.10 6.87 Arsenic
314 57440-39-3 06946 0.283 8.59 Barium
2.73 17440-41-7 06947 0.115 1.72 Beryllium
22.8 17440-42-8 07914 1.44 17.2 Boron
N.D.17440-43-9 06949 0.0567 1.72 Cadmium
20.4 17440-47-3 06951 0.189 5.15 Chromium
34.8 17440-50-8 06953 0.567 3.43 Copper
11,700 17439-89-6 01654 5.73 68.7 Iron
9.56 17439-92-1 06955 0.859 5.15 Lead
58.6 17439-96-5 06958 0.143 1.72 Manganese
1.21 J 17439-98-7 06960 0.292 3.43 Molybdenum
17.4 17440-02-0 06961 0.258 3.43 Nickel
5.33 J 17782-49-2 06936 0.755 6.87 Selenium
N.D.17440-22-4 06966 0.326 1.72 Silver
201 57440-24-6 07968 0.283 8.59 Strontium
N.D.17440-28-0 06925 1.37 10.3 Thallium
14.0 17440-66-6 06972 0.446 6.87 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.228 J 17439-97-6 00159 0.0171 0.341 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
7.71 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23.1 C.
% %%Wet Chemistry SM 2540 G-1997
44.0 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:20 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 15:20 1418806370021SW-846 6010C Arsenic 06935
5John P Hook07/09/2014 20:14 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 15:20 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 15 of 81

LL Sample # SW 7520699
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-3(5-6)-20140630 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 16:12 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS35T SDG#: DUK36-07
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:20 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 15:20 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 15:20 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 15:20 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 15:20 1418806370021SW-846 6010C Iron 01654
1John P Hook07/09/2014 20:10 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 15:20 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 15:20 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 15:20 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 15:20 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 15:20 1418806370021SW-846 6010C Silver 06966
5John P Hook07/09/2014 20:14 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 15:20 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 15:20 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:08 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402A1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 16 of 81

LL Sample # TL 7520700
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-3(5-6)-20140630 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 16:12 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS35S SDG#: DUK36-08
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.0229 J 17440-38-2 07035 0.0072 0.0400 Arsenic
0.0223 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0278 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
4.34 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
N.D.17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.204 17439-95-4 01757 0.0167 0.200 Magnesium
0.0099 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0071 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17440-09-7 01762 0.133 1.00 Potassium
0.0051 J 17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
2.76 17440-23-5 01767 0.167 2.00 Sodium
0.0436 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Beryllium 07047
1Joanne M Gates07/11/2014 08:26 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 17 of 81

LL Sample # TL 7520700
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-3(5-6)-20140630 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/30/2014 16:12 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS35S SDG#: DUK36-08
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 02:45 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:22 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 18 of 81

LL Sample # SW 7520701
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52T SDG#: DUK36-09BKG
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.410 4.96 Antimony
18.5 17440-38-2 06935 0.794 4.96 Arsenic
340 57440-39-3 06946 0.205 6.21 Barium
2.76 17440-41-7 06947 0.0831 1.24 Beryllium
8.38 J 17440-42-8 07914 1.04 12.4 Boron
N.D.17440-43-9 06949 0.0410 1.24 Cadmium
11.8 17440-47-3 06951 0.137 3.72 Chromium
27.0 17440-50-8 06953 0.410 2.48 Copper
11,400 17439-89-6 01654 4.14 49.6 Iron
8.63 17439-92-1 06955 0.621 3.72 Lead
81.1 17439-96-5 06958 0.103 1.24 Manganese
1.79 J 17439-98-7 06960 0.211 2.48 Molybdenum
18.6 17440-02-0 06961 0.186 2.48 Nickel
3.39 J 17782-49-2 06936 0.546 4.96 Selenium
N.D.17440-22-4 06966 0.236 1.24 Silver
184 57440-24-6 07968 0.205 6.21 Strontium
N.D.17440-28-0 06925 0.993 7.45 Thallium
16.6 17440-66-6 06972 0.323 4.96 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.0339 J 17439-97-6 00159 0.0126 0.251 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
7.53 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23.2 C.
% %%Wet Chemistry SM 2540 G-1997
21.0 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 14:32 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 14:32 1418806370021SW-846 6010C Arsenic 06935
5John P Hook07/09/2014 19:07 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 14:32 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 19 of 81

LL Sample # SW 7520701
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52T SDG#: DUK36-09BKG
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 14:32 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 14:32 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 14:32 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 14:32 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 14:32 1418806370021SW-846 6010C Iron 01654
1John P Hook07/09/2014 18:43 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 14:32 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 14:32 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 14:32 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 14:32 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 14:32 1418806370021SW-846 6010C Silver 06966
5John P Hook07/09/2014 19:07 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 14:32 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 14:32 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:11 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402A1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 20 of 81

LL Sample # SW 7520702
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 MS Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52T SDG#: DUK36-09MS
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
49.9 17440-36-0 06944 0.398 4.82 Antimony
35.8 17440-38-2 06935 0.772 4.82 Arsenic
571 57440-39-3 06946 0.199 6.03 Barium
8.80 17440-41-7 06947 0.0808 1.21 Beryllium
242 17440-42-8 07914 1.01 12.1 Boron
5.70 17440-43-9 06949 0.0398 1.21 Cadmium
39.7 17440-47-3 06951 0.133 3.62 Chromium
57.9 17440-50-8 06953 0.398 2.41 Copper
12,600 17439-89-6 01654 4.03 48.2 Iron
25.9 17439-92-1 06955 0.603 3.62 Lead
123 17439-96-5 06958 0.100 1.21 Manganese
235 17439-98-7 06960 0.205 2.41 Molybdenum
80.0 17440-02-0 06961 0.181 2.41 Nickel
20.7 17782-49-2 06936 0.530 4.82 Selenium
4.49 17440-22-4 06966 0.229 1.21 Silver
296 57440-24-6 07968 0.199 6.03 Strontium
13.5 17440-28-0 06925 0.964 7.23 Thallium
72.1 17440-66-6 06972 0.313 4.82 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.226 J 17439-97-6 00159 0.0118 0.237 Mercury
% %%Wet Chemistry SM 2540 G-1997
21.0 1n.a. 00118 0.50 0.50 Moisture
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 14:43 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 14:43 1418806370021SW-846 6010C Arsenic 06935
5John P Hook07/09/2014 19:26 1418806370023SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 14:43 1418806370021SW-846 6010C Beryllium 06947
1Eric L Eby07/08/2014 14:43 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 14:43 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 14:43 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 14:43 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 14:43 1418806370021SW-846 6010C Iron 01654
1John P Hook07/09/2014 18:55 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 14:43 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 14:43 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 14:43 1418806370021SW-846 6010C Nickel 06961
*=This limit was used in the evaluation of the final result
Page 21 of 81

LL Sample # SW 7520702
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 MS Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52T SDG#: DUK36-09MS
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 14:43 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 14:43 1418806370021SW-846 6010C Silver 06966
5John P Hook07/09/2014 19:26 1418806370023SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 14:43 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 14:43 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:21 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Scott W Freisher07/08/2014 19:40 14189820002B1SM 2540 G-1997 Moisture 00118
*=This limit was used in the evaluation of the final result
Page 22 of 81

LL Sample # SW 7520703
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 MSD Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52T SDG#: DUK36-09MSD
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
51.3 17440-36-0 06944 0.402 4.87 Antimony
36.5 17440-38-2 06935 0.779 4.87 Arsenic
604 57440-39-3 06946 0.201 6.09 Barium
9.06 17440-41-7 06947 0.0815 1.22 Beryllium
243 17440-42-8 07914 1.02 12.2 Boron
5.78 17440-43-9 06949 0.0402 1.22 Cadmium
40.5 17440-47-3 06951 0.134 3.65 Chromium
59.6 17440-50-8 06953 0.402 2.43 Copper
12,300 17439-89-6 01654 4.07 48.7 Iron
27.0 17439-92-1 06955 0.609 3.65 Lead
122 17439-96-5 06958 0.101 1.22 Manganese
240 17439-98-7 06960 0.207 2.43 Molybdenum
81.1 17440-02-0 06961 0.183 2.43 Nickel
21.1 17782-49-2 06936 0.536 4.87 Selenium
4.49 17440-22-4 06966 0.231 1.22 Silver
318 57440-24-6 07968 0.201 6.09 Strontium
13.6 17440-28-0 06925 0.974 7.30 Thallium
73.3 17440-66-6 06972 0.316 4.87 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.282 17439-97-6 00159 0.0122 0.244 Mercury
% %%Wet Chemistry SM 2540 G-1997
21.0 1n.a. 00118 0.50 0.50 Moisture
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 14:47 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 14:47 1418806370021SW-846 6010C Arsenic 06935
5John P Hook07/09/2014 19:30 1418806370023SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 14:47 1418806370021SW-846 6010C Beryllium 06947
1Eric L Eby07/08/2014 14:47 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 14:47 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 14:47 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 14:47 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 14:47 1418806370021SW-846 6010C Iron 01654
1John P Hook07/09/2014 18:59 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 14:47 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 14:47 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 14:47 1418806370021SW-846 6010C Nickel 06961
*=This limit was used in the evaluation of the final result
Page 23 of 81

LL Sample # SW 7520703
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 MSD Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52T SDG#: DUK36-09MSD
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 14:47 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 14:47 1418806370021SW-846 6010C Silver 06966
5John P Hook07/09/2014 19:30 1418806370023SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 14:47 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 14:47 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:23 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Scott W Freisher07/08/2014 19:40 14189820002B1SM 2540 G-1997 Moisture 00118
*=This limit was used in the evaluation of the final result
Page 24 of 81

LL Sample # SW 7520704
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 DUP Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52T SDG#: DUK36-09DUP
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.402 4.87 Antimony
20.8 17440-38-2 06935 0.779 4.87 Arsenic
389 57440-39-3 06946 0.201 6.09 Barium
3.42 17440-41-7 06947 0.0815 1.22 Beryllium
9.31 J 17440-42-8 07914 1.02 12.2 Boron
N.D.17440-43-9 06949 0.0402 1.22 Cadmium
13.7 17440-47-3 06951 0.134 3.65 Chromium
32.7 17440-50-8 06953 0.402 2.43 Copper
11,500 17439-89-6 01654 4.07 48.7 Iron
10.2 17439-92-1 06955 0.609 3.65 Lead
55.3 17439-96-5 06958 0.101 1.22 Manganese
1.51 J 17439-98-7 06960 0.207 2.43 Molybdenum
20.2 17440-02-0 06961 0.183 2.43 Nickel
4.68 J 17782-49-2 06936 0.536 4.87 Selenium
N.D.17440-22-4 06966 0.231 1.22 Silver
213 57440-24-6 07968 0.201 6.09 Strontium
N.D.17440-28-0 06925 0.974 7.30 Thallium
14.3 17440-66-6 06972 0.316 4.87 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.0395 J 17439-97-6 00159 0.0118 0.237 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
7.51 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23 C.
% %%Wet Chemistry SM 2540 G-1997
21.0 1n.a. 00118 0.50 0.50 Moisture
23.1 1n.a. 00121 0.50 0.50 Moisture Duplicate
The duplicate moisture value is provided to assess the precision of the
moisture test. For comparability purposes, the initial moisture
determination is the value used to perform dry weight calculations.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 14:39 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 14:39 1418806370021SW-846 6010C Arsenic 06935
5John P Hook07/09/2014 19:22 1418806370021SW-846 6010C Barium 06946
*=This limit was used in the evaluation of the final result
Page 25 of 81

LL Sample # SW 7520704
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 DUP Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52T SDG#: DUK36-09DUP
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 14:39 1418806370021SW-846 6010C Beryllium 06947
1Eric L Eby07/08/2014 14:39 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 14:39 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 14:39 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 14:39 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 14:39 1418806370021SW-846 6010C Iron 01654
1John P Hook07/09/2014 18:51 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 14:39 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 14:39 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 14:39 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 14:39 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 14:39 1418806370021SW-846 6010C Silver 06966
5John P Hook07/09/2014 19:22 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 14:39 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 14:39 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:19 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402A1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002B1SM 2540 G-1997 Moisture 00118
1Scott W Freisher07/08/2014 19:40 14189820002B1SM 2540 G-1997 Moisture Duplicate 00121
*=This limit was used in the evaluation of the final result
Page 26 of 81

LL Sample # TL 7520705
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52S SDG#: DUK36-10BKG
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.0055 J 17440-36-0 07044 0.0051 0.0400 Antimony
0.0197 J 17440-38-2 07035 0.0072 0.0400 Arsenic
0.105 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0284 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
5.40 17440-70-2 01750 0.0334 0.400 Calcium
0.0021 J 17440-47-3 07051 0.0013 0.0300 Chromium
0.0085 J 17440-50-8 07053 0.0028 0.0200 Copper
0.370 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.323 17439-95-4 01757 0.0167 0.200 Magnesium
0.0031 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0172 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
3.58 17440-23-5 01767 0.167 2.00 Sodium
0.122 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0059 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Beryllium 07047
1Joanne M Gates07/11/2014 08:01 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 27 of 81

LL Sample # TL 7520705
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52S SDG#: DUK36-10BKG
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 01:56 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:24 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 28 of 81

LL Sample # TL 7520706
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 MS Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52S SDG#: DUK36-10MS
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
4.82 17440-36-0 07044 0.0051 0.0400 Antimony
4.90 17440-38-2 07035 0.0072 0.0400 Arsenic
94.6 257440-39-3 07046 0.0083 0.250 Barium
4.86 27440-41-7 07047 0.0013 0.0200 Beryllium
4.49 17440-42-8 08014 0.0046 0.100 Boron
0.914 17440-43-9 07049 0.00033 0.0100 Cadmium
52.6 17440-70-2 01750 0.0334 0.400 Calcium
4.58 17440-47-3 07051 0.0013 0.0300 Chromium
4.72 17440-50-8 07053 0.0028 0.0200 Copper
5.25 17439-89-6 01754 0.0334 0.400 Iron
4.53 17439-92-1 07055 0.0047 0.0300 Lead
47.4 17439-95-4 01757 0.0167 0.200 Magnesium
4.51 17439-96-5 07058 0.00083 0.0100 Manganese
9.40 17439-98-7 07060 0.0017 0.0200 Molybdenum
4.50 17440-02-0 07061 0.0016 0.0200 Nickel
48.9 17440-09-7 01762 0.133 1.00 Potassium
0.965 17782-49-2 07036 0.0048 0.0400 Selenium
3.53 17440-22-4 07066 0.0018 0.0100 Silver
49.0 17440-23-5 01767 0.167 2.00 Sodium
5.06 27440-24-6 08068 0.00066 0.0200 Strontium
4.35 17440-28-0 07022 0.0051 0.0600 Thallium
4.62 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
0.0193 17439-97-6 00259 0.00060 0.0020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Arsenic 07035
25Tara L Snyder07/11/2014 02:11 1419006360011SW-846 6010C Barium 07046
2Joanne M Gates07/11/2014 08:56 1419006360012SW-846 6010C Beryllium 07047
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 29 of 81

LL Sample # TL 7520706
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 MS Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52S SDG#: DUK36-10MS
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Sodium 01767
2Joanne M Gates07/11/2014 08:56 1419006360012SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 02:07 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:26 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 30 of 81

LL Sample # TL 7520707
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 MSD Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52S SDG#: DUK36-10MSD
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
4.65 17440-36-0 07044 0.0051 0.0400 Antimony
4.72 17440-38-2 07035 0.0072 0.0400 Arsenic
90.7 257440-39-3 07046 0.0083 0.250 Barium
4.77 27440-41-7 07047 0.0013 0.0200 Beryllium
4.40 17440-42-8 08014 0.0046 0.100 Boron
0.880 17440-43-9 07049 0.00033 0.0100 Cadmium
50.6 17440-70-2 01750 0.0334 0.400 Calcium
4.51 17440-47-3 07051 0.0013 0.0300 Chromium
4.58 17440-50-8 07053 0.0028 0.0200 Copper
5.31 17439-89-6 01754 0.0334 0.400 Iron
4.38 17439-92-1 07055 0.0047 0.0300 Lead
46.3 17439-95-4 01757 0.0167 0.200 Magnesium
4.45 17439-96-5 07058 0.00083 0.0100 Manganese
9.15 17439-98-7 07060 0.0017 0.0200 Molybdenum
4.37 17440-02-0 07061 0.0016 0.0200 Nickel
47.8 17440-09-7 01762 0.133 1.00 Potassium
0.933 17782-49-2 07036 0.0048 0.0400 Selenium
4.03 17440-22-4 07066 0.0018 0.0100 Silver
48.7 17440-23-5 01767 0.167 2.00 Sodium
4.90 27440-24-6 08068 0.00066 0.0200 Strontium
4.19 17440-28-0 07022 0.0051 0.0600 Thallium
4.46 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
0.0182 17439-97-6 00259 0.00060 0.0020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Arsenic 07035
25Tara L Snyder07/11/2014 02:19 1419006360011SW-846 6010C Barium 07046
2Joanne M Gates07/11/2014 09:00 1419006360012SW-846 6010C Beryllium 07047
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 31 of 81

LL Sample # TL 7520707
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 MSD Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52S SDG#: DUK36-10MSD
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Sodium 01767
2Joanne M Gates07/11/2014 09:00 1419006360012SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 02:15 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:28 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 32 of 81

LL Sample # TL 7520708
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 DUP Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52S SDG#: DUK36-10DUP
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.0066 J 17440-36-0 07044 0.0051 0.0400 Antimony
0.0183 J 17440-38-2 07035 0.0072 0.0400 Arsenic
0.115 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0285 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
5.30 17440-70-2 01750 0.0334 0.400 Calcium
0.0019 J 17440-47-3 07051 0.0013 0.0300 Chromium
0.0091 J 17440-50-8 07053 0.0028 0.0200 Copper
0.362 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.314 17439-95-4 01757 0.0167 0.200 Magnesium
0.0032 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0149 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17440-09-7 01762 0.133 1.00 Potassium
0.0051 J 17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
3.43 17440-23-5 01767 0.167 2.00 Sodium
0.120 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0069 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Beryllium 07047
1Joanne M Gates07/11/2014 08:08 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 33 of 81

LL Sample # TL 7520708
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(2-4)-20140701 DUP Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS52S SDG#: DUK36-10DUP
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 02:03 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:31 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 34 of 81

LL Sample # SW 7520709
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(6-8)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:10 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS56T SDG#: DUK36-11
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.517 6.26 Antimony
42.2 17440-38-2 06935 1.00 6.26 Arsenic
708 57440-39-3 06946 0.258 7.83 Barium
7.84 17440-41-7 06947 0.105 1.57 Beryllium
19.0 17440-42-8 07914 1.32 15.7 Boron
N.D.17440-43-9 06949 0.0517 1.57 Cadmium
25.4 17440-47-3 06951 0.172 4.70 Chromium
66.4 17440-50-8 06953 0.517 3.13 Copper
13,500 17439-89-6 01654 5.23 62.6 Iron
18.8 17439-92-1 06955 0.783 4.70 Lead
85.7 17439-96-5 06958 0.130 1.57 Manganese
0.985 J 17439-98-7 06960 0.266 3.13 Molybdenum
34.9 17440-02-0 06961 0.235 3.13 Nickel
6.86 17782-49-2 06936 0.689 6.26 Selenium
N.D.17440-22-4 06966 0.298 1.57 Silver
475 57440-24-6 07968 0.258 7.83 Strontium
N.D.17440-28-0 06925 1.25 9.40 Thallium
28.0 17440-66-6 06972 0.407 6.26 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.0875 J 17439-97-6 00159 0.0156 0.311 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
7.80 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23.3 C.
% %%Wet Chemistry SM 2540 G-1997
37.4 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:24 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 15:24 1418806370021SW-846 6010C Arsenic 06935
5John P Hook07/09/2014 20:22 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 15:24 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 35 of 81

LL Sample # SW 7520709
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(6-8)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:10 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS56T SDG#: DUK36-11
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:24 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 15:24 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 15:24 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 15:24 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 15:24 1418806370021SW-846 6010C Iron 01654
1John P Hook07/09/2014 20:18 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 15:24 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 15:24 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 15:24 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 15:24 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 15:24 1418806370021SW-846 6010C Silver 06966
5John P Hook07/09/2014 20:22 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 15:24 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 15:24 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:25 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402A1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 36 of 81

LL Sample # TL 7520710
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(6-8)-20140701 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:10 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS56S SDG#: DUK36-12
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.0132 J 17440-36-0 07044 0.0051 0.0400 Antimony
0.0415 17440-38-2 07035 0.0072 0.0400 Arsenic
0.221 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0183 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
12.0 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
N.D.17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.214 17439-95-4 01757 0.0167 0.200 Magnesium
0.0019 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0112 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
0.300 J 17440-09-7 01762 0.133 1.00 Potassium
0.0284 J 17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
1.35 J 17440-23-5 01767 0.167 2.00 Sodium
0.247 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0023 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Beryllium 07047
1Joanne M Gates07/11/2014 08:30 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 37 of 81

LL Sample # TL 7520710
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-5(6-8)-20140701 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:10 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS56S SDG#: DUK36-12
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 02:48 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:33 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 38 of 81

LL Sample # SW 7520711
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-95(7-8)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:10 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS95T SDG#: DUK36-13
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.488 5.92 Antimony
42.3 17440-38-2 06935 0.947 5.92 Arsenic
686 57440-39-3 06946 0.244 7.40 Barium
7.41 17440-41-7 06947 0.0991 1.48 Beryllium
17.5 17440-42-8 07914 1.24 14.8 Boron
N.D.17440-43-9 06949 0.0488 1.48 Cadmium
25.3 17440-47-3 06951 0.163 4.44 Chromium
62.7 17440-50-8 06953 0.488 2.96 Copper
13,000 17439-89-6 01654 4.94 59.2 Iron
17.8 17439-92-1 06955 0.740 4.44 Lead
79.8 17439-96-5 06958 0.123 1.48 Manganese
0.975 J 17439-98-7 06960 0.251 2.96 Molybdenum
33.3 17440-02-0 06961 0.222 2.96 Nickel
6.74 17782-49-2 06936 0.651 5.92 Selenium
N.D.17440-22-4 06966 0.281 1.48 Silver
449 57440-24-6 07968 0.244 7.40 Strontium
N.D.17440-28-0 06925 1.18 8.88 Thallium
27.8 17440-66-6 06972 0.385 5.92 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.0955 J 17439-97-6 00159 0.0145 0.290 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
7.79 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 22.9 C.
% %%Wet Chemistry SM 2540 G-1997
35.0 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:28 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 15:28 1418806370021SW-846 6010C Arsenic 06935
5John P Hook07/09/2014 20:30 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 15:28 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 39 of 81

LL Sample # SW 7520711
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-95(7-8)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:10 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS95T SDG#: DUK36-13
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:28 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 15:28 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 15:28 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 15:28 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 15:28 1418806370021SW-846 6010C Iron 01654
1John P Hook07/09/2014 20:26 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 15:28 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 15:28 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 15:28 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 15:28 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 15:28 1418806370021SW-846 6010C Silver 06966
5John P Hook07/09/2014 20:30 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 15:28 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 15:28 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:27 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402A1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 40 of 81

LL Sample # TL 7520712
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-95(7-8)-20140701 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:10 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS95S SDG#: DUK36-14
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.0141 J 17440-36-0 07044 0.0051 0.0400 Antimony
0.0426 17440-38-2 07035 0.0072 0.0400 Arsenic
0.213 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0184 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
11.7 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
N.D.17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.220 17439-95-4 01757 0.0167 0.200 Magnesium
0.0028 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0150 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
0.283 J 17440-09-7 01762 0.133 1.00 Potassium
0.0280 J 17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
1.35 J 17440-23-5 01767 0.167 2.00 Sodium
0.243 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Beryllium 07047
1Joanne M Gates07/11/2014 08:34 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 41 of 81

LL Sample # TL 7520712
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-95(7-8)-20140701 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:10 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS95S SDG#: DUK36-14
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 02:52 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:35 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 42 of 81

LL Sample # SW 7520713
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-7(3-4)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:30 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS73T SDG#: DUK36-15
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.394 4.78 Antimony
4.27 J 17440-38-2 06935 0.764 4.78 Arsenic
31.8 17440-39-3 06946 0.0394 1.19 Barium
0.383 J 17440-41-7 06947 0.0800 1.19 Beryllium
1.96 J 17440-42-8 07914 1.00 11.9 Boron
N.D.17440-43-9 06949 0.0394 1.19 Cadmium
3.39 J 17440-47-3 06951 0.131 3.58 Chromium
5.03 17440-50-8 06953 0.394 2.39 Copper
2,180 17439-89-6 01654 3.99 47.8 Iron
2.51 J 17439-92-1 06955 0.597 3.58 Lead
8.22 17439-96-5 06958 0.0991 1.19 Manganese
0.294 J 17439-98-7 06960 0.203 2.39 Molybdenum
3.27 17440-02-0 06961 0.179 2.39 Nickel
N.D.17782-49-2 06936 0.525 4.78 Selenium
N.D.17440-22-4 06966 0.227 1.19 Silver
11.8 17440-24-6 07968 0.0394 1.19 Strontium
N.D.17440-28-0 06925 0.955 7.17 Thallium
5.99 17440-66-6 06972 0.310 4.78 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
N.D.17439-97-6 00159 0.0117 0.233 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
6.10 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23.2 C.
% %%Wet Chemistry SM 2540 G-1997
18.7 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Arsenic 06935
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 43 of 81

LL Sample # SW 7520713
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-7(3-4)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:30 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS73T SDG#: DUK36-15
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Iron 01654
1Tara L Snyder07/10/2014 04:41 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Silver 06966
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 15:32 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:29 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402A1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 44 of 81

LL Sample # TL 7520714
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-7(3-4)-20140701 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:30 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS73S SDG#: DUK36-16
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
N.D.17440-38-2 07035 0.0072 0.0400 Arsenic
0.0173 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0397 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
1.47 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.281 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.211 17439-95-4 01757 0.0167 0.200 Magnesium
0.0014 J 17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
6.09 17440-23-5 01767 0.167 2.00 Sodium
0.0101 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0060 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Beryllium 07047
1Joanne M Gates07/11/2014 08:45 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 45 of 81

LL Sample # TL 7520714
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-7(3-4)-20140701 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:30 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS73S SDG#: DUK36-16
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 02:56 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:41 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 46 of 81

LL Sample # SW 7520715
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-7(7-8)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:32 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS77T SDG#: DUK36-17
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.546 6.61 Antimony
31.1 17440-38-2 06935 1.06 6.61 Arsenic
543 57440-39-3 06946 0.273 8.27 Barium
5.79 17440-41-7 06947 0.111 1.65 Beryllium
15.6 J 17440-42-8 07914 1.39 16.5 Boron
N.D.17440-43-9 06949 0.0546 1.65 Cadmium
22.2 17440-47-3 06951 0.182 4.96 Chromium
58.2 17440-50-8 06953 0.546 3.31 Copper
8,130 17439-89-6 01654 5.52 66.1 Iron
17.7 17439-92-1 06955 0.827 4.96 Lead
43.5 17439-96-5 06958 0.137 1.65 Manganese
1.62 J 17439-98-7 06960 0.281 3.31 Molybdenum
27.0 17440-02-0 06961 0.248 3.31 Nickel
6.29 J 17782-49-2 06936 0.727 6.61 Selenium
N.D.17440-22-4 06966 0.314 1.65 Silver
336 57440-24-6 07968 0.273 8.27 Strontium
N.D.17440-28-0 06925 1.32 9.92 Thallium
22.4 17440-66-6 06972 0.430 6.61 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.0915 J 17439-97-6 00159 0.0157 0.315 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
7.21 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23.3 C.
% %%Wet Chemistry SM 2540 G-1997
40.7 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:36 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 15:36 1418806370021SW-846 6010C Arsenic 06935
5Tara L Snyder07/10/2014 04:48 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 15:36 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 47 of 81

LL Sample # SW 7520715
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-7(7-8)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:32 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS77T SDG#: DUK36-17
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:36 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 15:36 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 15:36 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 15:36 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 15:36 1418806370021SW-846 6010C Iron 01654
1Tara L Snyder07/10/2014 04:44 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 15:36 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 15:36 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 15:36 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 15:36 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 15:36 1418806370021SW-846 6010C Silver 06966
5Tara L Snyder07/10/2014 04:48 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 15:36 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 15:36 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:31 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402A1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 48 of 81

LL Sample # TL 7520716
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-7(7-8)-20140701 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:32 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS77S SDG#: DUK36-18
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.010 J 17440-36-0 07044 0.0051 0.0400 Antimony
0.0182 J 17440-38-2 07035 0.0072 0.0400 Arsenic
0.295 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0278 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
5.60 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
N.D.17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.306 17439-95-4 01757 0.0167 0.200 Magnesium
0.0054 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0261 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17440-09-7 01762 0.133 1.00 Potassium
0.0053 J 17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
2.71 17440-23-5 01767 0.167 2.00 Sodium
0.139 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Beryllium 07047
1Joanne M Gates07/11/2014 08:48 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 49 of 81

LL Sample # TL 7520716
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-7(7-8)-20140701 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:32 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS77S SDG#: DUK36-18
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 02:59 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:43 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 50 of 81

LL Sample # SW 7520717
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-4(18-20)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 12:48 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D418T SDG#: DUK36-19
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
0.839 J 17440-36-0 06944 0.699 8.47 Antimony
3.02 J 17440-38-2 06935 1.36 8.47 Arsenic
34.2 17440-39-3 06946 0.0699 2.12 Barium
N.D.17440-41-7 06947 0.142 2.12 Beryllium
7.03 J 17440-42-8 07914 1.78 21.2 Boron
0.0826 J 17440-43-9 06949 0.0699 2.12 Cadmium
6.51 17440-47-3 06951 0.233 6.36 Chromium
3.15 J 17440-50-8 06953 0.699 4.24 Copper
1,610 17439-89-6 01654 7.08 84.7 Iron
2.32 J 17439-92-1 06955 1.06 6.36 Lead
15.6 17439-96-5 06958 0.176 2.12 Manganese
0.428 J 17439-98-7 06960 0.360 4.24 Molybdenum
3.23 J 17440-02-0 06961 0.318 4.24 Nickel
N.D.17782-49-2 06936 0.932 8.47 Selenium
N.D.17440-22-4 06966 0.403 2.12 Silver
21.0 17440-24-6 07968 0.0699 2.12 Strontium
N.D.17440-28-0 06925 1.69 12.7 Thallium
9.63 17440-66-6 06972 0.551 8.47 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
N.D.17439-97-6 00159 0.0209 0.418 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
5.54 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23.1 C.
% %%Wet Chemistry SM 2540 G-1997
52.8 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Arsenic 06935
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 51 of 81

LL Sample # SW 7520717
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-4(18-20)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 12:48 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D418T SDG#: DUK36-19
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Iron 01654
1Tara L Snyder07/10/2014 04:53 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Silver 06966
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 15:40 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:33 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402B1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 52 of 81

LL Sample # TL 7520718
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-4(18-20)-20140701 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 12:48 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D418S SDG#: DUK36-20
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
N.D.17440-38-2 07035 0.0072 0.0400 Arsenic
0.0424 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0994 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
1.08 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
0.0037 J 17440-50-8 07053 0.0028 0.0200 Copper
0.0850 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.190 J 17439-95-4 01757 0.0167 0.200 Magnesium
0.0020 J 17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
12.6 17440-23-5 01767 0.167 2.00 Sodium
0.0033 J 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0091 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Beryllium 07047
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 53 of 81

LL Sample # TL 7520718
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-4(18-20)-20140701 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 12:48 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D418S SDG#: DUK36-20
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 03:03 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:45 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 54 of 81

LL Sample # SW 7520719
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-11(7-8)-20140702 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 09:58 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D117T SDG#: DUK36-21
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.345 4.18 Antimony
6.44 17440-38-2 06935 0.668 4.18 Arsenic
38.8 17440-39-3 06946 0.0345 1.04 Barium
0.845 J 17440-41-7 06947 0.0700 1.04 Beryllium
2.62 J 17440-42-8 07914 0.877 10.4 Boron
N.D.17440-43-9 06949 0.0345 1.04 Cadmium
4.16 17440-47-3 06951 0.115 3.13 Chromium
7.55 17440-50-8 06953 0.345 2.09 Copper
2,080 17439-89-6 01654 3.49 41.8 Iron
3.52 17439-92-1 06955 0.522 3.13 Lead
10.9 17439-96-5 06958 0.0867 1.04 Manganese
0.378 J 17439-98-7 06960 0.178 2.09 Molybdenum
3.93 17440-02-0 06961 0.157 2.09 Nickel
N.D.17782-49-2 06936 0.459 4.18 Selenium
N.D.17440-22-4 06966 0.198 1.04 Silver
21.3 17440-24-6 07968 0.0345 1.04 Strontium
N.D.17440-28-0 06925 0.835 6.27 Thallium
3.99 J 17440-66-6 06972 0.272 4.18 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
N.D.17439-97-6 00159 0.0108 0.216 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
6.43 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23.2 C.
% %%Wet Chemistry SM 2540 G-1997
8.8 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Arsenic 06935
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 55 of 81

LL Sample # SW 7520719
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-11(7-8)-20140702 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 09:58 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D117T SDG#: DUK36-21
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Iron 01654
1Tara L Snyder07/10/2014 04:56 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Silver 06966
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 15:43 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:35 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402B1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 56 of 81

LL Sample # TL 7520720
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-11(7-8)-20140702 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 09:58 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D117S SDG#: DUK36-22
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
N.D.17440-38-2 07035 0.0072 0.0400 Arsenic
0.0038 J 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0321 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
0.791 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.0362 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.278 17439-95-4 01757 0.0167 0.200 Magnesium
N.D.17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
2.55 17440-23-5 01767 0.167 2.00 Sodium
0.0202 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Beryllium 07047
1Joanne M Gates07/11/2014 08:52 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 57 of 81

LL Sample # TL 7520720
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-11(7-8)-20140702 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 09:58 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D117S SDG#: DUK36-22
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 03:07 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:47 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 58 of 81

LL Sample # SW 7520721
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-11(11-12)-20140702 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 10:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D111T SDG#: DUK36-23
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.383 4.65 Antimony
7.54 17440-38-2 06935 0.743 4.65 Arsenic
261 57440-39-3 06946 0.192 5.81 Barium
1.59 17440-41-7 06947 0.0778 1.16 Beryllium
4.89 J 17440-42-8 07914 0.976 11.6 Boron
N.D.17440-43-9 06949 0.0383 1.16 Cadmium
6.59 17440-47-3 06951 0.128 3.48 Chromium
14.7 17440-50-8 06953 0.383 2.32 Copper
9,420 17439-89-6 01654 3.88 46.5 Iron
3.60 17439-92-1 06955 0.581 3.48 Lead
46.9 17439-96-5 06958 0.0964 1.16 Manganese
0.441 J 17439-98-7 06960 0.197 2.32 Molybdenum
8.38 17440-02-0 06961 0.174 2.32 Nickel
0.555 J 17782-49-2 06936 0.511 4.65 Selenium
N.D.17440-22-4 06966 0.221 1.16 Silver
83.7 17440-24-6 07968 0.0383 1.16 Strontium
N.D.17440-28-0 06925 0.929 6.97 Thallium
6.30 17440-66-6 06972 0.302 4.65 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
N.D.17439-97-6 00159 0.0117 0.233 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
6.69 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23.1 C.
% %%Wet Chemistry SM 2540 G-1997
16.4 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Arsenic 06935
5Tara L Snyder07/10/2014 05:04 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 59 of 81

LL Sample # SW 7520721
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-11(11-12)-20140702 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 10:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D111T SDG#: DUK36-23
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Iron 01654
1Tara L Snyder07/10/2014 05:00 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Silver 06966
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 15:54 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:37 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402B1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 60 of 81

LL Sample # TL 7520722
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-11(11-12)-20140702 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 10:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D111S SDG#: DUK36-24
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
N.D.17440-38-2 07035 0.0072 0.0400 Arsenic
0.0571 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0535 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
1.30 17440-70-2 01750 0.0334 0.400 Calcium
0.0021 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.426 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.500 17439-95-4 01757 0.0167 0.200 Magnesium
0.0054 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0024 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
4.41 17440-23-5 01767 0.167 2.00 Sodium
0.0375 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0060 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Beryllium 07047
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 61 of 81

LL Sample # TL 7520722
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-11(11-12)-20140702 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 10:00 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D111S SDG#: DUK36-24
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 03:18 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:49 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 62 of 81

LL Sample # SW 7520723
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-7(15-16)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:35 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D715T SDG#: DUK36-25
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.377 4.57 Antimony
1.07 J 17440-38-2 06935 0.732 4.57 Arsenic
7.41 17440-39-3 06946 0.0377 1.14 Barium
N.D.17440-41-7 06947 0.0766 1.14 Beryllium
2.75 J 17440-42-8 07914 0.960 11.4 Boron
N.D.17440-43-9 06949 0.0377 1.14 Cadmium
1.12 J 17440-47-3 06951 0.126 3.43 Chromium
N.D.17440-50-8 06953 0.377 2.29 Copper
267 17439-89-6 01654 3.82 45.7 Iron
1.12 J 17439-92-1 06955 0.572 3.43 Lead
2.52 17439-96-5 06958 0.0949 1.14 Manganese
N.D.17439-98-7 06960 0.194 2.29 Molybdenum
0.252 J 17440-02-0 06961 0.171 2.29 Nickel
N.D.17782-49-2 06936 0.503 4.57 Selenium
N.D.17440-22-4 06966 0.217 1.14 Silver
3.43 17440-24-6 07968 0.0377 1.14 Strontium
N.D.17440-28-0 06925 0.915 6.86 Thallium
0.935 J 17440-66-6 06972 0.297 4.57 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
N.D.17439-97-6 00159 0.0118 0.237 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
7.16 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23.1 C.
% %%Wet Chemistry SM 2540 G-1997
16.7 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Arsenic 06935
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 63 of 81

LL Sample # SW 7520723
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-7(15-16)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:35 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D715T SDG#: DUK36-25
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Iron 01654
1Tara L Snyder07/10/2014 05:08 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Silver 06966
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 15:58 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:43 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402B1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 64 of 81

LL Sample # TL 7520724
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-7(15-16)-20140701 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:35 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D715S SDG#: DUK36-26
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
N.D.17440-38-2 07035 0.0072 0.0400 Arsenic
0.0447 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0527 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
1.86 17440-70-2 01750 0.0334 0.400 Calcium
0.0045 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.821 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.364 17439-95-4 01757 0.0167 0.200 Magnesium
0.0079 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0063 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
0.217 J 17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
5.74 17440-23-5 01767 0.167 2.00 Sodium
0.0250 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0099 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Beryllium 07047
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 65 of 81

LL Sample # TL 7520724
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-7(15-16)-20140701 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:35 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D715S SDG#: DUK36-26
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 03:22 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:51 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 66 of 81

LL Sample # SW 7520725
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-14(3-4)-20140702 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 15:30 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D143T SDG#: DUK36-27
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.537 6.50 Antimony
35.1 17440-38-2 06935 1.04 6.50 Arsenic
447 57440-39-3 06946 0.268 8.13 Barium
5.15 17440-41-7 06947 0.109 1.63 Beryllium
9.87 J 17440-42-8 07914 1.37 16.3 Boron
N.D.17440-43-9 06949 0.0537 1.63 Cadmium
21.1 17440-47-3 06951 0.179 4.88 Chromium
56.1 17440-50-8 06953 0.537 3.25 Copper
13,400 17439-89-6 01654 5.43 65.0 Iron
14.6 17439-92-1 06955 0.813 4.88 Lead
152 17439-96-5 06958 0.135 1.63 Manganese
3.02 J 17439-98-7 06960 0.276 3.25 Molybdenum
29.9 17440-02-0 06961 0.244 3.25 Nickel
2.77 J 17782-49-2 06936 0.715 6.50 Selenium
N.D.17440-22-4 06966 0.309 1.63 Silver
235 57440-24-6 07968 0.268 8.13 Strontium
N.D.17440-28-0 06925 1.30 9.76 Thallium
20.5 17440-66-6 06972 0.423 6.50 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.106 J 17439-97-6 00159 0.0156 0.312 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
6.32 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23.1 C.
% %%Wet Chemistry SM 2540 G-1997
38.5 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 16:02 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 16:02 1418806370021SW-846 6010C Arsenic 06935
5Tara L Snyder07/10/2014 05:16 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 16:02 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 67 of 81

LL Sample # SW 7520725
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-14(3-4)-20140702 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 15:30 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D143T SDG#: DUK36-27
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 16:02 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 16:02 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 16:02 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 16:02 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 16:02 1418806370021SW-846 6010C Iron 01654
1Tara L Snyder07/10/2014 05:12 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 16:02 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 16:02 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 16:02 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 16:02 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 16:02 1418806370021SW-846 6010C Silver 06966
5Tara L Snyder07/10/2014 05:16 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 16:02 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 16:02 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:45 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402B1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 68 of 81

LL Sample # TL 7520726
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-14(3-4)-20140702 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 15:30 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D143S SDG#: DUK36-28
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
N.D.17440-38-2 07035 0.0072 0.0400 Arsenic
0.0352 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0466 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
1.11 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.139 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.515 17439-95-4 01757 0.0167 0.200 Magnesium
0.0021 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0073 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
5.53 17440-23-5 01767 0.167 2.00 Sodium
0.0210 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0079 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Beryllium 07047
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 69 of 81

LL Sample # TL 7520726
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-14(3-4)-20140702 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 15:30 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D143S SDG#: DUK36-28
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 03:25 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:53 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 70 of 81

LL Sample # SW 7520727
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-14(7-8)-20140702 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 15:40 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D147T SDG#: DUK36-29
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.526 6.38 Antimony
39.0 17440-38-2 06935 1.02 6.38 Arsenic
443 57440-39-3 06946 0.263 7.97 Barium
2.64 17440-41-7 06947 0.107 1.59 Beryllium
12.4 J 17440-42-8 07914 1.34 15.9 Boron
N.D.17440-43-9 06949 0.0526 1.59 Cadmium
17.1 17440-47-3 06951 0.175 4.78 Chromium
34.9 17440-50-8 06953 0.526 3.19 Copper
16,200 17439-89-6 01654 5.32 63.8 Iron
9.93 17439-92-1 06955 0.797 4.78 Lead
72.7 17439-96-5 06958 0.132 1.59 Manganese
2.19 J 17439-98-7 06960 0.271 3.19 Molybdenum
16.6 17440-02-0 06961 0.239 3.19 Nickel
4.83 J 17782-49-2 06936 0.701 6.38 Selenium
N.D.17440-22-4 06966 0.303 1.59 Silver
195 57440-24-6 07968 0.263 7.97 Strontium
N.D.17440-28-0 06925 1.28 9.57 Thallium
15.0 17440-66-6 06972 0.414 6.38 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.131 J 17439-97-6 00159 0.0154 0.308 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
5.90 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23 C.
% %%Wet Chemistry SM 2540 G-1997
39.1 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 16:06 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 16:06 1418806370021SW-846 6010C Arsenic 06935
5Tara L Snyder07/10/2014 05:32 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 16:06 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 71 of 81

LL Sample # SW 7520727
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-14(7-8)-20140702 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 15:40 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D147T SDG#: DUK36-29
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 16:06 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 16:06 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 16:06 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 16:06 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 16:06 1418806370021SW-846 6010C Iron 01654
1Tara L Snyder07/10/2014 05:28 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 16:06 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 16:06 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 16:06 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 16:06 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 16:06 1418806370021SW-846 6010C Silver 06966
5Tara L Snyder07/10/2014 05:32 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 16:06 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 16:06 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:47 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 20:15 14184039402B1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 19:40 14189820002B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 72 of 81

LL Sample # TL 7520728
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-14(7-8)-20140702 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 15:40 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D147S SDG#: DUK36-30*
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
N.D.17440-38-2 07035 0.0072 0.0400 Arsenic
0.0870 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0250 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
1.71 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
N.D.17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.320 17439-95-4 01757 0.0167 0.200 Magnesium
N.D.17439-96-5 07058 0.00083 0.0100 Manganese
0.0089 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0021 J 17440-02-0 07061 0.0016 0.0200 Nickel
0.409 J 17440-09-7 01762 0.133 1.00 Potassium
0.0065 J 17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
2.76 17440-23-5 01767 0.167 2.00 Sodium
0.129 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Antimony 07044
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Barium 07046
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Beryllium 07047
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Boron 08014
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Cadmium 07049
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Calcium 01750
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 73 of 81

LL Sample # TL 7520728
LL Group # 1486445
Account # 10634
Sample Description: SS-F-DPT-14(7-8)-20140702 Solid Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 15:40 by RD
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:29
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
D147S SDG#: DUK36-30*
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Copper 07053
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Iron 01754
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Lead 07055
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Magnesium 01757
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Manganese 07058
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Molybdenum 07060
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Nickel 07061
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Potassium 01762
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Selenium 07036
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Silver 07066
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Sodium 01767
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Strontium 08068
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Thallium 07022
1Tara L Snyder07/11/2014 03:29 1419006360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 21:55 1419057130031SW-846 7470A Mercury 00259
1James L Mertz07/10/2014 06:33 1419006360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/10/2014 07:34 1419057130031SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/08/2014 12:00 14189-2486-
1567
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 74 of 81

Page 1 of 4

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1486445
Reported: 07/14/14 at 11:29 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Matrix QC may not be reported if insufficient sample or site-specific QC samples were not submitted. In these
situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise
specified in the method.

All Inorganic Initial Calibration and Continuing Calibration Blanks met acceptable method criteria unless
otherwise noted on the Analysis Report.

Laboratory Compliance Quality Control

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Batch number: 141880637002 Sample number(s): 7520693,7520695,7520697,7520699,7520701-
7520704,7520709,7520711,7520713,7520715,7520717,7520719,7520721,7520723,752072
5,7520727

Antimony N.D. 0.330 4.00 mg/kg 104 80-120
Arsenic N.D. 0.640 4.00 mg/kg 106 80-120
Barium 0.0340 J 0.0330 1.00 mg/kg 100 80-120
Beryllium N.D. 0.0670 1.00 mg/kg 100 80-120
Boron 2.54 J 0.840 10.0 mg/kg 98 80-120
Cadmium N.D. 0.0330 1.00 mg/kg 102 80-120
Chromium N.D. 0.110 3.00 mg/kg 100 80-120
Copper N.D. 0.330 2.00 mg/kg 102 80-120
Iron N.D. 3.34 40.0 mg/kg 105 80-120
Lead N.D. 0.500 3.00 mg/kg 104 80-120
Manganese N.D. 0.0830 1.00 mg/kg 103 80-120
Molybdenum N.D. 0.170 2.00 mg/kg 101 80-120
Nickel N.D. 0.150 2.00 mg/kg 106 80-120
Selenium N.D. 0.440 4.00 mg/kg 97 80-120
Silver N.D. 0.190 1.00 mg/kg 82 80-120
Strontium 0.179 J 0.0330 1.00 mg/kg 101 80-120
Thallium N.D. 0.800 6.00 mg/kg 92 80-120
Zinc 1.06 J 0.260 4.00 mg/kg 100 80-120

Batch number: 141880638001 Sample number(s): 7520693,7520695,7520697,7520699,7520701-
7520704,7520709,7520711,7520713,7520715,7520717,7520719,7520721,7520723,752072
5,7520727

Mercury N.D. 0.0100 0.200 mg/kg 85 80-120

Batch number: 141900636001 Sample number(s): 7520694,7520696,7520698,7520700,7520705-
7520708,7520710,7520712,7520714,7520716,7520718,7520720,7520722,7520724,752072
6,7520728

Antimony N.D. 0.0051 0.0400 mg/l 108 80-120
Arsenic N.D. 0.0072 0.0400 mg/l 106 80-120
Barium N.D. 0.00033 0.0100 mg/l 103 80-120
Beryllium N.D. 0.00067 0.0100 mg/l 102 80-120
Boron N.D. 0.0046 0.100 mg/l 95 80-120
Cadmium N.D. 0.00033 0.0100 mg/l 104 80-120
Calcium N.D. 0.0334 0.400 mg/l 103 80-120
Chromium N.D. 0.0013 0.0300 mg/l 103 80-120
Copper N.D. 0.0028 0.0200 mg/l 105 80-120
Iron N.D. 0.0334 0.400 mg/l 105 80-120
Lead N.D. 0.0047 0.0300 mg/l 110 80-120
Magnesium N.D. 0.0167 0.200 mg/l 102 80-120
Manganese N.D. 0.00083 0.0100 mg/l 104 80-120
Molybdenum N.D. 0.0017 0.0200 mg/l 107 80-120
Page 75 of 81

Page 2 of 4

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1486445
Reported: 07/14/14 at 11:29 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max
Nickel N.D. 0.0016 0.0200 mg/l 109 80-120
Potassium N.D. 0.133 1.00 mg/l 100 80-120
Selenium N.D. 0.0048 0.0400 mg/l 104 80-120
Silver N.D. 0.0018 0.0100 mg/l 111 80-120
Sodium N.D. 0.167 2.00 mg/l 103 80-120
Strontium N.D. 0.00033 0.0100 mg/l 104 80-120
Thallium N.D. 0.0051 0.0600 mg/l 98 80-120
Zinc N.D. 0.0020 0.0400 mg/l 103 80-120

Batch number: 141905713003 Sample number(s): 7520694,7520696,7520698,7520700,7520705-
7520708,7520710,7520712,7520714,7520716,7520718,7520720,7520722,7520724,752072
6,7520728

Mercury N.D. 0.00006
0
0.00020 mg/l 107 80-120

Batch number: 14184039402A Sample number(s):
7520693,7520695,7520697,7520699,7520701,7520704,7520709,7520711,7520713,752071
5

pH 100 90-110

Batch number: 14184039402B Sample number(s): 7520717,7520719,7520721,7520723,7520725,7520727
pH 100 90-110

Batch number: 14189820002A Sample number(s): 7520693,7520695,7520697,7520699
Moisture 100 99-101

Batch number: 14189820002B Sample number(s): 7520701-
7520704,7520709,7520711,7520713,7520715,7520717,7520719,7520721,7520723,752072
5,7520727

Moisture 100 99-101
Moisture 100 99-101
Moisture Duplicate 100 99-101

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 141880637002 Sample number(s): 7520693,7520695,7520697,7520699,7520701-
7520704,7520709,7520711,7520713,7520715,7520717,7520719,7520721,7520723,7520725,
7520727 UNSPK: 7520701 BKG: 7520701
Antimony 83 84 75-125 3 20 N.D. N.D. 0 (1) 20
Arsenic 96 98 75-125 2 20 14.6 16.5 12 (1) 20
Barium 96 108 75-125 6 20 269 307 13 20
Beryllium 100 104 83-119 3 20 2.18 2.70 22* (1) 20
Boron 97 96 84-110 1 20 6.62 J 7.35 J 10 (1) 20
Cadmium 95 95 75-120 1 20 N.D. N.D. 0 (1) 20
Chromium 116 118 75-125 2 20 9.34 10.9 15 (1) 20
Copper 102 107 75-125 3 20 21.3 25.8 19 20
Iron 965 (2) 741 (2) 75-125 2 20 9,010 9,100 1 20
Lead 96 100 75-125 4 20 6.81 8.09 17 (1) 20
Page 76 of 81

Page 3 of 4

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1486445
Reported: 07/14/14 at 11:29 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___
Manganese 70* 67* 75-125 1 20 64.1 43.7 38* 20
Molybdenum 97 98 82-110 2 20 1.42 J 1.19 J 17 (1) 20
Nickel 102 103 75-125 1 20 14.7 16.0 9 20
Selenium 96 97 75-125 2 20 2.68 J 3.70 J 32* (1) 20
Silver 75 74* 75-125 0 20 N.D. N.D. 0 (1) 20
Strontium 93 111 81-125 7 20 145 168 15 20
Thallium 75* 75* 78-119 1 20 N.D. N.D. 0 (1) 20
Zinc 92 93 75-125 2 20 13.1 11.3 15 (1) 20

Batch number: 141880638001 Sample number(s): 7520693,7520695,7520697,7520699,7520701-
7520704,7520709,7520711,7520713,7520715,7520717,7520719,7520721,7520723,7520725,
7520727 UNSPK: 7520701 BKG: 7520701
Mercury 97 122* 80-120 22* 20 0.0268 J 0.0312 J 15 (1) 20

Batch number: 141900636001 Sample number(s): 7520694,7520696,7520698,7520700,7520705-
7520708,7520710,7520712,7520714,7520716,7520718,7520720,7520722,7520724,7520726,
7520728 UNSPK: 7520705 BKG: 7520705
Antimony 96 93 75-125 4 20 0.0055 J 0.0066 J 18 (1) 20
Arsenic 98 94 75-125 4 20 0.0197 J 0.0183 J 7 (1) 20
Barium 94 91 75-125 4 20 0.105 0.115 10 20
Beryllium 97 95 75-125 2 20 N.D. N.D. 0 (1) 20
Boron 89 87 75-125 2 20 0.0284 J 0.0285 J 0 (1) 20
Cadmium 91 88 75-125 4 20 N.D. N.D. 0 (1) 20
Calcium 94 90 75-125 4 20 5.40 5.30 2 20
Chromium 91 90 75-125 1 20 0.0021 J 0.0019 J 12 (1) 20
Copper 94 91 75-125 3 20 0.0085 J 0.0091 J 8 (1) 20
Iron 98 99 75-125 1 20 0.370 J 0.362 J 2 (1) 20
Lead 91 88 75-125 3 20 N.D. N.D. 0 (1) 20
Magnesium 94 92 75-125 2 20 0.323 0.314 3 (1) 20
Manganese 90 89 75-125 1 20 0.0031 J 0.0032 J 4 (1) 20
Molybdenum 94 91 75-125 3 20 0.0172 J 0.0149 J 14 (1) 20
Nickel 90 87 75-125 3 20 N.D. N.D. 0 (1) 20
Potassium 98 96 75-125 2 20 N.D. N.D. 0 (1) 20
Selenium 96 93 75-125 3 20 N.D. 0.0051 J 200* (1) 20
Silver 71* 81 75-125 13 20 N.D. N.D. 0 (1) 20
Sodium 91 90 75-125 1 20 3.58 3.43 4 (1) 20
Strontium 99 96 75-125 3 20 0.122 0.120 1 20
Thallium 87 84 75-125 4 20 N.D. N.D. 0 (1) 20
Zinc 92 89 75-125 3 20 0.0059 J 0.0069 J 16 (1) 20

Batch number: 141905713003 Sample number(s): 7520694,7520696,7520698,7520700,7520705-
7520708,7520710,7520712,7520714,7520716,7520718,7520720,7520722,7520724,7520726,
7520728 UNSPK: 7520705 BKG: 7520705
Mercury 96 91 80-120 6 20 N.D. N.D. 0 (1) 20

Batch number: 14184039402A Sample number(s):
7520693,7520695,7520697,7520699,7520701,7520704,7520709,7520711,7520713,7520715
BKG: 7520701
pH 7.53 7.51 0 3

Batch number: 14184039402B Sample number(s): 7520717,7520719,7520721,7520723,7520725,7520727 BKG: 7520727
pH 5.90 5.86 1 3
Page 77 of 81

Page 4 of 4

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1486445
Reported: 07/14/14 at 11:29 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 14189820002A Sample number(s): 7520693,7520695,7520697,7520699 BKG: 7520697
Moisture 5.0 5.4 8* 5

Batch number: 14189820002B Sample number(s): 7520701-
7520704,7520709,7520711,7520713,7520715,7520717,7520719,7520721,7520723,7520725,
7520727 BKG: 7520701
Moisture 21.0 23.1 10* 5
Moisture 21.0 23.1 10* 5
Moisture Duplicate 21.0 23.1 10* 5

Page 78 of 81
Page 79 of 81
Page 80 of 81
Explanation of Symbols and Abbreviations

3768 0713
The following defines common symbols and abbreviations used in reporting technical data:
RL Reporting Limit BMQL Below Minimum Quantitation Level
N.D. none detected MPN Most Probable Number
TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units
IU International Units NTU nephelometric turbidity units
umhos/cm micromhos/cm ng nanogram(s)
C degrees Celsius F degrees Fahrenheit
meq milliequivalents lb. pound(s)
g gram(s) kg kilogram(s)
µg microgram(s) mg milligram(s)
mL milliliter(s) L liter(s)
m3 cubic meter(s) µL microliter(s)
pg/L picogram/liter
< less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be
reliably determined using this specific test.
> greater than
ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For
aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/l), because one liter of water has a
weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter per liter of gas.
ppb parts per billion
Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight
basis concentration to approximate the value present in a similar sample without moisture. All other results are reported
on an as-received basis.
Data Qualifiers:
C – result confirmed by reanalysis.
J - estimated value – The result is ≥ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ).
U.S. EPA CLP Data Qualifiers:
Organic Qualifiers Inorganic Qualifiers
A TIC is a possible aldol-condensation product B Value is <CRDL, but ≥IDL
B Analyte was also detected in the blank E Estimated due to interference
C Pesticide result confirmed by GC/MS M Duplicate injection precision not met
D Compound quantitated on a diluted sample N Spike sample not within control limits
E Concentration exceeds the calibration range of S Method of standard additions (MSA) used
the instrument for calculation
N Presumptive evidence of a compound (TICs only) U Compound was not detected
P Concentration difference between primary and W Post digestion spike out of control limits
confirmation columns >25% * Duplicate analysis not within control limits
U Compound was not detected + Correlation coefficient for MSA <0.995
X,Y,Z Defined in case narrative
Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.
Measurement uncertainty values, as applicable, are available upon request.
Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the
test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact
us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our
staff. This report shall not be reproduced except in full, without the written approval of the laboratory.
Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as “analyze immediately” are not
performed within 15 minutes.

WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE
FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM
ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF
MERCHANTABILITY. IN NO EVENT SHALL EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL, LLC BE LIABLE FOR INDIRECT, SPECIAL,
CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS
OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL AND (B) WHETHER
EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal
responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Eurofins Lancaster
Laboratories Environmental which includes any conditions that vary from the Standard Terms and Conditions, and Eurofins Lancaster Laboratories
Environmental hereby objects to any conflicting terms contained in any acceptance or order submitted by client.
Page 81 of 81

Respectfully Submitted,

[phone]

Page 2 of 28

LL Sample # SW 7519007
LL Group # 1486078
Account # 10634
Sample Description: SS-MB2(64.0-68.0)-20140625 Grab Soil Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/25/2014 14:45 by WS
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
MB264 SDG#: DUK35-01
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.452 5.48 Antimony
87.3 17440-38-2 06935 0.877 5.48 Arsenic
502 57440-39-3 06946 0.226 6.85 Barium
3.92 17440-41-7 06947 0.0918 1.37 Beryllium
42.3 17440-42-8 07914 1.15 13.7 Boron
N.D.17440-43-9 06949 0.0452 1.37 Cadmium
43.8 17440-47-3 06951 0.151 4.11 Chromium
59.1 17440-50-8 06953 0.452 2.74 Copper
14,500 17439-89-6 01654 4.58 54.8 Iron
26.1 17439-92-1 06955 0.685 4.11 Lead
87.6 17439-96-5 06958 0.114 1.37 Manganese
2.09 J 17439-98-7 06960 0.233 2.74 Molybdenum
29.8 17440-02-0 06961 0.205 2.74 Nickel
4.59 J 17782-49-2 06936 0.603 5.48 Selenium
N.D.17440-22-4 06966 0.260 1.37 Silver
318 57440-24-6 07968 0.226 6.85 Strontium
N.D.17440-28-0 06925 1.10 8.22 Thallium
43.6 17440-66-6 06972 0.356 5.48 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.140 J 17439-97-6 00159 0.0127 0.255 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
8.23 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23.6 C.
% %%Wet Chemistry SM 2540 G-1997
27.0 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 14:54 1418806370021SW-846 6010C Antimony 06944
1Eric L Eby07/08/2014 14:54 1418806370021SW-846 6010C Arsenic 06935
5John P Hook07/09/2014 20:34 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 14:54 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 3 of 28

LL Sample # SW 7519007
LL Group # 1486078
Account # 10634
Sample Description: SS-MB2(64.0-68.0)-20140625 Grab Soil Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/25/2014 14:45 by WS
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
MB264 SDG#: DUK35-01
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 14:54 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 14:54 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 14:54 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 14:54 1418806370021SW-846 6010C Copper 06953
1Eric L Eby07/08/2014 14:54 1418806370021SW-846 6010C Iron 01654
1John P Hook07/09/2014 19:38 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 14:54 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 14:54 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 14:54 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 14:54 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 14:54 1418806370021SW-846 6010C Silver 06966
5John P Hook07/09/2014 20:34 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 14:54 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 14:54 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 14:59 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 18:40 14184039401B1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 18:12 14189820001B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 4 of 28

LL Sample # TL 7519008
LL Group # 1486078
Account # 10634
Sample Description: SS-MB2(64.0-68.0)-20140625 Grab Soil Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/25/2014 14:45 by WS
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
M264S SDG#: DUK35-02
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.184 17440-38-2 07035 0.0072 0.0400 Arsenic
0.124 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0517 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
4.32 17440-70-2 01750 0.0334 0.400 Calcium
0.0024 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.0602 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.751 17439-95-4 01757 0.0167 0.200 Magnesium
0.0038 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0036 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
0.654 J 17440-09-7 01762 0.133 1.00 Potassium
0.0102 J 17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
1.39 J 17440-23-5 01767 0.167 2.00 Sodium
0.281 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Antimony 07044
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/10/2014 05:39 1418906360011SW-846 6010C Barium 07046
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Beryllium 07047
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Boron 08014
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Cadmium 07049
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Calcium 01750
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 5 of 28

LL Sample # TL 7519008
LL Group # 1486078
Account # 10634
Sample Description: SS-MB2(64.0-68.0)-20140625 Grab Soil Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/25/2014 14:45 by WS
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
M264S SDG#: DUK35-02
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Copper 07053
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Iron 01754
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Lead 07055
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Magnesium 01757
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Manganese 07058
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Molybdenum 07060
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Nickel 07061
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Potassium 01762
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Selenium 07036
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Silver 07066
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Sodium 01767
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Strontium 08068
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Thallium 07022
1Katlin N Cataldi07/09/2014 21:31 1418906360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/10/2014 13:38 1418957130021SW-846 7470A Mercury 00259
1Micaela L Dishong07/09/2014 09:10 1418906360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/09/2014 09:25 1418957130021SW-846 7470A WW SW846 Hg Digest 05713
n.a.Darin P Wagner07/07/2014 12:15 14188-482-15671SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 6 of 28

LL Sample # SW 7519009
LL Group # 1486078
Account # 10634
Sample Description: SS-MB2(76.0-80.0)-20140625 Grab Soil Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/25/2014 15:20 by WS
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
MB276 SDG#: DUK35-03
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.457 5.54 Antimony
155 57440-38-2 06935 4.43 27.7 Arsenic
735 107440-39-3 06946 0.457 13.9 Barium
5.70 17440-41-7 06947 0.0928 1.39 Beryllium
55.3 17440-42-8 07914 1.16 13.9 Boron
N.D.17440-43-9 06949 0.0457 1.39 Cadmium
54.5 17440-47-3 06951 0.152 4.16 Chromium
83.8 17440-50-8 06953 0.457 2.77 Copper
31,500 57439-89-6 01654 23.1 277 Iron
28.9 17439-92-1 06955 0.693 4.16 Lead
128 17439-96-5 06958 0.115 1.39 Manganese
3.01 17439-98-7 06960 0.235 2.77 Molybdenum
43.6 17440-02-0 06961 0.208 2.77 Nickel
6.74 17782-49-2 06936 0.609 5.54 Selenium
N.D.17440-22-4 06966 0.263 1.39 Silver
587 57440-24-6 07968 0.229 6.93 Strontium
N.D.17440-28-0 06925 1.11 8.31 Thallium
57.6 17440-66-6 06972 0.360 5.54 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.128 J 17439-97-6 00159 0.0137 0.275 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
8.41 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 23.5 C.
% %%Wet Chemistry SM 2540 G-1997
27.8 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 14:58 1418806370021SW-846 6010C Antimony 06944
5John P Hook07/09/2014 20:39 1418806370021SW-846 6010C Arsenic 06935
10John P Hook07/09/2014 20:43 1418806370021SW-846 6010C Barium 06946
1Eric L Eby07/08/2014 14:58 1418806370021SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 7 of 28

LL Sample # SW 7519009
LL Group # 1486078
Account # 10634
Sample Description: SS-MB2(76.0-80.0)-20140625 Grab Soil Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/25/2014 15:20 by WS
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
MB276 SDG#: DUK35-03
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Eric L Eby07/08/2014 14:58 1418806370021SW-846 6010C Boron 07914
1Eric L Eby07/08/2014 14:58 1418806370021SW-846 6010C Cadmium 06949
1Eric L Eby07/08/2014 14:58 1418806370021SW-846 6010C Chromium 06951
1Eric L Eby07/08/2014 14:58 1418806370021SW-846 6010C Copper 06953
5John P Hook07/09/2014 20:39 1418806370021SW-846 6010C Iron 01654
1John P Hook07/09/2014 19:42 1418806370021SW-846 6010C Lead 06955
1Eric L Eby07/08/2014 14:58 1418806370021SW-846 6010C Manganese 06958
1Eric L Eby07/08/2014 14:58 1418806370021SW-846 6010C Molybdenum 06960
1Eric L Eby07/08/2014 14:58 1418806370021SW-846 6010C Nickel 06961
1Eric L Eby07/08/2014 14:58 1418806370021SW-846 6010C Selenium 06936
1Eric L Eby07/08/2014 14:58 1418806370021SW-846 6010C Silver 06966
5John P Hook07/09/2014 20:39 1418806370021SW-846 6010C Strontium 07968
1Eric L Eby07/08/2014 14:58 1418806370021SW-846 6010C Thallium 06925
1Eric L Eby07/08/2014 14:58 1418806370021SW-846 6010C Zinc 06972
1Parker D Lindstrom07/11/2014 15:01 1418806380011SW-846 7471B Mercury 00159
1James L Mertz07/08/2014 05:19 1418806370021SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/08/2014 07:27 1418806380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/03/2014 18:40 14184039401B1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/08/2014 18:12 14189820001B1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 8 of 28

LL Sample # TL 7519010
LL Group # 1486078
Account # 10634
Sample Description: SS-MB2(76.0-80.0)-20140625 Grab Soil Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/25/2014 15:20 by WS
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
M276S SDG#: DUK35-04
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.316 17440-38-2 07035 0.0072 0.0400 Arsenic
0.0543 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.105 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
4.90 17440-70-2 01750 0.0334 0.400 Calcium
0.0023 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.125 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.849 17439-95-4 01757 0.0167 0.200 Magnesium
0.0034 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0043 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
0.437 J 17440-09-7 01762 0.133 1.00 Potassium
0.0235 J 17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
2.06 17440-23-5 01767 0.167 2.00 Sodium
0.185 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0025 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Antimony 07044
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Arsenic 07035
1Tara L Snyder07/10/2014 06:01 1418906360011SW-846 6010C Barium 07046
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Beryllium 07047
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Boron 08014
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Cadmium 07049
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Calcium 01750
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Chromium 07051
*=This limit was used in the evaluation of the final result
Page 9 of 28

LL Sample # TL 7519010
LL Group # 1486078
Account # 10634
Sample Description: SS-MB2(76.0-80.0)-20140625 Grab Soil Sample
Non-Volatile Extraction
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 06/25/2014 15:20 by WS
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
M276S SDG#: DUK35-04
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Copper 07053
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Iron 01754
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Lead 07055
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Magnesium 01757
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Manganese 07058
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Molybdenum 07060
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Nickel 07061
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Potassium 01762
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Selenium 07036
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Silver 07066
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Sodium 01767
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Strontium 08068
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Thallium 07022
1Katlin N Cataldi07/09/2014 22:07 1418906360011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/10/2014 13:46 1418957130021SW-846 7470A Mercury 00259
1Micaela L Dishong07/09/2014 09:10 1418906360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1James L Mertz07/09/2014 09:25 1418957130021SW-846 7470A WW SW846 Hg Digest 05713
n.a.Darin P Wagner07/07/2014 12:15 14188-482-15671SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 10 of 28

LL Sample # WW 7519011
LL Group # 1486078
Account # 10634
Sample Description: GW-MW16-20140701 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:40 by MP
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DSM16 SDG#: DUK35-05
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.0081 J 17440-38-2 07035 0.0072 0.0400 Arsenic
0.0263 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.143 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
8.66 17440-70-2 01750 0.0334 0.400 Calcium
0.0020 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.781 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
3.86 17439-95-4 01757 0.0167 0.200 Magnesium
0.0204 17439-96-5 07058 0.00083 0.0100 Manganese
0.0118 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
5.46 17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
26.9 17440-23-5 01767 0.167 2.00 Sodium
0.105 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0029 J 17440-62-2 07071 0.0019 0.0100 Vanadium
0.0041 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
28.0 516887-00-600224 1.0 2.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
31.8 514808-79-800228 1.5 5.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
23.8 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
140 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 11 of 28

LL Sample # WW 7519011
LL Group # 1486078
Account # 10634
Sample Description: GW-MW16-20140701 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:40 by MP
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DSM16 SDG#: DUK35-05
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 04:13 1418806350011SW-846 6010C Barium 07046
1Tara L Snyder07/09/2014 04:13 1418806350011SW-846 6010C Beryllium 07047
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Boron 08014
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Cadmium 07049
1Tara L Snyder07/09/2014 04:13 1418806350011SW-846 6010C Calcium 01750
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Copper 07053
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Iron 01754
1Tara L Snyder07/09/2014 04:13 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Magnesium 01757
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Molybdenum 07060
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Nickel 07061
1Tara L Snyder07/09/2014 04:13 1418806350011SW-846 6010C Potassium 01762
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Silver 07066
1Tara L Snyder07/09/2014 04:13 1418806350011SW-846 6010C Sodium 01767
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Strontium 08068
1Tara L Snyder07/09/2014 04:13 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 22:09 1418806350011SW-846 6010C Zinc 07072
1Damary Valentin07/16/2014 07:51 1419557130041SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/08/2014 11:00 1418857130011SW-846 7470A WW SW846 Hg Digest 05713
1Micaela L Dishong07/11/2014 09:34 1419157130022SW-846 7470A WW SW846 Hg Digest 05713
1James L Mertz07/15/2014 09:08 1419557130043SW-846 7470A WW SW846 Hg Digest 05713
5Clinton M Wilson07/02/2014 19:08 14183987601A1EPA 300.0 Bromide 01505
5Clinton M Wilson07/02/2014 19:08 14183987601A1EPA 300.0 Chloride 00224
5Clinton M Wilson07/02/2014 19:08 14183987601A1EPA 300.0 Nitrate Nitrogen 00368
5Clinton M Wilson07/02/2014 19:08 14183987601A1EPA 300.0 Nitrite Nitrogen 01506
5Clinton M Wilson07/02/2014 19:08 14183987601A1EPA 300.0 Sulfate 00228
1Michele L Graham07/07/2014 18:04 14188002103A1EPA 310.1 Total Alkalinity 12150
1Sarah E Thompson07/02/2014 12:20 14183021202A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 12 of 28

LL Sample # WW 7519012
LL Group # 1486078
Account # 10634
Sample Description: GW-MW16D-20140701 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:20 by MP
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS16D SDG#: DUK35-06FD
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.0083 J 17440-38-2 07035 0.0072 0.0400 Arsenic
0.0343 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.432 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
24.5 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
1.82 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
5.97 17439-95-4 01757 0.0167 0.200 Magnesium
0.269 17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0022 J 17440-02-0 07061 0.0016 0.0200 Nickel
4.82 17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
80.7 57440-23-5 01767 0.835 10.0 Sodium
0.154 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0043 J 17440-62-2 07071 0.0019 0.0100 Vanadium
0.0378 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
114 5016887-00-600224 10.0 20.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
89.0 1014808-79-800228 3.0 10.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
2.7 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
345 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 13 of 28

LL Sample # WW 7519012
LL Group # 1486078
Account # 10634
Sample Description: GW-MW16D-20140701 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 13:20 by MP
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS16D SDG#: DUK35-06FD
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 04:16 1418806350011SW-846 6010C Barium 07046
1Tara L Snyder07/09/2014 04:16 1418806350011SW-846 6010C Beryllium 07047
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Boron 08014
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Cadmium 07049
1Tara L Snyder07/09/2014 04:16 1418806350011SW-846 6010C Calcium 01750
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Copper 07053
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Iron 01754
1Tara L Snyder07/09/2014 04:16 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Magnesium 01757
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Molybdenum 07060
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Nickel 07061
1Tara L Snyder07/09/2014 04:16 1418806350011SW-846 6010C Potassium 01762
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Silver 07066
5Tara L Snyder07/09/2014 04:20 1418806350011SW-846 6010C Sodium 01767
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Strontium 08068
1Tara L Snyder07/09/2014 04:16 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 22:20 1418806350011SW-846 6010C Zinc 07072
1Damary Valentin07/16/2014 07:53 1419557130041SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/08/2014 11:00 1418857130011SW-846 7470A WW SW846 Hg Digest 05713
1Micaela L Dishong07/11/2014 09:34 1419157130022SW-846 7470A WW SW846 Hg Digest 05713
1James L Mertz07/15/2014 09:08 1419557130043SW-846 7470A WW SW846 Hg Digest 05713
5Clinton M Wilson07/02/2014 19:56 14183987601A1EPA 300.0 Bromide 01505
50Clinton M Wilson07/03/2014 13:05 14183987601A1EPA 300.0 Chloride 00224
5Clinton M Wilson07/02/2014 19:56 14183987601A1EPA 300.0 Nitrate Nitrogen 00368
5Clinton M Wilson07/02/2014 19:56 14183987601A1EPA 300.0 Nitrite Nitrogen 01506
10Clinton M Wilson07/03/2014 12:46 14183987601A1EPA 300.0 Sulfate 00228
1Michele L Graham07/07/2014 14:55 14188002102A1EPA 310.1 Total Alkalinity 12150
1Sarah E Thompson07/02/2014 12:20 14183021202A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 14 of 28

LL Sample # WW 7519013
LL Group # 1486078
Account # 10634
Sample Description: EB-02-20140701 Grab Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 12:20 by MP
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DSEB2 SDG#: DUK35-07EB
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
N.D.17440-38-2 07035 0.0072 0.0400 Arsenic
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.00094 J 17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-62-2 07071 0.0019 0.0100 Vanadium
N.D.17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 22:23 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 22:23 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 04:24 1418806350011SW-846 6010C Beryllium 07047
1John P Hook07/08/2014 22:23 1418806350011SW-846 6010C Cadmium 07049
1John P Hook07/08/2014 22:23 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 22:23 1418806350011SW-846 6010C Copper 07053
1Tara L Snyder07/09/2014 04:24 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 22:23 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 22:23 1418806350011SW-846 6010C Nickel 07061
1John P Hook07/08/2014 22:23 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 22:23 1418806350011SW-846 6010C Silver 07066
1Tara L Snyder07/09/2014 04:24 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 22:23 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 22:23 1418806350011SW-846 6010C Zinc 07072
1Damary Valentin07/16/2014 07:55 1419557130041SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/08/2014 11:00 1418857130011SW-846 7470A WW SW846 Hg Digest 05713
1Micaela L Dishong07/11/2014 09:34 1419157130022SW-846 7470A WW SW846 Hg Digest 05713
1James L Mertz07/15/2014 09:08 1419557130043SW-846 7470A WW SW846 Hg Digest 05713
*=This limit was used in the evaluation of the final result
Page 15 of 28

LL Sample # WW 7519014
LL Group # 1486078
Account # 10634
Sample Description: SB-02-20140701 Grab Water Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 12:10 by MP
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DSSB2 SDG#: DUK35-08
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
N.D.17440-38-2 07035 0.0072 0.0400 Arsenic
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
N.D.17439-92-1 07055 0.0047 0.0300 Lead
N.D.17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-62-2 07071 0.0019 0.0100 Vanadium
N.D.17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 22:27 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 22:27 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 04:27 1418806350011SW-846 6010C Beryllium 07047
1John P Hook07/08/2014 22:27 1418806350011SW-846 6010C Cadmium 07049
1John P Hook07/08/2014 22:27 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 22:27 1418806350011SW-846 6010C Copper 07053
1Tara L Snyder07/09/2014 04:27 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 22:27 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 22:27 1418806350011SW-846 6010C Nickel 07061
1John P Hook07/08/2014 22:27 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 22:27 1418806350011SW-846 6010C Silver 07066
1Tara L Snyder07/09/2014 04:27 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 22:27 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 22:27 1418806350011SW-846 6010C Zinc 07072
1Damary Valentin07/16/2014 07:57 1419557130041SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/08/2014 11:00 1418857130011SW-846 7470A WW SW846 Hg Digest 05713
1Micaela L Dishong07/11/2014 09:34 1419157130022SW-846 7470A WW SW846 Hg Digest 05713
1James L Mertz07/15/2014 09:08 1419557130043SW-846 7470A WW SW846 Hg Digest 05713
*=This limit was used in the evaluation of the final result
Page 16 of 28

LL Sample # WW 7519015
LL Group # 1486078
Account # 10634
Sample Description: GW-MW20-20140701 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 15:40 by MP
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DSM20 SDG#: DUK35-09
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
N.D.17440-38-2 07035 0.0072 0.0400 Arsenic
0.126 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.129 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
85.5 17440-70-2 01750 0.0334 0.400 Calcium
0.0019 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
2.61 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
8.94 17439-95-4 01757 0.0167 0.200 Magnesium
0.413 17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0134 J 17440-02-0 07061 0.0016 0.0200 Nickel
6.71 17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
16.3 17440-23-5 01767 0.167 2.00 Sodium
0.785 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0413 17440-62-2 07071 0.0019 0.0100 Vanadium
0.0054 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
18.8 516887-00-600224 1.0 2.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
53.7 514808-79-800228 1.5 5.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
207 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
334 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 17 of 28

LL Sample # WW 7519015
LL Group # 1486078
Account # 10634
Sample Description: GW-MW20-20140701 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 15:40 by MP
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DSM20 SDG#: DUK35-09
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 04:38 1418806350011SW-846 6010C Barium 07046
1Tara L Snyder07/09/2014 04:38 1418806350011SW-846 6010C Beryllium 07047
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Boron 08014
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Cadmium 07049
1Tara L Snyder07/09/2014 04:38 1418806350011SW-846 6010C Calcium 01750
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Copper 07053
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Iron 01754
1Tara L Snyder07/09/2014 04:38 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Magnesium 01757
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Molybdenum 07060
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Nickel 07061
1Tara L Snyder07/09/2014 04:38 1418806350011SW-846 6010C Potassium 01762
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Silver 07066
1Tara L Snyder07/09/2014 04:38 1418806350011SW-846 6010C Sodium 01767
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Strontium 08068
1Tara L Snyder07/09/2014 04:38 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 22:31 1418806350011SW-846 6010C Zinc 07072
1Damary Valentin07/16/2014 07:59 1419557130041SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/08/2014 11:00 1418857130011SW-846 7470A WW SW846 Hg Digest 05713
1Micaela L Dishong07/11/2014 09:34 1419157130022SW-846 7470A WW SW846 Hg Digest 05713
1James L Mertz07/15/2014 09:08 1419557130043SW-846 7470A WW SW846 Hg Digest 05713
5Clinton M Wilson07/02/2014 23:59 14183987601B1EPA 300.0 Bromide 01505
5Clinton M Wilson07/02/2014 23:59 14183987601B1EPA 300.0 Chloride 00224
5Clinton M Wilson07/02/2014 23:59 14183987601B1EPA 300.0 Nitrate Nitrogen 00368
5Clinton M Wilson07/02/2014 23:59 14183987601B1EPA 300.0 Nitrite Nitrogen 01506
5Clinton M Wilson07/02/2014 23:59 14183987601B1EPA 300.0 Sulfate 00228
1Michele L Graham07/07/2014 14:28 14188002102A1EPA 310.1 Total Alkalinity 12150
1Sarah E Thompson07/03/2014 07:43 14184021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 18 of 28

LL Sample # WW 7519016
LL Group # 1486078
Account # 10634
Sample Description: GW-MW20D-20140701 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 16:35 by MP
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS20D SDG#: DUK35-10FD*
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
N.D.17440-38-2 07035 0.0072 0.0400 Arsenic
0.0587 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.227 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
69.9 17440-70-2 01750 0.0334 0.400 Calcium
0.0014 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
2.31 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
5.62 17439-95-4 01757 0.0167 0.200 Magnesium
0.190 17439-96-5 07058 0.00083 0.0100 Manganese
0.0072 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
2.72 17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
51.7 27440-23-5 01767 0.334 4.00 Sodium
0.186 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-62-2 07071 0.0019 0.0100 Vanadium
0.0020 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
83.5 2016887-00-600224 4.0 8.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
69.6 514808-79-800228 1.5 5.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
118 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
365 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 19 of 28

LL Sample # WW 7519016
LL Group # 1486078
Account # 10634
Sample Description: GW-MW20D-20140701 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 16:35 by MP
Submitted: 07/02/2014 09:20
GeoSyntec Consultants
Reported: 07/16/2014 13:58
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS20D SDG#: DUK35-10FD*
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 04:46 1418806350011SW-846 6010C Barium 07046
1Tara L Snyder07/09/2014 04:46 1418806350011SW-846 6010C Beryllium 07047
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Boron 08014
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Cadmium 07049
1Tara L Snyder07/09/2014 04:46 1418806350011SW-846 6010C Calcium 01750
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Copper 07053
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Iron 01754
1Tara L Snyder07/09/2014 04:46 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Magnesium 01757
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Molybdenum 07060
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Nickel 07061
1Tara L Snyder07/09/2014 04:46 1418806350011SW-846 6010C Potassium 01762
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Silver 07066
2Tara L Snyder07/09/2014 04:50 1418806350011SW-846 6010C Sodium 01767
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Strontium 08068
1Tara L Snyder07/09/2014 04:46 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 22:35 1418806350011SW-846 6010C Zinc 07072
1Damary Valentin07/16/2014 08:01 1419557130041SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/08/2014 11:00 1418857130011SW-846 7470A WW SW846 Hg Digest 05713
1Micaela L Dishong07/11/2014 09:34 1419157130022SW-846 7470A WW SW846 Hg Digest 05713
1James L Mertz07/15/2014 09:08 1419557130043SW-846 7470A WW SW846 Hg Digest 05713
5Clinton M Wilson07/03/2014 01:20 14183987601B1EPA 300.0 Bromide 01505
20Clinton M Wilson07/03/2014 13:21 14183987601B1EPA 300.0 Chloride 00224
5Clinton M Wilson07/03/2014 01:20 14183987601B1EPA 300.0 Nitrate Nitrogen 00368
5Clinton M Wilson07/03/2014 01:20 14183987601B1EPA 300.0 Nitrite Nitrogen 01506
5Clinton M Wilson07/03/2014 01:20 14183987601B1EPA 300.0 Sulfate 00228
1Michele L Graham07/07/2014 14:09 14188002102A1EPA 310.1 Total Alkalinity 12150
1Sarah E Thompson07/03/2014 07:43 14184021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 20 of 28

Page 1 of 5

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1486078
Reported: 07/16/14 at 01:58 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Matrix QC may not be reported if insufficient sample or site-specific QC samples were not submitted. In these
situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise
specified in the method.

All Inorganic Initial Calibration and Continuing Calibration Blanks met acceptable method criteria unless
otherwise noted on the Analysis Report.

Laboratory Compliance Quality Control

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Batch number: 141880635001 Sample number(s): 7519011-7519016
Antimony N.D. 0.0051 0.0400 mg/l 109 88-111
Arsenic N.D. 0.0072 0.0400 mg/l 111 90-113
Barium N.D. 0.00033 0.0100 mg/l 108 90-110
Beryllium N.D. 0.00067 0.0100 mg/l 106 90-111
Boron N.D. 0.0046 0.100 mg/l 100 90-110
Cadmium N.D. 0.00033 0.0100 mg/l 105 90-112
Calcium N.D. 0.0334 0.400 mg/l 109 90-112
Chromium N.D. 0.0013 0.0300 mg/l 102 90-110
Copper N.D. 0.0028 0.0200 mg/l 108 90-112
Iron N.D. 0.0334 0.400 mg/l 112 90-112
Lead N.D. 0.0047 0.0300 mg/l 114 88-116
Magnesium N.D. 0.0167 0.200 mg/l 107 89-110
Manganese 0.0013 J 0.00083 0.0100 mg/l 108 90-110
Molybdenum N.D. 0.0017 0.0200 mg/l 106 90-110
Nickel N.D. 0.0016 0.0200 mg/l 111 90-117
Potassium N.D. 0.133 1.00 mg/l 104 90-110
Selenium N.D. 0.0048 0.0400 mg/l 103 89-113
Silver N.D. 0.0018 0.0100 mg/l 94 80-120
Sodium N.D. 0.167 2.00 mg/l 106 87-114
Strontium N.D. 0.00033 0.0100 mg/l 108 90-110
Thallium N.D. 0.0051 0.0600 mg/l 101 90-118
Vanadium N.D. 0.0019 0.0100 mg/l 102 90-110
Zinc N.D. 0.0020 0.0400 mg/l 104 90-110

Batch number: 141880637002 Sample number(s): 7519007,7519009
Antimony N.D. 0.330 4.00 mg/kg 104 80-120
Arsenic N.D. 0.640 4.00 mg/kg 106 80-120
Barium 0.0340 J 0.0330 1.00 mg/kg 100 80-120
Beryllium N.D. 0.0670 1.00 mg/kg 100 80-120
Boron 2.54 J 0.840 10.0 mg/kg 98 80-120
Cadmium N.D. 0.0330 1.00 mg/kg 102 80-120
Chromium N.D. 0.110 3.00 mg/kg 100 80-120
Copper N.D. 0.330 2.00 mg/kg 102 80-120
Iron N.D. 3.34 40.0 mg/kg 105 80-120
Lead N.D. 0.500 3.00 mg/kg 104 80-120
Manganese N.D. 0.0830 1.00 mg/kg 103 80-120
Molybdenum N.D. 0.170 2.00 mg/kg 101 80-120
Nickel N.D. 0.150 2.00 mg/kg 106 80-120
Selenium N.D. 0.440 4.00 mg/kg 97 80-120
Silver N.D. 0.190 1.00 mg/kg 82 80-120
Strontium 0.179 J 0.0330 1.00 mg/kg 101 80-120
Thallium N.D. 0.800 6.00 mg/kg 92 80-120
Zinc 1.06 J 0.260 4.00 mg/kg 100 80-120
Page 21 of 28

Page 2 of 5

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1486078
Reported: 07/16/14 at 01:58 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Batch number: 141880638001 Sample number(s): 7519007,7519009
Mercury N.D. 0.0100 0.200 mg/kg 85 80-120

Batch number: 141890636001 Sample number(s): 7519008,7519010
Antimony N.D. 0.0051 0.0400 mg/l 102 80-120
Arsenic N.D. 0.0072 0.0400 mg/l 102 80-120
Barium N.D. 0.00033 0.0100 mg/l 101 80-120
Beryllium N.D. 0.00067 0.0100 mg/l 100 80-120
Boron N.D. 0.0046 0.100 mg/l 97 80-120
Cadmium N.D. 0.00033 0.0100 mg/l 102 80-120
Calcium N.D. 0.0334 0.400 mg/l 101 80-120
Chromium N.D. 0.0013 0.0300 mg/l 101 80-120
Copper N.D. 0.0028 0.0200 mg/l 97 80-120
Iron N.D. 0.0334 0.400 mg/l 102 80-120
Lead N.D. 0.0047 0.0300 mg/l 105 80-120
Magnesium N.D. 0.0167 0.200 mg/l 98 80-120
Manganese 0.0011 J 0.00083 0.0100 mg/l 102 80-120
Molybdenum N.D. 0.0017 0.0200 mg/l 101 80-120
Nickel N.D. 0.0016 0.0200 mg/l 105 80-120
Potassium N.D. 0.133 1.00 mg/l 97 80-120
Selenium N.D. 0.0048 0.0400 mg/l 97 80-120
Silver N.D. 0.0018 0.0100 mg/l 103 80-120
Sodium N.D. 0.167 2.00 mg/l 98 80-120
Strontium N.D. 0.00033 0.0100 mg/l 99 80-120
Thallium 0.0056 J 0.0051 0.0600 mg/l 91 80-120
Zinc 0.0036 J 0.0020 0.0400 mg/l 101 80-120

Batch number: 141895713002 Sample number(s): 7519008,7519010
Mercury N.D. 0.00006
0
0.00020 mg/l 112 80-120

Batch number: 141955713004 Sample number(s): 7519011-7519016
Mercury N.D. 0.00006
0
0.00020 mg/l 100 80-120

Batch number: 14183987601A Sample number(s): 7519011-7519012
Bromide N.D. 0.40 0.50 mg/l 91 91 90-110 0 20
Chloride N.D. 0.20 0.40 mg/l 93 92 90-110 0 20
Nitrate Nitrogen N.D. 0.050 0.10 mg/l 93 94 90-110 0 20
Nitrite Nitrogen N.D. 0.080 0.10 mg/l 93 93 90-110 0 20
Sulfate N.D. 0.30 1.0 mg/l 98 99 90-110 0 20

Batch number: 14183987601B Sample number(s): 7519015-7519016
Bromide N.D. 0.40 0.50 mg/l 91 91 90-110 0 20
Chloride N.D. 0.20 0.40 mg/l 93 92 90-110 0 20
Nitrate Nitrogen N.D. 0.050 0.10 mg/l 93 94 90-110 0 20
Nitrite Nitrogen N.D. 0.080 0.10 mg/l 93 93 90-110 0 20
Sulfate N.D. 0.30 1.0 mg/l 98 99 90-110 0 20

Batch number: 14183021202A Sample number(s): 7519011-7519012
Total Dissolved Solids N.D. 9.7 30.0 mg/l 98 80-120

Batch number: 14184021201A Sample number(s): 7519015-7519016
Total Dissolved Solids N.D. 9.7 30.0 mg/l 95 80-120

Page 22 of 28

Page 3 of 5

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1486078
Reported: 07/16/14 at 01:58 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max
Batch number: 14184039401B Sample number(s): 7519007,7519009
pH 99 90-110

Batch number: 14188002102A Sample number(s): 7519012,7519015-7519016
Total Alkalinity N.D. 0.70 2.0 mg/l as
CaCO3
97 90-110

Batch number: 14188002103A Sample number(s): 7519011
Total Alkalinity N.D. 0.70 2.0 mg/l as
CaCO3
96 90-110

Batch number: 14189820001B Sample number(s): 7519007,7519009
Moisture 100 99-101

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 141880635001 Sample number(s): 7519011-7519016 UNSPK: P520777 BKG: P520777
Antimony 108 106 76-122 2 20 N.D. N.D. 0 (1) 20
Arsenic 104 108 81-123 3 20 0.0199 J 0.0133 J 39* (1) 20
Barium 102 101 78-125 1 20 0.144 0.136 6 20
Beryllium 102 101 87-114 1 20 N.D. N.D. 0 (1) 20
Boron 74* 87 87-111 6 20 2.35 2.10 11 (1) 20
Cadmium 99 99 75-122 0 20 N.D. N.D. 0 (1) 20
Calcium 7 (2) -1 (2) 75-125 0 20 89.4 84.3 6 20
Chromium 98 95 76-120 2 20 0.0017 J 0.0019 J 11 (1) 20
Copper 106 106 86-122 0 20 N.D. N.D. 0 (1) 20
Iron 72 (2) 112 (2) 75-125 7 20 4.72 4.44 6 20
Lead 101 100 75-125 1 20 N.D. N.D. 0 (1) 20
Magnesium 20 (2) 10 (2) 81-118 1 20 25.1 23.6 6 20
Manganese 98 94 75-125 2 20 0.459 0.430 7 20
Molybdenum 102 102 89-117 0 20 0.319 0.293 9 20
Nickel 104 103 79-123 1 20 N.D. N.D. 0 (1) 20
Potassium 100 98 77-128 1 20 14.7 13.8 6 20
Selenium 100 101 75-125 1 20 N.D. N.D. 0 (1) 20
Silver 93 91 75-125 2 20 N.D. N.D. 0 (1) 20
Sodium 21 (2) 51 (2) 84-117 3 20 52.1 47.3 10 (1) 20
Strontium 49* 72* 88-117 6 20 3.20 2.88 11 20
Thallium 95 94 75-125 0 20 N.D. N.D. 0 (1) 20
Vanadium 97 97 90-117 0 20 N.D. N.D. 0 (1) 20
Zinc 100 99 85-117 0 20 0.0041 J 0.0038 J 8 (1) 20

Batch number: 141880637002 Sample number(s): 7519007,7519009 UNSPK: P520701 BKG: P520701
Antimony 83 84 75-125 3 20 N.D. N.D. 0 (1) 20
Arsenic 96 98 75-125 2 20 14.6 16.5 12 (1) 20
Barium 96 108 75-125 6 20 269 307 13 20
Beryllium 100 104 83-119 3 20 2.18 2.70 22* (1) 20
Boron 97 96 84-110 1 20 6.62 J 7.35 J 10 (1) 20
Cadmium 95 95 75-120 1 20 N.D. N.D. 0 (1) 20
Page 23 of 28

Page 4 of 5

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1486078
Reported: 07/16/14 at 01:58 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___
Chromium 116 118 75-125 2 20 9.34 10.9 15 (1) 20
Copper 102 107 75-125 3 20 21.3 25.8 19 20
Iron 965 (2) 741 (2) 75-125 2 20 9,010 9,100 1 20
Lead 96 100 75-125 4 20 6.81 8.09 17 (1) 20
Manganese 70* 67* 75-125 1 20 64.1 43.7 38* 20
Molybdenum 97 98 82-110 2 20 1.42 J 1.19 J 17 (1) 20
Nickel 102 103 75-125 1 20 14.7 16.0 9 20
Selenium 96 97 75-125 2 20 2.68 J 3.70 J 32* (1) 20
Silver 75 74* 75-125 0 20 N.D. N.D. 0 (1) 20
Strontium 93 111 81-125 7 20 145 168 15 20
Thallium 75* 75* 78-119 1 20 N.D. N.D. 0 (1) 20
Zinc 92 93 75-125 2 20 13.1 11.3 15 (1) 20

Batch number: 141880638001 Sample number(s): 7519007,7519009 UNSPK: P520701 BKG: P520701
Mercury 97 122* 80-120 22* 20 0.0268 J 0.0312 J 15 (1) 20

Batch number: 141890636001 Sample number(s): 7519008,7519010 UNSPK: 7519008 BKG: 7519008
Antimony 88 87 75-125 1 20 N.D. N.D. 0 (1) 20
Arsenic 89 88 75-125 1 20 0.184 0.182 1 (1) 20
Barium 90 89 75-125 2 20 0.124 0.123 0 20
Beryllium 85 83 75-125 1 20 N.D. N.D. 0 (1) 20
Boron 86 86 75-125 1 20 0.0517 J 0.0473 J 9 (1) 20
Cadmium 89 88 75-125 1 20 N.D. N.D. 0 (1) 20
Calcium 89 89 75-125 0 20 4.32 4.36 1 20
Chromium 88 87 75-125 1 20 0.0024 J 0.0028 J 15 (1) 20
Copper 93 93 75-125 1 20 N.D. N.D. 0 (1) 20
Iron 87 87 75-125 0 20 0.0602 J 0.0572 J 5 (1) 20
Lead 89 88 75-125 1 20 N.D. N.D. 0 (1) 20
Magnesium 87 87 75-125 0 20 0.751 0.759 1 (1) 20
Manganese 88 87 75-125 1 20 0.0038 J 0.0037 J 2 (1) 20
Molybdenum 89 87 75-125 2 20 0.0036 J 0.0033 J 9 (1) 20
Nickel 89 89 75-125 1 20 N.D. N.D. 0 (1) 20
Potassium 92 92 75-125 0 20 0.654 J 0.663 J 1 (1) 20
Selenium 86 85 75-125 1 20 0.0102 J 0.0101 J 1 (1) 20
Silver 49* 48* 75-125 2 20 N.D. N.D. 0 (1) 20
Sodium 90 89 75-125 0 20 1.39 J 1.39 J 0 (1) 20
Strontium 90 89 75-125 1 20 0.281 0.282 0 20
Thallium 89 87 75-125 1 20 N.D. N.D. 0 (1) 20
Zinc 87 87 75-125 1 20 N.D. N.D. 0 (1) 20

Batch number: 141895713002 Sample number(s): 7519008,7519010 UNSPK: 7519008 BKG: 7519008
Mercury 99 93 80-120 7 20 N.D. N.D. 0 (1) 20

Batch number: 141955713004 Sample number(s): 7519011-7519016 UNSPK: P514111 BKG: P514111
Mercury 94 97 80-120 2 20 N.D. N.D. 0 (1) 20

Batch number: 14183987601A Sample number(s): 7519011-7519012 UNSPK: 7519011 BKG: 7519011
Bromide 89* 90-110 N.D. N.D. 0 (1) 20
Chloride 83* 90-110 28.0 27.8 0 20
Nitrate Nitrogen 92 90-110 N.D. N.D. 0 (1) 20
Nitrite Nitrogen 86* 90-110 N.D. N.D. 0 (1) 20
Sulfate 96 90-110 31.8 31.7 0 20
Page 24 of 28

Page 5 of 5

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1486078
Reported: 07/16/14 at 01:58 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 14183987601B Sample number(s): 7519015-7519016 UNSPK: 7519015 BKG: 7519015
Bromide 89* 90-110 N.D. N.D. 0 (1) 20
Chloride 85* 90-110 18.8 18.6 1 20
Nitrate Nitrogen 91 90-110 N.D. N.D. 0 (1) 20
Nitrite Nitrogen 88* 90-110 N.D. N.D. 0 (1) 20
Sulfate 97 90-110 53.7 53.7 0 20

Batch number: 14183021202A Sample number(s): 7519011-7519012 UNSPK: P518932 BKG: P518932
Total Dissolved Solids 102 66-131 1,620 1,880 15* 5

Batch number: 14184021201A Sample number(s): 7519015-7519016 UNSPK: P519692 BKG: P519692
Total Dissolved Solids 97 66-131 792 786 1 5

Batch number: 14184039401B Sample number(s): 7519007,7519009 BKG: 7519007
pH 8.23 8.20 0 3

Batch number: 14188002102A Sample number(s): 7519012,7519015-7519016 UNSPK: P520819 BKG: P520819
Total Alkalinity 89 85 17-146 2 5 296 296 0 5

Batch number: 14188002103A Sample number(s): 7519011 UNSPK: P520777 BKG: P520777
Total Alkalinity 47 48 17-146 1 5 235 235 0 5

Batch number: 14189820001B Sample number(s): 7519007,7519009 BKG: 7519009
Moisture 27.8 25.9 7* 5

Page 25 of 28
Page 26 of 28
Page 27 of 28
Explanation of Symbols and Abbreviations

3768 0713
The following defines common symbols and abbreviations used in reporting technical data:
RL Reporting Limit BMQL Below Minimum Quantitation Level
N.D. none detected MPN Most Probable Number
TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units
IU International Units NTU nephelometric turbidity units
umhos/cm micromhos/cm ng nanogram(s)
C degrees Celsius F degrees Fahrenheit
meq milliequivalents lb. pound(s)
g gram(s) kg kilogram(s)
µg microgram(s) mg milligram(s)
mL milliliter(s) L liter(s)
m3 cubic meter(s) µL microliter(s)
pg/L picogram/liter
< less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be
reliably determined using this specific test.
> greater than
ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For
aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/l), because one liter of water has a
weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter per liter of gas.
ppb parts per billion
Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight
basis concentration to approximate the value present in a similar sample without moisture. All other results are reported
on an as-received basis.
Data Qualifiers:
C – result confirmed by reanalysis.
J - estimated value – The result is ≥ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ).
U.S. EPA CLP Data Qualifiers:
Organic Qualifiers Inorganic Qualifiers
A TIC is a possible aldol-condensation product B Value is <CRDL, but ≥IDL
B Analyte was also detected in the blank E Estimated due to interference
C Pesticide result confirmed by GC/MS M Duplicate injection precision not met
D Compound quantitated on a diluted sample N Spike sample not within control limits
E Concentration exceeds the calibration range of S Method of standard additions (MSA) used
the instrument for calculation
N Presumptive evidence of a compound (TICs only) U Compound was not detected
P Concentration difference between primary and W Post digestion spike out of control limits
confirmation columns >25% * Duplicate analysis not within control limits
U Compound was not detected + Correlation coefficient for MSA <0.995
X,Y,Z Defined in case narrative
Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.
Measurement uncertainty values, as applicable, are available upon request.
Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the
test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact
us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our
staff. This report shall not be reproduced except in full, without the written approval of the laboratory.
Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as “analyze immediately” are not
performed within 15 minutes.

WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE
FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM
ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF
MERCHANTABILITY. IN NO EVENT SHALL EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL, LLC BE LIABLE FOR INDIRECT, SPECIAL,
CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS
OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL AND (B) WHETHER
EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal
responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Eurofins Lancaster
Laboratories Environmental which includes any conditions that vary from the Standard Terms and Conditions, and Eurofins Lancaster Laboratories
Environmental hereby objects to any conflicting terms contained in any acceptance or order submitted by client.
Page 28 of 28

ANALYTICAL RESULTS

Prepared by:

Eurofins Lancaster Laboratories Environmental
2425 New Holland Pike
Lancaster, PA 17601
Prepared for:

GeoSyntec Consultants
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607

July 14, 2014

Project: Duke Sutton, NC

Submittal Date: 07/03/2014
Group Number: 1486459
SDG: DUK37
PO Number: GC5592
State of Sample Origin: NC

Client Sample Description Lancaster Labs (LL) #
GW-MW13D-20140702 Grab Groundwater Sample 7520777
GW-MW13D-20140702 MS Grab Groundwater Sample 7520778
GW-MW13D-20140702 MSD Grab Groundwater Sample 7520779
GW-MW13D-20140702 DUP Grab Groundwater Sample 7520780
GW-MW13-20140702 Grab Groundwater Sample 7520781
GW-MW15-20140702 Grab Groundwater Sample 7520782
GW-MW159-20140702 Grab Groundwater Sample 7520783
GW-MW15D-20140702 Grab Groundwater Sample 7520784
GW-MW15-20140702-MBQC Grab Groundwater Sample 7520785

The specific methodologies used in obtaining the enclosed analytical results are indicated on the
Laboratory Sample Analysis Record.

ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Lauren Wellborn
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Beau Hodge
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Rachel Donahue
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Herwig Goldemund

Page 1 of 24

Respectfully Submitted,

[phone]

Page 2 of 24

LL Sample # WW 7520777
LL Group # 1486459
Account # 10634
Sample Description: GW-MW13D-20140702 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 12:10 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS13D SDG#: DUK37-01BKG
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.0199 J 17440-38-2 07035 0.0072 0.0400 Arsenic
0.144 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
2.35 57440-42-8 08014 0.0230 0.500 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
89.4 17440-70-2 01750 0.0334 0.400 Calcium
0.0017 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
4.72 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
25.1 17439-95-4 01757 0.0167 0.200 Magnesium
0.459 17439-96-5 07058 0.00083 0.0100 Manganese
0.319 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
14.7 17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
52.1 57440-23-5 01767 0.835 10.0 Sodium
3.20 57440-24-6 08068 0.0017 0.0500 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-62-2 07071 0.0019 0.0100 Vanadium
0.0041 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
59.6 2016887-00-600224 4.0 8.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
96.9 2014808-79-800228 6.0 20.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
235 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
516 1n.a. 00212 19.4 60.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 3 of 24

LL Sample # WW 7520777
LL Group # 1486459
Account # 10634
Sample Description: GW-MW13D-20140702 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 12:10 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS13D SDG#: DUK37-01BKG
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 21:43 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 21:43 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 03:16 1418806350011SW-846 6010C Barium 07046
1Tara L Snyder07/09/2014 03:16 1418806350011SW-846 6010C Beryllium 07047
5Tara L Snyder07/09/2014 03:39 1418806350011SW-846 6010C Boron 08014
1John P Hook07/08/2014 21:43 1418806350011SW-846 6010C Cadmium 07049
1Tara L Snyder07/09/2014 03:16 1418806350011SW-846 6010C Calcium 01750
1John P Hook07/08/2014 21:43 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 21:43 1418806350011SW-846 6010C Copper 07053
1John P Hook07/08/2014 21:43 1418806350011SW-846 6010C Iron 01754
1Joanne M Gates07/09/2014 12:59 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 21:43 1418806350011SW-846 6010C Magnesium 01757
1John P Hook07/08/2014 21:43 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 21:43 1418806350011SW-846 6010C Molybdenum 07060
1John P Hook07/08/2014 21:43 1418806350011SW-846 6010C Nickel 07061
1Tara L Snyder07/09/2014 03:16 1418806350011SW-846 6010C Potassium 01762
1John P Hook07/08/2014 21:43 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 21:43 1418806350011SW-846 6010C Silver 07066
5Tara L Snyder07/09/2014 03:39 1418806350011SW-846 6010C Sodium 01767
5Tara L Snyder07/09/2014 03:39 1418806350011SW-846 6010C Strontium 08068
1Tara L Snyder07/09/2014 03:16 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 21:43 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 21:43 1418806350011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 14:44 1418957130062SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/09/2014 09:23 1418957130061SW-846 7470A WW SW846 Hg Digest 05713
5Clinton M Wilson07/03/2014 19:51 14184987601B1EPA 300.0 Bromide 01505
20Sandra J Miller07/07/2014 07:21 14184987601B1EPA 300.0 Chloride 00224
5Clinton M Wilson07/03/2014 19:51 14184987601B1EPA 300.0 Nitrate Nitrogen 00368
5Clinton M Wilson07/03/2014 19:51 14184987601B1EPA 300.0 Nitrite Nitrogen 01506
20Clinton M Wilson07/05/2014 19:05 14184987601B1EPA 300.0 Sulfate 00228
1Michele L Graham07/07/2014 17:19 14188002103A1EPA 310.1 Total Alkalinity 12150
1Sarah E Thompson07/08/2014 10:13 14189021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 4 of 24

LL Sample # WW 7520778
LL Group # 1486459
Account # 10634
Sample Description: GW-MW13D-20140702 MS Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 12:15 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS13D SDG#: DUK37-01MS
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.540 17440-36-0 07044 0.0051 0.0400 Antimony
0.177 17440-38-2 07035 0.0072 0.0400 Arsenic
2.18 17440-39-3 07046 0.00033 0.0100 Barium
0.0512 17440-41-7 07047 0.00067 0.0100 Beryllium
3.84 57440-42-8 08014 0.0230 0.500 Boron
0.0494 17440-43-9 07049 0.00033 0.0100 Cadmium
89.7 17440-70-2 01750 0.0334 0.400 Calcium
0.197 17440-47-3 07051 0.0013 0.0300 Chromium
0.266 17440-50-8 07053 0.0028 0.0200 Copper
5.45 17439-89-6 01754 0.0334 0.400 Iron
0.151 17439-92-1 07055 0.0047 0.0300 Lead
25.5 17439-95-4 01757 0.0167 0.200 Magnesium
0.950 17439-96-5 07058 0.00083 0.0100 Manganese
2.35 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.519 17440-02-0 07061 0.0016 0.0200 Nickel
24.7 17440-09-7 01762 0.133 1.00 Potassium
0.150 17782-49-2 07036 0.0048 0.0400 Selenium
0.0467 17440-22-4 07066 0.0018 0.0100 Silver
54.2 57440-23-5 01767 0.835 10.0 Sodium
3.70 57440-24-6 08068 0.0017 0.0500 Strontium
0.142 17440-28-0 07022 0.0051 0.0600 Thallium
0.485 17440-62-2 07071 0.0019 0.0100 Vanadium
0.502 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
0.0010 17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
45.3 1024959-67-901505 4.0 5.0 Bromide
127 4016887-00-600224 8.0 16.0 Chloride
9.3 1014797-55-800368 0.50 1.0 Nitrate Nitrogen
8.2 1014797-65-001506 0.80 1.0 Nitrite Nitrogen
288 4014808-79-800228 12.0 40.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
323 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
895 1n.a. 00212 19.4 60.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 5 of 24

LL Sample # WW 7520778
LL Group # 1486459
Account # 10634
Sample Description: GW-MW13D-20140702 MS Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 12:15 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS13D SDG#: DUK37-01MS
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 21:54 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 21:54 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 03:28 1418806350011SW-846 6010C Barium 07046
1Tara L Snyder07/09/2014 03:28 1418806350011SW-846 6010C Beryllium 07047
5Tara L Snyder07/09/2014 03:58 1418806350012SW-846 6010C Boron 08014
1John P Hook07/08/2014 21:54 1418806350011SW-846 6010C Cadmium 07049
1Tara L Snyder07/09/2014 03:28 1418806350011SW-846 6010C Calcium 01750
1John P Hook07/08/2014 21:54 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 21:54 1418806350011SW-846 6010C Copper 07053
1John P Hook07/08/2014 21:54 1418806350011SW-846 6010C Iron 01754
1Joanne M Gates07/09/2014 13:59 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 21:54 1418806350011SW-846 6010C Magnesium 01757
1John P Hook07/08/2014 21:54 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 21:54 1418806350011SW-846 6010C Molybdenum 07060
1John P Hook07/08/2014 21:54 1418806350011SW-846 6010C Nickel 07061
1Tara L Snyder07/09/2014 03:28 1418806350011SW-846 6010C Potassium 01762
1John P Hook07/08/2014 21:54 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 21:54 1418806350011SW-846 6010C Silver 07066
5Tara L Snyder07/09/2014 03:58 1418806350012SW-846 6010C Sodium 01767
5Tara L Snyder07/09/2014 03:58 1418806350012SW-846 6010C Strontium 08068
1Tara L Snyder07/09/2014 03:28 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 21:54 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 21:54 1418806350011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 14:46 1418957130062SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/09/2014 09:23 1418957130061SW-846 7470A WW SW846 Hg Digest 05713
10Clinton M Wilson07/03/2014 20:23 14184987601B1EPA 300.0 Bromide 01505
40Sandra J Miller07/07/2014 07:53 14184987601B1EPA 300.0 Chloride 00224
10Clinton M Wilson07/03/2014 20:23 14184987601B1EPA 300.0 Nitrate Nitrogen 00368
10Clinton M Wilson07/03/2014 20:23 14184987601B1EPA 300.0 Nitrite Nitrogen 01506
40Clinton M Wilson07/05/2014 19:37 14184987601B2EPA 300.0 Sulfate 00228
1Michele L Graham07/07/2014 17:26 14188002103A1EPA 310.1 Total Alkalinity 12150
1Sarah E Thompson07/08/2014 10:13 14189021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 6 of 24

LL Sample # WW 7520779
LL Group # 1486459
Account # 10634
Sample Description: GW-MW13D-20140702 MSD Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 12:20 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS13D SDG#: DUK37-01MSD
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.532 17440-36-0 07044 0.0051 0.0400 Antimony
0.181 17440-38-2 07035 0.0072 0.0400 Arsenic
2.17 17440-39-3 07046 0.00033 0.0100 Barium
0.0507 17440-41-7 07047 0.00067 0.0100 Beryllium
4.09 57440-42-8 08014 0.0230 0.500 Boron
0.0494 17440-43-9 07049 0.00033 0.0100 Cadmium
89.4 17440-70-2 01750 0.0334 0.400 Calcium
0.192 17440-47-3 07051 0.0013 0.0300 Chromium
0.265 17440-50-8 07053 0.0028 0.0200 Copper
5.85 17439-89-6 01754 0.0334 0.400 Iron
0.150 17439-92-1 07055 0.0047 0.0300 Lead
25.3 17439-95-4 01757 0.0167 0.200 Magnesium
0.930 17439-96-5 07058 0.00083 0.0100 Manganese
2.35 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.513 17440-02-0 07061 0.0016 0.0200 Nickel
24.5 17440-09-7 01762 0.133 1.00 Potassium
0.151 17782-49-2 07036 0.0048 0.0400 Selenium
0.0455 17440-22-4 07066 0.0018 0.0100 Silver
57.2 57440-23-5 01767 0.835 10.0 Sodium
3.92 57440-24-6 08068 0.0017 0.0500 Strontium
0.142 17440-28-0 07022 0.0051 0.0600 Thallium
0.486 17440-62-2 07071 0.0019 0.0100 Vanadium
0.501 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
0.0010 17439-97-6 00259 0.000060 0.00020 Mercury
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3Wet Chemistry EPA 310.1
326 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
890 1n.a. 00212 19.4 60.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 21:58 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 21:58 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 03:31 1418806350011SW-846 6010C Barium 07046
1Tara L Snyder07/09/2014 03:31 1418806350011SW-846 6010C Beryllium 07047
*=This limit was used in the evaluation of the final result
Page 7 of 24

LL Sample # WW 7520779
LL Group # 1486459
Account # 10634
Sample Description: GW-MW13D-20140702 MSD Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 12:20 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS13D SDG#: DUK37-01MSD
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
5Tara L Snyder07/09/2014 04:01 1418806350012SW-846 6010C Boron 08014
1John P Hook07/08/2014 21:58 1418806350011SW-846 6010C Cadmium 07049
1Tara L Snyder07/09/2014 03:31 1418806350011SW-846 6010C Calcium 01750
1John P Hook07/08/2014 21:58 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 21:58 1418806350011SW-846 6010C Copper 07053
1John P Hook07/08/2014 21:58 1418806350011SW-846 6010C Iron 01754
1Joanne M Gates07/09/2014 14:03 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 21:58 1418806350011SW-846 6010C Magnesium 01757
1John P Hook07/08/2014 21:58 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 21:58 1418806350011SW-846 6010C Molybdenum 07060
1John P Hook07/08/2014 21:58 1418806350011SW-846 6010C Nickel 07061
1Tara L Snyder07/09/2014 03:31 1418806350011SW-846 6010C Potassium 01762
1John P Hook07/08/2014 21:58 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 21:58 1418806350011SW-846 6010C Silver 07066
5Tara L Snyder07/09/2014 04:01 1418806350011SW-846 6010C Sodium 01767
5Tara L Snyder07/09/2014 04:01 1418806350012SW-846 6010C Strontium 08068
1Tara L Snyder07/09/2014 03:31 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 21:58 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 21:58 1418806350011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 14:49 1418957130062SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/09/2014 09:23 1418957130061SW-846 7470A WW SW846 Hg Digest 05713
1Michele L Graham07/07/2014 17:32 14188002103A1EPA 310.1 Total Alkalinity 12150
1Sarah E Thompson07/08/2014 10:13 14189021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 8 of 24

LL Sample # WW 7520780
LL Group # 1486459
Account # 10634
Sample Description: GW-MW13D-20140702 DUP Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 12:10 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS13D SDG#: DUK37-01DUP
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.0133 J 17440-38-2 07035 0.0072 0.0400 Arsenic
0.136 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
2.10 57440-42-8 08014 0.0230 0.500 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
84.3 17440-70-2 01750 0.0334 0.400 Calcium
0.0019 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
4.44 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
23.6 17439-95-4 01757 0.0167 0.200 Magnesium
0.430 17439-96-5 07058 0.00083 0.0100 Manganese
0.293 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
13.8 17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
47.3 57440-23-5 01767 0.835 10.0 Sodium
2.88 57440-24-6 08068 0.0017 0.0500 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-62-2 07071 0.0019 0.0100 Vanadium
0.0038 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
58.9 2016887-00-600224 4.0 8.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
95.4 2014808-79-800228 6.0 20.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
235 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
503 1n.a. 00212 19.4 60.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 9 of 24

LL Sample # WW 7520780
LL Group # 1486459
Account # 10634
Sample Description: GW-MW13D-20140702 DUP Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 12:10 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS13D SDG#: DUK37-01DUP
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 21:50 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 21:50 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 03:24 1418806350011SW-846 6010C Barium 07046
1Tara L Snyder07/09/2014 03:24 1418806350011SW-846 6010C Beryllium 07047
5Tara L Snyder07/09/2014 03:54 1418806350011SW-846 6010C Boron 08014
1John P Hook07/08/2014 21:50 1418806350011SW-846 6010C Cadmium 07049
1Tara L Snyder07/09/2014 03:24 1418806350011SW-846 6010C Calcium 01750
1John P Hook07/08/2014 21:50 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 21:50 1418806350011SW-846 6010C Copper 07053
1John P Hook07/08/2014 21:50 1418806350011SW-846 6010C Iron 01754
1Tara L Snyder07/09/2014 03:24 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 21:50 1418806350011SW-846 6010C Magnesium 01757
1John P Hook07/08/2014 21:50 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 21:50 1418806350011SW-846 6010C Molybdenum 07060
1John P Hook07/08/2014 21:50 1418806350011SW-846 6010C Nickel 07061
1Tara L Snyder07/09/2014 03:24 1418806350011SW-846 6010C Potassium 01762
1John P Hook07/08/2014 21:50 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 21:50 1418806350011SW-846 6010C Silver 07066
5Tara L Snyder07/09/2014 03:54 1418806350011SW-846 6010C Sodium 01767
5Tara L Snyder07/09/2014 03:54 1418806350011SW-846 6010C Strontium 08068
1Tara L Snyder07/09/2014 03:24 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 21:50 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 21:50 1418806350011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 14:51 1418957130062SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/09/2014 09:23 1418957130061SW-846 7470A WW SW846 Hg Digest 05713
5Clinton M Wilson07/03/2014 20:07 14184987601B1EPA 300.0 Bromide 01505
20Sandra J Miller07/07/2014 07:37 14184987601B1EPA 300.0 Chloride 00224
5Clinton M Wilson07/03/2014 20:07 14184987601B1EPA 300.0 Nitrate Nitrogen 00368
5Clinton M Wilson07/03/2014 20:07 14184987601B1EPA 300.0 Nitrite Nitrogen 01506
20Clinton M Wilson07/05/2014 19:21 14184987601B1EPA 300.0 Sulfate 00228
1Michele L Graham07/07/2014 17:39 14188002103A1EPA 310.1 Total Alkalinity 12150
1Sarah E Thompson07/08/2014 10:13 14189021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 10 of 24

LL Sample # WW 7520781
LL Group # 1486459
Account # 10634
Sample Description: GW-MW13-20140702 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 12:11 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS-13 SDG#: DUK37-02
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.218 17440-38-2 07035 0.0072 0.0400 Arsenic
0.367 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.935 27440-42-8 08014 0.0092 0.200 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
45.3 17440-70-2 01750 0.0334 0.400 Calcium
0.0013 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
5.50 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
15.7 17439-95-4 01757 0.0167 0.200 Magnesium
0.145 17439-96-5 07058 0.00083 0.0100 Manganese
0.140 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
13.0 17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
44.8 27440-23-5 01767 0.334 4.00 Sodium
1.40 27440-24-6 08068 0.00066 0.0200 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-62-2 07071 0.0019 0.0100 Vanadium
0.0022 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
47.2 2016887-00-600224 4.0 8.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
128 2014808-79-800228 6.0 20.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
86.9 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
370 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 11 of 24

LL Sample # WW 7520781
LL Group # 1486459
Account # 10634
Sample Description: GW-MW13-20140702 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 12:11 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS-13 SDG#: DUK37-02
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 22:38 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 22:38 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 04:53 1418806350011SW-846 6010C Barium 07046
1Tara L Snyder07/09/2014 04:53 1418806350011SW-846 6010C Beryllium 07047
2Tara L Snyder07/09/2014 04:57 1418806350011SW-846 6010C Boron 08014
1John P Hook07/08/2014 22:38 1418806350011SW-846 6010C Cadmium 07049
1Tara L Snyder07/09/2014 04:53 1418806350011SW-846 6010C Calcium 01750
1John P Hook07/08/2014 22:38 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 22:38 1418806350011SW-846 6010C Copper 07053
1John P Hook07/08/2014 22:38 1418806350011SW-846 6010C Iron 01754
1Joanne M Gates07/09/2014 13:39 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 22:38 1418806350011SW-846 6010C Magnesium 01757
1John P Hook07/08/2014 22:38 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 22:38 1418806350011SW-846 6010C Molybdenum 07060
1John P Hook07/08/2014 22:38 1418806350011SW-846 6010C Nickel 07061
1Tara L Snyder07/09/2014 04:53 1418806350011SW-846 6010C Potassium 01762
1John P Hook07/08/2014 22:38 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 22:38 1418806350011SW-846 6010C Silver 07066
2Tara L Snyder07/09/2014 04:57 1418806350011SW-846 6010C Sodium 01767
2Tara L Snyder07/09/2014 04:57 1418806350011SW-846 6010C Strontium 08068
1Tara L Snyder07/09/2014 04:53 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 22:38 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 22:38 1418806350011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 14:53 1418957130061SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/09/2014 09:23 1418957130061SW-846 7470A WW SW846 Hg Digest 05713
5Clinton M Wilson07/03/2014 21:12 14184987601B1EPA 300.0 Bromide 01505
20Sandra J Miller07/07/2014 08:09 14184987601B1EPA 300.0 Chloride 00224
5Clinton M Wilson07/03/2014 21:12 14184987601B1EPA 300.0 Nitrate Nitrogen 00368
5Clinton M Wilson07/03/2014 21:12 14184987601B1EPA 300.0 Nitrite Nitrogen 01506
20Clinton M Wilson07/05/2014 19:54 14184987601B1EPA 300.0 Sulfate 00228
1Michele L Graham07/07/2014 17:45 14188002103A1EPA 310.1 Total Alkalinity 12150
1Sarah E Thompson07/08/2014 10:13 14189021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 12 of 24

LL Sample # WW 7520782
LL Group # 1486459
Account # 10634
Sample Description: GW-MW15-20140702 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 15:35 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS-15 SDG#: DUK37-03
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.0383 J 17440-38-2 07035 0.0072 0.0400 Arsenic
0.0365 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0592 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
114 17440-70-2 01750 0.0334 0.400 Calcium
0.0014 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
5.72 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
5.20 17439-95-4 01757 0.0167 0.200 Magnesium
0.109 17439-96-5 07058 0.00083 0.0100 Manganese
0.0076 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
3.50 17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
18.3 17440-23-5 01767 0.167 2.00 Sodium
0.553 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-62-2 07071 0.0019 0.0100 Vanadium
0.0022 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
45.1 1016887-00-600224 2.0 4.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
42.0 514808-79-800228 1.5 5.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
211 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
398 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 13 of 24

LL Sample # WW 7520782
LL Group # 1486459
Account # 10634
Sample Description: GW-MW15-20140702 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 15:35 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS-15 SDG#: DUK37-03
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 05:01 1418806350011SW-846 6010C Barium 07046
1Tara L Snyder07/09/2014 05:01 1418806350011SW-846 6010C Beryllium 07047
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Boron 08014
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Cadmium 07049
1Tara L Snyder07/09/2014 05:01 1418806350011SW-846 6010C Calcium 01750
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Copper 07053
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Iron 01754
1Joanne M Gates07/09/2014 13:51 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Magnesium 01757
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Molybdenum 07060
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Nickel 07061
1Tara L Snyder07/09/2014 05:01 1418806350011SW-846 6010C Potassium 01762
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Silver 07066
1Tara L Snyder07/09/2014 05:01 1418806350011SW-846 6010C Sodium 01767
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Strontium 08068
1Tara L Snyder07/09/2014 05:01 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 22:42 1418806350011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 14:59 1418957130061SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/09/2014 09:23 1418957130061SW-846 7470A WW SW846 Hg Digest 05713
5Clinton M Wilson07/03/2014 21:28 14184987601B1EPA 300.0 Bromide 01505
10Sandra J Miller07/07/2014 08:25 14184987601B1EPA 300.0 Chloride 00224
5Clinton M Wilson07/03/2014 21:28 14184987601B1EPA 300.0 Nitrate Nitrogen 00368
5Clinton M Wilson07/03/2014 21:28 14184987601B1EPA 300.0 Nitrite Nitrogen 01506
5Clinton M Wilson07/03/2014 21:28 14184987601B1EPA 300.0 Sulfate 00228
1Michele L Graham07/07/2014 16:45 14188002103A1EPA 310.1 Total Alkalinity 12150
1Sarah E Thompson07/08/2014 10:13 14189021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 14 of 24

LL Sample # WW 7520783
LL Group # 1486459
Account # 10634
Sample Description: GW-MW159-20140702 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 15:30 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS159 SDG#: DUK37-04
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.0377 J 17440-38-2 07035 0.0072 0.0400 Arsenic
0.0343 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0583 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
110 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
5.41 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
5.12 17439-95-4 01757 0.0167 0.200 Magnesium
0.105 17439-96-5 07058 0.00083 0.0100 Manganese
0.0069 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
3.38 17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
17.5 17440-23-5 01767 0.167 2.00 Sodium
0.548 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-62-2 07071 0.0019 0.0100 Vanadium
0.0021 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
43.6 1016887-00-600224 2.0 4.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
41.9 514808-79-800228 1.5 5.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
221 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
410 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 15 of 24

LL Sample # WW 7520783
LL Group # 1486459
Account # 10634
Sample Description: GW-MW159-20140702 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 15:30 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS159 SDG#: DUK37-04
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 05:08 1418806350011SW-846 6010C Barium 07046
1Tara L Snyder07/09/2014 05:08 1418806350011SW-846 6010C Beryllium 07047
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Boron 08014
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Cadmium 07049
1Tara L Snyder07/09/2014 05:08 1418806350011SW-846 6010C Calcium 01750
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Copper 07053
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Iron 01754
1Joanne M Gates07/09/2014 13:55 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Magnesium 01757
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Molybdenum 07060
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Nickel 07061
1Tara L Snyder07/09/2014 05:08 1418806350011SW-846 6010C Potassium 01762
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Silver 07066
1Tara L Snyder07/09/2014 05:08 1418806350011SW-846 6010C Sodium 01767
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Strontium 08068
1Tara L Snyder07/09/2014 05:08 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 22:46 1418806350011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 15:01 1418957130061SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/09/2014 09:23 1418957130061SW-846 7470A WW SW846 Hg Digest 05713
5Clinton M Wilson07/03/2014 21:44 14184987601B1EPA 300.0 Bromide 01505
10Sandra J Miller07/07/2014 08:42 14184987601B1EPA 300.0 Chloride 00224
5Clinton M Wilson07/03/2014 21:44 14184987601B1EPA 300.0 Nitrate Nitrogen 00368
5Clinton M Wilson07/03/2014 21:44 14184987601B1EPA 300.0 Nitrite Nitrogen 01506
5Clinton M Wilson07/03/2014 21:44 14184987601B1EPA 300.0 Sulfate 00228
1Michele L Graham07/07/2014 14:22 14188002102A1EPA 310.1 Total Alkalinity 12150
1Sarah E Thompson07/08/2014 10:13 14189021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 16 of 24

LL Sample # WW 7520784
LL Group # 1486459
Account # 10634
Sample Description: GW-MW15D-20140702 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 15:43 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS15D SDG#: DUK37-05
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
N.D.17440-38-2 07035 0.0072 0.0400 Arsenic
0.0533 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.550 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
61.5 17440-70-2 01750 0.0334 0.400 Calcium
0.0019 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.724 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
8.18 17439-95-4 01757 0.0167 0.200 Magnesium
1.62 27439-96-5 07058 0.0017 0.0200 Manganese
N.D.17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
7.61 17440-09-7 01762 0.133 1.00 Potassium
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
66.5 27440-23-5 01767 0.334 4.00 Sodium
0.615 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-62-2 07071 0.0019 0.0100 Vanadium
0.0062 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
mg/l mg/lmg/lWet Chemistry EPA 300.0
N.D.524959-67-901505 2.0 2.5 Bromide
131 5016887-00-600224 10.0 20.0 Chloride
N.D.514797-55-800368 0.25 0.50 Nitrate Nitrogen
N.D.514797-65-001506 0.40 0.50 Nitrite Nitrogen
75.7 1014808-79-800228 3.0 10.0 Sulfate
mg/l as CaCO3mg/l as CaCO3mg/l as CaCO3EPA 310.1
70.1 1n.a. 12150 0.70 2.0 Total Alkalinity
mg/l mg/lmg/lSM 2540 C-1997
435 1n.a. 00212 9.7 30.0 Total Dissolved Solids
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
*=This limit was used in the evaluation of the final result
Page 17 of 24

LL Sample # WW 7520784
LL Group # 1486459
Account # 10634
Sample Description: GW-MW15D-20140702 Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 15:43 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS15D SDG#: DUK37-05
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 22:49 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 22:49 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 05:23 1418806350011SW-846 6010C Barium 07046
1Tara L Snyder07/09/2014 05:23 1418806350011SW-846 6010C Beryllium 07047
1John P Hook07/08/2014 22:49 1418806350011SW-846 6010C Boron 08014
1John P Hook07/08/2014 22:49 1418806350011SW-846 6010C Cadmium 07049
1Tara L Snyder07/09/2014 05:23 1418806350011SW-846 6010C Calcium 01750
1John P Hook07/08/2014 22:49 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 22:49 1418806350011SW-846 6010C Copper 07053
1John P Hook07/08/2014 22:49 1418806350011SW-846 6010C Iron 01754
1Tara L Snyder07/09/2014 05:23 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 22:49 1418806350011SW-846 6010C Magnesium 01757
2Tara L Snyder07/09/2014 05:27 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 22:49 1418806350011SW-846 6010C Molybdenum 07060
1John P Hook07/08/2014 22:49 1418806350011SW-846 6010C Nickel 07061
1Tara L Snyder07/09/2014 05:23 1418806350011SW-846 6010C Potassium 01762
1John P Hook07/08/2014 22:49 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 22:49 1418806350011SW-846 6010C Silver 07066
2Tara L Snyder07/09/2014 05:27 1418806350011SW-846 6010C Sodium 01767
1John P Hook07/08/2014 22:49 1418806350011SW-846 6010C Strontium 08068
1Tara L Snyder07/09/2014 05:23 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 22:49 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 22:49 1418806350011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 15:03 1418957130061SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/09/2014 09:23 1418957130061SW-846 7470A WW SW846 Hg Digest 05713
5Clinton M Wilson07/03/2014 22:00 14184987601B1EPA 300.0 Bromide 01505
50Sandra J Miller07/07/2014 08:58 14184987601B1EPA 300.0 Chloride 00224
5Clinton M Wilson07/03/2014 22:00 14184987601B1EPA 300.0 Nitrate Nitrogen 00368
5Clinton M Wilson07/03/2014 22:00 14184987601B1EPA 300.0 Nitrite Nitrogen 01506
10Clinton M Wilson07/05/2014 20:42 14184987601B1EPA 300.0 Sulfate 00228
1Michele L Graham07/07/2014 21:07 14188002104A1EPA 310.1 Total Alkalinity 12150
1Sarah E Thompson07/08/2014 10:13 14189021201A1SM 2540 C-1997 Total Dissolved Solids 00212
*=This limit was used in the evaluation of the final result
Page 18 of 24

LL Sample # WW 7520785
LL Group # 1486459
Account # 10634
Sample Description: GW-MW15-20140702-MBQC Grab Groundwater Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 15:45 by MP
Submitted: 07/03/2014 09:15
GeoSyntec Consultants
Reported: 07/14/2014 11:33
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
DS15Q SDG#: DUK37-06*
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.0354 J 17440-38-2 07035 0.0072 0.0400 Arsenic
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
0.0015 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.105 17439-96-5 07058 0.00083 0.0100 Manganese
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17782-49-2 07036 0.0048 0.0400 Selenium
N.D.17440-22-4 07066 0.0018 0.0100 Silver
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
N.D.17440-62-2 07071 0.0019 0.0100 Vanadium
0.0022 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/08/2014 22:53 1418806350011SW-846 6010C Antimony 07044
1John P Hook07/08/2014 22:53 1418806350011SW-846 6010C Arsenic 07035
1Tara L Snyder07/09/2014 05:31 1418806350011SW-846 6010C Beryllium 07047
1John P Hook07/08/2014 22:53 1418806350011SW-846 6010C Cadmium 07049
1John P Hook07/08/2014 22:53 1418806350011SW-846 6010C Chromium 07051
1John P Hook07/08/2014 22:53 1418806350011SW-846 6010C Copper 07053
1Tara L Snyder07/09/2014 05:31 1418806350011SW-846 6010C Lead 07055
1John P Hook07/08/2014 22:53 1418806350011SW-846 6010C Manganese 07058
1John P Hook07/08/2014 22:53 1418806350011SW-846 6010C Nickel 07061
1John P Hook07/08/2014 22:53 1418806350011SW-846 6010C Selenium 07036
1John P Hook07/08/2014 22:53 1418806350011SW-846 6010C Silver 07066
1Tara L Snyder07/09/2014 05:31 1418806350011SW-846 6010C Thallium 07022
1John P Hook07/08/2014 22:53 1418806350011SW-846 6010C Vanadium 07071
1John P Hook07/08/2014 22:53 1418806350011SW-846 6010C Zinc 07072
1Parker D Lindstrom07/12/2014 15:05 1418957130061SW-846 7470A Mercury 00259
1Micaela L Dishong07/08/2014 11:13 1418806350011SW-846 3005A WW SW846(IV) ICP Dig (tot
rec)
10635
1James L Mertz07/09/2014 09:23 1418957130061SW-846 7470A WW SW846 Hg Digest 05713
*=This limit was used in the evaluation of the final result
Page 19 of 24

Page 1 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1486459
Reported: 07/14/14 at 11:33 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Matrix QC may not be reported if insufficient sample or site-specific QC samples were not submitted. In these
situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise
specified in the method.

All Inorganic Initial Calibration and Continuing Calibration Blanks met acceptable method criteria unless
otherwise noted on the Analysis Report.

Laboratory Compliance Quality Control

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Batch number: 141880635001 Sample number(s): 7520777-7520785
Antimony N.D. 0.0051 0.0400 mg/l 109 88-111
Arsenic N.D. 0.0072 0.0400 mg/l 111 90-113
Barium N.D. 0.00033 0.0100 mg/l 108 90-110
Beryllium N.D. 0.00067 0.0100 mg/l 106 90-111
Boron N.D. 0.0046 0.100 mg/l 100 90-110
Cadmium N.D. 0.00033 0.0100 mg/l 105 90-112
Calcium N.D. 0.0334 0.400 mg/l 109 90-112
Chromium N.D. 0.0013 0.0300 mg/l 102 90-110
Copper N.D. 0.0028 0.0200 mg/l 108 90-112
Iron N.D. 0.0334 0.400 mg/l 112 90-112
Lead N.D. 0.0047 0.0300 mg/l 114 88-116
Magnesium N.D. 0.0167 0.200 mg/l 107 89-110
Manganese 0.0013 J 0.00083 0.0100 mg/l 108 90-110
Molybdenum N.D. 0.0017 0.0200 mg/l 106 90-110
Nickel N.D. 0.0016 0.0200 mg/l 111 90-117
Potassium N.D. 0.133 1.00 mg/l 104 90-110
Selenium N.D. 0.0048 0.0400 mg/l 103 89-113
Silver N.D. 0.0018 0.0100 mg/l 94 80-120
Sodium N.D. 0.167 2.00 mg/l 106 87-114
Strontium N.D. 0.00033 0.0100 mg/l 108 90-110
Thallium N.D. 0.0051 0.0600 mg/l 101 90-118
Vanadium N.D. 0.0019 0.0100 mg/l 102 90-110
Zinc N.D. 0.0020 0.0400 mg/l 104 90-110

Batch number: 141895713006 Sample number(s): 7520777-7520785
Mercury N.D. 0.00006
0
0.00020 mg/l 103 80-120

Batch number: 14184987601B Sample number(s): 7520777-7520778,7520780-7520784
Bromide N.D. 0.40 0.50 mg/l 91 91 90-110 0 20
Chloride N.D. 0.20 0.40 mg/l 91 92 90-110 1 20
Nitrate Nitrogen N.D. 0.050 0.10 mg/l 92 92 90-110 0 20
Nitrite Nitrogen N.D. 0.080 0.10 mg/l 91 91 90-110 0 20
Sulfate N.D. 0.30 1.0 mg/l 98 98 90-110 0 20

Batch number: 14188002102A Sample number(s): 7520783
Total Alkalinity N.D. 0.70 2.0 mg/l as
CaCO3
97 90-110

Batch number: 14188002103A Sample number(s): 7520777-7520782
Total Alkalinity N.D. 0.70 2.0 mg/l as
CaCO3
96 90-110

Page 20 of 24

Page 2 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1486459
Reported: 07/14/14 at 11:33 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max
Batch number: 14188002104A Sample number(s): 7520784
Total Alkalinity N.D. 0.70 2.0 mg/l as
CaCO3
96 90-110

Batch number: 14189021201A Sample number(s): 7520777-7520784
Total Dissolved Solids N.D. 9.7 30.0 mg/l 89 80-120

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 141880635001 Sample number(s): 7520777-7520785 UNSPK: 7520777 BKG: 7520777
Antimony 108 106 76-122 2 20 N.D. N.D. 0 (1) 20
Arsenic 104 108 81-123 3 20 0.0199 J 0.0133 J 39* (1) 20
Barium 102 101 78-125 1 20 0.144 0.136 6 20
Beryllium 102 101 87-114 1 20 N.D. N.D. 0 (1) 20
Boron 74* 87 87-111 6 20 2.35 2.10 11 (1) 20
Cadmium 99 99 75-122 0 20 N.D. N.D. 0 (1) 20
Calcium 7 (2) -1 (2) 75-125 0 20 89.4 84.3 6 20
Chromium 98 95 76-120 2 20 0.0017 J 0.0019 J 11 (1) 20
Copper 106 106 86-122 0 20 N.D. N.D. 0 (1) 20
Iron 72 (2) 112 (2) 75-125 7 20 4.72 4.44 6 20
Lead 101 100 75-125 1 20 N.D. N.D. 0 (1) 20
Magnesium 20 (2) 10 (2) 81-118 1 20 25.1 23.6 6 20
Manganese 98 94 75-125 2 20 0.459 0.430 7 20
Molybdenum 102 102 89-117 0 20 0.319 0.293 9 20
Nickel 104 103 79-123 1 20 N.D. N.D. 0 (1) 20
Potassium 100 98 77-128 1 20 14.7 13.8 6 20
Selenium 100 101 75-125 1 20 N.D. N.D. 0 (1) 20
Silver 93 91 75-125 2 20 N.D. N.D. 0 (1) 20
Sodium 21 (2) 51 (2) 84-117 3 20 52.1 47.3 10 (1) 20
Strontium 49* 72* 88-117 6 20 3.20 2.88 11 20
Thallium 95 94 75-125 0 20 N.D. N.D. 0 (1) 20
Vanadium 97 97 90-117 0 20 N.D. N.D. 0 (1) 20
Zinc 100 99 85-117 0 20 0.0041 J 0.0038 J 8 (1) 20

Batch number: 141895713006 Sample number(s): 7520777-7520785 UNSPK: 7520777 BKG: 7520777
Mercury 102 102 80-120 0 20 N.D. N.D. 0 (1) 20

Batch number: 14184987601B Sample number(s): 7520777-7520778,7520780-7520784 UNSPK: 7520777 BKG: 7520777
Bromide 91 90-110 N.D. N.D. 0 (1) 20
Chloride 85* 90-110 59.6 58.9 1 20
Nitrate Nitrogen 93 90-110 N.D. N.D. 0 (1) 20
Nitrite Nitrogen 82* 90-110 N.D. N.D. 0 (1) 20
Sulfate 95 90-110 96.9 95.4 2 (1) 20

Batch number: 14188002102A Sample number(s): 7520783 UNSPK: P520819 BKG: P520819
Total Alkalinity 89 85 17-146 2 5 296 296 0 5

Batch number: 14188002103A Sample number(s): 7520777-7520782 UNSPK: 7520777 BKG: 7520777
Page 21 of 24

Page 3 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1486459
Reported: 07/14/14 at 11:33 AM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___
Total Alkalinity 47 48 17-146 1 5 235 235 0 5

Batch number: 14188002104A Sample number(s): 7520784 UNSPK: P520624 BKG: P520624
Total Alkalinity 90 17-146 61.9 63.8 3 5

Batch number: 14189021201A Sample number(s): 7520777-7520784 UNSPK: 7520777 BKG: 7520777
Total Dissolved Solids 95 94 66-131 1 23 516 503 3 5

Page 22 of 24
Page 23 of 24
Explanation of Symbols and Abbreviations

3768 0713
The following defines common symbols and abbreviations used in reporting technical data:
RL Reporting Limit BMQL Below Minimum Quantitation Level
N.D. none detected MPN Most Probable Number
TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units
IU International Units NTU nephelometric turbidity units
umhos/cm micromhos/cm ng nanogram(s)
C degrees Celsius F degrees Fahrenheit
meq milliequivalents lb. pound(s)
g gram(s) kg kilogram(s)
µg microgram(s) mg milligram(s)
mL milliliter(s) L liter(s)
m3 cubic meter(s) µL microliter(s)
pg/L picogram/liter
< less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be
reliably determined using this specific test.
> greater than
ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For
aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/l), because one liter of water has a
weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter per liter of gas.
ppb parts per billion
Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight
basis concentration to approximate the value present in a similar sample without moisture. All other results are reported
on an as-received basis.
Data Qualifiers:
C – result confirmed by reanalysis.
J - estimated value – The result is ≥ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ).
U.S. EPA CLP Data Qualifiers:
Organic Qualifiers Inorganic Qualifiers
A TIC is a possible aldol-condensation product B Value is <CRDL, but ≥IDL
B Analyte was also detected in the blank E Estimated due to interference
C Pesticide result confirmed by GC/MS M Duplicate injection precision not met
D Compound quantitated on a diluted sample N Spike sample not within control limits
E Concentration exceeds the calibration range of S Method of standard additions (MSA) used
the instrument for calculation
N Presumptive evidence of a compound (TICs only) U Compound was not detected
P Concentration difference between primary and W Post digestion spike out of control limits
confirmation columns >25% * Duplicate analysis not within control limits
U Compound was not detected + Correlation coefficient for MSA <0.995
X,Y,Z Defined in case narrative
Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.
Measurement uncertainty values, as applicable, are available upon request.
Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the
test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact
us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our
staff. This report shall not be reproduced except in full, without the written approval of the laboratory.
Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as “analyze immediately” are not
performed within 15 minutes.

WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE
FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM
ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF
MERCHANTABILITY. IN NO EVENT SHALL EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL, LLC BE LIABLE FOR INDIRECT, SPECIAL,
CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS
OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL AND (B) WHETHER
EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal
responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Eurofins Lancaster
Laboratories Environmental which includes any conditions that vary from the Standard Terms and Conditions, and Eurofins Lancaster Laboratories
Environmental hereby objects to any conflicting terms contained in any acceptance or order submitted by client.
Page 24 of 24

ANALYTICAL RESULTS

Prepared by:

Eurofins Lancaster Laboratories Environmental
2425 New Holland Pike
Lancaster, PA 17601
Prepared for:

GeoSyntec Consultants
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607

July 15, 2014

Project: Duke Sutton, NC

Submittal Date: 07/08/2014
Group Number: 1487148
SDG: DUK38
PO Number: GC5592
State of Sample Origin: NC

Client Sample Description Lancaster Labs (LL) #
SS-GP12(28-32)-20140702 Solid Sample 7525095
SS-GP12(28-32)-20140702 Solid Sample 7525096
SS-GP13(64-68)-20140701 Solid Sample 7525097
SS-GP13(64-68)-20140701 Solid Sample 7525098
SS-GP13(68-72)-20140701 Solid Sample 7525099
SS-GP13(68-72)-20140701 Solid Sample 7525100
SS-GP14(60-62)-20140702 Solid Sample 7525101
SS-GP14(60-62)-20140702 Solid Sample 7525102
SS-GP14(68-72)-20140702 Solid Sample 7525103
SS-GP14(68-72)-20140702 Solid Sample 7525104
SS-GP15(60-64)-20140701 Solid Sample 7525105
SS-GP15(60-64)-20140701 Solid Sample 7525106
SS-GP15(68.7-70.7)-20140701 Solid Sample 7525107
SS-GP15(68.7-70.7)-20140701 Solid Sample 7525108

The specific methodologies used in obtaining the enclosed analytical results are indicated on the
Laboratory Sample Analysis Record.

ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Lauren Wellborn
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Beau Hodge
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Rachel Donahue
ELECTRONIC
COPY TO
GeoSyntec Consultants Attn: Herwig Goldemund

Page 1 of 35

Respectfully Submitted,

[phone]

Page 2 of 35

LL Sample # SW 7525095
LL Group # 1487148
Account # 10634
Sample Description: SS-GP12(28-32)-20140702 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 12:20 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
12-28 SDG#: DUK38-01
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
0.758 J 17440-36-0 06944 0.509 6.17 Antimony
67.6 17440-38-2 06935 0.988 6.17 Arsenic
467 57440-39-3 06946 0.255 7.72 Barium
5.99 17440-41-7 06947 0.103 1.54 Beryllium
41.2 17440-42-8 07914 1.30 15.4 Boron
0.230 J 17440-43-9 06949 0.0509 1.54 Cadmium
46.8 17440-47-3 06951 0.170 4.63 Chromium
76.8 17440-50-8 06953 0.509 3.09 Copper
13,200 17439-89-6 01654 5.15 61.7 Iron
30.8 17439-92-1 06955 0.772 4.63 Lead
64.1 17439-96-5 06958 0.128 1.54 Manganese
4.39 17439-98-7 06960 0.262 3.09 Molybdenum
35.9 17440-02-0 06961 0.232 3.09 Nickel
5.43 J 17782-49-2 06936 0.679 6.17 Selenium
N.D.17440-22-4 06966 0.293 1.54 Silver
322 57440-24-6 07968 0.255 7.72 Strontium
5.45 J 17440-28-0 06925 1.23 9.26 Thallium
51.4 17440-66-6 06972 0.401 6.17 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.0871 J 17439-97-6 00159 0.0155 0.310 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
7.62 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 22 C.
% %%Wet Chemistry SM 2540 G-1997
37.7 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Antimony 06944
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Arsenic 06935
5Eric L Eby07/14/2014 16:39 1419206370011SW-846 6010C Barium 06946
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 3 of 35

LL Sample # SW 7525095
LL Group # 1487148
Account # 10634
Sample Description: SS-GP12(28-32)-20140702 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 12:20 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
12-28 SDG#: DUK38-01
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Boron 07914
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Cadmium 06949
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Chromium 06951
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Copper 06953
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Iron 01654
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Lead 06955
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Manganese 06958
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Molybdenum 06960
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Nickel 06961
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Selenium 06936
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Silver 06966
5Eric L Eby07/14/2014 16:39 1419206370011SW-846 6010C Strontium 07968
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Thallium 06925
1Joanne M Gates07/14/2014 09:52 1419206370011SW-846 6010C Zinc 06972
1Damary Valentin07/14/2014 15:33 1419206380011SW-846 7471B Mercury 00159
1James L Mertz07/13/2014 08:55 1419206370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/13/2014 10:58 1419206380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/11/2014 21:30 14192039401A1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/10/2014 18:44 14191820003A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 4 of 35

LL Sample # TL 7525096
LL Group # 1487148
Account # 10634
Sample Description: SS-GP12(28-32)-20140702 Solid Sample
SPLP NON-VOLATILE EXTRACTION
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 12:20 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1228S SDG#: DUK38-02
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.0222 J 17440-36-0 07044 0.0051 0.0400 Antimony
0.0716 17440-38-2 07035 0.0072 0.0400 Arsenic
0.135 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0463 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
3.24 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
0.0281 17440-50-8 07053 0.0028 0.0200 Copper
N.D.17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.529 17439-95-4 01757 0.0167 0.200 Magnesium
0.0080 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.141 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0046 J 17440-02-0 07061 0.0016 0.0200 Nickel
0.600 J 17440-09-7 01762 0.133 1.00 Potassium
0.0090 J 17782-49-2 07036 0.0048 0.0400 Selenium
N.D.107440-22-4 07066 0.0180 0.100 Silver
The silver result was performed by the Method of Standard Addition.
Reporting limits were raised due to interference from the sample matrix.
2.20 17440-23-5 01767 0.167 2.00 Sodium
0.191 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0027 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Antimony 07044
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Arsenic 07035
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Barium 07046
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Beryllium 07047
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Boron 08014
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Cadmium 07049
*=This limit was used in the evaluation of the final result
Page 5 of 35

LL Sample # TL 7525096
LL Group # 1487148
Account # 10634
Sample Description: SS-GP12(28-32)-20140702 Solid Sample
SPLP NON-VOLATILE EXTRACTION
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 12:20 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1228S SDG#: DUK38-02
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Calcium 01750
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Chromium 07051
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Copper 07053
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Iron 01754
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Lead 07055
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Magnesium 01757
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Manganese 07058
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Molybdenum 07060
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Nickel 07061
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Potassium 01762
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Selenium 07036
10Joanne M Gates07/15/2014 08:37 1419106360012SW-846 6010C Silver 07066
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Sodium 01767
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Strontium 08068
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Thallium 07022
1John P Hook07/14/2014 19:37 1419106360011SW-846 6010C Zinc 07072
1Damary Valentin07/14/2014 11:46 1419157130011SW-846 7470A Mercury 00259
1Micaela L Dishong07/14/2014 10:10 1419106360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong07/11/2014 09:00 1419157130011SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/09/2014 14:00 14190-2486-
1567A
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 6 of 35

LL Sample # SW 7525097
LL Group # 1487148
Account # 10634
Sample Description: SS-GP13(64-68)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 10:00 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
13-64 SDG#: DUK38-03
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.464 5.63 Antimony
129 17440-38-2 06935 0.900 5.63 Arsenic
865 107440-39-3 06946 0.464 14.1 Barium
6.56 17440-41-7 06947 0.0943 1.41 Beryllium
52.2 17440-42-8 07914 1.18 14.1 Boron
0.245 J 17440-43-9 06949 0.0464 1.41 Cadmium
49.0 17440-47-3 06951 0.155 4.22 Chromium
64.0 17440-50-8 06953 0.464 2.81 Copper
19,600 17439-89-6 01654 4.70 56.3 Iron
32.9 17439-92-1 06955 0.703 4.22 Lead
95.1 17439-96-5 06958 0.117 1.41 Manganese
2.01 J 17439-98-7 06960 0.239 2.81 Molybdenum
34.3 17440-02-0 06961 0.211 2.81 Nickel
6.68 17782-49-2 06936 0.619 5.63 Selenium
N.D.17440-22-4 06966 0.267 1.41 Silver
491 57440-24-6 07968 0.232 7.03 Strontium
6.25 J 17440-28-0 06925 1.13 8.44 Thallium
53.3 17440-66-6 06972 0.366 5.63 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.156 J 17439-97-6 00159 0.0137 0.274 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
8.69 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 21.6 C.
% %%Wet Chemistry SM 2540 G-1997
32.3 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Antimony 06944
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Arsenic 06935
10Eric L Eby07/14/2014 16:47 1419206370011SW-846 6010C Barium 06946
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 7 of 35

LL Sample # SW 7525097
LL Group # 1487148
Account # 10634
Sample Description: SS-GP13(64-68)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 10:00 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
13-64 SDG#: DUK38-03
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Boron 07914
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Cadmium 06949
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Chromium 06951
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Copper 06953
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Iron 01654
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Lead 06955
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Manganese 06958
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Molybdenum 06960
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Nickel 06961
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Selenium 06936
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Silver 06966
5Eric L Eby07/14/2014 16:43 1419206370011SW-846 6010C Strontium 07968
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Thallium 06925
1Joanne M Gates07/14/2014 09:56 1419206370011SW-846 6010C Zinc 06972
1Damary Valentin07/14/2014 15:43 1419206380011SW-846 7471B Mercury 00159
1James L Mertz07/13/2014 08:55 1419206370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/13/2014 10:58 1419206380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/11/2014 21:30 14192039401A1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/10/2014 18:44 14191820003A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 8 of 35

LL Sample # TL 7525098
LL Group # 1487148
Account # 10634
Sample Description: SS-GP13(64-68)-20140701 Solid Sample
SPLP NON-VOLATILE EXTRACTION
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 10:00 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1364S SDG#: DUK38-04
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.251 17440-38-2 07035 0.0072 0.0400 Arsenic
0.0676 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.137 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
4.42 17440-70-2 01750 0.0334 0.400 Calcium
0.0024 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.0523 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
1.23 17439-95-4 01757 0.0167 0.200 Magnesium
0.0013 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0045 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
0.168 J 17440-09-7 01762 0.133 1.00 Potassium
0.0344 J 17782-49-2 07036 0.0048 0.0400 Selenium
N.D.107440-22-4 07066 0.0180 0.100 Silver
The silver result was performed by the Method of Standard Addition.
Reporting limits were raised due to interference from the sample matrix.
3.06 17440-23-5 01767 0.167 2.00 Sodium
0.249 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0036 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Antimony 07044
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Arsenic 07035
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Barium 07046
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Beryllium 07047
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Boron 08014
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Cadmium 07049
*=This limit was used in the evaluation of the final result
Page 9 of 35

LL Sample # TL 7525098
LL Group # 1487148
Account # 10634
Sample Description: SS-GP13(64-68)-20140701 Solid Sample
SPLP NON-VOLATILE EXTRACTION
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 10:00 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1364S SDG#: DUK38-04
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Calcium 01750
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Chromium 07051
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Copper 07053
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Iron 01754
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Lead 07055
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Magnesium 01757
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Manganese 07058
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Molybdenum 07060
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Nickel 07061
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Potassium 01762
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Selenium 07036
10Joanne M Gates07/15/2014 08:52 1419106360012SW-846 6010C Silver 07066
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Sodium 01767
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Strontium 08068
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Thallium 07022
1John P Hook07/14/2014 20:14 1419106360011SW-846 6010C Zinc 07072
1Damary Valentin07/14/2014 11:58 1419157130011SW-846 7470A Mercury 00259
1Micaela L Dishong07/14/2014 10:10 1419106360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong07/11/2014 09:00 1419157130011SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/09/2014 14:00 14190-2486-
1567A
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 10 of 35

LL Sample # SW 7525099
LL Group # 1487148
Account # 10634
Sample Description: SS-GP13(68-72)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 10:10 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1368- SDG#: DUK38-05
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.450 5.45 Antimony
127 17440-38-2 06935 0.872 5.45 Arsenic
591 57440-39-3 06946 0.225 6.81 Barium
5.10 17440-41-7 06947 0.0913 1.36 Beryllium
52.3 17440-42-8 07914 1.14 13.6 Boron
0.285 J 17440-43-9 06949 0.0450 1.36 Cadmium
47.4 17440-47-3 06951 0.150 4.09 Chromium
64.8 17440-50-8 06953 0.450 2.72 Copper
19,500 17439-89-6 01654 4.55 54.5 Iron
31.4 17439-92-1 06955 0.681 4.09 Lead
101 17439-96-5 06958 0.113 1.36 Manganese
2.91 17439-98-7 06960 0.232 2.72 Molybdenum
40.8 17440-02-0 06961 0.204 2.72 Nickel
5.71 17782-49-2 06936 0.599 5.45 Selenium
N.D.17440-22-4 06966 0.259 1.36 Silver
388 57440-24-6 07968 0.225 6.81 Strontium
7.40 J 17440-28-0 06925 1.09 8.17 Thallium
53.4 17440-66-6 06972 0.354 5.45 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.186 J 17439-97-6 00159 0.0135 0.269 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
8.61 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 21.7 C.
% %%Wet Chemistry SM 2540 G-1997
30.1 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Antimony 06944
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Arsenic 06935
5Eric L Eby07/14/2014 16:59 1419206370011SW-846 6010C Barium 06946
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 11 of 35

LL Sample # SW 7525099
LL Group # 1487148
Account # 10634
Sample Description: SS-GP13(68-72)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 10:10 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1368- SDG#: DUK38-05
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Boron 07914
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Cadmium 06949
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Chromium 06951
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Copper 06953
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Iron 01654
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Lead 06955
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Manganese 06958
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Molybdenum 06960
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Nickel 06961
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Selenium 06936
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Silver 06966
5Eric L Eby07/14/2014 16:59 1419206370011SW-846 6010C Strontium 07968
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Thallium 06925
1Joanne M Gates07/14/2014 10:08 1419206370011SW-846 6010C Zinc 06972
1Damary Valentin07/14/2014 15:45 1419206380011SW-846 7471B Mercury 00159
1James L Mertz07/13/2014 08:55 1419206370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/13/2014 10:58 1419206380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/11/2014 21:30 14192039401A1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/10/2014 18:44 14191820003A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 12 of 35

LL Sample # TL 7525100
LL Group # 1487148
Account # 10634
Sample Description: SS-GP13(68-72)-20140701 Solid Sample
SPLP NON-VOLATILE EXTRACTION
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 10:10 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1368S SDG#: DUK38-06
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.0057 J 17440-36-0 07044 0.0051 0.0400 Antimony
0.254 17440-38-2 07035 0.0072 0.0400 Arsenic
0.0321 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.177 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
3.73 17440-70-2 01750 0.0334 0.400 Calcium
0.0024 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.119 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
1.18 17439-95-4 01757 0.0167 0.200 Magnesium
0.0022 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0064 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17440-09-7 01762 0.133 1.00 Potassium
0.0293 J 17782-49-2 07036 0.0048 0.0400 Selenium
0.0210 J 107440-22-4 07066 0.0180 0.100 Silver
The silver result was performed by the Method of Standard Addition.
Reporting limits were raised due to interference from the sample matrix.
3.95 17440-23-5 01767 0.167 2.00 Sodium
0.183 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0099 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Antimony 07044
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Arsenic 07035
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Barium 07046
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Beryllium 07047
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Boron 08014
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Cadmium 07049
*=This limit was used in the evaluation of the final result
Page 13 of 35

LL Sample # TL 7525100
LL Group # 1487148
Account # 10634
Sample Description: SS-GP13(68-72)-20140701 Solid Sample
SPLP NON-VOLATILE EXTRACTION
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 10:10 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1368S SDG#: DUK38-06
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Calcium 01750
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Chromium 07051
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Copper 07053
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Iron 01754
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Lead 07055
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Magnesium 01757
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Manganese 07058
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Molybdenum 07060
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Nickel 07061
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Potassium 01762
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Selenium 07036
10Joanne M Gates07/15/2014 09:14 1419106360012SW-846 6010C Silver 07066
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Sodium 01767
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Strontium 08068
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Thallium 07022
1John P Hook07/14/2014 20:18 1419106360011SW-846 6010C Zinc 07072
1Damary Valentin07/14/2014 12:00 1419157130011SW-846 7470A Mercury 00259
1Micaela L Dishong07/14/2014 10:10 1419106360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong07/11/2014 09:00 1419157130011SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/09/2014 14:00 14190-2486-
1567A
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 14 of 35

LL Sample # SW 7525101
LL Group # 1487148
Account # 10634
Sample Description: SS-GP14(60-62)-20140702 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 10:00 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1460- SDG#: DUK38-07
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.502 6.08 Antimony
137 17440-38-2 06935 0.973 6.08 Arsenic
562 57440-39-3 06946 0.251 7.60 Barium
3.82 17440-41-7 06947 0.102 1.52 Beryllium
34.3 17440-42-8 07914 1.28 15.2 Boron
0.228 J 17440-43-9 06949 0.0502 1.52 Cadmium
31.9 17440-47-3 06951 0.167 4.56 Chromium
58.8 17440-50-8 06953 0.502 3.04 Copper
13,500 17439-89-6 01654 5.08 60.8 Iron
24.2 17439-92-1 06955 0.760 4.56 Lead
72.8 17439-96-5 06958 0.126 1.52 Manganese
2.33 J 17439-98-7 06960 0.258 3.04 Molybdenum
26.5 17440-02-0 06961 0.228 3.04 Nickel
3.97 J 17782-49-2 06936 0.669 6.08 Selenium
N.D.17440-22-4 06966 0.289 1.52 Silver
295 57440-24-6 07968 0.251 7.60 Strontium
4.62 J 17440-28-0 06925 1.22 9.12 Thallium
36.3 17440-66-6 06972 0.395 6.08 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.0850 J 17439-97-6 00159 0.0144 0.289 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
8.65 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 21.6 C.
% %%Wet Chemistry SM 2540 G-1997
34.2 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Antimony 06944
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Arsenic 06935
5Eric L Eby07/14/2014 17:03 1419206370011SW-846 6010C Barium 06946
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 15 of 35

LL Sample # SW 7525101
LL Group # 1487148
Account # 10634
Sample Description: SS-GP14(60-62)-20140702 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 10:00 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1460- SDG#: DUK38-07
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Boron 07914
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Cadmium 06949
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Chromium 06951
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Copper 06953
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Iron 01654
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Lead 06955
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Manganese 06958
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Molybdenum 06960
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Nickel 06961
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Selenium 06936
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Silver 06966
5Eric L Eby07/14/2014 17:03 1419206370011SW-846 6010C Strontium 07968
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Thallium 06925
1Joanne M Gates07/14/2014 10:12 1419206370011SW-846 6010C Zinc 06972
1Damary Valentin07/14/2014 15:47 1419206380011SW-846 7471B Mercury 00159
1James L Mertz07/13/2014 08:55 1419206370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/13/2014 10:58 1419206380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/11/2014 21:30 14192039401A1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/10/2014 18:44 14191820003A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 16 of 35

LL Sample # TL 7525102
LL Group # 1487148
Account # 10634
Sample Description: SS-GP14(60-62)-20140702 Solid Sample
SPLP NON-VOLATILE EXTRACTION
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 10:00 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1460S SDG#: DUK38-08
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.247 17440-38-2 07035 0.0072 0.0400 Arsenic
0.0901 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0547 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
2.99 17440-70-2 01750 0.0334 0.400 Calcium
0.0033 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.114 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.603 17439-95-4 01757 0.0167 0.200 Magnesium
0.0031 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0053 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0020 J 17440-02-0 07061 0.0016 0.0200 Nickel
0.144 J 17440-09-7 01762 0.133 1.00 Potassium
0.0077 J 17782-49-2 07036 0.0048 0.0400 Selenium
N.D.107440-22-4 07066 0.0180 0.100 Silver
The silver result was performed by the Method of Standard Addition.
Reporting limits were raised due to interference from the sample matrix.
3.87 17440-23-5 01767 0.167 2.00 Sodium
0.102 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0049 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Antimony 07044
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Arsenic 07035
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Barium 07046
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Beryllium 07047
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Boron 08014
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Cadmium 07049
*=This limit was used in the evaluation of the final result
Page 17 of 35

LL Sample # TL 7525102
LL Group # 1487148
Account # 10634
Sample Description: SS-GP14(60-62)-20140702 Solid Sample
SPLP NON-VOLATILE EXTRACTION
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 10:00 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1460S SDG#: DUK38-08
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Calcium 01750
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Chromium 07051
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Copper 07053
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Iron 01754
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Lead 07055
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Magnesium 01757
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Manganese 07058
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Molybdenum 07060
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Nickel 07061
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Potassium 01762
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Selenium 07036
10Joanne M Gates07/15/2014 09:29 1419106360012SW-846 6010C Silver 07066
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Sodium 01767
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Strontium 08068
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Thallium 07022
1John P Hook07/14/2014 20:22 1419106360011SW-846 6010C Zinc 07072
1Damary Valentin07/14/2014 12:02 1419157130011SW-846 7470A Mercury 00259
1Micaela L Dishong07/14/2014 10:10 1419106360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong07/11/2014 09:00 1419157130011SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/09/2014 14:00 14190-2486-
1567A
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 18 of 35

LL Sample # SW 7525103
LL Group # 1487148
Account # 10634
Sample Description: SS-GP14(68-72)-20140702 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 10:15 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1468- SDG#: DUK38-09
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.459 5.56 Antimony
144 57440-38-2 06935 4.45 27.8 Arsenic
661 57440-39-3 06946 0.229 6.95 Barium
5.45 17440-41-7 06947 0.0932 1.39 Beryllium
45.5 17440-42-8 07914 1.17 13.9 Boron
0.163 J 17440-43-9 06949 0.0459 1.39 Cadmium
55.8 17440-47-3 06951 0.153 4.17 Chromium
66.5 17440-50-8 06953 0.459 2.78 Copper
29,500 57439-89-6 01654 23.2 278 Iron
29.6 17439-92-1 06955 0.695 4.17 Lead
114 17439-96-5 06958 0.115 1.39 Manganese
2.65 J 17439-98-7 06960 0.236 2.78 Molybdenum
41.0 17440-02-0 06961 0.209 2.78 Nickel
6.04 17782-49-2 06936 0.612 5.56 Selenium
N.D.17440-22-4 06966 0.264 1.39 Silver
598 57440-24-6 07968 0.229 6.95 Strontium
6.68 J 17440-28-0 06925 1.11 8.34 Thallium
55.4 17440-66-6 06972 0.362 5.56 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.124 J 17439-97-6 00159 0.0134 0.269 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
8.63 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 21.5 C.
% %%Wet Chemistry SM 2540 G-1997
29.5 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates07/14/2014 10:16 1419206370011SW-846 6010C Antimony 06944
5Eric L Eby07/14/2014 17:07 1419206370011SW-846 6010C Arsenic 06935
5Eric L Eby07/14/2014 17:07 1419206370011SW-846 6010C Barium 06946
1Joanne M Gates07/14/2014 10:16 1419206370011SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 19 of 35

LL Sample # SW 7525103
LL Group # 1487148
Account # 10634
Sample Description: SS-GP14(68-72)-20140702 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 10:15 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1468- SDG#: DUK38-09
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates07/14/2014 10:16 1419206370011SW-846 6010C Boron 07914
1Joanne M Gates07/14/2014 10:16 1419206370011SW-846 6010C Cadmium 06949
1Joanne M Gates07/14/2014 10:16 1419206370011SW-846 6010C Chromium 06951
1Joanne M Gates07/14/2014 10:16 1419206370011SW-846 6010C Copper 06953
5Eric L Eby07/14/2014 17:07 1419206370011SW-846 6010C Iron 01654
1Joanne M Gates07/14/2014 10:16 1419206370011SW-846 6010C Lead 06955
1Joanne M Gates07/14/2014 10:16 1419206370011SW-846 6010C Manganese 06958
1Joanne M Gates07/14/2014 10:16 1419206370011SW-846 6010C Molybdenum 06960
1Joanne M Gates07/14/2014 10:16 1419206370011SW-846 6010C Nickel 06961
1Joanne M Gates07/14/2014 10:16 1419206370011SW-846 6010C Selenium 06936
1Joanne M Gates07/14/2014 10:16 1419206370011SW-846 6010C Silver 06966
5Eric L Eby07/14/2014 17:07 1419206370011SW-846 6010C Strontium 07968
1Joanne M Gates07/14/2014 10:16 1419206370011SW-846 6010C Thallium 06925
1Joanne M Gates07/14/2014 10:16 1419206370011SW-846 6010C Zinc 06972
1Damary Valentin07/14/2014 15:53 1419206380011SW-846 7471B Mercury 00159
1James L Mertz07/13/2014 08:55 1419206370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/13/2014 10:58 1419206380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/11/2014 21:30 14192039401A1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/10/2014 18:44 14191820003A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 20 of 35

LL Sample # TL 7525104
LL Group # 1487148
Account # 10634
Sample Description: SS-GP14(68-72)-20140702 Solid Sample
SPLP NON-VOLATILE EXTRACTION
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 10:15 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1468S SDG#: DUK38-10
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
0.0057 J 17440-36-0 07044 0.0051 0.0400 Antimony
0.263 17440-38-2 07035 0.0072 0.0400 Arsenic
0.0281 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0761 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
4.83 17440-70-2 01750 0.0334 0.400 Calcium
0.0050 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.101 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.560 17439-95-4 01757 0.0167 0.200 Magnesium
0.0044 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0046 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17440-09-7 01762 0.133 1.00 Potassium
0.0281 J 17782-49-2 07036 0.0048 0.0400 Selenium
N.D.107440-22-4 07066 0.0180 0.100 Silver
The silver result was performed by the Method of Standard Addition.
Reporting limits were raised due to interference from the sample matrix.
3.24 17440-23-5 01767 0.167 2.00 Sodium
0.163 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0038 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Antimony 07044
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Arsenic 07035
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Barium 07046
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Beryllium 07047
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Boron 08014
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Cadmium 07049
*=This limit was used in the evaluation of the final result
Page 21 of 35

LL Sample # TL 7525104
LL Group # 1487148
Account # 10634
Sample Description: SS-GP14(68-72)-20140702 Solid Sample
SPLP NON-VOLATILE EXTRACTION
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/02/2014 10:15 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1468S SDG#: DUK38-10
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Calcium 01750
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Chromium 07051
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Copper 07053
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Iron 01754
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Lead 07055
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Magnesium 01757
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Manganese 07058
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Molybdenum 07060
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Nickel 07061
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Potassium 01762
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Selenium 07036
10Joanne M Gates07/15/2014 09:44 1419106360012SW-846 6010C Silver 07066
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Sodium 01767
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Strontium 08068
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Thallium 07022
1John P Hook07/14/2014 20:25 1419106360011SW-846 6010C Zinc 07072
1Damary Valentin07/14/2014 12:04 1419157130011SW-846 7470A Mercury 00259
1Micaela L Dishong07/14/2014 10:10 1419106360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong07/11/2014 09:00 1419157130011SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/09/2014 14:00 14190-2486-
1567A
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 22 of 35

LL Sample # SW 7525105
LL Group # 1487148
Account # 10634
Sample Description: SS-GP15(60-64)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:30 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1560- SDG#: DUK38-11
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.432 5.24 Antimony
125 17440-38-2 06935 0.839 5.24 Arsenic
493 57440-39-3 06946 0.216 6.55 Barium
4.89 17440-41-7 06947 0.0878 1.31 Beryllium
66.7 17440-42-8 07914 1.10 13.1 Boron
N.D.17440-43-9 06949 0.0432 1.31 Cadmium
65.1 17440-47-3 06951 0.144 3.93 Chromium
64.5 17440-50-8 06953 0.432 2.62 Copper
43,400 57439-89-6 01654 21.9 262 Iron
24.6 17439-92-1 06955 0.655 3.93 Lead
160 57439-96-5 06958 0.544 6.55 Manganese
2.68 17439-98-7 06960 0.223 2.62 Molybdenum
47.3 17440-02-0 06961 0.197 2.62 Nickel
4.54 J 17782-49-2 06936 0.576 5.24 Selenium
N.D.17440-22-4 06966 0.249 1.31 Silver
561 57440-24-6 07968 0.216 6.55 Strontium
9.28 17440-28-0 06925 1.05 7.86 Thallium
55.8 17440-66-6 06972 0.341 5.24 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.0778 J 17439-97-6 00159 0.0125 0.249 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
8.28 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 22.2 C.
% %%Wet Chemistry SM 2540 G-1997
25.9 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates07/14/2014 10:20 1419206370011SW-846 6010C Antimony 06944
1Joanne M Gates07/14/2014 10:20 1419206370011SW-846 6010C Arsenic 06935
5Eric L Eby07/14/2014 17:11 1419206370011SW-846 6010C Barium 06946
1Joanne M Gates07/14/2014 10:20 1419206370011SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 23 of 35

LL Sample # SW 7525105
LL Group # 1487148
Account # 10634
Sample Description: SS-GP15(60-64)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:30 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1560- SDG#: DUK38-11
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates07/14/2014 10:20 1419206370011SW-846 6010C Boron 07914
1Joanne M Gates07/14/2014 10:20 1419206370011SW-846 6010C Cadmium 06949
1Joanne M Gates07/14/2014 10:20 1419206370011SW-846 6010C Chromium 06951
1Joanne M Gates07/14/2014 10:20 1419206370011SW-846 6010C Copper 06953
5Eric L Eby07/14/2014 17:11 1419206370011SW-846 6010C Iron 01654
1Joanne M Gates07/14/2014 10:20 1419206370011SW-846 6010C Lead 06955
5Eric L Eby07/14/2014 17:11 1419206370011SW-846 6010C Manganese 06958
1Joanne M Gates07/14/2014 10:20 1419206370011SW-846 6010C Molybdenum 06960
1Joanne M Gates07/14/2014 10:20 1419206370011SW-846 6010C Nickel 06961
1Joanne M Gates07/14/2014 10:20 1419206370011SW-846 6010C Selenium 06936
1Joanne M Gates07/14/2014 10:20 1419206370011SW-846 6010C Silver 06966
5Eric L Eby07/14/2014 17:11 1419206370011SW-846 6010C Strontium 07968
1Joanne M Gates07/14/2014 10:20 1419206370011SW-846 6010C Thallium 06925
1Joanne M Gates07/14/2014 10:20 1419206370011SW-846 6010C Zinc 06972
1Damary Valentin07/14/2014 15:55 1419206380011SW-846 7471B Mercury 00159
1James L Mertz07/13/2014 08:55 1419206370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/13/2014 10:58 1419206380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/11/2014 21:30 14192039401B1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/10/2014 18:44 14191820003A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 24 of 35

LL Sample # TL 7525106
LL Group # 1487148
Account # 10634
Sample Description: SS-GP15(60-64)-20140701 Solid Sample
SPLP NON-VOLATILE EXTRACTION
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:30 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1560S SDG#: DUK38-12
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.208 17440-38-2 07035 0.0072 0.0400 Arsenic
0.0178 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.100 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
6.35 17440-70-2 01750 0.0334 0.400 Calcium
0.0036 J 17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.0561 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.678 17439-95-4 01757 0.0167 0.200 Magnesium
0.0021 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0042 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
N.D.17440-02-0 07061 0.0016 0.0200 Nickel
N.D.17440-09-7 01762 0.133 1.00 Potassium
0.0278 J 17782-49-2 07036 0.0048 0.0400 Selenium
N.D.107440-22-4 07066 0.0180 0.100 Silver
The silver result was performed by the Method of Standard Addition.
Reporting limits were raised due to interference from the sample matrix.
9.01 17440-23-5 01767 0.167 2.00 Sodium
0.197 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0030 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Antimony 07044
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Arsenic 07035
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Barium 07046
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Beryllium 07047
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Boron 08014
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Cadmium 07049
*=This limit was used in the evaluation of the final result
Page 25 of 35

LL Sample # TL 7525106
LL Group # 1487148
Account # 10634
Sample Description: SS-GP15(60-64)-20140701 Solid Sample
SPLP NON-VOLATILE EXTRACTION
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 14:30 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1560S SDG#: DUK38-12
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Calcium 01750
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Chromium 07051
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Copper 07053
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Iron 01754
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Lead 07055
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Magnesium 01757
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Manganese 07058
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Molybdenum 07060
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Nickel 07061
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Potassium 01762
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Selenium 07036
10Joanne M Gates07/15/2014 10:07 1419106360012SW-846 6010C Silver 07066
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Sodium 01767
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Strontium 08068
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Thallium 07022
1John P Hook07/14/2014 20:29 1419106360011SW-846 6010C Zinc 07072
1Damary Valentin07/14/2014 12:06 1419157130011SW-846 7470A Mercury 00259
1Micaela L Dishong07/14/2014 10:10 1419106360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong07/11/2014 09:00 1419157130011SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/09/2014 14:00 14190-2486-
1567A
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 26 of 35

LL Sample # SW 7525107
LL Group # 1487148
Account # 10634
Sample Description: SS-GP15(68.7-70.7)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 15:00 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1568- SDG#: DUK38-13
Dry
Limit of
Quantitation
Dry
Method
Detection Limit* Dry
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/kg mg/kgmg/kgMetals SW-846 6010C
N.D.17440-36-0 06944 0.453 5.49 Antimony
35.6 17440-38-2 06935 0.879 5.49 Arsenic
265 57440-39-3 06946 0.227 6.87 Barium
3.00 17440-41-7 06947 0.0920 1.37 Beryllium
30.2 17440-42-8 07914 1.15 13.7 Boron
N.D.17440-43-9 06949 0.0453 1.37 Cadmium
22.3 17440-47-3 06951 0.151 4.12 Chromium
28.9 17440-50-8 06953 0.453 2.75 Copper
22,400 17439-89-6 01654 4.59 54.9 Iron
15.2 17439-92-1 06955 0.687 4.12 Lead
63.4 17439-96-5 06958 0.114 1.37 Manganese
2.38 J 17439-98-7 06960 0.233 2.75 Molybdenum
112 17440-02-0 06961 0.206 2.75 Nickel
1.82 J 17782-49-2 06936 0.604 5.49 Selenium
N.D.17440-22-4 06966 0.261 1.37 Silver
237 57440-24-6 07968 0.227 6.87 Strontium
62.5 17440-28-0 06925 1.10 8.24 Thallium
27.5 17440-66-6 06972 0.357 5.49 Zinc
mg/kg mg/kgmg/kgSW-846 7471B
0.0272 J 17439-97-6 00159 0.0140 0.280 Mercury
Std. Units Std. UnitsStd. UnitsWet Chemistry SW-846 9045D modified
7.89 1n.a. 00394 0.0100 0.0100 pH
The pH was measured in water at 21.6 C.
% %%Wet Chemistry SM 2540 G-1997
29.3 1n.a. 00111 0.50 0.50 Moisture
Moisture represents the loss in weight of the sample after oven drying at
103 - 105 degrees Celsius. The moisture result reported is on an
as-received basis.
General Sample Comments
State of North Carolina Lab Certification No. 521

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Antimony 06944
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Arsenic 06935
5Eric L Eby07/14/2014 17:15 1419206370011SW-846 6010C Barium 06946
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Beryllium 06947
*=This limit was used in the evaluation of the final result
Page 27 of 35

LL Sample # SW 7525107
LL Group # 1487148
Account # 10634
Sample Description: SS-GP15(68.7-70.7)-20140701 Solid Sample
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 15:00 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1568- SDG#: DUK38-13
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Boron 07914
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Cadmium 06949
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Chromium 06951
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Copper 06953
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Iron 01654
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Lead 06955
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Manganese 06958
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Molybdenum 06960
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Nickel 06961
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Selenium 06936
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Silver 06966
5Eric L Eby07/14/2014 17:15 1419206370011SW-846 6010C Strontium 07968
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Thallium 06925
1Joanne M Gates07/14/2014 10:24 1419206370011SW-846 6010C Zinc 06972
1Damary Valentin07/14/2014 15:57 1419206380011SW-846 7471B Mercury 00159
1James L Mertz07/13/2014 08:55 1419206370011SW-846 3050B SW SW846 (IV)ICP/ICPMS
Digest
10637
1James L Mertz07/13/2014 10:58 1419206380011SW-846 7471B SW SW846 (IV) Hg Digest 10638
1Luz M Groff07/11/2014 21:30 14192039401B1SW-846 9045D
modified
pH 00394
1Scott W Freisher07/10/2014 18:44 14191820003A1SM 2540 G-1997 Moisture 00111
*=This limit was used in the evaluation of the final result
Page 28 of 35

LL Sample # TL 7525108
LL Group # 1487148
Account # 10634
Sample Description: SS-GP15(68.7-70.7)-20140701 Solid Sample
SPLP NON-VOLATILE EXTRACTION
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 15:00 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1568S SDG#: DUK38-14*
As Received
Limit of
Quantitation
As Received
Method
Detection Limit* As Received
ResultAnalysis Name CAS Number
Dilution
Factor
CAT
No.
mg/l mg/lmg/lMetals SW-846 6010C
N.D.17440-36-0 07044 0.0051 0.0400 Antimony
0.0914 17440-38-2 07035 0.0072 0.0400 Arsenic
0.0332 17440-39-3 07046 0.00033 0.0100 Barium
N.D.17440-41-7 07047 0.00067 0.0100 Beryllium
0.0763 J 17440-42-8 08014 0.0046 0.100 Boron
N.D.17440-43-9 07049 0.00033 0.0100 Cadmium
6.44 17440-70-2 01750 0.0334 0.400 Calcium
N.D.17440-47-3 07051 0.0013 0.0300 Chromium
N.D.17440-50-8 07053 0.0028 0.0200 Copper
0.0698 J 17439-89-6 01754 0.0334 0.400 Iron
N.D.17439-92-1 07055 0.0047 0.0300 Lead
0.960 17439-95-4 01757 0.0167 0.200 Magnesium
0.0033 J 17439-96-5 07058 0.00083 0.0100 Manganese
0.0026 J 17439-98-7 07060 0.0017 0.0200 Molybdenum
0.0021 J 17440-02-0 07061 0.0016 0.0200 Nickel
0.209 J 17440-09-7 01762 0.133 1.00 Potassium
0.0152 J 17782-49-2 07036 0.0048 0.0400 Selenium
N.D.107440-22-4 07066 0.0180 0.100 Silver
The silver result was performed by the Method of Standard Addition.
Reporting limits were raised due to interference from the sample matrix.
3.45 17440-23-5 01767 0.167 2.00 Sodium
0.240 17440-24-6 08068 0.00033 0.0100 Strontium
N.D.17440-28-0 07022 0.0051 0.0600 Thallium
0.0077 J 17440-66-6 07072 0.0020 0.0400 Zinc
mg/l mg/lmg/lSW-846 7470A
N.D.17439-97-6 00259 0.000060 0.00020 Mercury
General Sample Comments
State of North Carolina Lab Certification No. 521

If the analysis is for determination of Hazardous Waste Characteristics,
see Table 1 in EPA Code of Federal Regulations 40 CFR 261.24.

All QC is compliant unless otherwise noted. Please refer to the Quality
Control Summary for overall QC performance data and associated samples.
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Antimony 07044
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Arsenic 07035
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Barium 07046
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Beryllium 07047
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Boron 08014
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Cadmium 07049
*=This limit was used in the evaluation of the final result
Page 29 of 35

LL Sample # TL 7525108
LL Group # 1487148
Account # 10634
Sample Description: SS-GP15(68.7-70.7)-20140701 Solid Sample
SPLP NON-VOLATILE EXTRACTION
Duke Sutton

Project Name: Duke Sutton, NC
Collected: 07/01/2014 15:00 by WS
Submitted: 07/08/2014 09:20
GeoSyntec Consultants
Reported: 07/15/2014 12:40
2501 Blue Ridge Road
Suite 430
Raleigh NC 27607
1568S SDG#: DUK38-14*
Method Analysis Name CAT
No.
Analysis
Date and Time
Batch#Trial#Dilution
Factor
Analyst
Laboratory Sample Analysis Record
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Calcium 01750
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Chromium 07051
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Copper 07053
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Iron 01754
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Lead 07055
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Magnesium 01757
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Manganese 07058
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Molybdenum 07060
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Nickel 07061
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Potassium 01762
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Selenium 07036
10Joanne M Gates07/15/2014 10:22 1419106360012SW-846 6010C Silver 07066
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Sodium 01767
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Strontium 08068
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Thallium 07022
1John P Hook07/14/2014 20:33 1419106360011SW-846 6010C Zinc 07072
1Damary Valentin07/14/2014 12:08 1419157130011SW-846 7470A Mercury 00259
1Micaela L Dishong07/14/2014 10:10 1419106360011SW-846 3010A WW/TL SW846 (IV) ICP Dig
(tot)
10636
1Micaela L Dishong07/11/2014 09:00 1419157130011SW-846 7470A WW SW846 Hg Digest 05713
n.a.Christina A Huber07/09/2014 14:00 14190-2486-
1567A
1SW-846 1312 Synthetic Precipitation
Leach
01567
*=This limit was used in the evaluation of the final result
Page 30 of 35

Page 1 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1487148
Reported: 07/15/14 at 12:40 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Matrix QC may not be reported if insufficient sample or site-specific QC samples were not submitted. In these
situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise
specified in the method.

All Inorganic Initial Calibration and Continuing Calibration Blanks met acceptable method criteria unless
otherwise noted on the Analysis Report.

Laboratory Compliance Quality Control

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max

Batch number: 141910636001 Sample number(s): 7525096,7525098,7525100,7525102,7525104,7525106,7525108
Antimony N.D. 0.0051 0.0400 mg/l 106 80-120
Arsenic N.D. 0.0072 0.0400 mg/l 107 80-120
Barium N.D. 0.00033 0.0100 mg/l 103 80-120
Beryllium N.D. 0.00067 0.0100 mg/l 103 80-120
Boron N.D. 0.0046 0.100 mg/l 100 80-120
Cadmium N.D. 0.00033 0.0100 mg/l 108 80-120
Calcium N.D. 0.0334 0.400 mg/l 106 80-120
Chromium N.D. 0.0013 0.0300 mg/l 104 80-120
Copper N.D. 0.0028 0.0200 mg/l 105 80-120
Iron N.D. 0.0334 0.400 mg/l 107 80-120
Lead N.D. 0.0047 0.0300 mg/l 112 80-120
Magnesium N.D. 0.0167 0.200 mg/l 101 80-120
Manganese N.D. 0.00083 0.0100 mg/l 106 80-120
Molybdenum N.D. 0.0017 0.0200 mg/l 103 80-120
Nickel N.D. 0.0016 0.0200 mg/l 112 80-120
Potassium N.D. 0.133 1.00 mg/l 102 80-120
Selenium N.D. 0.0048 0.0400 mg/l 106 80-120
Silver N.D. 0.0018 0.0100 mg/l 111 80-120
Sodium N.D. 0.167 2.00 mg/l 100 80-120
Strontium N.D. 0.00033 0.0100 mg/l 105 80-120
Thallium N.D. 0.0051 0.0600 mg/l 107 80-120
Zinc N.D. 0.0020 0.0400 mg/l 107 80-120

Batch number: 141915713001 Sample number(s): 7525096,7525098,7525100,7525102,7525104,7525106,7525108
Mercury N.D. 0.00006
0
0.00020 mg/l 97 80-120

Batch number: 141920637001 Sample number(s): 7525095,7525097,7525099,7525101,7525103,7525105,7525107
Antimony N.D. 0.330 4.00 mg/kg 113 80-120
Arsenic N.D. 0.640 4.00 mg/kg 106 80-120
Barium N.D. 0.0330 1.00 mg/kg 104 80-120
Beryllium N.D. 0.0670 1.00 mg/kg 102 80-120
Boron 1.31 J 0.840 10.0 mg/kg 100 80-120
Cadmium N.D. 0.0330 1.00 mg/kg 105 80-120
Chromium N.D. 0.110 3.00 mg/kg 103 80-120
Copper N.D. 0.330 2.00 mg/kg 104 80-120
Iron N.D. 3.34 40.0 mg/kg 106 80-120
Lead N.D. 0.500 3.00 mg/kg 105 80-120
Manganese 0.0860 J 0.0830 1.00 mg/kg 103 80-120
Molybdenum N.D. 0.170 2.00 mg/kg 106 80-120
Nickel N.D. 0.150 2.00 mg/kg 109 80-120
Selenium N.D. 0.440 4.00 mg/kg 103 80-120
Silver N.D. 0.190 1.00 mg/kg 104 80-120
Page 31 of 35

Page 2 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1487148
Reported: 07/15/14 at 12:40 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Blank Blank Blank Report LCS LCSD LCS/LCSD
Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max
Strontium 0.105 J 0.0330 1.00 mg/kg 106 80-120
Thallium N.D. 0.800 6.00 mg/kg 120 80-120
Zinc 0.517 J 0.260 4.00 mg/kg 103 80-120

Batch number: 141920638001 Sample number(s): 7525095,7525097,7525099,7525101,7525103,7525105,7525107
Mercury N.D. 0.0100 0.200 mg/kg 92 80-120

Batch number: 14192039401A Sample number(s): 7525095,7525097,7525099,7525101,7525103
pH 99 90-110

Batch number: 14192039401B Sample number(s): 7525105,7525107
pH 99 90-110

Batch number: 14191820003A Sample number(s): 7525095,7525097,7525099,7525101,7525103,7525105,7525107
Moisture 100 99-101

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

Batch number: 141910636001 Sample number(s): 7525096,7525098,7525100,7525102,7525104,7525106,7525108 UNSPK:
7525096 BKG: 7525096
Antimony 89 87 75-125 1 20 0.0222 J 0.0207 J 7 (1) 20
Arsenic 94 93 75-125 2 20 0.0716 0.0748 4 (1) 20
Barium 89 89 75-125 1 20 0.135 0.137 1 20
Beryllium 86 85 75-125 2 20 N.D. N.D. 0 (1) 20
Boron 87 87 75-125 0 20 0.0463 J 0.0443 J 4 (1) 20
Cadmium 90 89 75-125 1 20 N.D. N.D. 0 (1) 20
Calcium 92 90 75-125 2 20 3.24 3.31 2 20
Chromium 87 87 75-125 1 20 N.D. N.D. 0 (1) 20
Copper 90 89 75-125 1 20 0.0281 0.0278 1 (1) 20
Iron 87 84 75-125 3 20 N.D. N.D. 0 (1) 20
Lead 86 84 75-125 2 20 N.D. N.D. 0 (1) 20
Magnesium 88 85 75-125 3 20 0.529 0.533 1 (1) 20
Manganese 89 89 75-125 1 20 0.0080 J 0.0083 J 4 (1) 20
Molybdenum 85 84 75-125 2 20 0.141 0.142 1 20
Nickel 88 86 75-125 1 20 0.0046 J 0.0048 J 4 (1) 20
Potassium 93 91 75-125 3 20 0.600 J 0.577 J 4 (1) 20
Selenium 89 89 75-125 0 20 0.0090 J 0.0117 J 25* (1) 20
Silver 7* 7* 75-125 3 20 N.D. N.D. 0 (1) 20
Sodium 90 87 75-125 3 20 2.20 2.22 1 (1) 20
Strontium 83 82 75-125 1 20 0.191 0.194 2 20
Thallium 85 83 75-125 2 20 N.D. N.D. 0 (1) 20
Zinc 91 90 75-125 1 20 0.0027 J 0.0024 J 12 (1) 20

Batch number: 141915713001 Sample number(s): 7525096,7525098,7525100,7525102,7525104,7525106,7525108 UNSPK:
7525096 BKG: 7525096
Mercury 73* 71* 80-120 2 20 N.D. N.D. 0 (1) 20

Batch number: 141920637001 Sample number(s): 7525095,7525097,7525099,7525101,7525103,7525105,7525107 UNSPK:
Page 32 of 35

Page 3 of 3

Quality Control Summary

Client Name: GeoSyntec Consultants Group Number: 1487148
Reported: 07/15/14 at 12:40 PM

*- Outside of specification
**-This limit was used in the evaluation of the final result for the blank
(1) The result for one or both determinations was less than five times the LOQ.
(2) The unspiked result was more than four times the spike added.

Sample Matrix Quality Control
Unspiked (UNSPK) = the sample used in conjunction with the matrix spike
Background (BKG) = the sample used in conjunction with the duplicate

MS MSD MS/MSD RPD BKG DUP DUP Dup RPD
Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___
P526716 BKG: P526716
Antimony 65* 68* 75-125 3 20 0.453 J 0.324 J 33* (1) 20
Arsenic 103 104 75-125 1 20 2.38 J 2.77 J 15 (1) 20
Barium 105 112 75-125 3 20 121 116 4 20
Beryllium 102 101 83-119 2 20 0.574 J 0.473 J 19 (1) 20
Boron 103 102 84-110 3 20 17.4 14.5 18 (1) 20
Cadmium 98 96 75-120 4 20 N.D. 0.0510 J 200* (1) 20
Chromium 118 116 75-125 2 20 18.7 17.9 4 20
Copper 116 132* 75-125 7 20 17.9 21.5 18 20
Iron -269
(2)
-30 (2) 75-125 1 20 19,000 16,200 16 20
Lead -377
(2)
317 (2) 75-125 74* 20 144 67.0 73* 20
Manganese 29 (2) 880 (2) 75-125 65* 20 417 307 30* 20
Molybdenum 98 97 82-110 3 20 0.990 J 0.724 J 31* (1) 20
Nickel 98 96 75-125 3 20 17.7 16.3 8 20
Selenium 96 99 75-125 1 20 N.D. N.D. 0 (1) 20
Silver 98 100 75-125 0 20 N.D. N.D. 0 (1) 20
Strontium 97 100 81-125 0 20 27.8 24.0 14 20
Thallium 112 111 78-119 3 20 N.D. N.D. 0 (1) 20
Zinc 117 136* 75-125 6 20 66.8 72.5 8 20

Batch number: 141920638001 Sample number(s): 7525095,7525097,7525099,7525101,7525103,7525105,7525107 UNSPK:
7525095 BKG: 7525095
Mercury 104 104 80-120 4 20 0.0543 J 0.0666 J 20 (1) 20

Batch number: 14192039401A Sample number(s): 7525095,7525097,7525099,7525101,7525103 BKG: P526010
pH 10.3 10.3 0 3

Batch number: 14192039401B Sample number(s): 7525105,7525107 BKG: P522507
pH 7.89 7.85 1 3

Batch number: 14191820003A Sample number(s): 7525095,7525097,7525099,7525101,7525103,7525105,7525107 BKG:
P526737
Moisture 3.7 3.7 1 5

Page 33 of 35
Page 34 of 35
Explanation of Symbols and Abbreviations

3768 0713
The following defines common symbols and abbreviations used in reporting technical data:
RL Reporting Limit BMQL Below Minimum Quantitation Level
N.D. none detected MPN Most Probable Number
TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units
IU International Units NTU nephelometric turbidity units
umhos/cm micromhos/cm ng nanogram(s)
C degrees Celsius F degrees Fahrenheit
meq milliequivalents lb. pound(s)
g gram(s) kg kilogram(s)
µg microgram(s) mg milligram(s)
mL milliliter(s) L liter(s)
m3 cubic meter(s) µL microliter(s)
pg/L picogram/liter
< less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be
reliably determined using this specific test.
> greater than
ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For
aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/l), because one liter of water has a
weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter per liter of gas.
ppb parts per billion
Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight
basis concentration to approximate the value present in a similar sample without moisture. All other results are reported
on an as-received basis.
Data Qualifiers:
C – result confirmed by reanalysis.
J - estimated value – The result is ≥ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ).
U.S. EPA CLP Data Qualifiers:
Organic Qualifiers Inorganic Qualifiers
A TIC is a possible aldol-condensation product B Value is <CRDL, but ≥IDL
B Analyte was also detected in the blank E Estimated due to interference
C Pesticide result confirmed by GC/MS M Duplicate injection precision not met
D Compound quantitated on a diluted sample N Spike sample not within control limits
E Concentration exceeds the calibration range of S Method of standard additions (MSA) used
the instrument for calculation
N Presumptive evidence of a compound (TICs only) U Compound was not detected
P Concentration difference between primary and W Post digestion spike out of control limits
confirmation columns >25% * Duplicate analysis not within control limits
U Compound was not detected + Correlation coefficient for MSA <0.995
X,Y,Z Defined in case narrative
Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.
Measurement uncertainty values, as applicable, are available upon request.
Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the
test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact
us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our
staff. This report shall not be reproduced except in full, without the written approval of the laboratory.
Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as “analyze immediately” are not
performed within 15 minutes.

WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE
FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM
ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF
MERCHANTABILITY. IN NO EVENT SHALL EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL, LLC BE LIABLE FOR INDIRECT, SPECIAL,
CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS
OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL AND (B) WHETHER
EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal
responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Eurofins Lancaster
Laboratories Environmental which includes any conditions that vary from the Standard Terms and Conditions, and Eurofins Lancaster Laboratories
Environmental hereby objects to any conflicting terms contained in any acceptance or order submitted by client.
Page 35 of 35