NC0005363_Cooling Pond Work Plan_20160818

47
synTerra
PROPOSED COOLING POND
ASSESSMENT WORK PLAN
FOR
W.H. WEATHERSPOON POWER PLANT
491 POWER PLANT ROAD
LUMBERTON, NORTH CAROLINA 28358
NPDES PERMIT ##NC0005363
N 34.590664 / W -78.970187
PREPARED FOR
DUKE ENERGY PROGRESSO INC.
410 S. WILMINGTON STREET/NC14
RALEIGH,, NORTH CAROLINA 27601
(� DUKE
ENERGY
PROGRESS
SUBMITTED: AUGUST 2016
PREPARED BY
SYNTERRA
148 RIVER STREET
GREENVILLEj, SOUTH CAROLINA
[phone]
INNOVATE 148 River Street, Suite 220 Greenville, SC 29601 [phone]

Proposed Cooling Pond Assessment Work Plan August 2016
W.H. Weatherspoon Power Plant SynTerra
TABLE OF CONTENTS
SECTION
PAGE
ExecutiveSummary.............................................................................................................. ES -1
1.0 Introduction..................................................................................................................1-1
2.0 Site Information........................................................................................................... 2-1
2.1
Plant Description.....................................................................................................
2-1
2.2
Ash Basin Description............................................................................................
2-1
2.3
Cooling Pond Description.....................................................................................
2-2
2.4
Regulatory Requirements......................................................................................
2-2
2.5
Receptor Information.............................................................................................
2-3
2.6
Risk Assessment......................................................................................................2-4
3.0 Regional Geology and Hydrogeology..................................................................... 3-1
3.1 Regional Geology....................................................................................................3-1
3.2 Regional Hydrogeology......................................................................................... 3-1
4.0 Cooling Pond Conceptual Model.............................................................................4-1
4.1
Physical Site Characteristics..................................................................................
4-1
4.2
Source Characteristics............................................................................................
4-1
4.3
Site Hydrogeology..................................................................................................
4-1
4.4
Cooling Pond Construction...................................................................................
4-2
4.5
Cooling Pond Hydraulics......................................................................................
4-3
4.5.1 Cooling Pond Inflows.......................................................................................4-3
4.5.1.1 Predominantly Non -Anthropogenic Inflows.......................................4-4
4.5.1.2 Anthropogenic Inflows............................................................................
4-4
4.5.2 Cooling Pond Outflows....................................................................................
4-5
4.5.3 Hydraulic Residence Time...............................................................................4-6
4.6 Chemical Constituents Introduced Into The Cooling Pond by
AnthropogenicSources.......................................................................................... 4-7
4.7 Potential Mechanisms For Coal Ash Transport To Cooling Pond ................... 4-7
4.8 Cooling Pond Analytical Data.............................................................................. 4-8
5.0 Cooling Pond Assessment Work Plan..................................................................... 5-1
5.1 Groundwater Monitoring Well Installation........................................................5-1
5.1.1 Well Completion............................................................................................... 5-1
5.1.2 Well Development............................................................................................ 5-2
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Proposed Cooling Pond Assessment Work Plan August 2016
W.H. Weatherspoon Power Plant SynTerra
TABLE OF CONTENTS
SECTION
PAGE
5.2 Wastewater and Surface Water Samples.............................................................5-2
5.2.1 Grab Water Samples.........................................................................................
5-2
5.2.2 Groundwater Samples......................................................................................5-3
5.3 Sediment Samples...................................................................................................
5-4
5.3.1 Sediment Core Samples....................................................................................
5-4
5.3.2 Sediment Grab Samples...................................................................................
5-5
5.4 Field and Sampling Quality Assurance/Quality Control Procedures .............
5-6
5.4.1 Field Logbooks..................................................................................................
5-6
5.4.2 Field Data Records............................................................................................
5-7
5.4.3 Sample Identification........................................................................................
5-7
5.4.4 Field Equipment Calibration...........................................................................
5-7
5.4.5 Sample Custody Requirements.......................................................................
5-8
5.4.6 Quality Assurance and Quality Control Samples ........................................
5-8
5.4.7 Decontamination Procedures..........................................................................
5-9
6.0 Modeling of Groundwater Impacts to Surface Water ..........................................
6-1
7.0 Cooling Pond Assessment Report............................................................................
7-1
8.0 Proposed Schedule.......................................................................................................8-1
9.0 References......................................................................................................................9-1
LIST OF FIGURES
Figure ES -1 Revised Waste Boundaries and Proposed Compliance Boundaries
Figure ES -2 Cooling Pond Assessment Sample Locations
Figure 1-1 Site Location Map
Figure 1-2 Revised Waste Boundaries and Proposed Compliance Boundaries
Figure 2-1 1951 Aerial Photograph
Figure 2-2 1957 USGS Topographic Map
Figure 2-3 Cooling Pond Outfalls — 2009 NPDES Permit NC0005363 Renewal
Application
Figure 2-4 Cooling Pond Outfall — 2014 NPDES Permit NC0005363 Renewal
Application
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LIST OF FIGURES
Figure 4-1 Water Level Map - January 2016 Surficial Groundwater
Figure 4-2 Cooling Pond Inflows and Outflows - 2009 NPDES Permit NC0005363
Renewal Application
Figure 4-3 Flows, Sources of Pollution, and Treatment Technologies - 2009 NPDES
Permit NC0005363 Renewal Application
Figure 4-4 Cooling Pond Inflows and Outflows - 2014 NPDES Permit NC0005363
Renewal Application
Figure 4-5 Flows, Sources of Pollution, and Treatment Technologies - 2014 NPDES
Permit NC0005363 Renewal Application
Figure 4-6 Potential Discharges Not Covered by Analysis - 2009 NPDES Permit
NC0005363 Renewal Application
Figure 4-7 Potential Discharges Not Covered by Analysis - 2014 NPDES Permit
NC0005363 Renewal Application
Figure 4-8 1958 Aerial Photograph
Figure 4-9 Plant Utility Piping Survey of Ash Basin
Figure 5-1 Cooling Pond Assessment Sample Locations
LIST OF TABLES
Table 2-1 NPDES Compliance Well Groundwater Monitoring Requirements
Table 5-1 Water Sample Parameters and Analytical Methods
Table 5-2 Sediment Sample Parameters and Analytical Methods
LIST OF APPENDICES
Appendix A NCDWR Request for Cooling Pond Assessment
Appendix B NPDES Permit NC0005363
Appendix C 2009 NPDES Permit NC0005363 Renewal Application
Appendix D 2014 NPDES Permit NC0005363 Renewal Application
Appendix E 2015 Water Use Report
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ACRONYMS
BOD
biochemical oxygen demand
CAP
Corrective Action Plan
CCR
coal combustion residuals
COD
chemical oxygen demand
CPCM
cooling pond conceptual model
CSA
Comprehensive Site Assessment
DWR
Division of Water Resources
FDR
field data record
IMAC
Interim Maximum Allowable Concentrations
MGY
million gallons per year
msl
mean sea level
NCDEQ
North Carolina Department of Environmental Quality
NPDES
National Pollutant Discharge Elimination System
NTUs
Nephelometric Turbidity Units
ORP
oxidation-reduction potential
PLM
polarized light microscopy
QA/QC
quality assurance/quality control
SCM
site conceptual model
SWAP
Source Water Assessment Program
TDS
total dissolved solids
TOC
total organic carbon
TSS
total suspended solids
USGS
United States Geological Survey
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Proposed Cooling Pond Assessment Work Plan August 2016
W.H. Weatherspoon Power Plant SynTerra
EXECUTIVE SUMMARY
Duke Energy Progress, LLC (Duke Energy), owns and operates the W.H. Weatherspoon
Power Plant (Weatherspoon Plant), located near Lumberton, in Robeson County, North
Carolina. Coal ash residue from the coal combustion process was placed in the Plant's
ash basin which is permitted by the North Carolina Department of Environmental
Quality (NCDEQ) Division of Water Resources (DWR) under the National Pollutant
Discharge Elimination System (NPDES).
DWR requests that Duke Energy provide data and conduct additional site assessment
to characterize the distribution of coal combustion residuals (CCR) at potential coal ash
disposal areas including the Weatherspoon Plant cooling pond (Appendix A). The
cooling pond assessment will supplement the on-going Weatherspoon Plant
Comprehensive Site Assessment (CSA). Similarly, this Proposed Cooling Pond
Assessment Work Plan is a standalone update to the Weatherspoon Plant CSA
Groundwater Assessment Work Plan (SynTerra, December 2014).
DWR also requests that Duke Energy provide updated facility site maps with the
revised waste boundaries and proposed compliance boundaries established according
to 15A NCAC 02L Section .0107 (Appendix A). The updated facility site map with the
revised waste boundaries and proposed compliance boundaries is presented in Figure
ES -1.
The content of this work plan includes the following:
07 Descriptions of the Weatherspoon Plant, the coal ash basin, and the cooling
pond;
161, NPDES permit NC0005363 (Appendix B) and highlights of pertinent permit
requirements;
EP A summary of receptor information presented in the CSA Report and the
baseline human health and ecological risk assessment presented in Corrective
Action Plan (CAP) Part 1 Report;
41, A description of the regional geology and hydrology; and
101 An interim cooling pond conceptual model that details cooling pond inflows,
outflows, hydraulics, potential chemical constituents introduced into the cooling
pond, and potential mechanisms for coal ash and coal transport to the cooling
pond.
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This work plan includes the following tasks:
01 Collect twenty three water samples from the locations indicated on Figure ES -2
for inorganic analysis by the Duke Energy Analytical Laboratory;
0' Collect thirty-two sediment core samples from the locations indicated on Figure
ES -2 for polarized light microscopy (PLM) analysis to determine the presence or
absence of coal ash. PLM analysis will be conducted by a subcontractor
laboratory;
,6' Collect thirty-two sediment grab samples from the locations indicated on Figure
ES -2 for inorganic analysis by the Duke Energy Analytical Laboratory;
161, Install a total of six groundwater monitoring wells at three locations on the
cooling pond dike (Figure ES -2). One groundwater well at each of the three well
pair locations will be screened in the shallow surficial (Coastal Plain surficial
deposits) aquifer and the other groundwater well will be screened in the lower
surficial (Yorktown Formation) aquifer; and
01 Collect groundwater samples from the six proposed groundwater wells and
three existing piezometers installed in the cooling pond dike (Figure ES -2) for
inorganic analysis by the Duke Energy Analytical Laboratory.
Water and sediment samples collected from the cooling pond and the onsite pond
(background location) will be collected from a boat. Surface water and sediment
samples collected from the Lumber River and Jacob Creek will be collected from the
shoreline. Sediment cores of approximately 1 foot in length will be collected manually
using a core retrieval device. Mechanical core collection (e.g., Geoprobeo from barge)
may be warranted if coal ash is determined to be present at depths beyond the
capability of manual coring devices.
PLM analysis conducted on the sediment cores will determine the percent composition
that is comprised of coal ash. Results of PLM analyses will be used to map the
distribution of coal ash, if present, in the cooling pond.
Wastewater, surface water, groundwater, and sediment grab samples will be submitted
to the Duke Energy analytical laboratory for inorganic analysis. Analytical results for
samples collected from the cooling pond, Lumber River, Jacob Creek, unnamed onsite
pond, groundwater will be compared to determine if discernable differences in water
quality exist across waterbodies.
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The proposed assessment activities will be conducted in general conformance with the
CSA Work Plan, Rev. 1, December 2014. Fieldwork for the cooling pond assessment
will commence within approximately 45 days following NCDEQ final approval of this
work plan. The information obtained through this Work Plan will be used to prepare a
Comprehensive Site Assessment (CSA) Supplemental Report 2 that presents field
observations, analytical data, revisions to the cooling pond conceptual model, and
conclusions regarding the presence or absence of CCR in the cooling pond. The CSA
Supplemental Report 2 will be submitted to NCDEQ approximately 60 days following
receipt and validation of all analytical data.
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1.0 INTRODUCTION
Duke Energy Progress, LLC (Duke Energy), owns and operates the W.H. Weatherspoon
Power Plant (Weatherspoon Plant), located near Lumberton, in Robeson County, North
Carolina (Figure 1-1). The Weatherspoon Plant became operational in 1949 with a
Babcock & Wilcox boiler (Unit 1). Two additional coal-fired electricity -generating units
(Units 2 and 3) were added in 1950 and 1952 (E-mail correspondence, July 2016). Four
oil and natural gas fueled combustion turbines were added in the 1970s. The coal-fired
units were retired in October 2011. The combustion turbines continue to generate
electricity at the Weatherspoon Plant.
The coal ash residue from the coal combustion process was placed in the Plant's coal
ash basin. The discharge from the ash basin to the Lumber River via the cooling pond is
permitted by the North Carolina Department of Environmental Quality (NCDEQ)
Division of Water Resources (DWR) under the National Pollutant Discharge
Elimination System (NPDES).
DWR requests that Duke Energy provide data and conduct additional site assessment
as needed to characterize the distribution of coal combustion residuals (CCR) at
confirmed and potential coal ash disposal areas including the Weatherspoon Plant
cooling pond (Appendix A). The cooling pond assessment will supplement the on-
going Weatherspoon Plant Comprehensive Site Assessment (CSA). Similarly, this
Cooling Pond Assessment Work Plan is a standalone update to the Weatherspoon Plant
CSA Groundwater Assessment Work Plan (SynTerra, December 2014). The information
obtained following execution of this Work Plan will be presented in a CSA
supplemental report.
DWR also requests that Duke Energy provide updated facility site maps with the
revised waste boundaries and proposed compliance boundaries established according
to 15A NCAC 02L Section .0107 (Appendix A). The updated facility site map with the
revised waste boundaries and proposed compliance boundaries is presented in Figure
1-2. The compliance boundaries are established 500 feet from the coal ash basin waste
boundary and 500 feet from the Weatherspoon Plant NPDES waste treatment unit (e.g.,
cooling pond) or the property boundary if the property boundary is within 500 feet of
the coal ash basin waste boundary or cooling pond boundary.
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2.0 SITE INFORMATION
2.1 Plant Description
The Weatherspoon Plant is a former coal-fired electricity -generating facility located in
Robeson County, North Carolina, near the City of Lumberton (Figure 1-1). The
Weatherspoon Plant started operations in 1949 with a Babcock & Wilcox boiler. Two
additional coal-fired units were added in the 1950s. Four oil and natural gas fueled
combustion turbines were added in the 1970s.
All of the coal-fired units were retired as of October 2011. The four oil and natural gas
fueled units continue to operate to meet peak demand. The facility is located southeast
of Lumberton on the east side of North Carolina Highway 72. The topography around
the property generally slopes downward toward the Lumber River.
The Weatherspoon Plant utilizes an approximate 225 -acre cooling pond located adjacent
to the Lumber River. Coal ash generated by the coal-fired electricity -generating units
was placed in the Plant's 55 -acre ash basin located north of the cooling pond and
northeast of the Plant. The Plant, cooling pond, and ash basin are located on the east
side of the Lumber River (Figure 1-2).
2.2 Ash Basin Description
The Weatherspoon Plant's only coal ash basin contains approximately 1,700,000 tons of
ash (Duke Energy, 2014). Ash is no longer generated at the site and Duke Energy is in
the process of evaluating closure options for the ash basin. The coal ash basin 500 foot
compliance boundary is shown on Figure 1-2.
Circa 1949 to 1955, ash was sluiced to a low area that was eventually encompassed by
the existing ash basin (Figure 2-1). The ash basin was constructed in phases using a
combination of basin excavation and earthen dike construction beginning in 1955.
Additional excavation and earthen dikes were constructed to the south of the original
basin as the Plant expanded and ash volume increased. The last of the perimeter
earthen dikes was constructed in 1979. The basin was also expanded vertically in the
northern portion of the basin by the use of interior dikes constructed of ash. Interior
ash dike construction began in 2001 (S&ME, 2012).
Ash historically generated from coal combustion was transferred to the ash basin via
sluicing. No other types of waste are believed to have been placed in the ash basin
other than permitted infrequent low volume wastes. The NPDES permitted discharge
from the ash basin to the cooling pond occurred at the northeast corner of the cooling
pond. According to Duke, ash has not been stored or placed elsewhere on or near the
site other than possible de minimis quantities at unknown locations.
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W.H. Weatherspoon Power Plant SynTerra
2.3 Cooling Pond Description
The cooling pond did not exist in 1949 when the Weatherspoon Plant became
operational. An aerial photograph taken in 1951 shows that an engineered channel was
constructed that connected two bends in the meandering Lumber River southwest of
the Weatherspoon Plant (Figure 2-1). The natural Lumber River channel appears to
have been severed by an engineered dam where the river water intake to the cooling
pond currently exists. The Lumber River on the north side of the engineered dam likely
served as the cooling water intake and the Lumber River channel south of the
engineered dam likely served as the heat sink or cooling water discharge.
The area where the cooling pond is now located appears to have been either mature
undeveloped woodlands or wetlands. It also appears that Jacob Creek channel flowed
northeast to southwest through the northeast arm of the current cooling pond and
discharged to the Lumber River near the southern most portion of the current cooling
pond (Figure 2-1). A United States Geological Survey (USGS) topographic map
recorded in 1957 identifies the cooling pond as the "Plant Cooling Lake" (Figure 2-2).
Therefore, the cooling pond appears to have been constructed between 1951 and 1957.
2.4 Regulatory Requirements
Wastewater discharge to surface waters of the state are regulated by the NCDEQ
NPDES program. The Weatherspoon Plant is permitted to discharge wastewater from
the cooling pond to the Lumber River under NPDES Permit NC0005363 (Appendix B).
Two outfalls, 001 and 002, are identified in the 2009 NPDES permit NC0005363 renewal
application (Figure 2-3; Appendix C). The permit authorizes the discharge of
recirculated cooling water, ash sluice water, domestic wastewater, chemical metal
cleaning water, and categorical low volume wastewater from the cooling pond via
cooling pond Outfall 001 to the Lumber River under severe weather conditions and
pond maintenance in accordance with effluent limitations, monitoring requirements,
and other conditions set forth in the permit. In addition, non -contact cooling water
from heat exchanger units was discharged to the Lumber River via Outfall 002.
However, the discharge of non -contact cooling water (Outfall 002) ceased following the
retirement of plant coal-fired units in October 2011. Consequently, the Outfall 002
discharge structure was capped and Outfall 001 is the only outfall listed in the 2014
NPDES permit NC0005363 renewal application (Figure 2-4; Appendix D).
Cooling pond discharges to the Lumber River via Outfall 001 will only occur:
,67 When a major storm is expected and additional freeboard is needed to prevent
overtopping of pond dikes; or
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41P When a release is necessary for maintenance purposes.
The last known discharge via Outfall 001 occurred in September 1999 (Appendix D; E-
mail correspondence, July 2016).
The NPDES permitting program requires that permits be renewed every five years. The
existing NPDES permit renewal for the Weatherspoon Plant became effective on
January 1, 2010 and expired on July 31, 2014. That permit has been administratively
continued due to Duke Energy's timely submittal of a renewal application submitted on
January 28, 2014 (E-mail correspondence, August 2016).
NPDES permit NC0005363 requires groundwater monitoring at the ash basin
compliance boundary. The compliance boundary for groundwater quality at the
Weatherspoon Plant ash basin is defined in accordance with Title15A NCAC 02L
.0107(a) as being established at either 500 feet from the waste boundary or at the
property boundary, whichever is closer to the waste. The location of the ash basin
compliance monitoring wells, the coal ash basin waste boundary, and the coal ash basin
compliance boundary are shown on Figure 1-2.
Currently, Duke Energy conducts routine compliance boundary monitoring during
March, June, and October each year for the parameters listed in Table 2-1. At the
direction of NCDEQ, Duke has adjusted the parameter list to support the CSA process
as of June 2015. The most current NPDES groundwater monitoring data is presented in
the CSA Supplement 1 (SynTerra, July 2016).
2.5 Receptor Information
SynTerra has conducted a receptor survey to identify potential receptors including
public and private water supply wells (including irrigation wells and unused or
abandoned wells) and surface water features within a 0.5 -mile radius of the
Weatherspoon Plant coal ash basin compliance boundary.
SynTerra presented the results of the receptor survey in two separate reports. The first
report included the results of a review of publicly available data from NCDEQ,
Department of Environmental Health, NC OneMap GeoSpatial Portal, DWR Source
Water Assessment Program (SWAP) online database, county geographic information
system, Environmental Data Resources, Inc. Records Review, the USGS National
Hydrography Dataset, as well as a vehicular survey along public roads located within
0.5 mile radius of the coal ash basin compliance boundary (SynTerra, September 2014).
The second report supplemented the initial report with additional information obtained
from questionnaires sent to owners of property within the 0.5 mile radius of the coal ash
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basin compliance boundary (SynTerra, November 2014). The report included a
sufficiently scaled map showing the ash basin location, the facility property boundary,
the coal ash basin compliance boundary, all monitoring wells, and the approximate
location of identified water supply wells. A table presented available information about
identified wells including the owner's name, address of well location with parcel
number, construction and usage data, and the approximate distance from the coal ash
basin compliance boundary.
The receptor survey within 0.5 mile radius of the coal ash basin compliance boundary
was updated on July 28, 2016 via vehicle survey on public roads within the 0.5 mile
radius area. No new supply wells were identified. A report of this receptor survey
findings is pending.
NCDEQ has managed groundwater sample collection from two nearby water supply
wells. The groundwater samples were collected from wells W-02 and W-06 in March
2015 and April 2015, respectively. Analytical results indicate that nearby water supply
wells sampled by DEQ have not been impacted by migration of coal ash constituents
from the coal ash basin (SynTerra, July 2016). Details of water supply wells within 0.5
mile radius of the coal ash basin compliance boundary is presented in Appendix B of
the CSA Report (SynTerra, August 2015).
2.6 Risk Assessment
Screening level human health and ecological risk assessments were conducted during
the CSA and the results are presented in Section 12.0 of the CSA Report (SynTerra,
August 2015). Human health and ecological baseline risk assessments were
subsequently conducted and the results were presented in Section 5.0 of the Corrective
Action Plan (CAP) Part 2. The only on-site scenario where coal ash constituents of
potential concern potentially posed unacceptable risk to human health was the adult
commercial/industrial worker exposed to arsenic in seep soil. Exposure to on-site Jacob
Creek surface water and sediment under the on-site adolescent trespasser scenario did
not pose unacceptable non -carcinogenic or carcinogenic human health risk (SynTerra,
February 2016). The cooling pond is a wastewater treatment unit. Consequently,
human exposure to cooling pond wastewater, sediment, or fish were not considered in
the baseline risk assessment.
The only off-site scenario where coal ash constituents posed potentially unacceptable
risk to human health involved adult and child consumption of fish caught from the
Lumber River under the subsistence fisher scenario. Antimony in fish tissue derived
from fish uptake and bioconcentration modeling resulted in a potentially unacceptable
non -carcinogenic health risk to children under this scenario. However, antimony in
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Lumber River surface water was detected at a higher concentration in the surface water
sample collected upstream relative to the Weatherspoon Plant. Consequently, the
potential non -carcinogenic health risk to children posed by antimony in Lumber River
surface water under the subsistence fisher risk scenario is not attributable to the
Weatherspoon Plant (SynTerra, February 2016).
The baseline ecological risk assessment identified potential risks to terrestrial herbivores
from aluminum, molybdenum and selenium and terrestrial omnivores and carnivores
from molybdenum and selenium in seeps and seep soils immediately surrounding the
ash basin. These potential risks were based upon hazard quotients derived using
lowest -observed -adverse -effects -levels or LOAEL. Similarly, potential risks to
terrestrial herbivore exposure to molybdenum and selenium and terrestrial omnivore
and carnivore exposure to selenium in the same area were identified based upon hazard
quotients derived using no -observed -adverse -effects -levels or NOAEL. No other areas
on or off site indicated potential risks to wildlife (SynTerra, February 2016). Wildlife
exposure to cooling pond waste water, sediment, or fish were not considered in the
ecological baseline risk assessment.
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3.0 REGIONAL GEOLOGY AND HYDROGEOLOGY
The vicinity of the Weatherspoon Plant is generally characterized by shallow water
table conditions occurring in surficial soils and unconsolidated sediments underlain by
Coastal Plain regional aquifer system. The following sections contain a synopsis of the
geologic and hydrogeologic characteristics of the area.
The North Carolina Coastal Plain is approximately 90 to 150 miles wide from the
Atlantic Ocean westward to its boundary with the Piedmont province (Winner and
Coble, 1989). Two natural subdivisions (Tidewater Region and Inner) of the Coastal
Plain were described by Stuckey (Stuckey, J.L., 1965). The Weatherspoon Plant is
located within the Inner Coastal Plain, which consists of the gently rolling land surface
between the Tidewater region and the Fall Line (Winner and Coble, 1989).
3.1 Regional Geology
The Coastal Plain comprises a wedge shaped sequence of stratified marine and non -
marine sedimentary rocks deposited on crystalline basement. Coastal Plain aquifers are
comprised of permeable sands, gravels, and limestone separated by confining units of
less permeable sediment. In this region, units of confined aquifers divided by confining
layers overlay the crystalline bedrock. The confining units at the top of these aquifers
consist of laterally extensive silt and clay rich layers. The Lower Cape Fear and Upper
Cape Fear aquifers are the lower-most (deepest) marine sediment units in Robeson
County (Winner and Coble, 1989). The Upper Cape Fear aquifer is overlain by the
Black Creek aquifer which is in turn overlain by the Pee Dee aquifer. In the Inner
Coastal Plain region, the confining unit between the Pee Dee aquifer and the overlying
Yorktown or Coastal Plain deposits (the surficial aquifer) is reported to be
discontinuous, meaning that the Yorktown and Pee Dee are semi -confined aquifers. A
detailed description of the regional geology is presented in Section 5.1 of the CSA
Report (SynTerra, August 2015).
3.2 Regional Hydrogeology
Groundwater is obtained from the surficial, Yorktown, Pee Dee, and Black Creek
aquifers in Robeson County. According to Winner and Coble (1989), the surficial
aquifer consists primarily of fine sands, clays, shells, peat beds, and scattered deposits
of coarse-grained material in the form of relic beach ridges and floodplain alluvium.
The areal extent of the surficial aquifer in the Coastal Plain is approximately 25,000
square miles with an average thickness of 35 feet. Average recharge to the surficial
aquifer is between 12 and 20 inches per year. The average estimated hydraulic
conductivity is 29 feet per day (Winner and Coble, 1989).
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The surficial aquifer in the vicinity of Weatherspoon is comprised of approximately 60
feet of Coastal Plain and Yorktown Formation sediments. It is the first saturated zone
underlying the land surface and the first aquifer to receive recharge from precipitation.
The recharge water is stored in the surficial aquifer as the groundwater migrates toward
local discharge points (lakes, rivers, streams, etc.). A portion of the groundwater in the
surficial aquifer migrates vertically to recharge semi -confined aquifers. On average,
only a fraction of the surficial aquifer recharge reaches the semi -confined aquifers due
to the substantial amount of time it takes for groundwater to reach these units (Giese et
al., 1997).
The Pee Dee confining unit, with an average thickness of 25 feet across the region,
underlies the surficial aquifer (Giese et al., 1997). The Pee Dee aquifer is composed of
fine to medium grained sand interbedded with gray to black marine clay and silt (Giese
et al., 1997). Shells are common throughout the aquifer. The aquifer thickness ranges
from 10 feet at its eastern edge to greater than 300 feet (Giese et al., 1997).
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4.0 COOLING POND CONCEPTUAL MODEL
Hydrogeologic and geochemical site conceptual models (SCMs) were developed for the
coal ash basin in Section 6.0 of the CSA Report (SynTerra, August 2015). An interim
cooling pond conceptual model (CPCM) has been developed based upon historical
knowledge of the cooling pond, the hydrogeologic SCMs developed in the CSA Report,
and ongoing cooling pond operations. The CPCM will be refined as needed as
additional site-specific information is obtained during the cooling pond assessment
process.
4.1 Physical Site Characteristics
Topography at the site ranges from approximately 140 feet above mean sea level (msl)
north of the site to approximately 110 feet msl at the cooling pond to the south and the
Lumber River to the west.
Based upon historical aerial photographs and historical topographic maps, the cooling
pond was constructed between March 1951 and 1957. A March 1951 aerial photograph
shows undisturbed mature woodlands and wetlands in the area where the cooling
pond now exists. Jacob Creek is observed meandered through the areas where the
northeast arm and the southern lobe of the cooling pond now exist (Figure 2-1). Jacob
Creek was redirected to the existing streambed during construction of the cooling pond.
Jacob Creek now flows between the eastern earthen berm of the cooling pond and the
Weatherspoon Plant eastern property boundary (Figure 1-2).
There are no standing trees or stumps protruding above the cooling pond surface at
typical water levels. Consequently, it appears that the area has been cleared of trees
and vegetation before the cooling pond was filled.
4.2 Source Characteristics
The focus of the cooling pond assessment is whether coal ash is present in the cooling
pond. The physical and chemical characteristics of coal ash are detailed in Sections 3.2
and 3.3 of the CSA Report (SynTerra, August 2015).
4.3 Site Hydrogeology
Topography at the site ranges from approximately 140 feet above mean sea level (msl)
north of the site to approximately 110 feet msl at the cooling pond to the south and the
Lumber River to the west. Jacob Creek flows south, toward the Lumber River, along
the east side of the cooling pond. The Lumber River and Jacob Creek act as discharge
areas with respect to groundwater flow.
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Four layered geologic units (Coastal Plain surficial deposits, Yorktown Formation, Pee
Dee Formation, and Black Creek Formation) were encountered in exploratory borings
installed at the site during the CSA field investigation.
The surficial unconfined aquifer is the first major hydrostratigraphic unit at the
Weatherspoon site. The upper portion of this aquifer consists of thin isolated deposits
of sub -angular to well-rounded gravel alluvium or Coastal Plain surficial deposits that
consist of black, gray, brown, light red, tan, or white silty fine sand, sandy silt, clayey
silt, or sandy clay. These deposits vary in thickness from approximately 3 to 30 feet.
The lower portion of the surficial aquifer consists of Yorktown deposits (identified
based on the characteristic color and content described for the formation) that range
from approximately 14 to 35 feet thick.
The Yorktown deposits at Weatherspoon consist of blue, green, gray, and white
fossiliferous sand and sandy silty clay. A clay rich confining unit, which appears to be
continuous across the site separates the Yorktown deposits from the underlying Pee
Dee sediments. The Coastal Plain surficial deposits and the Yorktown Formation are
pertinent to cooling pond hydrology. Details pertaining to the hydrogeology and
physical characteristics of confined water bearing units at the Weatherspoon Plant are
presented in Section 6.2 of the CSA Report (SynTerra, August 2015).
The surface of groundwater (water table) at Weatherspoon is typically located at depths
of three to 10 feet below ground surface, depending on antecedent precipitation and
topography. The surficial aquifer groundwater flow regime of the Weatherspoon Plant
is bounded on the southwest by the Lumber River and to the south and east by the
cooling pond and Jacob Creek (Figure 4-1). Based on site topography, groundwater on
the eastern side of Jacob Creek would be expected to flow west toward the creek. Ash
pore water contained within the coal ash basin is mounded above the underlying
Coastal Plain surficial deposits and the Yorktown Formation and is discharged from the
ash basin to unconfined groundwater as well as seeps above the ground surface.
4.4 Cooling Pond Construction
The cooling pond did not exist in 1949 when the Weatherspoon Plant became
operational. An aerial photograph taken in 1951 shows that an engineered channel was
constructed that connected two bends in the meandering Lumber River southwest of
the Weatherspoon Plant (Figure 2-1). The area where the cooling pond is now present
appears to have been either mature undeveloped woodlands or wetlands. It also
appears that Jacob Creek channel flowed northeast to southwest through the northeast
arm of the current cooling pond and discharged to the Lumber River near the southern
most portion of the current cooling pond. A USGS topographic map recorded in 1957
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(Bladenboro Quadrangle; Series: 15 and 1:62,500 scale) identifies the cooling pond as the
"Plant Cooling Lake" (Figure 2-2). Therefore, the cooling pond appears to have been
constructed between 1951 and 1957.
Construction of the cooling pond required clearing of the mature trees and vegetation
as well as rerouting Jacob Creek to flow along the eastern perimeter of the current
cooling pond. It appears reasonable that soil excavated during the rerouting and
construction of the Jacob Creek channel was likely used to construct the cooling pond
dike that separates the cooling pond and Jacob Creek. However, the soil used to create
the interior cooling pond dikes and the western cooling pond perimeter dike was likely
obtained from within the cooling pond during construction or from a borrow source.
4.5 Cooling Pond Hydraulics
The cooling pond water level is maintained between 108.5 feet and 109.5 feet above msl.
If the cooling pond water level drops below 108.5 feet msl, the cooling pond intake
pump loses suction and cooling pond makeup water is transferred from the Lumber
River to raise the cooling pond water level up to 109.5 feet msl. The freeboard available
for heavy rain events is 2.5 feet when the cooling pond level is 109.5 feet msl. The last
known NPDES discharge from the cooling pond to the Lumber River via Outfall 001
occurred in September 1999 due to rainfall associated with Hurricane Floyd (E-mail
correspondence, July 2016).
Under normal operating conditions, the maximum water elevation of the cooling pond
is 109.5 feet msl whereas the elevation of lower Jacob Creek surface water before
discharging to the Lumber River was measured and recorded to be 102.90 feet msl on
July 13, 2016. Consequently, the typical maximum depth of the cooling pond is
estimated to be approximately 7 feet or less during periods of average (seasonal)
precipitation. This assumes that the depth of soil excavation within the cooling pond
during construction of perimeter and interior dike construction did not extend
significantly below the water table. Measuring and recording water depths throughout
the cooling pond will be completed during the cooling pond assessment.
4.5.1 Cooling Pond Inflows
Inputs to the cooling pond are variable and can change from day to day and year
to year. This variability is demonstrated by the inflows and outflows listed in the
2009 and 2014 NPDES Permit NC0005363 renewal applications (Figures 4-2
through 4-5; Appendices C and D). Inflows presented in the sections that
follows are categorized as being either predominantly non -anthropogenic
sources or anthropogenic sources. Predominantly non -anthropogenic sources of
inflow, precipitation and makeup water from the Lumber River, are discussed in
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Section 4.5.1.1. Anthropogenic sources of inflow include process discharges to
the cooling pond and other discharges that are potentially impacted by residual
waste (e.g., surface water runoff and groundwater discharge containing site
related constituents). Anthropogenic sources of inflow to the cooling pond are
discussed in Section 4.5.1.2.
4.5.1.1 Predominantly Non -Anthropogenic Inflows
Predominantly non -anthropogenic sources of inflow include precipitation
and makeup water from the Lumber River. Average annual precipitation
in Lumberton is approximately 47.7 inches per year (usclimatedata.com,
July 30, 2016). Based upon this rate of annual precipitation, it is
conservatively estimated that annual precipitation contributes
approximately 290 million gallons of water to the cooling pond per year.
This estimate is based only on the amount of precipitation that occurs
within the total area of the cooling pond (225 acres) and does not include
surface water runoff.
Duke Energy submits an Annual Water Use Report to the North Carolina
Division of Water Resources for the cooling pond makeup water
withdrawn from the Lumber River. The 2015 Annual Water Use Report
submitted to the North Carolina Division of Water Resources by Duke
Energy indicates that the volume of water pumped from the Lumber
River to the cooling pond in 2015 was approximately 34.8 million gallons
(Appendix E).
The total estimated cooling pond inflows from annual precipitation (290
million gallons) and makeup water withdrawn annually from the Lumber
River (34.8 million gallons) is approximately 325 million gallons of water
per year.
4.5.1.2 Anthropogenic Inflows
Anthropogenic sources of inflow to the cooling pond include process
discharges and other discharges that are potentially impacted by residual
waste (e.g., surface water runoff and groundwater discharge containing
site related constituents).
The anthropogenic sources of inflow to the cooling pond listed in the 2014
NPDES Permit NC0005363 renewal application (Figures 4-4 and 4-5) are
summarized below and are presented as million gallons per year (MGY):
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Source
Estimated
Avg. Flow
Comments
C/D
0.073 MGY
Potable groundwater used for sanitary wastes
E
51.1 MGY
Oil/water separator discharge (oily wastes)*
G
69.4 MGY
Storm water runoff
H
4.0 MGY
Oil/water separator discharge (fuel oil remediation and
combustion turbine drains)
124.6 MGY
I Total cooling pond inflows from anthropogenic sources
* This inflow has since been eliminated (E-mail correspondence, August 2016).
Unconfined groundwater on the southernmost sides of the coal ash basin
flows south toward the cooling pond (Figure 4-1). Unconfined
groundwater flows from the coal ash basin likely discharges into the
cooling pond from a portion of the former Jacob Creek streambed. The
length of shoreline where groundwater is flowing towards the cooling
pond is estimated to be approximately 4,300 feet. In contrast, the length of
shoreline where cooling pond water is migrating into Jacob Creek and the
Lumber River via seepage is estimated to be approximately 12,300 feet.
Therefore, it appears likely that groundwater inflow is easily offset by
cooling pond outflow via seepage to Jacob Creek and the Lumber River.
Excluding the contribution of groundwater discharging into the cooling
pond, total inflows to the cooling pond from non -anthropogenic sources
(325 MGY) and anthropogenic sources (124.6 MGY) is approximately 450
MGY. Consequently, anthropogenic inflows comprise approximately 28
percent of the total inflows into the cooling pond with the balance being
made up by inflows from predominantly non -anthropogenic sources
(Section 4.5.1.1). This suggests that the concentration of highly soluble
constituents introduced into the cooling pond by anthropogenic sources
(e.g., boron) would be attenuated by means of dilution and flushing from
the cooling pond.
4.5.2 Cooling Pond Outflows
Three cooling pond outflows are listed in the 2014 NPDES Permit NC0005363
renewal application (Figures 4-4 and 4-5); discharge from the cooling pond to the
Lumber River via outfall 001, evaporation, and seepage. The outflow via Outfall
001 is listed as 0 MGD because the cooling pond is maintained at levels that are
capable of containing most precipitation events (Section 4.5). The last known
NPDES discharge from the cooling pond to the Lumber River via Outfall 001
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occurred in September 1999 due to rainfall associated with Hurricane Floyd (E-
mail correspondence, July 2016). Cooling pond outflow due to evaporation and
seepage is estimated to be 0.7 MGD or 256 MGY (Figures 4-4 and 4-5).
4.5.3 Hydraulic Residence Time
Hydraulic residence time, as it pertains to the cooling pond, is a measure of the
time that the volume of water in the cooling pond is replaced by an equal volume
of inflow. The hydraulic residence time of the cooling pond is calculated using
the following formula:
T= V/q
Where:
T = hydraulic residence time (years);
V = volume (gallons); and
q = volumetric flow rate (gallons/year)
Assuming that the area of the cooling pond is 9.8 million square feet (225 acres)
and the average depth is 3.5 feet, the cooling pond hydraulic capacity (V) is 256.6
million gallons of water.
If only inflows from Lumber River makeup water and precipitation to the
cooling pond are considered (Section 4.5.1.1), then the hydraulic residence time
(T) of the cooling pond is calculated to be:
256.6 million gallons = 0.79 years or 9.5 months
(34.8 + 290 million gallons/year)
Based upon this analysis, the cooling pond volume could have been replaced
with makeup water from the Lumber River and precipitation approximately 6
times since the coal-fired units were retired (October 2011 to July 2016).
If all estimated inflows to the cooling pond are considered, except for the inflow
contribution of groundwater, the hydraulic residence time (T) of the cooling
pond is calculated to be:
256.6 million gallons = 0.57 years or 6.9 months
(34.8 + 290 + 124.6 million gallons/year)
Based upon this analysis, the cooling pond volume could have been replaced
with water from non -anthropogenic and anthropogenic inflow sources
approximately 8.3 times since the coal-fired units were retired (October 2011 to
July 2016).
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4.6 Chemical Constituents Introduced Into The Cooling Pond by
Anthropogenic Sources
Potential discharges to the cooling pond listed in the 2009 and 2014 NPDES Permit
NC0005363 renewal applications that are not covered by chemical analysis under the
permit are presented in Figures 4-6 and 4-7, respectively. A comparison of the two
permit lists suggests that potential discharges to the cooling pond not covered by
chemical analysis under the permit has been significantly reduced since the coal-fired
units were retired in October 2011.
4.7 Potential Mechanisms For Coal Ash Transport To Cooling Pond
It appears that coal ash was managed in the area where the coal ash basin is currently
located prior to construction of the cooling pond. A 1951 aerial photograph shows a
cleared area northeast of Weatherspoon Plant operations and white trails connecting
disturbed (unvegetated) areas (Figure 2-1). In addition, a 1957 USGS topographic map
does not indicate the presence of an engineered coal ash basin (Figure 2-2). However, a
1958 aerial photograph clearly shows an engineered ash containment structure (Figure
4-8). If coal ash generated before construction of an engineered coal basin was managed
in a cleared area where the ash basin now exists, it is plausible that coal ash could have
been transported via surface water runoff to low lying areas including the cooling pond,
pre- and post -construction.
Particulate emissions from the coal-fired power plant stack would have occurred when
power generation operations began in 1949 until air emission control mechanisms were
installed. Consequently, it is plausible that some airborne deposition of coal ash into
the cooling pond occurred as a result of stack emissions. Similarly, it is plausible that
coal ash from the coal ash basin became airborne on windy days and was deposited into
the cooling pond.
Coal ash generated during coal fired power production was sluiced to the coal ash
basin. The sluice water accumulated in the coal ash basin until it infiltrated into the
underlying groundwater or was discharged from the coal ash basin. Sluice water was
discharged from the coal ash basin via the stilling basin located in the eastern corner of
the ash basin dike. Water within the stilling basin accumulated until it reached the level
of an overflow pipe which directed the discharge to the northeast arm of the cooling
pond by way of a 24 -inch diameter reinforced concrete decanting pipe (Figure 4-9). It is
plausible that some amount of coal ash in the sluice water could have been
inadvertently discharged to the cooling pond.
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Other than incidental transport of coal ash to the cooling pond via the mechanisms
discussed in this section, there are no known releases of coal ash from the coal ash basin
to the cooling pond.
4.8 Cooling Pond Analytical Data
The only analytical data available associated with the cooling pond is an analysis of a
grab cooling pond water sample used for preparation of the NPDES Permit NC0005363
renewal application submitted on January 28, 2014 (Appendix D) and a cooling pond
grab water sample collected near Outfall 001 on March 12, 2014 (E-mail correspondence,
August, 2016). The cooling pond grab water sample submitted for the NPDES permit
renewal application was analyzed for a range of water quality parameters and
pollutants including:
�1 Biochemical oxygen demand (BOD), chemical oxygen demand (COD), total
organic carbon (TOC), total suspended solids (TSS), ammonia, pH;
0 Metals, cyanide, and total phenols;
41, Volatile compounds; and
,67 Base/neutral compounds.
Analysis of the cooling pond water sample resulted in non -detections for all but the
following parameters:
Parameter
Analytical
Result
pH
6.8
su
BOD
3.1
mg/L
TOC
6.38
mg/L
Total iron
0.11
mg/L
Total antimony
0.005
mg/L
Total arsenic
0.006
mg/L
Total copper
0.004
mg/L
Total nickel
0.006
mg/L
su - standard units
The cooling pond grab water sample collected near Outfall 001 was analyzed for the
following inorganic constituents (E-mail correspondence, August, 2016):
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Parameter
Analytical
Result
Parameter
Analytical
Result
Chloride
15
mg/L
Total manganese
0.01
mg/L
Fluoride
< 1
mg/L
Total antimony
0.00415
mg/L
Sulfate
78
mg/L
Total arsenic
0.00214
mg/L
Total aluminum
0.047
mg/L
Total cadmium
< 0.001
mg/L
Total barium
0.093
mg/L
Total chromium
< 0.001
mg/L
Total boron
0.319
mg/L
Total lead
< 0.001
mg/L
Total calcium
22.9
mg/L
Total molybdenum
0.0224
mg/L
Total copper
< 0.005
mg/L
Total nickel
0.00501
mg/L_
Total hardness
73.9
mg/L*
Total selenium
0.00365
mg/L
Total iron
0.057
mg/L
Total zinc
0.00842
mg/L
Total magnesium
4.07
mg/L
TDS**
157
mg/L
* Total hardness expressed as mg/L CaCO3 (calcium carbonate)
** TDS - Total dissolved solids
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5.0 COOLING POND ASSESSMENT WORK PLAN
The scope of work discussed in this work plan is designed to meet the requirements of
15A NCAC 02L .0106(g) as it pertains to the cooling pond assessment. Aqueous and
solid media sampling will be performed to determine whether coal ash is present in the
cooling pond and, if present, the vertical and horizontal extent of coal ash within the
cooling pond. In addition, analytical results for samples collected from the cooling
pond, Lumber River, Jacob Creek, unnamed onsite pond, and groundwater will be
compared to determine if discernable differences in water quality exist across
waterbodies.
Six groundwater monitoring well installations are proposed at three locations on the
cooling pond dike (Figure 5-1). The installation of groundwater monitoring wells is
discussed in Section 5.1. Cooling pond assessment water and sediment sampling is
discussed in Sections 5.2 and 5.3, respectively. Quality assurance and quality control
procedures are discussed in Section 5.4.
5.1 Groundwater Monitoring Well Installation
Three groundwater monitoring well pairs will be installed along the cooling pond dike
at locations indicated in Figure 5-1. All proposed wells will be screened within the
upper or lower surficial (unconfined) aquifer. Each well pair will consist of a shallow
("S") well screened in Coastal Plain surficial deposits and an intermediate ("I") well
screened in underlying Yorktown Formation deposits.
5.1.1 Well Completion
Shallow and intermediate wells will be installed using rotary -sonic drilling. At
each location, intermediate wells will be the first followed by the installation of
the shallow well. A 6 -inch diameter sonic core barrel will be advanced to the
confining unit that separates the surficial aquifer and the first confined aquifer.
Continuous soil cores will be collected and evaluated to determine when Coastal
Plain surficial deposits, Yorktown Formation sand, and the confining unit are
encountered.
Intermediate wells will be constructed using five-foot pre -packed well screens
installed within the Yorktown Formation. Well casings will consist of two-inch
diameter NSF PVC schedule 40 flush -joint threaded casing. The annular space
between the borehole wall/inner casing and the pre -packed well screens for each
well will be filled with clean, well-rounded, washed, high-grade 20/40 mesh
silica sand. The sand pack will be installed to approximately 2 feet above the top
of the pre -packed screen, followed by the installation of an approximately 2 -foot
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pelletized bentonite seal above the sand pack. The remaining annular space will
be filled with a neat cement grout from the top of the upper bentonite seal to
near ground surface.
Shallow wells will be constructed in an identical manner as the intermediate
wells except that the boring will installed to a depth corresponding to the Coastal
Plain surficial deposit/Yorktown Formation interface. Shallow wells will be
constructed using five-foot pre -packed well screens centrally installed within
Coastal Plain sands.
Monitoring wells will be completed with steel flush -mount manholes with
locking expansion caps and well tags. Protective covers will be secured and
completed in a concrete collar and 2 -foot square concrete pad.
5.1.2 Well Development
Monitoring wells will be developed to remove drill fluids, clay, silt, sand, and
other fines that may have been introduced into the formation or sand pack
during drilling and well installation, and to establish communication of the well
with the aquifer. Well development will be performed using a portable
submersible pump, which will be repeatedly surged (moved up and down)
within the well screen interval until the water obtained is relatively clear.
Development will be continued by sustained pumping until monitoring
parameters (e.g., conductivity, pH, temperature) are stabilized and sample
turbidity decreases to acceptable levels (10 Nephelometric Turbidity Units or
NTUs). Well development will occur at least 24 hours after installation to allow
for grout cure time.
5.2 Wastewater and Surface Water Samples
Cooling pond wastewater samples and surface water samples from Jacob Creek,
Lumber River and unnamed onsite pond will be collected using either a new disposable
bailer or collected directly into unused sample bottle ware provided by the analytical
laboratory. If sampling from a boat, the bottle ware will be gently lowered into the
water until a portion of the bottle ware mouth is just below the water surface. Water
samples should not contain debris (e.g., leaves, grass, and surface sheen). Bottle ware
containing a preservative (e.g., acid) will be filled with the grab surface water sample
collected in bottle ware that does not contain a preservative.
5.2.1 Grab Water Samples
The following grab water samples will be collected in support of the cooling
pond assessment (Figure 5-1):
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E1, Fifteen grab water samples will be collected from the cooling pond (CP -1,
CP -2, CP -3, CP -4, CP -6, CP -7, CP -10, CP -12, CP -14, CP -16, CP -17, CP -19,
CP -20, CP -21, and CP -22). These samples will be collected from a boat;
47 A single grab surface water sample (LR -1) will be collected from the
Lumber River at the cooling pond makeup water intake. This sample will
be collected from the cooling pond makeup water intake structure by
lowering a new disposable bailer into the water by rope;
E1 Two background surface water grab samples (BG -1 and BG -2) will be
collected from the unnamed on-site pond (Figure 5-1). These samples will
be collected from a boat;
01 Two background surface water grab samples (BG -3 and BG -4) will be
collected from Jacob Creek. These samples will be collected from the
shoreline using a bailer; and
EP Three surface water grab samples will be collected from Jacob Creek (JC -1,
JC -2, and JC -3). These samples will be collected from the shoreline by
filling the sample bottleware directly or using a bailer.
The field parameters listed in Table 5-1 will be measured and recorded during
the collection of these water samples. All of the grab water samples will be
submitted to the Duke Energy analytical laboratory and analyzed for the
constituents listed in Table 5-1. Unfiltered and filtered (0.45 µm) grab
wastewater and surface water samples will be submitted for inorganic analyses.
Wastewater and surface water grab samples will not be analyzed for hexavalent
chromium.
Analytical results for surface water samples collected from the Lumber River, the
unnamed onsite pond, and Jacob Creek will be compared to 15A NCAC 2B .0200
Classifications and Water Quality Standards Applicable to Surface Waters and
Wetlands of North Carolina (2B Standards Class C Water). The cooling pond is
used for wastewater treatment and is permitted under the NPDES program.
Consequently, cooling pond water samples will not be compared to 2B Standards
Class C Water.
5.2.2 Groundwater Samples
Groundwater samples will be collected from the six new groundwater
monitoring wells (Section 5.1) and the three existing piezometers installed
within the cooling pond dike (Figure 5-1). Cooling pond piezometers are
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constructed with 10 -foot well screens at depths bracketing or just below the
water surface beneath the dike. Consequently, water samples collected from
cooling pond dike piezometers are expected to reflect the quality of seepage
water migrating from the cooling pond to the Lumber River (PZ -101) or Jacob
Creek (PZ -102 and PZ -103). However, samples collected from the new
groundwater monitoring wells (AW-4S/I, AW-5S/I, and AW-6S/I) will be
representative of surficial aquifer groundwater.
Groundwater samples will be collected using a peristaltic pump per the
groundwater sampling procedure presented in the Proposed Groundwater
Assessment Work Plan (SynTerra, December 2014). The field parameters listed
in Table 5-1 will be measured and recorded during groundwater sampling.
Groundwater samples will be submitted to the Duke Energy analytical
laboratory and analyzed for the constituents listed in Table 5-1. Unfiltered and
filtered (0.45 µm) groundwater samples will be submitted for inorganic analyses
including analysis for hexavalent chromium.
Groundwater results will be compared to the 15A NCAC Subchapter 02L
Standards and Interim Maximum Allowable Concentrations (IMACs). Appendix
1 of 15A NCAC Subchapter 02L Classifications and Water Quality Standards
Applicable to The Groundwaters of North Carolina lists IMACs. The IMACs were
issued in 2010 and 2011, however NCDEQ has not established a 21, standard for
these constituents as described in 15A NCAC 02L.0202(c). For this reason,
IMACs are for reference only.
5.3 Sediment Samples
Sediment core and grab samples will be collected from the cooling pond, Lumber River,
Jacob Creek, and the onsite background pond (Figure 5-1). Cooling pond and onsite
background pond sediment core and grab samples will be collected from a boat
whereas Jacob Creek and Lumber River sediment core and grab samples will be
collected from the shoreline. Sediment cores of approximately 1 foot in length will be
collected manually using a core retrieval device. Mechanical core collection (e.g.,
Geoprobe° from barge) may be warranted if coal ash is determined to be present at
depths beyond the capability of manual coring devices.
5.3.1 Sediment Core Samples
The following sediment core samples will be collected in support of the cooling
pond assessment (Figure 5-1):
y Twenty-four sediment core samples will be collected from the cooling
pond (CP -1 through CP -24). These samples will be collected from a boat;
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y One sediment core samples will be collected from the Lumber River (LR -
1). This sample will be collected from the shore nearest the cooling pond
makeup water intake.
E1, Two background sediment core samples will be collected from the
unnamed onsite pond (BG -1 and BG -2). These samples will be collected
from a boat;
41, Two background sediment core samples will be collected from Jacob
Creek (BG -3 and BG -4). These samples will be collected from the
shoreline; and
161, Three background sediment core samples will be collected from Jacob
Creek (JC -1, JC -2 and JC -3). These samples will be collected from the
shoreline.
Sediment core samples will be analyzed by polarized light microscopy (PLM) to
determine the presence of coal ash in sediment core samples and to quantify the
amounts of coal ash when present in core samples.
Sediment core samples will be collected after grab water samples are collected
but before collecting the sediment grab sample. Sediment core samples will be
collected with a coring device that can retrieve a relatively undisturbed 1 -foot
sediment core sample. The sediment core sample will be examined to determine
the depth where the sediment grab sample will be collected. Sediment core
samples will be submitted to an offsite subcontract laboratory for PLM analysis.
5.3.2 Sediment Grab Samples
The following grab sediment samples will be collected in support of the cooling
pond assessment (Figure 5-1):
y Twenty-four grab sediment samples will be collected from the cooling
pond (CM through CP -24). These samples will be collected from a boat;
One grab sediment samples will be collected from the Lumber River (LR -
1). This sample will be collected from the shore nearest the cooling pond
makeup water intake.
y Two background grab sediment samples will be collected from the onsite
cooling pond (BG -1 and BG -2). These samples will be collected from a
boat;
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161, Two background grab sediment samples will be collected from Jacob
Creek (BG -3 and BG -4). These samples will be collected from the
shoreline; and
E1, Three background grab sediment samples will be collected from Jacob
Creek (JC -1, JC -2 and JC -3). These samples will be collected from the
shoreline.
The depth of the grab sediment sample may be determined by what is observed
in the sediment core sample. The grab sediment sample should be collected from
the depth where distinct changes in sediment core color appears because this
may be an indication that coal ash or other unexpected material has been
deposited onto the sediment. The grab sediment sample may be collected from a
second core sample collected from a location immediately adjacent to the first
sediment core sampling location. Decontamination of the coring devise is not
necessary when collecting sediment core and grab samples from the same
sample location (e.g., CP -19). Decontamination of the coring devise is required
between the collection of sediment core and grab samples from different sample
locations (e.g., CP -19 and CP -20).
All of the grab sediment samples will be submitted to the Duke Energy analytical
laboratory and analyzed for the constituents listed in Table 5-2.
5.4 Field and Sampling Quality Assurance/Quality Control
Procedures
Documentation of field activities will be completed using a combination of logbooks,
field data records (FDRs), sample tracking systems, and sample custody records. Field
logbooks may be used to provide a general record of activities and events that occur
during the day. FDRs will be used to document and record sample identification,
sample collection time and date, field parameters, observations, and other pertinent
sample collection details.
5.4.1 Field Logbooks
The field logbooks are permanently bound and provide a hand written account
of general field activities. Entries are made in indelible ink, and corrections are
made with a single line with the author initials and date. Each page of the
logbook is dated and initialed by the person completing the log. Partially
completed pages will have a line drawn through the unused portion at the end of
each day with the author's initials. The following information is generally
entered into the field logbooks:
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10 The date and time of each entry;
101 A summary of important tasks or subtasks completed during the day;
01 A description of field tests completed in association with the daily task;
101 A description of samples collected including documentation of quality
control samples that were prepared (rinse blanks, duplicates, matrix spike,
split samples, etc.);
101 Documentation of equipment maintenance and calibration activities;
101 Documentation of equipment decontamination activities; and,
y Descriptions of deviations from the work plan.
5.4.2 Field Data Records
Sample FDRs contain sample collection and/or exploration details. A FDR may
be a preprinted fill-in the blanks form on paper or it may be an electronically
generated form where data and information is recorded and stored directly onto
an I -pad or similar. A FDR is completed each time a field sample is collected.
The goal of the FDR is to document exploration and sample collection methods,
materials, dates and times, and sample locations and identifiers. Field
measurements and observations associated with a given exploration or sample
collection task are recorded on the FDRs. FDRs are maintained throughout the
field program in files that become a permanent record of field program activities.
5.4.3 Sample Identification
In order to ensure that each number for every field sample collected is unique,
samples will be identified by the sample location and depth interval, if applicable
(e.g., CP -10 [0-1']). Samples will be numbered in accordance with the proposed
sample IDs shown on Figure 5-1.
5.4.4 Field Equipment Calibration
Field sampling equipment (e.g., YSI ph/conductivity/temperature/dissolved
oxygen/oxidation-reduction potential [ORP] meter) will be properly maintained
and calibrated prior to and during continued use to assure that measurements
are accurate within the limitations of the equipment. Personnel will follow the
manufacturers' instructions to determine if the instruments are functioning
within their established operation ranges. The calibration data will be recorded
in a dedicated calibration log. Sampling or field measurement instrument
determined to be malfunctioning will be repaired or will be replaced with a new
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piece of equipment. Field equipment calibration will be conducted in accordance
with the CSA Groundwater Assessment Work Plan (SynTerra, December 2014).
5.4.5 Sample Custody Requirements
A program of sample custody will be followed during sample handling activities
in both field and laboratory operations. This program is designed to account for
each sample at all times. The appropriate sampling and laboratory personnel
will complete chain -of -custody records, and laboratory receipt sheets.
Procedures for maintaining and documenting sample custody, sample packing,
and sample transport will be conducted in accordance with the CSA
Groundwater Assessment Work Plan (SynTerra, December 2014).
5.4.6 Quality Assurance and Quality Control Samples
The following quality assurance/quality control (QA/QC) samples will be
collected during the proposed field activities:
E1 Equipment rinse blanks (one per day);
01 Field Duplicates (one per 20 samples per sample medium)
Equipment rinse blanks will be collected from the sediment core collection
device and non -dedicated groundwater sampling equipment on days when they
are used for sample collection. The sediment core collection device will be
decontaminated when sample collection from a designated sampling location is
completed (Section 5.3.7). An aliquot of the final control rinse water will be
passed over the cleaned equipment directly into a sample container and
submitted for analysis.
Groundwater samples will be collected using a peristaltic pump and new sample
tubing. Used sample tubing will be discarded following sample collection from
individual monitoring wells. Deionized water provided by the analytical
laboratory will be transferred directly into equipment blank sample containers
via new and unused sample tubing.
A field duplicate is a replicate sample prepared at the sampling locations from
equal portions of all sample aliquots combined to make the sample. Both the
field duplicate and the sample are collected at the same time, in the same
container type, preserved in the same way, and analyzed by the same laboratory
as a measure of sampling and analytical precision.
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Field QA/QC samples will be analyzed for the laboratory analytical parameters
proposed for water and sediment samples identified on Tables 5-1 and 5-2,
respectively.
5.4.7 Decontamination Procedures
Proper decontamination of sampling equipment is essential to minimize the
possibility of cross contamination of samples. Previously used sampling
equipment will be decontaminated before sampling and between the collection
of each sample. New and unused disposable sampling equipment (e.g.,
peristaltic pump tubing) will be used for the collection of groundwater samples.
Field sampling equipment reused to collect multiple samples (e.g., sediment core
collection device) will be decontaminated between sample locations using
potable water and phosphate and borax -free detergent solution and a brush, if
necessary, to remove particulate matter and surface films. Equipment will then
be rinsed thoroughly with tap water to remove detergent solution prior to use at
the next sample location.
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6.0 MODELING OF GROUNDWATER IMPACTS TO SURFACE WATER
The cooling pond was incorporated into groundwater modeling conducted during the
CSA groundwater assessment. Groundwater modeling is presented in Section 4.0 of the
CAP Part 1 Report (SynTerra, November 2015) and Section 3.0 of the CAP Part 2 Report
(SynTerra, February 2016). Cooling pond assessment data will be used to determine
whether additional groundwater modeling is warranted.
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Proposed Cooling Pond Assessment Work Plan August 2016
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7.0 COOLING POND ASSESSMENT REPORT
The cooling pond assessment report will include the following components:
10 Executive Summary
,67 Site History and Source Characterization
161P Site Geology and Hydrogeology
161P Sampling Results
10 Site Conceptual Model
E1 Groundwater Modeling
161P Conclusions and Recommendations
`0 Figures
Tables
161, Appendices
The following deliverables will be included:
167 Piper and/or stiff diagrams showing selected monitoring wells, Jacob Creek
surface water, Lumber River surface water and cooling pond water sampling
locations as separate symbols.
E1P Geologic cross sections that include the relative position of the cooling pond
bottom and coal ash in the cooling pond (if found) relative to the ash basins and
the water table.
01 Photographs of sediment cores for each sampling location.
y Others as appropriate.
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8.0 PROPOSED SCHEDULE
Proposed schedule milestones are as follows:
Field work will be initiated within approximately 45 days following NCDEQ
final approval of this work plan; and
101 A cooling pond assessment report will be submitted to NCDEQ within
approximately 60 days following receipt and validation of all analytical data.
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9.0 REFERENCES
Duke Energy, 2014; http://www.duke-energy.com/pdfs/duke-energy-ash-metrics.pdf
(Updated Oct. 31, 2014)
DWR, July 2016; Letter correspondence from Mr. S.J. Zimmerman (DWR Director) to
Mr. H. Sideris (Duke Energy Sr. VP) dated July 8, 2016.
E-mail correspondence, July 2016; July 19, 2016 10:03 am E-mail correspondence from Kent
Tyndall (Duke Energy Environmental Professional) and Ted Volskay (SynTerra
Corporation Senior Scientist).
E-mail correspondence, August 2016; August 10, 2016 4:41 pm E-mail correspondence from
LaToya Fields Ogallo (Duke Energy Environmental Professional) and Ted Volskay
(SynTerra Corporation Senior Scientist).
Giese, G.L. Eimers, J.L., and Coble, R.W., 1997 Simulation of Ground -Water Flow in the
Coastal Plain Aquifer System of North Carolina, United States Geological Survey
Professional Paper 1404-M.
S&ME, 2012; Field Exploration Data Report, Progress Energy — Weatherspoon Plant Ash
Pond, Lumberton, North Carolina, S&ME Project No. 1054-12-062, June 11, 2012.
Stuckey, J.L., 1965; North Carolina: Its Geology and Mineral Resources, Raleigh, North
Carolina Department of Conservation and Development, 550p.
SynTerra, September 2014; Drinking Water Well and Receptor Survey for W.H.
Weatherspoon Power Plant, NPDES Permit# NC0005363; Prepared by SynTerra
Corporation, Greenville, South Carolina.
SynTerra, November 2014; Supplement to Drinking Water Well and Receptor Survey-W.H.
Weatherspoon Power Plant, NPDES Permit# NC0005363; Prepared by SynTerra
Corporation, Greenville, South Carolina.
SynTerra, December 2014; Proposed Groundwater Assessment Work Plan (Revision 1) —
W.H. Weatherspoon Power Plant; Prepared by SynTerra Corporation, Greenville,
South Carolina.
SynTerra, August 2015; Comprehensive Site Assessment Report — W.H. Weatherspoon Power
Plant, Prepared by SynTerra Corporation, Greenville, South Carolina.
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SynTerra, November 2015; Corrective Action Plan Part 1— W.H. Weatherspoon Power Plant;
Prepared by SynTerra Corporation, Greenville, South Carolina.
SynTerra, February 2016; Corrective Action Plan Part 2 — W.H. Weatherspoon Power Plant;
Prepared by SynTerra Corporation, Greenville, South Carolina.
SynTerra, July 2016; Comprehensive Site Assessment Supplement 1— W.H. Weatherspoon
Power Plant; Prepared by SynTerra Corporation, Greenville, South Carolina.
usclimatedata.com, July 30, 2016; http://www.usclimatedata.com/climate/lumberton
/north-carolina/united-states/usnc04O6, accessed on July 30, 2016.
Winner, M.D., Jr., and Coble, R.W., 1989, Hydrogeologic Framework of the North
Carolina Coastal Plain Aquifer System: U.S. Geological Survey Open -File
Report.
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FIGURES
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DUKE ENERGY PROGRESS PARCEL LINE
CCR SURFACE IMPOUNDMENT WASTE BOUNDARY
— —
CCR SURFACE IMPOUNDMENT COMPLIANCE BOUNDARY
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NPIDES TREATMENT UNIT
COMBINED COMPLIANCE BOUNDARY
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DITCH TO LUMBER RIVER OR JACOB CREEK
DITCH TO NPIDES TREATMENT UNIT (COOLING POND)
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CSA MONITORING WELL (SURVEYED)
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COMPLIANCE MONITORING WELL (SURVEYED)
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LEGEND
PROPOSED WATER AND SEDIMENT SAMPLE
le
PROPOSED SEDIMENT SAMPLE LOCATION
Q
PROPOSED GROUND WATER SAMPLE LOCATION
A-
PROPOSED GROUNDWATER WELL INSTALLATION (SHALLOW,
INTERMEDIATE)
»#=I
RAILROAD
1► — DITCH
I STREAM
ASH BASIN BOUNDARY
DUKE ENERGY PROGRESS WEATHERSPOON PLANT SITE BOUNDARY
NOTES:
SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17,2014. IT WAS OBTAINED FROM
WSP.
Z ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2013. IT WAS
OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS.
(http://services.nconemap.gov/)
3 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC
INFORMATION AND ANALYSIS. (http://services.nconemap.gov/)
4 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
COORDINATE SYSTEM FIPS 3200 (NAD83/2011).
GRAPHIC SCALE
350 0 350 700 1,050 1400
IN FEET
167 ,'DUKE
�
synTerra ENERGY
148 RIVER STREET, SUITE 220 WEATHERSPOON POWER PLANT
GREENVILLE, SC 29601 491 POWER PLANT RD
864-421-9999 LUMBERTON, NORTH CAROLINA
www.synterracorp.com
FIGURE ES -2
COOLING POND ASSESSMENT SAMPLE LOCATIONS
W.H. WEATHERSPOON POWER PLANT
LUMBERTON, NORTH CAROLINA

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g FROM THE NRCS GEOSPATIAL DATA GATEWAY AT http://datagateway.nres.usda.gov/
= FIGURE 1-1
GREENSBORO SITE LOCATION MAP
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•GREENVILLE W.H. WEATHERSPOON POWER PLANT
Terra OWER PLAN ON LUMBERTON, NORTH CAROLINA
Now ROBESON
COUNTY
- 148 RIVER STREET, SUITE 220 WILMINGTON
GREENVILLE, SOUTH CAROLINA DRAWN BY: C. NEWELL DATE: 6130/2015 GRAPHIC SCALE
PHONE [phone] PROJECT MANAGER: K. WEBB CONTOUR INTERVAL: IO FEET 1000 0 1000 2000
ww.synterracorp.com LAYOUT:FIG 1-1 MAP DATE:1993
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INQUIRY #: 4366192.12 4 N
YEAR: 1951
iS[_ EDR
750' N
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148 RIVER STREET, SUITE 220
GREENVILLE, SOUTH CAROLINA 29601
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FIGURE 2-1
www.syDRAWNnterrac
1951 AERIAL PHOTOGRAPH
DRAWN BY: K. SHECK
HECKm
'
T.VOLSKAY
W. H. WEATHERSPOON POWER PLANT
DATE: JULY 29, 2016
DATE
. E Weatherspoon
synMena
LUMBERTON, NORTH CAROLINA
BasinGEnssessogress n\CS09
Basin Assessment Plan\CSA Cooling Pond
Assessment\Cooling Pond Work Plan\Figures

Historical Topographic Map
s 410
ynTerra
148 RIVER STREET, SUITE 220
GREENVILLE, SOUTH CAROLINA 29601
PHONE [phone]
www.synterracorp.com
DRAWN BY: K. SHECK
PROJECT MANAGER: T. VOLSKAY
DATE: JULY29,2016
P:\Duke Energy Progress. 1 026\1 09. Weatherspoon Ash
Basin GW Assessment Plan\CSA Cooling Pond
Assessment\Cooling Pond Work Plan\Figures
FIGURE 2-2
1957 USGS TOPOGRAPHIC MAP
W. H. WEATHERSPOON POWER PLANT
LUMBERTON, NORTH CAROLINA
TARGET QUAD
SITE NAME: W.H. Weatherspoon
CLIENT: SynTerra
N
NAME: BLADENBORO
Power Plant
CONTACT: Mark Taylor
MAP YEAR: 1957
ADDRESS: POWER PLANT RD
INQUIRY#: 4366192.4
Lumberton, NC 28358
RESEARCH DATE: 07/27/2015
SERIES: 15
LAT/LONG: 34.58821-78.9743
SCALE: 1:62500
s 410
ynTerra
148 RIVER STREET, SUITE 220
GREENVILLE, SOUTH CAROLINA 29601
PHONE [phone]
www.synterracorp.com
DRAWN BY: K. SHECK
PROJECT MANAGER: T. VOLSKAY
DATE: JULY29,2016
P:\Duke Energy Progress. 1 026\1 09. Weatherspoon Ash
Basin GW Assessment Plan\CSA Cooling Pond
Assessment\Cooling Pond Work Plan\Figures
FIGURE 2-2
1957 USGS TOPOGRAPHIC MAP
W. H. WEATHERSPOON POWER PLANT
LUMBERTON, NORTH CAROLINA

Progress Energy Carolinas, Inc, NPDES Permit Number NCO005363
Weatherspoon Steam Electric Plant 2009 Renewal Application
Attachment 1
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www.synterracorp.com
DRAWN BY: K. SHECK 2009 NPDES PERMIT NC0005363
PROJECT MANAGER: T. VOLSKAY RENEWAL APPLICATION
DATE: JULY 29, 2016
synTerm Energy Assessment
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PHONE [phone] COOLING POND OUTFALLS
www.synterracorp.com
DRAWN BY: K. SHECK 2009 NPDES PERMIT NC0005363
PROJECT MANAGER: T. VOLSKAY RENEWAL APPLICATION
DATE: JULY 29, 2016
synTerm Energy Assessment
n\CS09 Weatherspoon Ash W. H. WEATHERSPOON POWER PLANT
Basin GW Assessment Plan\CSPlan\Fngg Pond LUMBERTON, NORTH CAROLINA
AssessmentlCoolin Pond Work Plan\Fi ures

Duke Energy Progress, Inc NPDES Permit Number NCO005363
Weatherwoon Plant 2014 Renewal Application
Attachment 1
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DATE
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WATER LEVELS COLLECTED BY SYNTERRA ON JANUARY 12, 2016.
APRIL 17, 2014 AERIAL PHOTOGRAPH OBTAINED FROM WSP GROUP IN CARY NORTH CAROLINA e
o ALL SURVEY INFORMATION, PROPERTY LINE AND LANDFILL LIMITS AND BOUNDARIES ARE
FROM ARCGIS FILES PROVIDED BY DUKE ENERGY PROGRESS.
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IN FEET
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orp.com
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DRAWN M J.N GER: TIN DATE: 06/10/2016
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NOTES:
WATER LEVELS COLLECTED BY SYNTERRA ON JANUARY 12, 2016.
APRIL 17, 2014 AERIAL PHOTOGRAPH OBTAINED FROM WSP GROUP IN CARY NORTH CAROLINA e
o ALL SURVEY INFORMATION, PROPERTY LINE AND LANDFILL LIMITS AND BOUNDARIES ARE
FROM ARCGIS FILES PROVIDED BY DUKE ENERGY PROGRESS.
DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE
SYSTEM RIPS 3200 (NAD 83).
GRAPHIC SCALE
'• r�' 250 0 250 500
IN FEET
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orp.com
Terra
DRAWN M J.N GER: TIN DATE: 06/10/2016
PROJECT MANAGER: TED VOLSKAY
COOLING POND synLAYOUT: FIG (WL MAP - SURFICIAL)
C
,46
a + 71c49
x
F•
s
�
a.
AW -3S : •�,_�, g.�'��
109 29 A *-vp
.. .
w�
77
�k ,
! p'
-Z 3
Y
icy a 1
a
3 YZ� .:
FIGURE 4-1
WATER LEVEL MAP - JANUARY 2016
SURFICIAL GROUNDWATER
W.H. WEATHERSPOON POWER PLANT
LUMBERTON, NORTH CAROLINA

Progress Energy Carolinas, Inc. NPOES Permit Number NC0005363
Weathers oon Stearn Electric Plant 2409 Renewal Applicatlon
Attachment 2 continued
Evaporation
Potable Water Sanitary Uvaste
S stem System
P
Metal Cleaning
Wastes
I Wells I Plant Systems taw Volui»e L
I Wastes
i
Lumber River i F
A +
.i
i
1
River intake i
Structure
Condenser --- AshSiuice
S stem
Pleat H
Exchan er
1
1
Plant Drains +
i
1
Fire Water E Irikemal Intake
Svstem structure
Q Plant Area Storm
Water Runort
Ash
Pond
s Low ilalume
Wastes
Coal Pile
Runoff
Secondal
Settling
K Evaporafon &
Basin
Seepage
MT
G
C7Separator
Cooling
Pond
B
N
Outfall 002 utfall001
Combustion
Turbine Sde
Septic 5_and & Q
Tank Gravel
Bed
Plant Drams
Oily Wastes
Retention
Bars in
OWWater
Separator
J
Storm Water Lumber River
Outtalk
4 148 RIVER STREET, SUITE 220 FIGURE 4-2
10 GREENVILLE, SOUTH CAROLINA 29601
PHONE [phone] COOLING POND INFLOWS AND OUTFLOWS
vmw.syDRAWNnterrac HECKm 2009 NPDES PERMIT NC0005363
DRAWN BY: K. SHECK
PROJECT MANAGER: T. VOLSKAY RENEWAL APPLICATION
DATE: JULY 29, 2016
YnTerra P\Duke EnergyProgress.1026\109. WeatherspoonAsh W. H. WEATHERSPOON POWER PLANT
Basin GW Assessment Plan\CSA Cooling Pond LUMBERTON NORTH CAROLINA
Assessment\Cooling Pond Work Plan\Figures

Progress Energy Carolinas, Inc. NPDES Permit NumbereNC0005363
Weathersg_von Steam Electric Plant -- -- 2009 Renewal ARP icatton
Attachment 2
Form 2C Item II -A Flows, Sources of Pollution, and Treatment Technologies
-Source
Estimated
Average Flow
Comments
A
4-16 MGD
Make up water`from Lumber River, Maximum rate is 9 12 MGD
B
4 03 MGD
Non -contact cooling water discharge, Maximum rate is 9 12 MGD
C
0 7 MGD
Make up for cooling pond, Maximum rate is 912 MGD
D
193 MGD
Condenser cooling water- all three units operating
E
2,400 GPM
Maximum make-up rate for fire water system
F
1"00 GPD
Low volume wastes to the ash pond
G
2 1 MGD
Ash pond discharge to cooling pond
H
191 MGD
Condenser discharge to cooling ,pond
I
120 GPM
Intermittent flow as required
J
0 14 MGD
Discharge to cooling pond from oillwater separator
K
0024 r MGD
Estimated -using averageAmly rainfall
L
0 14 MGD
Variable due to intermittent processes and runoff
M
0 ,7 MGD
Maxtmurn estimated rate is 1 6,MGD
N
0 MGD
Pond does not norrhally discharge See Attachment 3 for details
0
0 00125 MGD
Sanitary wastes
P
50,000 gallevent-
Units 1 & 2'
42,000 gal/event -
U n it.3
Amounts estimated, Usually evaporated in boiler
Q
0 19 MGD
Estimated using -average daily rainfall
R
0 011 MGD
Estimated using average daily rainfall
S
4,000 GPD
Low volume waste (reverse osmosis reject watef)
148 RIVER STREET, SUITE 220 FIGURE 4-3
GREENVILLE, SOUTH CAROLINA 29601
PHONE [phone] FLOWS, SOURCES OF POLLUTION, AND TREATMENT
www.synterracorp.com
DRAWN BY: K. SHECK TECHNOLOGIES -2009 NPDES PERMIT NC0005363
PROJDATE JTMA9,2016 T.VOLSKAY RENEWAL APPLICATION
DATE: JULY 29, 2016
synTero BasinGEn Assessment
Cooling
W. H. WEATHERSPOON POWER PLANT
Basin GW Assessment Plan\CSA Cooling Pond
Assessment\Cooling Pond Work Plan\Figures LUMBERTON, NORTH CAROLINA

Duke Energy Progress, Inc NPDES Permit Number NCO005363
Westhemponn Plant 2014 Renewal Application,
Attachment 2
Form 2C Item II -A Flows, Sources of Pollution, and Treatment Technologies
148 RIVER STREET, SUITE 220 FIGURE 4-4
GREENVILLE, SOUTH CAROLINA 29601
PHONE [phone] COOLING POND INFLOWS AND OUTFLOWS
www. synterracorp. com
DRAWN BY: K. SHECK 2014 NPDES PERMIT NC0005363
PROJECT MANAGER: T. VOLSKAY
DATEJULY 29, 2016 RENEWAL APPLICATION
:
YnTerra Energy Progress. 1 026\1 Assessment
Cooling Pond W. H. WEATHERSPOON POWER PLANT
Basin GW Assessment Plan\CSA Cooling Pond LUMBERTON, NORTH CAROLINA
Assessment\Cooling Pond Work Plan\Figures

Duke Energy Progress, Inc NPDES Permit- Number',NC00053G3
Weathers oon Plant 2014.Renewal'Applicition
Attachment 2 -Continued
'Source
-Esthnat6d'
Average-: Flow .
Comments
A
Q 7 MGD
Make up. water from. Lumber. River, Maximum rate is 9 12 MGD
B
0 MGD
Fire water system
C
120'GPV
Potable,water service-. intermittent flow as required
D
.0 0002 -MGD
Sanitary wastes
E
0 14,MG0
Dischargb-to cooling pond from oil/water separator
Ash pond does not.normally discharge See Attachment 3=for
F
0 MGD
details.
G
01-9,MGD
Estimated using°average daily rainfall
H
0 011.MGD
Estimated using average daily rainfall
1
0 MGD
Pond does not normally discharge 'See Attachment S.for details
,1
0 7 MGD
Maiimum�estimated rate is 1 6 MGD
148 RIVER STREET, SUITE 220 FIGURE 4-5
GREENVILLE, SOUTH CAROLINA 29601
PHONE [phone] FLOWS, SOURCES OF POLLUTION, AND TREATMENT
www.synterracorp.com
DRAWN BY: K. SHECK TECHNOLOGIES -2014 NPDES PERMIT NC0005363
PROJDATE JTMA9,2016 T.VOLSKAY RENEWAL APPLICATION
DATE: JULY 29, 2016
WnTerm
P.\Duke Energy Progress.1026\109. Weathers poon Ash W. H. WEATHERSPOON POWER PLANT
Basin GW Assessment Plan\CSA Cooling Pond
Assessment\Cooling Pond Work Plan\Figures LUMBERTON, NORTH CAROLINA

Progress Energy Carolinas, Inc: NPDES Permit Number NCO006363
Weathers oon Steam Electric Plant 2009.Renewal Application
Attachment 4
Form 2C item VI Potential Discharges Not Covered by Analysis
Chemical
Quantity
Frequency
Purpose
(usedlyr)
Hydrazine
165 gal
Continuous - when
units are a erational
Oxygen scavenger in boiler
Tnsodium phosphate
1,+000 Ib
As needed
pH control in boiler
Disodium ,phosphate
500 Ib
As, needed
pH. control in boiler
Morpholine '
275 gal
Continuous - when
pH control in boiler
units are o eratiohal
Sodium hypochlorite
12,950 gal
As•needed
Condenser and heat
exchanger biofoulin-q control
Sodium, hydroxide
9,000 gal
,As needed
Demineralizer regeneration
Sodium hydroxide
As needed
As needed
Cooling pond neutralization
Sulfuric acid
2,000 gal
As needed
Demineralizer regeneration
Sulfuric acid
19,000 gal.
As needed
Cooling pond. neutralization
Molybdenum trioxide
330 gal
As needed
Corrosion control in,boiler
Sodiums chlofide
8,000 Ib
Twice per month
Water softener regeneration
Sulfur, elemental
75 tdii
Continuous - when
Unit 3 iso erational
Flue gas,conddioning
Citric acid, 50%
1,460 gallevent
Approximately once
per 10 years per unit
Boiler cleaning
Citric acid, dry
3,500 Iblunitlevent
Approximately once
Boiler cleaning
per 10 years per.unit
Ammonium hydroxide
1,560 gal/event
Approximately once
er1fl years per unitBoiler,cleaning
1,775 16/eveht -
'Sodium Nitrite
Units. 1 & 2
Approximately once
Boder cleaning
1,450 lb/event -
per 10 years per unit
_ Unit 3 -
Corrosion Inhibitor
55 gal`lunitlevent
Approximately once
per 10 years per unit
Boiler cleaning
475 lb/event —
Ammonium bicarbonate
Urids; 1 & 2
Approximately once
Boiler cleaning
375 lblevent--
per 10 years per unit
unit 3
-
EDTA, 39%6,000
Approximately once
Boder cleaning
gal/unit/event
per 10 ears per unit
Hydrochloric,acid
1,000 gal/event
As -needed
Condenser cleaning
Rodine 213
5 galfevent
As needed
Condenser cleaning
Ammonium bifiuoride
100 lblevent
As needed
Condenser cleaning
4 148 RIVER STREET, SUITE 220 FIGURE 4-6
GREENVILLE, SOUTH CAROLINA 29601
PHONE [phone] POTENTIAL DISCHARGES NOT COVERED BY
www. synterracorp. conn
DRAWN BY: K. SHECK ANALYSIS - 2009 NPDES PERMIT NC0005363
PROJECT MANAGER: T. VOLSKAY
DATEJULY 29, 2016 RENEWAL APPLICATION
:
YnTero Energy Assessment
Cooling
W. H. WEATHERSPOON POWER PLANT
Basin GW Assessment Plan\CSA Cooling Pond LUMBERTON, NORTH CAROLINA
Assessment\Cooling Pond Work Plan\Figures

Duke Energy Progress, Inc. NPIDES Permit Number NCO005363
Weatherspoon PIant r �. 2014 Renewal Application
Attachment 4
Form 2C Item VI Potential Discharges Not Covered by Analysis
Chemical
Quantity
(usedlyr)
Frequency
Purpose
Sodium hydroxide
As needed
As needed
Cooling pond neutralization
5utfuric. acid
19,000 gal
As needed
Cooling pond neutralization
Sandblast Media
500-700 lb
As needed
Equipment cleaning
Rhodamine liquid dye
0.010.03
allevent
As needed
Performance testing
148 RIVER STREET, SUITE 220 FIGURE 4-7
GREENVILLE, SOUTH CAROLINA 29601
PHONE [phone] POTENTIAL DISCHARGES NOT COVERED BY
wwwsynterracorp.com
DRAWN BY: K.SHECK ANALYSIS - 2014 NPDES PERMIT NC0005363
tip DATE
T.VOLSKAY RENEWAL APPLICATION
DATE: JULY 29, 2016
synTerra BasinGEn Assessment
n\CS09 WeatherspoonAsh W. H. WEATHERSPOON POWER PLANT
Basin GW Asoolingent Plan\Crk Plan Cooling
Pond LUMBERTON, NORTH CAROLINA
Assessment\Conlin Pond Work Plan\Fi ures

0
INQUIRY #: 4366192.12
YEAR: 1958 4 N
I- 1 = 750' 1
DIR
148 RIVER STREET, SUITE 220
GREENVILLE, SOUTH CAROLINA 29601
PHONE [phone] FIGURE 4-8
www.syDRAWN
K.S ECK 1958 AERIAL PHOTOGRAPH
DRAWN BY: K. SHECK
PROJECTMANAGER:T. VOLSKAY
DATE: JULY 29,9,2016 W. H. WEATHERSPOON POWER PLANT
synTerm BasinGEnssess entPl n\CS09 olingPrspoonAsh LUMBERTON NORTH CAROLINA
Basin GW Assessment Plan\CSA Cooling Pond 1
Assessment\Cooling Pond Work Plan\Figures

Lower Basin Spillway Inlet
A? (Weatherspoon-9)
x.
-12 inch iamete .Origin utlet III
p
(Reported to be Ab i;t ned)
AWW& LOWER BASIN
(Weatherspoon))
UPPER
BASIN
- MIDDLE BASIN
24 -inch Diameter CMP
Upper Basin Outlet Structure
Y' (Weatherspoon-10)
ILLING BASIN
-inch Diameter RCP Decant Structure
24 -inch Diameter HDPE
Idle Basin Outlet Structure
(Weatherspoon-7)

A
V �
F 'a
Y L /
/
LR -1
CP -1
BG -2
CP -2
CP -24
7
G
� 7
i
A
AW -6S
AW -61
P-19 CP -20 �
I
PZ -102 I
JC -3
1}
N
AW -5S
AW -51
SR -2127
LEGEND
PROPOSED WATER AND SEDIMENT SAMPLE
le
PROPOSED SEDIMENT SAMPLE LOCATION
Q
PROPOSED GROUND WATER SAMPLE LOCATION
A-
PROPOSED GROUNDWATER WELL INSTALLATION (SHALLOW,
INTERMEDIATE)
»#=I
RAILROAD
1► — DITCH
I STREAM
ASH BASIN BOUNDARY
DUKE ENERGY PROGRESS WEATHERSPOON PLANT SITE BOUNDARY
NOTES:
SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17,2014. IT WAS OBTAINED FROM
WSP.
Z ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2013. IT WAS
OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS.
(http://services.nconemap.gov/)
3 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC
INFORMATION AND ANALYSIS. (http://services.nconemap.gov/)
4 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
COORDINATE SYSTEM FIPS 3200 (NAD83/2011).
GRAPHIC SCALE
350 0 350 700 1,050 1400
IN FEET
167 ,'DUKE
�
synTerra ENERGY
148 RIVER STREET, SUITE 220 WEATHERSPOON POWER PLANT
GREENVILLE, SC 29601 491 POWER PLANT RD
864-421-9999 LUMBERTON, NORTH CAROLINA
www.synterracorp.com
FIGURE 5-1
COOLING POND ASSESSMENT SAMPLE LOCATIONS
W.H. WEATHERSPOON POWER PLANT
LUMBERTON, NORTH CAROLINA

Proposed Cooling Pond Assessment Work Plan August 2016
W.H. Weatherspoon Power Plant
TABLES
SynTerra

TABLE 2-1
NPDES COMPLIANCE WELL GROUNDWATER MONITORING REQUIREMENTS*
W.H. WEATHERSPOON POWER PLANT
LUMBERTON, NORTH CAROLINA
Well
Nomenclature
Parameter Description
Frequency
Antimony
Chromium
Nickel
Thallium
Arsenic
Copper
Nitrate
Water Level
Monitoring Wells
BW -1, CW -1, CW -
2, CW -3
March, June,
and October
Barium
Iron
pH
Zinc
Boron
Lead
Selenium
Cadmium
Manganese
Sulfate
Chloride
Mercury
TDS
*Updated to include CAMA parameters in 2015
P:\Duke Energy Progress. 1026\109. Weatherspoon Ash Basin GW Assessment Plan\CSA Cooling Pond
Assessment\Cooling Pond Work Plan\Tables\
Table 2-1 GW Parameter.xlsx Page 1 of 1

TABLE 5-1
WATER SAMPLE PARAMETERS AND ANALYTICAL METHODS
W.H. WEATHERSPOON POWER PLANT
LUMBERTON, NORTH CAROLINA
PARAMETER
REPORTING LIMIT
UNITS
METHOD
FIELD PARAMETERS
H
NA
SU
Field Water Quality Meter
Specific Conductance
NA
µS/cm
Field Water Quality Meter
Temperature
NA
oC
Field Water Quality Meter
Dissolved Oxygen
NA
m L
Field Water Quality Meter
Oxidation Reduction Potential
NA
mV
Field Water Quality Meter
Turbidity
NA
INTU
lField Water Quality Meter
Ferrous Iron
NA
I m /L
IField Test Kit
INORGANICSNo,e i
Aluminum
0.005
m /L
EPA 200.7 or 6010C
Antimony
0.001
m L
EPA 200.8 or 6020A
Arsenic
0.001
m /L
EPA 200.8 or 6020A
Barium
0.005
m L
EPA 200.7 or 6010C
Beryllium
0.001
m /L
EPA 200.8 or 6020A
Boron
0.05
m L
EPA 200.7 or 6010C
Cadmium
0.001
m /L
EPA 200.8 or 6020A
Chromium
0.001
m L
EPA 200.7 or 6010C
Hexavalent Chromium"°te 2
0.00003
mg/L
EPA 218.7
Cobalt
0.001
m /L
EPA 200.8 or 6020A
Copper
0.005
m L
EPA 200.7 or 6010C
Iron
0.01
m /L
EPA 200.7 or 6010C
Lead
0.001
m L
EPA 200.8 or 6020A
Manganese
0.005
m /L
EPA 200.7 or 6010C
Mercury low level
0.000012
m L
EPA 245.7 or 1631
Molybdenum
0.005
m /L
EPA 200.7 or 6010C
Nickel
0.005
m L
EPA 200.7 or 6010C
Selenium
0.001
m /L
EPA 200.8 or 6020A
Strontium
0.005
m L
EPA 200.7 or 6010C
Thallium low level
0.0002
m /L
EPA 200.8 or 6020A
Vanadium low level
0.0003
m /L
EPA 200.8 or 6020A
Zinc 10.005
1 m /L
JEPA 200.7 or 6010C
ANIONS/CATIONS
Alkalinity as CaCO3
20
m /L
SM 2320B
Bicarbonate
20
m L
SM 2320
Calcium
0.01
m /L
EPA 200.7
Carbonate
20
m L
SM 2320
Chloride
0.1
m /L
EPA 300.0 or 9056A
Magnesium
0.005
m L
EPA 200.7
Methane
0.1
m /L
RSK 175
Potassium
0.1
m L
EPA 200.7
Sodium
0.05
m /L
EPA 200.7
Sulfate
0.1
m L
EPA 300.0 or 9056A
Sulfide
0.05
m /L
SM450OS-D
Total Dissolved Solids
25
m L
SM 2540C
Total Organic Carbon
0.1
m /L
SM 5310
Total Suspended Solids
2
m /L
SM 2450D
RADIOLOGICAL
Uranium"°te z
0.00005
mg/L
ISW846 3010A/6020A
Radium"°te z
1
1 pCi/L
I EPA 904.0 or 9320 or 903.1
Notes:
1. Constituents in wastewater, surface water, and groundwater samples will be analyzed for total and
dissolved concentrations.
2. Groundwater analysis only.
NA indicates not applicable.
P \Duke Energy Progress. 1026\109. Weatherspoon Ash Basin GW Assessment Plan\CSA Cooling Pond Assess ment\Cooling Pond Work
Plan\Tables\Table 5-1- Cooling Pond Water Sample Analytical Parameters

TABLE 5-2
SEDIMENT SAMPLE PARAMETERS AND ANALYTICAL METHODS
W.H. WEATHERSPOON POWER PLANT
DUKE ENERGY PROGRESS, INC., LUMBERTON, NORTH CAROLINA
INORGANIC COMPOUNDS
UNITS
METHOD
Aluminum
mg/kg
EPA 6010C
Antimony
mg/kg
EPA 6020A
Arsenic
mg/kg
EPA 6020A
Barium
mg/kg
EPA 6010C
Beryllium
mg/kg
EPA 6020A
Boron
mg/kg
EPA 6010C
Cadmium
mg/kg
EPA 6020A
Calcium
mg/kg
EPA 6010C
Chloride
mg/kg
EPA 9056A
Chromium
mg/kg
EPA 6010C
Cobalt
mg/kg
EPA 6020A
Copper
mg/kg
EPA 6010C
Iron
mg/kg
EPA 6010C
Lead
mg/kg
EPA 6020A
Magnesium
mg/kg
EPA 6010C
Manganese
mg/kg
EPA 6010C
Mercury
mg/kg
EPA Method 7470A/7471B
Molybdenum
mg/kg
EPA 6010C
Nickel
mg/kg
EPA 6010C
Nitrate as Nitrogen
mg/kg
EPA 9056A
pH
SU
EPA 9045D
Potassium
mg/kg
EPA 6010C
Selenium
mg/kg
EPA 6020A
Sodium
mg/kg
EPA 6010C
Strontium
mg/kg
EPA 6010C
Sulfate
mg/kg
EPA 9056A
Thallium (low level) (SPLP Extract only)
mg/kg
EPA 6020A
Vanadium
mg/kg
EPA 6020A
Zinc
mg/kg
EPA 6010C
Sediment Specific Samples
Cation exchange capacity
meg/100g
EPA 9081
Particle size distribution
Percent solids
Percent organic matter
%
EPA/600/R-02/069
Redox potential
mV
Faulkner et al. 1898
Notes:
1. Soil samples to be analyzed for Total Inorganics using USEPA Methods 6010/6020 and pH using USEPA
Method 9045, as noted above.
2. Ash samples to be analyzed for Total Inorganics using USEPA Methods 6010/6020 and pH using USEPA
Method 9045; select ash samples will also be analyzed for leaching potential using SPLP Extraction Method
1312 in conjunction with USEPA Methods 6010/6020.
P:\Duke Energy Progress. 1026\109. Weatherspoon Ash Basin GW Assessment Plan\CSA Cooling Pond Assessment\Cooling Pond
Worl< Plan\Tables\Table 5-2 - Cooling Pond Sediment Sample Analytical Parameters.xlsx

Proposed Cooling Pond Assessment Work Plan August 2016
W.H. Weatherspoon Power Plant
APPENDIX A
NCDWR REQUEST FOR COOLING POND
ASSESSMENT
SynTerra

Water Resources
ENVIRONMENTAL QUALITY
PAT MCCRORY
Governor
DONALD R. VAN DER VAART
Secretary
S. JAY ZIMMERMAN
Director
July 8, 2016
Mr. Harry Sideris
Senior Vice President
Environment, Health, and Safety
Duke Energy
526 South Church Street
Mail Code EC3XP
Charlotte, NC 28202
Subject: Additional Site Assessment Required
James E. Rogers Energy Complex (Formerly Cliffside Steam Station)
NPDES Permit NC0005088 — Rutherford and Cleveland Counties
Roxboro Steam Electric Plant
NPDES Permit NC0003425 — Person County
W. H. Weatherspoon Power Plant
NPDES Permit NC0005363 — Robeson County
Dear Mr. Sideris:
The North Carolina Department of Environmental Quality's Division of Water Resources (DWR)
requests Duke Energy (Duke) provide data and conduct additional site assessment as needed to
characterize the distribution of coal ash residuals (CCR) at confirmed and potential coal ash
disposal areas at the James E. Rogers Energy Complex, Roxboro Steam Electric Plant, and the
W.H. Weatherspoon Plant. Descriptions and approximate locations of these areas are provided
below.
The additional assessments shall be included as part of the on-going Comprehensive Site
Assessments (CSAs) for each of the subject facilities. Please be advised that these areas are to be
included in an updated Groundwater Assessment Plan (GAP) that conforms with the North
Carolina Department of Environment and Natural Resources Notice of Regulatory Requirements
letter dated August 13, 2014 and Comprehensive Coal Ash Management Act (CAMA). Site
activities shall follow the requirements under 15A NCAC 02L .0106(g). An assessment of surface
water quality for those areas that have impounded or flowing water shall also be conducted.
Area(s) of Wetness (AOW) related to these disposal areas should be assessed pursuant to CAMA
§130A-309.212.
State afNorth Carolina I Environmental Quality I Water Resources
1611 Mail service Center I Raleigh, North Caroline 27699-1611
919 707 9000

Additional Site Assessment Required
J u ly 8, 2016
The results of the characterization conducted to date in addition to pertinent historical records and
detailed plans for additional site assessments must provide adequate detail to allow technical
review of the proposed actions shall be provided to the DWR. GAPS are due to the DWR Central
Office and the appropriate DWR Regional Office no later than August 19, 2016. Results of related
investigations may be submitted as a CSA Addendum Report at a later date.
In addition to performing site assessment activities, facility site maps must be updated with the
revised waste boundaries and proposed compliance boundaries established according to 15A
NCAC 02L Section .0107. A letter requesting the approval of the new compliance boundaries
shall be submitted to the appropriate DWR Central Office later than August 19, 2016.
The following are background information and approximate locations of the identified areas at
each of the subject sites requiring additional assessment:
James E. Rogers Energy Complex
On November 16, 2015, Duke communicated orally to DWR that a historical coal ash disposal
area located was identified just north of the Broad River and west of the switchyard at the James
E. Rogers Energy Complex. Duke staff estimated the area to be approximately 3 acres in size, but
stated that the full extent of the area is unknown. The approximate location of the area is shown
below encircled. This area was not addressed in the Groundwater Assessment Plan (GAP),
Comprehensive Site Assessment (CSA) report, or Corrective Action Plans (CAPS) submitted to
DWR. Characterization of CCR within the footprint of this disposal area was confirmed by Duke;
however, no data related to this disposal area has been provided to DWR at this time.
21 Page

Additional Site Assessment Required
July 8, 2016
Roxboro Steam Electric Plant
Area 1 —This area was discovered by Duke and presented orally to DWR during a joint meeting
on January 14, 2016. This area is located directly east of the East Ash Basin and was subsequently
named by DWR the "Unnamed Eastern Extension Basin" for purposes of prioritization ranking
according to the Coal Ash Management Act. This area shall also include the discharge canal that
runs north along the eastern side of the East Ash Basin. This area was not addressed in the GAP,
CSA report, or CAPs submitted to DWR. The approximate location of the area is shown below
encircled.
Area 2 — This area is located directly south of the West Ash Basin and encompasses the three
"fingers" of the dammed watershed and the drainage canal that runs north along the west side of
the West Ash Basin. The drainage canal should be assessed for the presence of coal ash and surface
water standards. Based on site visits and information presented in the CSA and CAP reports, DWR
suspects that coal ash may be present in this area. This area was not addressed in the GAP, CSA
report, or CAPS submitted to DWR. The approximate location of the areas is shown below
encircled.
31 Page

Additional Site Assessment Required
July 8, 2016
W. H. Weatherspoon Power Plant
Duke informed DWR orally at a joint meeting on October 21, 2015, that the cooling pond may
contain coal ash. Also, according to the CSA Report for the facility, the cooling pond is part of
the treatment process before the effluent is discharged through the NPDES outfall. This area was
not addressed in the GAP, CSA report, or CAPS submitted to DWR; however, Duke has stated that
an investigation is currently underway. The approximate location of the area is shown below
encircled.
41 Page

Additional Site Assessment Required
J u ly 8, 2016
BOUND/J!Y
WASTE
BWNUTRY
4
F:
If you have any questions, please feel free to contact Steve Lanter at [phone].
Sincerely,
S. y erman, P.G., Director
Division of Water Resources
cc: Landon Davidson — Asheville Regional Office Supervisor
Danny Smith — Raleigh Regional Office Supervisor
Belinda Henson — Fayetteville Regional Office Supervisor
Jeff Poupart, DWR Water Quality Permitting Section Chief
WQROS Central File Copy
51 Page

Proposed Cooling Pond Assessment Work Plan August 2016
W.H. Weatherspoon Power Plant
APPENDIX B
NPDES PERMIT NC0005363
SynTerra

Permit NC0005363
STATE OF NORTH CAROLINA
DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES
DIVISION OF WATER QUALITY
PERMIT
TO DISCHARGE WASTEWATER UNDER THE
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM
In compliance with the provisions of North Carolina General Statute 143-215.1, other lawful
standards and regulations promulgated and adopted by the North Carolina Environmental
Management Commission, and the Federal Water Pollution Control Act, as amended,
Carolina Power £t Light Company d/b/a Progress Energy Carolinas, Inc.
is hereby authorized to discharge wastewater from a facility located at:
Weatherspoon Steam Electric Plant
491 Power Plant Road
Lumberton, North Carolina
Robeson County
to receiving waters designated as Lumber River in the Lumber River Basin in accordance with
effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III,
and IV hereof.
The permit shall become effective January 1, 2010.
This permit and the authorization to discharge shall expire at midnight on July 31, 2014.
Signed this day November 20, 2009.
Original signed by Gil Vinzani
Coleen H. Sullins, Director
Division of Water Quality
By Authority of the Environmental Management
Commission

Permit NC0005363
SUPPLEMENT TO PERMIT COVER SHEET
All previous NPDES Permits issued to this facility, whether for operation or discharge are
hereby revoked. As of this permit issuance, any previously issued permit bearing this number
is no longer effective. Therefore, the exclusive authority to operate and discharge from this
facility arises under the permit conditions, requirements, terms, and provisions included
herein.
Carolina Power £t Light Company d/b/a Progress Energy Carolinas, Inc. is
hereby authorized to:
1. Continue to discharge recirculated cooling water, coal pile runoff, stormwater
runoff, ash sluice water, domestic wastewater, chemical metal cleaning
wastewater, low volume wastewater including reject water from operation of a
reverse osmosis water treatment unit from a 225 acre cooling pond (Outfall 001 -
Cooling Pond) under extremely severe weather conditions or during pond
maintenance, and continue to discharge non -contact cooling water from heat
exchanger units (Outfall 002- Non contact cooling water), from a facility located
at Weatherspoon Steam Electric Plant, 491 Power Plant Road, Lumberton,
Robeson County, and;
2. Discharge (from Outfalls 001 and 002) into the Lumber River, a Class C -Swamp
water in the Lumber River Basin, at the locations specified on the attached map.
3. Discharge of Stormwater from Outfalls SW -1, SW -2, and SW -3.

Permit NC0005363

Permit NC0005363
_ Aitude:
_ongitude:
SCS Quad:_
4iver Basin:
Receiving Stream
River
Stream Class: -
34° 3-�'
78° 58"
1235W
03-07-51
LurnbLi
C-Swarnp
N1
Progress Energy
Weaitherspoon Elec'
Pla rat
Robeson County
NCO005363

Permit NC0005363
A.(1) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS [001 ]
Beginning on the effective date of this permit and lasting until expiration, the Permittee is
authorized to discharge recirculated cooling water, coal pile runoff, stormwater runoff, ash
sluice water, treated domestic wastewater, chemical metal cleaning wastewater, and low
volume wastewater including reject water from operation of an R. 0. unit from Outfall 001
under specified conditions'. Such discharges shall be limited and monitored by the Permittee
as specified below:
EFFLUENT
CHARACTERISTICS
EFFLUENT LIMITATIONS
MONITORING REQUIREMENTS
Monthly
Average
Weekly
Average
Daily
Maximum
Measurement
Frequency
Sample
Type
Sample
Location 2
Flow
Each Event
Estimate
E
Oil and Grease
Each Event
Grab
E
Total Suspended Solids
Each Event
Grab
E
Total Copper
Each Event
Grab
E
Total Iron
Each Event
Grab
E
Total Arsenic
Each Event
Grab
E
Total Selenium
Each Event
Grab
E
pH 3
Each Event
Grab
E
Temperature 4
Each Event
Grab
E
Acute Toxicity 5
Episodic
Grab
E
Footnotes:
1. This discharge is permitted only in cases caused by extreme rainfall; where unavoidable to
prevent loss of life, severe property damage, or damage to the cooling pond structure; or
maintenance activities. In the event a discharge occurs, the permittee shall inform the North
Carolina Division of Water Quality by telephone within 48 hours after the discharge event. The
permittee shall also provide the Division with the following written information within ten (10)
days of the discharge: a) a description and cause of the discharge; and b) the period of
discharge, including approximate dates and times, the anticipated period the discharge is
expected to continue, and steps being taken to reduce, eliminate, and prevent recurrence of
the discharge. The permittee shall take all reasonable steps to minimize any adverse impact to
receiving waters from the discharge, including such monitoring as is necessary to determine the
environmental impact of the discharge.
2. Sample Location: E= Effluent at discharge spillway.
3. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units.

Permit NC0005363
4. The temperature of the effluent shall be such as not to cause an increase in the temperature of
the receiving stream of more than 2.8°C and in no case cause the ambient water temperature
to exceed 32°C.
5. Acute Episodic Toxicity Testing (24-hour Fathead Minnow); refer to Section A(3).

Permit NC0005363
A. (2) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS [002]
Beginning on the effective date of this permit and lasting until expiration, the Permittee is
authorized to discharge non -contact cooling water from Outfall 002. Such discharges shall be
limited and monitored by the Permittee as specified below:
EFFLUENT
CHARACTERISTICS
EFFLUENT LIMITATIONS
MONITORING REQUIREMENTS
Monthly
Average
Weekly
Average
Daily
Maximum
Measurement
Frequency
Sample
Type
Sample
Locationl
Flow
Weekly
Pump Logs
E
Temperature 2
Quarterly
Grab
E,U,D
Total Residual Chlorine 3
200 pg/1
Monthly
Grab
E
Time of Chlorine Addition 3
120
min/day/unit
Daily
Logs
E
pH
Quarterly
Grab
E
Footnotes:
Sample Locations: E- Effluent; U- Upstream, approx. 1/4 mile above outfall, D -
Downstream, approx. 1/4 mile below outfall.
The temperature of the effluent shall be such as not to cause an increase in the
temperature of the receiving stream of more than 2.8°C and in no case cause the ambient
water temperature to exceed 32°C.
Monitoring requirements apply only if chlorine is added to the treatment system.
THERE SHALL BE NO DISCHARGE OF FLOATING SOLIDS OR VISIBLE FOAM IN OTHER THAN TRACE AMOUNTS.

Permit NC0005363
A. (3) ACUTE TOXICITY MONITORING (EPISODIC)
The permittee shall conduct FIVE acute toxicity tests using protocols defined as definitive in
E.P.A. Document EPA/600/4-90/027 entitled "Methods for Measuring the Acute Toxicity of
Effluents to Freshwater and Marine Organisms." The monitoring shall be performed as a
Fathead Minnow (Pimephales promelas) 24 hour static test. Effluent samples for self-
monitoring purposes must be obtained below all waste treatment. Sampling and subsequent
testing will occur during the first five discrete discharge events after the effective date of
this permit. After monitoring of the first five toxicity tests, the permittee will conduct one
test annually, with the annual period beginning in January of the next calendar year. The
annual test requirement must be performed and reported by June 30. If no discharge occurs
by June 30, notification will be made to the Division within 2 weeks after June 30. Toxicity
testing will be performed on the next discharge event for the annual test requirement.
The parameter code for this test is TAE6C. All toxicity testing results required as part of this
permit condition will be entered on the Effluent Discharge Form (MR -1) for the month in
which it was performed, using the appropriate parameter code. Additionally, DWQ Form AT -1
(original) is to be sent to the following address:
Attention: North Carolina Division of Water Quality
Environmental Sciences Section
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
Completed Aquatic Toxicity Test Forms shall be filed with the Environmental Sciences Section
no later than 30 days after the end of the reporting period for which the report is made.
Test data shall be complete and accurate and include all supporting chemical/ physical
measurements performed in association with the toxicity tests, as well as all dose/response
data. Total residual chlorine of the effluent toxicity sample must be measured and reported if
chlorine is employed for disinfection of the waste stream.
Should any test data from either these monitoring requirements or tests performed by the
North Carolina Division of Water Quality indicate potential impacts to the receiving stream,
this permit may be re -opened and modified to include alternate monitoring requirements or
limits.
NOTE: Failure to achieve test conditions as specified in the cited document, such as
minimum control organism survival and appropriate environmental controls, shall constitute
an invalid test and will require immediate follow-up testing to be completed no later than the
last day of the month following the month of the initial monitoring.

Permit NC0005363
A. (4.) BIOCIDE CONDITION
The permittee shall not discharge any biocides that have not been previously approved in conjunction
with the permit application. For biocides not previously approved by the Division of Water Quality, the
permittee shall notify the Director in writing prior to use of these biocides. Completion of Biocide
Worksheet Form 101 is not necessary for those outfalls with toxicity testing requirements.
A.(5) Cooling Water Intake Structure (CWIS)
The Weatherspoon Plant operates a closed -cycle condenser cooling system and therefore continues to
be in compliance with Section 316(b) requirements.

Permit NC0005363
B. (1) STORMWATER PERMIT REQUIREMENTS
Section A: Stormwater Permit Coverage
During the period beginning on the effective date of the permit and lasting until expiration,
the permittee is authorized to discharge stormwater associated with industrial activity. Such
discharges shall be controlled, limited and monitored as specified in this permit.
If industrial materials and activities are not exposed to precipitation or runoff as described in
40 CFR 5122.26(8), the facility may qualify for a No Exposure Exclusion from NPDES
stormwater discharge permit requirements. Any owner or operator wishing to obtain a No
Exposure Certification must submit a No Exposure Certification N01 form to the Division; must
receive approval by the Division; must maintain no exposure conditions unless authorized to
discharge under a valid NPDES stormwater permit; and must reapply for the No Exposure
Exclusion once every five (5) years.
Section B: Stormwater Permitted Activities
Until this permit expires or is modified or revoked, the permittee is authorized to discharge
stormwater to the surface waters of North Carolina or separate storm sewer system that has
been adequately treated and managed in accordance with the terms and conditions of this
individual permit. All stormwater discharges shall be in accordance with the conditions of this
permit.
Any other point source discharge to surface waters of the state is prohibited unless it is an
allowable non-stormwater discharge or is covered by this or another permit, authorization, or
approval. The stormwater discharges allowed by this individual permit shall not cause or
contribute to violations of Water Quality Standards.
This permit does not relieve the permittee from responsibility for compliance with any other
applicable federal, state, or local law, rule, standard, ordinance, order, judgment, or
decree.
B. (2) STORMWATER POLLUTION PREVENTION PLAN
The Permittee shall develop a Stormwater Pollution Prevention Plan, herein after
referred to as the Plan. This Plan shall be considered public information in accordance with
B. (6) Standard Conditions, Section E, Paragraph 3 of this individual permit. The Plan shall
include, at a minimum, the following items:
Site Plan. The site plan shall provide a description of the physical facility and the
potential pollutant sources which may be expected to contribute to contamination of
stormwater discharges. The site plan shall contain the following:

Permit NC0005363
(a) A general location map (USGS quadrangle map or appropriately drafted
equivalent map), showing the facility's location in relation to transportation
routes and surface waters, the name of the receiving water(s) to which the
stormwater outfall(s) discharges, or if the discharge is to a municipal separate
storm sewer system, the name of the municipality and the ultimate receiving
waters, and accurate latitude and longitude of the point(s) of discharge. The
general location map (or alternatively the site map) shall identify whether
each receiving water is impaired (on the state's 303(d) list of impaired
waters) or is located in a watershed for which a TMDL has been established,
and what the parameter(s) of concern are.
North Carolina's 303(d) List can be found here:
http://h2o.enr.state.nc.us/tmdl/Genera1_303d.htm#Downloads
North Carolina TMDL documents can be found here:
http://h2o.enr.state.nc.us/tmdI/TMDL list.htm#Fi nal_TMDLs.
(b) A narrative description of storage practices, loading and unloading activities,
outdoor process areas, dust or particulate generating or control processes, and
waste disposal practices. A narrative description of the potential pollutants
which could be expected to be present in the stormwater discharge from each
outfall.
(c) A site map drawn to scale (including a distance legend) showing: the site
property boundary, the stormwater discharge outfalls, all on-site and adjacent
surface waters and wetlands, industrial activity areas (including storage of
materials, disposal areas, process areas, loading and unloading areas, and haul
roads), site topography, all drainage features and structures, drainage areas
for each outfall, direction of flow in each drainage area, industrial activities
occurring in each drainage area, buildings, existing BMPs, and impervious
surfaces. The site map must indicate the percentage of each drainage area
that is impervious.
(d) A list of significant spills or leaks of pollutants that have occurred at the
facility during the three (3) previous years and any corrective actions taken to
mitigate spill impacts.
(e) Certification that the stormwater outfalls have been evaluated for the
presence of non-stormwater discharges. The certification statement will be
signed in accordance with the requirements found in B. (6) Standard
Conditions, Section B, Paragraph 3. The permittee shall re -certify annually
that the stormwater outfalls have been evaluated for the presence of non-
stormwater discharges.
2. Stormwater Management Plan. The stormwater management plan shall contain a
narrative description of the materials management practices employed which control
or minimize the exposure of significant materials to stormwater, including structural

Permit NC0005363
and nonstructural measures. The stormwater management plan, at a minimum, shall
incorporate the following:
(a) Feasibility Study. A review of the technical and economic feasibility of
changing the methods of operations and/or storage practices to eliminate or
reduce exposure of materials and processes to stormwater. Wherever
practical, the permittee shall prevent exposure of all storage areas, material
handling operations, and manufacturing or fueling operations. In areas where
elimination of exposure is not practical, the stormwater management plan shall
document the feasibility of diverting the stormwater runoff away from areas of
potential contamination.
(b) Secondary Containment Requirements and Records. Secondary containment is
required for: bulk storage of liquid materials; storage in any amount of Section
313 of Title III of the Superfund Amendments and Reauthorization Act (SARA)
water priority chemicals; and storage in any amount of hazardous substances,
in order to prevent leaks and spills from contaminating stormwater runoff. A
table or summary of all such tanks and stored materials and their associated
secondary containment areas shall be maintained. If the secondary
containment devices are connected directly to stormwater conveyance
systems, the connection shall be controlled by manually activated valves or
other similar devices (which shall be secured closed with a locking mechanism),
and any stormwater that accumulates in the containment area shall be at a
minimum visually observed for color, foam, outfall staining, visible sheens and
dry weather flow, prior to release of the accumulated stormwater.
Accumulated stormwater shall be released if found to be uncontaminated by
the material stored within the containment area. Records documenting the
individual making the observation, the description of the accumulated
stormwater, and the date and time of the release shall be kept for a period of
five years.
(c) BMP Summary. A listing of site structural and non-structural Best Management
Practices (BMP) shall be provided. The installation and implementation of
BMPs shall be based on the assessment of the potential for sources to
contribute significant quantities of pollutants to stormwater discharges and
data collected through monitoring of stormwater discharges. The BMP
Summary shall include a written record of the specific rationale for installation
and implementation of the selected site BMPs. The BMP Summary shall be
reviewed and updated annually.
3. Spill Prevention and Response Plan. The Spill Prevention and Response Plan (SPRP)
shall incorporate an assessment of potential pollutant sources based on a materials
inventory of the facility. Facility personnel (or the team) responsible for implementing
the SPRP shall be identified in a written list incorporated into the SPRP and signed and
dated by each individual acknowledging their responsibilities for the plan. A
responsible person shall be on-site at all times during facility operations that have the

Permit NC0005363
potential to contaminate stormwater runoff through spills or exposure of materials
associated with the facility operations. The SPRP must be site stormwater specific.
Therefore, an oil Spill Prevention Control and Countermeasure plan (SPCC) may be a
component of the SPRP, but may not be sufficient to completely address the
stormwater aspects of the SPRP. The common elements of the SPCC with the SPRP
may be incorporated by reference into the SPRP.
4. Preventative Maintenance and Good Housekeeping Program. A preventative
maintenance and good housekeeping program shall be developed. The program shall
list all stormwater control systems, stormwater discharge outfalls, all on-site and
adjacent surface waters and wetlands, industrial activity areas (including material
storage areas, material handling areas, disposal areas, process areas, loading and
unloading areas, and haul roads), all drainage features and structures, and existing
structural BMPs. The program shall establish schedules of inspections, maintenance,
and housekeeping activities of stormwater control systems, as well as facility
equipment, facility areas, and facility systems that present a potential for stormwater
exposure or stormwater pollution. Inspection of material handling areas and regular
cleaning schedules of these areas shall be incorporated into the program. Timely
compliance with the established schedules for inspections, maintenance, and
housekeeping shall be recorded in writing and maintained in the SPPP.
5. Employee Training. Training programs shall be developed and training provided at a
minimum on an annual basis for facility personnel with responsibilities for: spill
response and cleanup, preventative maintenance activities, and for any of the
facility's operations that have the potential to contaminate stormwater runoff.
Facility personnel (or team) responsible for implementing the training shall be
identified, and their annual training shall be documented by the signature of each
employee trained.
6. Responsible Party. The Stormwater Pollution Prevention Plan shall identify a specific
position(s) responsible for the overall coordination, development, implementation,
and revision to the Plan. Responsibilities for all components of the Plan shall be
documented and position assignments provided.
7. Plan Amendment. The permittee shall amend the Plan whenever there is a change in
design, construction, operation, or maintenance which has a significant effect on the
potential for the discharge of pollutants to surface waters. All aspects of the
Stormwater Pollution Prevention Plan shall be reviewed and updated on an annual
basis. The annual update shall include an updated list of significant spills or leaks of
pollutants for the previous three years, or the notation that no spills have occurred.
The annual update shall include re -certification that the stormwater outfalls have
been evaluated for the presence of non-stormwater discharges. Each annual update
shall include a re-evaluation of the effectiveness of the BMPs listed in the BMP
Summary of the Stormwater Management Plan.

Permit NC0005363
The Director may notify the permittee when the Plan does not meet one or more of
the minimum requirements of the permit. Within 30 days of such notice, the
permittee shall submit a time schedule to the Director for modifying the Plan to meet
minimum requirements. The permittee shall provide certification in writing (in
accordance with B. (6) Standard Conditions, Section B, Paragraph 5) to the Director
that the changes have been made.
8. Facility Inspections. Inspections of the facility and all stormwater systems shall occur
as part of the Preventative Maintenance and Good Housekeeping Program at a
minimum on a semi-annual schedule, once during the first half of the year (January to
June), and once during the second half (July to December), with at least 60 days
separating inspection dates (unless performed more frequently than semi-annually).
These facility inspections are different from, and in addition to, the stormwater
discharge characteristic monitoring required in B. (3), and B. (4) of this permit.
9. Implementation. The permittee shall implement the Plan. Implementation of the Plan
shall include documentation of all monitoring, measurements, inspections,
maintenance activities, and training provided to employees, including the log of the
sampling data and of actions taken to implement BMPs associated with the industrial
activities, including vehicle maintenance activities. Such documentation shall be kept
on-site for a period of five years and made available to the Director or the Director's
authorized representative immediately upon request.
B. (3) ANALYTICAL MONITORING REQUIREMENTS
Analytical monitoring of stormwater discharges shall be performed as specified in Table 1.
All analytical monitoring shall be performed during a representative storm event. The
required monitoring will result in a minimum of nine analytical samplings being conducted
over the term of the permit at each stormwater discharge outfall (SDO), unless representative
outfall status has been granted.
A representative storm event is a storm event that measures greater than 0.1 inches of
rainfall. The time between this storm event and the previous storm event measuring greater
than 0.1 inches must be at least 72 hours. A single storm event may have a period of no
precipitation of up to 10 hours. For example, if it rains but stops before producing any
collectable discharge, a sample may be collected if the next rain producing a discharge
begins within 10 hours.

Permit NC0005363
Table 1. Analytical Monitoring Requirements
Discharge
Characteristics
Units
Measurement
Frequencyl
Sample
Type2
Sample
Location3
40 CFR Part 423 Appendix A: 13
Priority Pollutant Metals (Ag, As,
Be, Cd, Cr, Cu, Hg, Ni, Pb, Sb,
Se, Tl, Zn )4
pg/l
semi-annual
Grab
SDO
Al
Pg/1
semi-annual
Grab
SDO
B
pg/l
semi-annual
Grab
SDO
COD
mg/1
semi-annual
Grab
SDO
TSS
Mg/1
semi-annual
Grab
SDO
Sulfate
mg/1
semi-annual
Grab
SDO
Oil and Grease (OEtG)
mg/1
semi-annual
Grab
SDO
pH
standard
I semi-annual
Grab
SDO
Total Rainfalls
inches
I semi-annual
Rain Gauge
Footnotes:
1 Measurement Frequency: Twice per year during a representative storm event, for each year until
either another permit is issued for this facility or until this permit is revoked or rescinded. If at the
end of this permitting cycle the permittee has submitted the appropriate paperwork for a renewal
permit before the submittal deadline, the permittee will be considered for a renewal application.
The applicant must continue semi-annual monitoring until the renewed permit is issued. See Table 2
for schedule of monitoring periods through the end of this permitting cycle.
2 If the stormwater runoff is controlled by a stormwater detention pond, a grab sample of the
discharge from the pond shall be collected within the first 30 minutes of discharge.
3 Sample Location: Samples shall be collected at each stormwater discharge outfall (SDO) unless
representative outfall status has been granted.
4 Mercury shall be analyzed by EPA Low-level detection method 1631 E. This method also requires a
field blank be analyzed. A benchmark does not apply; however, values above 0.012 ug/1 should be
noted on annual SDO DMR reports to the Regional Office.
5 For each sampled representative storm event the total precipitation must be recorded. An on-site
rain gauge or local rain gauge reading must be recorded.
The permittee shall complete the minimum nine analytical samplings in accordance with the
schedule specified below in Table 2. A minimum of 60 days must separate each sample
date unless monthly monitoring has been instituted under a Tier Two response.

Permit NC0005363
Table 2. Monitoring Schedule
Monitoring period 1,2
Sample Number
Start
End
Year 1 - Period 1
1
January 1, 2010
June 30, 2010
Year 1 - Period 2
2
July 1, 2010
December 31, 2010
Year 2 - Period 1
3
January 1, 2011
June 30, 2011
Year 2 - Period 2
4
July 1, 2011
December 31, 2011
Year 3 - Period 1
5
January 1, 2012
June 30, 2012
Year 3 - Period 2
6
July 1, 2012
December 31, 2012
Year 4 - Period 1
7
January 1, 2013
June 30, 2013
Year 4 - Period 2
8
July 1, 2013
December 31, 2013
Year 5 - Period 1
9
January 1, 2014
July 31, 2014
Fnntnntpt
Maintain semi-annual monitoring during permit renewal process. The applicant must continue semi-
annual monitoring until the renewed permit is issued.
If no discharge occurs during the sampling period, the permittee must submit a monitoring report
indicating "No Flow" within 30 days of the end of the six-month sampling period.
The permittee shall report the analytical results from the first sample with valid results
within the monitoring period. In addition, a separate signed Annual Summary DMR copy
shall be submitted to the local DWQ Regional Office (RO) by March 1 of each year. The
permittee shall compare monitoring results to the benchmark values in Table 3. The
benchmark values in Table 3 are not permit limits but should be used as guidelines for the
permittee's Stormwater Pollution Prevention Plan (SPPP). Exceedences of benchmark values
require the permittee to increase monitoring, increase management actions, increase record
keeping, and/or install stormwater Best Management Practices (BMPs) in a tiered program.
See below the descriptions of Tier One and Tier Two.
Table 3. Benchmark Values for Analytical Monitoring
Discharge Characteristics
Units
Benchmark
Aluminum
mg/l
0.75
Antimony
mg/l
0.09
Arsenic
mg/l
0.36
Beryllium
mg/l
0.07
Boron
N/A
N/A
Cadmium
mg/l
0.001
Chromium
mg/l
1

Permit NC0005363
Discharge Characteristics
Units
Benchmark
Copper
mg/l
0.007
Lead
mg/l
0.03
Mercury
ng/l
N/A
Nickel
mg/l
0.26
Selenium
mg/l
0.056
Silver
mg/l
0.001
Thallium
N/A
N/A
Zinc
mg/l
0.067
COD
mg/l
120
TSS
mg / l
100
Sulfate
mg/l
500
Oil and Grease (OEtG)
mg/l
30
pH (see footnote 1)
Standard
6- 91
Fontnotes*
1 If pH values outside this range are recorded in sampled stormwater discharges, but ambient
rainfall data indicate precipitation pH levels are within + 0.1 standard units of the measured
discharge values or lower, then the lower threshold of this benchmark range does not apply.
Readings from an on-site or local rain gauge (or local precipitation data) must be documented to
demonstrate background concentrations were below the benchmark pH range.

Permit NC0005363
Tier One
If: The first valid sampling results are above a benchmark value, or outside of the benchmark
range, for any parameter at any outfall;
Then: The permittee shall:
1. Conduct a stormwater management inspection of the facility within two weeks of receiving
sampling results.
2. Identify and evaluate possible causes of the benchmark value exceedence.
3. Identify potential, and select the specific: source controls, operational controls, or
physical improvements to reduce concentrations of the parameters of concern, or to
bring concentrations to within the benchmark range.
4. Implement the selected actions within two months of the inspection.
5. Record each instance of a Tier One response in the Stormwater Pollution Prevention Plan.
Include the date and value of the benchmark exceedence, the inspection date, the
personnel conducting the inspection, the selected actions, and the date the selected
actions were implemented.
Tier Two
If: During the term of this permit, the first valid sampling results are above the benchmark
values, or outside of the benchmark range, for any specific parameter at a specific discharge
outfall two times in a row (consecutive):
Then: The permittee shall:
1. Repeat all the required actions outlined above in Tier One.
2. Immediately institute monthly monitoring for all parameters (except mercury) at every
outfall where a sampling result exceeded the benchmark value for two consecutive
samples. Monthly (analytical and qualitative) monitoring shall continue until three
consecutive sample results are below the benchmark values, or within the benchmark
range, for all parameters at that outfall.
3. If no discharge occurs during the sampling period, the permittee is required to submit a
monthly monitoring report indicating "No Flow."
4. Maintain a record of the Tier Two response in the Stormwater Pollution Prevention Plan.

Permit NC0005363
During the term of this permit, if the valid sampling results required for the permit monitoring
periods exceed the benchmark value, or are outside the benchmark range, for any specific
parameter at any specific outfall on four occasions, the permittee shall notify the DWQ
Fayetteville Regional Office Supervisor in writing within 30 days of receipt of the fourth
analytical results. DWQ may, but is not limited to:
• Require that the permittee increase or decrease the monitoring frequency for the
remainder of the permit;
• Work with permittee to develop alternative response strategies;
• Require the permittee to install structural stormwater controls;
• Require the permittee to implement other stormwater control measures; or
• Require that the permittee implement site modifications to qualify for the No Exposure
Exclusion.
This site discharges to impaired waters experiencing problems with Mercury. A Total
Maximum Daily Load (TMDL) has been approved for this segment of The Lumber River. This
permit requires the permittee to monitor for the pollutant(s) of concern and submit results to
the Division of Water Quality. The Division will consider the monitoring results in determining
whether additional BMPs are needed to control the pollutant(s) of concern to the maximum
extent practicable.
If additional BMPs are needed to achieve the required level of control, the permittee will be
required to (1) develop a strategy for implementing appropriate BMPs, and (2) submit a
timetable for incorporation of those BMPs into the permitted Stormwater Pollution Prevention
Plan.
B. (4) QUALITATIVE MONITORING REQUIREMENTS
Qualitative monitoring requires a visual inspection of each stormwater outfall regardless of
representative outfall status and shall be performed as specified in Table 4, during the
analytical monitoring event. [If analytical monitoring is not required, the permittee still must
conduct semi-annual qualitative monitoring.] Qualitative monitoring is for the purpose of
evaluating the effectiveness of the Stormwater Pollution Prevention Plan (SPPP) and assessing
new sources of stormwater pollution.
In the event an atypical condition is noted at a stormwater discharge outfall, the permittee
shall document the suspected cause of the condition and any actions taken in response to the
discovery. This documentation will be maintained with the SPPP.

Permit NC0005363
Table 4. Qualitative Monitoring Requirements
Discharge Characteristics
Frequency1
Monitoring
Location2
Color
semi-annual
SDO
Odor
semi-annual
SDO
Clarity
semi-annual
SDO
Floating Solids
semi-annual
SDO
Suspended Solids
semi-annual
SDO
Foam
semi-annual
SDO
Oil Sheen
semi-annual
SDO
Erosion or deposition at
the outfall
semi-annual
SDO
Other obvious indicators
of stormwater pollution
semi-annual
SDO
Footnotes:
1 Measurement Frequency: Twice per year during a representative storm event, for each year until
either another permit is issued for this facility or until this permit is revoked or rescinded. If at the
end of this permitting cycle the permittee has submitted the appropriate paperwork for a renewal
permit before the submittal deadline, the permittee will be considered for a renewal application.
The applicant must continue semi-annual monitoring until the renewed permit is issued. See Table 2
for schedule of monitoring periods through the end of this permitting cycle.
2 Monitoring Location: Qualitative monitoring shall be performed at each stormwater discharge
outfall (SDO) regardless of representative outfall status.
REMOVED B. (5) ON-SITE VEHICLE MAINTENANCE MONITORING REQUIREMENTS
B. (6) STANDARD CONDITIONS FOR NPDES STORMWATER INDIVIDUAL PERMITS
SECTION A: STORMWATER COMPLIANCE AND LIABILITY
1. Compliance Schedule
The permittee shall comply with Limitations and Controls specified for stormwater discharges in
accordance with the following schedule:
Existing Facilities already operating but applying for permit coverage for the first time: The
Stormwater Pollution Prevention Plan shall be developed and implemented within 12 months of
the effective date of the initial permit and updated thereafter on an annual basis. Secondary
containment, as specified in B. (2) Section A, Paragraph 2(b) of this permit, shall be
accomplished within 12 months of the effective date of the initial permit issuance.

Permit NC0005363
New Facilities applying for coverage for the first time and existing facilities previously
permitted and applying for renewal under this permit: The Stormwater Pollution Prevention
Plan shall be developed and implemented prior to the beginning of discharges from the
operation of the industrial activity and be updated thereafter on an annual basis. Secondary
containment, as specified in B. (2), Section A, Paragraph 2(b) of this permit shall be
accomplished prior to the beginning of discharges from the operation of the industrial activity.
2. Duty to Comply
The permittee must comply with all conditions of this individual permit. Any permit
noncompliance constitutes a violation of the Clean Water Act and is grounds for enforcement
action; for permit termination, revocation and reissuance, or modification; or denial of a
permit upon renewal application.
a. The permittee shall comply with standards or prohibitions established under section
307(a) of the Clean Water Act for toxic pollutants within the time provided in the
regulations that establish these standards or prohibitions, even if the permit has not yet
been modified to incorporate the requirement.
The Clean Water Act provides that any person who violates a permit condition is
subject to a civil penalty not to exceed $25,000 per day for each violation. Any person
who negligently violates any permit condition is subject to criminal penalties of $2,500
to 25,000 per day of violation, or imprisonment for not more than 1 year, or both. Any
person who knowingly violates permit conditions is subject to criminal penalties of
$5,000 to $50,000 per day of violation, or imprisonment for not more than 3 years, or
both. Also, any person who violates a permit condition may be assessed an
administrative penalty not to exceed $10,000 per violation with the maximum amount
not to exceed $125,000. [Ref: Section 309 of the Federal Act 33 USC 1319 and 40 CFR
122.41(a).]
C. Under state law, a daily civil penalty of not more than ten thousand dollars ($10,000)
per violation may be assessed against any person who violates or fails to act in
accordance with the terms, conditions, or requirements of a permit. [Ref: NC General
Statutes 143-215.6A].
Any person may be assessed an administrative penalty by the Director for violating
section 301, 302, 306, 307, 308, 318 or 405 of the Act, or any permit condition or
limitation implementing any of such sections in a permit issued under section 402 of the
Act. Administrative penalties for Class I violations are not to exceed $10,000 per
violation, with the maximum amount of any Class I penalty assessed not to exceed
$25,000. Penalties for Class II violations are not to exceed $10,000 per day for each
day during which the violation continues, with the maximum amount of any Class II
penalty not to exceed $125,000.
3. Duty to Mitigate
The permittee shall take all reasonable steps to minimize or prevent any discharge in violation
of this individual permit which has a reasonable likelihood of adversely affecting human health
or the environment.

Permit NC0005363
4. Civil and Criminal Liabili
Except as provided in B. (6), Section C of this permit regarding bypassing of stormwater control
facilities, nothing in this individual permit shall be construed to relieve the permittee from any
responsibilities, liabilities, or penalties for noncompliance pursuant to NCGS 143-215.3, 143-
215.6A, 143-215.613, 143-215.6C or Section 309 of the Federal Act, 33 USC 1319. Furthermore,
the permittee is responsible for consequential damages, such as fish kills, even though the
responsibility for effective compliance may be temporarily suspended.
5. Oil and Hazardous Substance Liabili
Nothing in this individual permit shall be construed to preclude the institution of any legal
action or relieve the permittee from any responsibilities, liabilities, or penalties to which the
permittee is or may be subject to under NCGS 143-215.75 et seq. or Section 311 of the Federal
Act, 33 USC 1321.
6. Property Rights
The issuance of this individual permit does not convey any property rights in either real or
personal property, or any exclusive privileges, nor does it authorize any injury to private
property or any invasion of personal rights, nor any infringement of Federal, State or local laws
or regulations.
7. Severability
The provisions of this individual permit are severable, and if any provision of this individual
permit, or the application of any provision of this individual permit to any circumstances, is
held invalid, the application of such provision to other circumstances, and the remainder of this
individual permit, shall not be affected thereby.
8. Duty to Provide Information
The permittee shall furnish to the Director, within a reasonable time, any information which
the Director may request to determine whether cause exists for modifying, revoking and
reissuing, or terminating this permit or to determine compliance with this permit. The
permittee shall also furnish to the Director upon request, copies of records required to be kept
by this individual permit.
9. Penalties for Tampering
The Clean Water Act provides that any person who falsifies, tampers with, or knowingly renders
inaccurate, any monitoring device or method required to be maintained under this individual
permit shall, upon conviction, be punished by a fine of not more than $10,000 per violation, or
by imprisonment for not more than two years per violation, or by both. If a conviction of a
person is for a violation committed after a first conviction of such person under this paragraph,
punishment is a fine of not more that $20,000 per day of violation, or by imprisonment of not
more than 4 years, or both.

Permit NC0005363
10. Penalties for Falsification of Re
The Clean Water Act provides that any person who knowingly makes any false statement,
representation, or certification in any record or other document submitted or required to be
maintained under this individual permit, including monitoring reports or reports of compliance
or noncompliance shall, upon conviction, be punished by a fine of not more than $10,000 per
violation, or by imprisonment for not more than two years per violation, or by both.
SECTION B: STORMWATER GENERAL CONDITIONS
1. Individual Permit Expiration
The permittee is not authorized to discharge after the expiration date. In order to receive
automatic authorization to discharge beyond the expiration date, the permittee shall submit
forms and fees as are required by the agency authorized to issue permits no later than 180 days
prior to the expiration date. Any permittee that has not requested renewal at least 180 days
prior to expiration, or any permittee that does not have a permit after the expiration and has
not requested renewal at least 180 days prior to expiration, will be subjected to enforcement
procedures as provided in NCGS 5143-215.6 and 33 USC 1251 et. seq.
2. Transfers
This permit is not transferable to any person except after notice to and approval by the
Director. The Director may require modification or revocation and reissuance of the permit to
change the name and incorporate such other requirements as may be necessary under the Clean
Water Act. The Permittee is required to notify the Division in writing in the event the
permitted facility is sold or closed.
3. Signatory Requirements
All applications, reports, or information submitted to the Director shall be signed and certified.
All applications to be covered under this individual permit shall be signed as follows:
(1) In the case of a corporation: by a responsible corporate officer. For the
purpose of this Section, a responsible corporate officer means: (a) a president,
secretary, treasurer or vice president of the corporation in charge of a principal
business function, or any other person who performs similar policy or decision
making functions for the corporation, or (b) the manager of one or more
manufacturing, production, or operating facilities, provided, the manager is
authorized to make management decisions which govern the operation of the
regulated facility including having the explicit or implicit duty of making major
capital investment recommendations, and initiating and directing other
comprehensive measures to assure long term environmental compliance with
environmental laws and regulations; the manager can ensure that the necessary
systems are established or actions taken to gather complete and accurate
information for permit application requirements; and where authority to sign
documents has been assigned or delegated to the manager in accordance with
corporate procedures;

Permit NC0005363
(2) In the case of a partnership or limited partnership: by a general partner;
(3) In the case of a sole proprietorship: by the proprietor;
(4) In the case of a municipal, state, or other public entity: by a principal
executive officer, ranking elected official, or other duly authorized employee.
All reports required by the individual permit and other information requested by the
Director shall be signed by a person described above or by a duly authorized
representative of that person. A person is a duly authorized representative only if:
(l) The authorization is made in writing by a person described above;
(2) The authorization specified either an individual or a position having
responsibility for the overall operation of the regulated facility or activity,
such as the position of plant manager, operator of a well or well field,
superintendent, a position of equivalent responsibility, or an individual or
position having overall responsibility for environmental matters for the
company. (A duly authorized representative may thus be either a named
individual or any individual occupying a named position.); and
(3) The written authorization is submitted to the Director.
C. Any person signing a document under paragraphs a. or b. of this section shall make the
following certification:
"I certify, under penalty of law, that this document and all attachments were prepared
under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gather and evaluate the information submitted. Based on
my inquiry of the person or persons who manage the system, or those persons directly
responsible for gathering the information, the information submitted is, to the best of
my knowledge and belief, true, accurate, and complete. I am aware that there are
significant penalties for submitting false information, including the possibility of fines
and imprisonment for knowing violations."
4. Individual Permit Modification. Revocation and Reissuance. or Termination
The issuance of this individual permit does not prohibit the Director from reopening and
modifying the individual permit, revoking and reissuing the individual permit, or terminating
the individual permit as allowed by the laws, rules, and regulations contained in Title 40, Code
of Federal Regulations, Parts 122 and 123; Title 15A of the North Carolina Administrative Code,
Subchapter 2H .0100; and North Carolina General Statute 143-215.1 et al.
5. Permit Actions
The permit may be modified, revoked and reissued, or terminated for cause. The notification
of planned changes or anticipated noncompliance does not stay any individual permit condition.
SECTION C: STORMWATER OPERATION AND MAINTENANCE OF POLLUTION CONTROLS
1. Proper Operation and Maintenance

Permit NC0005363
The permittee shall at all times properly operate and maintain all facilities and systems of
treatment and control (and related appurtenances) which are installed or used by the permittee
to achieve compliance with the conditions of this individual permit. Proper operation and
maintenance also includes adequate laboratory controls and appropriate quality assurance
procedures. This provision requires the operation of back-up or auxiliary facilities or similar
systems which are installed by a permittee only when the operation is necessary to achieve
compliance with the conditions of this individual permit.
2. Need to Halt or Reduce Not a Defense
It shall not be a defense for a permittee in an enforcement action that it would have been
necessary to halt or reduce the permitted activity in order to maintain compliance with the
condition of this individual permit.
3. Bypassing, of Stormwater Control Facilities
Bypass is prohibited and the Director may take enforcement action against a permittee for
bypass unless:
Bypass was unavoidable to prevent loss of life, personal injury or severe property
damage; and
There were no feasible alternatives to the bypass, such as the use of auxiliary control
facilities, retention of stormwater or maintenance during normal periods of equipment
downtime or dry weather. This condition is not satisfied if adequate backup controls
should have been installed in the exercise of reasonable engineering judgment to
prevent a bypass which occurred during normal periods of equipment downtime or
preventive maintenance; and
C. The permittee submitted notices as required under, B. (6), Section E of this permit.
If the Director determines that it will meet the three conditions listed above, the Director may
approve an anticipated bypass after considering its adverse effects.

Permit NC0005363
SECTION D: STORMWATER MONITORING AND RECORDS
Representative Sampling
Samples collected and measurements taken, as required herein, shall be characteristic of the
volume and nature of the permitted discharge. Analytical sampling shall be performed during a
representative storm event. Samples shall be taken on a day and time that is characteristic of
the discharge. All samples shall be taken before the discharge joins or is diluted by any other
waste stream, body of water, or substance. Monitoring points as specified in this permit shall
not be changed without notification to and approval of the Director.
2. Recording Results
For each measurement, sample, inspection or maintenance activity performed or collected
pursuant to the requirements of this individual permit, the permittee shall record the following
information:
The date, exact place, and time of sampling, measurements, inspection or maintenance
activity;
b. The individual(s) who performed the sampling, measurements, inspection or
maintenance activity;
C. The date(s) analyses were performed;
d. The individual(s) who performed the analyses;
e. The analytical techniques or methods used; and
f. The results of such analyses.
3. Flow Measurements
Where required, appropriate flow measurement devices and methods consistent with accepted
scientific practices shall be selected and used to ensure the accuracy and reliability of
measurements of the volume of monitored discharges.
4. Test Procedures
Test procedures for the analysis of pollutants shall conform to the EMC regulations published
pursuant to NCGS 143-215.63 et. seq, the Water and Air Quality Reporting Acts, and to
regulations published pursuant to Section 304(8), 33 USC 1314, of the Federal Water Pollution
Control Act, as Amended, and Regulation 40 CFR 136.
To meet the intent of the monitoring required by this individual permit, all test procedures
must produce minimum detection and reporting levels and all data generated must be reported
down to the minimum detection or lower reporting level of the procedure.

Permit NC0005363
5. Representative Outfall
If a facility has multiple discharge locations with substantially identical stormwater discharges
that are required to be sampled, the permittee may petition the Director for representative
outfall status. If it is established that the stormwater discharges are substantially identical and
the permittee is granted representative outfall status, then sampling requirements may be
performed at a reduced number of outfalls.
6. Records Retention
Visual monitoring shall be documented and records maintained at the facility along with the
Stormwater Pollution Prevention Plan. Copies of analytical monitoring results shall also be
maintained on-site. The permittee shall retain records of all monitoring information, including
all calibration and maintenance records and all original strip chart recordings for continuous
monitoring instrumentation, and copies of all reports required by this individual permit for a
period of at least 5 years from the date of the sample, measurement, report or application.
This period may be extended by request of the Director at any time.
7. Inspection and Entry
The permittee shall allow the Director, or an authorized representative (including an authorized
contractor acting as a representative of the Director), or in the case of a facility which
discharges through a municipal separate storm sewer system, an authorized representative of a
municipal operator or the separate storm sewer system receiving the discharge, upon the
presentation of credentials and other documents as may be required by law, to;
Enter upon the permittee's premises where a regulated facility or activity is located or
conducted, or where records must be kept under the conditions of this individual
permit;
Have access to and copy, at reasonable times, any records that must be kept under the
conditions of this individual permit;
C. Inspect at reasonable times any facilities, equipment (including monitoring and control
equipment), practices, or operations regulated or required under this individual permit;
and
d. Sample or monitor at reasonable times, for the purposes of assuring individual permit
compliance or as otherwise authorized by the Clean Water Act, any substances or
parameters at any location.
SECTION E: STORMWATER REPORTING REQUIREMENTS
1. Discharge Monitoring Reports
Samples analyzed in accordance with the terms of this permit shall be submitted to the Division
on Discharge Monitoring Report (DMR) forms provided by the Director. Submittals shall be
delivered to the Division no later than 30 days from the date the facility receives the sampling
results from the laboratory.

Permit NC0005363
When no discharge has occurred from the facility during the report period, the permittee is
required to submit a discharge monitoring report within 30 days of the end of the three-month
sampling period, giving all required information and indicating "NO FLOW" as per NCAC T1 5A
026 .0506.
The permittee shall record the required qualitative monitoring observations on the SDO
Qualitative Monitoring Report (QMR) form provided by the Division, and shall retain the
completed forms on site. Qualitative monitoring results should not be submitted to the
Division, except upon DWQ's specific requirement to do so.
2. Submitting Reports
Duplicate signed copies of all reports required herein, shall be submitted to the following
address:
Division of Water Quality
Surface Water Protection Section
ATTENTION: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
In addition, a separate signed Annual Summary DMR copy shall be submitted to the
permittee's DWQ Regional Office (RO) by March 1 of each year.
3. Availability of Reports
Except for data determined to be confidential under NCGS 143-215.3(a)(2) or Section 308 of the
Federal Act, 33 USC 1318, all reports prepared in accordance with the terms shall be available
for public inspection at the offices of the Division of Water Quality. As required by the Act,
analytical data shall not be considered confidential. Knowingly making any false statement on
any such report may result in the imposition of criminal penalties as provided for in NCGS 143-
215.66 or in Section 309 of the Federal Act.
4. Non-Stormwater Discharges
If the storm event monitored in accordance with this individual permit coincides with a non-
stormwater discharge, the permittee shall separately monitor all parameters as required under
the non-stormwater discharge permit and provide this information with the stormwater
discharge monitoring report.
5. Planned Changes
The permittee shall give notice to the Director as soon as possible of any planned changes at
the permitted facility which could significantly alter the nature or quantity of pollutants
discharged. This notification requirement includes pollutants which are not specifically listed
in the individual permit or subject to notification requirements under 40 CFR Part 122.42 (a).
6. Anticipated Noncompliance

Permit NC0005363
The permittee shall give notice to the Director as soon as possible of any planned changes at
the permitted facility which may result in noncompliance with the individual permit
requirements.

7. Bypass
Permit NC0005363
Anticipated bypass. If the permittee knows in advance of the need for a bypass, it shall
submit prior notice, if possible at least ten days before the date of the bypass;
including an evaluation of the anticipated quality and affect of the bypass.
Unanticipated bypass. The permittee shall submit notice within 24 hours of becoming
aware of an unanticipated bypass.
8. Twenty-four Hour Reporting
The permittee shall report to the central office or the appropriate regional office any
noncompliance which may endanger health or the environment. Any information shall be
provided orally within 24 hours from the time the permittee became aware of the
circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
The written submission shall contain a description of the noncompliance, and its causes; the
period of noncompliance, including exact dates and times, and if the noncompliance has not
been corrected, the anticipated time compliance is expected to continue; and steps taken or
planned to reduce, eliminate, and prevent reoccurrence of the noncompliance.
The Director may waive the written report on a case-by-case basis if the oral report has been
received within 24 hours.
9. Other Noncompliance
The permittee shall report all instances of noncompliance not reported under 24 hour reporting
at the time monitoring reports are submitted.
10. Other Information
Where the permittee becomes aware that it failed to submit any relevant facts in an
application for an individual permit or in any report to the Director, it shall promptly submit
such facts or information.
SECTION F: STORMWATER LIMITATIONS REOPENER
This individual permit shall be modified or alternatively, revoked and reissued, to comply with any
applicable effluent guideline or water quality standard issued or approved under Sections 302(b) (2) (c),
and (d), 304(b) (2) and 307(a) of the Clean Water Act, if the effluent guideline or water quality
standard so issued or approved:
a. Contains different conditions or is otherwise more stringent than any effluent limitation in the
individual permit; or
b. Controls any pollutant not limited in the individual permit.
The individual permit as modified or reissued under this paragraph shall also contain any other
requirements in the Act then applicable.

Permit NC0005363
SECTION G: STORMWATER ADMINISTERING AND COMPLIANCE MONITORING FEE REQUIREMENTS
The permittee must pay the administering and compliance monitoring fee within 30 (thirty) days after
being billed by the Division. Failure to pay the fee in timely manner in accordance with 15A NCAC 2H
.0105(b)(4) may cause this Division to initiate action to revoke the individual permit.
SECTION H: DEFINITIONS FOR STORMWATER SECTION OF THIS PERMIT
1. Act
See Clean Water Act.
2. Arithmetic Mean
The arithmetic mean of any set of values is the summation of the individual values divided by
the number of individual values.
3. Allowable Non-Stormwater Disch
This permit regulates stormwater discharges. Non-stormwater discharges which shall be
allowed in the stormwater conveyance system are:
(a) All other discharges that are authorized by a non-stormwater NPDES permit.
(b) Uncontaminated groundwater, foundation drains, air -conditioner condensate without
added chemicals, springs, discharges of uncontaminated potable water, waterline and
fire hydrant flushings, water from footing drains, flows from riparian habitats and
wetlands.
(c) Discharges resulting from fire -fighting or fire -fighting training.
4. Best Management Practices (BMPs)
Measures or practices used to reduce the amount of pollution entering surface waters. BMPs
may take the form of a process, activity, or physical structure.
5. Bypass
A bypass is the known diversion of stormwater from any portion of a stormwater control facility
including the collection system, which is not a designed or established operating mode for the
facility.
6. Bulk Storage of Liquid Products
Liquid raw materials, manufactured products, waste materials or by-products with a single
above ground storage container having a capacity of greater than 660 gallons or with multiple
above ground storage containers located in close proximity to each other having a total
combined storage capacity of greater than 1,320 gallons.

Permit NC0005363
7. Clean Water Act
The Federal Water Pollution Control Act, also known as the Clean Water Act (CWA), as
amended, 33 USC 1251, et. seq.
8. Division or DWQ
The Division of Water Quality, Department of Environment and Natural Resources.
9. Director
The Director of the Division of Water Quality, the permit issuing authority.
10. EMC
The North Carolina Environmental Management Commission.
11. Grab Sample
An individual sample collected instantaneously. Grab samples that will be directly analyzed or
qualitatively monitored must be taken within the first 30 minutes of discharge.
12. Hazardous Substance
Any substance designated under 40 CFR Part 116 pursuant to Section 311 of the Clean Water
Act.
13. Landfill
A disposal facility or part of a disposal facility where waste is placed in or on land and which is
not a land treatment facility, a surface impoundment, an injection well, a hazardous waste
long-term storage facility or a surface storage facility.
14. Municipal Separate Storm Sewer System
A stormwater collection system within an incorporated area of local self-government such as a
city or town.
15. No Exposure
A condition of no exposure means that all industrial materials and activities are protected by a
storm resistant shelter or acceptable storage containers to prevent exposure to rain, snow,
snowmelt, or runoff. Industrial materials or activities include, but are not limited to, material
handling equipment or activities, industrial machinery, raw materials, intermediate products,
by-products, final products, or waste products. DWQ may grant a No Exposure Exclusion from
NPDES Stormwater Permitting requirements only if a facility complies with the terms and
conditions described in 40 CFR 9122.26(g).

Permit NC0005363
16. Overburden
Any material of any nature, consolidated or unconsolidated, that overlies a mineral deposit,
excluding topsoil or similar naturally -occurring surface materials that are not disturbed by
mining operations.
17. Permittee
The owner or operator issued a permit pursuant to this individual permit.
18. Point Source Discharge of Stormwater
Any discernible, confined and discrete conveyance including, but not specifically limited to, any
pipe, ditch, channel, tunnel, conduit, well, or discrete fissure from which stormwater is or may
be discharged to waters of the state.
19. Representative Storm Event
A storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72
hours in which no storm event measuring greater than 0.1 inches has occurred. A single storm event
may contain up to 10 consecutive hours of no precipitation. For example, if it rains for 2 hours without
producing any collectable discharge, and then stops, a sample may be collected if a rain producing a
discharge begins again within the next 10 hours.
20. Representative Outfall Status
When it is established that the discharge of stormwater runoff from a single outfall is
representative of the discharges at multiple outfalls, the DWQ may grant representative outfall
status. Representative outfall status allows the permittee to perform analytical monitoring at
a reduced number of outfalls.
21. Rinse Water Discharge
The discharge of rinse water from equipment cleaning areas associated with industrial activity.
Rinse waters from vehicle and equipment cleaning areas are process wastewaters and do not
include washwaters utilizing any type of detergent or cleaning agent.
22. Secondary Containment
Spill containment for the contents of the single largest tank within the containment structure
plus sufficient freeboard to allow for the 25 -year, 24-hour storm event.
23. Section 313 Water Prioritv Chemical
A chemical or chemical category which:
Is listed in 40 CFR 372.65 pursuant to Section 313 of Title III of the Superfund
Amendments and Reauthorization Act (SARA) of 1986, also titled the Emergency
Planning and Community Right -to -Know Act of 1986;

Permit NC0005363
Is present at or above threshold levels at a facility subject to SARA Title III, Section 313
reporting requirements; and
C. That meets at least one of the following criteria:
(1) Is listed in Appendix D of 40 CFR part 122 on Table II (organic priority
pollutants), Table III (certain metals, cyanides, and phenols), or Table IV
(certain toxic pollutants and hazardous substances);
(2) Is listed as a hazardous substance pursuant to section 311(b)(2)(A) of the CWA
at 40 CFR 116.4; or
(3) Is a pollutant for which EPA has published acute or chronic water quality
criteria.
24. Severe Property Damage
Means substantial physical damage to property, damage to the control facilities which causes
them to become inoperable, or substantial and permanent loss of natural resources which can
reasonably be expected to occur in the absence of a bypass. Severe property damage does not
mean economic loss caused by delays in production.
25. Significant Materials
Includes, but is not limited to: raw materials; fuels; materials such as solvents, detergents, and
plastic pellets; finished materials such as metallic products; raw materials used in food
processing or production; hazardous substances designated under section 101 (14) of CERCLA;
any chemical the facility is required to report pursuant to section 313 of Title III of SARA;
fertilizers; pesticides; and waste products such as ashes, slag and sludge that have the
potential to be released with stormwater discharges.
26. Significant Spills
Includes, but is not limited to: releases of oil or hazardous substances in excess of reportable
quantities under section 311 of the Clean Water Act (Ref: 40 CFR 110.10 and CFR 117.21) or
section 102 of CERCLA (Ref: 40 CFR 302.4).
27. Stormwater Runoff
The flow of water which results from precipitation and which occurs immediately following
rainfall or as a result of snowmelt.
28. Stormwater Associated with Industrial
The discharge from any point source which is used for collecting and conveying stormwater and
which is directly related to manufacturing, processing or raw material storage areas at an
industrial site. Facilities considered to be engaged in "industrial activities" include those
activities defined in 40 CFR 122.26(b)(14). The term does not include discharges from facilities
or activities excluded from the NPDES program.
29. Stormwater Pollution Prevention Plan

Permit NC0005363
A comprehensive site-specific plan which details measures and practices to reduce stormwater
pollution and is based on an evaluation of the pollution potential of the site.
30. Ten Year Design Storm
The maximum 24 hour precipitation event expected to be equaled or exceeded on the average
once in ten years. Design storm information can be found in the State of North Carolina Erosion
and Sediment Control Planning and Design Manual.
31. Total Flow
The flow corresponding to the time period over which the entire storm event occurs. Total
flow shall be either; (a) measured continuously, (b) calculated based on the amount of area
draining to the outfall, the amount of built -upon (impervious) area, and the total amount of
rainfall, or (c) estimated by the measurement of flow at 20 minute intervals during the rainfall
event.
32. Total Maximum Daily Load (TMDL)
A TMDL is a calculation of the maximum amount of a pollutant that a waterbody can receive
and still meet water quality standards, and an allocation of that amount to the pollutant's
sources. A TMDL is a detailed water quality assessment that provides the scientific foundation
for an implementation plan. The implementation plan outlines the steps necessary to reduce
pollutant loads in a certain body of water to restore and maintain water quality standards in all
seasons. The Clean Water Act, Section 303, establishes the water quality standards and TMDL
programs.
33. Toxic Pollutant
Any pollutant listed as toxic under Section 307(a)(1) of the Clean Water Act.
34. Upset
Means an exceptional incident in which there is unintentional and temporary noncompliance
with technology based permit effluent limitations because of factors beyond the reasonable
control of the permittee. An upset does not include noncompliance to the extent caused by
operational error, improperly designed treatment or control facilities, inadequate treatment or
control facilities, lack of preventive maintenance, or careless or improper operation.
35. Vehicle Maintenance Activity
Vehicle rehabilitation, mechanical repairs, painting, fueling, lubrication, vehicle cleaning
operations, or airport deicing operations.
36. Visible Sedimentation
Solid particulate matter, both mineral and organic, that has been or is being transported by
water, air, gravity, or ice from its site of origin which can be seen with the unaided eye.

Permit NC0005363
37. 25 -year, 24 hour storm event
The maximum 24-hour precipitation event expected to be equaled or exceeded, on the
average, once in 25 years.

Proposed Cooling Pond Assessment Work Plan August 2016
W.H. Weatherspoon Power Plant
APPENDIX C
SynTerra
2009 NPDES PERMIT NC0005363 RENEWAL
APPLICATION

&4?r Progress Energy
Progress Energy
Weatherspoon Steam Electric Plant
491 Power Plant Rd.
Lumberton, NC 28358
Mrs. Dina Sprinkle
NCDENR Division of Water Quality
Point Source Branch
1617 Mail Service Center
Raleigh, N. C. 27699-1617
RECEIVED
January 26, 2009
JAN 2 8 2009
DENR - WATER QUALITY
File No: WSPN — 12520-13-01 POINT SOURCE BRANCH
Subject: Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc.
Weatherspoon Steam Electric Plant, Robeson County, Lumberton, North Carolina
National Pollutant Discharge Elimination System (NPDES) Permit No. NC0005363
Renewal Application
Dear Mrs. Sprinkle:
The current NPDES permit for the Progress Energy Carolina's Weatherspoon Steam Electric Plant expires
on July 31, 2009. By this correspondence, Progress Energy Carolinas respectfully requests that the
NPDES permit for the facility be reissued. Enclosed are the completed application forms with
attachments, one signed original and two copies.
Progress Energy Carolinas has submitted five amendments to the last NPDES permit application. There
were two amendments to add coal freeze conditioning agents to Form 2C, Attachment 4 (November 2004
and December 2008); an amendment to incorporate the reverse osmosis water treatment system into full
operation (March 2005); an amendment to add three storm water outfalls along the access road to allow for
coal ash reclamation activities (March 2008); and an amendment to increase the predicted number of
trucks leaving the site with reclaimed ash (September 2008). The enclosed Form 2F includes sampling
data results from the new storm water outfalls as required by regulation. Some of the analyses have not
been conducted but the results will be submitted by the March 2010 due date under another transmittal.
The description of the management of solids generated during wastewater treatment at the Weatherspoon
Steam Electric Plant is described in Form 2C, Attachment 3.
Progress Energy Carolinas requests that the following condition be added to the renewed NPDES permit.
The purpose of this condition is to formally recognize the guidance and understanding we have received
from the Division in the past.
Progress Energy Carolinas, Inc.
Weatherspoon Steam Plant
491 Power Plant Road
Lumberton, NC 28358

Progress Energy Carolinas, Inc. NPDES Permit Number NC0005363
Weatherspoon Steam Electric Plant 2009 Renewal Application
Attachment 1
Form 1 Item XI Maps
a
21
M' keu
r lata e
ILI
u 001'
Poin
I,
1 }
r
j
f,US South0eas berton (NQ Qu
cD'1'=+39 20 a - r,
All igtits Re -set Not FwNavigat n
S �\ Plant (;o ing
v
LUX
Weat'enpoon Steam
Electric Plant Site
NORTH CAROLINA
0 0.4 0.8 1.2 1.6 2 miles

Progress Energy Carolinas, Inc. NPDES Permit Number NC0005363
Weatherspoon Steam Electric Plant 2009 Renewal Application
Attachment 1 continued
0 0.1 0.2 0.3 0.4 0.5 mile
1-2

Progress Energy Carolinas, Inc. NPDES Permit Number,NC0005363
Weatherspoon Steam Electric Plant 2009 Renewal Application
Attachment 2
Form 2C Item II -A Flows, Sources of Pollution, and Treatment Technologies
-Source
Estimated
Average Flow
Comments
A
4-16 MGD
Make up waterfrom Lumber River, Maximum rate is 9 12 MGD
B
4 03 MGD
Non -contact cooling water discharge, Maximum rate is 9 12 MGD
C
0 7 MGD
Make up for cooling pond, Maximum rate is 9.12 MGD
D
193 MGD
Condenser cooling water - all three units operating
E
2,400 GPM
Maximum make-up rate for fire water system
F
1`00 GPD
Low volume wastes to the ash pond
G
21 MGD
Ash pond discharge to cooling pond
H
191 MGD
Condenser discharge to cooling pond
1
120 GPM
Intermittent flow as required
J
0 14 MGD
Discharge to cooling pond from oil/water separator
K
0 024 MGD
Estimated using average daily rainfall
L
0 14 MGD
Variable due to intermittent processes and runoff
M
0.7 MGD
Maximum estimated rate is 1 6.MGD
N
0 MGD
Pond does not normally discharge See Attachment 3 for details
O
0 00125 MGD
Sanitary wastes
P
50,000 gal/event -
Units 1 & 2
42,000 gal/event -
Unit.3
Amounts estimated, Usually evaporated in boiler
Q
0 19 MGD
,Estimated using average daily rainfall
R
0 011 MGD
Estimated using average daily rainfall
S
4,000 GPD
Low volume waste (reverse osmosis refect water)
2-1

Progress Energy Carolinas, Inc. NPDES Permit Number NC0005363
Weatherspoon Steam Electric Plant 2009 Renewal Application
Attachment 2 continued
Combustion
Turbine Site
2-2
Evaporation
Potable Water -
Sanitary Waste Septic
Sand & Q
System
System Tank
Gravel
P
Bed
Metal Cleaning
Wastes
Wells
i
I Plant Systems
Low Volume L
Wastes
Plant Drains
Lumber RiverF
i
A
i
i
oily Wastes
River Intake
i
'
StructureNV
Ash�Siuice
sstem
Condenser
Retention
I I
Basin
Heat
Exchancier
i
Plant Drains
i
i
' D
�
E
OiUVNater
Fire"Water
Internal Intake
Separator
S stem
Structure
J
Q Plant Area Storm
Ash
Water Runoff
Pond
S Low Volume
Wastes
Coal Pile
Runoff
Secondary
Settling
K
Evaporation &
Basin
Seepage
M
G
C
Cooling
Pond
B
7Separator
NStormWater
Lumber River
NV
Outfalls
Outfa11002
Vater
Outfa11001
Combustion
Turbine Site
2-2

Progress Energy Carolinas, Inc. NPDES Permit Number NC0005363
Weatherspoon Steam Electric Plant 2009 Renewal Application
Attachment 3
Form 2C Item II -B Flows, Sources of Pollution, and Treatment Technologies
The Weatherspoon Steam Electric Plant is a steam cycle electric generating plant with three coal -burning
units and four internal combustion turbines Source water is withdrawn from the Lumber River as,
required to make up evaporative and seepage losses from the power plant's cooling pond Makeup
pumping rates from the river are, highly variable depending upon natural weather conditions, generation
load, plant operations, and cooling pond water level Water for,power plant use is also'withdrawn from
groundwater wells
Chemical constituents of the power plant discharges will, in part, be representative of the naturally
occurring chemical quality of the intake water and will also have chemical constituents of such quality and
quantity associated with similar discharges,for fossil generating facilities of'this size, type, and in this
geographical location Either all or part of the elements enumerated in the Periodic Table, either
singularly or in any combination, may from time to time be contained,m this discharge,
There are -five permitted outfalls at the Weatherspoon Steam Electric Plant, three of which are for storm
water along the access road Components of the discharges are described below
OUTFALL 001 - DISCHARGE FROM COOLING POND
Most of the power,plant waste streams are routed directly or indirectly to the 225 -acre off -stream cooling
pond located on the north side, of the Lumber'River in Robeson County, North Carolina, and thereby
recycled Releases from the cooling pond are rare, occurring usually when a mayor storm is expected
and additional freeboard is needed to prevent°overtopping of the,pond-dikes On other occasions, the,
pond may need to be drawn down for maintenance purposes The cooling pond last discharged to the
Lumber River in September of 1999 There are also incidental seepages and leaks through the dikes and
retaining wall (sheet pilings) to ifie Lumber River from the cooling pond The pH of the cooling pond is
neutralized when needed by adding acid or caustic at the circulation water pumps A description of the
waste streams that discharge info the -cooling ipond follows
Recirculated Cooling Water
This flow provides condenser cooling water for,the three generating units The`flow is,discharged into
the cooling pond and routed through the cooling pond by baffle dikes to achieve maximum surface
cooling efficiency before reaching the condenser cooling water circulating water'pumps to be used
again Cooling of the water is achieved primarily by evaporation from the pond surface, which'is
estimated to consume a maximum of approximately 1 6 MGD above natural evaporation rates during
times the units' are in full operation Control of'biolog'ical fouling on condenser surfaces is
accomplished by chlorination, as needed
Coal Pile Runoff
Rainfall runoff from the coal pile (approximately 6 acres) is routed to the cooling, pond, which provides
treatment by sedimentation Freeze conditioning agents may be applied to coal shipped via trains to
the power plant typically between November 15 and March 15
Storm Water Runoff
Rainfall runoff from power plant areas is ultimately routed ,to the cooling pond Sludges/sediments
collected `in sumps, catchment basins, etc are disposed of'in the ash pond or by,other appropriate
methods
Ash Sluice Water
Fly ash and bottom ash'from all three units is hydraulically conveyed by a ash sluice pipeline system
to the ash pond In addition, water from washing the interior of the precipitators is sent to the ash
3-1

Progress'Energy Carolinas, Inc. 'NPDES, Permit Number NC0005363
Weatherspoon Steam Electric Plant 2009 Renewal Application
pond via the -ash sluice pipeline In the ash pond,,a stand pipe allows for overflow release to a small
secondary settling basin containing another stand pipe for release, to the cooling pond
Sanitary Waste
`Sanitary waste is treated on-site by a septic tank and a sand and' gravel drainage field which
discharges to the cooling pond Flow from the system is dependent upon fluctuating demand due to
variations in the number of personnel on site When needed, residuals are,disposed of off-site by'a
licensed contract disposal firm
Metal Cleaning Waste
Wastes from the chemical cleaning of the boiler,tubes are normally disposed of by evaporation in
boilers, either onsite or at another Progress Energy facility Boiler cleaning is usually performed
every 10 years Should boiler cleaning wastes not be evaporated, they will be treated by
neutralization and precipitation in portable holding tanks The liquid fraction of°the metal cleaning
wastes will be discharged to the ash pond The sludge fraction of the metal cleaning wastes will be
disposed of in either the ash pond or by other,appropnate methods
Internal Combustion Turbine (CT) -Site
There are four internal combustion turbines located at the Weatherspoon Plant' All drains from the
CT site, including drains collecting rainfall, are routed through an oil -water separator which
discharges to the cooling pond Sludges/sediments collected in sumps, catchment basins; etc are
disposed of in the ash pond or by other appropriate methods
Low -Volume Waste
All low volume wastes are routed by gravity flow to the cooling pond Sumps collect°and convey
miscellaneous equipment, leakage, equipment drainage for maintenance, equipment wash down
water, sampling streams, and closed cooling water system blowdown Water treatment wastes
consist of solutions of sodium chloride, used for water softener regeneration, and sodium hydroxide
and sulfuric acid which are used in the regeneration of'derniineralizers Demineraliier regeneration
wastes are routed to the ash pond via the ash sluice line Reverse osmosis refect water and cleaning
solutions, and water'softener regeneration wastes are routed directly to the cooling pond Blowdown
of boilervater to control boiler chemistry is routed ,to a flash tank, which discharges to the cooling
pond Drains from areas likely to contain oil filled equipment or storage are routed through an oil -
water separator Sludges/sediments from sumps, catchment basins, etc are disposed of in the ash
pond ,or by other appropriate methods The air preheaters are water washed infrequently, When the
air preheaters are Washed, approximately 50,000 gallons of wastewater is produced and discharged
to the ash pond via1he ash sluice pipelines In addition, wastes from the chemical cleaning of the
condenser tubes and heat exchangers are normal ly,disposed,of,in the ash pond' Should condenser
and heat exchanger cleaning wastes not be discharged into the -ash pond, they will be evaporated At
this -time it is unclear as to how often condenser and heat exchanger cleaning may be performed
In, many cases, chemicals added during,the,plant processes are consumed or chemically altered
Only trace amounts might be discernable in water entering the cooling pond Because the•cooling
pond serves as a final treatment basin and receives significantly ,greater volumes,of water from other
inflows, detectable levels,of these chemicals should not occur in the infrequent cooling pond
discharge
Non -contact Cooling Water
Non -contact cooling water withdrawn from, the Lumber River passes through heat exchangers to
provide non -contact cooling for the power plant's closed cooling water system which is typically
discharged to Outfall 002 As necessary, however, the non -contact cooling water may be routed
temporarily to the cooling pond depending on the need for cooling pond makeup water Sodium
hypochlonte (chlorine) is added at the non -contact cooling water pump intake, as needed, to control
biological fouling of the heat exchanger surfaces
3-2

Progress Energy Carolinas, Inc. NPDES Permit Number NC0005363
Weathers'noon Steam Electric Plant 2009' Renewal Application
Miscellaneous Waste Streams to the Cooling Pond
`Coal Ash Management
From time to time fly and bottom ash in the ash pond may be stacked or relocated within the diked
boundary of the,ash pond system As this pond management activity does not alter the chemical
character of the pond contents, no change in the nature of,the discharge to the cooling pond is
anticipated
Coal Ash Reclamation
In the event a practicable market becomes available, Progress Energy may exercise the option of
reclaiming coal ash from the ash pond system In consideration of the scope of such an operation, no
additional discharges are expected to result from coal ash reclamation efforts Bestmanagement
practices are established for these activities During ash removal projects, trucks are filled within the
confines of the ash pond boundary and the load covered The trucks are washed down prior, to
leaving the area and travel along a graveled on-site roadway before exiting the site via the plant
access road
Herbicide and Pesticide Usage in the Treatment System Ponds
Herbicides may be used as,needed to control nuisance aquatic vegetation These herbicides are
applied by licensed applicators, or persons under the immediate supervision of a licensed applicator,
in accordance with the manufacturer's instructions Pesticides may be used as needed to, perform
biological assessments These Pesticides are applied by licensed applicators, or persons under the
immediate supervision of a licensed applicator, in accordance with the manufacturer's instructions
OUTFALL 002 — NON -CONTACT COOLING WATER
Non -contact cooling water is withdrawn from the. Lumber River and passed -through heat exchangers to
provide non -contact cooling for the plant's closed cooling water,system After passing through the heat
exchanger, non -contact cooling water is routed to the Lumber River via Outfall 002 Depending -on the
need forcooling pond ,makeup water, the non -contact cooling water may be directed to the cooling pond
Sodium hypochlorite (chlorine),is,added at the non -contact cooling water pump intake,, as needed, to
control biological fouling of the heat exchanger surfaces As established by written plant procedure,
chlorine is only added during times where non -contact cooling water is.routed to the cooling pond Upon
completiori of chlorine addition, the non -contact cooling water system is operated with discharge to the
cooling pond for a period of at least one hour prior to any redirection to Outfall 002 This procedure has
been'implernented to prevent the discharge of chlorine to the river
OUTPAL' LS SW -1, SW -1, AND SW -3 — STORM WATER
During periods when coal ash removal prolects,are,conducted, the access road'to,the power plant
becomes part of an industrial activity with three storm water outfalls along the road which are addressed
in EPA Form 2F Storm water from these three discrete,conveyances is ultimately discharged into the
Lumber River
3-3

Progress Energy Carolinas, Inc: NPDES Permit Number NC0005363
Weatherspoon Steam Electric Plant 2009 Renewal Application
Attachment 4
Form 2C Item VI Potential Discharges Not Covered by Analysis
Chemical
Quantity
Frequency
Purpose
(used/yr)
Hydrazine
165 gal
Continuous - when
units are operational
Oxygen scavenger in boiler
TrisodiUm phosphate
1,000 Ib
As needed
pH control in boiler
Disodium phosphate
5001b
As needed
pH, control in boiler
Morpholine
275 gal
Continuous - when
pH control in boiler
units are operational
Sodium hypochlorite
12,950 gal
As,needed
Condenser and heat
exchanger biofouling control
Sodium hydroxide
9,000 gal
As needed
Deminerahzer regeneration
Sodium hydroxide
As needed
As needed
Cooling pond neutralization
Sulfuric acid
2,000 gal
As needed
Demmeralizer regeneration
Sulfuric acid
19,000 gal,
As needed
Cooling pond neutralization
Molybdenum trioxide
330 gal
As needed
Corrosion control in,boder
Sodium chloride
8,000 Ib
Twice per month
Water softener regeneration
Sulfur, elemental
75 tonContinuous
- when
Flue gas, conditioning
Unit 3 isoperational
Citric acid, 50%
1,460 gal/event
Approximately once
Boiler cleaning
per 10 years per unit
Citric acid, dry
3,500 Ib/unit/event
Approximately once
Boiler cleaning
per 10 ears er,unit
_
Ammonium hydroxide
1,560 gal/event
Approximately once
goiler,cleaning
er 10 years per unit
1,775 Ib/event -
'Sodium Nitrite
Units 1 & 2
Approximately once
Boiler cleaning
1,450 Ib/event -
per 10 years per unit
_ Unit 3 -
Corrosion Inhibitor
55 gal/,'unit/event
Approximately once
Boiler cleaning
per 10 years per unit
475 Ib/event —
Amm`onium bicarbonate
Units 1 & 2
Approximately once
375 lb/event —
per 10 years per unit
Boiler cleaning
Unit 3
EDTA, 39%
6,000
Approximately once
Boiler cleaning
al/unit/event
per 10 years per unit
Hydrochloric,acid
1,000 gal/event
As,needed
Condenser cleaning
Rodine 213
5 gal/event
As needed
Condenser cleaning
Ammonium bifluonde
100 Ib/event
As needed
Condenser cleaning
4-1

Progress Energy Carolinas, Inc. NPDES Permit Number N00005363
Weatherspoon Steam Electric Plant 2009 Renewal Application
Chemical
Quantity
(used''/yr)
Frequency
Purpose
,FAF-10 foam agent
110 gal/,event
As needed
Condenser cleaning
FAF-20 anti -foam agent
20 gal/event
As needed
Condenser cleaning
Sodium carbonate
500 'lb/event
As needed
Condenser cleaning
Sodium hydroxide
400 gal/event
As needed
Condenser cleaning
Sandb►ast,Media
500-700 Ib
As needed
Equipment cleaning
Rhodamine liquid dye
0 01-0 03
al/event
As needed
Performance testing
Hypersperse MDC120
25 Ib/MG
Duping operation
'Reverse osmosis anti-scalent
Solisep MPT150
17 Ib/MG
During operation
'Reverse osmosis coagulant
Kleen MCT403
-
48 Ib/event
Quarterly or as
,needed
Reverse osmosis membrane
cleaning
Kleen MCT411
24 Ib/event
Quarterly or as
needed
Reverse osmosis membrane
cleaning
O'B Freezetrol 60
Variable
As needed
Coal freeze conditioning agent
O'B Freezetrol 62
Variable
As needed
Coal freeze conditioning agent
O'B Freezetrol 76-T
Variable
As needed
Coal freeze conditioning agent
FCA -1'000
Variable
As needed
" Coal freeze conditioning agent
,FCA -1010
Variable
As needed
Coal freeze conditioning agent
'FCA -2000
Variable
As needed
Coal freeze conditioning agent
FCA -2500
Variable
As needed
Coal freeze conditioning agent
FCA -3070
Variable
As,needed
Coal freeze conditioning agent,
SRA -6000
Variable
As needed
Coal°freeze conditioning agent
SRA -7000
Variable,
As needed
Coal freeze conditioning agent
Flomin ST-Geomelt55
Variable
As needed
Coal freeze conditioning agent
Flomin ST -944
Variable
As needed
Coal freeze conditioning agent
AKJ FC=504
Variable
As needed
Coal freeze'conditioning agent
BT 910
Variable
As, needed
Coal freeze conditioning agent
NALCO 8880
Variable
As needed
ent
Coal freeze conditioning agent
BIO -PRO 55
Variable
As needed
Coal freeze conditioning agent
FreeFlow SR -300
Variable
As needed
Coal freeze conditioning agent
4-2

Progress Energy Carolinas, Inc. NPDES Permit Number NC0005363
Weatherspoon Steam Electric Plant 2009 Renewal Application
Attachment 6
Form 2F Item III Site Drainage Maps
0 0.1 0.2 0 3 0.4 0.5 miles
6-1

Progress Energy Carolinas, Inc. NPDES Permit Number NC0005363
Weatherspoon Steam Electric Plant 2009 Renewal Application
Attachment 6 continued
—765 ft to top
of grade
Open Drainage from
drain abandoned rail line
pipe ditches and fields
cuardrese �•��Drain junction bo,
�® ..
;Underground pipe
• Catch
+� basin
SW -3 mA�� x.44.••
V. �f'P •.• '•
o�
a a
s '
r
Old
restrooms •-
Parking
Lot
N
1 Scale (approximated) c'd
I1 n = 80' pienKtabie
Approximated
6-2

Progress Energy Carolinas, Inc. NPDES Permit Number NC0005363
Weatherspoon Steam Electric Plant 2009 Renewal Application
Attachment 6 continued
N
1 Scale (approximated)
I 1" = 270'
NC 72
Power Plant Road
Used auto parts
business
Small pond
offsite
SW -1
Unnamed
tributary to the
Lumber River
Top of grade
6-3

Coal Fired plants in NC
Progress Energy
Weatherspoon.— NC0005363 — East
Issued Modification 5/13/32008, (original issued 9/27/2004)
Expire: 7/31/2009
There is no FGD process. There is one ash pond that discharges to, the main cooling pond. The,
cooling pond_ has a designated outfall with limits Modification was to address storm water
management requirements. There is no special condition for Dike inspection In the last -renewal
there was no pursuit of an RPA since—no changes or reduction in limits/monitonng lwere
considered valid. Fact Sheet supports last permit renewal. Narrative reviewed, no problems
noted:
Reviewed,By. Ron Berry
Review'Date '1/16/09
11

Cv Progress Energy
December 1, 2008
Mr. Gil Vinzani, Supervisor, Eastern NPDES Program
Division of Water Quality
North Carolina Department of Environment and Natural Resources
1617 Mail Service Center
Raleigh, NC 27699-1617
Subject: Carolina Power & Light Company dba Progress Energy Carolinas, Inc.
Asheville Steam Electric Plant NPDES Permit Number NC0000396
Cape Fear Steam Electric Plant NPDES Permit Number NC0003433
Lee Steam Electric Plant NPDES Permit Number NC0003417
Mayo Steam Electric Plant NPDES Permit Number NCO038377
Roxboro Steam Electric Plant NPDES Permit Number NC0003425
Sutton Steam Electric Plant NPDES Permit Number NC0001422
Weatherspoon Steam Electric Plant NPDES Permit Number NCO005363
NPDES Permit Application Amendment
Dear Mr. Vinzani:
Progress Energy Carolinas, Inc. (PEC) proposes to amend the NPDES Permit application for the
subject facilities to add three additional freeze conditioning agents.
These facilities expect to receive shipments of coal treated with freeze conditioning agents
during the winter months (November 15 through March 15). Freeze conditioning agents, needed
depending upon expected weather conditions during transport to ensure coal does not freeze in
railcars, will be applied at an approximate rate of 2 pints per ton of coal. The product names
used by the various coal mines which supply fuel to Progress Energy Carolinas power plants
could include one or more of the additional following products (MSDSs enclosed):
Product Name Primary Composition
FreeFlow SR -300 30-50% glycerin
Flomin ST -944 SRA > 50% diethylene glycol mixture and polymer/surfactant blend
Bio -Pro 55 55% glycerin
Coal pile runoff at each of these facilities flows to a treatment system (e.g., ash pond, cooling
pond, settling basin). However, since there is a slight potential that these chemicals could be
present in the wastewater that is ultimately discharged via a permitted outfall, PEC requests that
these products be appended to the NPDES permit application. Note that toxicity testing is a
permit requirement at each power plant outfall which contains the coal pile runoff waste stream.

�9�� Progress Energy
ptember T5, 2008
Mr. Gil Vinzani
SEP 15 2008
Supervisor, Eastern NPDES Program
North Carolina Department of Environment and Natural Resources
Division of Water Quality
1617 Mail Service Center
Raleigh, NC 27699-1617
L SEP7,&, 2008
DE"=R - WATER QUALITY t
Subject: Carolina Power & Light Company d/b/a Progress Energy Carolinas, Inc.
Weatherspoon Steam Electric Plant
NPDES Permit No. NC0005363
Permit Application Amendment
Dear Mr. Vinzani:
Progress Energy Carolinas, Inc., is amending our NPDES permit application to reflect an
increase in the planned number of trucks per day to transport coal ash off site as part of the ash
reclamation activity at the Weatherspoon Steam Electric Plant.
The ash reclamation activity currently conducted by the Weatherspoon Steam Electric Plant was
described in the latest NPDES permit application. In the cover letter, we indicated that twenty
trucks per day were planned. Due to changing market conditions, we are planning to increase the
number of trucks per day to approximately forty. We will continue to follow our Best
Management Practices (BMPs) and thus we do not expect any increased discharges into the three 4,11
permitted storm water outfalls. c?X
Please amend your files accordingly. If there are any questions, please contact Robin Bryson at
[phone].
I cert, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and
evaluate the information submitted. Based on my inquiry of the person or persons who manage the system,
or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties
for submitting false information, including the possibility offines and imprisonment for knowing violations.
Sincerely,
(�;/ 17Zr,6 -;�-AtJd
Mark Frederick, Plant Manager
JMF/rb
Enclosures
c: Mr. L. Baxley
Ms. R.
. Bryson
ro N atHers riYt�2rMskey o Inas, Inc.
491 Power Plant Road
Lumberton. NC 28358

Proposed Cooling Pond Assessment Work Plan August 2016
W.H. Weatherspoon Power Plant
SynTerra
2014 NPDES PERMIT NC0005363 RENEWAL
APPLICATION

DUKE
EMERUY
PROGRESS
January 28, 2014
v t
Mr. Tum Bel"ick
NCDENR-Division of Water Resources
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
ECEI E
JA M 2 9 ,,
Subject: Duku Energy Proyruss, Inc. (Duke Enargy)
Weatherspoon Plant, Robeson Cum ity
NPDcS Permit 7 NC0005313a Renewal Hppiication
Deas Mi. Belnick.
C. V. Seita..-. Enoi—gy Complex
'ov i swton Seam Plant RU
w:irni-gtan, RC 28401
910.341-;f ow
i yiu341-4fau
The current NPDES Wastewater Permit for the Duke Energy Prugrss, Inc. Weatherspoon Plant
expires on July 3 t, c'v tzF. By this correspondence, Duke Energy requests that the NPDEZ
permit for this facility be zissuad. Encivaud is the cumplatud appliCatiun furm vvith attazhmcnts:
one signed oi iginal and two copies. The facility has nut discharged from Outfall 001 since 1999=
therefore a grab sample was pulled from the cooling pond near the outfall in order to provide the
effluent analysis required by Furm 2C.
Thure have bean two modifications to the permit since it was originally issued in November,
2009. Fist, un June 15, 2011, the Division of Water Quality (now the Division of Water
Resources 101visionp issued a modification to remove Section B (stormwater requirementst on
the basis that coal ash hauling activity had ceased. Secondly, the Diviuiun issuud a mudificatiun
an April 17. 2012- to remove the effluent limits page associated With Outfall 002 (nun -contact
cooling water} on the Basis tnat the plant ceased operation of its coal-fired units and the
d6charga atruUmre vias capped. At this Lima, dcmulitiun acti,,itias at the Weatherspaun Plant
are ongoing. Form 2C Attachment 3 disuasses the remaini,.g wastewater streams at the site.
Doke Energy respeutfully requests that tha Division incurpurate the following changes into the
renewed permit for Outfall Oat:
Remove monitoring requirements for arsenic_ and selenium on the basis that coal ash is
no longer generated at the site or sluiced to the ash pond. i his is consistent with the
requirements for other facilities that Have decommissioned coai-flretl units.
Remove monitoring requirements for copper and irn on the basis that metal cleaning
wastes subject to 40 CFR 423.10 are no longer generated onsite.
Remove temperature monitoring and Foutnute 4 un the basis that rucietiulatud uoolin y
water Is nu lunge generated at the facility. Thurefure any disuharga from the treatment
unit referred to as the "cooling pond" cold nut actually cuntai, , proCaas wynte. used for
uuoling purposes.

vveadlempoon rianr, RoQeson county
19FUE5 Permit iF MCM1305363 Renewal application
P-gc Z
W Ifot]Ity 5ectlon m(5) as follows:
A(5) Cooling Water Intake Structure (CWIS)
The WeatherspseR-WaRif-9 rid
ther-efe ts. The
WeathCrspoon Plant no longer performs closed -cycle condenser cooling; than the water
intake structure is no longer subject to compliance with Section s 06b) requirements.
Add the fallowing two special conditions to the permit for consistency with other Duke
Energy facilities.
A(#) Groundwatur Monitoring
TRe permittee shall conduct g"u ndwater monitoring to determine the compliance of this
NPDES parmitted facility YJth the current groundwater standards found under 15A
NCAC 2L.0200. The monitoring shall be conducted in accordance with the Sampling
Plan approved by the Division.
A(#) Ash Pond Closure
Ash wvnd clu5arz- activities shall be conducted in accoriiance with the msR Puna Closure
plan approved by the Division.
A(#) Structural Integrity Inspections of Ash Pond Dam
The facility shall meet the dam design and dam safety requirements per 40 CFR 125.95.
Thank you, in advance, for your Lcnsideratiun of the eb%„e-requested items. If there are any
questions regarding the information provided in this letter or the er clobed application, please
contact Toys Ogellu, Environmental Specialist II in our North Carolina Regional MeauquaRers at
[phone]; or Kai it Tyndall. Environmental Professional fur the Waatherspocn Plant, at
(910) 3414775. These staff may also be reached via email at Leto a.O allu Dake-
Ener-gy.com or Kent.Tyndail(cDDuka-Enorcly.cc;m, respectively.
I ceniry, unver penarry or raw, mar rhis document and all attachments were prepared under my direction or
supervision in accordance with a systa..r ra -cr.- m -r yu..t.r.eapersonnei propeny garneranir evaruare me
:..rormarion suomirreo. aaseff on my inquiry or ripe person or persons who manage rhe system, or those persons
directly responsible for gathering the information, the inforrn.C.....or..'rrad to rnu rapt or r.., Kra :iarisa Q..a
r, K;, ....---ra, ane compiere. i am aware mar mere are signincanr penarries tor suumi?ring false information,
incpuaing me possibility of fines and imprisonment for knowing violations.
Sincerely,
Allen m. Clare
Station Manager
Enclosures: EPH Form i — General If
EPA Foy m 2C -- Wastewater Discharge Information

l•l.ese P -a ur type Fn u.. onslia„au smog Only.
Form Aooroved. OM13 No 2040-0086
FORM
U.S. ENVIRONMENTAL PROTECTION AGENCY
I EPA I.D. NUMBER
.�
GEIRERAC IRFIDI MATt61a
,.
C—.lid,edPernik. Pmg...a
F NCL] OUDS30&z0 1!
GENERAL
lR� rl h. tin._ 11..:....■.I...s h.1,,. _ _,....f..,;)
, , u ,. n
LABEL ITEMS
0l,.l111151t! lo -.37m- 0113
if a pwrited label has been pruMed, ansa it in ere
de=i(jiieted ---■a. Revl■w the Irll■nr,aG■n
Is Irrmmea, oro:: through a ti .mer ate correct a... in Rte
1. EPA I.D. NUMBER
appr0prlam m,n arse tlelow. Also, If any w the preprinted data
I$ absent flhe area to the /ell of the I.bef T___ fist_ the
III. FACILITY NAME
PLEASE PLACE LABEL IN THIS
SPACE
bdol-,tion that _hwld. ,r), please provide li in ere proper
c..! -n a e.(e) MM. It ate la..., o ....,,,Piet. aro correct, you
need not complete Items I, 111, V. and VI (except V046 whkh
V FACILITY MAILING
ADDRESS
most be ■.mpkfedComp6t■ all Name 0 me label
hes been Pro,deee. It -or �. Rte let.. ..ea nem
aesmPCens .110 for ate NWI --ming o ;;Ch this
y: FACILITY LOCATION
data I s collected.
II. POLLUTANT CHARACTERISTICS
INSTRUCTIONS: Complete A through J to determine whether you need to submit any permit application forms to the EPA. If you answer "yes' to any questions, ;ea m==t
sotimit Unix form no we sopplamanol rorn lisieo In Rte parenu.e.ls -ioIlowing the ge.stlon. M.rnIn .Ile M. in star iflim commn .. in. sopplemenwi form is attached, If
you .m -mm'n." to ..ah question, you nand net zmb „R ..my of there fem=. Yale may .nr :.r'ns' 9 year..cti=ty Is ..,deded from p.RnR mgeimm.nts; see Section. C of me
Instructions. See also. Section 0 of the Instructions for definitions of bold-faced terms
laws'
• ^
—"„n's
'a
Re
�ae�
aplClf IC Oula 7 iw=
ST Iftirle aEC3 IWN3
A Is this facifiry a publicly owned treatment works which
8 Does or will this facility refther exisdrng or proposed]
maxima In a aiscll.rge w waste or tRu U.n.: ;FORM 2A)
X
inelod.. concentrated animal feeding operation of
.,matt■ .nlr...l prude=tiem faellity which mosit: L. _
+s
,■
x,
discharge to waters of the U.S.? ;FORM 28)
C Is this a faeillty which currently results In discharges to
X
x
17. Is flus . proposes f..aliry f6.,—than thase descried in R
:..lots of th. U.S. o.hon than thus. described In A or 8
e. B . bore) : hi.h JI result in . dischargu to w.ters of
abo-? (FORM 2C)
the U.S.? ;FORM 2D)
_
_
_,
E Dws or will lflis racie=r tr..!, a;oro, or alapoa. or
h..�ordeae -=too? (FORM 3)
X
F Do you or will you Ir.J.ct res this r.cal..r Inousim.; .r
m=midp_I .foment bsl- the Iowa ==l stratum
X
containing, within one quarter mile of the well bore,
underground sources of drinking w..ar? ZFORM .r
ti
x
G. Do you or will you mtvot .. mix .actli.r any proaeceo water
H Do you or --:II you Inject .1 this f.ci;i,r solda ror species;
or oth.r nold: which a -- brought to the serious in
prwu=-= coah .: mining of =effort b; the Fra=ch
wm7;ecWn with conventional all or natural gas proauction,
X
solution mining of minerals, in situ combustion of fossil
X
intact fluids used for enhanced recovery of oil or n.wral
real, ov.. —very art g..7,.. a.I .nargy, TvRR .r
g.s, or injeic; fluids for storage of ligald hydleearbom:?
(FORM 4)
I Is this f.cility . proposed vtatle-.cry aeafee which Is en.
J 1= thl: f:cilft; _ trap■=d =tatlem.ry -sere. -hick i=
or the 2a indo_bW wt■eodes listed In the Instructions and
v
NOT one of the 28 industrial categories I:sted in the
v
which will potenflally emit 100 tons per year of sny air
L.e .crions .no n„ Ich will poicrairily .mit 290 tons per
pollummt ragalm:ad ender the CIa.R Air Act and may .Ifect
tie- of _m; alp f latamt to0rlated cnd.r the Cle-m Air Act
.,
4,
�•
u
a
■r be located in wn .fsh m.mt area? (FORM 5)
and may affect or be located In an attainment araa7
'FORM
III. NAME OF FACILITY
■
1 SKIP W. kit P.L_=t
n - Is n
IV. FACILITY CONTACT
A. NAME a TITLE (l. r.,Jr._1, h rill.)
B PHONE T.- .Adv d -a.)
e
Ly,ada Zr enc, E,iv!1Z'L rcntwl Pa.v caoio .-I
l t 1 s 1-$16
1x 1.
N N N - 4• e]
M -LING ADDRESS
A STREET OR P.O BOX
6
3 a L 3Ut. on 1, eam ,1an4 Roa
F3, CITY OR TOWN
C STATE D. ZIP CODE
4 wlliflingt on
,.
C l I
47
Vt. FACILITY LOCATION
... z7REE7, ROUTE NO. OR OTHER SPECIFIC IDENTIFIER
5 4 1 I rower A an xOad
m& Lod
M
A
C. CITY OR TOWN
D.STATEI E. ZIP CODE IF. COUNTY CODE rij drmevq
1129398
5
EPA Fenn 3514-1 (8-90) CONTINUE ON REVERSE

VII. SIC CODES (4-ftlt, in order o1 ori
A. FIRST B. SECOND
71IP'►'e�+»,
49,11
I rk
aieccr,c 'rover eervacee
-0-m
c. i RInD D. FOURTH
71
jplxrh�
7
1
u
Is
7d1. OrEr[ruOR IRfORMATION
n. 11—E B.Is the name listed In ltvnl
Y+Iy slap Rte o..ne(i
51 1JUKe energy rrogres4s, inC m Yl:S ❑ RD
C. STniOwv Or- vrcRnTCR D. PHONE rima rkle&...r,/
e 10a19EIlIRE M= PUBLIC rWh__ fh..-f-1....1 r-.-.W J jP
S=STATEty1D) ski-4 /75
P = PRIVATE O = O RSR ia1 r� u)'r
E STREET OR P O BOX
Y r Power Kant Oad
- m
F. CITY OR TOWN
G. STATE
H. ZIP CODE
IIX. INDIAN LAND
Is the facility lorded on Indian lands?
t! i,unwerr-on
lv%
ztSiDd
p YES Ito NO
t! 1/
X. EXISTING ENVIRONMENTAL PERMITS
A. NPDES dlv= I.S, .R Ilwl« D. PSD Mi.1{..fr lr. r )' . ts1Slr----:
TC T I I
g N Svcruvu�3n3 s
B. UIC the- E. OTHER .) r
T b 94T G b 0 b
9 U
1
_.0 –ir Vermis / _._=111111 we,–_e_al 1e-17 T.
C. RCRA f/ rdr:�_ ti E. OTHER r. .f r
P::
('
n
NCD OUD03UG20 g 1 W0000002G
_h Ue Sl lzr_San eermi■
Idof
I"
XI. MAP
Attach to this apprkation a topographic map of the area extending to at least one mile beyond property boundaries. The map must show the outline of the facility, the
10 Llan m each m Its cksang no proposoa InmWo and dim h.rgo a=orea, e.ch d its ho+..rdoes wa :e ;na-e..t, .. .g., or diapoa.l faoillu.a, .nd m.ch SII whole i;
Injects fields o...derq _o-d Include -11 :grins:, rim-_ .-d ether cart. -.t_r bodl=: In the mar r =: S.e in_tnrcti.na f.r predoe rgain--nts.
XII. NATURE OF BUSIRESS rl—. ­a, u..-Pd.")
The ;;.T. - .Chvzapov < Thine is ..-. vlcer.ie gv: cz_=i: g f-.ility ev .-i...ting of fv .- z:bi.;.
1160 MW : et --poeityl .
XIII. CERTIFICATION t..ee1--tructi--)
with the 140—.6... _-b.-dtfed 1 thl- ,kr tion —doll attachments and that. based on my
i..qu1., .f theoe __..._ i-mediately responsible for obtaining the information contained In the aprrication, f believe that the information is true, accurate, and comNrete I
am aware that theta are significant penalties far suun M.9 r.­ eel.r+n.uo11, ,+rcrl+w..Q N+. po_lbi.' of fi,a .nd lmpd. _. ,u+rf.
A. NAME d OFFICIAL TITLE fir,;. _ .., .f .f)
B. SIGNATURE
c. Cn 1 3113NEe
,..Lien A. Clare
COMMENTS FOR OFFICIAL USE ONLY
1C
EPA FvFm 3510-1 (8-90)

EPA 10. NUMBER (.0„-f.,+.._ /r.... f r3kn. , 1; Fens Approved
NCD 0083062D OMB No. 20400086.
Ple,..a Dri .t yr tvoe Ir, the enahaded , leas
only. -ooroval e1nlres -51.98
FORM U.S ENVIRONMENTAL PROTECTION AGENCY
EPA APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER
ZG EXia r wit; MFiNU�aC r uRlrvaor Cali M&WMAE, RllrwTNG mR0 alEvICGE 1'uRE UPERRI lams
NPDES corrsobdafed Permits Program
I OUTFALL LOCATION
For each outfall, fist the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving wotvp
,.tym'eR
(11.r'f
a. EK. -1700E O lvr:ol. QBE
D RECEIVING WATER(
1 DEG
2 MIN 3. SEC. 1. DEG. 2. RAIN.
3. SEC
001
34.00
34.00 58.00 -78.00 56.00
25.00
Lumber River
fl. FLOWS, SOURCES OF POLLUTION. AND TREATMENT TECHNOLOGIES
A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to the effluent, and treatment units
labeled to correspond to the more uetaflvu uescnptions in Iwm B uonsracr a wa or Bwlenco on.fle lino orawing By afl..mng average naffs BEwraon Inmitas, operations,
naB}te ,: units, and vett I!s If .;;.ter balonee eennat by detonnined (v.Q., provide - plctuftl de:oAption of the -..tine «nd amount of any
=epwe of --t■;: _nd a_ ■■llecti■11 op treatment measures.
B. For vach —th lt, provide.. do-jcriptio of- (.) All operations wntribeting w..:tcw-lec to the efflaent. Indadlag prowum -.stem te.-, aa.lem te.-, Coding aa.ar,
and -tone -atop runoff; (2) Tho --ms= fl— contributed By each operation and (31 The treatment received by the wastewater. Continue on additional she-ts If
necessary.
2. OPERATION(S) CONTRIBUTING FLOW 3. TREATMENT
FALL
NO. (11.-rf
b AVERAGE FLOW b. LIST CODES FROM
a OPER-7 ION irsrr AE.CRIF7OR TABLE zC-
001
Cooling Pona Discharge u MCa e.sc-arse ea sur.ace waver 4 A
n.rrarary warren -erz.c s;aeem w.th as= ane -cave. -ea _
a.00wi nap i w �0
..e...ee ova. e.ee erarnn _ ss lmentat on, flctation _
■urbine site d-ai-- seaamentar-5, u-tsrron
Y..ne sed3--t-tl�i, _
V nos ...
OFFICIAL USE ONLY
EP- Form .o-zC (U -03a) PAGE 1 of 4 CONTINUE ON REVERSE

f OMIIU111=IIIA&6 TA1.1*k1s]:ill
C. E..,..,p: for sw+.— runoff, Inks, or spliz, are any of the diseh..rg— d.seribed ire Ite... s II -A or B In:onnittan: or seasonal:
m YES I_ ,1.r.1h.J.I! -1.., rh1.) ❑ NO Mq- raSe_Il...lh)
a. FREWUENUT
q FLOW
a tvi7a PER
B TOTAL VOLUME
2 OPERATION{.)
WEEK
b. MONTHS
a retm rm, @ (,n _X4
(specify e,- um+s)
OUTF._LL
CONTRIBUTING FLOW
{r,__ b
PER YEAR
1 LONGTERM
2 MAXIMUM
1 LONGTERM
2 MAXIMUM
e. eeRrrivn
.vrol0leer (nn)
(u,r)
n -mgr)
(ipe•jy,,1 '.9C)
else
Zr tll!
ME7
sin ekry rl
001
c—I,n] ronu uIu=irnrg.
0
0
C.
0
0
(the ...11-, ro-d h._ -ct diucha 3.d
uxnae 6ape.nmor 1995:
III PRODUCTION
A. Doo:.n .fflow..t pld■lim limitation pw Ulgated by EPA under Section 304 of the Clean (Nater Act apply to your faciliry?
m YES j..plere hem 111-11r ❑ .O wr.
B Ala the limitation_ in the .ppilcabl. effluent ■sideline e -pressed in terms of production jar other measure of operaflonf?
U YES he. 11k 1 m NO
C. Ir you answered 'y.a' :o Ito,,, III -B, lint the cloantity which represents on ..ctuol me..:eram—t of boa.- level of production, .xpre::ed in th. teen_ a :d units u:ed in the
.ppli—blw effluent guidelinw, and indicate the affected outfalls
,. ,,a=Rptoz tq_Iv. PRODUCTION
2 AFFECTED OUTFALLS
a.OUr..i T PER 13—
a ERI I. op IeIE!4 URE
■ OPERATION, PRODUCT, MATERIAL, ETC
i�fx'cl)1
IV. IMPROVEMENTS
A. Are you now regaireo I!y any locel aothorhy w moat -my implementation vchadal. for the _mtructton, upgrading or operations of :asimr ter
tre.tm.nt egelpwent or practice: or any ■th�r an-immm■ntal pmgmm= which may affect the discharges described In this application? This Indudes, but is not limited to,
pennll =editions, adminlstrattve or enforcement orders enforcement romp! ante schedule letters, 50polati5m, cuan orcurs, ano gram yr loan canarrons
❑ YEa NO (w...; I.... /I. N)
I- IDENTIFICATION OF CONDITION
2. AFFECTED OUTFALLS
3. BRIEF DESCRIPTION OF PROJECT
4. FIRr,e COfFLI-RCI! En.Z
AGREEMENT, ETC
a RD.
s. SOURCE OF DISCHARGE
a. REQUIRED
b PROJECTED
B OP.ivR_ Too may each .dditlonal shoots do:odbing -my additionol -ter i--ktion control programs jar other environmental projocrs which may affect your
di.ch..rge..) y■= nwr h.--nd■—ay or which you plan Indicate whether each program :s now an..orw..y yr plasmon, one !....rein:. you ewarl or planned schedules for
construction
[_]MARK -X' IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAMS IS ATTACHED
EPA F.. 3SIG-2C (8-90) PAGE 2 of 4 CvR BREL' OR lu'ol!

-1
19x.,1U.R0M8ER;..jry,....„ ,.!;"7 .r
CONTINUED FROM PAGE 2 NCD 000830620
EPA Form 59 .Grsc i.-t;o1 PAGE 3 of 4 CONTINUE ON REVERSE
V. INTAKE AND EFFLUERT CH, R_,;C T ERI .IeS
A, B, & C: S_ instructions baler. preeeedi.-.g-CoerplAn erg eat of table- for e.eh oeBoll -Annotate this ootf.fl n --mbar In the :pave provided.
NOTE. Tables V.A. V -B, and V -C are Included on separate shoots numbered V-1 throw h V•4.
D. Um the up.— below to listany of th. pollutants listed in T.bl4 2-3 of the Irmtructions, -hIch you kn— r h.- ro.,rs to belie:., Is disch..rged nr m.y be d:sch.rged
f�nr..; outf.11. F.r. =R Ileal ■ list, briefly d=scribe the reasons you believe it to be present and report any anal-, tical data in your possession.
1 POLLUTANT
2 SOURCE
1 POLLUTANT
2. SOURCE
Asbestos
Trace amount in insulation,
:irc coazing.. .-d h_zneo_e�
a4ronc.um
Trucc nmounca or: pviauc-"E.
i_m
t'_a- _eui_ed ■e..l
.Rau
Zi_=_wi-gym
VI. POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS
is any pollutant listed In Item V -C a substance or a camponon..,r .. 3o5zaarruo —1 h you wnendy ova or m.nefaerore ra _n Im.ormedlate or fin -I prodact or byproduct?
® YES (l.,I, .11.mrh pr,Il.....r..: hefre } ❑ NO r'jT..r_ l,.... I7 H)
Antimony
Arsenic
Beryll.um
=ad nium
Ch« a-1�re
Cw;: -
Lead
Mercary
.;ickcl
Scic-la-
Sil-=_
Thallium
Zinc
EPA Form 59 .Grsc i.-t;o1 PAGE 3 of 4 CONTINUE ON REVERSE

CONTINUED FROM THE FRONT
VII BIOLOGICAL TOXICITY TESTING DATA
De you ha o ..ny knowledge .r reason ro believe th., any b1ologka7 amaC for coz- or cn=n w,uu.r Flan Mn made on any of your discharges or on a receiving water In
relation to ;our d1scha7= -ithin the loot 3 ;.ars?
❑ YES jidemo- tire mor) rl.le-. lh. rh.!_ p -IN, _m h.Gn,l m NO (F, ,,tial,.. Pill)
Vlll CONTRACT ANALYSIS INFORMATIDN
Were any of tho anuiyaaa reponea I.. Ilam w penwrrn . ly . wnuacr I-Pepora.ury or -9010'.g arm;
® YES list dje name, address, and telephone number NY. uml palhuants artall:eu r). ❑ NO ug1 ro ecoun 11
cucrr .nrc'n un—Or}' urJrrm rmr,R'r
A. NAME
B. ADDRESS
C TELEPHONE
D POLLUTANTS AN_1!7Zee
THE. E=-i_w—ental Laboratory,
2401 W. 5th Street
[phone]
All parameters
-..-.c
:.---nberee-, _e za:5e
In (`iei�ilNGnilvN
1 cert W,de, pe, -Tr a 16w th.r W. d—,.,-. .,,d .11.tt ch -...t. me.- prepared v_d..... y di. tio... -ope...sls- L, .e..rd.noe =th r t... deSiy...d to s M.t
ge..11fied perr.,..al propedr v.th.r -.d .7o1.P1. th. W .,,..tion _..hmftted. Based on my ingnlry of the person or persons who manage the system or those persons
d recty responsible forgathering the Information, the information submitted ls, to the beat in—Y.—M-90 .n., uari.i, a u., .ccRl..v, .I.W .W.urn.... I .." P W.'. PIPr um,.
are srvnibcant pena,d.. — oa...... ..... ct.ding tho po_ bifrty..l fi..v ..nd hr,pd..en..,...t ft k.,.wf.,g vlot,.ti..,,,,
A. NAME & OFFICIAL TITLE (.ypc. p.....)
B. PHONE NO. I..... _0e&
A11e- A. Clew, P1.=t M_nager
X910) 341-4750
c jGR..-ERE
D DATE SIGNED
EPA F.rm 3e1_zr' to-aer PAGE 4 of 4

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DuKe Energy Progress, ine NPDEs Permit Number NUO005363
weatners oon rlan[ AU Renewal Application
Attachment 1
Form 9 Item XI Maps
0 0.4 0.8 i.2 1.6 x ruts
1-1

Duke Energy Progress, Inc NPDES Permit Number NCO005363
weadlerspoon Hant 2014 Renewal Application
AttacRment 2
Form zG Iturn II -A Flows: SUMICezo ut PUllution. and Treatment Technologies
CumB§r River IntaKe
I1
i-xrn lUstlon
I E.-61Re bit.
Drains
I mivwaier I
separator
Feel Di
RerneMaiton
site
Grounuwater
vvec
B
Fite
Plant Are- stuRll
Wale. Re�ett
Asn
l'017i]
G
F
CMtng Font
R
C
Rniim Uoal-
Sde Drains
wiry wastes
Collection
-einp
viuvvaier
J
I
INaparat on 8
v;eepage
Guuah Girl
2-1
C
S.Rd S
Gravel
septic
Sygtom
C

VuKe Energy Progress. Inc
NPDES Pe, -it Number NCO005363
vveaEllerspoon P;ant 2014 Renewal „Application
Attachment 2 Conxinue'a
Svorre
Eutimatcd
Average Flow
Comments
A
0.7 MGD
Make up waLe, from Lumber River, maximum rate is a. iz MGu
B
0 MGD
Fir water system
C
120 GPM
Potable water service- intermittent Flow as required
D
0.0002 MGD
Sanitary wastes
E
0.14 MGD
Discharge to cooling pond from oillwaier sepaidtcr.
F
0 MGD
Ash pond does not normally discharge. See Attachmem 3 for
details.
G
0.19 MGD
Estimated using average daily rainfall
H
0.011 MGD
Estimated asing average daily rainfall
1
0 MGD
Pund dues not normally discharge. See Attachment 3 for details.
J
0.7 MGD
Maximum estimated rate is 1.6 MGD
2-2

Duke Energy Progress, Inc. NPDES Permit Number NC0006A3
vveaiMerspoon Plant 2014 Renewal Applicadon
Attachment 3
Fur„, zC Item II -6 Flows: Sources of Pollution; and Treatment Technologies
i Me vveatMerspoon Plant Mas roar operating internal combustion turbines. Th- tutal uluctric generation
capacity for ine site is -0500 lMvv. Prior to c0 -i -i, three coal-rirea units were also in operation; however
tMose units nave since ween reiiretf ants are in ine process or oeing demolished. Due to the retirement of
toe coal-iireo units, ine plant no longer meets tMe aennition or a steam electric generating facility under 40
CFR zF4.5.-10, ants is tMererore no longer consiOeretl a categorical intaustry.
i ne site currently Mas one permittee outran (00dall 'u0-iy iMe aischarge rrom tMe cz-a-acre on -stream
cooling pont] locatetl on tMe norm sine or tMe Cumner River in Roneson County, IgortM Carolina, vvater is
witMsrawn rrom tMe Cumber River as requires to mage up evaporative anti seepage losses. MaReup
pumping rates rrom iMe river are Mignly variable tiepenuing upon natural weaiMer conUldons anti cooling
pond water level. i Me cooling pons, inougn no longer uses tor coo,ing, will continue to Be mainiainea by
ine site.
Keleases irom iMe cooling pont3 are rare, potentially expectet7 to occur when a major storm is expectee
ane atlaitional rreeboaro is neebeO to prevent overtopping of tMe ponb ailtes. On other occasions,
releases may Be neeoeti ror maintenance purposes. , Mis pond last taiscnarget7 to the Eurnuer River in
aepiemoer or -i gyg. i Mere are also incieental seepages anti leaks through tMe diRes an'u retaining wall
tsMeei pilings to iMe Eumber River rrom tMe cooling pond.
Chemical constituents o, tMe power plant discharges will, in part, be representative of the naturally
occurring chemical quality of the intake water and will also have chemical constituents of such quality and
quantity associated with similar discharges for former fossil generating facilities of this size, type, and in
As geographical location. Either all or part of the elements enumerated in the Periodic Table, either
singularly or in any combination, may from time to time be contained in this discharge.
Inputs -to the cooling pond are described below -
Retired Coal -Fired Site
Prior to the retirement of the coal-fired units, most site wastewater streams were routed to the cooling
pond, These wastewaters included recirculated cooling water, coal pile runoff, storm water runoff, mEtal
cleaning wastes, low volume wastes, and the ash pond uutlEt (containing primarily sluiced fly and bottom
ash). E„gineered toe drains are also routed to the coaling pond. Seeps have been identified on the ash
pond dam. Drains from the coal site are routed to a calluction sump, which is then treated by an cil .,,ater
separato, before discharging to the cv—ding pond. Thi iallaztion sump and oil -water separst.-r ..ill bu
removed during the demolition process for the coal site.
Combustion Tarbfie CT Site
Hll drains from the combustion turbine situ, including drains collecting rainfall, are routed to the CT site oil -
water separator which discharges to the cooling pond. Sludgusla-diments collected in sumps, catchment
basins, etc, are disposed of by appropriate methods.
There is an oil remediation area onsite. Groundwater removed from the remediation area is treated
through a free-phasti uil recovery system vAich contains a dedicated oil/water separator. vvater tram that
system is then sent through the CT site oil/water separator before being discMargetl to tMe cooling pone.
Miscellaneuus Wastes
Biocide Usaye in the Cooliny Purid
Biocidal may be used as needed to control nuisance aquatic vegetation. i nese Merbiciaes are
applied by livansed applicaturs, or persons under the immediate supervision or a licenses applicator,
in accordancri with the manufacturer's instructions. Pesticides may Be usetl as neeeea to perform
3-1

Duke Energy Progress. Inc. NPDES Permit Number NC0005363
vveatnempoon Fiant _ 2014 Renewal Application
biological assessments. These pesticides are applied by licensed applicators, or persons unser the
Immediate supervision of a licensed applicator, in accordance with the manuiacturer's instructions.
Duke Energy holds Certificate of Coverage NCG560006 fog the General rermit to Discharge
Pesticides Under the NPDES Program.
Other Wastes
Other wastes such as samps collecting miscellaneous equipment leakage, equipment drainage for
maintenance, equipment wash down water, and sampling streams may be routed to the cooling pond_
Sanitary waste is treated on-site by two septic systems with combined capacity of 4,000 gpd. The
larger system (3,000 gpd) is listed as an input to the cooling pond since it consists of a sand and
gravel drainage field located adjacent to the pond. Both systems are dependent upon fluctuating
demand due to variations in the number of personnel on site. When needed, residuals are disposed
of off-site by a licensed contract disposal firm.
Previously, the plant also had three storm water oatfalls due to the plant's designation as a
categorical industry source subject to federal effluent guidelines. Storm water requirements were
initially established to cover coal ash hauling activity along an access road; however this activity
ceased in November 2010.
3-2

Duke Energy progress, Inc. NPDES PermIL Number WXU953us
Weathers„oon Plant 2014 Renewal Huullcauon
Attadiimunt 4
Form 2C Item VI Potential Disc'narges Mot Covurca 6y A..alya;a
Chemical
Quantity
(uaFUCl7yr)
Frequency
Purpose
Sodium hydroxide
As needed
As needed
Cooling pond neutralization
5alruric ac10
-iy,000 galHs
nee0e0
Cooling pont] neuvaiization
Sandblast Media
500-700 Ib
& needed
Equipment cleaning
Rllotlamine liquia t1ye
0.0 1-0.0;3
al/even
Hs needed
Performance Testing

Proposed Cooling Pond Assessment Work Plan August 2016
W.H. Weatherspoon Power Plant
APPENDIX E
2015 WATER USE REPORT
SynTerra

Watan Withdrawa l and 11ransA r R1i gis tuation Raga 1 ail 2
Ham submit Clay Logan
P4il visit Ihn tt1Q sedion for spersfia instn cliors regarding ti a comitfetiq of the al water i se report Upon com plc Win, f lease print of I a copy V your re=ds
then subrI it your repo by clicking the st bmit till los os the navigation W r
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0atpvIell Well C Ell 365 0 173 r-- Edit 41 elite
Lakii t akeul sneer C 053 91 4 320 -- Li i( 41 De 1.04
0 Adclground !a ice 10 Add Surface Source
Self Ian 3: Dlscharga Information
3-A . Average daily discialga and maximum clay dis&argq Ly mood in million gcllon s pg r day MID)
Alorth
k at Gays
Average Daily
Maximum Day
f lona
I of Gays
A ver.age Cally
Maximum 11 ay
Discharge l
I Isc.l arge (Ml
l ischarga (All
Disct arged
Disch ar( a (hlGa f
Discharge (AIGI I
Jan
a
1001
C 0011
Jul
0
0.00X1
a.00X
Hal
II
0.000
a 000
A ug
.1
a_0N
a OEXI
liar
I
C 000
0 000
l•tp
it
a=
a M
Apr
II
C 000
C 000
Oct
a
1100(
a 001
Allay
I
C 1X10
0.000
f lov
a
0.00(
a.0CA11
Juu
a
0,000
a 000
Gee
it
0 0(X1
a O0(
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Wlatar Wil hdravl al w cl Traasfan Rdgiitnation
Aage 2 of 2
3-8 Please compk to or a rows for eact discharge melhol If any of yaa r i I scl arge information was imporle, I front a p evaa s year please make sure you clic all In an fill in
the information tail t tank IN I is needed for it a 210 15 11 inq year
I.lentilerorRa i IIumter DlscharglType it verage I ally Days Iieclarged 1lsel art e0apaclt.
tIC0015363 Sur ace V later 1 001 Z; d 12 Qggf !�
A& flew 0rsdtarae
5ea6mi 41: Suit-lasin Trinsferinfarmatlon
domglete lhissection only if you w if dravi or purcl aseviater thatla not nihil to the out -h sin fromwl lot It rias will drawin.
4-A Ple,isecomllletecilrow for eadtransfersfsurface walarfrrv;iore sutrbasntaarvllher1111 any ofyour Inill infomiafipnwas iiiled front aprevious year Flnase
ei eke sure you click et dal fill in the informalior left blank fhM f is needeil for Ihe.1019 repo ing year
Clescirlil ofTronsfer Sol rcelut•lxsi■ ■ocaivingSul •Basln Yansfer41aicity
rlo transfers Listec
0 Add New Trinsfer
4-8. ■nler the average daily Incl ma xio iuni day surdace water I a9srer arl far ead nand in riilior gale its p r day (MG0 )
f Icnth
0 n f Gays
A veragl Bally
Ilaximum Day
Mouth
k of lays
A verage lady
Maximum Day
Translerncl
lransfer(IIOD)
Translar(MOD)
Translerr"
Trarsfer(M4G)
lransfer(MaG)
,Ian
0
1 DIX
11 000
Jul
0
0000
0000
let
0'
100
11000
Aug
U
0000
0000
Mar
0
11001
11000
Seg
0
0000
0.000
Apr
0
11001
1001
Oct
0
11000
0 O
May
13
100)
1.001
Nov
0
11000
0.000
.11111
0
1001
11 001
Dee
0
1 000
0 000
Y l de Morxnlr 1ra11 sfe r table
Do yeti i ave any crmtmel ls'I
Q A old Corrrr.l ent
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Wlatu Withdrawal and Transfan Ragistnalion
V11 �a tea W i mgnawg b T� a sen Reci; ng io
lioue 2011S.Annual Waleu Use Report F as Bea n Submittadl
thank you for subr itbN yoi r 21 19 Annu I Water IIsm Mepgt I.
Aage 1 A I
0veniiew ' Report SAO Login
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