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Home My WebLink AboutNC0000396_J16010397 Report_20160831DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report Order Number: J16010397 Project Name: ASHEVILLE - AB GW ASSESSMENT WATER Customer Name(s): Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu Customer Address: 200 CP and L Drive Arden,NC 28704 Lab Contact: Anne Pifer Phone: Digitally signed by Mary Ann Re ort Authorized B lJ� �— Ogle 2/5/2016 P Y V/J Date: 2016.02.0516:18:13 Date: (Signature)-05,00, Anne Pifer Program Comments: Please contact the Program Manager (Anne Pifer) with any questions regarding this report. Data Flags & Calculations: Page 1 of 81 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Page 2 of 81 Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2016001989 ASHEVILLE 20-Jan-16 9:34AM illegible AMW-1B 2016001990 ASHEVILLE 20-Jan-16 9:34 AM illegible AMW-1B DUP 2016001991 ASHEVILLE 20-Jan-16 10:49 AM illegible AMW-3B 2016001992 ASHEVILLE 20-Jan-16 1:28 PM illegible CB-01 2016001993 ASHEVILLE 20-Jan-16 2:16 PM illegible CB-01D 2016001994 ASHEVILLE 20-Jan-16 4:05 PM illegible MW-13D 2016001995 ASHEVILLE 20-Jan-16 3:52 PM illegible MW-13BR 2016001996 ASHEVILLE 20-Jan-16 11:22 AM illegible PZ-17S 2016001997 ASHEVILLE 20-Jan-16 3:20 PM illegible PZ-17D 2016001998 ASHEVILLE 20-Jan-16 11:16 AM illegible MW-3D 2016001999 ASHEVILLE 20-Jan-16 1:50 PM illegible MW-12D 2016002000 ASHEVILLE 20-Jan-16 4:40 PM illegible CB-08 2016002001 ASHEVILLE 20-Jan-16 3:28 PM illegible CB-08BR 2016002002 ASHEVILLE 20-Jan-16 12:33 PM illegible MW-08S 2016002003 ASHEVILLE 20-Jan-16 4:45 PM illegible Filter Blank 2016002004 ASHEVILLE 20-Jan-16 4:45 PM illegible Equipment Blank 2016002005 ASHEVILLE 20-Jan-16 11:03 AM illegible MW-09S 2016002006 ASHEVILLE 20-Jan-16 9:45 AM illegible MW-09D 2016002007 ASHEVILLE 20-Jan-16 9:20 AM illegible MW-09BR 19 Total Samples Page 3 of 81 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification ❑ Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report OV Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries ❑ Chain of Custody ❑ Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Mary Ann Ogle Date: 2/5/2016 Certificate of Laboratory Analysis Page 4 of 81 This report shall not be reproduced, except in full. Order # J16010397 Site: AMW-1 B Collection Date: 20-Jan-16 9:34 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.019 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 9.8 mg/L 0.5 Sulfate 120 mg/L 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.013 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) 0.396 mg/L 0.05 Iron (Fe) 6.78 mg/L 0.01 Manganese (Mn) 0.355 mg/L 0.005 Strontium (Sr) 0.083 mg/L 0.005 Zinc (Zn) 0.019 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 45.9 mg/L M4 0.01 Magnesium (Mg) 2.32 mg/L 0.005 Potassium (K) 1.98 mg/L 0.1 Sodium (Na) 21.2 mg/L M4 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.053 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) 0.393 mg/L 0.05 Iron (Fe) 8.11 mg/L 0.01 Manganese (Mn) 0.332 mg/L 0.005 Strontium (Sr) 0.083 mg/L 0.005 Zinc (Zn) 0.011 mg/L 0.005 Sample #: 2016001989 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:00 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/22/2016 02:49 BGN9034 50 EPA 300.0 01/22/2016 02:49 BGN9034 1 EPA 245.1 01/26/2016 18:11 ACPAYNE 1 EPA 245.1 01/27/2016 15:38 ACPAYNE 1 EPA 200.7 01/21/2016 10:49 FCJORDA 1 EPA 200.7 01/21/2016 10:49 FCJORDA 1 EPA 200.7 01/21/2016 10:49 FCJORDA 1 EPA 200.7 01/21/2016 10:49 FCJORDA 1 EPA 200.7 01/21/2016 10:49 FCJORDA 1 EPA 200.7 01/21/2016 10:49 FCJORDA 1 EPA 200.7 01/21/2016 10:49 FCJORDA 1 EPA 200.7 01/25/2016 11:27 FCJORDA 1 EPA 200.7 01/25/2016 11:27 FCJORDA 1 EPA 200.7 01/25/2016 11:27 FCJORDA 1 EPA 200.7 01/25/2016 11:27 FCJORDA 1 EPA 200.7 01/21/2016 17:11 FCJORDA 1 EPA 200.7 01/21/2016 17:11 FCJORDA 1 EPA 200.7 01/21/2016 17:11 FCJORDA 1 EPA 200.7 01/21/2016 17:11 FCJORDA 1 EPA 200.7 01/21/2016 17:11 FCJORDA 1 EPA 200.7 01/21/2016 17:11 FCJORDA 1 EPA 200.7 01/21/2016 17:11 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: AMW-1 B Collection Date: 20-Jan-16 9:34 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 2.02 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 2.12 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 250 mg/L 25 Total Carbon TOC 0.265 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 17 mg/L 5 Page 5 of 81 Sample #: 2016001989 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 19:50 MHALL3 1 EPA 200.8 01/25/2016 19:50 MHALL3 1 EPA 200.8 01/25/2016 19:50 MHALL3 1 EPA 200.8 01/25/2016 19:50 MHALL3 1 EPA 200.8 01/25/2016 19:50 MHALL3 1 EPA 200.8 01/25/2016 19:50 MHALL3 1 EPA 200.8 01/25/2016 19:50 MHALL3 1 EPA 200.8 01/25/2016 19:50 MHALL3 1 EPA 200.8 01/25/2016 19:50 MHALL3 1 EPA 200.8 01/25/2016 19:50 MHALL3 1 EPA 200.8 01/25/2016 19:50 MHALL3 1 EPA 200.8 01/25/2016 19:50 MHALL3 1 EPA 200.8 01/25/2016 19:50 MHALL3 1 EPA 200.8 01/22/2016 01:00 MHALL3 1 EPA 200.8 01/22/2016 01:00 MHALL3 1 EPA 200.8 01/22/2016 01:00 MHALL3 1 EPA 200.8 01/22/2016 01:00 MHALL3 1 EPA 200.8 01/22/2016 01:00 MHALL3 1 EPA 200.8 01/22/2016 01:00 MHALL3 1 EPA 200.8 01/22/2016 01:00 MHALL3 1 EPA 200.8 01/22/2016 01:00 MHALL3 1 EPA 200.8 01/22/2016 01:00 MHALL3 1 EPA 200.8 01/22/2016 01:00 MHALL3 1 EPA 200.8 01/22/2016 01:00 MHALL3 1 EPA 200.8 01/22/2016 01:00 MHALL3 1 EPA 200.8 01/22/2016 01:00 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis Page 6 of 81 This report shall not be reproduced, except in full. Order # J16010397 Site: AMW-1 B DUP Collection Date: 20-Jan-16 9:34 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.021 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 9.9 mg/L 0.5 Sulfate 130 mg/L 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.012 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) 0.401 mg/L 0.05 Iron (Fe) 6.62 mg/L 0.01 Manganese (Mn) 0.354 mg/L 0.005 Strontium (Sr) 0.083 mg/L 0.005 Zinc (Zn) 0.012 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 48.7 mg/L M4 0.01 Magnesium (Mg) 2.45 mg/L 0.005 Potassium (K) 2.08 mg/L 0.1 Sodium (Na) 22.2 mg/L M4 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.064 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) 0.402 mg/L 0.05 Iron (Fe) 7.58 mg/L 0.01 Manganese (Mn) 0.353 mg/L 0.005 Strontium (Sr) 0.083 mg/L 0.005 Zinc (Zn) 0.011 mg/L 0.005 Sample #: 2016001990 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:02 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/22/2016 03:05 BGN9034 50 EPA 300.0 01/22/2016 03:05 BGN9034 1 EPA 245.1 01/26/2016 18:14 ACPAYNE 1 EPA 245.1 01/27/2016 15:40 ACPAYNE 1 EPA 200.7 01/21/2016 11:00 FCJORDA 1 EPA 200.7 01/21/2016 11:00 FCJORDA 1 EPA 200.7 01/21/2016 11:00 FCJORDA 1 EPA 200.7 01/21/2016 11:00 FCJORDA 1 EPA 200.7 01/21/2016 11:00 FCJORDA 1 EPA 200.7 01/21/2016 11:00 FCJORDA 1 EPA 200.7 01/21/2016 11:00 FCJORDA 1 EPA 200.7 01/25/2016 11:38 FCJORDA 1 EPA 200.7 01/25/2016 11:38 FCJORDA 1 EPA 200.7 01/25/2016 11:38 FCJORDA 1 EPA 200.7 01/25/2016 11:38 FCJORDA 1 EPA 200.7 01/21/2016 17:23 FCJORDA 1 EPA 200.7 01/21/2016 17:23 FCJORDA 1 EPA 200.7 01/21/2016 17:23 FCJORDA 1 EPA 200.7 01/21/2016 17:23 FCJORDA 1 EPA 200.7 01/21/2016 17:23 FCJORDA 1 EPA 200.7 01/21/2016 17:23 FCJORDA 1 EPA 200.7 01/21/2016 17:23 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: AMW-1 B DUP Collection Date: 20-Jan-16 9:34 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 2.09 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 2.07 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 260 mg/L 25 Total Carbon TOC 0.279 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 15 mg/L 5 Page 7 of 81 Sample #: 2016001990 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 19:55 MHALL3 1 EPA 200.8 01/25/2016 19:55 MHALL3 1 EPA 200.8 01/25/2016 19:55 MHALL3 1 EPA 200.8 01/25/2016 19:55 MHALL3 1 EPA 200.8 01/25/2016 19:55 MHALL3 1 EPA 200.8 01/25/2016 19:55 MHALL3 1 EPA 200.8 01/25/2016 19:55 MHALL3 1 EPA 200.8 01/25/2016 19:55 MHALL3 1 EPA 200.8 01/25/2016 19:55 MHALL3 1 EPA 200.8 01/25/2016 19:55 MHALL3 1 EPA 200.8 01/25/2016 19:55 MHALL3 1 EPA 200.8 01/25/2016 19:55 MHALL3 1 EPA 200.8 01/25/2016 19:55 MHALL3 1 EPA 200.8 01/22/2016 00:40 MHALL3 1 EPA 200.8 01/22/2016 00:40 MHALL3 1 EPA 200.8 01/22/2016 00:40 MHALL3 1 EPA 200.8 01/22/2016 00:40 MHALL3 1 EPA 200.8 01/22/2016 00:40 MHALL3 1 EPA 200.8 01/22/2016 00:40 MHALL3 1 EPA 200.8 01/22/2016 00:40 MHALL3 1 EPA 200.8 01/22/2016 00:40 MHALL3 1 EPA 200.8 01/22/2016 00:40 MHALL3 1 EPA 200.8 01/22/2016 00:40 MHALL3 1 EPA 200.8 01/22/2016 00:40 MHALL3 1 EPA 200.8 01/22/2016 00:40 MHALL3 1 EPA 200.8 01/22/2016 00:40 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: AMW-3B Collection Date: 20-Jan-16 10:49 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.250 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 0.61 mg/L 0.1 Sulfate 1.3 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.007 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) 0.058 mg/L 0.005 Zinc (Zn) 0.008 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 6.15 mg/L 0.01 Magnesium (Mg) 1.85 mg/L 0.005 Potassium (K) 1.57 mg/L 0.1 Sodium (Na) 5.05 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.047 mg/L 0.005 Barium (Ba) 0.007 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.020 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) 0.058 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001991 Matrix: GW WW Page 8 of 81 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 12:57 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/22/2016 03:22 BGN9034 1 EPA 300.0 01/22/2016 03:22 BGN9034 1 EPA 245.1 01/26/2016 18:16 ACPAYNE 1 EPA 245.1 01/27/2016 15:43 ACPAYNE 1 EPA 200.7 01/21/2016 11:11 FCJORDA 1 EPA 200.7 01/21/2016 11:11 FCJORDA 1 EPA 200.7 01/21/2016 11:11 FCJORDA 1 EPA 200.7 01/21/2016 11:11 FCJORDA 1 EPA 200.7 01/21/2016 11:11 FCJORDA 1 EPA 200.7 01/21/2016 11:11 FCJORDA 1 EPA 200.7 01/21/2016 11:11 FCJORDA 1 EPA 200.7 01/25/2016 11:50 FCJORDA 1 EPA 200.7 01/25/2016 11:50 FCJORDA 1 EPA 200.7 01/25/2016 11:50 FCJORDA 1 EPA 200.7 01/25/2016 11:50 FCJORDA 1 EPA 200.7 01/21/2016 17:27 FCJORDA 1 EPA 200.7 01/21/2016 17:27 FCJORDA 1 EPA 200.7 01/21/2016 17:27 FCJORDA 1 EPA 200.7 01/21/2016 17:27 FCJORDA 1 EPA 200.7 01/21/2016 17:27 FCJORDA 1 EPA 200.7 01/21/2016 17:27 FCJORDA 1 EPA 200.7 01/21/2016 17:27 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: AMW-3B Collection Date: 20-Jan-16 10:49 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 47 mg/L 25 Total Carbon TOC 0.221 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 9 of 81 Sample #: 2016001991 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 20:00 MHALL3 1 EPA 200.8 01/25/2016 20:00 MHALL3 1 EPA 200.8 01/25/2016 20:00 MHALL3 1 EPA 200.8 01/25/2016 20:00 MHALL3 1 EPA 200.8 01/25/2016 20:00 MHALL3 1 EPA 200.8 01/25/2016 20:00 MHALL3 1 EPA 200.8 01/25/2016 20:00 MHALL3 1 EPA 200.8 01/25/2016 20:00 MHALL3 1 EPA 200.8 01/25/2016 20:00 MHALL3 1 EPA 200.8 01/25/2016 20:00 MHALL3 1 EPA 200.8 01/25/2016 20:00 MHALL3 1 EPA 200.8 01/25/2016 20:00 MHALL3 1 EPA 200.8 01/25/2016 20:00 MHALL3 1 EPA 200.8 01/22/2016 01:05 MHALL3 1 EPA 200.8 01/22/2016 01:05 MHALL3 1 EPA 200.8 01/22/2016 01:05 MHALL3 1 EPA 200.8 01/22/2016 01:05 MHALL3 1 EPA 200.8 01/22/2016 01:05 MHALL3 1 EPA 200.8 01/22/2016 01:05 MHALL3 1 EPA 200.8 01/22/2016 01:05 MHALL3 1 EPA 200.8 01/22/2016 01:05 MHALL3 1 EPA 200.8 01/22/2016 01:05 MHALL3 1 EPA 200.8 01/22/2016 01:05 MHALL3 1 EPA 200.8 01/22/2016 01:05 MHALL3 1 EPA 200.8 01/22/2016 01:05 MHALL3 1 EPA 200.8 01/22/2016 01:05 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis Page 10 of 81 This report shall not be reproduced, except in full. Order # J16010397 Site: CB-01 Collection Date: 20-Jan-16 1:28 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.436 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 2.2 mg/L 0.1 Sulfate < 0.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.050 mg/L 0.005 Barium (Ba) 0.015 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.022 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) 0.019 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 0.041 mg/L 0.01 Magnesium (Mg) 0.383 mg/L 0.005 Potassium (K) 0.373 mg/L 0.1 Sodium (Na) 1.03 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.336 mg/L 0.005 Barium (Ba) 0.020 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.279 mg/L 0.01 Manganese (Mn) 0.028 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) 0.020 mg/L 0.005 Sample #: 2016001992 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:03 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/21/2016 23:09 BGN9034 1 EPA 300.0 01/21/2016 23:09 BGN9034 1 EPA 245.1 01/26/2016 18:18 ACPAYNE 1 EPA 245.1 01/27/2016 15:58 ACPAYNE 1 EPA 200.7 01/21/2016 11:15 FCJORDA 1 EPA 200.7 01/21/2016 11:15 FCJORDA 1 EPA 200.7 01/21/2016 11:15 FCJORDA 1 EPA 200.7 01/21/2016 11:15 FCJORDA 1 EPA 200.7 01/21/2016 11:15 FCJORDA 1 EPA 200.7 01/21/2016 11:15 FCJORDA 1 EPA 200.7 01/21/2016 11:15 FCJORDA 1 EPA 200.7 01/25/2016 12:01 FCJORDA 1 EPA 200.7 01/25/2016 12:01 FCJORDA 1 EPA 200.7 01/25/2016 12:01 FCJORDA 1 EPA 200.7 01/25/2016 12:01 FCJORDA 1 EPA 200.7 01/21/2016 17:30 FCJORDA 1 EPA 200.7 01/21/2016 17:30 FCJORDA 1 EPA 200.7 01/21/2016 17:30 FCJORDA 1 EPA 200.7 01/21/2016 17:30 FCJORDA 1 EPA 200.7 01/21/2016 17:30 FCJORDA 1 EPA 200.7 01/21/2016 17:30 FCJORDA 1 EPA 200.7 01/21/2016 17:30 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: CB-01 Collection Date: 20-Jan-16 1:28 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.90 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.13 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 2.10 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.53 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 Total Carbon TOC 0.101 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 11 of 81 Sample #: 2016001992 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 20:04 MHALL3 1 EPA 200.8 01/25/2016 20:04 MHALL3 1 EPA 200.8 01/25/2016 20:04 MHALL3 1 EPA 200.8 01/25/2016 20:04 MHALL3 1 EPA 200.8 01/25/2016 20:04 MHALL3 1 EPA 200.8 01/25/2016 20:04 MHALL3 1 EPA 200.8 01/25/2016 20:04 MHALL3 1 EPA 200.8 01/25/2016 20:04 MHALL3 1 EPA 200.8 01/25/2016 20:04 MHALL3 1 EPA 200.8 01/25/2016 20:04 MHALL3 1 EPA 200.8 01/25/2016 20:04 MHALL3 1 EPA 200.8 01/25/2016 20:04 MHALL3 1 EPA 200.8 01/25/2016 20:04 MHALL3 1 EPA 200.8 01/22/2016 01:09 MHALL3 1 EPA 200.8 01/22/2016 01:09 MHALL3 1 EPA 200.8 01/22/2016 01:09 MHALL3 1 EPA 200.8 01/22/2016 01:09 MHALL3 1 EPA 200.8 01/22/2016 01:09 MHALL3 1 EPA 200.8 01/22/2016 01:09 MHALL3 1 EPA 200.8 01/22/2016 01:09 MHALL3 1 EPA 200.8 01/22/2016 01:09 MHALL3 1 EPA 200.8 01/22/2016 01:09 MHALL3 1 EPA 200.8 01/22/2016 01:09 MHALL3 1 EPA 200.8 01/22/2016 01:09 MHALL3 1 EPA 200.8 01/22/2016 01:09 MHALL3 1 EPA 200.8 01/22/2016 01:09 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis Page 12 of 81 This report shall not be reproduced, except in full. Order # J16010397 Site: CB-01 D Collection Date: 20-Jan-16 2:16 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.093 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 0.83 mg/L 0.1 Sulfate 3.2 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.012 mg/L 0.005 Barium (Ba) 0.010 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.142 mg/L 0.01 Manganese (Mn) 0.148 mg/L 0.005 Strontium (Sr) 0.014 mg/L 0.005 Zinc (Zn) 0.018 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 1.53 mg/L 0.01 Magnesium (Mg) 0.873 mg/L 0.005 Potassium (K) 0.861 mg/L 0.1 Sodium (Na) 1.78 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.094 mg/L 0.005 Barium (Ba) 0.011 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.269 mg/L 0.01 Manganese (Mn) 0.151 mg/L 0.005 Strontium (Sr) 0.014 mg/L 0.005 Zinc (Zn) 0.015 mg/L 0.005 Sample #: 2016001993 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:04 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/21/2016 23:59 BGN9034 1 EPA 300.0 01/21/2016 23:59 BGN9034 1 EPA 245.1 01/26/2016 18:26 ACPAYNE 1 EPA 245.1 01/27/2016 16:06 ACPAYNE 1 EPA 200.7 01/21/2016 11:19 FCJORDA 1 EPA 200.7 01/21/2016 11:19 FCJORDA 1 EPA 200.7 01/21/2016 11:19 FCJORDA 1 EPA 200.7 01/21/2016 11:19 FCJORDA 1 EPA 200.7 01/21/2016 11:19 FCJORDA 1 EPA 200.7 01/21/2016 11:19 FCJORDA 1 EPA 200.7 01/21/2016 11:19 FCJORDA 1 EPA 200.7 01/25/2016 12:05 FCJORDA 1 EPA 200.7 01/25/2016 12:05 FCJORDA 1 EPA 200.7 01/25/2016 12:05 FCJORDA 1 EPA 200.7 01/25/2016 12:05 FCJORDA 1 EPA 200.7 01/21/2016 17:34 FCJORDA 1 EPA 200.7 01/21/2016 17:34 FCJORDA 1 EPA 200.7 01/21/2016 17:34 FCJORDA 1 EPA 200.7 01/21/2016 17:34 FCJORDA 1 EPA 200.7 01/21/2016 17:34 FCJORDA 1 EPA 200.7 01/21/2016 17:34 FCJORDA 1 EPA 200.7 01/21/2016 17:34 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: CB-01 D Collection Date: 20-Jan-16 2:16 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 2.48 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 2.23 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 1.83 ug/L 1 Cobalt (Co) 2.34 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 2.72 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 Total Carbon TOC 0.112 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 13 of 81 Sample #: 2016001993 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 20:09 MHALL3 1 EPA 200.8 01/25/2016 20:09 MHALL3 1 EPA 200.8 01/25/2016 20:09 MHALL3 1 EPA 200.8 01/25/2016 20:09 MHALL3 1 EPA 200.8 01/25/2016 20:09 MHALL3 1 EPA 200.8 01/25/2016 20:09 MHALL3 1 EPA 200.8 01/25/2016 20:09 MHALL3 1 EPA 200.8 01/25/2016 20:09 MHALL3 1 EPA 200.8 01/25/2016 20:09 MHALL3 1 EPA 200.8 01/25/2016 20:09 MHALL3 1 EPA 200.8 01/25/2016 20:09 MHALL3 1 EPA 200.8 01/25/2016 20:09 MHALL3 1 EPA 200.8 01/25/2016 20:09 MHALL3 1 EPA 200.8 01/22/2016 01:14 MHALL3 1 EPA 200.8 01/22/2016 01:14 MHALL3 1 EPA 200.8 01/22/2016 01:14 MHALL3 1 EPA 200.8 01/22/2016 01:14 MHALL3 1 EPA 200.8 01/22/2016 01:14 MHALL3 1 EPA 200.8 01/22/2016 01:14 MHALL3 1 EPA 200.8 01/22/2016 01:14 MHALL3 1 EPA 200.8 01/22/2016 01:14 MHALL3 1 EPA 200.8 01/22/2016 01:14 MHALL3 1 EPA 200.8 01/22/2016 01:14 MHALL3 1 EPA 200.8 01/22/2016 01:14 MHALL3 1 EPA 200.8 01/22/2016 01:14 MHALL3 1 EPA 200.8 01/22/2016 01:14 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis Page 14 of 81 This report shall not be reproduced, except in full. Order # J16010397 Site: MW-13D Collection Date: 20-Jan-16 4:05 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.053 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 4.6 mg/L 0.1 Sulfate 1.2 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.021 mg/L 0.005 Barium (Ba) 0.016 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 2.63 mg/L 0.01 Manganese (Mn) 0.625 mg/L 0.005 Strontium (Sr) 0.214 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 15.6 mg/L 0.01 Magnesium (Mg) 1.76 mg/L 0.005 Potassium (K) 3.86 mg/L 0.1 Sodium (Na) 5.59 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.095 mg/L 0.005 Barium (Ba) 0.021 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 3.27 mg/L 0.01 Manganese (Mn) 0.747 mg/L 0.005 Strontium (Sr) 0.265 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001994 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:05 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/22/2016 00:16 BGN9034 1 EPA 300.0 01/22/2016 00:16 BGN9034 1 EPA 245.1 01/26/2016 18:33 ACPAYNE 1 EPA 245.1 01/27/2016 16:08 ACPAYNE 1 EPA 200.7 01/21/2016 11:23 FCJORDA 1 EPA 200.7 01/21/2016 11:23 FCJORDA 1 EPA 200.7 01/21/2016 11:23 FCJORDA 1 EPA 200.7 01/21/2016 11:23 FCJORDA 1 EPA 200.7 01/21/2016 11:23 FCJORDA 1 EPA 200.7 01/21/2016 11:23 FCJORDA 1 EPA 200.7 01/21/2016 11:23 FCJORDA 1 EPA 200.7 01/25/2016 12:09 FCJORDA 1 EPA 200.7 01/25/2016 12:09 FCJORDA 1 EPA 200.7 01/25/2016 12:09 FCJORDA 1 EPA 200.7 01/25/2016 12:09 FCJORDA 1 EPA 200.7 01/21/2016 17:38 FCJORDA 1 EPA 200.7 01/21/2016 17:38 FCJORDA 1 EPA 200.7 01/21/2016 17:38 FCJORDA 1 EPA 200.7 01/21/2016 17:38 FCJORDA 1 EPA 200.7 01/21/2016 17:38 FCJORDA 1 EPA 200.7 01/21/2016 17:38 FCJORDA 1 EPA 200.7 01/21/2016 17:38 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: MW-13D Collection Date: 20-Jan-16 4:05 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 5.20 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 2.60 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 4.69 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 2.46 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 69 mg/L 25 Total Carbon TOC 0.483 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 15 of 81 Sample #: 2016001994 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 20:14 MHALL3 1 EPA 200.8 01/25/2016 20:14 MHALL3 1 EPA 200.8 01/25/2016 20:14 MHALL3 1 EPA 200.8 01/25/2016 20:14 MHALL3 1 EPA 200.8 01/25/2016 20:14 MHALL3 1 EPA 200.8 01/25/2016 20:14 MHALL3 1 EPA 200.8 01/25/2016 20:14 MHALL3 1 EPA 200.8 01/25/2016 20:14 MHALL3 1 EPA 200.8 01/25/2016 20:14 MHALL3 1 EPA 200.8 01/25/2016 20:14 MHALL3 1 EPA 200.8 01/25/2016 20:14 MHALL3 1 EPA 200.8 01/25/2016 20:14 MHALL3 1 EPA 200.8 01/25/2016 20:14 MHALL3 1 EPA 200.8 01/22/2016 01:19 MHALL3 1 EPA 200.8 01/22/2016 01:19 MHALL3 1 EPA 200.8 01/22/2016 01:19 MHALL3 1 EPA 200.8 01/22/2016 01:19 MHALL3 1 EPA 200.8 01/22/2016 01:19 MHALL3 1 EPA 200.8 01/22/2016 01:19 MHALL3 1 EPA 200.8 01/22/2016 01:19 MHALL3 1 EPA 200.8 01/22/2016 01:19 MHALL3 1 EPA 200.8 01/22/2016 01:19 MHALL3 1 EPA 200.8 01/22/2016 01:19 MHALL3 1 EPA 200.8 01/22/2016 01:19 MHALL3 1 EPA 200.8 01/22/2016 01:19 MHALL3 1 EPA 200.8 01/22/2016 01:19 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis Page 16 of 81 This report shall not be reproduced, except in full. Order # J16010397 Site: MW-13BR Collection Date: 20-Jan-16 3:52 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.624 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 5.0 mg/L 0.1 Sulfate 1.8 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.035 mg/L 0.005 Barium (Ba) 0.028 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.026 mg/L 0.005 Strontium (Sr) 0.017 mg/L 0.005 Zinc (Zn) 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 2.22 mg/L 0.01 Magnesium (Mg) 2.14 mg/L 0.005 Potassium (K) 0.934 mg/L 0.1 Sodium (Na) 2.26 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.047 mg/L 0.005 Barium (Ba) 0.028 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.022 mg/L 0.01 Manganese (Mn) 0.025 mg/L 0.005 Strontium (Sr) 0.016 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001995 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:09 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/22/2016 00:33 BGN9034 1 EPA 300.0 01/22/2016 00:33 BGN9034 1 EPA 245.1 01/26/2016 18:35 ACPAYNE 1 EPA 245.1 01/27/2016 16:11 ACPAYNE 1 EPA 200.7 01/21/2016 11:27 FCJORDA 1 EPA 200.7 01/21/2016 11:27 FCJORDA 1 EPA 200.7 01/21/2016 11:27 FCJORDA 1 EPA 200.7 01/21/2016 11:27 FCJORDA 1 EPA 200.7 01/21/2016 11:27 FCJORDA 1 EPA 200.7 01/21/2016 11:27 FCJORDA 1 EPA 200.7 01/21/2016 11:27 FCJORDA 1 EPA 200.7 01/25/2016 12:13 FCJORDA 1 EPA 200.7 01/25/2016 12:13 FCJORDA 1 EPA 200.7 01/25/2016 12:13 FCJORDA 1 EPA 200.7 01/25/2016 12:13 FCJORDA 1 EPA 200.7 01/21/2016 17:42 FCJORDA 1 EPA 200.7 01/21/2016 17:42 FCJORDA 1 EPA 200.7 01/21/2016 17:42 FCJORDA 1 EPA 200.7 01/21/2016 17:42 FCJORDA 1 EPA 200.7 01/21/2016 17:42 FCJORDA 1 EPA 200.7 01/21/2016 17:42 FCJORDA 1 EPA 200.7 01/21/2016 17:42 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: MW-13BR Collection Date: 20-Jan-16 3:52 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 Total Carbon TOC 0.158 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 17 of 81 Sample #: 2016001995 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 20:19 MHALL3 1 EPA 200.8 01/25/2016 20:19 MHALL3 1 EPA 200.8 01/25/2016 20:19 MHALL3 1 EPA 200.8 01/25/2016 20:19 MHALL3 1 EPA 200.8 01/25/2016 20:19 MHALL3 1 EPA 200.8 01/25/2016 20:19 MHALL3 1 EPA 200.8 01/25/2016 20:19 MHALL3 1 EPA 200.8 01/25/2016 20:19 MHALL3 1 EPA 200.8 01/25/2016 20:19 MHALL3 1 EPA 200.8 01/25/2016 20:19 MHALL3 1 EPA 200.8 01/25/2016 20:19 MHALL3 1 EPA 200.8 01/25/2016 20:19 MHALL3 1 EPA 200.8 01/25/2016 20:19 MHALL3 1 EPA 200.8 01/22/2016 01:24 MHALL3 1 EPA 200.8 01/22/2016 01:24 MHALL3 1 EPA 200.8 01/22/2016 01:24 MHALL3 1 EPA 200.8 01/22/2016 01:24 MHALL3 1 EPA 200.8 01/22/2016 01:24 MHALL3 1 EPA 200.8 01/22/2016 01:24 MHALL3 1 EPA 200.8 01/22/2016 01:24 MHALL3 1 EPA 200.8 01/22/2016 01:24 MHALL3 1 EPA 200.8 01/22/2016 01:24 MHALL3 1 EPA 200.8 01/22/2016 01:24 MHALL3 1 EPA 200.8 01/22/2016 01:24 MHALL3 1 EPA 200.8 01/22/2016 01:24 MHALL3 1 EPA 200.8 01/22/2016 01:24 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: PZ-17S Collection Date: 20-Jan-16 11:22 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.281 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 1.8 mg/L 0.1 Sulfate 14 mg/L 0.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.036 mg/L 0.005 Barium (Ba) 0.061 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.018 mg/L 0.005 Strontium (Sr) 0.098 mg/L 0.005 Zinc (Zn) 0.030 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 3.28 mg/L 0.01 Magnesium (Mg) 0.722 mg/L 0.005 Potassium (K) 2.55 mg/L 0.1 Sodium (Na) 2.62 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.068 mg/L 0.005 Barium (Ba) 0.063 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.040 mg/L 0.01 Manganese (Mn) 0.019 mg/L 0.005 Strontium (Sr) 0.096 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001996 Matrix: GW WW Page 18 of 81 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:10 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/22/2016 02:32 BGN9034 5 EPA 300.0 01/22/2016 02:32 BGN9034 1 EPA 245.1 01/26/2016 18:38 ACPAYNE 1 EPA 245.1 01/27/2016 16:13 ACPAYNE 1 EPA 200.7 01/21/2016 11:31 FCJORDA 1 EPA 200.7 01/21/2016 11:31 FCJORDA 1 EPA 200.7 01/21/2016 11:31 FCJORDA 1 EPA 200.7 01/21/2016 11:31 FCJORDA 1 EPA 200.7 01/21/2016 11:31 FCJORDA 1 EPA 200.7 01/21/2016 11:31 FCJORDA 1 EPA 200.7 01/21/2016 11:31 FCJORDA 1 EPA 200.7 01/25/2016 12:17 FCJORDA 1 EPA 200.7 01/25/2016 12:17 FCJORDA 1 EPA 200.7 01/25/2016 12:17 FCJORDA 1 EPA 200.7 01/25/2016 12:17 FCJORDA 1 EPA 200.7 01/21/2016 17:46 FCJORDA 1 EPA 200.7 01/21/2016 17:46 FCJORDA 1 EPA 200.7 01/21/2016 17:46 FCJORDA 1 EPA 200.7 01/21/2016 17:46 FCJORDA 1 EPA 200.7 01/21/2016 17:46 FCJORDA 1 EPA 200.7 01/21/2016 17:46 FCJORDA 1 EPA 200.7 01/21/2016 17:46 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: PZ-17S Collection Date: 20-Jan-16 11:22 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) 1.66 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.44 ug/L 1 Selenium (Se) 7.59 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) 1.75 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.37 ug/L 1 Selenium (Se) 6.48 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 35 mg/L 25 Total Carbon TOC 0.181 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 19 of 81 Sample #: 2016001996 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 20:24 MHALL3 1 EPA 200.8 01/25/2016 20:24 MHALL3 1 EPA 200.8 01/25/2016 20:24 MHALL3 1 EPA 200.8 01/25/2016 20:24 MHALL3 1 EPA 200.8 01/25/2016 20:24 MHALL3 1 EPA 200.8 01/25/2016 20:24 MHALL3 1 EPA 200.8 01/25/2016 20:24 MHALL3 1 EPA 200.8 01/25/2016 20:24 MHALL3 1 EPA 200.8 01/25/2016 20:24 MHALL3 1 EPA 200.8 01/25/2016 20:24 MHALL3 1 EPA 200.8 01/25/2016 20:24 MHALL3 1 EPA 200.8 01/25/2016 20:24 MHALL3 1 EPA 200.8 01/25/2016 20:24 MHALL3 1 EPA 200.8 01/22/2016 01:29 MHALL3 1 EPA 200.8 01/22/2016 01:29 MHALL3 1 EPA 200.8 01/22/2016 01:29 MHALL3 1 EPA 200.8 01/22/2016 01:29 MHALL3 1 EPA 200.8 01/22/2016 01:29 MHALL3 1 EPA 200.8 01/22/2016 01:29 MHALL3 1 EPA 200.8 01/22/2016 01:29 MHALL3 1 EPA 200.8 01/22/2016 01:29 MHALL3 1 EPA 200.8 01/22/2016 01:29 MHALL3 1 EPA 200.8 01/22/2016 01:29 MHALL3 1 EPA 200.8 01/22/2016 01:29 MHALL3 1 EPA 200.8 01/22/2016 01:29 MHALL3 1 EPA 200.8 01/22/2016 01:29 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis Page 20 of 81 This report shall not be reproduced, except in full. Order # J16010397 Site: PZ-17D Collection Date: 20-Jan-16 3:20 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.490 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 8.5 mg/L 0.5 Sulfate 150 mg/L 2.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.057 mg/L 0.005 Boron (B) 0.847 mg/L 0.05 Iron (Fe) 0.028 mg/L 0.01 Manganese (Mn) 0.023 mg/L 0.005 Strontium (Sr) 0.284 mg/L 0.005 Zinc (Zn) 0.129 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 56.9 mg/L 0.01 Magnesium (Mg) 8.96 mg/L 0.005 Potassium (K) 7.32 mg/L 0.1 Sodium (Na) 10.1 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.087 mg/L 0.005 Barium (Ba) 0.057 mg/L 0.005 Boron (B) 0.846 mg/L 0.05 Iron (Fe) 0.363 mg/L 0.01 Manganese (Mn) 0.031 mg/L 0.005 Strontium (Sr) 0.281 mg/L 0.005 Zinc (Zn) 0.131 mg/L 0.005 Sample #: 2016001997 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:11 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/22/2016 03:39 BGN9034 25 EPA 300.0 01/22/2016 03:39 BGN9034 1 EPA 245.1 01/26/2016 18:40 ACPAYNE 1 EPA 245.1 01/27/2016 16:15 ACPAYNE 1 EPA 200.7 01/21/2016 11:34 FCJORDA 1 EPA 200.7 01/21/2016 11:34 FCJORDA 1 EPA 200.7 01/21/2016 11:34 FCJORDA 1 EPA 200.7 01/21/2016 11:34 FCJORDA 1 EPA 200.7 01/21/2016 11:34 FCJORDA 1 EPA 200.7 01/21/2016 11:34 FCJORDA 1 EPA 200.7 01/21/2016 11:34 FCJORDA 1 EPA 200.7 01/25/2016 12:21 FCJORDA 1 EPA 200.7 01/25/2016 12:21 FCJORDA 1 EPA 200.7 01/25/2016 12:21 FCJORDA 1 EPA 200.7 01/25/2016 12:21 FCJORDA 1 EPA 200.7 01/21/2016 17:49 FCJORDA 1 EPA 200.7 01/21/2016 17:49 FCJORDA 1 EPA 200.7 01/21/2016 17:49 FCJORDA 1 EPA 200.7 01/21/2016 17:49 FCJORDA 1 EPA 200.7 01/21/2016 17:49 FCJORDA 1 EPA 200.7 01/21/2016 17:49 FCJORDA 1 EPA 200.7 01/21/2016 17:49 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: PZ-17D Collection Date: 20-Jan-16 3:20 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 6.92 ug/L 1 Selenium (Se) 20.9 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 47.5 ug/L 1 Cobalt (Co) 1.19 ug/L 1 Copper (Cu) 2.07 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1.37 ug/L 1 Nickel (Ni) 30.3 ug/L 1 Selenium (Se) 20.3 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.427 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 290 mg/L 25 Total Carbon TOC 0.236 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 21 of 81 Sample #: 2016001997 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 19:30 MHALL3 1 EPA 200.8 01/25/2016 19:30 MHALL3 1 EPA 200.8 01/25/2016 19:30 MHALL3 1 EPA 200.8 01/25/2016 19:30 MHALL3 1 EPA 200.8 01/25/2016 19:30 MHALL3 1 EPA 200.8 01/25/2016 19:30 MHALL3 1 EPA 200.8 01/25/2016 19:30 MHALL3 1 EPA 200.8 01/25/2016 19:30 MHALL3 1 EPA 200.8 01/25/2016 19:30 MHALL3 1 EPA 200.8 01/25/2016 19:30 MHALL3 1 EPA 200.8 01/25/2016 19:30 MHALL3 1 EPA 200.8 01/25/2016 19:30 MHALL3 1 EPA 200.8 01/25/2016 19:30 MHALL3 1 EPA 200.8 01/22/2016 01:34 MHALL3 1 EPA 200.8 01/22/2016 01:34 MHALL3 1 EPA 200.8 01/22/2016 01:34 MHALL3 1 EPA 200.8 01/22/2016 01:34 MHALL3 1 EPA 200.8 01/22/2016 01:34 MHALL3 1 EPA 200.8 01/22/2016 01:34 MHALL3 1 EPA 200.8 01/22/2016 01:34 MHALL3 1 EPA 200.8 01/22/2016 01:34 MHALL3 1 EPA 200.8 01/22/2016 01:34 MHALL3 1 EPA 200.8 01/22/2016 01:34 MHALL3 1 EPA 200.8 01/22/2016 01:34 MHALL3 1 EPA 200.8 01/22/2016 01:34 MHALL3 1 EPA 200.8 01/22/2016 01:34 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: MW-31D Collection Date: 20-Jan-16 11:16 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 16 mg-N/L 0.2 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 10 mg/L 0.5 Sulfate 190 mg/L 2.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 1.40 mg/L 0.005 Barium (Ba) 0.053 mg/L 0.005 Boron (B) 0.637 mg/L 0.05 Iron (Fe) 1.28 mg/L 0.01 Manganese (Mn) 2.56 mg/L 0.005 Strontium (Sr) 0.569 mg/L 0.005 Zinc (Zn) 0.125 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 40.4 mg/L 0.01 Magnesium (Mg) 8.75 mg/L 0.005 Potassium (K) 10.6 mg/L 0.1 Sodium (Na) 17.6 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 1.82 mg/L 0.005 Barium (Ba) 0.053 mg/L 0.005 Boron (B) 0.639 mg/L 0.05 Iron (Fe) 1.54 mg/L 0.01 Manganese (Mn) 2.62 mg/L 0.005 Strontium (Sr) 0.583 mg/L 0.005 Zinc (Zn) 0.139 mg/L 0.005 Sample #: 2016001998 Matrix: GW WW Page 22 of 81 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 20 EPA 353.2 01/25/2016 13:06 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/22/2016 03:56 BGN9034 25 EPA 300.0 01/22/2016 03:56 BGN9034 1 EPA 245.1 01/26/2016 18:43 ACPAYNE 1 EPA 245.1 01/27/2016 16:18 ACPAYNE 1 EPA 200.7 01/21/2016 11:38 FCJORDA 1 EPA 200.7 01/21/2016 11:38 FCJORDA 1 EPA 200.7 01/21/2016 11:38 FCJORDA 1 EPA 200.7 01/21/2016 11:38 FCJORDA 1 EPA 200.7 01/21/2016 11:38 FCJORDA 1 EPA 200.7 01/21/2016 11:38 FCJORDA 1 EPA 200.7 01/21/2016 11:38 FCJORDA 1 EPA 200.7 01/25/2016 12:24 FCJORDA 1 EPA 200.7 01/25/2016 12:24 FCJORDA 1 EPA 200.7 01/25/2016 12:24 FCJORDA 1 EPA 200.7 01/25/2016 12:24 FCJORDA 1 EPA 200.7 01/21/2016 17:53 FCJORDA 1 EPA 200.7 01/21/2016 17:53 FCJORDA 1 EPA 200.7 01/21/2016 17:53 FCJORDA 1 EPA 200.7 01/21/2016 17:53 FCJORDA 1 EPA 200.7 01/21/2016 17:53 FCJORDA 1 EPA 200.7 01/21/2016 17:53 FCJORDA 1 EPA 200.7 01/21/2016 17:53 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: MW-31D Collection Date: 20-Jan-16 11:16 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) 1.23 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 84.8 ug/L 1 Copper (Cu) 36.0 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 47.1 ug/L 1 Selenium (Se) 5.82 ug/L 1 Thallium (TI) Low Level 0.617 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) 1.58 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 1.20 ug/L 1 Cobalt (Co) 85.2 ug/L 1 Copper (Cu) 40.0 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 47.3 ug/L 1 Selenium (Se) 5.01 ug/L 1 Thallium (TI) Low Level 0.802 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 310 mg/L 25 Total Carbon TOC 0.252 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 8.0 mg/L 5 Page 23 of 81 Sample #: 2016001998 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 20:29 MHALL3 1 EPA 200.8 01/25/2016 20:29 MHALL3 1 EPA 200.8 01/25/2016 20:29 MHALL3 1 EPA 200.8 01/25/2016 20:29 MHALL3 1 EPA 200.8 01/25/2016 20:29 MHALL3 1 EPA 200.8 01/25/2016 20:29 MHALL3 1 EPA 200.8 01/25/2016 20:29 MHALL3 1 EPA 200.8 01/25/2016 20:29 MHALL3 1 EPA 200.8 01/25/2016 20:29 MHALL3 1 EPA 200.8 01/25/2016 20:29 MHALL3 1 EPA 200.8 01/25/2016 20:29 MHALL3 1 EPA 200.8 01/25/2016 20:29 MHALL3 1 EPA 200.8 01/25/2016 20:29 MHALL3 1 EPA 200.8 01/22/2016 01:39 MHALL3 1 EPA 200.8 01/22/2016 01:39 MHALL3 1 EPA 200.8 01/22/2016 01:39 MHALL3 1 EPA 200.8 01/22/2016 01:39 MHALL3 1 EPA 200.8 01/22/2016 01:39 MHALL3 1 EPA 200.8 01/22/2016 01:39 MHALL3 1 EPA 200.8 01/22/2016 01:39 MHALL3 1 EPA 200.8 01/22/2016 01:39 MHALL3 1 EPA 200.8 01/22/2016 01:39 MHALL3 1 EPA 200.8 01/22/2016 01:39 MHALL3 1 EPA 200.8 01/22/2016 01:39 MHALL3 1 EPA 200.8 01/22/2016 01:39 MHALL3 1 EPA 200.8 01/22/2016 01:39 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis Page 24 of 81 This report shall not be reproduced, except in full. Order # J16010397 Site: MW-12D Collection Date: 20-Jan-16 1:50 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 1.4 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 8.8 mg/L 0.2 Sulfate 7.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.047 mg/L 0.005 Barium (Ba) 0.052 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.014 mg/L 0.01 Manganese (Mn) 0.124 mg/L 0.005 Strontium (Sr) 0.022 mg/L 0.005 Zinc (Zn) 0.036 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 3.43 mg/L 0.01 Magnesium (Mg) 2.34 mg/L 0.005 Potassium (K) 0.859 mg/L 0.1 Sodium (Na) 3.79 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.220 mg/L 0.005 Barium (Ba) 0.057 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.207 mg/L 0.01 Manganese (Mn) 0.123 mg/L 0.005 Strontium (Sr) 0.021 mg/L 0.005 Zinc (Zn) 0.018 mg/L 0.005 Sample #: 2016001999 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:18 LSTARL1 Vendor Method V_PACE 2 EPA 300.0 01/25/2016 15:18 BGN9034 1 EPA 300.0 01/25/2016 15:18 BGN9034 1 EPA 245.1 01/26/2016 18:45 ACPAYNE 1 EPA 245.1 01/27/2016 16:20 ACPAYNE 1 EPA 200.7 01/21/2016 11:50 FCJORDA 1 EPA 200.7 01/21/2016 11:50 FCJORDA 1 EPA 200.7 01/21/2016 11:50 FCJORDA 1 EPA 200.7 01/21/2016 11:50 FCJORDA 1 EPA 200.7 01/21/2016 11:50 FCJORDA 1 EPA 200.7 01/21/2016 11:50 FCJORDA 1 EPA 200.7 01/21/2016 11:50 FCJORDA 1 EPA 200.7 01/25/2016 12:36 FCJORDA 1 EPA 200.7 01/25/2016 12:36 FCJORDA 1 EPA 200.7 01/25/2016 12:36 FCJORDA 1 EPA 200.7 01/25/2016 12:36 FCJORDA 1 EPA 200.7 01/21/2016 18:08 FCJORDA 1 EPA 200.7 01/21/2016 18:08 FCJORDA 1 EPA 200.7 01/21/2016 18:08 FCJORDA 1 EPA 200.7 01/21/2016 18:08 FCJORDA 1 EPA 200.7 01/21/2016 18:08 FCJORDA 1 EPA 200.7 01/21/2016 18:08 FCJORDA 1 EPA 200.7 01/21/2016 18:08 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: MW-12D Collection Date: 20-Jan-16 1:50 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.20 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 2.04 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 10.2 ug/L 1 Cobalt (Co) 1.23 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 6.62 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 32 mg/L 25 Total Carbon TOC 0.149 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 25 of 81 Sample #: 2016001999 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 21:08 MHALL3 1 EPA 200.8 01/25/2016 21:08 MHALL3 1 EPA 200.8 01/25/2016 21:08 MHALL3 1 EPA 200.8 01/25/2016 21:08 MHALL3 1 EPA 200.8 01/25/2016 21:08 MHALL3 1 EPA 200.8 01/25/2016 21:08 MHALL3 1 EPA 200.8 01/25/2016 21:08 MHALL3 1 EPA 200.8 01/25/2016 21:08 MHALL3 1 EPA 200.8 01/25/2016 21:08 MHALL3 1 EPA 200.8 01/25/2016 21:08 MHALL3 1 EPA 200.8 01/25/2016 21:08 MHALL3 1 EPA 200.8 01/25/2016 21:08 MHALL3 1 EPA 200.8 01/25/2016 21:08 MHALL3 1 EPA 200.8 01/22/2016 02:18 MHALL3 1 EPA 200.8 01/22/2016 02:18 MHALL3 1 EPA 200.8 01/22/2016 02:18 MHALL3 1 EPA 200.8 01/22/2016 02:18 MHALL3 1 EPA 200.8 01/22/2016 02:18 MHALL3 1 EPA 200.8 01/22/2016 02:18 MHALL3 1 EPA 200.8 01/22/2016 02:18 MHALL3 1 EPA 200.8 01/22/2016 02:18 MHALL3 1 EPA 200.8 01/22/2016 02:18 MHALL3 1 EPA 200.8 01/22/2016 02:18 MHALL3 1 EPA 200.8 01/22/2016 02:18 MHALL3 1 EPA 200.8 01/22/2016 02:18 MHALL3 1 EPA 200.8 01/22/2016 02:18 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis Page 26 of 81 This report shall not be reproduced, except in full. Order # J16010397 Site: CB-08 Collection Date: 20-Jan-16 4:40 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 1.6 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 200 mg/L 5 Sulfate 120 mg/L 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 0.10 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.129 mg/L 0.005 Barium (Ba) 0.159 mg/L 0.005 Boron (B) 2.36 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 1.22 mg/L 0.005 Strontium (Sr) 0.578 mg/L 0.005 Zinc (Zn) 0.016 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 97.9 mg/L 0.1 Magnesium (Mg) 35.6 mg/L 0.05 Potassium (K) 2.31 mg/L 1 Sodium (Na) 7.14 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.148 mg/L 0.005 Barium (Ba) 0.161 mg/L 0.005 Boron (B) 2.30 mg/L 0.05 Iron (Fe) 0.016 mg/L 0.01 Manganese (Mn) 1.20 mg/L 0.005 Strontium (Sr) 0.567 mg/L 0.005 Zinc (Zn) 0.015 mg/L 0.005 Sample #: 2016002000 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:22 LSTARL1 Vendor Method V_PACE 50 EPA 300.0 01/25/2016 12:30 BGN9034 50 EPA 300.0 01/25/2016 12:30 BGN9034 1 EPA 245.1 01/26/2016 18:48 ACPAYNE 1 EPA 245.1 01/27/2016 16:23 ACPAYNE 1 EPA 200.7 01/21/2016 11:55 FCJORDA 1 EPA 200.7 01/21/2016 11:55 FCJORDA 1 EPA 200.7 01/21/2016 11:55 FCJORDA 1 EPA 200.7 01/21/2016 11:55 FCJORDA 1 EPA 200.7 01/21/2016 11:55 FCJORDA 1 EPA 200.7 01/21/2016 11:55 FCJORDA 1 EPA 200.7 01/21/2016 11:55 FCJORDA 10 EPA 200.7 01/25/2016 12:39 FCJORDA 10 EPA 200.7 01/25/2016 12:39 FCJORDA 10 EPA 200.7 01/25/2016 12:39 FCJORDA 10 EPA 200.7 01/25/2016 12:39 FCJORDA 1 EPA 200.7 01/21/2016 18:20 FCJORDA 1 EPA 200.7 01/21/2016 18:20 FCJORDA 1 EPA 200.7 01/21/2016 18:20 FCJORDA 1 EPA 200.7 01/21/2016 18:20 FCJORDA 1 EPA 200.7 01/21/2016 18:20 FCJORDA 1 EPA 200.7 01/21/2016 18:20 FCJORDA 1 EPA 200.7 01/21/2016 18:20 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: CB-08 Collection Date: 20-Jan-16 4:40 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 4.20 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 2.23 ug/L 1 Selenium (Se) 16.5 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 4.23 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 2.39 ug/L 1 Selenium (Se) 15.4 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 580 mg/L 25 Total Carbon TOC 0.738 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 27 of 81 Sample #: 2016002000 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 21:13 MHALL3 1 EPA 200.8 01/25/2016 21:13 MHALL3 1 EPA 200.8 01/25/2016 21:13 MHALL3 1 EPA 200.8 01/25/2016 21:13 MHALL3 1 EPA 200.8 01/25/2016 21:13 MHALL3 1 EPA 200.8 01/25/2016 21:13 MHALL3 1 EPA 200.8 01/25/2016 21:13 MHALL3 1 EPA 200.8 01/25/2016 21:13 MHALL3 1 EPA 200.8 01/25/2016 21:13 MHALL3 1 EPA 200.8 01/25/2016 21:13 MHALL3 1 EPA 200.8 01/25/2016 21:13 MHALL3 1 EPA 200.8 01/25/2016 21:13 MHALL3 1 EPA 200.8 01/25/2016 21:13 MHALL3 1 EPA 200.8 01/22/2016 01:58 MHALL3 1 EPA 200.8 01/22/2016 01:58 MHALL3 1 EPA 200.8 01/22/2016 01:58 MHALL3 1 EPA 200.8 01/22/2016 01:58 MHALL3 1 EPA 200.8 01/22/2016 01:58 MHALL3 1 EPA 200.8 01/22/2016 01:58 MHALL3 1 EPA 200.8 01/22/2016 01:58 MHALL3 1 EPA 200.8 01/22/2016 01:58 MHALL3 1 EPA 200.8 01/22/2016 01:58 MHALL3 1 EPA 200.8 01/22/2016 01:58 MHALL3 1 EPA 200.8 01/22/2016 01:58 MHALL3 1 EPA 200.8 01/22/2016 01:58 MHALL3 1 EPA 200.8 01/22/2016 01:58 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis Page 28 of 81 This report shall not be reproduced, except in full. Order # J16010397 Site: CB-08BR Collection Date: 20-Jan-16 3:28 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.014 mg-N/L N1 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 14 mg/L 1 Sulfate 26 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.018 mg/L 0.005 Boron (B) 0.091 mg/L 0.05 Iron (Fe) 0.590 mg/L 0.01 Manganese (Mn) 0.477 mg/L 0.005 Strontium (Sr) 0.153 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 37.0 mg/L 0.01 Magnesium (Mg) 4.44 mg/L 0.005 Potassium (K) 3.34 mg/L 0.1 Sodium (Na) 7.45 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.130 mg/L 0.005 Barium (Ba) 0.020 mg/L 0.005 Boron (B) 0.087 mg/L 0.05 Iron (Fe) 0.897 mg/L 0.01 Manganese (Mn) 0.452 mg/L 0.005 Strontium (Sr) 0.148 mg/L 0.005 Zinc (Zn) 0.005 mg/L 0.005 Sample #: 2016002001 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:23 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/25/2016 13:37 BGN9034 10 EPA 300.0 01/25/2016 13:37 BGN9034 1 EPA 245.1 01/26/2016 18:50 ACPAYNE 1 EPA 245.1 01/27/2016 16:25 ACPAYNE 1 EPA 200.7 01/21/2016 11:59 FCJORDA 1 EPA 200.7 01/21/2016 11:59 FCJORDA 1 EPA 200.7 01/21/2016 11:59 FCJORDA 1 EPA 200.7 01/21/2016 11:59 FCJORDA 1 EPA 200.7 01/21/2016 11:59 FCJORDA 1 EPA 200.7 01/21/2016 11:59 FCJORDA 1 EPA 200.7 01/21/2016 11:59 FCJORDA 1 EPA 200.7 01/25/2016 12:43 FCJORDA 1 EPA 200.7 01/25/2016 12:43 FCJORDA 1 EPA 200.7 01/25/2016 12:43 FCJORDA 1 EPA 200.7 01/25/2016 12:43 FCJORDA 1 EPA 200.7 01/21/2016 18:24 FCJORDA 1 EPA 200.7 01/21/2016 18:24 FCJORDA 1 EPA 200.7 01/21/2016 18:24 FCJORDA 1 EPA 200.7 01/21/2016 18:24 FCJORDA 1 EPA 200.7 01/21/2016 18:24 FCJORDA 1 EPA 200.7 01/21/2016 18:24 FCJORDA 1 EPA 200.7 01/21/2016 18:24 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: CB-08BR Collection Date: 20-Jan-16 3:28 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1.42 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1.33 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 180 mg/L 25 Total Carbon TOC 0.167 mg/L N1 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 29 of 81 Sample #: 2016002001 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 21:18 MHALL3 1 EPA 200.8 01/25/2016 21:18 MHALL3 1 EPA 200.8 01/25/2016 21:18 MHALL3 1 EPA 200.8 01/25/2016 21:18 MHALL3 1 EPA 200.8 01/25/2016 21:18 MHALL3 1 EPA 200.8 01/25/2016 21:18 MHALL3 1 EPA 200.8 01/25/2016 21:18 MHALL3 1 EPA 200.8 01/25/2016 21:18 MHALL3 1 EPA 200.8 01/25/2016 21:18 MHALL3 1 EPA 200.8 01/25/2016 21:18 MHALL3 1 EPA 200.8 01/25/2016 21:18 MHALL3 1 EPA 200.8 01/25/2016 21:18 MHALL3 1 EPA 200.8 01/25/2016 21:18 MHALL3 1 EPA 200.8 01/22/2016 02:23 MHALL3 1 EPA 200.8 01/22/2016 02:23 MHALL3 1 EPA 200.8 01/22/2016 02:23 MHALL3 1 EPA 200.8 01/22/2016 02:23 MHALL3 1 EPA 200.8 01/22/2016 02:23 MHALL3 1 EPA 200.8 01/22/2016 02:23 MHALL3 1 EPA 200.8 01/22/2016 02:23 MHALL3 1 EPA 200.8 01/22/2016 02:23 MHALL3 1 EPA 200.8 01/22/2016 02:23 MHALL3 1 EPA 200.8 01/22/2016 02:23 MHALL3 1 EPA 200.8 01/22/2016 02:23 MHALL3 1 EPA 200.8 01/22/2016 02:23 MHALL3 1 EPA 200.8 01/22/2016 02:23 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: MW-08S Collection Date: 20-Jan-16 12:33 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.144 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 420 mg/L 10 Sulfate 260 mg/L 10 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.180 mg/L 0.005 Boron (B) 6.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 2.82 mg/L 0.005 Strontium (Sr) 3.62 mg/L 0.005 Zinc (Zn) 0.017 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 231 mg/L 0.1 Magnesium (Mg) 79.5 mg/L 0.05 Potassium (K) 1.71 mg/L 1 Sodium (Na) 14.3 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.009 mg/L 0.005 Barium (Ba) 0.184 mg/L 0.005 Boron (B) 6.14 mg/L 0.05 Iron (Fe) 0.015 mg/L 0.01 Manganese (Mn) 2.92 mg/L 0.005 Strontium (Sr) 3.54 mg/L 0.005 Zinc (Zn) 0.032 mg/L 0.005 Page 30 of 81 Sample #: 2016002002 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:25 LSTARL1 Vendor Method V_PACE 100 EPA 300.0 01/25/2016 13:54 BGN9034 100 EPA 300.0 01/25/2016 13:54 BGN9034 1 EPA 245.1 01/26/2016 19:05 ACPAYNE 1 EPA 245.1 01/27/2016 16:32 ACPAYNE 1 EPA 200.7 01/21/2016 12:03 FCJORDA 1 EPA 200.7 01/21/2016 12:03 FCJORDA 1 EPA 200.7 01/21/2016 12:03 FCJORDA 1 EPA 200.7 01/21/2016 12:03 FCJORDA 1 EPA 200.7 01/21/2016 12:03 FCJORDA 1 EPA 200.7 01/21/2016 12:03 FCJORDA 1 EPA 200.7 01/21/2016 12:03 FCJORDA 10 EPA 200.7 01/25/2016 12:47 FCJORDA 10 EPA 200.7 01/25/2016 12:47 FCJORDA 10 EPA 200.7 01/25/2016 12:47 FCJORDA 10 EPA 200.7 01/25/2016 12:47 FCJORDA 1 EPA 200.7 01/21/2016 18:28 FCJORDA 1 EPA 200.7 01/21/2016 18:28 FCJORDA 1 EPA 200.7 01/21/2016 18:28 FCJORDA 1 EPA 200.7 01/21/2016 18:28 FCJORDA 1 EPA 200.7 01/21/2016 18:28 FCJORDA 1 EPA 200.7 01/21/2016 18:28 FCJORDA 1 EPA 200.7 01/21/2016 18:28 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: MW-08S Collection Date: 20-Jan-16 12:33 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 2.96 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 3.45 ug/L 1 Nickel (Ni) 1.58 ug/L 1 Selenium (Se) 1.05 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 2.75 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 3.72 ug/L 1 Nickel (Ni) 1.56 ug/L 1 Selenium (Se) 1.13 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 1300 mg/L 25 Total Carbon TOC 0.189 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 31 of 81 Sample #: 2016002002 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 21:22 MHALL3 1 EPA 200.8 01/25/2016 21:22 MHALL3 1 EPA 200.8 01/25/2016 21:22 MHALL3 1 EPA 200.8 01/25/2016 21:22 MHALL3 1 EPA 200.8 01/25/2016 21:22 MHALL3 1 EPA 200.8 01/25/2016 21:22 MHALL3 1 EPA 200.8 01/25/2016 21:22 MHALL3 1 EPA 200.8 01/25/2016 21:22 MHALL3 1 EPA 200.8 01/25/2016 21:22 MHALL3 1 EPA 200.8 01/25/2016 21:22 MHALL3 1 EPA 200.8 01/25/2016 21:22 MHALL3 1 EPA 200.8 01/25/2016 21:22 MHALL3 1 EPA 200.8 01/25/2016 21:22 MHALL3 1 EPA 200.8 01/22/2016 02:28 MHALL3 1 EPA 200.8 01/22/2016 02:28 MHALL3 1 EPA 200.8 01/22/2016 02:28 MHALL3 1 EPA 200.8 01/22/2016 02:28 MHALL3 1 EPA 200.8 01/22/2016 02:28 MHALL3 1 EPA 200.8 01/22/2016 02:28 MHALL3 1 EPA 200.8 01/22/2016 02:28 MHALL3 1 EPA 200.8 01/22/2016 02:28 MHALL3 1 EPA 200.8 01/22/2016 02:28 MHALL3 1 EPA 200.8 01/22/2016 02:28 MHALL3 1 EPA 200.8 01/22/2016 02:28 MHALL3 1 EPA 200.8 01/22/2016 02:28 MHALL3 1 EPA 200.8 01/22/2016 02:28 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis Page 32 of 81 This report shall not be reproduced, except in full. Order # J16010397 Site: Filter Blank Collection Date: 20-Jan-16 4:45 PM Analyte Result Units Qualifiers RDL Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2016002003 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 245.1 01/27/2016 16:39 ACPAYNE 1 EPA 200.7 01/21/2016 12:06 FCJORDA 1 EPA 200.7 01/21/2016 12:06 FCJORDA 1 EPA 200.7 01/21/2016 12:06 FCJORDA 1 EPA 200.7 01/21/2016 12:06 FCJORDA 1 EPA 200.7 01/21/2016 12:06 FCJORDA 1 EPA 200.7 01/21/2016 12:06 FCJORDA 1 EPA 200.7 01/21/2016 12:06 FCJORDA 1 EPA 200.8 01/25/2016 21:27 MHALL3 1 EPA 200.8 01/25/2016 21:27 MHALL3 1 EPA 200.8 01/25/2016 21:27 MHALL3 1 EPA 200.8 01/25/2016 21:27 MHALL3 1 EPA 200.8 01/25/2016 21:27 MHALL3 1 EPA 200.8 01/25/2016 21:27 MHALL3 1 EPA 200.8 01/25/2016 21:27 MHALL3 1 EPA 200.8 01/25/2016 21:27 MHALL3 1 EPA 200.8 01/25/2016 21:27 MHALL3 1 EPA 200.8 01/25/2016 21:27 MHALL3 1 EPA 200.8 01/25/2016 21:27 MHALL3 1 EPA 200.8 01/25/2016 21:27 MHALL3 1 EPA 200.8 01/25/2016 21:27 MHALL3 Certificate of Laboratory Analysis Page 33 of 81 This report shall not be reproduced, except in full. Order # J16010397 Site: Equipment Blank Collection Date: 20-Jan-16 4:45 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALCI - (Analvsis Performed by Pace Laboratories Vendor Parameter Complete INORGANIC IONS BY IC Chloride < 0.1 mg/L 0.1 Sulfate < 0.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 UNDIGESTED METALS BY ICP Calcium (Ca) < 0.01 mg/L 0.01 Magnesium (Mg) < 0.005 mg/L 0.005 Potassium (K) < 0.1 mg/L 0.1 Sodium (Na) < 0.05 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2016002004 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:27 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/25/2016 14:10 BGN9034 1 EPA 300.0 01/25/2016 14:10 BGN9034 1 EPA 245.1 01/26/2016 18:53 ACPAYNE 1 EPA 200.7 01/25/2016 12:51 FCJORDA 1 EPA 200.7 01/25/2016 12:51 FCJORDA 1 EPA 200.7 01/25/2016 12:51 FCJORDA 1 EPA 200.7 01/25/2016 12:51 FCJORDA 1 EPA 200.7 01/21/2016 18:31 FCJORDA 1 EPA 200.7 01/21/2016 18:31 FCJORDA 1 EPA 200.7 01/21/2016 18:31 FCJORDA 1 EPA 200.7 01/21/2016 18:31 FCJORDA 1 EPA 200.7 01/21/2016 18:31 FCJORDA 1 EPA 200.7 01/21/2016 18:31 FCJORDA 1 EPA 200.7 01/21/2016 18:31 FCJORDA 1 EPA 200.8 01/22/2016 02:33 MHALL3 1 EPA 200.8 01/22/2016 02:33 MHALL3 1 EPA 200.8 01/22/2016 02:33 MHALL3 1 EPA 200.8 01/22/2016 02:33 MHALL3 1 EPA 200.8 01/22/2016 02:33 MHALL3 1 EPA 200.8 01/22/2016 02:33 MHALL3 1 EPA 200.8 01/22/2016 02:33 MHALL3 1 EPA 200.8 01/22/2016 02:33 MHALL3 1 EPA 200.8 01/22/2016 02:33 MHALL3 1 EPA 200.8 01/22/2016 02:33 MHALL3 1 EPA 200.8 01/22/2016 02:33 MHALL3 1 EPA 200.8 01/22/2016 02:33 MHALL3 1 EPA 200.8 01/22/2016 02:33 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: Equipment Blank Collection Date: 20-Jan-16 4:45 PM Analyte Result Units Qualifiers RDL DF METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 Total Carbon Page 34 of 81 Sample #: 2016002004 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE SM2540C 01/25/201615:00 CJELLIO TOC < 0.1 mg/L 0.1 1 SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: MW-09S Collection Date: 20-Jan-16 11:03 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.749 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 530 mg/L 10 Sulfate 290 mg/L 10 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 0.09 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.015 mg/L 0.005 Barium (Ba) 0.148 mg/L 0.005 Boron (B) 5.57 mg/L 0.05 Iron (Fe) 0.068 mg/L 0.01 Manganese (Mn) 3.45 mg/L 0.005 Strontium (Sr) 2.62 mg/L 0.005 Zinc (Zn) 0.013 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 250 mg/L 0.1 Magnesium (Mg) 84.0 mg/L 0.05 Potassium (K) 3.66 mg/L 1 Sodium (Na) 17.0 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.040 mg/L 0.005 Barium (Ba) 0.147 mg/L 0.005 Boron (B) 5.56 mg/L 0.05 Iron (Fe) 0.078 mg/L 0.01 Manganese (Mn) 3.41 mg/L 0.005 Strontium (Sr) 2.60 mg/L 0.005 Zinc (Zn) 0.012 mg/L 0.005 Page 35 of 81 Sample #: 2016002005 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:28 LSTARL1 Vendor Method V_PACE 100 EPA 300.0 01/25/2016 14:27 BGN9034 100 EPA 300.0 01/25/2016 14:27 BGN9034 1 EPA 245.1 01/26/2016 19:12 ACPAYNE 1 EPA 245.1 01/27/2016 16:42 ACPAYNE 1 EPA 200.7 01/21/2016 12:10 FCJORDA 1 EPA 200.7 01/21/2016 12:10 FCJORDA 1 EPA 200.7 01/21/2016 12:10 FCJORDA 1 EPA 200.7 01/21/2016 12:10 FCJORDA 1 EPA 200.7 01/21/2016 12:10 FCJORDA 1 EPA 200.7 01/21/2016 12:10 FCJORDA 1 EPA 200.7 01/21/2016 12:10 FCJORDA 10 EPA 200.7 01/25/2016 12:55 FCJORDA 10 EPA 200.7 01/25/2016 12:55 FCJORDA 10 EPA 200.7 01/25/2016 12:55 FCJORDA 10 EPA 200.7 01/25/2016 12:55 FCJORDA 1 EPA 200.7 01/21/2016 18:35 FCJORDA 1 EPA 200.7 01/21/2016 18:35 FCJORDA 1 EPA 200.7 01/21/2016 18:35 FCJORDA 1 EPA 200.7 01/21/2016 18:35 FCJORDA 1 EPA 200.7 01/21/2016 18:35 FCJORDA 1 EPA 200.7 01/21/2016 18:35 FCJORDA 1 EPA 200.7 01/21/2016 18:35 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: MW-09S Collection Date: 20-Jan-16 11:03 AM Analyte Result Units Qualifiers TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L Arsenic (As) < 1 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) 13.1 ug/L Cobalt (Co) 3.95 ug/L Copper (Cu) < 1 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) < 1 ug/L Nickel (Ni) 10.8 ug/L Selenium (Se) 35.4 ug/L Thallium (TI) Low Level < 0.2 ug/L M2 Vanadium (V) Low Level < 0.3 ug/L TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L Arsenic (As) < 1 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) 16.1 ug/L Cobalt (Co) 3.64 ug/L Copper (Cu) < 1 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) < 1 ug/L Nickel (Ni) 9.71 ug/L Selenium (Se) 34.0 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level < 0.3 ug/L METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 1500 mg/L Total Carbon TOC 0.273 mg/L TOTAL SUSPENDED SOLIDS TSS < 5 mg/L Page 36 of 81 Sample #: 2016002005 Matrix: GW WW RDL DF Method Analysis Date/Time Analyst 1 1 EPA 200.8 01/25/2016 20:48 MHALL3 1 1 EPA 200.8 01/25/2016 20:48 MHALL3 1 1 EPA 200.8 01/25/2016 20:48 MHALL3 1 1 EPA 200.8 01/25/2016 20:48 MHALL3 1 1 EPA 200.8 01/25/2016 20:48 MHALL3 1 1 EPA 200.8 01/25/2016 20:48 MHALL3 1 1 EPA 200.8 01/25/2016 20:48 MHALL3 1 1 EPA 200.8 01/25/2016 20:48 MHALL3 1 1 EPA 200.8 01/25/2016 20:48 MHALL3 1 1 EPA 200.8 01/25/2016 20:48 MHALL3 1 1 EPA 200.8 01/25/2016 20:48 MHALL3 0.2 1 EPA 200.8 01/25/2016 20:48 MHALL3 0.3 1 EPA 200.8 01/25/2016 20:48 MHALL3 1 1 EPA 200.8 01/22/2016 02:37 MHALL3 1 1 EPA 200.8 01/22/2016 02:37 MHALL3 1 1 EPA 200.8 01/22/2016 02:37 MHALL3 1 1 EPA 200.8 01/22/2016 02:37 MHALL3 1 1 EPA 200.8 01/22/2016 02:37 MHALL3 1 1 EPA 200.8 01/22/2016 02:37 MHALL3 1 1 EPA 200.8 01/22/2016 02:37 MHALL3 1 1 EPA 200.8 01/22/2016 02:37 MHALL3 1 1 EPA 200.8 01/22/2016 02:37 MHALL3 1 1 EPA 200.8 01/22/2016 02:37 MHALL3 1 1 EPA 200.8 01/22/2016 02:37 MHALL3 0.2 1 EPA 200.8 01/22/2016 02:37 MHALL3 0.3 1 EPA 200.8 01/22/2016 02:37 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 25 1 SM2540C 01/25/201615:00 CJELLIO 0.1 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 5 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: MW-09D Collection Date: 20-Jan-16 9:45 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.417 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 510 mg/L 10 Sulfate 280 mg/L 10 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.020 mg/L 0.005 Barium (Ba) 0.146 mg/L 0.005 Boron (B) 5.19 mg/L 0.05 Iron (Fe) 17.1 mg/L 0.01 Manganese (Mn) 3.90 mg/L 0.005 Strontium (Sr) 1.74 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 235 mg/L 0.1 Magnesium (Mg) 82.3 mg/L 0.05 Potassium (K) 4.91 mg/L 1 Sodium (Na) 30.0 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.021 mg/L 0.005 Barium (Ba) 0.127 mg/L 0.005 Boron (B) 5.54 mg/L 0.05 Iron (Fe) 0.278 mg/L 0.01 Manganese (Mn) 3.66 mg/L 0.005 Strontium (Sr) 1.74 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 Page 37 of 81 Sample #: 2016002006 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:29 LSTARL1 Vendor Method V_PACE 100 EPA 300.0 01/25/2016 14:44 BGN9034 100 EPA 300.0 01/25/2016 14:44 BGN9034 1 EPA 245.1 01/26/2016 19:14 ACPAYNE 1 EPA 245.1 01/27/2016 16:44 ACPAYNE 1 EPA 200.7 01/21/2016 12:14 FCJORDA 1 EPA 200.7 01/21/2016 12:14 FCJORDA 1 EPA 200.7 01/21/2016 12:14 FCJORDA 1 EPA 200.7 01/21/2016 12:14 FCJORDA 1 EPA 200.7 01/21/2016 12:14 FCJORDA 1 EPA 200.7 01/21/2016 12:14 FCJORDA 1 EPA 200.7 01/21/2016 12:14 FCJORDA 10 EPA 200.7 01/25/2016 12:58 FCJORDA 10 EPA 200.7 01/25/2016 12:58 FCJORDA 10 EPA 200.7 01/25/2016 12:58 FCJORDA 10 EPA 200.7 01/25/2016 12:58 FCJORDA 1 EPA 200.7 01/21/2016 18:39 FCJORDA 1 EPA 200.7 01/21/2016 18:39 FCJORDA 1 EPA 200.7 01/21/2016 18:39 FCJORDA 1 EPA 200.7 01/21/2016 18:39 FCJORDA 1 EPA 200.7 01/21/2016 18:39 FCJORDA 1 EPA 200.7 01/21/2016 18:39 FCJORDA 1 EPA 200.7 01/21/2016 18:39 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: MW-09D Collection Date: 20-Jan-16 9:45 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.12 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.06 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 7.06 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 4.46 ug/L 1 Selenium (Se) 20.7 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 1400 mg/L 25 Total Carbon TOC 0.231 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 38 of 81 Sample #: 2016002006 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 21:32 MHALL3 1 EPA 200.8 01/25/2016 21:32 MHALL3 1 EPA 200.8 01/25/2016 21:32 MHALL3 1 EPA 200.8 01/25/2016 21:32 MHALL3 1 EPA 200.8 01/25/2016 21:32 MHALL3 1 EPA 200.8 01/25/2016 21:32 MHALL3 1 EPA 200.8 01/25/2016 21:32 MHALL3 1 EPA 200.8 01/25/2016 21:32 MHALL3 1 EPA 200.8 01/25/2016 21:32 MHALL3 1 EPA 200.8 01/25/2016 21:32 MHALL3 1 EPA 200.8 01/25/2016 21:32 MHALL3 1 EPA 200.8 01/25/2016 21:32 MHALL3 1 EPA 200.8 01/25/2016 21:32 MHALL3 1 EPA 200.8 01/22/2016 02:42 MHALL3 1 EPA 200.8 01/22/2016 02:42 MHALL3 1 EPA 200.8 01/22/2016 02:42 MHALL3 1 EPA 200.8 01/22/2016 02:42 MHALL3 1 EPA 200.8 01/22/2016 02:42 MHALL3 1 EPA 200.8 01/22/2016 02:42 MHALL3 1 EPA 200.8 01/22/2016 02:42 MHALL3 1 EPA 200.8 01/22/2016 02:42 MHALL3 1 EPA 200.8 01/22/2016 02:42 MHALL3 1 EPA 200.8 01/22/2016 02:42 MHALL3 1 EPA 200.8 01/22/2016 02:42 MHALL3 1 EPA 200.8 01/22/2016 02:42 MHALL3 1 EPA 200.8 01/22/2016 02:42 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis Page 39 of 81 This report shall not be reproduced, except in full. Order # J16010397 Site: MW-09BR Collection Date: 20-Jan-16 9:20 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.018 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 300 mg/L 5 Sulfate 120 mg/L 2.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.012 mg/L 0.005 Barium (Ba) 0.116 mg/L 0.005 Boron (B) 1.20 mg/L 0.05 Iron (Fe) 9.70 mg/L 0.01 Manganese (Mn) 0.649 mg/L 0.005 Strontium (Sr) 1.14 mg/L 0.005 Zinc (Zn) 0.014 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 167 mg/L 0.1 Magnesium (Mg) 31.4 mg/L 0.05 Potassium (K) 19.3 mg/L 1 Sodium (Na) 30.9 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.069 mg/L 0.005 Barium (Ba) 0.116 mg/L 0.005 Boron (B) 1.16 mg/L 0.05 Iron (Fe) 7.74 mg/L 0.01 Manganese (Mn) 0.631 mg/L 0.005 Strontium (Sr) 1.10 mg/L 0.005 Zinc (Zn) 0.015 mg/L 0.005 Sample #: 2016002007 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/25/2016 13:30 LSTARL1 Vendor Method V_PACE 50 EPA 300.0 01/26/2016 15:31 BGN9034 25 EPA 300.0 01/26/2016 15:31 BGN9034 1 EPA 245.1 01/26/2016 19:17 ACPAYNE 1 EPA 245.1 01/27/2016 16:47 ACPAYNE 1 EPA 200.7 01/21/2016 12:18 FCJORDA 1 EPA 200.7 01/21/2016 12:18 FCJORDA 1 EPA 200.7 01/21/2016 12:18 FCJORDA 1 EPA 200.7 01/21/2016 12:18 FCJORDA 1 EPA 200.7 01/21/2016 12:18 FCJORDA 1 EPA 200.7 01/21/2016 12:18 FCJORDA 1 EPA 200.7 01/21/2016 12:18 FCJORDA 10 EPA 200.7 01/25/2016 13:02 FCJORDA 10 EPA 200.7 01/25/2016 13:02 FCJORDA 10 EPA 200.7 01/25/2016 13:02 FCJORDA 10 EPA 200.7 01/25/2016 13:02 FCJORDA 1 EPA 200.7 01/21/2016 18:43 FCJORDA 1 EPA 200.7 01/21/2016 18:43 FCJORDA 1 EPA 200.7 01/21/2016 18:43 FCJORDA 1 EPA 200.7 01/21/2016 18:43 FCJORDA 1 EPA 200.7 01/21/2016 18:43 FCJORDA 1 EPA 200.7 01/21/2016 18:43 FCJORDA 1 EPA 200.7 01/21/2016 18:43 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010397 Site: MW-09BR Collection Date: 20-Jan-16 9:20 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 4.09 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 4.79 ug/L 1 Nickel (Ni) 1.42 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 890 mg/L 25 Total Carbon TOC 0.568 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 20 mg/L 5 Page 40 of 81 Sample #: 2016002007 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/25/2016 21:37 MHALL3 1 EPA 200.8 01/25/2016 21:37 MHALL3 1 EPA 200.8 01/25/2016 21:37 MHALL3 1 EPA 200.8 01/25/2016 21:37 MHALL3 1 EPA 200.8 01/25/2016 21:37 MHALL3 1 EPA 200.8 01/25/2016 21:37 MHALL3 1 EPA 200.8 01/25/2016 21:37 MHALL3 1 EPA 200.8 01/25/2016 21:37 MHALL3 1 EPA 200.8 01/25/2016 21:37 MHALL3 1 EPA 200.8 01/25/2016 21:37 MHALL3 1 EPA 200.8 01/25/2016 21:37 MHALL3 1 EPA 200.8 01/25/2016 21:37 MHALL3 1 EPA 200.8 01/25/2016 21:37 MHALL3 1 EPA 200.8 01/22/2016 02:47 MHALL3 1 EPA 200.8 01/22/2016 02:47 MHALL3 1 EPA 200.8 01/22/2016 02:47 MHALL3 1 EPA 200.8 01/22/2016 02:47 MHALL3 1 EPA 200.8 01/22/2016 02:47 MHALL3 1 EPA 200.8 01/22/2016 02:47 MHALL3 1 EPA 200.8 01/22/2016 02:47 MHALL3 1 EPA 200.8 01/22/2016 02:47 MHALL3 1 EPA 200.8 01/22/2016 02:47 MHALL3 1 EPA 200.8 01/22/2016 02:47 MHALL3 1 EPA 200.8 01/22/2016 02:47 MHALL3 1 EPA 200.8 01/22/2016 02:47 MHALL3 1 EPA 200.8 01/22/2016 02:47 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/25/201615:00 CJELLIO 1 SM5310C/EPA9060A 01/29/201612:21 GHUTCHI 1 SM2540D 01/25/2016 09:41 CJELLIO Certificate of Laboratory Analysis Page 41 of 81 This report shall not be reproduced, except in full. Order # J16010397 Qualifiers: M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to the spike level. The associated Laboratory Control Spike recovery was acceptable. N1 See additional information listed below. -- Additional Information -- N1--The TOC and NO2NO3 samples for CB-08BR were received unpreserved and do not meet preservation requirements per 40 CFR 136 (ph<2). Acid was added to the samples and the data has been flagged. If this data is to be reported on a DMR, the data must be flagged with an explanation. aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinffte. Suite 100 y Huntersville, INC 28078 (704)875-9092 January 27, 2016 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 16010397 Pace Project No.: 92283899 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on January 21, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, C .. Chris Bishop for Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Program Manager, Duke Energy Anne Pifer Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 39 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. OQ9Wigcsfoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J16010397 Pace Project No.: 92283899 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 525 N 8th Street, Salina, KS 67401 A21-A Certification M 2926.01 Alaska Certification M UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification M 88-0680 California Certification M 01155CA Colorado Certification #Pace Connecticut Certification M PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification M 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification M 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification M 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification M 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification M E83079 Georgia Certification M 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification M 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification M E-10383 Kentucky Certification #: 90050 Louisiana Certification M FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification M Cert 0074 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification M TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification M 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J16010397 Pace Project No.: 92283899 Lab ID Sample ID Matrix Date Collected Date Received 92283899001 2016001989 Water 01/20/16 09:34 01/21/1613:00 92283899002 2016001990 Water 01/20/16 09:34 01/21/1613:00 92283899003 2016001991 Water 01/20/1610:49 01/21/1613:00 92283899004 2016001992 Water 01/20/1613:28 01/21/1613:00 92283899005 2016001993 Water 01/20/1614:16 01/21/1613:00 92283899006 2016001994 Water 01/20/1616:05 01/21/1613:00 92283899007 2016001995 Water 01/20/1615:52 01/21/1613:00 92283899008 2016001996 Water 01/20/1611:22 01/21/1613:00 92283899009 2016001997 Water 01/20/1615:20 01/21/1613:00 92283899010 2016001998 Water 01/20/1611:16 01/21/1613:00 92283899011 2016001999 Water 01/20/1613:50 01/21/1613:00 92283899012 2016002000 Water 01/20/1616:40 01/21/1613:00 92283899013 2016002001 Water 01/20/1615:28 01/21/1613:00 92283899014 2016002002 Water 01/20/1612:33 01/21/1613:00 92283899015 2016002004 Water 01/20/1616:45 01/21/1613:00 92283899016 2016002005 Water 01/20/1611:03 01/21/1613:00 92283899017 2016002006 Water 01/20/16 09:45 01/21/16 13:00 92283899018 2016002007 Water 01/20/16 09:20 01/21/1613:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J16010397 92283899 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92283899001 2016001989 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899002 2016001990 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899003 2016001991 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899004 2016001992 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899005 2016001993 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899006 2016001994 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899007 2016001995 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899008 2016001996 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899009 2016001997 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899010 2016001998 RSK 175 STV 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J16010397 Pace Project No.: 92283899 Analytes Lab ID Sample ID Method Analysts Reported Laboratory SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899011 2016001999 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899012 2016002000 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899013 2016002001 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899014 2016002002 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899015 2016002004 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899016 2016002005 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899017 2016002006 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283899018 2016002007 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J16010397 92283899 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92283899001 2016001989 RSK 175 Methane 20.6 ug/L 10.0 01/22/16 12:55 SM 2320B Alkalinity, Bicarbonate (CaCO3) 52.2 mg/L 5.0 01/25/16 15:47 SM 2320B Alkalinity, Total as CaCO3 52.2 mg/L 5.0 01/25/16 15:47 92283899002 2016001990 RSK 175 Methane 21.3 ug/L 10.0 01/22/16 13:03 SM 2320B Alkalinity, Bicarbonate (CaCO3) 52.8 mg/L 5.0 01/25/16 16:20 SM 2320B Alkalinity, Total as CaCO3 52.8 mg/L 5.0 01/25/16 16:20 92283899003 2016001991 SM 2320B Alkalinity, Bicarbonate (CaCO3) 31.8 mg/L 5.0 01/25/16 16:31 SM 2320B Alkalinity, Total as CaCO3 31.8 mg/L 5.0 01/25/16 16:31 EPA218.7 Chromium, Hexavalent 0.18 ug/L 0.030 01/25/1613:26 92283899005 2016001993 SM 2320B Alkalinity, Bicarbonate (CaCO3) 7.8 mg/L 5.0 01/25/16 16:51 SM 2320B Alkalinity, Total as CaCO3 7.8 mg/L 5.0 01/25/16 16:51 92283899006 2016001994 RSK 175 Methane 102 ug/L 10.0 01/22/16 13:36 SM 2320B Alkalinity, Bicarbonate (CaCO3) 58.0 mg/L 5.0 01/25/16 17:02 SM 2320B Alkalinity, Total as CaCO3 58.0 mg/L 5.0 01/25/16 17:02 92283899007 2016001995 SM 2320B Alkalinity, Bicarbonate (CaCO3) 9.0 mg/L 5.0 01/25/16 17:33 SM 2320B Alkalinity, Total as CaCO3 9.0 mg/L 5.0 01/25/16 17:33 EPA218.7 Chromium, Hexavalent 0.25 ug/L 0.030 01/25/1614:18 92283899008 2016001996 EPA218.7 Chromium, Hexavalent 0.12 ug/L 0.030 01/25/1614:31 92283899009 2016001997 SM 2320B Alkalinity, Bicarbonate (CaCO3) 62.1 mg/L 5.0 01/25/16 17:53 SM 2320B Alkalinity, Total as CaCO3 62.1 mg/L 5.0 01/25/16 17:53 EPA218.7 Chromium, Hexavalent 0.12 ug/L 0.030 01/25/1614:44 92283899011 2016001999 EPA218.7 Chromium, Hexavalent 0.076 ug/L 0.030 01/25/1615:36 M1 92283899012 2016002000 SM 2320B Alkalinity, Bicarbonate (CaCO3) 12.9 mg/L 5.0 01/25/16 18:42 SM 2320B Alkalinity, Total as CaCO3 12.9 mg/L 5.0 01/25/16 18:42 EPA218.7 Chromium, Hexavalent 0.27 ug/L 0.030 01/25/1616:15 92283899013 2016002001 SM 2320B Alkalinity, Bicarbonate (CaCO3) 91.0 mg/L 5.0 01/25/16 18:53 SM 2320B Alkalinity, Total as CaCO3 91.0 mg/L 5.0 01/25/16 18:53 92283899014 2016002002 SM 2320B Alkalinity, Bicarbonate (CaCO3) 81.0 mg/L 5.0 01/25/16 19:06 SM 2320B Alkalinity, Total as CaCO3 81.0 mg/L 5.0 01/25/16 19:06 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J16010397 Pace Project No.: 92283899 Lab Sample ID Method 92283899016 SM 2320B SM 2320B EPA 218.7 92283899017 SM 2320B SM 2320B 92283899018 SM 2320B SM 2320B SUMMARY OF DETECTION Client Sample ID Parameters 2016002005 Alkalinity, Bicarbonate (CaCO3) Alkalinity, Total as CaCO3 Chromium, Hexavalent 2016002006 Alkalinity, Bicarbonate (CaCO3) Alkalinity, Total as CaCO3 2016002007 Alkalinity, Bicarbonate (CaCO3) Alkalinity, Total as CaCO3 Result Units 39.4 mg/L 39.4 mg/L 0.50 ug/L 36.8 mg/L 36.8 mg/L 109 mg/L 109 mg/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Report Limit Analyzed Qualifiers 5.0 01/25/1619:46 5.0 01/25/1619:46 0.15 01/26/16 09:10 5.0 01/25/1619:58 5.0 01/25/1619:58 5.0 01/25/16 20:10 5.0 01/25/1620:10 Page 7 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098�t�i .8ffte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010397 Pace Project No.: 92283899 Method: RSK 175 Description: RSK 175 AIR Headspace Client: Duke Energy Date: January 27, 2016 General Information: 18 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010397 Pace Project No.: 92283899 Method: SM 2320B Description: 2320E Alkalinity Client: Duke Energy Date: January 27, 2016 General Information: 18 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onic8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010397 Pace Project No.: 92283899 Method: SM 4500-S213 Description: 4500S2D Sulfide Water Client: Duke Energy Date: January 27, 2016 General Information: 18 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WET/42660 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92283899001,92283899011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1652670) • Sulfide • MSD (Lab ID: 1652671) • Sulfide Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010397 Pace Project No.: 92283899 Method: EPA 218.7 Description: Hexavalent Chromium by IC Client: Duke Energy Date: January 27, 2016 General Information: 18 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/54232 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92283899001,92283899011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1458496) • Chromium. Hexavalent • MSD (Lab ID: 1458497) • Chromium, Hexavalent • MSD (Lab ID: 1458499) • Chromium. Hexavalent Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016001989 Lab ID: 92283899001 Collected: 01/20/16 09:34 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 20.6 ug/L 10.0 1 01/22/1612:55 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 52.2 mg/L 5.0 1 01/25/16 15:47 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 15:47 Alkalinity, Total as CaCO3 52.2 mg/L 5.0 1 01/25/16 15:47 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/25/16 12:34 18540-29-9 M1 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016001990 Lab ID: 92283899002 Collected: 01/20/16 09:34 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 21.3 ug/L 10.0 1 01/22/1613:03 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 52.8 mg/L 5.0 1 01/25/16 16:20 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 16:20 Alkalinity, Total as CaCO3 52.8 mg/L 5.0 1 01/25/16 16:20 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/25/16 13:13 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016001991 Lab ID: 92283899003 Collected: 01/20/16 10:49 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/22/1613:12 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 31.8 mg/L 5.0 1 01/25/16 16:31 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 16:31 Alkalinity, Total as CaCO3 31.8 mg/L 5.0 1 01/25/16 16:31 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.18 ug/L 0.030 1 01/25/16 13:26 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016001992 Lab ID: 92283899004 Collected: 01/20/16 13:28 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/22/1613:20 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/25/16 16:43 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 16:43 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/25/16 16:43 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/25/16 13:39 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016001993 Lab ID: 92283899005 Collected: 01/20/16 14:16 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/22/1613:28 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 7.8 mg/L 5.0 1 01/25/16 16:51 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 16:51 Alkalinity, Total as CaCO3 7.8 mg/L 5.0 1 01/25/16 16:51 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/25/16 13:52 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016001994 Lab ID: 92283899006 Collected: 01/20/16 16:05 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 102 ug/L 10.0 1 01/22/1613:36 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 58.0 mg/L 5.0 1 01/25/16 17:02 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 17:02 Alkalinity, Total as CaCO3 58.0 mg/L 5.0 1 01/25/16 17:02 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/25/16 14:05 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016001995 Lab ID: 92283899007 Collected: 01/20/16 15:52 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/22/1614:05 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 9.0 mg/L 5.0 1 01/25/16 17:33 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 17:33 Alkalinity, Total as CaCO3 9.0 mg/L 5.0 1 01/25/16 17:33 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.25 ug/L 0.030 1 01/25/16 14:18 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016001996 Lab ID: 92283899008 Collected: 01/20/16 11:22 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/22/1614:21 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/25/16 17:44 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 17:44 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/25/16 17:44 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.12 ug/L 0.030 1 01/25/16 14:31 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinlc&�rfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016001997 Lab ID: 92283899009 Collected: 01/20/16 15:20 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/22/1614:29 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 62.1 mg/L 5.0 1 01/25/16 17:53 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 17:53 Alkalinity, Total as CaCO3 62.1 mg/L 5.0 1 01/25/16 17:53 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.12 ug/L 0.030 1 01/25/16 14:44 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016001998 Lab ID: 92283899010 Collected: 01/20/16 11:16 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/22/1614:37 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/25/16 18:05 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 18:05 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/25/16 18:05 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/25/16 14:57 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016001999 Lab ID: 92283899011 Collected: 01/20/16 13:50 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/22/1614:45 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/25/16 18:12 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 18:12 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/25/16 18:12 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 M1 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.076 ug/L 0.030 1 01/25/16 15:36 18540-29-9 M1 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016002000 Lab ID: 92283899012 Collected: 01/20/16 16:40 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/22/1614:54 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 12.9 mg/L 5.0 1 01/25/16 18:42 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 18:42 Alkalinity, Total as CaCO3 12.9 mg/L 5.0 1 01/25/16 18:42 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.27 ug/L 0.030 1 01/25/16 16:15 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016002001 Lab ID: 92283899013 Collected: 01/20/16 15:28 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/22/1615:02 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 91.0 mg/L 5.0 1 01/25/16 18:53 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 18:53 Alkalinity, Total as CaCO3 91.0 mg/L 5.0 1 01/25/16 18:53 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/25/16 16:28 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016002002 Lab ID: 92283899014 Collected: 01/20/16 12:33 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/22/1615:10 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 81.0 mg/L 5.0 1 01/25/16 19:06 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 19:06 Alkalinity, Total as CaCO3 81.0 mg/L 5.0 1 01/25/16 19:06 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/25/16 16:41 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016002004 Lab ID: 92283899015 Collected: 01/20/16 16:45 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/22/1615:18 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/25/16 19:38 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 19:38 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/25/16 19:38 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/25/16 16:54 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016002005 Lab ID: 92283899016 Collected: 01/20/16 11:03 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/22/1615:56 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 39.4 mg/L 5.0 1 01/25/16 19:46 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 19:46 Alkalinity, Total as CaCO3 39.4 mg/L 5.0 1 01/25/16 19:46 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.50 ug/L 0.15 5 01/26/16 09:10 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016002006 Lab ID: 92283899017 Collected: 01/20/16 09:45 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/22/1616:05 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 36.8 mg/L 5.0 1 01/25/16 19:58 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 19:58 Alkalinity, Total as CaCO3 36.8 mg/L 5.0 1 01/25/16 19:58 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/25/16 17:20 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010397 Pace Project No.: 92283899 Sample: 2016002007 Lab ID: 92283899018 Collected: 01/20/16 09:20 Received: 01/21/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/22/1616:13 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 109 mg/L 5.0 1 01/25/16 20:10 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/25/16 20:10 Alkalinity, Total as CaCO3 109 mg/L 5.0 1 01/25/16 20:10 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/26/1612:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/25/16 17:33 18540-29-9 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098�t�inic&�rfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010397 Pace Project No.: 92283899 QC Batch: AIR/25074 Analysis Method: RSK 175 QC Batch Method: RSK 175 Analysis Description: RSK 175 AIR HEADSPACE Associated Lab Samples: 92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007, 92283899008,92283899009,92283899010,92283899011,92283899012,92283899013,92283899014, 92283899015 METHOD BLANK: 2179438 Matrix: Water Associated Lab Samples: 92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007, 92283899008,92283899009,92283899010,92283899011,92283899012,92283899013,92283899014, 92283899015 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Methane ug/L ND 10.0 01/22/1612:15 LABORATORY CONTROL SAMPLE & LCSD: 2179439 2179440 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Methane ug/L 60.7 60.9 54.9 100 91 85-115 10 20 SAMPLE DUPLICATE: 2179569 92283758001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L 1.5J 1.3J 20 SAMPLE DUPLICATE: 2179570 92283899007 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 2.7J 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/27/2016 01:24 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010397 Pace Project No.: 92283899 QC Batch: AIR/25075 Analysis Method: RSK 175 QC Batch Method: RSK 175 Analysis Description: RSK 175 AIR HEADSPACE Associated Lab Samples: 92283899016, 92283899017, 92283899018 METHOD BLANK: 2179443 Matrix: Water Associated Lab Samples: 92283899016, 92283899017, 92283899018 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Methane ug/L ND 10.0 01/22/1615:40 LABORATORY CONTROL SAMPLE & LCSD: 2179444 2179445 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Methane ug/L 60.7 54.9 60.0 91 99 85-115 9 20 SAMPLE DUPLICATE: 2180110 92283899016 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 1.11 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/27/2016 01:24 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010397 Pace Project No.: 92283899 QC Batch: WET/42657 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007, 92283899008,92283899009,92283899010,92283899011,92283899012,92283899013,92283899014, 92283899015,92283899016,92283899017,92283899018 METHOD BLANK: 1652541 Matrix: Water Associated Lab Samples: 92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007, 92283899008,92283899009,92283899010,92283899011,92283899012,92283899013,92283899014, 92283899015,92283899016,92283899017,92283899018 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Alkalinity, Carbonate (CaCO3) mg/L ND 5.0 01/25/16 15:25 Alkalinity, Total as CaCO3 mg/L ND 5.0 01/25/16 15:25 Alkalinity, Bicarbonate (CaCO3) mg/L ND 5.0 01/25/16 15:25 LABORATORY CONTROL SAMPLE: 1652542 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 48.1 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1652543 1652544 MS MSD 92283899001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 52.2 50 50 102 99.5 100 95 80-120 3 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1652545 1652546 MS MSD 92283899011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L ND 50 50 53.0 53.0 97 97 80-120 0 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/27/2016 01:24 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010397 Pace Project No.: 92283899 QC Batch: WET/42660 Analysis Method: SM 4500-S2D QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007, 92283899008,92283899009,92283899010,92283899011,92283899012,92283899013,92283899014, 92283899015,92283899016,92283899017,92283899018 METHOD BLANK: 1652666 Matrix: Water Associated Lab Samples: 92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007, 92283899008,92283899009,92283899010,92283899011,92283899012,92283899013,92283899014, 92283899015,92283899016,92283899017,92283899018 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide mg/L ND 0.10 01/26/1612:00 LABORATORY CONTROL SAMPLE: 1652667 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide mg/L .5 0.51 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1652668 1652669 MS MSD 92283899001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Sulfide mg/L ND .5 .5 0.54 0.54 108 108 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1652670 1652671 MS MSD 92283899011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide mg/L ND .5 .5 0.43 0.43 87 87 90-110 0 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/27/2016 01:24 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010397 Pace Project No.: 92283899 QC Batch: WETA/54232 Analysis Method: EPA 218.7 QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC Associated Lab Samples: 92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007, 92283899008,92283899009,92283899010,92283899011,92283899012,92283899013,92283899014, 92283899015,92283899016,92283899017,92283899018 METHOD BLANK: 1458494 Matrix: Water Associated Lab Samples: 92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007, 92283899008,92283899009,92283899010,92283899011,92283899012,92283899013,92283899014, 92283899015,92283899016,92283899017,92283899018 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chromium, Hexavalent ug/L ND 0.030 01/25/16 11:45 LABORATORY CONTROL SAMPLE: 1458495 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chromium, Hexavalent ug/L .075 0.074 98 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1458496 1458497 MS MSD 92283899001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Chromium, Hexavalent ug/L ND .025 .025 0.035 0.031 139 125 85-115 11 20 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1458498 1458499 MS MSD 92283899011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent ug/L 0.076 .075 .075 0.14 0.14 88 83 85-115 2 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/27/2016 01:24 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J16010397 Pace Project No.: 92283899 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/27/2016 01:24 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 39 acmnalytical www.pacelabs.com Pace Analytical Services, Inc. ogp I gcgf&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J16010397 Pace Project No.: 92283899 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92283899001 2016001989 RSK 175 AIR/25074 92283899002 2016001990 RSK 175 AIR/25074 92283899003 2016001991 RSK 175 AIR/25074 92283899004 2016001992 RSK 175 AIR/25074 92283899005 2016001993 RSK 175 AIR/25074 92283899006 2016001994 RSK 175 AIR/25074 92283899007 2016001995 RSK 175 AIR/25074 92283899008 2016001996 RSK 175 AIR/25074 92283899009 2016001997 RSK 175 AIR/25074 92283899010 2016001998 RSK 175 AIR/25074 92283899011 2016001999 RSK 175 AIR/25074 92283899012 2016002000 RSK 175 AIR/25074 92283899013 2016002001 RSK 175 AIR/25074 92283899014 2016002002 RSK 175 AIR/25074 92283899015 2016002004 RSK 175 AIR/25074 92283899016 2016002005 RSK 175 AIR/25075 92283899017 2016002006 RSK 175 AIR/25075 92283899018 2016002007 RSK 175 AIR/25075 92283899001 2016001989 SM 2320B WET/42657 92283899002 2016001990 SM 2320B WET/42657 92283899003 2016001991 SM 2320B WET/42657 92283899004 2016001992 SM 2320B WET/42657 92283899005 2016001993 SM 2320B WET/42657 92283899006 2016001994 SM 2320B WET/42657 92283899007 2016001995 SM 2320B WET/42657 92283899008 2016001996 SM 2320B WET/42657 92283899009 2016001997 SM 2320B WET/42657 92283899010 2016001998 SM 2320B WET/42657 92283899011 2016001999 SM 2320B WET/42657 92283899012 2016002000 SM 2320B WET/42657 92283899013 2016002001 SM 2320B WET/42657 92283899014 2016002002 SM 2320B WET/42657 92283899015 2016002004 SM 2320B WET/42657 92283899016 2016002005 SM 2320B WET/42657 92283899017 2016002006 SM 2320B WET/42657 92283899018 2016002007 SM 2320B WET/42657 92283899001 2016001989 SM 4500-S2D WET/42660 92283899002 2016001990 SM 4500-S2D WET/42660 92283899003 2016001991 SM 4500-S2D WET/42660 92283899004 2016001992 SM 4500-S2D WET/42660 92283899005 2016001993 SM 4500-S2D WET/42660 92283899006 2016001994 SM 4500-S2D WET/42660 92283899007 2016001995 SM 4500-S2D WET/42660 92283899008 2016001996 SM 4500-S2D WET/42660 92283899009 2016001997 SM 4500-S2D WET/42660 92283899010 2016001998 SM 4500-S2D WET/42660 92283899011 2016001999 SM 4500-S2D WET/42660 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /27/2016 01:24 PM without the written consent of Pace Analytical Services, Inc.. Page 36 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J16010397 Pace Project No.: 92283899 Lab ID Sample ID QC Batch Method QC Batch 92283899012 2016002000 SM 4500-S2D WET/42660 92283899013 2016002001 SM 4500-S2D WET/42660 92283899014 2016002002 SM 4500-S2D WET/42660 92283899015 2016002004 SM 4500-S2D WET/42660 92283899016 2016002005 SM 4500-S2D WET/42660 92283899017 2016002006 SM 4500-S2D WET/42660 92283899018 2016002007 SM 4500-S2D WET/42660 92283899001 2016001989 EPA 218.7 WETA/54232 92283899002 2016001990 EPA 218.7 WETA/54232 92283899003 2016001991 EPA 218.7 WETA/54232 92283899004 2016001992 EPA 218.7 WETA/54232 92283899005 2016001993 EPA 218.7 WETA/54232 92283899006 2016001994 EPA 218.7 WETA/54232 92283899007 2016001995 EPA 218.7 WETA/54232 92283899008 2016001996 EPA 218.7 WETA/54232 92283899009 2016001997 EPA 218.7 WETA/54232 92283899010 2016001998 EPA 218.7 WETA/54232 92283899011 2016001999 EPA 218.7 WETA/54232 92283899012 2016002000 EPA 218.7 WETA/54232 92283899013 2016002001 EPA 218.7 WETA/54232 92283899014 2016002002 EPA 218.7 WETA/54232 92283899015 2016002004 EPA 218.7 WETA/54232 92283899016 2016002005 EPA 218.7 WETA/54232 92283899017 2016002006 EPA 218.7 WETA/54232 92283899018 2016002007 EPA 218.7 WETA/54232 Date: 01/27/2016 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Method Analytical Batch Page 37 of 39 Document Name: Document Revised: 26OCT2015 �JceAnatXica( Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: r F-CHR-CS-003-rev.17 Pace Huntersville Quality Office Client Name: Project #: Courier: [—]Fed Ex.� ❑UPS ❑LISPS [—]Client ❑Commercial OPace ❑Other: 111111111111111111111111 92263899 Custody Seal on Cooler/Box Present? ❑Yes_- Wo Seals Intact? ❑Yes ❑No Packing Material: ❑Bu le Wrap ❑ ubB ble Bags None Other: Thermometer O' 5Q5 Used: Type of Ice: '[lWet []Blue ❑None .❑Samples on ice, cooling process has begun Cooler Temp Corrected (°C); L_J . Biological Tissue Frozen? ❑Yes . ' ❑Nq . ❑N/A Temp should be above freezing to VC Correction Factor: 0.0 °C Date and Initials of Person Examining. Contents: A USDA Regulated Soil (❑ N/A, water sample) Did samples orig a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a.foreign source (internationally, ❑Yes ❑No including Hawaii and Puerto Rico)? ❑Yes ❑NV'o If Yes to either question, fill out a Regulated Soil Checklist and Include with SCUR/COC paperwork, COMMENTS: Chain of Custody Present? OYes No ❑N/A 1. Chain of Custody Filled Out? ❑ es ONo ❑N/A 2. Chain of Custody Relinquished? ❑ es No-' El N/A 3. Sampler Name and/or Signature on COC? [a es No ❑N/A 4, Samples Arrived within Hold Time? es o ❑N/A S. Short Hold Time Analysis (<72 hr)? E I es ❑No ❑N/A 6. Rush Turn Around Time Requested? ❑Yes No ❑N/A 7. Sufficient Volume? []Yes El No ❑N/A 8. Correct Containers Used? Yes ❑Na/®N/A 9. -Pace Containers Used? ❑Yes 06 ❑N/A Containers Intact? Q es [-]No ❑N/A 1 . Filtered Volume Received for Dissolved Tests? []Yes (]No ❑Nr 11. Note if sediment is visible in the dissolved container Sample Labels Match COC? ❑Yes ❑No ❑N/A 12. -Includes Date/Time/ID/Analysis Matrix: All containers needing acid/base preservation have been checked? ❑Yes ❑No [I N/A 13 All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2SO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide) ❑ es ❑No ❑N/A Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC,LLHg ❑Yes ❑No 17.19'/A n Samples checked fordechlorization ❑Yes [:]No N/ 14. Headspace in VOA Vials (>5-6mm)? ❑Yes [:]No N 15. Trip Blank Present? ❑Yes ❑No El 16. Trip Blank Custody Seals Present? ❑Yes ❑ No N/A Pace Trip Blank Lot # (if purchased): CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Date/Time: Field Data Required? Des ❑No Project Manager SCURF Review: Date; 12l lt~p Note: whenever there is a discrepancy affecting North Carof a compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers). Page 38 of 39 Page 80 of 81 8 M 1 3 c c Ci II 4 S` C 0 m m r c NmM 0 3 `� z z V cn 6i cr K \. \ 1 c" = A N Cl cu -Q . W 3-n R �r Ryp o �V a n R In CY 41 3M Q 6 Cn V CL S y � � C - - r- zw _ V Customer, important: please indicate desired turnaround c. rl •� �`ti+ -4 • Chi w Q ? c N 6 OI a n y i c _ n v I I r i a Ijr'j In �h hA c Page 39 of 39 CHAIN OF CUSTODY RECORD AND ANALYStS REQUEST FORM Page 81 of 81 ji�ixw ---------------- — ------ ........... A ........... ..Ar L41:m................... -------- ......... -11 r" i . ng"= U*E chn!z Duke E110Fgy I or 1 hW Code 01GOAP 40 V 74041� 1 j0f*r* Matrix GW_WW r-ags-1.- . . � I j � 'l , .71, 1 -1 i Aria lyticall Laboratory I=w 14g— P." Rd I I I DISTRIBUTION i Chwfwj 0 C�u*tw%V L Mmr*WWWW. N.C. 29M !L49W BY imlGINAL W LAR. COPY I -- I&&% A Thee Sample Log ATN-V�& ! __ - 4, Ground Weer MIMS Syrtterra EVI) ivww ABGWASa05*dVll W21111 F� � 6 1 " (_rOnrcrig WIN& CRAUET_ W406— COC REV [)ATE I - ---------- A 'a-1 T 9ytlTsrra M-475 5031 Pace FillrErtlon (0.4ar Uffl) Ufffilt"1111 Elusinows UrIM Fmw ce—?. Irank, P0 1142081 W21WA N'H_1 1u. CDaLsl"r Volume (mL) 2M 40 ml M* ras Sao am N 2SO O $OO 50 &Bt" ASIHEV[LLE Ty"' pl!t gL.. PET PET PET PET ipuPE FOPE HDM HDFf ;L- Sam pie DHsc ription of 10 QrSfAm" F0 COANAWO 0 3PPIL)Wlatc .9 T nr-Ahfl'"rj L) a U) F_ ui ------------------- la 0 g I a I zg r !.11 i GP3 Location > Ohle T1. Z Ly 001 ci ilcl i AAVJ- F5 2.6 zq q a AmW- DuP z 7 I—L—L L q 4.1 AAA W c ZPA i 3eg I-U-/4 jq14 '7 j qq4 f Z A,1122-- L; F- t z I 1 1 I b AA W a j 11 M yjw vz 1)t Z- Z. I AAW-olS Filter Blank Euipment Blank�°Fa°2 Z (x Ij J u, D I- —U1 09qs, M W1. AZ V4�vq 6f—. p-20 �62f4z_o WOONUL I HEI Customer lo Won 04W 0alaw RIM` " Oatm;T mand Requested Turna12! o iu7iz '14 Dap If 6T /_7 X �&Wn'quisbed N'y nabOTime A&FA ac) <7 —1 Se4LVLocLsd By Damonnu .4#Hr a — FLEMENTS by JGI' MS [TRMI-, An. Be, Cd, Ca, CF. 0 % MD, N1, Pb, 5b, So, TI lLll, V @LL) E-f'Hher ASAP ELEMENTS by 1CP JTRMJ,� Al, On, 0, Fs, Mit, Sr, In 1CP_UF0g&oW Co, Mg, K, Nm HU kay U5.1 Add. Godir VAR Apply