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Home My WebLink AboutNC0000396_J16040379 Report_20160831DUE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report Order Number: J16040379 Project Name: ASHEVILLE - AB GW ASSESSMENT WATER Customer Name(s): Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu Customer Address: 200 CP and L Drive Arden,NC 28704 Lab Contact: Mary Ann Ogle hone: 980-875-5274 Digitally signed by ary Ann Ogle Report Authorized By: Date: 2016.04.27 Date: 4/27/2016 (Signature) 14:54:26-04'00' Mary Ann Ogle Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Analytical Lab Page 1 of 35 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Analytical Lab Page 2 of 35 Collection Sample ID Plant/Station Date and Time Collected By 2016010628 ASHEVILLE 1 Total Samples 14-Apr-16 11:28 AM illegible Sample Description ABMW-11 BR Analytical Lab Page 3 of 35 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals 0 Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes 0 No All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No Report Sections Included: CI Job Summary Report ❑� Sample Identification Technical Validation of Data Package ❑� Analytical Laboratory Certificate of Analysis El Analytical Laboratory QC Report ❑d Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries ❑� Chain of Custody ❑� Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Mary Ann Ogle Date: 4/27/2016 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16040379 Site: ABMW-11 BR Collection Date: 14-Apr-16 11:28 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.02 mg-N/L 0.02 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 3.2 mg/L 0.1 Sulfate 40 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.126 mg/L 0.005 Barium (Ba) 0.012 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.020 mg/L 0.01 Manganese (Mn) 0.043 mg/L 0.005 Strontium (Sr) 0.100 mg/L 0.005 Zinc (Zn) 0.019 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 26.6 mg/L 0.01 Magnesium (Mg) 2.82 mg/L 0.005 Potassium (K) 15.9 mg/L 0.1 Sodium (Na) 19.3 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.992 mg/L 0.005 Barium (Ba) 0.018 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 3.47 mg/L 0.01 Manganese (Mn) 0.085 mg/L 0.005 Strontium (Sr) 0.104 mg/L 0.005 Zinc (Zn) 0.024 mg/L 0.005 Sample #: 2016010628 Matrix: GW_WW Analytical Lab Page 4 of 35 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 2 EPA 353.2 04/18/2016 13:16 LSTARLI Vendor Method V_PACE 1 EPA 300.0 04/20/2016 23:09 BGN9034 10 EPA 300.0 04/20/2016 23:09 BGN9034 1 EPA 245.1 04/23/2016 08:48 DMFRANC 1 EPA 245.1 04/23/2016 09:19 DMFRANC 1 EPA 200.7 04/19/2016 15:49 JJMACKE 1 EPA 200.7 04/19/2016 15:49 JJMACKE 1 EPA 200.7 04/19/2016 15:49 JJMACKE 1 EPA 200.7 04/19/2016 15:49 JJMACKE 1 EPA 200.7 04/19/2016 15:49 JJMACKE 1 EPA 200.7 04/19/2016 15:49 JJMACKE 1 EPA 200.7 04/19/2016 15:49 JJMACKE 1 EPA 200.7 04/15/2016 13:25 JJMACKE 1 EPA 200.7 04/15/2016 13:25 JJMACKE 1 EPA 200.7 04/15/2016 13:25 JJMACKE 1 EPA 200.7 04/15/2016 13:25 JJMACKE 1 EPA 200.7 04/18/2016 11:06 JJMACKE 1 EPA 200.7 04/18/2016 11:06 JJMACKE 1 EPA 200.7 04/18/2016 11:06 JJMACKE 1 EPA 200.7 04/18/2016 11:06 JJMACKE 1 EPA 200.7 04/18/2016 11:06 JJMACKE 1 EPA 200.7 04/18/2016 11:06 JJMACKE 1 EPA 200.7 04/18/2016 11:06 JJMACKE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16040379 Site: ABMW-11 BR Collection Date: 14-Apr-16 11:28 AM Analyte Result Units Qualifiers TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L Arsenic (As) < 1 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) 1.28 ug/L Cobalt (Co) < 1 ug/L Copper (Cu) 9.19 ug/L Lead (Pb) 1.63 ug/L Molybdenum (Mo) 12.4 ug/L Nickel (Ni) 4.98 ug/L Selenium (Se) < 1 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level 0.534 ug/L TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L Arsenic (As) < 1 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) 87.2 ug/L Cobalt (Co) 2.22 ug/L Copper (Cu) 6.11 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) 15.4 ug/L Nickel (Ni) 52.0 ug/L Selenium (Se) < 1 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level 2.31 ug/L METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete RADIOLOGICAL - (Analysis Performed by GEL) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 190 mg/L Total Carbon TOC 1.3 mg/L TOTAL SUSPENDED SOLIDS TSS 100 mg/L Sample #: 2016010628 Matrix: GW_WW Analytical Lab Page 5 of 35 RDL DF Method Analysis Date/Time Analyst 1 1 EPA 200.8 04/19/2016 14:14 JAHERMA 1 1 EPA 200.8 04/19/2016 14:14 JAHERMA 1 1 EPA 200.8 04/19/2016 14:14 JAHERMA 1 1 EPA 200.8 04/19/2016 14:14 JAHERMA 1 1 EPA 200.8 04/19/2016 14:14 JAHERMA 1 1 EPA 200.8 04/19/2016 14:14 JAHERMA 1 1 EPA 200.8 04/19/2016 14:14 JAHERMA 1 1 EPA 200.8 04/19/2016 14:14 JAHERMA 1 1 EPA 200.8 04/19/2016 14:14 JAHERMA 1 1 EPA 200.8 04/19/2016 14:14 JAHERMA 1 1 EPA 200.8 04/19/2016 14:14 JAHERMA 0.2 1 EPA 200.8 04/19/2016 14:14 JAHERMA 0.3 1 EPA 200.8 04/19/2016 14:14 JAHERMA 1 1 EPA 200.8 04/19/2016 15:47 JAHERMA 1 1 EPA 200.8 04/19/2016 15:47 JAHERMA 1 1 EPA 200.8 04/19/2016 15:47 JAHERMA 1 1 EPA 200.8 04/19/2016 15:47 JAHERMA 1 1 EPA 200.8 04/19/2016 15:47 JAHERMA 1 1 EPA 200.8 04/19/2016 15:47 JAHERMA 1 1 EPA 200.8 04/19/2016 15:47 JAHERMA 1 1 EPA 200.8 04/19/2016 15:47 JAHERMA 1 1 EPA 200.8 04/19/2016 15:47 JAHERMA 1 1 EPA 200.8 04/19/2016 15:47 JAHERMA 1 1 EPA 200.8 04/19/2016 15:47 JAHERMA 0.2 1 EPA 200.8 04/19/2016 15:47 JAHERMA 0.3 1 EPA 200.8 04/19/2016 15:47 JAHERMA Vendor Method V_PACE Vendor Method v_GEL Vendor Method V_PACE 25 1 SM2540C 04/18/201614:25 PARMSTR 0.1 1 SM5310C/EPA9060A 04/19/201614:02 GHUTCHI 5 1 SM2540D 04/15/201610:50 PARMSTR aceAnalyical www.pacelabs.com Pa�nalyil�afrlatervices, Inc. e. Suite 100 Huntersville, INC 28078 (704)875-9092 April 25, 2016 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 16040379 Pace Project No.: 92294093 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 15, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Anne Pifer Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 18 lacmnalyfical www.pacelabs.com PaHnal t XtiLabervices, Inc. G040cwke. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J16040379 Pace Project No.: 92294093 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 525 N 8th Street, Salina, KS 67401 A21-A Certification M 2926.01 Alaska Certification M UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification M 88-0680 California Certification M 01155CA Colorado Certification #Pace Connecticut Certification M PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification M 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification M 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification M 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification M 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification M E83079 Georgia Certification M 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification M 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification M E-10383 Louisiana Certification M FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Michigan Certification M 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification M Cert 0074 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Wyoming Certification: FL NELAC Reciprocity West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 18 aceAnalyical www.pacelabs.com Pa�nalyil�afrlatervices, Inc. �Q�Cigc&� e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J16040379 Pace Project No.: 92294093 Lab ID Sample ID SAMPLE SUMMARY Matrix Date Collected Date Received 92294093001 2016010628 Water 04/14/1611:28 04/15/1614:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 18 aceAnalyical www.pacelabs.com Pa�nalyil�afrlatervices, Inc. e. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J16040379 92294093 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92294093001 2016010628 RSK 175 DR1 1 PASI-M SM 2320B TEP 3 PASI-A SM 4500-S2D WRC 1 PASI-A EPA 218.7 TK1 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 18 aceAnalyical www.pacelabs.com Pa�nal il�tifrl bervices, Inc. �Offli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: J16040379 Pace Project No.: 92294093 Lab Sample ID Client Sample ID Method Parameters 92294093001 2016010628 RSK 175 Methane SM 2320B Alkalinity, Bicarbonate (CaCO3) SM 2320B Alkalinity, Total as CaCO3 Result Units 26.3 ug/L 95.4 mg/L 95.4 mg/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Report Limit Analyzed Qualifiers 10.0 04/18/16 21:31 5.0 04/21/1618:26 5.0 04/21/1618:26 Page 5 of 18 aceAnaiXical www.pacelabs.com Pa�nal il�tifrl bervices, Inc. �Offlinic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040379 Pace Project No.: 92294093 Method: RSK 175 Description: RSK 175 AIR Headspace Client: Duke Energy Date: April 25, 2016 General Information: 1 sample was analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: AIR/25714 R1: RPD value was outside control limits. • DUP (Lab ID: 2235966) • Methane Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 18 aceAnalyical www.pacelabs.com Pa�nal il�tifrl bervices, Inc. �Offli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040379 Pace Project No.: 92294093 Method: SM 2320B Description: 2320E Alkalinity Client: Duke Energy Date: April 25, 2016 General Information: 1 sample was analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 18 aceAnalyical www.pacelabs.com Pa�nal il�tifrl bervices, Inc. �Offli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040379 Pace Project No.: 92294093 Method: SM 4500-S213 Description: 4500S2D Sulfide Water Client: Duke Energy Date: April 25, 2016 General Information: 1 sample was analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WET/44377 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92293980001,92294063001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1715002) • Sulfide • MSD (Lab ID: 1715003) • Sulfide M3: Matrix spike recovery was outside laboratory control limits due to matrix interferences. • MS (Lab ID: 1715004) • Sulfide • MSD (Lab ID: 1715005) • Sulfide Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 18 aceAnaiXical www.pacelabs.com Pa�nal il�tifrl bervices, Inc. �Offlic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040379 Pace Project No.: 92294093 Method: EPA 218.7 Description: Hexavalent Chromium by IC Client: Duke Energy Date: April 25, 2016 General Information: 1 sample was analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/57123 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92293975006,92294145002 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1550400) • Chromium. Hexavalent • MSD (Lab ID: 1550401) • Chromium, Hexavalent Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 18 aceAnalyical www.pacelabs.com Pa�nal il�tifrl bervices, Inc. �Off�i�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040379 Pace Project No.: 92294093 Sample: 2016010628 Lab ID: 92294093001 Collected: 04/14/16 11:28 Received: 04/15/16 14:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 26.3 ug/L 10.0 1 04/18/16 21:31 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 95.4 mg/L 5.0 1 04/21/16 18:26 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 04/21/16 18:26 Alkalinity, Total as CaCO3 95.4 mg/L 5.0 1 04/21/16 18:26 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 04/21/1612:30 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 04/23/16 14:27 18540-29-9 Date: 04/25/2016 10:45 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 18 aceAnaiXical www.pacelabs.com Pa�nal il�tifrl bervices, Inc. �Off�i�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040379 Pace Project No.: 92294093 QC Batch: AIR/25714 Analysis Method: RSK 175 QC Batch Method: RSK 175 Analysis Description: RSK 175 AIR HEADSPACE Associated Lab Samples: 92294093001 METHOD BLANK: 2234083 Matrix: Water Associated Lab Samples: 92294093001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Methane ug/L ND 10.0 04/18/16 21:23 LABORATORY CONTROL SAMPLE & LCSD: 2234084 2234085 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Methane ug/L 60.7 59.7 54.8 98 90 85-115 9 20 SAMPLE DUPLICATE: 2235966 92293934021 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L 3970 6220 44 20 R1 SAMPLE DUPLICATE: 2235967 92294093001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L 26.3 24.6 7 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/25/2016 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 11 of 18 aceAnaiXical www.pacelabs.com Pa�nal il�tifrl bervices, Inc. �Offlic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040379 Pace Project No.: 92294093 QC Batch: WET/44349 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 92294093001 METHOD BLANK: 1714319 Associated Lab Samples: 92294093001 Parameter Units Alkalinity, Carbonate (CaCO3) mg/L Alkalinity, Total as CaCO3 mg/L Alkalinity, Bicarbonate (CaCO3) mg/L LABORATORY CONTROL SAMPLE: 1714320 Parameter Units Alkalinity, Total as CaCO3 mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 5.0 04/21/1614:05 ND 5.0 04/21/1614:05 ND 5.0 04/21/1614:05 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 50 48.8 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1714321 1714322 MS MSD 92293978003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 120 50 50 172 171 105 101 80-120 1 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1714323 1714324 MS MSD 92293983005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Alkalinity, Total as CaCO3 mg/L 36.8 50 50 79.9 79.7 86 86 80-120 0 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/25/2016 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 12 of 18 aceAnaiXical www.pacelabs.com Pa�nal il�tifrl bervices, Inc. �Offligc&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040379 Pace Project No.: 92294093 QC Batch: WET/44377 Analysis Method: SM 4500-S2D QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 92294093001 METHOD BLANK: 1715000 Matrix: Water Associated Lab Samples: 92294093001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide mg/L ND 0.10 04/21/1612:30 LABORATORY CONTROL SAMPLE: 1715001 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide mg/L .5 0.51 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1715002 1715003 MS MSD 92293980001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide mg/L ND .5 .5 0.55 0.55 111 111 90-110 0 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1715004 1715005 MS MSD 92294063001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide mg/L ND .5 .5 ND ND 3 3 90-110 10 M3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/25/2016 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 13 of 18 aceAnaiXical www.pacelabs.com Pa�nal il�tifrl bervices, Inc. �Offli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040379 Pace Project No.: 92294093 QC Batch: WETA/57123 Analysis Method: EPA 218.7 QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC Associated Lab Samples: 92294093001 METHOD BLANK: 1550398 Matrix: Water Associated Lab Samples: 92294093001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chromium, Hexavalent ug/L ND 0.030 04/23/16 09:45 LABORATORY CONTROL SAMPLE: 1550399 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chromium, Hexavalent ug/L .075 0.075 99 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1550400 1550401 MS MSD 92293975006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent ug/L ND .025 .025 .017J .0151 68 59 85-115 20 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1550402 1550403 MS MSD 92294145002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent ug/L 2.0 .75 .75 2.6 2.7 89 102 85-115 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/25/2016 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 14 of 18 aceAnaiXical www.pacelabs.com Pa e 1 ti I ervices, Inc. Ana ,1i�alora 098g �c&� t� Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J16040379 Pace Project No.: 92294093 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M3 Matrix spike recovery was outside laboratory control limits due to matrix interferences. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/25/2016 10:45 AM without the written consent of Pace Analytical Services, Inc.. Page 15 of 18 aceAnalyical www.pacelabs.com Pa e 1 ti I ervices, Inc. Ana ,1i�tifr 098 9nVJIe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J16040379 Pace Project No.: 92294093 Lab ID Sample ID QC Batch Method QC Batch 92294093001 2016010628 RSK 175 AIR/25714 92294093001 2016010628 SM 2320B WET/44349 92294093001 2016010628 SM 4500-S2D WET/44377 92294093001 2016010628 EPA 218.7 WETA/57123 Date: 04/25/2016 10:45 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Method Analytical Batch Page 16 of 18 Document Name: Document Revised: 18FEB2016 m Sample Condition Upon Recelpt(SCUR) Page 1 of 2 Analytical I c?ceAnalytkal Document No.: Issuing Authority: age i F-CHR-CS-003•rev.18 Pace Huntersville Quality Office ab 35 Client Name; ``+�tl jj� 9�i� ! ,� 4 Y .. . , Pro IA��T " V'l:.�ilf�.� I V�� 1 Courier: LlFed Ex l ❑UPS ❑LISPS []Client ❑ Commercial ®Pgce ❑Other: 92294093 Custody Seal Present? ❑Yes ❑N6--_ Seals Intact? ❑Yes ❑No L, Date/Initials Person Examining Contents: L ' k �� LO Packing Material: ❑Bubble Wrap ❑Bubble Bags ❑None DOther: Thermometer: QT-1505 ❑ Type of Ice: OWef ❑Blue []None OSamples on Ice, cooling process has begun Correction factor: 0.0°C Cooler Temp Corrected (°C): `?s, L Biological Tissue Frozen? []Yes []No []N[A- Temp should be above freezing to 6°C USDA Regulated Soil ( 0-N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, ❑Yes DN6-�-- Including Hawaii and Puerto Rico)? []Yes ❑No — COMMENTS: Chain of Custody Present? Eyes []NO ❑N/A 1. Chain of Custody Filled Out? @ s ❑No ❑N/A 2. - Chaln of Custody Relinquished? UVrs ❑No ❑N/A 3. Sampler Name and/or Signature on COC? G]xes I]No ❑N/A 4. Samples Arrived within Hold Time? Yes-- ❑No ❑NIA 5. Short Hold Time Analysis (<72 hr.)? ❑Yes N6 ❑N/A 6. Rush Turn Around Time Requested? es []NO ❑N/A 7. Sufficient Volume? MY Cs ❑No ❑N/A 8. Correct Containers Used? -Pace Containers Used? Q9Yes- ❑Na OYes� ❑No� ❑N/A ❑N/A 9. Containers Intact? esr []NO ❑N/A 10. Filtered Volume Received for Dissolved Tests? ❑Yes ❑No ©N/A- 11. Note if sediment is visible In the dissolved container Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: ®Yes` []No ❑N/A 12. All containers needing acid/base preservation have been checked? All.contalners needing preservation are found to be In compliance with EPA recommendation? (HNOs, H2SO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide) Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC,LLHg QYes- QY6s []Yes ❑No []No []No ❑N/A ❑N/A ON/A 11 Sam ples checked for dech lorinatio n [Dyw ❑No ❑N/A 14. Headspace in VOA Via Is (>5-6mm)? []Yes ®K'o Trip Blank Present? Trip Blank Custody Seals Present? Pace Trip Blank Lot ff (if purchased): []Yes []Yes ❑No []NO QuIK' QN/A 16. CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Date/Time: Field Data Required? ❑Yes ❑No Project Manager SCURF Review: �,fjpC Date: Al 15- i 6 Project Manager SRF Review: _ Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the. North Carolina DEHNRCertification Office (i.e. ,but of hold, incorrect preservative, out of temp, Incorrect containers) Page 17 of 18 C w W M a w Ix N CO J Q 0 Q p /U Y Uj I]: O; O' F- V OI LL Pi Q� z o; t� ui a ? 1n r+ Y ti C U r o Y c r g m s -Io �ac°.1 W S j °0 > w " N 2 IY V � , d � D U g $ japed Ai 14 Ja Sai o J �' :LnluEar i = g Am Pue On II LlliTl E O � ePUln$ a z c p o F w eSEYc QF6^ a i II� � - a •ojYuap)g01E •R1lul1=� x j i 0 a bt]S `la �+ E n n Bard-n, IF�f• I r O v w HeY!) eaeyleyy s ri W. ssi a E gvip ==�N c � � m` •dwo, n � C v s LO t m Ln CD jg I CT] c—1 3 f o F lQ fV rH r-1 a L o a v. F � i � 3ti"\dg M o i6 Cr w C J a Cp a w 61 4 I ai .._.._...._...�. ?............ ..... .... . Analytical Lab Page 23 of 35 -4- -o-_ o o o � _o_ o a o p ry nCx C ! T e — n I E hV rs a N. �1 < a ! 4 Q FFIv 7 p Z G r v l n I v I 0;� i r I N --� ---I punoJeurni pwitap I! elevlpul asap;d aueyivdwl'�nwolsn� � N C I i•�,� S fa Q � E in E 1 C I � � z J J FChnd Y F L f0.; ID �k e` 0 ° d U a a RI � 3a LCy ) � Ifs g ...7E + f Y +� 1i IX t E £ i F- G z7 ILU 1 a iuw v' ........... ..._................. Page 18 of 18 ® Laboratories LLc nalytical Lab ,_ age 24 of 35 a member of The GEL Group IN'. April 22, 2016 Mary Ann Ogle Duke Energy Analytical Laboratory 13339 Hagers Ferry Road Mail Code: MGO3A2 Huntersville, North Carolina 28078 Re: AB GW Assessment Water Work Order: 395455 SDG: J16040379 Dear Mary: P4 Box 30712 Charleston. SC 29417 2040 Sange Road Chad eston.SC29407 P 843556.8171 F 843.76Gi.1178 GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received on April 15, 2016. This original data report has been prepared and reviewed in accordance with GEL's standard operating procedures. Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time. We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at (843) 556-8171, ext. 4443. Sincerely, Lindsay Fabra Project Manager Purchase Order: 1142110 DPNNGO Enclosures gel.com Pa 111111111111111111111111111111111111111 Analytical Lab Page 25 of 35 GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Report for DUP0002 Duke Energy Client SDG: J16040379 GEL Work Order: 395455 The Qualifiers in this report are defined as follows: * A quality control analyte recovery is outside of specified acceptance criteria ** Analyte is a Tracer compound ** Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD. Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis. The designation ND, if present, appears in the result column when the analyte concentration is not detected above the limit as defined in the 'U' qualifier above. This data report has been prepared and reviewed in accordance with GEL Laboratories LLC standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra. Reviewed by JU,&Y , Page 2 of 11 Analytical Lab GEL LABORATORIES LLC Page 26 of 35 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Duke Energy Analytical Laboratory Address : 13339 Hagers Ferry Road Mail Code: MG03A2 Huntersville, North Carolina 28078 Contact: Mary Ann Ogle Project: AB GW Assessment Water Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector: 2016010628 395455001 Water 14-APR-16 11:28 15-APR-16 Client Report Date: April 22, 2016 Project: DUKE00225 Client ID: DUP0002 Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method Metals Analysis-ICP-MS SW846 3010A/6020A Liquid "As Received" Uranium-238 0.0017 0.000067 0.0002 ug/mL 1 SKJ 04/19/16 1449 1560300 1 Uranium-236 U ND 0.00001 0.00005 ug/mL 1 PRB 04/20/16 1542 1560300 2 Uranium-233 U ND 0.00001 0.00005 ug/mL 1 PRB 04/20/16 2246 1560300 3 Uranium-234 U ND 0.00001 0.00005 ug/mL 1 Rad Gas Flow Proportional Counting GFPC, Ra228, Liquid "As Received" Radium-228 U ND 1.59 3.00 pCi/L AXM6 04/21/16 1130 1560419 4 Rad Radium-226 Lucas Cell, Ra226, liquid "As Received" Radium-226 1.31 0.640 1.00 pCi/L LXP1 04/21/16 0905 1560375 5 The following Prep Methods were performed: Method Description Analyst Date Time Prep Batch SW846 3010A SW 846 3010 Acid Digestion JP1 04/15/16 2040 1560299 The following Analytical Methods were performed: Method Description I SW846 3010A/6020A 2 SW846 3010A/6020A 3 SW846 3010A/6020A 4 EPA 904.0/SW846 9320 Modified 5 EPA 903.1 Modified Comments Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 78 (15%-125%) Notes: Page 3 of 11 Analytical Lab Page 27 of 35 GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com QC Summary Duke Energy Analytical Laboratory 13339 Hagers Ferry Road Mail Code: MG03A2 Huntersville, North Carolina Contact: Mary Ann Ogle Workorder: 395455 Report Date: April 22, 2016 Page 1 of 3 Parmname NOM Sample Qual QC Units RPD%o REC% Range Anlst Date Time Metals Analysis - ICPMS Batch 1560300 QC1203529611 395455001 DUP Uranium-233 U ND U ND ug/mL N/A PRB 04/20/16 22:48 Uranium-234 U ND U ND ug/mL N/A Uranium-236 U ND U ND ug/mL N/A 04/20/1615:43 Uranium-238 0.0017 0.00172 ug/mL 1.35 (0%-20%) SKJ 04/19/1614:50 QC1203529610 LCS Uranium-238 0.0496 0.0535 ug/mL 108 (80%-120%) 04/19/1614:47 QC1203529699 LCS Uranium-233 0.0005 0.000525 ug/mL 105 (80%-120%) PRB 04/20/16 22:45 Uranium-234 0.00055 0.000596 ug/mL 108 (80%-120%) Uranium-236 0.005 0.00474 u9/mL 94.8 (80%-120%) 04/20/1615:40 QC1203529609 MB Uranium-233 U ND ug/mL 04/20/16 22:43 Uranium-234 U ND ug/mL Uranium-236 U ND ug/mL 04/20/1615:38 Uranium-238 U ND ug/mL SKJ 04/19/1614:46 QC1203529612 395455001 MS Uranium-238 0.0496 0.0017 0.0552 ug/mL 108 (75%-125%) 04/19/1614:52 QC1203529700 395455001 MS Uranium-233 0.0005 U ND 0.000496 ug/mL 99.2 (75%-125%) PRB 04/20/16 22:50 Uranium-234 0.00055 U ND 0.000564 ug/mL 103 (75%-125%) Uranium-236 0.005 U ND 0.00469 ug/mL 93.9 (75%-125%) 04/20/1615:45 QC1203529613 395455001 SDILT Uranium-233 U ND U ND ug/L N/A 04/20/16 22:52 Page 4 of 11 Analytical Lab Page 28 of 35 GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 395455 Page 2 of 3 Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Time Metals Analysis - ICPMS Batch 1560300 Uranium-234 U ND U ND ug/L N/A Uranium-236 U ND U ND ug/L N/A (0%-10%) PRB 04/20/1615:47 Uranium-238 1.70 0.363 ug/L 6.72 (0%-10%) SKJ 04/19/1614:53 Rad Gas Flow Batch 1560419 QC1203529991 395455001 DUP Radium-228 U 1.28 U 0.434 pCi/L N/A N/AAXM6 04/21/1611:30 QC1203529992 LCS Radium-228 46.5 51.1 pCi/L 110 (75%-125%) 04/21/1611:30 QC1203529990 MB Radium-228 U -0.256 pCi/L 04/22/1611:25 Rad Ra-226 Batch 1560375 QC1203529848 395455001 DUP Radium-226 1.31 1.55 pCi/L 17.3 (0% - 100%) LXP1 04/21/16 09:05 QC1203529850 LCS Radium-226 24.4 23.4 pCi/L 95.9 (75%-125%) 04/21/16 09:35 QC1203529847 MB Radium-226 U 0.413 pCi/L 04/21/16 09:05 QC1203529849 395455001 MS Radium-226 122 1.31 132 pCi/L 107 (75%-125%) 04/21/16 09:35 Notes: The Qualifiers in this report are defined as follows: ** Analyte is a Tracer compound < Result is less than value reported > Result is greater than value reported BD Results are either below the MDC or tracer recovery is low E %difference of sample and SD is >10%. Sample concentration must meet flagging criteria FA Failed analysis. FB Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed invalid for reporting to regulatory agencies H Analytical holding time was exceeded Page 5 of 11 Analytical Lab Page 29 of 35 GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 395455 Parmname NOM Sample Qual QC Units RPD%o REC'% Page 3 of 3 Range Anlst Date Time J Value is estimated K Analyte present. Reported value may be biased high. Actual value is expected to be lower. L Analyte present. Reported value may be biased low. Actual value is expected to be higher. M M if above MDC and less than LLD M REMP Result > MDC/CL and < RDL N Metals --The Matrix spike sample recovery is not within specified control limits N/A RPD or %Recovery limits do not apply. N1 See case narrative ND Analyte concentration is not detected above the detection limit NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER. R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD. UI Gamma Spectroscopy --Uncertain identification UJ Gamma Spectroscopy --Uncertain identification UL Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias. X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y Other specific qualifiers were required to properly define the results. Consult case narrative. ^ RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry. h Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more or %RPD not applicable. ^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result. * Indicates that a Quality Control parameter was not within specifications. For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations. Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary. Page 6of11 I Analytical Lab Page 30 of 35 w 41 k 187o i -T —, I V) (Ovo) slut —I 1 J PS)AIOSSIC3 (sr,O) SIEle w PEIAJOSSIQ eas) S1 l (aced A) JA 10 iE E r C 's < tr < F5 1 0 `U ill Sol > Cr —7 wnjUwn I(qu pule azz) (03Ed A) splilnS, (OOLCA .64-41N '001 VOSIO 0 LS *Dud A W M 0 0 m )ASN) —PROW SSI LO dwoo M 7-- i It > AE V, t.0 M -4, Ln Oir rH C) 0 10 r-i c !a Um 0 ............. CL CL 0 UJ CL Z zk; .5 i, " . .2 0 0 �2 4 7 < 5 U, L) < 12 0. rL E S 13! to g, 10 Z a LU CD --- ---- ............. . .... E mr W Page 7 of 11 Laboratories «C SAMPLE RECEIPT & REVIEW FORM Analytical Lab Page 31 of 35 Suspected Hazard I1wrmation COC/Samples marked as radioactive? Classified Radioactive B or III by RSO? COC/Samples marked containing PCBs? Package, COC, and/or<Samples:inarked as beryllium or nsbestos'containmg? Shipped as a DOT Hazardous? Samples identified as Foreign Soil? Sample Receipt Criteria 1 Shipping containers received intact and sealed? 2 Samples requiring cold preservation within (0 G 6 deg. C)?* 2a Daily check performed and passed on IR temperature gun? 3 Chain of custody documents included with shipment? 4 Sample containers intact and sealed? 5 Samples requiring chemical preservation at proper pH? 6 Do Low Level Perchlorate samples have headspace as r uired? 7 VOA vials contain acid preservation? 8 VOA vials free of headspace (defined as < 6mm bubble)? 9 Are Encore containers present? 10 Samples received within holding time? 11 Sample ID's on COC match ID's on bottles? 12 Date & time on COC match date & time on bottles? 13 Number of containers received match number indicated on COC? 14 Are sample containers identifiable as GEL rovided? 15 COC form is properly signed in 16 Carrier and tracking number. (Use Continuation Form if needed): Date Received: tS t; v o If Net Counts > IoOcpm on samples not marked "radioactive", cor } Z iinvestigation. aximum Net Counts Observed* (Observed Counts - Area Backgr f yes, were swipes taken of sample containers e action levels? Qi yes,°-sam �les,are to be segregated as' Safety Controlled Sam ' les,?a iazard Class Shipped: UN#: the Radiation Safety Group for further z Z Comments/Qualifiers (Required for Non -Conforming Items) Circle Applicable: Seals broken Damaged container Leaking container Other (describe) Preservation Method: Ice bags Blue ice Dry ice one Other (describe) *all temperatures are recorded in Celsius Temperature Device Serial #:'6 651- - Secondary Temperature Device ria # ([f Applicable): %-ucic Applicable: Seals broken Damaged con Sample ID's, containers affected and observed pH: If Preservation added In1#• Sample ID's Wand affected: (If unknown, select No) Sample ID's and containers affected: and tests affected: ple ID's and contai 10 to volatiles laboratory) container FedEx Air FedEx Ground UPS Field Services/ Courier PM (or PMA) review: Initials Date i l= f .•7 — Page— i— I of _ �-�GL-CHL-SR-001 Rev 3 Page 8 of l 1 Analytical Lab Page 32 of 35 Technical Case Narrative Duke Energy (DUPO) SDG #: J16040379 Work Order #: 395455 Metals Product: Determination of Metals by ICP-MS Analytical Method: SW846 3010A/6020A Analytical Procedure: GL-MA-E-014 REV# 28 Analytical Batch: 1560300 Preparation Method: SW846 3010A Preparation Procedure: GL-MA-E-008 REV# 18 Preparation Batch: 1560299 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 395455001 2016010628 1203529609 Method Blank (MB)ICP-MS 1203529610 Laboratory Control Sample (LCS) 1203529699 Laboratory Control Sample (LCS) 1203529613 395455001(2016010628L) Serial Dilution (SD) 1203529611 395455001(2016010628D) Sample Duplicate (DUP) 1203529612 395455001(2016010628S) Matrix Spike (MS) 1203529700 395455001(2016010628S) Matrix Spike (MS) The samples in this SDG were analyzed on an "as received" basis. Data Summary: There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable. Radiochemistry Product: GFPC, Ra228, Liquid Analytical Method: EPA 904.0/SW846 9320 Modified Analytical Procedure: GL-RAD-A-009 REV# 17 Analytical Batch: 1560419 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 395455001 2016010628 1203529990 Method Blank (MB) 1203529991 395455001(2016010628) Sample Duplicate (DUP) 1203529992 Laboratory Control Sample (LCS) Page 9 of 11 Analytical Lab Page 33 of 35 The samples in this SDG were analyzed on an "as received" basis. Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions. Technical Information Recounts Sample 1203529990 (MB) was re-eluted due to a suspected blank false positive. The recount is reported. Product: Lucas Cell, Ra226, liquid Analytical Method: EPA 903.1 Modified Analytical Procedure: GL-RAD-A-008 REV# 14 Analytical Batch: 1560375 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 395455001 2016010628 1203529847 Method Blank (MB) 1203529848 395455001(2016010628) Sample Duplicate (DUP) 1203529849 395455001(2016010628) Matrix Spike (MS) 1203529850 Laboratory Control Sample (LCS) The samples in this SDG were analyzed on an "as received" basis. Data Summary• All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions. Miscellaneous Information Additional Comments The matrix spike, 1203529849 (2016010628MS), aliquot was reduced to conserve sample volume. Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative. Page 10 of 11 Analytical Lab Page 34 of 35 List of current GEL Certifications as of 22 April 2016 State Certification Alaska UST-0110 Arkansas 88-0651 CLIA 42D0904046 California 2940 Colorado SC00012 Connecticut PH-0169 Delaware SC00012 DoD ELAP/ ISO17025 A2LA 2567.01 Florida NELAP E87156 Foreign Soils Permit P330-15-00283, P330-15-00253 Georgia SC00012 Georgia SDWA 967 Hawaii SC00012 Idaho Chemistry SC00012 Idaho Radiochemistry SC00012 Illinois NELAP 200029 Indiana C—SC-01 Kansas NELAP E-10332 Kentucky SDWA 90129 Kentucky Wastewater 90129 Louisiana NELAP 03046 (A133904) Louisiana SDWA LA160006 Maryland 270 Massachusetts M—SC012 Michigan 9976 Mississippi SC00012 Nebraska NE—OS-26-13 Nevada SC000122016-1 New Hampshire NELAP 205415 New Jersey NELAP SC002 New Mexico SC00012 New York NELAP 11501 North Carolina 233 North Carolina SDWA 45709 North Dakota R-158 Oklahoma 9904 Pennsylvania NELAP 68-00485 S.Carolina Radchem 10120002 South Carolina Chemistry 10120001 Tennessee TN 02934 Texas NELAP T104704235-16-11 Utah NELAP SC000122016-20 Vermont VT87156 Virginia NELAP 460202 Washington C780 West Virginia 997404 Page 11 of 11 .—__._- _--IS REQUEST FORM Anal------Lpaan�rBWay nsaurni4,.la„Trns .. - -•- - -'-- --- - � Analytical Lab r--. �>r --- -•- ['MAIN C}P �GUST�CkY REGClRQ AP�IU o.a I.nr � � �#IST�leu�r�rl- Page 3!'Syrft iCa E131} DukeErrer �°'�� LUo.++rt�ry mr cee. hhxi7As Oked- Add .ftrnll r rx {i�V� YIILV� Chalm arrGustad}' !4 H+ryr,unrfe, x C. aeaT4 - - --- - __`._ - ,! �4c d 4 D i ; ettIIN�L ra L, coPv to q ap.ra4T, area ; �LocQw sr Irnr.f rr, OAAWU FFMAM.. 8a_nNLag J!k 1� T _ .' ` j1+- ' l "us{M iOtkA" rww 11T v RaceRYxhNA3 J Yr4 1= r,e, po: J �,.µ7s.5n; 1� #�y [� [ Ikailon {0.46 uan} �i MKS T i� plc f f7 .L7ti7 UMllrearrd -Tq�{ l _ - Iralr!' xF. C®!r To: Rr F9+iaa!#Iiws - ao. Mae F'f -- Ter ~ r lat - `- 'A-14 NOl:.d.. ,[ I seer' y4V,ms I i MO 40 WA aoa I MG.03A1 GEL nd der@ - SUO A k 506 yw„ Ccwftk Rf Tina PET Ome PET CEO PEr PET 401"E YET PO 1142110 sample I7eecriptitam ear I t} s.,,R, ...e .+.,. w S + ._-... �rf7a.,nNsr, Infaneb9Pion CL CCS LocaUorr -_ i + awn ° " ; aw nm. ei dIa s� 250 &N 5DO Stan awre HDPE HOPE i4M tt$, o E. 13 _. _L! 0 0 13 I FARm- l - --- - ®' VTR to d.1. � z 4 8 2 # � ,nr n 6 — -- - Aecsi - r � R9c{r•Bbgrd lurnanauntl Talal 82 g d P1nrPfTlm« Aocep6rd { d • v "14 fa�ys. ad B Loraffitm -t'� '• - - - .-.! Im f Ld _ f i - /} 7 Days V JI n e -as W L,1 e L - 7- ELEMENTS by ICP MS ffRM5: PA, lie, Gd, Gu, Cc, C4, go, 0. Pb, Ih, 56, n ILL), V {I.Ll � � -0thsa FSARi -p.- ELJBlKENT'& ay r-F ITRW A}, Ian. Rl Fr, }!n, qr, Zh aCR_UaWgwowd Ca, Mg, K, Na Hp k3y745-1 n Add. CrYA Will Apply Csl.solrsri mrr111s : nit mrrrnl4tl IIGR, Ri69.1'Ip [5