NC0003425_J16040675 Report_20160801

Duke Energy Analytical Lab
+ _ DUKE Analytical Laboratory Page 1 of44
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J16040675
Project Name: ROXBORO - AB GW ASSESSMENT SURFACE
Customer Name(s): Brian Wilker, Tim Hunsucker, Fred Holt, Brandon Russo, Kathy Webb, John To
Customer Address: Roxboro Steam Station
1700 Dunnaway Road
Semora,NC 27343
Lab Contact: Mary Ann Ogle Phone: [phone]
dc=com, do duke -energy, dc=ent,
do=nam,ou=Accounts,ou=Personal,
u=PNTmnsitional, cn=MA05125 (154363)
Report Authorized By: f IagnotospeciFledportions ofthis ate: 5/12/2016
document.
(Signature) 016a13 b933r-nano
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By
Duke Energy Analytical Lab
Page 2 of 44
Sample Description
2016011727
Roxboro
26-Apr-16 10:50 AM
ILLEGIBLE
CV-2
2016011729
Roxboro
26-Apr-16 10:20 AM
ILLEGIBLE
CL-2S
2016011730
Roxboro
26-Apr-16 8:20 AM
ILLEGIBLE
CL-2
2016011731
Roxboro
26-Apr-16 9:25 AM
ILLEGIBLE
CL-5S
2016011732
Roxboro
26-Apr-16 8:50 AM
ILLEGIBLE
CL-5
2016011733
Roxboro
26-Apr-16 11:15 AM
ILLEGIBLE
CL-7
2016011734
Roxboro
26-Apr-16 5:00 PM
FIELD BLANK
2016011735
Roxboro
26-Apr-16
TRIP BLANK
8 Total Samples

Duke Energy Analytical Lab
Page 3 of 44
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
OV Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Anne Pridgeon Date: 5/12/2016

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040675
Site: CV-2
Collection Date: 26-Apr-16 10:50 AM
Analyte
Result
Units Qualifiers
RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
6.0
mg/L
0.1
Sulfate
63
mg/L
1
MERCURY IN WATER - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
DISSOLVED METALS BY ICP
Aluminum (Al)
0.006
mg/L
0.005
Barium (Ba)
0.040
mg/L
0.005
Boron (B)
1.18
mg/L
0.05
Iron (Fe)
0.039
mg/L
0.01
Manganese (Mn)
0.302
mg/L
0.005
Strontium (Sr)
0.372
mg/L
0.005
Zinc (Zn)
0.019
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
20.5
mg/L
0.01
Magnesium (Mg)
7.76
mg/L
0.005
Potassium (K)
4.33
mg/L
0.1
Sodium (Na)
11.0
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
0.173
mg/L
0.005
Barium (Ba)
0.041
mg/L
0.005
Boron (B)
1.10
mg/L
0.05
Iron (Fe)
0.240
mg/L
0.01
Manganese (Mn)
0.322
mg/L
0.005
Strontium (Sr)
0.355
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Duke Energy Analytical Lab
Page 4 of 44
Sample #: 2016011727
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/27/2016 13:52 TLINN
1 EPA 300.0 05/03/2016 10:17 BGN9034
10 EPA 300.0 05/03/2016 10:17 BGN9034
Vendor Method V_PACE
1 EPA 200.7
04/28/2016 11:22
MHH7131
1 EPA 200.7
04/28/2016 11:22
MHH7131
1 EPA 200.7
04/28/2016 11:22
MHH7131
1 EPA 200.7
04/28/2016 11:22
MHH7131
1 EPA 200.7
04/28/2016 11:22
MHH7131
1 EPA 200.7
04/28/2016 11:22
MHH7131
1 EPA 200.7
04/28/2016 11:22
MHH7131
1 EPA 200.7
04/28/2016 13:26
MHH7131
1 EPA 200.7
04/28/2016 13:26
MHH7131
1 EPA 200.7
04/28/2016 13:26
MHH7131
1 EPA 200.7
04/28/2016 13:26
MHH7131
1 EPA 200.7
04/29/2016 11:05
JJMACKE
1 EPA 200.7
04/29/2016 11:05
JJMACKE
1 EPA 200.7
04/29/2016 11:05
JJMACKE
1 EPA 200.7
04/29/2016 11:05
JJMACKE
1 EPA 200.7
04/29/2016 11:05
JJMACKE
1 EPA 200.7
04/29/2016 11:05
JJMACKE
1 EPA 200.7
04/29/2016 11:05
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040675
Site: CV-2
Collection Date: 26-Apr-16 10:50 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
2.75
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
10.9
ug/L
Lead (Pb)
1.66
ug/L
Molybdenum (Mo)
88.4
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
1.01
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
0.628
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
3.48
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
89.2
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
1.10
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
1.01
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
150
mg/L
Total Carbon
TOC
6.0
mg/L
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
Duke Energy Analytical Lab
Page 5 of 44
Sample #:
2016011727
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/28/2016 19:44
MHALL3
1
1
EPA 200.8
04/28/2016 19:44
MHALL3
1
1
EPA 200.8
04/28/2016 19:44
MHALL3
1
1
EPA 200.8
04/28/2016 19:44
MHALL3
1
1
EPA 200.8
04/28/2016 19:44
MHALL3
1
1
EPA 200.8
04/28/2016 19:44
MHALL3
1
1
EPA 200.8
04/28/2016 19:44
MHALL3
1
1
EPA 200.8
04/28/2016 19:44
MHALL3
1
1
EPA 200.8
04/28/2016 19:44
MHALL3
1
1
EPA 200.8
04/28/2016 19:44
MHALL3
1
1
EPA 200.8
04/28/2016 19:44
MHALL3
0.2
1
EPA 200.8
04/28/2016 19:44
MHALL3
0.3
1
EPA 200.8
04/28/2016 19:44
MHALL3
1
1
EPA 200.8
04/28/2016 21:43
MHALL3
1
1
EPA 200.8
04/28/2016 21:43
MHALL3
1
1
EPA 200.8
04/28/2016 21:43
MHALL3
1
1
EPA 200.8
04/28/2016 21:43
MHALL3
1
1
EPA 200.8
04/28/2016 21:43
MHALL3
1
1
EPA 200.8
04/28/2016 21:43
MHALL3
1
1
EPA 200.8
04/28/2016 21:43
MHALL3
1
1
EPA 200.8
04/28/2016 21:43
MHALL3
1
1
EPA 200.8
04/28/2016 21:43
MHALL3
1
1
EPA 200.8
04/28/2016 21:43
MHALL3
1
1
EPA 200.8
04/28/2016 21:43
MHALL3
0.2
1
EPA 200.8
04/28/2016 21:43
MHALL3
0.3
1
EPA 200.8
04/28/2016 21:43
MHALL3
Vendor Method V_PACE
Vendor Method V_PACE
25
1 SM2540C
04/28/201614:08
PARMSTR
0.5
5 SM5310C/EPA9060A
05/03/201611:39
CJELLIO
5
1 SM2540D
04/29/201610:30
PARMSTR

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040675
Site: CL-2S
Collection Date: 26-Apr-16 10:20 AM
Analyte
Result
Units Qualifiers
RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
6.0
mg/L
0.1
Sulfate
63
mg/L
1
MERCURY IN WATER - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
DISSOLVED METALS BY ICP
Aluminum (Al)
0.005
mg/L
0.005
Barium (Ba)
0.038
mg/L
0.005
Boron (B)
1.15
mg/L
0.05
Iron (Fe)
0.041
mg/L
0.01
Manganese (Mn)
0.294
mg/L
0.005
Strontium (Sr)
0.360
mg/L
0.005
Zinc (Zn)
0.021
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
20.7
mg/L
0.01
Magnesium (Mg)
7.82
mg/L
0.005
Potassium (K)
4.42
mg/L
0.1
Sodium (Na)
11.1
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
0.179
mg/L
0.005
Barium (Ba)
0.040
mg/L
0.005
Boron (B)
1.11
mg/L
0.05
Iron (Fe)
0.247
mg/L
0.01
Manganese (Mn)
0.326
mg/L
0.005
Strontium (Sr)
0.356
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Duke Energy Analytical Lab
Page 6 of 44
Sample #: 2016011729
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/27/2016 13:53 TLINN
1 EPA 300.0 05/03/2016 10:33 BGN9034
10 EPA 300.0 05/03/2016 10:33 BGN9034
Vendor Method V_PACE
1 EPA 200.7
04/28/2016 11:34
MHH7131
1 EPA 200.7
04/28/2016 11:34
MHH7131
1 EPA 200.7
04/28/2016 11:34
MHH7131
1 EPA 200.7
04/28/2016 11:34
MHH7131
1 EPA 200.7
04/28/2016 11:34
MHH7131
1 EPA 200.7
04/28/2016 11:34
MHH7131
1 EPA 200.7
04/28/2016 11:34
MHH7131
1 EPA 200.7
04/28/2016 13:38
MHH7131
1 EPA 200.7
04/28/2016 13:38
MHH7131
1 EPA 200.7
04/28/2016 13:38
MHH7131
1 EPA 200.7
04/28/2016 13:38
MHH7131
1 EPA 200.7
04/29/2016 11:16
JJMACKE
1 EPA 200.7
04/29/2016 11:16
JJMACKE
1 EPA 200.7
04/29/2016 11:16
JJMACKE
1 EPA 200.7
04/29/2016 11:16
JJMACKE
1 EPA 200.7
04/29/2016 11:16
JJMACKE
1 EPA 200.7
04/29/2016 11:16
JJMACKE
1 EPA 200.7
04/29/2016 11:16
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040675
Site: CL-2S
Collection Date: 26-Apr-16 10:20 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
2.76
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
12.7
ug/L
Lead (Pb)
1.71
ug/L
Molybdenum (Mo)
89.6
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
0.628
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
3.67
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
95.2
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
1.01
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
1.08
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
160
mg/L
Total Carbon
TOC
5.9
mg/L
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
Duke Energy Analytical Lab
Page 7 of 44
Sample #:
2016011729
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/28/2016 19:15
MHALL3
1
1
EPA 200.8
04/28/2016 19:15
MHALL3
1
1
EPA 200.8
04/28/2016 19:15
MHALL3
1
1
EPA 200.8
04/28/2016 19:15
MHALL3
1
1
EPA 200.8
04/28/2016 19:15
MHALL3
1
1
EPA 200.8
04/28/2016 19:15
MHALL3
1
1
EPA 200.8
04/28/2016 19:15
MHALL3
1
1
EPA 200.8
04/28/2016 19:15
MHALL3
1
1
EPA 200.8
04/28/2016 19:15
MHALL3
1
1
EPA 200.8
04/28/2016 19:15
MHALL3
1
1
EPA 200.8
04/28/2016 19:15
MHALL3
0.2
1
EPA 200.8
04/28/2016 19:15
MHALL3
0.3
1
EPA 200.8
04/28/2016 19:15
MHALL3
1
1
EPA 200.8
04/28/2016 21:50
MHALL3
1
1
EPA 200.8
04/28/2016 21:50
MHALL3
1
1
EPA 200.8
04/28/2016 21:50
MHALL3
1
1
EPA 200.8
04/28/2016 21:50
MHALL3
1
1
EPA 200.8
04/28/2016 21:50
MHALL3
1
1
EPA 200.8
04/28/2016 21:50
MHALL3
1
1
EPA 200.8
04/28/2016 21:50
MHALL3
1
1
EPA 200.8
04/28/2016 21:50
MHALL3
1
1
EPA 200.8
04/28/2016 21:50
MHALL3
1
1
EPA 200.8
04/28/2016 21:50
MHALL3
1
1
EPA 200.8
04/28/2016 21:50
MHALL3
0.2
1
EPA 200.8
04/28/2016 21:50
MHALL3
0.3
1
EPA 200.8
04/28/2016 21:50
MHALL3
Vendor Method V_PACE
Vendor Method V_PACE
25
1 SM2540C
04/28/201614:08
PARMSTR
0.5
5 SM5310C/EPA9060A
05/03/201611:39
CJELLIO
5
1 SM2540D
04/29/201610:30
PARMSTR

Certificate of Laborator Anal sis Duke EnergyAnalyti8 Lab
y y Page 8 of 44
This report shall not be reproduced, except in full.
Order # J16040675
Site: CL-2
Collection Date: 26-Apr-16 8:20 AM
Analyte
Result
Units Qualifiers
RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
6.0
mg/L
0.1
Sulfate
62
mg/L
1
MERCURY IN WATER - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
DISSOLVED METALS BY ICP
Aluminum (Al)
0.008
mg/L
0.005
Barium (Ba)
0.039
mg/L
0.005
Boron (B)
1.15
mg/L
0.05
Iron (Fe)
0.064
mg/L
0.01
Manganese (Mn)
0.328
mg/L
0.005
Strontium (Sr)
0.362
mg/L
0.005
Zinc (Zn)
0.016
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
20.1
mg/L
0.01
Magnesium (Mg)
7.65
mg/L
0.005
Potassium (K)
4.32
mg/L
0.1
Sodium (Na)
10.8
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
0.347
mg/L
0.005
Barium (Ba)
0.042
mg/L
0.005
Boron (B)
1.12
mg/L
0.05
Iron (Fe)
0.428
mg/L
0.01
Manganese (Mn)
0.390
mg/L
0.005
Strontium (Sr)
0.363
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016011730
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/27/2016 13:54 TLINN
1 EPA 300.0 05/03/2016 10:49 BGN9034
10 EPA 300.0 05/03/2016 10:49 BGN9034
Vendor Method V_PACE
1 EPA 200.7
04/28/2016 11:38
MHH7131
1 EPA 200.7
04/28/2016 11:38
MHH7131
1 EPA 200.7
04/28/2016 11:38
MHH7131
1 EPA 200.7
04/28/2016 11:38
MHH7131
1 EPA 200.7
04/28/2016 11:38
MHH7131
1 EPA 200.7
04/28/2016 11:38
MHH7131
1 EPA 200.7
04/28/2016 11:38
MHH7131
1 EPA 200.7
04/28/2016 13:42
MHH7131
1 EPA 200.7
04/28/2016 13:42
MHH7131
1 EPA 200.7
04/28/2016 13:42
MHH7131
1 EPA 200.7
04/28/2016 13:42
MHH7131
1 EPA 200.7
04/29/2016 11:20
JJMACKE
1 EPA 200.7
04/29/2016 11:20
JJMACKE
1 EPA 200.7
04/29/2016 11:20
JJMACKE
1 EPA 200.7
04/29/2016 11:20
JJMACKE
1 EPA 200.7
04/29/2016 11:20
JJMACKE
1 EPA 200.7
04/29/2016 11:20
JJMACKE
1 EPA 200.7
04/29/2016 11:20
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040675
Site: CL-2
Collection Date: 26-Apr-16 8:20 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
2.46
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
9.62
ug/L
Lead (Pb)
1.40
ug/L
Molybdenum (Mo)
85.2
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
0.688
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
3.42
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
79.6
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
1.09
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
1.35
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
160
mg/L
Total Carbon
TOC
6.2
mg/L
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
Duke Energy Analytical Lab
Page 9 of 44
Sample #:
2016011730
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/28/2016 19:51
MHALL3
1
1
EPA 200.8
04/28/2016 19:51
MHALL3
1
1
EPA 200.8
04/28/2016 19:51
MHALL3
1
1
EPA 200.8
04/28/2016 19:51
MHALL3
1
1
EPA 200.8
04/28/2016 19:51
MHALL3
1
1
EPA 200.8
04/28/2016 19:51
MHALL3
1
1
EPA 200.8
04/28/2016 19:51
MHALL3
1
1
EPA 200.8
04/28/2016 19:51
MHALL3
1
1
EPA 200.8
04/28/2016 19:51
MHALL3
1
1
EPA 200.8
04/28/2016 19:51
MHALL3
1
1
EPA 200.8
04/28/2016 19:51
MHALL3
0.2
1
EPA 200.8
04/28/2016 19:51
MHALL3
0.3
1
EPA 200.8
04/28/2016 19:51
MHALL3
1
1
EPA 200.8
04/28/2016 21:15
MHALL3
1
1
EPA 200.8
04/28/2016 21:15
MHALL3
1
1
EPA 200.8
04/28/2016 21:15
MHALL3
1
1
EPA 200.8
04/28/2016 21:15
MHALL3
1
1
EPA 200.8
04/28/2016 21:15
MHALL3
1
1
EPA 200.8
04/28/2016 21:15
MHALL3
1
1
EPA 200.8
04/28/2016 21:15
MHALL3
1
1
EPA 200.8
04/28/2016 21:15
MHALL3
1
1
EPA 200.8
04/28/2016 21:15
MHALL3
1
1
EPA 200.8
04/28/2016 21:15
MHALL3
1
1
EPA 200.8
04/28/2016 21:15
MHALL3
0.2
1
EPA 200.8
04/28/2016 21:15
MHALL3
0.3
1
EPA 200.8
04/28/2016 21:15
MHALL3
Vendor Method V_PACE
Vendor Method V_PACE
25
1 SM2540C
04/28/201614:08
PARMSTR
0.5
5 SM5310C/EPA9060A
05/03/201611:39
CJELLIO
5
1 SM2540D
04/29/201610:30
PARMSTR

Certificate of Laborator Anal sis Duke Energy i0 Lab
y y Page Page 10 of 44
This report shall not be reproduced, except in full.
Order # J16040675
Site: CL-5S
Collection Date: 26-Apr-16 9:25 AM
Analyte
Result
Units Qualifiers
RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.054
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
6.0
mg/L
0.1
Sulfate
63
mg/L
1
MERCURY IN WATER - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
DISSOLVED METALS BY ICP
Aluminum (Al)
0.012
mg/L
0.005
Barium (Ba)
0.039
mg/L
0.005
Boron (B)
1.15
mg/L
0.05
Iron (Fe)
0.041
mg/L
0.01
Manganese (Mn)
0.292
mg/L
0.005
Strontium (Sr)
0.361
mg/L
0.005
Zinc (Zn)
0.019
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
20.6
mg/L
0.01
Magnesium (Mg)
7.78
mg/L
0.005
Potassium (K)
4.39
mg/L
0.1
Sodium (Na)
11.1
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
0.178
mg/L
0.005
Barium (Ba)
0.040
mg/L
0.005
Boron (B)
1.10
mg/L
0.05
Iron (Fe)
0.241
mg/L
0.01
Manganese (Mn)
0.323
mg/L
0.005
Strontium (Sr)
0.355
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016011731
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/27/2016 13:55 TLINN
1 EPA 300.0 05/03/2016 11:05 BGN9034
10 EPA 300.0 05/03/2016 11:05 BGN9034
Vendor Method V_PACE
1 EPA 200.7
04/28/2016 11:42
MHH7131
1 EPA 200.7
04/28/2016 11:42
MHH7131
1 EPA 200.7
04/28/2016 11:42
MHH7131
1 EPA 200.7
04/28/2016 11:42
MHH7131
1 EPA 200.7
04/28/2016 11:42
MHH7131
1 EPA 200.7
04/28/2016 11:42
MHH7131
1 EPA 200.7
04/28/2016 11:42
MHH7131
1 EPA 200.7
04/28/2016 13:46
MHH7131
1 EPA 200.7
04/28/2016 13:46
MHH7131
1 EPA 200.7
04/28/2016 13:46
MHH7131
1 EPA 200.7
04/28/2016 13:46
MHH7131
1 EPA 200.7
04/29/2016 11:24
JJMACKE
1 EPA 200.7
04/29/2016 11:24
JJMACKE
1 EPA 200.7
04/29/2016 11:24
JJMACKE
1 EPA 200.7
04/29/2016 11:24
JJMACKE
1 EPA 200.7
04/29/2016 11:24
JJMACKE
1 EPA 200.7
04/29/2016 11:24
JJMACKE
1 EPA 200.7
04/29/2016 11:24
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040675
Site: CL-5S
Collection Date: 26-Apr-16 9:25 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
2.76
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
11.9
ug/L
Lead (Pb)
1.67
ug/L
Molybdenum (Mo)
91.4
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
1.01
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
0.770
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
3.38
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
87.5
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
1.06
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
1.00
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
150
mg/L
Total Carbon
TOC
6.1
mg/L
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
Duke Energy Analytical Lab
Page 11 of 44
Sample #:
2016011731
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/28/2016 19:58
MHALL3
1
1
EPA 200.8
04/28/2016 19:58
MHALL3
1
1
EPA 200.8
04/28/2016 19:58
MHALL3
1
1
EPA 200.8
04/28/2016 19:58
MHALL3
1
1
EPA 200.8
04/28/2016 19:58
MHALL3
1
1
EPA 200.8
04/28/2016 19:58
MHALL3
1
1
EPA 200.8
04/28/2016 19:58
MHALL3
1
1
EPA 200.8
04/28/2016 19:58
MHALL3
1
1
EPA 200.8
04/28/2016 19:58
MHALL3
1
1
EPA 200.8
04/28/2016 19:58
MHALL3
1
1
EPA 200.8
04/28/2016 19:58
MHALL3
0.2
1
EPA 200.8
04/28/2016 19:58
MHALL3
0.3
1
EPA 200.8
04/28/2016 19:58
MHALL3
1
1
EPA 200.8
04/28/2016 21:57
MHALL3
1
1
EPA 200.8
04/28/2016 21:57
MHALL3
1
1
EPA 200.8
04/28/2016 21:57
MHALL3
1
1
EPA 200.8
04/28/2016 21:57
MHALL3
1
1
EPA 200.8
04/28/2016 21:57
MHALL3
1
1
EPA 200.8
04/28/2016 21:57
MHALL3
1
1
EPA 200.8
04/28/2016 21:57
MHALL3
1
1
EPA 200.8
04/28/2016 21:57
MHALL3
1
1
EPA 200.8
04/28/2016 21:57
MHALL3
1
1
EPA 200.8
04/28/2016 21:57
MHALL3
1
1
EPA 200.8
04/28/2016 21:57
MHALL3
0.2
1
EPA 200.8
04/28/2016 21:57
MHALL3
0.3
1
EPA 200.8
04/28/2016 21:57
MHALL3
Vendor Method V_PACE
Vendor Method V_PACE
25
1 SM2540C
04/28/201614:08
PARMSTR
0.5
5 SM5310C/EPA9060A
05/03/201611:39
CJELLIO
5
1 SM2540D
04/29/201610:30
PARMSTR

Certificate of Laborator Anal sis Duke Energy i2 Lab
y y Page Page 12 of 44
This report shall not be reproduced, except in full.
Order # J16040675
Site: CL-5
Collection Date: 26-Apr-16 8:50 AM
Analyte
Result
Units Qualifiers
RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.025
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
6.4
mg/L
0.1
Sulfate
75
mg/L
1
MERCURY IN WATER - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
DISSOLVED METALS BY ICP
Aluminum (Al)
0.007
mg/L
0.005
Barium (Ba)
0.055
mg/L
0.005
Boron (B)
1.48
mg/L
0.05
Iron (Fe)
0.034
mg/L
0.01
Manganese (Mn)
0.956
mg/L
0.005
Strontium (Sr)
0.457
mg/L
0.005
Zinc (Zn)
0.020
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
24.7
mg/L
0.01
Magnesium (Mg)
9.27
mg/L
0.005
Potassium (K)
4.95
mg/L
0.1
Sodium (Na)
12.2
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
0.332
mg/L
0.005
Barium (Ba)
0.059
mg/L
0.005
Boron (B)
1.43
mg/L
0.05
Iron (Fe)
0.480
mg/L
0.01
Manganese (Mn)
0.885
mg/L
0.005
Strontium (Sr)
0.463
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016011732
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/27/2016 13:57 TLINN
1 EPA 300.0 05/03/2016 15:51 BGN9034
10 EPA 300.0 05/03/2016 15:51 BGN9034
Vendor Method V_PACE
1 EPA 200.7
04/28/2016 11:46
MHH7131
1 EPA 200.7
04/28/2016 11:46
MHH7131
1 EPA 200.7
04/28/2016 11:46
MHH7131
1 EPA 200.7
04/28/2016 11:46
MHH7131
1 EPA 200.7
04/28/2016 11:46
MHH7131
1 EPA 200.7
04/28/2016 11:46
MHH7131
1 EPA 200.7
04/28/2016 11:46
MHH7131
1 EPA 200.7
04/28/2016 13:50
MHH7131
1 EPA 200.7
04/28/2016 13:50
MHH7131
1 EPA 200.7
04/28/2016 13:50
MHH7131
1 EPA 200.7
04/28/2016 13:50
MHH7131
1 EPA 200.7
04/29/2016 11:27
JJMACKE
1 EPA 200.7
04/29/2016 11:27
JJMACKE
1 EPA 200.7
04/29/2016 11:27
JJMACKE
1 EPA 200.7
04/29/2016 11:27
JJMACKE
1 EPA 200.7
04/29/2016 11:27
JJMACKE
1 EPA 200.7
04/29/2016 11:27
JJMACKE
1 EPA 200.7
04/29/2016 11:27
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040675
Site: CL-5
Collection Date: 26-Apr-16 8:50 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
2.09
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
10.4
ug/L
Lead (Pb)
1.55
ug/L
Molybdenum (Mo)
94.9
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
1.08
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
0.433
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
4.60
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
94.4
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
1.27
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
1.36
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
190
mg/L
Total Carbon
TOC
6.0
mg/L
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
Duke Energy Analytical Lab
Page 13 of 44
Sample #:
2016011732
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/28/2016 20:05
MHALL3
1
1
EPA 200.8
04/28/2016 20:05
MHALL3
1
1
EPA 200.8
04/28/2016 20:05
MHALL3
1
1
EPA 200.8
04/28/2016 20:05
MHALL3
1
1
EPA 200.8
04/28/2016 20:05
MHALL3
1
1
EPA 200.8
04/28/2016 20:05
MHALL3
1
1
EPA 200.8
04/28/2016 20:05
MHALL3
1
1
EPA 200.8
04/28/2016 20:05
MHALL3
1
1
EPA 200.8
04/28/2016 20:05
MHALL3
1
1
EPA 200.8
04/28/2016 20:05
MHALL3
1
1
EPA 200.8
04/28/2016 20:05
MHALL3
0.2
1
EPA 200.8
04/28/2016 20:05
MHALL3
0.3
1
EPA 200.8
04/28/2016 20:05
MHALL3
1
1
EPA 200.8
04/28/2016 22:05
MHALL3
1
1
EPA 200.8
04/28/2016 22:05
MHALL3
1
1
EPA 200.8
04/28/2016 22:05
MHALL3
1
1
EPA 200.8
04/28/2016 22:05
MHALL3
1
1
EPA 200.8
04/28/2016 22:05
MHALL3
1
1
EPA 200.8
04/28/2016 22:05
MHALL3
1
1
EPA 200.8
04/28/2016 22:05
MHALL3
1
1
EPA 200.8
04/28/2016 22:05
MHALL3
1
1
EPA 200.8
04/28/2016 22:05
MHALL3
1
1
EPA 200.8
04/28/2016 22:05
MHALL3
1
1
EPA 200.8
04/28/2016 22:05
MHALL3
0.2
1
EPA 200.8
04/28/2016 22:05
MHALL3
0.3
1
EPA 200.8
04/28/2016 22:05
MHALL3
Vendor Method V_PACE
Vendor Method V_PACE
25
1 SM2540C
04/28/201614:08
PARMSTR
0.5
5 SM5310C/EPA9060A
05/03/201611:39
CJELLIO
5
1 SM2540D
04/29/201610:30
PARMSTR

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040675
Site: CL-7
Collection Date: 26-Apr-16 11:15 AM
Analyte
Result
Units Qualifiers
RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.025
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
5.9
mg/L
0.1
Sulfate
62
mg/L
1
MERCURY IN WATER - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
DISSOLVED METALS BY ICP
Aluminum (Al)
0.005
mg/L
0.005
Barium (Ba)
0.038
mg/L
0.005
Boron (B)
1.13
mg/L
0.05
Iron (Fe)
0.041
mg/L
0.01
Manganese (Mn)
0.290
mg/L
0.005
Strontium (Sr)
0.358
mg/L
0.005
Zinc (Zn)
0.016
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
20.6
mg/L
0.01
Magnesium (Mg)
7.78
mg/L
0.005
Potassium (K)
4.37
mg/L
0.1
Sodium (Na)
11.1
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
0.171
mg/L
0.005
Barium (Ba)
0.041
mg/L
0.005
Boron (B)
1.13
mg/L
0.05
Iron (Fe)
0.244
mg/L
0.01
Manganese (Mn)
0.336
mg/L
0.005
Strontium (Sr)
0.366
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Duke Energy Analytical Lab
Page 14 of 44
Sample #: 2016011733
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 04/27/2016 13:58 TLINN
1 EPA 300.0 05/03/2016 16:07 BGN9034
10 EPA 300.0 05/03/2016 16:07 BGN9034
Vendor Method V_PACE
1 EPA 200.7
04/28/2016 11:50
MHH7131
1 EPA 200.7
04/28/2016 11:50
MHH7131
1 EPA 200.7
04/28/2016 11:50
MHH7131
1 EPA 200.7
04/28/2016 11:50
MHH7131
1 EPA 200.7
04/28/2016 11:50
MHH7131
1 EPA 200.7
04/28/2016 11:50
MHH7131
1 EPA 200.7
04/28/2016 11:50
MHH7131
1 EPA 200.7
04/28/2016 13:54
MHH7131
1 EPA 200.7
04/28/2016 13:54
MHH7131
1 EPA 200.7
04/28/2016 13:54
MHH7131
1 EPA 200.7
04/28/2016 13:54
MHH7131
1 EPA 200.7
04/29/2016 11:31
JJMACKE
1 EPA 200.7
04/29/2016 11:31
JJMACKE
1 EPA 200.7
04/29/2016 11:31
JJMACKE
1 EPA 200.7
04/29/2016 11:31
JJMACKE
1 EPA 200.7
04/29/2016 11:31
JJMACKE
1 EPA 200.7
04/29/2016 11:31
JJMACKE
1 EPA 200.7
04/29/2016 11:31
JJMACKE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040675
Site: CL-7
Collection Date: 26-Apr-16 11:15 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
Arsenic (As)
2.28
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
11.0
ug/L
Lead (Pb)
1.57
ug/L
Molybdenum (Mo)
91.3
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
1.28
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
0.720
ug/L
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
Arsenic (As)
3.61
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
95.6
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
1.30
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
1.15
ug/L
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
160
mg/L
Total Carbon
TOC
6.0
mg/L
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
Duke Energy Analytical Lab
Page 15 of 44
Sample #:
2016011733
Matrix:
GW_WW
RDL
DF
Method
Analysis Date/Time
Analyst
1
1
EPA 200.8
04/28/2016 20:12
MHALL3
1
1
EPA 200.8
04/28/2016 20:12
MHALL3
1
1
EPA 200.8
04/28/2016 20:12
MHALL3
1
1
EPA 200.8
04/28/2016 20:12
MHALL3
1
1
EPA 200.8
04/28/2016 20:12
MHALL3
1
1
EPA 200.8
04/28/2016 20:12
MHALL3
1
1
EPA 200.8
04/28/2016 20:12
MHALL3
1
1
EPA 200.8
04/28/2016 20:12
MHALL3
1
1
EPA 200.8
04/28/2016 20:12
MHALL3
1
1
EPA 200.8
04/28/2016 20:12
MHALL3
1
1
EPA 200.8
04/28/2016 20:12
MHALL3
0.2
1
EPA 200.8
04/28/2016 20:12
MHALL3
0.3
1
EPA 200.8
04/28/2016 20:12
MHALL3
1
1
EPA 200.8
04/28/2016 22:12
MHALL3
1
1
EPA 200.8
04/28/2016 22:12
MHALL3
1
1
EPA 200.8
04/28/2016 22:12
MHALL3
1
1
EPA 200.8
04/28/2016 22:12
MHALL3
1
1
EPA 200.8
04/28/2016 22:12
MHALL3
1
1
EPA 200.8
04/28/2016 22:12
MHALL3
1
1
EPA 200.8
04/28/2016 22:12
MHALL3
1
1
EPA 200.8
04/28/2016 22:12
MHALL3
1
1
EPA 200.8
04/28/2016 22:12
MHALL3
1
1
EPA 200.8
04/28/2016 22:12
MHALL3
1
1
EPA 200.8
04/28/2016 22:12
MHALL3
0.2
1
EPA 200.8
04/28/2016 22:12
MHALL3
0.3
1
EPA 200.8
04/28/2016 22:12
MHALL3
Vendor Method V_PACE
Vendor Method V_PACE
25
1 SM2540C
04/28/201614:08
PARMSTR
0.5
5 SM5310C/EPA9060A
05/03/201611:39
CJELLIO
5
1 SM2540D
04/29/201610:30
PARMSTR

Certificate of Laborator Anal sis Duke Energy i6 Lab
y y Page Page 16 of 44
This report shall not be reproduced, except in full.
Order # J16040675
Site: FIELD BLANK
Collection Date: 26-Apr-16 5:00 PM
Analyte Result Units Qualifiers RDL DF
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2016011734
Matrix: GW_WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laborator Anal sis Duke Energy i7 Lab
y y Page Page 17 of 44
This report shall not be reproduced, except in full.
Order # J16040675
Site: TRIP BLANK
Collection Date: 26-Apr-16
Analyte Result Units Qualifiers RDL DF
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2016011735
Matrix: GW_WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0989 l 98 Ue. Suite 100
Huntersville, INC 28078
[phone]
May 10, 2016
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 16040675
Pace Project No.: 92295447
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory between April 27, 2016
and April 29, 2016. The results relate only to the samples included in this report. Results reported
herein conform to the most current TN standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Anne Pifer
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 26

aceAnaiXical
www.pacelabs.com
Duke Energy Xnal i alcrabervices, Inc.
0989Kli§c&�rWe. Suite 100
y Huntersville, NC 28078
[phone]
Project: J16040675
Pace Project No.: 92295447
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, INC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
VirginiaNELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 2 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0989I9698f4e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J16040675
Pace Project No.: 92295447
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92295447001
2016011727
Water
04/26/1610:50
04/27/1612:20
92295447002
2016011729
Water
04/26/1610:20
04/27/1612:20
92295447003
2016011730
Water
04/26/16 08:20
04/27/1612:20
92295447004
2016011731
Water
04/26/16 09:25
04/27/1612:20
92295447005
2016011732
Water
04/26/16 08:50
04/27/1612:20
92295447006
2016011733
Water
04/26/1611:15
04/27/1612:20
92295447007
2016011734
Water
04/26/1617:00
04/29/1614:38
92295447008
2016011735
Water
04/26/16 00:00
04/29/1614:38
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alcrabervices, Inc.
O Q�tf�T98f4e. Suite 100
yy Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16040675
92295447
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92295447001
2016011727
RSK 175 Modified
ZDO
1
PASI-C
EPA 1631E
SH1
1
PASI-A
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
MSH
1
PASI-A
92295447002
2016011729
RSK 175 Modified
ZDO
1
PASI-C
EPA 1631E
SH1
1
PASI-A
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
MSH
1
PASI-A
92295447003
2016011730
RSK 175 Modified
ZDO
1
PASI-C
EPA 1631E
SH1
1
PASI-A
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
MSH
1
PASI-A
92295447004
2016011731
RSK 175 Modified
ZDO
1
PASI-C
EPA 1631E
SH1
1
PASI-A
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
MSH
1
PASI-A
92295447005
2016011732
RSK 175 Modified
ZDO
1
PASI-C
EPA 1631E
SH1
1
PASI-A
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
MSH
1
PASI-A
92295447006
2016011733
RSK 175 Modified
ZDO
1
PASI-C
EPA 1631E
SH1
1
PASI-A
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
MSH
1
PASI-A
92295447007
2016011734
EPA 1631E
SH1
1
PASI-A
92295447008
2016011735
EPA 1631E
SH1
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 4 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0989I9298 We. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J16040675
92295447
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92295447001
2016011727
EPA 1631E
Mercury
1.36
ng/L
0.50
05/09/1612:19
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
38.8
mg/L
5.0
05/02/16 23:17
SM 2320B
Alkalinity, Total as CaCO3
38.8
mg/L
5.0
05/02/16 23:17
92295447002
2016011729
EPA 1631E
Mercury
1.29
ng/L
0.50
05/09/1612:26
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
39.4
mg/L
5.0
05/02/16 23:27
SM 2320B
Alkalinity, Total as CaCO3
39.4
mg/L
5.0
05/02/16 23:27
92295447003
2016011730
EPA 1631E
Mercury
2.02
ng/L
0.50
05/09/1612:34
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
37.3
mg/L
5.0
05/02/16 23:37
SM 2320B
Alkalinity, Total as CaCO3
37.3
mg/L
5.0
05/02/16 23:37
92295447004
2016011731
EPA 1631E
Mercury
1.41
ng/L
0.50
05/09/1612:41
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
38.0
mg/L
5.0
05/03/16 00:09
SM 2320B
Alkalinity, Total as CaCO3
38.0
mg/L
5.0
05/03/16 00:09
92295447005
2016011732
EPA 1631E
Mercury
1.88
ng/L
0.50
05/09/1612:49
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
41.1
mg/L
5.0
05/03/16 00:19
SM 2320B
Alkalinity, Total as CaCO3
41.1
mg/L
5.0
05/03/16 00:19
92295447006
2016011733
EPA 1631E
Mercury
1.33
ng/L
0.50
05/09/1612:57
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
37.4
mg/L
5.0
05/03/16 00:30
SM 2320B
Alkalinity, Total as CaCO3
37.4
mg/L
5.0
05/03/16 00:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0989I9998M We. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040675
Pace Project No.: 92295447
Method: RSK 175 Modified
Description: RSK 175 Headspace
Client: Duke Energy
Date: May 10, 2016
General Information:
6 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 6 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0989I9498f4e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040675
Pace Project No.: 92295447
Method: EPA 1631 E
Description: 1631 E Mercury,Low Level
Client: Duke Energy
Date: May 10, 2016
General Information:
8 samples were analyzed for EPA 1631 E. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 1631 E with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0989I9998f4e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040675
Pace Project No.: 92295447
Method: SM 2320B
Description: 2320E Alkalinity
Client: Duke Energy
Date: May 10, 2016
General Information:
6 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 8 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0989I9698f4e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040675
Pace Project No.: 92295447
Method: SM 4500-S213
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: May 10, 2016
General Information:
6 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/44578
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92295327007,92295343002
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1722395)
• Sulfide
• MSD (Lab ID: 1722396)
• Sulfide
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 9 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alcrabervices, Inc.
O Q�tf198f4e. Suite 100
yy Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040675
Pace Project No.: 92295447
Sample: 2016011727 Lab ID: 92295447001 Collected: 04/26/16 10:50 Received: 04/27/16 12:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
2320B Alkalinity
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Carbonate (CaCO3)
Alkalinity, Total as CaCO3
4500S2D Sulfide Water
Sulfide
Date: 05/10/2016 10:33 AM
Analytical Method: RSK 175 Modified
ND ug/L
10.0
1
04/30/16 01:25 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
1.36 ng/L
0.50
1 05/09/1610:45
05/09/1612:19 7439-97-6
Analytical Method: SM 2320B
38.8 mg/L
5.0
1
05/02/16 23:17
ND mg/L
5.0
1
05/02/16 23:17
38.8 mg/L
5.0
1
05/02/16 23:17
Analytical Method: SM 4500-S21D
ND mg/L
0.10
1
05/03/1615:30 18496-25-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0989I9898f4e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040675
Pace Project No.: 92295447
Sample: 2016011729 Lab ID: 92295447002 Collected: 04/26/16 10:20 Received: 04/27/16 12:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
2320B Alkalinity
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Carbonate (CaCO3)
Alkalinity, Total as CaCO3
4500S2D Sulfide Water
Sulfide
Date: 05/10/2016 10:33 AM
Analytical Method: RSK 175 Modified
ND ug/L
10.0
1
04/30/16 01:40 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
1.29 ng/L
0.50
1 05/09/1610:45
05/09/1612:26 7439-97-6
Analytical Method: SM 2320B
39.4 mg/L
5.0
1
05/02/16 23:27
ND mg/L
5.0
1
05/02/16 23:27
39.4 mg/L
5.0
1
05/02/16 23:27
Analytical Method: SM 4500-S21D
ND mg/L
0.10
1
05/03/1615:30 18496-25-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 11 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�a
QVbervices, Inc.
O 9998f4e. Suite 100
yy Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040675
Pace Project No.: 92295447
Sample: 2016011730 Lab ID: 92295447003 Collected: 04/26/16 08:20 Received: 04/27/16 12:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
2320B Alkalinity
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Carbonate (CaCO3)
Alkalinity, Total as CaCO3
4500S2D Sulfide Water
Sulfide
Date: 05/10/2016 10:33 AM
Analytical Method: RSK 175 Modified
ND ug/L
10.0
1
04/30/16 01:56 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
2.02 ng/L
0.50
1 05/09/1610:45
05/09/1612:34 7439-97-6
Analytical Method: SM 2320B
37.3 mg/L
5.0
1
05/02/16 23:37
ND mg/L
5.0
1
05/02/16 23:37
37.3 mg/L
5.0
1
05/02/16 23:37
Analytical Method: SM 4500-S21D
ND mg/L
0.10
1
05/03/1615:30 18496-25-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0980i6c&M We. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040675
Pace Project No.: 92295447
Sample: 2016011731 Lab ID: 92295447004 Collected: 04/26/16 09:25 Received: 04/27/16 12:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
2320B Alkalinity
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Carbonate (CaCO3)
Alkalinity, Total as CaCO3
4500S2D Sulfide Water
Sulfide
Date: 05/10/2016 10:33 AM
Analytical Method: RSK 175 Modified
ND ug/L
10.0
1
04/30/16 02:11 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
1.41 ng/L
0.50
1 05/09/1610:45
05/09/1612:41 7439-97-6
Analytical Method: SM 2320B
38.0 mg/L
5.0
1
05/03/16 00:09
ND mg/L
5.0
1
05/03/16 00:09
38.0 mg/L
5.0
1
05/03/16 00:09
Analytical Method: SM 4500-S21D
ND mg/L
0.10
1
05/03/1615:30 18496-25-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0980iT-W'We. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040675
Pace Project No.: 92295447
Sample: 2016011732 Lab ID: 92295447005 Collected: 04/26/16 08:50 Received: 04/27/16 12:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
2320B Alkalinity
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Carbonate (CaCO3)
Alkalinity, Total as CaCO3
4500S2D Sulfide Water
Sulfide
Date: 05/10/2016 10:33 AM
Analytical Method: RSK 175 Modified
ND ug/L
10.0
1
04/30/16 02:26 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
1.88 ng/L
0.50
1 05/09/1610:45
05/09/1612:49 7439-97-6
Analytical Method: SM 2320B
41.1 mg/L
5.0
1
05/03/16 00:19
ND mg/L
5.0
1
05/03/16 00:19
41.1 mg/L
5.0
1
05/03/16 00:19
Analytical Method: SM 4500-S21D
ND mg/L
0.10
1
05/03/1615:30 18496-25-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 14 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0980i2c&M We. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040675
Pace Project No.: 92295447
Sample: 2016011733 Lab ID: 92295447006 Collected: 04/26/16 11:15 Received: 04/27/16 12:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
2320B Alkalinity
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Carbonate (CaCO3)
Alkalinity, Total as CaCO3
4500S2D Sulfide Water
Sulfide
Date: 05/10/2016 10:33 AM
Analytical Method: RSK 175 Modified
ND ug/L
10.0
1
04/30/16 02:42 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
1.33 ng/L
0.50
1 05/09/1610:45
05/09/1612:57 7439-97-6
Analytical Method: SM 2320B
37.4 mg/L
5.0
1
05/03/16 00:30
ND mg/L
5.0
1
05/03/16 00:30
37.4 mg/L
5.0
1
05/03/16 00:30
Analytical Method: SM 4500-S21D
ND mg/L
0.10
1
05/03/1615:30 18496-25-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
09Q�K3i - We. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040675
Pace Project No.: 92295447
Sample: 2016011734 Lab ID: 92295447007 Collected: 04/26/16 17:00 Received: 04/29/16 14:38 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Mercury ND ng/L 0.50 1 05/09/1610:45 05/09/1614:30 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/10/2016 10:33 AM without the written consent of Pace Analytical Services, Inc.. Page 16 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0980i4c&M We. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040675
Pace Project No.: 92295447
Sample: 2016011735 Lab ID: 92295447008 Collected: 04/26/16 00:00 Received: 04/29/16 14:38 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Mercury ND ng/L 0.50 1 05/09/1610:45 05/09/1614:37 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/10/2016 10:33 AM without the written consent of Pace Analytical Services, Inc.. Page 17 of 26

aceAnaiXical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0980i9c&M We. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040675
Pace Project No.: 92295447
QC Batch: GCV/10558
Analysis Method:
RSK 175 Modified
QC Batch Method: RSK 175 Modified
Analysis Description:
RSK 175 HEADSPACE
Associated Lab Samples: 92295447001, 92295447002, 92295447003, 92295447004,
92295447005, 92295447006
METHOD BLANK: 1722840
Matrix: Water
Associated Lab Samples: 92295447001, 92295447002, 92295447003, 92295447004,
92295447005, 92295447006
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Methane
ug/L
ND 10.0
04/29/16 21:36
LABORATORY CONTROL SAMPLE:
1722841
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Methane
ug/L
396 378
95 70-130
MATRIX SPIKE SAMPLE:
1722842
92295331001 Spike
MS MS
% Rec
Parameter
Units
Result Conc.
Result % Rec
Limits Qualifiers
Methane
ug/L
11.2 396
442 109
70-130
SAMPLE DUPLICATE: 1722843
92295331004 Dup
Max
Parameter
Units
Result Result
RPD RPD
Qualifiers
Methane
ug/L
ND ND
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/10/2016 10:33 AM without the written consent of Pace Analytical Services, Inc.. Page 18 of 26

aceAnaiXical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0980i6c&M We. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040675
Pace Project No.: 92295447
QC Batch: MERP/9387 Analysis Method: EPA 1631 E
QC Batch Method: EPA 1631E Analysis Description: 1631E Mercury,Low Level
Associated Lab Samples: 92295447001, 92295447002, 92295447003, 92295447004, 92295447005, 92295447006, 92295447007,
92295447008
METHOD BLANK: 1728601 Matrix: Water
Associated Lab Samples: 92295447001, 92295447002, 92295447003, 92295447004, 92295447005, 92295447006, 92295447007,
92295447008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 05/09/1611:40
METHOD BLANK: 1728602 Matrix: Water
Associated Lab Samples: 92295447001, 92295447002, 92295447003, 92295447004, 92295447005, 92295447006, 92295447007,
92295447008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 05/09/1613:27
METHOD BLANK: 1728603 Matrix: Water
Associated Lab Samples: 92295447001, 92295447002, 92295447003, 92295447004, 92295447005, 92295447006, 92295447007,
92295447008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 05/09/1615:33
LABORATORY CONTROL SAMPLE: 1728604
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ng/L 5 5.21 104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1728605 1728606
MS MSD
92295135001 Spike Spike MS MSD MS MSD % Rec
Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD
RPD Qual
Mercury ng/L 0.820 25 25 24.9 25.2 96 98 71-125 1
24
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1728607 1728608
MS MSD
92295135005 Spike Spike MS MSD MS MSD % Rec
Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD
RPD Qual
Mercury ng/L 0.816 25 25 24.9 23.8 96 92 71-125 5
24
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/10/2016 10:33 AM without the written consent of Pace Analytical Services, Inc..
Page 19 of 26

aceAnaiXical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
098V�98M We. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040675
Pace Project No.: 92295447
QC Batch: WET/44624 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92295447001, 92295447002, 92295447003, 92295447004, 92295447005, 92295447006
METHOD BLANK: 1723797
Matrix: Water
Associated Lab Samples: 92295447001, 92295447002, 92295447003, 92295447004, 92295447005,
92295447006
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Alkalinity, Carbonate (CaCO3)
mg/L
ND 5.0
05/02/16 20:33
Alkalinity, Total as CaCO3
mg/L
ND 5.0
05/02/16 20:33
Alkalinity, Bicarbonate (CaCO3)
mg/L
ND 5.0
05/02/16 20:33
LABORATORY CONTROL SAMPLE: 1723798
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 48.1 96 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1723799 1723800
MS MSD
92295331006 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L ND 50 50 48.2 48.6 96 97 80-120 1 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1723801 1723802
MS MSD
92295447003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Alkalinity, Total as CaCO3 mg/L 37.3 50 50 85.4 84.9 96 95 80-120 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/10/2016 10:33 AM without the written consent of Pace Analytical Services, Inc..
Page 20 of 26

aceAnaiXical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0980igc&M We. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040675
Pace Project No.: 92295447
QC Batch: WET/44578 Analysis Method: SM 4500-S21D
QC Batch Method: SM 4500-S21D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92295447001, 92295447002, 92295447003, 92295447004
METHOD BLANK: 1722391 Matrix: Water
Associated Lab Samples: 92295447001, 92295447002, 92295447003, 92295447004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 05/03/1615:30
LABORATORY CONTROL SAMPLE: 1722392
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.51 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1722393 1722394
MS MSD
92295327007 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.49 0.49 98 98 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1722395 1722396
MS MSD
92295343002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.44 0.44 89 89 90-110 0 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/10/2016 10:33 AM without the written consent of Pace Analytical Services, Inc..
Page 21 of 26

aceAnaiXical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
0980998f4e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040675
Pace Project No.: 92295447
QC Batch: WET/44579 Analysis Method: SM 4500-S21D
QC Batch Method: SM 4500-S21D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92295447005, 92295447006
METHOD BLANK: 1722399 Matrix: Water
Associated Lab Samples: 92295447005, 92295447006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 05/03/1615:30
LABORATORY CONTROL SAMPLE: 1722400
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.51 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1722401 1722402
MS MSD
92295449003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.48 0.48 95 95 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1722403 1722404
MS MSD
92295449009 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.45 0.45 90 90 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/10/2016 10:33 AM without the written consent of Pace Analytical Services, Inc..
Page 22 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alcrabervices, Inc.
09_ fl'i6c&�rWe. Suite 100
y Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J16040675
Pace Project No.: 92295447
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/10/2016 10:33 AM without the written consent of Pace Analytical Services, Inc.. Page 23 of 26

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alcrabervices, Inc.
09_ fl'inlc&�rWe. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
J16040675
92295447
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92295447001
2016011727
RSK 175 Modified
GCV/10558
92295447002
2016011729
RSK 175 Modified
GCV/10558
92295447003
2016011730
RSK 175 Modified
GCV/10558
92295447004
2016011731
RSK 175 Modified
GCV/10558
92295447005
2016011732
RSK 175 Modified
GCV/10558
92295447006
2016011733
RSK 175 Modified
GCV/10558
92295447001
2016011727
EPA 1631 E
MERP/9387
EPA 1631 E
MERC/9014
92295447002
2016011729
EPA 1631 E
MERP/9387
EPA 1631 E
MERC/9014
92295447003
2016011730
EPA 1631 E
MERP/9387
EPA 1631 E
MERC/9014
92295447004
2016011731
EPA 1631 E
MERP/9387
EPA 1631 E
MERC/9014
92295447005
2016011732
EPA 1631 E
MERP/9387
EPA 1631 E
MERC/9014
92295447006
2016011733
EPA 1631 E
MERP/9387
EPA 1631 E
MERC/9014
92295447007
2016011734
EPA 1631 E
MERP/9387
EPA 1631 E
MERC/9014
92295447008
2016011735
EPA 1631 E
MERP/9387
EPA 1631 E
MERC/9014
92295447001
2016011727
SM 2320B
WET/44624
92295447002
2016011729
SM 2320B
WET/44624
92295447003
2016011730
SM 2320B
WET/44624
92295447004
2016011731
SM 2320B
WET/44624
92295447005
2016011732
SM 2320B
WET/44624
92295447006
2016011733
SM 2320B
WET/44624
92295447001
2016011727
SM 4500-S2D
WET/44578
92295447002
2016011729
SM 4500-S2D
WET/44578
92295447003
2016011730
SM 4500-S2D
WET/44578
92295447004
2016011731
SM 4500-S2D
WET/44578
92295447005
2016011732
SM 4500-S2D
WET/44579
92295447006
2016011733
SM 4500-S2D
WET/44579
Date: 05/10/2016 10:33 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 24 of 26

Document Name:
Document Revised: IBFE82016
Sample Condition Upon Recelpt(SCUR)
bage toy Analytical Lab
aceAnalXical
Document No.:
Issuing AuthorityPage 42 of 44
F-CHR-CS-003-rev.18
Pace Huntersville Quality Office
Sample Condition 1pon— Client Name:
Receipt Project I
Courier: OF d Ex ❑UPS OOSPS, ❑Client
ElCommercial ]Pace ❑Other:
WO#:92295447
1111111111111111111111111
92295447
I �
Custody Seal Present? Oyes ONo Seals Intact? Oyes []No
Date/Initials Person Examining Contents: d;71(
Packing Material: ❑Bubble Wrap ❑Bubble Bags ❑None []Other:
-
Thermometer: ®"T1505 [] Type of Ice: UWet ❑Blue []None [lSamples on ice, cooling process has begun
Correction Factor: 0.0°C Cooler Temp Corrected (°C): " , �� Biological Tissue Frozen? ❑Yes ❑No []N/A
Temp should be above freezing to 6°C
USDA Regulated Soil ( Q' N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally,
1-1vac ridr including Hawaii and Puerto Rico)? []Yes E[No
COMMENTS:
Chain of Custody Present?
0s
❑No
❑N/A
1.
Chain of Custody Filled Out?
[DYes
[-]No
❑N/A
2.
Chain of Custody Relinquished?
DYes
[-]No
❑N/A
3.
Sampler Name and/or Signature on COC?
es -©No
❑N/A
4.
Samples Arrived within Hold Time?
es
❑No _
❑N/A
5.
Short Hold Time Analysis (<72 hr.)?
❑Yes
06
❑N/A
6.
Rush Turn Around Time Requested?
❑Yes _
QNo
❑N/A
7.
StifficientVolume?
❑ties .
[:]No
❑N/A
8.
Correct Containers Used?
DYes
[:]No
❑N/A
9.
-Pace Containers Used? eY'9'
®ivo!
❑N/A
t:
Containers Intact?
❑Yes
[)No
❑N/A
10. 4--1 f�
Filtered Volume Received for Dissolved Tests?
❑Yes
[:]No_.
[jN/A
11. Note if sediment is visible in the dissolved container
Sample Labeis Match CDC?
Gs
[-]No
❑N/A
12.
`
-Includes Date/Time/ID/Analysis Matrix: w
�[
}
All containers needing acid/base preservation have been
13F
checked?
ElYs
❑No
❑N/A
All containers needing preservation are found to be in
compliance with EPA recommendation?~`
(HNO3, H2SO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide)
❑tires
❑No
❑N/A
Exceptions: VOA, Coliform, TOC, Oil and Grease,
/
DRO/8015 (water) DOC,LLHg
DYes
[:]No
❑N/A
Samples checked for dechlorination
[14s
j]No
❑N/A
14.
Headspace in VOA Vials (>5-6mm)?
[-]Yes
ONo
❑N/A
15.
Trip Blank Present?
❑Yes
[:]No
EfN/A
16,
Trip Blank Custody Seals Present?
❑Yes
[:]No
pN/A
Pace Trip Blank Lot N (if purchased):
CLIENT NOTIFICATION/RESOLUTION 1 Field IData Required? ❑Yes []No
Person Contacted: /'[M WYJA Date/Time:
Comments/Resolution: Li✓ d"4 kW
Project Manager SCURF Review: Date:�L�
Project Manager SRF Review: Date:
Note: Whenever there is a discrepancy affecting North Caro ina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification office (i.e.
.Out of hold, incorrect preservative, out of temp, incorrect containers)
Page 25 of 26

Duke Energy Analytical Lab
Page 43 of 44
�7
&IM
-+3
C
C
a M M
e
N C m
i
M M
aIN
1
b
ccic
its,\
�`✓
3^
3i 3
w' -
x S
a
y�,�
n-nJ
;o
vI
Tf .} n-n
n
c
ba
v
C% VI
4a
A
' I
-
C
x F-
m
f
F "
o
-4i3tCMTi9F {FF'ftinFi4lf1i�3t9s18&�Fl��" '
dosirad turnaround
A �
I O n B
N w
3 m
I
V � C
...................... -
a
si
(J-
_.I
i
_.._..�
rn
3
4
�i
I
!
o
1
w
E
it
III
„IL
N
;
a
_
r11
LO
pg
�
I
i g
43
� m
0
m
w.F
AI y
r
a
•m
tl
Ql ,
I
I
C) LM
� �
i
N
b
pp fh.�t
q
�
y e i1�ti �e? � •
�
Comp.
Grab
{
. ;;
2!
�e
st
a
TSS,TDS
wi
4b,
¢ e!
,p
H
Methane (RSK
1751 v_Pace
N
3
i• $ iI
Im
�
Cl, SO4.
4 I $I I v
u m
G0
a
a m m
m
t i
TOC, Nitrate-
Nitrite
m
+
i
Alkalinity,
Blcarbmnata,
.Carbonate-51_Pam
m
Sulfide
(V_pace)
oil
i
o
3
Hg 1631e
{V_Pace)
i
n; °
�
Q G)
0 �
C In m
I
� J
A
>
o i -i . o to
_
Metals (see
D
below)
m
N ; o I
bl5solved
x
metals
0
ILA
I
C 3
rD
'a y
0
0
o
a o o
Total IIIContairnera
6i
rn
Page 26 of 26

GRAIN OF 'CUSTOD'
..—
- - - _
Duke Eroer9Y
An6llyticall.ahorbHsry 135300%yrer"lif
ch— or Cu Rmd'y & 115ww ..*i. p. G. Nwo T Ev
P ,*Y f1q/I'J�idldW
fern N l - e.� aPFNt4 7 i
AND ANALYSIS REQUEST FORM
i+ul%hAicil li�OC93Dffd 1�Y 41dN-------- -._._._.
Aeld�pundhhlWr� 17PO&�,
Y4.Mr Y;497
• AB G Wnzmwv 5UF-tFAGE
l
.a. wenle
wider
P`arce
......
--R�—
._..---- --•.._e._.
Fjr' CwLlcrcl
FID #1699536 +S�+I
�
um�llornd
Ixh&m U►nIE '.
My,obr� Ti
armftm tc11
Yee
No'"
reiaA
ct ® n'
iiiw
4Cmlidnor VDIudii I4IY1I.] u
�Contiinsr Type PET
40 j d
30 1& �� 00 1, IS FnL
gong
PET PIT PET PC DWw
1"'+ tF M
�mp1e oea�riptkrn ar 147
3
33.
� I —
rEmAlw" paw--
R&W Blank
Trip slink
-
i
�aiomwr Pw wi11aI.N an mppfgip4q+ ell
s'NJormatlan.h
i 1,3
m>
-/A
go
Ilk
+
,
+ r
-
1 I.
w
#iil4 AmN ned EW
ELEMENTS h1' ICP—MS (TRUj: AA, Bs, Cd,C44 Cr, CM No, N11, Pb- W Sm, TI ILL}. w ELL)
ELEMENTS hp ICP [TRMI- fy1, 9a,. H. F6, M(L Sr, Zn ICR—Und1gialad Qk ft K. NA Hey Lpf 245.1
Du�ale'�d n'�+M� : all m�tili IMP, IMS,!'IY
0
Duke Energy Analytical Lab
p -1�of —1— Page 44 of 44
CNSTFdWTr DN Synterra ED'D
ORPUML to LAB, COPY h5 I
RCOC REV DATE
0
4
Q
tI
1
2
0 '4
Toul t$
ig Requestud Turmaround
�
fryy ff,�
L
E
'14 Clays
7 Days
}� f
"hm
v
`,Auld CrAd will Appiy