NC0000396_J16040148 Report_20160831

DUKE Analytical Laboratory Page 1of34
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J16040148
ASHEVILLE - AB GW ASSESSMENT WATER
Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
200 CP and L Drive
Arden,NC 28704
Mary Ann Ogle
Phone: [phone]
Digitally signed by Mary Ann
Ogle
Date: 2016.04.1816:34:42 Date:
-04'00'
Mary Ann Ogle
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
4/18/2016
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Page 2 of 34
Collection
Sample ID Plant/Station Date and Time Collected By
2016009799 ASHEVILLE
1 Total Samples
06-Apr-16 2:41 PM illegible
Sample Description
CB-9

Page 3 of 34
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
OV Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 4/18/2016

Certificate of Laboratory Analysis Page 4 of 34
This report shall not be reproduced, except in full.
Order # J16040148
Site: CB-9
Collection Date: 06-Apr-16 2:41 PM
Analyte Result Units Qualifiers RDL
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.251 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.022
mg/L
0.005
Barium (Ba)
0.026
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.033
mg/L
0.005
Strontium (Sr)
0.007
mg/L
0.005
Zinc (Zn)
0.033
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
10.6
ug/L
1
Lead (Pb)
1.56
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.50
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Total Carbon
TOC
0.161
mg/L
0.1
Sample #: 2016009799
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
1 EPA 353.2 04/07/2016 14:37 LSTARL1
Vendor Method V_PACE
1 EPA 245.1
04/11/2016 14:01
DMFRANC
1 EPA 200.7
04/09/2016 12:57
JJMACKE
1 EPA 200.7
04/09/2016 12:57
JJMACKE
1 EPA 200.7
04/09/2016 12:57
JJMACKE
1 EPA 200.7
04/09/2016 12:57
JJMACKE
1 EPA 200.7
04/09/2016 12:57
JJMACKE
1 EPA 200.7
04/09/2016 12:57
JJMACKE
1 EPA 200.7
04/09/2016 12:57
JJMACKE
1 EPA 200.8
04/08/2016 19:05
MHALL3
1 EPA 200.8
04/08/2016 19:05
MHALL3
1 EPA 200.8
04/08/2016 19:05
MHALL3
1 EPA 200.8
04/08/2016 19:05
MHALL3
1 EPA 200.8
04/08/2016 19:05
MHALL3
1 EPA 200.8
04/08/2016 19:05
MHALL3
1 EPA 200.8
04/08/2016 19:05
MHALL3
1 EPA 200.8
04/08/2016 19:05
MHALL3
1 EPA 200.8
04/08/2016 19:05
MHALL3
1 EPA 200.8
04/08/2016 19:05
MHALL3
1 EPA 200.8
04/08/2016 19:05
MHALL3
1 EPA 200.8
04/08/2016 19:05
MHALL3
1 EPA 200.8
04/08/2016 19:05
MHALL3
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
1 SM5310C/EPA9060A 04/08/201614:05 CJELLIO

® Laboratories LLc
ve5of34
a member of The GEL Group IN'.
PO Box 30712 Charleston, SC 29417
2040 Savage Road Charlestan. SC 25407
F 843.556.8171
F 843.766.1178
gel.com
April 14, 2016
Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078
Re: AB GW Assessment Water
Work Order: 394827
SDG: J16040148
Dear Mary:
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on April 07, 2016. This original data report has been prepared and reviewed in accordance
with GEL's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.
Sincerely,
Lindsay Fabra
Project Manager
Purchase Order: 1250944 DPNNGO
Enclosures
Pa 1111111111111111111111111111111111111111111111111111111111111

Page 6 of 34
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
for
DUP0002 Duke Energy
Client SDG: J16040148 GEL Work Order: 394827
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the 'U' qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
Reviewed by
JU,&Y ,
Page 2 of 13

GEL LABORATORIES LLC Page 7 of 34
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Report Date: April 14, 2016
Company: Duke Energy Analytical Laboratory
Address : 13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact: Mary Ann Ogle
Project: AB GW Assessment WaterClient prefers Chem and RadChem on the same CoA excluding the uncertainty value
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016009799
394827001
Water
06-APR-16 14:41
07-APR-16
Client
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-233 U ND
0.00001
0.00005
ug/mL
1 SKJ 04/12/16
0215 1558182 1
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1
Uranium-238 0.00124
0.000067
0.0002
ug/mL
1 PRB 04/12/16
1547 1558182 2
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 2.18
1.64
3.00
pCi/L
AXM6 04/13/16
1436 1558331 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 1.80
0.476
1.00
pCi/L
CXP3 04/12/16
0915 1558202 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JXM5
04/08/16
0800 1558164
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test
Result
Nominal Recovery%
Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"
89.9
(15%-125%)
Notes:
Page 3 of 13

Page 8 of 34
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina
Contact: Mary Ann Ogle
Workorder: 394827
Report Date: April 14, 2016
Page 1 of 3
Parmname
NOM
Sample
Qual
QC
Units
RPD%o
REC%
Range
Anlst
Date Time
Metals Analysis - ICPMS
Batch 1558182
QC1203523785
394841001
DUP
Uranium-233
U
ND
U
ND
ug/mL
N/A
SKJ
04/12/16 02:23
Uranium-234
U
ND
U
ND
ug/mL
N/A
Uranium-236
U
ND
U
ND
ug/mL
N/A
Uranium-238
J
0.000188
J
0.0000759
ug/mL
85
(+/-0.0002)
PRB
04/12/16 15:52
QC1203523783
LCS
Uranium-238
0.0496
0.0494
ug/mL
99.5
(80%-120%)
04/12/1615:45
QC1203523784
LCS
Uranium-233
0.0005
0.000537
ug/mL
107
(80%-120%)
SKJ
04/12/16 02:13
Uranium-234
0.00055
0.000588
ug/mL
107
(80%-120%)
Uranium-236
0.005
0.00468
ug/mL
93.7
(80%-120%)
QC1203523782
MB
Uranium-233
U
ND
ug/mL
04/12/16 02:12
Uranium-234
U
ND
ug/mL
Uranium-236
U
ND
ug/mL
Uranium-238
J
0.0000956
ug/mL
PRB
04/12/1615:43
QC1203523786
394841001
MS
Uranium-238
0.0496
J
0.000188
0.0492
ug/mL
98.7
(75%-125%)
04/12/1615:53
QC1203523787
394841001
MS
Uranium-233
0.0005
U
ND
0.000544
ug/mL
109
(75%-125%)
SKJ
04/12/16 02:24
Uranium-234
0.00055
U
ND
0.00059
ug/mL
107
(75%-125%)
Uranium-236
0.005
U
ND
0.00467
ug/mL
93.4
(75%-125%)
QC1203523788
394841001
SDILT
Uranium-233
U
ND
U
ND
ug/L
N/A
04/12/16 02:26
Page 4 of 13

Page 9 of 34
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 394827
Page 2 of 3
Parmname
NOM
Sample
Qual
QC
Units
RPD%
REC%
Range
Anlst
Date Time
Metals Analysis - ICPMS
Batch 1558182
Uranium-234
U
ND
U
ND
ug/L
N/A
Uranium-236
U
ND
U
ND
ug/L
N/A
(0%-10%)
SKJ
04/12/16 02:26
Uranium-238
J
0.188
U
ND
ug/L
N/A
(0%-10%)
PRB
04/12/1615:55
Rad Gas Flow
Batch 1558331
QC1203524143 394827001 DUP
Radium-228
2.18
2.76
pCi/L
23.4
(0% - 100%)
AXM6
04/13/16 14:40
QC1203524144 LCS
Radium-228
46.6
48.4
pCi/L
104
(75%-125%)
04/13/1612:49
QC1203524142 MB
Radium-228
U
-0.271
pCi/L
04/13/1612:49
Rad Ra-226
Batch 1558202
QC1203523834 394827001 DUP
Radium-226
1.80
1.62
pCi/L
10.1
(0% - 100%)
CXP3
04/12/16 10:20
QC1203523836 LCS
Radium-226
24.4
23.6
pCi/L
96.6
(75%-125%)
04/12/1610:20
QC1203523833 MB
Radium-226
U
0.284
pCi/L
04/12/1610:20
QC1203523835 394827001 MS
Radium-226
122
1.80
116
DCi/L
93.5
(75%-125%)
04/12/1610:20
Notes:
The Qualifiers in this report are defined as follows:
** Analyte is a Tracer compound
< Result is less than value reported
> Result is greater than value reported
BD Results are either below the MDC or tracer recovery is low
E %difference of sample and SD is >10%. Sample concentration must meet flagging criteria
FA Failed analysis.
FB Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
H Analytical holding time was exceeded
Page 5 of 13

Page 10 of 34
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 394827
Parmname NOM Sample Qual QC Units RPD% REC'% Range Anlst
J Value is estimated
K Analyte present. Reported value may be biased high. Actual value is expected to be lower.
L Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M M if above MDC and less than LLD
M REMP Result > MDC/CL and < RDL
N Metals --The Matrix spike sample recovery is not within specified control limits
N/A RPD or %Recovery limits do not apply.
N1 See case narrative
ND Analyte concentration is not detected above the detection limit
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
R Sample results are rejected
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
UI Gamma Spectroscopy --Uncertain identification
UJ Gamma Spectroscopy --Uncertain identification
UL Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Y Other specific qualifiers were required to properly define the results. Consult case narrative.
^ RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
h Preparation or preservation holding time was exceeded
Page 3 of 3
Date Time
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
Page 6of13

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Page 8 of 13

Laboratories
Page 13 of 34
L,c
SAMPLE RECEIPT & REVIEW FORM
Client: e`
SDG/AR/COC/Work Order:_ _ 61 1 `A 1 ISD7
Received By: (Date
Received: •- {a
Suspected Hazard information
>"investigation.
o
If Net Counts > tt74cpm on samples not marked "radioactive", contact the Radiation Safety Group for further
COC/Samples marked as radioactive?
Maximum Net Counts Observed* (Observed Counts - Area Background Counts):
Classified Radioactive H or III by RSO?
,-
�f yes, Were swipes taken of sample containers < action levels?
COC/Samples les marked containing PCBs?
t?ackage, COC, A-6l6r Sam les marked as
•`tlium'or
'
be asbestoscontai�in" ?
� Safety
salt' Tes are to be;segre' afed WSafe ControlleTSam les,'and.o erie$iby tbe'GEL~~,: Cu,.-;'
ou
Shi ed as a DOT Hazardous?
f
Pazard Class Shipped: UN#:
Sam les identified as Foreign Soil?
Sample Receipt Criteria
�ia
Z
Comments/Qualifiers (Required for Non -Conforming Items)
1
Shipping containers received intact and
Circle Applicable: Seals broken Damaged container t.caking container Other (describe)
sealed?
2
Samples requiring cold preservation
Preservation Method: Ice bags Blue ice Dry ice None Other (describe)
within (0,5 6 deg. C)?*
*all temperatures are recorded in Celsius
t
t t
2a
Daily check performed and passed on IR
Temperature Device Serial #:
Secondary Temperature Device Serial N (If Applicable):
temperature gun.?
� ; �� 41
3
Chain of custody documents included
with shipment?
A
Sample containers intact and sealed?
Circle Applicable: Seals broken Damaged container Leaking container Other (describe)
5
Samples requiring chemical preservation
I
Sample ID's, containers affected and observed pH:
at proper pH?
6
Do Low Level Perchlorate samples have
Sample ID's and containers affected:
heads ace as required?
7
VOA vials contain acid preservation?
%
I
(If unknown, select No)
8
VOA vials free of headspace (defined as
Sample [Us and containers affected:
< 6mm bubble)?
9
Are Encore containers present?
(if yes, immediately deliver to Volatiles laboratory)
10
Samples received within holding time?
ID's and tests affected:
11
Sample ID's on COC match ID's on
!
Sample ID's and containers affected:
bottles?
J
12
Date & time on COC match date & time
Sample ID's affected:
on bottles?
13
Number of containers received match
I
Sample ID's affected:
number indicated on COC?
14
Are sample containers identifiable as
GELprovided?
15
COC form is property signed in
relinquished/received ;sections?
Circle Applicable;
FedEx Air FedEx Ground UPS Field Services Courier, Other
d q
,.,. i,.�9 G�t�}r` � � G'�`•SL.� C..� tT7 � l �-�� _ 'C C:.S'`.'"y`., t '4:.�n+
16
Carrier and tracking number.
Comments (Use Continuation Form if needed):
PM (or PMA) review: Initial'
krIE zo Date Page of
t MeV 3
Page 9 of 13

Page 14 of 34
Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16040148
Work Order #: 394827
Metals
Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1558182
Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1558164
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
Client Sample Identification
394827001
2016009799
1203523782
Method Blank (MB)ICP-MS
1203523783
Laboratory Control Sample (LCS)
1203523784
Laboratory Control Sample (LCS)
1203523788
394841001(2016009694L) Serial Dilution (SD)
1203523785
394841001(2016009694D) Sample Duplicate (DUP)
1203523786
394841001(2016009694S) Matrix Spike (MS)
1203523787
394841001(2016009694S) Matrix Spike (MS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.
Radiochemistry
Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1558331
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID# Client Sample Identification
394827001 2016009799
1203524142 Method Blank (MB)
1203524143 394827001(2016009799) Sample Duplicate (DUP)
1203524144 Laboratory Control Sample (LCS)
Page 10 of 13

Page 15 of 34
The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Technical Information
Recounts
Samples 1203524143 (2016009799DUP) and 394827001 (2016009799) were recounted due to high relative
percent difference/relative error ratio. The recounts are reported.
Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1558202
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID# Client Sample Identification
394827001 2016009799
1203523833 Method Blank (MB)
1203523834 394827001(2016009799) Sample Duplicate (DUP)
1203523835 394827001(2016009799) Matrix Spike (MS)
1203523836 Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary•
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Miscellaneous Information
Additional Comments
The matrix spike, 1203523835 (2016009799MS), aliquot was reduced to conserve sample volume.
Certification Statement
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
Page 11 of 13

requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 16 of 34
Page 12 of 13

Page 17 of 34
List of current GEL Certifications as of 14 April 2016
State
Certification
Alaska
UST-0110
Arkansas
88-0651
CLIA
42D0904046
California
2940
Colorado
SC00012
Connecticut
PH-0169
Delaware
SC00012
DoD ELAP/ ISO17025 A2LA
2567.01
Florida NELAP
E87156
Foreign Soils Permit
P330-15-00283, P330-15-00253
Georgia
SC00012
Georgia SDWA
967
Hawaii
SC00012
Idaho Chemistry
SC00012
Idaho Radiochemistry
SC00012
Illinois NELAP
200029
Indiana
C—SC-01
Kansas NELAP
E-10332
Kentucky SDWA
90129
Kentucky Wastewater
90129
Louisiana NELAP
03046 (A233904)
Louisiana SDWA
LA160006
Maryland
270
Massachusetts
M—SC012
Michigan
9976
Mississippi
SC00012
Nebraska
NE—OS-26-13
Nevada
SC000122016-1
New Hampshire NELAP
205415
New Jersey NELAP
SC002
New Mexico
SC00012
New York NELAP
11501
North Carolina
233
North Carolina SDWA
45709
North Dakota
R-158
Oklahoma
9904
Pennsylvania NELAP
68-00485
S.Carolina Radchem
10120002
South Carolina Chemistry
10120001
Tennessee
TN 02934
Texas NELAP
T104704235-16-11
Utah NELAP
SC000122016-20
Vermont
VT87156
Virginia NELAP
460202
Washington
C780
West Virginia
997404
Page 13 of 13

aceAnaiXical
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Pace Analytical Services, Inc.
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y Huntersville, INC 28078
[phone]
April 14, 2016
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 16040148
Pace Project No.: 92292984
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 07, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Anne Pifer
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
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lacmnalyfica(
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Pace Analytical Services, Inc.
oQg%c8f3A4e. Suite 100
Huntersville, NC 28078
[phone]
Project: J16040148
Pace Project No.: 92292984
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A21-A Certification M 2926.01
Alaska Certification M UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification M 88-0680
California Certification M 01155CA
Colorado Certification #Pace
Connecticut Certification M PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification M 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification M 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification M 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification M 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification M E83079
Georgia Certification M 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification M 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification M E-10383
Louisiana Certification M FL NELAC Reciprocity
Louisiana Environmental Certificate M 05007
Maryland Certification: #346
Michigan Certification M 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification M Cert 0074
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 16

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[phone]
SAMPLE SUMMARY
Project: J16040148
Pace Project No.: 92292984
Lab ID Sample ID Matrix Date Collected Date Received
92292984001 2016009799 Water 04/06/1614:41 04/07/1615:15
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16040148
92292984
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92292984001
2016009799
RSK 175
DR1
1
PASI-M
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
TK1
1
PASI-O
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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Project: J16040148
Pace Project No.: 92292984
Lab Sample ID
Method
92292984001
EPA 218.7
Client Sample ID
Parameters
2016009799
Chromium, Hexavalent
SUMMARY OF DETECTION
Result UnitE
0.089 ug/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Report Limit Analyzed Qualifiers
0.030 04/13/1615:52
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aceAnaiXical
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PROJECT NARRATIVE
Project: J16040148
Pace Project No.: 92292984
Method: RSK 175
Description: RSK 175 AIR Headspace
Client: Duke Energy
Date: April 14, 2016
General Information:
1 sample was analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16040148
Pace Project No.: 92292984
Method: SM 4500-S213
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: April 14, 2016
General Information:
1 sample was analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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Pace Analytical Services, Inc.
098g i - ue. Suite 100
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[phone]
PROJECT NARRATIVE
Project: J16040148
Pace Project No.: 92292984
Method: EPA 218.7
Description: Hexavalent Chromium by IC
Client: Duke Energy
Date: April 14, 2016
General Information:
1 sample was analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/56791
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92293144001,92293219004
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1538578)
• Chromium. Hexavalent
• MSD (Lab ID: 1538577)
• Chromium, Hexavalent
• MSD (Lab ID: 1538579)
• Chromium. Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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[phone]
ANALYTICAL RESULTS
Project: J16040148
Pace Project No.: 92292984
Sample: 2016009799
Lab ID: 92292984001 Collected:
04/06/16
14:41
Received: 04/07/16 15:15 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
04/12/16 09:40
74-82-8
4500S21) Sulfide Water
Analytical Method: SM 4500-S2D
Sulfide
ND mg/L
0.10
1
04/12/1619:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.089 ug/L
0.030
1
04/13/16 15:52
18540-29-9
REPORT OF LABORATORY ANALYSIS
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Date: 04/14/2016 11:00 AM without the written consent of Pace Analytical Services, Inc.. Page 9 of 16

aceAnaiXical
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Pace Analytical Services, Inc.
098gl i - ue. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040148
Pace Project No.: 92292984
QC Batch: AIR/25665
Analysis Method: RSK 175
QC Batch Method: RSK 175
Analysis Description: RSK 175 AIR HEADSPACE
Associated Lab Samples: 92292984001
METHOD BLANK: 2228970
Matrix: Water
Associated Lab Samples: 92292984001
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Methane
ug/L
ND 10.0
04/12/16 06:28
LABORATORY CONTROL SAMPLE & LCSD:
2228971
2228972
Spike LCS LCSD
LCS LCSD
% Rec
Max
Parameter
Units
Conc. Result Result
% Rec % Rec
Limits RPD
RPD Qualifiers
Methane
ug/L
60.7 59.5 58.6
98 97
85-115
2 20
SAMPLE DUPLICATE: 2230336
92292984001 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Methane
ug/L
ND 1 AJ
20
SAMPLE DUPLICATE: 2230337
92293020020 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Methane
ug/L
2.2J 2.3J
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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Pace Analytical Services, Inc.
098g i - ue. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040148
Pace Project No.: 92292984
QC Batch: WET/44159 Analysis Method: SM 4500-S2D
QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92292984001
METHOD BLANK: 1707185 Matrix: Water
Associated Lab Samples: 92292984001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 04/12/1619:30
LABORATORY CONTROL SAMPLE: 1707186
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.52 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1707187 1707188
MS MSD
92292995005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.48 0.48 93 93 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1707189 1707190
MS MSD
92293027001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.52 0.52 103 103 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/14/2016 11:00 AM without the written consent of Pace Analytical Services, Inc..
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QUALITY CONTROL DATA
Project: J16040148
Pace Project No.: 92292984
QC Batch: WETA/56791 Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC
Associated Lab Samples: 92292984001
METHOD BLANK: 1538574 Matrix: Water
Associated Lab Samples: 92292984001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chromium, Hexavalent ug/L ND 0.030 04/13/16 13:42
LABORATORY CONTROL SAMPLE: 1538575
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chromium, Hexavalent ug/L .075 0.068 91 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1538576 1538577
MS MSD
92293144001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND .025 .025 .021J .02J 85 78 85-115 20 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1538578 1538579
MS MSD
92293219004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND .075 .075 0.058 0.059 77 78 85-115 2 20 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALIFIERS
Project: J16040148
Pace Project No.: 92292984
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-M Pace Analytical Services - Minneapolis
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16040148
Pace Project No.: 92292984
Lab ID
Sample ID
QC Batch Method
QC Batch
92292984001
2016009799
RSK 175
AIR/25665
92292984001
2016009799
SM 4500-S2D
WET/44159
92292984001
2016009799
EPA 218.7
WETA/56791
Date: 04/14/2016 11:00 AM
REPORT OF LABORATORY ANALYSIS
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Analytical Method
Analytical
Batch
Page 14 of 16

Document Name: uocument nevisea: iw-t /uao
© Sample Condition Upon Receipt(SCUR) Page 1 of 2
Analylleal Document No.: Issuing Authority:
We 32of
F-CHR-CS-003-rev.18 Pace Huntersville Quality ce
Sample Condition ++.. �� (� Page 2 of 2 for Internal Use ONLY
.. Client Name: Y�� d��:`rCr+:�jQi�/� �I
Receipt Projec 9/' 4
Courier Eked ❑UPS ❑USPS ❑Client 11111111111l�lll�����1
Commercial OFace ❑Other: 92292984
Custody Seal Present? ❑Yes No Seals Intact? ❑Yes [—]No
Date/Initials Person Examining Contents:
Packing Material: ❑Bubble rap Bubble Bags ❑None ❑Other:
Thermometer: 05 ❑ Type of Ice: �. et ❑Blue []None ample, on €ce, cooling process has begun
Correction Factor: 0.0°C Cooler Temp Corrected (°C): . Biological Tissue Frozen? []Yes ❑No 0 A —'-
Temp should be above free ' to 6°C
USDA Regulated Soo ( N/A, water sample)
Did samples or}'g€riate In a quarantine zone within the United States: CA, NY, or SC (check maps)? did samples originate from a foreign source {internatio ally,
mv— Flxt" Including Hawaii and Puerto Ricol? FlYes o
COMMENTS:
Chain of Custody Present?
Yes
❑No
❑N/A
1.
Chain of Custody Filled Out?
Yes
[]No
❑N/A
2,
Chain of Custody Relinquished?
Yes,, -[]No
❑N/A
3,
Sampler Name and/or Signature on COO
Yes
❑No
[I N/A
4.
Samples Arrived within Hold Time?
Yes
❑No
❑N/A
5.
Short Hold Time Analysis (<72 hr.)?
❑Yes
0116­
❑N/A
6.
Rush Turn Around Time Requested?
❑Yes
0/
©f1
❑N/A
7,
5tiff icientVol ume?
es
[:]No
❑N/A
8.
Correct Containers Used?
es
[]No❑NIA
9.
-Pace Containers Used?
Yes
❑No
❑N/A
Containers Intact?
EfY,,
[]No_
❑N/A
10. '
Filtered Volume Received for Dissolved Tests?
[]Yes
❑No
N/A
11. Note if sediment is visible In the dissolved container
Sample Labels Match COC?
es
❑No
❑N/A
12.
-Includes Date/Time/ID/Analysis Matrix:
All containers needing acid/base preservation have been
13
checked?
es
❑No
❑N/A
All.containers needing preservation are found to be in
compliance with EPA recommendation?
(HNO3, H2SO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide)
Yes
❑No
[]NIA
Exceptions: VOA, Coliform, TOC, oil and Grease,
DRO/8015 (water) DOC,LLHg
❑Yes
[]No
N/A
Samples checked for dechlorination
B les
❑No
❑NIA
14.
Headspace in VOA Vials (>5-6mm)?
❑Yes
❑No
NIA
15.
Trip Blank Present?
❑Yes
[:]No
N/A
16.
rip BI an k Custody S ea is resen
es
No
j 9K
Pace Trip Blank Lot tt (if purchased):
_
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Resolution:
Date/Time:
Field Data Required? ❑Yes ❑No
Project Manager SCURF Review: 4 Date: q I+ I f �
Project Manager SRF Review: Date: "i 18 ) 1(
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
.Out of hold, Incorrect preservative, out of temp, incorrect containers)
Page 15 of 16

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Page 33 of 34
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Page 16 of 16

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