NC0003417_Rain from Hurrican Matthew (2)_20161027

ENERGY.
October 27, 2016
Mr. Jeffrey O. Poupart
North Carolina Department of Environment and Natural Resources
Division of Water Resources, Wastewater Branch
1617 Mail Service Center
Harry K. Sideris
Senior Vice President
Environmental, Health & Safety
526 S. Church Street
Mail Code: EC3XP
Charlotte, NC 28202
[phone]
Raleigh, NC 27699-1617 RECEI ED1NNICDMfD W
OCT 3 12016
Subject: Duke Energy Progress, LLC.
HF Lee Energy Complex NPDES Permit NC0003417 Water Quaiity
NPDES Application Update Permitting ,,est en
Wayne County
Dear Mr. Poupart:
The rains from Hurricane Matthew were significant at the HF Lee Energy Complex (HF
Lee) and the areas of the Neuse River downstream of Goldsboro. The Neuse River
level rose high enough to enter the cooling pond at HF Lee through outfall 002 and also
by over -topping the cooling pond dike. The site has not seen a flooding event like this
since Hurricane Floyd in 1999. As a result of the severe weather conditions from the
hurricane, the dike of cooling pond breached in the southeast corner of the pond. A
temporary repair has been completed and most of the discharge from the breach has
been eliminated.
Duke Energy would like to add a new emergency outfall at the site of the breach in the
current NPDES permitting process. Although a permanent solution for the breach repair
is still being developed, we think this emergency outfall would be valuable during severe
weather events to allow for the discharge of the pond in instances where the river rises
and flows into the pond via Outfall 002 or from over -topping the dike. The addition of
the new emergency outfall would avoid a scenario where the pond breaches because of
the influx of water from the river. The new outfall would be located at approximate
coordinates 350 22' 18" N and 780 03'54" W, and would only be used during severe
weather events or maintenance. Duke Energy also thinks appropriate limits at this new
outfall would mirror the limits at Outfall 002.
Enclosed for your consideration and use are analytical monitoring results from the
cooling pond during the breach and a topographic map showing the approximate
location of the breach.
If there are any questions regarding this request, please contact Mr. Steve Cahoon via
phone at [phone] or via email at steve.cahoon @ duke-energy.com.

I certify, under penalty of law, that this document and all attachments were prepared under my
direction or supervision in accordance with a system designed to assure that qualified personnel
properly gather and evaluate the information submitted. Based on my inquiry of the person or
persons who manage the system, or those persons directly responsible for gathering the
information, the information submitted is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations.
Sincerely,
Harry K. Sideris
Senior Vice President
Environment, Health and Safety
Enclosures

Anal
lab
Certificate of LaboratoryAnalysis Page 5 olt 13
This report shall not be reproduced, except in full.
Order # A 6100336
Site, COOLING POND
Sample #:
2016033099
Collection Date: 12-00-16 5;46 PM
Matrix:
NPDES
Analyte
Result
Units Qualifiers
RDL
OF
Method
Analysis DateITlme
Analyst
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease
< 5
mg/L
5
1
EPA 1664B
1011312016 09:30
CJELLIO
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
1
EPA 245.1
10/1412016 09:19
DMFRANC
TOTAL RECOVERABLE METALS
BY ICP
Iron (Fe)
1.67
mg/L
0.01
1
EPA 200.7
10114120161(W1
JJMACKE
TOTAL RECOVERABLE METALS
BY ICP -RAS
Antimony (Sb)
41
ug/L
1
1
EPA 200.8
1011312016 2013
CWSPEN3
Arsenic (As)
<1
ug/l.
1
1
EPA 200.6
10!1312016 20:13
CWSPEN3
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
10/13/2016 2073
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
1
EPA 200.8
10/13/2016 20:13
CWSPEN3
Chromium (Cr)
1.65
ug/L
1
1
EPA 200.8
10/13120162013
CWSPEN3
Copper (Cu)
3.39
ug/L
1
1
EPA 200.8
10/13/2016 20.13
CWSPEN3
Lead (Pb)
1.37
ug/L
1
1
EPA 200.8
10/13/2016 20.13
CWSPEN3
Nickel (NO
<1
ug/L
1
1
EPA 200.8
10113/201162013
CWSPEN3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
10113/2016 20.13
CWSPEN3
Silver (Ag) Low Level
< 0.3
uglL
0.3
1
EPA 200.8
10/1312016 20.13
CWSPEN3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
10113/2016 20:13
CWSPEN3
Zinc (Zn)
7.13
ug/L
5
1
EPA 200.8
101131201620:13
CWSPEN3
TOXICITY - (Analysis Performed by ETT Environmental)
Vendor Parameter
1
Vendor Method
V ETT
TOTAL SUSPENDED SOLIDS
TSS
16
mg/L
5
1
SM2540D
101131201619;17
HGRUVER

an
eAnalydcal
www.peardLoom
ANALYTICAL RESULTS
Project: J16100360
Pace Project No.: 92316133
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
(704)8759092
Sample: 2016033236
Parameters
Lab ID: 92316133001
Results Units
Collected: 10/13/16 16:20
Report Limit OF
Received:
Prepared
1011411614;00
Analyzed
Matrix: Water
GAS No. Qual
alpha -BHC
NO
ug/L
0,050
1
10114/1617:30 10/17/1611:38 319-84.6
608 GCS Pesticides and PCBs Analytical Method: EPA608 Preparation Method, EPA 3510
Aldrin
NO
u9/L
0.050
1
1011411617:30 10/1711611:38 309.00-2
alpha -BHC
NO
ug/L
0,050
1
10114/1617:30 10/17/1611:38 319-84.6
beta -BHC
NO
ug/L
0.050
1
10114/1617:30 10117/1611:38 319-85-7
delta -BHC
NO
ug/L
0.050
1
10114/1617:30 10117/1611:38 319.86.8
gamma -BHC (Lindane)
NO
ug1L
0.050
1
10/14116 17:30 1011711611:38 58-89-9
Chlordane (Technical)
NO
ug/L
0,50
1
10114/16 17:30 1011711611.38 57-74-9
4,4' -DDD
NO
ug/L
0.050
1
1011411617:30 10/1711611:38 72-54-8
4,4' -DDE
NO
ug/L
0.050
1
10114/1617:30 1011711611:38 72-55.9
4,4' -DDT
NO
ug/L
0,050
1
1011411617:30 10117/1611:38 50.29.3
Dieldrin
NO
ug/L
0.050
1
10/1411617:30 10117/1611:38 60.57-1
Endosulfan I
NO
ug/L
0,050
1
10/14/1617:30 1011711611:38 959-98-8
Endosulfan 11
NO
ug/L
0,050
1
1011411617:30 1011711611:38 33213.65.9
Endosulfan sulfate
NO
ug/L
0.050
1
1011411617:30 10/1711611:38 1031-07-8
Endrin
NO
ug1L
0.050
1
10/1411617:30 1011711611:38 72-20-8
Endrin aldehyde
NO
ug1L
0.050
1
10/1411617:30 10117/1611:38 7421-93.4
Heptachlor
ND
uglL
0.650
1
1011411617:30 10/17/1611:38 76-44-8
Heptachlor epoxide
NO
ug/L
0.050
1
10114/1617:30 1011711611:38 1024-57-3
PCB -1016 (Aroclor 1016)
NO
ug/L
0,50
1
10114/1617:30 10117/1611:36 12674-11.2
PCB -1221 (Aroclor 1221) `
NO
ug/L
0.50
1
10/14/1617:30 10117116 11:38 11104-28-2
PCB -1232 (Aroclor 1232)
NO
ug/L
0.50
1
1011411617:30 10117/1611:38 11141-16.5
PCB -1242 (Aroclor 1242)
NO
uglL
0.50
1
1011411617:30 10117/16 11:38 53469-21-9
PCB -1248 (Aroclor 1248)
NO
ug/L
0.50
1
10114/1617:30 10117/16 11:38 12672-29-6
PCB -1254 (AroGor 1254)
NO
ug/L
0.50
1
1011411617:30 10117/16 11:38 11097-69-1
PCB -1260 (Aroclor 1260)
NO
ug/L
0.50
1
1011411617:30 10/17/16 11:38 11096-82-5
Toxaphene
NO
ug/L
0.50
1
10114/1617:30 1011711611:38 8001-35-2
Surrogates
Tetrachioro-m-xylene (S)
90
'3l}
20-110
1
10/14/16 17:30 1011711611:38 877-09-8
Decachtorobiphenyl (S)
46
20-138
1
10114/16 17:30 10/1711611:38 2051-24-3
F{�P74�1�41�11! [9�
Analytical Method; EPA 200.7 Preparation Method: EPA 200,7
Antimony
NO
ug/L
5.0
Arsenic
NO
ug/L
10.0
Beryllium
NO
ug/L
1.0
Cadmium
NO
ug/L
1,0
Chromium
NO
ug/L
5.0
Copper
5.9
ug/L
5.0
Iron
1660
ug/L
50.0
Lead
NO
ug/L
5.0
Nickel
NO
ug/L
5.0
Selenium
NO
ug/L
10.0
Silver
NO
ugiL
5.0
Thallium
NO
ug/L
10.0
Zinc
NO
ug/L
10.0
245.1 Mercury
Analytical Method: EPA245.1 Preparation Melhoc
1 10115/16 01:00 10/1511611.46 7440.36-0
1 10115/1601:00 10/15/1611;46 7440.38-2
1 10/15/16 01:00 10/1511611:46 744041-7
1 10/15/16 01:00 10/15/1611:46 7440-43-9
1 10/15/16 01:00 1011511511:46 7440-47-3
1 10/15/16 01:00 1011511611.46 7440-50-8
1 110/15/16 01:00 10115/1611:46 7439.89-6
1 10/15/16 01:00 10115/1611:46 7439-92-1
1 10/15/16 01:00 10115116 11 A6 7440-02-0
1 10115/16 01:00 10115/16 I II A6 778249-2
1 10115/16 01:00 10/15/16 11A6 7440.22.4
1 10/15/16 01:00 10/1511611:46 7440-28-0
1 1011511601:00 10/1511611AG 7440.66-6
: EPA 245,1
Mercury NO ug/L 0.20 1 10115/1601:45 1011711611:01 7439.97.6
REPORT OF LABORATORY ANALYSIS
This report shat not be reproduced, except In full.
Date: 10/1712016 04,29 PM without the written consent of Pace Analytical Services; LLC:
Page 12 of 42

aceAnalytical
ANALYTICAL RESULTS
Project: J16100360
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Hunteravige, NC 28076
(704)8759092
Pare Project No.: 92316133
Sample: 2016033236 Lab 10: 92316133001 Collected.,10113116 16.20 Received: 1011411614:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
625 MSSV Analytical Method: EPA625 Preparation Method. EPA625
Acenaphthene
NO
ug/L
5.0
1 10/14/16 17:00 10/17/16 11:19 83-32-9
Acenaphthylene
NO
ug/L
5.0
1 10/1411617:00 10/17/16 11:19 208-9133-8
Anthracene
NO
ug/L
5,0
1 1011411617:00 10/1711611:19 120-12-7
Benzidine
NO
ug/L
50.0
1 10/1411517:00 1011711611.19 92-87-5 L2
Benzo(a)anthracene
NO
ug/L
511
1 1011411617:00 1011711611:19 56-55.3
Benzo(a)pyrene
NO
ug/L
5A
1 10/1411617:00 10/17/1611:19 50.32.8
Benzo(b)fluoranthene
NO
ug/L
5,0
1 10/1411617:00 10/1711611:19 205-99.2
Benzo(g,h,i)peryiene
NO
ug/L
5.0
1 10/14/1617:00 10/17/1611:19 191-24-2
Benzo(k)fluoranthene
NO
ug/L
510
1 10/1411617:00 10117/1611:19 207-08-9
4-Bromophenylphenyl ether
ND
ug/L
5.0
1 1011411617:00 10117/16 11:19 101-55-3
Butylbenzylphthalate
ND
ug/L
5.0
1 10/14116 17:00 1011711611:19 85-68-7
bis(2-Chloroethoxy)methane
ND
ug/L
10.0
1 10114/1617:00 1011711611:19 111-91-1
bis(2-Chloroethyl) ether
NO
ug/L
5A
1 1011411617:00 1011711611:19 111-44.4
2-Chloronaphthatene
NO
ug/L
5.0
1 1011411617:00 10117/1611:19 91-58-7
2 -Chlorophenol
NO
ug/L
5.0
1 1011411617:00 1011711611:19 95-57-8
4-Chlorophenylphenyt ether
NO
ug/L
50
1 10114116 17:00 10117/1611:19 7005-72-3
Chrysene
ND,
ug/L
5.0
1 10/14/16 17:00 10/1711611:19 218-01-9
Dibenz(a,h)anthracene
ND
ug/L
5,0
1 10114/1617:00 10/17/1611:19 53-70.3
3,3'-Dichlorobenzidine
ND
ug/L
25,0
1 1011411617:00 1011711611:19 91-94-1
2,4-Dichicrophenol
ND
ug/L
5.0
1 1011411617:00 1011711611:19 120-83-2
Diethylphthalate
NO
ug/L
5.0
1 1011411617:00 1011711611:19 84-66-2
2,4 -Dimethylphenol
ND
ug/L
10.0
1 10/14/1617:00 1011711611:19 105-67.9
Dimethylphthalate
ND
ug/L
5.0
1 10114/1617:00 1011711611:19 131-11-3
01-n-butylphthalate
ND
ug/L
5.0
1 1011411617:00 10117/1611:19 84.74.2
4,6-Dinitro-2-melhylphenol
ND
ug/L
20.0
1 10114/1617:00 10117/1611:19 534.52-1
2,4-Dinitrophenot
NO
ug/L
50.0
1 10114/1617:00 1011711611:19 51-28-5
2,4-Dinitrotoluene
ND
ug/L
5.0
1 10114/1617:00 1011711611:19 121-14-2
2,6-Dlnitrototuene
ND
ug/L
5.0
1 1011411617:00 1011711611:19 606-20-2
Di-n-octylphthalate
ND
ug/L
5.0
1 1011411617:00 1011711611:19 117.84.0
1,2-Diphenylhydrazine
ND
ug/L
5.0
1 1011411617:00 1011711611:19 122.66-7
bis(2-Ethylhexyl)phthalate
ND
ug/L
5.0
1 10/1411617:DD 1011711611:19 117.51-7
Fluoranthene
ND
ug/L
5.0
1 10/1411617:00 1011711611:19 206-44-0
Fluorene
NO
ug/L
5.0
1 10/1411617:00 1011711611:19 86-73-7
Hexachloro-1,3-butadiene
NO
ug/L
5.0
1 1011411617:DD 1011711611:19 87-68-3
Hexachlorobenzene
NO
ug/L
5.0
1 1011411617:00 1011711611:19 118-74-1
Hexachtorocyclopentadiene
ND
ug/L
10.0
1 1011411617:00 10/17/1611:19 77-47-4
Hexachtoroethane
NO
ug1L
5.0
1 1011411617:00 10/1711611:19 67-72-1
Indeno(1,2,3-cd)pyrene
NO
ug/L
5.0
1 1011411617:00 10/1711611:19 193-39.5
Isophorone
ND
ug/L
10.0
1 10114/1617:00 1011711611:19 78-59-1
384-Methylphenol(m&p Cresol)
NO
ug/L
10.0
1 10/14/16 17:00 10/17/1611:19
Naphthalene
NO
ug/L
5.0
1 1011411617:00 10117/1611:19 91-20-3
Nitrobenzene
ND
ug1L
5.0
1 10/1411617:00 1011711611:19 98.95-3
2-Nitrophenol
NO
ug/L
5.0
1 10/1411617:00 10117/1611:19 88.75.5
4-Nitrophenol
NO
uglL
50.0
1 10/14/1617:00 10/1711611:19 100.02-7
N-Nitrosodimethylamine
NO
ug/L'
5,0
1 10/14/1617:00 10/1711611:19 62-75.9
N-Nitroso-di-n-propylamine
NO
ug/L
5.0
1 1011411617:DD 1011711611:19 621-64-7
N-Nitrosodiphenylamine
ND
ug/L
10.0
1 10114/1617:00 10/1711611:19 M30.6
REPORT OF LABORATORY ANALYSIS
This report
shag not be reproduced, except
In Pull,
Date: 1011712016 04'29 PM
without the written
consent or pace Analytical
Services, LLC, Page 13 of 42

• J
aceAna
10cal
www.petefebseore
ANALYTICAL RESULTS
Project: J16100360
Pace Analytical Services, LLC
9800KinceyAve. Suite 100
Huntensville, NC 28078
[phone]
Pace Project No.: 92316133
Sample: 2016033236 Lab ID: 92316133001 Collected; - 1011311616.20 Received: 10/14/1614,.00 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
625 MSSV Analytical Method: EPA625 Preparation Method: EPA 625
2,2'-Oxybis(1-chloropropane)
NO
ug/L
5,0
1
1011411617:00 10/1711611:19
108-60.1
Pentachlorophenol
NO
uglL
1010
1
1011411617;00 1011711611:19
87.86-5
Phenanthrene
NO
ug/L
5.0
1
1011411617:00 1011711611:19
85-01-8
Phenol
ND
uglL
5.0
1
10/1411617:00 10117/1611:19
Pyrene
NO
ug/L
5.0
1
1011411617:00 10/1711611:19
129.00.0
2,4,6 -Trichlorophenol
NO
ug/L
10.0
1
10/14/16 17:00 10/17116 11:19
88-06-2
Surrogates
Nitrobenzene-d5(S)
65
%
10-120
1
10114/16 17:00 10/17/16 11:19
4165-50.0
2-Fluorobiphenyl (S)
56
%
15.120
1
10114/1617:00 1011711611:19
321.60.6
Terphenyl-dl4 (S)
77
%
11-131
1
10114/1617:00 10117116 1119
1718.51-0
Phenol -d6 (S)
23
%
10-120
1
10/14/16 17:00 10/17116 11:19
13127-88-3
2-Fluorophenol(S)
33
%
10-120
1
10/14/16 17;00 10/17116 1119
367-12-4
2,4,6-Tribromophenol(S)
66
%
10-137
1
10/14/16 17;00 10117/16 11:19
118-79-6
624 Volatile Organics
Analytical Method:
EPA 624
Acrolein
NO
ug/L
5.0
1
10/15/16 23:31
107-02.8
Acrylonitrile
NO
ug/L
50.0
1
10/15/16 23:31
107-13-1
Benzene
NO
ug►L
2.0
1
10/15/16 23:31
71-43-2
Bromodichloromethane
NO
uglL
2.0
1
10/15116 23:31
75-27.4
Bromoform
ND
ug/L
2.0
1
10115/16 23:31
75:25-2
Bromomethane
ND
ug/L
2.0
1
10115/16 23:31
74-83-9
Carbon tetrachloride
ND
ug/L
2.0
1
10/15116 23:31
56-23-5
Chlorobenzene
ND
ug/L
2.0
1
10115/16 23:31
108-90-7
Chloroethane
ND
ug/L
2.0
1
10/15/16 23:31
75-00-3
2-Chloroethylvinyt ether
NO
ug/L
5.0
1
10115116 23:31
110-75-8 c2
Chloroform
ND
uglL
2.0
1
10/15/16 23:31
67-66-3
Chloromethane
NO
uglL
2.0
1
10/15/16 23:31
74-87-3
Dibromochloromethane
ND
ug/L
2.0
1
10/15116 23:31
124-48-1
1,2 -Dichlorobenzene
NO
ug/L
2.0
1
10/15116 23:31
95-50-1
1,"Ichlorobenzene
ND
ug/L
2.0
1
10/1511623:31
541-73-1
1,4 -Dichlorobenzene
ND
ug/L
2.0
1
10/1511623:31
10646-7
11-131chloroethane
ND
ug/L
2.0
1
10/1511523:31
75.34.3
1,2-Dichloroethane
NO
ug/L
2.0
1
10/1511623:31
107-06.2 '
1,1-Dichloroelhene
NO
ug/L
2.0
1
10/15/1623:31
75.35.4
trans-1,2-Dichloroethene
NO
ug/L
2.0
1
10/15/1623:31
156.60.5
1,2-Dichloropropane
ND
ug/L
2.0
1
10/15/16 23131
78-87-5
cis-1,3-Dichlompropene
ND
ug/L
2.0
1
10115/16 23,31
10061-01-5
trans-1,3-Dichlompropene
NO
ug/L
2.0
1
10/15116 23:31
10061-02-6
Ethylbeazene
ND
uglL
2.0
1
10/15/16 23:31
100-41-4
Methylene Chloride
ND
ug/L
2.0
1
10115/16 23:31
75-09-2
1,1,2,2 -Tetrachloroethane
ND
ug/L
2.0
1
10115/16 2331
79-34-5
Tetrdchloraelhene
NO
ug/L
2.0
1
10115116 23:31
127-18-4
Toluene
NO
ug/L
2.0
1
10/15116 23:31
108.88-3
1,2,4-Trichlorobenzene
NO
ug/L
2.0
1
10/15/16 23:31
120-82-1
1,1,1 -Trichloroethane
NO
ug/L
2.0
1
10/15116 23:31
71-55-6
1,1,2 -Trichloroethane
NO
ug/L
2,0
1
10/15/16 23:31
79.00-5
Trichloroethene
NO
ug/L
2.0
1
10/15/16 23:31
79-01-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except In full,
Date: 1011712016 04:29 PM without the written consent of Pace Analytical Services. I.I.C. Page 14 of 42

.y
aceAnalytical
f wwwpaceiaba.com
P
t
ANALYTICAL RESULTS
Project. J16100360
Pace Project No.: 92316133
Pace Anstylical Services, LLC
9800 Kincey Ave. Suite 100
Huntersvilia, NC 28078
[phone]
Sample: 2016033236
Lab ID: 92316133001
Collected. 10/1311618:20
Received., 10/14/16 14A0 Matrix: Water
Parameters
Results Units
Report Limit
DF
Prepared Analyzed
CAS No. Qual
624 Volatile Organics
Analytical Method. EPA 624
Trichlorofluoromethane
NO ug/L
2.0
1
10115/1623,,31
75-69-4
Vinyl chloride
ND ug1L
2.0
1
10/15/16 23:31
75-01-4
Surrogates
4-Bromofluorobenzene (S)
94 %
70-130
1
10115/16 23.31
460 -OD -4
Toluene -de (S)
104 %
70-130
1
10/15/16 23:31
2037-26-5
1,2-Dichloroethane-d4 (S)
95 %
70.130
1
1011511623:31
17060-07-0
4500CNE Cyanide, Total
Analytical Method: SM 4500 -CN -
Cyanide
ND mg/L
0.0060
1
1011511614:47
57-12-5 M1,R1
Date: 10/17/2016 04:29 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, UC.
Page 15 of 42

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full,
Order # J16100404
Site: Cooling Pond
Collection Date: 16 -Oct -16 10:03 AM
Analyte
Result
Units Qualifiers
RDL
OF
TOTAL CYANIDE - lAnalysis
Per(ormed_by Pace
Laborstorles)
CWSPEN3
EPA 200.8
Vendor Parameter
CWSPEN3
EPA 200.8
101171201619:33
1
Dioxin by EPA 1613 - (Analysis Performed by Pace Laboratories)
10/17/2016 19:33
CWSPEN3
Vendor Parameter
101171201619:33
CWSPEN3
EPA 200.8
1
MERCURY (COLD VAPOR) IN WATER
EPA 200.8
10/17/201619:33
CWSPEN3
Mercury (Hg)
<0.06
opt
0.05
1
TOTAL RECOVERABLE METALS
BY ICP
10/17/2016 19:33
CWSPEN3
Vendor Method
Iron (Fe)
1.52
mg/L
0.01
1
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
1.18
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
1
Chromium (Cr)
1.37
ug/L
1
1
Copper (Cu)
6.99
ug/L
1
1
Lead (Pb)
1.32
ug/L
1
1
Nickel (Ni)
< 1
ug1L
1
1
Selenium (Se)
< 1
ugtL
1
1
Silver (Ag) Low Level
< 0.3
ug/L
0.3
1
Thallium (11) Low Level
< 0.2
ug1L
0.2
1
Zinc (Zn)
5.34
ug/L
5
1
PCBS - (Analysis Performed by Pace Laborstoriesl
Vendor Parameter Complete
SEMIVOLATILES - (Analysis Perlomed by Pace Laboratorles
Vendor Parameter Complete
Sample #: 2016033482
Matrix: NPDES
Page 7 of 55
Method Analysis DateMme Analyst
Vendor Method V_PACE
Vendor Method
V_PACE
EPA 245.1 10/171201611:57 DMFRANC
EPA 200.7 10118/201611:56 MHH7131
EPA 200.8
10/17/201619:33
CWSPEN3
EPA 200.8
10/17/2016 193
CWSPEN3
EPA 200.8
10117/201619:33
CWSPEN3
EPA 200.8
10/17/20161933
CWSPEN3
EPA 200.8
101171201619:33
CWSPEN3
EPA 200.8
10/17/2016 19:33
CWSPEN3
EPA 200.8
101171201619:33
CWSPEN3
EPA 200.8
10117/201619:33
CWSPEN3
EPA 200.8
10/17/201619:33
CWSPEN3
EPA 200.8
10/17/201619:33
CWSPEN3
EPA 200.8
10/17/2016 19:33
CWSPEN3
EPA 200.8
10/17/2016 19:33
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE

ceAnalyiical
o4wvtpace4abs com
ANALYTICAL RESULTS
Project: J16100404
Pace Analytical Services, LLC
085"w6we, Suite 100
Huntersvlife, NC 28078
[phone]
Pace Project No.: 92316201
Sample: 2016033482 Lab ID: 92316201002 Collected. 10/1611610:03 Received: 1011711608:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
608 GCS Pesticides and PCBs Analytical Method: EPA 508 Preparation Method: EPA 3510
Aldrin
NO
ug/L
0.050
1
1011911610:24
10/1911613:51
309.00.2
alpha -BHC
NO
ug/L
0.050
1
10119/1610:24
10/1911613:51
319-84-6
beta -BHC
NO
ug/L
0.050
1
1011911610:24
10119/1613:51
319-85-7
delta -BHC
NO
ug/L
0.050
1
10/19/1610:24
10119/1613:51
319-86.8
gamma -BHC (Lindane)
NO
ug/L
0.050
1
10/19/1610:24
10/19/1613.51
58-89-9
Chlordane (Technical)
NO
ug/L
0.50
1
10/1911510:24
10119/16 13:51
57-74-9
4,4' -DDD
NO
ug/L
0.050
1
1011911510:24
10/1911613:51
72-54-8
4,4' -DDE
NO
ug/L
0.050
1
10119/1610:24
1011911613;51
72-55.9
4,4%DDT
NO
ug/L
0.050
1
1011911610:24
1011911613;51
50-29-3
Dlelddn
NO
ug/L
0.050
1
1011911610:24
10/1911613:51
60-57-1
Endosultan I
NO
ug/L
0.050
1
1011911610:24
10/19/16 13:51
959-98-8
Endosultan II
NO
ug1L
0.050
1
10/19/15 10:24
10119116 13:51
33213-65 9
Endosulfan sulfate
NO
ug/L
0.050
1
10119116 10:24
10/19/16 13:51
1031-07-8
Endrin
ND
ug/L
0.050
1
10/1911610:24
10119/1613:51
72-20.8
Endrin aldehyde
NO
ug1L
0.050
1
10/19116 10:24
10/19/16 13:51
7421-93-4
Heptachlor
NO
ug/L
0.050
1
1011911610:24
1011911613:51
76414-8 L3
Heptachlor epoxide
NO
ug/L
0.050
1
1011911610:24
10/19/16 13:51
1024.57.3
PCB -1016 (Arocior 1016)
NO
ug/L
0.50
1
1011911610:24
10/19/16 13:51
12674-11.2
PCB -1221 (Arocior 1221)
NO
ug/L
0.50
1
10/19/16 10:24
10119/1613:51
11104-28-2
PCB -1232 (Arocior 1232)
NO
ug/L
0.50
1
10/19/16 10:24
10119/1613;51
11141-16-5
PCB -1242 (Arocior 1242)
NO
ug/L
0.50
1
10/19/16 10:24
10/19/16 13:51
53469-21-9
PCB -1248 (Arocior 1248)
NO
ug/L
0.50
1
10/19/16 10:24
10119118 13:51
12672-29-6
PCB -1254 (Arocior 1254)
NO
ug/L
0.50
1
10/19/16 10:24
10/19116 13:51
11097-69-1
PCB -1260 (Arocior 1260)
NO
ug/L
0.50
1
10/1911610:24
10119/16 13:51
11096.82-5
Toxaphene
NO
ug/L
0.50
1
10119/1610:24
1011911613:51
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
91
%
20-110
1
10/19/16 10:24
10/19/16 13:51
677-09-8
Decachlorobiphenyl (S)
29
%
20-138
1
10/1911610:24
10/19/16 13:51
2051-24-3
625 MSSV
Analytical Method: EPA 625 Preparation Method. EPA 625
Acenaphthene
NO
ug/L
5.0
1
10/17/16 12:01
10/18/16 12:16
83-32-9
Acenaphthylene
NO
ug/L
5.0
1
10/17/16 12:01
10/18/16 12:16
208-96.8
Anthracene
NO
ug/L
5.0
1
10117/16 12:01
10/18/16 12:16
120-12-7
Benzidine
NO
ug/L
50.0
1
1011711612:01
10/18/1612:16
92-87-5 L2
Benzo(a)anthracene
NO
ug/L
5.0
1
10/17/1612:01
10/18/1612:16
56-55-3
Benzo(a)pyrene
NO
uglL
5.0
1
10/17/16 12:01
10/18/16 12:16
50-32.8
Benzo(b)tiuoranlhene
NO
ug/L
5.0
1
10/17/1612:01
10/18/1612:16
205-99-2
Benzo(g,h,i)perylene
NO
ug/L
5.0
1
10/17/1612:01
10/1811612:16
191-24-2
Benzo(k)fluorenthene
NO
ug/L
5.0
1
10117/1612:01
1011811612:16
207-08-9
4-Bromophenylphenyl ether
NO
ug/L
5.0
1
10/17116 12.01
10/1811612:16
101-55-3
Bulylbenzyiphtholate
NO
ug/L
5.0
1
1011711612:01
10118/1612:16
85-68-7
4-Chloro-3-methyiphenol
NO
ug/L
5.0
1
10117/1612:01
10/18/1612:16
59-50-7
bis(2-Chloroelhoxy)methane
NO
ug/L
10.0
1
10/1711612:01
1011811612:16
111-91-1
bis(2-Chloroethyi) ether
NO
ug/L
5.0
1
1011711612:01
10/18/16 12:16
111-44-4
2-Chloronaphthalene
NO
ug/L
5.0
1
1011711612:01
1011811612:16
91-58-7
2 -Chlorophenol
NO
ug/L
5.0
1
10/17/16 12:01
10/18/16 12:16
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
5.0
1
10117/1612:01
10/18/1612:16
7005-72-3
REPORT
OF LABORATORY
ANALYSIS
This report shell not be reproduced. except
In full.
Date: 10/2012016 07:43 AM
without the written consent of Pace Analytical Services, LLC,
Page 11 of 27

Y
aceAnalyticat
1 wwwpacebbseom
r
Project: J16100404
Pace Project No.: 92316201
Sample: 2016033482
Parameters
625 MSSV
Chrysene
Dibenz(a,h)anthracene
3,3'-Dichiorobenzidine
2.4-Dichlorophenol
Diethylphthalate
2.4 -Dimethylphenol
Dimethylphthalate
Di-n-butylphthalate
4,6-Dirtitro-2-methylphenot
2,4-Dinitrophenol
2,4Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
1,2-Diphenylhydrazine
bis(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1, 3 -butadiene
Hexachlorobenzene
Hexachiorocyclopentadiene
Hexachioroethane
Indeno(1,2,3-cd)pyrene
Isophorone
384-Methylphenol(m&p Cresol)
Naphthalene
Nitrobenzene
2-NNrophenol
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitroso-dl-n-propylamine
N-Nitrosodlphenylamine
2,2'-Oxybis(1-chioropropane)
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
2,4,6 -Trichlorophenol
Surrogates
Nitrobenzene -d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol -d6 (S)
2-Fluorophenot (S)
2,4,6-Tribromophenol (S)
4500CNE Cyanide, Total
Cyanide
Pace Analytical Services, LLC
Iylomwfte. Suite 100
Huntersvig'e,NC28078
[phone]
ANALYTICAL RESULTS
LabID: 92316201002 Collected, 1011611610;03 Received: 101171160&.30 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Analytical Method: EPA625 Preparation Method:. EPA625
NO
ug/L
5.0
1
10/17/1612:01
1011811612:16 218.01-9
NO
ug/L
510
1
10/17/16 12:01
10/18/16 12:16 53.70.3
NO
ug/L
25.0
1
10117/1612:01
10/1811612:16 91.94-1
NO
ug/L
5.0
1
1011711612:01
1011811612:16 120-83-2
NO
ug/L
5.0
1
1011711612,01
1011811612:16 84-66-2
NO
ug/L
10.0
1
1011711612;01
1011811612:16 105-67-9
ND
ug/L
5.0
1
1011711612:01
101181161216 131-11-3
NO
ug/L
5.0
1
1011711612:01
10116/1612:16 84-74-2
NO
ug/L
20.0
1
1011711612:01
1011811612;16 534.52-1
NO
ug/L
50.0
1
1011711612:01
10/1811612'16 5128-5
NO
ug/L
5.0
1
1011711612;01
1011811612,16 121-14-2
NO
ug/L
5,0
1
1011711612:01
1011811612.16 606-20-2
NO
ug/L
5.0
1
10/1711612.01
1011811612:16 117.84.0
NO
ug/L
5.0
1
1011711612:01
1011811612:16 122.66.7
NO
uglL
5A
1
1011711612.01
1011811612,16 117.817
NO
ug/L
5.0
1
10/1711612:01
10/1811612:16 206-440
NO
ug/L
5.0
1
10/17116 12:01
10/18/16 12:16 86-73-7
NO
ug/L
5.0
1
1011711612:01
10/1811612;16 87-68-3
NO
ug/L
510
1
1011711612;01
1011811612:15 118-74.1
NO
uglL
10,0
1
10/1711612:01
1011811612,16 77.47-4
NO
uglL
5,0
1
10117/16 12:01
1011811612;16 67-72-1
NO
ug/L
5,0
1
10/1711612:01
10/1811612:16 193-39.5
NO
ug/L
10,0
1
10/1711612;01
10/1811612:16 78-59-1
NO
ug/L
10,0
1
10/17/1612:01
1011811612:16
NO
ug/L
5,0
1
10/17/1612,01
101181161216 9120-3
NO
ug/L
5,0
1
10/17/1612:01
1011811612:16 98.95.3
NO
ug/L
510
1
10/17/1612:01
10/18/1612:16 88.75.5
NO
ug/L
50,0
1
1011711612:01
10118/1612:16 100-02-7
NO
ug/L
510
1
10/1711612:01
1011811612:16 62-75-9
NO
ug/L
5,0
1
10/1711612:01
10118/1612,16 621-64-7
NO
ug/L
10,0
1
10/17/1612:01
1011811612:16 86-30-6
NO
ug/L
510
1
10/1711612:01
10/1811612:16 108-60-1
NO
ug/L
10.0
1
10/17/16 12:91
10/18/16 1216 87.86-5
NO
uglL
5,0
1
10117/1612:01
1011811612''„16 8541-8
NO
ug/L
5,0
1
10117/1612;91
10/1811612:15
NO
ug/L
5.0
1
1011711612.01
10/18/1612.•16 129.00.0
NO
ug/L
10.0
1
10117/1612:01
10/1811612:16 88-06-2
73
%
10-120
1
10/17/16 12,01
10/18/161216 4165-6D-0
62
%
15.120
1
10/17/1612:01
1011811612:16 321.60.8
82
%
11-131
1
1011711612-01
10/18/16 12'16 1718-51-0
29
%
10-120
1
1D/17/1612:01
1011811612;16 13127.88.3
39
%
10-120
1
10/1711612;01
1011811612:16 367-12-4
85
%
10-137
1
1011711612:01
1011811612,16 118-79-6
Analytical Method: SM 4500-CN•E
NO mglL 0,0080 1
REPORT OF LABORATORY ANALYSIS
1011811612:04 57-12.5
This report shall not be reproduced, except in full,
Date:1012012016 07.43 AM wtthoutthe written consent of Pace Analytical Services, LLC- Page 12 of 27

Certificate of Laboratory Analysis Page 7 of 62
This report shall not be reproduced, except in lull.
Order # A 6100443
Site: Coating Pond Sample #: 2016033541
Collection Date: 17-0ct-16 3;37 PM Matrix: NPDES
Analyte
Result
Units Qualifiers
RDE
DF
TOTAL CYANIDE - (Analysis
Performed by Pace
Laboratories)
CWSPEN3
EPA 200.8
Vendor Parameter
CWSPEN3
EPA 200.8
10/18/2016 17:13
1
Dioxin by EPA 1613 - (Analysis Performed by Pace
Laboratories}
CWSPEN3
EPA 200.8
Vendor Parameter
CWSPEN3
EPA 200.8
10/181201617:13
1
MERCUljY (C21.0 VAeQR)
IN WATER
CWSPEN3
EPA 200.8
10118/201617:13
Mercury (Hg)
< 0.05
ug/L
0.05
1
TOTAL RECOVERABLE METALS BY ICP
CWSPEN3
Vendor Method
Iron (Fe)
1.28
mg1L
0.01
1
TOTAL RECOVERABLE METALS
BY ICP -MS
Antimony (Sb)
c 1
ug1t.
1
1
Arsenic (As)
1.22
ug/t.
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd) Low level
40.1
ug/L
0.1
1
Chromium (Cr)
1.04
ugk,
1
1
Copper (Cu)
6.64
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Silver (Ag) Low Level
a 0.3
ug/L
0.3
1
Thallium (TI) Low Level
c 0.2
ug/L
0.2
1
Zinc (Zn)
< 5
ug/L
5
1
PCBS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
SEMIVOLATILES - (Analysis
Performed by Pace
Laboratoriesl
Vendor Parameter
Complete
VOLATILES - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Method Analysis DateMme Analyst
Vendor Method V_PACE
Vendor Method V PACE
EPA 245.1 10118/201611:23 DMFRANC
EPA 200.7 10/18/2016 15:31 MHH7131
EPA 200.8
101181201617:13
CWSPEN3
EPA 200.8
10/18/201617:13
CWSPEN3
EPA 200.8
10/18/201617:13
CWSPEN3
EPA 200.8
10/18/2016 17:13
CWSPEN3
EPA 200.8
10/18/2016 17:13
CWSPEN3
EPA 200.8
10/18/2016 17:13
CWSPEN3
EPA 200.8
10/18/2016 17:13
CWSPEN3
EPA 200.8
10/181201617:13
CWSPEN3
EPA 200.8
10/181201617:13
CWSPEN3
EPA 200.8
10118/201617:13
CWSPEN3
EPA 200.8
101181201617:13
CWSPEN3
EPA 200.8
101181201617:13
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V.,PACE
Vendor Method
V—PACE

aceAna1j ca!
www.pace/sDsmm
ANALYTICAL RESULTS
Project: J1610D443
Pace Analytical Services, LLC
1926 CM12ra. Suite 100
HuntersviEte, NC 28078
[phone]
Pace Project No.: 92316307
Sample: 2016033541 Lab ID: 92316307002 Collected: 1011711615:37 Received: 1011811609;19 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
608 GCS Pesticides and PCBs Analytical Method; EPA 608 Preparation Method: EPA 3510
Aldrin
NO
ug/L
0.050
1
10/1911610:24 1011911618:03 309.00-2
alpha -BHC
NO
ug/L
0.050
1
1011911610:24
10/1911618:03 3194M-6
beta -BHC
NO
ug/L
0.050
1
10119/1610:24
10/1911618:03 319-85-7
delta -BHC
NO
ug/L
0.050
1
10/1911610:24
10/1911618:03 319-86-8
gamma -BHC (Lindane)
NO
ug/L
0.050
1
10119116 10:24
1011911618:03 58-89-9
Chlordane (Technical)
NO
ug/L
0.50
1
10119/16 10:24
10/19/16 18:03 57-74-9
4,4' -DDD
ND
ug/L
0.050
1
1011911610:24
1011911618:03 72-54-8
4,4' -DDE
NO
ug/L
0.050
1
10/1911610:24
1011911618;03 72.55.9
4,4' -DOT
NO
ug/L
0.050
1
10/19/1610:24
10/19/1618:03 50.29.3
Dieldrin
NO
ug/L
0.050
1
10/19/1610:24
10/19/1618:03 60.57-1
Endosulfan I
NO
uglL
0.050
1
10/19116 1024
10119/1618:03 959.98-8
Endosulfan II
NO
ug/L
0.050
1
10/19116 10.24
10/19116 18:03 33213-65-9
Endosulfan sulfate
NO
ug/L
0.050
1
10/19/16 1024
10/19/16 18:03 1031-07-8
Endrin
NO
ug/L
0.050
1
1011911610:24
1011911618:03 72-20-8
Endrin aldehyde
NO
ug/L
M050
1
10119/1610:24
10/19/16 18:03 7421-934
Heptachlor
NO
ug/L
0,050
1
10/19/1610:24
10119/1618:03 76-44-8 L3
Heptachlor epoxide
NO
ug/L
0.050
1
10/1911610:24
1011911618:03 1024-57-3
PCB -1016 (Aroclor 1016)
NO
ug/L
0.50
1
1011911610;24
1011911618:03 12674-11.2
PCB -1221 (Aroclor 1221)
NO
ug/L
0.50
1
10/1911610:24
10/19/16 18:03 11104-28.2
PCB -1232 (Aroclor 1232)
NO
ug/L
0.50
1
10/1911610:24
10/19116 18:03 11141-16.5
PCB -1242 (Aroclor 1242)
ND
uglL
0.50
1
10/1911610:24
10119/16 18:03 53469-21-9
PCB -1248 (Aroclor 1248)
NO
ug/L
0.50
1
10/1911610:24
10/19116 18:03 12672-29-6
PCB -1254 (Aroclor 1254)
NO
ug/L
0.50
1
10/19/16 10:24
10/19116 18:03 11097-69-1
PCB -1260 (Aroclor 1260)
ND
ug/L
0.50
1
10119/16 10:24
10/19116 18:03 11096-82-5
Toxaphene
ND
ug/L
0150
1
10/19/1610:24
10119/1618:03 8001-35-2
Surrogates
-
Tetrachloro-rn-xylene(S)
65
%
20-110
1
ID119/1610:24
10/1911618M3 877-09-8
Decachlorobiphenyl (S)
24
%
20.138
1
10119116 10:24
10/1911618:03 2051-24-3
625 MSSV
Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene
NO
ug/L
5.0
1
10118/1611:00
10/1911612:38 83.32.9
Acenaphthylene
ND
ug/L
5,0
1
10118/1611:00
1011911612:38 208-96.8
Anthracene
ND
ug/L
5.0
1
1011811611:00
1011911612:38 120-12-7
Benzidine
ND
ug/L
50.0
1
10/18/1611:00
10/19/1612:38 92-87-5 L2
Benzo(a)anthracene
ND
ug/L
5.0
1
1011811611:00
10119/1612:38 56-55-3
Benzo(a)pyrene
ND
ug/L
5,0
1
10118/1611:00
1011911612:38 50-32-8
Benzo(b)Huoranthene
ND
ug/L
5.0
1
10/18/1611:00
1011911612:38 205-99-2
Benzo(g,h,l)perylene
ND
ug/L
5.0
1
1011811611:00
1011911612:36 191-24-2
Benzo(k)iluoranthene
ND
ug/L
5.0
1
10118/1611:00
1011911612:38 207-08-9
4-Bromophenytphenyl ether
ND
ug/L
510
1
10/18/16 11:00
10119/1612:38 101-55-3
Butylbenzylphthalate
NO
ug/L
5.0
1
10/18/1611:00
1011911612:38 85.68-7
4-Chloro-3-methylphenol
ND
ug/L
5.0
1
10/18/16 III=
10119/1612:38 59.50.7
bls(2-Chlorcelhoxy)methane
NO
ug/L
10.0
1
10118/1611:00
1011911512:38 111-91-1
bis(2-Chtomethyl) ether
NO
ug/L
5.0
1
10/18/16 11;00
1011911612:38 111-44.4
2-Chloronaphthatene
NO
ug/L
5.0
1
10118/1611:00
10/19/1612:38 91-58-7
2 -Chlorophenol
NO
ug/L
5.0
1
10118/1611:00
10119/1612:38 95.57-8
4-Chlorophenylpheny) ether
ND
ug/L
5.0
1
10/18/1611:00
10/19/1612:38 7005-72-3
REPORT
OF LABORATORY
ANALYSIS
This report shall not be reproduced, except
in full,
Date: 10/20/2016 08:58 AM
without the written consent of Pace /analytical Services, I.I.C.
Page 13 of 34

S
acoAnalyiical
wwrnxpaceraba.eom
ANALYTICAL RESULTS
Project: J161DO443
Pace Project No.: 92316307
Pace Analytical services, LLC
suite'ioo
Huntersville, NC 28078
[phone]
Sample: 2016033541 Lab ID: 92316307002 Collected: 1011711615:37 Received: 10/18/16 09:19 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
Chrysene
ND
ugiL
5.0
1
1011811611:00
1011911612:38 218-01-9
Dibenz(a,h)anthracene
ND
ugiL
5.0
1
1011811611:00
1011911612:38 53-70-3
3,31-Dichlorobenzidine
ND
ug/L
25.0
1
1011811611:00
1011911612:38 91-94-1
2,4-Dichlorophenol
ND
ug/L
5.0
1
1011811611:00
1011911612:38 120.83-2
Diethylphthalate
ND
ug/L
5.0
1
10/18/1611:00
1011911612:38 84-66.2
2,4 -Dimethylphenol
ND
ug/L
10.0
1
1011811611:00
1011911612:38 105-67-9
Dimethylphthalate
ND
ug/L
5.0
1
1011811611:00
1011911612:38 131-11-3
Di-n-bu(ylphthalate
ND
ug/L
5.0
1
1011811611:00
10119/1612:38 84-74-2
4,6-Dinitro-2-methylphenol
ND
ug/L
20.0
1
1011811611:00
1011911612:38 534-52-1
2,4-Dinitrophenoi
ND
ug/L
50.0
1
1011811611:00
1011911612:38 51-28-5
2,4-Dinitrotoluene
ND
ug/L
5.0
1
10118/1611:00
1011911612:38 121-14-2
2,6-Dinitrotoluene
NO
ug/L
5.0
1
1011811611:00
1011911612:38 606-20.2
Di-n-octylphthalate
ND
ug/L
5.0
1
10118/1611:00
1011911612:38 117-84-D
1,2-Diphenylhydrazine
ND
ug/L
5.0
1
1011811611:00
1011911612:38 122-66-7
bis(2-Ethyihexyl)phthalate
ND
ug/L
5.0
1
10118/16 11:00
10/19/16 12:38 117-81-7
Fluoranthene
ND
ug/L
5.0
1
1011811611:00
10119/1612:38 206.44-0
Fluorene
ND
ug/L
5.0
1
10118/1611:00
10119/1612:38 86.73-7
Hexachloro-1,3-butadiene
ND
ug/L
5.0
1
1011811611:00
1011911612:38 87.88-3
Hexachiorobenzene
ND
ug/L
5.0
1
1011811611:00
1011911612:38 118-74-1
Hexachlorocyclopentadiene
ND
ug/L
10.0
1
1011811611:00
1011911612:38 77-47-4
Hexachloroethane
ND
ug/L
5.0
1
1011811611:00
10/19/1612.38 67-72-1
Indeno(1,2,3-cd)pyrene
ND
ug/L
5.0
1
10118/1611:00
1011911612:38 193-39-5
Isophorone
ND
ug/L
10.0
1
1011811611:00
1011911612:38 76.59-1
384-Methylphenol(m8p Cresol)
ND
ug/L
10.0
1
10/1811611:00
1011911612:38
Naphthalene
ND
ug/L
5.0
1
10118/1611:00
10/1911612:38 91-20-3
Nltrobenzene
ND
ug/L
5,0
1
1011811611:00
1011911612,38 98-95-3
2-Nilrophenol
ND
ug/L
5.0
1
1011811611:00
10119/1612:38 68-75-5
4-Nitrophenol
ND
ug/L
50.0
1
1011811611:00
1011911612:38 100-02-7
N-Nitrosodimethylamine
ND
ug/L
5.0
1
1011811611:00
10/1911612,38 62-75-9
N-Nitroso-di-n-propylamine
ND
ug/L
5,0
1
1011811611:00
10/1911612:38 621-64-7
N-Nitrosodiphenylamine
ND
ug/L
10,0
1
10/18/1611:00
10119/1612,38 86-30-6
2,2'-Oxybis(1-chloropropane)
ND
ug/L
5.0
1
10/1811611:00
10/19/1612:36 108.60-1
Pentachlorophenol
ND
ug/L
10.0
1
10/18/1611:00
10119/1612:38 87-86.5
Phenanthrene
ND
ug/L
5.0
1
10/1811611:00
10/1911612:38 85-01-8
Phenol
ND
ug/L
5.0
1
10/18/1611:00
1011911612:38
Pyrene
ND
ug/L
5.0
1
10/1811611:00
1011911612;38 129-00-0
2,4,6 -Trichlorophenol
ND
ug/L
10.0
1
10118/1611:00
1011911612:38 88-06-2
Surrogates
Nitrobenzene -d5 (S)
76
°%
10.120
1
10/18/1611:00
101191161Z38 4165-60-0
2-Fluorobiphenyl (S)
61
°%
15420
1
1011811611:00
1011911612:38 321-60.8
Terphenyl-dl4 (S)
81
°%
11-131
1
1011811611:00
10/1911612:38 1718-51-0
Phenol -d6 (5)
25
°%
10-120
1
10118116 11:00
10119/1612:38 13127-88.3
2-Fluorophenol (S)
37
°%
10.120
1
1011811611:00
10119/1612:38 367-12-4
2,4,6-Tribromophenot (S)
74
°%
10-137
1
10118/16 11:00
10/19/16 12:38 118-79.6
624 Volatile Organics
Analytical Method: EPA 624
Acrolein
ND
ugiL
5.0
1
10118/16 20:29 107-02-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full.
Date: 10120/2016 08:58 AM without the written consent of Pere Analytical Services, LLC. Page 14 of 34

„ ar
ceAnalytical
w+►�tPnee�ebsmm
t
ANALYTICAL RESULTS
Pace Analytical Services, LLC
ig18%�1�oLsuite 100
HunteravAe, NC 2BD78
[phone]
Project: J16100443
Pace Project No.: 92316307
Sample: 2016033541 Lab I0: 92316307002 Collected;- 1011711615,37 Received: 10/18/16 09,19 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
624 Volatile Organics Analytical Method: EPA 624
Acrylonitrile
ND
ug/L
5010
1
10118/16 20:29 107-13-1
Benzene
ND
ug1L
2.0
1
10118/16 20:29 71-43-2
Bromodichloromethane
ND
ug/L
2.0
1
10/18/16 20:29 75-27-4
Bromoform
ND
ug/L
10
1
10/18/16 20:29 75-25.2
Bromomethane
ND
ug/1-
2.0
1
10/18115 20:29 74-83-9
Carbon tetrachloride
ND
ug/L
2.0
1
10118116.20:29 56-23-5
Chlorobenzene
ND
ug/L
2.0
1
10/18/16 20:29 108-90.7
Chloroethane
ND
ug/L
2.0
1
10/18/16 2029 75-00-3
2-Chloroethylvinyl ether
ND
ug/L
5.0
1
10/18/16 20:29 110-75-8 c2
Chloroform
ND
ug/L
2.0
1
10/18/16 20:29 67-66-3
Chloromethane
ND
ug/L
2.0
1
10/18116 20:29 74-87.3
Dibromochloromethane
ND
ug/L
2.0
1
10118/16 20:29 124-48-1
1,2 -Dichlorobenzene
ND
ug/L
2.0
1
10118/16 20:29 95-50-1
1,3 -Dichlorobenzene
ND
ug/L
2.0
1
10/18/16 20:29 541-73-1
1,4 -Dichlorobenzene
ND
ug/L
2.0
1
10/18/16 20:29 10646-7
1,1-Dichloroethane
ND
ug/L
2.0
1
10/18/16 20:29 75-34-3
1,2-Dichloroethane
ND
ug/L
2.0
1
10118116 20:29 107-06.2
1,1-Dichloroethene
ND
ug/L
2,0
1
10/18116 20:29 75-35.4
trans-1,2-Dichloroethene
ND
ug/L
2,0
1
10/1811620:29 156-60-5
1,2-Dichloropropene
ND
ug1L
2.0
1
10/18/16 20:29 78-87-5
cis-1,3-DicNoropropene
ND
ug/L
2.0
1
10/18/16 20:29 10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
2A
1
10/18/16 20:29 10061-02-6
Ethyibenzene
ND
ug/L
2.0
1
10/18/16 20:29 100414
Methylene Chloride
ND
ug/L
2.0
1
10/18/16 20:29 75-09-2
1,1,2,2 -Tetrachloroethane
ND
ug/L
2,0
1
10118/1620:29 70-34-5
Tetrachloroethene
ND
ug/L
2.0
1
10118116 20:29 127-18.4
Toluene
ND
ug/L
2.0
1
10/18/16 20:29 108-88.3
1,2,4-Tdchlorobenzene
ND
ug/L
2.0
1
1011811620:29 120-82-1
1,1,1 -Trichloroethane
ND
ug/L
2,0
1
10/1811620:29 71-55-6
1,1,2-Trichicroethane
ND
ug/L
2,0
1
10118/1620:29 79.00-5
Trichloroethene
ND
ug/L
2.0
1
10/18/16 2M29 79.01.6
Trichlorofluoromethane
ND
ug/L
2,0
1
10/18/16 20:29 75-69-4
Vinyl chloride
ND
ug/L
2.0
1
10/18/16 20:29 75-01-4
Surrogates
4-Bromofluorobenzene (S)
91
%
70-130
1
10/18/16 20:29 460-00.4
Toluene -d8 (S)
108
%
70-130
1
10/18/16 20:29 2037.26-5
1,2-Dichloroethane-d4(S)
95
%
70-130
1
10/18/1520:29 17060-07-0
450OCNE Cyanide, Total
Analytical Method: SM 4500 -CN -E
Cyanide
ND
mg/L
0.0080
1
10/19/1612:00 57-12-5
Date: 10/20/2016 08:58 AM
REPORT OF LABORATORY ANALYSIS
This report shag not be reproduced, except In f A,
without the written consent of Pace Analytics) Services, I.I.C.
Page 15 of 34

Duke Energy Progress, Inc. H. F. Lee Energy Complex
NPDES Permit Number NCO03417
Attachment
0 0.2 0.4 0.6 0.8 1 mi
USGS Northwest Goldsboro (NQ Quadrangle
10/25/2016