NC0000396_J16020574 Report_20160831

DUE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J16020574
Project Name: ASHEVILLE - AB GW ASSESSMENT WATER
Customer Name(s): Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Customer Address: 200 CP and L Drive
Arden,NC 28704
Lab Contact: Mary Ann Ogle Phone: [phone]
c� Digitally signed by Mary
/ "' �S('__AnnOgle
Report Authorized By: / / Date: 2016.03.07 15:42:15 Date: 3i7i2016
(Signature) ///-05,00,
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Analytical Lab
Page 1 of 29
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By
Sample Description
2016005300
ASHEVILLE 22-Feb-16 2:36 PM Bart M Fitzpatrick MW-06BR
(PACE)
2016005301
ASHEVILLE 22-Feb-16 11:45 AM Bart M Fitzpatrick Filter Blank
(PACE)
2016005302
ASHEVILLE 22-Feb-16 11:45 AM Bart M Fitzpatrick Equipment Blank
(PACE)
3 Total Samples
Analytical Lab
Page 2 of 29

Analytical Lab
Page 3 of 29
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
CI Job Summary Report
❑� Sample Identification
Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
El Analytical Laboratory QC Report
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 3/7/2016

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020574
Site: MW-06BR
Collection Date: 22-Feb-16 2:36 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
3.9
mg/L
0.1
Sulfate
48
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.024
mg/L
0.005
Barium (Ba)
0.009
mg/L
0.005
Boron (B)
0.106
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
0.034
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
16.2
mg/L
0.01
Magnesium (Mg)
0.544
mg/L
0.005
Potassium (K)
1.82
mg/L
0.1
Sodium (Na)
22.2
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.078
mg/L
0.005
Barium (Ba)
0.011
mg/L
0.005
Boron (B)
0.112
mg/L
0.05
Iron (Fe)
0.025
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
0.035
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016005300
Matrix: GW WW
Analytical Lab
Page 4 of 29
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 02/26/2016 08:42 LSTARLI
Vendor Method V_PACE
1 EPA 300.0
02/25/2016 20:15
BGN9034
10 EPA 300.0
02/25/2016 20:15
BGN9034
1 EPA 245.1
02/29/2016 12:07
LSTARL1
1 EPA 245.1
02/29/2016 12:39
LSTARLI
1 EPA 200.7
02/25/2016 12:38
MHH7131
1 EPA 200.7
02/25/2016 12:38
MHH7131
1 EPA 200.7
02/25/2016 12:38
MHH7131
1 EPA 200.7
02/25/2016 12:38
MHH7131
1 EPA 200.7
02/25/2016 12:38
MHH7131
1 EPA 200.7
02/25/2016 12:38
MHH7131
1 EPA 200.7
02/25/2016 12:38
MHH7131
1 EPA 200.7
02/26/2016 10:31
JJMACKE
1 EPA 200.7
02/26/2016 10:31
JJMACKE
1 EPA 200.7
02/26/2016 10:31
JJMACKE
1 EPA 200.7
02/26/2016 10:31
JJMACKE
1 EPA 200.7
02/26/2016 13:39
JJMACKE
1 EPA 200.7
02/26/2016 13:39
JJMACKE
1 EPA 200.7
02/26/2016 13:39
JJMACKE
1 EPA 200.7
02/26/2016 13:39
JJMACKE
1 EPA 200.7
02/26/2016 13:39
JJMACKE
1 EPA 200.7
02/26/2016 13:39
JJMACKE
1 EPA 200.7
02/26/2016 13:39
JJMACKE

Certificate of Laboratory Analysis sis Analytical Lab
• Page 5 of 29
This report shall not be reproduced, except in full.
Order # J16020574
Site: MW-06BR
Collection Date: 22-Feb-16 2:36 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.92
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.97
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
140
mg/L
25
Total Carbon
TOC
0.202
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2016005300
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
03/01/2016 13:51
MHALL3
1
EPA 200.8
03/01/2016 13:51
MHALL3
1
EPA 200.8
03/01/2016 13:51
MHALL3
1
EPA 200.8
03/01/2016 13:51
MHALL3
1
EPA 200.8
03/01/2016 13:51
MHALL3
1
EPA 200.8
03/01/2016 13:51
MHALL3
1
EPA 200.8
03/01/2016 13:51
MHALL3
1
EPA 200.8
03/01/2016 13:51
MHALL3
1
EPA 200.8
03/01/2016 13:51
MHALL3
1
EPA 200.8
03/01/2016 13:51
MHALL3
1
EPA 200.8
03/01/2016 13:51
MHALL3
1
EPA 200.8
03/01/2016 13:51
MHALL3
1
EPA 200.8
03/01/2016 13:51
MHALL3
1
EPA 200.8
03/01/2016 14:54
MHALL3
1
EPA 200.8
03/01/2016 14:54
MHALL3
1
EPA 200.8
03/01/2016 14:54
MHALL3
1
EPA 200.8
03/01/2016 14:54
MHALL3
1
EPA 200.8
03/01/2016 14:54
MHALL3
1
EPA 200.8
03/01/2016 14:54
MHALL3
1
EPA 200.8
03/01/2016 14:54
MHALL3
1
EPA 200.8
03/01/2016 14:54
MHALL3
1
EPA 200.8
03/01/2016 14:54
MHALL3
1
EPA 200.8
03/01/2016 14:54
MHALL3
1
EPA 200.8
03/01/2016 14:54
MHALL3
1
EPA 200.8
03/01/2016 14:54
MHALL3
1
EPA 200.8
03/01/2016 14:54
MHALL3
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 02/25/201613:59 CJELLIO
1 SM5310C/EPA9060A 02/27/201612:29 GHUTCHI
1 SM2540D 02/25/201611:52 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020574
Site: Filter Blank
Collection Date: 22-Feb-16 11:45 AM
Analyte
Result
Units Qualifiers
RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2016005301
Matrix: GW WW
Analytical Lab
Page 6 of 29
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
02/29/2016 12:41
LSTARL1
1
EPA 200.7
02/25/2016 11:27
MHH7131
1
EPA 200.7
02/25/2016 11:27
MHH7131
1
EPA 200.7
02/25/2016 11:27
MHH7131
1
EPA 200.7
02/25/2016 11:27
MHH7131
1
EPA 200.7
02/25/2016 11:27
MHH7131
1
EPA 200.7
02/25/2016 11:27
MHH7131
1
EPA 200.7
02/25/2016 11:27
MHH7131
1
EPA 200.8
03/01/2016 14:15
MHALL3
1
EPA 200.8
03/01/2016 14:15
MHALL3
1
EPA 200.8
03/01/2016 14:15
MHALL3
1
EPA 200.8
03/01/2016 14:15
MHALL3
1
EPA 200.8
03/01/2016 14:15
MHALL3
1
EPA 200.8
03/01/2016 14:15
MHALL3
1
EPA 200.8
03/01/2016 14:15
MHALL3
1
EPA 200.8
03/01/2016 14:15
MHALL3
1
EPA 200.8
03/01/2016 14:15
MHALL3
1
EPA 200.8
03/01/2016 14:15
MHALL3
1
EPA 200.8
03/01/2016 14:15
MHALL3
1
EPA 200.8
03/01/2016 14:15
MHALL3
1
EPA 200.8
03/01/2016 14:15
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020574
Site: Equipment Blank
Collection Date: 22-Feb-16 11:45 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
Calcium (Ca)
< 0.01
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2016005302
Matrix: GW WW
Analytical Lab
Page 7 of 29
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 02/26/2016 08:43 LSTARLI
Vendor Method V_PACE
1 EPA 300.0
02/25/2016 19:26
BGN9034
1 EPA 300.0
02/25/2016 19:26
BGN9034
1 EPA 245.1
02/29/2016 12:10
LSTARL1
1 EPA 200.7
02/26/2016 10:42
JJMACKE
1 EPA 200.7
02/26/2016 10:42
JJMACKE
1 EPA 200.7
02/26/2016 10:42
JJMACKE
1 EPA 200.7
02/26/2016 10:42
JJMACKE
1 EPA 200.7
02/26/2016 13:42
JJMACKE
1 EPA 200.7
02/26/2016 13:42
JJMACKE
1 EPA 200.7
02/26/2016 13:42
JJMACKE
1 EPA 200.7
02/26/2016 13:42
JJMACKE
1 EPA 200.7
02/26/2016 13:42
JJMACKE
1 EPA 200.7
02/26/2016 13:42
JJMACKE
1 EPA 200.7
02/26/2016 13:42
JJMACKE
1 EPA 200.8
03/01/2016 15:14
MHALL3
1 EPA 200.8
03/01/2016 15:14
MHALL3
1 EPA 200.8
03/01/2016 15:14
MHALL3
1 EPA 200.8
03/01/2016 15:14
MHALL3
1 EPA 200.8
03/01/2016 15:14
MHALL3
1 EPA 200.8
03/01/2016 15:14
MHALL3
1 EPA 200.8
03/01/2016 15:14
MHALL3
1 EPA 200.8
03/01/2016 15:14
MHALL3
1 EPA 200.8
03/01/2016 15:14
MHALL3
1 EPA 200.8
03/01/2016 15:14
MHALL3
1 EPA 200.8
03/01/2016 15:14
MHALL3
1 EPA 200.8
03/01/2016 15:14
MHALL3
1 EPA 200.8
03/01/2016 15:14
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020574
Site: Equipment Blank
Collection Date: 22-Feb-16 11:45 AM
Sample #: 2016005302
Matrix: GW WW
Analytical Lab
Page 8 of 29
Analyte
Result Units Qualifiers
RDL
DF Method
Analysis Date/Time
Analyst
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
TOTAL DISSOLVED SOLIDS
TDS
< 25 mg/L
25
1 SM2540C
02/25/2016 13:59
CJELLIO
Total Carbon
TOC
< 0.1 mg/L
0.1
1 SM5310C/EPA9060A
02/27/2016 12:29
GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS
< 5 mg/L
5
1 SM2540D
02/25/2016 11:52
CJELLIO

aceAnalyical
www.pacelabs.com
Pa�nalyil�afrlabervices, Inc.
%gi9c&f241e. Suite 100
Huntersville, INC 28078
[phone]
March 04, 2016
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 16020574
Pace Project No.: 92287711
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on February 24, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Anne Pifer
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 20

lacmnalyfical
www.pacelabs.com
PaHnal Xti Labervices, Inc.
ftglKi6cgfNe. Suite 100
Huntersville, NC 28078
[phone]
Project: J16020574
Pace Project No.: 92287711
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Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE SUMMARY
Project: J16020574
Pace Project No.: 92287711
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92287711001
92287711002
2016005300
2016005302
Water
Water
02/22/1614:36
02/22/1611:45
02/24/1616:00
02/24/1616:00
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16020574
92287711
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92287711001
2016005300
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92287711002
2016005302
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
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SUMMARY OF DETECTION
Project: J16020574
Pace Project No.: 92287711
Lab Sample ID
Method
Client Sample ID
Parameters
92287711001
2016005300
RSK 175
Methane
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
SM 2320B
Alkalinity, Total as CaCO3
SM 4500-S21D
Sulfide
EPA 218.7
Chromium, Hexavalent
Result
Units
27.9
ug/L
34.4
mg/L
34.4
mg/L
0.32
mg/L
0.053
ug/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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Report Limit Analyzed Qualifiers
10.0
02/25/1614:53 1g
5.0
02/29/16 20:28
5.0
02/29/16 20:28
0.10
02/26/1614:30
0.030
03/01/1613:02
Page 5 of 20

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PROJECT NARRATIVE
Project: J16020574
Pace Project No.: 92287711
Method: RSK 175
Description: RSK 175 AIR Headspace
Client: Duke Energy
Date: March 04, 2016
General Information:
2 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: AIR/25314
1g: Closing continuing calibration verification sample not analyzed due to instrument error. Data accepted based on LCS recovery
and sample duplicate.
•2016005300 (Lab ID:92287711001)
• Methane
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16020574
Pace Project No.: 92287711
Method: SM 2320B
Description: 2320E Alkalinity
Client: Duke Energy
Date: March 04, 2016
General Information:
2 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/43307
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92287592001,92287711002
M1: Matrix spike recovery exceeded QC limits.
• MS (Lab ID: 1674894)
• Alkalinity, Total as CaCO3
• MS (Lab ID: 1674896)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1674895)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1674897)
• Alkalinity, Total as CaCO3
Additional Comments:
Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16020574
Pace Project No.: 92287711
Method: SM 4500-S213
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: March 04, 2016
General Information:
2 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16020574
Pace Project No.: 92287711
Method: EPA 218.7
Description: Hexavalent Chromium by IC
Client: Duke Energy
Date: March 04, 2016
General Information:
2 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/55437
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92287631001,92287761002
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1492931)
• Chromium, Hexavalent
• MSD (Lab ID: 1492932)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16020574
Pace Project No.: 92287711
Sample: 2016005300
Lab ID: 92287711001 Collected:
02/22/16 14:36
Received: 02/24/16 16:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
27.9 ug/L
10.0
1
02/25/1614:53
74-82-8 1g
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
34.4 mg/L
5.0
1
02/29/16 20:28
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
02/29/16 20:28
Alkalinity, Total as CaCO3
34.4 mg/L
5.0
1
02/29/16 20:28
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
0.32 mg/L
0.10
1
02/26/1614:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.053 ug/L
0.030
1
03/01/16 13:02
18540-29-9
Date: 03/04/2016 03:33 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16020574
Pace Project No.: 92287711
Sample: 2016005302
Lab ID: 92287711002 Collected:
02/22/16 11:45
Received: 02/24/16 16:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
02/29/1611:16
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
02/29/16 20:39
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
02/29/16 20:39
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
02/29/16 20:39
M1
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
02/26/1614:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
03/01/16 13:15
18540-29-9
Date: 03/04/2016 03:33 PM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J16020574
Pace Project No.: 92287711
QC Batch: AIR/25314
Analysis Method: RSK 175
QC Batch Method: RSK 175
Analysis Description: RSK 175 AIR HEADSPACE
Associated Lab Samples: 92287711001
METHOD BLANK: 2198780
Matrix: Water
Associated Lab Samples: 92287711001
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers
Methane
ug/L
ND 10.0 02/25/1614:45
LABORATORY CONTROL SAMPLE: 2198781
Spike LCS LCS % Rec
Parameter
Units
Conc. Result % Rec Limits Qualifiers
Methane
ug/L
60.7 63.5 105 85-115
SAMPLE DUPLICATE: 2200635
92287719001 Dup Max
Parameter
Units
Result Result RPD RPD Qualifiers
Methane
ug/L
ND 2.1J 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J16020574
Pace Project No.: 92287711
QC Batch: AIR/25338
Analysis Method: RSK 175
QC Batch Method: RSK 175
Analysis Description: RSK 175 AIR HEADSPACE
Associated Lab Samples: 92287711002
METHOD BLANK: 2200637
Matrix: Water
Associated Lab Samples: 92287711002
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Methane
ug/L
ND 10.0
02/29/1610:27
LABORATORY CONTROL SAMPLE & LCSD:
2200638
2200639
Spike LCS LCSD
LCS LCSD
% Rec Max
Parameter
Units
Conc. Result Result
% Rec % Rec
Limits RPD RPD Qualifiers
Methane
ug/L
60.7 57.1 58.2
94 96
85-115 2 20
SAMPLE DUPLICATE: 2200640
92287645004 Dup
Max
Parameter
Units
Result Result
RPD
RPD Qualifiers
Methane
ug/L
1030 990
4
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J16020574
Pace Project No.: 92287711
QC Batch: WET/43307 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92287711001, 92287711002
METHOD BLANK: 1674892
Associated Lab Samples: 92287711001,
92287711002
Parameter
Units
Alkalinity, Carbonate (CaCO3)
mg/L
Alkalinity, Total as CaCO3
mg/L
Alkalinity, Bicarbonate (CaCO3)
mg/L
LABORATORY CONTROL SAMPLE: 1674893
Parameter Units
Alkalinity, Total as CaCO3 mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed
ND 5.0 02/29/1618:06
ND 5.0 02/29/1618:06
ND 5.0 02/29/1618:06
Spike LCS
Conc. Result
50 48.1
Qualifiers
LCS % Rec
% Rec Limits Qualifiers
96 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1674894 1674895
MS MSD
92287592001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L ND 50 50 1AJ 1.11 3 2 80-120 25 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1674896 1674897
MS MSD
92287711002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Alkalinity, Total as CaCO3 mg/L ND 50 50 9.1 9.2 18 18 80-120 1 25 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J16020574
Pace Project No.: 92287711
QC Batch: WET/43280 Analysis Method: SM 4500-S2D
QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92287711001, 92287711002
METHOD BLANK: 1674239 Matrix: Water
Associated Lab Samples: 92287711001, 92287711002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 02/26/1614:30
LABORATORY CONTROL SAMPLE: 1674240
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.50 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1674241 1674242
MS MSD
92287719001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.47 0.47 94 94 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1674243 1674244
MS MSD
92287719002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.49 0.49 99 99 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J16020574
Pace Project No.: 92287711
QC Batch: WETA/55437
Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7
Analysis Description: Chromium,
Hexavalent IC
Associated Lab Samples: 92287711001, 92287711002
METHOD BLANK: 1492929
Matrix: Water
Associated Lab Samples: 92287711001, 92287711002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chromium, Hexavalent ug/L
ND 0.030
03/01/16 11:44
LABORATORY CONTROL SAMPLE: 1492930
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chromium, Hexavalent ug/L
.075 0.075
100 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1492931 1492932
MS MSD
92287631001
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND
.025 .025 0.038
0.038 153 153 85-115 0 20 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1492933 1492934
MS MSD
92287761002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L 0.60 .38 .38 0.98 0.98 103 101 85-115 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALIFIERS
Project: J16020574
Pace Project No.: 92287711
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-M Pace Analytical Services - Minneapolis
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
1g Closing continuing calibration verification sample not analyzed due to instrument error. Data accepted based on LCS
recovery and sample duplicate.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16020574
Pace Project No.: 92287711
Lab ID
Sample ID
QC Batch Method
QC Batch
92287711001
2016005300
RSK 175
AIR/25314
92287711002
2016005302
RSK 175
AIR/25338
92287711001
2016005300
SM 2320B
WET/43307
92287711002
2016005302
SM 2320B
WET/43307
92287711001
2016005300
SM 4500-S2D
WET/43280
92287711002
2016005302
SM 4500-S2D
WET/43280
92287711001
2016005300
EPA 218.7
WETA/55437
92287711002
2016005302
EPA 218.7
WETA/55437
Date: 03/04/2016 03:33 PM
REPORT OF LABORATORY ANALYSIS
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Analytical Method
Analytical
Batch
Page 18 of 20

iceAnalytica!
Document Name:
Sample Condition Upon Receipt(SCUR)
Document Revised: 260g,200q ical La
Page 1 of 2
Document No.:
F-CHR-CS-003-rev.17
Issuing Authority:
Pace Huntersville Quality Office
Client Name:
Project #:
Courier: ❑Fed ❑UPS ❑U PS ❑Client
❑Commercial [} ace ❑Other:
Custody Seal on Cooler/Box Present? Oyes ❑No
W01# E, 9'.:28 711
1111111111111111111111
97287711
Seals Intact? ❑Yes ONO
Packing Material: ❑Bu le Wrap ❑B bG ble Bags ❑None ❑0ther:
Thermometer 1505 Type of Ice: et []Blue ❑None Samples on ice, cooling process has begun
Used: Yp ®
Cooler Temp Corrected (°C): Biological Tissue Frozen? ❑Yes .: ❑No Otv/A
Temp should be above freezing to 6'C Correction Factor: 0.0 °C Date and Initials of Person Examining.Contents:
USDA Regulated Soil
n ❑ N/A, waken sample}
Did samples oa in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a.foreign source (internationally, _/
❑Yes ❑No including Hawaii and Puerto Rica)? [_]YesQNr
If vac to Pithpr nupctinn. fill out a Regulated Soil Checklist and Include with SCUR/COC paperwork,
COMMENTS:
Chain of Custody Present?
' Yes
No
[I N/A
1.
Chain of Custody Filled Out?
Yes
,`]No
❑N/A
2.
Chain of Custody Relinquished?
EjYes
No
❑N/A
3.
Sampler Name and/or Signature on COC?
No
❑N/A
4.
Samples Arrived within Hold Time?
es
QNa
❑N/A
S.
Short Hold Time Analysis (<72 hr)?
Cqr,,
❑No
[]NIA
G.
Rush Turn Around Time Requested?
❑Yes
No
❑N/A
7.
Sufficient Volume?
❑ es
❑No
❑N/A
8.
Correct Containers Used?
-Pace Containers Used?
D4,
[]YesNo
❑No
❑N/A
❑N/A
9.
Containers Intact?
❑ es
❑No
❑N/A
4C
Filtered Volume Received for Dissolved Tests?
❑Y
[]No
❑ /A
11. Note if sediment is visible in the dissolved container
Sample Labels Match COC? f Yes []No ❑N/A
-Includes Date/T€me/ID/Anaiysls Matrix;__ Y
All containers needing acid/base preservation have been
checked? ❑ e� s ❑No N/A
All containers needing preservation are found to be in
compliance with EPA recommendation?
(HNO3, H2SO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide) es' ON, ❑N/A
Exceptions: VOA, Coliform, TOC, Oil and Grease,
DRO/8015 (water) DOC,LLHg ❑Yes ❑No gNIA
12.
Samples checked for dechlorizatlon
❑Yes
❑No
❑ CIP,,
14•
Headspace in VOA Vials (>5-6mm)?
❑Yes
❑No
15,
Trip Blank Present?
Trip Blank Custody Seals Present?
Pace Trip Blank Lot ft (if purchased):
[]Yes❑No
[]Yes
❑No
nN/
N/A
16.
-
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Resolution:
Date/Time:
Field Data Required? LJYes LJNo
Project Manager SCURF Review: 1 Date: Z2-Note: whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the Nlorth Ca olina OEHNR Certification Office (Le. Out of
hold, incorrect preservative, out of temp, incorrect containers). Page 19 of 20

Analytical Lab
Page 28 of 29
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