NC0000396_J16070325 report_20160831

DUKE Analytical Laboratory Page 1 of 75
" EIERGY.
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J16070325
ASHEVILLE - AB GW ASSESSMENT WATER
Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
200 CP and L Drive
Arden,NC 28704
Anne
/Pridgeon
q / aa:oa haft,
zo 1 6 08.091839:6) N'00'
Anne Pridgeon
Phone: [phone]
Date:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
8/2/2016
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory OC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Page 2 of 75
Sample ID Plant/Station
2016021445
2016021446
2016021447
2016021448
2016021449
2016021450
6 Total Samples
Collection
Date and Time Collected By
Sample Description
ASHEVILLE
12-Jul-16 10:30 AM
illegible
MW-18BRL
ASHEVILLE
12-Jul-16 9:05 AM
illegible
MW-17A
ASHEVILLE
12-Jul-16 2:04 PM
illegible
CB-9BR
ASHEVILLE
12-Jul-16 2:04 PM
illegible
CB-9BR Dup
ASHEVILLE
12-Jul-16 1:50 PM
illegible
Filter Blank
ASHEVILLE
12-Jul-16 1:50 PM
illegible
Equipment Blank

Page 3 of 75
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals E Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable. &.11 Yes ❑ No
Report Sections Included:
V Job Summary Report
U Sample Identification
n Technical Validation of Data Package
0 Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
IJ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
Electronic Data Deliverable (EDD) Sent Separatel
Reviewed By: DBA Account Date: 8/2/2016

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6070325
Site: MW-18BRL
Collection Date: 12-Jul-16 10:30 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.012 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
9.4
mg/L
1
Sulfate
260
mg/L
5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (Al)
0.007
mg/L
0.005
Barium (Ba)
0.021
mg/L
0.005
Boron (B)
0.081
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.407
mg/L
0.005
Strontium (Sr)
0.354
mg/L
0.005
Zinc (Zn)
0.010
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
93.2
mg/L
0.01
Magnesium (Mg)
6.26
mg/L
0.005
Potassium (K)
7.92
mg/L
0.1
Sodium (Na)
26.9
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
0.053
mg/L
0.005
Barium (Ba)
0.029
mg/L
0.005
Boron (B)
0.077
mg/L
0.05
Iron (Fe)
0.016
mg/L
0.01
Manganese (Mn)
0.387
mg/L
0.005
Strontium (Sr)
0.350
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016021445
Matrix: GW WW
Page 4 of 75
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 07/18/2016 13:33 LSTARLI
Vendor Method V_PACE
10
EPA 300.0
07/14/2016 21:50
BGN9034
50
EPA 300.0
07/14/2016 21:50
BGN9034
1
EPA 245.1
07/21/2016 13:51
DMFRANC
1
EPA 245.1
07/18/2016 15:49
DMFRANC
1
EPA 200.7
07/14/2016 13:40
JJMACKE
1
EPA 200.7
07/14/2016 13:40
JJMACKE
1
EPA 200.7
07/14/2016 13:40
JJMACKE
1
EPA 200.7
07/14/2016 13:40
JJMACKE
1
EPA 200.7
07/14/2016 13:40
JJMACKE
1
EPA 200.7
07/14/2016 13:40
JJMACKE
1
EPA 200.7
07/14/2016 13:40
JJMACKE
1
EPA 200.7
07/19/2016 13:32
JJMACKE
1
EPA 200.7
07/19/2016 13:32
JJMACKE
1
EPA 200.7
07/19/2016 13:32
JJMACKE
1
EPA 200.7
07/19/2016 13:32
JJMACKE
1
EPA 200.7
07/23/2016 12:32
JJMACKE
1
EPA 200.7
07/23/2016 12:32
JJMACKE
1
EPA 200.7
07/23/2016 12:32
JJMACKE
1
EPA 200.7
07/23/2016 12:32
JJMACKE
1
EPA 200.7
07/23/2016 12:32
JJMACKE
1
EPA 200.7
07/23/2016 12:32
JJMACKE
1
EPA 200.7
07/23/2016 12:32
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6070325
Site: MW-18BRL
Collection Date: 12-Jul-16 10:30 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
1.21
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
6.97
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
4.25
ug/L
Nickel (Ni)
1.82
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
1.84
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
Arsenic (As)
1.20
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
4.17
Nickel (Ni)
1.50
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
1.74
Page 5 of 75
Sample #:
2016021445
Matrix:
GW WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
0.2
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
0.3
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
ug/L
0.2
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
ug/L
0.3
1
EPA 200.8
07/15/2016 04:20
CWSPEN3
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
RADIOLOGICAL - (Analvsis Performed by GEL)
Vendor Parameter Complete
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS 460 mg/L
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
50 1 SM2540C 07/18/201614:26 PARMSTR

Certificate of Laboratory Analysis Page 6 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Site: MW-18BRL
Sample #:
2016021445
Collection Date: 12-Jul-16
10:30 AM
Matrix:
GW WW
Analyte
Result
Units Qualifiers RDL DF Method
Analysis Date/Time Analyst
Total Carbon
TOC
4.0
mg/L 0.1 1 SM5310C/EPA9060A 07/15/201614:37 CJELLIO
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L 5 1 SM2540D
07/18/2016 09:55 PARMSTR

Certificate of Laboratory Analysis Page 7 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Site: MW-17A
Collection Date: 12-Jul-16 9:05 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.016 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
430
mg/L
10
Sulfate
190
mg/L
5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
Calcium (Ca)
208
mg/L
0.1
Magnesium (Mg)
63.3
mg/L
0.05
Potassium (K)
4.53
mg/L
0.1
Sodium (Na)
14.8
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
0.119
mg/L
0.005
Barium (Ba)
0.127
mg/L
0.005
Boron (B)
2.47
mg/L
0.05
Iron (Fe)
35.5
mg/L
0.01
Manganese (Mn)
5.04
mg/L
0.005
Strontium (Sr)
0.648
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016021446
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 07/18/2016 13:34 LSTARLI
Vendor Method V_PACE
100
EPA 300.0
07/14/2016 23:02
BGN9034
50
EPA 300.0
07/14/2016 23:02
BGN9034
1
EPA 245.1
07/21/2016 13:54
DMFRANC
10
EPA 200.7
07/19/2016 13:36
JJMACKE
10
EPA 200.7
07/19/2016 13:36
JJMACKE
1
EPA 200.7
07/19/2016 13:36
JJMACKE
1
EPA 200.7
07/19/2016 13:36
JJMACKE
1
EPA 200.7
07/23/2016 13:04
JJMACKE
1
EPA 200.7
07/23/2016 13:04
JJMACKE
1
EPA 200.7
07/23/2016 13:04
JJMACKE
1
EPA 200.7
07/23/2016 13:04
JJMACKE
1
EPA 200.7
07/23/2016 13:04
JJMACKE
1
EPA 200.7
07/23/2016 13:04
JJMACKE
1
EPA 200.7
07/23/2016 13:04
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6070325
Site: MW-17A
Collection Date: 12-Jul-16 9:05 AM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
1.26
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
17.0
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
3.61
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
RADIOLOGICAL - (Analvsis Performed by GEL
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
1300
mg/L
Total Carbon
TOC
1.6
mg/L
TOTAL SUSPENDED SOLIDS
TSS
7.8
mg/L
Page 8 of 75
Sample #:
2016021446
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
07/15/2016 12:28
CWSPEN3
EPA 200.8
07/15/2016 12:28
CWSPEN3
EPA 200.8
07/15/2016 12:28
CWSPEN3
EPA 200.8
07/15/2016 12:28
CWSPEN3
EPA 200.8
07/15/2016 12:28
CWSPEN3
EPA 200.8
07/15/2016 12:28
CWSPEN3
EPA 200.8
07/15/2016 12:28
CWSPEN3
EPA 200.8
07/15/2016 12:28
CWSPEN3
EPA 200.8
07/15/2016 12:28
CWSPEN3
EPA 200.8
07/15/2016 12:28
CWSPEN3
EPA 200.8
07/15/2016 12:28
CWSPEN3
EPA 200.8
07/15/2016 12:28
CWSPEN3
EPA 200.8
07/15/2016 12:28
CWSPEN3
Vendor Method v_GEL
Vendor Method V_PACE
25 1 SM2540C 07/18/201614:26 PARMSTR
0.1 1 SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO
5 1 SM2540D 07/18/2016 09:55 PARMSTR

Certificate of Laboratory Analysis Page 9 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Site: CB-913R
Collection Date: 12-Jul-16 2:04 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.131 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
6.4
mg/L
0.1
Sulfate
1.3
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (Al)
< 0.005
mg/L
0.005
Barium (Ba)
0.023
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.039
mg/L
0.005
Strontium (Sr)
0.064
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
9.24
mg/L
0.01
Magnesium (Mg)
3.08
mg/L
0.005
Potassium (K)
2.31
mg/L
0.1
Sodium (Na)
4.27
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
0.107
mg/L
0.005
Barium (Ba)
0.025
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.236
mg/L
0.01
Manganese (Mn)
0.043
mg/L
0.005
Strontium (Sr)
0.065
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016021447
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 07/18/2016 13:35 LSTARLI
Vendor Method V_PACE
1 EPA 300.0
07/14/2016 23:25
BGN9034
1 EPA 300.0
07/14/2016 23:25
BGN9034
1 EPA 245.1
07/21/2016 13:56
DMFRANC
1 EPA 245.1
07/18/2016 15:58
DMFRANC
1 EPA 200.7
07/14/2016 13:44
JJMACKE
1 EPA 200.7
07/14/2016 13:44
JJMACKE
1 EPA 200.7
07/14/2016 13:44
JJMACKE
1 EPA 200.7
07/14/2016 13:44
JJMACKE
1 EPA 200.7
07/14/2016 13:44
JJMACKE
1 EPA 200.7
07/14/2016 13:44
JJMACKE
1 EPA 200.7
07/14/2016 13:44
JJMACKE
1 EPA 200.7
07/19/2016 13:39
JJMACKE
1 EPA 200.7
07/19/2016 13:39
JJMACKE
1 EPA 200.7
07/19/2016 13:39
JJMACKE
1 EPA 200.7
07/19/2016 13:39
JJMACKE
1 EPA 200.7
07/23/2016 13:08
JJMACKE
1 EPA 200.7
07/23/2016 13:08
JJMACKE
1 EPA 200.7
07/23/2016 13:08
JJMACKE
1 EPA 200.7
07/23/2016 13:08
JJMACKE
1 EPA 200.7
07/23/2016 13:08
JJMACKE
1 EPA 200.7
07/23/2016 13:08
JJMACKE
1 EPA 200.7
07/23/2016 13:08
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6070325
Site: CB-913R
Collection Date: 12-Jul-16 2:04 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
1.50
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
1.69
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
0.318
Page 10 of 75
Sample #:
2016021447
Matrix:
GW WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
0.2
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
0.3
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
ug/L
0.2
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
ug/L
0.3
1
EPA 200.8
07/15/2016 04:26
CWSPEN3
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
RADIOLOGICAL - (Analvsis Performed by GEL)
Vendor Parameter Complete
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS 67 mg/L
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
25 1 SM2540C 07/18/201614:26 PARMSTR

Certificate of Laboratory Analysis Page 11 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Site: CB-9BR Sample #: 2016021447
Collection Date: 12-Jul-16 2:04 PM Matrix: GW WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
Total Carbon
TOC 0.238 mg/L 0.1 1 SM5310C/EPA9060A 07/15/201614:37 CJELLIO
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 07/18/2016 09:55 PARMSTR

Certificate of Laboratory Analysis Page 12 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Site: CB-9BR Dup
Collection Date: 12-Jul-16 2:04 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.131 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
6.4
mg/L
0.1
Sulfate
1.3
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (Al)
< 0.005
mg/L
0.005
Barium (Ba)
0.023
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.040
mg/L
0.005
Strontium (Sr)
0.064
mg/L
0.005
Zinc (Zn)
0.012
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
8.70
mg/L
0.01
Magnesium (Mg)
2.99
mg/L
0.005
Potassium (K)
2.34
mg/L
0.1
Sodium (Na)
3.47
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
0.096
mg/L
0.005
Barium (Ba)
0.025
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.214
mg/L
0.01
Manganese (Mn)
0.042
mg/L
0.005
Strontium (Sr)
0.065
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016021448
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 07/18/2016 13:41 LSTARLI
Vendor Method V_PACE
1 EPA 300.0
07/14/2016 23:41
BGN9034
1 EPA 300.0
07/14/2016 23:41
BGN9034
1 EPA 245.1
07/21/2016 14:30
DMFRANC
1 EPA 245.1
07/18/2016 16:01
DMFRANC
1 EPA 200.7
07/14/2016 14:01
JJMACKE
1 EPA 200.7
07/14/2016 14:01
JJMACKE
1 EPA 200.7
07/14/2016 14:01
JJMACKE
1 EPA 200.7
07/14/2016 14:01
JJMACKE
1 EPA 200.7
07/14/2016 14:01
JJMACKE
1 EPA 200.7
07/14/2016 14:01
JJMACKE
1 EPA 200.7
07/14/2016 14:01
JJMACKE
1 EPA 200.7
07/19/2016 13:43
JJMACKE
1 EPA 200.7
07/19/2016 13:43
JJMACKE
1 EPA 200.7
07/19/2016 13:43
JJMACKE
1 EPA 200.7
07/19/2016 13:43
JJMACKE
1 EPA 200.7
07/23/2016 13:12
JJMACKE
1 EPA 200.7
07/23/2016 13:12
JJMACKE
1 EPA 200.7
07/23/2016 13:12
JJMACKE
1 EPA 200.7
07/23/2016 13:12
JJMACKE
1 EPA 200.7
07/23/2016 13:12
JJMACKE
1 EPA 200.7
07/23/2016 13:12
JJMACKE
1 EPA 200.7
07/23/2016 13:12
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6070325
Site: CB-9BR Dup
Collection Date: 12-Jul-16 2:04 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
8.07
ug/L
Lead (Pb)
1.11
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
1.85
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
1.85
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
Page 13 of 75
Sample #:
2016021448
Matrix:
GW WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
0.2
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
0.3
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
ug/L
1
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
ug/L
0.2
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
ug/L
0.3
1
EPA 200.8
07/15/2016 04:33
CWSPEN3
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
RADIOLOGICAL - (Analvsis Performed by GEL)
Vendor Parameter Complete
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS 83 mg/L
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
25 1 SM2540C 07/18/201614:26 PARMSTR

Certificate of Laboratory Analysis Page 14 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Site: CB-9BR Dup Sample #: 2016021448
Collection Date: 12-Jul-16 2:04 PM Matrix: GW WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
Total Carbon
TOC 0.221 mg/L 0.1 1 SM5310C/EPA9060A 07/15/201614:37 CJELLIO
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 07/18/2016 09:55 PARMSTR

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6070325
Site: Filter Blank
Collection Date: 12-Jul-16
1:50 PM
Analyte
Result
Units Qualifiers
RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (Al)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
2.81
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2016021449
Matrix: GW WW
Page 15 of 75
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
07/18/2016 16:03
DMFRANC
1
EPA 200.7
07/14/2016 14:12
JJMACKE
1
EPA 200.7
07/14/2016 14:12
JJMACKE
1
EPA 200.7
07/14/2016 14:12
JJMACKE
1
EPA 200.7
07/14/2016 14:12
JJMACKE
1
EPA 200.7
07/14/2016 14:12
JJMACKE
1
EPA 200.7
07/14/2016 14:12
JJMACKE
1
EPA 200.7
07/14/2016 14:12
JJMACKE
1
EPA 200.8
07/14/2016 21:24
CWSPEN3
1
EPA 200.8
07/14/2016 21:24
CWSPEN3
1
EPA 200.8
07/14/2016 21:24
CWSPEN3
1
EPA 200.8
07/14/2016 21:24
CWSPEN3
1
EPA 200.8
07/14/2016 21:24
CWSPEN3
1
EPA 200.8
07/14/2016 21:24
CWSPEN3
1
EPA 200.8
07/14/2016 21:24
CWSPEN3
1
EPA 200.8
07/14/2016 21:24
CWSPEN3
1
EPA 200.8
07/14/2016 21:24
CWSPEN3
1
EPA 200.8
07/14/2016 21:24
CWSPEN3
1
EPA 200.8
07/14/2016 21:24
CWSPEN3
1
EPA 200.8
07/14/2016 21:24
CWSPEN3
1
EPA 200.8
07/14/2016 21:24
CWSPEN3

Certificate of Laboratory Analysis Page 16 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Site: Equipment Blank
Collection Date: 12-Jul-16 1:50 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
0.40
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
Calcium (Ca)
< 0.01
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2016021450
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2
07/18/2016 13:45
LSTARLI
1 EPA 300.0
07/26/2016 12:38
BGN9034
1 EPA 300.0
07/26/2016 12:38
BGN9034
1 EPA 245.1
07/21/2016 14:32
DMFRANC
1 EPA 200.7
07/19/2016 13:49
JJMACKE
1 EPA 200.7
07/19/2016 13:49
JJMACKE
1 EPA 200.7
07/19/2016 13:49
JJMACKE
1 EPA 200.7
07/19/2016 13:49
JJMACKE
1 EPA 200.7
07/23/2016 13:15
JJMACKE
1 EPA 200.7
07/23/2016 13:15
JJMACKE
1 EPA 200.7
07/23/2016 13:15
JJMACKE
1 EPA 200.7
07/23/2016 13:15
JJMACKE
1 EPA 200.7
07/23/2016 13:15
JJMACKE
1 EPA 200.7
07/23/2016 13:15
JJMACKE
1 EPA 200.7
07/23/2016 13:15
JJMACKE
1 EPA 200.8
07/15/2016 04:39
CWSPEN3
1 EPA 200.8
07/15/2016 04:39
CWSPEN3
1 EPA 200.8
07/15/2016 04:39
CWSPEN3
1 EPA 200.8
07/15/2016 04:39
CWSPEN3
1 EPA 200.8
07/15/2016 04:39
CWSPEN3
1 EPA 200.8
07/15/2016 04:39
CWSPEN3
1 EPA 200.8
07/15/2016 04:39
CWSPEN3
1 EPA 200.8
07/15/2016 04:39
CWSPEN3
1 EPA 200.8
07/15/2016 04:39
CWSPEN3
1 EPA 200.8
07/15/2016 04:39
CWSPEN3
1 EPA 200.8
07/15/2016 04:39
CWSPEN3
1 EPA 200.8
07/15/2016 04:39
CWSPEN3
1 EPA 200.8
07/15/2016 04:39
CWSPEN3

Certificate of Laboratory Analysis Page 17 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Site: Equipment Blank
Sample #: 2016021450
Collection Date: 12-Jul-16 1:50 PM
Matrix: GW WW
Analyte
Result Units Qualifiers RDL
DF Method Analysis Date/Time
Analyst
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
Total Carbon
TOC
0.228 mg/L 0.1
1 SM5310C/EPA9060A 07/15/201614:37
CJELLIO
TOTAL SUSPENDED SOLIDS
TSS
< 5 mg/L 5
1 SM2540D 07/18/2016 09:55
PARMSTR

Certificate of Laboratory Analysis Page 18 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level II QC Summary
Q16070429 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Nitrite + Nitrate
-0.0016
-0.0016
mg-N/L
1
0.01
< 1/2 RDL
(Colorimetric)
Blank # 2
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Nitrite + Nitrate
-0.0007
-0.0007
mg-N/L
1
0.01
< 1/2 RDL
(Colorimetric)
Blank # 3
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Nitrite + Nitrate
0.0005
0.0005
mg-N/L
1
0.01
< 1/2 RDL
(Colorimetric)
Blank # 4
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Nitrite + Nitrate
0.0009
0.0009
mg-N/L
1
0.01
< 1/2 RDL
(Colorimetric)
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Nitrite + Nitrate
0.301
3.01
mg-N/L
10
3.01
99.9 90
110
(Colorimetric)
LCS # 2
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Nitrite + Nitrate
0.301
3.01
mg-N/L
10
3.01
99.9 90
110
(Colorimetric)
LCS # 3
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Nitrite + Nitrate
0.298
2.98
mg-N/L
10
3.01
99 90
110
(Colorimetric)
LCS # 4
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Nitrite + Nitrate
0.296
2.96
mg-N/L
10
3.01
98.2 90
110
(Colorimetric)
NIS # 1
Parent Sample:
J16060271
-- 2016016749
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Nitrite + Nitrate
0.253
0.253
mg-N/L
1
0.25
101 90
110
(Colorimetric)
MSD # 1
Parent Sample:
J16060271
-- 2016016749
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
RPD Qualifier
Nitrite + Nitrate
0.253
0.253
mg-N/L
1
0.25
101 90
110
0.278
(Colorimetric)

Certificate of Laboratory Analysis Page 19 of 75
This report shall not be reproduced, except in full.
Order # J16070325
Level II QC Summary
Q16070429 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
MS # 2
Parameter
Measured
Final
Nitrite + Nitrate
0.258
0.258
(Colorimetric)
MSD # 2
Parameter
Measured
Final
Nitrite + Nitrate
0.256
0.256
(Colorimetric)
MS # 3
Parameter
Measured
Final
Nitrite + Nitrate
0.364
0.364
(Colorimetric)
MSD # 3
Parameter
Measured
Final
Nitrite + Nitrate
0.366
0.366
(Colorimetric)
MS # 4
Parameter
Measured
Final
Nitrite + Nitrate
0.256
0.256
(Colorimetric)
MSD # 4
Parameter
Measured
Final
Nitrite + Nitrate
0.256
0.256
(Colorimetric)
Parent Sample: J16070367 -- 2016021651
Units: Dil Spike % Recovery LCL UCL Qualifier
mg-N/L 1 0.25 102 90 110
Parent Sample: J16070367 -- 2016021651
Units: Dil Spike % Recovery LCL UCL RPD Qualifier
mg-N/L 1 0.25 101 90 110 0.709
Parent Sample: J16070325 -- 2016021448
Units: Dil Spike % Recovery LCL UCL Qualifier
mg-N/L 1 0.25 93.4 90 110
Parent Sample: J16070325 -- 2016021448
Units: Dil 521ke % Recovery LCL UCL RPD Qualifier
mg-N/L 1 0.25 94.2 90 110 0.853
Parent Sample: J16070132 -- 2016021202
Units: Dil Spike % Recovery LCL UCL Qualifier
mg-N/L 1 0.25 101 90 110
Parent Sample: J16070132 -- 2016021202
Units: Dil Spike % Recovery LCL UCL RPD Qualifier
mg-N/L 1 0.25 101 90 110 0.0395

Certificate of Laboratory Analysis Page 20 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level II QC Summary
Q16070340 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Chloride
-0.0034
-0.0034
Sulfate
-0.0384
-0.0384
Spiked Sample # 1
Parameter
Measured
Final
Chloride
4.29
4.29
Sulfate
1.91
1.91
IS # 1
Parameter
Measured
Final
Chloride
9.09
9.09
Sulfate
6.71
6.71
ISD # 1
Parameter
Measured
Final
Chloride
9.1
9.1
Sulfate
6.71
6.71
LCS # 1
Parameter
Measured
Final
Chloride
5.25
5.25
Sulfate
5.23
5.23
Units:
Dil
RDL
Relative Concentration
Qualifier
mg/L
1
0.1
< 1/2 RDL
mg/L
1
0.1
< 1/2 RDL
Units:
Dil
Qualifier
mg/L
1
0.1
mg/L
1
0.1
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
5
96.1
80
120
mg/L
1
5
96.1
80
120
Units:
Dil
Sgike
% Recovery
LCL
UCL
RPD Qualifier
mg/L
1
5
96.3
80
120
0.179
mg/L
1
5
96.1
80
120
0.0166
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
5
105
80
120
mg/L
1
5
105
80
120

Certificate of Laboratory Analysis Page 21 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level II QC Summary
Q16070552 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Mercury (Hg)
0.021
0.021
Spiked Sample # 1
Parameter
Measured
Final
Mercury (Hg)
0.0922
1.84
Spiked Sample # 2
Parameter
Measured
Final
Mercury (Hg)
0.0171
0.343
IS # 1
Parameter Measured Final
Mercury (Hg) 0.953 19.1
ISD # 1
Parameter Measured Final
Mercury (Hg) 0.951 19
IS # 2
Parameter
Measured
Final
Mercury (Hg)
0.941
18.8
ISD # 2
Parameter
Measured
Final
Mercury (Hg)
0.949
19
LCS # 1
Parameter
Measured
Final
Mercury (Hg)
1.97
1.97
Units: Dil RDL Relative Concentration Qualifier
ug/L 1 0.05 < 1/2 RDL
Units: Dil Qualifier
ug/L 20 0.05
Units: Dil Qualifier
ug/L 20 0.05
Units: Dil Spike % Recovery LCL UCL Qualifier
ug/L 20 20 86 70 130
Units: Dil Spike % Recovery LCL UCL RPD Qualifier
ug/L 20 20 85.9 70 130 0.175
Units: Dil Spike % Recovery LCL UCL Qualifier
ug/L 20 20 92.4 70 130
Units: Dil Spike % Recovery LCL UCL RPD Qualifier
ug/L 20 20 93.1 70 130 0.809
Units: Dil Spike % Recovery LCL UCL Qualifier
ug/L 1 2 98.3 85 115

Certificate of Laboratory Analysis Page 22 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level II QC Summary
Q16070437 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Blank # 1
Parameter
Measured
Final
Mercury (Hg)
0.006
0.006
Spiked Sample # 1
Parameter
Measured
Final
Mercury (Hg)
0.012
0.012
ISD # 1
Parameter Measured Final
Mercury (Hg) 1.04 1.04
Parameter Measured Final
Mercury (Hg) 1.01 1.01
LCS # 1
Parameter Measured Final
Mercury (Hg) 2.02 2.02
Units:
Dil
RDL
Relative Concentration
Qualifier
ug/L
1
0.05
< 1/2 RDL
Units:
Dil
Qualifier
ug/L
1
0.05
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
ug/L
1
1
103
70
130
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD Qualifier
ug/L
1
1
100
70
130
2.47
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
ug/L
1
2
101
85
115

Certificate of Laboratory Analysis Page 23 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level II QC Summary
Q16070341 ICP Dissolved DISSOLVED METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Aluminum (Al)
0.000029
0.000029
mg/L
1
0.005
< 1/2 RDL
Barium (Ba)
0.00006
0.00006
mg/L
1
0.005
< 1/2 RDL
Boron (B)
0.000281
0.000281
mg/L
1
0.05
< 1/2 RDL
Iron (Fe)
-0.000508
-0.000508
mg/L
1
0.01
< 1/2 RDL
Manganese (Mn)
-0.000329
-0.000329
mg/L
1
0.005
< 1/2 RDL
Strontium (Sr)
0.000134
0.000134
mg/L
1
0.005
< 1/2 RDL
Zinc (Zn)
-0.000785
-0.000785
mg/L
1
0.005
< 1/2 RDL
Blank # 2
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Aluminum (Al)
-0.000007
-0.000007
mg/L
1
0.005
< 1/2 RDL
Barium (Ba)
0.000039
0,000039
mg/L
1
0.005
< 1/2 RDL
Boron (B)
0.00088
0.00088
mg/L
1
0.05
< 1/2 RDL
Iron (Fe)
-0.000931
-0.000931
mg/L
1
0.01
< 1/2 RDL
Manganese (Mn)
-0.000163
-0.000163
mg/L
1
0.005
< 1/2 RDL
Strontium (Sr)
0.000104
0.000104
mg/L
1
0.005
< 1/2 RDL
Zinc (Zn)
-0.000664
-0.000664
mg/L
1
0.005
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Aluminum (Al)
2.09
2.09
mg/L
1
2
105
85
115
Barium (Ba)
0.985
0.985
mg/L
1
1
98.5
85
115
Boron (B)
1.98
1.98
mg/L
1
2
99.2
85
115
Iron (Fe)
2.05
2.05
mg/L
1
2
103
85
115
Manganese (Mn)
0.982
0.982
mg/L
1
1
98.2
85
115
Strontium (Sr)
1.91
1.91
mg/L
1
2
95.5
85
115
Zinc (Zn)
1.03
1.03
mg/L
1
1
103
85
115
LCS # 2
Parameter
Measured
Final
Units:
Aluminum (Al)
2.1
2.1
mg/L
Barium (Ba)
0.991
0.991
mg/L
Boron (B)
2.01
2.01
mg/L
Iron (Fe)
2.05
2.05
mg/L
Manganese (Mn)
0.989
0.989
mg/L
Strontium (Sr)
1.92
1.92
mg/L
Zinc (Zn)
1.03
1.03
mg/L
MS # 1
Parameter Measured Final Units:
Aluminum (Al) 5.53 5.53 mg/L
Dil
Spike
% Recovery LCL
UCL Qualifier
1
2
105 85
115
1
1
99.1 85
115
1
2
100 85
115
1
2
103 85
115
1
1
98.9 85
115
1
2
96.2 85
115
1
1
103 85
115
Parent Sample:
J16070328 -- 2016021471
Dil
Spike
% Recovery LCL
UCL Qualifier
1
5
109 70
130

Certificate of Laboratory Analysis Page 24 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level II QC Summary
Q16070341 ICP Dissolved DISSOLVED METALS BY ICP
MS # 1
Parent Sample:
J16070328
-- 2016021471
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Barium (Ba)
5.26
5.26
mg/L
1
5
104 70
130
Boron (B)
10.7
10.7
mg/L
1
5
93.7 70
130
Iron (Fe)
5.3
5.3
mg/L
1
5
101 70
130
Manganese (Mn)
7.89
7.89
mg/L
1
5
96.8 70
130
Strontium (Sr)
7.3
7.3
mg/L
1
5
102 70
130
Zinc (Zn)
5.21
5.21
mg/L
1
5
104 70
130
MSD # 1
Parent Sample:
J16070328
-- 2016021471
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
RPD Qualifier
Aluminum (Al)
5.63
5.63
mg/L
1
5
111 70
130
1.83
Barium (Ba)
5.35
5.35
mg/L
1
5
105 70
130
1.65
Boron (B)
10.9
10.9
mg/L
1
5
97.5 70
130
4
Iron (Fe)
5.39
5.39
mg/L
1
5
103 70
130
1.86
Manganese (Mn)
8.03
8.03
mg/L
1
5
99.5 70
130
2.77
Strontium (Sr)
7.37
7.37
mg/L
1
5
104 70
130
1.32
Zinc (Zn)
5.29
5.29
mg/L
1
5
106 70
130
1.64
MS # 2
Parent Sample:
J16070300 -- 2016021339
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Aluminum (Al)
5.43
5.43
mg/L
1
5
108 70
130
Barium (Ba)
5.17
5.17
mg/L
1
5
103 70
130
Boron (B)
5.11
5.11
mg/L
1
5
102 70
130
Iron (Fe)
5.69
5.69
mg/L
1
5
99.5 70
130
Manganese (Mn)
5.57
5.57
mg/L
1
5
105 70
130
Strontium (Sr)
5.35
5.35
mg/L
1
5
99.9 70
130
Zinc (Zn)
5.13
5.13
mg/L
1
5
103 70
130
MSD # 2
Parent Sample:
J16070300 -- 2016021339
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
RPD Qualifier
Aluminum (Al)
5.52
5.52
mg/L
1
5
110 70
130
1.74
Barium (Ba)
5.27
5.27
mg/L
1
5
105 70
130
2.02
Boron (B)
5.22
5.22
mg/L
1
5
104 70
130
2.23
Iron (Fe)
5.81
5.81
mg/L
1
5
102 70
130
2.32
Manganese (Mn)
5.67
5.67
mg/L
1
5
107 70
130
1.98
Strontium (Sr)
5.43
5.43
mg/L
1
5
102 70
130
1.71
Zinc (Zn)
5.24
5.24
mg/L
1
5
105 70
130
2.04
MS # 3
Parent Sample:
J16070325
-- 2016021448
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Aluminum (Al)
5.52
5.52
mg/L
1
5
110 70
130
Barium (Ba)
5.23
5.23
mg/L
1
5
104 70
130

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6070325
Level II QC Summary
Q16070341 ICP Dissolved DISSOLVED METALS BY ICP
MS # 3
Parameter
Measured
Final
Units:
Dil
Spike
Boron (B)
5.09
5.09
mg/L
1
5
Iron (Fe)
5.09
5.09
mg/L
1
5
Manganese (Mn)
5.4
5.4
mg/L
1
5
Strontium (Sr)
5.08
5.08
mg/L
1
5
Zinc (Zn)
5.29
5.29
mg/L
1
5
MSD # 3
Parameter
Measured
Final
Units:
Dil
Spike
Aluminum (Al)
5.52
5.52
mg/L
1
5
Barium (Ba)
5.24
5.24
mg/L
1
5
Boron (B)
5.11
5.11
mg/L
1
5
Iron (Fe)
5.12
5.12
mg/L
1
5
Manganese (Mn)
5.42
5.42
mg/L
1
5
Strontium (Sr)
5.09
5.09
mg/L
1
5
Zinc (Zn)
5.31
5.31
mg/L
1
5
Page 25 of 75
Parent Sample: J16070325 -- 2016021448
% Recovery
LCL
UCL
Qualifier
102
70
130
102
70
130
107
70
130
100
70
130
106
70
130
Parent Sample:
J16070325 -- 2016021448
% Recovery
LCL
UCL
RPD Qualifier
110
70
130
0.0725
104
70
130
0.211
102
70
130
0.294
102
70
130
0.431
108
70
130
0.41
101
70
130
0.139
106
70
130
0.246

Certificate of Laboratory Analysis Page 26 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level II QC Summary
Q16070475 ICP Undigested UNDIGESTED METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Calcium (Ca)
0.00129
0.00129
mg/L
1
0.01
< 1/2 RDL
Magnesium (Mg)
0.000115
0.000115
mg/L
1
0.005
< 1/2 RDL
Potassium (K)
-0.00152
-0.00152
mg/L
1
0.1
< 1/2 RDL
Sodium (Na)
-0.00992
-0.00992
mg/L
1
0.05
< 1/2 RDL
Blank # 2
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Calcium (Ca)
0.00148
0.00148
mg/L
1
0.01
< 1/2 RDL
Magnesium (Mg)
0.000217
0.000217
mg/L
1
0.005
< 1/2 RDL
Potassium (K)
0.00492
0.00492
mg/L
1
0.1
< 1/2 RDL
Sodium (Na)
-0.0117
-0.0117
mg/L
1
0.05
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Calcium (Ca)
2.04
2.04
mg/L
1
2
102
85
115
Magnesium (Mg)
1.99
1.99
mg/L
1
2
99.3
85
115
Potassium (K)
3.98
3.98
mg/L
1
4
99.6
85
115
Sodium (Na)
8.38
8.38
mg/L
1
8.1
103
85
115
LCS # 2
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Calcium (Ca)
2.14
2.14
mg/L
1
2
107
85
115
Magnesium (Mg)
2.08
2.08
mg/L
1
2
104
85
115
Potassium (K)
4.21
4.21
mg/L
1
4
105
85
115
Sodium (Na)
8.85
8.85
mg/L
1
8.1
109
85
115
MS # 1
Parent Sample:
J16070328
-- 2016021471
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Calcium (Ca)
104
104
mg/L
1
5
0
70
130
Magnesium (Mg)
21.2
21.2
mg/L
1
5
88.2
70
130
Potassium (K)
15.9
15.9
mg/L
1
5
93.2
70
130
Sodium (Na)
38.3
38.3
mg/L
1
5
106
70
130
MSD # 1
Parent Sample:
J16070328
-- 2016021471
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD Qualifier
Calcium (Ca)
104
104
mg/L
1
5
204
70
130
200
Magnesium (Mg)
21.1
21.1
mg/L
1
5
88
70
130
0.25
Potassium (K)
16
16
mg/L
1
5
94
70
130
0.876
Sodium (Na)
38.3
38.3
mg/L
1
5
107
70
130
0.981

Certificate of Laboratory Analysis Page 27 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level I1 QC Summary
Q16070475 ICP Undigested UNDIGESTED METALS BY ICP
MS # 2
Parent Sample:
J16070300
-- 2016021340
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Calcium (Ca)
19.1
19.1
mg/L
1
5
93.9 70
130
Magnesium (Mg)
7.69
7.69
mg/L
1
5
104 70
130
Potassium (K)
10.1
10.1
mg/L
1
5
98.1 70
130
Sodium (Na)
51.5
51.5
mg/L
1
5
71.7 70
130
MSD # 2
Parent Sample:
J16070300
-- 2016021340
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
RPD Qualifier
Calcium (Ca)
19.3
19.3
mg/L
1
5
97.7 70
130
3.97
Magnesium (Mg)
7.78
7.78
mg/L
1
5
105 70
130
1.66
Potassium (K)
10.2
10.2
mg/L
1
5
101 70
130
3.07
Sodium (Na)
52.1
52.1
mg/L
1
5
83.3 70
130
14.9
MS # 3
Parent Sample:
J16070378
-- 2016021704
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Calcium (Ca)
25.9
25.9
mg/L
1
5
102 70
130
Magnesium (Mg)
7.35
7.35
mg/L
1
5
113 70
130
Potassium (K)
12.9
12.9
mg/L
1
5
102 70
130
Sodium (Na)
22.6
22.6
mg/L
1
5
107 70
130
MSD # 3
Parent Sample:
J16070378
-- 2016021704
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
RPD Qualifier
Calcium (Ca)
26
26
mg/L
1
5
104 70
130
1.61
Magnesium (Mg)
7.39
7.39
mg/L
1
5
114 70
130
0.671
Potassium (K)
13
13
mg/L
1
5
104 70
130
1.83
Sodium (Na)
22.8
22.8
mg/L
1
5
110 70
130
2.73
MS # 4
Parent Sample:
J16070399
-- 2016021854
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Calcium (Ca)
65.4
65.4
mg/L
1
5
83.2 70
130
Magnesium (Mg)
18.6
18.6
mg/L
1
5
95.7 70
130
Potassium (K)
11
11
mg/L
1
5
110 70
130
Sodium (Na)
25.6
25.6
mg/L
1
5
103 70
130
MSD # 4
Parent Sample:
J16070399
-- 2016021854
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
RPD Qualifier
Calcium (Ca)
65.8
65.8
mg/L
1
5
91 70
130
8.91
Magnesium (Mg)
18.6
18.6
mg/L
1
5
96.6 70
130
1.02
Potassium (K)
11
11
mg/L
1
5
110 70
130
0.4
Sodium (Na)
25.7
25.7
mg/L
1
5
105 70
130
1.9

Certificate of Laboratory Analysis Page 28 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level II QC Summary
Q16070518 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Aluminum (Al)
0.00109
0.00109
mg/L
1
0.005
< 1/2 RDL
Barium (Ba)
0.000186
0.000186
mg/L
1
0.005
< 1/2 RDL
Boron (B)
-0.000474
-0.000474
mg/L
1
0.05
< 1/2 RDL
Iron (Fe)
0.000233
0.000233
mg/L
1
0.01
< 1/2 RDL
Manganese (Mn)
-0.000141
-0.000141
mg/L
1
0.005
< 1/2 RDL
Strontium (Sr)
0.000099
0.000099
mg/L
1
0.005
< 1/2 RDL
Zinc (Zn)
0.000136
0.000136
mg/L
1
0.005
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Aluminum (Al)
5.47
5.47
mg/L
Barium (Ba)
4.99
4.99
mg/L
Boron (B)
4.98
4.98
mg/L
Iron (Fe)
4.93
4.93
mg/L
Manganese (Mn)
5.16
5.16
mg/L
Strontium (Sr)
4.94
4.94
mg/L
Zinc (Zn)
5.03
5.03
mg/L
MS # 1
Parameter
Measured
Final
Units:
Aluminum (Al)
5.4
5.4
mg/L
Barium (Ba)
5
5
mg/L
Boron (B)
5.08
5.08
mg/L
Iron (Fe)
4.91
4.91
mg/L
Manganese (Mn)
5.46
5.46
mg/L
Strontium (Sr)
5.25
5.25
mg/L
Zinc (Zn)
4.86
4.86
mg/L
MSD # 1
Parameter
Measured
Final
Units:
Aluminum (Al)
5.49
5.49
mg/L
Barium (Ba)
5.08
5.08
mg/L
Boron (B)
5.18
5.18
mg/L
Iron (Fe)
4.98
4.98
mg/L
Manganese (Mn)
5.54
5.54
mg/L
Strontium (Sr)
5.33
5.33
mg/L
Zinc (Zn)
4.91
4.91
mg/L
Dil
Spike
% Recovery LCL
UCL
Qualifier
1
5
109 85
115
1
5
99.7 85
115
1
5
99.6 85
115
1
5
98.6 85
115
1
5
103 85
115
1
5
98.8 85
115
1
5
101 85
115
Parent Sample:
J16070325
-- 2016021445
DiI
Spike
% Recovery LCL
UCL
Qualifier
1
5
107 70
130
1
5
99.5 70
130
1
5
100 70
130
1
5
97.8 70
130
1
5
101 70
130
1
5
98.1 70
130
1
5
97.1 70
130
Parent Sample:
J16070325
-- 2016021445
DiI
Spike
% Recovery LCL
UCL
RPD Qualifier
1
5
109 70
130
1.65
1
5
101 70
130
1.59
1
5
102 70
130
1.96
1
5
99.2 70
130
1.42
1
5
103 70
130
1.49
1
5
99.6 70
130
1.54
1
5
98.2 70
130
1.09

Certificate of Laboratory Analysis Page 29 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level II QC Summary
Q16070304 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Antimony (Sb)
-0.091
-0.091
ug/L
1
1
< 1/2 RDL
Arsenic (As)
0.0151
0.0151
ug/L
1
1
< 1/2 RDL
Beryllium (Be)
0.0675
0.0675
ug/L
1
1
< 1/2 RDL
Cadmium (Cd)
0.0121
0.0121
ug/L
1
1
< 1/2 RDL
Chromium (Cr)
-0.0814
-0.0814
ug/L
1
1
< 1/2 RDL
Cobalt (Co)
0.0099
0.0099
ug/L
1
1
< 1/2 RDL
Copper (Cu)
-0.11
-0.11
ug/L
1
1
< 1/2 RDL
Lead (Pb)
0.0068
0.0068
ug/L
1
1
< 1/2 RDL
Molybdenum (Mo)
0.0034
0.0034
ug/L
1
1
< 1/2 RDL
Nickel (Ni)
-0.0029
-0.0029
ug/L
1
1
< 1/2 RDL
Selenium (Se)
-0.081
-0.081
ug/L
1
1
< 1/2 RDL
Thallium (TI) Low Level
-0.0346
-0.0346
ug/L
1
0.2
< 1/2 RDL
Vanadium (V) Low Level
0.0426
0.0426
ug/L
1
0.3
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
52.3
52.3
ug/L
1
50
105
85
115
Arsenic (As)
51.1
51.1
ug/L
1
50
102
85
115
Beryllium (Be)
50
50
ug/L
1
50
100
85
115
Cadmium (Cd)
51.4
51.4
ug/L
1
50
103
85
115
Chromium (Cr)
51.8
51.8
ug/L
1
50
104
85
115
Cobalt (Co)
50.7
50.7
ug/L
1
50
101
85
115
Copper (Cu)
50.7
50.7
ug/L
1
50
101
85
115
Lead (Pb)
52
52
ug/L
1
50
104
85
115
Molybdenum (Mo)
51.7
51.7
ug/L
1
50
103
85
115
Nickel (Ni)
51.4
51.4
ug/L
1
50
103
85
115
Selenium (Se)
49.1
49.1
ug/L
1
50
98.1
85
115
Thallium (TI) Low Level
49.6
49.6
ug/L
1
50
99.1
85
115
MS # 1
Parent Sample:
J16070300 -- 2016021339
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
51.8
51.8
ug/L
1
50
103
70
130
Arsenic (As)
50.6
50.6
ug/L
1
50
101
70
130
Beryllium (Be)
55.5
55.5
ug/L
1
50
111
70
130
Cadmium (Cd)
50
50
ug/L
1
50
100
70
130
Chromium (Cr)
51.6
51.6
ug/L
1
50
102
70
130
Cobalt (Co)
49.8
49.8
ug/L
1
50
96.7
70
130
Copper (Cu)
48.9
48.9
ug/L
1
50
97.5
70
130
Lead (Pb)
50.8
50.8
ug/L
1
50
101
70
130
Molybdenum (Mo)
54.2
54.2
ug/L
1
50
102
70
130

Certificate of Laboratory Analysis Page 30 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level I1 QC Summary
Q16070304 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
MS # 1
Parent Sample:
J16070300
-- 2016021339
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Nickel (Ni)
53.3
53.3
ug/L
1
50
97.7
70
130
Selenium (Se)
48.2
48.2
ug/L
1
50
96.5
70
130
Thallium (TI) Low Level
48.4
48.4
ug/L
1
50
96.8
70
130
MSD # 1
Parent Sample:
J16070300
-- 2016021339
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD Qualifier
Antimony (Sb)
52.5
52.5
ug/L
1
50
104
70
130
1.42
Arsenic (As)
51.2
51.2
ug/L
1
50
102
70
130
1.23
Beryllium (Be)
54.1
54.1
ug/L
1
50
108
70
130
2.64
Cadmium (Cd)
50.8
50.8
ug/L
1
50
102
70
130
1.66
Chromium (Cr)
52
52
ug/L
1
50
103
70
130
0.773
Cobalt (Co)
50.4
50.4
ug/L
1
50
98
70
130
1.33
Copper (Cu)
49.4
49.4
ug/L
1
50
98.5
70
130
1.04
Lead (Pb)
51.1
51.1
ug/L
1
50
102
70
130
0.572
Molybdenum (Mo)
54.4
54.4
ug/L
1
50
102
70
130
0.412
Nickel (Ni)
54.5
54.5
ug/L
1
50
100
70
130
2.42
Selenium (Se)
48.8
48.8
ug/L
1
50
97.8
70
130
1.3
Thallium (TI) Low Level
49.5
49.5
ug/L
1
50
99
70
130
2.25

Certificate of Laboratory Analysis Page 31 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level I1 QC Summary
Q16070315 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Antimony (Sb)
-0.0234
-0.0234
ug/L
1
1
< 1/2 RDL
Arsenic (As)
0.0143
0.0143
ug/L
1
1
< 1/2 RDL
Beryllium (Be)
0.0062
0.0062
ug/L
1
1
< 1/2 RDL
Cadmium (Cd)
0.0007
0.0007
ug/L
1
1
< 1/2 RDL
Chromium (Cr)
-0.0808
-0.0808
ug/L
1
1
< 1/2 RDL
Cobalt (Co)
0.0068
0.0068
ug/L
1
1
< 1/2 RDL
Copper (Cu)
-0.141
-0.141
ug/L
1
1
< 1/2 RDL
Lead (Pb)
0.0024
0.0024
ug/L
1
1
< 1/2 RDL
Molybdenum (Mo)
0.0014
0.0014
ug/L
1
1
< 1/2 RDL
Nickel (Ni)
-0.0172
-0.0172
ug/L
1
1
< 1/2 RDL
Selenium (Se)
-0.0861
-0.0861
ug/L
1
1
< 1/2 RDL
Thallium (TI) Low Level
-0.0237
-0.0237
ug/L
1
0.2
< 1/2 RDL
Vanadium (V) Low Level
0.0239
0.0239
ug/L
1
0.3
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
50.4
50.4
ug/L
1
50
101
85
115
Arsenic (As)
48.3
48.3
ug/L
1
50
96.7
85
115
Beryllium (Be)
53.9
53.9
ug/L
1
50
108
85
115
Cadmium (Cd)
49.7
49.7
ug/L
1
50
99.4
85
115
Chromium (Cr)
51
51
ug/L
1
50
102
85
115
Cobalt (Co)
48.2
48.2
ug/L
1
50
96.4
85
115
Copper (Cu)
48.6
48.6
ug/L
1
50
97.2
85
115
Lead (Pb)
50.3
50.3
ug/L
1
50
101
85
115
Molybdenum (Mo)
49.8
49.8
ug/L
1
50
99.7
85
115
Nickel (Ni)
48.3
48.3
ug/L
1
50
96.5
85
115
Selenium (Se)
47.1
47.1
ug/L
1
50
94.2
85
115
Thallium (TI) Low Level
49.6
49.6
ug/L
1
50
99.1
85
115
Vanadium (V) Low Level
50.5
50.5
ug/L
1
50
101
85
115
MS #1
Parent Sample:
J16070325 -- 2016021446
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
51.5
51.5
ug/L
1
50
103
70
130
Arsenic (As)
50.9
50.9
ug/L
1
50
99.2
70
130
Beryllium (Be)
50.3
50.3
ug/L
1
50
100
70
130
Cadmium (Cd)
48.7
48.7
ug/L
1
50
97.3
70
130
Chromium (Cr)
50
50
ug/L
1
50
99.4
70
130
Cobalt (Co)
63.1
63.1
ug/L
1
50
92.3
70
130
Copper (Cu)
46.8
46.8
ug/L
1
50
93.3
70
130
Lead (Pb)
50.1
50.1
ug/L
1
50
100
70
130

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6070325
Level II QC Summary
Q16070315 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units:
Dil
Spike
Molybdenum (Mo)
50.1
50.1
ug/L
1
50
Nickel (Ni)
51.5
51.5
ug/L
1
50
Selenium (Se)
48
48
ug/L
1
50
Thallium (TI) Low Level
44.8
44.8
ug/L
1
50
Vanadium (V) Low Level
50.7
50.7
ug/L
1
50
MSD # 1
Parameter
Measured
Final
Units:
Dil
Spike
Antimony (Sb)
51.5
51.5
ug/L
1
50
Arsenic (As)
51.1
51.1
ug/L
1
50
Beryllium (Be)
49.6
49.6
ug/L
1
50
Cadmium (Cd)
49.4
49.4
ug/L
1
50
Chromium (Cr)
51.2
51.2
ug/L
1
50
Cobalt (Co)
63.8
63.8
ug/L
1
50
Copper (Cu)
47.3
47.3
ug/L
1
50
Lead (Pb)
50.3
50.3
ug/L
1
50
Molybdenum (Mo)
50.9
50.9
ug/L
1
50
Nickel (Ni)
50.8
50.8
ug/L
1
50
Selenium (Se)
48.2
48.2
ug/L
1
50
Thallium (TI) Low Level
46.9
46.9
ug/L
1
50
Vanadium (V) Low Level
51.7
51.7
ug/L
1
50
Page 32 of 75
Parent Sample: J16070325 -- 2016021446
% Recovery
LCL
UCL Qualifier
99.9
70
130
95.7
70
130
96
70
130
89.6
70
130
101
70
130
Parent Sample: J16070325 -- 2016021446
% Recovery
LCL
UCL
RPD Qualifier
103
70
130
0.118
99.6
70
130
0.412
98.6
70
130
1.55
98.8
70
130
1.49
102
70
130
2.41
93.7
70
130
1.48
94.4
70
130
1.15
100
70
130
0.456
102
70
130
1.68
94.5
70
130
1.33
96.4
70
130
0.383
93.9
70
130
4.66
103
70
130
1.99

Certificate of Laboratory Analysis Page 33 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level II QC Summary
Q16070415 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Parameter Measured
TDS
Duplicate # 1
Parameter Measured
TDS
Duplicate # 2
Parameter Measured
TDS
LCS # 1
Parameter Measured
TDS
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
-1
mg/L
1
25
< 1/2 RDL
Parent Sample:
J16070325
-- 2016021447
Final
Units:
Dil
RPD Qualifier
70
mg/L
1
4.38
Parent Sample:
J16070325
-- 2016021448
Final
Units:
Dil
RPD Qualifier
79
mg/L
1
4.94
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
102
mg/L
1
100
102 90
110

Certificate of Laboratory Analysis Page 34 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level II QC Summary
Q16070294 Total Carbon Total Carbon
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
TOC
0.025
mg/L
1
0.1
< 1/2 RDL
Blank # 2
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
TOC
0.049
mg/L
1
0.1
< 1/2 RDL
Spiked Sample # 1
Parameter
Measured
Final
Units:
Dil
Qualifier
TOC
1.75
mg/L
1
0.1
Spiked Sample # 2
Parameter
Measured
Final
Units:
Dil
Qualifier
TOC
0.281
mg/L
1
0.1
Spiked Sample # 3
Parameter
Measured
Final
Units:
Dil
Qualifier
TOC
0.84
mg/L
1
0.1
Spiked Sample # 4
Parameter
Measured
Final
Units:
Dil
Qualifier
TOC
1.43
mg/L
1
0.1
IS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
TOC
3.68
mg/L
1
2
96.6
80
120
ISD # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD
Qualifier
TOC
3.82
mg/L
1
2
103
80
120
6.85
IS # 2
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
TOC
2.39
mg/L
1
2
105
80
120
ISD # 2
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD
Qualifier
TOC
2.33
mg/L
1
2
103
80
120
2.69
IS # 3
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
TOC
2.82
mg/L
1
2
98.8
80
120
ISD # 3
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD
Qualifier
TOC
2.9
mg/L
1
2
103
80
120
4.31

Certificate of Laboratory Analysis Page 35 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level II QC Summary
Q16070294 Total Carbon Total Carbon
IS # 4
ISD # 4
LCS # 1
LCS # 2
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
TOC
3.46
mg/L
1
2
102
80
120
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD Qualifier
TOC
3.41
mg/L
1
2
99.3
80
120
2.29
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
TOC
2.92
mg/L
1
2.87
102
85
115
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
TOC
2.93
mg/L
1
2.87
102
85
115

Certificate of Laboratory Analysis Page 36 of 75
This report shall not be reproduced, except in full.
Order # A 6070325
Level II QC Summary
Q16070396 TSS TOTAL SUSPENDED SOLIDS
Blank # 1
Parameter Measured
TSS
Duplicate # 1
Parameter Measured
TSS
Duplicate # 2
Parameter Measured
TSS
LCS # 1
Parameter Measured
TSS
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
0
mg/L
1
5
< 1/2 RDL
Parent Sample:
J16060373
-- 2016017127
Final
Units:
Dil
RPD Qualifier
2
mg/L
1
10.5
Parent Sample:
J16060373
-- 2016017128
Final
Units:
Dil
RPD Qualifier
0
mg/L
1
0
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
51.2
mg/L
1
50
102 90
110

® Laboratories LLC
ge 37 of 75 17
a member of The GEL Group IN'.
July 29, 2016
Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078
Re: AB GW Assessment Water
Work Order: 401638
SDG: J16070325
Dear Mary:
P4 Box 30712 Charleston. SC 29417
2040 Sange Road Chad eston.SC29407
P 843 556.8171
F 843.76Gi.1178
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on July 14, 2016. This original data report has been prepared and reviewed in accordance
with GEL's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.
Sincerely,
Chelsea Seagle for
Lindsay Fabra
Project Manager
Purchase Order: 1250944
Enclosures
gel.com

Page 38 of 75
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
for
DUP0002 Duke Energy
Client SDG: J16070325 GEL Work Order: 401638
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the 'U' qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
Reviewed by
Page 2 of 15

GEL LABORATORIES LLC Page 39 of 75
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016021445
401638001
Water
12-JUL-16 10:30
14-JUL-16
Client
Report Date: July 29, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Uranium Liquid "As Received"
Uranium-238 0.0241
0.000067
0.0002
ug/mL
1.00
1
SKJ 07/28/16
0936 1581994 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1.00
1
SKJ 07/29/16
0940 1581994 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1.00
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1.00
1
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 3.13
0.818
1.00
pCi/L
AXM6 07/28/16
1534 1582445 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 3.39
0.474
1.00
pCi/L
LXPI 07/27/16
1005 1583317 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time
Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
SXWl
07/15/16
0642
1581993
The following Analytical Methods were performed:
Method Description Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 63.3 (15%-125%)
Notes:
Column headers are defined as follows:
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 3 of 15

GEL LABORATORIES LLC Page 40 of 75
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016021446
401638002
Water
12-JUL-16 09:05
14-JUL-16
Client
Report Date: July 29, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Uranium Liquid "As Received"
Uranium-238 U ND
0.000067
0.0002
ug/mL
1.00 1 SKJ 07/28/16
0938 1581994
Uranium-233 U ND
0.00001
0.00005
ug/mL
1.00 1 SKJ 07/29/16
0941 1581994
Uranium-234 U ND
0.00001
0.00005
ug/mL
1.00 1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1.00 1
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 U ND
0.996
1.00
pCi/L
AXM6 07/28/16
1534 1582445
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 1.96
0.471
1.00
pCi/L
LXPI 07/27/16
1005 1583317
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
sxwt
07/15/16
0642 1581993
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test
Result
Nominal Recovery%
Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"
54.8
(15%-125%)
Notes:
Column headers are defined as follows:
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
1
2
tj
4
Page 4 of 15

GEL LABORATORIES LLC Page41 of75
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016021447
401638003
Water
12-JUL-16 14:04
14-JUL-16
Client
Report Date: July 29, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Uranium Liquid "As Received"
Uranium-238 U ND
0.000067
0.0002
ug/mL
1.00
1
SKJ 07/28/16
0939 1581994 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1.00
1
SKJ 07/29/16
0943 1581994 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1.00
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1.00
1
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 U ND
0.592
1.00
pCi/L
AXM6 07/28/16
1534 1582445 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 2.60
0.560
1.00
pCi/L
LXPI 07/27/16
1005 1583317 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time
Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
SXWl
07/15/16
0642
1581993
The following Analytical Methods were performed:
Method Description Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 96 (15%-125%)
Notes:
Column headers are defined as follows:
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 5 of 15

GEL LABORATORIES LLC Page 42 of 75
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016021448
401638004
Water
12-JUL-16 14:04
14-JUL-16
Client
Report Date: July 29, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units PF DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Uranium Liquid "As Received"
Uranium-238 U ND
0.000067
0.0002
ug/mL
1.00
1
SKJ 07/28/16
0941 1581994 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1.00
1
SKJ 07/29/16
0944 1581994 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1.00
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1.00
1
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 U ND
0.633
1.00
pCi/L
AXM6 07/28/16
1534 1582445 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 1.21
0.405
1.00
pCi/L
LXPI 07/27/16
1035 1583317 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time
Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
SXWl
07/15/16
0642
1581993
The following Analytical Methods were performed:
Method Description Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 88.9 (15%-125%)
Notes:
Column headers are defined as follows:
DF: Dilution Factor Lc/LC: Critical Level
DL: Detection Limit PF: Prep Factor
MDA: Minimum Detectable Activity RL: Reporting Limit
MDC: Minimum Detectable Concentration SQL: Sample Quantitation Limit
Page 6of15

Page 43 of 75
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina
Contact: Mary Ann Ogle
Workorder: 401638
Report Date: July 29, 2016
Page 1 of 3
Parmname
NOM
Sample
Qual
QC
Units
RPD%o
REC%
Range Anlst
Date Time
Metals Analysis - ICPMS
Batch 1581994
QC1203585489
401636001 DUP
Uranium-233
U
ND
U
ND
ug/mL
N/A
SKJ
07/29/16 09:21
Uranium-234
U
ND
U
ND
ug/mL
N/A
Uranium-236
U
ND
U
ND
ug/mL
N/A
Uranium-238
J
0.000158
J
0.000177
ug/mL
10.9 ^
(+/-0.0002)
07/28/16 09:20
QC1203585487
LCS
Uranium-238
0.0496
0.0535
ug/mL
108
(80%-120%)
07/28/16 09:05
QC1203585488
LCS
Uranium-233
0.0005
0.00055
ug/mL
110
(80%-120%)
07/29/16 08:20
Uranium-234
0.00055
0.000545
ug/mL
99.1
(80%-120%)
Uranium-236
0.005
0.00518
ug/mL
104
(80%-120%)
QC1203585486
MB
Uranium-233
U
ND
ug/mL
07/29/16 08:18
Uranium-234
U
ND
ug/mL
Uranium-236
U
ND
ug/mL
Uranium-238
U
ND
ug/mL
07/28/16 09:04
QC1203585490
401636001 MS
Uranium-238
0.0496
J
0.000158
0.0526
ug/mL
106
(75%-125%)
07/28/16 09:22
QC1203585491
401636001 MS
Uranium-233
0.0005
U
ND
0.000536
ug/mL
107
(75%-125%)
07/29/16 09:23
Uranium-234
0.00055
U
ND
0.000547
ug/mL
99.5
(75%-125%)
Uranium-236
0.005
U
ND
0.00533
ug/mL
107
(75%-125%)
QC1203585492
401636001 SDILT
Uranium-233
U
ND
U
ND
ug/L
N/A
07/29/16 09:24
Page 7 of 15

Page 44 of 75
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 401638
Page 2 of 3
Parmname
NOM
Sample
Qual
QC
Units
RPD%
REC%
Range Anlst
Date Time
Metals Analysis - ICPMS
Batch 1581994
Uranium-234
U
ND
U
ND
ug/L
N/A
Uranium-236
U
ND
U
ND
ug/L
N/A
(0%-10%) SKJ
07/29/16 09:24
Uranium-238
J
0.158
U
ND
ug/L
N/A
(0%-10%)
07/28/16 09:23
Rad Gas Flow
Batch 1582445
QC1203586579 401638004 DUP
Radium-228
U
0.111
U
0.148
pCi/L
N/A
N/AAXM6
07/28/1615:34
QC1203586580 LCS
Radium-228
15.0
11.7
pCi/L
78.3
(75%-125%)
07/28/1615:34
QC1203586578 MB
Radium-228
U
0.0413
pCi/L
07/28/1615:34
Rad Ra-226
Batch 1583317
QC1203588597 401821001 DUP
Radium-226
0.719
0.957
pCi/L
28.4
(0%- 100%) LXP1
07/27/16 11:20
QC1203588599 LCS
Radium-226
24.4
24.9
pCi/L
102
(75%-125%)
07/27/1611:55
QC1203588596 MB
Radium-226
U
0.387
pCi/L
07/27/1610:35
QC1203588598 401821001 MS
Radium-226
122
0.719
113
DCi/L
92.4
(75%-125%)
07/27/1611:20
Notes:
The Qualifiers in this report are defined as follows:
** Analyte is a Tracer compound
< Result is less than value reported
> Result is greater than value reported
BD Results are either below the MDC or tracer recovery is low
E %difference of sample and SD is >10%. Sample concentration must meet flagging criteria
FA Failed analysis.
FB Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
H Analytical holding time was exceeded
Page 8 of 15

Page 45 of 75
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 401638
Parmname NOM Sample Qual QC Units RPD%o REC'%
Page 3 of 3
Range Anlst Date Time
J Value is estimated
K Analyte present. Reported value may be biased high. Actual value is expected to be lower.
L Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M M if above MDC and less than LLD
M REMP Result > MDC/CL and < RDL
N Metals --The Matrix spike sample recovery is not within specified control limits
N/A RPD or %Recovery limits do not apply.
N1 See case narrative
ND Analyte concentration is not detected above the detection limit
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
R Sample results are rejected
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
UI Gamma Spectroscopy --Uncertain identification
UJ Gamma Spectroscopy --Uncertain identification
UL Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Y Other specific qualifiers were required to properly define the results. Consult case narrative.
^ RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
h Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
Page 9 of 15

W
Page 46 of 75
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Page 10 of 15
I N

Page 47 of 75
Laboratories PLC A M DT V DTi rVYPT Rs RV..VTF.W FORM
Client: D U SDG/AR/COC/Work
Order:
lJ j U
Received By: Q,
o -If
Date Received: 4--
Net Counts > 100cpm on samples not marked "radioactive", contact the Radiation Safety Group for further
Suspected Hazard Information p. Z investigation.
COC/Samples marked as radioactive?
Maximum Net Counts Observed* (Observed Counts - Area Background Counts):
Classified Radioactive II or III by RSO?
If
yes, Were swipes taken of sample containers < action levels?
COC/Samples marked containing PCBs?
/
^.`
Package COC; and/or Samples marked as
If
":
sainples;are to be segregated as Safety Controlled Satriples; and opened by Uiee GEL Safety Group.' _'
beryllium orasbestos coatizining?
Yes,
UN#:
Shipped as a DOT Hazardous?
/
Hazard Class Shipped:
Samples identified as Foreign Soil?
/
Z Comments/Qualifiers (Required for Non -Conforming Items)
Sample Receipt Criteria,
z
Shipping containers received intact and
Circle Applicable: Seals broken Damaged container Leaking container Other (describe)
1
sealed?
2
Samples requiring cold preservation
/
/
Pre: ervatian Method: ce a S. Blue ice Dry ice None Other (describe)
*ail temperatures are r rded in Celsius Vc—
within (0 < 6 deg. C)?*
Daily check performed and passed on IR
Device Serial It:
Temperature Device Serial # (If Applicable):2a
temperature
gun?3Chain
of custody documents included
JV)c
,
with shipment?icable:
Seals broken Damaged container Leaking container Other (describe)
4
Sample containers intact and sealed?
Samples requiring chemical preservation
Sample ID's, containers affected and observed pH:
a
at proper pH?
reservation add9d IAM
Do Low Level Perchlorate samples have
/
l
Sample ID's and containers affected:
6
headspace as required?
VOA vials contain acid preservation?
/
(If unknown, select No)
7
VOA vials free of headspace (defined as
Sample ID's and containers affected:
8
< 6mm bubble)?
(If yes, immediately deliver to Volatiles laboratory)
9
Are Encore containers present?
/
ID's and tests affected:
10
Samples received within holding time?
Sample ID's on COC match ID's on
Sample ID's and containers affected:
11
bottles?
Date &time on COC match date & time
Sample ID's affected:
12
on bottles?
Number of containers received match
Sample ID's affected:
13
number indicated on COC?
Are sample containers identifiable as
14
GELprovided?
COC form is properly signed in
15
relinquished/received stations?
Circle Applicable:
FedEx Air FedEx Ground UPS Field Services C.uriet Other
16
Carrier and tracking number.
Comments (Use Continuation Form if needed):
PM (or PMA) review: Initials -•1 ; 1 T— Date I I 1 "i I t Page _ I of —I_
GL-CHt_-SR-001 Rev 3
Page 11 of 15

Page 48 of 75
Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16070325
Work Order #: 401638
Metals
Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1581994
Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1581993
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
Client Sample Identification
401638001
2016021445
401638002
2016021446
401638003
2016021447
401638004
2016021448
1203585486
Method Blank (MB)ICP-MS
1203585487
Laboratory Control Sample (LCS)
1203585488
Laboratory Control Sample (LCS)
1203585492
401636001(2016021471L) Serial Dilution (SD)
1203585489
401636001(2016021471D) Sample Duplicate (DUP)
1203585490
401636001(2016021471S) Matrix Spike (MS)
1203585491
401636001(2016021471S) Matrix Spike (MS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.
Radiochemistry
Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1582445
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID# Client Sample Identification
401638001 2016021445
Page 12 of 15

Page 49 of 75
401638002 2016021446
401638003 2016021447
401638004 2016021448
1203586578 Method Blank (MB)
1203586579 401638004(2016021448) Sample Duplicate (DUP)
1203586580 Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summarv:
There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.
Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1583317
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID# Client Sample Identification
401638001 2016021445
401638002 2016021446
401638003 2016021447
401638004 2016021448
1203588596 Method Blank (MB)
1203588597 401821001(NonSDG) Sample Duplicate (DUP)
1203588598 401821001(NonSDG) Matrix Spike (MS)
1203588599 Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summarv•
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Miscellaneous information
Additional Comments
The matrix spike, 1203588598 (Non SDG 401821001MS), aliquot was reduced to conserve sample volume.
Page 13 of 15

Page 50 of 75
Certification Statement
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 14 of 15

Page 51 of 75
List of current GEL Certifications as of 29 July 2016
State
Certification
Alaska
UST-0110
Arkansas
88-0651
CLIA
42D0904046
California
2940
Colorado
SC00012
Connecticut
PH-0169
Delaware
SC00012
DoD ELAP/ ISO17025 A2LA
2567.01
Florida NELAP
E87156
Foreign Soils Permit
P330-15-00283, P330-15-00253
Georgia
SC00012
Georgia SDWA
967
Hawaii
SC00012
Idaho Chemistry
SC00012
Idaho Radiochemistry
SC00012
Illinois NELAP
200029
Indiana
C—SC-01
Kansas NELAP
E-10332
Kentucky SDWA
90129
Kentucky Wastewater
90129
Louisiana NELAP
03046 (A133904)
Louisiana SDWA
LA160006
Maryland
270
Massachusetts
M—SC012
Michigan
9976
Mississippi
SC00012
Nebraska
NE—OS-26-13
Nevada
SC000122016-1
New Hampshire NELAP
205415
New Jersey NELAP
SC002
New Mexico
SC00012
New York NELAP
11501
North Carolina
233
North Carolina SDWA
45709
North Dakota
R-158
Oklahoma
9904
Pennsylvania NELAP
68-00485
S.Carolina Radchem
10120002
South Carolina Chemistry
10120001
Tennessee
TN 02934
Texas NELAP
T104704235-16-11
Utah NELAP
SC000122016-20
Vermont
VT87156
Virginia NELAP
460202
Washington
C780
West Virginia
997404
Page 15 of 15

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, INC 28078
[phone]
July 21, 2016
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 16070325
Pace Project No.: 92304968
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on July 13, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 1 of 23

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Project: J16070325
Pace Project No.: 92304968
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification M 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification M E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification M 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE SUMMARY
Project: J16070325
Pace Project No.: 92304968
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92304968001
2016021445
Water
07/12/1610:30
07/13/1612:15
92304968002
2016021446
Water
07/12/16 09:05
07/13/16 12:15
92304968003
2016021447
Water
07/12/1614:04
07/13/1612:15
92304968004
2016021448
Water
07/12/1614:04
07/13/1612:15
92304968005
2016021450
Water
07/12/1613:50
07/13/1612:15
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16070325
92304968
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92304968001
2016021445
RSK 175 Modified
ZDO
1
PASI-C
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
AEM
1
PASI-O
92304968002
2016021446
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
AEM
1
PASI-O
92304968003
2016021447
RSK 175 Modified
ZDO
1
PASI-C
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
AEM
1
PASI-O
92304968004
2016021448
RSK 175 Modified
ZDO
1
PASI-C
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
AEM
1
PASI-O
92304968005
2016021450
RSK 175 Modified
ZDO
1
PASI-C
SM 2320B
KDF
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
REPORT OF LABORATORY ANALYSIS
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SUMMARY OF DETECTION
Project: J16070325
Pace Project No.: 92304968
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
92304968001
2016021445
RSK 175 Modified
Methane
81.5
ug/L
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
69.9
mg/L
SM 2320B
Alkalinity, Total as CaCO3
69.9
mg/L
92304968002
2016021446
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
13.9
mg/L
SM 2320B
Alkalinity, Total as CaCO3
13.9
mg/L
92304968003
2016021447
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
41.6
mg/L
SM 2320B
Alkalinity, Total as CaCO3
41.6
mg/L
EPA 218.7
Chromium, Hexavalent
0.14
ug/L
92304968004
2016021448
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
35.9
mg/L
SM 2320B
Alkalinity, Total as CaCO3
35.9
mg/L
EPA 218.7
Chromium, Hexavalent
0.13
ug/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Report Limit Analyzed Qualifiers
10.0 07/20/1617:33
5.0 07/16/16 22:23
5.0 07/16/16 22:23
5.0 07/16/16 22:34
5.0 07/16/16 22:34
5.0 07/16/16 23:04
5.0 07/16/16 23:04
0.030 07/18/16 21:07
5.0 07/16/16 23:16
5.0 07/16/16 23:16
0.030 07/18/16 21:20
Page 5 of 23

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PROJECT NARRATIVE
Project: J16070325
Pace Project No.: 92304968
Method: RSK 175 Modified
Description: RSK 175 Headspace
Client: Duke Energy
Date: July 21, 2016
General Information:
4 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 321519
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304098010
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1783837)
• Methane
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16070325
Pace Project No.: 92304968
Method: SM 2320B
Description: 2320E Alkalinity
Client: Duke Energy
Date: July 21, 2016
General Information:
5 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16070325
Pace Project No.: 92304968
Method: SM 4500-S213
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: July 21, 2016
General Information:
5 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 321606
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304968001,92304968002
M3: Matrix spike recovery was outside laboratory control limits due to matrix interferences.
• MS (Lab ID: 1782276)
• Sulfide
• MSD (Lab ID: 1782277)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16070325
Pace Project No.: 92304968
Method: EPA 218.7
Description: Hexavalent Chromium by IC
Client: Duke Energy
Date: July 21, 2016
General Information:
4 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 309440
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304976001,92304981001
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1640510)
• Chromium, Hexavalent
• MSD (Lab ID: 1640511)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16070325
Pace Project No.: 92304968
Sample: 2016021445
Lab ID: 92304968001 Collected:
07/12/16 10:30
Received: 07/13/16 12:15 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Methane
81.5 ug/L
10.0
1
07/20/1617:33
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
69.9 mg/L
5.0
1
07/16/16 22:23
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
07/16/16 22:23
Alkalinity, Total as CaCO3
69.9 mg/L
5.0
1
07/16/16 22:23
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
07/18/16 21:20
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
07/18/16 20:41
18540-29-9
Date: 07/21 /2016 04:56 PM
REPORT OF LABORATORY ANALYSIS
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Page 10 of 23

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ANALYTICAL RESULTS
Project: J16070325
Pace Project No.: 92304968
Sample: 2016021446
Lab ID: 92304968002 Collected:
07/12/16 09:05
Received: 07/13/16 12:15 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed CAS No. Qual
2320E Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
13.9 mg/L
5.0
1
07/16/16 22:34
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
07/16/16 22:34
Alkalinity, Total as CaCO3
13.9 mg/L
5.0
1
07/16/16 22:34
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
07/18/16 21:20 18496-25-8 M3
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
07/18/16 20:54 18540-29-9
Date: 07/21 /2016 04:56 PM
REPORT OF LABORATORY ANALYSIS
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Page 11 of 23

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ANALYTICAL RESULTS
Project: J16070325
Pace Project No.: 92304968
Sample: 2016021447
Lab ID: 92304968003 Collected:
07/12/16 14:04
Received: 07/13/16 12:15 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Methane
ND ug/L
10.0
1
07/20/1617:48
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
41.6 mg/L
5.0
1
07/16/16 23:04
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
07/16/16 23:04
Alkalinity, Total as CaCO3
41.6 mg/L
5.0
1
07/16/16 23:04
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
07/18/16 21:20
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.14 ug/L
0.030
1
07/18/16 21:07
18540-29-9
Date: 07/21 /2016 04:56 PM
REPORT OF LABORATORY ANALYSIS
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Page 12 of 23

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ANALYTICAL RESULTS
Project: J16070325
Pace Project No.: 92304968
Sample: 2016021448
Lab ID: 92304968004 Collected:
07/12/16 14:04
Received: 07/13/16 12:15 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Methane
ND ug/L
10.0
1
07/20/1618:03
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
35.9 mg/L
5.0
1
07/16/16 23:16
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
07/16/16 23:16
Alkalinity, Total as CaCO3
35.9 mg/L
5.0
1
07/16/16 23:16
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
07/18/16 21:20
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.13 ug/L
0.030
1
07/18/16 21:20
18540-29-9
Date: 07/21 /2016 04:56 PM
REPORT OF LABORATORY ANALYSIS
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Page 13 of 23

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ANALYTICAL RESULTS
Project: J16070325
Pace Project No.: 92304968
Sample: 2016021450
Lab ID: 92304968005 Collected:
07/12/16 13:50
Received: 07/13/16 12:15 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Methane
ND ug/L
10.0
1
07/20/1618:18 74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
07/17/16 12:50
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
07/17/16 12:50
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
07/17/16 12:50
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
07/18/16 21:20 18496-25-8
Date: 07/21 /2016 04:56 PM
REPORT OF LABORATORY ANALYSIS
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Page 14 of 23

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QUALITY CONTROL DATA
Project: J16070325
Pace Project No.: 92304968
QC Batch: 321519
Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified
Analysis Description: RSK
175 HEADSPACE
Associated Lab Samples: 92304968001, 92304968003, 92304968004, 92304968005
METHOD BLANK: 1781804
Matrix: Water
Associated Lab Samples: 92304968001, 92304968003, 92304968004, 92304968005
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Methane
ug/L
ND 10.0
07/20/1614:48 N2
LABORATORY CONTROL SAMPLE:
1781805
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Methane
ug/L
396 454
115 70-130 N2
MATRIX SPIKE SAMPLE:
1783837
92304098010 Spike
MS MS % Rec
Parameter
Units
Result Conc.
Result % Rec Limits Qualifiers
Methane
ug/L
10100 396
10700 143 70-130 H5,M1,N2
SAMPLE DUPLICATE: 1783838
92304098012 Dup
Max
Parameter
Units
Result Result
RPD RPD Qualifiers
Methane
ug/L
8380 7530
11 20 H5,N2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 07/21 /2016 04:56 PM without the written consent of Pace Analytical Services, Inc.. Page 15 of 23

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QUALITY CONTROL DATA
Project: J16070325
Pace Project No.: 92304968
QC Batch: 321462 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92304968001, 92304968002, 92304968003, 92304968004
METHOD BLANK: 1781600
Matrix: Water
Associated Lab Samples: 92304968001, 92304968002, 92304968003, 92304968004
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Alkalinity, Carbonate (CaCO3)
mg/L
ND 5.0
07/16/16 16:55
Alkalinity, Total as CaCO3
mg/L
ND 5.0
07/16/16 16:55
Alkalinity, Bicarbonate (CaCO3)
mg/L
ND 5.0
07/16/16 16:55
LABORATORY CONTROL SAMPLE: 1781601
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 52.8 106 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1781602 1781603
MS MSD
92304866003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 1 AJ 50 50 49.4 48.4 96 94 80-120 2 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1781604 1781605
MS MSD
92304966005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Alkalinity, Total as CaCO3 mg/L 238 50 50 279 288 82 100 80-120 3 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 07/21 /2016 04:56 PM without the written consent of Pace Analytical Services, Inc..
Page 16 of 23

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QUALITY CONTROL DATA
Project: J16070325
Pace Project No.: 92304968
QC Batch: 321477 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92304968005
METHOD BLANK: 1781655
Associated Lab Samples: 92304968005
Parameter Units
Alkalinity, Carbonate (CaCO3) mg/L
Alkalinity, Total as CaCO3 mg/L
Alkalinity, Bicarbonate (CaCO3) mg/L
LABORATORY CONTROL SAMPLE: 1781656
Parameter Units
Alkalinity, Total as CaCO3 mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 5.0 07/17/1612:29
ND 5.0 07/17/1612:29
ND 5.0 07/17/1612:29
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
50 52.5 105 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1781657 1781658
MS MSD
92304968005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L ND 50 50 49.5 49.2 99 98 80-120 1 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1781659 1781660
MS MSD
92304981007 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Alkalinity, Total as CaCO3 mg/L ND 50 50 49.7 49.1 99 98 80-120 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/21 /2016 04:56 PM without the written consent of Pace Analytical Services, Inc..
Page 17 of 23

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinyfte. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16070325
Pace Project No.: 92304968
QC Batch: 321606 Analysis Method: SM 4500-S2D
QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92304968001, 92304968002, 92304968003, 92304968004, 92304968005
METHOD BLANK: 1782272 Matrix: Water
Associated Lab Samples: 92304968001, 92304968002, 92304968003, 92304968004, 92304968005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 07/18/16 21:20
LABORATORY CONTROL SAMPLE: 1782273
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.50 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1782274 1782275
MS MSD
92304968001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.49 0.49 97 97 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1782276 1782277
MS MSD
92304968002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.22 0.22 26 26 90-110 0 10 M3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/21 /2016 04:56 PM without the written consent of Pace Analytical Services, Inc..
Page 18 of 23

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16070325
Pace Project No.: 92304968
QC Batch: 309440 Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC
Associated Lab Samples: 92304968001, 92304968002, 92304968003, 92304968004
METHOD BLANK: 1640506 Matrix: Water
Associated Lab Samples: 92304968001, 92304968002, 92304968003, 92304968004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chromium, Hexavalent ug/L ND 0.030 07/18/16 18:31
LABORATORY CONTROL SAMPLE: 1640507
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chromium, Hexavalent ug/L .075 0.072 96 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1640508 1640509
MS MSD
92304981001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND .075 .075 0.079 0.075 106 100 85-115 5 20
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1640510 1640511
MS MSD
92304976001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L 6.1 1 1 7.6 7.7 147 158 85-115 1 20 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/21 /2016 04:56 PM without the written consent of Pace Analytical Services, Inc..
Page 19 of 23

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onvfte. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J16070325
Pace Project No.: 92304968
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
H5 Reanalysis conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M3 Matrix spike recovery was outside laboratory control limits due to matrix interferences.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold TN accreditation for this parameter.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/21 /2016 04:56 PM without the written consent of Pace Analytical Services, Inc.. Page 20 of 23

acmnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
og6g I qc&f fte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16070325
Pace Project No.: 92304968
Lab ID Sample ID QC Batch Method QC Batch
92304968001
2016021445
RSK 175 Modified
321519
92304968003
2016021447
RSK 175 Modified
321519
92304968004
2016021448
RSK 175 Modified
321519
92304968005
2016021450
RSK 175 Modified
321519
92304968001
2016021445
SM 2320B
321462
92304968002
2016021446
SM 2320B
321462
92304968003
2016021447
SM 2320B
321462
92304968004
2016021448
SM 2320B
321462
92304968005
2016021450
SM 2320B
321477
92304968001
2016021445
SM 4500-S2D
321606
92304968002
2016021446
SM 4500-S2D
321606
92304968003
2016021447
SM 4500-S2D
321606
92304968004
2016021448
SM 4500-S2D
321606
92304968005
2016021450
SM 4500-S2D
321606
92304968001
2016021445
EPA 218.7
309440
92304968002
2016021446
EPA 218.7
309440
92304968003
2016021447
EPA 218.7
309440
92304968004
2016021448
EPA 218.7
309440
Date: 07/21/2016 04:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 21 of 23

Document Name:
Document Revised:April 25, 2016
/7aceAnalytfcaf
Sample Condition Upon Recept(SCUR)
Page 1
Document No.:
Issuing Authority:
F-CHR-CS-003-rev.19
Pace Huntersville Quality Office
Sample Condition 11'pon Client Name:
Receipt
Proje
Courier: ❑Fed Ex ❑UPS ❑LISPS ❑Client
❑ Commercial ❑pace ❑Other:
Custody Seal Present? []Yes [ NOu Seals Intact? QY6__ [-]No
WO#:92304966
IIIIIIuJ!luumuuu
PackingMaterial: Bubble Wrap Bubble Bags Date/Initlals Person Examining Contents: _ (
❑ p ❑ g []None _ ❑0ther:
Thermometer: T1505 Type of Ice: Dot ❑Blue ❑None OSamples on ice, cooling process has begun
Correction Factor: 0.0°C Cooler Temp Corrected (°C): _ +�. [', Biological Tissue Frozen? ❑Yes ❑No ❑ A
Temp should be above freezing to VC
USDA Regulated Soil { [L-]-N/A, water sample)
Did samples on hate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (intern, +ovally,
❑Yes QN? indudina Hawaii and Puerto Rico]? FlYes ifNn
Comments/Discrepancy:
Chain of Custody Present?
ElYes
❑No
❑N/A
1.
Samples Arrived within Hold Time?
©Yes
❑No
❑N/A
2.
Short Hold Time Analysis (<72 hr.)?
[]Yes
QNn_
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
[INd
❑N/A
4.
Sufficient Volume?
©Yes
[:]No
[--]N/A
5.
Correct Containers Used?
❑Yes
❑No
❑N/A
6.
-Pace Containers Used?
©Y6s
❑No
[]NIA
Containers Intact?
oyes `
[:]No
❑N/A
7.
Samples Field Filtered?
❑Yes
❑No
ON/A
8. Note if sediment is visible in the dissolved container
Sample Labels Match COC?
QYes
❑No
❑N/A
9.
-Includes Date/1'ime/I0/Analysis Matrix:
All containers needing acid/base preservation have been
10. HNOpW2
checked?
L]Yes
❑No
❑N/A
All containers needing preservation are found to be in
HQ PKQ
compliance with EPA recommendation?
H2504pW2
(HNO2, H2504, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide)
❑Yes
❑No
❑NIA
Exceptions: VOA, Coliform, TOC, Oil and Grease,
NaDHpHa12
DRO/8015 (water) DOC,LLHg
[]Yes
[:]No
QN[A
N.OH/ZnOAcpfb4
Samples checked for dechlorination?
[]Yes
❑No
[DN-A
11.
Headspace in VOA Vials (>5.6mm)?
[]Yes
❑NO ❑N/A
12.
Trip Blank Present?
❑Yes
❑No
®Nr
13.
Trip Blank Custody Seals Present?
❑Yes
❑No
EIN/A_
Pace Trip Blank Lot li (if purchased):
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Sample
Discrepancy:
DateMme:
Field Data Required? ❑Yes ❑No
Project Manager SCURF Review: Date: -4'((34
Project Manager SRF Review: Date: +1101b
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers)
Page 22 of 23

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