The URL can be used to link to this page

Home My WebLink AboutNC0000396_J16010461 Report_20160831DUKE Analytical Laboratory Page 1of60 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J16010461 ASHEVILLE - AB GW ASSESSMENT WATER Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu 200 CP and L Drive Arden,NC 28704 Anne Pifer Phone: Anne Pifer Ko��EA/ RGY, Date: Please contact the Program Manager (Anne Pifer) with any questions regarding this report. Data Flags & Calculations: 2/5/2016 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Page 2 of 60 Sample ID Plant/Station 2016002228 2016002229 2016002230 2016002231 2016002232 2016002233 2016002234 2016002235 2016002236 2016002237 2016002238 2016002239 2016002240 13 Total Samples ASHEVILLE ASHEVILLE ASHEVILLE ASHEVILLE ASHEVILLE ASHEVILLE ASHEVILLE ASHEVILLE ASHEVILLE ASHEVILLE ASHEVILLE ASHEVILLE ASHEVILLE Collection Date and Time Collected By 20-Jan-16 5:40 PM 21-Jan-16 10:13 AM 21-Jan-16 11:15 AM 21-Jan-16 12:01 PM 21-Jan-16 12:13 PM 21-Jan-16 1:01 PM 21-Jan-16 12:20 PM 21-Jan-16 11:37 AM 21-Jan-16 10:30 AM 21-Jan-16 12:20 PM 21-Jan-16 11:10 AM 21-Jan-16 2:39 PM 21-Jan-16 2:39 PM Bart M Fitzpatrick Bart M Fitzpatrick Bart M Fitzpatrick Bart M Fitzpatrick Bart M Fitzpatrick Bart M Fitzpatrick Bart M Fitzpatrick Bart M Fitzpatrick Bart M Fitzpatrick Kyle Donovan Kyle Donovan Kyle Donovan Kyle Donovan Sample Description GW-2 ABMW-04 ABMW-04D ABMW-02 ABMW-02S GW-3 CB-09SL CB-09 CB-09BR CB-6 MW-20A Filter Blank Equipment Blank Page 3 of 60 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification ❑ Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report OV Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries ❑ Chain of Custody ❑ Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Therona T James Date: 2/5/2016 Certificate of Laboratory Analysis Page 4 of 60 This report shall not be reproduced, except in full. Order # J16010461 Site: GW-2 Collection Date: 20-Jan-16 5:40 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.502 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 210 mg/L 5 Sulfate 120 mg/L 2 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.143 mg/L 0.005 Barium (Ba) 0.209 mg/L 0.005 Boron (B) 1.69 mg/L 0.05 Iron (Fe) 0.077 mg/L 0.01 Manganese (Mn) 2.12 mg/L 0.005 Strontium (Sr) 0.658 mg/L 0.005 Zinc (Zn) 0.054 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 113 mg/L 0.1 Magnesium (Mg) 34.6 mg/L 0.05 Potassium (K) 2.58 mg/L 1 Sodium (Na) 6.83 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.284 mg/L 0.005 Barium (Ba) 0.250 mg/L 0.005 Boron (B) 1.72 mg/L 0.05 Iron (Fe) 0.472 mg/L 0.01 Manganese (Mn) 2.14 mg/L 0.005 Strontium (Sr) 0.675 mg/L 0.005 Zinc (Zn) 0.053 mg/L 0.005 Sample #: 2016002228 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:33 LSTARL1 Vendor Method V_PACE 50 EPA 300.0 01/25/2016 20:39 BGN9034 20 EPA 300.0 01/25/2016 20:39 BGN9034 1 EPA 245.1 01/26/2016 19:22 ACPAYNE 1 EPA 245.1 01/27/2016 16:49 ACPAYNE 1 EPA 200.7 01/25/2016 09:57 FCJORDA 1 EPA 200.7 01/25/2016 09:57 FCJORDA 1 EPA 200.7 01/25/2016 09:57 FCJORDA 1 EPA 200.7 01/25/2016 09:57 FCJORDA 1 EPA 200.7 01/25/2016 09:57 FCJORDA 1 EPA 200.7 01/25/2016 09:57 FCJORDA 1 EPA 200.7 01/25/2016 09:57 FCJORDA 10 EPA 200.7 01/25/2016 13:06 FCJORDA 10 EPA 200.7 01/25/2016 13:06 FCJORDA 10 EPA 200.7 01/25/2016 13:06 FCJORDA 10 EPA 200.7 01/25/2016 13:06 FCJORDA 1 EPA 200.7 01/26/2016 10:28 FCJORDA 1 EPA 200.7 01/26/2016 10:28 FCJORDA 1 EPA 200.7 01/26/2016 10:28 FCJORDA 1 EPA 200.7 01/26/2016 10:28 FCJORDA 1 EPA 200.7 01/26/2016 10:28 FCJORDA 1 EPA 200.7 01/26/2016 10:28 FCJORDA 1 EPA 200.7 01/26/2016 10:28 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: GW-2 Collection Date: 20-Jan-16 5:40 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) 1.70 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 2.85 ug/L 1 Cobalt (Co) 10.7 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 11.8 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) 1.82 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 52.0 ug/L 1 Cobalt (Co) 11.5 ug/L 1 Copper (Cu) 1.66 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1.29 ug/L 1 Nickel (Ni) 29.3 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.581 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 660 mg/L 25 Total Carbon TOC 0.205 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 5.0 mg/L 5 Page 5 of 60 Sample #: 2016002228 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 22:31 MHALL3 1 EPA 200.8 01/25/2016 22:31 MHALL3 1 EPA 200.8 01/25/2016 22:31 MHALL3 1 EPA 200.8 01/25/2016 22:31 MHALL3 1 EPA 200.8 01/25/2016 22:31 MHALL3 1 EPA 200.8 01/25/2016 22:31 MHALL3 1 EPA 200.8 01/25/2016 22:31 MHALL3 1 EPA 200.8 01/25/2016 22:31 MHALL3 1 EPA 200.8 01/25/2016 22:31 MHALL3 1 EPA 200.8 01/25/2016 22:31 MHALL3 1 EPA 200.8 01/25/2016 22:31 MHALL3 1 EPA 200.8 01/25/2016 22:31 MHALL3 1 EPA 200.8 01/25/2016 22:31 MHALL3 1 EPA 200.8 01/26/2016 00:43 MHALL3 1 EPA 200.8 01/26/2016 00:43 MHALL3 1 EPA 200.8 01/26/2016 00:43 MHALL3 1 EPA 200.8 01/26/2016 00:43 MHALL3 1 EPA 200.8 01/26/2016 00:43 MHALL3 1 EPA 200.8 01/26/2016 00:43 MHALL3 1 EPA 200.8 01/26/2016 00:43 MHALL3 1 EPA 200.8 01/26/2016 00:43 MHALL3 1 EPA 200.8 01/26/2016 00:43 MHALL3 1 EPA 200.8 01/26/2016 00:43 MHALL3 1 EPA 200.8 01/26/2016 00:43 MHALL3 1 EPA 200.8 01/26/2016 00:43 MHALL3 1 EPA 200.8 01/26/2016 00:43 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/26/201615:53 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/26/2016 09:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: ABMW-04 Collection Date: 21-Jan-16 10:13 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.046 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 16 mg/L 1 Sulfate 290 mg/L 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.060 mg/L 0.005 Barium (Ba) 0.158 mg/L 0.005 Boron (B) 3.50 mg/L 0.05 Iron (Fe) 0.286 mg/L 0.01 Manganese (Mn) 0.098 mg/L 0.005 Strontium (Sr) 3.60 mg/L 0.005 Zinc (Zn) 0.045 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 130 mg/L 0.1 Magnesium (Mg) 64.0 mg/L 0.05 Potassium (K) 19.3 mg/L 1 Sodium (Na) 50.8 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.529 mg/L 0.005 Barium (Ba) 0.162 mg/L 0.005 Boron (B) 3.49 mg/L 0.05 Iron (Fe) 0.478 mg/L 0.01 Manganese (Mn) 0.093 mg/L 0.005 Strontium (Sr) 3.59 mg/L 0.005 Zinc (Zn) 0.045 mg/L 0.005 Sample #: 2016002229 Matrix: GW WW Page 6 of 60 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:40 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/25/2016 20:56 BGN9034 50 EPA 300.0 01/25/2016 20:56 BGN9034 1 EPA 245.1 01/26/2016 19:24 ACPAYNE 1 EPA 245.1 01/27/2016 16:51 ACPAYNE 1 EPA 200.7 01/25/2016 10:08 FCJORDA 1 EPA 200.7 01/25/2016 10:08 FCJORDA 1 EPA 200.7 01/25/2016 10:08 FCJORDA 1 EPA 200.7 01/25/2016 10:08 FCJORDA 1 EPA 200.7 01/25/2016 10:08 FCJORDA 1 EPA 200.7 01/25/2016 10:08 FCJORDA 1 EPA 200.7 01/25/2016 10:08 FCJORDA 10 EPA 200.7 01/25/2016 13:10 FCJORDA 10 EPA 200.7 01/25/2016 13:10 FCJORDA 10 EPA 200.7 01/25/2016 13:10 FCJORDA 10 EPA 200.7 01/25/2016 13:10 FCJORDA 1 EPA 200.7 01/26/2016 10:31 FCJORDA 1 EPA 200.7 01/26/2016 10:31 FCJORDA 1 EPA 200.7 01/26/2016 10:31 FCJORDA 1 EPA 200.7 01/26/2016 10:31 FCJORDA 1 EPA 200.7 01/26/2016 10:31 FCJORDA 1 EPA 200.7 01/26/2016 10:31 FCJORDA 1 EPA 200.7 01/26/2016 10:31 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: ABMW-04 Collection Date: 21-Jan-16 10:13 AM Analyte Result Units Qualifiers TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) 2.68 ug/L Arsenic (As) 791 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) < 1 ug/L Cobalt (Co) < 1 ug/L Copper (Cu) < 1 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) 536 ug/L Nickel (Ni) < 1 ug/L Selenium (Se) < 1 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level 5.69 ug/L TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) 2.95 ug/L Arsenic (As) 812 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) < 1 ug/L Cobalt (Co) < 1 ug/L Copper (Cu) 1.02 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) 533 ug/L Nickel (Ni) 1.12 ug/L Selenium (Se) < 1 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level 7.11 ug/L METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 820 mg/L Total Carbon TOC 0.539 mg/L TOTAL SUSPENDED SOLIDS TSS 11 mg/L Page 7 of 60 Sample #: 2016002229 Matrix: GW WW RDL DF Method Analysis Date/Time Analyst 1 1 EPA 200.8 01/25/2016 22:36 MHALL3 10 10 EPA 200.8 01/25/2016 22:36 MHALL3 1 1 EPA 200.8 01/25/2016 22:36 MHALL3 1 1 EPA 200.8 01/25/2016 22:36 MHALL3 1 1 EPA 200.8 01/25/2016 22:36 MHALL3 1 1 EPA 200.8 01/25/2016 22:36 MHALL3 1 1 EPA 200.8 01/25/2016 22:36 MHALL3 1 1 EPA 200.8 01/25/2016 22:36 MHALL3 10 10 EPA 200.8 01/25/2016 22:36 MHALL3 1 1 EPA 200.8 01/25/2016 22:36 MHALL3 1 1 EPA 200.8 01/25/2016 22:36 MHALL3 0.2 1 EPA 200.8 01/25/2016 22:36 MHALL3 0.3 1 EPA 200.8 01/25/2016 22:36 MHALL3 1 1 EPA 200.8 01/26/2016 00:48 MHALL3 10 10 EPA 200.8 01/26/2016 00:48 MHALL3 1 1 EPA 200.8 01/26/2016 00:48 MHALL3 1 1 EPA 200.8 01/26/2016 00:48 MHALL3 1 1 EPA 200.8 01/26/2016 00:48 MHALL3 1 1 EPA 200.8 01/26/2016 00:48 MHALL3 1 1 EPA 200.8 01/26/2016 00:48 MHALL3 1 1 EPA 200.8 01/26/2016 00:48 MHALL3 10 10 EPA 200.8 01/26/2016 00:48 MHALL3 1 1 EPA 200.8 01/26/2016 00:48 MHALL3 1 1 EPA 200.8 01/26/2016 00:48 MHALL3 0.2 1 EPA 200.8 01/26/2016 00:48 MHALL3 0.3 1 EPA 200.8 01/26/2016 00:48 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 25 1 SM2540C 01/26/201615:53 CJELLIO 0.1 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 5 1 SM2540D 01/26/2016 09:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: ABMW-04D Collection Date: 21-Jan-16 11:15 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.017 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 13 mg/L 0.2 Sulfate 120 mg/L 2 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.019 mg/L 0.005 Barium (Ba) 0.083 mg/L 0.005 Boron (B) 1.13 mg/L 0.05 Iron (Fe) 7.30 mg/L 0.01 Manganese (Mn) 5.98 mg/L 0.005 Strontium (Sr) 0.185 mg/L 0.005 Zinc (Zn) 0.085 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 33.6 mg/L 0.01 Magnesium (Mg) 13.5 mg/L 0.005 Potassium (K) 1.91 mg/L 0.1 Sodium (Na) 5.23 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.364 mg/L 0.005 Barium (Ba) 0.083 mg/L 0.005 Boron (B) 1.11 mg/L 0.05 Iron (Fe) 7.63 mg/L 0.01 Manganese (Mn) 5.79 mg/L 0.005 Strontium (Sr) 0.181 mg/L 0.005 Zinc (Zn) 0.081 mg/L 0.005 Sample #: 2016002230 Matrix: GW WW Page 8 of 60 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:43 LSTARL1 Vendor Method V_PACE 2 EPA 300.0 01/26/2016 15:48 BGN9034 20 EPA 300.0 01/26/2016 15:48 BGN9034 1 EPA 245.1 01/26/2016 19:27 ACPAYNE 1 EPA 245.1 01/27/2016 16:54 ACPAYNE 1 EPA 200.7 01/25/2016 10:20 FCJORDA 1 EPA 200.7 01/25/2016 10:20 FCJORDA 1 EPA 200.7 01/25/2016 10:20 FCJORDA 1 EPA 200.7 01/25/2016 10:20 FCJORDA 1 EPA 200.7 01/25/2016 10:20 FCJORDA 1 EPA 200.7 01/25/2016 10:20 FCJORDA 1 EPA 200.7 01/25/2016 10:20 FCJORDA 1 EPA 200.7 01/25/2016 13:21 FCJORDA 1 EPA 200.7 01/25/2016 13:21 FCJORDA 1 EPA 200.7 01/25/2016 13:21 FCJORDA 1 EPA 200.7 01/25/2016 13:21 FCJORDA 1 EPA 200.7 01/26/2016 10:35 FCJORDA 1 EPA 200.7 01/26/2016 10:35 FCJORDA 1 EPA 200.7 01/26/2016 10:35 FCJORDA 1 EPA 200.7 01/26/2016 10:35 FCJORDA 1 EPA 200.7 01/26/2016 10:35 FCJORDA 1 EPA 200.7 01/26/2016 10:35 FCJORDA 1 EPA 200.7 01/26/2016 10:35 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: ABMW-04D Collection Date: 21-Jan-16 11:15 AM Analyte Result Units Qualifiers TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L Arsenic (As) 1.87 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) < 1 ug/L Cobalt (Co) 51.8 ug/L Copper (Cu) < 1 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) < 1 ug/L Nickel (Ni) 2.32 ug/L Selenium (Se) < 1 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level < 0.3 ug/L TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L Arsenic (As) 2.21 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) 1.15 ug/L Cobalt (Co) 50.4 ug/L Copper (Cu) < 1 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) 1.12 ug/L Nickel (Ni) 2.62 ug/L Selenium (Se) < 1 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level 0.603 ug/L METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 240 mg/L Total Carbon TOC 0.511 mg/L TOTAL SUSPENDED SOLIDS TSS 6.0 mg/L Page 9 of 60 Sample #: 2016002230 Matrix: GW WW RDL DF Method Analysis Date/Time Analyst 1 1 EPA 200.8 01/25/2016 22:41 MHALL3 1 1 EPA 200.8 01/25/2016 22:41 MHALL3 1 1 EPA 200.8 01/25/2016 22:41 MHALL3 1 1 EPA 200.8 01/25/2016 22:41 MHALL3 1 1 EPA 200.8 01/25/2016 22:41 MHALL3 1 1 EPA 200.8 01/25/2016 22:41 MHALL3 1 1 EPA 200.8 01/25/2016 22:41 MHALL3 1 1 EPA 200.8 01/25/2016 22:41 MHALL3 1 1 EPA 200.8 01/25/2016 22:41 MHALL3 1 1 EPA 200.8 01/25/2016 22:41 MHALL3 1 1 EPA 200.8 01/25/2016 22:41 MHALL3 0.2 1 EPA 200.8 01/25/2016 22:41 MHALL3 0.3 1 EPA 200.8 01/25/2016 22:41 MHALL3 1 1 EPA 200.8 01/26/2016 00:53 MHALL3 1 1 EPA 200.8 01/26/2016 00:53 MHALL3 1 1 EPA 200.8 01/26/2016 00:53 MHALL3 1 1 EPA 200.8 01/26/2016 00:53 MHALL3 1 1 EPA 200.8 01/26/2016 00:53 MHALL3 1 1 EPA 200.8 01/26/2016 00:53 MHALL3 1 1 EPA 200.8 01/26/2016 00:53 MHALL3 1 1 EPA 200.8 01/26/2016 00:53 MHALL3 1 1 EPA 200.8 01/26/2016 00:53 MHALL3 1 1 EPA 200.8 01/26/2016 00:53 MHALL3 1 1 EPA 200.8 01/26/2016 00:53 MHALL3 0.2 1 EPA 200.8 01/26/2016 00:53 MHALL3 0.3 1 EPA 200.8 01/26/2016 00:53 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 25 1 SM2540C 01/26/201615:53 CJELLIO 0.1 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 5 1 SM2540D 01/26/2016 09:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: ABMW-02 Collection Date: 21-Jan-16 12:01 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.015 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 7.9 mg/L 0.5 Sulfate 200 mg/L 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.032 mg/L 0.005 Barium (Ba) 0.327 mg/L 0.005 Boron (B) 2.00 mg/L 0.05 Iron (Fe) 2.94 mg/L 0.01 Manganese (Mn) 2.00 mg/L 0.005 Strontium (Sr) 6.76 mg/L 0.005 Zinc (Zn) 0.010 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 190 mg/L 0.1 Magnesium (Mg) 45.9 mg/L 0.05 Potassium (K) 18.2 mg/L 1 Sodium (Na) 26.0 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.067 mg/L 0.005 Barium (Ba) 0.343 mg/L 0.005 Boron (B) 2.06 mg/L 0.05 Iron (Fe) 3.41 mg/L 0.01 Manganese (Mn) 2.07 mg/L 0.005 Strontium (Sr) 6.94 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016002231 Matrix: GW WW Page 10 of 60 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:45 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/26/2016 17:33 BGN9034 50 EPA 300.0 01/26/2016 17:33 BGN9034 1 EPA 245.1 01/26/2016 19:29 ACPAYNE 1 EPA 245.1 01/27/2016 16:56 ACPAYNE 1 EPA 200.7 01/25/2016 10:23 FCJORDA 1 EPA 200.7 01/25/2016 10:23 FCJORDA 1 EPA 200.7 01/25/2016 10:23 FCJORDA 1 EPA 200.7 01/25/2016 10:23 FCJORDA 1 EPA 200.7 01/25/2016 10:23 FCJORDA 1 EPA 200.7 01/25/2016 10:23 FCJORDA 1 EPA 200.7 01/25/2016 10:23 FCJORDA 10 EPA 200.7 01/25/2016 13:25 FCJORDA 10 EPA 200.7 01/25/2016 13:25 FCJORDA 10 EPA 200.7 01/25/2016 13:25 FCJORDA 10 EPA 200.7 01/25/2016 13:25 FCJORDA 1 EPA 200.7 01/26/2016 10:39 FCJORDA 1 EPA 200.7 01/26/2016 10:39 FCJORDA 1 EPA 200.7 01/26/2016 10:39 FCJORDA 1 EPA 200.7 01/26/2016 10:39 FCJORDA 1 EPA 200.7 01/26/2016 10:39 FCJORDA 1 EPA 200.7 01/26/2016 10:39 FCJORDA 1 EPA 200.7 01/26/2016 10:39 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: ABMW-02 Collection Date: 21-Jan-16 12:01 PM Analyte Result Units Qualifiers TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L Arsenic (As) 1490 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) < 1 ug/L Cobalt (Co) 13.2 ug/L Copper (Cu) < 1 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) 279 ug/L Nickel (Ni) 1.62 ug/L Selenium (Se) < 1 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level 1.90 ug/L TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L Arsenic (As) 1600 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) < 1 ug/L Cobalt (Co) 13.2 ug/L Copper (Cu) < 1 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) 281 ug/L Nickel (Ni) 1.51 ug/L Selenium (Se) < 1 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level 2.97 ug/L METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 840 mg/L Total Carbon TOC 0.674 mg/L TOTAL SUSPENDED SOLIDS TSS 10 mg/L Page 11 of 60 Sample #: 2016002231 Matrix: GW WW RDL DF Method Analysis Date/Time Analyst 1 1 EPA 200.8 01/25/2016 22:46 MHALL3 10 10 EPA 200.8 01/25/2016 22:46 MHALL3 1 1 EPA 200.8 01/25/2016 22:46 MHALL3 1 1 EPA 200.8 01/25/2016 22:46 MHALL3 1 1 EPA 200.8 01/25/2016 22:46 MHALL3 1 1 EPA 200.8 01/25/2016 22:46 MHALL3 1 1 EPA 200.8 01/25/2016 22:46 MHALL3 1 1 EPA 200.8 01/25/2016 22:46 MHALL3 1 1 EPA 200.8 01/25/2016 22:46 MHALL3 1 1 EPA 200.8 01/25/2016 22:46 MHALL3 1 1 EPA 200.8 01/25/2016 22:46 MHALL3 0.2 1 EPA 200.8 01/25/2016 22:46 MHALL3 0.3 1 EPA 200.8 01/25/2016 22:46 MHALL3 1 1 EPA 200.8 01/26/2016 00:57 MHALL3 10 10 EPA 200.8 01/26/2016 00:57 MHALL3 1 1 EPA 200.8 01/26/2016 00:57 MHALL3 1 1 EPA 200.8 01/26/2016 00:57 MHALL3 1 1 EPA 200.8 01/26/2016 00:57 MHALL3 1 1 EPA 200.8 01/26/2016 00:57 MHALL3 1 1 EPA 200.8 01/26/2016 00:57 MHALL3 1 1 EPA 200.8 01/26/2016 00:57 MHALL3 1 1 EPA 200.8 01/26/2016 00:57 MHALL3 1 1 EPA 200.8 01/26/2016 00:57 MHALL3 1 1 EPA 200.8 01/26/2016 00:57 MHALL3 0.2 1 EPA 200.8 01/26/2016 00:57 MHALL3 0.3 1 EPA 200.8 01/26/2016 00:57 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 25 1 SM2540C 01/26/201615:53 CJELLIO 0.1 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 5 1 SM2540D 01/26/2016 09:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: ABMW-02S Collection Date: 21-Jan-16 12:13 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.497 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 16 mg/L 1 Sulfate 630 mg/L 10 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 14.5 mg/L 0.005 Barium (Ba) 0.017 mg/L 0.005 Boron (B) 0.912 mg/L 0.05 Iron (Fe) 0.028 mg/L 0.01 Manganese (Mn) 20.0 mg/L 0.005 Strontium (Sr) 0.355 mg/L 0.005 Zinc (Zn) 0.493 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 92.5 mg/L 0.1 Magnesium (Mg) 27.2 mg/L 0.05 Potassium (K) 5.02 mg/L 1 Sodium (Na) 16.2 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 13.3 mg/L 0.005 Barium (Ba) 0.015 mg/L 0.005 Boron (B) 0.851 mg/L 0.05 Iron (Fe) 0.027 mg/L 0.01 Manganese (Mn) 18.4 mg/L 0.005 Strontium (Sr) 0.340 mg/L 0.005 Zinc (Zn) 0.435 mg/L 0.005 Page 12 of 60 Sample #: 2016002232 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:46 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/25/2016 21:13 BGN9034 100 EPA 300.0 01/25/2016 21:13 BGN9034 1 EPA 245.1 01/26/2016 19:31 ACPAYNE 1 EPA 245.1 01/29/2016 15:23 ACPAYNE 1 EPA 200.7 01/25/2016 10:27 FCJORDA 1 EPA 200.7 01/25/2016 10:27 FCJORDA 1 EPA 200.7 01/25/2016 10:27 FCJORDA 1 EPA 200.7 01/25/2016 10:27 FCJORDA 1 EPA 200.7 01/25/2016 10:27 FCJORDA 1 EPA 200.7 01/25/2016 10:27 FCJORDA 1 EPA 200.7 01/25/2016 10:27 FCJORDA 10 EPA 200.7 01/25/2016 13:29 FCJORDA 10 EPA 200.7 01/25/2016 13:29 FCJORDA 10 EPA 200.7 01/25/2016 13:29 FCJORDA 10 EPA 200.7 01/25/2016 13:29 FCJORDA 1 EPA 200.7 01/26/2016 10:43 FCJORDA 1 EPA 200.7 01/26/2016 10:43 FCJORDA 1 EPA 200.7 01/26/2016 10:43 FCJORDA 1 EPA 200.7 01/26/2016 10:43 FCJORDA 1 EPA 200.7 01/26/2016 10:43 FCJORDA 1 EPA 200.7 01/26/2016 10:43 FCJORDA 1 EPA 200.7 01/26/2016 10:43 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: ABMW-02S Collection Date: 21-Jan-16 12:13 PM Analyte Result Units Qualifiers TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L Arsenic (As) 23.5 ug/L Beryllium (Be) 11.7 ug/L Cadmium (Cd) 3.52 ug/L Chromium (Cr) < 1 ug/L Cobalt (Co) 588 ug/L Copper (Cu) 4.42 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) < 1 ug/L Nickel (Ni) 291 ug/L Selenium (Se) 2.52 ug/L Thallium (TI) Low Level 0.235 ug/L Vanadium (V) Low Level < 0.3 ug/L TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L Arsenic (As) 23.5 ug/L Beryllium (Be) 12.4 ug/L Cadmium (Cd) 3.48 ug/L Chromium (Cr) < 1 ug/L Cobalt (Co) 589 ug/L Copper (Cu) 4.61 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) 1.05 ug/L Nickel (Ni) 286 ug/L Selenium (Se) 2.48 ug/L Thallium (TI) Low Level 0.258 ug/L Vanadium (V) Low Level 0.364 ug/L METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 710 mg/L Total Carbon TOC 0.363 mg/L TOTAL SUSPENDED SOLIDS TSS < 5 mg/L Page 13 of 60 Sample #: 2016002232 Matrix: GW WW RDL DF Method Analysis Date/Time Analyst 1 1 EPA 200.8 01/25/2016 22:50 MHALL3 1 1 EPA 200.8 01/25/2016 22:50 MHALL3 1 1 EPA 200.8 01/25/2016 22:50 MHALL3 1 1 EPA 200.8 01/25/2016 22:50 MHALL3 1 1 EPA 200.8 01/25/2016 22:50 MHALL3 10 10 EPA 200.8 01/25/2016 22:50 MHALL3 1 1 EPA 200.8 01/25/2016 22:50 MHALL3 1 1 EPA 200.8 01/25/2016 22:50 MHALL3 1 1 EPA 200.8 01/25/2016 22:50 MHALL3 1 1 EPA 200.8 01/25/2016 22:50 MHALL3 1 1 EPA 200.8 01/25/2016 22:50 MHALL3 0.2 1 EPA 200.8 01/25/2016 22:50 MHALL3 0.3 1 EPA 200.8 01/25/2016 22:50 MHALL3 1 1 EPA 200.8 01/26/2016 01:02 MHALL3 1 1 EPA 200.8 01/26/2016 01:02 MHALL3 1 1 EPA 200.8 01/26/2016 01:02 MHALL3 1 1 EPA 200.8 01/26/2016 01:02 MHALL3 1 1 EPA 200.8 01/26/2016 01:02 MHALL3 10 10 EPA 200.8 01/26/2016 01:02 MHALL3 1 1 EPA 200.8 01/26/2016 01:02 MHALL3 1 1 EPA 200.8 01/26/2016 01:02 MHALL3 1 1 EPA 200.8 01/26/2016 01:02 MHALL3 1 1 EPA 200.8 01/26/2016 01:02 MHALL3 1 1 EPA 200.8 01/26/2016 01:02 MHALL3 0.2 1 EPA 200.8 01/26/2016 01:02 MHALL3 0.3 1 EPA 200.8 01/26/2016 01:02 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 25 1 SM2540C 01/26/201615:53 CJELLIO 0.1 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 5 1 SM2540D 01/26/2016 09:45 CJELLIO Certificate of Laboratory Analysis Page 14 of 60 This report shall not be reproduced, except in full. Order # J16010461 Site: GW-3 Collection Date: 21-Jan-16 1:01 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.061 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 17 mg/L 0.2 Sulfate 50 mg/L 2 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.009 mg/L 0.005 Barium (Ba) 0.091 mg/L 0.005 Boron (B) 0.678 mg/L 0.05 Iron (Fe) 0.491 mg/L 0.01 Manganese (Mn) 3.56 mg/L 0.005 Strontium (Sr) 0.435 mg/L 0.005 Zinc (Zn) 0.007 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 27.1 mg/L 0.01 Magnesium (Mg) 9.07 mg/L 0.005 Potassium (K) 2.88 mg/L 0.1 Sodium (Na) 12.7 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.182 mg/L 0.005 Barium (Ba) 0.072 mg/L 0.005 Boron (B) 0.477 mg/L 0.05 Iron (Fe) 0.955 mg/L 0.01 Manganese (Mn) 3.20 mg/L 0.005 Strontium (Sr) 0.316 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016002233 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:47 LSTARL1 Vendor Method V_PACE 2 EPA 300.0 01/26/2016 17:50 BGN9034 20 EPA 300.0 01/26/2016 17:50 BGN9034 1 EPA 245.1 01/26/2016 19:39 ACPAYNE 1 EPA 245.1 01/29/2016 15:37 ACPAYNE 1 EPA 200.7 01/25/2016 10:31 FCJORDA 1 EPA 200.7 01/25/2016 10:31 FCJORDA 1 EPA 200.7 01/25/2016 10:31 FCJORDA 1 EPA 200.7 01/25/2016 10:31 FCJORDA 1 EPA 200.7 01/25/2016 10:31 FCJORDA 1 EPA 200.7 01/25/2016 10:31 FCJORDA 1 EPA 200.7 01/25/2016 10:31 FCJORDA 1 EPA 200.7 01/25/2016 13:33 FCJORDA 1 EPA 200.7 01/25/2016 13:33 FCJORDA 1 EPA 200.7 01/25/2016 13:33 FCJORDA 1 EPA 200.7 01/25/2016 13:33 FCJORDA 1 EPA 200.7 01/26/2016 10:47 FCJORDA 1 EPA 200.7 01/26/2016 10:47 FCJORDA 1 EPA 200.7 01/26/2016 10:47 FCJORDA 1 EPA 200.7 01/26/2016 10:47 FCJORDA 1 EPA 200.7 01/26/2016 10:47 FCJORDA 1 EPA 200.7 01/26/2016 10:47 FCJORDA 1 EPA 200.7 01/26/2016 10:47 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: GW-3 Collection Date: 21-Jan-16 1:01 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 44.6 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 2.34 ug/L 1 Selenium (Se) 1.22 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 51.5 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 2.41 ug/L 1 Selenium (Se) 1.17 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 200 mg/L 25 Total Carbon TOC 0.757 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 6.0 mg/L 5 Page 15 of 60 Sample #: 2016002233 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 22:55 MHALL3 1 EPA 200.8 01/25/2016 22:55 MHALL3 1 EPA 200.8 01/25/2016 22:55 MHALL3 1 EPA 200.8 01/25/2016 22:55 MHALL3 1 EPA 200.8 01/25/2016 22:55 MHALL3 1 EPA 200.8 01/25/2016 22:55 MHALL3 1 EPA 200.8 01/25/2016 22:55 MHALL3 1 EPA 200.8 01/25/2016 22:55 MHALL3 1 EPA 200.8 01/25/2016 22:55 MHALL3 1 EPA 200.8 01/25/2016 22:55 MHALL3 1 EPA 200.8 01/25/2016 22:55 MHALL3 1 EPA 200.8 01/25/2016 22:55 MHALL3 1 EPA 200.8 01/25/2016 22:55 MHALL3 1 EPA 200.8 01/26/2016 01:07 MHALL3 1 EPA 200.8 01/26/2016 01:07 MHALL3 1 EPA 200.8 01/26/2016 01:07 MHALL3 1 EPA 200.8 01/26/2016 01:07 MHALL3 1 EPA 200.8 01/26/2016 01:07 MHALL3 1 EPA 200.8 01/26/2016 01:07 MHALL3 1 EPA 200.8 01/26/2016 01:07 MHALL3 1 EPA 200.8 01/26/2016 01:07 MHALL3 1 EPA 200.8 01/26/2016 01:07 MHALL3 1 EPA 200.8 01/26/2016 01:07 MHALL3 1 EPA 200.8 01/26/2016 01:07 MHALL3 1 EPA 200.8 01/26/2016 01:07 MHALL3 1 EPA 200.8 01/26/2016 01:07 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/26/201615:53 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/26/2016 09:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: CB-09SL Collection Date: 21-Jan-16 12:20 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.262 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 6.5 mg/L 0.1 Sulfate 0.24 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.007 mg/L 0.005 Barium (Ba) 0.033 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.016 mg/L 0.005 Strontium (Sr) 0.026 mg/L 0.005 Zinc (Zn) 0.029 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 3.14 mg/L 0.01 Magnesium (Mg) 1.88 mg/L 0.005 Potassium (K) 2.02 mg/L 0.1 Sodium (Na) 3.00 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.167 mg/L 0.005 Barium (Ba) 0.043 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.095 mg/L 0.01 Manganese (Mn) 0.015 mg/L 0.005 Strontium (Sr) 0.030 mg/L 0.005 Zinc (Zn) 0.022 mg/L 0.005 Sample #: 2016002234 Matrix: GW WW Page 16 of 60 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:48 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/25/2016 19:48 BGN9034 1 EPA 300.0 01/25/2016 19:48 BGN9034 1 EPA 245.1 01/26/2016 19:46 ACPAYNE 1 EPA 245.1 01/29/2016 15:39 ACPAYNE 1 EPA 200.7 01/25/2016 10:35 FCJORDA 1 EPA 200.7 01/25/2016 10:35 FCJORDA 1 EPA 200.7 01/25/2016 10:35 FCJORDA 1 EPA 200.7 01/25/2016 10:35 FCJORDA 1 EPA 200.7 01/25/2016 10:35 FCJORDA 1 EPA 200.7 01/25/2016 10:35 FCJORDA 1 EPA 200.7 01/25/2016 10:35 FCJORDA 1 EPA 200.7 01/25/2016 13:37 FCJORDA 1 EPA 200.7 01/25/2016 13:37 FCJORDA 1 EPA 200.7 01/25/2016 13:37 FCJORDA 1 EPA 200.7 01/25/2016 13:37 FCJORDA 1 EPA 200.7 01/26/2016 10:50 FCJORDA 1 EPA 200.7 01/26/2016 10:50 FCJORDA 1 EPA 200.7 01/26/2016 10:50 FCJORDA 1 EPA 200.7 01/26/2016 10:50 FCJORDA 1 EPA 200.7 01/26/2016 10:50 FCJORDA 1 EPA 200.7 01/26/2016 10:50 FCJORDA 1 EPA 200.7 01/26/2016 10:50 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: CB-09SL Collection Date: 21-Jan-16 12:20 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 41 mg/L 25 Total Carbon TOC 0.152 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 17 of 60 Sample #: 2016002234 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 22:11 MHALL3 1 EPA 200.8 01/25/2016 22:11 MHALL3 1 EPA 200.8 01/25/2016 22:11 MHALL3 1 EPA 200.8 01/25/2016 22:11 MHALL3 1 EPA 200.8 01/25/2016 22:11 MHALL3 1 EPA 200.8 01/25/2016 22:11 MHALL3 1 EPA 200.8 01/25/2016 22:11 MHALL3 1 EPA 200.8 01/25/2016 22:11 MHALL3 1 EPA 200.8 01/25/2016 22:11 MHALL3 1 EPA 200.8 01/25/2016 22:11 MHALL3 1 EPA 200.8 01/25/2016 22:11 MHALL3 1 EPA 200.8 01/25/2016 22:11 MHALL3 1 EPA 200.8 01/25/2016 22:11 MHALL3 1 EPA 200.8 01/26/2016 01:12 MHALL3 1 EPA 200.8 01/26/2016 01:12 MHALL3 1 EPA 200.8 01/26/2016 01:12 MHALL3 1 EPA 200.8 01/26/2016 01:12 MHALL3 1 EPA 200.8 01/26/2016 01:12 MHALL3 1 EPA 200.8 01/26/2016 01:12 MHALL3 1 EPA 200.8 01/26/2016 01:12 MHALL3 1 EPA 200.8 01/26/2016 01:12 MHALL3 1 EPA 200.8 01/26/2016 01:12 MHALL3 1 EPA 200.8 01/26/2016 01:12 MHALL3 1 EPA 200.8 01/26/2016 01:12 MHALL3 1 EPA 200.8 01/26/2016 01:12 MHALL3 1 EPA 200.8 01/26/2016 01:12 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/26/201615:53 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/26/2016 09:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: CB-09 Collection Date: 21-Jan-16 11:37 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.256 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 6.9 mg/L 0.1 Sulfate 0.14 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.021 mg/L 0.005 Barium (Ba) 0.022 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.034 mg/L 0.005 Strontium (Sr) 0.007 mg/L 0.005 Zinc (Zn) 0.022 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 0.463 mg/L 0.01 Magnesium (Mg) 0.913 mg/L 0.005 Potassium (K) 0.689 mg/L 0.1 Sodium (Na) 3.89 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.062 mg/L 0.005 Barium (Ba) 0.026 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.084 mg/L 0.01 Manganese (Mn) 0.036 mg/L 0.005 Strontium (Sr) 0.007 mg/L 0.005 Zinc (Zn) 0.011 mg/L 0.005 Sample #: 2016002235 Matrix: GW WW Page 18 of 60 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:49 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/25/2016 20:05 BGN9034 1 EPA 300.0 01/25/2016 20:05 BGN9034 1 EPA 245.1 01/26/2016 19:49 ACPAYNE 1 EPA 245.1 01/29/2016 15:42 ACPAYNE 1 EPA 200.7 01/25/2016 10:39 FCJORDA 1 EPA 200.7 01/25/2016 10:39 FCJORDA 1 EPA 200.7 01/25/2016 10:39 FCJORDA 1 EPA 200.7 01/25/2016 10:39 FCJORDA 1 EPA 200.7 01/25/2016 10:39 FCJORDA 1 EPA 200.7 01/25/2016 10:39 FCJORDA 1 EPA 200.7 01/25/2016 10:39 FCJORDA 1 EPA 200.7 01/25/2016 13:40 FCJORDA 1 EPA 200.7 01/25/2016 13:40 FCJORDA 1 EPA 200.7 01/25/2016 13:40 FCJORDA 1 EPA 200.7 01/25/2016 13:40 FCJORDA 1 EPA 200.7 01/26/2016 10:54 FCJORDA 1 EPA 200.7 01/26/2016 10:54 FCJORDA 1 EPA 200.7 01/26/2016 10:54 FCJORDA 1 EPA 200.7 01/26/2016 10:54 FCJORDA 1 EPA 200.7 01/26/2016 10:54 FCJORDA 1 EPA 200.7 01/26/2016 10:54 FCJORDA 1 EPA 200.7 01/26/2016 10:54 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: CB-09 Collection Date: 21-Jan-16 11:37 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.09 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.28 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 Total Carbon TOC 0.143 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 19 of 60 Sample #: 2016002235 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 23:29 MHALL3 1 EPA 200.8 01/25/2016 23:29 MHALL3 1 EPA 200.8 01/25/2016 23:29 MHALL3 1 EPA 200.8 01/25/2016 23:29 MHALL3 1 EPA 200.8 01/25/2016 23:29 MHALL3 1 EPA 200.8 01/25/2016 23:29 MHALL3 1 EPA 200.8 01/25/2016 23:29 MHALL3 1 EPA 200.8 01/25/2016 23:29 MHALL3 1 EPA 200.8 01/25/2016 23:29 MHALL3 1 EPA 200.8 01/25/2016 23:29 MHALL3 1 EPA 200.8 01/25/2016 23:29 MHALL3 1 EPA 200.8 01/25/2016 23:29 MHALL3 1 EPA 200.8 01/25/2016 23:29 MHALL3 1 EPA 200.8 01/26/2016 01:17 MHALL3 1 EPA 200.8 01/26/2016 01:17 MHALL3 1 EPA 200.8 01/26/2016 01:17 MHALL3 1 EPA 200.8 01/26/2016 01:17 MHALL3 1 EPA 200.8 01/26/2016 01:17 MHALL3 1 EPA 200.8 01/26/2016 01:17 MHALL3 1 EPA 200.8 01/26/2016 01:17 MHALL3 1 EPA 200.8 01/26/2016 01:17 MHALL3 1 EPA 200.8 01/26/2016 01:17 MHALL3 1 EPA 200.8 01/26/2016 01:17 MHALL3 1 EPA 200.8 01/26/2016 01:17 MHALL3 1 EPA 200.8 01/26/2016 01:17 MHALL3 1 EPA 200.8 01/26/2016 01:17 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/26/201615:53 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/26/2016 09:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: CB-09BR Collection Date: 21-Jan-16 10:30 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.125 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 6.4 mg/L 0.1 Sulfate 1.2 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.018 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.103 mg/L 0.01 Manganese (Mn) 0.065 mg/L 0.005 Strontium (Sr) 0.068 mg/L 0.005 Zinc (Zn) 0.027 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 10.5 mg/L 0.01 Magnesium (Mg) 3.02 mg/L 0.005 Potassium (K) 2.55 mg/L 0.1 Sodium (Na) 3.47 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.080 mg/L 0.005 Barium (Ba) 0.020 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.678 mg/L 0.01 Manganese (Mn) 0.070 mg/L 0.005 Strontium (Sr) 0.071 mg/L 0.005 Zinc (Zn) 0.032 mg/L 0.005 Sample #: 2016002236 Matrix: GW WW Page 20 of 60 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:51 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/25/2016 20:22 BGN9034 1 EPA 300.0 01/25/2016 20:22 BGN9034 1 EPA 245.1 01/26/2016 19:51 ACPAYNE 1 EPA 245.1 01/29/2016 15:44 ACPAYNE 1 EPA 200.7 01/25/2016 10:43 FCJORDA 1 EPA 200.7 01/25/2016 10:43 FCJORDA 1 EPA 200.7 01/25/2016 10:43 FCJORDA 1 EPA 200.7 01/25/2016 10:43 FCJORDA 1 EPA 200.7 01/25/2016 10:43 FCJORDA 1 EPA 200.7 01/25/2016 10:43 FCJORDA 1 EPA 200.7 01/25/2016 10:43 FCJORDA 1 EPA 200.7 01/25/2016 13:44 FCJORDA 1 EPA 200.7 01/25/2016 13:44 FCJORDA 1 EPA 200.7 01/25/2016 13:44 FCJORDA 1 EPA 200.7 01/25/2016 13:44 FCJORDA 1 EPA 200.7 01/26/2016 10:58 FCJORDA 1 EPA 200.7 01/26/2016 10:58 FCJORDA 1 EPA 200.7 01/26/2016 10:58 FCJORDA 1 EPA 200.7 01/26/2016 10:58 FCJORDA 1 EPA 200.7 01/26/2016 10:58 FCJORDA 1 EPA 200.7 01/26/2016 10:58 FCJORDA 1 EPA 200.7 01/26/2016 10:58 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: CB-09BR Collection Date: 21-Jan-16 10:30 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 9.08 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 5.79 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 76 mg/L 25 Total Carbon TOC 0.325 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 11 mg/L 5 Page 21 of 60 Sample #: 2016002236 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 23:00 MHALL3 1 EPA 200.8 01/25/2016 23:00 MHALL3 1 EPA 200.8 01/25/2016 23:00 MHALL3 1 EPA 200.8 01/25/2016 23:00 MHALL3 1 EPA 200.8 01/25/2016 23:00 MHALL3 1 EPA 200.8 01/25/2016 23:00 MHALL3 1 EPA 200.8 01/25/2016 23:00 MHALL3 1 EPA 200.8 01/25/2016 23:00 MHALL3 1 EPA 200.8 01/25/2016 23:00 MHALL3 1 EPA 200.8 01/25/2016 23:00 MHALL3 1 EPA 200.8 01/25/2016 23:00 MHALL3 1 EPA 200.8 01/25/2016 23:00 MHALL3 1 EPA 200.8 01/25/2016 23:00 MHALL3 1 EPA 200.8 01/26/2016 01:41 MHALL3 1 EPA 200.8 01/26/2016 01:41 MHALL3 1 EPA 200.8 01/26/2016 01:41 MHALL3 1 EPA 200.8 01/26/2016 01:41 MHALL3 1 EPA 200.8 01/26/2016 01:41 MHALL3 1 EPA 200.8 01/26/2016 01:41 MHALL3 1 EPA 200.8 01/26/2016 01:41 MHALL3 1 EPA 200.8 01/26/2016 01:41 MHALL3 1 EPA 200.8 01/26/2016 01:41 MHALL3 1 EPA 200.8 01/26/2016 01:41 MHALL3 1 EPA 200.8 01/26/2016 01:41 MHALL3 1 EPA 200.8 01/26/2016 01:41 MHALL3 1 EPA 200.8 01/26/2016 01:41 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/26/201615:53 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/26/2016 09:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: CB-6 Collection Date: 21-Jan-16 12:20 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.018 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 55 mg/L 2 Sulfate 590 mg/L 20 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 1.26 mg/L 0.005 Barium (Ba) 0.037 mg/L 0.005 Boron (B) 0.512 mg/L 0.05 Iron (Fe) 21.2 mg/L 0.01 Manganese (Mn) 12.2 mg/L 0.005 Strontium (Sr) 0.756 mg/L 0.005 Zinc (Zn) 0.018 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 144 mg/L 0.1 Magnesium (Mg) 26.9 mg/L 0.05 Potassium (K) 11.6 mg/L 1 Sodium (Na) 41.0 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 1.60 mg/L 0.005 Barium (Ba) 0.045 mg/L 0.005 Boron (B) 0.599 mg/L 0.05 Iron (Fe) 16.6 mg/L 0.01 Manganese (Mn) 14.3 mg/L 0.005 Strontium (Sr) 0.911 mg/L 0.005 Zinc (Zn) 0.018 mg/L 0.005 Page 22 of 60 Sample #: 2016002237 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:52 LSTARL1 Vendor Method V_PACE 20 EPA 300.0 01/26/2016 18:07 BGN9034 200 EPA 300.0 01/26/2016 18:07 BGN9034 1 EPA 245.1 01/26/2016 19:53 ACPAYNE 1 EPA 245.1 01/29/2016 15:47 ACPAYNE 1 EPA 200.7 01/25/2016 10:46 FCJORDA 1 EPA 200.7 01/25/2016 10:46 FCJORDA 1 EPA 200.7 01/25/2016 10:46 FCJORDA 1 EPA 200.7 01/25/2016 10:46 FCJORDA 1 EPA 200.7 01/25/2016 10:46 FCJORDA 1 EPA 200.7 01/25/2016 10:46 FCJORDA 1 EPA 200.7 01/25/2016 10:46 FCJORDA 10 EPA 200.7 01/25/2016 13:48 FCJORDA 10 EPA 200.7 01/25/2016 13:48 FCJORDA 10 EPA 200.7 01/25/2016 13:48 FCJORDA 10 EPA 200.7 01/25/2016 13:48 FCJORDA 1 EPA 200.7 01/26/2016 11:21 FCJORDA 1 EPA 200.7 01/26/2016 11:21 FCJORDA 1 EPA 200.7 01/26/2016 11:21 FCJORDA 1 EPA 200.7 01/26/2016 11:21 FCJORDA 1 EPA 200.7 01/26/2016 11:21 FCJORDA 1 EPA 200.7 01/26/2016 11:21 FCJORDA 1 EPA 200.7 01/26/2016 11:21 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: CB-6 Collection Date: 21-Jan-16 12:20 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 22.3 ug/L 1 Copper (Cu) 1.79 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 17.4 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 23.6 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 18.7 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 910 mg/L 25 Total Carbon TOC 1.9 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 23 of 60 Sample #: 2016002237 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 23:05 MHALL3 1 EPA 200.8 01/25/2016 23:05 MHALL3 1 EPA 200.8 01/25/2016 23:05 MHALL3 1 EPA 200.8 01/25/2016 23:05 MHALL3 1 EPA 200.8 01/25/2016 23:05 MHALL3 1 EPA 200.8 01/25/2016 23:05 MHALL3 1 EPA 200.8 01/25/2016 23:05 MHALL3 1 EPA 200.8 01/25/2016 23:05 MHALL3 1 EPA 200.8 01/25/2016 23:05 MHALL3 1 EPA 200.8 01/25/2016 23:05 MHALL3 1 EPA 200.8 01/25/2016 23:05 MHALL3 1 EPA 200.8 01/25/2016 23:05 MHALL3 1 EPA 200.8 01/25/2016 23:05 MHALL3 1 EPA 200.8 01/26/2016 01:22 MHALL3 1 EPA 200.8 01/26/2016 01:22 MHALL3 1 EPA 200.8 01/26/2016 01:22 MHALL3 1 EPA 200.8 01/26/2016 01:22 MHALL3 1 EPA 200.8 01/26/2016 01:22 MHALL3 1 EPA 200.8 01/26/2016 01:22 MHALL3 1 EPA 200.8 01/26/2016 01:22 MHALL3 1 EPA 200.8 01/26/2016 01:22 MHALL3 1 EPA 200.8 01/26/2016 01:22 MHALL3 1 EPA 200.8 01/26/2016 01:22 MHALL3 1 EPA 200.8 01/26/2016 01:22 MHALL3 1 EPA 200.8 01/26/2016 01:22 MHALL3 1 EPA 200.8 01/26/2016 01:22 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/26/201615:53 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/26/2016 09:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: MW-20A Collection Date: 21-Jan-16 11:10 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.126 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 13 mg/L 1 Sulfate 180 mg/L 2.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.753 mg/L 0.005 Barium (Ba) 0.037 mg/L 0.005 Boron (B) 0.613 mg/L 0.05 Iron (Fe) 6.72 mg/L 0.01 Manganese (Mn) 4.61 mg/L 0.005 Strontium (Sr) 0.261 mg/L 0.005 Zinc (Zn) 0.022 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 32.9 mg/L 0.01 Magnesium (Mg) 11.4 mg/L 0.005 Potassium (K) 2.50 mg/L 0.1 Sodium (Na) 12.4 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 1.80 mg/L 0.005 Barium (Ba) 0.039 mg/L 0.005 Boron (B) 0.625 mg/L 0.05 Iron (Fe) 7.11 mg/L 0.01 Manganese (Mn) 4.61 mg/L 0.005 Strontium (Sr) 0.269 mg/L 0.005 Zinc (Zn) 0.008 mg/L 0.005 Sample #: 2016002238 Matrix: GW WW Page 24 of 60 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:53 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/26/2016 18:40 BGN9034 25 EPA 300.0 01/26/2016 18:40 BGN9034 1 EPA 245.1 01/26/2016 19:56 ACPAYNE 1 EPA 245.1 01/29/2016 15:49 ACPAYNE 1 EPA 200.7 01/25/2016 10:58 FCJORDA 1 EPA 200.7 01/25/2016 10:58 FCJORDA 1 EPA 200.7 01/25/2016 10:58 FCJORDA 1 EPA 200.7 01/25/2016 10:58 FCJORDA 1 EPA 200.7 01/25/2016 10:58 FCJORDA 1 EPA 200.7 01/25/2016 10:58 FCJORDA 1 EPA 200.7 01/25/2016 10:58 FCJORDA 1 EPA 200.7 01/25/2016 13:52 FCJORDA 1 EPA 200.7 01/25/2016 13:52 FCJORDA 1 EPA 200.7 01/25/2016 13:52 FCJORDA 1 EPA 200.7 01/25/2016 13:52 FCJORDA 1 EPA 200.7 01/26/2016 11:10 FCJORDA 1 EPA 200.7 01/26/2016 11:10 FCJORDA 1 EPA 200.7 01/26/2016 11:10 FCJORDA 1 EPA 200.7 01/26/2016 11:10 FCJORDA 1 EPA 200.7 01/26/2016 11:10 FCJORDA 1 EPA 200.7 01/26/2016 11:10 FCJORDA 1 EPA 200.7 01/26/2016 11:10 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: MW-20A Collection Date: 21-Jan-16 11:10 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) 1.55 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 33.1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 9.04 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) 1.57 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 33.8 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 9.30 ug/L 1 Selenium (Se) 1.19 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 300 mg/L 25 Total Carbon TOC 1.6 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 7.0 mg/L 5 Page 25 of 60 Sample #: 2016002238 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 23:10 MHALL3 1 EPA 200.8 01/25/2016 23:10 MHALL3 1 EPA 200.8 01/25/2016 23:10 MHALL3 1 EPA 200.8 01/25/2016 23:10 MHALL3 1 EPA 200.8 01/25/2016 23:10 MHALL3 1 EPA 200.8 01/25/2016 23:10 MHALL3 1 EPA 200.8 01/25/2016 23:10 MHALL3 1 EPA 200.8 01/25/2016 23:10 MHALL3 1 EPA 200.8 01/25/2016 23:10 MHALL3 1 EPA 200.8 01/25/2016 23:10 MHALL3 1 EPA 200.8 01/25/2016 23:10 MHALL3 1 EPA 200.8 01/25/2016 23:10 MHALL3 1 EPA 200.8 01/25/2016 23:10 MHALL3 1 EPA 200.8 01/26/2016 02:01 MHALL3 1 EPA 200.8 01/26/2016 02:01 MHALL3 1 EPA 200.8 01/26/2016 02:01 MHALL3 1 EPA 200.8 01/26/2016 02:01 MHALL3 1 EPA 200.8 01/26/2016 02:01 MHALL3 1 EPA 200.8 01/26/2016 02:01 MHALL3 1 EPA 200.8 01/26/2016 02:01 MHALL3 1 EPA 200.8 01/26/2016 02:01 MHALL3 1 EPA 200.8 01/26/2016 02:01 MHALL3 1 EPA 200.8 01/26/2016 02:01 MHALL3 1 EPA 200.8 01/26/2016 02:01 MHALL3 1 EPA 200.8 01/26/2016 02:01 MHALL3 1 EPA 200.8 01/26/2016 02:01 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/26/201615:53 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/26/2016 09:45 CJELLIO Certificate of Laboratory Analysis Page 26 of 60 This report shall not be reproduced, except in full. Order # J16010461 Site: Filter Blank Collection Date: 21-Jan-16 2:39 PM Analyte Result Units Qualifiers RDL Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2016002239 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 245.1 01/29/2016 15:52 ACPAYNE 1 EPA 200.7 01/25/2016 11:02 FCJORDA 1 EPA 200.7 01/25/2016 11:02 FCJORDA 1 EPA 200.7 01/25/2016 11:02 FCJORDA 1 EPA 200.7 01/25/2016 11:02 FCJORDA 1 EPA 200.7 01/25/2016 11:02 FCJORDA 1 EPA 200.7 01/25/2016 11:02 FCJORDA 1 EPA 200.7 01/25/2016 11:02 FCJORDA 1 EPA 200.8 01/25/2016 23:49 MHALL3 1 EPA 200.8 01/25/2016 23:49 MHALL3 1 EPA 200.8 01/25/2016 23:49 MHALL3 1 EPA 200.8 01/25/2016 23:49 MHALL3 1 EPA 200.8 01/25/2016 23:49 MHALL3 1 EPA 200.8 01/25/2016 23:49 MHALL3 1 EPA 200.8 01/25/2016 23:49 MHALL3 1 EPA 200.8 01/25/2016 23:49 MHALL3 1 EPA 200.8 01/25/2016 23:49 MHALL3 1 EPA 200.8 01/25/2016 23:49 MHALL3 1 EPA 200.8 01/25/2016 23:49 MHALL3 1 EPA 200.8 01/25/2016 23:49 MHALL3 1 EPA 200.8 01/25/2016 23:49 MHALL3 Certificate of Laboratory Analysis Page 27 of 60 This report shall not be reproduced, except in full. Order # J16010461 Site: Equipment Blank Collection Date: 21-Jan-16 2:39 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALCI - (Analvsis Performed by Pace Laboratories Vendor Parameter Complete INORGANIC IONS BY IC Chloride < 0.1 mg/L 0.1 Sulfate < 0.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 UNDIGESTED METALS BY ICP Calcium (Ca) < 0.01 mg/L 0.01 Magnesium (Mg) < 0.005 mg/L 0.005 Potassium (K) < 0.1 mg/L 0.1 Sodium (Na) < 0.05 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2016002240 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:59 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/25/2016 22:21 BGN9034 1 EPA 300.0 01/25/2016 22:21 BGN9034 1 EPA 245.1 01/26/2016 19:58 ACPAYNE 1 EPA 200.7 01/25/2016 13:56 FCJORDA 1 EPA 200.7 01/25/2016 13:56 FCJORDA 1 EPA 200.7 01/25/2016 13:56 FCJORDA 1 EPA 200.7 01/25/2016 13:56 FCJORDA 1 EPA 200.7 01/26/2016 11:23 FCJORDA 1 EPA 200.7 01/26/2016 11:23 FCJORDA 1 EPA 200.7 01/26/2016 11:23 FCJORDA 1 EPA 200.7 01/26/2016 11:23 FCJORDA 1 EPA 200.7 01/26/2016 11:23 FCJORDA 1 EPA 200.7 01/26/2016 11:23 FCJORDA 1 EPA 200.7 01/26/2016 11:23 FCJORDA 1 EPA 200.8 01/26/2016 02:06 MHALL3 1 EPA 200.8 01/26/2016 02:06 MHALL3 1 EPA 200.8 01/26/2016 02:06 MHALL3 1 EPA 200.8 01/26/2016 02:06 MHALL3 1 EPA 200.8 01/26/2016 02:06 MHALL3 1 EPA 200.8 01/26/2016 02:06 MHALL3 1 EPA 200.8 01/26/2016 02:06 MHALL3 1 EPA 200.8 01/26/2016 02:06 MHALL3 1 EPA 200.8 01/26/2016 02:06 MHALL3 1 EPA 200.8 01/26/2016 02:06 MHALL3 1 EPA 200.8 01/26/2016 02:06 MHALL3 1 EPA 200.8 01/26/2016 02:06 MHALL3 1 EPA 200.8 01/26/2016 02:06 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010461 Site: Equipment Blank Collection Date: 21-Jan-16 2:39 PM Analyte Result Units Qualifiers RDL DF METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 Total Carbon Page 28 of 60 Sample #: 2016002240 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE SM2540C 01/26/201615:53 CJELLIO TOC 0.113 mg/L 0.1 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 01/26/2016 09:45 CJELLIO aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i�c&fir&e. Suite 100 �J Huntersville, INC 28078 (704)875-9092 January 28, 2016 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 16010461 Pace Project No.: 92283994 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on January 25, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Program Manager, Duke Energy Anne Pifer Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 31 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. OQ9K3i SW. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J16010461 Pace Project No.: 92283994 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 525 N 8th Street, Salina, KS 67401 A21-A Certification M 2926.01 Alaska Certification M UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification M 88-0680 California Certification M 01155CA Colorado Certification #Pace Connecticut Certification M PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification M 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification M 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification M 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification M 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification M E83079 Georgia Certification M 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification M 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification M E-10383 Kentucky Certification #: 90050 Louisiana Certification M FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification M Cert 0074 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification M TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification M 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098niy fir&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J16010461 Pace Project No.: 92283994 Lab ID Sample ID Matrix Date Collected Date Received 92283994001 2016002228 Water 01/20/1617:40 01/25/1611:07 92283994002 2016002229 Water 01/21/1610:13 01/25/1611:07 92283994003 2016002230 Water 01/21/1611:15 01/25/1611:07 92283994004 2016002231 Water 01/21/1612:01 01/25/1611:07 92283994005 2016002232 Water 01/21/1612:13 01/25/1611:07 92283994006 2016002233 Water 01/21/1613:01 01/25/1611:07 92283994007 2016002234 Water 01/21/1612:20 01/25/1611:07 92283994008 2016002235 Water 01/21/1611:37 01/25/1611:07 92283994009 2016002236 Water 01/21/1610:30 01/25/1611:07 92283994010 2016002237 Water 01/21/1612:20 01/25/1611:07 92283994011 2016002238 Water 01/21/1611:10 01/25/1611:07 92283994012 2016002240 Water 01/21/1614:39 01/25/1611:07 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnfir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J16010461 92283994 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92283994001 2016002228 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283994002 2016002229 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283994003 2016002230 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283994004 2016002231 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283994005 2016002232 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283994006 2016002233 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283994007 2016002234 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283994008 2016002235 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283994009 2016002236 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283994010 2016002237 RSK 175 STV 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnfir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J16010461 Pace Project No.: 92283994 Analytes Lab ID Sample ID Method Analysts Reported Laboratory SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283994011 2016002238 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283994012 2016002240 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K3i�c&fir&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J16010461 92283994 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92283994001 2016002228 SM 2320B Alkalinity, Bicarbonate (CaCO3) 19.7 mg/L 5.0 01/26/16 12:41 SM 2320B Alkalinity, Total as CaCO3 19.7 mg/L 5.0 01/26/16 12:41 EPA218.7 Chromium, Hexavalent 0.050 ug/L 0.030 01/28/1610:36 M1 92283994002 2016002229 SM 2320B Alkalinity, Bicarbonate (CaCO3) 394 mg/L 5.0 01/26/16 13:18 SM 2320B Alkalinity, Total as CaCO3 394 mg/L 5.0 01/26/16 13:18 92283994003 2016002230 SM 2320B Alkalinity, Bicarbonate (CaCO3) 51.2 mg/L 5.0 01/26/16 13:34 SM 2320B Alkalinity, Total as CaCO3 51.2 mg/L 5.0 01/26/16 13:34 92283994004 2016002231 RSK 175 Methane 26.8 ug/L 10.0 01/27/16 14:54 SM 2320B Alkalinity, Bicarbonate (CaCO3) 524 mg/L 5.0 01/26/16 13:46 SM 2320B Alkalinity, Total as CaCO3 524 mg/L 5.0 01/26/16 13:46 92283994005 2016002232 RSK 175 Methane 13.0 ug/L 10.0 01/27/16 15:03 92283994006 2016002233 SM 2320B Alkalinity, Bicarbonate (CaCO3) 43.5 mg/L 5.0 01/26/16 14:12 SM 2320B Alkalinity, Total as CaCO3 43.5 mg/L 5.0 01/26/16 14:12 92283994007 2016002234 SM 2320B Alkalinity, Bicarbonate (CaCO3) 14.1 mg/L 5.0 01/26/16 14:43 SM 2320B Alkalinity, Total as CaCO3 14.1 mg/L 5.0 01/26/16 14:43 EPA218.7 Chromium, Hexavalent 0.20 ug/L 0.030 01/28/1611:41 92283994008 2016002235 EPA218.7 Chromium, Hexavalent 0.12 ug/L 0.060 01/28/1611:54 92283994009 2016002236 SM 2320B Alkalinity, Bicarbonate (CaCO3) 38.3 mg/L 5.0 01/26/16 15:02 SM 2320B Alkalinity, Total as CaCO3 38.3 mg/L 5.0 01/26/16 15:02 EPA218.7 Chromium, Hexavalent 0.068 ug/L 0.060 01/28/1612:07 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnfir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010461 Pace Project No.: 92283994 Method: RSK 175 Description: RSK 175 AIR Headspace Client: Duke Energy Date: January 28, 2016 General Information: 12 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnfir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010461 Pace Project No.: 92283994 Method: SM 2320B Description: 2320E Alkalinity Client: Duke Energy Date: January 28, 2016 General Information: 12 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WET/42677 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92283994001,92283994011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1653211) • Alkalinity, Total as CaCO3 • MSD (Lab ID: 1653212) • Alkalinity, Total as CaCO3 Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098v�c&fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010461 Pace Project No.: 92283994 Method: SM 4500-S213 Description: 4500S2D Sulfide Water Client: Duke Energy Date: January 28, 2016 General Information: 12 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnfir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010461 Pace Project No.: 92283994 Method: EPA 218.7 Description: Hexavalent Chromium by IC Client: Duke Energy Date: January 28, 2016 General Information: 12 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/54288 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92283994001,92283994011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1460290) • Chromium. Hexavalent Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnfir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010461 Pace Project No.: 92283994 Sample: 2016002228 Lab ID: 92283994001 Collected: 01/20/16 17:40 Received: 01/25/16 11:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/27/1614:30 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 19.7 mg/L 5.0 1 01/26/16 12:41 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/26/16 12:41 Alkalinity, Total as CaCO3 19.7 mg/L 5.0 1 01/26/16 12:41 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.050 ug/L 0.030 1 01/28/16 10:36 18540-29-9 M1 Date: 01/28/2016 05:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwnfir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010461 Pace Project No.: 92283994 Sample: 2016002229 Lab ID: 92283994002 Collected: 01/21/16 10:13 Received: 01/25/16 11:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/27/1614:38 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 394 mg/L 5.0 1 01/26/16 13:18 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/26/16 13:18 Alkalinity, Total as CaCO3 394 mg/L 5.0 1 01/26/16 13:18 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/27/16 15:23 18540-29-9 Date: 01/28/2016 05:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwiy fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010461 Pace Project No.: 92283994 Sample: 2016002230 Lab ID: 92283994003 Collected: 01/21/16 11:15 Received: 01/25/16 11:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/27/1614:46 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 51.2 mg/L 5.0 1 01/26/16 13:34 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/26/16 13:34 Alkalinity, Total as CaCO3 51.2 mg/L 5.0 1 01/26/16 13:34 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/27/16 15:36 18540-29-9 Date: 01/28/2016 05:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oi�c&w. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010461 Pace Project No.: 92283994 Sample: 2016002231 Lab ID: 92283994004 Collected: 01/21/16 12:01 Received: 01/25/16 11:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 26.8 ug/L 10.0 1 01/27/1614:54 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 524 mg/L 5.0 1 01/26/16 13:46 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/26/16 13:46 Alkalinity, Total as CaCO3 524 mg/L 5.0 1 01/26/16 13:46 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.060 2 01/28/16 11:15 18540-29-9 Date: 01/28/2016 05:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8w. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010461 Pace Project No.: 92283994 Sample: 2016002232 Lab ID: 92283994005 Collected: 01/21/16 12:13 Received: 01/25/16 11:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 13.0 ug/L 10.0 1 01/27/1615:03 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/26/16 14:05 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/26/16 14:05 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/26/16 14:05 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.060 2 01/28/16 11:28 18540-29-9 Date: 01/28/2016 05:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g%c&fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010461 Pace Project No.: 92283994 Sample: 2016002233 Lab ID: 92283994006 Collected: 01/21/16 13:01 Received: 01/25/16 11:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/27/1615:11 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 43.5 mg/L 5.0 1 01/26/16 14:12 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/26/16 14:12 Alkalinity, Total as CaCO3 43.5 mg/L 5.0 1 01/26/16 14:12 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/27/16 16:15 18540-29-9 Date: 01/28/2016 05:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8w. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010461 Pace Project No.: 92283994 Sample: 2016002234 Lab ID: 92283994007 Collected: 01/21/16 12:20 Received: 01/25/16 11:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/27/1615:19 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 14.1 mg/L 5.0 1 01/26/16 14:43 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/26/16 14:43 Alkalinity, Total as CaCO3 14.1 mg/L 5.0 1 01/26/16 14:43 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.20 ug/L 0.030 1 01/28/16 11:41 18540-29-9 Date: 01/28/2016 05:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8w. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010461 Pace Project No.: 92283994 Sample: 2016002235 Lab ID: 92283994008 Collected: 01/21/16 11:37 Received: 01/25/16 11:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/27/1615:27 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/26/16 14:54 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/26/16 14:54 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/26/16 14:54 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.12 ug/L 0.060 2 01/28/16 11:54 18540-29-9 Date: 01/28/2016 05:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8w. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010461 Pace Project No.: 92283994 Sample: 2016002236 Lab ID: 92283994009 Collected: 01/21/16 10:30 Received: 01/25/16 11:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/27/1615:55 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 38.3 mg/L 5.0 1 01/26/16 15:02 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/26/16 15:02 Alkalinity, Total as CaCO3 38.3 mg/L 5.0 1 01/26/16 15:02 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.068 ug/L 0.060 2 01/28/16 12:07 18540-29-9 Date: 01/28/2016 05:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8w. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010461 Pace Project No.: 92283994 Sample: 2016002237 Lab ID: 92283994010 Collected: 01/21/16 12:20 Received: 01/25/16 11:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/27/1616:12 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/26/16 15:14 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/26/16 15:14 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/26/16 15:14 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/27/16 17:07 18540-29-9 Date: 01/28/2016 05:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8w. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010461 Pace Project No.: 92283994 Sample: 2016002238 Lab ID: 92283994011 Collected: 01/21/16 11:10 Received: 01/25/16 11:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/27/1616:20 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/26/16 15:20 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/26/16 15:20 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/26/16 15:20 M1 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/27/16 17:46 18540-29-9 Date: 01/28/2016 05:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onfir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010461 Pace Project No.: 92283994 Sample: 2016002240 Lab ID: 92283994012 Collected: 01/21/16 14:39 Received: 01/25/16 11:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/27/1616:28 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/26/16 15:53 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/26/16 15:53 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/26/16 15:53 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.060 2 01/28/16 12:20 18540-29-9 Date: 01/28/2016 05:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oy fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010461 Pace Project No.: 92283994 QC Batch: AIR/25094 Analysis Method: RSK 175 QC Batch Method: RSK 175 Analysis Description: RSK 175 AIR HEADSPACE Associated Lab Samples: 92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007, 92283994008,92283994009,92283994010,92283994011,92283994012 METHOD BLANK: 2181048 Matrix: Water Associated Lab Samples: 92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007, 92283994008,92283994009,92283994010,92283994011,92283994012 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Methane ug/L ND 10.0 01/27/1613:53 LABORATORY CONTROL SAMPLE & LCSD: 2181049 2181050 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Methane ug/L 60.7 56.1 54.9 93 91 85-115 2 20 SAMPLE DUPLICATE: 2182260 92283997001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 1.5J 20 SAMPLE DUPLICATE: 2182261 92283994009 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 1.3J 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/28/2016 05:10 PM without the written consent of Pace Analytical Services, Inc.. Page 23 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onfir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010461 Pace Project No.: 92283994 QC Batch: WET/42677 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007, 92283994008,92283994009,92283994010,92283994011,92283994012 METHOD BLANK: 1653207 Matrix: Water Associated Lab Samples: 92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007, 92283994008,92283994009,92283994010,92283994011,92283994012 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Alkalinity, Carbonate (CaCO3) mg/L ND 5.0 01/26/16 12:20 Alkalinity, Total as CaCO3 mg/L ND 5.0 01/26/16 12:20 Alkalinity, Bicarbonate (CaCO3) mg/L ND 5.0 01/26/16 12:20 LABORATORY CONTROL SAMPLE: 1653208 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 48.5 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1653209 1653210 MS MSD 92283994001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Alkalinity, Total as CaCO3 mg/L 19.7 50 50 67.7 67.2 96 95 80-120 1 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1653211 1653212 MS MSD 92283994011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L ND 50 50 41.7 42.2 75 75 80-120 1 25 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/28/2016 05:10 PM without the written consent of Pace Analytical Services, Inc.. Page 24 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnfir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010461 Pace Project No.: 92283994 QC Batch: WET/42680 Analysis Method: SM 4500-S2D QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007, 92283994008,92283994009,92283994010,92283994011,92283994012 METHOD BLANK: 1653324 Matrix: Water Associated Lab Samples: 92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007, 92283994008,92283994009,92283994010,92283994011,92283994012 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide mg/L ND 0.10 01/26/1612:00 LABORATORY CONTROL SAMPLE: 1653325 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide mg/L .5 0.51 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1653326 1653327 MS MSD 92283997001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Sulfide mg/L ND .5 .5 0.50 0.50 99 99 90-110 0 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1653328 1653329 MS MSD 92283994001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Sulfide mg/L ND .5 .5 0.54 0.54 108 108 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/28/2016 05:10 PM without the written consent of Pace Analytical Services, Inc.. Page 25 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�Iji�c&fir&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010461 Pace Project No.: 92283994 QC Batch: WETA/54288 Analysis Method: EPA 218.7 QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC Associated Lab Samples: 92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007, 92283994008,92283994009,92283994010,92283994011,92283994012 METHOD BLANK: 1460288 Matrix: Water Associated Lab Samples: 92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007, 92283994008,92283994009,92283994010,92283994011,92283994012 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chromium, Hexavalent ug/L ND 0.030 01/27/16 14:18 LABORATORY CONTROL SAMPLE: 1460289 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chromium, Hexavalent ug/L .075 0.080 106 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1460290 1460291 MS MSD 92283994001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Chromium, Hexavalent ug/L 0.050 .025 .025 0.069 0.072 75 88 85-115 4 20 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1460292 1460293 MS MSD 92283994011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Chromium, Hexavalent ug/L ND .075 .075 0.068 0.067 91 89 85-115 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/28/2016 05:10 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnfir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J16010461 Pace Project No.: 92283994 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS H1 Analysis conducted outside the EPA method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/28/2016 05:10 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 31 acmnalytical www.pacelabs.com Pace Analytical Services, Inc. og6g I�gc&f646e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J16010461 Pace Project No.: 92283994 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92283994001 2016002228 RSK 175 AIR/25094 92283994002 2016002229 RSK 175 AIR/25094 92283994003 2016002230 RSK 175 AIR/25094 92283994004 2016002231 RSK 175 AIR/25094 92283994005 2016002232 RSK 175 AIR/25094 92283994006 2016002233 RSK 175 AIR/25094 92283994007 2016002234 RSK 175 AIR/25094 92283994008 2016002235 RSK 175 AIR/25094 92283994009 2016002236 RSK 175 AIR/25094 92283994010 2016002237 RSK 175 AIR/25094 92283994011 2016002238 RSK 175 AIR/25094 92283994012 2016002240 RSK 175 AIR/25094 92283994001 2016002228 SM 2320B WET/42677 92283994002 2016002229 SM 2320B WET/42677 92283994003 2016002230 SM 2320B WET/42677 92283994004 2016002231 SM 2320B WET/42677 92283994005 2016002232 SM 2320B WET/42677 92283994006 2016002233 SM 2320B WET/42677 92283994007 2016002234 SM 2320B WET/42677 92283994008 2016002235 SM 2320B WET/42677 92283994009 2016002236 SM 2320B WET/42677 92283994010 2016002237 SM 2320B WET/42677 92283994011 2016002238 SM 2320B WET/42677 92283994012 2016002240 SM 2320B WET/42677 92283994001 2016002228 SM 4500-S2D WET/42680 92283994002 2016002229 SM 4500-S2D WET/42680 92283994003 2016002230 SM 4500-S2D WET/42680 92283994004 2016002231 SM 4500-S2D WET/42680 92283994005 2016002232 SM 4500-S2D WET/42680 92283994006 2016002233 SM 4500-S2D WET/42680 92283994007 2016002234 SM 4500-S2D WET/42680 92283994008 2016002235 SM 4500-S2D WET/42680 92283994009 2016002236 SM 4500-S2D WET/42680 92283994010 2016002237 SM 4500-S2D WET/42680 92283994011 2016002238 SM 4500-S2D WET/42680 92283994012 2016002240 SM 4500-S2D WET/42680 92283994001 2016002228 EPA 218.7 WETA/54288 92283994002 2016002229 EPA 218.7 WETA/54288 92283994003 2016002230 EPA 218.7 WETA/54288 92283994004 2016002231 EPA 218.7 WETA/54288 92283994005 2016002232 EPA 218.7 WETA/54288 92283994006 2016002233 EPA 218.7 WETA/54288 92283994007 2016002234 EPA 218.7 WETA/54288 92283994008 2016002235 EPA 218.7 WETA/54288 92283994009 2016002236 EPA 218.7 WETA/54288 92283994010 2016002237 EPA 218.7 WETA/54288 92283994011 2016002238 EPA 218.7 WETA/54288 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /28/2016 05:10 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 31 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g".8w. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J16010461 Pace Project No.: 92283994 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92283994012 2016002240 EPA 218.7 W ETA/54288 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/28/2016 05:10 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 31 Document Name: Document Revised: 260CT2015 11�Sample aceAnalytical Condition Upon Receipt(SCUR) Page 1 of 2 Document No,: Issuing Authority: F-CHR-CS-003-rev.17 Pace Huntersville Quality Office Client Name: Project#: " l,. Courier: Fed x ❑ ❑UPS ❑LISPS ©Client ❑Commercial ❑Pace ❑Other: Custody Seal on Cooler/Box Present? Packing Material: OBbbl Wra p WO#:91283994 11111111111111111111111 ❑Yes ❑No Seals Intact? ❑Yes ❑No ❑Bubble Bags ❑None ❑other: Thermometer 0 1505 Used: Type of Ice: ❑ We[ []Blue ❑None .[]Samples on ice, cooling process has begun Cooler Temp Corrected ('C): Biological Tissue Frozen? ❑Yes ❑No :. - ❑N A" Temp should be above freezing to VC Correction Factor: 0.0 °C Date and Initials of Person Examining Contents: USDA Regulated Soil (❑ N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate froT a.foreign source (internationally,, f� ❑Yes ❑No including Hawaii and Puerto Rico)? []Yes No If Yes to either question, fill out a Regulated Soil Checklist and Include with SOUR/COC paperwork. COMMENTS: Chain of Custody Present? des _- [--]No []N/A 1. Chain of Custody Filled Out? r Yes E]No ❑N/A 2. Chain of Custody Relinquished? 0 es EINo ❑N/A 3. Sampler Name and/or Signature on COC? [3a /❑No ❑N/A 4. Samples Arrived within Hold Time? El Yes_-- ❑No ❑N/A 5. Short Hold Time Analysis (<72 hr)? ❑Yes No ❑N/A 6. Rush Turn Around Time Requested? 0 5, o [�N/ 7, Sufficient Volume? Yes ❑No []N/A 8. Correct Containers Used? [-']Yes []No ❑N/A 9. • Pace Containers Used? []Yes []No ❑N/A Containers Intact? ❑ eY s ❑No ❑N/A 10, Filtered Volume Received for Dissolved Tests? ❑Yes ❑No ❑ N/A 11. Note if sediment is visible In the dissolved container Sample Labels Match COC? []Yeses [:]No❑N/A 12. „� j LC -Includes Date/Time/ID/Analysis Matrix: All containers needing ac€d/base preservation have been checked? [ eY s ❑No ❑N/A 13 All containers needing preservation are found to be in j compliance with EPA recommendation? (HNO3, H2SO4, HCk2; NaOH >9 Sulfide, NaOH>12 Cyanide) ❑Yes ❑No ❑N/A Exceptions: VOA, Coliform, TOC, Oil and Grease, / DRO/8015 (water) DOC,LLHg [1 Yes ❑No ❑N/ Samples checked for dechlorization ❑Yes []No EJN A 14, Headspace in VOA Vials (>5-6mm)? ❑Yes ❑No N/. 15. Trip Blank Present? ❑Yes ❑No N/ , 16. Trip Blank Custody Seals Present? [-]Yes [:]No ❑N/A Pace Trip Blank Lot # (if purchased): CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Project Manager SCURF Review: -J1r, Note: Whenever there is a discrepancy affecting North Carolina hold, incorrect preservative, out of temp, incorrect containers). Field Data Required? ❑Yes ❑No Date/Time: Date: I t tl nce samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. but of Page 30 of 31 ----•-----._.---._-._.-,_---_._ _ CHAIN CF CUSTODY RECORD AND ANALYSIS REQUEST =OR'f Duke Energy Duke EncrgyAr�alytit:al Latiolatory--� r--•-•---------•------•-•-•-------------•---•-•-------•---•-------..,._._.------•-•-------.._._._._ gy r ' Analytical Lobo rato Use Onl Analytical Laboratory Mail Cod, MG@3A2 (Buildigr4osi i iOrder #-- / triz GW 4VW NC 13379 Heger. furry Rd i i �� 1" s.rn,H. aWi�++mq From SC Chain or Custody 8 Hunte ift. N. C. 28 0 79 i ' Sample Log 17a,1 576S2aa' i iLoggea B- Dace 8 T�irYe - _ Fe.:jlagerosose .1/�-'r SAMPLE PROGRAM Project Name AB GW Assessm nt water Phase$lwell_sj Phan, N,: Client SynTerra 980-875-5D32 Business Unit: Proce.a: Rmp, Center To: Prejoet ID: ActMtf to: Mail Cud.: MG03A3 w.e,rhddy: st.tt.e: ASHEVILLE .._..ComdrGround Water_ NPDES_ j—n' . /P.StiDrinking Water LIST _ {}� RCRA Waste _'_om.•_.. ..--._.-_.._.-_.._. _..--'---...-.-_.-_.._.._. i r1. ^ ', t Filtration (0.45 um) j3 : Ell � ? t tlnfiitered Preservative Ice Ice Ic. 81-1 Ice Container Volume (mL) 2000 40 ml 300 .1. 500 500 Container Type PET glass PET PET PET PET Sample Description or ID Customer to com loto alla P PPropria[c U) vYr d �._ i y c non -shaded areas. ❑ m rrll '� .-. z �, c m m E i Collection information GaPS Location i Date Time Signature a v T a [n h -• r. M- _- U U' •C d ... F- Z - = v m a m 9> ._ tt1 E I m .3� CSr!L1-7 -Zl-l� f 1 Z c2 -3 �' J ' W = C� � I� ZI-I(c /Z 4 t --7_ 1Zi3 a,,/ a <-S-(7�GS1.. -Z/-l/ lZZ-7c -r...odt:- ''� ! z r l 1-24-IE 2 t r iI l i i Filter Blank (-Lf-14 fg3ef ;;01. �! F Euipment Blank (-Zt`-J� i 1• i I i Y 4ui omnr to Sion Bate be ow TOTAL .Rol-Inq, shell By Dratefrlmo Accepted By: Z1 2 1 1 1 1 1 1 1 1 & 1 4 1 i I a l & 1 X 1 0 tool Relingdished By Dateffime Accept etl Sy. --� ! a i DatarTlm / 'r- � �y Relinqulshetl ey OatefTlme Acce , Date e S 1 �' DatelTlme ealedlL ck Opened By _��' DatefTlme -, - J moms ELEMENTS y ICP_MS (TRM): As, Be. Cd, Co. Cr, Cu,' Ni, Pb, Sb, Se, Tl (LL), V (LL) - - ELEMENTS by ICP (TRM): Al, So. B, Fe, Mn, Sr, Zn _�--- -:'= nlved metals : all metals ICP, ]MS,Hg ICP Undigested Ca, Mg, K, No Hg by 245.1 0 I Page 59 of 60 SVllterra cDD Page _1_ of DISTRIBUTION �C /- j ORIGINAL to LAB, COPY to CLIENT 1�]'/J '� i i Il ll. t COC REV DATE 1/22/2015 i ntmrcd 250 500 500I 500 ..�,. HDPE HDPE HOPE HOPE 0 I Requested Turnaround I Total ii o? *14 Days m a .. c " 7 Days of ? c o� 0. E 'us 48 Hr E C, 'Other ASAP U Add. Cost Will Apply Duke Energy Analytical Laboratory Chain of Custody b i Sample Log - i - ! Pro}ect Hama -- - AB GW A' ph se 4 Client SynTerra 6 a —mess Unit: i - - - - - - - CHAIN OF CUSTODY RECORD AND A_ NALYSIS REQUEST FORM_ _ _--_-_-- I Synterra EDI --I Anal ical LaboratoryUse Only- i Page 6Fdy-e 60 of 60 Duke Energy Analytical Laboratory i iOrder �d �Ix GW_WW NC_ SamplesOri9lnatlpFrom SC_ _,_ DISTRIBUTION Mail Coda MG03A2 (Buildin9 7405) t3339 He9ara Ferry ad 1 i Date g ey1� e /�(,1jG SAMPLE PROGRAM ; ORIGINAL to LAB, COPY to CLIENT Hunteraville, N. C. 28078 iLOg98d ( / ✓ 1 Ground Water NP S (704) 875L245 I:Ven� _ LIST Drinking Water_ UST_ Fax_}704j 875-6038-----_.----- - - �t • {/ i RCRA Waste C C REV DATE 1122/2015 '------- e No: m nt Water C 1 3ti or 7I _ Cooler em C . .-_..-..-.._..............----.._.._.. _.. _.._.._.._. - - - ----- -�1--1 - No: ! C 11".0— m As; umt 11 Unfiltered filtered Process: n Activity ID: I Samp e1 Del Descriptio GP5 L . A6M 6M1, F Eul 10-875-511dc ! Ell I``w i 14LUO l IWAmm i Y9 4 bp. Center To: Preservative Ice lee Ice Hlee ,,,„,,,, a„ a,,,,,,• ••• , 250 500 500 500 ail coca: Container Volume (ML) 2000 40 ml 300 125 500 500 HDPE HOPE HOPE HOPE iGO3A3 Container Type PET glass PET PET PET PET VILLE tr2 a c .•. Y a r �' i or ID Customer to complete all appropriate rn _ m w E non -shaded areas. p w; O Z f ccL a Collection Information c C U) ^ V1 UO Y$ W 7cation Date Time SI nat re O - o,4 17 lZ1�( I I 1 -LI-I IZZo q5l /-zr-l� II3� o g r,i-Zi-/(v la3o I 1 72- 1-t1-1� fl to � i 2 1 I 1 1 1 1 l �• , 0 0 0 Blank liter Blank (-u-1. H3 t pment 0 0 TOTAL A d 5 i 0 0 0 ii ♦ 6 J us omer o s n a e a ow Accepted By: Date/Time D!atelTime / Y l DateRlme Accepted By. Dat BY �� 7✓ i �/ J, Acce � Date I a DateRlme / 1% � —Z ealedll. ck Opened By DatelTime DateRlme IBy S by ICP_MS (TRM): As, Be, Cd, Co, Cr, Cu, Mo, Ni, Pb, Sb, Se, TI (LL), V (LL) TRM): AI, Ba, B, We, Mn, Sr, Zn ICP_Undigested Ca, Mg, K, Na ELEMENTS by ICP (Hg by 245.1 ELEMENT _. —I.ed metals: all metals ICP, IMS,Hg ,�, Requested Turnaround Total it N c •14 Days ,93-4 c0 1E c 7 Days YC / � 0 c°� •48Hr E 'm o a, E *Other _ASAP `Add. Cost Will Apply U 0