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Home My WebLink AboutWQ0023181_Monitoring - 10-2016_20161109.I �6C �C-�f0j C 9 es, �f �r�'J! .s I ,ye z Lab, O_jCAt, Accurate. Timely. Responsive. Innovative-,. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Tuesday, October 25, 2016 International Paper, Inc. (IN019) Attn: Royce Boykin 335 Jesse Hill Rd. Snow Hill, NC 28580 RE: Laboratory Results for Project Number: [none], Project Name/Desc: NPDES ENCO Workorder(s): CZ14897 Dear Royce Boykin, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Thursday, October 13, 2016. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Chuck Smith Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 1 of 8 www.encolabs.com SAMPLE SUMMARY/ LABORATORY CHRONICLE Client ID: Wet Yard Pond Lab ID: CZ14897-01 Sampled: 10/13/16 10:28 Received: 10/13/16 13:00 Parameter Hold Date/Time(s) Prea Date/Time(s) Analysis Date/Time(s) EPA 420.1 11/10/16 10/18/16 09:43 10/19/16 09:51 Field 10/13/16 10:42 10/13/16 10:28 10/13/16 10:28 SM 2540C-1997 10/20/16 10/17/16 13:30 10/17/16 13:30 SM 4500CIE-1997 11/10/16 10/17/16 09:29 10/17/16 12:58 SM 5220D-1997 11/10/16 10/24/16 11:36 10/24/16 14:30 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 2 of 8 4 =SN" �( www.encolabs.com FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 3 of 8 SAMPLE DETECTION SUMMARY Client ID: Wet Yard Pond Lab ID: CZ14897-01 Analyte Results Elm Mmol PL_ SIAL Method Notes Chemical Oxygen Demand 52 10 10 mg/L SM 522OD-1997 Chloride 5.3 1.9 5.0 mg/L SM 4500CI E-1997 pH 8.42 0 0 pH Units Field Phenolics 0.04 3 0.03 0.05 mg/L EPA 420.1 Temperature 20.9 0 0 °C Field Total Dissolved Solids 110 so 50 mg/L SM 254OC-1997 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 3 of 8 C www.encolabs.com ANALYTICAL RESULTS Description: Wet Yard Pond Lab Sample ID: CZ14897-01 Received: 10/13/16 13:00 Matrix: Surface Water Sampled- 10/13/16 10:28 Work Order: CZ14897 Project: NPDES Sampled By: Client Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591J Flan Units LE MDL FOL Batch Method Analyzed ft Notes pH 8.42 pH Units Analyte rCAS Numberl Results Flag Units DF MDL IQ Batch Method Analyzed 1y Notes Chemical Oxygen DemandA 52 mg/L 1 10 10 6324011 SM 5220D-1997 10/24/16 14:30 30C Chloride [16887-00-6]A 5.3 mg/L 1 1.9 5.0 6317011 SM 4500CIE-1997 10/17/16 12:58 JLJ Total Dissolved SolidsA 110 mg/L 1 50 50 6J17004 SM 254OC-1997 10/17/16 13:30 MMR 1 Field Parameters 0.05 6118008 EPA 420.1 10/19/16 09:51 CRG Analyte rCAS Numberl Results Flan Units LE MDL FOL Batch Method Analyzed ft Notes pH 8.42 pH Units 1 0 0 6314007 Field 10/13/16 10:28 CLI Temperature 20.9 °C 1 0 0 6314007 Field 10/13/1610:28 CLI Classical Chemistry Parameters ^ - ENCO Orlando certified analyte [NC 9191 Analyte KAS Numberl Results fin UnitsDF ODL PDI, Batch Method Analyzed Notes Phenolics^ 0.04 J mg/L 1 0.03 0.05 6118008 EPA 420.1 10/19/16 09:51 CRG FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 8 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 6117004 - NO PREP Blank (6717004-BLKi) Prepared & Analyzed: 10/17/2016 13:30 Spike Source %REC RPD Anal Stte Result Elm P_Q6 UDita Level Result %REC Limits RPD Limit Notes Total Dissolved Solids 50 U 50 mg/L LCS (6317004-BS3) Prepared & Analyzed: 10/17/2016 13:30 Spike Source %REC RPD Analyte Result flag P-QL 11M Level Result %REC Limits RPD Limit Notes Chloride 1.9 U 5.0 mg/L LCS (6717011-BS1) Prepared: 10/17/2016 09:29 Analyzed: 10/17/2016 11:38 Spike Source %REC RPD Spike Source %REC Elan P-QL RPD Anal yje Result Elag PQL Units Level Result %REC Limits RPD Mina Notes Total Dissolved Solids 980 Prepared: 10/17/2016 09:29 Analyzed: 10/17/2016 12:57 50 mg/L 1000 98 90-110 Duplicate (6717004-DUPS) Spike Source %REC Prepared & Analyzed: 10/17/2016 13:30 Analyte Resin flag P-QL Source: CZ14849-01 Level Result %REC Limits RPD Limit Notes Chloride 5.6 5.0 mg/L 5.3 6 10 Matrix Spike (6317011-MS1) Prepared: 10/17/2016 09:29 Analyzed: 10/17/2016 11:38 Spike Source %REC RPD Analyte Resul flag POL Units Level Resu %REC Limits RPD Lima Notes Total Dissolved Solids 480 Level Result %REC Limits . RPD 50 mg/L 500 3 20 Duplicate (6117004-DUP2) Matrix Spike Dup (6717011-MSD3) Prepared: 10/17/2016 09:29 Analyzed: 10/17/2016 11:40 Prepared & Analyzed: 10/17/2016 13:30 Source: CZ14892-01 Spike Source %REC RPD Analyte Result Elaa P-QL UUM Level Result °/aREC Limits RPD i.imit Notes Total Dissolved Solids 50 U 50 mg/L 50 U 20 Batch 6117011- NO PREP Blank (6317011-BLKi) Prepared: 10/17/2016 09:29 Analyzed: 10/17/2016 11:37 Spike Source %REC RPD Analyte Result flag P-QL 11M Level Result %REC Limits RPD Limit Notes Chloride 1.9 U 5.0 mg/L LCS (6717011-BS1) Prepared: 10/17/2016 09:29 Analyzed: 10/17/2016 11:38 Source: CZ13576-01 Analyte Chloride Batch 6724011- Same SpikeSource %REC Result Flag PGL Units Level Result %REC Limits RPD 770 25 mg/L 200 620 74 80-120 0.5 RPD Limit Notes 25 QM -07 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 5 of 8 Spike Source %REC RPD AnalResult Elan P-QL Units Level Result %REC Limits RPD Limit Notes Chloride 97 5.0 mg/L 100 97 80-120 Duplicate (6117011-DUP1) Prepared: 10/17/2016 09:29 Analyzed: 10/17/2016 12:57 Source: CZ14897-01 Spike Source %REC RPD Analyte Resin flag P-QL Units Level Result %REC Limits RPD Limit Notes Chloride 5.6 5.0 mg/L 5.3 6 10 Matrix Spike (6317011-MS1) Prepared: 10/17/2016 09:29 Analyzed: 10/17/2016 11:38 Source: CZ13576-01 Spike Source %REC RPD Analyte Rexul Flag P-QL Units Level Result %REC Limits . RPD Limit Notes Chloride 770 25 mg/L 200 620 72 80-120 QM -07 Matrix Spike Dup (6717011-MSD3) Prepared: 10/17/2016 09:29 Analyzed: 10/17/2016 11:40 Source: CZ13576-01 Analyte Chloride Batch 6724011- Same SpikeSource %REC Result Flag PGL Units Level Result %REC Limits RPD 770 25 mg/L 200 620 74 80-120 0.5 RPD Limit Notes 25 QM -07 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 5 of 8 QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 6124011 - Same - Continued Blank (6324011-BLK3) Prepared: 10/24/2016 11:36. Analyzed: 10/24/2016 14:30 Spike Source %REC RPD Analyte Result flag M Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 10 U 10 mg/L LCS (6324011-BS1) Prepared: 10/24/2016 11:36 Analyzed: 10/24/2016 14:30 Spike Source %REC RPD Analyte Result Flag POL unilu Level Result %REC Limits RPD Limit Notes Phenolics 0.03 U 0.05 mg/L LCS (6718008 -BSI) Prepared: 10/18/2016 09:43'Analyzed: 10/19/2016 09:51 Spike Source %REC Spike Source %REC RPD Analyte Resin Flag M Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 500 10 mg/L 500 100 90-110 Matrix Spike (6724011 -MSI) Source: AZ06869-06 Prepared: 10/24/2016 11:36 Analyzed: 10/24/2016 14:30 Source:CZ09494-01 Spike Source %REC RPD Analyte Result, Elm POL Units Level Result %REC Limits RPD Spike Source %REC RPD Anai3ft Resul Flaci POL Units Level Result %REC Limits RPD Limft Notes Chemical Oxygen Demand 1500 20 mg/L 1000 550 91 90-110 Matrix Spike Dup (6324011-MSDi) Prepared: 10/24/2016 11:36 Analyzed: 10/24/2016 14:30 Source: CZ09494-01 Spike Source %REC RPD Analyte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 1500 20 mg/L 1000 550 93 90-110 1 10 Classical Chemistry Parameters - Quality Control Batch 6118008 - NO PREP Blank (6318008-BLK1) Prepared: 10/18/2016 09:43 Analyzed: 10/19/2016 09:51 Spike Source %REC RPD Analyte Result Flag POL unilu Level Result %REC Limits RPD Limit Notes Phenolics 0.03 U 0.05 mg/L LCS (6718008 -BSI) Prepared: 10/18/2016 09:43'Analyzed: 10/19/2016 09:51 Source: AZ06869-06 Anal Phenolics Spike Source %REC Result —FIM 4 Units Level Resul %REC Limits RPD 0.42 0.05 mg/L 0.500 0.04 76 91-114 3 RPD Limit Notes 10 QM -07 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 6 of 8 Spike Source %REC RPD Analyte Result Elan P91 Units Level Result %REC Limits RPD Limit Notes Phenolics 0.46 0.05 mg/L 0.500 92 91-114 Matrix Spike (6118008-MS3) Prepared: 10/18/2016 09:43 Analyzed: 10/19/2016 09:51 Source: AZ06869-06 Spike Source %REC RPD Analyte Result, Elm POL Units Level Result %REC Limits RPD Limi Notes Phenolics 0.43 0.05 mg/L 0.500 0.04 79 91-114 QM -07 Matrix Spike Dup (6718008-MSDi) Prepared: 10/18/2016 09:43 Analyzed: 10/19/2016 09:51 Source: AZ06869-06 Anal Phenolics Spike Source %REC Result —FIM 4 Units Level Resul %REC Limits RPD 0.42 0.05 mg/L 0.500 0.04 76 91-114 3 RPD Limit Notes 10 QM -07 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 6 of 8 � for www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. QM -07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 7 of 8 ENVIRONMENTAL CONSERVATION LABORATORIES CHAIN -OF -CUSTODY RECORD www.encolabs.corvs �. 10-/75 Central Port Dc 6810 EzecuOvc.Park Courrsuile 111 1.02-A VJoodwfndis`Grdusiral Gt. Oriando, FL 32U-1 Jacksonville FL 32216-6069 Cary, NC 27511 (407)626-5314. Fax.(407)850.69,15 (904)296.3007 Fox (904)-296.6210 (919) 567-3090 Faz,(919).467-3515. Pag@ .Of- Client,Name Project Number Dat"me Received By DatelTime Requested ConddifJionn Upon Receipt Uv Acceptable Unacceptable Analyses Requested Turnaround Times Inc l I r I Address Proiecl ame/Desc o �j Note : Rush repuests subject io .acceptanco�6y the facility Ji:4 .t= Hill Rd- (L .. City/ST/zip PO It t Billing info 0 . nav C 285BO n -Standard. it Cl Tel Fax Reporting Contact � r ' 6 �i (25 2) 456-2599 R�ce.Etoukin � _Expedited Due samplers) Name, Affiliation (Print) Billing Contact; Annette Lynch it Cab Wbrkorder ` Samplers) signature Site Location; Tme,Zone o 0 . 'r T } Preservation (See:Ccdes) (Combina ras kcessary) Collection 'l Matrix Total r of ample Comments" Item M sample ID (Field Identrfc.aion) Col action pinta Tioie. CompGrafi (see codes) 7777777777 Cont mets 7 j 0, IV, - Affi, 1 I x _ 1 Liz r , i Zi i li i r ,' F-. 4i �} .• r. k�-,-4- t ... <-- <-- Total of Containers Sample Kt Prepared By ,,Dale�me Comments(SpecialReponing,Requiremonls Relinquished By; Ralinq, -hod: y )� Dal ime Dal4ne'e- 'Re[i ved By - !' -y. Rei:ulved, DateFrime Date)Tim=_ Relinquisfied.By Dat"me Received By DatelTime Cooler 0s 8 Temps on Receipt / I r DG ConddifJionn Upon Receipt Uv Acceptable Unacceptable Matrix : GWrGroundwaler SO -Soil DW -Drinking Waler SE -Sediment SW-Surlace Water WW -Wastewater A -Air O-Other(detailincomments ] Preservation: Wee h,`ic1 rv-nrvu4,s•n25u4 nv-noun u•tJurerlueierrr.rwii,i,ioi�wi „. Note: All samples submitted to ENCO.Labs are in accordance with the terms and conditions listed on the reverse of thisform. uHa.ss prior writ ten agreements exist Sample Preservation Verification ENCO Cary 'Work Order: CZ14897 Project: NODES Client International. Paper, Inc. (!N019) Prdj6c [none] Logged In: :13 -Oct -16 14:2- 5 Logged By: Andrew -8 G,00,n,s 'r-zia9mi - Rbageht, Name. ID 1 2 -- I .Reagent Name ID 4L Rea�ent-Name ID 5 6 Page 1 of 1 WH Cont; TP �' Require rnpm. A 25OmLA+H2,S.C)4 <2 Y.1,6,,/ NA 'Y IAT- NA D 2,5OmLP-�H2804 N / NA '� I Y-�v I NA Y11- . . Rbageht, Name. ID 1 2 -- I .Reagent Name ID 4L Rea�ent-Name ID 5 6 Page 1 of 1