NC0000396_J16020326 Report_20160831

DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J16020326
Project Name: ASHEVILLE - AB GW ASSESSMENT WATER
Customer Name(s): Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Customer Address: 200 CP and L Drive
Arden,NC 28704
Lab Contact: Mary Ann Ogle Phone: [phone]
/ Digitally signed by Mary Ann
(� Ogle
Report Authorized By: Date: 2016.02.2411:47:15 Date: 2/24/2016
(Signature)-05'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Page 1 of 35
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2016004243
2016004244
2016004245
2016004246
4 Total Samples
Collected By
Sample Description
ASHEVILLE
11-Feb-16 10:45 AM
BMT
DW-3
ASHEVILLE
11-Feb-16 9:48 AM
BMT
DW-4
ASHEVILLE
11-Feb-16 1:17 PM
BMT
DW-5
ASHEVILLE
11-Feb-16 12:27 PM
BMT
DW-6
Page 2 of 35

Page 3 of 35
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
OV Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 2/24/2016

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
Site: DW-3
Collection Date: 11-Feb-16 10:45 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.402 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
60
mg/L
1
Sulfate
12
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L N1
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.039
mg/L
0.005
Barium (Ba)
0.048
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.040
mg/L
0.005
Strontium (Sr)
0.077
mg/L
0.005
Zinc (Zn)
0.010
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
8.29
mg/L
0.01
Magnesium (Mg)
5.19
mg/L
0.005
Potassium (K)
1.61
mg/L
0.1
Sodium (Na)
27.9
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.078
mg/L
0.005
Barium (Ba)
0.048
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.369
mg/L
0.01
Manganese (Mn)
0.038
mg/L
0.005
Strontium (Sr)
0.075
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Page 4 of 35
Sample #: 2016004243
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_PACE
1 EPA 353.2
02/18/2016 10:33
LSTARL1
Vendor Method
V_PACE
10 EPA 300.0
02/12/2016 14:28
BGN9034
10 EPA 300.0
02/12/2016 14:28
BGN9034
1 EPA 245.1
02/16/2016 14:40
ACPAYNE
1 EPA 245.1
02/19/2016 15:30
ACPAYNE
1 EPA 200.7
02/15/2016 12:14
MHALL3
1 EPA 200.7
02/15/2016 12:14
MHALL3
1 EPA 200.7
02/15/2016 12:14
MHALL3
1 EPA 200.7
02/15/2016 12:14
MHALL3
1 EPA 200.7
02/15/2016 12:14
MHALL3
1 EPA 200.7
02/15/2016 12:14
MHALL3
1 EPA 200.7
02/15/2016 12:14
MHALL3
1 EPA 200.7
02/16/2016 16:17
MHALL3
1 EPA 200.7
02/16/2016 16:17
MHALL3
1 EPA 200.7
02/16/2016 16:17
MHALL3
1 EPA 200.7
02/16/2016 16:17
MHALL3
1 EPA 200.7
02/15/2016 10:50
MHH7131
1 EPA 200.7
02/15/2016 10:50
MHH7131
1 EPA 200.7
02/15/2016 10:50
MHH7131
1 EPA 200.7
02/15/2016 10:50
MHH7131
1 EPA 200.7
02/15/2016 10:50
MHH7131
1 EPA 200.7
02/15/2016 10:50
MHH7131
1 EPA 200.7
02/15/2016 10:50
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
Site: DW-3
Collection Date: 11-Feb-16 10:45 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
7.52
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
7.21
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
150
mg/L
Total Carbon
TOC
0.366
mg/L
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
Page 5 of 35
Sample #:
2016004243
Matrix:
GW WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
02/16/2016 14:12
JAHERMA
1
1
EPA 200.8
02/16/2016 14:12
JAHERMA
1
1
EPA 200.8
02/16/2016 14:12
JAHERMA
1
1
EPA 200.8
02/16/2016 14:12
JAHERMA
1
1
EPA 200.8
02/16/2016 14:12
JAHERMA
1
1
EPA 200.8
02/16/2016 14:12
JAHERMA
1
1
EPA 200.8
02/16/2016 14:12
JAHERMA
1
1
EPA 200.8
02/16/2016 14:12
JAHERMA
1
1
EPA 200.8
02/16/2016 14:12
JAHERMA
1
1
EPA 200.8
02/16/2016 14:12
JAHERMA
1
1
EPA 200.8
02/16/2016 14:12
JAHERMA
0.2
1
EPA 200.8
02/16/2016 14:12
JAHERMA
0.3
1
EPA 200.8
02/16/2016 14:12
JAHERMA
1
1
EPA 200.8
02/19/2016 15:30
JAHERMA
1
1
EPA 200.8
02/19/2016 15:30
JAHERMA
1
1
EPA 200.8
02/19/2016 15:30
JAHERMA
1
1
EPA 200.8
02/19/2016 15:30
JAHERMA
1
1
EPA 200.8
02/19/2016 15:30
JAHERMA
1
1
EPA 200.8
02/19/2016 15:30
JAHERMA
1
1
EPA 200.8
02/19/2016 15:30
JAHERMA
1
1
EPA 200.8
02/19/2016 15:30
JAHERMA
1
1
EPA 200.8
02/19/2016 15:30
JAHERMA
1
1
EPA 200.8
02/19/2016 15:30
JAHERMA
1
1
EPA 200.8
02/19/2016 15:30
JAHERMA
0.2
1
EPA 200.8
02/19/2016 15:30
JAHERMA
0.3
1
EPA 200.8
02/19/2016 15:30
JAHERMA
Vendor Method V_PACE
Vendor Method V_PACE
25 1 SM2540C 02/15/201611:39 JASTOWE
0.1 1 SM5310C/EPA9060A 02/17/201613:10 GHUTCHI
5 1 SM2540D 02/15/2016 09:20 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
Site: DW-4
Collection Date: 11-Feb-16 9:48 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.296 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
76
mg/L
1
Sulfate
84
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
1.25
mg/L
0.005
Barium (Ba)
0.046
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
1.83
mg/L
0.005
Strontium (Sr)
0.198
mg/L
0.005
Zinc (Zn)
0.083
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
21.4
mg/L
0.01
Magnesium (Mg)
9.67
mg/L
0.005
Potassium (K)
4.52
mg/L
0.1
Sodium (Na)
39.0
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
1.42
mg/L
0.005
Barium (Ba)
0.046
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
2.45
mg/L
0.01
Manganese (Mn)
1.88
mg/L
0.005
Strontium (Sr)
0.203
mg/L
0.005
Zinc (Zn)
0.093
mg/L
0.005
Page 6 of 35
Sample #: 2016004244
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_PACE
1 EPA 353.2
02/18/2016 10:34
LSTARL1
Vendor Method
V_PACE
10 EPA 300.0
02/12/2016 14:45
BGN9034
10 EPA 300.0
02/12/2016 14:45
BGN9034
1 EPA 245.1
02/16/2016 14:42
ACPAYNE
1 EPA 245.1
02/16/2016 15:28
ACPAYNE
1 EPA 200.7
02/15/2016 12:18
MHALL3
1 EPA 200.7
02/15/2016 12:18
MHALL3
1 EPA 200.7
02/15/2016 12:18
MHALL3
1 EPA 200.7
02/15/2016 12:18
MHALL3
1 EPA 200.7
02/15/2016 12:18
MHALL3
1 EPA 200.7
02/15/2016 12:18
MHALL3
1 EPA 200.7
02/15/2016 12:18
MHALL3
1 EPA 200.7
02/16/2016 16:21
MHALL3
1 EPA 200.7
02/16/2016 16:21
MHALL3
1 EPA 200.7
02/16/2016 16:21
MHALL3
1 EPA 200.7
02/16/2016 16:21
MHALL3
1 EPA 200.7
02/15/2016 10:55
MHH7131
1 EPA 200.7
02/15/2016 10:55
MHH7131
1 EPA 200.7
02/15/2016 10:55
MHH7131
1 EPA 200.7
02/15/2016 10:55
MHH7131
1 EPA 200.7
02/15/2016 10:55
MHH7131
1 EPA 200.7
02/15/2016 10:55
MHH7131
1 EPA 200.7
02/15/2016 10:55
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
Site: DW-4
Collection Date: 11-Feb-16 9:48 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
1.45
ug/L
Beryllium (Be)
1.62
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
127
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
42.6
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
1.62
ug/L
Beryllium (Be)
1.04
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
128
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
42.1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
280
mg/L
Total Carbon
TOC
0.385
mg/L
TOTAL SUSPENDED SOLIDS
TSS
7.0
mg/L
Page 7 of 35
Sample #:
2016004244
Matrix:
GW WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
02/16/2016 14:17
JAHERMA
1
1
EPA 200.8
02/16/2016 14:17
JAHERMA
1
1
EPA 200.8
02/16/2016 14:17
JAHERMA
1
1
EPA 200.8
02/16/2016 14:17
JAHERMA
1
1
EPA 200.8
02/16/2016 14:17
JAHERMA
1
1
EPA 200.8
02/16/2016 14:17
JAHERMA
1
1
EPA 200.8
02/16/2016 14:17
JAHERMA
1
1
EPA 200.8
02/16/2016 14:17
JAHERMA
1
1
EPA 200.8
02/16/2016 14:17
JAHERMA
1
1
EPA 200.8
02/16/2016 14:17
JAHERMA
1
1
EPA 200.8
02/16/2016 14:17
JAHERMA
0.2
1
EPA 200.8
02/16/2016 14:17
JAHERMA
0.3
1
EPA 200.8
02/16/2016 14:17
JAHERMA
1
1
EPA 200.8
02/19/2016 16:00
JAHERMA
1
1
EPA 200.8
02/19/2016 16:00
JAHERMA
1
1
EPA 200.8
02/19/2016 16:00
JAHERMA
1
1
EPA 200.8
02/19/2016 16:00
JAHERMA
1
1
EPA 200.8
02/19/2016 16:00
JAHERMA
1
1
EPA 200.8
02/19/2016 16:00
JAHERMA
1
1
EPA 200.8
02/19/2016 16:00
JAHERMA
1
1
EPA 200.8
02/19/2016 16:00
JAHERMA
1
1
EPA 200.8
02/19/2016 16:00
JAHERMA
1
1
EPA 200.8
02/19/2016 16:00
JAHERMA
1
1
EPA 200.8
02/19/2016 16:00
JAHERMA
0.2
1
EPA 200.8
02/19/2016 16:00
JAHERMA
0.3
1
EPA 200.8
02/19/2016 16:00
JAHERMA
Vendor Method V_PACE
Vendor Method V_PACE
25 1 SM2540C 02/15/201611:39 JASTOWE
0.1 1 SM5310C/EPA9060A 02/17/201613:10 GHUTCHI
5 1 SM2540D 02/15/2016 09:20 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
Site: DW-5
Collection Date: 11-Feb-16 1:17 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
56
mg/L
1
Sulfate
19
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.025
mg/L
0.005
Barium (Ba)
0.009
mg/L
0.005
Boron (B)
0.079
mg/L
0.05
Iron (Fe)
14.4
mg/L
0.01
Manganese (Mn)
0.501
mg/L
0.005
Strontium (Sr)
0.120
mg/L
0.005
Zinc (Zn)
0.007
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
34.2
mg/L
0.01
Magnesium (Mg)
4.29
mg/L
0.005
Potassium (K)
3.00
mg/L
0.1
Sodium (Na)
15.9
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.031
mg/L
0.005
Barium (Ba)
0.008
mg/L
0.005
Boron (B)
0.079
mg/L
0.05
Iron (Fe)
17.3
mg/L
0.01
Manganese (Mn)
0.491
mg/L
0.005
Strontium (Sr)
0.116
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Page 8 of 35
Sample #: 2016004245
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_PACE
1 EPA 353.2
02/18/2016 10:35
LSTARL1
Vendor Method
V_PACE
10 EPA 300.0
02/12/2016 15:02
BGN9034
10 EPA 300.0
02/12/2016 15:02
BGN9034
1 EPA 245.1
02/16/2016 14:45
ACPAYNE
1 EPA 245.1
02/16/2016 15:31
ACPAYNE
1 EPA 200.7
02/15/2016 12:22
MHALL3
1 EPA 200.7
02/15/2016 12:22
MHALL3
1 EPA 200.7
02/15/2016 12:22
MHALL3
1 EPA 200.7
02/15/2016 12:22
MHALL3
1 EPA 200.7
02/15/2016 12:22
MHALL3
1 EPA 200.7
02/15/2016 12:22
MHALL3
1 EPA 200.7
02/15/2016 12:22
MHALL3
1 EPA 200.7
02/16/2016 16:25
MHALL3
1 EPA 200.7
02/16/2016 16:25
MHALL3
1 EPA 200.7
02/16/2016 16:25
MHALL3
1 EPA 200.7
02/16/2016 16:25
MHALL3
1 EPA 200.7
02/15/2016 10:59
MHH7131
1 EPA 200.7
02/15/2016 10:59
MHH7131
1 EPA 200.7
02/15/2016 10:59
MHH7131
1 EPA 200.7
02/15/2016 10:59
MHH7131
1 EPA 200.7
02/15/2016 10:59
MHH7131
1 EPA 200.7
02/15/2016 10:59
MHH7131
1 EPA 200.7
02/15/2016 10:59
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
Site: DW-5
Collection Date: 11-Feb-16 1:17 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
220
mg/L
Total Carbon
TOC
0.255
mg/L
TOTAL SUSPENDED SOLIDS
TSS
25
mg/L
Page 9 of 35
Sample #:
2016004245
Matrix:
GW WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
02/16/2016 15:25
JAHERMA
1
1
EPA 200.8
02/16/2016 15:25
JAHERMA
1
1
EPA 200.8
02/16/2016 15:25
JAHERMA
1
1
EPA 200.8
02/16/2016 15:25
JAHERMA
1
1
EPA 200.8
02/16/2016 15:25
JAHERMA
1
1
EPA 200.8
02/16/2016 15:25
JAHERMA
1
1
EPA 200.8
02/16/2016 15:25
JAHERMA
1
1
EPA 200.8
02/16/2016 15:25
JAHERMA
1
1
EPA 200.8
02/16/2016 15:25
JAHERMA
1
1
EPA 200.8
02/16/2016 15:25
JAHERMA
1
1
EPA 200.8
02/16/2016 15:25
JAHERMA
0.2
1
EPA 200.8
02/16/2016 15:25
JAHERMA
0.3
1
EPA 200.8
02/16/2016 15:25
JAHERMA
1
1
EPA 200.8
02/19/2016 16:19
JAHERMA
1
1
EPA 200.8
02/19/2016 16:19
JAHERMA
1
1
EPA 200.8
02/19/2016 16:19
JAHERMA
1
1
EPA 200.8
02/19/2016 16:19
JAHERMA
1
1
EPA 200.8
02/19/2016 16:19
JAHERMA
1
1
EPA 200.8
02/19/2016 16:19
JAHERMA
1
1
EPA 200.8
02/19/2016 16:19
JAHERMA
1
1
EPA 200.8
02/19/2016 16:19
JAHERMA
1
1
EPA 200.8
02/19/2016 16:19
JAHERMA
1
1
EPA 200.8
02/19/2016 16:19
JAHERMA
1
1
EPA 200.8
02/19/2016 16:19
JAHERMA
0.2
1
EPA 200.8
02/19/2016 16:19
JAHERMA
0.3
1
EPA 200.8
02/19/2016 16:19
JAHERMA
Vendor Method V_PACE
Vendor Method V_PACE
25 1 SM2540C 02/15/201611:39 JASTOWE
0.1 1 SM5310C/EPA9060A 02/17/201613:10 GHUTCHI
5 1 SM2540D 02/15/2016 09:20 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
Site: DW-6
Collection Date: 11-Feb-16 12:27 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
1.6
mg/L
0.1
Sulfate
0.46
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.028
mg/L
0.005
Barium (Ba)
0.016
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
19.7
mg/L
0.01
Manganese (Mn)
0.586
mg/L
0.005
Strontium (Sr)
0.094
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
9.20
mg/L
0.01
Magnesium (Mg)
2.24
mg/L
0.005
Potassium (K)
2.37
mg/L
0.1
Sodium (Na)
7.71
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.044
mg/L
0.005
Barium (Ba)
0.018
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
28.0
mg/L
0.01
Manganese (Mn)
0.607
mg/L
0.005
Strontium (Sr)
0.094
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Page 10 of 35
Sample #: 2016004246
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_PACE
1 EPA 353.2
02/18/2016 10:38
LSTARL1
Vendor Method
V_PACE
1 EPA 300.0
02/15/2016 08:55
BGN9034
1 EPA 300.0
02/15/2016 08:55
BGN9034
1 EPA 245.1
02/16/2016 14:47
ACPAYNE
1 EPA 245.1
02/16/2016 15:33
ACPAYNE
1 EPA 200.7
02/15/2016 12:34
MHALL3
1 EPA 200.7
02/15/2016 12:34
MHALL3
1 EPA 200.7
02/15/2016 12:34
MHALL3
1 EPA 200.7
02/15/2016 12:34
MHALL3
1 EPA 200.7
02/15/2016 12:34
MHALL3
1 EPA 200.7
02/15/2016 12:34
MHALL3
1 EPA 200.7
02/15/2016 12:34
MHALL3
1 EPA 200.7
02/16/2016 16:28
MHALL3
1 EPA 200.7
02/16/2016 16:28
MHALL3
1 EPA 200.7
02/16/2016 16:28
MHALL3
1 EPA 200.7
02/16/2016 16:28
MHALL3
1 EPA 200.7
02/15/2016 11:03
MHH7131
1 EPA 200.7
02/15/2016 11:03
MHH7131
1 EPA 200.7
02/15/2016 11:03
MHH7131
1 EPA 200.7
02/15/2016 11:03
MHH7131
1 EPA 200.7
02/15/2016 11:03
MHH7131
1 EPA 200.7
02/15/2016 11:03
MHH7131
1 EPA 200.7
02/15/2016 11:03
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
Site: DW-6
Collection Date: 11-Feb-16 12:27 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
1.11
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
68
mg/L
Total Carbon
TOC
0.296
mg/L
TOTAL SUSPENDED SOLIDS
TSS
51
mg/L
Page 11 of 35
Sample #:
2016004246
Matrix:
GW WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
02/16/2016 15:30
JAHERMA
1
1
EPA 200.8
02/16/2016 15:30
JAHERMA
1
1
EPA 200.8
02/16/2016 15:30
JAHERMA
1
1
EPA 200.8
02/16/2016 15:30
JAHERMA
1
1
EPA 200.8
02/16/2016 15:30
JAHERMA
1
1
EPA 200.8
02/16/2016 15:30
JAHERMA
1
1
EPA 200.8
02/16/2016 15:30
JAHERMA
1
1
EPA 200.8
02/16/2016 15:30
JAHERMA
1
1
EPA 200.8
02/16/2016 15:30
JAHERMA
1
1
EPA 200.8
02/16/2016 15:30
JAHERMA
1
1
EPA 200.8
02/16/2016 15:30
JAHERMA
0.2
1
EPA 200.8
02/16/2016 15:30
JAHERMA
0.3
1
EPA 200.8
02/16/2016 15:30
JAHERMA
1
1
EPA 200.8
02/19/2016 16:24
JAHERMA
1
1
EPA 200.8
02/19/2016 16:24
JAHERMA
1
1
EPA 200.8
02/19/2016 16:24
JAHERMA
1
1
EPA 200.8
02/19/2016 16:24
JAHERMA
1
1
EPA 200.8
02/19/2016 16:24
JAHERMA
1
1
EPA 200.8
02/19/2016 16:24
JAHERMA
1
1
EPA 200.8
02/19/2016 16:24
JAHERMA
1
1
EPA 200.8
02/19/2016 16:24
JAHERMA
1
1
EPA 200.8
02/19/2016 16:24
JAHERMA
1
1
EPA 200.8
02/19/2016 16:24
JAHERMA
1
1
EPA 200.8
02/19/2016 16:24
JAHERMA
0.2
1
EPA 200.8
02/19/2016 16:24
JAHERMA
0.3
1
EPA 200.8
02/19/2016 16:24
JAHERMA
Vendor Method V_PACE
Vendor Method V_PACE
25 1 SM2540C 02/15/201611:39 JASTOWE
0.1 1 SM5310C/EPA9060A 02/17/201613:10 GHUTCHI
5 1 SM2540D 02/15/2016 09:20 CJELLIO

Certificate of Laboratory Analysis Page 12 of 35
This report shall not be reproduced, except in full.
Order # J16020326
Qualifiers:
N1 See additional information listed below.
-- Additional Information --
N1 - Insufficient sample volume to perform the dissolved metals analysis from the original container. As a result, the
TSS sample was filtered in-house on 2/17/16 using a 0.45 micron filter and analyzed as HG 245.1 Dissolved.

aceAnaiXical
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Pace Analytical Services, Inc.
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y Huntersville, INC 28078
[phone]
February 17, 2016
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 16020326
Pace Project No.: 92286451
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on February 12, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Anne Pifer
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 22

lacmnalyfica(
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[phone]
Project: J16020326
Pace Project No.: 92286451
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A21-A Certification M 2926.01
Alaska Certification M UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification M 88-0680
California Certification M 01155CA
Colorado Certification #Pace
Connecticut Certification M PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification M 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification M 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification M 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
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Alabama Certification M 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
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Hawaii Certification: FL NELAC Reciprocity
Illinois Certification M 200068
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Kansas Certification M E-10383
Kentucky Certification #: 90050
Louisiana Certification M FL NELAC Reciprocity
Louisiana Environmental Certificate M 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification M Cert 0074
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
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North Dakota Certification #: R-216
Oklahoma Certification #: D9947
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Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification M TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
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REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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SAMPLE SUMMARY
Project: J16020326
Pace Project No.: 92286451
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92286451001
2016004243
Water
02/11/1610:45
02/12/1612:38
92286451002
2016004244
Water
02/11/16 09:48
02/12/16 12:38
92286451003
2016004245
Water
02/11/1613:17
02/12/1612:38
92286451004
2016004246
Water
02/11/1612:27
02/12/1612:38
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 22

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Pace Analytical Services, Inc.
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16020326
92286451
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92286451001
2016004243
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92286451002
2016004244
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92286451003
2016004245
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92286451004
2016004246
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 4 of 22

aceAnaiXical
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Pace Analytical Services, Inc.
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Project: J16020326
Pace Project No.: 92286451
Lab Sample ID
Method
92286451001
SM 2320B
SM 2320B
EPA 218.7
92286451003
SM 2320B
SM 2320B
92286451004
RSK 175
SM 2320B
SM 2320B
SUMMARY OF DETECTION
Client Sample ID
Parameters
2016004243
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
Chromium, Hexavalent
2016004245
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
2016004246
Methane
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
Result
Units
5.4
mg/L
5.4
mg/L
0.38
ug/L
51.9
mg/L
51.9
mg/L
3150
ug/L
48.3
mg/L
48.3
mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Report Limit Analyzed Qualifiers
5.0 02/15/1613:56
5.0 02/15/1613:56
0.060 02/15/1614:22
5.0 02/15/1614:14
5.0 02/15/1614:14
10.0 02/15/16 21:13
5.0 02/15/1614:26
5.0 02/15/1614:26
Page 5 of 22

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PROJECT NARRATIVE
Project: J16020326
Pace Project No.: 92286451
Method: RSK 175
Description: RSK 175 AIR Headspace
Client: Duke Energy
Date: February 17, 2016
General Information:
4 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 6 of 22

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Pace Analytical Services, Inc.
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PROJECT NARRATIVE
Project: J16020326
Pace Project No.: 92286451
Method: SM 2320B
Description: 2320E Alkalinity
Client: Duke Energy
Date: February 17, 2016
General Information:
4 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 22

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PROJECT NARRATIVE
Project: J16020326
Pace Project No.: 92286451
Method: SM 4500-S213
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: February 17, 2016
General Information:
4 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16020326
Pace Project No.: 92286451
Method: EPA 218.7
Description: Hexavalent Chromium by IC
Client: Duke Energy
Date: February 17, 2016
General Information:
4 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/55037
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92286451002,92286457003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 1480049)
• Chromium. Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 9 of 22

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ANALYTICAL RESULTS
Project: J16020326
Pace Project No.: 92286451
Sample: 2016004243
Lab ID: 92286451001 Collected:
02/11/16 10:45
Received: 02/12/16 12:38 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
02/15/16 20:48
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
5.4 mg/L
5.0
1
02/15/16 13:56
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
02/15/16 13:56
Alkalinity, Total as CaCO3
5.4 mg/L
5.0
1
02/15/16 13:56
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
02/16/1615:15
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.38 ug/L
0.060
2
02/15/16 14:22
18540-29-9
Date: 02/17/2016 12:52 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 10 of 22

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ANALYTICAL RESULTS
Project: J16020326
Pace Project No.: 92286451
Sample: 2016004244
Lab ID: 92286451002 Collected:
02/11/16 09:48
Received: 02/12/16 12:38 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
02/15/16 20:56
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
02/15/16 14:06
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
02/15/16 14:06
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
02/15/16 14:06
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
02/16/1615:15
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
02/16/16 12:00
18540-29-9 M1
Date: 02/17/2016 12:52 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 11 of 22

aceAnaiXical
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ANALYTICAL RESULTS
Project: J16020326
Pace Project No.: 92286451
Sample: 2016004245
Lab ID: 92286451003 Collected:
02/11/16 13:17
Received: 02/12/16 12:38 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
02/15/16 21:04
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
51.9 mg/L
5.0
1
02/15/16 14:14
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
02/15/16 14:14
Alkalinity, Total as CaCO3
51.9 mg/L
5.0
1
02/15/16 14:14
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
02/16/1615:15
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
02/16/16 12:39
18540-29-9
Date: 02/17/2016 12:52 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 12 of 22

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ANALYTICAL RESULTS
Project: J16020326
Pace Project No.: 92286451
Sample: 2016004246
Lab ID: 92286451004 Collected:
02/11/16 12:27
Received: 02/12/16 12:38 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
3150 ug/L
10.0
1
02/15/16 21:13
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
48.3 mg/L
5.0
1
02/15/16 14:26
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
02/15/16 14:26
Alkalinity, Total as CaCO3
48.3 mg/L
5.0
1
02/15/16 14:26
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
02/16/1615:15
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
1.5
50
02/16/16 12:52
18540-29-9
Date: 02/17/2016 12:52 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 13 of 22

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QUALITY CONTROL DATA
Project: J16020326
Pace Project No.: 92286451
QC Batch: AIR/25221
Analysis Method: RSK 175
QC Batch Method: RSK 175
Analysis Description: RSK 175 AIR HEADSPACE
Associated Lab Samples: 92286451001, 92286451002,
92286451003, 92286451004
METHOD BLANK: 2191768
Matrix: Water
Associated Lab Samples: 92286451001, 92286451002,
92286451003, 92286451004
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Methane
ug/L
ND 10.0
02/15/1618:12
LABORATORY CONTROL SAMPLE & LCSD:
2191769
2191770
Spike LCS LCSD
LCS LCSD
% Rec
Max
Parameter
Units
Conc. Result Result
% Rec % Rec
Limits RPD
RPD Qualifiers
Methane
ug/L
60.7 55.3 52.8
91 87
85-115
5 20
SAMPLE DUPLICATE: 2192335
92286145002 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Methane
ug/L
6.9J 6.6J
20
SAMPLE DUPLICATE: 2192336
92286457006 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Methane
ug/L
ND 1.11
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/17/2016 12:52 PM without the written consent of Pace Analytical Services, Inc.. Page 14 of 22

aceAnaiXical
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[phone]
QUALITY CONTROL DATA
Project: J16020326
Pace Project No.: 92286451
QC Batch: WET/43044 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92286451001, 92286451002, 92286451003, 92286451004
METHOD BLANK: 1666285
Matrix: Water
Associated Lab Samples: 92286451001,
92286451002, 92286451003, 92286451004
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Alkalinity, Carbonate (CaCO3)
mg/L
ND 5.0
02/15/16 12:58
Alkalinity, Total as CaCO3
mg/L
ND 5.0
02/15/16 12:58
Alkalinity, Bicarbonate (CaCO3)
mg/L
ND 5.0
02/15/16 12:58
LABORATORY CONTROL SAMPLE: 1666286
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 49.0 98 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1666287 1666288
MS MSD
92286448001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L ND 50 50 49.2 48.6 98 97 80-120 1 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1666289 1666290
MS MSD
92286457005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Alkalinity, Total as CaCO3 mg/L ND 50 50 52.3 52.1 100 100 80-120 0 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/17/2016 12:52 PM without the written consent of Pace Analytical Services, Inc..
Page 15 of 22

aceAnaiXical
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Pace Analytical Services, Inc.
098g igvt� e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16020326
Pace Project No.: 92286451
QC Batch: WET/43068 Analysis Method: SM 4500-S2D
QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92286451001, 92286451002, 92286451003, 92286451004
METHOD BLANK: 1666880 Matrix: Water
Associated Lab Samples: 92286451001, 92286451002, 92286451003, 92286451004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 02/16/1615:15
LABORATORY CONTROL SAMPLE: 1666881
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.50 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1666882 1666883
MS MSD
92286122003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.51 0.51 102 102 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1666884 1666885
MS MSD
92286122004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.46 0.46 92 92 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/17/2016 12:52 PM without the written consent of Pace Analytical Services, Inc..
Page 16 of 22

aceAnaiXical
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[phone]
QUALITY CONTROL DATA
Project: J16020326
Pace Project No.: 92286451
QC Batch: WETA/55036
Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7
Analysis Description: Chromium,
Hexavalent IC
Associated Lab Samples: 92286451001
METHOD BLANK: 1480042
Matrix: Water
Associated Lab Samples: 92286451001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Chromium, Hexavalent
ug/L
ND 0.030
02/15/16 11:07
LABORATORY CONTROL SAMPLE: 1480043
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Chromium, Hexavalent
ug/L
.075 0.072
96 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1480044 1480045
MS MSD
92285911002
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units
Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L
1.6
.75 .75 2.3
2.4 100 107 85-115 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/17/2016 12:52 PM without the written consent of Pace Analytical Services, Inc..
Page 17 of 22

aceAnaiXical
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y Huntersville, NC 28078
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QUALITY CONTROL DATA
Project: J16020326
Pace Project No.: 92286451
QC Batch: WETA/55037
Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7
Analysis Description: Chromium,
Hexavalent IC
Associated Lab Samples: 92286451002, 92286451003,
92286451004
METHOD BLANK: 1480046
Matrix: Water
Associated Lab Samples: 92286451002, 92286451003,
92286451004
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chromium, Hexavalent ug/L
ND 0.030
02/16/16 11:34
LABORATORY CONTROL SAMPLE: 1480047
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chromium, Hexavalent ug/L
.075 0.074
98 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1480048 1480049
MS MSD
92286451002
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND
.025 .025 0.042
0.037 98 76 85-115 14 20 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1480050 1480051
MS MSD
92286457003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L 0.034 .075 .075 0.11 0.10 101 93 85-115 6 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/17/2016 12:52 PM without the written consent of Pace Analytical Services, Inc..
Page 18 of 22

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QUALIFIERS
Project: J16020326
Pace Project No.: 92286451
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-M Pace Analytical Services - Minneapolis
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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Date: 02/17/2016 12:52 PM without the written consent of Pace Analytical Services, Inc.. Page 19 of 22

acmnalytical
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16020326
Pace Project No.: 92286451
Lab ID Sample ID QC Batch Method QC Batch
92286451001
2016004243
RSK 175
AIR/25221
92286451002
2016004244
RSK 175
AIR/25221
92286451003
2016004245
RSK 175
AIR/25221
92286451004
2016004246
RSK 175
AIR/25221
92286451001
2016004243
SM 2320B
WET/43044
92286451002
2016004244
SM 2320B
WET/43044
92286451003
2016004245
SM 2320B
WET/43044
92286451004
2016004246
SM 2320B
WET/43044
92286451001
2016004243
SM 4500-S2D
WET/43068
92286451002
2016004244
SM 4500-S2D
WET/43068
92286451003
2016004245
SM 4500-S2D
WET/43068
92286451004
2016004246
SM 4500-S2D
WET/43068
92286451001
2016004243
EPA 218.7
WETA/55036
92286451002
2016004244
EPA 218.7
WETA/55037
92286451003
2016004245
EPA 218.7
WETA/55037
92286451004
2016004246
EPA 218.7
WETA/55037
Date: 02/17/2016 12:52 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 20 of 22

Document Name:
Document Revised: 260CT2015
acEARalytfcal�
Sample Condition Upon Receipt(SCUR)
Pagel of 2
Document No.:
Issuing Authori# ; age JJ o
F-CHR-CS-403•rev.17
Pace Huntersville Quality Office
IBM PA
Client Name: Project#f: W0# , 91'04'r 64'51
Courier: ❑Fed Ex ❑UPS ❑USPS ❑Client
❑Commercial ❑Pace ❑Other: 92286451
,
Custody Seal on Cooler/Box Present?
Packing Material: ❑Bub le Wrap
Thermometer 505
❑Yes No Seals Intact? Des ❑No
Bubble Ba s None Other:
g ❑ ❑
Used: TYp ice: Wet ❑Blue ❑None 0 a5 mples on ice, cooling process has begun
Cooler Temp Corrected ('C): Biological Tissue Frozen? Dyes ❑No; N/A 7
Temp should be above freezing to 6°C Correction Facto °C Date and initials of Person Examining.Contents:
USDA Regulated Soil (❑ N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, orSC (check maps)? Did samples originate from a,foreign source (internationally,
❑Yes ❑No including Hawaii and Puerto Ric oJ? ❑Yes o
If Yes to either question, fill out a Regulated Soil Checkilst and include with SOUR/COC paperwork,
COMMENTS:
Chain of Custody Present?
es
[]NO
❑N/A
1.
Chain of Custody Filled Out?
EK
N.
❑N/A
2.
Chain of Custody Relinquished?
es
No
❑N/A
3.
Sampler Name and/or Signature on COC?
es
❑No
❑N/A
4.
Samples Arrived within Bold Time?
Yes
No
[I N/A
5.
Short Hold Time Analysis (<72 hr)?
es
No
❑N/A
6.
Rush Turn Around Time Requested?
es
❑No
❑N/A
7.
Sufficient Volume?
Yes
❑No
❑N/A
8.
Correct Containers Used?
Yes/
[]IN
N/A
9. 7 .
ON/A
-Pace Containers Used?
❑4es
[N
Containers Intact?
Yes
[]No
❑N/A
0
Filtered Volume Received for Dissolved Tests?
[]Yes
ONo
O N/A
11. Note if sediment Is visible in the dissolved container
Sample Labels Match COC?
❑
❑No
❑N/A
12.
-Includes Date/Time/ID/Analysis Matrix:_ �!
All containers needing acid/base preservation have been
checked?
Yes
❑No
❑N/A
13.
All containers needing preservation are found to be in
compliance with EPA recommendation?
(HNO3, H2SO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide)
Yes
No
❑N/A
Exceptions: VOA, Coliform, TOC, Oil and Grease,
DRO/8015 (water) DOC,LLHg
El es
❑No
❑N/A
Samples checked for dechlorization
❑Yes
[:]No
❑ /A
14.
Headspace in VOA Vials (>5-6mm)?
❑Yes
[]No
, N/
15.
Trip Blank Present?
❑Yes
❑No
2fhlV
16,
Trip Blank Custody Seals Present?
❑Yes
❑No
N/A
Pace Trip Blank Lot # (if purchased);
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Resolution:.
Field Data Required? ❑Yes ❑No
Date/Time:
Project Manager SCURF Review: 19 Date: ��-
Note: Wheneverthere is a discrepancy affecting North Carolina compliance samples, a copy of thisform will be sentto the North Carolina DEHNR Certification Office (i,e. Out of
hold, incorrect preservative, out of temp, incorrect containers),
Page 21 of 22

Page 34 of 35
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Page 22 of 22

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