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Home My WebLink AboutNC0000396_J16010355 Report_20160831DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report Order Number: J16010355 Project Name: ASHEVILLE - AB GW ASSESSMENT WATER Customer Name(s): Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu Customer Address: 200 CP and L Drive Lab Contact: Report Authorized By: (Signature) Program Comments: Arden,NC 28704 nne fifer Phone: Date: Anne ' r Please contact the Program Manager (Anne Pifer) with any questions regarding this report. Data Flags & Calculations: 2/4/2016 Page 1 of 74 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Page 2 of 74 Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2016001809 ASHEVILLE 18-Jan-16 4:01 PM illegible CB-05 2016001810 ASHEVILLE 18-Jan-16 2:04 PM illegible MW-21D 2016001811 ASHEVILLE 18-Jan-16 12:08 PM illegible MW-22D 2016001812 ASHEVILLE 18-Jan-16 11:21 AM illegible MW-22BR 2016001813 ASHEVILLE 18-Jan-16 4:23 PM illegible MW-16A 2016001814 ASHEVILLE 18-Jan-16 3:25 PM illegible MW-15A 2016001815 ASHEVILLE 18-Jan-16 2:27 PM illegible MW-15D 2016001816 ASHEVILLE 18-Jan-16 1:22 PM illegible MW-11 2016001817 ASHEVILLE 18-Jan-16 12:18 PM illegible MW-11D 2016001818 ASHEVILLE 18-Jan-16 10:35 AM illegible MW-14BR 2016001819 ASHEVILLE 18-Jan-16 3:56 PM illegible GW-1BR 2016001820 ASHEVILLE 18-Jan-16 3:09 PM illegible GW-1 2016001821 ASHEVILLE 18-Jan-16 2:51 PM illegible GW-01D 2016001822 ASHEVILLE 18-Jan-16 11:35AM illegible MW-01BR 2016001823 ASHEVILLE 18-Jan-16 10:44AM illegible MW-01D 15 Total Samples Page 3 of 74 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification ❑ Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries ❑ Chain of Custody ❑ Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 2/4/2016 Certificate of Laboratory Analysis Page 4 of 74 This report shall not be reproduced, except in full. Order # J16010355 Site: CB-05 Collection Date: 18-Jan-16 4:01 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.020 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 22 mg/L 1 Sulfate 48 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.100 mg/L 0.005 Barium (Ba) 0.019 mg/L 0.005 Boron (B) 0.180 mg/L 0.05 Iron (Fe) 27.2 mg/L 0.01 Manganese (Mn) 0.616 mg/L 0.005 Strontium (Sr) 0.042 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 8.60 mg/L 0.01 Magnesium (Mg) 5.42 mg/L 0.005 Potassium (K) 0.833 mg/L 0.1 Sodium (Na) 18.7 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.105 mg/L 0.005 Barium (Ba) 0.021 mg/L 0.005 Boron (B) 0.186 mg/L 0.05 Iron (Fe) 26.9 mg/L 0.01 Manganese (Mn) 0.625 mg/L 0.005 Strontium (Sr) 0.042 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001809 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 10:32 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/20/2016 17:48 BGN9034 10 EPA 300.0 01/20/2016 17:48 BGN9034 1 EPA 245.1 01/25/2016 17:23 ACPAYNE 1 EPA 245.1 01/25/2016 20:38 ACPAYNE 1 EPA 200.7 01/20/2016 11:34 FCJORDA 1 EPA 200.7 01/20/2016 11:34 FCJORDA 1 EPA 200.7 01/20/2016 11:34 FCJORDA 1 EPA 200.7 01/20/2016 11:34 FCJORDA 1 EPA 200.7 01/20/2016 11:34 FCJORDA 1 EPA 200.7 01/20/2016 11:34 FCJORDA 1 EPA 200.7 01/20/2016 11:34 FCJORDA 1 EPA 200.7 01/20/2016 15:02 FCJORDA 1 EPA 200.7 01/20/2016 15:02 FCJORDA 1 EPA 200.7 01/20/2016 15:02 FCJORDA 1 EPA 200.7 01/20/2016 15:02 FCJORDA 1 EPA 200.7 01/21/2016 15:20 FCJORDA 1 EPA 200.7 01/21/2016 15:20 FCJORDA 1 EPA 200.7 01/21/2016 15:20 FCJORDA 1 EPA 200.7 01/21/2016 15:20 FCJORDA 1 EPA 200.7 01/21/2016 15:20 FCJORDA 1 EPA 200.7 01/21/2016 15:20 FCJORDA 1 EPA 200.7 01/21/2016 15:20 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: CB-05 Collection Date: 18-Jan-16 4:01 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.338 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.461 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 130 mg/L 25 Total Carbon TOC 7.9 mg/L 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 5 of 74 Sample #: 2016001809 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 17:15 MHALL3 1 EPA 200.8 01/21/2016 17:15 MHALL3 1 EPA 200.8 01/21/2016 17:15 MHALL3 1 EPA 200.8 01/21/2016 17:15 MHALL3 1 EPA 200.8 01/21/2016 17:15 MHALL3 1 EPA 200.8 01/21/2016 17:15 MHALL3 1 EPA 200.8 01/21/2016 17:15 MHALL3 1 EPA 200.8 01/21/2016 17:15 MHALL3 1 EPA 200.8 01/21/2016 17:15 MHALL3 1 EPA 200.8 01/21/2016 17:15 MHALL3 1 EPA 200.8 01/21/2016 17:15 MHALL3 1 EPA 200.8 01/21/2016 17:15 MHALL3 1 EPA 200.8 01/21/2016 17:15 MHALL3 1 EPA 200.8 01/21/2016 20:01 MHALL3 1 EPA 200.8 01/21/2016 20:01 MHALL3 1 EPA 200.8 01/21/2016 20:01 MHALL3 1 EPA 200.8 01/21/2016 20:01 MHALL3 1 EPA 200.8 01/21/2016 20:01 MHALL3 1 EPA 200.8 01/21/2016 20:01 MHALL3 1 EPA 200.8 01/21/2016 20:01 MHALL3 1 EPA 200.8 01/21/2016 20:01 MHALL3 1 EPA 200.8 01/21/2016 20:01 MHALL3 1 EPA 200.8 01/21/2016 20:01 MHALL3 1 EPA 200.8 01/21/2016 20:01 MHALL3 1 EPA 200.8 01/21/2016 20:01 MHALL3 1 EPA 200.8 01/21/2016 20:01 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/21/201614:35 CJELLIO 10 SM5310C/EPA9060A 01/20/201613:06 GHUTCHI 1 SM2540D 01/21/2016 09:09 CJELLIO Certificate of Laboratory Analysis Page 6 of 74 This report shall not be reproduced, except in full. Order # J16010355 Site: MW-21 D Collection Date: 18-Jan-16 2:04 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.042 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 29 mg/L 0.5 Sulfate 29 mg/L 0.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.015 mg/L 0.005 Barium (Ba) 0.043 mg/L 0.005 Boron (B) 0.092 mg/L 0.05 Iron (Fe) 1.51 mg/L 0.01 Manganese (Mn) 0.647 mg/L 0.005 Strontium (Sr) 0.075 mg/L 0.005 Zinc (Zn) 0.008 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 9.46 mg/L 0.01 Magnesium (Mg) 3.85 mg/L 0.005 Potassium (K) 1.42 mg/L 0.1 Sodium (Na) 15.1 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.023 mg/L 0.005 Barium (Ba) 0.046 mg/L 0.005 Boron (B) 0.095 mg/L 0.05 Iron (Fe) 2.44 mg/L 0.01 Manganese (Mn) 0.645 mg/L 0.005 Strontium (Sr) 0.075 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001810 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 10:33 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/20/2016 16:57 BGN9034 5 EPA 300.0 01/20/2016 16:57 BGN9034 1 EPA 245.1 01/25/2016 17:25 ACPAYNE 1 EPA 245.1 01/25/2016 20:40 ACPAYNE 1 EPA 200.7 01/20/2016 11:38 FCJORDA 1 EPA 200.7 01/20/2016 11:38 FCJORDA 1 EPA 200.7 01/20/2016 11:38 FCJORDA 1 EPA 200.7 01/20/2016 11:38 FCJORDA 1 EPA 200.7 01/20/2016 11:38 FCJORDA 1 EPA 200.7 01/20/2016 11:38 FCJORDA 1 EPA 200.7 01/20/2016 11:38 FCJORDA 1 EPA 200.7 01/20/2016 15:14 FCJORDA 1 EPA 200.7 01/20/2016 15:14 FCJORDA 1 EPA 200.7 01/20/2016 15:14 FCJORDA 1 EPA 200.7 01/20/2016 15:14 FCJORDA 1 EPA 200.7 01/21/2016 15:32 FCJORDA 1 EPA 200.7 01/21/2016 15:32 FCJORDA 1 EPA 200.7 01/21/2016 15:32 FCJORDA 1 EPA 200.7 01/21/2016 15:32 FCJORDA 1 EPA 200.7 01/21/2016 15:32 FCJORDA 1 EPA 200.7 01/21/2016 15:32 FCJORDA 1 EPA 200.7 01/21/2016 15:32 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-21 D Collection Date: 18-Jan-16 2:04 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.28 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.01 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.09 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 110 mg/L 25 Total Carbon TOC 0.257 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 7 of 74 Sample #: 2016001810 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 17:34 MHALL3 1 EPA 200.8 01/21/2016 17:34 MHALL3 1 EPA 200.8 01/21/2016 17:34 MHALL3 1 EPA 200.8 01/21/2016 17:34 MHALL3 1 EPA 200.8 01/21/2016 17:34 MHALL3 1 EPA 200.8 01/21/2016 17:34 MHALL3 1 EPA 200.8 01/21/2016 17:34 MHALL3 1 EPA 200.8 01/21/2016 17:34 MHALL3 1 EPA 200.8 01/21/2016 17:34 MHALL3 1 EPA 200.8 01/21/2016 17:34 MHALL3 1 EPA 200.8 01/21/2016 17:34 MHALL3 1 EPA 200.8 01/21/2016 17:34 MHALL3 1 EPA 200.8 01/21/2016 17:34 MHALL3 1 EPA 200.8 01/21/2016 19:42 MHALL3 1 EPA 200.8 01/21/2016 19:42 MHALL3 1 EPA 200.8 01/21/2016 19:42 MHALL3 1 EPA 200.8 01/21/2016 19:42 MHALL3 1 EPA 200.8 01/21/2016 19:42 MHALL3 1 EPA 200.8 01/21/2016 19:42 MHALL3 1 EPA 200.8 01/21/2016 19:42 MHALL3 1 EPA 200.8 01/21/2016 19:42 MHALL3 1 EPA 200.8 01/21/2016 19:42 MHALL3 1 EPA 200.8 01/21/2016 19:42 MHALL3 1 EPA 200.8 01/21/2016 19:42 MHALL3 1 EPA 200.8 01/21/2016 19:42 MHALL3 1 EPA 200.8 01/21/2016 19:42 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/21/201614:35 CJELLIO 1 SM5310C/EPA9060A 01/20/201613:06 GHUTCHI 1 SM2540D 01/21/2016 09:09 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-22D Collection Date: 18-Jan-16 12:08 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.444 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 45 mg/L 0.5 Sulfate 10 mg/L 0.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.033 mg/L 0.005 Barium (Ba) 0.037 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.116 mg/L 0.005 Strontium (Sr) 0.065 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 7.56 mg/L 0.01 Magnesium (Mg) 5.57 mg/L 0.005 Potassium (K) 1.59 mg/L 0.1 Sodium (Na) 14.1 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.065 mg/L 0.005 Barium (Ba) 0.040 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.039 mg/L 0.01 Manganese (Mn) 0.118 mg/L 0.005 Strontium (Sr) 0.065 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001811 Matrix: GW WW Page 8 of 74 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 10:51 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/20/2016 18:05 BGN9034 5 EPA 300.0 01/20/2016 18:05 BGN9034 1 EPA 245.1 01/25/2016 17:28 ACPAYNE 1 EPA 245.1 01/25/2016 20:43 ACPAYNE 1 EPA 200.7 01/20/2016 11:41 FCJORDA 1 EPA 200.7 01/20/2016 11:41 FCJORDA 1 EPA 200.7 01/20/2016 11:41 FCJORDA 1 EPA 200.7 01/20/2016 11:41 FCJORDA 1 EPA 200.7 01/20/2016 11:41 FCJORDA 1 EPA 200.7 01/20/2016 11:41 FCJORDA 1 EPA 200.7 01/20/2016 11:41 FCJORDA 1 EPA 200.7 01/20/2016 15:33 FCJORDA 1 EPA 200.7 01/20/2016 15:33 FCJORDA 1 EPA 200.7 01/20/2016 15:33 FCJORDA 1 EPA 200.7 01/20/2016 15:33 FCJORDA 1 EPA 200.7 01/21/2016 15:40 FCJORDA 1 EPA 200.7 01/21/2016 15:40 FCJORDA 1 EPA 200.7 01/21/2016 15:40 FCJORDA 1 EPA 200.7 01/21/2016 15:40 FCJORDA 1 EPA 200.7 01/21/2016 15:40 FCJORDA 1 EPA 200.7 01/21/2016 15:40 FCJORDA 1 EPA 200.7 01/21/2016 15:40 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-22D Collection Date: 18-Jan-16 12:08 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 6.62 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 6.76 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 98 mg/L 25 Total Carbon TOC 0.262 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 9 of 74 Sample #: 2016001811 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 17:39 MHALL3 1 EPA 200.8 01/21/2016 17:39 MHALL3 1 EPA 200.8 01/21/2016 17:39 MHALL3 1 EPA 200.8 01/21/2016 17:39 MHALL3 1 EPA 200.8 01/21/2016 17:39 MHALL3 1 EPA 200.8 01/21/2016 17:39 MHALL3 1 EPA 200.8 01/21/2016 17:39 MHALL3 1 EPA 200.8 01/21/2016 17:39 MHALL3 1 EPA 200.8 01/21/2016 17:39 MHALL3 1 EPA 200.8 01/21/2016 17:39 MHALL3 1 EPA 200.8 01/21/2016 17:39 MHALL3 1 EPA 200.8 01/21/2016 17:39 MHALL3 1 EPA 200.8 01/21/2016 17:39 MHALL3 1 EPA 200.8 01/21/2016 20:06 MHALL3 1 EPA 200.8 01/21/2016 20:06 MHALL3 1 EPA 200.8 01/21/2016 20:06 MHALL3 1 EPA 200.8 01/21/2016 20:06 MHALL3 1 EPA 200.8 01/21/2016 20:06 MHALL3 1 EPA 200.8 01/21/2016 20:06 MHALL3 1 EPA 200.8 01/21/2016 20:06 MHALL3 1 EPA 200.8 01/21/2016 20:06 MHALL3 1 EPA 200.8 01/21/2016 20:06 MHALL3 1 EPA 200.8 01/21/2016 20:06 MHALL3 1 EPA 200.8 01/21/2016 20:06 MHALL3 1 EPA 200.8 01/21/2016 20:06 MHALL3 1 EPA 200.8 01/21/2016 20:06 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/21/201614:35 CJELLIO 1 SM5310C/EPA9060A 01/20/201613:06 GHUTCHI 1 SM2540D 01/21/2016 09:09 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-22BR Collection Date: 18-Jan-16 11:21 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.015 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 51 mg/L 1 Sulfate 20 mg/L 0.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.027 mg/L 0.005 Barium (Ba) 0.020 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 14.3 mg/L 0.01 Manganese (Mn) 0.259 mg/L 0.005 Strontium (Sr) 0.098 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 10.6 mg/L 0.01 Magnesium (Mg) 4.32 mg/L 0.005 Potassium (K) 3.24 mg/L 0.1 Sodium (Na) 17.0 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.083 mg/L 0.005 Barium (Ba) 0.019 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 14.7 mg/L 0.01 Manganese (Mn) 0.262 mg/L 0.005 Strontium (Sr) 0.098 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001812 Matrix: GW WW Page 10 of 74 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 10:55 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/21/2016 08:15 BGN9034 5 EPA 300.0 01/21/2016 08:15 BGN9034 1 EPA 245.1 01/25/2016 17:30 ACPAYNE 1 EPA 245.1 01/25/2016 20:45 ACPAYNE 1 EPA 200.7 01/20/2016 11:45 FCJORDA 1 EPA 200.7 01/20/2016 11:45 FCJORDA 1 EPA 200.7 01/20/2016 11:45 FCJORDA 1 EPA 200.7 01/20/2016 11:45 FCJORDA 1 EPA 200.7 01/20/2016 11:45 FCJORDA 1 EPA 200.7 01/20/2016 11:45 FCJORDA 1 EPA 200.7 01/20/2016 11:45 FCJORDA 1 EPA 200.7 01/20/2016 15:44 FCJORDA 1 EPA 200.7 01/20/2016 15:44 FCJORDA 1 EPA 200.7 01/20/2016 15:44 FCJORDA 1 EPA 200.7 01/20/2016 15:44 FCJORDA 1 EPA 200.7 01/21/2016 15:44 FCJORDA 1 EPA 200.7 01/21/2016 15:44 FCJORDA 1 EPA 200.7 01/21/2016 15:44 FCJORDA 1 EPA 200.7 01/21/2016 15:44 FCJORDA 1 EPA 200.7 01/21/2016 15:44 FCJORDA 1 EPA 200.7 01/21/2016 15:44 FCJORDA 1 EPA 200.7 01/21/2016 15:44 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-22BR Collection Date: 18-Jan-16 11:21 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 140 mg/L 25 Total Carbon TOC 0.362 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 11 of 74 Sample #: 2016001812 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 17:44 MHALL3 1 EPA 200.8 01/21/2016 17:44 MHALL3 1 EPA 200.8 01/21/2016 17:44 MHALL3 1 EPA 200.8 01/21/2016 17:44 MHALL3 1 EPA 200.8 01/21/2016 17:44 MHALL3 1 EPA 200.8 01/21/2016 17:44 MHALL3 1 EPA 200.8 01/21/2016 17:44 MHALL3 1 EPA 200.8 01/21/2016 17:44 MHALL3 1 EPA 200.8 01/21/2016 17:44 MHALL3 1 EPA 200.8 01/21/2016 17:44 MHALL3 1 EPA 200.8 01/21/2016 17:44 MHALL3 1 EPA 200.8 01/21/2016 17:44 MHALL3 1 EPA 200.8 01/21/2016 17:44 MHALL3 1 EPA 200.8 01/21/2016 20:11 MHALL3 1 EPA 200.8 01/21/2016 20:11 MHALL3 1 EPA 200.8 01/21/2016 20:11 MHALL3 1 EPA 200.8 01/21/2016 20:11 MHALL3 1 EPA 200.8 01/21/2016 20:11 MHALL3 1 EPA 200.8 01/21/2016 20:11 MHALL3 1 EPA 200.8 01/21/2016 20:11 MHALL3 1 EPA 200.8 01/21/2016 20:11 MHALL3 1 EPA 200.8 01/21/2016 20:11 MHALL3 1 EPA 200.8 01/21/2016 20:11 MHALL3 1 EPA 200.8 01/21/2016 20:11 MHALL3 1 EPA 200.8 01/21/2016 20:11 MHALL3 1 EPA 200.8 01/21/2016 20:11 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/21/201614:35 CJELLIO 1 SM5310C/EPA9060A 01/20/201613:06 GHUTCHI 1 SM2540D 01/21/2016 09:09 CJELLIO Certificate of Laboratory Analysis Page 12 of 74 This report shall not be reproduced, except in full. Order # J16010355 Site: MW-16A Collection Date: 18-Jan-16 4:23 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.036 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 140 mg/L 2 Sulfate 59 mg/L 2 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.422 mg/L 0.005 Barium (Ba) 0.208 mg/L 0.005 Boron (B) 0.617 mg/L 0.05 Iron (Fe) 0.062 mg/L 0.01 Manganese (Mn) 2.24 mg/L 0.005 Strontium (Sr) 0.331 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 44.7 mg/L 0.01 Magnesium (Mg) 15.8 mg/L 0.005 Potassium (K) 2.95 mg/L 0.1 Sodium (Na) 22.1 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.260 mg/L 0.005 Barium (Ba) 0.162 mg/L 0.005 Boron (B) 0.524 mg/L 0.05 Iron (Fe) 0.096 mg/L 0.01 Manganese (Mn) 1.62 mg/L 0.005 Strontium (Sr) 0.275 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001813 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 10:56 LSTARL1 Vendor Method V_PACE 20 EPA 300.0 01/20/2016 18:39 BGN9034 20 EPA 300.0 01/20/2016 18:39 BGN9034 1 EPA 245.1 01/25/2016 17:33 ACPAYNE 1 EPA 245.1 01/26/2016 09:50 ACPAYNE 1 EPA 200.7 01/20/2016 11:49 FCJORDA 1 EPA 200.7 01/20/2016 11:49 FCJORDA 1 EPA 200.7 01/20/2016 11:49 FCJORDA 1 EPA 200.7 01/20/2016 11:49 FCJORDA 1 EPA 200.7 01/20/2016 11:49 FCJORDA 1 EPA 200.7 01/20/2016 11:49 FCJORDA 1 EPA 200.7 01/20/2016 11:49 FCJORDA 1 EPA 200.7 01/20/2016 15:56 FCJORDA 1 EPA 200.7 01/20/2016 15:56 FCJORDA 1 EPA 200.7 01/20/2016 15:56 FCJORDA 1 EPA 200.7 01/20/2016 15:56 FCJORDA 1 EPA 200.7 01/21/2016 15:47 FCJORDA 1 EPA 200.7 01/21/2016 15:47 FCJORDA 1 EPA 200.7 01/21/2016 15:47 FCJORDA 1 EPA 200.7 01/21/2016 15:47 FCJORDA 1 EPA 200.7 01/21/2016 15:47 FCJORDA 1 EPA 200.7 01/21/2016 15:47 FCJORDA 1 EPA 200.7 01/21/2016 15:47 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-16A Collection Date: 18-Jan-16 4:23 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 2.28 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.33 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 330 mg/L 25 Total Carbon TOC 0.748 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 13 of 74 Sample #: 2016001813 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 17:49 MHALL3 1 EPA 200.8 01/21/2016 17:49 MHALL3 1 EPA 200.8 01/21/2016 17:49 MHALL3 1 EPA 200.8 01/21/2016 17:49 MHALL3 1 EPA 200.8 01/21/2016 17:49 MHALL3 1 EPA 200.8 01/21/2016 17:49 MHALL3 1 EPA 200.8 01/21/2016 17:49 MHALL3 1 EPA 200.8 01/21/2016 17:49 MHALL3 1 EPA 200.8 01/21/2016 17:49 MHALL3 1 EPA 200.8 01/21/2016 17:49 MHALL3 1 EPA 200.8 01/21/2016 17:49 MHALL3 1 EPA 200.8 01/21/2016 17:49 MHALL3 1 EPA 200.8 01/21/2016 17:49 MHALL3 1 EPA 200.8 01/21/2016 20:16 MHALL3 1 EPA 200.8 01/21/2016 20:16 MHALL3 1 EPA 200.8 01/21/2016 20:16 MHALL3 1 EPA 200.8 01/21/2016 20:16 MHALL3 1 EPA 200.8 01/21/2016 20:16 MHALL3 1 EPA 200.8 01/21/2016 20:16 MHALL3 1 EPA 200.8 01/21/2016 20:16 MHALL3 1 EPA 200.8 01/21/2016 20:16 MHALL3 1 EPA 200.8 01/21/2016 20:16 MHALL3 1 EPA 200.8 01/21/2016 20:16 MHALL3 1 EPA 200.8 01/21/2016 20:16 MHALL3 1 EPA 200.8 01/21/2016 20:16 MHALL3 1 EPA 200.8 01/21/2016 20:16 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/21/201614:35 CJELLIO 1 SM5310C/EPA9060A 01/20/201613:06 GHUTCHI 1 SM2540D 01/21/2016 09:09 CJELLIO Certificate of Laboratory Analysis Page 14 of 74 This report shall not be reproduced, except in full. Order # J16010355 Site: MW-15A Collection Date: 18-Jan-16 3:25 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.029 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 43 mg/L 0.5 Sulfate 5.8 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.112 mg/L 0.005 Barium (Ba) 0.090 mg/L 0.005 Boron (B) 0.058 mg/L 0.05 Iron (Fe) 0.037 mg/L 0.01 Manganese (Mn) 0.957 mg/L 0.005 Strontium (Sr) 0.101 mg/L 0.005 Zinc (Zn) 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 6.99 mg/L 0.01 Magnesium (Mg) 4.19 mg/L 0.005 Potassium (K) 0.948 mg/L 0.1 Sodium (Na) 11.9 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.132 mg/L 0.005 Barium (Ba) 0.092 mg/L 0.005 Boron (B) 0.060 mg/L 0.05 Iron (Fe) 0.043 mg/L 0.01 Manganese (Mn) 1.000 mg/L 0.005 Strontium (Sr) 0.100 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001814 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 10:57 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/20/2016 21:16 BGN9034 1 EPA 300.0 01/20/2016 21:16 BGN9034 1 EPA 245.1 01/26/2016 16:01 ACPAYNE 1 EPA 245.1 01/25/2016 21:00 ACPAYNE 1 EPA 200.7 01/20/2016 11:53 FCJORDA 1 EPA 200.7 01/20/2016 11:53 FCJORDA 1 EPA 200.7 01/20/2016 11:53 FCJORDA 1 EPA 200.7 01/20/2016 11:53 FCJORDA 1 EPA 200.7 01/20/2016 11:53 FCJORDA 1 EPA 200.7 01/20/2016 11:53 FCJORDA 1 EPA 200.7 01/20/2016 11:53 FCJORDA 1 EPA 200.7 01/20/2016 16:00 FCJORDA 1 EPA 200.7 01/20/2016 16:00 FCJORDA 1 EPA 200.7 01/20/2016 16:00 FCJORDA 1 EPA 200.7 01/20/2016 16:00 FCJORDA 1 EPA 200.7 01/21/2016 15:51 FCJORDA 1 EPA 200.7 01/21/2016 15:51 FCJORDA 1 EPA 200.7 01/21/2016 15:51 FCJORDA 1 EPA 200.7 01/21/2016 15:51 FCJORDA 1 EPA 200.7 01/21/2016 15:51 FCJORDA 1 EPA 200.7 01/21/2016 15:51 FCJORDA 1 EPA 200.7 01/21/2016 15:51 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-15A Collection Date: 18-Jan-16 3:25 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 91 mg/L 25 Total Carbon TOC 0.347 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 15 of 74 Sample #: 2016001814 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 17:54 MHALL3 1 EPA 200.8 01/21/2016 17:54 MHALL3 1 EPA 200.8 01/21/2016 17:54 MHALL3 1 EPA 200.8 01/21/2016 17:54 MHALL3 1 EPA 200.8 01/21/2016 17:54 MHALL3 1 EPA 200.8 01/21/2016 17:54 MHALL3 1 EPA 200.8 01/21/2016 17:54 MHALL3 1 EPA 200.8 01/21/2016 17:54 MHALL3 1 EPA 200.8 01/21/2016 17:54 MHALL3 1 EPA 200.8 01/21/2016 17:54 MHALL3 1 EPA 200.8 01/21/2016 17:54 MHALL3 1 EPA 200.8 01/21/2016 17:54 MHALL3 1 EPA 200.8 01/21/2016 17:54 MHALL3 1 EPA 200.8 01/21/2016 20:21 MHALL3 1 EPA 200.8 01/21/2016 20:21 MHALL3 1 EPA 200.8 01/21/2016 20:21 MHALL3 1 EPA 200.8 01/21/2016 20:21 MHALL3 1 EPA 200.8 01/21/2016 20:21 MHALL3 1 EPA 200.8 01/21/2016 20:21 MHALL3 1 EPA 200.8 01/21/2016 20:21 MHALL3 1 EPA 200.8 01/21/2016 20:21 MHALL3 1 EPA 200.8 01/21/2016 20:21 MHALL3 1 EPA 200.8 01/21/2016 20:21 MHALL3 1 EPA 200.8 01/21/2016 20:21 MHALL3 1 EPA 200.8 01/21/2016 20:21 MHALL3 1 EPA 200.8 01/21/2016 20:21 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/21/201614:35 CJELLIO 1 SM5310C/EPA9060A 01/20/201613:06 GHUTCHI 1 SM2540D 01/21/2016 09:09 CJELLIO Certificate of Laboratory Analysis Page 16 of 74 This report shall not be reproduced, except in full. Order # J16010355 Site: MW-15D Collection Date: 18-Jan-16 2:27 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.793 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 11 mg/L 0.2 Sulfate 0.32 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.009 mg/L 0.005 Barium (Ba) 0.064 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.023 mg/L 0.005 Strontium (Sr) 0.119 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 8.11 mg/L 0.01 Magnesium (Mg) 2.50 mg/L 0.005 Potassium (K) 2.68 mg/L 0.1 Sodium (Na) 7.05 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.070 mg/L 0.005 Barium (Ba) 0.059 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.143 mg/L 0.01 Manganese (Mn) 0.030 mg/L 0.005 Strontium (Sr) 0.118 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001815 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 10:59 LSTARL1 Vendor Method V_PACE 2 EPA 300.0 01/21/2016 08:32 BGN9034 1 EPA 300.0 01/21/2016 08:32 BGN9034 1 EPA 245.1 01/26/2016 16:09 ACPAYNE 1 EPA 245.1 01/25/2016 21:02 ACPAYNE 1 EPA 200.7 01/20/2016 11:57 FCJORDA 1 EPA 200.7 01/20/2016 11:57 FCJORDA 1 EPA 200.7 01/20/2016 11:57 FCJORDA 1 EPA 200.7 01/20/2016 11:57 FCJORDA 1 EPA 200.7 01/20/2016 11:57 FCJORDA 1 EPA 200.7 01/20/2016 11:57 FCJORDA 1 EPA 200.7 01/20/2016 11:57 FCJORDA 1 EPA 200.7 01/20/2016 16:04 FCJORDA 1 EPA 200.7 01/20/2016 16:04 FCJORDA 1 EPA 200.7 01/20/2016 16:04 FCJORDA 1 EPA 200.7 01/20/2016 16:04 FCJORDA 1 EPA 200.7 01/21/2016 15:55 FCJORDA 1 EPA 200.7 01/21/2016 15:55 FCJORDA 1 EPA 200.7 01/21/2016 15:55 FCJORDA 1 EPA 200.7 01/21/2016 15:55 FCJORDA 1 EPA 200.7 01/21/2016 15:55 FCJORDA 1 EPA 200.7 01/21/2016 15:55 FCJORDA 1 EPA 200.7 01/21/2016 15:55 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-15D Collection Date: 18-Jan-16 2:27 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.561 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.736 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 75 mg/L 25 Total Carbon TOC 0.166 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 17 of 74 Sample #: 2016001815 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 17:59 MHALL3 1 EPA 200.8 01/21/2016 17:59 MHALL3 1 EPA 200.8 01/21/2016 17:59 MHALL3 1 EPA 200.8 01/21/2016 17:59 MHALL3 1 EPA 200.8 01/21/2016 17:59 MHALL3 1 EPA 200.8 01/21/2016 17:59 MHALL3 1 EPA 200.8 01/21/2016 17:59 MHALL3 1 EPA 200.8 01/21/2016 17:59 MHALL3 1 EPA 200.8 01/21/2016 17:59 MHALL3 1 EPA 200.8 01/21/2016 17:59 MHALL3 1 EPA 200.8 01/21/2016 17:59 MHALL3 1 EPA 200.8 01/21/2016 17:59 MHALL3 1 EPA 200.8 01/21/2016 17:59 MHALL3 1 EPA 200.8 01/21/2016 20:26 MHALL3 1 EPA 200.8 01/21/2016 20:26 MHALL3 1 EPA 200.8 01/21/2016 20:26 MHALL3 1 EPA 200.8 01/21/2016 20:26 MHALL3 1 EPA 200.8 01/21/2016 20:26 MHALL3 1 EPA 200.8 01/21/2016 20:26 MHALL3 1 EPA 200.8 01/21/2016 20:26 MHALL3 1 EPA 200.8 01/21/2016 20:26 MHALL3 1 EPA 200.8 01/21/2016 20:26 MHALL3 1 EPA 200.8 01/21/2016 20:26 MHALL3 1 EPA 200.8 01/21/2016 20:26 MHALL3 1 EPA 200.8 01/21/2016 20:26 MHALL3 1 EPA 200.8 01/21/2016 20:26 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/21/201614:35 CJELLIO 1 SM5310C/EPA9060A 01/20/201613:06 GHUTCHI 1 SM2540D 01/21/2016 09:09 CJELLIO Certificate of Laboratory Analysis Page 18 of 74 This report shall not be reproduced, except in full. Order # J16010355 Site: MW-11 Collection Date: 18-Jan-16 1:22 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.662 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 120 mg/L 2 Sulfate 30 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.112 mg/L 0.005 Barium (Ba) 0.113 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.259 mg/L 0.005 Strontium (Sr) 0.139 mg/L 0.005 Zinc (Zn) 0.017 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 26.6 mg/L 0.01 Magnesium (Mg) 13.5 mg/L 0.005 Potassium (K) 1.49 mg/L 0.1 Sodium (Na) 40.1 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.145 mg/L 0.005 Barium (Ba) 0.115 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.025 mg/L 0.01 Manganese (Mn) 0.239 mg/L 0.005 Strontium (Sr) 0.137 mg/L 0.005 Zinc (Zn) 0.005 mg/L 0.005 Sample #: 2016001816 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:01 LSTARL1 Vendor Method V_PACE 20 EPA 300.0 01/21/2016 08:49 BGN9034 10 EPA 300.0 01/21/2016 08:49 BGN9034 1 EPA 245.1 01/26/2016 16:11 ACPAYNE 1 EPA 245.1 01/25/2016 21:05 ACPAYNE 1 EPA 200.7 01/20/2016 12:03 FCJORDA 1 EPA 200.7 01/20/2016 12:03 FCJORDA 1 EPA 200.7 01/20/2016 12:03 FCJORDA 1 EPA 200.7 01/20/2016 12:03 FCJORDA 1 EPA 200.7 01/20/2016 12:03 FCJORDA 1 EPA 200.7 01/20/2016 12:03 FCJORDA 1 EPA 200.7 01/20/2016 12:03 FCJORDA 1 EPA 200.7 01/20/2016 16:08 FCJORDA 1 EPA 200.7 01/20/2016 16:08 FCJORDA 1 EPA 200.7 01/20/2016 16:08 FCJORDA 1 EPA 200.7 01/20/2016 16:08 FCJORDA 1 EPA 200.7 01/21/2016 15:59 FCJORDA 1 EPA 200.7 01/21/2016 15:59 FCJORDA 1 EPA 200.7 01/21/2016 15:59 FCJORDA 1 EPA 200.7 01/21/2016 15:59 FCJORDA 1 EPA 200.7 01/21/2016 15:59 FCJORDA 1 EPA 200.7 01/21/2016 15:59 FCJORDA 1 EPA 200.7 01/21/2016 15:59 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-11 Collection Date: 18-Jan-16 1:22 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 2.86 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 4.13 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 4.33 ug/L 1 Cobalt (Co) 1.23 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 4.38 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 280 mg/L 25 Total Carbon TOC 1.1 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 19 of 74 Sample #: 2016001816 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 18:04 MHALL3 1 EPA 200.8 01/21/2016 18:04 MHALL3 1 EPA 200.8 01/21/2016 18:04 MHALL3 1 EPA 200.8 01/21/2016 18:04 MHALL3 1 EPA 200.8 01/21/2016 18:04 MHALL3 1 EPA 200.8 01/21/2016 18:04 MHALL3 1 EPA 200.8 01/21/2016 18:04 MHALL3 1 EPA 200.8 01/21/2016 18:04 MHALL3 1 EPA 200.8 01/21/2016 18:04 MHALL3 1 EPA 200.8 01/21/2016 18:04 MHALL3 1 EPA 200.8 01/21/2016 18:04 MHALL3 1 EPA 200.8 01/21/2016 18:04 MHALL3 1 EPA 200.8 01/21/2016 18:04 MHALL3 1 EPA 200.8 01/21/2016 20:31 MHALL3 1 EPA 200.8 01/21/2016 20:31 MHALL3 1 EPA 200.8 01/21/2016 20:31 MHALL3 1 EPA 200.8 01/21/2016 20:31 MHALL3 1 EPA 200.8 01/21/2016 20:31 MHALL3 1 EPA 200.8 01/21/2016 20:31 MHALL3 1 EPA 200.8 01/21/2016 20:31 MHALL3 1 EPA 200.8 01/21/2016 20:31 MHALL3 1 EPA 200.8 01/21/2016 20:31 MHALL3 1 EPA 200.8 01/21/2016 20:31 MHALL3 1 EPA 200.8 01/21/2016 20:31 MHALL3 1 EPA 200.8 01/21/2016 20:31 MHALL3 1 EPA 200.8 01/21/2016 20:31 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/21/201614:35 CJELLIO 1 SM5310C/EPA9060A 01/20/201613:06 GHUTCHI 1 SM2540D 01/21/2016 09:09 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-11 D Collection Date: 18-Jan-16 12:18 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 2.7 mg-N/L 0.05 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 150 mg/L 2.5 Sulfate 16 mg/L 0.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.106 mg/L 0.005 Barium (Ba) 0.287 mg/L 0.005 Boron (B) 0.054 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.129 mg/L 0.005 Strontium (Sr) 0.307 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 30.4 mg/L 0.01 Magnesium (Mg) 13.4 mg/L 0.005 Potassium (K) 3.51 mg/L 0.1 Sodium (Na) 39.3 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.222 mg/L 0.005 Barium (Ba) 0.300 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.196 mg/L 0.01 Manganese (Mn) 0.134 mg/L 0.005 Strontium (Sr) 0.296 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001817 Matrix: GW WW Page 20 of 74 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 5 EPA 353.2 01/21/2016 11:07 LSTARL1 Vendor Method V_PACE 25 EPA 300.0 01/20/2016 20:42 BGN9034 5 EPA 300.0 01/20/2016 20:42 BGN9034 1 EPA 245.1 01/26/2016 16:14 ACPAYNE 1 EPA 245.1 01/25/2016 21:07 ACPAYNE 1 EPA 200.7 01/20/2016 12:07 FCJORDA 1 EPA 200.7 01/20/2016 12:07 FCJORDA 1 EPA 200.7 01/20/2016 12:07 FCJORDA 1 EPA 200.7 01/20/2016 12:07 FCJORDA 1 EPA 200.7 01/20/2016 12:07 FCJORDA 1 EPA 200.7 01/20/2016 12:07 FCJORDA 1 EPA 200.7 01/20/2016 12:07 FCJORDA 1 EPA 200.7 01/20/2016 16:11 FCJORDA 1 EPA 200.7 01/20/2016 16:11 FCJORDA 1 EPA 200.7 01/20/2016 16:11 FCJORDA 1 EPA 200.7 01/20/2016 16:11 FCJORDA 1 EPA 200.7 01/21/2016 16:03 FCJORDA 1 EPA 200.7 01/21/2016 16:03 FCJORDA 1 EPA 200.7 01/21/2016 16:03 FCJORDA 1 EPA 200.7 01/21/2016 16:03 FCJORDA 1 EPA 200.7 01/21/2016 16:03 FCJORDA 1 EPA 200.7 01/21/2016 16:03 FCJORDA 1 EPA 200.7 01/21/2016 16:03 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-11 D Collection Date: 18-Jan-16 12:18 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 300 mg/L 25 Total Carbon TOC 0.409 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 6.0 mg/L 5 Page 21 of 74 Sample #: 2016001817 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 18:09 MHALL3 1 EPA 200.8 01/21/2016 18:09 MHALL3 1 EPA 200.8 01/21/2016 18:09 MHALL3 1 EPA 200.8 01/21/2016 18:09 MHALL3 1 EPA 200.8 01/21/2016 18:09 MHALL3 1 EPA 200.8 01/21/2016 18:09 MHALL3 1 EPA 200.8 01/21/2016 18:09 MHALL3 1 EPA 200.8 01/21/2016 18:09 MHALL3 1 EPA 200.8 01/21/2016 18:09 MHALL3 1 EPA 200.8 01/21/2016 18:09 MHALL3 1 EPA 200.8 01/21/2016 18:09 MHALL3 1 EPA 200.8 01/21/2016 18:09 MHALL3 1 EPA 200.8 01/21/2016 18:09 MHALL3 1 EPA 200.8 01/21/2016 20:36 MHALL3 1 EPA 200.8 01/21/2016 20:36 MHALL3 1 EPA 200.8 01/21/2016 20:36 MHALL3 1 EPA 200.8 01/21/2016 20:36 MHALL3 1 EPA 200.8 01/21/2016 20:36 MHALL3 1 EPA 200.8 01/21/2016 20:36 MHALL3 1 EPA 200.8 01/21/2016 20:36 MHALL3 1 EPA 200.8 01/21/2016 20:36 MHALL3 1 EPA 200.8 01/21/2016 20:36 MHALL3 1 EPA 200.8 01/21/2016 20:36 MHALL3 1 EPA 200.8 01/21/2016 20:36 MHALL3 1 EPA 200.8 01/21/2016 20:36 MHALL3 1 EPA 200.8 01/21/2016 20:36 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/21/201614:35 CJELLIO 1 SM5310C/EPA9060A 01/20/201613:06 GHUTCHI 1 SM2540D 01/21/2016 09:09 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-14BR Collection Date: 18-Jan-16 10:35 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.621 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 6.2 mg/L 0.5 Sulfate 190 mg/L 2.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.061 mg/L 0.005 Boron (B) 0.352 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) 0.282 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 81.0 mg/L 0.01 Magnesium (Mg) 13.0 mg/L 0.005 Potassium (K) 6.36 mg/L 0.1 Sodium (Na) 8.99 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.036 mg/L 0.005 Barium (Ba) 0.061 mg/L 0.005 Boron (B) 0.352 mg/L 0.05 Iron (Fe) 0.057 mg/L 0.01 Manganese (Mn) 0.016 mg/L 0.005 Strontium (Sr) 0.282 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001818 Matrix: GW WW Page 22 of 74 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:03 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/20/2016 20:59 BGN9034 25 EPA 300.0 01/20/2016 20:59 BGN9034 1 EPA 245.1 01/26/2016 16:16 ACPAYNE 1 EPA 245.1 01/25/2016 21:10 ACPAYNE 1 EPA 200.7 01/20/2016 12:11 FCJORDA 1 EPA 200.7 01/20/2016 12:11 FCJORDA 1 EPA 200.7 01/20/2016 12:11 FCJORDA 1 EPA 200.7 01/20/2016 12:11 FCJORDA 1 EPA 200.7 01/20/2016 12:11 FCJORDA 1 EPA 200.7 01/20/2016 12:11 FCJORDA 1 EPA 200.7 01/20/2016 12:11 FCJORDA 1 EPA 200.7 01/20/2016 16:15 FCJORDA 1 EPA 200.7 01/20/2016 16:15 FCJORDA 1 EPA 200.7 01/20/2016 16:15 FCJORDA 1 EPA 200.7 01/20/2016 16:15 FCJORDA 1 EPA 200.7 01/21/2016 16:07 FCJORDA 1 EPA 200.7 01/21/2016 16:07 FCJORDA 1 EPA 200.7 01/21/2016 16:07 FCJORDA 1 EPA 200.7 01/21/2016 16:07 FCJORDA 1 EPA 200.7 01/21/2016 16:07 FCJORDA 1 EPA 200.7 01/21/2016 16:07 FCJORDA 1 EPA 200.7 01/21/2016 16:07 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-14BR Collection Date: 18-Jan-16 10:35 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 3.87 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) 9.88 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 4.11 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) 9.05 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.333 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 390 mg/L 25 Total Carbon TOC 0.708 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 23 of 74 Sample #: 2016001818 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 18:14 MHALL3 1 EPA 200.8 01/21/2016 18:14 MHALL3 1 EPA 200.8 01/21/2016 18:14 MHALL3 1 EPA 200.8 01/21/2016 18:14 MHALL3 1 EPA 200.8 01/21/2016 18:14 MHALL3 1 EPA 200.8 01/21/2016 18:14 MHALL3 1 EPA 200.8 01/21/2016 18:14 MHALL3 1 EPA 200.8 01/21/2016 18:14 MHALL3 1 EPA 200.8 01/21/2016 18:14 MHALL3 1 EPA 200.8 01/21/2016 18:14 MHALL3 1 EPA 200.8 01/21/2016 18:14 MHALL3 1 EPA 200.8 01/21/2016 18:14 MHALL3 1 EPA 200.8 01/21/2016 18:14 MHALL3 1 EPA 200.8 01/21/2016 20:40 MHALL3 1 EPA 200.8 01/21/2016 20:40 MHALL3 1 EPA 200.8 01/21/2016 20:40 MHALL3 1 EPA 200.8 01/21/2016 20:40 MHALL3 1 EPA 200.8 01/21/2016 20:40 MHALL3 1 EPA 200.8 01/21/2016 20:40 MHALL3 1 EPA 200.8 01/21/2016 20:40 MHALL3 1 EPA 200.8 01/21/2016 20:40 MHALL3 1 EPA 200.8 01/21/2016 20:40 MHALL3 1 EPA 200.8 01/21/2016 20:40 MHALL3 1 EPA 200.8 01/21/2016 20:40 MHALL3 1 EPA 200.8 01/21/2016 20:40 MHALL3 1 EPA 200.8 01/21/2016 20:40 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/21/201614:35 CJELLIO 1 SM5310C/EPA9060A 01/20/201613:06 GHUTCHI 1 SM2540D 01/21/2016 09:09 CJELLIO Certificate of Laboratory Analysis Page 24 of 74 This report shall not be reproduced, except in full. Order # J16010355 Site: GW-1 BR Collection Date: 18-Jan-16 3:56 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 1.5 mg/L 0.1 Sulfate 5.2 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.006 mg/L 0.005 Barium (Ba) 0.011 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.897 mg/L 0.01 Manganese (Mn) 0.063 mg/L 0.005 Strontium (Sr) 0.087 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 16.8 mg/L 0.01 Magnesium (Mg) 3.34 mg/L 0.005 Potassium (K) 3.78 mg/L 0.1 Sodium (Na) 7.28 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.028 mg/L 0.005 Barium (Ba) 0.012 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 1.19 mg/L 0.01 Manganese (Mn) 0.065 mg/L 0.005 Strontium (Sr) 0.088 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001819 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:04 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/20/2016 23:14 BGN9034 1 EPA 300.0 01/20/2016 23:14 BGN9034 1 EPA 245.1 01/26/2016 16:18 ACPAYNE 1 EPA 245.1 01/25/2016 21:12 ACPAYNE 1 EPA 200.7 01/20/2016 12:22 FCJORDA 1 EPA 200.7 01/20/2016 12:22 FCJORDA 1 EPA 200.7 01/20/2016 12:22 FCJORDA 1 EPA 200.7 01/20/2016 12:22 FCJORDA 1 EPA 200.7 01/20/2016 12:22 FCJORDA 1 EPA 200.7 01/20/2016 12:22 FCJORDA 1 EPA 200.7 01/20/2016 12:22 FCJORDA 1 EPA 200.7 01/20/2016 16:27 FCJORDA 1 EPA 200.7 01/20/2016 16:27 FCJORDA 1 EPA 200.7 01/20/2016 16:27 FCJORDA 1 EPA 200.7 01/20/2016 16:27 FCJORDA 1 EPA 200.7 01/21/2016 16:22 FCJORDA 1 EPA 200.7 01/21/2016 16:22 FCJORDA 1 EPA 200.7 01/21/2016 16:22 FCJORDA 1 EPA 200.7 01/21/2016 16:22 FCJORDA 1 EPA 200.7 01/21/2016 16:22 FCJORDA 1 EPA 200.7 01/21/2016 16:22 FCJORDA 1 EPA 200.7 01/21/2016 16:22 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: GW-1 BR Collection Date: 18-Jan-16 3:56 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 3.30 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 3.40 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.317 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 110 mg/L 25 Total Carbon TOC 0.550 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 25 of 74 Sample #: 2016001819 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 18:53 MHALL3 1 EPA 200.8 01/21/2016 18:53 MHALL3 1 EPA 200.8 01/21/2016 18:53 MHALL3 1 EPA 200.8 01/21/2016 18:53 MHALL3 1 EPA 200.8 01/21/2016 18:53 MHALL3 1 EPA 200.8 01/21/2016 18:53 MHALL3 1 EPA 200.8 01/21/2016 18:53 MHALL3 1 EPA 200.8 01/21/2016 18:53 MHALL3 1 EPA 200.8 01/21/2016 18:53 MHALL3 1 EPA 200.8 01/21/2016 18:53 MHALL3 1 EPA 200.8 01/21/2016 18:53 MHALL3 1 EPA 200.8 01/21/2016 18:53 MHALL3 1 EPA 200.8 01/21/2016 18:53 MHALL3 1 EPA 200.8 01/21/2016 21:20 MHALL3 1 EPA 200.8 01/21/2016 21:20 MHALL3 1 EPA 200.8 01/21/2016 21:20 MHALL3 1 EPA 200.8 01/21/2016 21:20 MHALL3 1 EPA 200.8 01/21/2016 21:20 MHALL3 1 EPA 200.8 01/21/2016 21:20 MHALL3 1 EPA 200.8 01/21/2016 21:20 MHALL3 1 EPA 200.8 01/21/2016 21:20 MHALL3 1 EPA 200.8 01/21/2016 21:20 MHALL3 1 EPA 200.8 01/21/2016 21:20 MHALL3 1 EPA 200.8 01/21/2016 21:20 MHALL3 1 EPA 200.8 01/21/2016 21:20 MHALL3 1 EPA 200.8 01/21/2016 21:20 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/21/201614:35 CJELLIO 1 SM5310C/EPA9060A 01/20/201613:06 GHUTCHI 1 SM2540D 01/21/2016 09:09 CJELLIO Certificate of Laboratory Analysis Page 26 of 74 This report shall not be reproduced, except in full. Order # J16010355 Site: GW-1 Collection Date: 18-Jan-16 3:09 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 5.7 mg-N/L 0.05 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 5.5 mg/L 0.1 Sulfate 29 mg/L 0.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 0.19 ug/L B2 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.177 mg/L 0.005 Barium (Ba) 0.075 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.716 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) 0.017 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 10.2 mg/L 0.01 Magnesium (Mg) 8.70 mg/L 0.005 Potassium (K) 0.693 mg/L 0.1 Sodium (Na) 1.13 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.276 mg/L 0.005 Barium (Ba) 0.073 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.104 mg/L 0.01 Manganese (Mn) 0.725 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) 0.014 mg/L 0.005 Sample #: 2016001820 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 5 EPA 353.2 01/21/2016 11:10 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/21/2016 00:22 BGN9034 5 EPA 300.0 01/21/2016 00:22 BGN9034 1 EPA 245.1 01/26/2016 16:21 ACPAYNE 1 EPA 245.1 01/25/2016 21:15 ACPAYNE 1 EPA 200.7 01/20/2016 12:26 FCJORDA 1 EPA 200.7 01/20/2016 12:26 FCJORDA 1 EPA 200.7 01/20/2016 12:26 FCJORDA 1 EPA 200.7 01/20/2016 12:26 FCJORDA 1 EPA 200.7 01/20/2016 12:26 FCJORDA 1 EPA 200.7 01/20/2016 12:26 FCJORDA 1 EPA 200.7 01/20/2016 12:26 FCJORDA 1 EPA 200.7 01/20/2016 16:31 FCJORDA 1 EPA 200.7 01/20/2016 16:31 FCJORDA 1 EPA 200.7 01/20/2016 16:31 FCJORDA 1 EPA 200.7 01/20/2016 16:31 FCJORDA 1 EPA 200.7 01/21/2016 16:33 FCJORDA 1 EPA 200.7 01/21/2016 16:33 FCJORDA 1 EPA 200.7 01/21/2016 16:33 FCJORDA 1 EPA 200.7 01/21/2016 16:33 FCJORDA 1 EPA 200.7 01/21/2016 16:33 FCJORDA 1 EPA 200.7 01/21/2016 16:33 FCJORDA 1 EPA 200.7 01/21/2016 16:33 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: GW-1 Collection Date: 18-Jan-16 3:09 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 1.05 ug/L 1 Cobalt (Co) 6.44 ug/L 1 Copper (Cu) 1.07 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 3.96 ug/L 1 Selenium (Se) 1.47 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 1.20 ug/L 1 Cobalt (Co) 6.13 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 3.40 ug/L 1 Selenium (Se) 1.53 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 82 mg/L 25 Total Carbon TOC 0.655 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 27 of 74 Sample #: 2016001820 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 18:33 MHALL3 1 EPA 200.8 01/21/2016 18:33 MHALL3 1 EPA 200.8 01/21/2016 18:33 MHALL3 1 EPA 200.8 01/21/2016 18:33 MHALL3 1 EPA 200.8 01/21/2016 18:33 MHALL3 1 EPA 200.8 01/21/2016 18:33 MHALL3 1 EPA 200.8 01/21/2016 18:33 MHALL3 1 EPA 200.8 01/21/2016 18:33 MHALL3 1 EPA 200.8 01/21/2016 18:33 MHALL3 1 EPA 200.8 01/21/2016 18:33 MHALL3 1 EPA 200.8 01/21/2016 18:33 MHALL3 1 EPA 200.8 01/21/2016 18:33 MHALL3 1 EPA 200.8 01/21/2016 18:33 MHALL3 1 EPA 200.8 01/21/2016 21:00 MHALL3 1 EPA 200.8 01/21/2016 21:00 MHALL3 1 EPA 200.8 01/21/2016 21:00 MHALL3 1 EPA 200.8 01/21/2016 21:00 MHALL3 1 EPA 200.8 01/21/2016 21:00 MHALL3 1 EPA 200.8 01/21/2016 21:00 MHALL3 1 EPA 200.8 01/21/2016 21:00 MHALL3 1 EPA 200.8 01/21/2016 21:00 MHALL3 1 EPA 200.8 01/21/2016 21:00 MHALL3 1 EPA 200.8 01/21/2016 21:00 MHALL3 1 EPA 200.8 01/21/2016 21:00 MHALL3 1 EPA 200.8 01/21/2016 21:00 MHALL3 1 EPA 200.8 01/21/2016 21:00 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/21/201614:35 CJELLIO 1 SM5310C/EPA9060A 01/20/201613:06 GHUTCHI 1 SM2540D 01/21/2016 09:09 CJELLIO Certificate of Laboratory Analysis Page 28 of 74 This report shall not be reproduced, except in full. Order # J16010355 Site: GW-01 D Collection Date: 18-Jan-16 2:51 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.646 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 4.2 mg/L 0.1 Sulfate 1.4 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 0.09 ug/L B2 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.021 mg/L 0.005 Barium (Ba) 0.031 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.095 mg/L 0.005 Strontium (Sr) 0.024 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 1.66 mg/L 0.01 Magnesium (Mg) 1.73 mg/L 0.005 Potassium (K) 1.09 mg/L 0.1 Sodium (Na) 2.09 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.126 mg/L 0.005 Barium (Ba) 0.036 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.221 mg/L 0.01 Manganese (Mn) 0.097 mg/L 0.005 Strontium (Sr) 0.025 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001821 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:22 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/20/2016 22:23 BGN9034 1 EPA 300.0 01/20/2016 22:23 BGN9034 1 EPA 245.1 01/26/2016 16:23 ACPAYNE 1 EPA 245.1 01/25/2016 21:17 ACPAYNE 1 EPA 200.7 01/20/2016 12:30 FCJORDA 1 EPA 200.7 01/20/2016 12:30 FCJORDA 1 EPA 200.7 01/20/2016 12:30 FCJORDA 1 EPA 200.7 01/20/2016 12:30 FCJORDA 1 EPA 200.7 01/20/2016 12:30 FCJORDA 1 EPA 200.7 01/20/2016 12:30 FCJORDA 1 EPA 200.7 01/20/2016 12:30 FCJORDA 1 EPA 200.7 01/20/2016 16:35 FCJORDA 1 EPA 200.7 01/20/2016 16:35 FCJORDA 1 EPA 200.7 01/20/2016 16:35 FCJORDA 1 EPA 200.7 01/20/2016 16:35 FCJORDA 1 EPA 200.7 01/21/2016 16:37 FCJORDA 1 EPA 200.7 01/21/2016 16:37 FCJORDA 1 EPA 200.7 01/21/2016 16:37 FCJORDA 1 EPA 200.7 01/21/2016 16:37 FCJORDA 1 EPA 200.7 01/21/2016 16:37 FCJORDA 1 EPA 200.7 01/21/2016 16:37 FCJORDA 1 EPA 200.7 01/21/2016 16:37 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: GW-01 D Collection Date: 18-Jan-16 2:51 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.61 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.62 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.10 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.339 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 32 mg/L 25 Total Carbon TOC 0.158 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 29 of 74 Sample #: 2016001821 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 18:58 MHALL3 1 EPA 200.8 01/21/2016 18:58 MHALL3 1 EPA 200.8 01/21/2016 18:58 MHALL3 1 EPA 200.8 01/21/2016 18:58 MHALL3 1 EPA 200.8 01/21/2016 18:58 MHALL3 1 EPA 200.8 01/21/2016 18:58 MHALL3 1 EPA 200.8 01/21/2016 18:58 MHALL3 1 EPA 200.8 01/21/2016 18:58 MHALL3 1 EPA 200.8 01/21/2016 18:58 MHALL3 1 EPA 200.8 01/21/2016 18:58 MHALL3 1 EPA 200.8 01/21/2016 18:58 MHALL3 1 EPA 200.8 01/21/2016 18:58 MHALL3 1 EPA 200.8 01/21/2016 18:58 MHALL3 1 EPA 200.8 01/21/2016 21:24 MHALL3 1 EPA 200.8 01/21/2016 21:24 MHALL3 1 EPA 200.8 01/21/2016 21:24 MHALL3 1 EPA 200.8 01/21/2016 21:24 MHALL3 1 EPA 200.8 01/21/2016 21:24 MHALL3 1 EPA 200.8 01/21/2016 21:24 MHALL3 1 EPA 200.8 01/21/2016 21:24 MHALL3 1 EPA 200.8 01/21/2016 21:24 MHALL3 1 EPA 200.8 01/21/2016 21:24 MHALL3 1 EPA 200.8 01/21/2016 21:24 MHALL3 1 EPA 200.8 01/21/2016 21:24 MHALL3 1 EPA 200.8 01/21/2016 21:24 MHALL3 1 EPA 200.8 01/21/2016 21:24 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/21/201614:35 CJELLIO 1 SM5310C/EPA9060A 01/20/201613:06 GHUTCHI 1 SM2540D 01/21/2016 09:09 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-01 BR Collection Date: 18-Jan-16 11:35 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.013 mg-N/L M2 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 1.7 mg/L 0.1 Sulfate 7.5 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.005 mg/L 0.005 Barium (Ba) 0.016 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 2.68 mg/L 0.01 Manganese (Mn) 0.077 mg/L 0.005 Strontium (Sr) 0.064 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 7.89 mg/L 0.01 Magnesium (Mg) 2.68 mg/L 0.005 Potassium (K) 2.93 mg/L 0.1 Sodium (Na) 5.22 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.037 mg/L 0.005 Barium (Ba) 0.016 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 3.02 mg/L 0.01 Manganese (Mn) 0.075 mg/L 0.005 Strontium (Sr) 0.063 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001822 Matrix: GW WW Page 30 of 74 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:19 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/20/2016 23:48 BGN9034 1 EPA 300.0 01/20/2016 23:48 BGN9034 1 EPA 245.1 01/26/2016 16:26 ACPAYNE 1 EPA 245.1 01/25/2016 20:45 ACPAYNE 1 EPA 200.7 01/20/2016 12:34 FCJORDA 1 EPA 200.7 01/20/2016 12:34 FCJORDA 1 EPA 200.7 01/20/2016 12:34 FCJORDA 1 EPA 200.7 01/20/2016 12:34 FCJORDA 1 EPA 200.7 01/20/2016 12:34 FCJORDA 1 EPA 200.7 01/20/2016 12:34 FCJORDA 1 EPA 200.7 01/20/2016 12:34 FCJORDA 1 EPA 200.7 01/20/2016 16:38 FCJORDA 1 EPA 200.7 01/20/2016 16:38 FCJORDA 1 EPA 200.7 01/20/2016 16:38 FCJORDA 1 EPA 200.7 01/20/2016 16:38 FCJORDA 1 EPA 200.7 01/21/2016 16:41 FCJORDA 1 EPA 200.7 01/21/2016 16:41 FCJORDA 1 EPA 200.7 01/21/2016 16:41 FCJORDA 1 EPA 200.7 01/21/2016 16:41 FCJORDA 1 EPA 200.7 01/21/2016 16:41 FCJORDA 1 EPA 200.7 01/21/2016 16:41 FCJORDA 1 EPA 200.7 01/21/2016 16:41 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-01 BR Collection Date: 18-Jan-16 11:35 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 56 mg/L 25 Total Carbon TOC 0.113 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 31 of 74 Sample #: 2016001822 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 19:03 MHALL3 1 EPA 200.8 01/21/2016 19:03 MHALL3 1 EPA 200.8 01/21/2016 19:03 MHALL3 1 EPA 200.8 01/21/2016 19:03 MHALL3 1 EPA 200.8 01/21/2016 19:03 MHALL3 1 EPA 200.8 01/21/2016 19:03 MHALL3 1 EPA 200.8 01/21/2016 19:03 MHALL3 1 EPA 200.8 01/21/2016 19:03 MHALL3 1 EPA 200.8 01/21/2016 19:03 MHALL3 1 EPA 200.8 01/21/2016 19:03 MHALL3 1 EPA 200.8 01/21/2016 19:03 MHALL3 1 EPA 200.8 01/21/2016 19:03 MHALL3 1 EPA 200.8 01/21/2016 19:03 MHALL3 1 EPA 200.8 01/21/2016 21:29 MHALL3 1 EPA 200.8 01/21/2016 21:29 MHALL3 1 EPA 200.8 01/21/2016 21:29 MHALL3 1 EPA 200.8 01/21/2016 21:29 MHALL3 1 EPA 200.8 01/21/2016 21:29 MHALL3 1 EPA 200.8 01/21/2016 21:29 MHALL3 1 EPA 200.8 01/21/2016 21:29 MHALL3 1 EPA 200.8 01/21/2016 21:29 MHALL3 1 EPA 200.8 01/21/2016 21:29 MHALL3 1 EPA 200.8 01/21/2016 21:29 MHALL3 1 EPA 200.8 01/21/2016 21:29 MHALL3 1 EPA 200.8 01/21/2016 21:29 MHALL3 1 EPA 200.8 01/21/2016 21:29 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/21/201614:35 CJELLIO 1 SM5310C/EPA9060A 01/20/201613:06 GHUTCHI 1 SM2540D 01/21/2016 09:09 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-01 D Collection Date: 18-Jan-16 10:44 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 1.3 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 3.6 mg/L 0.1 Sulfate 3.5 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.018 mg/L 0.005 Barium (Ba) 0.016 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.038 mg/L 0.005 Strontium (Sr) 0.030 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 2.13 mg/L 0.01 Magnesium (Mg) 2.37 mg/L 0.005 Potassium (K) 1.11 mg/L 0.1 Sodium (Na) 2.69 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.028 mg/L 0.005 Barium (Ba) 0.019 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.071 mg/L 0.01 Manganese (Mn) 0.039 mg/L 0.005 Strontium (Sr) 0.028 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016001823 Matrix: GW WW Page 32 of 74 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/21/2016 11:26 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/21/2016 00:05 BGN9034 1 EPA 300.0 01/21/2016 00:05 BGN9034 1 EPA 245.1 01/26/2016 16:28 ACPAYNE 1 EPA 245.1 01/27/2016 14:33 ACPAYNE 1 EPA 200.7 01/20/2016 12:45 FCJORDA 1 EPA 200.7 01/20/2016 12:45 FCJORDA 1 EPA 200.7 01/20/2016 12:45 FCJORDA 1 EPA 200.7 01/20/2016 12:45 FCJORDA 1 EPA 200.7 01/20/2016 12:45 FCJORDA 1 EPA 200.7 01/20/2016 12:45 FCJORDA 1 EPA 200.7 01/20/2016 12:45 FCJORDA 1 EPA 200.7 01/20/2016 16:42 FCJORDA 1 EPA 200.7 01/20/2016 16:42 FCJORDA 1 EPA 200.7 01/20/2016 16:42 FCJORDA 1 EPA 200.7 01/20/2016 16:42 FCJORDA 1 EPA 200.7 01/21/2016 16:45 FCJORDA 1 EPA 200.7 01/21/2016 16:45 FCJORDA 1 EPA 200.7 01/21/2016 16:45 FCJORDA 1 EPA 200.7 01/21/2016 16:45 FCJORDA 1 EPA 200.7 01/21/2016 16:45 FCJORDA 1 EPA 200.7 01/21/2016 16:45 FCJORDA 1 EPA 200.7 01/21/2016 16:45 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010355 Site: MW-01 D Collection Date: 18-Jan-16 10:44 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 2.83 ug/L 1 Copper (Cu) 2.90 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 3.45 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 2.47 ug/L 1 Copper (Cu) 2.68 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 2.56 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 37 mg/L 25 Total Carbon TOC 0.139 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 33 of 74 Sample #: 2016001823 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/21/2016 19:07 MHALL3 1 EPA 200.8 01/21/2016 19:07 MHALL3 1 EPA 200.8 01/21/2016 19:07 MHALL3 1 EPA 200.8 01/21/2016 19:07 MHALL3 1 EPA 200.8 01/21/2016 19:07 MHALL3 1 EPA 200.8 01/21/2016 19:07 MHALL3 1 EPA 200.8 01/21/2016 19:07 MHALL3 1 EPA 200.8 01/21/2016 19:07 MHALL3 1 EPA 200.8 01/21/2016 19:07 MHALL3 1 EPA 200.8 01/21/2016 19:07 MHALL3 1 EPA 200.8 01/21/2016 19:07 MHALL3 1 EPA 200.8 01/21/2016 19:07 MHALL3 1 EPA 200.8 01/21/2016 19:07 MHALL3 1 EPA 200.8 01/21/2016 21:34 MHALL3 1 EPA 200.8 01/21/2016 21:34 MHALL3 1 EPA 200.8 01/21/2016 21:34 MHALL3 1 EPA 200.8 01/21/2016 21:34 MHALL3 1 EPA 200.8 01/21/2016 21:34 MHALL3 1 EPA 200.8 01/21/2016 21:34 MHALL3 1 EPA 200.8 01/21/2016 21:34 MHALL3 1 EPA 200.8 01/21/2016 21:34 MHALL3 1 EPA 200.8 01/21/2016 21:34 MHALL3 1 EPA 200.8 01/21/2016 21:34 MHALL3 1 EPA 200.8 01/21/2016 21:34 MHALL3 1 EPA 200.8 01/21/2016 21:34 MHALL3 1 EPA 200.8 01/21/2016 21:34 MHALL3 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/21/201614:35 CJELLIO 1 SM5310C/EPA9060A 01/20/201613:06 GHUTCHI 1 SM2540D 01/21/2016 09:09 CJELLIO Certificate of Laboratory Analysis Page 34 of 74 This report shall not be reproduced, except in full. Order # J16010355 Qualifiers: B2 Target analyte was detected in blank(s) at a concentration greater than the reporting limit but less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes. M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, INC 28078 (704)875-9092 January 26, 2016 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 16010355 Pace Project No.: 92283470 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on January 19, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Program Manager, Duke Energy Anne Pifer Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 39 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. offig l9gcsffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J16010355 Pace Project No.: 92283470 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 525 N 8th Street, Salina, KS 67401 A21-A Certification M 2926.01 Alaska Certification M UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification M 88-0680 California Certification M 01155CA Colorado Certification #Pace Connecticut Certification M PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification M 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification M 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification M 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification M 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification M E83079 Georgia Certification M 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification M 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification M E-10383 Kentucky Certification #: 90050 Louisiana Certification M FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification M Cert 0074 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification M TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification M 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098v i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J16010355 Pace Project No.: 92283470 Lab ID Sample ID Matrix Date Collected Date Received 92283470001 2016001809 Water 01/18/1616:01 01/19/1613:00 92283470002 2016001810 Water 01/18/1614:04 01/19/1613:00 92283470003 2016001811 Water 01/18/1612:08 01/19/1613:00 92283470004 2016001812 Water 01/18/1611:21 01/19/1613:00 92283470005 2016001813 Water 01/18/1616:23 01/19/1613:00 92283470006 2016001814 Water 01/18/1615:25 01/19/1613:00 92283470007 2016001815 Water 01/18/1614:27 01/19/1613:00 92283470008 2016001816 Water 01/18/1613:22 01/19/1613:00 92283470009 2016001817 Water 01/18/1612:18 01/19/1613:00 92283470010 2016001818 Water 01/18/1610:35 01/19/1613:00 92283470011 2016001819 Water 01/18/1615:56 01/19/1613:00 92283470012 2016001820 Water 01/18/1615:09 01/19/1613:00 92283470013 2016001821 Water 01/18/1614:51 01/19/1613:00 92283470014 2016001822 Water 01/18/1611:35 01/19/1613:00 92283470015 2016001823 Water 01/18/1610:44 01/19/1613:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J16010355 92283470 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92283470001 2016001809 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283470002 2016001810 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283470003 2016001811 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283470004 2016001812 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283470005 2016001813 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283470006 2016001814 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283470007 2016001815 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283470008 2016001816 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283470009 2016001817 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283470010 2016001818 RSK 175 STV 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J16010355 Pace Project No.: 92283470 Analytes Lab ID Sample ID Method Analysts Reported Laboratory SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283470011 2016001819 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283470012 2016001820 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283470013 2016001821 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283470014 2016001822 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92283470015 2016001823 RSK 175 STV 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J16010355 92283470 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92283470001 2016001809 RSK 175 Methane 1100 ug/L 10.0 01/21/16 15:11 SM 2320B Alkalinity, Bicarbonate (CaCO3) 36.4 mg/L 5.0 01/21/16 22:47 SM 2320B Alkalinity, Total as CaCO3 36.4 mg/L 5.0 01/21/16 22:47 92283470002 2016001810 SM 2320B Alkalinity, Bicarbonate (CaCO3) 10.0 mg/L 5.0 01/21/16 22:57 SM 2320B Alkalinity, Total as CaCO3 10.0 mg/L 5.0 01/21/16 22:57 92283470003 2016001811 EPA 218.7 Chromium, Hexavalent 0.57 ug/L 0.15 01/21/1609:03 92283470004 2016001812 SM 2320B Alkalinity, Bicarbonate (CaCO3) 15.7 mg/L 5.0 01/24/16 13:17 SM 2320B Alkalinity, Total as CaCO3 15.7 mg/L 5.0 01/24/16 13:17 92283470005 2016001813 EPA 218.7 Chromium, Hexavalent 0.034 ug/L 0.030 01/20/1619:38 92283470007 2016001815 SM 2320B Alkalinity, Bicarbonate (CaCO3) 32.4 mg/L 5.0 01/24/16 13:46 SM 2320B Alkalinity, Total as CaCO3 32.4 mg/L 5.0 01/24/16 13:46 EPA 218.7 Chromium, Hexavalent 0.17 ug/L 0.030 01/20/16 20:04 92283470008 2016001816 SM 2320B Alkalinity, Bicarbonate (CaCO3) 29.5 mg/L 5.0 01/24/16 13:57 SM 2320B Alkalinity, Total as CaCO3 29.5 mg/L 5.0 01/24/16 13:57 EPA 218.7 Chromium, Hexavalent 0.48 ug/L 0.15 01/21/1609:16 92283470009 2016001817 SM 2320B Alkalinity, Bicarbonate (CaCO3) 6.3 mg/L 5.0 01/24/16 14:27 SM 2320B Alkalinity, Total as CaCO3 6.3 mg/L 5.0 01/24/16 14:27 EPA 218.7 Chromium, Hexavalent 0.091 ug/L 0.030 01/20/16 20:30 92283470010 2016001818 SM 2320B Alkalinity, Bicarbonate (CaCO3) 98.6 mg/L 5.0 01/24/16 14:38 SM 2320B Alkalinity, Total as CaCO3 98.6 mg/L 5.0 01/24/16 14:38 EPA 218.7 Chromium, Hexavalent 0.15 ug/L 0.030 01/20/16 20:43 92283470011 2016001819 SM 2320B Alkalinity, Bicarbonate (CaCO3) 70.4 mg/L 5.0 01/24/16 14:49 SM 2320B Alkalinity, Total as CaCO3 70.4 mg/L 5.0 01/24/16 14:49 92283470012 2016001820 SM 2320B Alkalinity, Bicarbonate (CaCO3) 5.5 mg/L 5.0 01/24/16 15:00 SM 2320B Alkalinity, Total as CaCO3 5.5 mg/L 5.0 01/24/16 15:00 EPA 218.7 Chromium, Hexavalent 0.87 ug/L 0.15 01/21/1609:29 92283470013 2016001821 SM 2320B Alkalinity, Bicarbonate (CaCO3) 7.7 mg/L 5.0 01/24/16 15:10 SM 2320B Alkalinity, Total as CaCO3 7.7 mg/L 5.0 01/24/16 15:10 EPA 218.7 Chromium, Hexavalent 0.091 ug/L 0.030 01/20/16 22:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gWinic8f fte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J16010355 Pace Project No.: 92283470 Lab Sample ID Method 92283470014 SM 2320B SM 2320B 92283470015 SM 2320B SM 2320B SUMMARY OF DETECTION Client Sample ID Parameters 2016001822 Alkalinity, Bicarbonate (CaCO3) Alkalinity, Total as CaCO3 2016001823 Alkalinity, Bicarbonate (CaCO3) Alkalinity, Total as CaCO3 Result Units 36.3 mg/L 36.3 mg/L 10.3 mg/L 10.3 mg/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Report Limit Analyzed Qualifiers 5.0 01/24/1615:40 5.0 01/24/1615:40 5.0 01/24/1615:50 5.0 01/24/1615:50 Page 7 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinffte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010355 Pace Project No.: 92283470 Method: RSK 175 Description: RSK 175 AIR Headspace Client: Duke Energy Date: January 26, 2016 General Information: 15 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010355 Pace Project No.: 92283470 Method: SM 2320B Description: 2320E Alkalinity Client: Duke Energy Date: January 26, 2016 General Information: 15 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WET/42615 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35224916005,35224916019 M1: Matrix spike recovery exceeded QC limits. • MS (Lab ID: 1651483) • Alkalinity, Total as CaCO3 • MS (Lab ID: 1651485) • Alkalinity, Total as CaCO3 • MSD (Lab ID: 1651484) • Alkalinity, Total as CaCO3 • MSD (Lab ID: 1651486) • Alkalinity, Total as CaCO3 Additional Comments: Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010355 Pace Project No.: 92283470 Method: SM 4500-S213 Description: 4500S2D Sulfide Water Client: Duke Energy Date: January 26, 2016 General Information: 15 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098�t�i .8ffte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010355 Pace Project No.: 92283470 Method: EPA 218.7 Description: Hexavalent Chromium by IC Client: Duke Energy Date: January 26, 2016 General Information: 15 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010355 Pace Project No.: 92283470 Sample: 2016001809 Lab ID: 92283470001 Collected: 01/18/16 16:01 Received: 01/19/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 1100 ug/L 10.0 1 01/21/1615:11 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 36.4 mg/L 5.0 1 01/21/16 22:47 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/21/16 22:47 Alkalinity, Total as CaCO3 36.4 mg/L 5.0 1 01/21/16 22:47 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/20/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/20/16 18:20 18540-29-9 Date: 01/26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010355 Pace Project No.: 92283470 Sample: 2016001810 Lab ID: 92283470002 Collected: 01/18/16 14:04 Received: 01/19/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/1615:20 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 10.0 mg/L 5.0 1 01/21/16 22:57 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/21/16 22:57 Alkalinity, Total as CaCO3 10.0 mg/L 5.0 1 01/21/16 22:57 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/20/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/20/16 18:59 18540-29-9 Date: 01/26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010355 Pace Project No.: 92283470 Sample: 2016001811 Lab ID: 92283470003 Collected: 01/18/16 12:08 Received: 01/19/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/1615:28 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/24/16 12:43 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 12:43 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/24/16 12:43 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/20/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.57 ug/L 0.15 5 01/21/16 09:03 18540-29-9 Date: 01/26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010355 Pace Project No.: 92283470 Sample: 2016001812 Lab ID: 92283470004 Collected: 01/18/16 11:21 Received: 01/19/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/1615:36 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 15.7 mg/L 5.0 1 01/24/16 13:17 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 13:17 Alkalinity, Total as CaCO3 15.7 mg/L 5.0 1 01/24/16 13:17 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/20/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/20/16 19:25 18540-29-9 Date: 01/26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010355 Pace Project No.: 92283470 Sample: 2016001813 Lab ID: 92283470005 Collected: 01/18/16 16:23 Received: 01/19/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/1615:44 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/24/16 13:28 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 13:28 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/24/16 13:28 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/20/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.034 ug/L 0.030 1 01/20/16 19:38 18540-29-9 Date: 01/26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010355 Pace Project No.: 92283470 Sample: 2016001814 Lab ID: 92283470006 Collected: 01/18/16 15:25 Received: 01/19/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/1616:30 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/24/16 13:37 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 13:37 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/24/16 13:37 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/20/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/20/16 19:51 18540-29-9 Date: 01/26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010355 Pace Project No.: 92283470 Sample: 2016001815 Lab ID: 92283470007 Collected: 01/18/16 14:27 Received: 01/19/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/1616:47 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 32.4 mg/L 5.0 1 01/24/16 13:46 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 13:46 Alkalinity, Total as CaCO3 32.4 mg/L 5.0 1 01/24/16 13:46 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/20/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.17 ug/L 0.030 1 01/20/16 20:04 18540-29-9 Date: 01/26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010355 Pace Project No.: 92283470 Sample: 2016001816 Lab ID: 92283470008 Collected: 01/18/16 13:22 Received: 01/19/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/1616:55 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 29.5 mg/L 5.0 1 01/24/16 13:57 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 13:57 Alkalinity, Total as CaCO3 29.5 mg/L 5.0 1 01/24/16 13:57 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/20/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.48 ug/L 0.15 5 01/21/16 09:16 18540-29-9 Date: 01/26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010355 Pace Project No.: 92283470 Sample: 2016001817 Lab ID: 92283470009 Collected: 01/18/16 12:18 Received: 01/19/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/1617:03 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 6.3 mg/L 5.0 1 01/24/16 14:27 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 14:27 Alkalinity, Total as CaCO3 6.3 mg/L 5.0 1 01/24/16 14:27 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/20/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.091 ug/L 0.030 1 01/20/16 20:30 18540-29-9 Date: 01/26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010355 Pace Project No.: 92283470 Sample: 2016001818 Lab ID: 92283470010 Collected: 01/18/16 10:35 Received: 01/19/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/1617:11 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 98.6 mg/L 5.0 1 01/24/16 14:38 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 14:38 Alkalinity, Total as CaCO3 98.6 mg/L 5.0 1 01/24/16 14:38 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/20/1615:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.15 ug/L 0.030 1 01/20/16 20:43 18540-29-9 Date: 01/26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010355 Pace Project No.: 92283470 Sample: 2016001819 Lab ID: 92283470011 Collected: 01/18/16 15:56 Received: 01/19/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/1617:20 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 70.4 mg/L 5.0 1 01/24/16 14:49 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 14:49 Alkalinity, Total as CaCO3 70.4 mg/L 5.0 1 01/24/16 14:49 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/20/1616:02 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/20/16 21:48 18540-29-9 Date: 01/26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010355 Pace Project No.: 92283470 Sample: 2016001820 Lab ID: 92283470012 Collected: 01/18/16 15:09 Received: 01/19/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/1617:28 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 5.5 mg/L 5.0 1 01/24/16 15:00 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 15:00 Alkalinity, Total as CaCO3 5.5 mg/L 5.0 1 01/24/16 15:00 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/20/1616:02 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.87 ug/L 0.15 5 01/21/16 09:29 18540-29-9 Date: 01/26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010355 Pace Project No.: 92283470 Sample: 2016001821 Lab ID: 92283470013 Collected: 01/18/16 14:51 Received: 01/19/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/1617:36 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 7.7 mg/L 5.0 1 01/24/16 15:10 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 15:10 Alkalinity, Total as CaCO3 7.7 mg/L 5.0 1 01/24/16 15:10 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/20/1616:02 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.091 ug/L 0.030 1 01/20/16 22:40 18540-29-9 Date: 01/26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010355 Pace Project No.: 92283470 Sample: 2016001822 Lab ID: 92283470014 Collected: 01/18/16 11:35 Received: 01/19/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/1617:44 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 36.3 mg/L 5.0 1 01/24/16 15:40 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 15:40 Alkalinity, Total as CaCO3 36.3 mg/L 5.0 1 01/24/16 15:40 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/20/1616:02 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/20/16 22:53 18540-29-9 Date: 01/26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010355 Pace Project No.: 92283470 Sample: 2016001823 Lab ID: 92283470015 Collected: 01/18/16 10:44 Received: 01/19/16 13:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/21/1618:09 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 10.3 mg/L 5.0 1 01/24/16 15:50 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/24/16 15:50 Alkalinity, Total as CaCO3 10.3 mg/L 5.0 1 01/24/16 15:50 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/20/1616:02 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/20/16 23:06 18540-29-9 Date: 01/26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinic&�r fte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010355 Pace Project No.: 92283470 QC Batch: AIR/25052 Analysis Method: RSK 175 QC Batch Method: RSK 175 Analysis Description: RSK 175 AIR HEADSPACE Associated Lab Samples: 92283470001, 92283470002, 92283470003, 92283470004, 92283470005 METHOD BLANK: 2177725 Matrix: Water Associated Lab Samples: 92283470001, 92283470002, 92283470003, 92283470004, 92283470005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Methane ug/L ND 10.0 01/21/1612:39 LABORATORY CONTROL SAMPLE & LCSD: 2177726 2177727 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Methane ug/L 60.7 60.2 60.6 99 100 85-115 1 20 SAMPLE DUPLICATE: 2178902 10336339019 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 3.1J 20 SAMPLE DUPLICATE: 2178903 92283352007 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L 1970 2010 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/26/2016 11:42 AM without the written consent of Pace Analytical Services, Inc.. Page 27 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010355 Pace Project No.: 92283470 QC Batch: AIR/25065 Analysis Method: RSK 175 QC Batch Method: RSK 175 Analysis Description: RSK 175 AIR HEADSPACE Associated Lab Samples: 92283470006,92283470007,92283470008,92283470009,92283470010,92283470011,92283470012, 92283470013,92283470014,92283470015 METHOD BLANK: 2178463 Matrix: Water Associated Lab Samples: 92283470006,92283470007,92283470008,92283470009,92283470010,92283470011,92283470012, 92283470013,92283470014,92283470015 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Methane ug/L ND 10.0 01/21/1616:22 LABORATORY CONTROL SAMPLE & LCSD: 2178464 2178465 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Methane ug/L 60.7 60.6 61.6 100 102 85-115 2 20 SAMPLE DUPLICATE: 2179324 92283470006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 2J 20 SAMPLE DUPLICATE: 2179325 92283470015 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 1AJ 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/26/2016 11:42 AM without the written consent of Pace Analytical Services, Inc.. Page 28 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010355 Pace Project No.: 92283470 QC Batch: WET/42615 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 92283470001, 92283470002 METHOD BLANK: 1651481 Associated Lab Samples: 92283470001, 92283470002 Parameter Units Alkalinity, Carbonate (CaCO3) mg/L Alkalinity, Total as CaCO3 mg/L Alkalinity, Bicarbonate (CaCO3) mg/L LABORATORY CONTROL SAMPLE: 1651482 Parameter Units Alkalinity, Total as CaCO3 mg/L Matrix: Water Blank Reporting Result Limit Analyzed ND 5.0 01/21/1617:12 ND 5.0 01/21/1617:12 ND 5.0 01/21/1617:12 Spike LCS Conc. Result 50 50.0 Qualifiers LCS % Rec % Rec Limits Qualifiers 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1651483 1651484 MS MSD 35224916005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 215 50 50 714 710 997 989 80-120 1 25 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1651485 1651486 MS MSD 35224916019 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Alkalinity, Total as CaCO3 mg/L 246 50 50 744 749 997 1010 80-120 1 25 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/26/2016 11:42 AM without the written consent of Pace Analytical Services, Inc.. Page 29 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010355 Pace Project No.: 92283470 QC Batch: WET/42616 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 92283470003, 92283470004, 92283470005, 92283470006, 92283470007, 92283470008, 92283470009, 92283470010,92283470011,92283470012,92283470013,92283470014,92283470015 METHOD BLANK: 1651489 Matrix: Water Associated Lab Samples: 92283470003, 92283470004, 92283470005, 92283470006, 92283470007, 92283470008, 92283470009, 92283470010,92283470011,92283470012,92283470013,92283470014,92283470015 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Alkalinity, Carbonate (CaCO3) mg/L ND 5.0 01/24/16 12:21 Alkalinity, Total as CaCO3 mg/L ND 5.0 01/24/16 12:21 Alkalinity, Bicarbonate (CaCO3) mg/L ND 5.0 01/24/16 12:21 LABORATORY CONTROL SAMPLE: 1651490 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 48.8 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1651491 1651492 MS MSD 92283470003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Alkalinity, Total as CaCO3 mg/L ND 50 50 53.1 53.1 97 97 80-120 0 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1651493 1651494 MS MSD 92283470013 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 7.7 50 50 56.3 55.9 97 96 80-120 1 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/26/2016 11:42 AM without the written consent of Pace Analytical Services, Inc.. Page 30 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010355 Pace Project No.: 92283470 QC Batch: WET/42590 Analysis Method: SM 4500-S2D QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 92283470001, 92283470002, 92283470003, 92283470004, 92283470005, 92283470006, 92283470007, 92283470008,92283470009,92283470010 METHOD BLANK: 1650677 Matrix: Water Associated Lab Samples: 92283470001, 92283470002, 92283470003, 92283470004, 92283470005, 92283470006, 92283470007, 92283470008,92283470009,92283470010 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide mg/L ND 0.10 01/20/1615:30 LABORATORY CONTROL SAMPLE: 1650678 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide mg/L .5 0.51 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1650679 1650680 MS MSD 92283352001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Sulfide mg/L ND .5 .5 0.49 0.49 98 98 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1650681 1650682 MS MSD 92283470001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Sulfide mg/L ND .5 .5 0.54 0.54 109 109 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/26/2016 11:42 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010355 Pace Project No.: 92283470 QC Batch: WET/42591 Analysis Method: SM 4500-S2D QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 92283470011, 92283470012, 92283470013, 92283470014, 92283470015 METHOD BLANK: 1650684 Matrix: Water Associated Lab Samples: 92283470011, 92283470012, 92283470013, 92283470014, 92283470015 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide mg/L ND 0.10 01/20/1616:02 LABORATORY CONTROL SAMPLE: 1650685 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide mg/L .5 0.51 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1650686 1650687 MS MSD 92283470011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide mg/L ND .5 .5 0.55 0.55 93 93 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/26/2016 11:42 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010355 Pace Project No.: 92283470 QC Batch: WETA/54049 Analysis Method: EPA 218.7 QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC Associated Lab Samples: 92283470001, 92283470002, 92283470003, 92283470004, 92283470005, 92283470006, 92283470007, 92283470008,92283470009,92283470010 METHOD BLANK: 1453501 Matrix: Water Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chromium, Hexavalent ug/L ND 0.030 01/20/16 13:53 LABORATORY CONTROL SAMPLE: 1453502 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chromium, Hexavalent ug/L .075 0.067 89 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1453503 1453504 MS MSD 92283352001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent ug/L ND .025 .025 0.035 0.034 83 78 85-115 4 20 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1453505 1453506 MS MSD 92283470001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent ug/L ND .075 .075 0.082 0.067 109 90 85-115 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/26/2016 11:42 AM without the written consent of Pace Analytical Services, Inc.. Page 33 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010355 Pace Project No.: 92283470 QC Batch: WETA/54056 Analysis Method: EPA 218.7 QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC Associated Lab Samples: 92283470011, 92283470012, 92283470013, 92283470014, 92283470015 METHOD BLANK: 1453816 Matrix: Water Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chromium, Hexavalent ug/L ND 0.030 01/20/16 21:22 LABORATORY CONTROL SAMPLE: 1453817 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chromium, Hexavalent ug/L .075 0.079 105 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1453818 1453819 MS MSD 92283470011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent ug/L ND .075 .075 0.068 0.073 91 98 85-115 7 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/26/2016 11:42 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 39 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J16010355 Pace Project No.: 92283470 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/26/2016 11:42 AM without the written consent of Pace Analytical Services, Inc.. Page 35 of 39 acmnalytical www.pacelabs.com Pace Analytical Services, Inc. og6g I bc&f fte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J16010355 Pace Project No.: 92283470 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92283470001 2016001809 RSK 175 AIR/25052 92283470002 2016001810 RSK 175 AIR/25052 92283470003 2016001811 RSK 175 AIR/25052 92283470004 2016001812 RSK 175 AIR/25052 92283470005 2016001813 RSK 175 AIR/25052 92283470006 2016001814 RSK 175 AIR/25065 92283470007 2016001815 RSK 175 AIR/25065 92283470008 2016001816 RSK 175 AIR/25065 92283470009 2016001817 RSK 175 AIR/25065 92283470010 2016001818 RSK 175 AIR/25065 92283470011 2016001819 RSK 175 AIR/25065 92283470012 2016001820 RSK 175 AIR/25065 92283470013 2016001821 RSK 175 AIR/25065 92283470014 2016001822 RSK 175 AIR/25065 92283470015 2016001823 RSK 175 AIR/25065 92283470001 2016001809 SM 2320B WET/42615 92283470002 2016001810 SM 2320B WET/42615 92283470003 2016001811 SM 2320B WET/42616 92283470004 2016001812 SM 2320B WET/42616 92283470005 2016001813 SM 2320B WET/42616 92283470006 2016001814 SM 2320B WET/42616 92283470007 2016001815 SM 2320B WET/42616 92283470008 2016001816 SM 2320B WET/42616 92283470009 2016001817 SM 2320B WET/42616 92283470010 2016001818 SM 2320B WET/42616 92283470011 2016001819 SM 2320B WET/42616 92283470012 2016001820 SM 2320B WET/42616 92283470013 2016001821 SM 2320B WET/42616 92283470014 2016001822 SM 2320B WET/42616 92283470015 2016001823 SM 2320B WET/42616 92283470001 2016001809 SM 4500-S2D WET/42590 92283470002 2016001810 SM 4500-S2D WET/42590 92283470003 2016001811 SM 4500-S2D WET/42590 92283470004 2016001812 SM 4500-S2D WET/42590 92283470005 2016001813 SM 4500-S2D WET/42590 92283470006 2016001814 SM 4500-S2D WET/42590 92283470007 2016001815 SM 4500-S2D WET/42590 92283470008 2016001816 SM 4500-S2D WET/42590 92283470009 2016001817 SM 4500-S2D WET/42590 92283470010 2016001818 SM 4500-S2D WET/42590 92283470011 2016001819 SM 4500-S2D WET/42591 92283470012 2016001820 SM 4500-S2D WET/42591 92283470013 2016001821 SM 4500-S2D WET/42591 92283470014 2016001822 SM 4500-S2D WET/42591 92283470015 2016001823 SM 4500-S2D WET/42591 92283470001 2016001809 EPA 218.7 WETA/54049 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /26/2016 11:42 AM without the written consent of Pace Analytical Services, Inc.. Page 36 of 39 acmnalytical www.pacelabs.com Pace Analytical Services, Inc. og6g inlc&f fte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J16010355 Pace Project No.: 92283470 Lab ID Sample ID QC Batch Method QC Batch 92283470002 2016001810 EPA 218.7 WETA/54049 92283470003 2016001811 EPA 218.7 WETA/54049 92283470004 2016001812 EPA 218.7 WETA/54049 92283470005 2016001813 EPA 218.7 WETA/54049 92283470006 2016001814 EPA 218.7 WETA/54049 92283470007 2016001815 EPA 218.7 WETA/54049 92283470008 2016001816 EPA 218.7 WETA/54049 92283470009 2016001817 EPA 218.7 WETA/54049 92283470010 2016001818 EPA 218.7 WETA/54049 92283470011 2016001819 EPA 218.7 WETA/54056 92283470012 2016001820 EPA 218.7 WETA/54056 92283470013 2016001821 EPA 218.7 WETA/54056 92283470014 2016001822 EPA 218.7 WETA/54056 92283470015 2016001823 EPA 218.7 WETA/54056 Date: 01 /26/2016 11:42 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Method Analytical Batch Page 37 of 39 Document Name: Document Revised: 260CT2015 aCBAr�alyflCal Sample Condition Upon Recelpt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CHR-CS-003-rev.17 Pace Huntersville Quality Office Client Name: Project #: 0. f Courier: ❑Fed ❑UPS ❑LISPS ❑Client ❑Commercial n]P-a a []Other. WO 4 922283470 1111111111111111111111 922113470 Custody Seal on Cooler/Box Present? ❑�u'bhl, 60 Seals Intact? ❑Yes ❑No Packing Material: ❑B bble Wrap ❑ Bags [-]None ❑Other: y_ Ther Used: r YI5{)5 Type of Ice: 0 eW t ❑Blue ❑None Used: O-Sampies on ice, coolingprocess has begun Cooler Temp Corrected (°C): _ Biological Tissue Frozen? [:]Yes❑W-. ❑N/A Temp should be above freezing to 6°C Correction Factor: 0.0 °C Date and Initials of Person Examining. Contents: USDA Regulated Soil (❑ N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a,foreign source (internationally, ❑Yes ❑No including Hawaii and Puerto Ric(3)? []Yes ❑No If Yes to either question, fill out a Regulated Soil Checklist and include with SCUR/COC paperwork COMMENTS: Chain of Custody Present? ❑ es ❑No []N/A 1, Chain of Custody Filled Out? es ONo ❑N/A 2, Chain of Custody Relinquished? ®Yes No [I NIA 1 3. Sampler Name and/or Signature on COC? [;J1` s ❑No ❑N/A 4. Samples Arrived within Hold Time? es ❑No ❑N/A 5, Short Hold Time Analysis (<72 hr)? [:] es ❑No ❑N/A 6, Rush Turn Around Time Requested? []Yes o [:1N/A 7. Sufficient Volume? es (]No ❑N/A 8. Correct Containers Used? 13Yes ❑No �N/A 9. -Pace Containers Used? ❑Yes o ❑N/A Containers Intact? 0 es ON. ❑N/A 0. Filtered Volume Received for Dissolved Tests? ❑Yes ff No ❑pf A 11. Note if sediment is visible in the dissolved container Sample Labels Match COC? Yes [-]No ❑N/A 12. -Includes Date/Time/ID/Analysis Matrix: All containers needing acid/base preservation have been checked? Yes ❑No ❑N/A 13. All containers needing preservation are found to be in compliance with EPA recommendation? /� (HNO3i H2SO4, HCI<2, NaOH >9 Sulfide, NaOH>12 Cyanide) ❑Yes ❑No ❑N/A Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC,LLHg ❑Yes ❑No N/A Samples checked for dechlorization ❑Yes ❑No /A 14. Headspace in VDA Vials (>5-6mm)? ❑Yes ❑No ❑ / 15. Trip Blank Present? ❑Yes ❑No ©/,4 16. Trip Blank Custody Seals Present? []Yes❑No ❑ /A Pace Trip Blank Lot # (if purchased): CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Date/Time- Field Data -Required? ❑Yes ❑No Project Manager SCURF Review: Ot Date: I[rq /jP Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers), Page 38 of 39 C)i I-- i Uzi Wi :3 T CY LL, o 13 J}!E iJ7 Q i.3 btu a!� c 'Q I Q:i pi U i Wi `a, j 1 Q L)i LLi O L.. Ol GD'' U ` N Saaul@lu00 # lelol i) 'o b o. O, o. b . o, m.- o.. ro, 'o. o >• C�� N '-i o a'�� s paAlosSlp l I O a o a w h 4 I o a MOlaq aas) slezaw - I — ��m p # 5 o w $ W)edA) r - ° S0 ui i N x IAJO LD UO oc _.- -._._._._; i 1 o P l I (43Uaua013 A) to w i 11 ,ten a eplllnS Z N � - N 6 `QE@uQga@ale - IL i 3 i 'A11ull@Mltl m i i = a 01IJ4IN 01121llN '`J(il w g ! C Q 'E B o w lOS'19 a b 3 _ E w W rn hl@@45 A (9L� )Igv) @urR1a1N N I j (a N E.f t l I`y r, N N r N r _ SalS 'Sl r r 1% U a 9@aJ X•rs. ..j/, f %'� f /' �` f J yam' t •dwop m y J i U LL r.. CL E o412 _ � �� o � � � � � %` •-.,7` In =7 ^y F, vl I� ' ( ) rM ......... LL i n 1 p H Ri J LL ti c-``` i R. uu E 6 R I N22 � J u ro o E l C e U E lq ? I � a _ C ap'idw Z>n^r. t Page 73 of 74 ' D J N E( 0.I¢ H � U cF C> punoieuanp paalsop ale:)lpul aseeld :iueuodury UuwojsnO s 7- E \\ a 1 E r,t a l CC Im � 1 R Y ~ D y w N c U 4. a O E EL �I h � �- ��:` •'� 8 z cai « `S 4 U N � mu.N m 0. Q �¢� ,. •^ G E t.7 N tom.. '• ) hhD Lu W > xx 0 S `\\y`• w m� m T ujWO 9 i F t 6 0: 0 2 H u Page 39 of 39f1 i CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM ------------ - - ------------- --------- - - - - - - - - - - - - - - - - - - - - A�h2kml Lmbwwt-3ry Use Only Paqq - ------------ ErWTW Annityfit,01 110111;;�illkl�c;� i iorftr* PC— Page I � 74 of 74 Synterra EDD iFtSVOY mm C�4. 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