NC0000396_J16040163 Report_20160831

DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J16040163
Project Name: ASHEVILLE - AB GW ASSESSMENT WATER
Customer Name(s): Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Customer Address: 200 CP and L Drive
Arden,NC 28704
Lab Contact: Mary Ann Ogle Digitally signed b?hone: 980-875-5274
Mary Ann Ogle
Report Authorized By: ii Date: 2016.04.18 Date: 4/18/2016
(Signature) C/ 17:04:46-04'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Page 1 of 54
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2016009888
2016009889
2016009890
2016009891
2016009892
2016009893
6 Total Samples
Collected By
Sample Description
ASHEVILLE
07-Apr-16 9:44 AM
illegible
CB-1
ASHEVILLE
07-Apr-16 12:12 PM
illegible
MW-11
ASHEVILLE
07-Apr-16 1:42 PM
illegible
MW-11D
ASHEVILLE
07-Apr-16 3:22 PM
illegible
MW-15A
ASHEVILLE
07-Apr-16
illegible
Filter Blank
ASHEVILLE
07-Apr-16 4:20 PM
illegible
Equipment Blank
Page 2 of 54

Page 3 of 54
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
OV Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 4/18/2016

Certificate of Laboratory Analysis Page 4 of 54
This report shall not be reproduced, except in full.
Order # J16040163
Site: CB-1
Collection Date: 07-Apr-16 9:44 AM
Analyte Result Units Qualifiers RDL
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.399 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.047
mg/L
0.005
Barium (Ba)
0.016
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.022
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
0.031
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.85
ug/L
1
Copper(Cu)
11.2
ug/L
1
Lead (Pb)
1.53
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.27
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Total Carbon
TOC
0.121
mg/L
0.1
Sample #: 2016009888
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
1 EPA 353.2 04/09/2016 12:30 LSTARL1
Vendor Method V_PACE
1 EPA 245.1
04/11/2016 14:33
DMFRANC
1 EPA 200.7
04/09/2016 12:08
JJMACKE
1 EPA 200.7
04/09/2016 12:08
JJMACKE
1 EPA 200.7
04/09/2016 12:08
JJMACKE
1 EPA 200.7
04/09/2016 12:08
JJMACKE
1 EPA 200.7
04/09/2016 12:08
JJMACKE
1 EPA 200.7
04/09/2016 12:08
JJMACKE
1 EPA 200.7
04/09/2016 12:08
JJMACKE
1 EPA 200.8
04/10/2016 17:35
MHALL3
1 EPA 200.8
04/10/2016 17:35
MHALL3
1 EPA 200.8
04/10/2016 17:35
MHALL3
1 EPA 200.8
04/10/2016 17:35
MHALL3
1 EPA 200.8
04/10/2016 17:35
MHALL3
1 EPA 200.8
04/10/2016 17:35
MHALL3
1 EPA 200.8
04/10/2016 17:35
MHALL3
1 EPA 200.8
04/10/2016 17:35
MHALL3
1 EPA 200.8
04/10/2016 17:35
MHALL3
1 EPA 200.8
04/10/2016 17:35
MHALL3
1 EPA 200.8
04/10/2016 17:35
MHALL3
1 EPA 200.8
04/10/2016 17:35
MHALL3
1 EPA 200.8
04/10/2016 17:35
MHALL3
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
1 SM5310C/EPA9060A 04/08/201614:05 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
Site: MW-11
Collection Date: 07-Apr-16 12:12 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 1.4 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
97
mg/L
2
Sulfate
28
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.076
mg/L
0.005
Barium (Ba)
0.078
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.011
mg/L
0.01
Manganese (Mn)
0.177
mg/L
0.005
Strontium (Sr)
0.119
mg/L
0.005
Zinc (Zn)
0.018
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
23.8
mg/L
0.01
Magnesium (Mg)
11.4
mg/L
0.005
Potassium (K)
1.07
mg/L
0.1
Sodium (Na)
38.4
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.098
mg/L
0.005
Barium (Ba)
0.088
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.281
mg/L
0.005
Strontium (Sr)
0.125
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016009889
Matrix: GW_WW
Page 5 of 54
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/09/2016 12:31 LSTARL1
Vendor Method V_PACE
20
EPA 300.0
04/12/2016 00:53
BGN9034
10
EPA 300.0
04/12/2016 00:53
BGN9034
1
EPA 245.1
04/11/2016 13:25
DMFRANC
1
EPA 245.1
04/11/2016 14:35
DMFRANC
1
EPA 200.7
04/09/2016 12:12
JJMACKE
1
EPA 200.7
04/09/2016 12:12
JJMACKE
1
EPA 200.7
04/09/2016 12:12
JJMACKE
1
EPA 200.7
04/09/2016 12:12
JJMACKE
1
EPA 200.7
04/09/2016 12:12
JJMACKE
1
EPA 200.7
04/09/2016 12:12
JJMACKE
1
EPA 200.7
04/09/2016 12:12
JJMACKE
1
EPA 200.7
04/08/2016 11:54
JJMACKE
1
EPA 200.7
04/08/2016 11:54
JJMACKE
1
EPA 200.7
04/08/2016 11:54
JJMACKE
1
EPA 200.7
04/08/2016 11:54
JJMACKE
1
EPA 200.7
04/11/2016 15:39
JJMACKE
1
EPA 200.7
04/11/2016 15:39
JJMACKE
1
EPA 200.7
04/11/2016 15:39
JJMACKE
1
EPA 200.7
04/11/2016 15:39
JJMACKE
1
EPA 200.7
04/11/2016 15:39
JJMACKE
1
EPA 200.7
04/11/2016 15:39
JJMACKE
1
EPA 200.7
04/11/2016 15:39
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
Site: MW-11
Collection Date: 07-Apr-16 12:12 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
1.72
ug/L
Cobalt (Co)
1.02
ug/L
Copper (Cu)
5.72
ug/L
Lead (Pb)
1.57
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
1.40
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
2.89
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
2.54
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
220
mg/L
Total Carbon
TOC
1.1
mg/L
Page 6 of 54
Sample #:
2016009889
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/10/2016 17:57
MHALL3
1
1
EPA 200.8
04/10/2016 17:57
MHALL3
1
1
EPA 200.8
04/10/2016 17:57
MHALL3
1
1
EPA 200.8
04/10/2016 17:57
MHALL3
1
1
EPA 200.8
04/10/2016 17:57
MHALL3
1
1
EPA 200.8
04/10/2016 17:57
MHALL3
1
1
EPA 200.8
04/10/2016 17:57
MHALL3
1
1
EPA 200.8
04/10/2016 17:57
MHALL3
1
1
EPA 200.8
04/10/2016 17:57
MHALL3
1
1
EPA 200.8
04/10/2016 17:57
MHALL3
1
1
EPA 200.8
04/10/2016 17:57
MHALL3
0.2
1
EPA 200.8
04/10/2016 17:57
MHALL3
0.3
1
EPA 200.8
04/10/2016 17:57
MHALL3
1
1
EPA 200.8
04/09/2016 16:59
MHALL3
1
1
EPA 200.8
04/09/2016 16:59
MHALL3
1
1
EPA 200.8
04/09/2016 16:59
MHALL3
1
1
EPA 200.8
04/09/2016 16:59
MHALL3
1
1
EPA 200.8
04/09/2016 16:59
MHALL3
1
1
EPA 200.8
04/09/2016 16:59
MHALL3
1
1
EPA 200.8
04/09/2016 16:59
MHALL3
1
1
EPA 200.8
04/09/2016 16:59
MHALL3
1
1
EPA 200.8
04/09/2016 16:59
MHALL3
1
1
EPA 200.8
04/09/2016 16:59
MHALL3
1
1
EPA 200.8
04/09/2016 16:59
MHALL3
0.2
1
EPA 200.8
04/09/2016 16:59
MHALL3
0.3
1
EPA 200.8
04/09/2016 16:59
MHALL3
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
25
1
SM2540C
04/13/201613:02
PARMSTR
0.1
1
SM5310C/EPA9060A
04/08/201614:05
CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
Site: MW-11
Collection Date: 07-Apr-16 12:12 PM
Analyte Result
TOTAL SUSPENDED SOLIDS
TSS < 5
Units Qualifiers RDL DF
mg/L 5 1
Page 7 of 54
Sample #: 2016009889
Matrix: GW WW
Method Analysis Date/Time Analyst
SM2540D 04/13/201610:30 PARMSTR

Certificate of Laboratory Analysis Page 8 of 54
This report shall not be reproduced, except in full.
Order # J16040163
Site: MW-11 D
Collection Date: 07-Apr-16 1:42 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 2.4 mg-N/L 0.05
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
160
mg/L
2.5
Sulfate
13
mg/L
0.5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.117
mg/L
0.005
Barium (Ba)
0.304
mg/L
0.005
Boron (B)
0.059
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.142
mg/L
0.005
Strontium (Sr)
0.339
mg/L
0.005
Zinc (Zn)
0.019
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
33.0
mg/L
0.01
Magnesium (Mg)
14.4
mg/L
0.005
Potassium (K)
3.71
mg/L
0.1
Sodium (Na)
42.9
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.161
mg/L
0.005
Barium (Ba)
0.307
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.074
mg/L
0.01
Manganese (Mn)
0.140
mg/L
0.005
Strontium (Sr)
0.326
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016009890
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
5 EPA 353.2 04/09/2016 12:43 LSTARL1
Vendor Method V_PACE
25
EPA 300.0
04/12/2016 02:32
BGN9034
5
EPA 300.0
04/12/2016 02:32
BGN9034
1
EPA 245.1
04/11/2016 13:27
DMFRANC
1
EPA 245.1
04/11/2016 14:38
DMFRANC
1
EPA 200.7
04/09/2016 12:16
JJMACKE
1
EPA 200.7
04/09/2016 12:16
JJMACKE
1
EPA 200.7
04/09/2016 12:16
JJMACKE
1
EPA 200.7
04/09/2016 12:16
JJMACKE
1
EPA 200.7
04/09/2016 12:16
JJMACKE
1
EPA 200.7
04/09/2016 12:16
JJMACKE
1
EPA 200.7
04/09/2016 12:16
JJMACKE
1
EPA 200.7
04/08/2016 11:58
JJMACKE
1
EPA 200.7
04/08/2016 11:58
JJMACKE
1
EPA 200.7
04/08/2016 11:58
JJMACKE
1
EPA 200.7
04/08/2016 11:58
JJMACKE
1
EPA 200.7
04/11/2016 16:10
JJMACKE
1
EPA 200.7
04/11/2016 16:10
JJMACKE
1
EPA 200.7
04/11/2016 16:10
JJMACKE
1
EPA 200.7
04/11/2016 16:10
JJMACKE
1
EPA 200.7
04/11/2016 16:10
JJMACKE
1
EPA 200.7
04/11/2016 16:10
JJMACKE
1
EPA 200.7
04/11/2016 16:10
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
Site: MW-11 D
Collection Date: 07-Apr-16 1:42 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
8.85
ug/L
Lead (Pb)
1.73
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
1.01
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
380
mg/L
Total Carbon
TOC
0.429
mg/L
Page 9 of 54
Sample #:
2016009890
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/10/2016 18:02
MHALL3
1
1
EPA 200.8
04/10/2016 18:02
MHALL3
1
1
EPA 200.8
04/10/2016 18:02
MHALL3
1
1
EPA 200.8
04/10/2016 18:02
MHALL3
1
1
EPA 200.8
04/10/2016 18:02
MHALL3
1
1
EPA 200.8
04/10/2016 18:02
MHALL3
1
1
EPA 200.8
04/10/2016 18:02
MHALL3
1
1
EPA 200.8
04/10/2016 18:02
MHALL3
1
1
EPA 200.8
04/10/2016 18:02
MHALL3
1
1
EPA 200.8
04/10/2016 18:02
MHALL3
1
1
EPA 200.8
04/10/2016 18:02
MHALL3
0.2
1
EPA 200.8
04/10/2016 18:02
MHALL3
0.3
1
EPA 200.8
04/10/2016 18:02
MHALL3
1
1
EPA 200.8
04/09/2016 16:10
MHALL3
1
1
EPA 200.8
04/09/2016 16:10
MHALL3
1
1
EPA 200.8
04/09/2016 16:10
MHALL3
1
1
EPA 200.8
04/09/2016 16:10
MHALL3
1
1
EPA 200.8
04/09/2016 16:10
MHALL3
1
1
EPA 200.8
04/09/2016 16:10
MHALL3
1
1
EPA 200.8
04/09/2016 16:10
MHALL3
1
1
EPA 200.8
04/09/2016 16:10
MHALL3
1
1
EPA 200.8
04/09/2016 16:10
MHALL3
1
1
EPA 200.8
04/09/2016 16:10
MHALL3
1
1
EPA 200.8
04/09/2016 16:10
MHALL3
0.2
1
EPA 200.8
04/09/2016 16:10
MHALL3
0.3
1
EPA 200.8
04/09/2016 16:10
MHALL3
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
25
1
SM2540C
04/13/201613:02
PARMSTR
0.1
1
SM5310C/EPA9060A
04/08/201614:05
CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
Site: MW-11 D
Collection Date: 07-Apr-16 1:42 PM
Analyte Result
TOTAL SUSPENDED SOLIDS
TSS < 5
Units Qualifiers RDL DF
mg/L 5 1
Page 10 of 54
Sample #: 2016009890
Matrix: GW_WW
Method Analysis Date/Time Analyst
SM2540D 04/13/201610:30 PARMSTR

Certificate of Laboratory Analysis Page 11 of 54
This report shall not be reproduced, except in full.
Order # J16040163
Site: MW-15A
Collection Date: 07-Apr-16 3:22 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.132 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
36
mg/L
1
Sulfate
4.8
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.108
mg/L
0.005
Barium (Ba)
0.080
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.058
mg/L
0.01
Manganese (Mn)
0.727
mg/L
0.005
Strontium (Sr)
0.090
mg/L
0.005
Zinc (Zn)
0.018
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
6.26
mg/L
0.01
Magnesium (Mg)
3.97
mg/L
0.005
Potassium (K)
0.898
mg/L
0.1
Sodium (Na)
11.0
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.121
mg/L
0.005
Barium (Ba)
0.083
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.063
mg/L
0.01
Manganese (Mn)
0.673
mg/L
0.005
Strontium (Sr)
0.090
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016009891
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/09/2016 12:33 LSTARL1
Vendor Method V_PACE
10 EPA 300.0
04/12/2016 02:48
BGN9034
1 EPA 300.0
04/12/2016 02:48
BGN9034
1 EPA 245.1
04/11/2016 13:30
DMFRANC
1 EPA 245.1
04/11/2016 14:40
DMFRANC
1 EPA 200.7
04/09/2016 12:35
JJMACKE
1 EPA 200.7
04/09/2016 12:35
JJMACKE
1 EPA 200.7
04/09/2016 12:35
JJMACKE
1 EPA 200.7
04/09/2016 12:35
JJMACKE
1 EPA 200.7
04/09/2016 12:35
JJMACKE
1 EPA 200.7
04/09/2016 12:35
JJMACKE
1 EPA 200.7
04/09/2016 12:35
JJMACKE
1 EPA 200.7
04/08/2016 12:02
JJMACKE
1 EPA 200.7
04/08/2016 12:02
JJMACKE
1 EPA 200.7
04/08/2016 12:02
JJMACKE
1 EPA 200.7
04/08/2016 12:02
JJMACKE
1 EPA 200.7
04/11/2016 16:14
JJMACKE
1 EPA 200.7
04/11/2016 16:14
JJMACKE
1 EPA 200.7
04/11/2016 16:14
JJMACKE
1 EPA 200.7
04/11/2016 16:14
JJMACKE
1 EPA 200.7
04/11/2016 16:14
JJMACKE
1 EPA 200.7
04/11/2016 16:14
JJMACKE
1 EPA 200.7
04/11/2016 16:14
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
Site: MW-15A
Collection Date: 07-Apr-16 3:22 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
8.43
ug/L
Lead (Pb)
1.62
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
69
mg/L
Total Carbon
TOC
0.334
mg/L
Page 12 of 54
Sample #:
2016009891
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/10/2016 18:08
MHALL3
1
1
EPA 200.8
04/10/2016 18:08
MHALL3
1
1
EPA 200.8
04/10/2016 18:08
MHALL3
1
1
EPA 200.8
04/10/2016 18:08
MHALL3
1
1
EPA 200.8
04/10/2016 18:08
MHALL3
1
1
EPA 200.8
04/10/2016 18:08
MHALL3
1
1
EPA 200.8
04/10/2016 18:08
MHALL3
1
1
EPA 200.8
04/10/2016 18:08
MHALL3
1
1
EPA 200.8
04/10/2016 18:08
MHALL3
1
1
EPA 200.8
04/10/2016 18:08
MHALL3
1
1
EPA 200.8
04/10/2016 18:08
MHALL3
0.2
1
EPA 200.8
04/10/2016 18:08
MHALL3
0.3
1
EPA 200.8
04/10/2016 18:08
MHALL3
1
1
EPA 200.8
04/09/2016 17:04
MHALL3
1
1
EPA 200.8
04/09/2016 17:04
MHALL3
1
1
EPA 200.8
04/09/2016 17:04
MHALL3
1
1
EPA 200.8
04/09/2016 17:04
MHALL3
1
1
EPA 200.8
04/09/2016 17:04
MHALL3
1
1
EPA 200.8
04/09/2016 17:04
MHALL3
1
1
EPA 200.8
04/09/2016 17:04
MHALL3
1
1
EPA 200.8
04/09/2016 17:04
MHALL3
1
1
EPA 200.8
04/09/2016 17:04
MHALL3
1
1
EPA 200.8
04/09/2016 17:04
MHALL3
1
1
EPA 200.8
04/09/2016 17:04
MHALL3
0.2
1
EPA 200.8
04/09/2016 17:04
MHALL3
0.3
1
EPA 200.8
04/09/2016 17:04
MHALL3
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
25
1
SM2540C
04/13/201613:02
PARMSTR
0.1
1
SM5310C/EPA9060A
04/08/201614:05
CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
Site: MW-15A
Collection Date: 07-Apr-16 3:22 PM
Analyte Result
TOTAL SUSPENDED SOLIDS
TSS < 5
Units Qualifiers RDL DF
mg/L 5 1
Page 13 of 54
Sample #: 2016009891
Matrix: GW_WW
Method Analysis Date/Time Analyst
SM2540D 04/13/201610:30 PARMSTR

Certificate of Laboratory Analysis Page 14 of 54
This report shall not be reproduced, except in full.
Order # J16040163
Site: Filter Blank
Collection Date: 07-Apr-16
Analyte
Result
Units Qualifiers
RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
5.01
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2016009892
Matrix: GW_WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
04/11/2016 14:43
DMFRANC
1
EPA 200.7
04/09/2016 12:46
JJMACKE
1
EPA 200.7
04/09/2016 12:46
JJMACKE
1
EPA 200.7
04/09/2016 12:46
JJMACKE
1
EPA 200.7
04/09/2016 12:46
JJMACKE
1
EPA 200.7
04/09/2016 12:46
JJMACKE
1
EPA 200.7
04/09/2016 12:46
JJMACKE
1
EPA 200.7
04/09/2016 12:46
JJMACKE
1
EPA 200.8
04/10/2016 18:13
MHALL3
1
EPA 200.8
04/10/2016 18:13
MHALL3
1
EPA 200.8
04/10/2016 18:13
MHALL3
1
EPA 200.8
04/10/2016 18:13
MHALL3
1
EPA 200.8
04/10/2016 18:13
MHALL3
1
EPA 200.8
04/10/2016 18:13
MHALL3
1
EPA 200.8
04/10/2016 18:13
MHALL3
1
EPA 200.8
04/10/2016 18:13
MHALL3
1
EPA 200.8
04/10/2016 18:13
MHALL3
1
EPA 200.8
04/10/2016 18:13
MHALL3
1
EPA 200.8
04/10/2016 18:13
MHALL3
1
EPA 200.8
04/10/2016 18:13
MHALL3
1
EPA 200.8
04/10/2016 18:13
MHALL3

Certificate of Laboratory Analysis Page 15 of 54
This report shall not be reproduced, except in full.
Order # J16040163
Site: Equipment Blank
Collection Date: 07-Apr-16 4:20 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
Calcium (Ca)
< 0.01
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2016009893
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2
04/09/2016 12:35
LSTARL1
1 EPA 300.0
04/11/2016 11:37
BGN9034
1 EPA 300.0
04/11/2016 11:37
BGN9034
1 EPA 245.1
04/11/2016 13:32
DMFRANC
1 EPA 200.7
04/08/2016 12:06
JJMACKE
1 EPA 200.7
04/08/2016 12:06
JJMACKE
1 EPA 200.7
04/08/2016 12:06
JJMACKE
1 EPA 200.7
04/08/2016 12:06
JJMACKE
1 EPA 200.7
04/11/2016 16:18
JJMACKE
1 EPA 200.7
04/11/2016 16:18
JJMACKE
1 EPA 200.7
04/11/2016 16:18
JJMACKE
1 EPA 200.7
04/11/2016 16:18
JJMACKE
1 EPA 200.7
04/11/2016 16:18
JJMACKE
1 EPA 200.7
04/11/2016 16:18
JJMACKE
1 EPA 200.7
04/11/2016 16:18
JJMACKE
1 EPA 200.8
04/09/2016 17:09
MHALL3
1 EPA 200.8
04/09/2016 17:09
MHALL3
1 EPA 200.8
04/09/2016 17:09
MHALL3
1 EPA 200.8
04/09/2016 17:09
MHALL3
1 EPA 200.8
04/09/2016 17:09
MHALL3
1 EPA 200.8
04/09/2016 17:09
MHALL3
1 EPA 200.8
04/09/2016 17:09
MHALL3
1 EPA 200.8
04/09/2016 17:09
MHALL3
1 EPA 200.8
04/09/2016 17:09
MHALL3
1 EPA 200.8
04/09/2016 17:09
MHALL3
1 EPA 200.8
04/09/2016 17:09
MHALL3
1 EPA 200.8
04/09/2016 17:09
MHALL3
1 EPA 200.8
04/09/2016 17:09
MHALL3
Vendor Method V_PACE

Site: Equipment Blank
Collection Date: 07-Apr-16 4:20 PM
Certificate of Laboratory Analysis Page 16 of 54
This report shall not be reproduced, except in full.
Order # J16040163
Sample #: 2016009893
Matrix: GW_WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.138 mg/L 0.1 1 SM5310C/EPA9060A 04/08/201614:05 CJELLIO
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 04/13/2016 10:30 PARMSTR

® Laboratories LLc
r17of54
a member of The GEL Group IN'.
April 14, 2016
Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078
Re: AB GW Assessment Water
Work Order: 394930
SDG: J16040163
Dear Mary:
PO Box 30712 Charleston, SC 29417
2040 Savage Road Charlestan. SC 25407
F 843.556.8171
F 843.766.1178
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on April 08, 2016. This original data report has been prepared and reviewed in accordance
with GEL's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.
Sincerely,
Lindsay Fabra
Project Manager
Purchase Order: 1142110 DPNNGO
Enclosures
gel.com

Page 18 of 54
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
for
DUP0002 Duke Energy
Client SDG: J16040163 GEL Work Order: 394930
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
N Metals --The Matrix spike sample recovery is not within specified control limits
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the 'U' qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
Reviewed by
JU,&Y ,
Page 2 of 15

GEL LABORATORIES LLC Page 19of54
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: April 14, 2016
Company: Duke Energy Analytical Laboratory
Address : 13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact: Mary Ann Ogle
Project: AB GW Assessment WaterClient prefers Chem and RadChem on the same CoA excluding the uncertainty value
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016009888
394930001
Water
07-APR-16 09:44
08-APR-16
Client
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-238 U ND
0.000067
0.0002
ug/mL
1
PRB 04/11/16
1824 1558577 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1
PRB 04/12/16
1224 1558577 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 U ND
1.45
3.00
pCi/L
AXM6 04/14/16
1126 1558649 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 14.4
0.801
1.00
pCi/L
CXP3 04/14/16
0850 1558609 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JXM5
04/11/16
0800
1558576
The following Analytical Methods were performed:
Method Description Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 92.4 (15%-125%)
Notes:
Page 3 of 15

GEL LABORATORIES LLC Page 20 of 54
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: April 14, 2016
Company: Duke Energy Analytical Laboratory
Address : 13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact: Mary Ann Ogle
Project: AB GW Assessment WaterClient prefers Chem and RadChem on the same CoA excluding the uncertainty value
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016009889
394930002
Water
07-APR-16 12:12
08-APR-16
Client
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-238 U ND
0.000067
0.0002
ug/mL
1
PRB 04/11/16
1826 1558577 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1
PRB 04/12/16
1225 1558577 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 2.19
1.46
3.00
pCi/L
AXM6 04/14/16
1124 1558649 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 1.31
0.755
1.00
pCi/L
CXP3 04/14/16
0920 1558609 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JXM5
04/11/16
0800
1558576
The following Analytical Methods were performed:
Method Description Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 88.9 (15%-125%)
Notes:
Page 4 of 15

GEL LABORATORIES LLC Page21 of54
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: April 14, 2016
Company: Duke Energy Analytical Laboratory
Address : 13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact: Mary Ann Ogle
Project: AB GW Assessment WaterClient prefers Chem and RadChem on the same CoA excluding the uncertainty value
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016009890
394930003
Water
07-APR-16 13:42
08-APR-16
Client
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-238 J 0.0000844
0.000067
0.0002
ug/mL
1
PRB 04/11/16
1828 1558577 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1
PRB 04/12/16
1227 1558577 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 U ND
1.42
3.00
pCi/L
AXM6 04/14/16
1124 1558649 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 3.53
0.814
1.00
pCi/L
CXP3 04/14/16
0920 1558609 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JXM5
04/11/16
0800
1558576
The following Analytical Methods were performed:
Method Description Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 100 (15%-125%)
Notes:
Page 5 of 15

GEL LABORATORIES LLC Page 22 of 54
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: April 14, 2016
Company: Duke Energy Analytical Laboratory
Address : 13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact: Mary Ann Ogle
Project: AB GW Assessment WaterClient prefers Chem and RadChem on the same CoA excluding the uncertainty value
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016009891
394930004
Water
07-APR-16 15:22
08-APR-16
Client
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-238 U ND
0.000067
0.0002
ug/mL
1
PRB 04/11/16
1829 1558577 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1
PRB 04/12/16
1229 1558577 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 U ND
1.44
3.00
pCi/L
AXM6 04/14/16
1124 1558649 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 1.76
0.678
1.00
pCi/L
CXP3 04/14/16
0920 1558609 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JXM5
04/11/16
0800
1558576
The following Analytical Methods were performed:
Method Description Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 100 (15%-125%)
Notes:
Page 6of15

Page 23 of 54
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina
Contact: Mary Ann Ogle
Workorder: 394930
Report Date: April 14, 2016
Page 1 of 3
Parmname
NOM
Sample
Qual
QC
Units
RPD%o
REC%
Range Anlst
Date Time
Metals Analysis - ICPMS
Batch 1558577
QC1203524851
394929001
DUP
Uranium-233
U
ND
U
ND
ug/mL
N/A
PRB
04/12/1612:10
Uranium-234
U
ND
U
ND
ug/mL
N/A
Uranium-236
U
ND
U
ND
ug/mL
N/A
Uranium-238
0.000932
0.000986
ug/mL
5.61 ^
(+/-0.0002)
04/11/1618:09
QC1203524849
LCS
Uranium-238
0.0496
0.0531
ug/mL
107
(80%-120%)
04/11/1618:06
QC1203524850
LCS
Uranium-233
0.0005
0.000511
ug/mL
102
(80%-120%)
04/12/1612:06
Uranium-234
0.00055
0.000595
ug/mL
108
(80%-120%)
Uranium-236
0.005
0.0054
ug/mL
108
(80%-120%)
QC1203524848
MB
Uranium-233
U
ND
ug/mL
04/12/1612:05
Uranium-234
U
ND
ug/mL
Uranium-236
U
ND
ug/mL
Uranium-238
U
ND
ug/mL
04/11/1618:04
QC1203524852
394929001
MS
Uranium-238
0.0496
0.000932
0.0518
ug/mL
102
(75%-125%)
04/11/1618:11
QC1203524853
394929001
MS
Uranium-233
0.0005
U
ND
0.000512
ug/mL
102
(75%-125%)
04/12/1612:12
Uranium-234
0.00055
U
ND
0.000598
ug/mL
109
(75%-125%)
Uranium-236
0.005
U
ND
0.00525
ug/mL
105
(75%-125%)
QC1203524854
394929001
SDILT
Uranium-233
U
ND
U
ND
ug/L
N/A
04/12/1612:13
Page 7 of 15

Page 24 of 54
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 394930
Page 2 of 3
Parmname
NOM
Sample
Qual
QC
Units
RPD%
REC%
Range Anlst
Date Time
Metals Analysis - ICPMS
Batch 1558577
Uranium-234
U
ND
U
ND
ug/L
N/A
Uranium-236
U
ND
U
ND
ug/L
N/A
(0%-10%) PRB
04/12/1612:13
Uranium-238
0.932
J
0.190
ug/L
1.89
(0%-10%)
04/11/1618:14
Rad Gas Flow
Batch 1558649
QC1203525064 394929003 DUP
Radium-228
1.67
3.05
pCi/L
58.7
(0% - 100%) AXM6
04/14/16 11:26
QC1203525065 LCS
Radium-228
46.6
43.0
pCi/L
92.3
(75%-125%)
04/14/1611:26
QC1203525063 MB
Radium-228
U
0.950
pCi/L
04/14/1611:26
Rad Ra-226
Batch 1558609
QC1203524945 394929001 DUP
Radium-226
2.16
1.07
pCi/L
67.4
(0% - 100%) CXP3
04/14/16 09:20
QC1203524947 LCS
Radium-226
24.4
23.1
pCi/L
94.5
(75%-125%)
04/14/16 09:55
QC1203524944 MB
Radium-226
U
0.112
pCi/L
04/14/16 09:20
QC1203524946 394929001 MS
Radium-226
122
2.16
116
DCi/L
93.3
(75%-125%)
04/14/16 09:55
Notes:
The Qualifiers in this report are defined as follows:
** Analyte is a Tracer compound
< Result is less than value reported
> Result is greater than value reported
BD Results are either below the MDC or tracer recovery is low
E %difference of sample and SD is >10%. Sample concentration must meet flagging criteria
FA Failed analysis.
FB Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
H Analytical holding time was exceeded
Page 8 of 15

Page 25 of 54
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 394930
Parmname NOM Sample Qual QC Units RPD%o REC'%
Page 3 of 3
Range Anlst Date Time
J Value is estimated
K Analyte present. Reported value may be biased high. Actual value is expected to be lower.
L Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M M if above MDC and less than LLD
M REMP Result > MDC/CL and < RDL
N Metals --The Matrix spike sample recovery is not within specified control limits
N/A RPD or %Recovery limits do not apply.
N1 See case narrative
ND Analyte concentration is not detected above the detection limit
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
R Sample results are rejected
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
UI Gamma Spectroscopy --Uncertain identification
UJ Gamma Spectroscopy --Uncertain identification
UL Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Y Other specific qualifiers were required to properly define the results. Consult case narrative.
^ RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
h Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
Page 9 of 15

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Page 10 of 15

ry I Laboratories Page 27 of 54
uc
SAMPLE RECEIPT & REVIEW FORM
I Hazard Information
pies marked as radioactive?
Radioactive U or III by RSO?
pies marked containing PCBs?
:OC andlor Sa nlks marked as .`
ar:asbestos`containing?`:
Sill
ped as a DOT Hazardous?
Sam
les identified as Foreign Soil?
Sample Receipt Criteria
1
Shipping containers received intact and
sealed?
2
Samples requiring cold preservation
within (0 < 6 deg. C)?*
2a
Daily check performed and passed on IR
temperature gun?
3
Chain of custody documents included
j
with shipment?
f
4
Sample containers intact and sealed?
f
S
Samples requiring chemical preservation,
at proper pH?
6
Do Low Level Perchlorate samples have
heads ace as required?
7
VOA vials contain acid preservation?
8
VOA vials free of headspace (defined as
< 6mm bubble)?
9
Are Encore containers present?
10
Samples received within holding time?
11
Sample ID's on COC match ID's on
bottles?
12
Date & time on COC'match date &time
/
on bottles?
l
13
Number of containers received match
f
number indicated on COC?
j
14
Are sample containers identifiable as
GEL provided?
15
COC form is properly signed in
16 Carrier and tracking number.
:omments (Use Continuation Form if needed):
..vrnv uer:Z Q 44 Q_-Zt"I —
Date Received: `
, j*If Net Counts > looepm o samples not marked "radioactive", contact the Radiation Safety Group for further
investigation.
./` mum Net Counts Observed* (Observed Counts -Area Background Caunts):
P yes, Were swipes taken of sample containers < action levels?
es •sam les:are to be 6; egated as,Safety•Controlled'Sam tes, an8'o ned by the{CEL;Safety Group,
,Hazard Class Shipped: UN#:
Comments/Qualifiers (Required for Non -Conforming Items)
Circle Applicable: Seals broken Damaged container Leaking container Other (describe)
Preservation Method: Ice bags Blue ice Dry ice one' Other (describe)
*all temperatures are recorded in Celsius jC
Temperature Device Serial #: l'
Secondary Temperature Device Serial # (If Applicable):
Leaking
Sample ID's, containers affected and observed pH:
/ Sample ID's and containers affected:
1
(If unknown, select No)
Sample ID's and containers affected:
(f (If Yes. immediately deliver to Volatiles laboratory)
ID's and tests affected:
Sample ID's and containers arr �,aa•
M0
Sample ID's affected:
FedEx Air FedEx Ground UPS Field Services \ Courier )Other
PM (or PMA) review: Initial `�' Date t3 �� Page I of
GL-CHL-SR-001 Rev 3
Page 11 of 15

Page 28 of 54
Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16040163
Work Order #: 394930
Metals
Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1558577
Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1558576
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
Client Sample Identification
394930001
2016009888
394930002
2016009889
394930003
2016009890
394930004
2016009891
1203524848
Method Blank (MB)ICP-MS
1203524849
Laboratory Control Sample (LCS)
1203524850
Laboratory Control Sample (LCS)
1203524854
394929001(2016009880L) Serial Dilution (SD)
1203524851
394929001(2016009880D) Sample Duplicate (DUP)
1203524852
394929001(2016009880S) Matrix Spike (MS)
1203524853
394929001(2016009880S) Matrix Spike (MS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.
Radiochemistry
Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1558649
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID# Client Sample Identification
394930001 2016009888
Page 12 of 15

Page 29 of 54
394930002 2016009889
394930003 2016009890
394930004 2016009891
1203525063 Method Blank (MB)
1203525064 394929003(2016009882) Sample Duplicate (DUP)
1203525065 Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summarv:
There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.
Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1558609
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
Client Sample Identification
394930001
2016009888
394930002
2016009889
394930003
2016009890
394930004
2016009891
1203524944
Method Blank (MB)
1203524945
394929001(2016009880) Sample Duplicate (DUP)
1203524946
394929001(2016009880) Matrix Spike (MS)
1203524947
Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summarv•
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Miscellaneous information
Additional Comments
The matrix spike, 1203524946 (2016009880MS), aliquot was reduced to conserve sample volume.
Page 13 of 15

Page 30 of 54
Certification Statement
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 14 of 15

Page 31 of 54
List of current GEL Certifications as of 14 April 2016
State
Certification
Alaska
UST-0110
Arkansas
88-0651
CLIA
42D0904046
California
2940
Colorado
SC00012
Connecticut
PH-0169
Delaware
SC00012
DoD ELAP/ ISO17025 A2LA
2567.01
Florida NELAP
E87156
Foreign Soils Permit
P330-15-00283, P330-15-00253
Georgia
SC00012
Georgia SDWA
967
Hawaii
SC00012
Idaho Chemistry
SC00012
Idaho Radiochemistry
SC00012
Illinois NELAP
200029
Indiana
C—SC-01
Kansas NELAP
E-10332
Kentucky SDWA
90129
Kentucky Wastewater
90129
Louisiana NELAP
03046 (A233904)
Louisiana SDWA
LA160006
Maryland
270
Massachusetts
M—SC012
Michigan
9976
Mississippi
SC00012
Nebraska
NE—OS-26-13
Nevada
SC000122016-1
New Hampshire NELAP
205415
New Jersey NELAP
SC002
New Mexico
SC00012
New York NELAP
11501
North Carolina
233
North Carolina SDWA
45709
North Dakota
R-158
Oklahoma
9904
Pennsylvania NELAP
68-00485
S.Carolina Radchem
10120002
South Carolina Chemistry
10120001
Tennessee
TN 02934
Texas NELAP
T104704235-16-11
Utah NELAP
SC000122016-20
Vermont
VT87156
Virginia NELAP
460202
Washington
C780
West Virginia
997404
Page 15 of 15

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098ninyewe. Suite 100
y Huntersville, INC 28078
[phone]
April 14, 2016
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 16040163
Pace Project No.: 92293130
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 08, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Anne Pifer
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 22

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
OQ9 l9scsf4w e. Suite 100
Huntersville, NC 28078
[phone]
Project: J16040163
Pace Project No.: 92293130
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A21-A Certification M 2926.01
Alaska Certification M UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification M 88-0680
California Certification M 01155CA
Colorado Certification #Pace
Connecticut Certification M PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification M 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification M 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification M 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification M 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification M E83079
Georgia Certification M 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification M 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification M E-10383
Louisiana Certification M FL NELAC Reciprocity
Louisiana Environmental Certificate M 05007
Maryland Certification: #346
Michigan Certification M 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification M Cert 0074
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE SUMMARY
Project: J16040163
Pace Project No.: 92293130
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92293130001
2016009888
Water
04/07/16 09:44
04/08/16 14:46
92293130002
2016009889
Water
04/07/1612:12
04/08/1614:46
92293130003
2016009890
Water
04/07/1613:42
04/08/1614:46
92293130004
2016009891
Water
04/07/1615:22
04/08/1614:46
92293130005
2016009893
Water
04/07/1616:20
04/08/1614:46
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16040163
92293130
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92293130001
2016009888
RSK 175
DR1
1
PASI-M
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92293130002
2016009889
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92293130003
2016009890
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92293130004
2016009891
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92293130005
2016009893
RSK 175
DR1
1
PASI-M
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
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Project: J16040163
Pace Project No.: 92293130
Lab Sample ID
Method
92293130002
SM 2320B
SM 2320B
EPA 218.7
92293130003
SM 2320B
SM 2320B
EPA 218.7
SUMMARY OF DETECTION
Client Sample ID
Parameters
2016009889
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
Chromium, Hexavalent
2016009890
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
Chromium, Hexavalent
Result
Units
25.0
mg/L
25.0
mg/L
0.41
ug/L
7.0 mg/L
7.0 mg/L
0.13 ug/L
REPORT OF LABORATORY ANALYSIS
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Report Limit Analyzed Qualifiers
5.0 04/11/1616:02
5.0 04/11/1616:02
0.060 04/14/16 08:22
5.0 04/11/1616:13
5.0 04/11/1616:13
0.030 04/13/1615:26
Page 5 of 22

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PROJECT NARRATIVE
Project: J16040163
Pace Project No.: 92293130
Method: RSK 175
Description: RSK 175 AIR Headspace
Client: Duke Energy
Date: April 14, 2016
General Information:
5 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16040163
Pace Project No.: 92293130
Method: SM 2320B
Description: 2320E Alkalinity
Client: Duke Energy
Date: April 14, 2016
General Information:
4 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16040163
Pace Project No.: 92293130
Method: SM 4500-S213
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: April 14, 2016
General Information:
5 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16040163
Pace Project No.: 92293130
Method: EPA 218.7
Description: Hexavalent Chromium by IC
Client: Duke Energy
Date: April 14, 2016
General Information:
4 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/56791
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92293144001,92293219004
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1538578)
• Chromium. Hexavalent
• MSD (Lab ID: 1538577)
• Chromium, Hexavalent
• MSD (Lab ID: 1538579)
• Chromium. Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16040163
Pace Project No.: 92293130
Sample: 2016009888
Lab ID: 92293130001 Collected:
04/07/16 09:44
Received: 04/08/16 14:46 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/12/16 20:46
74-82-8
4500S21) Sulfide Water
Analytical Method: SM 4500-S2D
Sulfide
ND mg/L
0.10
1
04/13/1617:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
04/13/16 15:00
18540-29-9
Date: 04/14/2016 03:30 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16040163
Pace Project No.: 92293130
Sample: 2016009889
Lab ID: 92293130002 Collected:
04/07/16 12:12
Received: 04/08/16 14:46 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/12/16 20:54
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
25.0 mg/L
5.0
1
04/11/16 16:02
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/11/16 16:02
Alkalinity, Total as CaCO3
25.0 mg/L
5.0
1
04/11/16 16:02
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/13/1617:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.41 ug/L
0.060
2
04/14/16 08:22
18540-29-9
Date: 04/14/2016 03:30 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16040163
Pace Project No.: 92293130
Sample: 2016009890
Lab ID: 92293130003 Collected:
04/07/16 13:42
Received: 04/08/16 14:46 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/12/16 21:03
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
7.0 mg/L
5.0
1
04/11/16 16:13
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/11/16 16:13
Alkalinity, Total as CaCO3
7.0 mg/L
5.0
1
04/11/16 16:13
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/13/1617:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.13 ug/L
0.030
1
04/13/16 15:26
18540-29-9
Date: 04/14/2016 03:30 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16040163
Pace Project No.: 92293130
Sample: 2016009891
Lab ID: 92293130004 Collected:
04/07/16 15:22
Received: 04/08/16 14:46 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/12/16 21:11
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
04/11/16 16:42
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/11/16 16:42
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
04/11/16 16:42
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/13/1617:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
04/13/16 15:39
18540-29-9
Date: 04/14/2016 03:30 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16040163
Pace Project No.: 92293130
Sample: 2016009893
Lab ID: 92293130005 Collected:
04/07/16 16:20
Received: 04/08/16 14:46 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/12/16 21:19 74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
04/11/16 16:51
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
04/11/16 16:51
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
04/11/16 16:51
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
04/13/1617:00 18496-25-8
Date: 04/14/2016 03:30 PM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J16040163
Pace Project No.: 92293130
QC Batch: AIR/25676
Analysis Method: RSK 175
QC Batch Method: RSK 175
Analysis Description: RSK 175 AIR HEADSPACE
Associated Lab Samples: 92293130001, 92293130002,
92293130003, 92293130004, 92293130005
METHOD BLANK: 2229612
Matrix: Water
Associated Lab Samples: 92293130001, 92293130002,
92293130003, 92293130004, 92293130005
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Methane
ug/L
ND 10.0 04/12/16 20:05
LABORATORY CONTROL SAMPLE & LCSD:
2229613
2229614
Spike LCS LCSD LCS LCSD
% Rec Max
Parameter
Units
Conc. Result Result % Rec % Rec
Limits RPD RPD Qualifiers
Methane
ug/L
60.7 58.8 61.6 97 102
85-115 5 20
SAMPLE DUPLICATE: 2230460
92293138002 Dup
Max
Parameter
Units
Result Result RPD
RPD Qualifiers
Methane
ug/L
3.9J 4.9J
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J16040163
Pace Project No.: 92293130
QC Batch: WET/44149 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92293130002, 92293130003, 92293130004, 92293130005
METHOD BLANK: 1706782
Matrix: Water
Associated Lab Samples: 92293130002, 92293130003, 92293130004, 92293130005
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Alkalinity, Carbonate (CaCO3)
mg/L
ND 5.0
04/11/16 14:33
Alkalinity, Total as CaCO3
mg/L
ND 5.0
04/11/16 14:33
Alkalinity, Bicarbonate (CaCO3)
mg/L
ND 5.0
04/11/16 14:33
LABORATORY CONTROL SAMPLE: 1706783
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 50.9 102 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1706784 1706785
MS MSD
92293023011 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 141 50 50 188 191 95 101 80-120 2 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1706786 1706787
MS MSD
92293138003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Alkalinity, Total as CaCO3 mg/L 36.4 50 50 85.7 85.8 99 99 80-120 0 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J16040163
Pace Project No.: 92293130
QC Batch: WET/44191 Analysis Method: SM 4500-S2D
QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92293130001, 92293130002, 92293130003, 92293130004, 92293130005
METHOD BLANK: 1708503 Matrix: Water
Associated Lab Samples: 92293130001, 92293130002, 92293130003, 92293130004, 92293130005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 04/13/1617:00
LABORATORY CONTROL SAMPLE: 1708504
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.52 104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1708505 1708506
MS MSD
92293023005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.46 0.46 91 91 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1708507 1708508
MS MSD
92293130003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.46 0.46 92 92 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J16040163
Pace Project No.: 92293130
QC Batch: WETA/56791 Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC
Associated Lab Samples: 92293130001, 92293130002, 92293130003, 92293130004
METHOD BLANK: 1538574 Matrix: Water
Associated Lab Samples: 92293130001, 92293130002, 92293130003, 92293130004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chromium, Hexavalent ug/L ND 0.030 04/13/16 13:42
LABORATORY CONTROL SAMPLE: 1538575
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chromium, Hexavalent ug/L .075 0.068 91 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1538576 1538577
MS MSD
92293144001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND .025 .025 .021J .02J 85 78 85-115 20 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1538578 1538579
MS MSD
92293219004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND .075 .075 0.058 0.059 77 78 85-115 2 20 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALIFIERS
Project: J16040163
Pace Project No.: 92293130
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-M Pace Analytical Services - Minneapolis
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/14/2016 03:30 PM without the written consent of Pace Analytical Services, Inc.. Page 19 of 22

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g invewe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16040163
Pace Project No.: 92293130
Lab ID Sample ID QC Batch Method QC Batch
92293130001
2016009888
RSK 175
AIR/25676
92293130002
2016009889
RSK 175
AIR/25676
92293130003
2016009890
RSK 175
AIR/25676
92293130004
2016009891
RSK 175
AIR/25676
92293130005
2016009893
RSK 175
AIR/25676
92293130002
2016009889
SM 2320B
WET/44149
92293130003
2016009890
SM 2320B
WET/44149
92293130004
2016009891
SM 2320B
WET/44149
92293130005
2016009893
SM 2320B
WET/44149
92293130001
2016009888
SM 4500-S2D
WET/44191
92293130002
2016009889
SM 4500-S2D
WET/44191
92293130003
2016009890
SM 4500-S2D
WET/44191
92293130004
2016009891
SM 4500-S2D
WET/44191
92293130005
2016009893
SM 4500-S2D
WET/44191
92293130001
2016009888
EPA 218.7
WETA/56791
92293130002
2016009889
EPA 218.7
WETA/56791
92293130003
2016009890
EPA 218.7
WETA/56791
92293130004
2016009891
EPA 218.7
WETA/56791
Date: 04/14/2016 03:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 20 of 22

Document Name: uocumemt neviseo:.Lsrtnzuio
Sample Condition Upon Receipt(SOUR) Page 1 of 2
aC8Aa7alyi~rCal Document No.: Issuing Authority:
F-CHR-CS-003-rev.18 Pace Huntersville Quality Once 2 of
Pa®a 7 of 7 fnr Infernal Ilse ONLY
Sampler p • Client Name: (��j♦' 129It.� 130
—Jeceiptf Project W0J� ° 910;.1 .. �
Courier: commercial ac ❑Fx ❑UPS ❑USPS ❑Client I� II I I III IIIII �� III ���
El e ❑other: 92293130
Custody Seal Present? ❑Yes ,- No Seals Intact? ❑Yes []No
date/Initials Person Examining Contents:���/��
Packing Material: ❑Bub le Wrap ubble Bags L]NoneX ❑Other:
Thermometer: 1505 ❑ Type of Ice: Wet []Blue []None OSapls on Ice, cooling process has begun
Correction Factor: O.O°C Cooler Temp Corrected (°C): 1 #j Biological Tissue Frozen? ❑Yes ❑No A
Temp should be above free ` to VC
USDA Regulat soil ( /A, water sample) /
Did samples iginate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (intern 'finally,
❑Yes No Including Hawaii and Puerto Rlco)? ❑Yes o
COMMENTS:
Chain of Custody Present?
es
❑No
❑N/A
1.
Chain of Custody Filled Out?
es
❑No
❑N/A
2.
Chain of Custody Relinquished?
0 es
[]No
❑N/A
3.
Sampler Name and/or Signature on COC?
126s
❑No
❑N/A
4.
Samples Arrived within Hold Time?
Yes
❑No
❑N/A
5.
Short Hold Time Analysis (<72 hr.)?
❑Yes
0110
❑N/A
67
Rush Turn Around Time Requested?
Oyes
o
❑N/A
7.
Sufficient Volume?
es
[:]No
❑N/A
8.
Correct Containers Used?
1145
[:]No
❑N/A
9.
-Pace Containers Used?
es
i�Vo
❑N/A
Containers Intact?
es
[:]No
❑N/A
10.
Filtered Volume Received for Dissolved Tests?
❑Yes
❑No
Elf /A
11. Note if sediment is visible in the dissolved container
Sample Labels Match COC?
es
❑No
❑N/A
12.
-Includes Date/Time/ID/Analysis Matrix:
All containers needing acid/base preservation have been
13.
checked?
2<1
❑No
❑N/A
All containers needing preservation are found to be in
compliance with EPA recommendation?
(HNO3i H2SO4, HCI<2s NaOH >9 Sulfide, NaOH>12 Cyanide)
es
❑No
❑N/A
Exceptions: VOA, Coliform, TOC, Oil and Grease,
DRO/8015 (water) DOC,LLHg
❑Yes
[]No
1/A
Samples checked for dechlorination
Q es
[]No
❑N/A
14,
Headspace in VOA Vials (>5-6mm)?
❑Yes
❑No
1306
15.
Trip Blank Present?
❑Yes
❑No
11i,
-Tr4p-0lank-ftstody-SealOres-ent?
[—]Yes
❑No
N/A —
Pace Trip Blank Lot # (if purchased):
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Resolution:
Date/Time:
Field Data Required? ❑Yes (:]No
Project Manager SCURF Review: 0 Date: g114
Project Manager SRF Review: mate: 110b
.Note: Wheneverthere is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
.Out of hold, incorrect preservative, out of temp, incorrect containers)
Page 21 of 22

Page 53 of 54
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ra
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i 0
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w
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rn
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175) Pace
.
.010
Cl, SO4,
TOC, Nitrate -
MI
Nitrite I 1-ij
rM
�w
Bicarbonate,
Ctistonier,
desired
Important:
please
turnaround
Indicate
Carbonate
ace
Sulfide l
fili
(V_Paco GL
10181 KaU I m (228 and 2 oy
Uranium M 17,
Z,
K-N
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1 0
0
CA
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3
r
(% Pace)
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below
M 1 0
z
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metals (0.45)
Dissolved
CS
metals (0.10)
C;
0
p
O
a
o
G
d
O
O
p
yr
Total Container
M
0 Q
10
Page 22 of 22

_ _CHAIN OF CUSTODY RECORD ,AND ANALYSIS REQUEST FORM Page 54 of 54
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