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HomeMy WebLinkAbout2016-05-13 Roxboro Hutson Report FinalGEO-HYDRO, INC Consulting in Geology and Hydrogeology 1928 E. 14th Avenue Denver, Colorado 80206 (303)322-3171 EXPERT REPORT OF MARK A. HUTSON, PG Roxboro Steam Electric Plant S emora, NC Prepared for: Southern Environmental Law Center 601 West Rosemary Street Suite 220 Chapel Hill, NC 27516-2356 May 2016 GEO-HYDRO, INC 1. Summary of Opinions Formed Based upon my review of the available information I have formed the following opinions on closure of the coal ash basins at the Roxboro Steam Electric Plant (Roxboro). 1. Coal ash stored in the Roxboro ash basins is the source of contamination detected in groundwater. 2. Capping coal ash located within the Roxboro ash basins will not protect groundwater quality downgradient of the basins. 3. The groundwater flow and transport model does not reflect real-world conditions. 4. Monitored Natural Attenuation (MNA) is not an acceptable groundwater remediation strategy at Roxboro. 5. Capping coal ash located within the Roxboro ash basins will not be protective of surface water quality. 6. Removal of the coal ash will remove the source and reduce the concentration and extent of groundwater contaminants. 7. The coal combustion residual impoundment risk classification proposed by the North Carolina Department of Environmental Quality (NCDEQ) improperly minimizes protection of environmental quality. The background and rationale behind each of these opinions are described in this report. GEO-HYDRO, INC 2. Introduction Duke Energy (Duke) reportedly stores approximately 33,390,000 tons of coal ash in various areas around the Roxboro facility, including ash stored in two unlined ash basins (East and West), lined and unlined landfills, and other ash filled areas'. An additional poorly identified and uncharacterized Unnamed Eastern Extension impoundment was recently reported to NCDEQ. The location and volume of additional coal ash contained in the Unnamed Eastern Extension impoundment was not identified in any of the documents reviewed. Pollution caused by the coal ash at this site is currently the subject of an enforcement action brought by the NCDEQ. Organizations represented by the Southern Environmental Law Center are also parties to this litigation. North Carolina General Assembly Session Law 2014-122, the Coal Ash Management Act (LAMA) of 2014, required the owner of coal combustion waste surface impoundments to conduct groundwater monitoring, assessment and remedial activities at coal ash basins across the state, as necessary. The owner of the coal ash surface impoundments was required to submit a Groundwater Assessment Plan (GAP) to NCDEQ by December 31, 2014. Comprehensive Site Assessment (CSA) reports that reported the results of site characterization activities were required to be submitted within 180 days of approval of the GAP. Information developed under the CSA provided the data to be used to prepare Corrective Action Plans (CAP) that were to be submitted to NCDEQ within 90 days of submittal of the CSA. An agreement between Duke Energy and NCDEQ resulted in breaking the CAP into Parts I and 2. As of this date only the CAP Part I has been produced for the Roxboro site. Further, CAMA specifies that any impoundments classified by NCDEQ as high-risk be closed no later than December 31, 2019 by dewatering the waste and either, a) excavating the ash and converting the impoundment to an industrial landfill, or b) excavating and transporting the waste off- site for disposal in an appropriately licensed landfill. Intermediate -risk impoundments are required to be closed similarly to high-risk impoundments, but under a relaxed closure deadline of December 31, 2024. Impoundments classified as low-risk by NCDEQ must be closed by December 31, 2029 either similarly to the high and intermediate -risk sites, or by dewatering to the extent practicable and capping the waste in place. In January 2016 the NCDEQ issued Draft Proposed Risk Classifications (NCDEQ, 2016) for 10 ash impoundment sites, including Roxboro. NCDEQ assigned separate proposed risk classifications for the West, East, and Unnamed Eastern Extension ash ponds. The East Ash Basin (EAB) was rated low to intermediate risk and the West Ash Basin (WAB) was rated low risk, thus allowing for closure of these impoundments by capping waste in place. The Unnamed Eastern Extension (UEE) ' SynTerra, 2015a 2 GEO-HYDRO, INC impoundment was rated intermediate risk pending further assessment. On behalf of the Southern Environmental Law Center, I have reviewed the Groundwater Assessment Plan (SynTerra, 2014), Comprehensive Site Assessment (SynTerra, 2015a), the Corrective Action Plan Part 1 (SynTerra, 2015b), the Corrective Action Plan Part 2 (SynTerra, 2016), the Draft Proposed Risk Classifications (NCDEQ, 2016), and three National Pollutant Discharge Elimination System (NPDES) discharge monitoring reports (DMR's) for Roxboro (Duke Energy, 2014). 1 have also reviewed raw groundwater model input and output files provided by Duke to facilitate understanding of the model that informs the CAP Parts 1 and 2. This report details my opinions regarding: the source of groundwater and surface water pollution at Roxboro, potential remedies for that pollution discussed in the Corrective Action Plan, and the proposed risk classification for the Roxboro site. GEO-HYDRO, INC 3. Qualifications The opinions expressed in this document have been formulated based upon my formal education in geology and over thirty-five years of experience on a wide range of environmental characterization and remediation sites. My education includes B.S. and M.S. degrees in geology from Northern Illinois University and the University of Illinois at Chicago, respectively. I am a registered Professional Geologist (PG) in Kansas, Nebraska, Indiana, and Wisconsin, a Certified Professional Geologist by the American Institute of Professional Geologists, and am currently serving as Past President of the Colorado Ground Water Association. My entire professional career has been focused on regulatory, site characterization, and remediation issues related to waste handling and disposal practices and facilities. I have worked on contaminated sites in over 35 states and the Caribbean. My site characterization and remediation experience includes activities at sites located in a full range of geologic conditions, involving soil and groundwater contamination in both unconsolidated and consolidated geologic media, and a wide range of contaminants. I have served in various technical and managerial roles in conducting all aspects of site characterization and remediation including definition of the nature and extent of contamination, directing human health and ecological risk assessments, conducting feasibility studies for selection of appropriate remedies to meet remediation goals, and implementing remedial strategies. For the last ten years much of my consulting activity has been related to groundwater contamination and permitting issues at coal ash storage and disposal sites. 2 GEO-HYDRO, INC 4. Site Background Site Setting and History The Roxboro plant is a coal-fired electricity -generating facility located near Semora, in Person County North Carolina. Hyco Reservoir borders the Roxboro plant to the north and west. Coal ash generated at the plant has been sluiced to the ash basins and hauled to landfill overlying the ash basins since operations commenced in 1966. The EAB was constructed in 1966 by constructing an earthen dam across two unnamed creeks located southeast of the power station (Figure 1). An unlined landfill was constructed over the top of the sluiced ash in the EAB in the late 1980s and a lined landfill was constructed over the unlined landfill in 20042. The ground surface elevation below the EAB dam was reported to be between 390 and 400 feet mean sea level (MSI) 3. Groundwater elevations in EAB monitoring wells are reported to be between 464 and 469 ft ms14. The difference between the reported ash basin groundwater elevations and the natural ground surface elevations underlying the EAB indicates that from 64 to 79 feet of saturated coal ash is present within the EAB. The WAB was constructed in 1973 by installing a dam across Sargents Creek, located south of the power station. Coal combustion waste was historically sluiced into the WAB. A Flue Gas Desulfurization (FGD) System, including a lined gypsum settling pond was constructed over a portion of the WAB. The WAB currently remains in operation, receiving sluiced bottom ash from the power station and surface waters discharged from the EAB and overlying lined landfill. The ground surface elevation along the buried Sargents Creek was reported to be between 390 and 410 feet msl prior to construction of the WAB 5 Groundwater elevations in WAB monitoring wells are reported to be between 448 and 463 ft ms16. The difference between the reported ash basin groundwater elevations and the natural ground surface elevations underlying the basin indicates that from 38 to 73 feet of saturated coal ash is present within the WAB. Hydrogeology The CSA describes three natural hydrogeologic units or zones of groundwater flow at the Roxboro Plant. Coal ash is considered as its own hydrogeologic unit that is localized to the ash basins. The zone closest to the surface is the shallow or surficial flow zone encompassing saturated conditions, where present, in the saprolite and alluvium beneath the Site. A transition zone is encountered below the shallow zone and is characterized primarily by partially weathered rock of variable thickness. The 2 SynTerra, 2015b, p. 1-2. 3 SynTerra, 2015b, Appendix E, p.3. 4 SynTerra, 2015a, Figure 6-5. 5 SynTerra, 2015b, Appendix E, p.4. 6 SynTerra, 2015a, Figure 6-5. 5 GEO-HYDRO, INC bedrock flow zone occurs below the transition zone and is characterized by the storage and transmission of groundwater in water -bearing fractures. Due to its limited occurrence and extent, the shallow zone is considered part of the transition zone. Where present, groundwater exists under unconfined conditions in each of the hydrogeologic units. The surficial/transition zone and bedrock aquifers are interconnected. On a regional scale groundwater appears to flow from highland areas in the south and east, to the northwest toward Hyco Lake. On a local scale groundwater flow directions are poorly defined. Large areas of the Bedrock Water Level Map included with both the CSA and CAP Part 1 (Figure 2) show neither groundwater elevation data nor contours. Due to the scarcity of head data the description of the groundwater flow system included in the Groundwater Modeling Report8 describes groundwater flow in terms of inferred flows. The groundwater flow system beneath the eastern lobe of the EAB is inferred to receive recharge from uplands to the south and east9, and discharge from the eastern lobe by flowing toward the water intake canal, or northeast to a stream that drains the lake (now identified as the unnamed eastern extension) that flows along the eastern side of the EAB and discharges into the water intake canal10. Groundwater flow into the western lobe of the EAB is inferred to occur from the west, south and east' 1. Groundwater discharges from the western lobe of the EAB are inferred to occur to the north toward the plant. Further, the modeling report infers that groundwater beneath the EAB flows toward discharge areas in wetlands and/or ponds located north of the EAB dam. Groundwater flow into the WAB is inferred to flow into the basin from upland areas to the east. Groundwater appears to discharge from the WAB to the north, west and south. Groundwater is inferred to discharge from the WAB by flow to the north through and around the dam, through and beneath the dam on the south end of the WAB, and to discharge into the canal located west of the WAB. Surface waters from the EAB, including groundwater that has discharged to surface water, are routed to the west where it enters the northern end of the WAB. Sluice water used to transport bottom ash to the WAB also discharges into the northern end of the WAB. Surface water from these sources, along with precipitation and groundwater that discharges from the WAB, discharges through the filter dam at the south end of the WAB and into the discharge canal. The discharge canal wraps around the west side of the WAB, ultimately discharging into Hyco Lake. The CAP indicates 12 that seeps and surface 7 SynTerra, 2015a, p.26. 8 SynTerra, 2015b, Appendix E 9 The discussion of groundwater flow included in Appendix E (p. 4) erroneously indicates that flow toward the EAB is from uplands to the north and west. Examination of head distribution maps included with the modeling report make it clear that this statement in the text is in error. 10 SynTerra, 2015b, Appendix E, Section 2.2. 11 The Groundwater Modeling Report actually says recharge is from the north rather than the south. It appears that this was a mistake as the limited groundwater head data shows higher heads located south of the west lobe. 12 SynTerra, 2015b, Section 2.2.3. M GEO-HYDRO, INC water drain into NPDES-permitted surface water bodies, but fails to recognize that the parameters required for testing under the NPDES permit are not those that are elevated by coal ash impacts. Nature and Extent of Contamination Data collected during the CSA show that groundwater is impacted by the ash basins with boron, strontium, sulfate, total dissolved solids (TDS) and to a lesser extent, cobalt, iron, manganese, and vanadium. 13 The CSA also determined that Hyco Lake and the plant's cooling water intake and discharge canals are the primary receptors of impacted groundwater and seeps, and that groundwater flow direction data and surface water data indicate that constituents of interest are migrating to the 14 reservoir Some of the most problematic issues at the Roxboro plant are related to the interaction of groundwater and surface water bodies on and around the plant site. The CAP Part 2 confirms this observation is several locations 15. Rapid discharge of contaminated groundwater into surface drainages limits the extent of groundwater contaminant plumes to the area beneath the basins, and between the basins and surface discharge areas. Ash -impacted groundwater plumes are not restricted to the immediate area of the basins by a lack of migration, their size is restricted because the contaminated groundwater discharges to surface water. Particularly problematic is the fact that the discharge channel that carries most of the discharge from this site has still not been characterized. No surface water samples were collected from the outflow channel even though all of the combined drainage from the East and West Ash Basins are routed to Hyco Reservoir through this channel. Contaminated water is collected in the East Ash Basin and pumped to the West Ash Bain where it is again passed through ash and presumably leaches additional contaminants. The west discharge channel carries surface water discharge also receives groundwater discharges from beneath the West Ash Basin. It should be expected that contaminant loading will increase in the down stream direction. The fact that the west discharge canal outfall was not sampled during the CSA, nor sampled as a data gap, would appear to indicated that Duke is not interested in identifying the potential magnitude of impacts to Hyco Reservoir. Characterization of water quality in Hyco Reservoir is inadequate. The surface water sample location nearest to the discharge channel outfall point is NPDES outfall 003 (Figure 1-2) located between the West Cooling and Hyco reservoirs. Review of discharge monitoring reports for outfall 003 shows that selenium is the only coal ash related parameter that is included on the analyte list for sampling at this location. All of the other key parameters expected to be found in discharges from the site are not being monitored Outfall 003. Surface water sample locations SW -01, SW -2 and SW -3 are located at tributaries along Hyco Reservoir that are located further from the outfall and separated from the 13 SynTerra, 2015b, p. 3-8 14 SynTerra, 2015a, p.114 15 An example is located in SynTerra, 2016, page 2-2, 4`h bullet 7 GEO-HYDRO, INC reservoir by a long peninsula. None of the surface water sample locations adequately characterize impacts to Hyco Reservoir. Even without adequate characterization of water quality, the human Health Risk Assessment concluded " that exposure to fish tissue caught from Hyco Reservoir and consumed under the hypothetical recreational and subsistence fishing scenarios resulted in potentially unacceptable noncarcinogenic health risk. This conclusion was based on fish tissue concentrations modeled from surface water results in the absence of Hyco Reservoir surface water samples. The discussion presented in the CAP part 2 cites uncertainty and overestimation associated with the fish tissue modeling to assert that consumption of fish is not expected to pose risk to human health. However, as was described above, the surface water samples that the modeling was based on does not include characterization of the discharge from the west discharge channel, nor water directly from potentially impacted areas of Hyco Reservoir. Additional characterization of surface water and sediment on the site and in Hyco Reservoir is a severe data gap since potential hazards to human health from consumption of fish from Hyco Reservoir were identified. Determination of Background Water Quality Accurate and appropriate determination of background water quality is of critical importance to evaluation of groundwater impacts from the ash basins. Provisional background concentrations for groundwater, as well as other media, were proposed in the CAP Part 1. The CAP Part 2 reported analytical results from rounds 1 thru 4 of background groundwater sampling, but further evaluation of results and background concentrations was deferred to future reports. Groundwater monitoring results are currently being compared to provisional background concentrations that are based on an incomplete data set. Further, the values identified as the provisional background are either calculated values or are the highest value recorded at any of the various locations, both of which are dependent on the distribution of concentrations obtained during sampling. Water quality monitoring results are easily influenced by sampling methods and techniques and can easily provide spurious data. Even the background data set that is being developed by sampling new background wells around the Roxboro site are capable of producing outliers in the data set that if not removed could skew the background concentration. The complete data set needs to be evaluated for sampling or analytical problems and tested to eliminate outliers that could skew the data prior calculating or selecting background concentrations. Decisions about remedial strategies to be utilized to clean-up or at least temporarily contain ash -related contaminants must not be based on incomplete or skewed background data. This is absolutely what is happening with decisions currently being made on the Roxboro site. 16 SynTerra, 2016, Appendix D, Section 5.5, p. 5-16, 3rd paragraph N. GEO-HYDRO, INC Groundwater Mode The groundwater flow and transport model of the site was constructed and used in the CAP Part 1 to evaluate groundwater flow and investigate three remedial scenarios. The scenarios investigated included the No Action scenario, a Cap -In -Place scenario, and an Ash Excavation scenario. The model was used to predict contaminant distributions for the next 5, 15 and 30 years, under each scenario. Groundwater modeling reported in the CAP Part 2 17 increased the time duration of model runs to 100 years, but reported results only for the No Action and Cap -In -Place scenarios. The Excavation scenario was omitted without explanation. The No Action scenario'8 relies on natural attenuation processes to reduce contaminant concentrations over time. The ash basin remains in place without modification and "the assumption is made that current recharge and contaminant loading rates from the ash to the underlying formations are held constant". "The flow system is assumed to be at steady state with respect to the conditions in 2015." "Concentrations in the ash were held constant at the measured concentrations." Using these assumptions the model predicts that the boron plumes will continue to expand laterally and downward, and increase in concentration over time. The predicted increases in plume size are predicted to be from on the order of few hundred feet to very small. This result is likely due to constraints on plume size related to known hydrologic boundaries as were described above. Once a plume reaches a hydrologic boundary the constituents migrating with groundwater are transferred to the surface water system and the groundwater plume does not continue to grow in size though contaminants continue to migrate with surface water. The Cap -In -Place scenario involves placing an unspecified low permeability cover over the ash basin to prevent infiltration. The cover system is described in CAP Part 1 as a hybrid cap -in-place approach or a low permeability surface cover19. In CAP Part 2 the cap is described as a "low permeable composite cover (liner)"20, not necessarily a synthetic cap. The groundwater model assumes that infiltration from above is set at zero, something that is not realistically achievable even with a well constructed synthetic cap. Evaluation of realistic infiltration through the specific materials that are to be used to construct the cap must be performed in order to accurately predict the volume of infiltration and the volume of leachate that can be expected to migrate out of the basin. While MODFLOW does not offer cap performance evaluations, other programs such as HELP could be used to generate reasonable infiltration values for use in MODFLOW. 17 SynTerra, 2016, Appendix B 18 The entire description of this scenario is presented in the CAP, Appendix E, Section 6.1. 19 SynTerra, 2015b, p. ES -9 and 2-15 20 SynTerra, 2016, p. ES -2 Z GEO-HYDRO, INC The CAP Part 2 makes a brief reference to a system of drains or other engineering controls will be constructed to control inflow of groundwater and lower the groundwater table below the ash21. Use of drains to lower the water table beneath the ash basins is not discussed anywhere other than in the Executive Summary. No engineering controls other than installation of an assumed 100% effective cap were included in modeling reported under this program. The impacts of engineering controls on groundwater flow and contaminant transport cannot be known on the basis of information provided in this document. Results of simulation of the cap -in-place scenario predict that zones of boron concentration increase in size and concentration relative to 2015 conditions, but the magnitude of the increases are less that those calculated under the No Action scenario. Concerns with the Capping Ash Basin scenario include the assumption of no recharge within the basin and changing the way that contaminant concentrations in the source material are handled. The hydrogeology of the Roxboro impoundments (see description of groundwater flow above) includes recharge into the basins from higher elevation areas to the south and east. Capping of the ash in the basin will not control influx of groundwater from upland areas. Discharges of groundwater into the ash basins are likely significant as groundwater discharges into the basin were sufficient to maintain streams prior to their being buried under coal waste. The Excavation scenario represents complete removal of the ash by inactivating the upper four model layers, adding drain cells to simulate drainages, and setting recharge within the ash basin to ambient levels. This scenario predicts the largest reduction in ash -related contaminant concentrations of any of the tested scenarios. Despite providing the most improvement in groundwater quality the Excavation Scenario was not selected by Duke as the recommended source control alternative and was not included in the modeling reported in the CAP Part 2. 21 SynTerra, 2016, p. ES -2 10 GEO-HYDRO, INC 5. Opinion 1: Coal Ash Stored in the Roxboro Ash Basins is the Source of Contamination Detected in Groundwater Coal ash is the source of contaminants detected in groundwater at concentrations above applicable standards in the vicinity and downgradient of the ash basin. Data collected during the CSA show that groundwater is impacted by the ash basins with boron, strontium, sulfate, TDS and to a lesser extent, cobalt, iron, manganese, and vanadium. 22 The lateral extent of groundwater impacts outside of the ash basins is limited by the presence of water local discharge areas. The contaminated pore water migrates out of the ash basins and either directly into surface water, or into groundwater that subsequently discharges to surface water, and eventually into Hyco Lake. This interpretation is consistent with the CSA which states that: Hydrologic boundaries are present downgradient of the ash basins in the form of the intake canal, the discharge canal and the cooling reservoir which discharges to Hyco Lake. When the CCR constituents reach these hydrologic boundaries, they are removed from the groundwater system, and they enter the surface water system. At the Site, boron is the primary constituent that is migrating from the ash basins. 23 22 SynTerra, 2015b, p. 3-8 13 SynTerra 2015b, p.3-8 11 GEO-HYDRO, INC 6. Opinion 2: Capping Coal Ash Located Within the Roxboro Ash Basin Will Not Protect Groundwater Quality Downgradient of the Basins The CAMA process proposed designation of the Roxboro site as low-risk creates the possibility that Duke could pursue closure of the Roxboro impoundment by capping the disposed ash in place. Capping the waste within the footprint of the ash basin will not be protective of groundwater quality downgradient of the basin. Environmental contaminants contained in coal ash are leached into groundwater when precipitation infiltrates through the waste or, when groundwater flows through waste that has been placed below the water table. In the case of the Roxboro ash basins, both of these processes are currently acting to create the contaminated ash porewater, groundwater, and surface water that discharge into local surface waters and eventually into Hyco Lake. The cap -in-place remedy would likely reduce the amount of water that enters the waste from precipitation. This remedy would however do nothing to reduce the amount of groundwater that flows laterally into the basin from surrounding geologic units, through the capped waste, into downgradient groundwater, and eventually into Hyco Lake. The lined landfill that was constructed over a portion of the EAB should function as a cap over the ash disposed in the unlined landfill and ash basin. The CSA 24 indicates that construction of a lined landfill has resulted in decreasing concentrations of iron, manganese and chromium in three monitoring wells (GMW-06, GMW-10 and GMW-11). The available data set does not show a clear pattern of decreasing contaminant concentrations related to construction of the lined landfill. Review of the comprehensive analytical results from Roxboro 25 shows that large decreases in several parameters were observed in some monitoring wells during the first few sampling events and prior to construction of the lined landfill. Figures 3 and 4 show graphs of boron, sulfate, selenium and TDS concentrations measured in samples from wells in the immediate vicinity of the lined landfill. Sulfate, TDS, and selenium26 concentrations in some wells were very high initially and show rapid declines in concentration between the initial sampling event in 2002 and 2004 when the lined landfill was constructed. This is an indication that decreased contaminant concentrations in wells since their early sampling events appear to have been due to improper well development or sampling techniques rather than improving water quality resulting from landfill construction. Boron, sulfate, and TDS concentrations have been increasing rapidly in monitoring well GMW-8 since 2013. Analytical data graphs show that concentrations of ash -related parameters in wells 24 SynTerra, 2015b, p.1-8 25 SynTerra, 2015a, Attachment 3 26 Note that boron was not included in the tested parameters until 2002, so the early concentrations of boron are unknown. 12 GEO-HYDRO, INC GMW-06, GMW-08 and GMW-11 have remained at or above water quality standards despite the presence of the lined landfill. Continued detections of elevated concentrations 27 of ash -related contaminants at in groundwater around the lined landfill indicates that ash underlying the lined landfill continues to release contaminants to groundwater, even though most infiltration from above has presumably been eliminated by the landfill liner. This result is to be expected at any location where ash remains submerged below the local water table. Continued generation and downgradient migration of leachate will occur in the Roxboro Ash basins unless all of the ash in the basin is dewatered and remains above the high water table, a scenario that is unlikely to occur at Roxboro. Groundwater modeling reports prepared in support of the CAPS provided no estimation of the amount of saturated ash that would remain at Roxboro should the capping in place remediation scenario be implemented. An estimate of the thickness of the remaining thickness of saturated ash can be obtained by comparing the elevation of the natural ground surface beneath the basins to the groundwater elevation in wells just outside of the basins28. The ground surface elevation below the EAB dam was reported to be between 390 and 400 feet ms129. Groundwater elevations in EAB monitoring wells located just outside of the basin are reported to be between 462 and 513 ft n1s130. The difference between the lowest measured groundwater elevation in wells located just outside the ash basin and the highest natural ground surface elevations underlying the EAB indicates that at least 62 feet of saturated coal should be expected to be present beneath the EAB were the cap in place remediation scenario implemented. The natural ground surface elevation beneath the WAB was reported to be between 390 and 410 feet ms131. Groundwater elevations in WAB monitoring wells located just outside the ash basin are reported to be between 452 and 456 ft ms132. The difference between the lowest measured groundwater elevation in wells located just outside the ash basin and the highest natural ground surface elevations underlying the WAB indicates that at least 42 feet of saturated coal should be expected to be present beneath the WAB were the cap in place remediation scenario implemented. The CAP Part 2 makes a brief reference to a system of drains or other engineering controls will be constructed to control inflow of groundwater and lower the groundwater table below the ash33. Use of drains to lower the water table beneath the ash basins is not discussed anywhere other than in the Executive Summary. No engineering controls other than installation of an assumed 100% effective 27 above 2L standards 28 Estimates of the thickness of saturated ash that would likely remain were the capping ash in place scenario implemented are provided since the groundwater modeling report did not provide an estimation. Further modeling, or better model reporting, should be conducted to refine these estimates. 29 SynTerra, 2015b, Appendix E, p.3. 30 SynTerra, 2015a, Figure 6-5. 31 SynTerra, 2015b, Appendix E, p.4. 32 SynTerra, 2015a, Figure 6-5. 33 SynTerra, 2016, p. ES -2 13 GEO-HYDRO, INC cap were included in modeling reported under this program. The impacts of engineering controls on groundwater flow and contaminant transport cannot be known on the basis of information provided in this document. The modeling report indicates that excavation of the ash reduces the concentration of boron in groundwater more than either the No Action or Cap -In -Place scenarios. This indicates that removal of the Roxboro coal ash is the most effective option for improving groundwater quality and minimizing future discharges to Hyco Lake. This is as would be expected considering that the cap in place scenario would leave a significant thickness of saturated ash in place that would continue to leach ash constituents into the groundwater far into the future. Even though there are serious flaws in the groundwater modeling that artificially restrict groundwater impacts under the cap -in-place scenario (see Opinion 3), the modeling effort confirms that ash excavation is the option that is most protective of the environment and is a permanent solution. 14 GEO-HYDRO, INC 7. Opinion 3: The Groundwater Flow and Transport Model Does Not Reflect Real -World Conditions Groundwater models can be useful tools that can be employed to evaluate alternative actions at waste disposal site such as Roxboro. This usefulness, however, is predicated on the model being constructed in a manner that faithfully recreates actual field conditions. In this case, the models include fundamental inconsistencies between observed and modeled conditions that cast doubt on results and make it likely that the nature and extent of groundwater contamination under the cap -in place scenario is understated. Each of the identified issues with the current model are identified separately below. Groundwater Flow Modeling Model Geometry Artificially Isolates the Ash The layering of ash used in the model flow model effectively works to restrict calculated flow of water into/out of the ash layers. The MODFLOW code used to model the impoundment calculates head and groundwater flux between each side, top, and bottom of adjacent cells. The ash in layers 1- 4 has no lateral continuity with any of the adjacent natural materials in the sides of the basin. The layers extend laterally to the edge of the basin and terminate at a no flow boundary. Lateral flow of groundwater from/to the sides of the basin into the ash is not considered in this model. When a 100% effective cap is assumed, the only flow in the ash of layers 1-4 is vertically into or out of the underlying saprolite through the bottom of layer 4 (and top of layer 5). This prohibition of lateral flow at the edges of the ash pond into/from the enclosing saprolite is compounded by the corresponding imposition of the horizontal -to -vertical anisotropy for hydraulic conductivity. As modeled, the vertical flow between the ash and saprolite is constrained by hydraulic conductivity that is only 20% of that which would exist were the connection between the materials to occur horizontally under the same gradients. The conditions included in this model create the equivalent of a 100% effective liner on the top and sides and an 80% effective liner at the bottom of the ash. This is, of course, not reflective of real—world conditions. Assumption of Cap Effectiveness The Cap—In-Place scenario assumes construction of a 100% effective cap over the ash in Layer 1. While zero infiltration through the cap and into the ash is an easy assumption to make, in the real world some infiltration through even the most robust cap systems is expected. When an assumed 100% effective cap over the top of the ash is combined with lateral isolation of the ash by no -flow boundaries (described above), the only flow in the ash of layers 1-4 is vertically into or out of the underlying saprolite through the bottom of layer 4. This is an assumed condition that has no basis in the real world. The combined effect of artificially restricting inflow of groundwater from the sides 15 GEO-HYDRO, INC of the basin into the ash and assuming a 100% effective cap is to provide overly optimistic evaluations of the effectiveness of the cap -in-place remedial scenario. Specific cap materials must be identified and a realistic estimate of infiltration must be incorporated into the model, including how they change as the cap materials deteriorate over time, if the Cap -In -Place scenario is to be seriously evaluated. Fate and Transport Modeling Constant Concentration Cells Within the Ash The Roxboro baseline and the no action transport simulations have a huge number of fixed concentration (source) cells that define the concentrations levels within the four ash layers. There are 42,232 constant concentration cells in the ash (10,558 in each of Layers 1 — 4). Each cell defines the concentration of 4 components. Due to the restrictions of the flow model, all flow to/from the ash ponds occurs through the cells of Layer 4. The use of constant concentrations in the ash in Layer 4 cells means that concentration of each constituent in water leaving the ash basin is completely determined by the fixed concentration assigned for each Layer 4 cell that discharges leachate, regardless of the distribution of constituent concentrations within rest of the ash. The cap -in-place scenario is dramatically different. The number of constant concentration cells is greatly reduced, but not they are not eliminated. Instead of 42,232 such cells, this scenario has only 930 constant concentrations cells. All of 930 constant concentration cells are in Layer 4. The remaining 41302 ash cells in Layers 1 thru 4 are variable concentration cells. In MT3DMS variable concentration cells add no contaminants to the groundwater. Coincident with installation of the cap, the modeler assumes that any ash that remains saturated is somehow incapable of producing contamination for any constituent except for the remaining 930 constant concentration cells. The shift in the MT3DMS source from leachate producer to inert media has no justification. The remaining 930 cells generate contamination in perpetuity. However, the concentrations of contaminants generated upon installation of the cap bears no apparent relationship to the concentrations generated immediately prior to the installation of the cap. In the case of boron, each of the 930 cells is a constant concentration of 3000 ppm. There is no explanation in the report as to why these cells and these alone will continue to generate contamination, why that contamination for boron would be at 3000 ppm in each cell regardless of previously simulated concentrations. It is also noted that any leachate with higher boron concentrations migrating through these cells would have its concentration reduced to 3000 ppm before further migration. The impact of these 930 cells on the remaining 3 constituents is even more dramatic. The constant concentrations for each of these constituents in each of the 930 cells is zero. This means that upon installation of the cap, this scenario sets any previous concentrations in these cells to zero. It also 16 GEO-HYDRO, INC means that any water migrating through these cells from the overlying ash is also reset to zero. There is no real-world scenario for this to be a result of installing a cap to prevent infiltration. Constant Concentration Cells Beneath the Ash Landfill In addition to the 42,232 constant concentration cells within the ash for the baseline and no -act scenarios. There are 275 constant concentration cells, each with 4 components, in Layer 7; 320 constant concentration cells, each with 4 components, in Layer 8, and 26 constant concentration cells, each with 4 components in Layer 9. These cells are assigned constant contaminant values that represent the postulated concentrations in leachate that migrates downward from waste disposal facilities to the water table. The concentrations that are assigned to the water table beneath the gypsum pile and the unlined landfill are not developed from concentrations of leachate within the facilities. The methodology used to develop the water table assigned concentration beneath the landfill is problematic. There are no data from within the landfill regarding leachate composition. In lieu of using facility - specific water quality data, the modelers postulated that leachate within the landfill would be similar to pore water within the ash ponds. The water quality within the ash ponds varies significantly from place to place. The aggregate data from the ash pond analyses were used to develop a single value for assignment to the water table. There are a variety of methods that could be used estimate a single value of a contaminant from a variable data set. The method chosen by the Roxboro modelers is not among the valid ones. The geometric mean of the boron data from the ash pond was assumed representative of the landfill leachate at the water table. A geometric mean is a specialized averaging technique that is used to find a central value of numbers that are log -normally distributed. There is no expectation that concentrations of a contaminants found in pore water in heterogeneous deposits of ash in the ponds are log -normally distributed. The effect of using the geometric mean of concentration data is that the geometric mean is weighted toward the small values of the sample being averaged. For example, a leachate sample of 1 and a leachate sample of 10,000 (both within the range of values observed for boron) have an arithmetic mean (standard averaging technique) of 5000.5. The geometric mean is 100. If the ash leachate is the landfill can be assumed to be similar or analogous to the pore water of the ponded ash, an appropriate composite value for modeling purposes will be higher than the geometric mean of the data from the ponded ash. The same geometric mean of the observed ash value is used elsewhere in the model; where no data exist, the geometric mean is assumed. The effect of using this value is almost certainly an underestimation of the source concentrations in the model. Subsequent to the installation of the cap, the modeler eliminates the constant concentrations cells at the water table beneath the waste disposal facilities. This represents the cessation of leachate 17 GEO-HYDRO, INC migration from the facilities to the underlying groundwater. No explanation is offered to justify that there would be the cessation of leakage from these facilities as a result of installation of the cap over the ash. GEO-HYDRO, INC 8. Opinion 4: Monitored Natural Attenuation Is Not An Acceptable Groundwater Remediation Strategy at Roxboro The CAP Part 134 indicates that Duke may evaluate monitored natural attenuation (MNA) as a potential groundwater remedy for certain area of the Roxboro site. This document attempts to make it appear that MNA is a viable remedial option for impacted groundwater downgradient of the Roxboro ash basin. From a technical standpoint, MNA remedies typically require: • That there are no current receptors, including surface water or wetland discharges and water supply wells. • That there is sufficient lateral space between the contaminant source and groundwater discharge areas to allow natural attenuation to reduce contaminant concentrations prior to reaching a receptor. • Evidence that the location of the leading edge of the contaminant plumes be stable (not be expanding). • That there is a natural reduction in contaminant concentrations along flow paths. • That there is sufficient space between the contaminant source and groundwater discharge areas to allow a monitoring system to be established, including sentry wells located ahead of the leading edge of the contaminant plume. None of these technical factors for considering NINA as an appropriate remedial strategy at the Roxboro site are met. From a scientific standpoint there is no justification for considering MNA. The CAP Part 2 continues to try to make it appear that MNA is a viable remedial option for this ash basin. An evaluation of NINA provided in the CAP Part 235 does not support its use at Roxboro. For instance, the document states: "However, at Roxboro, that portion of groundwater flow within bedrock (where bedrock is unweathered and has no soil like properties) is not likely to sorb large amounts of the key constituents." (p.6-9, top paragraph), and "Roxboro is primarily underlain by bedrock and for this reason there is insufficient data to observe significant trends." (p.6-11, last sentence) Since sorption of key constituents is not likely to be effective in bedrock and Roxboro is primarily underlain by bedrock, it is hard to imagine a rationale for concluding that MNA is an appropriate remedial option other than a cost driven evaluation. 34 SynTerra, 2015b, p.5-1 35 SynTerra, 2016, Section 6.4.1 19 GEO-HYDRO, INC The CAP attempt to make it appear that NINA is a viable remedial option for impacted downgradient of the Roxboro ash basin. However, MNA is not a viable closure option for this site for several reasons including the following: • Duke Energy has not proposed removal of the waste for disposal in a secure location. Hydrogeologic conditions presented in this document shows that some of the ash would remain saturated after capping. Saturated ash will continue to leach metals into groundwater that will flow toward and eventually discharge into Hyco Lake. As a practical matter, in the absence of removal all sources of contamination cannot be controlled Many of the ash -related constituents in groundwater at this site neither degrade nor attenuate. The Geochemical Site Conceptual Mode136 states that boron is an indicator of coal ash impacts to groundwater because it "is essentially inert, has limited potential for sorption and lacks an affinity to form complexes with other ions." The characteristics of the contaminant plumes alone are sufficient to render the Roxboro site ineligible to use MNA as a remediation strategy. 36 SynTerra, 2015b, Section 3.3 20 GEO-HYDRO, INC 8. Opinion 5: Capping Coal Ash Located Within the Roxboro Ash Basin Will Not Be Protective of Surface Water Quality The most problematic issues at the Roxboro plant are related to the interaction of groundwater and surface water bodies on and around the plant site. The CAP indicates in several locations that the lateral extent of groundwater contamination is generally limited to areas beneath or immediately downgradient of the ash basins. However, at the Roxboro site the ash basins are bounded by drainage features on around the perimeter of the basins that act as groundwater discharge areas. Ash -impacted groundwater plumes are not restricted to the immediate area of the basins by a lack of migration; their size is restricted only because the contaminated groundwater discharges to surface water features. This is particularly problematic since water quality in the outflow channel that carries most of the discharge from this site has not been characterized. No surface water samples were collected from the outflow channel even though the combined drainage from the East and West Ash Basins are passed through this channel to Hyco Reservoir. Surface water monitoring conducted under NPDES Permit NC0003425 does not include the most common analytical parameters that are found in ash impacted waters. This means that a major discharge of likely ash -impacted water from the Roxboro site into Hyco Lake was not sampled as part of the CSA and is not being appropriately monitored under NPDES requirements. The chemistry and volume of water that flows through canals and into Hyco Lake under current and expected closure conditions must be evaluated to assure that the selected remedy is protective of water quality in Hyco Reservoir. Water quality in Hyco Reservoir has also never been adequately characterized. The surface water sample location nearest to the discharge channel outfall point is NPDES outfall 003 located between the West Cooling and Hyco reservoirs. Review of discharge monitoring reports for outfall 003 shows that selenium is the only coal ash related parameter that is included on the analyte list for sampling at this location. All of the other key parameters expected to be found in discharges from the site are not being monitored Outfall 003. Surface water sample locations SW -01, SW -2 and SW - 3 are located at tributaries along Hyco Reservoir that are located further from the outfall and separated from the reservoir by a long peninsula. None of the surface water sample locations adequately characterize impacts to Hyco Reservoir. Even without adequate characterization of water quality, the Human Health Risk Assessment concluded 37 that exposure to fish tissue caught from Hyco Reservoir and consumed under the hypothetical recreational and subsistence fishing scenarios resulted in potentially unacceptable noncarcinogenic health risk. This conclusion was based on fish tissue concentrations modeled from surface water results in the absence of actual Hyco Reservoir surface water samples. The discussion 37 SynTerra, 2016, Appendix D, Section 5.5, p. 5-16, 3rd paragraph 21 GEO-HYDRO, INC presented in the CAP part 2 cites uncertainty and overestimation associated with the fish tissue modeling to assert that consumption of fish is not expected to pose risk to human health. However, as was described above, the surface water samples that the modeling was based on do not include characterization of the discharge from the west discharge channel, nor water directly from potentially impacted areas of Hyco Reservoir. Additional characterization of surface water and sediment on the site and in Hyco Reservoir is a severe data gap since a potential hazard to human health from consumption of fish from Hyco Reservoir was identified. A cap -in-place remedy would not be protective of surface water quality. While a cap would likely reduce the amount of water that enters the waste from precipitation, this remedy would do nothing to reduce the amount of groundwater that flows laterally into the basin from surrounding geologic units, through the capped waste, into downgradient surface water drainages, and eventually into Hyco Lake. Groundwater would continue to flow into the ash basins from adjacent upland areas. Groundwater that flows through the ash will continue to leach metals from the ash and transport those metals down -gradient before discharging into adjacent surface water features. Even though there are serious flaws in the groundwater modeling that artificially restrict groundwater impacts under the cap -in-place scenario (see Opinion 3), the modeling effort confirms that ash excavation is the option that is most protective of the environment and is a permanent solution. 22 GEO-HYDRO, INC 9. Opinion 6: Removal of the Coal Ash Will Remove the Source and Reduce the Concentration and Extent of Groundwater Contaminants Removal (excavation) of the coal ash from the Roxboro ash basin is the only remediation scenario that will separate the coal ash source materials from groundwater and eliminate flow of contaminated groundwater and surface water into Hyco Lake. Excavation of the ash will remove the source of groundwater and surface water contaminants, and reduce the concentration and extent of current contaminants. The groundwater flow and transport model of the site was used in the CAP to evaluate groundwater flow and investigate three remedial scenarios. The scenarios investigated included the Existing Conditions scenario, a Capping Ash in Place scenario, and a Removal of Ash scenario. The model was used to predict contaminant distributions for the next 5, 15 and 30 years, under each scenario. The model showed that the Removal of Ash scenario resulted in the largest reduction in ash -related contaminant concentrations of any of the modeled scenarios. Even though there are serious flaws in the groundwater modeling that artificially restrict groundwater impacts under the cap -in-place scenario (see Opinion 3), the modeling effort confirms that ash excavation is the option that is most protective of the environment and is a permanent solution. 23 GEO-HYDRO, INC 10. Opinion 7: The Coal Combustion Residual Impoundment Risk Classification Proposed by NCDEQ Improperly Minimizes Protection of Environmental Quality A risk ranking process was specified in CAMA to determine the type of closure permitted at each facility. The law specifically requires NCDEQ to classify each impoundment as either high-risk, intermediate -risk, or low-risk, based on consideration, at a minimum, of all of the following criteria. (1) Any hazards to public health, safety, or welfare resulting from the impoundment. (2) The structural condition and hazard potential of the impoundment. (3) The proximity of surface waters to the impoundment and whether any surface waters are contaminated or threatened by contamination as a result of the impoundment. (4) Information concerning the horizontal and vertical extent of soil and groundwater contamination for all contaminants confirmed to be present in groundwater in exceedance of groundwater quality standards and all significant factors affecting contaminant transport. (5) The location and nature of all receptors and significant exposure pathways. (6) The geological and hydrogeological features influencing the movement and chemical and physical character of the contaminants. (7) The amount and characteristics of coal combustion residuals in the impoundment. (8) Whether the impoundment is located within an area subject to a 100 -year flood. (9) Any other factor the Department deems relevant to establishment of risk. In order to evaluate each impoundment on the nine criteria the NCDEW established a risk classification group38. The Risk Classification Group was broken into three sub -groups of people based on areas of expertise (Groundwater, Surface Water, and Dam Safety) to develop a set of risk factors to address each of the nine required criteria. Each subgroup reportedly placed a primary emphasis on risk as it relates to the public from a groundwater, surface water, and dam safety perspective and established one key factor that "plays a significant role in assigning an overall classification" for that group. Other factors not identified as Key Factors were supposedly used to "refine the risk classification and address the actual or potential risk to the environment and natural resources." The result of the risk classification methodology utilized by NCDEQ is that environmental and ecologic risks posed by the Roxboro site were not fully considered by NCDEQ when establishing the overall site risk and clean-up priorities. This resulted in the West, East, and Unnamed Eastern Extension ash ponds being assigned Low, Low to Intermediate, and Intermediate risk ratings, " NDEQ, 2016, p. 13, Classification Methodology 24 GEO-HYDRO, INC respectively, ratings that essentially ignore the known environmental impacts of the Roxboro ash ponds. For example, Table 1 provides a listing of the groundwater risk classification factors and associated ratings for each ash pond at Roxboro. Ten groundwater risk factors were established and received ratings by NDEQ for each ash pond. Table 1 Groundwater Risk Classifications Unnamed Eastern Groundwater Factors East Ash Pond West Ash Pond Extension Number of downgradient receptors within 1500 feet of compliance boundary that are potentially or currently Low Risk Low Risk Low Risk known to be exposed to impacted water. (Key Factor) Amount of stored CCR reported in an impoundment High Risk High Risk High Risk Depth of CCR with respect to the water table High Risk High Risk High Risk Exceedance of 2L or IMAC standards at or beyond the High Risk High Risk High Risk established CCR compliance boundary Population served by water supply wells within 1,500 feet Low /Intermediate Low /Intermediate Low /Intermediate upgradient or side gradient of the compliance boundary Risk Risk Risk Population served by water supply wells within 1,500 feet Low Risk Low Risk Low Risk downgradient of the compliance boundary Proximity of 2L or IMAC exceedances beyond the High Risk Intermediate Risk High Risk compliance boundary with respect to water supply wells Groundwater emanating from the impoundment exceeds High Risk High Risk High Risk 2L or IMAC and that discharges to a surface water body Ingestion of contaminated soil or fugitive emissions Low Risk Low Risk Low Risk Data Gaps and Uncertainty High Risk High Risk High Risk The West Ash Pond received High or Intermediate ratings for 6 of the 10 groundwater risk classification factors, one factor was rated as Low/Intermediate, and only 3 received ratings of Low Risk. Only 30% of the rated groundwater risk classification factors were rated Low Risk, yet NCDEQ gave the Roxboro West Pond an overall Low Risk rating for groundwater. The East Ash Pond received 6 High Risk ratings, one factor was rated as Low/Intermediate, and only 3 received ratings of Low Risk. High risk rankings were assigned to 60% of the rated groundwater risk classification factors, yet NCDEQ gave the Roxboro East Pond an overall Low to Intermediate Risk rating for groundwater. 25 GEO-HYDRO, INC The Unnamed Eastern Extension received High risk ratings for 6 of the 10 groundwater risk classification factors, one factor was rated Low/Intermediate, and only 3 received ratings of Low Risk. High risk rankings were assigned to 60% of the rated groundwater risk classification factors, yet NCDEQ gave the Roxboro Unnamed Eastern Extension an overall Low Risk Rating for groundwater. Table 2 provides a listing of the surface water risk classification factors and associated ratings for each of the Roxboro ash ponds. A total of eight surface water risk factors were rated by NCDEQ for each pond. The West Pond received High or Intermediate ratings for 6 of the 8 surface water risk classification factors and only 2 received ratings of Low Risk. Only 25% of the rated surface water risk classification factors were rated Low Risk, yet NCDEQ gave the Roxboro West Pond an overall Low Risk rating for surface water. Table 2 Surface Water Risk Factors Unnamed Eastern Surface Water Factors East Ash Pond West Ash Pond Extension Landscape Position and Floodplain (Key Factor) Low Risk Low Risk Low Risk NPDES Wastewater and Ash Disposal Methods Low/ Intermediate High Risk Intermediate / High Risk Risk Impoundments Footprint Siting in Natural Drainage High Risk High Risk High Risk Way or Stream Potential to Impact Surface Water Based on Total High Risk High Risk Low Risk Ash Amount at Facility Potential to Impact Surface Water Based on Dilution High Risk High Risk High Risk Development Density of Single -Family Residences Intermediate Risk Intermediate Risk Intermediate Risk along Lake/Reservoir Shoreline Classification of the Receiving Waters Intermediate Risk Intermediate Risk Intermediate Risk Proximity to Water Supply Intake Low Risk Low Risk Low Risk The East Pond received High or Intermediate ratings for 5 of the 8 surface water risk classification factors, one factor was rated as Low/Intermediate, and only 2 received ratings of Low Risk. Only 25% of the rated groundwater risk classification factors were rated Low Risk, yet NCDEQ gave the Roxboro East Pond an overall Low Risk rating for surface water. The Unnamed East Extension Pond received High or Intermediate ratings for 5 of the 8 surface water risk classification factors and only 3 received ratings of Low Risk. Only 37.5% of the rated 26 GEO-HYDRO, INC surface water risk classification factors were rated Low Risk, yet NCDEQ gave the Unnamed Eastern Extension pond an overall Low Risk rating for surface water. The preceding analysis uses the risk ratings applied by NCDEQ with no evaluation or judgment about whether they were or were not appropriately applied. The risk ratings given to the Roxboro ash basins demonstrate that protection of environmental and natural resources is not being treated as priority issues by the North Carolina agency entrusted with the responsibility to do just that. The approach utilized by NCDEQ effectively ignores impacts to the natural environmental and natural resources, and even ignores future human users of the groundwater and surface water resources. It appears that in the view of NCDEQ the only way that a site can be rated as Intermediate or High Risk is if a facility is located within a 100 -year floodplain or if 11 or more people within 1,500 feet of the compliance boundary are potentially or currently known to be exposed to ash -impacted groundwater39. It is hard to imagine that exposed persons 1 through 10 would agree with this rating scheme. 39 NCDEQ, 2016, page 15, Key Factors 27 GEO-HYDRO, INC References Duke Energy, 2014, Discharge Monitoring Reports for September, October, and November 2014. National Pollutant Discharge Elimination System, Permit NC0003425. NCDEQ, 2016, Coal Combustion Residual Impoundment Risk Classifications, January 2016. SynTerra, 2014, Groundwater Assessment Work Plan for Roxboro Steam Electric Plant, Semora, NC, September 2014. SynTerra, 2015a, Comprehensive Site Assessment Report, Roxboro Steam Electric Plant, Semora, NC, September 2015. SynTerra, 2015b, Corrective Action Plan, Part 1, Roxboro Steam Electric Plant, Semora, NC, December 2015. SynTerra, 2016, Corrective Action Plan, Part 2, Roxboro Steam Electric Plant, Semora, NC, February 2016. United States Geological Survey, Olive Hill, N.C., 7.5 Minute Topographic Map, 1968, revised 1994. GEO-HYDRO, INC Figures r ' r:— f 60 _ � — I � � `-•y ' ,� _ _. f_fi - f 7 '.�_��. �`\s�_:.� �-.R �. I ITIS- a tk.� 1445 " �' � f--. L_ '" i � J•- _ - '�Ir 7 �.- ++ I 7 - _ .x ti i a -y M _ ZZ - --.Jh _ 1�'�il �. tl -: -• e'. Ir`� `+li:{ ;IM1 `<ti.tlhJl t=~�ik1, e' t' ^. 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Sample Date Sulfate Concentration December 2002 -April 2015 GEO-HYDRO, INC Consulting in Geology and Hydrogeology —6 GMW-06 t GMW-07 GMW-08 --X—GMW-09 eX r GMW-10 +GMW-11 2L Standard (700 ug/1) Data From: Syn Terra, 2015a, Attachment 3 0 GMW-06 f-GMW -07 GMW-08 X GMW-09 —X GMW-10 —41 W-11 2L Standard (250 mg/I) Data From: SynTerra, 2015a, Attachment 3 Figure 4 Boron and Sulfate Concentrations Lined Landfill area Monitoring Wells Roxboro Steam Electric Plant 400 350 300 250 rn E 200 y 150 100 50 0 \ti O19 O°� OOb 0�\19 \ti Selenium Concentration December 2002 - April 2015 2500 2000 £ 1500 Sample Date TDS Concentration December 2002 - April 2015 o.�`y 0^3 O1b 500 0 o°o o°� o°�' 0°6 06 o°b o o°° o^d^ oN oN5 o� AV Sample Date GEO-HYDRO, INC Consulting in Geology and Hydrogeology $GMW-06 tGMW-07 GMW-08 GMW-09 --*— GMW-10 --0--G MW -11 2L Standard (20 ug/I) Data From: Syn Terra, 2015a, Attachment 3 —4-- GMW-06 t G M W-07 GMW-08 GMW-09 --)K—GMW-10 —e GMW-11 2L Standard (500 mg/I) Data From: S ynTe rra, 2015a, Attachment 3 Figure 5 Selenium and TDS Concentrations Lined Landfill area Monitoring Wells Roxboro Steam Electric Plant