NC0000396_J16040242 Report_20160831

DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J16040242
Project Name: ASHEVILLE - AB GW ASSESSMENT WATER
Customer Name(s): Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Customer Address: 200 CP and L Drive
Arden,NC 28704
Lab Contact: Mary Ann Ogle Phone: [phone]
Digitally signed by Mary Ann
Ogle
Report Authorized By: / Date: 2016.04.2216:24:10 Date: 4/21/2016
(Signature) //-04'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Page 1 of 60
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2016010154
2016010155
2016010156
2016010157
2016010158
2016010159
2016010160
2016010161
8 Total Samples
Collected By
Sample Description
ASHEVILLE
11-Apr-16 10:02 AM
Synterra
MW-18D
ASHEVILLE
11-Apr-16 10:28 AM
Synterra
MW-18BR
ASHEVILLE
11-Apr-16 9:00 AM
Synterra
MW-17A
ASHEVILLE
11-Apr-16 1:17 PM
Synterra
MW-22D
ASHEVILLE
11-Apr-16 1:42 PM
Synterra
MW-22BR
ASHEVILLE
11-Apr-16 2:45 PM
Synterra
MW-17A
ASHEVILLE
11-Apr-16 4:20 PM
Synterra
Filter Blank 3
ASHEVILLE
11-Apr-16 4:20 PM
Synterra
Equipment Blank 3
Page 2 of 60

Page 3 of 60
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
OV Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 4/21/2016

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
Site: MW-18D
Collection Date: 11-Apr-16 10:02 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.037 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
97
mg/L
5
Sulfate
280
mg/L
5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.010
mg/L
0.005
Barium (Ba)
0.045
mg/L
0.005
Boron (B)
0.842
mg/L
0.05
Iron (Fe)
2.39
mg/L
0.01
Manganese (Mn)
1.19
mg/L
0.005
Strontium (Sr)
0.280
mg/L
0.005
Zinc (Zn)
0.022
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
118
mg/L
0.1
Magnesium (Mg)
29.8
mg/L
0.05
Potassium (K)
8.17
mg/L
0.1
Sodium (Na)
13.8
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.015
mg/L
0.005
Barium (Ba)
0.050
mg/L
0.005
Boron (B)
0.887
mg/L
0.05
Iron (Fe)
1.62
mg/L
0.01
Manganese (Mn)
1.26
mg/L
0.005
Strontium (Sr)
0.291
mg/L
0.005
Zinc (Zn)
0.007
mg/L
0.005
Sample #: 2016010154
Matrix: GW_WW
Page 4 of 60
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/14/2016 12:16 LSTARL1
Vendor Method V_PACE
50
EPA 300.0
04/13/2016 02:34
BGN9034
50
EPA 300.0
04/13/2016 02:34
BGN9034
1
EPA 245.1
04/15/2016 10:47
DMFRANC
1
EPA 245.1
04/15/2016 11:02
DMFRANC
1
EPA 200.7
04/14/2016 15:23
JJMACKE
1
EPA 200.7
04/14/2016 15:23
JJMACKE
1
EPA 200.7
04/14/2016 15:23
JJMACKE
1
EPA 200.7
04/14/2016 15:23
JJMACKE
1
EPA 200.7
04/14/2016 15:23
JJMACKE
1
EPA 200.7
04/14/2016 15:23
JJMACKE
1
EPA 200.7
04/14/2016 15:23
JJMACKE
10
EPA 200.7
04/14/2016 12:38
JJMACKE
10
EPA 200.7
04/14/2016 12:38
JJMACKE
1
EPA 200.7
04/14/2016 12:38
JJMACKE
1
EPA 200.7
04/14/2016 12:38
JJMACKE
1
EPA 200.7
04/13/2016 14:24
JJMACKE
1
EPA 200.7
04/13/2016 14:24
JJMACKE
1
EPA 200.7
04/13/2016 14:24
JJMACKE
1
EPA 200.7
04/13/2016 14:24
JJMACKE
1
EPA 200.7
04/13/2016 14:24
JJMACKE
1
EPA 200.7
04/13/2016 14:24
JJMACKE
1
EPA 200.7
04/13/2016 14:24
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
Site: MW-18D
Collection Date: 11-Apr-16 10:02 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
4.67
ug/L
Copper (Cu)
9.66
ug/L
Lead (Pb)
1.62
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
2.74
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L M2
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
4.09
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
2.60
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
620
mg/L
Total Carbon
TOC
0.309
mg/L
Page 5 of 60
Sample #:
2016010154
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/14/2016 15:50
JAHERMA
1
1
EPA 200.8
04/14/2016 15:50
JAHERMA
1
1
EPA 200.8
04/14/2016 15:50
JAHERMA
1
1
EPA 200.8
04/14/2016 15:50
JAHERMA
1
1
EPA 200.8
04/14/2016 15:50
JAHERMA
1
1
EPA 200.8
04/14/2016 15:50
JAHERMA
1
1
EPA 200.8
04/14/2016 15:50
JAHERMA
1
1
EPA 200.8
04/14/2016 15:50
JAHERMA
1
1
EPA 200.8
04/14/2016 15:50
JAHERMA
1
1
EPA 200.8
04/14/2016 15:50
JAHERMA
1
1
EPA 200.8
04/14/2016 15:50
JAHERMA
0.2
1
EPA 200.8
04/14/2016 15:50
JAHERMA
0.3
1
EPA 200.8
04/14/2016 15:50
JAHERMA
1
1
EPA 200.8
04/14/2016 17:06
JAHERMA
1
1
EPA 200.8
04/14/2016 17:06
JAHERMA
1
1
EPA 200.8
04/14/2016 17:06
JAHERMA
1
1
EPA 200.8
04/14/2016 17:06
JAHERMA
1
1
EPA 200.8
04/14/2016 17:06
JAHERMA
1
1
EPA 200.8
04/14/2016 17:06
JAHERMA
1
1
EPA 200.8
04/14/2016 17:06
JAHERMA
1
1
EPA 200.8
04/14/2016 17:06
JAHERMA
1
1
EPA 200.8
04/14/2016 17:06
JAHERMA
1
1
EPA 200.8
04/14/2016 17:06
JAHERMA
1
1
EPA 200.8
04/14/2016 17:06
JAHERMA
0.2
1
EPA 200.8
04/14/2016 17:06
JAHERMA
0.3
1
EPA 200.8
04/14/2016 17:06
JAHERMA
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
25 1 SM2540C 04/14/201613:17 PARMSTR
0.1 1 SM5310C/EPA9060A 04/14/201611:05 GHUTCHI

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
Site: MW-18D
Collection Date: 11-Apr-16 10:02 AM
Analyte Result
TOTAL SUSPENDED SOLIDS
TSS < 5
Units Qualifiers RDL DF
mg/L 5 1
Page 6 of 60
Sample #: 2016010154
Matrix: GW_WW
Method Analysis Date/Time Analyst
SM2540D 04/14/201610:00 PARMSTR

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
Site: MW-18BR
Collection Date: 11-Apr-16 10:28 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.291 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
97
mg/L
5
Sulfate
290
mg/L
5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.008
mg/L
0.005
Barium (Ba)
0.038
mg/L
0.005
Boron (B)
0.887
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.210
mg/L
0.005
Strontium (Sr)
0.407
mg/L
0.005
Zinc (Zn)
0.023
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
123
mg/L
0.1
Magnesium (Mg)
28.0
mg/L
0.05
Potassium (K)
8.76
mg/L
0.1
Sodium (Na)
14.6
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.017
mg/L
0.005
Barium (Ba)
0.039
mg/L
0.005
Boron (B)
0.906
mg/L
0.05
Iron (Fe)
0.014
mg/L
0.01
Manganese (Mn)
0.216
mg/L
0.005
Strontium (Sr)
0.413
mg/L
0.005
Zinc (Zn)
0.008
mg/L
0.005
Sample #: 2016010155
Matrix: GW_WW
Page 7 of 60
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/14/2016 12:17 LSTARL1
Vendor Method V_PACE
50
EPA 300.0
04/13/2016 02:50
BGN9034
50
EPA 300.0
04/13/2016 02:50
BGN9034
1
EPA 245.1
04/15/2016 10:50
DMFRANC
1
EPA 245.1
04/15/2016 11:18
DMFRANC
1
EPA 200.7
04/14/2016 15:11
JJMACKE
1
EPA 200.7
04/14/2016 15:11
JJMACKE
1
EPA 200.7
04/14/2016 15:11
JJMACKE
1
EPA 200.7
04/14/2016 15:11
JJMACKE
1
EPA 200.7
04/14/2016 15:11
JJMACKE
1
EPA 200.7
04/14/2016 15:11
JJMACKE
1
EPA 200.7
04/14/2016 15:11
JJMACKE
10
EPA 200.7
04/14/2016 12:41
JJMACKE
10
EPA 200.7
04/14/2016 12:41
JJMACKE
1
EPA 200.7
04/14/2016 12:41
JJMACKE
1
EPA 200.7
04/14/2016 12:41
JJMACKE
1
EPA 200.7
04/13/2016 14:12
JJMACKE
1
EPA 200.7
04/13/2016 14:12
JJMACKE
1
EPA 200.7
04/13/2016 14:12
JJMACKE
1
EPA 200.7
04/13/2016 14:12
JJMACKE
1
EPA 200.7
04/13/2016 14:12
JJMACKE
1
EPA 200.7
04/13/2016 14:12
JJMACKE
1
EPA 200.7
04/13/2016 14:12
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
Site: MW-18BR
Collection Date: 11-Apr-16 10:28 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
1.21
ug/L
Copper (Cu)
11.6
ug/L
Lead (Pb)
1.88
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
4.54
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
1.14
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
4.31
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
650
mg/L
Total Carbon
TOC
0.264
mg/L
Page 8 of 60
Sample #:
2016010155
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/14/2016 16:06
JAHERMA
1
1
EPA 200.8
04/14/2016 16:06
JAHERMA
1
1
EPA 200.8
04/14/2016 16:06
JAHERMA
1
1
EPA 200.8
04/14/2016 16:06
JAHERMA
1
1
EPA 200.8
04/14/2016 16:06
JAHERMA
1
1
EPA 200.8
04/14/2016 16:06
JAHERMA
1
1
EPA 200.8
04/14/2016 16:06
JAHERMA
1
1
EPA 200.8
04/14/2016 16:06
JAHERMA
1
1
EPA 200.8
04/14/2016 16:06
JAHERMA
1
1
EPA 200.8
04/14/2016 16:06
JAHERMA
1
1
EPA 200.8
04/14/2016 16:06
JAHERMA
0.2
1
EPA 200.8
04/14/2016 16:06
JAHERMA
0.3
1
EPA 200.8
04/14/2016 16:06
JAHERMA
1
1
EPA 200.8
04/14/2016 17:28
JAHERMA
1
1
EPA 200.8
04/14/2016 17:28
JAHERMA
1
1
EPA 200.8
04/14/2016 17:28
JAHERMA
1
1
EPA 200.8
04/14/2016 17:28
JAHERMA
1
1
EPA 200.8
04/14/2016 17:28
JAHERMA
1
1
EPA 200.8
04/14/2016 17:28
JAHERMA
1
1
EPA 200.8
04/14/2016 17:28
JAHERMA
1
1
EPA 200.8
04/14/2016 17:28
JAHERMA
1
1
EPA 200.8
04/14/2016 17:28
JAHERMA
1
1
EPA 200.8
04/14/2016 17:28
JAHERMA
1
1
EPA 200.8
04/14/2016 17:28
JAHERMA
0.2
1
EPA 200.8
04/14/2016 17:28
JAHERMA
0.3
1
EPA 200.8
04/14/2016 17:28
JAHERMA
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
25 1 SM2540C 04/14/201613:17 PARMSTR
0.1 1 SM5310C/EPA9060A 04/14/201611:05 GHUTCHI

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
Site: MW-18BR
Collection Date: 11-Apr-16 10:28 AM
Analyte Result
TOTAL SUSPENDED SOLIDS
TSS < 5
Units Qualifiers RDL DF
mg/L 5 1
Page 9 of 60
Sample #: 2016010155
Matrix: GW_WW
Method Analysis Date/Time Analyst
SM2540D 04/14/201610:00 PARMSTR

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
Site: MW-17A
Collection Date: 11-Apr-16 9:00 AM
Analyte Result
Units Qualifiers
RDL
DF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01
mg-N/L
0.01
1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC
Chloride 410
mg/L
5
50
Sulfate 190
mg/L
5
50
SULFIDE - (Analysis Performed by Pace Laboratories
Page 10 of 60
Sample #: 2016010156
Matrix: GW_WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
EPA 353.2 04/14/2016 12:19 LSTARL1
Vendor Method
V_PACE
EPA 300.0
04/13/2016 03:07 BGN9034
EPA 300.0
04/13/2016 03:07 BGN9034
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 1.5 mg/L 0.1 1 SM5310C/EPA9060A 04/14/201611:05 GHUTCHI

Certificate of Laboratory Analysis Page 11 of 60
This report shall not be reproduced, except in full.
Order # J16040242
Site: MW-22D
Collection Date: 11-Apr-16 1:17 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.290 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
35
mg/L
1
Sulfate
11
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.026
mg/L
0.005
Barium (Ba)
0.030
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.093
mg/L
0.005
Strontium (Sr)
0.054
mg/L
0.005
Zinc (Zn)
0.021
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
6.08
mg/L
0.01
Magnesium (Mg)
4.53
mg/L
0.005
Potassium (K)
1.35
mg/L
0.1
Sodium (Na)
12.7
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.091
mg/L
0.005
Barium (Ba)
0.034
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.062
mg/L
0.01
Manganese (Mn)
0.107
mg/L
0.005
Strontium (Sr)
0.055
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016010157
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/14/2016 12:23 LSTARL1
Vendor Method V_PACE
10 EPA 300.0
04/13/2016 03:23
BGN9034
10 EPA 300.0
04/13/2016 03:23
BGN9034
1 EPA 245.1
04/15/2016 10:52
DMFRANC
1 EPA 245.1
04/15/2016 11:25
DMFRANC
1 EPA 200.7
04/14/2016 15:27
JJMACKE
1 EPA 200.7
04/14/2016 15:27
JJMACKE
1 EPA 200.7
04/14/2016 15:27
JJMACKE
1 EPA 200.7
04/14/2016 15:27
JJMACKE
1 EPA 200.7
04/14/2016 15:27
JJMACKE
1 EPA 200.7
04/14/2016 15:27
JJMACKE
1 EPA 200.7
04/14/2016 15:27
JJMACKE
1 EPA 200.7
04/14/2016 12:45
JJMACKE
1 EPA 200.7
04/14/2016 12:45
JJMACKE
1 EPA 200.7
04/14/2016 12:45
JJMACKE
1 EPA 200.7
04/14/2016 12:45
JJMACKE
1 EPA 200.7
04/13/2016 14:28
JJMACKE
1 EPA 200.7
04/13/2016 14:28
JJMACKE
1 EPA 200.7
04/13/2016 14:28
JJMACKE
1 EPA 200.7
04/13/2016 14:28
JJMACKE
1 EPA 200.7
04/13/2016 14:28
JJMACKE
1 EPA 200.7
04/13/2016 14:28
JJMACKE
1 EPA 200.7
04/13/2016 14:28
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
Site: MW-22D
Collection Date: 11-Apr-16 1:17 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
12.4
ug/L
Lead (Pb)
1.89
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
6.22
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
0.326
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
5.49
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
0.209
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
98
mg/L
Total Carbon
TOC
0.301
mg/L
Page 12 of 60
Sample #:
2016010157
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/14/2016 16:11
JAHERMA
1
1
EPA 200.8
04/14/2016 16:11
JAHERMA
1
1
EPA 200.8
04/14/2016 16:11
JAHERMA
1
1
EPA 200.8
04/14/2016 16:11
JAHERMA
1
1
EPA 200.8
04/14/2016 16:11
JAHERMA
1
1
EPA 200.8
04/14/2016 16:11
JAHERMA
1
1
EPA 200.8
04/14/2016 16:11
JAHERMA
1
1
EPA 200.8
04/14/2016 16:11
JAHERMA
1
1
EPA 200.8
04/14/2016 16:11
JAHERMA
1
1
EPA 200.8
04/14/2016 16:11
JAHERMA
1
1
EPA 200.8
04/14/2016 16:11
JAHERMA
0.2
1
EPA 200.8
04/14/2016 16:11
JAHERMA
0.3
1
EPA 200.8
04/14/2016 16:11
JAHERMA
1
1
EPA 200.8
04/14/2016 17:33
JAHERMA
1
1
EPA 200.8
04/14/2016 17:33
JAHERMA
1
1
EPA 200.8
04/14/2016 17:33
JAHERMA
1
1
EPA 200.8
04/14/2016 17:33
JAHERMA
1
1
EPA 200.8
04/14/2016 17:33
JAHERMA
1
1
EPA 200.8
04/14/2016 17:33
JAHERMA
1
1
EPA 200.8
04/14/2016 17:33
JAHERMA
1
1
EPA 200.8
04/14/2016 17:33
JAHERMA
1
1
EPA 200.8
04/14/2016 17:33
JAHERMA
1
1
EPA 200.8
04/14/2016 17:33
JAHERMA
1
1
EPA 200.8
04/14/2016 17:33
JAHERMA
0.2
1
EPA 200.8
04/14/2016 17:33
JAHERMA
0.3
1
EPA 200.8
04/14/2016 17:33
JAHERMA
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
25 1 SM2540C 04/14/201613:17 PARMSTR
0.1 1 SM5310C/EPA9060A 04/14/201611:05 GHUTCHI

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
Site: MW-22D
Collection Date: 11-Apr-16 1:17 PM
Analyte Result
TOTAL SUSPENDED SOLIDS
TSS < 5
Units Qualifiers RDL DF
mg/L 5 1
Page 13 of 60
Sample #: 2016010157
Matrix: GW_WW
Method Analysis Date/Time Analyst
SM2540D 04/14/201610:00 PARMSTR

Certificate of Laboratory Analysis Page 14 of 60
This report shall not be reproduced, except in full.
Order # J16040242
Site: MW-22BR
Collection Date: 11-Apr-16 1:42 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
49
mg/L
1
Sulfate
19
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.019
mg/L
0.005
Barium (Ba)
0.018
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
15.1
mg/L
0.01
Manganese (Mn)
0.306
mg/L
0.005
Strontium (Sr)
0.097
mg/L
0.005
Zinc (Zn)
0.025
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
11.0
mg/L
0.01
Magnesium (Mg)
4.39
mg/L
0.005
Potassium (K)
3.01
mg/L
0.1
Sodium (Na)
16.0
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.061
mg/L
0.005
Barium (Ba)
0.019
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
16.9
mg/L
0.01
Manganese (Mn)
0.310
mg/L
0.005
Strontium (Sr)
0.101
mg/L
0.005
Zinc (Zn)
0.020
mg/L
0.005
Sample #: 2016010158
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/14/2016 12:27 LSTARL1
Vendor Method V_PACE
10 EPA 300.0
04/13/2016 03:40
BGN9034
10 EPA 300.0
04/13/2016 03:40
BGN9034
1 EPA 245.1
04/15/2016 10:54
DMFRANC
1 EPA 245.1
04/15/2016 11:28
DMFRANC
1 EPA 200.7
04/14/2016 15:30
JJMACKE
1 EPA 200.7
04/14/2016 15:30
JJMACKE
1 EPA 200.7
04/14/2016 15:30
JJMACKE
1 EPA 200.7
04/14/2016 15:30
JJMACKE
1 EPA 200.7
04/14/2016 15:30
JJMACKE
1 EPA 200.7
04/14/2016 15:30
JJMACKE
1 EPA 200.7
04/14/2016 15:30
JJMACKE
1 EPA 200.7
04/14/2016 12:49
JJMACKE
1 EPA 200.7
04/14/2016 12:49
JJMACKE
1 EPA 200.7
04/14/2016 12:49
JJMACKE
1 EPA 200.7
04/14/2016 12:49
JJMACKE
1 EPA 200.7
04/13/2016 14:31
JJMACKE
1 EPA 200.7
04/13/2016 14:31
JJMACKE
1 EPA 200.7
04/13/2016 14:31
JJMACKE
1 EPA 200.7
04/13/2016 14:31
JJMACKE
1 EPA 200.7
04/13/2016 14:31
JJMACKE
1 EPA 200.7
04/13/2016 14:31
JJMACKE
1 EPA 200.7
04/13/2016 14:31
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
Site: MW-22BR
Collection Date: 11-Apr-16 1:42 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
3.90
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
160
mg/L
Total Carbon
TOC
0.405
mg/L
Page 15 of 60
Sample #:
2016010158
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/14/2016 16:33
JAHERMA
1
1
EPA 200.8
04/14/2016 16:33
JAHERMA
1
1
EPA 200.8
04/14/2016 16:33
JAHERMA
1
1
EPA 200.8
04/14/2016 16:33
JAHERMA
1
1
EPA 200.8
04/14/2016 16:33
JAHERMA
1
1
EPA 200.8
04/14/2016 16:33
JAHERMA
1
1
EPA 200.8
04/14/2016 16:33
JAHERMA
1
1
EPA 200.8
04/14/2016 16:33
JAHERMA
1
1
EPA 200.8
04/14/2016 16:33
JAHERMA
1
1
EPA 200.8
04/14/2016 16:33
JAHERMA
1
1
EPA 200.8
04/14/2016 16:33
JAHERMA
0.2
1
EPA 200.8
04/14/2016 16:33
JAHERMA
0.3
1
EPA 200.8
04/14/2016 16:33
JAHERMA
1
1
EPA 200.8
04/14/2016 17:55
JAHERMA
1
1
EPA 200.8
04/14/2016 17:55
JAHERMA
1
1
EPA 200.8
04/14/2016 17:55
JAHERMA
1
1
EPA 200.8
04/14/2016 17:55
JAHERMA
1
1
EPA 200.8
04/14/2016 17:55
JAHERMA
1
1
EPA 200.8
04/14/2016 17:55
JAHERMA
1
1
EPA 200.8
04/14/2016 17:55
JAHERMA
1
1
EPA 200.8
04/14/2016 17:55
JAHERMA
1
1
EPA 200.8
04/14/2016 17:55
JAHERMA
1
1
EPA 200.8
04/14/2016 17:55
JAHERMA
1
1
EPA 200.8
04/14/2016 17:55
JAHERMA
0.2
1
EPA 200.8
04/14/2016 17:55
JAHERMA
0.3
1
EPA 200.8
04/14/2016 17:55
JAHERMA
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
25 1 SM2540C 04/14/201613:17 PARMSTR
0.1 1 SM5310C/EPA9060A 04/14/201611:05 GHUTCHI

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
Site: MW-22BR
Collection Date: 11-Apr-16 1:42 PM
Analyte Result
TOTAL SUSPENDED SOLIDS
TSS 5.0
Units Qualifiers RDL DF
mg/L 5 1
Page 16 of 60
Sample #: 2016010158
Matrix: GW_WW
Method Analysis Date/Time Analyst
SM2540D 04/14/201610:00 PARMSTR

Certificate of Laboratory Analysis Page 17 of 60
This report shall not be reproduced, except in full.
Order # J16040242
Site: MW-17A
Collection Date: 11-Apr-16 2:45 PM
Analyte
Result
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
UNDIGESTED METALS BY ICP
Calcium (Ca)
178
Magnesium (Mg)
56.1
Potassium (K)
4.46
Sodium (Na)
14.9
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
1.02
Barium (Ba)
0.141
Boron (B)
1.98
Iron (Fe)
30.0
Manganese (Mn)
5.90
Strontium (Sr)
0.625
Zinc (Zn)
0.006
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
Arsenic (As)
1.40
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
22.4
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
4.77
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
1.17
Sample #: 2016010159
Matrix: GW_WW
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
0.05
1
EPA 245.1
04/15/2016 10:57
DMFRANC
mg/L
0.1
10
EPA 200.7
04/14/2016 13:01
JJMACKE
mg/L
0.05
10
EPA 200.7
04/14/2016 13:01
JJMACKE
mg/L
0.1
1
EPA 200.7
04/14/2016 13:01
JJMACKE
mg/L
0.05
1
EPA 200.7
04/14/2016 13:01
JJMACKE
mg/L
0.005
1
EPA 200.7
04/13/2016 14:35
JJMACKE
mg/L
0.005
1
EPA 200.7
04/13/2016 14:35
JJMACKE
mg/L
0.05
1
EPA 200.7
04/13/2016 14:35
JJMACKE
mg/L
0.01
1
EPA 200.7
04/13/2016 14:35
JJMACKE
mg/L
0.005
1
EPA 200.7
04/13/2016 14:35
JJMACKE
mg/L
0.005
1
EPA 200.7
04/13/2016 14:35
JJMACKE
mg/L
0.005
1
EPA 200.7
04/13/2016 14:35
JJMACKE
ug/L
1
1
EPA 200.8
04/14/2016 18:00
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2016 18:00
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2016 18:00
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2016 18:00
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2016 18:00
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2016 18:00
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2016 18:00
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2016 18:00
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2016 18:00
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2016 18:00
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2016 18:00
JAHERMA
ug/L
0.2
1
EPA 200.8
04/14/2016 18:00
JAHERMA
ug/L
0.3
1
EPA 200.8
04/14/2016 18:00
JAHERMA

Certificate of Laboratory Analysis Page 18 of 60
This report shall not be reproduced, except in full.
Order # J16040242
Site: Filter Blank 3
Collection Date: 11-Apr-16 4:20 PM
Analyte
Result
Units Qualifiers
RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
4.95
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2016010160
Matrix: GW_WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
04/15/2016 11:30
DMFRANC
1
EPA 200.7
04/14/2016 15:34
JJMACKE
1
EPA 200.7
04/14/2016 15:34
JJMACKE
1
EPA 200.7
04/14/2016 15:34
JJMACKE
1
EPA 200.7
04/14/2016 15:34
JJMACKE
1
EPA 200.7
04/14/2016 15:34
JJMACKE
1
EPA 200.7
04/14/2016 15:34
JJMACKE
1
EPA 200.7
04/14/2016 15:34
JJMACKE
1
EPA 200.8
04/14/2016 16:39
JAHERMA
1
EPA 200.8
04/14/2016 16:39
JAHERMA
1
EPA 200.8
04/14/2016 16:39
JAHERMA
1
EPA 200.8
04/14/2016 16:39
JAHERMA
1
EPA 200.8
04/14/2016 16:39
JAHERMA
1
EPA 200.8
04/14/2016 16:39
JAHERMA
1
EPA 200.8
04/14/2016 16:39
JAHERMA
1
EPA 200.8
04/14/2016 16:39
JAHERMA
1
EPA 200.8
04/14/2016 16:39
JAHERMA
1
EPA 200.8
04/14/2016 16:39
JAHERMA
1
EPA 200.8
04/14/2016 16:39
JAHERMA
1
EPA 200.8
04/14/2016 16:39
JAHERMA
1
EPA 200.8
04/14/2016 16:39
JAHERMA

Certificate of Laboratory Analysis Page 19 of 60
This report shall not be reproduced, except in full.
Order # J16040242
Site: Equipment Blank 3
Collection Date: 11-Apr-16 4:20 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
Calcium (Ca)
< 0.01
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2016010161
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2
04/14/2016 12:28
LSTARL1
1 EPA 300.0
04/13/2016 00:06
BGN9034
1 EPA 300.0
04/13/2016 00:06
BGN9034
1 EPA 245.1
04/15/2016 10:59
DMFRANC
1 EPA 200.7
04/14/2016 13:33
JJMACKE
1 EPA 200.7
04/14/2016 13:33
JJMACKE
1 EPA 200.7
04/14/2016 13:33
JJMACKE
1 EPA 200.7
04/14/2016 13:33
JJMACKE
1 EPA 200.7
04/13/2016 14:39
JJMACKE
1 EPA 200.7
04/13/2016 14:39
JJMACKE
1 EPA 200.7
04/13/2016 14:39
JJMACKE
1 EPA 200.7
04/13/2016 14:39
JJMACKE
1 EPA 200.7
04/13/2016 14:39
JJMACKE
1 EPA 200.7
04/13/2016 14:39
JJMACKE
1 EPA 200.7
04/13/2016 14:39
JJMACKE
1 EPA 200.8
04/14/2016 18:06
JAHERMA
1 EPA 200.8
04/14/2016 18:06
JAHERMA
1 EPA 200.8
04/14/2016 18:06
JAHERMA
1 EPA 200.8
04/14/2016 18:06
JAHERMA
1 EPA 200.8
04/14/2016 18:06
JAHERMA
1 EPA 200.8
04/14/2016 18:06
JAHERMA
1 EPA 200.8
04/14/2016 18:06
JAHERMA
1 EPA 200.8
04/14/2016 18:06
JAHERMA
1 EPA 200.8
04/14/2016 18:06
JAHERMA
1 EPA 200.8
04/14/2016 18:06
JAHERMA
1 EPA 200.8
04/14/2016 18:06
JAHERMA
1 EPA 200.8
04/14/2016 18:06
JAHERMA
1 EPA 200.8
04/14/2016 18:06
JAHERMA
Vendor Method V_PACE

Site: Equipment Blank 3
Collection Date: 11-Apr-16 4:20 PM
Certificate of Laboratory Analysis Page 20 of 60
This report shall not be reproduced, except in full.
Order # J16040242
Sample #: 2016010161
Matrix: GW_WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.315 mg/L 0.1 1 SM5310C/EPA9060A 04/14/201611:05 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 04/14/2016 10:00 PARMSTR
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.

® Laboratories LLc
a member of The GEL Group IN'.
April 19, 2016
Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Re: AB GW Assessment Water
Work Order: 395096
SDG: J16040242
Dear Mary:
PO BOX 30712 Charleston, SC 29417
2040 Savage Road Charlestan. SC 29407
F 843.556.8171
F 843.766.1178
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on April 12, 2016. This original data report has been prepared and reviewed in accordance
with GEL's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.
Sincerely,
Lindsay Fabra
Project Manager
Purchase Order: 1250944 DPNNGO
Enclosures
gel.com
Pa 11111111111111111111111

Page 22 of 60
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
for
DUP0002 Duke Energy
Client SDG: J16040242 GEL Work Order: 395096
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the 'U' qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
Reviewed by
JU,&Y ,
Page 2 of 15

GEL LABORATORIES LLC Page 23 of 60
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016010154
395096001
Water
11-APR-16 10:02
12-APR-16
Client
Report Date: April 19, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-233 U ND
0.00001
0.00005
ug/mL
1
SKJ 04/15/16
1332 1559298 1
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1
Uranium-238 U ND
0.000067
0.0002
ug/mL
1
PRB 04/14/16
1840 1559298 2
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 U ND
1.88
3.00
pCi/L
AXM6 04/18/16
1246 1559316 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 0.747
0.447
1.00
pCi/L
LXP1 04/19/16
0830 1559634 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JXM5
04/13/16
0738
1559297
The following Analytical Methods were performed:
Method Description Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 89.6 (15%-125%)
Notes:
Page 3 of 15

GEL LABORATORIES LLC Page 24 of 60
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016010155
395096002
Water
11-APR-16 10:28
12-APR-16
Client
Report Date: April 19, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-233 U ND
0.00001
0.00005
ug/mL
1
SKJ 04/15/16
1338 1559298 1
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1
Uranium-238 U ND
0.000067
0.0002
ug/mL
1
PRB 04/14/16
1847 1559298 2
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 U ND
1.75
3.00
pCi/L
AXM6 04/18/16
1246 1559316 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 1.21
0.446
1.00
pCi/L
LXP1 04/19/16
0830 1559634 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JXM5
04/13/16
0738
1559297
The following Analytical Methods were performed:
Method Description Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 92.1 (15%-125%)
Notes:
Page 4 of 15

GEL LABORATORIES LLC Page 25 of 60
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016010157
395096003
Water
11-APR-16 13:17
12-APR-16
Client
Report Date: April 19, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-233 U ND
0.00001
0.00005
ug/mL
1 SKJ 04/15/16
1339 1559298 1
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1
Uranium-238 U ND
0.000067
0.0002
ug/mL
1 PRB 04/14/16
1849 1559298 2
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 1.33
1.30
3.00
pCi/L
AXM6 04/18/16
1246 1559316 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 0.497
0.421
1.00
pCi/L
LXP1 04/19/16
0830 1559634 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JXM5
04/13/16
0738 1559297
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test
Result
Nominal Recovery%
Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"
92.4
(15%-125%)
Notes:
Page 5 of 15

GEL LABORATORIES LLC Page 26 of 60
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016010158
395096004
Water
11-APR-16 13:42
12-APR-16
Client
Report Date: April 19, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-233 U ND
0.00001
0.00005
ug/mL
1
SKJ 04/15/16
1341 1559298 1
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1
Uranium-238 U ND
0.000067
0.0002
ug/mL
1
PRB 04/14/16
1851 1559298 2
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 1.40
1.28
3.00
pCi/L
AXM6 04/18/16
1246 1559316 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 4.85
0.493
1.00
pCi/L
LXP1 04/19/16
0830 1559634 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JXM5
04/13/16
0738
1559297
The following Analytical Methods were performed:
Method Description Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 93.3 (15%-125%)
Notes:
Page 6of15

Page 27 of 60
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina
Contact: Mary Ann Ogle
Workorder: 395096
Report Date: April 19, 2016
Page 1 of 3
Parmname
NOM
Sample
Qual
QC
Units
RPD%o
REC%
Range
Anlst
Date Time
Metals Analysis - ICPMS
Batch 1559298
QC1203526807
395096001
DUP
Uranium-233
U
ND
U
ND
ug/mL
N/A
SKJ
04/15/1613:33
Uranium-234
U
ND
U
ND
ug/mL
N/A
Uranium-236
U
ND
U
ND
ug/mL
N/A
Uranium-238
U
ND
U
ND
ug/mL
N/A
PRB
04/14/1618:42
QC1203526805
LCS
Uranium-238
0.0496
0.0547
ug/mL
110
(80%-120%)
04/14/1618:39
QC1203526806
LCS
Uranium-233
0.0005
0.000532
ug/mL
106
(80%-120%)
SKJ
04/15/1613:27
Uranium-234
0.00055
0.000605
ug/mL
110
(80%-120%)
Uranium-236
0.005
0.00525
ug/mL
105
(80%-120%)
QC1203526804
MB
Uranium-233
U
ND
ug/mL
04/15/1613:26
Uranium-234
U
ND
ug/mL
Uranium-236
U
ND
ug/mL
Uranium-238
U
ND
ug/mL
PRB
04/14/1618:37
QC1203526808
395096001
MS
Uranium-238
0.0496
U
ND
0.0548
ug/mL
110
(75%-125%)
04/14/1618:44
QC1203526809
395096001
MS
Uranium-233
0.0005
U
ND
0.000521
ug/mL
104
(75%-125%)
SKJ
04/15/1613:35
Uranium-234
0.00055
U
ND
0.000584
ug/mL
106
(75%-125%)
Uranium-236
0.005
U
ND
0.00513
ug/mL
102
(75%-125%)
QC1203526810
395096001
SDILT
Uranium-233
U
ND
U
ND
ug/L
N/A
04/15/1613:36
Page 7 of 15

Page 28 of 60
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 395096
Page 2 of 3
Parmname NOM
Sample Qual QC Units
RPD%
REC% Range Anlst
Date Time
Metals Analysis - ICPMS
Batch 1559298
Uranium-234 U
ND U ND
ug/L
N/A
Uranium-236 U
ND U ND
ug/L
N/A
(0%-10%) SKJ
04/15/1613:36
Uranium-238 U
ND 50.5
ug/L
N/A
(0%-10%) PRB
04/14/1618:46
Rad Gas Flow
Batch 1559316
QC1203526838 395096004 DUP
Radium-228
1.40 2.54
pCi/L
58.1
(0% - 100%) AXM6
04/18/16 12:46
QC1203526839 LCS
Radium-228 46.5
46.4
pCi/L
99.8 (75%-125%)
04/18/1612:46
QC1203526837 MB
Radium-228
U 0.758
pCi/L
04/18/1612:46
Rad Ra-226
Batch 1559634
QC1203527795 395096001 DUP
Radium-226
0.747 0.908
pCi/L
19.6
(0% - 100%) LXP1
04/19/16 09:00
QC1203527797 LCS
Radium-226 24.4
30.4
pCi/L
125 (75%-125%)
04/19/16 09:30
QC1203527794 MB
Radium-226
U 0.319
pCi/L
04/19/16 09:00
QC1203527796 395096001 MS
Radium-226 122
0.747 128
pCi/L
104 (75%-125%)
04/19/16 09:30
Notes:
The Qualifiers in this report are defined as follows:
** Analyte is a Tracer compound
< Result is less than value reported
> Result is greater than value reported
BD Results are either below the MDC or tracer recovery
is low
E %difference of sample and SD is >10%. Sample
concentration must meet flagging criteria
FA Failed analysis.
FB Mercury was found present at quantifiable concentrations in field blanks received with these samples.
Data associated with the blank are deemed
invalid for reporting to regulatory agencies
H Analytical holding time was exceeded
Page 8 of 15

Page 29 of 60
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 395096
Parmname NOM Sample Qual QC Units RPD%o REC'%
Page 3 of 3
Range Anlst Date Time
J Value is estimated
K Analyte present. Reported value may be biased high. Actual value is expected to be lower.
L Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M M if above MDC and less than LLD
M REMP Result > MDC/CL and < RDL
N Metals --The Matrix spike sample recovery is not within specified control limits
N/A RPD or %Recovery limits do not apply.
N1 See case narrative
ND Analyte concentration is not detected above the detection limit
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
R Sample results are rejected
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
UI Gamma Spectroscopy --Uncertain identification
UJ Gamma Spectroscopy --Uncertain identification
UL Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Y Other specific qualifiers were required to properly define the results. Consult case narrative.
^ RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
h Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
Page 9 of 15

Page 30 of 60
ro
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Page 10 of 15

Page 31 of 60
Laboratories LI- fi
SAMPLE RECEIPT & REVIEW FORM
Client:
SDG/AR/COC/Work Order: ,
Received By:
Date Received: M/
Suspected Hazard Information
o
*If Net Counts> 100cpm on samples not marked "radioactive, contact the Radiation Safety oup for further
>-
z
investigation
OCC/Sarrples marked as radioactive?
X
Maximum Net Counts Observer (Observed Counts- Area Background Counts):
Classified Radioactive II or III by RSO?
If yes, Were wipes taken of wnVe containers < action levels?
C:OC/Sarroe marked containing PCBs?
Pack COC, ardor Sanples marked as
beryllium or asbestos containing?
If yes, WATOesare to be segregated as Safety Controlled Samples, and opened by the GEL Safety Grog.
Shipped as a DOT Hazardous?
Hazard Gass Shipped: UN#:
Samples identified as Foreign Sal?
Sample Receipt Criteria
8
z
z
Comments/Qualifies(Required for Non -Conforming Items)
ShippingoontadnersreC9vedintact and
Circle Applicable: Sedsbroken Damagedoontainer Leakingcontalner Other(describe)
1
wed?
2
Samples requiring cold preservation
Preservation Method. icebags Blueice Dryice a.NorteOther(describe)
within (0 < 6 deg. C)?*
l I temperatures are recorded in Celsius
2a
Daily Check performed and passed on I R
temperature
Temperature Device Serial #
Secondary Temperature DwiceSerial # (If Applicable): A
gun?
6
3
Chanofkxfstodydocuments IndWed
with shipment?
Circle Applicable: Sealsbroken Damagedocnteiner Lealdngcontalner Other(describe)
4
Samoecant! nersintactand sod ei?
1V
Sarrplesrequiringchard cal preservation
Sample ID's,containers affected and observed pH:
5
at proper pH?
A
If Preservation added, Lpj#
6
Do Low Level Perchlorate sarrples have
Sample ID'sand containers affected:
headspace as requi red?
7
VOA vials contain add preservation?
(if unknown, select No)
VCAvialsfreeofheadspace(definedas
Sample ID'saxicontainers affected:
8
< 6mm bubble)?
9
Are Enoore oo ntainers present?
(if yes, immediately deliver to Volatiles laboratory)
I D's and tests affected:
10
Samples received within holding time?
11
Sample I D's on COC match I D's on
Sample I D's aid containers affected:
bottles'
12
Date& time on COC match date& time
SanplelD'saffected:
on bottles?
13
Number of containers re dvedmatch
SampleiD'saffected:numbernurr
indicated on COC?
14
Aresarrpleoorntainersidentifiabieas
GEL ovided?
15
COC form isproperly signed in
relinquished/received sections?
ate OrdeApplic
FedEx Air FedEx Ground UPS Reid Services Courier Other
16
Carrier" trackingnumber.
Comments (Use Continuation Form if needed):
PM (or PMA) review: initials ° _—_ _Date 5. Page of -t---
GL-CHL-SR-001 Rev 3
Page 11 of 15

Page 32 of 60
Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16040242
Work Order #: 395096
Metals
Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1559298
Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1559297
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
Client Sample Identification
395096001
2016010154
395096002
2016010155
395096003
2016010157
395096004
2016010158
1203526804
Method Blank (MB)ICP-MS
1203526805
Laboratory Control Sample (LCS)
1203526806
Laboratory Control Sample (LCS)
1203526810
395096001(2016010154L) Serial Dilution (SD)
1203526807
395096001(2016010154D) Sample Duplicate (DUP)
1203526808
395096001(2016010154S) Matrix Spike (MS)
1203526809
395096001(2016010154S) Matrix Spike (MS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.
Radiochemistry
Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1559316
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID# Client Sample Identification
395096001 2016010154
Page 12 of 15

Page 33 of 60
395096002 2016010155
395096003 2016010157
395096004 2016010158
1203526837 Method Blank (MB)
1203526838 395096004(2016010158) Sample Duplicate (DUP)
1203526839 Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summarv:
There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.
Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1559634
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
Client Sample Identification
395096001
2016010154
395096002
2016010155
395096003
2016010157
395096004
2016010158
1203527794
Method Blank (MB)
1203527795
395096001(2016010154) Sample Duplicate (DUP)
1203527796
395096001(2016010154) Matrix Spike (MS)
1203527797
Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summarv•
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Miscellaneous information
Additional Comments
The matrix spike, 1203527796 (2016010154MS), aliquot was reduced to conserve sample volume.
Page 13 of 15

Page 34 of 60
Certification Statement
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 14 of 15

Page 35 of 60
List of current GEL Certifications as of 19 April 2016
State
Certification
Alaska
UST-0110
Arkansas
88-0651
CLIA
42D0904046
California
2940
Colorado
SC00012
Connecticut
PH-0169
Delaware
SC00012
DoD ELAP/ ISO17025 A2LA
2567.01
Florida NELAP
E87156
Foreign Soils Permit
P330-15-00283, P330-15-00253
Georgia
SC00012
Georgia SDWA
967
Hawaii
SC00012
Idaho Chemistry
SC00012
Idaho Radiochemistry
SC00012
Illinois NELAP
200029
Indiana
C—SC-01
Kansas NELAP
E-10332
Kentucky SDWA
90129
Kentucky Wastewater
90129
Louisiana NELAP
03046 (A233904)
Louisiana SDWA
LA160006
Maryland
270
Massachusetts
M—SC012
Michigan
9976
Mississippi
SC00012
Nebraska
NE—OS-26-13
Nevada
SC000122016-1
New Hampshire NELAP
205415
New Jersey NELAP
SC002
New Mexico
SC00012
New York NELAP
11501
North Carolina
233
North Carolina SDWA
45709
North Dakota
R-158
Oklahoma
9904
Pennsylvania NELAP
68-00485
S.Carolina Radchem
10120002
South Carolina Chemistry
10120001
Tennessee
TN 02934
Texas NELAP
T104704235-16-11
Utah NELAP
SC000122016-20
Vermont
VT87156
Virginia NELAP
460202
Washington
C780
West Virginia
997404
Page 15 of 15

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[phone]
April 19, 2016
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 16040242
Pace Project No.: 92293408
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 12, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Anne Pifer
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 24

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
OQ9*csfke. Suite 100
Huntersville, NC 28078
[phone]
Project: J16040242
Pace Project No.: 92293408
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A21-A Certification M 2926.01
Alaska Certification M UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification M 88-0680
California Certification M 01155CA
Colorado Certification #Pace
Connecticut Certification M PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification M 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification M 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification M 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification M 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification M E83079
Georgia Certification M 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification M 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification M E-10383
Louisiana Certification M FL NELAC Reciprocity
Louisiana Environmental Certificate M 05007
Maryland Certification: #346
Michigan Certification M 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification M Cert 0074
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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aceAnaiXical
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SAMPLE SUMMARY
Project: J16040242
Pace Project No.: 92293408
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92293408001
2016010154
Water
04/11/1610:02
04/12/1613:46
92293408002
2016010155
Water
04/11/1610:28
04/12/1613:46
92293408003
2016010156
Water
04/11/16 09:00
04/12/16 13:46
92293408004
2016010157
Water
04/11/1613:17
04/12/1613:46
92293408005
2016010158
Water
04/11/1613:42
04/12/1613:46
92293408006
2016010161
Water
04/11/1616:20
04/12/1613:46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 24

aceAnaiXical
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Pace Analytical Services, Inc.
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[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16040242
92293408
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92293408001
2016010154
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92293408002
2016010155
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92293408003
2016010156
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92293408004
2016010157
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92293408005
2016010158
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92293408006
2016010161
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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Pace Analytical Services, Inc.
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[phone]
Project: J16040242
Pace Project No.: 92293408
Lab Sample ID
Method
92293408001
SM 2320B
SM 2320B
92293408002
SM 2320B
SM 2320B
EPA 218.7
92293408003
SM 2320B
SM 2320B
92293408004
EPA 218.7
92293408005
SM 2320B
SM 2320B
SUMMARY OF DETECTION
Client Sample ID
Parameters
2016010154
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
2016010155
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
Chromium, Hexavalent
2016010156
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
2016010157
Chromium, Hexavalent
2016010158
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
Result
Units
30.1
mg/L
30.1
mg/L
28.0
mg/L
28.0
mg/L
0.043
ug/L
20.8
mg/L
20.8
mg/L
0.75
ug/L
20.6
mg/L
20.6
mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Report Limit Analyzed Qualifiers
5.0
04/15/1616:08
5.0
04/15/1616:08
5.0
04/15/1616:20
5.0
04/15/1616:20
0.030
04/15/1618:29
5.0 04/15/1616:31
5.0 04/15/1616:31
0.15 04/18/16 09:41 M1
5.0 04/15/1617:10
5.0 04/15/1617:10
Page 5 of 24

aceAnaiXical
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Pace Analytical Services, Inc.
098gwinic&fir&e. Suite 100
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[phone]
PROJECT NARRATIVE
Project: J16040242
Pace Project No.: 92293408
Method: RSK 175
Description: RSK 175 AIR Headspace
Client: Duke Energy
Date: April 19, 2016
General Information:
5 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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[phone]
PROJECT NARRATIVE
Project: J16040242
Pace Project No.: 92293408
Method: SM 2320B
Description: 2320E Alkalinity
Client: Duke Energy
Date: April 19, 2016
General Information:
6 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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098m.8w. Suite 100
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[phone]
PROJECT NARRATIVE
Project: J16040242
Pace Project No.: 92293408
Method: SM 4500-S213
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: April 19, 2016
General Information:
6 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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PROJECT NARRATIVE
Project: J16040242
Pace Project No.: 92293408
Method: EPA 218.7
Description: Hexavalent Chromium by IC
Client: Duke Energy
Date: April 19, 2016
General Information:
5 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/56898
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92293293006,92293408003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 1542726)
• Chromium. Hexavalent
QC Batch: WETA/56918
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92293408004,92293525003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1544168)
• Chromium, Hexavalent
• MS (Lab ID: 1544170)
• Chromium, Hexavalent
• MSD (Lab ID: 1544169)
• Chromium, Hexavalent
R1: RPD value was outside control limits.
• MSD (Lab ID: 1544171)
• Chromium. Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 9 of 24

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ANALYTICAL RESULTS
Project: J16040242
Pace Project No.: 92293408
Sample: 2016010154
Lab ID: 92293408001 Collected:
04/11/16 10:02
Received: 04/12/16 13:46 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/15/16 08:56
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
30.1 mg/L
5.0
1
04/15/16 16:08
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/15/16 16:08
Alkalinity, Total as CaCO3
30.1 mg/L
5.0
1
04/15/16 16:08
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/14/1619:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
04/15/16 18:16
18540-29-9
Date: 04/19/2016 04:55 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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Page 10 of 24

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Pace Analytical Services, Inc.
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[phone]
ANALYTICAL RESULTS
Project: J16040242
Pace Project No.: 92293408
Sample: 2016010155
Lab ID: 92293408002 Collected:
04/11/16 10:28
Received: 04/12/16 13:46 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/15/16 09:37
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
28.0 mg/L
5.0
1
04/15/16 16:20
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/15/16 16:20
Alkalinity, Total as CaCO3
28.0 mg/L
5.0
1
04/15/16 16:20
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/14/1619:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.043 ug/L
0.030
1
04/15/16 18:29
18540-29-9
Date: 04/19/2016 04:55 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16040242
Pace Project No.: 92293408
Sample: 2016010156
Lab ID: 92293408003 Collected:
04/11/16 09:00
Received: 04/12/16 13:46 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed CAS No. Qual
2320E Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
20.8 mg/L
5.0
1
04/15/16 16:31
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/15/16 16:31
Alkalinity, Total as CaCO3
20.8 mg/L
5.0
1
04/15/16 16:31
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/14/1619:00 18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
04/15/16 19:08 18540-29-9
Date: 04/19/2016 04:55 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16040242
Pace Project No.: 92293408
Sample: 2016010157
Lab ID: 92293408004 Collected:
04/11/16 13:17
Received: 04/12/16 13:46 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/15/16 09:46
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
04/15/16 17:02
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/15/16 17:02
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
04/15/16 17:02
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/14/1619:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.75 ug/L
0.15
5
04/18/16 09:41
18540-29-9 M1
Date: 04/19/2016 04:55 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 24

aceAnaiXical
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Pace Analytical Services, Inc.
098m.8w. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040242
Pace Project No.: 92293408
Sample: 2016010158
Lab ID: 92293408005 Collected:
04/11/16 13:42
Received: 04/12/16 13:46 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/15/16 09:54
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
20.6 mg/L
5.0
1
04/15/16 17:10
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/15/16 17:10
Alkalinity, Total as CaCO3
20.6 mg/L
5.0
1
04/15/16 17:10
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/14/1619:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
04/15/16 20:00
18540-29-9
Date: 04/19/2016 04:55 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 14 of 24

aceAnaiXical
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Pace Analytical Services, Inc.
098onfir&e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040242
Pace Project No.: 92293408
Sample: 2016010161
Lab ID: 92293408006 Collected:
04/11/16 16:20
Received: 04/12/16 13:46 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/15/1610:02 74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
04/15/16 17:22
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/15/16 17:22
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
04/15/16 17:22
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/14/1619:00 18496-25-8
Date: 04/19/2016 04:55 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 24

aceAnaiXical
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Pace Analytical Services, Inc.
098oy fir&e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040242
Pace Project No.: 92293408
QC Batch: AIR/25691
Analysis Method: RSK 175
QC Batch Method: RSK 175
Analysis Description: RSK 175 AIR HEADSPACE
Associated Lab Samples: 92293408001, 92293408002,
92293408004, 92293408005, 92293408006
METHOD BLANK: 2231173
Matrix: Water
Associated Lab Samples: 92293408001, 92293408002,
92293408004, 92293408005, 92293408006
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Methane
ug/L
ND 10.0 04/15/16 07:20
LABORATORY CONTROL SAMPLE & LCSD:
2231174
2231175
Spike LCS LCSD LCS LCSD
% Rec Max
Parameter
Units
Conc. Result Result % Rec % Rec
Limits RPD RPD Qualifiers
Methane
ug/L
60.7 60.2 59.6 99 98
85-115 1 20
SAMPLE DUPLICATE: 2234656
92293276005 Dup
Max
Parameter
Units
Result Result RPD
RPD Qualifiers
Methane
ug/L
1 AJ 1.6J
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/19/2016 04:55 PM without the written consent of Pace Analytical Services, Inc..
Page 16 of 24

aceAnaiXical
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Pace Analytical Services, Inc.
098onfir&e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040242
Pace Project No.: 92293408
QC Batch: WET/44242 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92293408001, 92293408002, 92293408003, 92293408004, 92293408005, 92293408006
METHOD BLANK: 1709856
Matrix: Water
Associated Lab Samples: 92293408001, 92293408002, 92293408003, 92293408004, 92293408005,
92293408006
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Alkalinity, Carbonate (CaCO3)
mg/L
ND 5.0
04/15/16 13:07
Alkalinity, Total as CaCO3
mg/L
ND 5.0
04/15/16 13:07
Alkalinity, Bicarbonate (CaCO3)
mg/L
ND 5.0
04/15/16 13:07
LABORATORY CONTROL SAMPLE: 1709857
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 49.4 99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1709858 1709859
MS MSD
92293293003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 12.8 50 50 62.0 61.4 98 97 80-120 1 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1709860 1709861
MS MSD
92293293013 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Alkalinity, Total as CaCO3 mg/L ND 50 50 48.6 48.3 97 97 80-120 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/19/2016 04:55 PM without the written consent of Pace Analytical Services, Inc..
Page 17 of 24

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098nnfir&e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040242
Pace Project No.: 92293408
QC Batch: WET/44258
Analysis Method: SM 4500-S2D
QC Batch Method: SM 4500-S2D
Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92293408001, 92293408002,
92293408003, 92293408004, 92293408005, 92293408006
METHOD BLANK: 1710637
Matrix: Water
Associated Lab Samples: 92293408001, 92293408002,
92293408003, 92293408004, 92293408005, 92293408006
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Sulfide mg/L
ND 0.10 04/14/1619:00
LABORATORY CONTROL SAMPLE: 1710638
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Sulfide mg/L
.5 0.51 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1710639 1710640
MS MSD
92293293007
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND
.5 .5 0.53 0.53 105 105 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1710641 1710642
MS MSD
92293408004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.52 0.52 104 104 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/19/2016 04:55 PM without the written consent of Pace Analytical Services, Inc..
Page 18 of 24

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
09Q�Iji�c&fir&e. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040242
Pace Project No.: 92293408
QC Batch: WETA/56898
Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7
Analysis Description: Chromium,
Hexavalent IC
Associated Lab Samples: 92293408001, 92293408002,
92293408003, 92293408005
METHOD BLANK: 1542723
Matrix: Water
Associated Lab Samples: 92293408001, 92293408002,
92293408003, 92293408005
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chromium, Hexavalent ug/L
ND 0.030
04/15/16 15:33
LABORATORY CONTROL SAMPLE: 1542724
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chromium, Hexavalent ug/L
.075 0.066
88 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1542725 1542726
MS MSD
92293293006
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L 0.0111
.025 .025 0.033
.026J 86 60 85-115 20 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1542727 1542728
MS MSD
92293408003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND .075 .075 0.071 0.076 94 102 85-115 8 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/19/2016 04:55 PM without the written consent of Pace Analytical Services, Inc..
Page 19 of 24

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098nnfir&e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040242
Pace Project No.: 92293408
QC Batch: WETA/56918 Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC
Associated Lab Samples: 92293408004
METHOD BLANK: 1544166 Matrix: Water
Associated Lab Samples: 92293408004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chromium, Hexavalent ug/L ND 0.030 04/18/16 09:15
LABORATORY CONTROL SAMPLE: 1544167
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chromium, Hexavalent ug/L .075 0.078 104 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1544168 1544169
MS MSD
92293408004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L 0.75 .12 .12 0.80 0.81 41 52 85-115 2 20 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1544170 1544171
MS MSD
92293525003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND .075 .075 0.087 0.064 116 85 85-115 30 20 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/19/2016 04:55 PM without the written consent of Pace Analytical Services, Inc..
Page 20 of 24

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onfir&e. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J16040242
Pace Project No.: 92293408
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-M Pace Analytical Services - Minneapolis
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/19/2016 04:55 PM without the written consent of Pace Analytical Services, Inc.. Page 21 of 24

acmnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
ogp I gc&f606e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16040242
Pace Project No.: 92293408
Lab ID Sample ID QC Batch Method QC Batch
92293408001
2016010154
RSK 175
AIR/25691
92293408002
2016010155
RSK 175
AIR/25691
92293408004
2016010157
RSK 175
AIR/25691
92293408005
2016010158
RSK 175
AIR/25691
92293408006
2016010161
RSK 175
AIR/25691
92293408001
2016010154
SM 2320B
WET/44242
92293408002
2016010155
SM 2320B
WET/44242
92293408003
2016010156
SM 2320B
WET/44242
92293408004
2016010157
SM 2320B
WET/44242
92293408005
2016010158
SM 2320B
WET/44242
92293408006
2016010161
SM 2320B
WET/44242
92293408001
2016010154
SM 4500-S2D
WET/44258
92293408002
2016010155
SM 4500-S2D
WET/44258
92293408003
2016010156
SM 4500-S2D
WET/44258
92293408004
2016010157
SM 4500-S2D
WET/44258
92293408005
2016010158
SM 4500-S2D
WET/44258
92293408006
2016010161
SM 4500-S2D
WET/44258
92293408001
2016010154
EPA 218.7
WETA/56898
92293408002
2016010155
EPA 218.7
WETA/56898
92293408003
2016010156
EPA 218.7
WETA/56898
92293408004 2016010157 EPA 218.7 WETA/56918
92293408005 2016010158 EPA 218.7 WETA/56898
Date: 04/19/2016 04:55 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 22 of 24

Document Name: Document Revised: 18FEB2016
�JceAnalXicale Sample Condition Upon Receipt(SCUR) Page 1 of 2
Document No.: Issuing Authority: Page 58 of 6
F-CHR-CS-003-rev.18 Pace Huntersville Quality Office
Client Name: 3 wko—, `y`"`'�r3/ �i of ° d�d!'!,'293_408
ReceiptG' V Project
Courier: ❑Fed Ex ❑UPS ❑LISPS ❑Client
[] Commercial Pace ❑Other: 9t283.408
Custody Seal Present? []Yes gNo Seals intact? Dyes NNo - � r /'41,6
Date/Initials Person Examining Contents: i-
Packing Material: []Bubble Wrap Bubble Bags ❑None [-]Other:
Thermometer: (tT1505 ❑ Type of Ice: Wet []Blue ❑None ❑Samples on ice, cooling process has begun
Correction Factor: 0.0°C Cooler Temp Corrected (°C): Biological Tissue Frozen? []Yes �ENo ❑N/A
Temp should be above freezing to 6°C
USDA Regulated Soil (❑ N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (Internationally,
IlYes 17INo Includine Hawaii and Puerto Rlcol? FlYes rMNo
COMMENTS:
Chain of Custody Present?
poyes
❑No
El N/A
1.
Chain of Custody Filled Out?
NYes
[]NO
[I N/A
2.
Chain of Custody Relinquished?
KYes
❑No
[I N/A
3.
Sampler Name and/or Signature on COC?
❑Yes
19NO
❑N/A
4.
Samples Arrived within Hold Time?
Kyes
❑No
❑N/A
S.
Short Hold Time Analysis (<72 hr.)?
t,-Yes
40
N/ i
6.
Rush Turn Around Time Requested?
❑Yes
WHo
❑N/A
7.
StlfficientVol ume?
Yes
❑No
❑N/A
8.
Correct Containers Used?
WYes
❑No
❑N/A
9.
Pace Containers Used?
Yes
WNo
[—]N/A
Containers Intact?
50yes
❑No
El N/A
10.
Filtered Volume Received for Dissolved Tests?
❑Yes
QqNo
❑N/A
11. Note if sediment is visible in the dissolved container
Sample Labels Match COC?
MYes
❑No
❑N/A
12.
-Includes Date/Time/ID/Analysis Matrix: W C
All containers needing acid/base preservation have been
13.
checked?
Pes
❑No
❑N/A
All. containers needing preservation are found to be in
compliance with EPA recommendation?
(14IV03, H2SO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide)
PCs
❑No
❑N/A
Exceptions: VOA, Coliform, TOC, Oil and Grease,
DRO/801S (water) DOC,LLHg
❑Yes
No
❑N/A
Samples checked for dechlorination
Dyes
No
❑N/A
14.
Headspace in VOA Vials (>5-6mm)?
❑Yes
No
❑N/A
15.
Trip Blank Present?
❑Yes
PNo
❑N/A
16,
Trip Blank Custody Seals Present?
❑Yes
® No
rr
❑N/A
Pace Trip Blank Lot 0 (if purchased):
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Resolution:
Date/Time:
Field Data Required? [-]Yes [-]NO
Project Manager SCURF Review: Date: L(�f� lb
Project Manager SRF Review: Date: q)+a 110
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
-Out of hold, incorrect preservative, out of temp, incorrect containers)
Page 23 of 24

Page 59 of 60
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