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Home My WebLink AboutNC0000396_J16010376-F_20160831DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report Order Number: J16010376 Project Name: ASHEVILLE - AB GW ASSESSMENT WATER Customer Name(s): Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu Customer Address: 200 CP and L Drive Arden,NC 28704 Lab Contact: Anne Pifer Phone: Report Authorized By: pate: 2/5/2016 (Signature) Anne Pifer Program Comments: Please contact the Program Manager (Anne Pifer) with any questions regarding this report. Data Flags & Calculations: Page 1 of 75 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Page 2 of 75 Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2016001905 ASHEVILLE 19-Jan-16 3:55 PM illegible MW-10 2016001907 ASHEVILLE 19-Jan-16 2:44 PM illegible AMW-2A 2016001908 ASHEVILLE 19-Jan-16 1:27 PM illegible MW-24S 2016001909 ASHEVILLE 19-Jan-16 10:58 AM illegible MW-23DL 2016001910 ASHEVILLE 19-Jan-16 10:35 AM illegible MW-23DU 2016001911 ASHEVILLE 19-Jan-16 3:12 PM illegible CB-4 2016001912 ASHEVILLE 19-Jan-16 3:45 PM illegible CB-41B 2016001913 ASHEVILLE 19-Jan-16 11:14 AM illegible MW-05D 2016001914 ASHEVILLE 19-Jan-16 11:58 AM illegible MW-05BR 2016001915 ASHEVILLE 19-Jan-16 4:28 PM illegible MW-18D 2016001916 ASHEVILLE 19-Jan-16 3:20 PM illegible MW-18BR 2016001917 ASHEVILLE 19-Jan-16 12:08 PM illegible MW-17A 2016001918 ASHEVILLE 19-Jan-16 10:20 AM illegible MW-16BR 2016001919 ASHEVILLE 19-Jan-16 4:15 PM illegible FILTER BLANK 2016001920 ASHEVILLE 19-Jan-16 4:15 PM illegible EQUIPMENT BLANK 2016001921 ASHEVILLE 19-Jan-16 10:35 AM illegible MW-23DU DUP 2016001922 ASHEVILLE 19-Jan-16 2:23 PM illegible CB-07 17 Total Samples Page 3 of 75 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification ❑ Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report OV Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries ❑ Chain of Custody ❑ Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 2/5/2016 Certificate of Laboratory Analysis Page 4 of 75 This report shall not be reproduced, except in full. Order # J16010376 Site: MW-10 Collection Date: 19-Jan-16 3:55 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.099 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 14 mg/L 0.5 Sulfate 0.29 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 0.10 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.038 mg/L 0.005 Barium (Ba) 0.050 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.056 mg/L 0.01 Manganese (Mn) 0.196 mg/L 0.005 Strontium (Sr) 0.026 mg/L 0.005 Zinc (Zn) 0.022 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 2.32 mg/L 0.01 Magnesium (Mg) 2.80 mg/L 0.005 Potassium (K) 1.35 mg/L 0.1 Sodium (Na) 4.85 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.044 mg/L 0.005 Barium (Ba) 0.054 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.063 mg/L 0.01 Manganese (Mn) 0.185 mg/L 0.005 Strontium (Sr) 0.025 mg/L 0.005 Zinc (Zn) 0.015 mg/L 0.005 Sample #: 2016001905 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:27 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/21/2016 11:37 BGN9034 1 EPA 300.0 01/21/2016 11:37 BGN9034 1 EPA 245.1 01/26/2016 17:13 ACPAYNE 1 EPA 245.1 01/27/2016 14:41 ACPAYNE 1 EPA 200.7 01/20/2016 13:08 FCJORDA 1 EPA 200.7 01/20/2016 13:08 FCJORDA 1 EPA 200.7 01/20/2016 13:08 FCJORDA 1 EPA 200.7 01/20/2016 13:08 FCJORDA 1 EPA 200.7 01/20/2016 13:08 FCJORDA 1 EPA 200.7 01/20/2016 13:08 FCJORDA 1 EPA 200.7 01/20/2016 13:08 FCJORDA 1 EPA 200.7 01/20/2016 16:46 FCJORDA 1 EPA 200.7 01/20/2016 16:46 FCJORDA 1 EPA 200.7 01/20/2016 16:46 FCJORDA 1 EPA 200.7 01/20/2016 16:46 FCJORDA 1 EPA 200.7 01/21/2016 12:37 FCJORDA 1 EPA 200.7 01/21/2016 12:37 FCJORDA 1 EPA 200.7 01/21/2016 12:37 FCJORDA 1 EPA 200.7 01/21/2016 12:37 FCJORDA 1 EPA 200.7 01/21/2016 12:37 FCJORDA 1 EPA 200.7 01/21/2016 12:37 FCJORDA 1 EPA 200.7 01/21/2016 12:37 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-10 Collection Date: 19-Jan-16 3:55 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 3.03 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 3.08 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 2.99 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 2.78 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 40 mg/L 25 Total Carbon TOC 0.625 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 5 of 75 Sample #: 2016001905 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 22:28 MHALL3 1 EPA 200.8 01/21/2016 22:28 MHALL3 1 EPA 200.8 01/21/2016 22:28 MHALL3 1 EPA 200.8 01/21/2016 22:28 MHALL3 1 EPA 200.8 01/21/2016 22:28 MHALL3 1 EPA 200.8 01/21/2016 22:28 MHALL3 1 EPA 200.8 01/21/2016 22:28 MHALL3 1 EPA 200.8 01/21/2016 22:28 MHALL3 1 EPA 200.8 01/21/2016 22:28 MHALL3 1 EPA 200.8 01/21/2016 22:28 MHALL3 1 EPA 200.8 01/21/2016 22:28 MHALL3 1 EPA 200.8 01/21/2016 22:28 MHALL3 1 EPA 200.8 01/21/2016 22:28 MHALL3 1 EPA 200.8 01/21/2016 15:13 MHALL3 1 EPA 200.8 01/21/2016 15:13 MHALL3 1 EPA 200.8 01/21/2016 15:13 MHALL3 1 EPA 200.8 01/21/2016 15:13 MHALL3 1 EPA 200.8 01/21/2016 15:13 MHALL3 1 EPA 200.8 01/21/2016 15:13 MHALL3 1 EPA 200.8 01/21/2016 15:13 MHALL3 1 EPA 200.8 01/21/2016 15:13 MHALL3 1 EPA 200.8 01/21/2016 15:13 MHALL3 1 EPA 200.8 01/21/2016 15:13 MHALL3 1 EPA 200.8 01/21/2016 15:13 MHALL3 1 EPA 200.8 01/21/2016 15:13 MHALL3 1 EPA 200.8 01/21/2016 15:13 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/24/201615:28 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/24/201612:45 CJELLIO Certificate of Laboratory Analysis Page 6 of 75 This report shall not be reproduced, except in full. Order # J16010376 Site: AMW-2A Collection Date: 19-Jan-16 2:44 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.018 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 7.7 mg/L 1 Sulfate 51 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.040 mg/L 0.005 Barium (Ba) 0.047 mg/L 0.005 Boron (B) 0.121 mg/L 0.05 Iron (Fe) 23.6 mg/L 0.01 Manganese (Mn) 2.84 mg/L 0.005 Strontium (Sr) 0.161 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 16.9 mg/L 0.01 Magnesium (Mg) 5.17 mg/L 0.005 Potassium (K) 3.17 mg/L 0.1 Sodium (Na) 9.34 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.049 mg/L 0.005 Barium (Ba) 0.055 mg/L 0.005 Boron (B) 0.132 mg/L 0.05 Iron (Fe) 25.7 mg/L 0.01 Manganese (Mn) 3.11 mg/L 0.005 Strontium (Sr) 0.174 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001907 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:28 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/21/2016 11:54 BGN9034 10 EPA 300.0 01/21/2016 11:54 BGN9034 1 EPA 245.1 01/26/2016 17:20 ACPAYNE 1 EPA 245.1 01/27/2016 14:43 ACPAYNE 1 EPA 200.7 01/20/2016 13:24 FCJORDA 1 EPA 200.7 01/20/2016 13:24 FCJORDA 1 EPA 200.7 01/20/2016 13:24 FCJORDA 1 EPA 200.7 01/20/2016 13:24 FCJORDA 1 EPA 200.7 01/20/2016 13:24 FCJORDA 1 EPA 200.7 01/20/2016 13:24 FCJORDA 1 EPA 200.7 01/20/2016 13:24 FCJORDA 1 EPA 200.7 01/20/2016 16:50 FCJORDA 1 EPA 200.7 01/20/2016 16:50 FCJORDA 1 EPA 200.7 01/20/2016 16:50 FCJORDA 1 EPA 200.7 01/20/2016 16:50 FCJORDA 1 EPA 200.7 01/21/2016 12:48 FCJORDA 1 EPA 200.7 01/21/2016 12:48 FCJORDA 1 EPA 200.7 01/21/2016 12:48 FCJORDA 1 EPA 200.7 01/21/2016 12:48 FCJORDA 1 EPA 200.7 01/21/2016 12:48 FCJORDA 1 EPA 200.7 01/21/2016 12:48 FCJORDA 1 EPA 200.7 01/21/2016 12:48 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: AMW-2A Collection Date: 19-Jan-16 2:44 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 21.3 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 2.46 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 20.5 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 2.21 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 140 mg/L 25 Total Carbon TOC 2.1 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 7 of 75 Sample #: 2016001907 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 22:33 MHALL3 1 EPA 200.8 01/21/2016 22:33 MHALL3 1 EPA 200.8 01/21/2016 22:33 MHALL3 1 EPA 200.8 01/21/2016 22:33 MHALL3 1 EPA 200.8 01/21/2016 22:33 MHALL3 1 EPA 200.8 01/21/2016 22:33 MHALL3 1 EPA 200.8 01/21/2016 22:33 MHALL3 1 EPA 200.8 01/21/2016 22:33 MHALL3 1 EPA 200.8 01/21/2016 22:33 MHALL3 1 EPA 200.8 01/21/2016 22:33 MHALL3 1 EPA 200.8 01/21/2016 22:33 MHALL3 1 EPA 200.8 01/21/2016 22:33 MHALL3 1 EPA 200.8 01/21/2016 22:33 MHALL3 1 EPA 200.8 01/21/2016 14:32 MHALL3 1 EPA 200.8 01/21/2016 14:32 MHALL3 1 EPA 200.8 01/21/2016 14:32 MHALL3 1 EPA 200.8 01/21/2016 14:32 MHALL3 1 EPA 200.8 01/21/2016 14:32 MHALL3 1 EPA 200.8 01/21/2016 14:32 MHALL3 1 EPA 200.8 01/21/2016 14:32 MHALL3 1 EPA 200.8 01/21/2016 14:32 MHALL3 1 EPA 200.8 01/21/2016 14:32 MHALL3 1 EPA 200.8 01/21/2016 14:32 MHALL3 1 EPA 200.8 01/21/2016 14:32 MHALL3 1 EPA 200.8 01/21/2016 14:32 MHALL3 1 EPA 200.8 01/21/2016 14:32 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/24/201615:28 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/24/201612:45 CJELLIO Certificate of Laboratory Analysis Page 8 of 75 This report shall not be reproduced, except in full. Order # J16010376 Site: MW-24S Collection Date: 19-Jan-16 1:27 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 1.1 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 14 mg/L 1 Sulfate 0.66 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.028 mg/L 0.005 Barium (Ba) 0.051 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.146 mg/L 0.005 Strontium (Sr) 0.037 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 3.03 mg/L 0.01 Magnesium (Mg) 3.65 mg/L 0.005 Potassium (K) 1.49 mg/L 0.1 Sodium (Na) 3.31 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.038 mg/L 0.005 Barium (Ba) 0.056 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.150 mg/L 0.005 Strontium (Sr) 0.037 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001908 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:29 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/25/2016 10:31 BGN9034 1 EPA 300.0 01/25/2016 10:31 BGN9034 1 EPA 245.1 01/26/2016 17:23 ACPAYNE 1 EPA 245.1 01/27/2016 14:46 ACPAYNE 1 EPA 200.7 01/20/2016 13:35 FCJORDA 1 EPA 200.7 01/20/2016 13:35 FCJORDA 1 EPA 200.7 01/20/2016 13:35 FCJORDA 1 EPA 200.7 01/20/2016 13:35 FCJORDA 1 EPA 200.7 01/20/2016 13:35 FCJORDA 1 EPA 200.7 01/20/2016 13:35 FCJORDA 1 EPA 200.7 01/20/2016 13:35 FCJORDA 1 EPA 200.7 01/20/2016 16:54 FCJORDA 1 EPA 200.7 01/20/2016 16:54 FCJORDA 1 EPA 200.7 01/20/2016 16:54 FCJORDA 1 EPA 200.7 01/20/2016 16:54 FCJORDA 1 EPA 200.7 01/21/2016 12:52 FCJORDA 1 EPA 200.7 01/21/2016 12:52 FCJORDA 1 EPA 200.7 01/21/2016 12:52 FCJORDA 1 EPA 200.7 01/21/2016 12:52 FCJORDA 1 EPA 200.7 01/21/2016 12:52 FCJORDA 1 EPA 200.7 01/21/2016 12:52 FCJORDA 1 EPA 200.7 01/21/2016 12:52 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-24S Collection Date: 19-Jan-16 1:27 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.06 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.02 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 36 mg/L 25 Total Carbon TOC 0.193 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 9 of 75 Sample #: 2016001908 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 22:38 MHALL3 1 EPA 200.8 01/21/2016 22:38 MHALL3 1 EPA 200.8 01/21/2016 22:38 MHALL3 1 EPA 200.8 01/21/2016 22:38 MHALL3 1 EPA 200.8 01/21/2016 22:38 MHALL3 1 EPA 200.8 01/21/2016 22:38 MHALL3 1 EPA 200.8 01/21/2016 22:38 MHALL3 1 EPA 200.8 01/21/2016 22:38 MHALL3 1 EPA 200.8 01/21/2016 22:38 MHALL3 1 EPA 200.8 01/21/2016 22:38 MHALL3 1 EPA 200.8 01/21/2016 22:38 MHALL3 1 EPA 200.8 01/21/2016 22:38 MHALL3 1 EPA 200.8 01/21/2016 22:38 MHALL3 1 EPA 200.8 01/21/2016 15:03 MHALL3 1 EPA 200.8 01/21/2016 15:03 MHALL3 1 EPA 200.8 01/21/2016 15:03 MHALL3 1 EPA 200.8 01/21/2016 15:03 MHALL3 1 EPA 200.8 01/21/2016 15:03 MHALL3 1 EPA 200.8 01/21/2016 15:03 MHALL3 1 EPA 200.8 01/21/2016 15:03 MHALL3 1 EPA 200.8 01/21/2016 15:03 MHALL3 1 EPA 200.8 01/21/2016 15:03 MHALL3 1 EPA 200.8 01/21/2016 15:03 MHALL3 1 EPA 200.8 01/21/2016 15:03 MHALL3 1 EPA 200.8 01/21/2016 15:03 MHALL3 1 EPA 200.8 01/21/2016 15:03 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/24/201615:28 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/24/201612:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-23DL Collection Date: 19-Jan-16 10:58 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.020 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 4.0 mg/L 0.1 Sulfate 22 mg/L 0.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.026 mg/L 0.005 Barium (Ba) 0.014 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 10.7 mg/L 0.01 Manganese (Mn) 0.082 mg/L 0.005 Strontium (Sr) 0.114 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 34.5 mg/L 0.01 Magnesium (Mg) 4.17 mg/L 0.005 Potassium (K) 3.19 mg/L 0.1 Sodium (Na) 6.85 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.026 mg/L 0.005 Barium (Ba) 0.014 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 11.6 mg/L 0.01 Manganese (Mn) 0.087 mg/L 0.005 Strontium (Sr) 0.119 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001909 Matrix: GW WW Page 10 of 75 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:31 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/21/2016 14:42 BGN9034 5 EPA 300.0 01/21/2016 14:42 BGN9034 1 EPA 245.1 01/26/2016 17:25 ACPAYNE 1 EPA 245.1 01/27/2016 14:48 ACPAYNE 1 EPA 200.7 01/20/2016 13:39 FCJORDA 1 EPA 200.7 01/20/2016 13:39 FCJORDA 1 EPA 200.7 01/20/2016 13:39 FCJORDA 1 EPA 200.7 01/20/2016 13:39 FCJORDA 1 EPA 200.7 01/20/2016 13:39 FCJORDA 1 EPA 200.7 01/20/2016 13:39 FCJORDA 1 EPA 200.7 01/20/2016 13:39 FCJORDA 1 EPA 200.7 01/20/2016 16:58 FCJORDA 1 EPA 200.7 01/20/2016 16:58 FCJORDA 1 EPA 200.7 01/20/2016 16:58 FCJORDA 1 EPA 200.7 01/20/2016 16:58 FCJORDA 1 EPA 200.7 01/21/2016 12:56 FCJORDA 1 EPA 200.7 01/21/2016 12:56 FCJORDA 1 EPA 200.7 01/21/2016 12:56 FCJORDA 1 EPA 200.7 01/21/2016 12:56 FCJORDA 1 EPA 200.7 01/21/2016 12:56 FCJORDA 1 EPA 200.7 01/21/2016 12:56 FCJORDA 1 EPA 200.7 01/21/2016 12:56 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-23DL Collection Date: 19-Jan-16 10:58 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 10.7 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 150 mg/L 25 Total Carbon TOC 0.179 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 22 mg/L 5 Page 11 of 75 Sample #: 2016001909 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 22:43 MHALL3 1 EPA 200.8 01/21/2016 22:43 MHALL3 1 EPA 200.8 01/21/2016 22:43 MHALL3 1 EPA 200.8 01/21/2016 22:43 MHALL3 1 EPA 200.8 01/21/2016 22:43 MHALL3 1 EPA 200.8 01/21/2016 22:43 MHALL3 1 EPA 200.8 01/21/2016 22:43 MHALL3 1 EPA 200.8 01/21/2016 22:43 MHALL3 1 EPA 200.8 01/21/2016 22:43 MHALL3 1 EPA 200.8 01/21/2016 22:43 MHALL3 1 EPA 200.8 01/21/2016 22:43 MHALL3 1 EPA 200.8 01/21/2016 22:43 MHALL3 1 EPA 200.8 01/21/2016 22:43 MHALL3 1 EPA 200.8 01/21/2016 15:08 MHALL3 1 EPA 200.8 01/21/2016 15:08 MHALL3 1 EPA 200.8 01/21/2016 15:08 MHALL3 1 EPA 200.8 01/21/2016 15:08 MHALL3 1 EPA 200.8 01/21/2016 15:08 MHALL3 1 EPA 200.8 01/21/2016 15:08 MHALL3 1 EPA 200.8 01/21/2016 15:08 MHALL3 1 EPA 200.8 01/21/2016 15:08 MHALL3 1 EPA 200.8 01/21/2016 15:08 MHALL3 1 EPA 200.8 01/21/2016 15:08 MHALL3 1 EPA 200.8 01/21/2016 15:08 MHALL3 1 EPA 200.8 01/21/2016 15:08 MHALL3 1 EPA 200.8 01/21/2016 15:08 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/24/201615:28 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/24/201612:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-23DU Collection Date: 19-Jan-16 10:35 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.454 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 8.0 mg/L 0.1 Sulfate 20 mg/L 0.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.009 mg/L 0.005 Barium (Ba) 0.034 mg/L 0.005 Boron (B) 0.080 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.265 mg/L 0.005 Strontium (Sr) 0.037 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 5.25 mg/L 0.01 Magnesium (Mg) 3.20 mg/L 0.005 Potassium (K) 1.48 mg/L 0.1 Sodium (Na) 8.62 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.030 mg/L 0.005 Barium (Ba) 0.038 mg/L 0.005 Boron (B) 0.084 mg/L 0.05 Iron (Fe) 0.478 mg/L 0.01 Manganese (Mn) 0.301 mg/L 0.005 Strontium (Sr) 0.038 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001910 Matrix: GW WW Page 12 of 75 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:32 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/21/2016 14:59 BGN9034 5 EPA 300.0 01/21/2016 14:59 BGN9034 1 EPA 245.1 01/26/2016 17:28 ACPAYNE 1 EPA 245.1 01/27/2016 14:50 ACPAYNE 1 EPA 200.7 01/20/2016 13:43 FCJORDA 1 EPA 200.7 01/20/2016 13:43 FCJORDA 1 EPA 200.7 01/20/2016 13:43 FCJORDA 1 EPA 200.7 01/20/2016 13:43 FCJORDA 1 EPA 200.7 01/20/2016 13:43 FCJORDA 1 EPA 200.7 01/20/2016 13:43 FCJORDA 1 EPA 200.7 01/20/2016 13:43 FCJORDA 1 EPA 200.7 01/20/2016 17:02 FCJORDA 1 EPA 200.7 01/20/2016 17:02 FCJORDA 1 EPA 200.7 01/20/2016 17:02 FCJORDA 1 EPA 200.7 01/20/2016 17:02 FCJORDA 1 EPA 200.7 01/21/2016 13:00 FCJORDA 1 EPA 200.7 01/21/2016 13:00 FCJORDA 1 EPA 200.7 01/21/2016 13:00 FCJORDA 1 EPA 200.7 01/21/2016 13:00 FCJORDA 1 EPA 200.7 01/21/2016 13:00 FCJORDA 1 EPA 200.7 01/21/2016 13:00 FCJORDA 1 EPA 200.7 01/21/2016 13:00 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-23DU Collection Date: 19-Jan-16 10:35 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 4.20 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 3.49 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 4.57 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.17 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 67 mg/L 25 Total Carbon TOC 0.162 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 13 of 75 Sample #: 2016001910 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 22:48 MHALL3 1 EPA 200.8 01/21/2016 22:48 MHALL3 1 EPA 200.8 01/21/2016 22:48 MHALL3 1 EPA 200.8 01/21/2016 22:48 MHALL3 1 EPA 200.8 01/21/2016 22:48 MHALL3 1 EPA 200.8 01/21/2016 22:48 MHALL3 1 EPA 200.8 01/21/2016 22:48 MHALL3 1 EPA 200.8 01/21/2016 22:48 MHALL3 1 EPA 200.8 01/21/2016 22:48 MHALL3 1 EPA 200.8 01/21/2016 22:48 MHALL3 1 EPA 200.8 01/21/2016 22:48 MHALL3 1 EPA 200.8 01/21/2016 22:48 MHALL3 1 EPA 200.8 01/21/2016 22:48 MHALL3 1 EPA 200.8 01/21/2016 15:18 MHALL3 1 EPA 200.8 01/21/2016 15:18 MHALL3 1 EPA 200.8 01/21/2016 15:18 MHALL3 1 EPA 200.8 01/21/2016 15:18 MHALL3 1 EPA 200.8 01/21/2016 15:18 MHALL3 1 EPA 200.8 01/21/2016 15:18 MHALL3 1 EPA 200.8 01/21/2016 15:18 MHALL3 1 EPA 200.8 01/21/2016 15:18 MHALL3 1 EPA 200.8 01/21/2016 15:18 MHALL3 1 EPA 200.8 01/21/2016 15:18 MHALL3 1 EPA 200.8 01/21/2016 15:18 MHALL3 1 EPA 200.8 01/21/2016 15:18 MHALL3 1 EPA 200.8 01/21/2016 15:18 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/24/201615:28 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/24/201612:45 CJELLIO Certificate of Laboratory Analysis Page 14 of 75 This report shall not be reproduced, except in full. Order # J16010376 Site: CB-4 Collection Date: 19-Jan-16 3:12 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.290 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 2.2 mg/L 0.2 Sulfate 100 mg/L 2 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.013 mg/L 0.005 Barium (Ba) 0.052 mg/L 0.005 Boron (B) 0.378 mg/L 0.05 Iron (Fe) 0.050 mg/L 0.01 Manganese (Mn) 0.393 mg/L 0.005 Strontium (Sr) 0.134 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 16.8 mg/L 0.01 Magnesium (Mg) 3.72 mg/L 0.005 Potassium (K) 2.22 mg/L 0.1 Sodium (Na) 14.9 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.029 mg/L 0.005 Barium (Ba) 0.054 mg/L 0.005 Boron (B) 0.378 mg/L 0.05 Iron (Fe) 0.010 mg/L 0.01 Manganese (Mn) 0.382 mg/L 0.005 Strontium (Sr) 0.136 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001911 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:33 LSTARL1 Vendor Method V_PACE 2 EPA 300.0 01/21/2016 15:16 BGN9034 20 EPA 300.0 01/21/2016 15:16 BGN9034 1 EPA 245.1 01/26/2016 17:30 ACPAYNE 1 EPA 245.1 01/27/2016 14:53 ACPAYNE 1 EPA 200.7 01/20/2016 13:47 FCJORDA 1 EPA 200.7 01/20/2016 13:47 FCJORDA 1 EPA 200.7 01/20/2016 13:47 FCJORDA 1 EPA 200.7 01/20/2016 13:47 FCJORDA 1 EPA 200.7 01/20/2016 13:47 FCJORDA 1 EPA 200.7 01/20/2016 13:47 FCJORDA 1 EPA 200.7 01/20/2016 13:47 FCJORDA 1 EPA 200.7 01/20/2016 17:13 FCJORDA 1 EPA 200.7 01/20/2016 17:13 FCJORDA 1 EPA 200.7 01/20/2016 17:13 FCJORDA 1 EPA 200.7 01/20/2016 17:13 FCJORDA 1 EPA 200.7 01/21/2016 13:03 FCJORDA 1 EPA 200.7 01/21/2016 13:03 FCJORDA 1 EPA 200.7 01/21/2016 13:03 FCJORDA 1 EPA 200.7 01/21/2016 13:03 FCJORDA 1 EPA 200.7 01/21/2016 13:03 FCJORDA 1 EPA 200.7 01/21/2016 13:03 FCJORDA 1 EPA 200.7 01/21/2016 13:03 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: CB-4 Collection Date: 19-Jan-16 3:12 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.07 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) 7.31 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.05 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) 7.36 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 120 mg/L 25 Total Carbon TOC 0.129 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 15 of 75 Sample #: 2016001911 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 22:53 MHALL3 1 EPA 200.8 01/21/2016 22:53 MHALL3 1 EPA 200.8 01/21/2016 22:53 MHALL3 1 EPA 200.8 01/21/2016 22:53 MHALL3 1 EPA 200.8 01/21/2016 22:53 MHALL3 1 EPA 200.8 01/21/2016 22:53 MHALL3 1 EPA 200.8 01/21/2016 22:53 MHALL3 1 EPA 200.8 01/21/2016 22:53 MHALL3 1 EPA 200.8 01/21/2016 22:53 MHALL3 1 EPA 200.8 01/21/2016 22:53 MHALL3 1 EPA 200.8 01/21/2016 22:53 MHALL3 1 EPA 200.8 01/21/2016 22:53 MHALL3 1 EPA 200.8 01/21/2016 22:53 MHALL3 1 EPA 200.8 01/21/2016 15:22 MHALL3 1 EPA 200.8 01/21/2016 15:22 MHALL3 1 EPA 200.8 01/21/2016 15:22 MHALL3 1 EPA 200.8 01/21/2016 15:22 MHALL3 1 EPA 200.8 01/21/2016 15:22 MHALL3 1 EPA 200.8 01/21/2016 15:22 MHALL3 1 EPA 200.8 01/21/2016 15:22 MHALL3 1 EPA 200.8 01/21/2016 15:22 MHALL3 1 EPA 200.8 01/21/2016 15:22 MHALL3 1 EPA 200.8 01/21/2016 15:22 MHALL3 1 EPA 200.8 01/21/2016 15:22 MHALL3 1 EPA 200.8 01/21/2016 15:22 MHALL3 1 EPA 200.8 01/21/2016 15:22 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/24/201615:28 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/24/201612:45 CJELLIO Certificate of Laboratory Analysis Page 16 of 75 This report shall not be reproduced, except in full. Order # J16010376 Site: CB-4B Collection Date: 19-Jan-16 3:45 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 6.6 mg/L 0.2 Sulfate 69 mg/L 2 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.016 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.369 mg/L 0.01 Manganese (Mn) 0.065 mg/L 0.005 Strontium (Sr) 0.130 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 22.0 mg/L 0.01 Magnesium (Mg) 3.50 mg/L 0.005 Potassium (K) 5.94 mg/L 0.1 Sodium (Na) 18.2 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.022 mg/L 0.005 Barium (Ba) 0.013 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 1.24 mg/L 0.01 Manganese (Mn) 0.067 mg/L 0.005 Strontium (Sr) 0.129 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001912 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:34 LSTARL1 Vendor Method V_PACE 2 EPA 300.0 01/21/2016 15:32 BGN9034 20 EPA 300.0 01/21/2016 15:32 BGN9034 1 EPA 245.1 01/26/2016 17:32 ACPAYNE 1 EPA 245.1 01/27/2016 14:55 ACPAYNE 1 EPA 200.7 01/20/2016 13:51 FCJORDA 1 EPA 200.7 01/20/2016 13:51 FCJORDA 1 EPA 200.7 01/20/2016 13:51 FCJORDA 1 EPA 200.7 01/20/2016 13:51 FCJORDA 1 EPA 200.7 01/20/2016 13:51 FCJORDA 1 EPA 200.7 01/20/2016 13:51 FCJORDA 1 EPA 200.7 01/20/2016 13:51 FCJORDA 1 EPA 200.7 01/20/2016 17:17 FCJORDA 1 EPA 200.7 01/20/2016 17:17 FCJORDA 1 EPA 200.7 01/20/2016 17:17 FCJORDA 1 EPA 200.7 01/20/2016 17:17 FCJORDA 1 EPA 200.7 01/21/2016 13:07 FCJORDA 1 EPA 200.7 01/21/2016 13:07 FCJORDA 1 EPA 200.7 01/21/2016 13:07 FCJORDA 1 EPA 200.7 01/21/2016 13:07 FCJORDA 1 EPA 200.7 01/21/2016 13:07 FCJORDA 1 EPA 200.7 01/21/2016 13:07 FCJORDA 1 EPA 200.7 01/21/2016 13:07 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: CB-4B Collection Date: 19-Jan-16 3:45 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 4.15 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 6.60 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 280 mg/L 25 Total Carbon TOC 0.520 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 17 of 75 Sample #: 2016001912 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 22:57 MHALL3 1 EPA 200.8 01/21/2016 22:57 MHALL3 1 EPA 200.8 01/21/2016 22:57 MHALL3 1 EPA 200.8 01/21/2016 22:57 MHALL3 1 EPA 200.8 01/21/2016 22:57 MHALL3 1 EPA 200.8 01/21/2016 22:57 MHALL3 1 EPA 200.8 01/21/2016 22:57 MHALL3 1 EPA 200.8 01/21/2016 22:57 MHALL3 1 EPA 200.8 01/21/2016 22:57 MHALL3 1 EPA 200.8 01/21/2016 22:57 MHALL3 1 EPA 200.8 01/21/2016 22:57 MHALL3 1 EPA 200.8 01/21/2016 22:57 MHALL3 1 EPA 200.8 01/21/2016 22:57 MHALL3 1 EPA 200.8 01/21/2016 15:27 MHALL3 1 EPA 200.8 01/21/2016 15:27 MHALL3 1 EPA 200.8 01/21/2016 15:27 MHALL3 1 EPA 200.8 01/21/2016 15:27 MHALL3 1 EPA 200.8 01/21/2016 15:27 MHALL3 1 EPA 200.8 01/21/2016 15:27 MHALL3 1 EPA 200.8 01/21/2016 15:27 MHALL3 1 EPA 200.8 01/21/2016 15:27 MHALL3 1 EPA 200.8 01/21/2016 15:27 MHALL3 1 EPA 200.8 01/21/2016 15:27 MHALL3 1 EPA 200.8 01/21/2016 15:27 MHALL3 1 EPA 200.8 01/21/2016 15:27 MHALL3 1 EPA 200.8 01/21/2016 15:27 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/24/201615:28 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/24/201612:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-05D Collection Date: 19-Jan-16 11:14 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.933 mg-N/L M2 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 9.6 mg/L 0.5 Sulfate 190 mg/L 2.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.643 mg/L 0.005 Barium (Ba) 0.038 mg/L 0.005 Boron (B) 0.600 mg/L 0.05 Iron (Fe) 2.36 mg/L 0.01 Manganese (Mn) 0.469 mg/L 0.005 Strontium (Sr) 0.296 mg/L 0.005 Zinc (Zn) 0.030 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 27.5 mg/L 0.01 Magnesium (Mg) 8.11 mg/L 0.005 Potassium (K) 2.73 mg/L 0.1 Sodium (Na) 21.5 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.714 mg/L 0.005 Barium (Ba) 0.041 mg/L 0.005 Boron (B) 0.638 mg/L 0.05 Iron (Fe) 2.44 mg/L 0.01 Manganese (Mn) 0.494 mg/L 0.005 Strontium (Sr) 0.305 mg/L 0.005 Zinc (Zn) 0.026 mg/L 0.005 Sample #: 2016001913 Matrix: GW WW Page 18 of 75 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:41 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/21/2016 15:49 BGN9034 25 EPA 300.0 01/21/2016 15:49 BGN9034 1 EPA 245.1 01/26/2016 17:35 ACPAYNE 1 EPA 245.1 01/27/2016 14:58 ACPAYNE 1 EPA 200.7 01/20/2016 13:54 FCJORDA 1 EPA 200.7 01/20/2016 13:54 FCJORDA 1 EPA 200.7 01/20/2016 13:54 FCJORDA 1 EPA 200.7 01/20/2016 13:54 FCJORDA 1 EPA 200.7 01/20/2016 13:54 FCJORDA 1 EPA 200.7 01/20/2016 13:54 FCJORDA 1 EPA 200.7 01/20/2016 13:54 FCJORDA 1 EPA 200.7 01/20/2016 17:21 FCJORDA 1 EPA 200.7 01/20/2016 17:21 FCJORDA 1 EPA 200.7 01/20/2016 17:21 FCJORDA 1 EPA 200.7 01/20/2016 17:21 FCJORDA 1 EPA 200.7 01/21/2016 13:11 FCJORDA 1 EPA 200.7 01/21/2016 13:11 FCJORDA 1 EPA 200.7 01/21/2016 13:11 FCJORDA 1 EPA 200.7 01/21/2016 13:11 FCJORDA 1 EPA 200.7 01/21/2016 13:11 FCJORDA 1 EPA 200.7 01/21/2016 13:11 FCJORDA 1 EPA 200.7 01/21/2016 13:11 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-05D Collection Date: 19-Jan-16 11:14 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 24.0 ug/L 1 Copper (Cu) 7.13 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 18.8 ug/L 1 Selenium (Se) 3.42 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 24.3 ug/L 1 Copper (Cu) 6.91 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 17.5 ug/L 1 Selenium (Se) 3.96 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 240 mg/L 25 Total Carbon TOC 0.147 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 19 of 75 Sample #: 2016001913 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 23:02 MHALL3 1 EPA 200.8 01/21/2016 23:02 MHALL3 1 EPA 200.8 01/21/2016 23:02 MHALL3 1 EPA 200.8 01/21/2016 23:02 MHALL3 1 EPA 200.8 01/21/2016 23:02 MHALL3 1 EPA 200.8 01/21/2016 23:02 MHALL3 1 EPA 200.8 01/21/2016 23:02 MHALL3 1 EPA 200.8 01/21/2016 23:02 MHALL3 1 EPA 200.8 01/21/2016 23:02 MHALL3 1 EPA 200.8 01/21/2016 23:02 MHALL3 1 EPA 200.8 01/21/2016 23:02 MHALL3 1 EPA 200.8 01/21/2016 23:02 MHALL3 1 EPA 200.8 01/21/2016 23:02 MHALL3 1 EPA 200.8 01/21/2016 15:32 MHALL3 1 EPA 200.8 01/21/2016 15:32 MHALL3 1 EPA 200.8 01/21/2016 15:32 MHALL3 1 EPA 200.8 01/21/2016 15:32 MHALL3 1 EPA 200.8 01/21/2016 15:32 MHALL3 1 EPA 200.8 01/21/2016 15:32 MHALL3 1 EPA 200.8 01/21/2016 15:32 MHALL3 1 EPA 200.8 01/21/2016 15:32 MHALL3 1 EPA 200.8 01/21/2016 15:32 MHALL3 1 EPA 200.8 01/21/2016 15:32 MHALL3 1 EPA 200.8 01/21/2016 15:32 MHALL3 1 EPA 200.8 01/21/2016 15:32 MHALL3 1 EPA 200.8 01/21/2016 15:32 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/24/201615:28 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/24/201612:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-05BR Collection Date: 19-Jan-16 11:58 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.017 mg-N/L M2 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 8.9 mg/L 0.2 Sulfate 120 mg/L 2 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.046 mg/L 0.005 Barium (Ba) 0.016 mg/L 0.005 Boron (B) 0.349 mg/L 0.05 Iron (Fe) 28.7 mg/L 0.01 Manganese (Mn) 0.214 mg/L 0.005 Strontium (Sr) 0.207 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 25.4 mg/L 0.01 Magnesium (Mg) 4.73 mg/L 0.005 Potassium (K) 3.31 mg/L 0.1 Sodium (Na) 16.9 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.059 mg/L 0.005 Barium (Ba) 0.017 mg/L 0.005 Boron (B) 0.360 mg/L 0.05 Iron (Fe) 29.8 mg/L 0.01 Manganese (Mn) 0.221 mg/L 0.005 Strontium (Sr) 0.211 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001914 Matrix: GW WW Page 20 of 75 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:45 LSTARL1 Vendor Method V_PACE 2 EPA 300.0 01/21/2016 16:06 BGN9034 20 EPA 300.0 01/21/2016 16:06 BGN9034 1 EPA 245.1 01/26/2016 17:37 ACPAYNE 1 EPA 245.1 01/27/2016 15:00 ACPAYNE 1 EPA 200.7 01/20/2016 13:58 FCJORDA 1 EPA 200.7 01/20/2016 13:58 FCJORDA 1 EPA 200.7 01/20/2016 13:58 FCJORDA 1 EPA 200.7 01/20/2016 13:58 FCJORDA 1 EPA 200.7 01/20/2016 13:58 FCJORDA 1 EPA 200.7 01/20/2016 13:58 FCJORDA 1 EPA 200.7 01/20/2016 13:58 FCJORDA 1 EPA 200.7 01/20/2016 17:25 FCJORDA 1 EPA 200.7 01/20/2016 17:25 FCJORDA 1 EPA 200.7 01/20/2016 17:25 FCJORDA 1 EPA 200.7 01/20/2016 17:25 FCJORDA 1 EPA 200.7 01/21/2016 13:15 FCJORDA 1 EPA 200.7 01/21/2016 13:15 FCJORDA 1 EPA 200.7 01/21/2016 13:15 FCJORDA 1 EPA 200.7 01/21/2016 13:15 FCJORDA 1 EPA 200.7 01/21/2016 13:15 FCJORDA 1 EPA 200.7 01/21/2016 13:15 FCJORDA 1 EPA 200.7 01/21/2016 13:15 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-05BR Collection Date: 19-Jan-16 11:58 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1.04 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 230 mg/L 25 Total Carbon TOC 0.185 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 31 mg/L 5 Page 21 of 75 Sample #: 2016001914 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 23:07 MHALL3 1 EPA 200.8 01/21/2016 23:07 MHALL3 1 EPA 200.8 01/21/2016 23:07 MHALL3 1 EPA 200.8 01/21/2016 23:07 MHALL3 1 EPA 200.8 01/21/2016 23:07 MHALL3 1 EPA 200.8 01/21/2016 23:07 MHALL3 1 EPA 200.8 01/21/2016 23:07 MHALL3 1 EPA 200.8 01/21/2016 23:07 MHALL3 1 EPA 200.8 01/21/2016 23:07 MHALL3 1 EPA 200.8 01/21/2016 23:07 MHALL3 1 EPA 200.8 01/21/2016 23:07 MHALL3 1 EPA 200.8 01/21/2016 23:07 MHALL3 1 EPA 200.8 01/21/2016 23:07 MHALL3 1 EPA 200.8 01/21/2016 15:37 MHALL3 1 EPA 200.8 01/21/2016 15:37 MHALL3 1 EPA 200.8 01/21/2016 15:37 MHALL3 1 EPA 200.8 01/21/2016 15:37 MHALL3 1 EPA 200.8 01/21/2016 15:37 MHALL3 1 EPA 200.8 01/21/2016 15:37 MHALL3 1 EPA 200.8 01/21/2016 15:37 MHALL3 1 EPA 200.8 01/21/2016 15:37 MHALL3 1 EPA 200.8 01/21/2016 15:37 MHALL3 1 EPA 200.8 01/21/2016 15:37 MHALL3 1 EPA 200.8 01/21/2016 15:37 MHALL3 1 EPA 200.8 01/21/2016 15:37 MHALL3 1 EPA 200.8 01/21/2016 15:37 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/24/201615:28 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/24/201612:45 CJELLIO Certificate of Laboratory Analysis Page 22 of 75 This report shall not be reproduced, except in full. Order # J16010376 Site: MW-18D Collection Date: 19-Jan-16 4:28 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.077 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 97 mg/L 5 Sulfate 300 mg/L 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.009 mg/L 0.005 Barium (Ba) 0.050 mg/L 0.005 Boron (B) 0.837 mg/L 0.05 Iron (Fe) 1.99 mg/L 0.01 Manganese (Mn) 1.29 mg/L 0.005 Strontium (Sr) 0.276 mg/L 0.005 Zinc (Zn) 0.007 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 104 mg/L 0.1 Magnesium (Mg) 26.0 mg/L 0.05 Potassium (K) 6.95 mg/L 1 Sodium (Na) 12.1 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.013 mg/L 0.005 Barium (Ba) 0.053 mg/L 0.005 Boron (B) 0.884 mg/L 0.05 Iron (Fe) 1.84 mg/L 0.01 Manganese (Mn) 1.29 mg/L 0.005 Strontium (Sr) 0.290 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 Sample #: 2016001915 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:46 LSTARL1 Vendor Method V_PACE 50 EPA 300.0 01/21/2016 14:09 BGN9034 50 EPA 300.0 01/21/2016 14:09 BGN9034 1 EPA 245.1 01/26/2016 17:40 ACPAYNE 1 EPA 245.1 01/27/2016 15:16 ACPAYNE 1 EPA 200.7 01/20/2016 14:02 FCJORDA 1 EPA 200.7 01/20/2016 14:02 FCJORDA 1 EPA 200.7 01/20/2016 14:02 FCJORDA 1 EPA 200.7 01/20/2016 14:02 FCJORDA 1 EPA 200.7 01/20/2016 14:02 FCJORDA 1 EPA 200.7 01/20/2016 14:02 FCJORDA 1 EPA 200.7 01/20/2016 14:02 FCJORDA 10 EPA 200.7 01/20/2016 17:29 FCJORDA 10 EPA 200.7 01/20/2016 17:29 FCJORDA 10 EPA 200.7 01/20/2016 17:29 FCJORDA 10 EPA 200.7 01/20/2016 17:29 FCJORDA 1 EPA 200.7 01/21/2016 13:19 FCJORDA 1 EPA 200.7 01/21/2016 13:19 FCJORDA 1 EPA 200.7 01/21/2016 13:19 FCJORDA 1 EPA 200.7 01/21/2016 13:19 FCJORDA 1 EPA 200.7 01/21/2016 13:19 FCJORDA 1 EPA 200.7 01/21/2016 13:19 FCJORDA 1 EPA 200.7 01/21/2016 13:19 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-18D Collection Date: 19-Jan-16 4:28 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 4.43 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) 1.27 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 2.79 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 4.44 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 2.49 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 610 mg/L 25 Total Carbon TOC 0.289 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 23 of 75 Sample #: 2016001915 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 23:12 MHALL3 1 EPA 200.8 01/21/2016 23:12 MHALL3 1 EPA 200.8 01/21/2016 23:12 MHALL3 1 EPA 200.8 01/21/2016 23:12 MHALL3 1 EPA 200.8 01/21/2016 23:12 MHALL3 1 EPA 200.8 01/21/2016 23:12 MHALL3 1 EPA 200.8 01/21/2016 23:12 MHALL3 1 EPA 200.8 01/21/2016 23:12 MHALL3 1 EPA 200.8 01/21/2016 23:12 MHALL3 1 EPA 200.8 01/21/2016 23:12 MHALL3 1 EPA 200.8 01/21/2016 23:12 MHALL3 1 EPA 200.8 01/21/2016 23:12 MHALL3 1 EPA 200.8 01/21/2016 23:12 MHALL3 1 EPA 200.8 01/21/2016 15:42 MHALL3 1 EPA 200.8 01/21/2016 15:42 MHALL3 1 EPA 200.8 01/21/2016 15:42 MHALL3 1 EPA 200.8 01/21/2016 15:42 MHALL3 1 EPA 200.8 01/21/2016 15:42 MHALL3 1 EPA 200.8 01/21/2016 15:42 MHALL3 1 EPA 200.8 01/21/2016 15:42 MHALL3 1 EPA 200.8 01/21/2016 15:42 MHALL3 1 EPA 200.8 01/21/2016 15:42 MHALL3 1 EPA 200.8 01/21/2016 15:42 MHALL3 1 EPA 200.8 01/21/2016 15:42 MHALL3 1 EPA 200.8 01/21/2016 15:42 MHALL3 1 EPA 200.8 01/21/2016 15:42 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/24/201615:28 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/24/201612:45 CJELLIO Certificate of Laboratory Analysis Page 24 of 75 This report shall not be reproduced, except in full. Order # J16010376 Site: MW-18BR Collection Date: 19-Jan-16 3:20 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.277 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 99 mg/L 5 Sulfate 290 mg/L 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.007 mg/L 0.005 Barium (Ba) 0.037 mg/L 0.005 Boron (B) 0.859 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.204 mg/L 0.005 Strontium (Sr) 0.394 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 120 mg/L 0.1 Magnesium (Mg) 27.3 mg/L 0.05 Potassium (K) 8.53 mg/L 1 Sodium (Na) 14.0 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.015 mg/L 0.005 Barium (Ba) 0.041 mg/L 0.005 Boron (B) 0.974 mg/L 0.05 Iron (Fe) 0.010 mg/L 0.01 Manganese (Mn) 0.221 mg/L 0.005 Strontium (Sr) 0.436 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 Sample #: 2016001916 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:47 LSTARL1 Vendor Method V_PACE 50 EPA 300.0 01/21/2016 18:05 BGN9034 50 EPA 300.0 01/21/2016 18:05 BGN9034 1 EPA 245.1 01/26/2016 17:52 ACPAYNE 1 EPA 245.1 01/27/2016 15:23 ACPAYNE 1 EPA 200.7 01/20/2016 14:14 FCJORDA 1 EPA 200.7 01/20/2016 14:14 FCJORDA 1 EPA 200.7 01/20/2016 14:14 FCJORDA 1 EPA 200.7 01/20/2016 14:14 FCJORDA 1 EPA 200.7 01/20/2016 14:14 FCJORDA 1 EPA 200.7 01/20/2016 14:14 FCJORDA 1 EPA 200.7 01/20/2016 14:14 FCJORDA 10 EPA 200.7 01/20/2016 17:33 FCJORDA 10 EPA 200.7 01/20/2016 17:33 FCJORDA 10 EPA 200.7 01/20/2016 17:33 FCJORDA 10 EPA 200.7 01/20/2016 17:33 FCJORDA 1 EPA 200.7 01/21/2016 13:31 FCJORDA 1 EPA 200.7 01/21/2016 13:31 FCJORDA 1 EPA 200.7 01/21/2016 13:31 FCJORDA 1 EPA 200.7 01/21/2016 13:31 FCJORDA 1 EPA 200.7 01/21/2016 13:31 FCJORDA 1 EPA 200.7 01/21/2016 13:31 FCJORDA 1 EPA 200.7 01/21/2016 13:31 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-18BR Collection Date: 19-Jan-16 3:20 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 4.11 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 4.16 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 630 mg/L 25 Total Carbon TOC 0.219 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 25 of 75 Sample #: 2016001916 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 22:09 MHALL3 1 EPA 200.8 01/21/2016 22:09 MHALL3 1 EPA 200.8 01/21/2016 22:09 MHALL3 1 EPA 200.8 01/21/2016 22:09 MHALL3 1 EPA 200.8 01/21/2016 22:09 MHALL3 1 EPA 200.8 01/21/2016 22:09 MHALL3 1 EPA 200.8 01/21/2016 22:09 MHALL3 1 EPA 200.8 01/21/2016 22:09 MHALL3 1 EPA 200.8 01/21/2016 22:09 MHALL3 1 EPA 200.8 01/21/2016 22:09 MHALL3 1 EPA 200.8 01/21/2016 22:09 MHALL3 1 EPA 200.8 01/21/2016 22:09 MHALL3 1 EPA 200.8 01/21/2016 22:09 MHALL3 1 EPA 200.8 01/21/2016 16:21 MHALL3 1 EPA 200.8 01/21/2016 16:21 MHALL3 1 EPA 200.8 01/21/2016 16:21 MHALL3 1 EPA 200.8 01/21/2016 16:21 MHALL3 1 EPA 200.8 01/21/2016 16:21 MHALL3 1 EPA 200.8 01/21/2016 16:21 MHALL3 1 EPA 200.8 01/21/2016 16:21 MHALL3 1 EPA 200.8 01/21/2016 16:21 MHALL3 1 EPA 200.8 01/21/2016 16:21 MHALL3 1 EPA 200.8 01/21/2016 16:21 MHALL3 1 EPA 200.8 01/21/2016 16:21 MHALL3 1 EPA 200.8 01/21/2016 16:21 MHALL3 1 EPA 200.8 01/21/2016 16:21 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/24/201615:28 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/24/201612:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-17A Collection Date: 19-Jan-16 12:08 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.014 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 410 mg/L 10 Sulfate 170 mg/L 10 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.117 mg/L 0.005 Barium (Ba) 0.128 mg/L 0.005 Boron (B) 1.82 mg/L 0.05 Iron (Fe) 23.8 mg/L 0.01 Manganese (Mn) 6.33 mg/L 0.005 Strontium (Sr) 0.584 mg/L 0.005 Zinc (Zn) 0.009 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 172 mg/L 0.1 Magnesium (Mg) 54.4 mg/L 0.05 Potassium (K) 4.27 mg/L 1 Sodium (Na) 14.1 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.091 mg/L 0.005 Barium (Ba) 0.134 mg/L 0.005 Boron (B) 1.94 mg/L 0.05 Iron (Fe) 24.2 mg/L 0.01 Manganese (Mn) 6.42 mg/L 0.005 Strontium (Sr) 0.602 mg/L 0.005 Zinc (Zn) 0.008 mg/L 0.005 Page 26 of 75 Sample #: 2016001917 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:49 LSTARL1 Vendor Method V_PACE 100 EPA 300.0 01/21/2016 17:14 BGN9034 100 EPA 300.0 01/21/2016 17:14 BGN9034 1 EPA 245.1 01/26/2016 17:59 ACPAYNE 1 EPA 245.1 01/27/2016 15:26 ACPAYNE 1 EPA 200.7 01/20/2016 14:18 FCJORDA 1 EPA 200.7 01/20/2016 14:18 FCJORDA 1 EPA 200.7 01/20/2016 14:18 FCJORDA 1 EPA 200.7 01/20/2016 14:18 FCJORDA 1 EPA 200.7 01/20/2016 14:18 FCJORDA 1 EPA 200.7 01/20/2016 14:18 FCJORDA 1 EPA 200.7 01/20/2016 14:18 FCJORDA 10 EPA 200.7 01/20/2016 17:36 FCJORDA 10 EPA 200.7 01/20/2016 17:36 FCJORDA 10 EPA 200.7 01/20/2016 17:36 FCJORDA 10 EPA 200.7 01/20/2016 17:36 FCJORDA 1 EPA 200.7 01/21/2016 13:42 FCJORDA 1 EPA 200.7 01/21/2016 13:42 FCJORDA 1 EPA 200.7 01/21/2016 13:42 FCJORDA 1 EPA 200.7 01/21/2016 13:42 FCJORDA 1 EPA 200.7 01/21/2016 13:42 FCJORDA 1 EPA 200.7 01/21/2016 13:42 FCJORDA 1 EPA 200.7 01/21/2016 13:42 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-17A Collection Date: 19-Jan-16 12:08 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 30.4 ug/L 1 Cobalt (Co) 22.4 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 33.8 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 4.18 ug/L 1 Cobalt (Co) 22.4 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 6.10 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 1100 mg/L 25 Total Carbon TOC 1.5 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 13 mg/L 5 Page 27 of 75 Sample #: 2016001917 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 23:32 MHALL3 1 EPA 200.8 01/21/2016 23:32 MHALL3 1 EPA 200.8 01/21/2016 23:32 MHALL3 1 EPA 200.8 01/21/2016 23:32 MHALL3 1 EPA 200.8 01/21/2016 23:32 MHALL3 1 EPA 200.8 01/21/2016 23:32 MHALL3 1 EPA 200.8 01/21/2016 23:32 MHALL3 1 EPA 200.8 01/21/2016 23:32 MHALL3 1 EPA 200.8 01/21/2016 23:32 MHALL3 1 EPA 200.8 01/21/2016 23:32 MHALL3 1 EPA 200.8 01/21/2016 23:32 MHALL3 1 EPA 200.8 01/21/2016 23:32 MHALL3 1 EPA 200.8 01/21/2016 23:32 MHALL3 1 EPA 200.8 01/21/2016 16:02 MHALL3 1 EPA 200.8 01/21/2016 16:02 MHALL3 1 EPA 200.8 01/21/2016 16:02 MHALL3 1 EPA 200.8 01/21/2016 16:02 MHALL3 1 EPA 200.8 01/21/2016 16:02 MHALL3 1 EPA 200.8 01/21/2016 16:02 MHALL3 1 EPA 200.8 01/21/2016 16:02 MHALL3 1 EPA 200.8 01/21/2016 16:02 MHALL3 1 EPA 200.8 01/21/2016 16:02 MHALL3 1 EPA 200.8 01/21/2016 16:02 MHALL3 1 EPA 200.8 01/21/2016 16:02 MHALL3 1 EPA 200.8 01/21/2016 16:02 MHALL3 1 EPA 200.8 01/21/2016 16:02 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/24/201615:28 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/24/201612:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-16BR Collection Date: 19-Jan-16 10:20 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.013 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 130 mg/L 2 Sulfate 39 mg/L 2 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.106 mg/L 0.005 Barium (Ba) 0.304 mg/L 0.005 Boron (B) 0.198 mg/L 0.05 Iron (Fe) 56.9 mg/L 0.1 Manganese (Mn) 0.776 mg/L 0.005 Strontium (Sr) 0.288 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 22.1 mg/L 0.01 Magnesium (Mg) 5.05 mg/L 0.005 Potassium (K) 3.29 mg/L 0.1 Sodium (Na) 20.2 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.100 mg/L 0.005 Barium (Ba) 0.296 mg/L 0.005 Boron (B) 0.216 mg/L 0.05 Iron (Fe) 58.2 mg/L 0.01 Manganese (Mn) 0.757 mg/L 0.005 Strontium (Sr) 0.278 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001918 Matrix: GW WW Page 28 of 75 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:50 LSTARL1 Vendor Method V_PACE 20 EPA 300.0 01/21/2016 18:21 BGN9034 20 EPA 300.0 01/21/2016 18:21 BGN9034 1 EPA 245.1 01/26/2016 18:01 ACPAYNE 1 EPA 245.1 01/27/2016 15:28 ACPAYNE 1 EPA 200.7 01/20/2016 14:21 FCJORDA 1 EPA 200.7 01/20/2016 14:21 FCJORDA 1 EPA 200.7 01/20/2016 14:21 FCJORDA 10 EPA 200.7 01/20/2016 14:21 FCJORDA 1 EPA 200.7 01/20/2016 14:21 FCJORDA 1 EPA 200.7 01/20/2016 14:21 FCJORDA 1 EPA 200.7 01/20/2016 14:21 FCJORDA 1 EPA 200.7 01/20/2016 17:40 FCJORDA 1 EPA 200.7 01/20/2016 17:40 FCJORDA 1 EPA 200.7 01/20/2016 17:40 FCJORDA 1 EPA 200.7 01/20/2016 17:40 FCJORDA 1 EPA 200.7 01/21/2016 13:46 FCJORDA 1 EPA 200.7 01/21/2016 13:46 FCJORDA 1 EPA 200.7 01/21/2016 13:46 FCJORDA 1 EPA 200.7 01/21/2016 13:46 FCJORDA 1 EPA 200.7 01/21/2016 13:46 FCJORDA 1 EPA 200.7 01/21/2016 13:46 FCJORDA 1 EPA 200.7 01/21/2016 13:46 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-16BR Collection Date: 19-Jan-16 10:20 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.11 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.68 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 310 mg/L 25 Total Carbon TOC 0.394 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 7.0 mg/L 5 Page 29 of 75 Sample #: 2016001918 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 23:51 MHALL3 1 EPA 200.8 01/21/2016 23:51 MHALL3 1 EPA 200.8 01/21/2016 23:51 MHALL3 1 EPA 200.8 01/21/2016 23:51 MHALL3 1 EPA 200.8 01/21/2016 23:51 MHALL3 1 EPA 200.8 01/21/2016 23:51 MHALL3 1 EPA 200.8 01/21/2016 23:51 MHALL3 1 EPA 200.8 01/21/2016 23:51 MHALL3 1 EPA 200.8 01/21/2016 23:51 MHALL3 1 EPA 200.8 01/21/2016 23:51 MHALL3 1 EPA 200.8 01/21/2016 23:51 MHALL3 1 EPA 200.8 01/21/2016 23:51 MHALL3 1 EPA 200.8 01/21/2016 23:51 MHALL3 1 EPA 200.8 01/21/2016 16:26 MHALL3 1 EPA 200.8 01/21/2016 16:26 MHALL3 1 EPA 200.8 01/21/2016 16:26 MHALL3 1 EPA 200.8 01/21/2016 16:26 MHALL3 1 EPA 200.8 01/21/2016 16:26 MHALL3 1 EPA 200.8 01/21/2016 16:26 MHALL3 1 EPA 200.8 01/21/2016 16:26 MHALL3 1 EPA 200.8 01/21/2016 16:26 MHALL3 1 EPA 200.8 01/21/2016 16:26 MHALL3 1 EPA 200.8 01/21/2016 16:26 MHALL3 1 EPA 200.8 01/21/2016 16:26 MHALL3 1 EPA 200.8 01/21/2016 16:26 MHALL3 1 EPA 200.8 01/21/2016 16:26 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/24/201615:28 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/24/201612:45 CJELLIO Certificate of Laboratory Analysis Page 30 of 75 This report shall not be reproduced, except in full. Order # J16010376 Site: FILTER BLANK Collection Date: 19-Jan-16 4:15 PM Analyte Result Units Qualifiers RDL Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2016001919 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 245.1 01/27/2016 15:31 ACPAYNE 1 EPA 200.7 01/20/2016 14:30 FCJORDA 1 EPA 200.7 01/20/2016 14:30 FCJORDA 1 EPA 200.7 01/20/2016 14:30 FCJORDA 1 EPA 200.7 01/20/2016 14:30 FCJORDA 1 EPA 200.7 01/20/2016 14:30 FCJORDA 1 EPA 200.7 01/20/2016 14:30 FCJORDA 1 EPA 200.7 01/20/2016 14:30 FCJORDA 1 EPA 200.8 01/21/2016 23:56 MHALL3 1 EPA 200.8 01/21/2016 23:56 MHALL3 1 EPA 200.8 01/21/2016 23:56 MHALL3 1 EPA 200.8 01/21/2016 23:56 MHALL3 1 EPA 200.8 01/21/2016 23:56 MHALL3 1 EPA 200.8 01/21/2016 23:56 MHALL3 1 EPA 200.8 01/21/2016 23:56 MHALL3 1 EPA 200.8 01/21/2016 23:56 MHALL3 1 EPA 200.8 01/21/2016 23:56 MHALL3 1 EPA 200.8 01/21/2016 23:56 MHALL3 1 EPA 200.8 01/21/2016 23:56 MHALL3 1 EPA 200.8 01/21/2016 23:56 MHALL3 1 EPA 200.8 01/21/2016 23:56 MHALL3 Certificate of Laboratory Analysis Page 31 of 75 This report shall not be reproduced, except in full. Order # J16010376 Site: EQUIPMENT BLANK Collection Date: 19-Jan-16 4:15 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALCI - (Analvsis Performed by Pace Laboratories Vendor Parameter Complete INORGANIC IONS BY IC Chloride < 0.1 mg/L 0.1 Sulfate < 0.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 UNDIGESTED METALS BY ICP Calcium (Ca) < 0.01 mg/L 0.01 Magnesium (Mg) < 0.005 mg/L 0.005 Potassium (K) < 0.1 mg/L 0.1 Sodium (Na) < 0.05 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2016001920 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:53 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/21/2016 18:38 BGN9034 1 EPA 300.0 01/21/2016 18:38 BGN9034 1 EPA 245.1 01/26/2016 18:04 ACPAYNE 1 EPA 200.7 01/20/2016 17:44 FCJORDA 1 EPA 200.7 01/20/2016 17:44 FCJORDA 1 EPA 200.7 01/20/2016 17:44 FCJORDA 1 EPA 200.7 01/20/2016 17:44 FCJORDA 1 EPA 200.7 01/21/2016 13:50 FCJORDA 1 EPA 200.7 01/21/2016 13:50 FCJORDA 1 EPA 200.7 01/21/2016 13:50 FCJORDA 1 EPA 200.7 01/21/2016 13:50 FCJORDA 1 EPA 200.7 01/21/2016 13:50 FCJORDA 1 EPA 200.7 01/21/2016 13:50 FCJORDA 1 EPA 200.7 01/21/2016 13:50 FCJORDA 1 EPA 200.8 01/21/2016 16:31 MHALL3 1 EPA 200.8 01/21/2016 16:31 MHALL3 1 EPA 200.8 01/21/2016 16:31 MHALL3 1 EPA 200.8 01/21/2016 16:31 MHALL3 1 EPA 200.8 01/21/2016 16:31 MHALL3 1 EPA 200.8 01/21/2016 16:31 MHALL3 1 EPA 200.8 01/21/2016 16:31 MHALL3 1 EPA 200.8 01/21/2016 16:31 MHALL3 1 EPA 200.8 01/21/2016 16:31 MHALL3 1 EPA 200.8 01/21/2016 16:31 MHALL3 1 EPA 200.8 01/21/2016 16:31 MHALL3 1 EPA 200.8 01/21/2016 16:31 MHALL3 1 EPA 200.8 01/21/2016 16:31 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: EQUIPMENT BLANK Collection Date: 19-Jan-16 4:15 PM Analyte Result Units Qualifiers RDL DF METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 Total Carbon Page 32 of 75 Sample #: 2016001920 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE SM2540C 01/24/201615:28 CJELLIO TOC < 0.1 mg/L 0.1 1 SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 01/24/2016 12:45 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-23DU DUP Collection Date: 19-Jan-16 10:35 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.450 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 8.4 mg/L 0.1 Sulfate 20 mg/L 0.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.009 mg/L 0.005 Barium (Ba) 0.034 mg/L 0.005 Boron (B) 0.079 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.251 mg/L 0.005 Strontium (Sr) 0.036 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 5.24 mg/L 0.01 Magnesium (Mg) 3.18 mg/L 0.005 Potassium (K) 1.46 mg/L 0.1 Sodium (Na) 8.56 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.028 mg/L 0.005 Barium (Ba) 0.038 mg/L 0.005 Boron (B) 0.083 mg/L 0.05 Iron (Fe) 0.429 mg/L 0.01 Manganese (Mn) 0.297 mg/L 0.005 Strontium (Sr) 0.038 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001921 Matrix: GW WW Page 33 of 75 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:55 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/21/2016 20:54 BGN9034 5 EPA 300.0 01/21/2016 20:54 BGN9034 1 EPA 245.1 01/26/2016 18:06 ACPAYNE 1 EPA 245.1 01/27/2016 15:33 ACPAYNE 1 EPA 200.7 01/20/2016 15:17 FCJORDA 1 EPA 200.7 01/20/2016 15:17 FCJORDA 1 EPA 200.7 01/20/2016 15:17 FCJORDA 1 EPA 200.7 01/20/2016 15:17 FCJORDA 1 EPA 200.7 01/20/2016 15:17 FCJORDA 1 EPA 200.7 01/20/2016 15:17 FCJORDA 1 EPA 200.7 01/20/2016 15:17 FCJORDA 1 EPA 200.7 01/20/2016 17:48 FCJORDA 1 EPA 200.7 01/20/2016 17:48 FCJORDA 1 EPA 200.7 01/20/2016 17:48 FCJORDA 1 EPA 200.7 01/20/2016 17:48 FCJORDA 1 EPA 200.7 01/21/2016 13:54 FCJORDA 1 EPA 200.7 01/21/2016 13:54 FCJORDA 1 EPA 200.7 01/21/2016 13:54 FCJORDA 1 EPA 200.7 01/21/2016 13:54 FCJORDA 1 EPA 200.7 01/21/2016 13:54 FCJORDA 1 EPA 200.7 01/21/2016 13:54 FCJORDA 1 EPA 200.7 01/21/2016 13:54 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: MW-23DU DUP Collection Date: 19-Jan-16 10:35 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 3.73 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.11 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 4.68 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.14 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 83 mg/L 25 Total Carbon TOC 0.166 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 34 of 75 Sample #: 2016001921 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/22/2016 00:01 MHALL3 1 EPA 200.8 01/22/2016 00:01 MHALL3 1 EPA 200.8 01/22/2016 00:01 MHALL3 1 EPA 200.8 01/22/2016 00:01 MHALL3 1 EPA 200.8 01/22/2016 00:01 MHALL3 1 EPA 200.8 01/22/2016 00:01 MHALL3 1 EPA 200.8 01/22/2016 00:01 MHALL3 1 EPA 200.8 01/22/2016 00:01 MHALL3 1 EPA 200.8 01/22/2016 00:01 MHALL3 1 EPA 200.8 01/22/2016 00:01 MHALL3 1 EPA 200.8 01/22/2016 00:01 MHALL3 1 EPA 200.8 01/22/2016 00:01 MHALL3 1 EPA 200.8 01/22/2016 00:01 MHALL3 1 EPA 200.8 01/21/2016 16:36 MHALL3 1 EPA 200.8 01/21/2016 16:36 MHALL3 1 EPA 200.8 01/21/2016 16:36 MHALL3 1 EPA 200.8 01/21/2016 16:36 MHALL3 1 EPA 200.8 01/21/2016 16:36 MHALL3 1 EPA 200.8 01/21/2016 16:36 MHALL3 1 EPA 200.8 01/21/2016 16:36 MHALL3 1 EPA 200.8 01/21/2016 16:36 MHALL3 1 EPA 200.8 01/21/2016 16:36 MHALL3 1 EPA 200.8 01/21/2016 16:36 MHALL3 1 EPA 200.8 01/21/2016 16:36 MHALL3 1 EPA 200.8 01/21/2016 16:36 MHALL3 1 EPA 200.8 01/21/2016 16:36 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/24/201615:28 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/24/201612:45 CJELLIO Certificate of Laboratory Analysis Page 35 of 75 This report shall not be reproduced, except in full. Order # J16010376 Site: CB-07 Collection Date: 19-Jan-16 2:23 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.035 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 65 mg/L 1 Sulfate 31 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.007 mg/L 0.005 Barium (Ba) 0.039 mg/L 0.005 Boron (B) 0.122 mg/L 0.05 Iron (Fe) 0.010 mg/L 0.01 Manganese (Mn) 0.015 mg/L 0.005 Strontium (Sr) 0.316 mg/L 0.005 Zinc (Zn) 0.073 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 27.6 mg/L 0.01 Magnesium (Mg) 5.20 mg/L 0.005 Potassium (K) 7.61 mg/L 0.1 Sodium (Na) 14.0 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.030 mg/L 0.005 Barium (Ba) 0.041 mg/L 0.005 Boron (B) 0.121 mg/L 0.05 Iron (Fe) 0.044 mg/L 0.01 Manganese (Mn) 0.014 mg/L 0.005 Strontium (Sr) 0.318 mg/L 0.005 Zinc (Zn) 0.086 mg/L 0.005 Sample #: 2016001922 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:56 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/21/2016 19:12 BGN9034 10 EPA 300.0 01/21/2016 19:12 BGN9034 1 EPA 245.1 01/26/2016 18:09 ACPAYNE 1 EPA 245.1 01/27/2016 15:35 ACPAYNE 1 EPA 200.7 01/20/2016 14:38 FCJORDA 1 EPA 200.7 01/20/2016 14:38 FCJORDA 1 EPA 200.7 01/20/2016 14:38 FCJORDA 1 EPA 200.7 01/20/2016 14:38 FCJORDA 1 EPA 200.7 01/20/2016 14:38 FCJORDA 1 EPA 200.7 01/20/2016 14:38 FCJORDA 1 EPA 200.7 01/20/2016 14:38 FCJORDA 1 EPA 200.7 01/20/2016 18:00 FCJORDA 1 EPA 200.7 01/20/2016 18:00 FCJORDA 1 EPA 200.7 01/20/2016 18:00 FCJORDA 1 EPA 200.7 01/20/2016 18:00 FCJORDA 1 EPA 200.7 01/21/2016 13:58 FCJORDA 1 EPA 200.7 01/21/2016 13:58 FCJORDA 1 EPA 200.7 01/21/2016 13:58 FCJORDA 1 EPA 200.7 01/21/2016 13:58 FCJORDA 1 EPA 200.7 01/21/2016 13:58 FCJORDA 1 EPA 200.7 01/21/2016 13:58 FCJORDA 1 EPA 200.7 01/21/2016 13:58 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010376 Site: CB-07 Collection Date: 19-Jan-16 2:23 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 1.29 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.07 ug/L 1 Selenium (Se) 8.28 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1.02 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) 8.13 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 200 mg/L 25 Total Carbon TOC 0.993 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 36 of 75 Sample #: 2016001922 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/22/2016 00:06 MHALL3 1 EPA 200.8 01/22/2016 00:06 MHALL3 1 EPA 200.8 01/22/2016 00:06 MHALL3 1 EPA 200.8 01/22/2016 00:06 MHALL3 1 EPA 200.8 01/22/2016 00:06 MHALL3 1 EPA 200.8 01/22/2016 00:06 MHALL3 1 EPA 200.8 01/22/2016 00:06 MHALL3 1 EPA 200.8 01/22/2016 00:06 MHALL3 1 EPA 200.8 01/22/2016 00:06 MHALL3 1 EPA 200.8 01/22/2016 00:06 MHALL3 1 EPA 200.8 01/22/2016 00:06 MHALL3 1 EPA 200.8 01/22/2016 00:06 MHALL3 1 EPA 200.8 01/22/2016 00:06 MHALL3 1 EPA 200.8 01/21/2016 16:41 MHALL3 1 EPA 200.8 01/21/2016 16:41 MHALL3 1 EPA 200.8 01/21/2016 16:41 MHALL3 1 EPA 200.8 01/21/2016 16:41 MHALL3 1 EPA 200.8 01/21/2016 16:41 MHALL3 1 EPA 200.8 01/21/2016 16:41 MHALL3 1 EPA 200.8 01/21/2016 16:41 MHALL3 1 EPA 200.8 01/21/2016 16:41 MHALL3 1 EPA 200.8 01/21/2016 16:41 MHALL3 1 EPA 200.8 01/21/2016 16:41 MHALL3 1 EPA 200.8 01/21/2016 16:41 MHALL3 1 EPA 200.8 01/21/2016 16:41 MHALL3 1 EPA 200.8 01/21/2016 16:41 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/24/201615:28 CJELLIO 1 SM5310C/EPA9060A 01/26/201612:01 GHUTCHI 1 SM2540D 01/24/201612:45 CJELLIO Certificate of Laboratory Analysis Page 37 of 75 This report shall not be reproduced, except in full. Order # J16010376 Qualifiers: M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, INC 28078 (704)875-9092 January 25, 2016 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 16010376 Pace Project No.: 92283619 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on January 20, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Program Manager, Duke Energy Anne Pifer Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 37 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. OQ9%Csf fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J16010376 Pace Project No.: 92283619 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 525 N 8th Street, Salina, KS 67401 A21-A Certification M 2926.01 Alaska Certification M UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification M 88-0680 California Certification M 01155CA Colorado Certification #Pace Connecticut Certification M PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification M 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification M 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification M 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification M 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification M E83079 Georgia Certification M 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification M 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification M E-10383 Kentucky Certification #: 90050 Louisiana Certification M FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification M Cert 0074 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification M TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification M 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J16010376 Pace Project No.: 92283619 Lab ID Sample ID Matrix Date Collected Date Received 92283619001 2016001905 Water 01/19/1615:55 01/20/1611:40 92283619002 2016001907 Water 01/19/1614:44 01/20/1611:40 92283619003 2016001908 Water 01/19/1613:27 01/20/1611:40 92283619004 2016001909 Water 01/19/1610:58 01/20/1611:40 92283619005 2016001910 Water 01/19/1610:35 01/20/1611:40 92283619006 2016001911 Water 01/19/1615:12 01/20/1611:40 92283619007 2016001912 Water 01/19/1615:45 01/20/1611:40 92283619008 2016001913 Water 01/19/1611:14 01/20/1611:40 92283619009 2016001914 Water 01/19/1611:58 01/20/1611:40 92283619010 2016001915 Water 01/19/1616:28 01/20/1611:40 92283619011 2016001916 Water 01/19/1615:20 01/20/1611:40 92283619012 2016001922 Water 01/19/1614:23 01/20/1611:40 92283619013 2016001917 Water 01/19/1612:08 01/20/1611:40 92283619014 2016001918 Water 01/19/1610:20 01/20/1611:40 92283619015 2016001920 Water 01/19/1616:15 01/20/1611:40 92283619016 2016001921 Water 01/19/1610:35 01/20/1611:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gWinlc8f fe. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J16010376 92283619 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92283619001 2016001905 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283619002 2016001907 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283619003 2016001908 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283619004 2016001909 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283619005 2016001910 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283619006 2016001911 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283619007 2016001912 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283619008 2016001913 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283619009 2016001914 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283619010 2016001915 RSK 175 STV 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinffte. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J16010376 Pace Project No.: 92283619 Analytes Lab ID Sample ID Method Analysts Reported Laboratory SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283619011 2016001916 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283619012 2016001922 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283619013 2016001917 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283619014 2016001918 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283619015 2016001920 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283619016 2016001921 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J16010376 92283619 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92283619001 2016001905 RSK 175 Methane 71.8 ug/L 10.0 01/21/16 19:14 SM 2320B Alkalinity, Bicarbonate (CaCO3) 6.3 mg/L 5.0 01/24/16 17:50 SM 2320B Alkalinity, Total as CaCO3 6.3 mg/L 5.0 01/24/16 17:50 EPA 218.7 Chromium, Hexavalent 0.17 ug/L 0.030 01/22/16 09:55 M1 92283619002 2016001907 RSK 175 Methane 1040 ug/L 10.0 01/21/16 19:22 SM 2320B Alkalinity, Bicarbonate (CaCO3) 72.8 mg/L 5.0 01/24/16 18:25 SM 2320B Alkalinity, Total as CaCO3 72.8 mg/L 5.0 01/24/16 18:25 92283619003 2016001908 SM 2320B Alkalinity, Bicarbonate (CaCO3) 7.1 mg/L 5.0 01/24/16 18:37 SM 2320B Alkalinity, Total as CaCO3 7.1 mg/L 5.0 01/24/16 18:37 EPA218.7 Chromium, Hexavalent 0.31 ug/L 0.060 01/22/1614:54 92283619004 2016001909 SM 2320B Alkalinity, Bicarbonate (CaCO3) 92.4 mg/L 5.0 01/24/16 18:46 SM 2320B Alkalinity, Total as CaCO3 92.4 mg/L 5.0 01/24/16 18:46 92283619005 2016001910 SM 2320B Alkalinity, Bicarbonate (CaCO3) 15.4 mg/L 5.0 01/24/16 18:58 SM 2320B Alkalinity, Total as CaCO3 15.4 mg/L 5.0 01/24/16 18:58 EPA218.7 Chromium, Hexavalent 0.15 ug/L 0.030 01/22/1611:13 92283619007 2016001912 SM 2320B Alkalinity, Bicarbonate (CaCO3) 39.0 mg/L 5.0 01/24/16 19:36 SM 2320B Alkalinity, Total as CaCO3 39.0 mg/L 5.0 01/24/16 19:36 92283619009 2016001914 SM 2320B Alkalinity, Bicarbonate (CaCO3) 28.7 mg/L 5.0 01/24/16 19:53 SM 2320B Alkalinity, Total as CaCO3 28.7 mg/L 5.0 01/24/16 19:53 92283619010 2016001915 SM 2320B Alkalinity, Bicarbonate (CaCO3) 32.4 mg/L 5.0 01/24/16 20:05 SM 2320B Alkalinity, Total as CaCO3 32.4 mg/L 5.0 01/24/16 20:05 92283619011 2016001916 SM 2320B Alkalinity, Bicarbonate (CaCO3) 26.8 mg/L 5.0 01/24/16 20:16 SM 2320B Alkalinity, Total as CaCO3 26.8 mg/L 5.0 01/24/16 20:16 EPA218.7 Chromium, Hexavalent 0.056 ug/L 0.030 01/22/1612:57 M1 92283619012 2016001922 SM 2320B Alkalinity, Bicarbonate (CaCO3) 29.1 mg/L 5.0 01/24/16 20:52 SM 2320B Alkalinity, Total as CaCO3 29.1 mg/L 5.0 01/24/16 20:52 92283619014 2016001918 RSK 175 Methane 12.9 ug/L 10.0 01/21/1621:50 SM 2320B Alkalinity, Bicarbonate (CaCO3) 12.3 mg/L 5.0 01/24/16 21:12 SM 2320B Alkalinity, Total as CaCO3 12.3 mg/L 5.0 01/24/16 21:12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: J16010376 Pace Project No.: 92283619 Lab Sample ID Client Sample ID Method Parameters 92283619016 2016001921 SM 2320B Alkalinity, Bicarbonate (CaCO3) SM 2320B Alkalinity, Total as CaCO3 EPA 218.7 Chromium, Hexavalent Result Units 15.7 mg/L 15.7 mg/L 0.13 ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Report Limit Analyzed Qualifiers 5.0 01/24/1621:51 5.0 01/24/1621:51 0.030 01/22/1614:28 Page 7 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098�t�i .8fftie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010376 Pace Project No.: 92283619 Method: RSK 175 Description: RSK 175 AIR Headspace Client: Duke Energy Date: January 25, 2016 General Information: 16 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010376 Pace Project No.: 92283619 Method: SM 2320B Description: 2320E Alkalinity Client: Duke Energy Date: January 25, 2016 General Information: 16 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010376 Pace Project No.: 92283619 Method: SM 4500-S213 Description: 4500S2D Sulfide Water Client: Duke Energy Date: January 25, 2016 General Information: 16 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098�t�i .8fftie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010376 Pace Project No.: 92283619 Method: EPA 218.7 Description: Hexavalent Chromium by IC Client: Duke Energy Date: January 25, 2016 General Information: 16 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001905 Lab ID: 92283619001 Collected: 01/19/16 15:55 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 71.8 ug/L 10.0 1 01/21/1619:14 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 6.3 mg/L 5.0 1 01/24/16 17:50 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 17:50 Alkalinity, Total as CaCO3 6.3 mg/L 5.0 1 01/24/16 17:50 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.17 ug/L 0.030 1 01/22/16 09:55 18540-29-9 M1 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001907 Lab ID: 92283619002 Collected: 01/19/16 14:44 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 1040 ug/L 10.0 1 01/21/1619:22 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 72.8 mg/L 5.0 1 01/24/16 18:25 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 18:25 Alkalinity, Total as CaCO3 72.8 mg/L 5.0 1 01/24/16 18:25 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/22/16 10:34 18540-29-9 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001908 Lab ID: 92283619003 Collected: 01/19/16 13:27 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/1619:47 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 7.1 mg/L 5.0 1 01/24/16 18:37 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 18:37 Alkalinity, Total as CaCO3 7.1 mg/L 5.0 1 01/24/16 18:37 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.31 ug/L 0.060 2 01/22/16 14:54 18540-29-9 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001909 Lab ID: 92283619004 Collected: 01/19/16 10:58 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/16 20:03 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 92.4 mg/L 5.0 1 01/24/16 18:46 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 18:46 Alkalinity, Total as CaCO3 92.4 mg/L 5.0 1 01/24/16 18:46 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/22/16 11:00 18540-29-9 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001910 Lab ID: 92283619005 Collected: 01/19/16 10:35 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/16 20:11 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 15.4 mg/L 5.0 1 01/24/16 18:58 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 18:58 Alkalinity, Total as CaCO3 15.4 mg/L 5.0 1 01/24/16 18:58 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.15 ug/L 0.030 1 01/22/16 11:13 18540-29-9 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001911 Lab ID: 92283619006 Collected: 01/19/16 15:12 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/16 20:20 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/24/16 19:09 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 19:09 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/24/16 19:09 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/22/16 11:26 18540-29-9 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001912 Lab ID: 92283619007 Collected: 01/19/16 15:45 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/16 20:28 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 39.0 mg/L 5.0 1 01/24/16 19:36 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 19:36 Alkalinity, Total as CaCO3 39.0 mg/L 5.0 1 01/24/16 19:36 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/22/16 11:39 18540-29-9 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001913 Lab ID: 92283619008 Collected: 01/19/16 11:14 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/16 20:36 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/24/16 19:47 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 19:47 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/24/16 19:47 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/22/16 11:52 18540-29-9 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001914 Lab ID: 92283619009 Collected: 01/19/16 11:58 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/16 20:44 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 28.7 mg/L 5.0 1 01/24/16 19:53 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 19:53 Alkalinity, Total as CaCO3 28.7 mg/L 5.0 1 01/24/16 19:53 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/22/16 12:05 18540-29-9 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001915 Lab ID: 92283619010 Collected: 01/19/16 16:28 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/16 20:53 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 32.4 mg/L 5.0 1 01/24/16 20:05 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 20:05 Alkalinity, Total as CaCO3 32.4 mg/L 5.0 1 01/24/16 20:05 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/22/16 12:18 18540-29-9 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001916 Lab ID: 92283619011 Collected: 01/19/16 15:20 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/16 21:01 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 26.8 mg/L 5.0 1 01/24/16 20:16 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 20:16 Alkalinity, Total as CaCO3 26.8 mg/L 5.0 1 01/24/16 20:16 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.056 ug/L 0.030 1 01/22/16 12:57 18540-29-9 M1 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001922 Lab ID: 92283619012 Collected: 01/19/16 14:23 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/16 21:25 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 29.1 mg/L 5.0 1 01/24/16 20:52 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 20:52 Alkalinity, Total as CaCO3 29.1 mg/L 5.0 1 01/24/16 20:52 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/22/16 13:36 18540-29-9 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinlc&�r fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001917 Lab ID: 92283619013 Collected: 01/19/16 12:08 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/16 21:42 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/24/16 21:04 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 21:04 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/24/16 21:04 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/22/16 13:49 18540-29-9 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001918 Lab ID: 92283619014 Collected: 01/19/16 10:20 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 12.9 ug/L 10.0 1 01/21/16 21:50 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 12.3 mg/L 5.0 1 01/24/16 21:12 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 21:12 Alkalinity, Total as CaCO3 12.3 mg/L 5.0 1 01/24/16 21:12 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/22/16 14:02 18540-29-9 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001920 Lab ID: 92283619015 Collected: 01/19/16 16:15 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/16 21:58 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/24/16 21:42 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 21:42 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/24/16 21:42 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/22/16 14:15 18540-29-9 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010376 Pace Project No.: 92283619 Sample: 2016001921 Lab ID: 92283619016 Collected: 01/19/16 10:35 Received: 01/20/16 11:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/16 22:06 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 15.7 mg/L 5.0 1 01/24/16 21:51 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 21:51 Alkalinity, Total as CaCO3 15.7 mg/L 5.0 1 01/24/16 21:51 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/21/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.13 ug/L 0.030 1 01/22/16 14:28 18540-29-9 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010376 Pace Project No.: 92283619 QC Batch: AIR/25065 Analysis Method: RSK 175 QC Batch Method: RSK 175 Analysis Description: RSK 175 AIR HEADSPACE Associated Lab Samples: 92283619001, 92283619002 METHOD BLANK: 2178463 Matrix: Water Associated Lab Samples: 92283619001, 92283619002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Methane ug/L ND 10.0 01/21/1616:22 LABORATORY CONTROL SAMPLE & LCSD: 2178464 2178465 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Methane ug/L 60.7 60.6 61.6 100 102 85-115 2 20 SAMPLE DUPLICATE: 2179324 92283470006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 2J 20 SAMPLE DUPLICATE: 2179325 92283470015 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 1.4J 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/25/2016 11:40 AM without the written consent of Pace Analytical Services, Inc.. Page 28 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010376 Pace Project No.: 92283619 QC Batch: AIR/25069 Analysis Method: RSK 175 QC Batch Method: RSK 175 Analysis Description: RSK 175 AIR HEADSPACE Associated Lab Samples: 92283619003, 92283619004, 92283619005, 92283619006, 92283619007, 92283619008, 92283619009, 92283619010,92283619011,92283619012,92283619013,92283619014,92283619015,92283619016 METHOD BLANK: 2178774 Matrix: Water Associated Lab Samples: 92283619003, 92283619004, 92283619005, 92283619006, 92283619007, 92283619008, 92283619009, 92283619010,92283619011,92283619012,92283619013,92283619014,92283619015,92283619016 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Methane ug/L ND 10.0 01/21/1619:39 LABORATORY CONTROL SAMPLE & LCSD: 2178775 2178776 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Methane ug/L 60.7 61.6 57.9 102 95 85-115 6 20 SAMPLE DUPLICATE: 2179332 92283619003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 1.2J 20 SAMPLE DUPLICATE: 2179333 92283619012 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 1.3J 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/25/2016 11:40 AM without the written consent of Pace Analytical Services, Inc.. Page 29 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010376 Pace Project No.: 92283619 QC Batch: WET/42634 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 92283619001, 92283619002, 92283619003, 92283619004, 92283619005, 92283619006, 92283619007, 92283619008,92283619009,92283619010,92283619011,92283619012,92283619013,92283619014, 92283619015,92283619016 METHOD BLANK: 1652087 Matrix: Water Associated Lab Samples: 92283619001, 92283619002, 92283619003, 92283619004, 92283619005, 92283619006, 92283619007, 92283619008,92283619009,92283619010,92283619011,92283619012,92283619013,92283619014, 92283619015,92283619016 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Alkalinity, Carbonate (CaCO3) mg/L ND 5.0 01/24/16 17:31 Alkalinity, Total as CaCO3 mg/L ND 5.0 01/24/16 17:31 Alkalinity, Bicarbonate (CaCO3) mg/L ND 5.0 01/24/16 17:31 LABORATORY CONTROL SAMPLE: 1652088 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 48.2 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1652089 1652090 MS MSD 92283619001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 6.3 50 50 55.8 55.6 99 99 80-120 0 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1652091 1652092 MS MSD 92283619011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 26.8 50 50 77.2 75.7 101 98 80-120 2 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/25/2016 11:40 AM without the written consent of Pace Analytical Services, Inc.. Page 30 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010376 Pace Project No.: 92283619 QC Batch: WET/42614 Analysis Method: SM 4500-S2D QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 92283619001, 92283619002, 92283619003, 92283619004, 92283619005, 92283619006, 92283619007, 92283619008,92283619009,92283619010,92283619011,92283619012,92283619013,92283619014, 92283619015,92283619016 METHOD BLANK: 1651471 Matrix: Water Associated Lab Samples: 92283619001, 92283619002, 92283619003, 92283619004, 92283619005, 92283619006, 92283619007, 92283619008,92283619009,92283619010,92283619011,92283619012,92283619013,92283619014, 92283619015,92283619016 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide mg/L ND 0.10 01/21/1615:30 LABORATORY CONTROL SAMPLE: 1651472 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide mg/L .5 0.50 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1651473 1651474 MS MSD 92283619001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Sulfide mg/L ND .5 .5 0.47 0.47 93 93 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1651475 1651476 MS MSD 92283619011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide mg/L ND .5 .5 0.48 0.48 96 96 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/25/2016 11:40 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010376 Pace Project No.: 92283619 QC Batch: WETA/54135 Analysis Method: EPA 218.7 QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC Associated Lab Samples: 92283619001, 92283619002, 92283619003, 92283619004, 92283619005, 92283619006, 92283619007, 92283619008,92283619009,92283619010,92283619011,92283619012,92283619013,92283619014, 92283619015,92283619016 METHOD BLANK: 1456413 Associated Lab Samples: Parameter Units Chromium, Hexavalent ug/L LABORATORY CONTROL SAMPLE: 1456414 Parameter Units Chromium, Hexavalent ug/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.030 01 /22/16 09:29 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers .075 0.081 108 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1456415 1456416 MS MSD 92283619001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent ug/L 0.17 .025 .025 0.19 0.20 87 127 85-115 5 20 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1456417 1456418 MS MSD 92283619011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent ug/L 0.056 .075 .075 0.12 0.11 84 77 85-115 5 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/25/2016 11:40 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J16010376 Pace Project No.: 92283619 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/25/2016 11:40 AM without the written consent of Pace Analytical Services, Inc.. Page 33 of 37 acmnalytical www.pacelabs.com Pace Analytical Services, Inc. og6g inlc&f fte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J16010376 Pace Project No.: 92283619 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92283619001 2016001905 RSK 175 AIR/25065 92283619002 2016001907 RSK 175 AIR/25065 92283619003 2016001908 RSK 175 AIR/25069 92283619004 2016001909 RSK 175 AIR/25069 92283619005 2016001910 RSK 175 AIR/25069 92283619006 2016001911 RSK 175 AIR/25069 92283619007 2016001912 RSK 175 AIR/25069 92283619008 2016001913 RSK 175 AIR/25069 92283619009 2016001914 RSK 175 AIR/25069 92283619010 2016001915 RSK 175 AIR/25069 92283619011 2016001916 RSK 175 AIR/25069 92283619012 2016001922 RSK 175 AIR/25069 92283619013 2016001917 RSK 175 AIR/25069 92283619014 2016001918 RSK 175 AIR/25069 92283619015 2016001920 RSK 175 AIR/25069 92283619016 2016001921 RSK 175 AIR/25069 92283619001 2016001905 SM 2320B WET/42634 92283619002 2016001907 SM 2320B WET/42634 92283619003 2016001908 SM 2320B WET/42634 92283619004 2016001909 SM 2320B WET/42634 92283619005 2016001910 SM 2320B WET/42634 92283619006 2016001911 SM 2320B WET/42634 92283619007 2016001912 SM 2320B WET/42634 92283619008 2016001913 SM 2320B WET/42634 92283619009 2016001914 SM 2320B WET/42634 92283619010 2016001915 SM 2320B WET/42634 92283619011 2016001916 SM 2320B WET/42634 92283619012 2016001922 SM 2320B WET/42634 92283619013 2016001917 SM 2320B WET/42634 92283619014 2016001918 SM 2320B WET/42634 92283619015 2016001920 SM 2320B WET/42634 92283619016 2016001921 SM 2320B WET/42634 92283619001 2016001905 SM 4500-S2D WET/42614 92283619002 2016001907 SM 4500-S2D WET/42614 92283619003 2016001908 SM 4500-S2D WET/42614 92283619004 2016001909 SM 4500-S2D WET/42614 92283619005 2016001910 SM 4500-S2D WET/42614 92283619006 2016001911 SM 4500-S2D WET/42614 92283619007 2016001912 SM 4500-S2D WET/42614 92283619008 2016001913 SM 4500-S2D WET/42614 92283619009 2016001914 SM 4500-S2D WET/42614 92283619010 2016001915 SM 4500-S2D WET/42614 92283619011 2016001916 SM 4500-S2D WET/42614 92283619012 2016001922 SM 4500-S2D WET/42614 92283619013 2016001917 SM 4500-S2D WET/42614 92283619014 2016001918 SM 4500-S2D WET/42614 92283619015 2016001920 SM 4500-S2D WET/42614 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /25/2016 11:40 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 37 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J16010376 Pace Project No.: 92283619 Lab ID Sample ID QC Batch Method QC Batch 92283619016 2016001921 SM 4500-S2D WET/42614 92283619001 2016001905 EPA 218.7 WETA/54135 92283619002 2016001907 EPA 218.7 WETA/54135 92283619003 2016001908 EPA 218.7 WETA/54135 92283619004 2016001909 EPA 218.7 WETA/54135 92283619005 2016001910 EPA 218.7 WETA/54135 92283619006 2016001911 EPA 218.7 WETA/54135 92283619007 2016001912 EPA 218.7 WETA/54135 92283619008 2016001913 EPA 218.7 WETA/54135 92283619009 2016001914 EPA 218.7 WETA/54135 92283619010 2016001915 EPA 218.7 WETA/54135 92283619011 2016001916 EPA 218.7 WETA/54135 92283619012 2016001922 EPA 218.7 WETA/54135 92283619013 2016001917 EPA 218.7 WETA/54135 92283619014 2016001918 EPA 218.7 WETA/54135 92283619015 2016001920 EPA 218.7 WETA/54135 92283619016 2016001921 EPA 218.7 WETA/54135 Date: 01/25/2016 11:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Method Analytical Batch Page 35 of 37 Document Name: Document Revised: 26OCT2015 aceAnalXieal o Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CHR-CS-003-rev.17 Pace Huntersville Quality Office MMEM Client Name: Project #: po Courier: Eked E:C"- [-]UPS ❑USPS ❑Client ❑Commercial [Pace ❑other: W0t1:92283619 �11111111111111111111111I Custody Seal on Cooler/Box Present? ❑Yes �No Seals Intact? ❑Yes []NO Packing Material: ❑ ubtfe Wrap 1 Bubble Bags []None ❑Other: Thermometer T1505 i Used: Type of Ice: ❑Wet ❑Blue ❑None []Samples on ice, cooling process has begun Cooler Temp Corrected (°C): �' Biological Tissue Frozen? ❑Yes ❑No— ❑hF/A Temp should be above freezing to 6°C Correction Factor: 0.0 °C Date and Initials of Person Examining.Contents:' USDA Regulated Soil N/A, water sample) Did samples Ong' e n a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally ..-- ❑Yes ❑ o including Hawaii and Puerto Rico)? []yes ONO If Yes to either question, fill out a Regulated Soil Checklist and include with SCUR/COC tmaerwork. COMMENTS: Chain of Custody Present? Yes -,-[]No ❑N/A 1. Chain of Custody Filled Out? Yes ❑No [I N/A 2. Chain of Custody Relinquished? Yes No [I N/A 3. Sampler Name and/or Signature on COC? es ❑No []N/A 4. Samples Arrived within Hold Time? Yes No ❑N/A 5. Short Hold Time Analysis (<72 hr)? Yes ❑No N/A 6. Rush Turn Around Time Requested? []Yes No ❑N/A 7. Sufficient Volume? es No ❑N/A 8. Correct Containers Used? -Pace Containers Used? iaYes ❑Yes []No N/A E3N0L�N/A 9. Containers Intact? Yes ON. ❑N/A A(Y' Filtered Volume Received for Dissolved Tests? ❑Yes,f❑No ❑N/A 11. Note if sediment is visible in the dissolved container Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: -[' Yes ❑No ❑N/A 12. All containers needing acid/base preservation have been checked? All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2SO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide) Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC,LLHg Yes El No Y�'[]No -' []Yes ❑No []N/A []N/A ❑N/A, 13. Samples checked for dechlorization ❑Yes ❑No (DN/A 14. Headspace in VOA Vials (>5-6mm)? [I Yes ❑No ❑N/,fir 15. Trip Blank Present? Trip Blank Custody Seals Present? Pace Trip Blank Lot # (if purchased): ❑Yes ❑Yes ❑No ❑No N/ N/A 16. CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Field Data -Required? ❑Yes ❑No Date/Time: Project Manager SCURF Review: 1 Date: 11-7,0 N Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le. Out of hold, incorrect preservative, out of temp, incorrect containers). Page 36 of 37 I �a P rf a f kil O rn m C '�" r- r- u m m a z L 2 fAN I 7 r}y� L S' o �) fA > In - 1v N a - n w IC n m i 0 o m d N J v n � " 1 3 iIJ CS fi � ice, �--�--�•-� -�-- ._... _... _. _. _ ._. ........... 'J_1��'..L.._.1`I{1ti�Ga l.._.._ 4- j Customer, important: please indicate desired turnaround 0 N IT R � 5_ Sn ` (3 uJ C/) n Page 74 of 75 tiO3 t— 4 0 tXv � 'I4 ly 1 � � r O = g � -;F it ar 3 O mAg v V .._o a O 1 C3 f �t , �r,l �• fr Y �r �� L 1 �' 4' Vi P n it Ij G 13 a j 1 r y4I1 ', m " z C v o Camp. i m CD 9. N N _ ry TSS,TOS M 1 Y ti C I gif I "' (yNNN N N N (v'(n Methane (R5K y i ! (/y 179) V Shealy NO 3 a pif�17 CI, So , m o n a "i � �^ H rl - — TOC, Nitrate- j m i Nitrite T v E n t Alkalinity, i � m 10 J Carbonate o r V Sheal i Sulfide R-Element 1] o ' ti i O77II { a C 0 c� D Y I j (V_Pacej o v a %� -- Metals (ses m x D +m m @I� _ y below Dissolved m = g l` m 0=1 R a _ 3 metals 0.45) m o t ,- a, rn m m eq `Z '� �' a i Total a Conlainers urn a 2- s d 1 G• C� rt`' > C, c11ya Q Page �f 7 6 r;z e::> / 4 ---- -------- - ----- ------ ------ CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM Page 75 of 75 Duke EiieMy Awhftal LjibDrat m0c."Nopw m,"474m icwd" MNWX Gw M Page -1 -- Uf 1- -9 133-�QmpF"ft Gr I DISTRIBUTODN ORIGANAL lu LAB, COPY 10 CLIENT smwi-E PfmdftAm G�nd Wmiur 1m4jv&fi245 - -- ------------- L ..7 1±1 !t-2":EMPL - - --! L All Gw jusevivIltrit WANT -40 Wondow Gnlun® weaw UST FKRA W904 COC REV DATE 112212GIS —J" YZN�;, ------ ------------------ 4"'" PAGE 1`1111rallian R.45 um) I ISO 40 Unnithimi %w C� I. ■ *w* c 300 13 0 250 W 27 600 aDf&dFwvbIume(mLj 500 AMEMILLE orltmInqrTyFm d1UPL PEI gimm PEr PET HDRE 1�311 17 IMPF Sam pio Ehes-cripti6n or it) me.". di T nS, E Tj 70 nun-whaded i wwom I dt Ld CL IP Gft Locatlon 2 1 0 1 1, 1 x I Z- 'o 14 -Z 209 z 3 D L- f,e, 6-Y jr 9/01 'r- - -,K 4por r 145-4 7- -79 # 44 1) 6 :117 1 M 0 - 1:7,4 )20'd Y I Z I 0 1 Z- I I I r ; i F4Wr Blank 2 1 1 11 1 i Euipmant Blank A 10A A t -41 a L TOTAL 0 1. 1 A A. Actepled ay: 6111 ro via DsIeM Acr49phO `cr joy Oate17T,tM� ,ark i3penwes By ELEM,.FAJTS by rCP — OASITAM).' As, Be, Cd. Co, Cr, Cu. Mo, Ni, Pb. Sb, Se, TI (LLI, V JILLO F� :4, EEL E MEMP-3 tty rG P (TRM): AI. Oil, 113r Fe, Mn. Sr. Zri XP�-Widig"Woo Ca, M% K. Na Hg by ?AS. 1 DiEsGived mcitals : all amtols icp, Ims. "m ctc�pq- s- sa .2 713 E 40 Hr E 'QttNx --MAV 'Add. Gost VVIII Apply ic