The URL can be used to link to this page

Home My WebLink AboutNC0003425_J16040677 Report_20160801Page 1 of 66 1� DUKE ENERGY Certificate of Laboratory Analysis Order ID Roxboro: AB GW ASSESSMENT SOIL J16040677 Program Manager: Rodney Wike Please contact the Program Manager, Rodney Wike, at 980-875-5186 with any questions regarding this report. Sample Number: 2016011745 CV-2 Collected Date: 04/26/2016 01:40 PM Collected By: ILLEGIBLE Date Received: 04/27/16 Result: Units: Qualifier: RDL: Dilution: Method: PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete 1 V_A.Analytical SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE Sample Number: 2016011746 NL-4 Collected Date: 04/26/2016 02:05 PM Collected By: ILLEGIBLE Date Received: 04/27/16 Result: Units: Qualifier: RDL: Dilution: Method: PERCENT SOLIDS - (Analvsis Performed by Pace Laboratories Vendor Parameter Complete 1 V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete 1 V_A.Analytical SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE This report should not be reproduced, except in its entirety, without the written consent of Duke Energy Corporation. All results are reported on dry weight unless otherwise noted. This report is not to be used for regulatory purposes. These results meet method requirements except where noted with qualifiers or program comments. Mail Code MG03A2 -- 13339 Hagers Ferry Road, Huntersville, NC 28078. -- Phone: 704-787-5245 Fax 980-875-4349 Monday, 16 May 2016, 02:45 PM Page # 1 of 3 Page 2 of 66 DUE Certificate of Laboratory Analysis " ENERGY Order ID Roxboro: AB GW ASSESSMENT SOIL J16040677 Program Manager: Rodney Wike Sample Number: 2016011746 NL-4 Collected Date: 04/26/2016 02:05 PM Collected By: ILLEGIBLE Date Received: 04/27/16 Result: Units: Qualifier: RDL: Dilution: Method: TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE Sample Number: 2016011747 NL-8 Collected Date: 04/26/2016 02:30 PM Collected By: ILLEGIBLE Result: Units: Qualifier: PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample Number: 2016011748 SL-8 Collected Date: 04/26/2016 02:55 PM Collected By: ILLEGIBLE Result: Units: Qualifier: PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories Vendor Parameter Complete Date Received: 04/27/16 RDL: Dilution: Method: 1 V_PACE 1 V_PACE 1 V_PACE 1 V_PACE 1 V_A.Analytical 1 V_PACE 1 V_PACE Date Received: 04/27/16 RDL: Dilution: Method: 1 V_PACE 1 V_PACE 1 V_PACE 1 V_PACE This report should not be reproduced, except in its entirety, without the written consent of Duke Energy Corporation. All results are reported on dry weight unless otherwise noted. This report is not to be used for regulatory purposes. These results meet method requirements except where noted with qualifiers or program comments. Mail Code MG03A2 -- 13339 Hagers Ferry Road, Huntersville, NC 28078. -- Phone: 704-787-5245 Fax 980-875-4349 Monday, 16 May 2016, 02:45 PM Page # 2 of 3 Page 3 of 66 DUE Certificate of Laboratory Analysis " ENERGY Order ID Roxboro: AB GW ASSESSMENT SOIL J16040677 Program Manager: Rodney Wike Sample Number: 2016011748 SL-8 Collected Date: 04/26/2016 02:55 PM Collected By: ILLEGIBLE Date Received: 04/27/16 Result: Units: SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Qualifier: RDL: Dilution: Method: 1 V_A.Analytical 1 V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE Sample Number: 2016011749 CL-2 Collected Date: 04/26/2016 04:16 PM Collected By: ILLEGIBLE Date Received: 04/27/16 Result: Units: Qualifier: RDL: Dilution: Method: PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE SEDIMENT ANALYSIS - (Analvsis Performed by Access Analytical) Vendor Parameter Complete 1 V_A.Analytical SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 1 V_PACE Program Manager: RodneyWilke Report Authorized By: 980-875-5186 (Signature) /* An EDD has been included with this report. 7 This report should not be reproduced, except in its entirety, without the written consent of Duke Energy Corporation. All results are reported on dry weight unless otherwise noted. This report is not to be used for regulatory purposes. These results meet method requirements except where noted with qualifiers or program comments. Mail Code MG03A2 -- 13339 Hagers Ferry Road, Huntersville, NC 28078. -- Phone: 704-787-5245 Fax 980-875-4349 Monday, 16 May 2016, 02:45 PM Page # 3 of 3 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9P2Q.�C4,8y&ie. Suite 100 �Huntersville, INC 28078 (704)875-9092 May 16, 2016 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 16040677 Pace Project No.: 92295417 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 27, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, C Chris Bishop for Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Program Manager, Duke Energy Anne Pifer Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. %gig%y&ie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J16040677 Pace Project No.: 92295417 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification M PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Virginia VELAP ID: 460263 North Dakota Certification #: R-150 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification M E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Wyoming Certification: FL NELAC Reciprocity West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Virginia VELAP ID: 460263 Virginia VELAP Certification ID: 460263 Wisconsin Certification #: 405132750 Wisconsin DATCP Certification #: 105-444 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. qP2Q.�C6'8y&ie. Suite 100 �Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J16040677 Pace Project No.: 92295417 Lab ID Sample ID Matrix Date Collected Date Received 92295417001 2016011745 Solid 04/26/1613:40 04/27/1612:20 92295417002 2016011746 Solid 04/26/1614:05 04/27/1612:20 92295417003 2016011747 Solid 04/26/1614:30 04/27/1612:20 92295417004 2016011748 Solid 04/26/1614:55 04/27/1612:20 92295417005 2016011749 Solid 04/26/1616:16 04/27/1612:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. qpgQ. 'C 8y&.. Suite 100 �Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J16040677 Pace Project No.: 92295417 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92295417001 2016011745 EPA 6010 CKJ 17 PASI-0 EPA 6010 CDF 12 PASI-A EPA 6020 CKJ 7 PASI-O EPA 6020B JMW 12 PASI-A EPA7470 SH1 1 PASI-A EPA 7471 RVK 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 300.0 MDW 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E BRJ 1 PASI-A EPA 9056 KEK 2 PASI-O EPA 9056 KEK 1 PASI-O EPA 9060 TJJ 6 PASI-G 92295417002 2016011746 EPA 6010 CKJ 17 PASI-0 EPA 6010 CDF 12 PASI-A EPA 6020 CKJ 7 PASI-O EPA 6020B JMW 12 PASI-A EPA7470 SH1 1 PASI-A EPA 7471 RVK 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 300.0 MDW 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E BRJ 1 PASI-A EPA 9056 KEK 2 PASI-O EPA 9056 KEK 1 PASI-O EPA 9060 TJJ 6 PASI-G 92295417003 2016011747 EPA 6010 CKJ 17 PASI-0 EPA 6010 CDF 12 PASI-A EPA 6020 CKJ 7 PASI-O EPA 6020B JMW 12 PASI-A EPA7470 SH1 1 PASI-A EPA 7471 RVK 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 300.0 MDW 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E BRJ 1 PASI-A EPA 9056 KEK 2 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. qP2Q.�C8'8y&ie. Suite 100 �Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J16040677 Pace Project No.: 92295417 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 9056 KEK 1 PASI-O EPA 9060 TJJ 6 PASI-G 92295417004 2016011748 EPA 6010 CKJ 17 PASI-0 EPA 6010 CDF 12 PASI-A EPA 6020 CKJ 7 PASI-O EPA 6020B JMW 12 PASI-A EPA7470 SH1 1 PASI-A EPA 7471 RVK 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 300.0 MDW 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E BRJ 1 PASI-A EPA 9056 KEK 2 PASI-O EPA 9056 KEK 1 PASI-O EPA 9060 TJJ 6 PASI-G 92295417005 2016011749 EPA 6010 CKJ 17 PASI-0 EPA 6010 CDF 12 PASI-A EPA 6020 CKJ 7 PASI-O EPA 6020B JMW 12 PASI-A EPA7470 SH1 1 PASI-A EPA 7471 RVK 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 300.0 MDW 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E BRJ 1 PASI-A EPA 9056 KEK 2 PASI-O EPA 9056 KEK 1 PASI-O EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. qP2Q.�C§'8y&ie. Suite 100 �Huntersville, NC 28078 (704)875-9092 Project: J16040677 Pace Project No.: 92295417 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92295417001 2016011745 EPA 6010 Aluminum 6800 mg/kg 4.8 05/04/16 08:29 EPA 6010 Barium 68.6 mg/kg 0.48 05/04/16 08:29 EPA 6010 Beryllium 0.28 mg/kg 0.048 05/04/16 08:29 EPA 6010 Boron 3.1 mg/kg 2.4 05/04/16 08:29 EPA 6010 Calcium 886 mg/kg 23.9 05/04/16 08:29 EPA 6010 Chromium 6.6 mg/kg 0.24 05/04/16 08:29 EPA 6010 Copper 9.5 mg/kg 0.24 05/04/16 08:29 EPA 6010 Iron 9400 mg/kg 1.9 05/04/16 08:29 EPA 6010 Magnesium 1180 mg/kg 23.9 05/04/16 08:29 EPA 6010 Manganese 721 mg/kg 1.2 05/04/16 10:11 EPA 6010 Molybdenum 8.1 mg/kg 0.48 05/04/16 08:29 EPA 6010 Nickel 3.9 mg/kg 0.24 05/04/16 08:29 EPA 6010 Potassium 421 mg/kg 47.9 05/04/16 08:29 EPA 6010 Strontium 15.9 mg/kg 0.48 05/04/16 08:29 EPA 6010 Zinc 19.0 mg/kg 0.96 05/04/16 08:29 EPA 6010 Aluminum 0.26 mg/L 0.10 05/06/16 16:38 EPA 6010 Barium 0.17 mg/L 0.050 05/06/16 16:38 EPA 6010 Boron 0.22 mg/L 0.20 05/06/16 16:38 EPA 6010 Calcium 24.5 mg/L 1.0 05/06/16 16:38 EPA 6010 Iron 0.14 mg/L 0.050 05/06/16 16:38 EPA 6010 Magnesium 3.5 mg/L 0.10 05/06/16 16:38 EPA 6010 Manganese 4.4 mg/L 0.0050 05/06/16 16:38 EPA 6010 Strontium 0.27 mg/L 0.0050 05/06/16 16:38 EPA 6010 Zinc 0.19 mg/L 0.050 05/06/16 16:38 EPA 6020 Arsenic 13.9 mg/kg 0.96 05/04/16 08:53 EPA 6020 Cobalt 5.3 mg/kg 0.96 05/04/16 08:53 EPA 6020 Lead 3.7 mg/kg 0.96 05/04/16 08:53 EPA 6020 Selenium 3.3 mg/kg 0.96 05/04/16 08:53 EPA 6020 Vanadium 23.3 mg/kg 0.96 05/04/16 08:53 EPA 6020B Antimony 0.51 ug/L 0.50 05/13/16 12:39 EPA 6020B Arsenic 1.8 ug/L 0.50 05/13/16 12:39 EPA 6020B Chromium 0.68 ug/L 0.50 05/13/16 12:39 EPA 6020B Cobalt 1.4 ug/L 0.50 05/13/16 12:39 EPA 6020B Copper 1.6 ug/L 1.0 05/13/16 12:39 EPA 6020B Molybdenum 6.7 ug/L 0.50 05/13/16 12:39 EPA 6020B Selenium 1.3 ug/L 0.50 05/13/16 12:39 EPA 6020B Vanadium 2.1 ug/L 0.50 05/13/16 12:39 EPA 7471 Mercury 0.031 mg/kg 0.0080 05/04/16 16:07 EPA 9045 pH at 25 Degrees C 7.2 Std. Units 0.10 05/02/16 09:50 EPA 300.0 Sulfate 77.3 mg/L 10.0 05/09/16 15:04 EPA 9060 Total Organic Carbon 14000 mg/kg 6270 05/05/16 07:13 EPA 9060 Total Organic Carbon 13200 mg/kg 6160 05/05/16 07:19 EPA 9060 Total Organic Carbon 11600 mg/kg 5980 05/05/16 07:27 EPA 9060 Total Organic Carbon 13400 mg/kg 6130 05/05/16 07:35 EPA 9060 Mean Total Organic Carbon 13000 mg/kg 6140 05/05/16 07:13 EPA 9060 RSD% 7.6 % 05/05/16 07:13 REPORT OF LABORATORY ANALYSIS M1 M1 M1 M1 M1 M1 M1 M1 M1 H6 B Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0g8pli6'8y&ie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J16040677 Pace Project No.: 92295417 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92295417002 2016011746 EPA 6010 Aluminum 9110 mg/kg 5.1 05/04/16 08:33 EPA 6010 Barium 89.0 mg/kg 0.51 05/04/16 08:33 EPA 6010 Beryllium 1.0 mg/kg 0.051 05/04/16 08:33 EPA 6010 Boron 4.0 mg/kg 2.5 05/04/16 08:33 EPA 6010 Calcium 5010 mg/kg 25.3 05/04/16 08:33 EPA 6010 Chromium 10.6 mg/kg 0.25 05/04/16 08:33 EPA 6010 Copper 15.9 mg/kg 0.25 05/04/16 08:33 EPA 6010 Iron 8580 mg/kg 2.0 05/04/16 08:33 EPA 6010 Magnesium 676 mg/kg 25.3 05/04/16 08:33 EPA 6010 Manganese 1080 mg/kg 1.3 05/04/16 10:15 EPA 6010 Molybdenum 8.3 mg/kg 0.51 05/04/16 08:33 EPA 6010 Nickel 8.3 mg/kg 0.25 05/04/16 08:33 EPA 6010 Potassium 727 mg/kg 50.6 05/04/16 08:33 EPA 6010 Sodium 111 mg/kg 50.6 05/04/16 08:33 EPA 6010 Strontium 49.7 mg/kg 0.51 05/04/16 08:33 EPA 6010 Zinc 23.3 mg/kg 1.0 05/04/16 08:33 EPA 6010 Barium 0.14 mg/L 0.050 05/06/16 16:47 EPA 6010 Calcium 37.0 mg/L 1.0 05/06/16 16:47 EPA 6010 Iron 0.26 mg/L 0.050 05/06/16 16:47 EPA 6010 Magnesium 3.3 mg/L 0.10 05/06/16 16:47 EPA 6010 Manganese 5.6 mg/L 0.0050 05/06/16 16:47 EPA 6010 Strontium 0.36 mg/L 0.0050 05/06/16 16:47 EPA 6010 Zinc 0.093 mg/L 0.050 05/06/16 16:47 EPA 6020 Arsenic 29.7 mg/kg 1.0 05/04/16 08:55 EPA 6020 Cobalt 6.2 mg/kg 1.0 05/04/16 08:55 EPA 6020 Lead 9.4 mg/kg 1.0 05/04/16 08:55 EPA 6020 Selenium 5.6 mg/kg 1.0 05/04/16 08:55 EPA 6020 Vanadium 30.6 mg/kg 1.0 05/04/16 08:55 EPA 6020B Antimony 0.88 ug/L 0.50 05/13/16 12:43 EPA 6020B Arsenic 227 ug/L 0.50 05/13/16 12:43 EPA 6020B Cobalt 0.56 ug/L 0.50 05/13/16 12:43 EPA 6020B Molybdenum 302 ug/L 0.50 05/13/16 12:43 EPA 6020B Selenium 6.3 ug/L 0.50 05/13/16 12:43 EPA 6020B Vanadium 1.7 ug/L 0.50 05/13/16 12:43 EPA 7471 Mercury 0.047 mg/kg 0.0076 05/04/16 16:10 EPA 9045 pH at 25 Degrees C 7.6 Std. Units 0.10 05/02/16 09:50 H6 EPA 300.0 Sulfate 12.4 mg/L 2.0 05/09/16 15:48 B EPA 9060 Total Organic Carbon 13000 mg/kg 3330 05/05/16 08:44 EPA 9060 Total Organic Carbon 13300 mg/kg 3250 05/05/16 08:49 EPA 9060 Total Organic Carbon 11500 mg/kg 3360 05/05/16 08:56 EPA 9060 Total Organic Carbon 11700 mg/kg 3320 05/05/16 09:05 EPA 9060 Mean Total Organic Carbon 12400 mg/kg 3310 05/05/16 08:44 EPA 9060 RSD% 7.4 % 05/05/16 08:44 92295417003 2016011747 EPA 6010 Aluminum 947 mg/kg 4.9 05/04/16 08:37 EPA 6010 Barium 10 mg/kg 0.49 05/04/16 08:37 EPA 6010 Beryllium 0.050 mg/kg 0.049 05/04/16 08:37 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�fflinlc&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J16040677 Pace Project No.: 92295417 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92295417003 2016011747 EPA 6010 Calcium 170 mg/kg 24.7 05/04/16 08:37 EPA 6010 Chromium 0.99 mg/kg 0.25 05/04/16 08:37 EPA 6010 Copper 2.8 mg/kg 0.25 05/04/16 08:37 EPA 6010 Iron 1140 mg/kg 2.0 05/04/16 08:37 EPA 6010 Magnesium 154 mg/kg 24.7 05/04/16 08:37 EPA 6010 Manganese 145 mg/kg 0.25 05/04/16 08:37 EPA 6010 Molybdenum 4.4 mg/kg 0.49 05/04/16 08:37 EPA 6010 Nickel 0.59 mg/kg 0.25 05/04/16 08:37 EPA 6010 Potassium 87.5 mg/kg 49.3 05/04/16 08:37 EPA 6010 Strontium 3.1 mg/kg 0.49 05/04/16 08:37 EPA 6010 Zinc 3.4 mg/kg 0.99 05/04/16 08:37 EPA 6010 Aluminum 0.22 mg/L 0.10 05/06/16 16:50 EPA 6010 Barium 0.21 mg/L 0.050 05/06/16 16:50 EPA 6010 Boron 0.27 mg/L 0.20 05/06/16 16:50 EPA 6010 Calcium 11.6 mg/L 1.0 05/06/16 16:50 EPA 6010 Iron 0.080 mg/L 0.050 05/06/16 16:50 EPA 6010 Magnesium 3.1 mg/L 0.10 05/06/16 16:50 EPA 6010 Manganese 7.4 mg/L 0.0050 05/06/16 16:50 EPA 6010 Sodium 5.3 mg/L 5.0 05/06/16 16:50 EPA 6010 Strontium 0.20 mg/L 0.0050 05/06/16 16:50 EPA 6010 Zinc 0.18 mg/L 0.050 05/06/16 16:50 EPA 6020 Arsenic 3.1 mg/kg 0.99 05/04/16 08:58 EPA 6020 Selenium 1.3 mg/kg 0.99 05/04/16 08:58 EPA 6020 Vanadium 3.2 mg/kg 0.99 05/04/16 08:58 EPA 6020B Antimony 0.69 ug/L 0.50 05/13/16 12:56 EPA 6020B Arsenic 6.1 ug/L 0.50 05/13/16 12:56 EPA 6020B Cobalt 5.0 ug/L 0.50 05/13/16 12:56 EPA 6020B Molybdenum 19.2 ug/L 0.50 05/13/16 12:56 EPA 6020B Selenium 1.8 ug/L 0.50 05/13/16 12:56 EPA 6020B Vanadium 0.67 ug/L 0.50 05/13/16 12:56 EPA 9045 pH at 25 Degrees C 7.6 Std. Units 0.10 05/02/16 09:50 H6 EPA 300.0 Sulfate 65.7 mg/L 8.0 05/09/16 23:30 B EPA 9060 Total Organic Carbon 9200 mg/kg 3330 05/05/16 09:11 EPA 9060 Total Organic Carbon 8800 mg/kg 3370 05/05/16 09:20 EPA 9060 Total Organic Carbon 10100 mg/kg 3280 05/05/16 09:27 EPA 9060 Total Organic Carbon 9840 mg/kg 3350 05/05/16 09:33 EPA 9060 Mean Total Organic Carbon 9490 mg/kg 3330 05/05/16 09:11 EPA 9060 RSD% 6.4 % 05/05/16 09:11 92295417004 2016011748 EPA 6010 Aluminum 894 mg/kg 4.8 05/04/16 08:42 EPA 6010 Barium 6.4 mg/kg 0.48 05/04/16 08:42 EPA 6010 Calcium 138 mg/kg 24.2 05/04/16 08:42 EPA 6010 Chromium 1.1 mg/kg 0.24 05/04/16 08:42 EPA 6010 Copper 1.5 mg/kg 0.24 05/04/16 08:42 EPA 6010 Iron 1100 mg/kg 1.9 05/04/16 08:42 EPA 6010 Magnesium 113 mg/kg 24.2 05/04/16 08:42 EPA 6010 Manganese 63.3 mg/kg 0.24 05/04/16 08:42 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J16040677 Pace Project No.: 92295417 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92295417004 2016011748 EPA 6010 Molybdenum 3.1 mg/kg 0.48 05/04/16 08:42 EPA 6010 Nickel 0.55 mg/kg 0.24 05/04/16 08:42 EPA 6010 Strontium 2.5 mg/kg 0.48 05/04/16 08:42 EPA 6010 Zinc 2.9 mg/kg 0.97 05/04/16 08:42 EPA 6010 Aluminum 0.44 mg/L 0.10 05/06/16 16:53 EPA 6010 Barium 0.22 mg/L 0.050 05/06/16 16:53 EPA 6010 Boron 0.25 mg/L 0.20 05/06/16 16:53 EPA 6010 Calcium 15.1 mg/L 1.0 05/06/16 16:53 EPA 6010 Iron 0.29 mg/L 0.050 05/06/16 16:53 EPA 6010 Magnesium 4.3 mg/L 0.10 05/06/16 16:53 EPA 6010 Manganese 6.4 mg/L 0.0050 05/06/16 16:53 EPA 6010 Nickel 0.0055 mg/L 0.0050 05/06/16 16:53 EPA 6010 Strontium 0.27 mg/L 0.0050 05/06/16 16:53 EPA 6010 Zinc 0.21 mg/L 0.050 05/06/16 16:53 EPA 6020 Arsenic 3.4 mg/kg 0.97 05/04/16 09:00 EPA 6020 Selenium 1.7 mg/kg 0.97 05/04/16 09:00 EPA 6020 Vanadium 3.0 mg/kg 0.97 05/04/16 09:00 EPA 6020B Antimony 0.71 ug/L 0.50 05/13/16 13:00 EPA 6020B Arsenic 1.6 ug/L 0.50 05/13/16 13:00 EPA 6020B Beryllium 0.13 ug/L 0.10 05/13/16 13:00 EPA 6020B Cadmium 0.12 ug/L 0.080 05/13/16 13:00 EPA 6020E Chromium 0.96 ug/L 0.50 05/13/16 13:00 EPA 6020B Cobalt 7.5 ug/L 0.50 05/13/16 13:00 EPA 6020B Molybdenum 2.3 ug/L 0.50 05/13/16 13:00 EPA 6020B Selenium 1.9 ug/L 0.50 05/13/16 13:00 EPA 6020B Thallium 0.11 ug/L 0.10 05/13/16 13:00 EPA 6020B Vanadium 0.91 ug/L 0.50 05/13/16 13:00 EPA 9045 pH at 25 Degrees C 7.3 Std. Units 0.10 05/02/16 09:50 H6 EPA 300.0 Sulfate 76.1 mg/L 8.0 05/09/16 23:43 B EPA 9060 Total Organic Carbon 12400 mg/kg 2660 05/05/16 09:48 EPA 9060 Total Organic Carbon 13400 mg/kg 2650 05/05/16 09:53 EPA 9060 Total Organic Carbon 11300 mg/kg 2670 05/05/16 10:00 EPA 9060 Total Organic Carbon 12400 mg/kg 2630 05/05/16 10:07 EPA 9060 Mean Total Organic Carbon 12400 mg/kg 2650 05/05/16 09:48 EPA 9060 RSD% 7.0 % 05/05/16 09:48 92295417005 2016011749 EPA 6010 Aluminum 305 mg/kg 4.9 05/04/16 08:46 EPA 6010 Barium 3.8 mg/kg 0.49 05/04/16 08:46 EPA 6010 Boron 4.9 mg/kg 2.5 05/04/16 08:46 EPA 6010 Calcium 104 mg/kg 24.7 05/04/16 08:46 EPA 6010 Chromium 0.49 mg/kg 0.25 05/04/16 08:46 EPA 6010 Copper 0.69 mg/kg 0.25 05/04/16 08:46 EPA 6010 Iron 93.1 mg/kg 2.0 05/04/16 08:46 EPA 6010 Magnesium 56.9 mg/kg 24.7 05/04/16 08:46 EPA 6010 Manganese 2.1 mg/kg 0.25 05/04/16 08:46 EPA 6010 Nickel 0.36 mg/kg 0.25 05/04/16 08:46 EPA 6010 Potassium 75.5 mg/kg 49.5 05/04/16 08:46 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffii�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J16040677 Pace Project No.: 92295417 Lab Sample ID Method Client Sample ID Parameters 92295417005 2016011749 EPA 6010 Strontium EPA 6010 Zinc EPA 6010 Barium EPA 6010 Boron EPA 6010 Calcium EPA 6010 Magnesium EPA 6010 Manganese EPA 6010 Strontium EPA 6010 Zinc EPA 6020 Vanadium EPA 6020B Antimony EPA 6020B Arsenic EPA 6020B Chromium EPA 6020B Molybdenum EPA 6020B Selenium EPA 6020B Vanadium EPA 9045 pH at 25 Degrees C EPA 300.0 Sulfate EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Mean Total Organic Carbon EPA 9060 RSD% SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 5.0 mg/kg 0.49 05/04/16 08:46 1.0 mg/kg 0.99 05/04/16 08:46 0.13 mg/L 0.050 05/06/1616:57 0.24 mg/L 0.20 05/06/1616:57 5.2 mg/L 1.0 05/06/1616:57 1.1 mg/L 0.10 05/06/1616:57 0.050 mg/L 0.0050 05/06/1616:57 0.26 mg/L 0.0050 05/06/1616:57 0.16 mg/L 0.050 05/06/1616:57 1.1 mg/kg 0.99 05/04/16 09:03 22.7 ug/L 0.50 05/13/1613:13 70.4 ug/L 0.50 05/13/1613:13 2.0 ug/L 0.50 05/13/1613:13 55.5 ug/L 0.50 05/13/1613:13 41.4 ug/L 0.50 05/13/1613:13 126 ug/L 0.50 05/13/1613:13 7.7 Std. Units 0.10 05/02/16 09:50 H6 5.5 mg/L 2.0 05/09/1616:56 B 25000 mg/kg 1990 05/05/1610:15 29400 mg/kg 1960 05/05/1610:23 30300 mg/kg 1970 05/05/1610:32 28700 mg/kg 1970 05/05/1610:40 28400 mg/kg 1970 05/05/1610:15 8.2 % 05/05/1610:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�fflic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 16, 2016 General Information: 5 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/30187 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35241272001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1560296) • Aluminum • Barium • Calcium • Iron • Magnesium • Strontium • MSD (Lab ID: 1560297) • Aluminum • Antimony • Barium • Beryllium • Boron • Calcium • Chromium • Copper REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ff�i�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 16, 2016 QC Batch: MPRP/30187 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35241272001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Iron • Magnesium • Manganese • Molybdenum • Potassium • Sodium • Strontium • Zinc R1: RPD value was outside control limits. • MSD (Lab ID: 1560297) • Antimony • Beryllium • Boron • Calcium • Chromium • Copper • Iron • Magnesium • Manganese • Nickel • Potassium • Sodium • Strontium • Zinc Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 6010 Description: 6010 MET ICP, SPLP Client: Duke Energy Date: May 16, 2016 General Information: 5 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3010A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/21619 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92295417001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1727356) • Aluminum • Barium • Boron • Calcium • Iron • Magnesium • Manganese • Nickel • Potassium • Sodium • Strontium • Zinc • MSD (Lab ID: 1727357) • Aluminum • Barium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ff�ic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 6010 Description: 6010 MET ICP, SPLP Client: Duke Energy Date: May 16, 2016 QC Batch: MPRP/21619 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92295417001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Boron • Calcium • Iron • Magnesium • Manganese • Nickel • Potassium • Sodium • Strontium • Zinc Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffligc&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 16, 2016 General Information: 5 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/30185 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35241630041 R1: RPD value was outside control limits. • MSD (Lab ID: 1560289) • Vanadium Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 12220 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 6020E Description: 6020 MET ICPMS, SPLP Client: Duke Energy Date: May 16, 2016 General Information: 5 samples were analyzed for EPA 6020B . All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3010A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g%c8w. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 7470 Description: 7470 Mercury, SPLP Client: Duke Energy Date: May 16, 2016 General Information: 5 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKinic& &e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: May 16, 2016 General Information: 5 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKiny&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: May 16, 2016 General Information: 5 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 116: Analysis initiated outside of the 15 minute EPA required holding time. •2016011745 (Lab ID:92295417001) •2016011746 (Lab ID:92295417002) •2016011747 (Lab ID:92295417003) •2016011748 (Lab ID:92295417004) •2016011749 (Lab ID:92295417005) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKiny&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: May 16, 2016 General Information: 5 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/27522 B: Analyte was detected in the associated method blank. • BLANK for HBN 312176 [WETA/275 (Lab ID: 1728518) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gK4-8y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: May 16, 2016 General Information: 5 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/27534 B: Analyte was detected in the associated method blank. • BLANK for HBN 312289 [WETA/275 (Lab ID: 1729113) • Nitrogen, Nitrate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g%c& &e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: May 16, 2016 General Information: 5 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K�i�c& &e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: May 16, 2016 General Information: 5 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/57328 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92295417005 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1556237) • Chloride • Sulfate Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/57328 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • 2016011745 (Lab ID: 92295417001) • Chloride • Sulfate •2016011746 (Lab ID:92295417002) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098v�%Y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: May 16, 2016 Analyte Comments: QC Batch: WETA/57328 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2016011747 (Lab ID:92295417003) • Chloride • Sulfate •2016011748 (Lab ID:92295417004) • Chloride • Sulfate •2016011749 (Lab ID:92295417005) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g igc&w. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: May 16, 2016 General Information: 5 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 111: Analysis conducted outside the EPA method holding time. •2016011749 (Lab ID:92295417005) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/57327 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92295417005 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1556233) • Nitrate as N Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/57327 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2016011745 (Lab ID:92295417001) • Nitrate as N •2016011746 (Lab ID:92295417002) • Nitrate as N •2016011747 (Lab ID:92295417003) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g ��c&�r�ie. Suite 100 �yJ Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: May 16, 2016 Analyte Comments: QC Batch: WETA/57327 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2016011748 (Lab ID:92295417004) • Nitrate as N •2016011749 (Lab ID:92295417005) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni�c y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16040677 Pace Project No.: 92295417 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: May 16, 2016 General Information: 5 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninic& &e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040677 Pace Project No.: 92295417 Sample: 2016011745 Lab ID: 92295417001 Collected: 04/26/16 13:40 Received: 04/27/16 12:20 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 6800 mg/kg 4.8 1 05/03/16 17:30 05/04/16 08:29 7429-90-5 Antimony ND mg/kg 0.72 1 05/03/16 17:30 05/04/16 08:29 7440-36-0 Barium 68.6 mg/kg 0.48 1 05/03/16 17:30 05/04/16 08:29 7440-39-3 Beryllium 0.28 mg/kg 0.048 1 05/03/16 17:30 05/04/16 08:29 7440-41-7 Boron 3.1 mg/kg 2.4 1 05/03/16 17:30 05/04/16 08:29 7440-42-8 Calcium 886 mg/kg 23.9 1 05/03/16 17:30 05/04/16 08:29 7440-70-2 Chromium 6.6 mg/kg 0.24 1 05/03/16 17:30 05/04/16 08:29 7440-47-3 Copper 9.5 mg/kg 0.24 1 05/03/16 17:30 05/04/16 08:29 7440-50-8 Iron 9400 mg/kg 1.9 1 05/03/16 17:30 05/04/16 08:29 7439-89-6 Magnesium 1180 mg/kg 23.9 1 05/03/16 17:30 05/04/16 08:29 7439-95-4 Manganese 721 mg/kg 1.2 5 05/03/16 17:30 05/04/1610:11 7439-96-5 Molybdenum 8.1 mg/kg 0.48 1 05/03/16 17:30 05/04/16 08:29 7439-98-7 Nickel 3.9 mg/kg 0.24 1 05/03/16 17:30 05/04/16 08:29 7440-02-0 Potassium 421 mg/kg 47.9 1 05/03/16 17:30 05/04/16 08:29 7440-09-7 Sodium ND mg/kg 47.9 1 05/03/16 17:30 05/04/16 08:29 7440-23-5 Strontium 15.9 mg/kg 0.48 1 05/03/16 17:30 05/04/16 08:29 7440-24-6 Zinc 19.0 mg/kg 0.96 1 05/03/16 17:30 05/04/16 08:29 7440-66-6 6010 MET ICP, SPLP Analytical Method: EPA 6010 Preparation Method: EPA 3010A Leachate Method/Date: EPA 1312; 05/01/16 16:00 Aluminum 0.26 mg/L 0.10 1 05/05/16 22:00 05/06/16 16:38 7429-90-5 M1 Barium 0.17 mg/L 0.050 1 05/05/16 22:00 05/06/16 16:38 7440-39-3 M1 Boron 0.22 mg/L 0.20 1 05/05/16 22:00 05/06/16 16:38 7440-42-8 M1 Calcium 24.5 mg/L 1.0 1 05/05/16 22:00 05/06/16 16:38 7440-70-2 M1 Iron 0.14 mg/L 0.050 1 05/05/16 22:00 05/06/16 16:38 7439-89-6 M1 Magnesium 3.5 mg/L 0.10 1 05/05/16 22:00 05/06/16 16:38 7439-95-4 M1 Manganese 4.4 mg/L 0.0050 1 05/05/16 22:00 05/06/16 16:38 7439-96-5 M1 Nickel ND mg/L 0.0050 1 05/05/16 22:00 05/06/16 16:38 7440-02-0 M1 Potassium ND mg/L 5.0 1 05/05/16 22:00 05/06/16 16:38 7440-09-7 M1 Sodium ND mg/L 5.0 1 05/05/16 22:00 05/06/16 16:38 7440-23-5 M1 Strontium 0.27 mg/L 0.0050 1 05/05/16 22:00 05/06/16 16:38 7440-24-6 M1 Zinc 0.19 mg/L 0.050 1 05/05/16 22:00 05/06/16 16:38 7440-66-6 M1 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Arsenic 13.9 mg/kg 0.96 20 05/03/16 17:30 05/04/16 08:53 7440-38-2 Cadmium ND mg/kg 0.11 20 05/03/16 17:30 05/04/16 08:53 7440-43-9 Cobalt 5.3 mg/kg 0.96 20 05/03/16 17:30 05/04/16 08:53 7440-48-4 Lead 3.7 mg/kg 0.96 20 05/03/16 17:30 05/04/16 08:53 7439-92-1 Selenium 3.3 mg/kg 0.96 20 05/03/16 17:30 05/04/16 08:53 7782-49-2 Thallium ND mg/kg 0.96 20 05/03/16 17:30 05/04/16 08:53 7440-28-0 Vanadium 23.3 mg/kg 0.96 20 05/03/16 17:30 05/04/16 08:53 7440-62-2 6020 MET ICPMS, SPLP Analytical Method: EPA 6020B Preparation Method: EPA 3010A Leachate Method/Date: EPA 1312; 05/01/16 16:00 Antimony 0.51 ug/L 0.50 1 05/06/1618:10 05/13/1612:39 7440-36-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 28 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni�c y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040677 Pace Project No.: 92295417 Sample: 2016011745 Lab ID: 92295417001 Collected: 04/26/16 13:40 Received: 04/27/16 12:20 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS, SPLP Arsenic Beryllium Cadmium Chromium Cobalt Copper Lead Molybdenum Selenium Thallium Vanadium 7470 Mercury, SPLP Mercury 7471 Mercury Mercury 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Total Organic Carbon Quad Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Date: 05/16/2016 07:58 AM Analytical Method: EPA 6020B Preparation Method: EPA 3010A Leachate Method/Date: EPA 1312; 05/01/16 16:00 1.8 ug/L 0.50 1 05/06/1618:10 05/13/1612:39 7440-38-2 ND ug/L 0.10 1 05/06/1618:10 05/13/1612:39 7440-41-7 ND ug/L 0.080 1 05/06/1618:10 05/13/1612:39 7440-43-9 0.68 ug/L 0.50 1 05/06/1618:10 05/13/1612:39 7440-47-3 1.4 ug/L 0.50 1 05/06/1618:10 05/13/1612:39 7440-48-4 1.6 ug/L 1.0 1 05/06/1618:10 05/13/1612:39 7440-50-8 ND ug/L 0.50 1 05/06/1618:10 05/13/1612:39 7439-92-1 6.7 ug/L 0.50 1 05/06/1618:10 05/13/1612:39 7439-98-7 1.3 ug/L 0.50 1 05/06/1618:10 05/13/1612:39 7782-49-2 ND ug/L 0.10 1 05/06/1618:10 05/13/1612:39 7440-28-0 2.1 ug/L 0.50 1 05/06/1618:10 05/13/1612:39 7440-62-2 Analytical Method: EPA 7470 Preparation Method: EPA 7470 Leachate Method/Date: EPA 1312; 05/01/16 16:00 ND ug/L 0.20 1 05/06/1610:00 05/06/1613:54 7439-97-6 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.031 mg/kg 0.0080 1 05/04/16 08:20 05/04/16 16:07 7439-97-6 Analytical Method: EPA 9045 7.2 Std. Units 0.10 1 05/02/16 09:50 H6 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/01/16 16:00 77.3 mg/L 10.0 5 05/09/1615:04 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/01/16 16:00 ND mg/L 0.20 1 05/10/1617:53 B Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/01/16 16:00 ND mg/L 5.0 1 05/09/16 22:45 16887-00-6 Analytical Method: EPA 9056 ND mg/kg 253 5 04/28/1613:11 16887-00-6 D3 ND mg/kg 253 5 04/28/1613:11 14808-79-8 D3 Analytical Method: EPA 9056 ND mg/kg 25.3 5 04/28/1613:11 14797-55-8 D3 Analytical Method: EPA 9060 14000 mg/kg 6270 1 05/05/16 07:13 7440-44-0 13200 mg/kg 6160 1 05/05/16 07:19 7440-44-0 11600 mg/kg 5980 1 05/05/16 07:27 7440-44-0 13400 mg/kg 6130 1 05/05/16 07:35 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K�i�c& &e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040677 Pace Project No.: 92295417 Sample: 2016011745 Lab ID: 92295417001 Collected: 04/26/16 13:40 Received: 04/27/16 12:20 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Mean Total Organic Carbon 13000 mg/kg 6140 1 05/05/16 07:13 7440-44-0 Surrogates RSD% 7.6 % 1 05/05/16 07:13 Date: 05/16/2016 07:58 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K�i�c& &e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040677 Pace Project No.: 92295417 Sample: 2016011746 Lab ID: 92295417002 Collected: 04/26/16 14:05 Received: 04/27/16 12:20 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 9110 mg/kg 5.1 1 05/03/16 17:30 05/04/16 08:33 7429-90-5 Antimony ND mg/kg 0.76 1 05/03/16 17:30 05/04/16 08:33 7440-36-0 Barium 89.0 mg/kg 0.51 1 05/03/16 17:30 05/04/16 08:33 7440-39-3 Beryllium 1.0 mg/kg 0.051 1 05/03/16 17:30 05/04/16 08:33 7440-41-7 Boron 4.0 mg/kg 2.5 1 05/03/16 17:30 05/04/16 08:33 7440-42-8 Calcium 5010 mg/kg 25.3 1 05/03/16 17:30 05/04/16 08:33 7440-70-2 Chromium 10.6 mg/kg 0.25 1 05/03/16 17:30 05/04/16 08:33 7440-47-3 Copper 15.9 mg/kg 0.25 1 05/03/16 17:30 05/04/16 08:33 7440-50-8 Iron 8580 mg/kg 2.0 1 05/03/16 17:30 05/04/16 08:33 7439-89-6 Magnesium 676 mg/kg 25.3 1 05/03/16 17:30 05/04/16 08:33 7439-95-4 Manganese 1080 mg/kg 1.3 5 05/03/16 17:30 05/04/1610:15 7439-96-5 Molybdenum 8.3 mg/kg 0.51 1 05/03/16 17:30 05/04/16 08:33 7439-98-7 Nickel 8.3 mg/kg 0.25 1 05/03/16 17:30 05/04/16 08:33 7440-02-0 Potassium 727 mg/kg 50.6 1 05/03/16 17:30 05/04/16 08:33 7440-09-7 Sodium 111 mg/kg 50.6 1 05/03/16 17:30 05/04/16 08:33 7440-23-5 Strontium 49.7 mg/kg 0.51 1 05/03/16 17:30 05/04/16 08:33 7440-24-6 Zinc 23.3 mg/kg 1.0 1 05/03/16 17:30 05/04/16 08:33 7440-66-6 6010 MET ICP, SPLP Analytical Method: EPA 6010 Preparation Method: EPA 3010A Leachate Method/Date: EPA 1312; 05/01/16 16:00 Aluminum ND mg/L 0.10 1 05/05/16 22:00 05/06/16 16:47 7429-90-5 Barium 0.14 mg/L 0.050 1 05/05/16 22:00 05/06/16 16:47 7440-39-3 Boron ND mg/L 0.20 1 05/05/16 22:00 05/06/16 16:47 7440-42-8 Calcium 37.0 mg/L 1.0 1 05/05/16 22:00 05/06/16 16:47 7440-70-2 Iron 0.26 mg/L 0.050 1 05/05/16 22:00 05/06/16 16:47 7439-89-6 Magnesium 3.3 mg/L 0.10 1 05/05/16 22:00 05/06/16 16:47 7439-95-4 Manganese 5.6 mg/L 0.0050 1 05/05/16 22:00 05/06/16 16:47 7439-96-5 Nickel ND mg/L 0.0050 1 05/05/16 22:00 05/06/16 16:47 7440-02-0 Potassium ND mg/L 5.0 1 05/05/16 22:00 05/06/16 16:47 7440-09-7 Sodium ND mg/L 5.0 1 05/05/16 22:00 05/06/16 16:47 7440-23-5 Strontium 0.36 mg/L 0.0050 1 05/05/16 22:00 05/06/16 16:47 7440-24-6 Zinc 0.093 mg/L 0.050 1 05/05/16 22:00 05/06/16 16:47 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Arsenic 29.7 mg/kg 1.0 20 05/03/16 17:30 05/04/16 08:55 7440-38-2 Cadmium ND mg/kg 0.12 20 05/03/16 17:30 05/04/16 08:55 7440-43-9 Cobalt 6.2 mg/kg 1.0 20 05/03/16 17:30 05/04/16 08:55 7440-48-4 Lead 9.4 mg/kg 1.0 20 05/03/16 17:30 05/04/16 08:55 7439-92-1 Selenium 5.6 mg/kg 1.0 20 05/03/16 17:30 05/04/16 08:55 7782-49-2 Thallium ND mg/kg 1.0 20 05/03/16 17:30 05/04/16 08:55 7440-28-0 Vanadium 30.6 mg/kg 1.0 20 05/03/16 17:30 05/04/16 08:55 7440-62-2 6020 MET ICPMS, SPLP Analytical Method: EPA 6020B Preparation Method: EPA 3010A Leachate Method/Date: EPA 1312; 05/01/16 16:00 Antimony 0.88 ug/L 0.50 1 05/06/1618:10 05/13/1612:43 7440-36-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni�c y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040677 Pace Project No.: 92295417 Sample: 2016011746 Lab ID: 92295417002 Collected: 04/26/16 14:05 Received: 04/27/16 12:20 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS, SPLP Arsenic Beryllium Cadmium Chromium Cobalt Copper Lead Molybdenum Selenium Thallium Vanadium 7470 Mercury, SPLP Mercury 7471 Mercury Mercury 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Total Organic Carbon Quad Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Date: 05/16/2016 07:58 AM Analytical Method: EPA 6020B Preparation Method: EPA 3010A Leachate Method/Date: EPA 1312; 05/01/16 16:00 227 ug/L 0.50 1 05/06/1618:10 05/13/1612:43 7440-38-2 ND ug/L 0.10 1 05/06/1618:10 05/13/1612:43 7440-41-7 ND ug/L 0.080 1 05/06/1618:10 05/13/1612:43 7440-43-9 ND ug/L 0.50 1 05/06/1618:10 05/13/1612:43 7440-47-3 0.56 ug/L 0.50 1 05/06/1618:10 05/13/1612:43 7440-48-4 ND ug/L 1.0 1 05/06/1618:10 05/13/1612:43 7440-50-8 ND ug/L 0.50 1 05/06/1618:10 05/13/1612:43 7439-92-1 302 ug/L 0.50 1 05/06/1618:10 05/13/1612:43 7439-98-7 6.3 ug/L 0.50 1 05/06/1618:10 05/13/1612:43 7782-49-2 ND ug/L 0.10 1 05/06/1618:10 05/13/1612:43 7440-28-0 1.7 ug/L 0.50 1 05/06/1618:10 05/13/1612:43 7440-62-2 Analytical Method: EPA 7470 Preparation Method: EPA 7470 Leachate Method/Date: EPA 1312; 05/01/16 16:00 ND ug/L 0.20 1 05/06/1610:00 05/06/1614:01 7439-97-6 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.047 mg/kg 0.0076 1 05/04/16 08:20 05/04/16 16:10 7439-97-6 Analytical Method: EPA 9045 7.6 Std. Units 0.10 1 05/02/16 09:50 H6 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/01/16 16:00 12.4 mg/L 2.0 1 05/09/1615:48 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/01/16 16:00 ND mg/L 0.20 1 05/10/1617:58 B Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/01/16 16:00 ND mg/L 5.0 1 05/09/16 22:48 16887-00-6 Analytical Method: EPA 9056 ND mg/kg 253 5 04/28/1613:33 16887-00-6 D3 ND mg/kg 253 5 04/28/1613:33 14808-79-8 D3 Analytical Method: EPA 9056 ND mg/kg 25.3 5 04/28/1613:33 14797-55-8 D3 Analytical Method: EPA 9060 13000 mg/kg 3330 1 05/05/16 08:44 7440-44-0 13300 mg/kg 3250 1 05/05/16 08:49 7440-44-0 11500 mg/kg 3360 1 05/05/16 08:56 7440-44-0 11700 mg/kg 3320 1 05/05/16 09:05 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni�c y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040677 Pace Project No.: 92295417 Sample: 2016011746 Lab ID: 92295417002 Collected: 04/26/16 14:05 Received: 04/27/16 12:20 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Mean Total Organic Carbon 12400 mg/kg 3310 1 05/05/16 08:44 7440-44-0 Surrogates RSD% 7.4 % 1 05/05/16 08:44 Date: 05/16/2016 07:58 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 33 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098v�%Y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040677 Pace Project No.: 92295417 Sample: 2016011747 Lab ID: 92295417003 Collected: 04/26/16 14:30 Received: 04/27/16 12:20 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 947 mg/kg 4.9 1 05/03/16 17:30 05/04/16 08:37 7429-90-5 Antimony ND mg/kg 0.74 1 05/03/16 17:30 05/04/16 08:37 7440-36-0 Barium 10 mg/kg 0.49 1 05/03/16 17:30 05/04/16 08:37 7440-39-3 Beryllium 0.050 mg/kg 0.049 1 05/03/16 17:30 05/04/16 08:37 7440-41-7 Boron ND mg/kg 2.5 1 05/03/16 17:30 05/04/16 08:37 7440-42-8 Calcium 170 mg/kg 24.7 1 05/03/16 17:30 05/04/16 08:37 7440-70-2 Chromium 0.99 mg/kg 0.25 1 05/03/16 17:30 05/04/16 08:37 7440-47-3 Copper 2.8 mg/kg 0.25 1 05/03/16 17:30 05/04/16 08:37 7440-50-8 Iron 1140 mg/kg 2.0 1 05/03/16 17:30 05/04/16 08:37 7439-89-6 Magnesium 154 mg/kg 24.7 1 05/03/16 17:30 05/04/16 08:37 7439-95-4 Manganese 145 mg/kg 0.25 1 05/03/16 17:30 05/04/16 08:37 7439-96-5 Molybdenum 4.4 mg/kg 0.49 1 05/03/16 17:30 05/04/16 08:37 7439-98-7 Nickel 0.59 mg/kg 0.25 1 05/03/16 17:30 05/04/16 08:37 7440-02-0 Potassium 87.5 mg/kg 49.3 1 05/03/16 17:30 05/04/16 08:37 7440-09-7 Sodium ND mg/kg 49.3 1 05/03/16 17:30 05/04/16 08:37 7440-23-5 Strontium 3.1 mg/kg 0.49 1 05/03/16 17:30 05/04/16 08:37 7440-24-6 Zinc 3.4 mg/kg 0.99 1 05/03/16 17:30 05/04/16 08:37 7440-66-6 6010 MET ICP, SPLP Analytical Method: EPA 6010 Preparation Method: EPA 3010A Leachate Method/Date: EPA 1312; 05/01/16 16:00 Aluminum 0.22 mg/L 0.10 1 05/05/16 22:00 05/06/16 16:50 7429-90-5 Barium 0.21 mg/L 0.050 1 05/05/16 22:00 05/06/16 16:50 7440-39-3 Boron 0.27 mg/L 0.20 1 05/05/16 22:00 05/06/16 16:50 7440-42-8 Calcium 11.6 mg/L 1.0 1 05/05/16 22:00 05/06/16 16:50 7440-70-2 Iron 0.080 mg/L 0.050 1 05/05/16 22:00 05/06/16 16:50 7439-89-6 Magnesium 3.1 mg/L 0.10 1 05/05/16 22:00 05/06/16 16:50 7439-95-4 Manganese 7.4 mg/L 0.0050 1 05/05/16 22:00 05/06/16 16:50 7439-96-5 Nickel ND mg/L 0.0050 1 05/05/16 22:00 05/06/16 16:50 7440-02-0 Potassium ND mg/L 5.0 1 05/05/16 22:00 05/06/16 16:50 7440-09-7 Sodium 5.3 mg/L 5.0 1 05/05/16 22:00 05/06/16 16:50 7440-23-5 Strontium 0.20 mg/L 0.0050 1 05/05/16 22:00 05/06/16 16:50 7440-24-6 Zinc 0.18 mg/L 0.050 1 05/05/16 22:00 05/06/16 16:50 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Arsenic 3.1 mg/kg 0.99 20 05/03/16 17:30 05/04/16 08:58 7440-38-2 Cadmium ND mg/kg 0.12 20 05/03/16 17:30 05/04/16 08:58 7440-43-9 Cobalt ND mg/kg 0.99 20 05/03/16 17:30 05/04/16 08:58 7440-48-4 Lead ND mg/kg 0.99 20 05/03/16 17:30 05/04/16 08:58 7439-92-1 Selenium 1.3 mg/kg 0.99 20 05/03/16 17:30 05/04/16 08:58 7782-49-2 Thallium ND mg/kg 0.99 20 05/03/16 17:30 05/04/16 08:58 7440-28-0 Vanadium 3.2 mg/kg 0.99 20 05/03/16 17:30 05/04/16 08:58 7440-62-2 6020 MET ICPMS, SPLP Analytical Method: EPA 6020B Preparation Method: EPA 3010A Leachate Method/Date: EPA 1312; 05/01/16 16:00 Antimony 0.69 ug/L 0.50 1 05/06/1618:10 05/13/1612:56 7440-36-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nigc y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040677 Pace Project No.: 92295417 Sample: 2016011747 Lab ID: 92295417003 Collected: 04/26/16 14:30 Received: 04/27/16 12:20 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS, SPLP Arsenic Beryllium Cadmium Chromium Cobalt Copper Lead Molybdenum Selenium Thallium Vanadium 7470 Mercury, SPLP Mercury 7471 Mercury Mercury 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Total Organic Carbon Quad Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Date: 05/16/2016 07:58 AM Analytical Method: EPA 6020B Preparation Method: EPA 3010A Leachate Method/Date: EPA 1312; 05/01/16 16:00 6.1 ug/L 0.50 1 05/06/1618:10 05/13/1612:56 7440-38-2 ND ug/L 0.10 1 05/06/1618:10 05/13/1612:56 7440-41-7 ND ug/L 0.080 1 05/06/1618:10 05/13/1612:56 7440-43-9 ND ug/L 0.50 1 05/06/1618:10 05/13/1612:56 7440-47-3 5.0 ug/L 0.50 1 05/06/1618:10 05/13/1612:56 7440-48-4 ND ug/L 1.0 1 05/06/1618:10 05/13/1612:56 7440-50-8 ND ug/L 0.50 1 05/06/1618:10 05/13/1612:56 7439-92-1 19.2 ug/L 0.50 1 05/06/1618:10 05/13/1612:56 7439-98-7 1.8 ug/L 0.50 1 05/06/1618:10 05/13/1612:56 7782-49-2 ND ug/L 0.10 1 05/06/1618:10 05/13/1612:56 7440-28-0 0.67 ug/L 0.50 1 05/06/1618:10 05/13/1612:56 7440-62-2 Analytical Method: EPA 7470 Preparation Method: EPA 7470 Leachate Method/Date: EPA 1312; 05/01/16 16:00 ND ug/L 0.20 1 05/06/1610:00 05/06/1614:08 7439-97-6 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0080 1 05/04/16 08:20 05/04/16 16:12 7439-97-6 Analytical Method: EPA 9045 7.6 Std. Units 0.10 1 05/02/16 09:50 H6 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/01/16 16:00 65.7 mg/L 8.0 4 05/09/16 23:30 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/01/16 16:00 ND mg/L 0.20 1 05/10/1617:59 B Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/01/16 16:00 ND mg/L 5.0 1 05/09/16 22:49 16887-00-6 Analytical Method: EPA 9056 ND mg/kg 247 5 04/28/1613:55 16887-00-6 D3 ND mg/kg 247 5 04/28/1613:55 14808-79-8 D3 Analytical Method: EPA 9056 ND mg/kg 24.7 5 04/28/1613:55 14797-55-8 D3 Analytical Method: EPA 9060 9200 mg/kg 3330 1 05/05/16 09:11 7440-44-0 8800 mg/kg 3370 1 05/05/16 09:20 7440-44-0 10100 mg/kg 3280 1 05/05/16 09:27 7440-44-0 9840 mg/kg 3350 1 05/05/16 09:33 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 35 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni�c y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040677 Pace Project No.: 92295417 Sample: 2016011747 Lab ID: 92295417003 Collected: 04/26/16 14:30 Received: 04/27/16 12:20 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Mean Total Organic Carbon 9490 mg/kg 3330 1 05/05/16 09:11 7440-44-0 Surrogates RSD% 6.4 % 1 05/05/16 09:11 Date: 05/16/2016 07:58 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 36 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwiny&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040677 Pace Project No.: 92295417 Sample: 2016011748 Lab ID: 92295417004 Collected: 04/26/16 14:55 Received: 04/27/16 12:20 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 894 mg/kg 4.8 1 05/03/16 17:30 05/04/16 08:42 7429-90-5 Antimony ND mg/kg 0.73 1 05/03/16 17:30 05/04/16 08:42 7440-36-0 Barium 6.4 mg/kg 0.48 1 05/03/16 17:30 05/04/16 08:42 7440-39-3 Beryllium ND mg/kg 0.048 1 05/03/16 17:30 05/04/16 08:42 7440-41-7 Boron ND mg/kg 2.4 1 05/03/16 17:30 05/04/16 08:42 7440-42-8 Calcium 138 mg/kg 24.2 1 05/03/16 17:30 05/04/16 08:42 7440-70-2 Chromium 1.1 mg/kg 0.24 1 05/03/16 17:30 05/04/16 08:42 7440-47-3 Copper 1.5 mg/kg 0.24 1 05/03/16 17:30 05/04/16 08:42 7440-50-8 Iron 1100 mg/kg 1.9 1 05/03/16 17:30 05/04/16 08:42 7439-89-6 Magnesium 113 mg/kg 24.2 1 05/03/16 17:30 05/04/16 08:42 7439-95-4 Manganese 63.3 mg/kg 0.24 1 05/03/16 17:30 05/04/16 08:42 7439-96-5 Molybdenum 3.1 mg/kg 0.48 1 05/03/16 17:30 05/04/16 08:42 7439-98-7 Nickel 0.55 mg/kg 0.24 1 05/03/16 17:30 05/04/16 08:42 7440-02-0 Potassium ND mg/kg 48.5 1 05/03/16 17:30 05/04/16 08:42 7440-09-7 Sodium ND mg/kg 48.5 1 05/03/16 17:30 05/04/16 08:42 7440-23-5 Strontium 2.5 mg/kg 0.48 1 05/03/16 17:30 05/04/16 08:42 7440-24-6 Zinc 2.9 mg/kg 0.97 1 05/03/16 17:30 05/04/16 08:42 7440-66-6 6010 MET ICP, SPLP Analytical Method: EPA 6010 Preparation Method: EPA 3010A Leachate Method/Date: EPA 1312; 05/01/16 16:00 Aluminum 0.44 mg/L 0.10 1 05/05/16 22:00 05/06/16 16:53 7429-90-5 Barium 0.22 mg/L 0.050 1 05/05/16 22:00 05/06/16 16:53 7440-39-3 Boron 0.25 mg/L 0.20 1 05/05/16 22:00 05/06/16 16:53 7440-42-8 Calcium 15.1 mg/L 1.0 1 05/05/16 22:00 05/06/16 16:53 7440-70-2 Iron 0.29 mg/L 0.050 1 05/05/16 22:00 05/06/16 16:53 7439-89-6 Magnesium 4.3 mg/L 0.10 1 05/05/16 22:00 05/06/16 16:53 7439-95-4 Manganese 6.4 mg/L 0.0050 1 05/05/16 22:00 05/06/16 16:53 7439-96-5 Nickel 0.0055 mg/L 0.0050 1 05/05/16 22:00 05/06/16 16:53 7440-02-0 Potassium ND mg/L 5.0 1 05/05/16 22:00 05/06/16 16:53 7440-09-7 Sodium ND mg/L 5.0 1 05/05/16 22:00 05/06/16 16:53 7440-23-5 Strontium 0.27 mg/L 0.0050 1 05/05/16 22:00 05/06/16 16:53 7440-24-6 Zinc 0.21 mg/L 0.050 1 05/05/16 22:00 05/06/16 16:53 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Arsenic 3.4 mg/kg 0.97 20 05/03/16 17:30 05/04/16 09:00 7440-38-2 Cadmium ND mg/kg 0.12 20 05/03/16 17:30 05/04/16 09:00 7440-43-9 Cobalt ND mg/kg 0.97 20 05/03/16 17:30 05/04/16 09:00 7440-48-4 Lead ND mg/kg 0.97 20 05/03/16 17:30 05/04/16 09:00 7439-92-1 Selenium 1.7 mg/kg 0.97 20 05/03/16 17:30 05/04/16 09:00 7782-49-2 Thallium ND mg/kg 0.97 20 05/03/16 17:30 05/04/16 09:00 7440-28-0 Vanadium 3.0 mg/kg 0.97 20 05/03/16 17:30 05/04/16 09:00 7440-62-2 6020 MET ICPMS, SPLP Analytical Method: EPA 6020B Preparation Method: EPA 3010A Leachate Method/Date: EPA 1312; 05/01/16 16:00 Antimony 0.71 ug/L 0.50 1 05/06/1618:10 05/13/1613:00 7440-36-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 37 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwinic& &e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040677 Pace Project No.: 92295417 Sample: 2016011748 Lab ID: 92295417004 Collected: 04/26/16 14:55 Received: 04/27/16 12:20 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS, SPLP Arsenic Beryllium Cadmium Chromium Cobalt Copper Lead Molybdenum Selenium Thallium Vanadium 7470 Mercury, SPLP Mercury 7471 Mercury Mercury 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Total Organic Carbon Quad Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Date: 05/16/2016 07:58 AM Analytical Method: EPA 6020B Preparation Method: EPA 3010A Leachate Method/Date: EPA 1312; 05/01/16 16:00 1.6 ug/L 0.50 1 05/06/1618:10 05/13/1613:00 7440-38-2 0.13 ug/L 0.10 1 05/06/1618:10 05/13/1613:00 7440-41-7 0.12 ug/L 0.080 1 05/06/1618:10 05/13/1613:00 7440-43-9 0.96 ug/L 0.50 1 05/06/1618:10 05/13/1613:00 7440-47-3 7.5 ug/L 0.50 1 05/06/1618:10 05/13/1613:00 7440-48-4 ND ug/L 1.0 1 05/06/1618:10 05/13/1613:00 7440-50-8 ND ug/L 0.50 1 05/06/1618:10 05/13/1613:00 7439-92-1 2.3 ug/L 0.50 1 05/06/1618:10 05/13/1613:00 7439-98-7 1.9 ug/L 0.50 1 05/06/1618:10 05/13/1613:00 7782-49-2 0.11 ug/L 0.10 1 05/06/1618:10 05/13/1613:00 7440-28-0 0.91 ug/L 0.50 1 05/06/1618:10 05/13/1613:00 7440-62-2 Analytical Method: EPA 7470 Preparation Method: EPA 7470 Leachate Method/Date: EPA 1312; 05/01/16 16:00 ND ug/L 0.20 1 05/06/1610:00 05/06/1614:11 7439-97-6 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0079 1 05/04/16 08:20 05/04/16 16:14 7439-97-6 Analytical Method: EPA 9045 7.3 Std. Units 0.10 1 05/02/16 09:50 H6 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/01/16 16:00 76.1 mg/L 8.0 4 05/09/16 23:43 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/01/16 16:00 ND mg/L 0.20 1 05/10/1618:04 B Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/01/16 16:00 ND mg/L 5.0 1 05/09/16 22:50 16887-00-6 Analytical Method: EPA 9056 ND mg/kg 243 5 04/28/1614:17 16887-00-6 D3 ND mg/kg 243 5 04/28/1614:17 14808-79-8 D3 Analytical Method: EPA 9056 ND mg/kg 24.3 5 04/28/1614:17 14797-55-8 D3 Analytical Method: EPA 9060 12400 mg/kg 2660 1 05/05/16 09:48 7440-44-0 13400 mg/kg 2650 1 05/05/16 09:53 7440-44-0 11300 mg/kg 2670 1 05/05/1610:00 7440-44-0 12400 mg/kg 2630 1 05/05/1610:07 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 38 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gWi2c8w. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040677 Pace Project No.: 92295417 Sample: 2016011748 Lab ID: 92295417004 Collected: 04/26/16 14:55 Received: 04/27/16 12:20 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Mean Total Organic Carbon 12400 mg/kg 2650 1 05/05/16 09:48 7440-44-0 Surrogates RSD% 7.0 % 1 05/05/16 09:48 Date: 05/16/2016 07:58 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 39 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mc8w. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040677 Pace Project No.: 92295417 Sample: 2016011749 Lab ID: 92295417005 Collected: 04/26/16 16:16 Received: 04/27/16 12:20 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 305 mg/kg 4.9 1 05/03/16 17:30 05/04/16 08:46 7429-90-5 Antimony ND mg/kg 0.74 1 05/03/16 17:30 05/04/16 08:46 7440-36-0 Barium 3.8 mg/kg 0.49 1 05/03/16 17:30 05/04/16 08:46 7440-39-3 Beryllium ND mg/kg 0.049 1 05/03/16 17:30 05/04/16 08:46 7440-41-7 Boron 4.9 mg/kg 2.5 1 05/03/16 17:30 05/04/16 08:46 7440-42-8 Calcium 104 mg/kg 24.7 1 05/03/16 17:30 05/04/16 08:46 7440-70-2 Chromium 0.49 mg/kg 0.25 1 05/03/16 17:30 05/04/16 08:46 7440-47-3 Copper 0.69 mg/kg 0.25 1 05/03/16 17:30 05/04/16 08:46 7440-50-8 Iron 93.1 mg/kg 2.0 1 05/03/16 17:30 05/04/16 08:46 7439-89-6 Magnesium 56.9 mg/kg 24.7 1 05/03/16 17:30 05/04/16 08:46 7439-95-4 Manganese 2.1 mg/kg 0.25 1 05/03/16 17:30 05/04/16 08:46 7439-96-5 Molybdenum ND mg/kg 0.49 1 05/03/16 17:30 05/04/16 08:46 7439-98-7 Nickel 0.36 mg/kg 0.25 1 05/03/16 17:30 05/04/16 08:46 7440-02-0 Potassium 75.5 mg/kg 49.5 1 05/03/16 17:30 05/04/16 08:46 7440-09-7 Sodium ND mg/kg 49.5 1 05/03/16 17:30 05/04/16 08:46 7440-23-5 Strontium 5.0 mg/kg 0.49 1 05/03/16 17:30 05/04/16 08:46 7440-24-6 Zinc 1.0 mg/kg 0.99 1 05/03/16 17:30 05/04/16 08:46 7440-66-6 6010 MET ICP, SPLP Analytical Method: EPA 6010 Preparation Method: EPA 3010A Leachate Method/Date: EPA 1312; 05/01/16 16:00 Aluminum ND mg/L 0.10 1 05/05/16 22:00 05/06/16 16:57 7429-90-5 Barium 0.13 mg/L 0.050 1 05/05/16 22:00 05/06/16 16:57 7440-39-3 Boron 0.24 mg/L 0.20 1 05/05/16 22:00 05/06/16 16:57 7440-42-8 Calcium 5.2 mg/L 1.0 1 05/05/16 22:00 05/06/16 16:57 7440-70-2 Iron ND mg/L 0.050 1 05/05/16 22:00 05/06/16 16:57 7439-89-6 Magnesium 1.1 mg/L 0.10 1 05/05/16 22:00 05/06/16 16:57 7439-95-4 Manganese 0.050 mg/L 0.0050 1 05/05/16 22:00 05/06/16 16:57 7439-96-5 Nickel ND mg/L 0.0050 1 05/05/16 22:00 05/06/16 16:57 7440-02-0 Potassium ND mg/L 5.0 1 05/05/16 22:00 05/06/16 16:57 7440-09-7 Sodium ND mg/L 5.0 1 05/05/16 22:00 05/06/16 16:57 7440-23-5 Strontium 0.26 mg/L 0.0050 1 05/05/16 22:00 05/06/16 16:57 7440-24-6 Zinc 0.16 mg/L 0.050 1 05/05/16 22:00 05/06/16 16:57 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Arsenic ND mg/kg 0.99 20 05/03/16 17:30 05/04/16 09:03 7440-38-2 Cadmium ND mg/kg 0.12 20 05/03/16 17:30 05/04/16 09:03 7440-43-9 Cobalt ND mg/kg 0.99 20 05/03/16 17:30 05/04/16 09:03 7440-48-4 Lead ND mg/kg 0.99 20 05/03/16 17:30 05/04/16 09:03 7439-92-1 Selenium ND mg/kg 0.99 20 05/03/16 17:30 05/04/16 09:03 7782-49-2 Thallium ND mg/kg 0.99 20 05/03/16 17:30 05/04/16 09:03 7440-28-0 Vanadium 1.1 mg/kg 0.99 20 05/03/16 17:30 05/04/16 09:03 7440-62-2 6020 MET ICPMS, SPLP Analytical Method: EPA 6020B Preparation Method: EPA 3010A Leachate Method/Date: EPA 1312; 05/01/16 16:00 Antimony 22.7 ug/L 0.50 1 05/06/1618:10 05/13/1613:13 7440-36-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 40 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g%c& &e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040677 Pace Project No.: 92295417 Sample: 2016011749 Lab ID: 92295417005 Collected: 04/26/16 16:16 Received: 04/27/16 12:20 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS, SPLP Arsenic Beryllium Cadmium Chromium Cobalt Copper Lead Molybdenum Selenium Thallium Vanadium 7470 Mercury, SPLP Mercury 7471 Mercury Mercury 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Total Organic Carbon Quad Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Date: 05/16/2016 07:58 AM Analytical Method: EPA 6020B Preparation Method: EPA 3010A Leachate Method/Date: EPA 1312; 05/01/16 16:00 70.4 ug/L 0.50 1 05/06/1618:10 05/13/1613:13 7440-38-2 ND ug/L 0.10 1 05/06/1618:10 05/13/1613:13 7440-41-7 ND ug/L 0.080 1 05/06/1618:10 05/13/1613:13 7440-43-9 2.0 ug/L 0.50 1 05/06/1618:10 05/13/1613:13 7440-47-3 ND ug/L 0.50 1 05/06/1618:10 05/13/1613:13 7440-48-4 ND ug/L 1.0 1 05/06/1618:10 05/13/1613:13 7440-50-8 ND ug/L 0.50 1 05/06/1618:10 05/13/1613:13 7439-92-1 55.5 ug/L 0.50 1 05/06/1618:10 05/13/1613:13 7439-98-7 41.4 ug/L 0.50 1 05/06/1618:10 05/13/1613:13 7782-49-2 ND ug/L 0.10 1 05/06/1618:10 05/13/1613:13 7440-28-0 126 ug/L 0.50 1 05/06/1618:10 05/13/1613:13 7440-62-2 Analytical Method: EPA 7470 Preparation Method: EPA 7470 Leachate Method/Date: EPA 1312; 05/01/16 16:00 ND ug/L 0.20 1 05/06/1610:00 05/06/1614:13 7439-97-6 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0080 1 05/04/16 08:20 05/04/16 16:16 7439-97-6 Analytical Method: EPA 9045 7.7 Std. Units 0.10 1 05/02/16 09:50 H6 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/01/16 16:00 5.5 mg/L 2.0 1 05/09/1616:56 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/01/16 16:00 ND mg/L 0.20 1 05/10/1618:05 B Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/01/16 16:00 ND mg/L 5.0 1 05/09/16 22:51 16887-00-6 Analytical Method: EPA 9056 ND mg/kg 249 5 04/28/1614:39 16887-00-6 D3,M1 ND mg/kg 249 5 04/28/1614:39 14808-79-8 D3,M1 Analytical Method: EPA 9056 ND mg/kg 24.9 5 04/28/1614:39 14797-55-8 D3,1-11, M1 Analytical Method: EPA 9060 25000 mg/kg 1990 1 05/05/1610:15 7440-44-0 29400 mg/kg 1960 1 05/05/1610:23 7440-44-0 30300 mg/kg 1970 1 05/05/1610:32 7440-44-0 28700 mg/kg 1970 1 05/05/1610:40 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 41 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mc8w. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16040677 Pace Project No.: 92295417 Sample: 2016011749 Lab ID: 92295417005 Collected: 04/26/16 16:16 Received: 04/27/16 12:20 Matrix: Solid Results reported on a "wet -weight" basis Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Mean Total Organic Carbon 28400 mg/kg 1970 1 05/05/16 10:15 7440-44-0 Surrogates RSD% 8.2 % 1 05/05/1610:15 Date: 05/16/2016 07:58 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 42 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mc8w. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040677 Pace Project No.: 92295417 QC Batch: MERP/9372 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury SPLP Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 METHOD BLANK: 1727436 Matrix: Water Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 05/06/1613:49 LABORATORY CONTROL SAMPLE: 1727437 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.6 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1727438 1727439 MS MSD 92295417001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.5 2.6 100 104 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 43 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mc& &e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040677 Pace Project No.: 92295417 QC Batch: MERP/6860 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 METHOD BLANK: 1560311 Matrix: Solid Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0081 05/04/1615:37 LABORATORY CONTROL SAMPLE: 1560312 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .081 0.079 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1560313 1560314 MS MSD 35241630010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.00591 .0827 .0848 0.083 0.086 93 95 80-120 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 44 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mc8w. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040677 Pace Project No.: 92295417 QC Batch: MPRP/30187 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 METHOD BLANK: 1560294 Matrix: Solid Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 Blank Reporting Parameter Units Result Limit Analyzed Aluminum mg/kg ND 5.0 05/04/16 07:57 Antimony mg/kg ND 0.75 05/04/16 07:57 Barium mg/kg ND 0.50 05/04/16 07:57 Beryllium mg/kg ND 0.050 05/04/16 07:57 Boron mg/kg ND 2.5 05/04/16 07:57 Calcium mg/kg ND 25.1 05/04/16 07:57 Chromium mg/kg ND 0.25 05/04/16 07:57 Copper mg/kg ND 0.25 05/04/16 07:57 Iron mg/kg ND 2.0 05/04/16 07:57 Magnesium mg/kg ND 25.1 05/04/16 07:57 Manganese mg/kg ND 0.25 05/04/16 07:57 Molybdenum mg/kg ND 0.50 05/04/16 07:57 Nickel mg/kg ND 0.25 05/04/16 07:57 Potassium mg/kg ND 50.1 05/04/16 07:57 Sodium mg/kg ND 50.1 05/04/16 07:57 Strontium mg/kg ND 0.50 05/04/16 07:57 Zinc mg/kg ND 1.0 05/04/16 07:57 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1560295 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 125 136 109 80-120 Antimony mg/kg 12.5 13.2 105 80-120 Barium mg/kg 12.5 13.7 110 80-120 Beryllium mg/kg 1.3 1.4 108 80-120 Boron mg/kg 125 121 97 80-120 Calcium mg/kg 627 692 110 80-120 Chromium mg/kg 12.5 14.3 114 80-120 Copper mg/kg 12.5 13.6 109 80-120 Iron mg/kg 125 136 109 80-120 Magnesium mg/kg 627 691 110 80-120 Manganese mg/kg 12.5 14.2 113 80-120 Molybdenum mg/kg 12.5 14.0 112 80-120 Nickel mg/kg 12.5 13.8 110 80-120 Potassium mg/kg 627 673 107 80-120 Sodium mg/kg 627 692 110 80-120 Strontium mg/kg 12.5 13.6 108 80-120 Zinc mg/kg 62.7 64.4 103 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 45 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mc8w. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040677 Pace Project No.: 92295417 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1560296 1560297 MS MSD 35241272001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Aluminum mg/kg 1170 130 131 1540 1550 284 289 75-125 1 20 M1 Antimony mg/kg 0.41U 13 13.1 10.8 6.8 82 51 75-125 45 20 M1,R1 Barium mg/kg 15.6 13 13.1 23.5 22.4 61 52 75-125 5 20 M1 Beryllium mg/kg 0.18 1.26 1.26 1.2 0.90 82 55 75-125 32 20 M1,R1 Boron mg/kg 21.9 130 131 123 87.6 77 50 75-125 33 20 M1,R1 Calcium mg/kg 44000 651 653 82800 32000 5960 -1840 75-125 89 20 M1,R1 Chromium mg/kg 7.2 13 13.1 17.4 25.8 78 142 75-125 39 20 M1,R1 Copper mg/kg 4.2 13 13.1 15.5 23.2 87 146 75-125 40 20 M1,R1 Iron mg/kg 3370 130 131 2970 48700 -310 34700 75-125 177 20 M1,R1 Magnesium mg/kg 543 651 653 1570 904 157 55 75-125 54 20 M1,R1 Manganese mg/kg 22.8 13 13.1 32.7 310 76 2200 75-125 162 20 M1,R1 Molybdenum mg/kg 2.3 13 13.1 12.9 11.5 81 70 75-125 12 20 M1 Nickel mg/kg 2.5 13 13.1 12.7 18.6 79 123 75-125 38 20 R1 Potassium mg/kg 139 651 653 761 575 95 67 75-125 28 20 M1,R1 Sodium mg/kg 81.4 651 653 698 467 95 59 75-125 40 20 M1,R1 Strontium mg/kg 94.7 13 13.1 168 78.3 564 -126 75-125 73 20 M1,R1 Zinc mg/kg 10.8 65.1 65.3 65.6 52.9 84 64 75-125 21 20 M1,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 46 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ony&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040677 Pace Project No.: 92295417 QC Batch: MPRP/21619 Analysis Method: EPA 6010 QC Batch Method: EPA 3010A Analysis Description: 6010 MET SPLP Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 METHOD BLANK: 1727354 Matrix: Water Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Aluminum mg/L ND 0.10 05/06/1616:29 Barium mg/L ND 0.050 05/06/1616:29 Boron mg/L ND 0.20 05/06/1616:29 Calcium mg/L ND 1.0 05/06/1616:29 Iron mg/L ND 0.050 05/06/1616:29 Magnesium mg/L ND 0.10 05/06/1616:29 Manganese mg/L ND 0.0050 05/06/1616:29 Nickel mg/L ND 0.0050 05/06/1616:29 Potassium mg/L ND 5.0 05/06/1616:29 Sodium mg/L ND 5.0 05/06/1616:29 Strontium mg/L ND 0.0050 05/06/1616:29 Zinc mg/L ND 0.050 05/06/1616:29 LABORATORY CONTROL SAMPLE: 1727355 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Aluminum mg/L 5 4.9 98 80-120 Barium mg/L .5 0.50 100 80-120 Boron mg/L .5 0.55 110 80-120 Calcium mg/L 5 5.2 105 80-120 Iron mg/L 5 5.1 102 80-120 Magnesium mg/L 5 5.0 99 80-120 Manganese mg/L .5 0.48 96 80-120 Nickel mg/L .5 0.50 99 80-120 Potassium mg/L 5 ND 99 80-120 Sodium mg/L 5 5.6 113 80-120 Strontium mg/L .5 0.48 96 80-120 Zinc mg/L .5 0.51 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1727356 1727357 MS MSD 92295417001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/L 0.26 5 5 22.2 22.2 440 439 75-125 0 20 M1 Barium mg/L 0.17 .5 .5 2.4 2.4 438 440 75-125 0 20 M1 Boron mg/L 0.22 .5 .5 2.5 2.5 458 463 75-125 1 20 M1 Calcium mg/L 24.5 5 5 46.5 46.6 441 441 75-125 0 20 M1 Iron mg/L 0.14 5 5 22.5 22.6 448 449 75-125 0 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 47 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�Ijin�c& &e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040677 Pace Project No.: 92295417 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1727356 1727357 MS MSD 92295417001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Magnesium mg/L 3.5 5 5 25.2 25.1 434 433 75-125 0 20 M1 Manganese mg/L 4.4 .5 .5 6.4 6.4 392 391 75-125 0 20 M1 Nickel mg/L ND .5 .5 2.2 2.2 433 431 75-125 0 20 M1 Potassium mg/L ND 5 5 24.0 24.0 441 442 75-125 0 20 M1 Sodium mg/L ND 5 5 24.0 24.5 410 421 75-125 2 20 M1 Strontium mg/L 0.27 .5 .5 2.4 2.4 427 428 75-125 0 20 M1 Zinc mg/L 0.19 .5 .5 2.2 2.3 401 413 75-125 3 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 48 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ony&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040677 Pace Project No.: 92295417 QC Batch: MPRP/30185 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 METHOD BLANK: 1560286 Matrix: Solid Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Arsenic mg/kg ND 1.0 05/04/16 07:55 Cadmium mg/kg ND 0.12 05/04/16 07:55 Cobalt mg/kg ND 1.0 05/04/16 07:55 Lead mg/kg ND 1.0 05/04/16 07:55 Selenium mg/kg ND 1.0 05/04/16 07:55 Thallium mg/kg ND 1.0 05/04/16 07:55 Vanadium mg/kg ND 1.0 05/04/16 07:55 LABORATORY CONTROL SAMPLE: 1560287 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 25.9 20.6 80 80-120 Cadmium mg/kg 2.6 2.0 79 80-120 L5 Cobalt mg/kg 25.9 20.9 81 80-120 Lead mg/kg 25.9 20.7 80 80-120 Selenium mg/kg 25.9 20.6 80 80-120 Thallium mg/kg 25.9 21.2 82 80-120 Vanadium mg/kg 25.9 20.9 81 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1560288 1560289 MS MSD 35241630041 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Arsenic mg/kg 1.5 28.4 27.9 28.4 24.9 95 84 75-125 13 20 Cadmium mg/kg 0.081 U 2.82 2.82 2.8 2.4 97 84 75-125 16 20 Cobalt mg/kg 0.62J 28.4 27.9 27.5 24.4 95 85 75-125 12 20 Lead mg/kg 3.2 28.4 27.9 31.1 26.3 98 83 75-125 17 20 Selenium mg/kg 0.56U 28.4 27.9 27.2 24.2 94 85 75-125 12 20 Thallium mg/kg 0.56U 28.4 27.9 28.8 24.7 101 88 75-125 15 20 Vanadium mg/kg 4.2 28.4 27.9 33.8 27.5 104 83 75-125 21 20 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 49 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nny&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040677 Pace Project No.: 92295417 QC Batch: MPRP/21638 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET SPLP Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 METHOD BLANK: 1727989 Matrix: Water Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony ug/L ND 0.50 05/13/1612:30 Arsenic ug/L ND 0.50 05/13/1612:30 Beryllium ug/L ND 0.10 05/13/1612:30 Cadmium ug/L ND 0.080 05/13/1612:30 Chromium ug/L ND 0.50 05/13/1612:30 Cobalt ug/L ND 0.50 05/13/1612:30 Copper ug/L ND 1.0 05/13/1612:30 Lead ug/L ND 0.50 05/13/1612:30 Molybdenum ug/L ND 0.50 05/13/1612:30 Selenium ug/L ND 0.50 05/13/1612:30 Thallium ug/L ND 0.10 05/13/1612:30 Vanadium ug/L ND 0.50 05/13/1612:30 LABORATORY CONTROL SAMPLE: 1727990 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 33.3 30.4 91 80-120 Arsenic ug/L 33.3 29.8 89 80-120 Beryllium ug/L 33.3 30.0 90 80-120 Cadmium ug/L 33.3 29.6 89 80-120 Chromium ug/L 33.3 31.1 93 80-120 Cobalt ug/L 33.3 31.1 93 80-120 Copper ug/L 33.3 31.4 94 80-120 Lead ug/L 33.3 31.1 93 80-120 Molybdenum ug/L 33.3 31.3 94 80-120 Selenium ug/L 33.3 29.1 87 80-120 Thallium ug/L 33.3 30.4 91 80-120 Vanadium ug/L 33.3 30.5 92 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1727991 1727992 MS MSD 92295417002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L 0.88 33.3 33.3 31.2 32.6 91 95 5 Arsenic ug/L 227 33.3 33.3 260 264 102 112 1 Beryllium ug/L ND 33.3 33.3 30.1 31.2 90 94 4 Cadmium ug/L ND 33.3 33.3 29.7 30.9 89 93 4 Chromium ug/L ND 33.3 33.3 30.5 32.2 91 96 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 50 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mc& &e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040677 Pace Project No.: 92295417 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1727991 1727992 MS MSD 92295417002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cobalt ug/L 0.56 33.3 33.3 30.6 32.2 90 95 5 Copper ug/L ND 33.3 33.3 29.4 30.5 87 90 4 Lead ug/L ND 33.3 33.3 30.2 31.2 90 93 3 Molybdenum ug/L 302 33.3 33.3 339 349 108 138 3 Selenium ug/L 6.3 33.3 33.3 33.8 34.0 83 83 1 Thallium ug/L ND 33.3 33.3 29.9 31.5 90 95 5 Vanadium ug/L 1.7 33.3 33.3 32.1 33.5 91 95 4 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 51 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nny&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040677 Pace Project No.: 92295417 QC Batch: WETA/27522 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 METHOD BLANK: 1728518 Matrix: Water Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 2.0 2.0 05/09/1613:46 B LABORATORY CONTROL SAMPLE: 1728519 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.4 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1728520 1728521 MS MSD 92295417001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 77.3 20 20 101 101 119 119 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 52 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ony&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040677 Pace Project No.: 92295417 QC Batch: WETA/27534 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 METHOD BLANK: 1729113 Matrix: Water Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.13 0.020 05/10/16 17:49 B LABORATORY CONTROL SAMPLE: 1729114 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1729115 1729116 MS MSD 92295417001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 2.5 2.5 2.5 2.5 98 98 90-110 0 10 B Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 53 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g"c8w. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040677 Pace Project No.: 92295417 QC Batch: WETA/27533 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 METHOD BLANK: 1729089 Matrix: Water Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 05/09/16 22:43 LABORATORY CONTROL SAMPLE: 1729090 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.5 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1729091 1729092 MS MSD 92295417001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 10 10 11.1 11.1 100 100 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 54 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ogc y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040677 Pace Project No.: 92295417 QC Batch: WETA/57328 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 METHOD BLANK: 1556234 Matrix: Solid Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 50.1 04/28/1615:24 Sulfate mg/kg ND 50.1 04/28/1615:24 LABORATORY CONTROL SAMPLE: 1556235 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/kg 497 485 98 80-120 Sulfate mg/kg 497 478 96 80-120 MATRIX SPIKE SAMPLE: 1556237 92295417005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chloride mg/kg ND 503 875 155 80-120 M1 Sulfate mg/kg ND 503 932 168 80-120 M1 SAMPLE DUPLICATE: 1556236 92295417005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Chloride mg/kg ND ND 20 Sulfate mg/kg ND ND 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 55 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ony&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040677 Pace Project No.: 92295417 QC Batch: WETA/57327 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 METHOD BLANK: 1556228 Matrix: Solid Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 04/28/16 15:24 LABORATORY CONTROL SAMPLE: 1556229 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.7 48.1 97 80-120 MATRIX SPIKE SAMPLE: 1556233 92295417005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 50.3 89.3 178 80-120 H1,M1 SAMPLE DUPLICATE: 1556232 92295417005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 56 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oi�c y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16040677 Pace Project No.: 92295417 QC Batch: WETA/33482 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92295417001, 92295417002, 92295417003, 92295417004, 92295417005 METHOD BLANK: 1329725 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 647 05/05/16 06:19 LABORATORY CONTROL SAMPLE: 1329726 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 114000 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1329727 1329728 MS MSD 92295417001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 13000 56500 55800 69200 67700 99 98 50-150 2 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 57 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinlc& &e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J16040677 Pace Project No.: 92295417 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICPM/12220 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. H1 Analysis conducted outside the EPA method holding time. H6 Analysis initiated outside of the 15 minute EPA required holding time. L5 LCS recovery exceeded QC limits. Batch accepted based on matrix spike recovery within LCS limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 58 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oi�c y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: J16040677 92295417 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92295417001 2016011745 EPA 3050 MPRP/30187 EPA 6010 ICP/18037 92295417002 2016011746 EPA 3050 MPRP/30187 EPA 6010 ICP/18037 92295417003 2016011747 EPA 3050 MPRP/30187 EPA 6010 ICP/18037 92295417004 2016011748 EPA 3050 MPRP/30187 EPA 6010 ICP/18037 92295417005 2016011749 EPA 3050 MPRP/30187 EPA 6010 ICP/18037 92295417001 2016011745 EPA 3010A MPRP/21619 EPA6010 ICP/19396 92295417002 2016011746 EPA 3010A MPRP/21619 EPA 6010 ICP/19396 92295417003 2016011747 EPA 3010A MPRP/21619 EPA6010 ICP/19396 92295417004 2016011748 EPA 3010A MPRP/21619 EPA6010 ICP/19396 92295417005 2016011749 EPA 3010A MPRP/21619 EPA 6010 ICP/19396 92295417001 2016011745 EPA 3050 MPRP/30185 EPA 6020 ICPM/12220 92295417002 2016011746 EPA 3050 MPRP/30185 EPA 6020 ICPM/12220 92295417003 2016011747 EPA 3050 MPRP/30185 EPA 6020 ICPM/12220 92295417004 2016011748 EPA 3050 MPRP/30185 EPA 6020 ICPM/12220 92295417005 2016011749 EPA 3050 MPRP/30185 EPA 6020 ICPM/12220 92295417001 2016011745 EPA 3010A MPRP/21638 EPA 6020B ICPM/1223 92295417002 2016011746 EPA 3010A MPRP/21638 EPA 6020B ICPM/1223 92295417003 2016011747 EPA 3010A MPRP/21638 EPA 6020B ICPM/1223 92295417004 2016011748 EPA 3010A MPRP/21638 EPA 6020B ICPM/1223 92295417005 2016011749 EPA 3010A MPRP/21638 EPA 6020E ICPM/1223 92295417001 2016011745 EPA 7470 MERP/9372 EPA 7470 MERC/9002 92295417002 2016011746 EPA 7470 MERP/9372 EPA 7470 MERC/9002 92295417003 2016011747 EPA 7470 MERP/9372 EPA 7470 MERC/9002 92295417004 2016011748 EPA 7470 MERP/9372 EPA 7470 MERC/9002 92295417005 2016011749 EPA 7470 MERP/9372 EPA 7470 MERC/9002 92295417001 2016011745 EPA 7471 MERP/6860 EPA 7471 MERC/6827 92295417002 2016011746 EPA 7471 MERP/6860 EPA 7471 MERC/6827 92295417003 2016011747 EPA 7471 MERP/6860 EPA 7471 MERC/6827 92295417004 2016011748 EPA 7471 MERP/6860 EPA 7471 MERC/6827 92295417005 2016011749 EPA 7471 MERP/6860 EPA 7471 MERC/6827 92295417001 2016011745 EPA 9045 WET/37416 92295417002 2016011746 EPA 9045 WET/37416 92295417003 2016011747 EPA 9045 WET/37416 92295417004 2016011748 EPA 9045 WET/37416 92295417005 2016011749 EPA 9045 WET/37416 92295417001 2016011745 EPA 300.0 WETA/27522 92295417002 2016011746 EPA 300.0 WETA/27522 92295417003 2016011747 EPA 300.0 WETA/27522 92295417004 2016011748 EPA 300.0 WETA/27522 92295417005 2016011749 EPA 300.0 WETA/27522 92295417001 2016011745 EPA 353.2 WETA/27534 92295417002 2016011746 EPA 353.2 WETA/27534 92295417003 2016011747 EPA 353.2 WETA/27534 92295417004 2016011748 EPA 353.2 WETA/27534 92295417005 2016011749 EPA 353.2 WETA/27534 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 59 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mc& &e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J16040677 Pace Project No.: 92295417 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92295417001 2016011745 SM 4500-CI-E WETA/27533 92295417002 2016011746 SM 4500-CI-E WETA/27533 92295417003 2016011747 SM 4500-CI-E WETA/27533 92295417004 2016011748 SM 4500-CI-E WETA/27533 92295417005 2016011749 SM 4500-CI-E WETA/27533 92295417001 2016011745 EPA 9056 WETA/57328 92295417002 2016011746 EPA 9056 WETA/57328 92295417003 2016011747 EPA 9056 WETA/57328 92295417004 2016011748 EPA 9056 WETA/57328 92295417005 2016011749 EPA 9056 WETA/57328 92295417001 2016011745 EPA 9056 WETA/57327 92295417002 2016011746 EPA 9056 WETA/57327 92295417003 2016011747 EPA 9056 WETA/57327 92295417004 2016011748 EPA 9056 WETA/57327 92295417005 2016011749 EPA 9056 WETA/57327 92295417001 2016011745 EPA 9060 WETA/33482 92295417001 2016011745 EPA 9060 WETA/33483 92295417002 2016011746 EPA 9060 WETA/33482 92295417002 2016011746 EPA 9060 WETA/33483 92295417003 2016011747 EPA 9060 WETA/33482 92295417003 2016011747 EPA 9060 WETA/33483 92295417004 2016011748 EPA 9060 WETA/33482 92295417004 2016011748 EPA 9060 WETA/33483 92295417005 2016011749 EPA 9060 WETA/33482 92295417005 2016011749 EPA 9060 WETA/33483 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/16/2016 07:58 AM without the written consent of Pace Analytical Services, Inc.. Page 60 of 62 Document Name. Sample Condition Upon Recel 72eAnalXicalo Document No.: F-CHR-CS-003-rev.18 Document Revised: 18FEB2016 Page 1 of 2 Issuing AuthoriPMge 64 of 66 Pace Huntersviile Qualitv Office Sample Condition Upon Client Name: Receipt Projec D) �-- T� Courier: ❑Fef x ❑UPs ❑USPS ❑Client ❑ Commercial ❑Other: Custody Seal Present? ❑Yes ®No' Seals Intact? ❑Yes ❑N W0#:92295417 N��11 ��ti��l fill I4� III 92295417 Date/Initials Person Examining Contents: 4-2 j`L Packing Material: ❑Bubble Wrap ❑Bubble Bags ❑None ❑Other: Thermometer: ❑ i1505 ❑ Type of Ice: D et []Blue ❑None ❑samples on ice, cooling process has begun Correction Factor: 0.0°C Cooler Temp Corrected ('C): Biological Tissue Frozen? []Yes ❑No QN/A Temp should be above freez'ng to 6°C USDA Regulated Soil (l/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, I'lYes F7zNo including Hawaii and Puerto Rico)? FlYes FIN COMMENTS: Chain of Custody Present? ❑yees []No [I N/A 1. Chain of Custody Filled Out? ®Yes [--]No ❑N/A 2. Chain of Custody Relinquished? UY6i , [:]No ❑N/A 3. Sampler Name and/or Signature on COC? es []NO ❑N/A 4. Samples Arrived within Hold Time? [Yes ❑No ❑NJA 5, Short Hold Time Analysis (02 hr.)? ❑Yes 01�0 (--]N/A 6. Rush Turn Around Time Requested? ❑Yes ❑No ❑N/A 7. Sufficient Volume? []yes ❑No ❑N/A 8. Correct Containers Used? []Yes ❑No [_1 N/A 9. -Pace Containers Used? L`j-.}�'-P QYes-• RNN ❑N/A Containers intact? ®Yes ❑No ❑N/A 10. Filtered Volume Received for Dissolved Tests? ❑Yes ❑No �� [31VJA 11. Note if sediment is visible in the dissolved container Sample Labels Match COC? [fifes ❑No ❑N/A 12. -Includes Date/Time/ID/Analysis Matrix: ' l L'— All containers needing acid/base preservation have been / 13. checked? []Yes []No QN/A All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2SO4, HCI<2; NaOH >9 Sulfide, NaCIH>12 Cyanide) Des ❑No ON/A Exceptions: VOA, Coliform, TOC, Oil and Grease, Z DRO/8015 (water) DOC,LLHg ❑Yes []No j�N/A Samples checked for dechlorination []Yes [:]No ❑N/A 14. Headspace in VOA Vials (>5-6mm)? []Yes []No ❑N/A 15. Trip Blank Present? ❑Yes ❑No [fN/A 16. Trip Blank Custody Seals Present? []Yes []No ❑N/A Pace Trip Blank Lot # (if purchased): CLIENT NOTIFICATION/RESOLUTION Field Data Required? ❑Yes ❑No Person Contacted: Date/Time: Comments/Resolution: Project Manager SCURF Review: f Date: L 4- / Project Manager SRF Review: Ci Date: & Note: Whenever there is a discrepancy affecting North tarolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification office (i.e. .Out of hold, incorrect preservative, out of temp, incorrect containers) Page 61 of 62 Page 65 of 66 C � n 3 m m 7 m li N z� d A m !" I Z� om � � I - V 3 3 m o c n Z A a� $_ s R a M 3 n 0 M� i C O rn a' N ' o x c ro S 7 b a O . 0 t.a v y- 4a �. 0 z a O 1 w ID wA-f CL tI�' n • o I n .. Customer to cmnplMe appropriate catumns to rig;N .., n n ^ �q V n Q7 /'wrr w M a w c$ n D y Z 2 i ! D 3 I r GI C Uf �' w c m ! x n K au4 n a w f i'e o .0 N IOUy v n ley e u Cr p l z c i yea m7! m 0 N n o l p 7 1 Q a ^ C,----------------- I I I j -'r - a m rD 0 ti C, e i i �`vl CT O pNn \ 3 > � Cd o y C}i v i 5r / d 0 � r7• Ul i } � O � c -a m. Ln i L CrV A 1 Camp."Analys s `F ai o Reqire m is 1 D i "Grab Total Metals ,Anions, r a PH " r 1- 8 oz jar (PAGE) 5 v i Oi ij d I C"\1 }�. Oi I -- TOC t-- 4 oz jar.. 4 (PACE) mn a m O• 1� SPLP - Total Metals and i Anions 2-8 m oz jars (PACE) ° 3 3 i _ Sediment specific tests f 2 - 8 oz jar (ACCESS I �� ANALYTICAL) a i 5 � i Hexachrom VI j I Radio nuclides i - :p 0 G 0 Z 7 i > m FD j E7 $ i p C' r Z t` `''Total # of Containers z z a In cn 0 v z z f' {n (A x ((M'� 76.E -4 -n O ?1 age 62 of 62 DUKE CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM f fL. Analytltal Laharatoryr $erwiea9 - - - - - ` _,_,_._._ ----- - Analytical Laboratory Use Ortly - - - i![4 Mmm Code MGii3A2 ;Buildln9 74RP A44rk �Jr9!rt Mevlz: .��}{IL 11++++ 11 11'' ,,1 �4�,1;�#{ I 1alS&HajammFerreRd ; �'�4.o4Lti1:11r. ^" aamglesOrlaareM ' EEV F Y ry JidlMersvHl4, IJ, C. 21LfIT8 j `i-n,4o•dch' baa&4,ap Stierra EDD r66 i1G—IL i — 1 Idf 1 — i DISTFUDUTIOH QN— ORIGINAL to LAB, COPY to CLIENT Fix: P31Y Ji76-43A9' I SAMPLE PROGRAM Ground Wahar_ 7 lac'I Nen+ �,rWIDES Plara AS Gfalmliywtxfef Assessment -Sail I Z)F% ex Nu- Pace iEE rt UIa@T� f an e ne" Me Follokvii Ptt}Mdd[ G�orrrs94 a LAM OF. 86M,Y...k r a,Lw 10 - air�.re�: r-u trlv:1:7jaQ ,�-H1Mt ., All1 4w Access Analytical 3'rlISIv," c,P,oxr+ig_ rµisues�i I' PO Number�.142057 3 n� ui �+r � ao- r c, W 2 tU OveGAG MCMUntirtg has' tRoll eSUblrslled aMi Is r7 A indkwLed abova Preaevvauves. when used nr4S1 he I `�' w IIJ CL Q _I p: 1] E.rvrdr corract rcc£duhtlnaj In all 5 41rco ml DU licids aboue. Cf pdaed with m 15 minutes W Wirrhple � � 6 :countin. 'Fur 6 ratitl IUnil and Prpc"s liJ. UulJUCti011 � F'j as . Mweii --- 1 i.8118'GtlOfl lltid rrni[lon La 1 lr6 {6dL8NYnaN, lu111 t3=,j`af}G,11 le IDescri tion or ID Elele Tlerw 5I natr4+ tlEF CL. .-^ Fya W < 'G [+1 OC � } 2 x. y rl. { I CL.— /b 1 d II -_ - 41 nT R , EQUIPME T a K 1 PER U - — "IIziI"IF frletaJs: AL 5b. As, Ea, Be, 5, Cd, Ca, Cr, Cv, Cu. F4, Pta, Mg, Mf;, N10. W. K. 5e, Na, Sr, TI, V, 7A, klercury, PH Anions: GI, Nitrate --Al, 604 5®di:m®4jl Spvq,ifie Parameters.: CEC^ Parlicic Siza Dwinbvtlan, REd.ox Pblantial j 'ItR0qud12$tpd TU rrwnld �i 1d D,sye u H- _'I' Ik"