NC0000396_J16040290 Report_20160831

DUKE Analytical Laboratory Page 1of67
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J16040290
ASHEVILLE - AB GW ASSESSMENT WATER
Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
200 CP and L Drive
Arden,NC 28704
Mary Ann Ogle
Phone: [phone]
M—com, c—d,k 3)
r ,�/%// ✓y//C do--Accountsduke-energy, do=ent, do=nam,
�( -Accounts, outsPersonal,
u=PNTransitional, cn—MA05125 (15436Date:
2016.04.29 09:50:15-04'00'
Mary Ann Ogle
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
4/28/2016
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2016010294
2016010297
2016010298
2016010299
2016010300
2016010301
2016010302
7 Total Samples
Collected By
Sample Description
ASHEVILLE
12-Apr-16 8:30 AM
illegible
MW-17A
ASHEVILLE
12-Apr-16 10:18 AM
illegible
MW-24S
ASHEVILLE
12-Apr-16 1:10 PM
illegible
AMW-3B
ASHEVILLE
12-Apr-16 1:33 PM
illegible
MW-10
ASHEVILLE
12-Apr-16 3:46 PM
illegible
MW-21D
ASHEVILLE
12-Apr-16 10:18 AM
illegible
DUP
ASHEVILLE
12-Apr-16 5:00 PM
illegible
Equipment Blank
Page 2 of 67

Page 3 of 67
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
OV Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 4/28/2016

Certificate of Laboratory Analysis Page 4 of 67
This report shall not be reproduced, except in full.
Order # J16040290
Site: MW-17A
Collection Date: 12-Apr-16 8:30 AM
Analyte Result Units Qualifiers RDL DF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg) < 0.05 ug/L
DISSOLVED METALS BY ICP
Aluminum (AI) 0.257 mg/L
Barium (Ba) 0.165 mg/L
Boron (B) 1.88 mg/L
Iron (Fe) 20.4 mg/L
Manganese (Mn) 5.96 mg/L
Strontium (Sr) 0.622 mg/L
Zinc (Zn) 0.023 mg/L
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
1.05
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
19.8
ug/L
Copper (Cu)
2.37
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
4.19
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
1200
mg/L
TOTAL SUSPENDED SOLIDS
TSS
10
mg/L
Sample #: 2016010294
Matrix: GW_WW
Method Analysis Date/Time Analyst
0.05
1
EPA 245.1
04/18/2016 13:48
DMFRANC
0.005
1
EPA 200.7
04/14/2016 15:44
JJMACKE
0.005
1
EPA 200.7
04/14/2016 15:44
JJMACKE
0.05
1
EPA 200.7
04/14/2016 15:44
JJMACKE
0.01
1
EPA 200.7
04/14/2016 15:44
JJMACKE
0.005
1
EPA 200.7
04/14/2016 15:44
JJMACKE
0.005
1
EPA 200.7
04/14/2016 15:44
JJMACKE
0.005
1
EPA 200.7
04/14/2016 15:44
JJMACKE
1
1
EPA 200.8
04/15/2016 13:15
JAHERMA
1
1
EPA 200.8
04/15/2016 13:15
JAHERMA
1
1
EPA 200.8
04/15/2016 13:15
JAHERMA
1
1
EPA 200.8
04/15/2016 13:15
JAHERMA
1
1
EPA 200.8
04/15/2016 13:15
JAHERMA
1
1
EPA 200.8
04/15/2016 13:15
JAHERMA
1
1
EPA 200.8
04/15/2016 13:15
JAHERMA
1
1
EPA 200.8
04/15/2016 13:15
JAHERMA
1
1
EPA 200.8
04/15/2016 13:15
JAHERMA
1
1
EPA 200.8
04/15/2016 13:15
JAHERMA
1
1
EPA 200.8
04/15/2016 13:15
JAHERMA
0.2
1
EPA 200.8
04/15/2016 13:15
JAHERMA
0.3
1
EPA 200.8
04/15/2016 13:15
JAHERMA
Vendor Method V_PACE
Vendor Method v_GEL
25 1 SM2540C 04/18/201614:25 PARMSTR
5 1 SM2540D 04/15/201610:50 PARMSTR

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
Site: MW-24S
Collection Date: 12-Apr-16 10:18 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 1.2 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
14
mg/L
0.5
Sulfate
0.74
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.034
mg/L
0.005
Barium (Ba)
0.054
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.148
mg/L
0.005
Strontium (Sr)
0.038
mg/L
0.005
Zinc (Zn)
0.018
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
3.10
mg/L
0.01
Magnesium (Mg)
3.73
mg/L
0.005
Potassium (K)
1.54
mg/L
0.1
Sodium (Na)
3.38
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.271
mg/L
0.005
Barium (Ba)
0.253
mg/L
0.005
Boron (B)
0.232
mg/L
0.05
Iron (Fe)
0.235
mg/L B2
0.01
Manganese (Mn)
0.359
mg/L
0.005
Strontium (Sr)
0.228
mg/L
0.005
Zinc (Zn)
0.232
mg/L
0.005
Sample #: 2016010297
Matrix: GW_WW
Page 5 of 67
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/14/2016 12:09 LSTARL1
Vendor Method V_PACE
5 EPA 300.0
04/15/2016 13:04
BGN9034
1 EPA 300.0
04/15/2016 13:04
BGN9034
1 EPA 245.1
04/18/2016 13:36
DMFRANC
1 EPA 245.1
04/18/2016 13:51
DMFRANC
1 EPA 200.7
04/14/2016 15:48
JJMACKE
1 EPA 200.7
04/14/2016 15:48
JJMACKE
1 EPA 200.7
04/14/2016 15:48
JJMACKE
1 EPA 200.7
04/14/2016 15:48
JJMACKE
1 EPA 200.7
04/14/2016 15:48
JJMACKE
1 EPA 200.7
04/14/2016 15:48
JJMACKE
1 EPA 200.7
04/14/2016 15:48
JJMACKE
1 EPA 200.7
04/14/2016 13:36
JJMACKE
1 EPA 200.7
04/14/2016 13:36
JJMACKE
1 EPA 200.7
04/14/2016 13:36
JJMACKE
1 EPA 200.7
04/14/2016 13:36
JJMACKE
1 EPA 200.7
04/14/2016 17:15
JJMACKE
1 EPA 200.7
04/14/2016 17:15
JJMACKE
1 EPA 200.7
04/14/2016 17:15
JJMACKE
1 EPA 200.7
04/14/2016 17:15
JJMACKE
1 EPA 200.7
04/14/2016 17:15
JJMACKE
1 EPA 200.7
04/14/2016 17:15
JJMACKE
1 EPA 200.7
04/14/2016 17:15
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
Site: MW-24S
Collection Date: 12-Apr-16 10:18 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
10.0
ug/L
Lead (Pb)
1.54
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
1.01
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
1.04
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
63
mg/L
Total Carbon
TOC
0.214
mg/L
Page 6 of 67
Sample #:
2016010297
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/15/2016 13:20
JAHERMA
1
1
EPA 200.8
04/15/2016 13:20
JAHERMA
1
1
EPA 200.8
04/15/2016 13:20
JAHERMA
1
1
EPA 200.8
04/15/2016 13:20
JAHERMA
1
1
EPA 200.8
04/15/2016 13:20
JAHERMA
1
1
EPA 200.8
04/15/2016 13:20
JAHERMA
1
1
EPA 200.8
04/15/2016 13:20
JAHERMA
1
1
EPA 200.8
04/15/2016 13:20
JAHERMA
1
1
EPA 200.8
04/15/2016 13:20
JAHERMA
1
1
EPA 200.8
04/15/2016 13:20
JAHERMA
1
1
EPA 200.8
04/15/2016 13:20
JAHERMA
0.2
1
EPA 200.8
04/15/2016 13:20
JAHERMA
0.3
1
EPA 200.8
04/15/2016 13:20
JAHERMA
1
1
EPA 200.8
04/19/2016 12:01
SLS2560
1
1
EPA 200.8
04/19/2016 12:01
SLS2560
1
1
EPA 200.8
04/19/2016 12:01
SLS2560
1
1
EPA 200.8
04/19/2016 12:01
SLS2560
1
1
EPA 200.8
04/19/2016 12:01
SLS2560
1
1
EPA 200.8
04/19/2016 12:01
SLS2560
1
1
EPA 200.8
04/19/2016 12:01
SLS2560
1
1
EPA 200.8
04/19/2016 12:01
SLS2560
1
1
EPA 200.8
04/19/2016 12:01
SLS2560
1
1
EPA 200.8
04/19/2016 12:01
SLS2560
1
1
EPA 200.8
04/19/2016 12:01
SLS2560
0.2
1
EPA 200.8
04/19/2016 12:01
SLS2560
0.3
1
EPA 200.8
04/19/2016 12:01
SLS2560
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
25
1
SM2540C
04/18/201614:25
PARMSTR
0.1
1
SM5310C/EPA9060A
04/14/201611:05
GHUTCHI

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
Site: MW-24S
Collection Date: 12-Apr-16 10:18 AM
Analyte Result
TOTAL SUSPENDED SOLIDS
TSS < 5
Units Qualifiers RDL DF
mg/L 5 1
Page 7 of 67
Sample #: 2016010297
Matrix: GW_WW
Method Analysis Date/Time Analyst
SM2540D 04/15/201610:50 PARMSTR

Certificate of Laboratory Analysis Page 8 of 67
This report shall not be reproduced, except in full.
Order # J16040290
Site: AMW-3B
Collection Date: 12-Apr-16 1:10 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.192 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
0.60
mg/L
0.1
Sulfate
1.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.006
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
0.056
mg/L
0.005
Zinc (Zn)
0.018
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
6.07
mg/L
0.01
Magnesium (Mg)
1.83
mg/L
0.005
Potassium (K)
1.63
mg/L
0.1
Sodium (Na)
5.18
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.017
mg/L
0.005
Barium (Ba)
0.007
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L B2
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
0.056
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016010298
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/14/2016 12:10 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
04/15/2016 11:19
BGN9034
1 EPA 300.0
04/15/2016 11:19
BGN9034
1 EPA 245.1
04/18/2016 13:38
DMFRANC
1 EPA 245.1
04/18/2016 13:53
DMFRANC
1 EPA 200.7
04/14/2016 15:52
JJMACKE
1 EPA 200.7
04/14/2016 15:52
JJMACKE
1 EPA 200.7
04/14/2016 15:52
JJMACKE
1 EPA 200.7
04/14/2016 15:52
JJMACKE
1 EPA 200.7
04/14/2016 15:52
JJMACKE
1 EPA 200.7
04/14/2016 15:52
JJMACKE
1 EPA 200.7
04/14/2016 15:52
JJMACKE
1 EPA 200.7
04/14/2016 13:40
JJMACKE
1 EPA 200.7
04/14/2016 13:40
JJMACKE
1 EPA 200.7
04/14/2016 13:40
JJMACKE
1 EPA 200.7
04/14/2016 13:40
JJMACKE
1 EPA 200.7
04/14/2016 17:26
JJMACKE
1 EPA 200.7
04/14/2016 17:26
JJMACKE
1 EPA 200.7
04/14/2016 17:26
JJMACKE
1 EPA 200.7
04/14/2016 17:26
JJMACKE
1 EPA 200.7
04/14/2016 17:26
JJMACKE
1 EPA 200.7
04/14/2016 17:26
JJMACKE
1 EPA 200.7
04/14/2016 17:26
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
Site: AMW-3B
Collection Date: 12-Apr-16 1:10 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
11.5
ug/L
Lead (Pb)
1.53
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
67
mg/L
Total Carbon
TOC
< 0.1
mg/L
Page 9 of 67
Sample #:
2016010298
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/14/2016 22:54
JAHERMA
1
1
EPA 200.8
04/14/2016 22:54
JAHERMA
1
1
EPA 200.8
04/14/2016 22:54
JAHERMA
1
1
EPA 200.8
04/14/2016 22:54
JAHERMA
1
1
EPA 200.8
04/14/2016 22:54
JAHERMA
1
1
EPA 200.8
04/14/2016 22:54
JAHERMA
1
1
EPA 200.8
04/14/2016 22:54
JAHERMA
1
1
EPA 200.8
04/14/2016 22:54
JAHERMA
1
1
EPA 200.8
04/14/2016 22:54
JAHERMA
1
1
EPA 200.8
04/14/2016 22:54
JAHERMA
1
1
EPA 200.8
04/14/2016 22:54
JAHERMA
0.2
1
EPA 200.8
04/14/2016 22:54
JAHERMA
0.3
1
EPA 200.8
04/14/2016 22:54
JAHERMA
1
1
EPA 200.8
04/19/2016 11:38
SLS2560
1
1
EPA 200.8
04/19/2016 11:38
SLS2560
1
1
EPA 200.8
04/19/2016 11:38
SLS2560
1
1
EPA 200.8
04/19/2016 11:38
SLS2560
1
1
EPA 200.8
04/19/2016 11:38
SLS2560
1
1
EPA 200.8
04/19/2016 11:38
SLS2560
1
1
EPA 200.8
04/19/2016 11:38
SLS2560
1
1
EPA 200.8
04/19/2016 11:38
SLS2560
1
1
EPA 200.8
04/19/2016 11:38
SLS2560
1
1
EPA 200.8
04/19/2016 11:38
SLS2560
1
1
EPA 200.8
04/19/2016 11:38
SLS2560
0.2
1
EPA 200.8
04/19/2016 11:38
SLS2560
0.3
1
EPA 200.8
04/19/2016 11:38
SLS2560
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
25
1
SM2540C
04/18/201614:25
PARMSTR
0.1
1
SM5310C/EPA9060A
04/14/201611:05
GHUTCHI

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
Site: AMW-3B
Collection Date: 12-Apr-16 1:10 PM
Analyte Result
TOTAL SUSPENDED SOLIDS
TSS < 5
Units Qualifiers RDL DF
mg/L 5 1
Page 10 of 67
Sample #: 2016010298
Matrix: GW_WW
Method Analysis Date/Time Analyst
SM2540D 04/15/201610:50 PARMSTR

Certificate of Laboratory Analysis Page 11 of 67
This report shall not be reproduced, except in full.
Order # J16040290
Site: MW-10
Collection Date: 12-Apr-16 1:33 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.104 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
12
mg/L
0.5
Sulfate
0.43
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.037
mg/L
0.005
Barium (Ba)
0.051
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.260
mg/L
0.01
Manganese (Mn)
0.241
mg/L
0.005
Strontium (Sr)
0.026
mg/L
0.005
Zinc (Zn)
0.034
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
2.30
mg/L
0.01
Magnesium (Mg)
2.58
mg/L
0.005
Potassium (K)
1.33
mg/L
0.1
Sodium (Na)
4.15
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.039
mg/L
0.005
Barium (Ba)
0.050
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.054
mg/L B2
0.01
Manganese (Mn)
0.142
mg/L
0.005
Strontium (Sr)
0.024
mg/L
0.005
Zinc (Zn)
0.014
mg/L
0.005
Sample #: 2016010299
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/14/2016 12:11 LSTARL1
Vendor Method V_PACE
5 EPA 300.0
04/15/2016 13:21
BGN9034
1 EPA 300.0
04/15/2016 13:21
BGN9034
1 EPA 245.1
04/18/2016 13:29
DMFRANC
1 EPA 245.1
04/18/2016 13:55
DMFRANC
1 EPA 200.7
04/14/2016 15:56
JJMACKE
1 EPA 200.7
04/14/2016 15:56
JJMACKE
1 EPA 200.7
04/14/2016 15:56
JJMACKE
1 EPA 200.7
04/14/2016 15:56
JJMACKE
1 EPA 200.7
04/14/2016 15:56
JJMACKE
1 EPA 200.7
04/14/2016 15:56
JJMACKE
1 EPA 200.7
04/14/2016 15:56
JJMACKE
1 EPA 200.7
04/14/2016 13:44
JJMACKE
1 EPA 200.7
04/14/2016 13:44
JJMACKE
1 EPA 200.7
04/14/2016 13:44
JJMACKE
1 EPA 200.7
04/14/2016 13:44
JJMACKE
1 EPA 200.7
04/14/2016 17:30
JJMACKE
1 EPA 200.7
04/14/2016 17:30
JJMACKE
1 EPA 200.7
04/14/2016 17:30
JJMACKE
1 EPA 200.7
04/14/2016 17:30
JJMACKE
1 EPA 200.7
04/14/2016 17:30
JJMACKE
1 EPA 200.7
04/14/2016 17:30
JJMACKE
1 EPA 200.7
04/14/2016 17:30
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
Site: MW-10
Collection Date: 12-Apr-16 1:33 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
2.99
ug/L
Copper (Cu)
13.8
ug/L
Lead (Pb)
1.92
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
2.89
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
2.12
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
2.44
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
46
mg/L
Total Carbon
TOC
0.595
mg/L
Page 12 of 67
Sample #:
2016010299
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/15/2016 13:25
JAHERMA
1
1
EPA 200.8
04/15/2016 13:25
JAHERMA
1
1
EPA 200.8
04/15/2016 13:25
JAHERMA
1
1
EPA 200.8
04/15/2016 13:25
JAHERMA
1
1
EPA 200.8
04/15/2016 13:25
JAHERMA
1
1
EPA 200.8
04/15/2016 13:25
JAHERMA
1
1
EPA 200.8
04/15/2016 13:25
JAHERMA
1
1
EPA 200.8
04/15/2016 13:25
JAHERMA
1
1
EPA 200.8
04/15/2016 13:25
JAHERMA
1
1
EPA 200.8
04/15/2016 13:25
JAHERMA
1
1
EPA 200.8
04/15/2016 13:25
JAHERMA
0.2
1
EPA 200.8
04/15/2016 13:25
JAHERMA
0.3
1
EPA 200.8
04/15/2016 13:25
JAHERMA
1
1
EPA 200.8
04/19/2016 12:07
SLS2560
1
1
EPA 200.8
04/19/2016 12:07
SLS2560
1
1
EPA 200.8
04/19/2016 12:07
SLS2560
1
1
EPA 200.8
04/19/2016 12:07
SLS2560
1
1
EPA 200.8
04/19/2016 12:07
SLS2560
1
1
EPA 200.8
04/19/2016 12:07
SLS2560
1
1
EPA 200.8
04/19/2016 12:07
SLS2560
1
1
EPA 200.8
04/19/2016 12:07
SLS2560
1
1
EPA 200.8
04/19/2016 12:07
SLS2560
1
1
EPA 200.8
04/19/2016 12:07
SLS2560
1
1
EPA 200.8
04/19/2016 12:07
SLS2560
0.2
1
EPA 200.8
04/19/2016 12:07
SLS2560
0.3
1
EPA 200.8
04/19/2016 12:07
SLS2560
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
25
1
SM2540C
04/18/201614:25
PARMSTR
0.1
1
SM5310C/EPA9060A
04/14/201611:05
GHUTCHI

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
Site: MW-10
Collection Date: 12-Apr-16 1:33 PM
Analyte Result
TOTAL SUSPENDED SOLIDS
TSS < 5
Units Qualifiers RDL DF
mg/L 5 1
Page 13 of 67
Sample #: 2016010299
Matrix: GW_WW
Method Analysis Date/Time Analyst
SM2540D 04/15/201610:50 PARMSTR

Certificate of Laboratory Analysis Page 14 of 67
This report shall not be reproduced, except in full.
Order # J16040290
Site: MW-21 D
Collection Date: 12-Apr-16 3:46 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
28
mg/L
0.5
Sulfate
34
mg/L
0.5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.019
mg/L
0.005
Barium (Ba)
0.043
mg/L
0.005
Boron (B)
0.082
mg/L
0.05
Iron (Fe)
1.63
mg/L
0.01
Manganese (Mn)
0.562
mg/L
0.005
Strontium (Sr)
0.073
mg/L
0.005
Zinc (Zn)
0.023
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
9.38
mg/L
0.01
Magnesium (Mg)
3.84
mg/L
0.005
Potassium (K)
1.40
mg/L
0.1
Sodium (Na)
15.0
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.024
mg/L
0.005
Barium (Ba)
0.045
mg/L
0.005
Boron (B)
0.079
mg/L
0.05
Iron (Fe)
1.98
mg/L B2
0.01
Manganese (Mn)
0.552
mg/L
0.005
Strontium (Sr)
0.072
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016010300
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/14/2016 12:13 LSTARL1
Vendor Method V_PACE
5 EPA 300.0
04/15/2016 11:52
BGN9034
5 EPA 300.0
04/15/2016 11:52
BGN9034
1 EPA 245.1
04/18/2016 13:41
DMFRANC
1 EPA 245.1
04/18/2016 14:07
DMFRANC
1 EPA 200.7
04/14/2016 16:08
JJMACKE
1 EPA 200.7
04/14/2016 16:08
JJMACKE
1 EPA 200.7
04/14/2016 16:08
JJMACKE
1 EPA 200.7
04/14/2016 16:08
JJMACKE
1 EPA 200.7
04/14/2016 16:08
JJMACKE
1 EPA 200.7
04/14/2016 16:08
JJMACKE
1 EPA 200.7
04/14/2016 16:08
JJMACKE
1 EPA 200.7
04/14/2016 13:48
JJMACKE
1 EPA 200.7
04/14/2016 13:48
JJMACKE
1 EPA 200.7
04/14/2016 13:48
JJMACKE
1 EPA 200.7
04/14/2016 13:48
JJMACKE
1 EPA 200.7
04/14/2016 17:34
JJMACKE
1 EPA 200.7
04/14/2016 17:34
JJMACKE
1 EPA 200.7
04/14/2016 17:34
JJMACKE
1 EPA 200.7
04/14/2016 17:34
JJMACKE
1 EPA 200.7
04/14/2016 17:34
JJMACKE
1 EPA 200.7
04/14/2016 17:34
JJMACKE
1 EPA 200.7
04/14/2016 17:34
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
Site: MW-21 D
Collection Date: 12-Apr-16 3:46 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
2.35
ug/L
Copper (Cu)
9.42
ug/L
Lead (Pb)
1.82
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
1.81
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
1.63
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
1.01
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
130
mg/L
Total Carbon
TOC
0.298
mg/L
Page 15 of 67
Sample #:
2016010300
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/15/2016 16:51
JAHERMA
1
1
EPA 200.8
04/15/2016 16:51
JAHERMA
1
1
EPA 200.8
04/15/2016 16:51
JAHERMA
1
1
EPA 200.8
04/15/2016 16:51
JAHERMA
1
1
EPA 200.8
04/15/2016 16:51
JAHERMA
1
1
EPA 200.8
04/15/2016 16:51
JAHERMA
1
1
EPA 200.8
04/15/2016 16:51
JAHERMA
1
1
EPA 200.8
04/15/2016 16:51
JAHERMA
1
1
EPA 200.8
04/15/2016 16:51
JAHERMA
1
1
EPA 200.8
04/15/2016 16:51
JAHERMA
1
1
EPA 200.8
04/15/2016 16:51
JAHERMA
0.2
1
EPA 200.8
04/15/2016 16:51
JAHERMA
0.3
1
EPA 200.8
04/15/2016 16:51
JAHERMA
1
1
EPA 200.8
04/19/2016 12:13
SLS2560
1
1
EPA 200.8
04/19/2016 12:13
SLS2560
1
1
EPA 200.8
04/19/2016 12:13
SLS2560
1
1
EPA 200.8
04/19/2016 12:13
SLS2560
1
1
EPA 200.8
04/19/2016 12:13
SLS2560
1
1
EPA 200.8
04/19/2016 12:13
SLS2560
1
1
EPA 200.8
04/19/2016 12:13
SLS2560
1
1
EPA 200.8
04/19/2016 12:13
SLS2560
1
1
EPA 200.8
04/19/2016 12:13
SLS2560
1
1
EPA 200.8
04/19/2016 12:13
SLS2560
1
1
EPA 200.8
04/19/2016 12:13
SLS2560
0.2
1
EPA 200.8
04/19/2016 12:13
SLS2560
0.3
1
EPA 200.8
04/19/2016 12:13
SLS2560
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
25
1
SM2540C
04/18/201614:25
PARMSTR
0.1
1
SM5310C/EPA9060A
04/14/201611:05
GHUTCHI

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
Site: MW-21 D
Collection Date: 12-Apr-16 3:46 PM
Analyte Result
TOTAL SUSPENDED SOLIDS
TSS < 5
Units Qualifiers RDL DF
mg/L 5 1
Page 16 of 67
Sample #: 2016010300
Matrix: GW_WW
Method Analysis Date/Time Analyst
SM2540D 04/15/201610:50 PARMSTR

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
Site: DUP
Collection Date: 12-Apr-16 10:18 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 1.2 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
15
mg/L
0.5
Sulfate
0.78
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.033
mg/L
0.005
Barium (Ba)
0.057
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.149
mg/L
0.005
Strontium (Sr)
0.040
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
3.07
mg/L
0.01
Magnesium (Mg)
3.68
mg/L
0.005
Potassium (K)
1.54
mg/L
0.1
Sodium (Na)
3.34
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.055
mg/L
0.005
Barium (Ba)
0.059
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.016
mg/L B2
0.01
Manganese (Mn)
0.153
mg/L
0.005
Strontium (Sr)
0.040
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016010301
Matrix: GW_WW
Page 17 of 67
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/14/2016 12:14 LSTARL1
Vendor Method V_PACE
5 EPA 300.0
04/15/2016 13:37
BGN9034
1 EPA 300.0
04/15/2016 13:37
BGN9034
1 EPA 245.1
04/18/2016 13:43
DMFRANC
1 EPA 245.1
04/18/2016 14:15
DMFRANC
1 EPA 200.7
04/14/2016 16:19
JJMACKE
1 EPA 200.7
04/14/2016 16:19
JJMACKE
1 EPA 200.7
04/14/2016 16:19
JJMACKE
1 EPA 200.7
04/14/2016 16:19
JJMACKE
1 EPA 200.7
04/14/2016 16:19
JJMACKE
1 EPA 200.7
04/14/2016 16:19
JJMACKE
1 EPA 200.7
04/14/2016 16:19
JJMACKE
1 EPA 200.7
04/14/2016 13:52
JJMACKE
1 EPA 200.7
04/14/2016 13:52
JJMACKE
1 EPA 200.7
04/14/2016 13:52
JJMACKE
1 EPA 200.7
04/14/2016 13:52
JJMACKE
1 EPA 200.7
04/14/2016 17:38
JJMACKE
1 EPA 200.7
04/14/2016 17:38
JJMACKE
1 EPA 200.7
04/14/2016 17:38
JJMACKE
1 EPA 200.7
04/14/2016 17:38
JJMACKE
1 EPA 200.7
04/14/2016 17:38
JJMACKE
1 EPA 200.7
04/14/2016 17:38
JJMACKE
1 EPA 200.7
04/14/2016 17:38
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
Site: DUP
Collection Date: 12-Apr-16 10:18 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
2.57
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
1.05
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
57
mg/L
Total Carbon
TOC
0.207
mg/L
Page 18 of 67
Sample #:
2016010301
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/15/2016 16:57
JAHERMA
1
1
EPA 200.8
04/15/2016 16:57
JAHERMA
1
1
EPA 200.8
04/15/2016 16:57
JAHERMA
1
1
EPA 200.8
04/15/2016 16:57
JAHERMA
1
1
EPA 200.8
04/15/2016 16:57
JAHERMA
1
1
EPA 200.8
04/15/2016 16:57
JAHERMA
1
1
EPA 200.8
04/15/2016 16:57
JAHERMA
1
1
EPA 200.8
04/15/2016 16:57
JAHERMA
1
1
EPA 200.8
04/15/2016 16:57
JAHERMA
1
1
EPA 200.8
04/15/2016 16:57
JAHERMA
1
1
EPA 200.8
04/15/2016 16:57
JAHERMA
0.2
1
EPA 200.8
04/15/2016 16:57
JAHERMA
0.3
1
EPA 200.8
04/15/2016 16:57
JAHERMA
1
1
EPA 200.8
04/19/2016 12:36
SLS2560
1
1
EPA 200.8
04/19/2016 12:36
SLS2560
1
1
EPA 200.8
04/19/2016 12:36
SLS2560
1
1
EPA 200.8
04/19/2016 12:36
SLS2560
1
1
EPA 200.8
04/19/2016 12:36
SLS2560
1
1
EPA 200.8
04/19/2016 12:36
SLS2560
1
1
EPA 200.8
04/19/2016 12:36
SLS2560
1
1
EPA 200.8
04/19/2016 12:36
SLS2560
1
1
EPA 200.8
04/19/2016 12:36
SLS2560
1
1
EPA 200.8
04/19/2016 12:36
SLS2560
1
1
EPA 200.8
04/19/2016 12:36
SLS2560
0.2
1
EPA 200.8
04/19/2016 12:36
SLS2560
0.3
1
EPA 200.8
04/19/2016 12:36
SLS2560
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
25
1
SM2540C
04/18/201614:25
PARMSTR
0.1
1
SM5310C/EPA9060A
04/14/201611:05
GHUTCHI

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
Site: DUP
Collection Date: 12-Apr-16 10:18 AM
Analyte Result
TOTAL SUSPENDED SOLIDS
TSS < 5
Units Qualifiers RDL DF
mg/L 5 1
Page 19 of 67
Sample #: 2016010301
Matrix: GW_WW
Method Analysis Date/Time Analyst
SM2540D 04/15/201610:50 PARMSTR

Certificate of Laboratory Analysis Page 20 of 67
This report shall not be reproduced, except in full.
Order # J16040290
Site: Equipment Blank
Collection Date: 12-Apr-16 5:00 PM
Analyte
Result
Units Qualifiers
RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
0.012
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L B2
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016010302
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2
04/14/2016 12:15
LSTARL1
1 EPA 300.0
04/15/2016 09:37
BGN9034
1 EPA 300.0
04/15/2016 09:37
BGN9034
1 EPA 245.1
04/18/2016 13:46
DMFRANC
1 EPA 245.1
04/18/2016 14:17
DMFRANC
1 EPA 200.7
04/14/2016 16:24
JJMACKE
1 EPA 200.7
04/14/2016 16:24
JJMACKE
1 EPA 200.7
04/14/2016 16:24
JJMACKE
1 EPA 200.7
04/14/2016 16:24
JJMACKE
1 EPA 200.7
04/14/2016 16:24
JJMACKE
1 EPA 200.7
04/14/2016 16:24
JJMACKE
1 EPA 200.7
04/14/2016 16:24
JJMACKE
1 EPA 200.7
04/14/2016 13:55
JJMACKE
1 EPA 200.7
04/14/2016 13:55
JJMACKE
1 EPA 200.7
04/14/2016 13:55
JJMACKE
1 EPA 200.7
04/14/2016 13:55
JJMACKE
1 EPA 200.7
04/14/2016 17:42
JJMACKE
1 EPA 200.7
04/14/2016 17:42
JJMACKE
1 EPA 200.7
04/14/2016 17:42
JJMACKE
1 EPA 200.7
04/14/2016 17:42
JJMACKE
1 EPA 200.7
04/14/2016 17:42
JJMACKE
1 EPA 200.7
04/14/2016 17:42
JJMACKE
1 EPA 200.7
04/14/2016 17:42
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
Site: Equipment Blank
Collection Date: 12-Apr-16 5:00 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
5.00
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Total Carbon
TOC
0.236
mg/L
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
Page 21 of 67
Sample #:
2016010302
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/15/2016 13:58
JAHERMA
1
1
EPA 200.8
04/15/2016 13:58
JAHERMA
1
1
EPA 200.8
04/15/2016 13:58
JAHERMA
1
1
EPA 200.8
04/15/2016 13:58
JAHERMA
1
1
EPA 200.8
04/15/2016 13:58
JAHERMA
1
1
EPA 200.8
04/15/2016 13:58
JAHERMA
1
1
EPA 200.8
04/15/2016 13:58
JAHERMA
1
1
EPA 200.8
04/15/2016 13:58
JAHERMA
1
1
EPA 200.8
04/15/2016 13:58
JAHERMA
1
1
EPA 200.8
04/15/2016 13:58
JAHERMA
1
1
EPA 200.8
04/15/2016 13:58
JAHERMA
0.2
1
EPA 200.8
04/15/2016 13:58
JAHERMA
0.3
1
EPA 200.8
04/15/2016 13:58
JAHERMA
1
1
EPA 200.8
04/19/2016 12:42
SLS2560
1
1
EPA 200.8
04/19/2016 12:42
SLS2560
1
1
EPA 200.8
04/19/2016 12:42
SLS2560
1
1
EPA 200.8
04/19/2016 12:42
SLS2560
1
1
EPA 200.8
04/19/2016 12:42
SLS2560
1
1
EPA 200.8
04/19/2016 12:42
SLS2560
1
1
EPA 200.8
04/19/2016 12:42
SLS2560
1
1
EPA 200.8
04/19/2016 12:42
SLS2560
1
1
EPA 200.8
04/19/2016 12:42
SLS2560
1
1
EPA 200.8
04/19/2016 12:42
SLS2560
1
1
EPA 200.8
04/19/2016 12:42
SLS2560
0.2
1
EPA 200.8
04/19/2016 12:42
SLS2560
0.3
1
EPA 200.8
04/19/2016 12:42
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
0.1 1 SM5310C/EPA9060A 04/14/201611:05 GHUTCHI
5 1 SM2540D 04/15/201610:50 PARMSTR
Qualifiers:

Certificate of Laboratory Analysis Page 22 of 67
This report shall not be reproduced, except in full.
Order # J16040290
B2 Target analyte was detected in blank(s) at a concentration greater than % the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.

® Laboratories LLc
0*0 40 0
a member of The GEL Group IN'.
P4 Box 30712 Charleston. SC 29417
2040 Sange Road Chad eston.SC29407
P 843 556.8171
F 843.76Gi.1178
gel.com
April 21, 2016
Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078
Re: AB GW Assessment Water
Work Order: 395205
SDG: J16040290
Dear Mary:
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on April 13, 2016. This original data report has been prepared and reviewed in accordance
with GEL's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.
Sincerely,
Lindsay Fabra
Project Manager
Purchase Order: 1142110 DPNNGO
Enclosures
Pa 11111111111111111111111111111111111111111111111111111111111111

Page 24 of 67
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
for
DUP0002 Duke Energy
Client SDG: J16040290 GEL Work Order: 395205
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the 'U' qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
Reviewed by
JU,&Y ,
Page 2 of 19

GEL LABORATORIES LLC Page 25 of 67
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016010294
395205001
Water
12-APR-16 08:30
13-APR-16
Client
Report Date: April 21, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-238 J 0.0000945
0.000067
0.0002
ug/mL
1
SKJ 04/19/16
1424 1559603 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1
SKJ 04/15/16
1434 1559603 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1
PRB 04/20/16
1557 1559603 3
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 2.37
1.53
3.00
pCi/L
AXM6 04/20/16
1506 1559959 4
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 0.891
0.427
1.00
pCi/L
LXP1 04/19/16
0830 1559634 5
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JP1
04/13/16
2100
1559601
The following Analytical Methods were performed:
Method Description Analyst Comments
I SW846 3010A/6020A
2 SW846 3010A/6020A
3 SW846 3010A/6020A
4 EPA 904.0/SW846 9320 Modified
5 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 102 (15%-125%)
Notes:
Page 3 of 19

GEL LABORATORIES LLC Page 26 of 67
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016010297
395205002
Water
12-APR-16 10:18
13-APR-16
Client
Report Date: April 21, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-238 J 0.000168
0.000067
0.0002
ug/mL
1
SKJ 04/19/16
1434 1559603 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1
SKJ 04/15/16
1443 1559603 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1
PRB 04/20/16
1609 1559603 3
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 U ND
2.15
3.00
pCi/L
AXM6 04/20/16
1506 1559959 4
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 1.76
0.518
1.00
pCi/L
LXP1 04/19/16
0830 1559634 5
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JP1
04/13/16
2100
1559601
The following Analytical Methods were performed:
Method Description Analyst Comments
I SW846 3010A/6020A
2 SW846 3010A/6020A
3 SW846 3010A/6020A
4 EPA 904.0/SW846 9320 Modified
5 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 92.9 (15%-125%)
Notes:
Page 4 of 19

GEL LABORATORIES LLC Page 27 of 67
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016010298
395205003
Water
12-APR-16 13:10
13-APR-16
Client
Report Date: April 21, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-238 U ND
0.000067
0.0002
ug/mL
1 SKJ 04/19/16
1435 1559603 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1 SKJ 04/15/16
1444 1559603 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1 PRB 04/20/16
1610 1559603 3
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 U ND
1.23
3.00
pCi/L
AXM6 04/20/16
1506 1559959 4
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 7.41
0.441
1.00
pCi/L
LXP1 04/19/16
0900 1559634 5
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JP1
04/13/16
2100 1559601
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 SW846 3010A/6020A
4 EPA 904.0/SW846 9320 Modified
5 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 98.6 (15%-125%)
Notes:
Page 5 of 19

GEL LABORATORIES LLC Page 28 of 67
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016010299
395205004
Water
12-APR-16 13:33
13-APR-16
Client
Report Date: April 21, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-238 U ND
0.000067
0.0002
ug/mL
1 SKJ 04/19/16
1437 1559603 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1 SKJ 04/15/16
1446 1559603 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1 PRB 04/20/16
1612 1559603 3
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 U ND
1.26
3.00
pCi/L
AXM6 04/20/16
1506 1559959 4
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 1.17
0.439
1.00
pCi/L
LXP1 04/19/16
0900 1559634 5
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JP1
04/13/16
2100 1559601
The following Analytical Methods were performed:
Method Description
Analyst Comments
I SW846 3010A/6020A
2 SW846 3010A/6020A
3 SW846 3010A/6020A
4 EPA 904.0/SW846 9320 Modified
5 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 100 (15%-125%)
Notes:
Page 6of19

GEL LABORATORIES LLC Page 29 of 67
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016010300
395205005
Water
12-APR-16 15:46
13-APR-16
Client
Report Date: April 21, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-238 U ND
0.000067
0.0002
ug/mL
1 SKJ 04/19/16
1438 1559603 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1 SKJ 04/15/16
1448 1559603 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1 PRB 04/20/16
1614 1559603 3
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 2.63
2.24
3.00
pCi/L
AXM6 04/20/16
1506 1559959 4
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 2.35
0.535
1.00
pCi/L
LXP1 04/19/16
0900 1559634 5
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JP1
04/13/16
2100 1559601
The following Analytical Methods were performed:
Method Description
Analyst Comments
I SW846 3010A/6020A
2 SW846 3010A/6020A
3 SW846 3010A/6020A
4 EPA 904.0/SW846 9320 Modified
5 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 98.5 (15%-125%)
Notes:
Page 7 of 19

GEL LABORATORIES LLC Page 30 of 67
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016010301
395205006
Water
12-APR-16 10:18
13-APR-16
Client
Report Date: April 21, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-238 U ND
0.000067
0.0002
ug/mL
1 SKJ 04/19/16
1440 1559603 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1 SKJ 04/15/16
1449 1559603 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1 PRB 04/20/16
1615 1559603 3
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 3.42
1.75
3.00
pCi/L
AXM6 04/20/16
1506 1559959 4
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 2.54
0.446
1.00
pCi/L
LXP1 04/19/16
0900 1559634 5
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JP1
04/13/16
2100 1559601
The following Analytical Methods were performed:
Method Description
Analyst Comments
I SW846 3010A/6020A
2 SW846 3010A/6020A
3 SW846 3010A/6020A
4 EPA 904.0/SW846 9320 Modified
5 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 99.7 (15%-125%)
Notes:
Page 8 of 19

Page 31 of 67
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina
Contact: Mary Ann Ogle
Workorder: 395205
Report Date: April 21, 2016
Page 1 of 3
Parmname
NOM
Sample
Qual
QC
Units
RPD%o
REC%
Range
Anlst
Date Time
Metals Analysis - ICPMS
Batch 1559603
QC1203527741
395205001
DUP
Uranium-233
U
ND
U
ND
ug/mL
N/A
SKJ
04/15/1614:35
Uranium-234
U
ND
U
ND
ug/mL
N/A
Uranium-236
U
ND
U
ND
ug/mL
N/A
PRB
04/20/1615:58
Uranium-238
J
0.0000945
U
ND
ug/mL
200 ^
SKJ
04/19/1614:25
QC1203527740
LCS
Uranium-238
0.0496
0.0529
ug/mL
107
(80%-120%)
04/19/1614:22
QC1203527778
LCS
Uranium-233
0.0005
0.000504
ug/mL
101
(80%-120%)
04/15/1614:32
Uranium-234
0.00055
0.00057
ug/mL
104
(80%-120%)
Uranium-236
0.005
0.00473
ug/mL
94.5
(80%-120%)
PRB
04/20/1615:55
QC1203527739
MB
Uranium-233
U
ND
ug/mL
SKJ
04/15/1614:31
Uranium-234
U
ND
ug/mL
Uranium-236
U
ND
ug/mL
PRB
04/20/1615:53
Uranium-238
U
ND
ug/mL
SKJ
04/19/1614:21
QC1203527742
395205001
MS
Uranium-238
0.0496
J
0.0000945
0.0527
ug/mL
106
(75%-125%)
04/19/1614:27
QC1203527779
395205001
MS
Uranium-233
0.0005
U
ND
0.000483
ug/mL
96.6
(75%-125%)
04/15/1614:37
Uranium-234
0.00055
U
ND
0.000553
ug/mL
101
(75%-125%)
Uranium-236
0.005
U
ND
0.00483
ug/mL
96.5
(75%-125%)
PRB
04/20/1616:00
QC1203527743
395205001
SDILT
Uranium-233
U
ND
U
ND
ug/L
N/A
SKJ
04/15/1614:38
Page 9 of 19

Page 32 of 67
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 395205
Page 2 of 3
Parmname
NOM Sample
Qual
QC
Units
RPD%
REC% Range Anlst
Date Time
Metals Analysis - ICPMS
Batch 1559603
Uranium-234
U ND
U
ND
ug/L
N/A
Uranium-236
U ND
U
ND
ug/L
N/A
(0%-10%) PRB
04/20/1616:02
Uranium-238
J 0.0945
U
ND
ug/L
N/A
(0%-10%) SKJ
04/19/1614:28
Rad Gas Flow
Batch 1559959
QC1203528625 395205006 DUP
Radium-228
3.42
1.68
pCi/L
68.5
(0% - 100%) AXM6
04/20/16 15:09
QC1203528626 LCS
Radium-228
93.0
84.0
pCi/L
90.3 (75%-125%)
04/20/1615:06
QC1203528624 MB
Radium-228
U
0.413
pCi/L
04/20/1615:09
Rad Ra-226
Batch 1559634
QC1203527795 395096001 DUP
Radium-226 0.747
0.908 pCi/L 19.6
(0% - 100%) LXP1 04/19/16 09:00
QC1203527797 LCS
Radium-226 24.4
30.4 pCi/L
125 (75%-125%) 04/19/16 09:30
QC1203527794 MB
Radium-226 U
0.319 pCi/L
04/19/16 09:00
QC1203527796 395096001 MS
Radium-226 122 0.747
128 pCi/L
104 (75%-125%) 04/19/16 09:30
Notes:
The Qualifiers in this report are defined as follows:
** Analyte is a Tracer compound
< Result is less than value reported
> Result is greater than value reported
BD Results are either below the MDC or tracer recovery is low
E %difference of sample and SD is >10%. Sample concentration must meet flagging criteria
FA Failed analysis.
FB Mercury was found present at quantifiable concentrations in field blanks received with these samples.
Data associated with the blank are deemed
invalid for reporting to regulatory agencies
H Analytical holding time was exceeded
Page 10 of 19

Page 33 of 67
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 395205
Parmname NOM Sample Qual QC Units RPD% REC'% Range Anlst
J Value is estimated
K Analyte present. Reported value may be biased high. Actual value is expected to be lower.
L Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M M if above MDC and less than LLD
M REMP Result > MDC/CL and < RDL
N Metals --The Matrix spike sample recovery is not within specified control limits
N/A RPD or %Recovery limits do not apply.
N1 See case narrative
ND Analyte concentration is not detected above the detection limit
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
R Sample results are rejected
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
UI Gamma Spectroscopy --Uncertain identification
UJ Gamma Spectroscopy --Uncertain identification
UL Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Y Other specific qualifiers were required to properly define the results. Consult case narrative.
^ RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
h Preparation or preservation holding time was exceeded
Page 3 of 3
Date Time
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
Page 11 of 19

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Page 12 of 19

LaboratodeS LLC
Page 35 of 67
xeceive(i By:
Suspected Hazard Information 0
COC/Samples marked as radioactive? J
Classified Radioactive II or III by RSO? /
COC/Samples marked containing W-110
raclsaget COC,- andlor Samliles mai`ked as
berylhum'or asbestos contammg?'r
Shipped as a DOT Hazardous?
Sam les identified as Foreig n Soil?
Sample Receipt Criteria
1 Shipping containers received intact and
sealed?
2 Samples requiring cold preservation
within (0 g 6 deg. C)?*
2a Daily check performed and passed on IR
temperature gun? ;
3 Chain of custody documents included
with shipment?
4 Sample containers intact and sealed?
5 Samples requiring chemical preservation
at proper pH?
6 Do Low Level Perchlorate samples have
heads ace as required?
7 VOA vials contain acid preservation?
8 VOA vials free of headspace (defined as
< 6mm bubble)?
9 Are Encore containers present?
14 Samples received within holding time?
11 Sample ID's on COC match ID's on
bottles?
12 Date & time on COC match date & time
on bottles?
13 Number of containers received match
number indicated on COC?
14 Are sample containers identifiable as
GELprovided?
15 COC form is properly signed in
16 (Carrier and tracking number.
Continuation Form if
JAlVIFLE RECEIPT & REVIEW FORM
)G/AR/COC/Work Order: r 5
ate Received:
f Net Counts > IAOcpm on samples not marked "radioactive", contact the Radiation Safety Group for further
vestigation.
aximum Net Counts Observed* (Observed Counts - Area Background Counts):
yes, Were swipes taken of sample containers < action levels?
yes',samples aze to be,segregated as Safe`ty`.Controlleii`SariSples and"apened6ytlte GEG`Safety Groiip
tzard Class Shipped. UN#:
Comments/Qualifiers (Required for Non -Conforming Items)
le Applicable: Seals broken Damaged container Leaking container Other (describe)
ervation Method: Ice bags Blue ice Dry ice otie Other (describe)
temperatures are recorded in Celsius {�
perature Device Serial #.
mdary Temperature Device Serial # (If Applicable):
ctc AppucaDle: Seals broken Damaged container Leaking
nple ID's, containers affected and observed pH:
>res .rvatinn added [ nt#•
npte ID s and containers affected:
unknown, select No)
nple [Us and containers affected -
yes, immediately deliver to Voladles
s and tests affected:
70e 0s and containers aft en i.
FedEx Air FedEx Ground UPS Field Services ( Courier ) Other
PM (or PMA) review:
Page 13 of 19
Date — Page -- L of _ _ -
GL-CHL-SR-001 Rev 3

Page 36 of 67
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Page 14 of 19

Laboratories LLc
Page 37 of 67
SAMPLE RECEIPT & REVIEW FORM
Client
DG/AR/COC/Work Order:
Received B � ` r` =a
y' "'
Date Received: 9 (
Suspected Hazard Information
o
z
If Net Counts > 100cpm on samples not marked "radioactive", contact the Radiation Safety Group for further
investigation,
COC/Samples marked as radioactive?
Classified Radioactive 11 or III by RSO?
vlaximum Net Counts Observed* (Observed Counts - Area Background Counts): c
yes, Were swipes taken of sample containers
COC/Samples marked containing PCBs?
< action levels?
Package, COC, andlor Sampies.inaked as ;;
-.
beryllium'or asliesfos cgntatnuig?, -=
Shipped as a DOT Hazardous?
yes xam' les are to be•se" gated is;Seety:CStiirolled:Sani tes and"opened li32he GEL;Safety Gioa'
fazard Class Shipped:
Samples identified as Forei n Soil?
UN#:
1 .
Sample Receipt Criteria
Zl -e
z
I Ze Comments/Quailfiers (Required for Non -Conforming Items)
I Shipping containers received intact and
sealed?
Circle Applicable Seals broken Damaged container ! etddng container Outer (describe)
2 Samples requiring cold preservation
I Preservation Method: Ice bags Blue ice Dry ice one Other (describe)
within (0 < 6 deg. C)?*
*all temperatures are recorded in Celsius
2a Daily check performed and passed on IR
Tempemmre Device Serial H:
temperature gun?
Chain
Secondary Temperature Device Serial #t (If Applicable): (-
of custody documents included
3
/
�"
with shipment?
I
Circle Applicable Seals broken Damaged container L caking container Other (describe)
Santpie If}'s, containers affected and observed pH:
4
Sample containers intact and sealed?
5
Samples requiring chemical preservation
at proper pH?
6Do
Low Level Perchlorate samples have
Sample ID's and containers affected:
heads ace as required?
7
VOA vials contain acid preservation?
( (If unknown, select No)
Sample tD's and containers affected:
8
VOA vials free of headspace (defined as
< 6rnm bubble)?
9
Are Encore containers present?
Of ycs, immediately deliver to Voladles laboratory)
14
Samples received within holding time?
( ID's and tests affected;
Sample ID's and containers affected:
I I
Sample ID's on COC match ID's on
bottles?
Sample ID's affected:
12
Date & time on COC match date & time
on bottles?
13
Number of containers received match
Sample ID's affected:
number indicated on COC?
I
14
Are sample containers identifiable as
GEL rovided?
15
COC form is property;. signed in
relinquished/received!sections?
'
Circle Applicable:
FedEx Air FedEx Ground UPS Field Services Courier Other
PM (or PMA) review: Initials Date
GL-CHL-SR-001 Rev 3
Page 15 of 19

Page 38 of 67
Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16040290
Work Order #: 395205
Metals
Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1559603
Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1559601
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
395205001
395205002
395205003
395205004
395205005
395205006
Client Sample Identification
2016010294
2016010297
2016010298
2016010299
2016010300
2016010301
1203527739
Method Blank (MB)ICP-MS
1203527740
Laboratory Control Sample (LCS)
1203527778
Laboratory Control Sample (LCS)
1203527743
395205001(2016010294L) Serial Dilution (SD)
1203527741
395205001(2016010294D) Sample Duplicate (DUP)
1203527742
395205001(2016010294S) Matrix Spike (MS)
1203527779
395205001(2016010294S) Matrix Spike (MS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.
Radiochemistry
Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1559959
Page 16 of 19

Page 39 of 67
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
Client Sample Identification
395205001
2016010294
395205002
2016010297
395205003
2016010298
395205004
2016010299
395205005
2016010300
395205006 2016010301
1203528624 Method Blank (MB)
1203528625 395205006(2016010301) Sample Duplicate (DUP)
1203528626 Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.
Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1559634
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
Client Sample Identification
395205001
2016010294
395205002
2016010297
395205003
2016010298
395205004
2016010299
395205005
2016010300
395205006
2016010301
1203527794
Method Blank (MB)
1203527795
395096001(2016010154) Sample Duplicate (DUP)
1203527796
395096001(2016010154) Matrix Spike (MS)
1203527797
Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary•
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Miscellaneous Information
Page 17 of 19

Page 40 of 67
Additional Comments
The matrix spike, 1203527796 (2016010154MS), aliquot was reduced to conserve sample volume.
Certification Statement
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 18 of 19

Page 41 of 67
List of current GEL Certifications as of 21 April 2016
State
Certification
Alaska
UST-0110
Arkansas
88-0651
CLIA
42D0904046
California
2940
Colorado
SC00012
Connecticut
PH-0169
Delaware
SC00012
DoD ELAP/ ISO17025 A2LA
2567.01
Florida NELAP
E87156
Foreign Soils Permit
P330-15-00283, P330-15-00253
Georgia
SC00012
Georgia SDWA
967
Hawaii
SC00012
Idaho Chemistry
SC00012
Idaho Radiochemistry
SC00012
Illinois NELAP
200029
Indiana
C—SC-01
Kansas NELAP
E-10332
Kentucky SDWA
90129
Kentucky Wastewater
90129
Louisiana NELAP
03046 (A133904)
Louisiana SDWA
LA160006
Maryland
270
Massachusetts
M—SC012
Michigan
9976
Mississippi
SC00012
Nebraska
NE—OS-26-13
Nevada
SC000122016-1
New Hampshire NELAP
205415
New Jersey NELAP
SC002
New Mexico
SC00012
New York NELAP
11501
North Carolina
233
North Carolina SDWA
45709
North Dakota
R-158
Oklahoma
9904
Pennsylvania NELAP
68-00485
S.Carolina Radchem
10120002
South Carolina Chemistry
10120001
Tennessee
TN 02934
Texas NELAP
T104704235-16-11
Utah NELAP
SC000122016-20
Vermont
VT87156
Virginia NELAP
460202
Washington
C780
West Virginia
997404
Page 19 of 19

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onfree. Suite 100
Huntersville, INC 28078
[phone]
April 20, 2016
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 16040290
Pace Project No.: 92293592
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 13, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Vials received with no headspace, liquid poured off before analysis.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy Anne Pifer
Mary Ann Ogle, Duke Energy Rodney Wilke, Duke Energy
pQ PIC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
!q �y without the written consent of Pace Analytical Services, Inc.. Page 1 of 25
ep -ATQ/

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
OQ9Wiinfifte. Suite 100
Huntersville, NC 28078
[phone]
Project: J16040290
Pace Project No.: 92293592
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A21-A Certification M 2926.01
Alaska Certification M UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification M 88-0680
California Certification M 01155CA
Colorado Certification #Pace
Connecticut Certification M PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification M 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification M 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification M 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification M 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification M E83079
Georgia Certification M 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification M 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification M E-10383
Louisiana Certification M FL NELAC Reciprocity
Louisiana Environmental Certificate M 05007
Maryland Certification: #346
Michigan Certification M 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification M Cert 0074
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE SUMMARY
Project: J16040290
Pace Project No.: 92293592
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92293592001
2016010294
Water
04/12/16 08:30
04/13/16 10:30
92293592002
2016010297
Water
04/12/1610:18
04/13/1610:30
92293592003
2016010298
Water
04/12/1613:10
04/13/1610:30
92293592004
2016010299
Water
04/12/1613:33
04/13/1610:30
92293592005
2016010300
Water
04/12/1615:46
04/13/1610:30
92293592006
2016010301
Water
04/12/1610:18
04/13/1610:30
92293592007
2016010302
Water
04/12/1617:00
04/13/1610:30
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16040290
92293592
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92293592001
2016010294
RSK 175
DR1
1
PASI-M
92293592002
2016010297
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92293592003
2016010298
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92293592004
2016010299
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92293592005
2016010300
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92293592006
2016010301
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92293592007
2016010302
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
REPORT OF LABORATORY ANALYSIS
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Project: J16040290
Pace Project No.: 92293592
Lab Sample ID
Method
92293592002
SM 2320B
SM 2320B
EPA 218.7
92293592003
SM 2320B
SM 2320B
EPA 218.7
92293592004
RSK 175
SM 2320B
SM 2320B
EPA 218.7
92293592006
SM 2320B
SM 2320B
EPA 218.7
SUMMARY OF DETECTION
Client Sample ID
Parameters
2016010297
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
Chromium, Hexavalent
2016010298
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
Chromium, Hexavalent
2016010299
Methane
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
Chromium, Hexavalent
2016010301
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
Chromium, Hexavalent
Result
Units
15.8
mg/L
15.8
mg/L
0.26
ug/L
33.1
mg/L
33.1
mg/L
0.18
ug/L
32.7
ug/L
10.8
mg/L
10.8
mg/L
0.12
ug/L
6.4
mg/L
6.4
mg/L
0.26
ug/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Report Limit Analyzed Qualifiers
5.0 04/16/1610:10
5.0 04/16/1610:10
0.030 04/15/1619:35
5.0 04/16/1610:20
5.0 04/16/1610:20
0.030 04/15/1619:48
10.0
04/15/1616:37
5.0
04/16/1610:46
5.0
04/16/1610:46
0.030
04/15/16 20:01
5.0 04/16/1611:14
5.0 04/16/1611:14
0.030 04/15/16 20:27
Page 5 of 25

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PROJECT NARRATIVE
Project: J16040290
Pace Project No.: 92293592
Method: RSK 175
Description: RSK 175 AIR Headspace
Client: Duke Energy
Date: April 20, 2016
General Information:
7 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16040290
Pace Project No.: 92293592
Method: SM 2320B
Description: 2320E Alkalinity
Client: Duke Energy
Date: April 20, 2016
General Information:
6 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16040290
Pace Project No.: 92293592
Method: SM 4500-S213
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: April 20, 2016
General Information:
6 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16040290
Pace Project No.: 92293592
Method: EPA 218.7
Description: Hexavalent Chromium by IC
Client: Duke Energy
Date: April 20, 2016
General Information:
5 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16040290
Pace Project No.: 92293592
Sample: 2016010294 Lab ID: 92293592001 Collected: 04/12/16 08:30 Received: 04/13/16 10:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 AIR Headspace Analytical Method: RSK 175
Methane ND ug/L 10.0 1 04/15/1616:05 74-82-8
Date: 04/20/2016 11:21 AM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16040290
Pace Project No.: 92293592
Sample: 2016010297
Lab ID: 92293592002 Collected:
04/12/16 10:18
Received: 04/13/16 10:30 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/15/1616:21
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
15.8 mg/L
5.0
1
04/16/16 10:10
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/16/16 10:10
Alkalinity, Total as CaCO3
15.8 mg/L
5.0
1
04/16/16 10:10
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/19/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.26 ug/L
0.030
1
04/15/16 19:35
18540-29-9
Date: 04/20/2016 11:21 AM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16040290
Pace Project No.: 92293592
Sample: 2016010298
Lab ID: 92293592003 Collected:
04/12/16 13:10
Received: 04/13/16 10:30 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/15/1616:29
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
33.1 mg/L
5.0
1
04/16/16 10:20
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/16/16 10:20
Alkalinity, Total as CaCO3
33.1 mg/L
5.0
1
04/16/16 10:20
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/19/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.18 ug/L
0.030
1
04/15/16 19:48
18540-29-9
Date: 04/20/2016 11:21 AM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16040290
Pace Project No.: 92293592
Sample: 2016010299
Lab ID: 92293592004 Collected:
04/12/16 13:33
Received: 04/13/16 10:30 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
32.7 ug/L
10.0
1
04/15/1616:37
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
10.8 mg/L
5.0
1
04/16/16 10:46
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/16/16 10:46
Alkalinity, Total as CaCO3
10.8 mg/L
5.0
1
04/16/16 10:46
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/19/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.12 ug/L
0.030
1
04/15/16 20:01
18540-29-9
Date: 04/20/2016 11:21 AM
REPORT OF LABORATORY ANALYSIS
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Page 13 of 25

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ANALYTICAL RESULTS
Project: J16040290
Pace Project No.: 92293592
Sample: 2016010300
Lab ID: 92293592005 Collected:
04/12/16 15:46
Received: 04/13/16 10:30 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/15/1616:45
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
04/16/16 11:00
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/16/16 11:00
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
04/16/16 11:00
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/19/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
04/15/16 20:14
18540-29-9
Date: 04/20/2016 11:21 AM
REPORT OF LABORATORY ANALYSIS
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Page 14 of 25

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ANALYTICAL RESULTS
Project: J16040290
Pace Project No.: 92293592
Sample: 2016010301
Lab ID: 92293592006 Collected:
04/12/16 10:18
Received: 04/13/16 10:30 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/15/1616:54
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
6.4 mg/L
5.0
1
04/16/16 11:14
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/16/16 11:14
Alkalinity, Total as CaCO3
6.4 mg/L
5.0
1
04/16/16 11:14
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/19/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.26 ug/L
0.030
1
04/15/16 20:27
18540-29-9
Date: 04/20/2016 11:21 AM
REPORT OF LABORATORY ANALYSIS
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Page 15 of 25

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ANALYTICAL RESULTS
Project: J16040290
Pace Project No.: 92293592
Sample: 2016010302
Lab ID: 92293592007 Collected:
04/12/16 17:00
Received: 04/13/16 10:30 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/15/1617:02 74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
04/17/16 12:16
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/17/16 12:16
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
04/17/16 12:16
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/19/1611:30 18496-25-8
Date: 04/20/2016 11:21 AM
REPORT OF LABORATORY ANALYSIS
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Page 16 of 25

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QUALITY CONTROL DATA
Project: J16040290
Pace Project No.: 92293592
QC Batch: AIR/25707
Analysis Method: RSK 175
QC Batch Method: RSK 175
Analysis Description: RSK 175 AIR HEADSPACE
Associated Lab Samples: 92293592001,92293592002,92293592003,92293592004,92293592005,92293592006,92293592007
METHOD BLANK: 2232579
Matrix: Water
Associated Lab Samples: 92293592001,
92293592002,
92293592003, 92293592004, 92293592005, 92293592006, 92293592007
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Methane
ug/L
ND 10.0 04/15/1614:18
LABORATORY CONTROL SAMPLE &
LCSD: 2232580
2232581
Spike LCS LCSD LCS LCSD
% Rec Max
Parameter
Units
Conc. Result Result % Rec % Rec
Limits RPD RPD Qualifiers
Methane
ug/L
60.7 59.6 58.0 98 96
85-115 3 20
SAMPLE DUPLICATE: 2234671
10344553008 Dup
Max
Parameter
Units
Result Result RPD
RPD Qualifiers
Methane
ug/L
ND 1.7J
20
SAMPLE DUPLICATE: 2234672
92293592001 Dup
Max
Parameter
Units
Result Result RPD
RPD Qualifiers
Methane
ug/L
ND 4.8J
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/20/2016 11:21 AM without the written consent of Pace Analytical Services, Inc.. Page 17 of 25

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QUALITY CONTROL DATA
Project: J16040290
Pace Project No.: 92293592
QC Batch: WET/44279 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92293592002, 92293592003, 92293592004, 92293592005, 92293592006
METHOD BLANK: 1711312
Matrix: Water
Associated Lab Samples: 92293592002, 92293592003, 92293592004, 92293592005, 92293592006
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Alkalinity, Carbonate (CaCO3)
mg/L
ND 5.0
04/15/16 23:44
Alkalinity, Total as CaCO3
mg/L
ND 5.0
04/15/16 23:44
Alkalinity, Bicarbonate (CaCO3)
mg/L
ND 5.0
04/15/16 23:44
LABORATORY CONTROL SAMPLE: 1711313
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 50.1 100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1711314 1711315
MS MSD
92293530004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L ND 50 50 44.8 45.3 90 91 80-120 1 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1711316 1711317
MS MSD
92293539005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Alkalinity, Total as CaCO3 mg/L 14.4 50 50 64.3 64.7 100 101 80-120 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 11:21 AM without the written consent of Pace Analytical Services, Inc..
Page 18 of 25

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098on roe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040290
Pace Project No.: 92293592
QC Batch: WET/44287 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92293592007
METHOD BLANK: 1711827
Associated Lab Samples: 92293592007
Parameter Units
Alkalinity, Carbonate (CaCO3) mg/L
Alkalinity, Total as CaCO3 mg/L
Alkalinity, Bicarbonate (CaCO3) mg/L
LABORATORY CONTROL SAMPLE: 1711828
Parameter Units
Alkalinity, Total as CaCO3 mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 5.0 04/17/1611:55
ND 5.0 04/17/1611:55
ND 5.0 04/17/1611:55
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
50 49.2 98 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1711829 1711830
MS MSD
92293592007 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L ND 50 50 48.6 48.6 97 97 80-120 0 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1711831 1711832
MS MSD
92293750005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Alkalinity, Total as CaCO3 mg/L ND 50 50 48.7 48.9 97 98 80-120 0 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 11:21 AM without the written consent of Pace Analytical Services, Inc..
Page 19 of 25

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinlc&roe. Suite100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040290
Pace Project No.: 92293592
QC Batch: WET/44329
Analysis Method: SM 4500-S2D
QC Batch Method: SM 4500-S2D
Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92293592002, 92293592003,
92293592004, 92293592005, 92293592006, 92293592007
METHOD BLANK: 1713758
Matrix: Water
Associated Lab Samples: 92293592002, 92293592003,
92293592004, 92293592005, 92293592006, 92293592007
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Sulfide mg/L
ND 0.10 04/19/1611:30
LABORATORY CONTROL SAMPLE: 1713759
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Sulfide mg/L
.5 0.53 106 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1713760 1713761
MS MSD
92293519001
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND
.5 .5 0.52 0.52 104 104 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1713762 1713763
MS MSD
92293592006 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.52 0.52 104 104 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 11:21 AM without the written consent of Pace Analytical Services, Inc..
Page 20 of 25

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098on roe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040290
Pace Project No.: 92293592
QC Batch: WETA/56904
Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7
Analysis Description: Chromium, Hexavalent IC
Associated Lab Samples: 92293592002, 92293592003,
92293592004, 92293592005, 92293592006
METHOD BLANK: 1543057
Matrix: Water
Associated Lab Samples: 92293592002, 92293592003,
92293592004, 92293592005, 92293592006
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Chromium, Hexavalent ug/L
ND 0.030 04/15/16 17:51
LABORATORY CONTROL SAMPLE: 1543058
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Chromium, Hexavalent ug/L
.075 0.074 98 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1543059 1543060
MS MSD
92293516003
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L 0.061
.025 .025 0.083 0.086 91 103 85-115 4 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 11:21 AM without the written consent of Pace Analytical Services, Inc..
Page 21 of 25

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098on roe. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J16040290
Pace Project No.: 92293592
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-M Pace Analytical Services - Minneapolis
PASI-O Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 11:21 AM without the written consent of Pace Analytical Services, Inc.. Page 22 of 25

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098mc&roe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16040290
Pace Project No.: 92293592
Lab ID Sample ID QC Batch Method QC Batch
92293592001
2016010294
RSK 175
AIR/25707
92293592002
2016010297
RSK 175
AIR/25707
92293592003
2016010298
RSK 175
AIR/25707
92293592004
2016010299
RSK 175
AIR/25707
92293592005
2016010300
RSK 175
AIR/25707
92293592006
2016010301
RSK 175
AIR/25707
92293592007
2016010302
RSK 175
AIR/25707
92293592002
2016010297
SM 2320B
WET/44279
92293592003
2016010298
SM 2320B
WET/44279
92293592004
2016010299
SM 2320B
WET/44279
92293592005
2016010300
SM 2320B
WET/44279
92293592006
2016010301
SM 2320B
WET/44279
92293592007
2016010302
SM 2320B
WET/44287
92293592002
2016010297
SM 4500-S2D
WET/44329
92293592003
2016010298
SM 4500-S2D
WET/44329
92293592004
2016010299
SM 4500-S2D
WET/44329
92293592005
2016010300
SM 4500-S2D
WET/44329
92293592006
2016010301
SM 4500-S2D
WET/44329
92293592007
2016010302
SM 4500-S2D
WET/44329
92293592002
2016010297
EPA 218.7
WETA/56904
92293592003
2016010298
EPA 218.7
WETA/56904
92293592004
2016010299
EPA 218.7
WETA/56904
92293592005
2016010300
EPA 218.7
WETA/56904
92293592006
2016010301
EPA 218.7
WETA/56904
Date: 04/20/2016 11:21 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 23 of 25

Document Name:
Document Revised: 18FE82016
aceRnalyticalo
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority: age 00 o
F-CHR-CS-003-rev.18
Pace Huntersville Quality Office
Sample Condition UponClient Name: WQ 9�Ie'�:�592
Receipt Project
Courier: ❑Fed Ex ❑UPS ❑LISPS OaCilent
❑ Commercial ❑Pace ❑Other: 972931392
Custody Sea[ Present? ❑Yes [ANo Seals Intact? ❑Yes Wo
Date/In[tials Person Examining Contents:"3 11,6
Packing Material: []Bubble Wrap [Bubble Bags ❑None [—]Other:
-
Thermometer: t� T1505 d Type of Ice: 19Wet []131ue [-]None ❑Samples on Ice, cooling process has begun
Correction Factor: O.0°C Cooler Temp Corrected (°C): 0 C. Biological Tissue Frozen? ❑Yes XNo ❑N/A
Temp should be above freezing to 6°C
USDA Regulated Soil ( 0 N/A, water sample)
Did samples originate In a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (Internationally,
❑Yes ®No including Hawaii and Puerto Rlco)? []Yes NNo
COMMENTS:
Chain of Custody Present?
❑Yes
[]NO
❑N/A
1.
Chain of Custody Filled Out?
Yes
[:]No
❑N/A
2.
Chain of Custody Relinquished?
Yes
❑No
❑N/A
3.
Sampler Name and/or Signature on COC?
[:]Yes
No
❑N/A
4.
Samples Arrived within Hold Time?
QNYes
[:]No
EJN/A
S.
Short Hold Time Analysis (02 hr.)?
❑Yes
RNo
❑N/A
6.
Rush Turn Around Time Requested?
[:]Yes
MNo
❑N/A
7.
Sufficient Volume?
pyes
[]No
❑N/A
8.
Correct Containers Used?
j QYes
[]No
❑N/A
9.
-Pace Containers Used?
Yes
No
[]N/A
Containers Intact?
pyes
©No
ON/A
10.
Filtered Volume Received for Dissolved Tests?
❑Yes
No
❑N/A
11. Note if sediment is visible in the dissolved container
Sample Labels Match COC? (pYes
❑No
ON/A
12.
-includes Date/Time/ID/Analysis Matrix: Iui ou_
All containers needing acid/base preservation have been
13
checked?
(PYes
❑No
❑N/A
All.containers needing preservation are found to be in
compliance with EPA recommendation?
(HNO3i HZSO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide)
Yes
❑No
❑N/A
Exceptions: VOA, Coliform, TOC, Oil and Grease,
DRO/8015 (water) DOC,LLHg
❑Yes
jANo
(]N/A
Samples checked for dechlorination
❑Yes
®No
(]N/A
14.
Headspace in VOA Vials (>5-6mm)?
[]Yes
®No
ON/A
15.
Trip Blank Present?
❑Yes
PNo
[]N/A
16.
Trip Blank Custody Seals Present?
❑Yes
®No
[]N/A
Pace Trip Blank Lot# (if purchased);
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Resolution:
Date/Time:
Field Data Required? ❑Yes ❑No
Project Manager SCURF Review: Date: q
Project Manager SRF Review: 1u 4 Date: � /l y Ilk
Note: Wheneverthere is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
.Out of hold, incorrect preservative, out of temp, incorrect containers)
Page 24 of 25

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