NC0003425_J16060542report_20160801

Lab
'■" DUKE Analytical Laboratory Duke EnergyAPagel1aof711
" EIERGY.
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J16060542
Project Name: ROXBORO - AB GW ASSESSMENT WATER
Customer Name(s): Brian Wilker, Tim Hunsucker, Fred Holt, Brandon Russo, Kathy Webb, John To
Customer Address: Roxboro Steam Station
1700 Dunnaway Road
Semora,NC 27343
Lab Contact: Anne Pridgeon Phone: [phone]
Reason: I have reviewed this
document.
Report Authorized By: Date:2016.06.2916:06:18 Date: 6/29/2016
(Signature)-04'00'
Anne Pridgeon
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory OC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2016018104
Roxboro
17-Jun-16 11:51 AM
2016018105
Roxboro
17-Jun-16 10:16 AM
2016018106
Roxboro
17-Jun-16 9:00 AM
2016018107
Roxboro
17-Jun-16 11:40 AM
2016018108
Roxboro
17-Jun-16 11:40 AM
5 Total Samples
Collected By
Daniel Youngblood
Daniel Youngblood
Daniel Youngblood
Daniel Youngblood
Daniel Youngblood
Duke Energy Analytical Lab
Page 2 of 71
Sample Description
MW-26BR
MW-20BRL
MW-23BR
Filter Blank
Equipment Blank

Duke Energy Analytical Lab
Page 3 of 71
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals E Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable. &.11 Yes ❑ No
Report Sections Included:
V Job Summary Report
U Sample Identification
n Technical Validation of Data Package
0 Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
IJ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
Electronic Data Deliverable (EDD) Sent Separatel
Reviewed By: Anne Pridgeon Date: 6/29/2016

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6060542
Site: MW-26BR
Collection Date: 17-Jun-16 11:51 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.012 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
35
mg/L
1
Sulfate
74
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (Al)
< 0.005
mg/L
0.005
Barium (Ba)
0.070
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.280
mg/L
0.01
Manganese (Mn)
0.584
mg/L
0.005
Strontium (Sr)
0.273
mg/L
0.005
Zinc (Zn)
0.010
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
102
mg/L
0.1
Magnesium (Mg)
43.7
mg/L
0.05
Potassium (K)
8.01
mg/L
0.1
Sodium (Na)
25.5
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
0.131
mg/L
0.005
Barium (Ba)
0.070
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.424
mg/L
0.01
Manganese (Mn)
0.594
mg/L
0.005
Strontium (Sr)
0.279
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Duke Energy Analytical Lab
Page 4 of 71
Sample #: 2016018104
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 06/23/2016 13:46 LSTARLI
Vendor Method V_PACE
10
EPA 300.0
06/20/2016 21:25
BGN9034
10
EPA 300.0
06/20/2016 21:25
BGN9034
1
EPA 245.1
06/22/2016 13:29
DMFRANC
1
EPA 245.1
06/22/2016 13:44
DMFRANC
1
EPA 200.7
06/22/2016 16:03
JJMACKE
1
EPA 200.7
06/22/2016 16:03
JJMACKE
1
EPA 200.7
06/22/2016 16:03
JJMACKE
1
EPA 200.7
06/22/2016 16:03
JJMACKE
1
EPA 200.7
06/22/2016 16:03
JJMACKE
1
EPA 200.7
06/22/2016 16:03
JJMACKE
1
EPA 200.7
06/22/2016 16:03
JJMACKE
10
EPA 200.7
06/23/2016 12:04
JJMACKE
10
EPA 200.7
06/23/2016 12:04
JJMACKE
1
EPA 200.7
06/23/2016 12:04
JJMACKE
1
EPA 200.7
06/23/2016 12:04
JJMACKE
1
EPA 200.7
06/23/2016 13:43
MHH7131
1
EPA 200.7
06/23/2016 13:43
MHH7131
1
EPA 200.7
06/23/2016 13:43
MHH7131
1
EPA 200.7
06/23/2016 13:43
MHH7131
1
EPA 200.7
06/23/2016 13:43
MHH7131
1
EPA 200.7
06/23/2016 13:43
MHH7131
1
EPA 200.7
06/23/2016 13:43
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6060542
Site: MW-26BR
Collection Date: 17-Jun-16 11:51 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
6.94
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
4.27
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.803
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
1.86
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
4.67
ug/L
1
Nickel (Ni)
1.28
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.04
ug/L B2
0.3
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
RADIOLOGICAL - (Analvsis Performed by GEL)
Vendor Parameter Complete
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS 550 mg/L 25
Duke Energy Analytical Lab
Page 5 of 71
Sample #: 2016018104
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2016 13:37
MHALL3
1
EPA 200.8
06/23/2016 13:37
MHALL3
1
EPA 200.8
06/23/2016 13:37
MHALL3
1
EPA 200.8
06/23/2016 13:37
MHALL3
1
EPA 200.8
06/23/2016 13:37
MHALL3
1
EPA 200.8
06/23/2016 13:37
MHALL3
1
EPA 200.8
06/23/2016 13:37
MHALL3
1
EPA 200.8
06/23/2016 13:37
MHALL3
1
EPA 200.8
06/23/2016 13:37
MHALL3
1
EPA 200.8
06/23/2016 13:37
MHALL3
1
EPA 200.8
06/23/2016 13:37
MHALL3
1
EPA 200.8
06/23/2016 13:37
MHALL3
1
EPA 200.8
06/23/2016 13:37
MHALL3
1
EPA 200.8
06/23/2016 15:50
MHALL3
1
EPA 200.8
06/23/2016 15:50
MHALL3
1
EPA 200.8
06/23/2016 15:50
MHALL3
1
EPA 200.8
06/23/2016 15:50
MHALL3
1
EPA 200.8
06/23/2016 15:50
MHALL3
1
EPA 200.8
06/23/2016 15:50
MHALL3
1
EPA 200.8
06/23/2016 15:50
MHALL3
1
EPA 200.8
06/23/2016 15:50
MHALL3
1
EPA 200.8
06/23/2016 15:50
MHALL3
1
EPA 200.8
06/23/2016 15:50
MHALL3
1
EPA 200.8
06/23/2016 15:50
MHALL3
1
EPA 200.8
06/23/2016 15:50
MHALL3
1
EPA 200.8
06/23/2016 15:50
MHALL3
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
1 SM2540C 06/21/201614:40 PARMSTR

Certificate of LaboratoryAnalysis Duke EnergyAnalyti6 Lab
y Page 6 of 71
This report shall not be reproduced, except in full.
Order # A 6060542
Site: MW-26BR
Sample #:
2016018104
Collection Date: 17-Jun-16
11:51 AM
Matrix:
GW WW
Analyte
Result
Units Qualifiers RDL DF Method
Analysis Date/Time Analyst
Total Carbon
TOC
1.4
mg/L 0.1 1 SM5310C/EPA9060A 06/22/201614:20 CJELLIO
TOTAL SUSPENDED SOLIDS
TSS
6.0
mg/L 5 1 SM2540D
06/22/2016 09:45 PARMSTR

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6060542
Site: MW-20BRL
Collection Date: 17-Jun-16 10:16 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.013 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
5.5
mg/L
0.1
Sulfate
7.7
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (Al)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.088
mg/L
0.01
Manganese (Mn)
0.298
mg/L
0.005
Strontium (Sr)
0.151
mg/L
0.005
Zinc (Zn)
0.008
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
41.2
mg/L
0.01
Magnesium (Mg)
5.68
mg/L
0.005
Potassium (K)
3.06
mg/L
0.1
Sodium (Na)
13.7
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.088
mg/L
0.01
Manganese (Mn)
0.289
mg/L
0.005
Strontium (Sr)
0.156
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Duke Energy Analytical Lab
Page 7 of 71
Sample #: 2016018105
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 06/23/2016 13:47 LSTARLI
Vendor Method V_PACE
1 EPA 300.0
06/21/2016 12:31
BGN9034
1 EPA 300.0
06/21/2016 12:31
BGN9034
1 EPA 245.1
06/22/2016 13:36
DMFRANC
1 EPA 245.1
06/22/2016 13:46
DMFRANC
1 EPA 200.7
06/22/2016 16:07
JJMACKE
1 EPA 200.7
06/22/2016 16:07
JJMACKE
1 EPA 200.7
06/22/2016 16:07
JJMACKE
1 EPA 200.7
06/22/2016 16:07
JJMACKE
1 EPA 200.7
06/22/2016 16:07
JJMACKE
1 EPA 200.7
06/22/2016 16:07
JJMACKE
1 EPA 200.7
06/22/2016 16:07
JJMACKE
1 EPA 200.7
06/23/2016 12:16
JJMACKE
1 EPA 200.7
06/23/2016 12:16
JJMACKE
1 EPA 200.7
06/23/2016 12:16
JJMACKE
1 EPA 200.7
06/23/2016 12:16
JJMACKE
1 EPA 200.7
06/23/2016 13:57
MHH7131
1 EPA 200.7
06/23/2016 13:57
MHH7131
1 EPA 200.7
06/23/2016 13:57
MHH7131
1 EPA 200.7
06/23/2016 13:57
MHH7131
1 EPA 200.7
06/23/2016 13:57
MHH7131
1 EPA 200.7
06/23/2016 13:57
MHH7131
1 EPA 200.7
06/23/2016 13:57
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6060542
Site: MW-20BRL
Collection Date: 17-Jun-16 10:16 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
5.06
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.31
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.39
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L B2
0.3
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
RADIOLOGICAL - (Analvsis Performed by GEL)
Vendor Parameter Complete
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS 220 mg/L 25
Duke Energy Analytical Lab
Page 8 of 71
Sample #: 2016018105
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2016 13:44
MHALL3
1
EPA 200.8
06/23/2016 13:44
MHALL3
1
EPA 200.8
06/23/2016 13:44
MHALL3
1
EPA 200.8
06/23/2016 13:44
MHALL3
1
EPA 200.8
06/23/2016 13:44
MHALL3
1
EPA 200.8
06/23/2016 13:44
MHALL3
1
EPA 200.8
06/23/2016 13:44
MHALL3
1
EPA 200.8
06/23/2016 13:44
MHALL3
1
EPA 200.8
06/23/2016 13:44
MHALL3
1
EPA 200.8
06/23/2016 13:44
MHALL3
1
EPA 200.8
06/23/2016 13:44
MHALL3
1
EPA 200.8
06/23/2016 13:44
MHALL3
1
EPA 200.8
06/23/2016 13:44
MHALL3
1
EPA 200.8
06/23/2016 15:22
MHALL3
1
EPA 200.8
06/23/2016 15:22
MHALL3
1
EPA 200.8
06/23/2016 15:22
MHALL3
1
EPA 200.8
06/23/2016 15:22
MHALL3
1
EPA 200.8
06/23/2016 15:22
MHALL3
1
EPA 200.8
06/23/2016 15:22
MHALL3
1
EPA 200.8
06/23/2016 15:22
MHALL3
1
EPA 200.8
06/23/2016 15:22
MHALL3
1
EPA 200.8
06/23/2016 15:22
MHALL3
1
EPA 200.8
06/23/2016 15:22
MHALL3
1
EPA 200.8
06/23/2016 15:22
MHALL3
1
EPA 200.8
06/23/2016 15:22
MHALL3
1
EPA 200.8
06/23/2016 15:22
MHALL3
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
1 SM2540C 06/21/201614:40 PARMSTR

Certificate of LaboratoryAnalysis Duke EnergyAnalyti9 Lab
y Page 9 of 71
This report shall not be reproduced, except in full.
Order # A 6060542
Site: MW-20BRL
Sample #:
2016018105
Collection Date: 17-Jun-16
10:16 AM
Matrix:
GW WW
Analyte
Result
Units Qualifiers RDL DF Method
Analysis Date/Time Analyst
Total Carbon
TOC
0.246
mg/L 0.1 1 SM5310C/EPA9060A 06/22/201614:20 CJELLIO
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L 5 1 SM2540D
06/22/2016 09:45 PARMSTR

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6060542
Site: MW-23BR
Collection Date: 17-Jun-16 9:00 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
34
mg/L
1
Sulfate
5.0
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (Al)
0.007
mg/L
0.005
Barium (Ba)
0.017
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.018
mg/L
0.01
Manganese (Mn)
0.309
mg/L
0.005
Strontium (Sr)
0.186
mg/L
0.005
Zinc (Zn)
0.009
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
85.9
mg/L
0.01
Magnesium (Mg)
8.38
mg/L
0.005
Potassium (K)
5.91
mg/L
0.1
Sodium (Na)
19.0
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
0.503
mg/L
0.005
Barium (Ba)
0.066
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.429
mg/L
0.01
Manganese (Mn)
0.380
mg/L
0.005
Strontium (Sr)
0.413
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Duke Energy Analytical Lab
Page 10 of 71
Sample #: 2016018106
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 06/23/2016 13:48 LSTARLI
Vendor Method V_PACE
10
EPA 300.0
06/21/2016 12:48
BGN9034
1
EPA 300.0
06/21/2016 12:48
BGN9034
1
EPA 245.1
06/22/2016 13:39
DMFRANC
1
EPA 245.1
06/22/2016 13:49
DMFRANC
1
EPA 200.7
06/22/2016 16:11
JJMACKE
1
EPA 200.7
06/22/2016 16:11
JJMACKE
1
EPA 200.7
06/22/2016 16:11
JJMACKE
1
EPA 200.7
06/22/2016 16:11
JJMACKE
1
EPA 200.7
06/22/2016 16:11
JJMACKE
1
EPA 200.7
06/22/2016 16:11
JJMACKE
1
EPA 200.7
06/22/2016 16:11
JJMACKE
1
EPA 200.7
06/23/2016 12:19
JJMACKE
1
EPA 200.7
06/23/2016 12:19
JJMACKE
1
EPA 200.7
06/23/2016 12:19
JJMACKE
1
EPA 200.7
06/23/2016 12:19
JJMACKE
1
EPA 200.7
06/23/2016 14:53
MHH7131
1
EPA 200.7
06/23/2016 14:53
MHH7131
1
EPA 200.7
06/23/2016 14:53
MHH7131
1
EPA 200.7
06/23/2016 14:53
MHH7131
1
EPA 200.7
06/23/2016 14:53
MHH7131
1
EPA 200.7
06/23/2016 14:53
MHH7131
1
EPA 200.7
06/23/2016 14:53
MHH7131

Certificate of LaboratoryAnalysis Duke Energy Page Analytical Lab
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This report shall not be reproduced, except in full.
Order # A 6060542
Site: MW-23BR
Collection Date: 17-Jun-16 9:00 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
6.16
ug/L
1
Lead (Pb)
1.02
ug/L
1
Molybdenum (Mo)
2.47
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.400
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
1.36
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
4.26
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.74
ug/L
1
Nickel (Ni)
2.70
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.865
ug/L B2
0.3
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
RADIOLOGICAL - (Analvsis Performed by GEL)
Vendor Parameter Complete
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS 290 mg/L 25
Sample #: 2016018106
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2016 13:09
MHALL3
1
EPA 200.8
06/23/2016 13:09
MHALL3
1
EPA 200.8
06/23/2016 13:09
MHALL3
1
EPA 200.8
06/23/2016 13:09
MHALL3
1
EPA 200.8
06/23/2016 13:09
MHALL3
1
EPA 200.8
06/23/2016 13:09
MHALL3
1
EPA 200.8
06/23/2016 13:09
MHALL3
1
EPA 200.8
06/23/2016 13:09
MHALL3
1
EPA 200.8
06/23/2016 13:09
MHALL3
1
EPA 200.8
06/23/2016 13:09
MHALL3
1
EPA 200.8
06/23/2016 13:09
MHALL3
1
EPA 200.8
06/23/2016 13:09
MHALL3
1
EPA 200.8
06/23/2016 13:09
MHALL3
1
EPA 200.8
06/23/2016 15:57
MHALL3
1
EPA 200.8
06/23/2016 15:57
MHALL3
1
EPA 200.8
06/23/2016 15:57
MHALL3
1
EPA 200.8
06/23/2016 15:57
MHALL3
1
EPA 200.8
06/23/2016 15:57
MHALL3
1
EPA 200.8
06/23/2016 15:57
MHALL3
1
EPA 200.8
06/23/2016 15:57
MHALL3
1
EPA 200.8
06/23/2016 15:57
MHALL3
1
EPA 200.8
06/23/2016 15:57
MHALL3
1
EPA 200.8
06/23/2016 15:57
MHALL3
1
EPA 200.8
06/23/2016 15:57
MHALL3
1
EPA 200.8
06/23/2016 15:57
MHALL3
1
EPA 200.8
06/23/2016 15:57
MHALL3
Vendor Method V_PACE
Vendor Method v_GEL
Vendor Method V_PACE
1 SM2540C 06/21/201614:40 PARMSTR

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical2Lab
y Page 12 of 71
This report shall not be reproduced, except in full.
Order # A 6060542
Site: MW-23BR Sample #: 2016018106
Collection Date: 17-Jun-16 9:00 AM Matrix: GW WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
Total Carbon
TOC 1.2 mg/L 0.1 1 SM5310C/EPA9060A 06/22/201614:20 CJELLIO
TOTAL SUSPENDED SOLIDS
TSS 97 mg/L 5 1 SM2540D 06/22/2016 09:45 PARMSTR

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6060542
Site: Filter Blank
Collection Date: 17-Jun-16 11:40 AM
Analyte
Result
Units Qualifiers
RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (Al)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
4.09
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Duke Energy Analytical Lab
Page 13 of 71
Sample #: 2016018107
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
06/22/2016 13:51
DMFRANC
1
EPA 200.7
06/25/2016 08:58
JJMACKE
1
EPA 200.7
06/25/2016 08:58
JJMACKE
1
EPA 200.7
06/25/2016 08:58
JJMACKE
1
EPA 200.7
06/25/2016 08:58
JJMACKE
1
EPA 200.7
06/25/2016 08:58
JJMACKE
1
EPA 200.7
06/25/2016 08:58
JJMACKE
1
EPA 200.7
06/25/2016 08:58
JJMACKE
1
EPA 200.8
06/23/2016 13:51
MHALL3
1
EPA 200.8
06/23/2016 13:51
MHALL3
1
EPA 200.8
06/23/2016 13:51
MHALL3
1
EPA 200.8
06/23/2016 13:51
MHALL3
1
EPA 200.8
06/23/2016 13:51
MHALL3
1
EPA 200.8
06/23/2016 13:51
MHALL3
1
EPA 200.8
06/23/2016 13:51
MHALL3
1
EPA 200.8
06/23/2016 13:51
MHALL3
1
EPA 200.8
06/23/2016 13:51
MHALL3
1
EPA 200.8
06/23/2016 13:51
MHALL3
1
EPA 200.8
06/23/2016 13:51
MHALL3
1
EPA 200.8
06/23/2016 13:51
MHALL3
1
EPA 200.8
06/23/2016 13:51
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6060542
Site: Equipment Blank
Collection Date: 17-Jun-16 11:40 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
Calcium (Ca)
< 0.01
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
B2 0.3
Duke Energy Analytical Lab
Page 14 of 71
Sample #: 2016018108
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2
06/23/2016 13:50
LSTARLI
1 EPA 300.0
06/20/2016 22:22
BGN9034
1 EPA 300.0
06/20/2016 22:22
BGN9034
1 EPA 245.1
06/22/2016 13:41
DMFRANC
1 EPA 200.7
06/23/2016 12:23
JJMACKE
1 EPA 200.7
06/23/2016 12:23
JJMACKE
1 EPA 200.7
06/23/2016 12:23
JJMACKE
1 EPA 200.7
06/23/2016 12:23
JJMACKE
1 EPA 200.7
06/23/2016 14:05
MHH7131
1 EPA 200.7
06/23/2016 14:05
MHH7131
1 EPA 200.7
06/23/2016 14:05
MHH7131
1 EPA 200.7
06/23/2016 14:05
MHH7131
1 EPA 200.7
06/23/2016 14:05
MHH7131
1 EPA 200.7
06/23/2016 14:05
MHH7131
1 EPA 200.7
06/23/2016 14:05
MHH7131
1 EPA 200.8
06/23/2016 16:11
MHALL3
1 EPA 200.8
06/23/2016 16:11
MHALL3
1 EPA 200.8
06/23/2016 16:11
MHALL3
1 EPA 200.8
06/23/2016 16:11
MHALL3
1 EPA 200.8
06/23/2016 16:11
MHALL3
1 EPA 200.8
06/23/2016 16:11
MHALL3
1 EPA 200.8
06/23/2016 16:11
MHALL3
1 EPA 200.8
06/23/2016 16:11
MHALL3
1 EPA 200.8
06/23/2016 16:11
MHALL3
1 EPA 200.8
06/23/2016 16:11
MHALL3
1 EPA 200.8
06/23/2016 16:11
MHALL3
1 EPA 200.8
06/23/2016 16:11
MHALL3
1 EPA 200.8
06/23/2016 16:11
MHALL3

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical5Lab
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This report shall not be reproduced, except in full.
Order # A 6060542
Site: Equipment Blank
Sample #: 2016018108
Collection Date: 17-Jun-16 11:40
AM
Matrix: GW WW
Analyte
Result Units Qualifiers RDL
DF Method Analysis Date/Time
Analyst
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
Total Carbon
TOC
0.240 mg/L 0.1
1 SM5310C/EPA9060A 06/22/201614:20
CJELLIO
TOTAL SUSPENDED SOLIDS
TSS
< 5 mg/L 5
1 SM2540D 06/22/2016 09:45
PARMSTR
Qualifiers:
B2 Target analyte was detected in blank(s) at a concentration greater than 1/2 the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical6Lab
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This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060647 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Nitrite + Nitrate
0.0012
0.0012
mg-N/L
1
0.01
< 1/2 RDL
(Colorimetric)
Blank # 2
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Nitrite + Nitrate
0.0021
0.0021
mg-N/L
1
0.01
< 1/2 RDL
(Colorimetric)
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Nitrite + Nitrate
0.296
1.48
mg-N/L
5
1.25
96.1
(Colorimetric)
ISD # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD
Qualifier
Nitrite + Nitrate
0.286
1.43
mg-N/L
5
1.25
92
4.38
(Colorimetric)
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Nitrite + Nitrate
0.302
3.02
mg-N/L
10
3.01
100
90
110
(Colorimetric)
LCS # 2
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Nitrite + Nitrate
0.303
3.03
mg-N/L
10
3.01
101
90
110
(Colorimetric)
MS # 1
Parent Sample:
J16060538
-- 2016018092
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Nitrite + Nitrate
0.248
0.248
mg-N/L
1
0.25
96.8
90
110
(Colorimetric)
MSD # 1
Parent Sample:
J16060538
-- 2016018092
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD
Qualifier
Nitrite + Nitrate
0.249
0.249
mg-N/L
1
0.25
97.4
90
110
0.577
(Colorimetric)

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical7Lab
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This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060519 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter Measured Final
Chloride 0.0201 0.0201
Sulfate-0.0025-0.0025
ISD # 1
IS # 2
ISD # 2
LCS # 1
Parameter
Measured
Final
Chloride
8.22
8.22
Sulfate
5.65
5.65
Parameter
Measured
Final
Chloride
8.23
8.23
Sulfate
5.68
5.68
Parameter
Measured
Final
Chloride
7.46
7.46
Sulfate
9.58
9.58
Parameter
Measured
Final
Chloride
7.47
7.47
Sulfate
9.58
9.58
Parameter
Measured
Final
Chloride
4.82
4.82
Sulfate
4.85
4.85
Units:
Dil
RDL
Relative Concentration
Qualifier
mg/L
1
0.1
< 1/2 RDL
mg/L
1
0.1
< 1/2 RDL
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
5
102
80
120
mg/L
1
5
99.1
80
120
Units:
Dil
Sgike
% Recovery
LCL
UCL
RPD
Qualifier
mg/L
1
5
102
80
120
0.265
mg/L
1
5
99.7
80
120
0.586
Units:
Dil
Sgike
% Recovery
LCL
UCL
Qualifier
mg/L
1
5
103
80
120
mg/L
1
5
97
80
120
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD
Qualifier
mg/L
1
5
103
80
120
0.0934
mg/L
1
5
97
80
120
0.0453
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
mg/L
1
5
96.5
90
110
mg/L
1
5
97
90
110

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical8Lab
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This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060613 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Mercury (Hg)
0.013
0.013
Blank # 2
Parameter
Measured
Final
Mercury (Hg)
0.008
0.008
Parameter Measured Final
Mercury (Hg) 0.909 18.2
ISD # 1
Parameter
Measured
Final
Mercury (Hg)
0.889
17.8
LCS # 1
Parameter
Measured
Final
Mercury (Hg)
2.03
2.03
LCS # 2
Parameter Measured Final
Mercury (Hg) 1.91 1.91
MS # 1
Parameter
Measured
Final
Mercury (Hg)
0.944
0.944
MSD # 1
Parameter
Measured
Final
Mercury (Hg)
0.942
0.942
Units:
Dil
RDL
Relative Concentration
Qualifier
ug/L
1
0.05
< 1/2 RDL
Units:
Dil
RDL
Relative Concentration
Qualifier
ug/L
1
0.05
< 1/2 RDL
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
ug/L
20
20
86.1 70
130
Units:
Dil
Spike
% Recovery LCL
UCL
RPD
Qualifier
ug/L
20
20
84.1 70
130
2.35
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
ug/L
1
2
102 85
115
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
ug/L
1
2
95.3 85
115
Parent Sample:
J16060542
-- 2016018104
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
ug/L
1
1
93.2 70
130
Parent Sample:
J16060542
-- 2016018104
Units:
Dil
Spike
% Recovery LCL
UCL
RPD
Qualifier
ug/L
1
1
93 70
130
0.215

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical9Lab
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This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060614 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Blank # 1
Parameter Measured Final
Mercury (Hg) 0.013 0.013
ISD # 1
IS # 2
ISD # 2
LCS # 1
Parameter Measured Final
Mercury (Hg) 0.909 18.2
Parameter Measured Final
Mercury (Hg) 0.889 17.8
Parameter Measured Final
Mercury (Hg) 0.944 0.944
Parameter Measured Final
Mercury (Hg) 0.942 0.942
Parameter Measured Final
Mercury (Hg) 2.03 2.03
Units:
Dil
RDL
Relative Concentration
Qualifier
ug/L
1
0.05
< 1/2 RDL
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
ug/L
20
20
86.1
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD
Qualifier
ug/L
20
20
84.1
2.35
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
ug/L
1
1
93.2
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD
Qualifier
ug/L
1
1
93
0.215
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
ug/L
1
2
102

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This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060619 ICP Dissolved DISSOLVED METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Aluminum (Al)
0.000411
0.000411
mg/L
1
0.005
< 1/2 RDL
Barium (Ba)
0.000013
0.000013
mg/L
1
0.005
< 1/2 RDL
Boron (B)
-0.00265
-0.00265
mg/L
1
0.05
< 1/2 RDL
Iron (Fe)
-0.000613
-0.000613
mg/L
1
0.01
< 1/2 RDL
Manganese (Mn)
-0.000081
-0.000081
mg/L
1
0.005
< 1/2 RDL
Strontium (Sr)
0.000025
0.000025
mg/L
1
0.005
< 1/2 RDL
Zinc (Zn)
0.000069
0.000069
mg/L
1
0.005
< 1/2 RDL
Blank # 2
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Aluminum (Al)
0.000271
0.000271
mg/L
1
0.005
< 1/2 RDL
Barium (Ba)
0.000043
0,000043
mg/L
1
0.005
< 1/2 RDL
Boron (B)
-0.00246
-0.00246
mg/L
1
0.05
< 1/2 RDL
Iron (Fe)
0.000603
0.000603
mg/L
1
0.01
< 1/2 RDL
Manganese (Mn)
-0.000156
-0.000156
mg/L
1
0.005
< 1/2 RDL
Strontium (Sr)
0.000021
0.000021
mg/L
1
0.005
< 1/2 RDL
Zinc (Zn)
-0.000184
-0.000184
mg/L
1
0.005
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Aluminum (Al)
2.05
2.05
mg/L
1
2
103
85
115
Barium (Ba)
0.974
0.974
mg/L
1
1
97.4
85
115
Boron (B)
1.94
1.94
mg/L
1
2
97.2
85
115
Iron (Fe)
2
2
mg/L
1
2
100
85
115
Manganese (Mn)
0.965
0.965
mg/L
1
1
96.5
85
115
Strontium (Sr)
1.89
1.89
mg/L
1
2
94.5
85
115
Zinc (Zn)
1.01
1.01
mg/L
1
1
101
85
115
LCS # 2
Parameter
Measured
Final
Units:
Aluminum (Al)
2.04
2.04
mg/L
Barium (Ba)
0.968
0.968
mg/L
Boron (B)
1.94
1.94
mg/L
Iron (Fe)
2.02
2.02
mg/L
Manganese (Mn)
0.97
0.97
mg/L
Strontium (Sr)
1.89
1.89
mg/L
Zinc (Zn)
1.02
1.02
mg/L
MS # 1
Parameter Measured Final Units:
Aluminum (Al) 5.21 5.21 mg/L
Dil
Spike
% Recovery LCL
UCL Qualifier
1
2
102 85
115
1
1
96.8 85
115
1
2
97.1 85
115
1
2
101 85
115
1
1
97 85
115
1
2
94.5 85
115
1
1
102 85
115
Parent Sample:
J16060426 -- 2016017418
Dil
Spike
% Recovery LCL
UCL Qualifier
1
5
104 70
130

Certificate of LaboratoryAnalysis Duke Energy Page Analytical Lab
y Page 21 of 71
This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060619 ICP Dissolved DISSOLVED METALS BY ICP
MS # 1
Parent Sample:
J16060426
-- 2016017418
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Barium (Ba)
5.05
5.05
mg/L
1
5
99.9 70
130
Boron (B)
5.02
5.02
mg/L
1
5
98.9 70
130
Iron (Fe)
14.7
14.7
mg/L
1
5
96.6 70
130
Manganese (Mn)
5.08
5.08
mg/L
1
5
101 70
130
Strontium (Sr)
5.19
5.19
mg/L
1
5
97.3 70
130
Zinc (Zn)
5
5
mg/L
1
5
99.9 70
130
MSD # 1
Parent Sample:
J16060426
-- 2016017418
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
RPD Qualifier
Aluminum (Al)
5.19
5.19
mg/L
1
5
103 70
130
0.367
Barium (Ba)
5.02
5.02
mg/L
1
5
99.4 70
130
0.522
Boron (B)
5.01
5.01
mg/L
1
5
98.7 70
130
0.202
Iron (Fe)
14.6
14.6
mg/L
1
5
95.2 70
130
1.46
Manganese (Mn)
5.06
5.06
mg/L
1
5
100 70
130
0.417
Strontium (Sr)
5.16
5.16
mg/L
1
5
96.6 70
130
0.702
Zinc (Zn)
4.96
4.96
mg/L
1
5
99 70
130
0.885
MS # 2
Parent Sample:
J16060523
-- 2016017982
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Aluminum (Al)
5.09
5.09
mg/L
1
5
101 70
130
Barium (Ba)
4.92
4.92
mg/L
1
5
98.1 70
130
Boron (B)
5.85
5.85
mg/L
1
5
95.1 70
130
Iron (Fe)
4.75
4.75
mg/L
1
5
95 70
130
Manganese (Mn)
4.97
4.97
mg/L
1
5
99.1 70
130
Strontium (Sr)
4.86
4.86
mg/L
1
5
94.7 70
130
Zinc (Zn)
4.93
4.93
mg/L
1
5
98.4 70
130
MSD # 2
Parent Sample:
J16060523
-- 2016017982
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
RPD Qualifier
Aluminum (Al)
5.13
5.13
mg/L
1
5
102 70
130
0.611
Barium (Ba)
4.94
4.94
mg/L
1
5
98.5 70
130
0.488
Boron (B)
5.89
5.89
mg/L
1
5
95.9 70
130
0.796
Iron (Fe)
4.77
4.77
mg/L
1
5
95.4 70
130
0.42
Manganese (Mn)
5
5
mg/L
1
5
99.7 70
130
0.563
Strontium (Sr)
4.92
4.92
mg/L
1
5
96 70
130
1.38
Zinc (Zn)
4.95
4.95
mg/L
1
5
98.9 70
130
0.507
MS # 3
Parent Sample:
J16060510
-- 2016017893
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Aluminum (Al)
5.14
5.14
mg/L
1
5
103 70
130
Barium (Ba)
5.04
5.04
mg/L
1
5
99.3 70
130

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060619 ICP Dissolved DISSOLVED METALS BY ICP
MS # 3
Parameter
Measured
Final
Units:
Dil
Spike
Boron (B)
4.96
4.96
mg/L
1
5
Iron (Fe)
7.78
7.78
mg/L
1
5
Manganese (Mn)
5.89
5.89
mg/L
1
5
Strontium (Sr)
5.05
5.05
mg/L
1
5
Zinc (Zn)
4.97
4.97
mg/L
1
5
MSD # 3
Parameter
Measured
Final
Units:
Dil
Spike
Aluminum (Al)
5.17
5.17
mg/L
1
5
Barium (Ba)
5.08
5.08
mg/L
1
5
Boron (B)
5
5
mg/L
1
5
Iron (Fe)
7.82
7.82
mg/L
1
5
Manganese (Mn)
5.93
5.93
mg/L
1
5
Strontium (Sr)
5.07
5.07
mg/L
1
5
Zinc (Zn)
5
5
mg/L
1
5
Duke Energy Analytical Lab
Page 22 of 71
Parent Sample: J16060510 -- 2016017893
% Recovery
LCL
UCL
Qualifier
99
70
130
95.1
70
130
96.8
70
130
97.4
70
130
99.3
70
130
Parent Sample:
J16060510
-- 2016017893
% Recovery
LCL
UCL
RPD Qualifier
103
70
130
0.602
100
70
130
0.802
99.7
70
130
0.765
96
70
130
0.921
97.6
70
130
0.823
97.9
70
130
0.492
99.9
70
130
0.622

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical3Lab
y Page 23 of 71
This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060728 ICP Dissolved DISSOLVED METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Aluminum (Al)
0.000095
0.000095
mg/L
1
0.005
< 1/2 RDL
Barium (Ba)
0.000014
0.000014
mg/L
1
0.005
< 1/2 RDL
Boron (B)
-0.00121
-0.00121
mg/L
1
0.05
< 1/2 RDL
Iron (Fe)
-0.000132
-0.000132
mg/L
1
0.01
< 1/2 RDL
Manganese (Mn)
-0.000199
-0.000199
mg/L
1
0.005
< 1/2 RDL
Strontium (Sr)
0.000023
0.000023
mg/L
1
0.005
< 1/2 RDL
Zinc (Zn)
-0.00127
-0.00127
mg/L
1
0.005
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Aluminum (Al)
2.08
2.08
mg/L
Barium (Ba)
0.966
0.966
mg/L
Boron (B)
1.93
1.93
mg/L
Iron (Fe)
1.99
1.99
mg/L
Manganese (Mn)
0.958
0.958
mg/L
Strontium (Sr)
1.86
1.86
mg/L
Zinc (Zn)
1
1
mg/L
MS # 1
Parameter
Measured
Final
Units:
Aluminum (Al)
5.43
5.43
mg/L
Barium (Ba)
5.07
5.07
mg/L
Boron (B)
5.14
5.14
mg/L
Iron (Fe)
5.06
5.06
mg/L
Manganese (Mn)
5.17
5.17
mg/L
Strontium (Sr)
5.52
5.52
mg/L
Zinc (Zn)
5
5
mg/L
MSD # 1
Parameter
Measured
Final
Units:
Aluminum (Al)
5.43
5.43
mg/L
Barium (Ba)
5.09
5.09
mg/L
Boron (B)
5.16
5.16
mg/L
Iron (Fe)
5.07
5.07
mg/L
Manganese (Mn)
5.18
5.18
mg/L
Strontium (Sr)
5.51
5.51
mg/L
Zinc (Zn)
5.01
5.01
mg/L
MS # 2
Parameter
Measured
Final
Units:
Aluminum (Al)
5.38
5.38
mg/L
Dil
Spike
% Recovery LCL
UCL
Qualifier
1
2
104 85
115
1
1
96.6 85
115
1
2
96.4 85
115
1
2
99.3 85
115
1
1
95.8 85
115
1
2
92.8 85
115
1
1
100 85
115
Parent Sample:
J16060665
-- 2016018444
DiI
Spike
% Recovery LCL
UCL
Qualifier
1
5
108 70
130
1
5
101 70
130
1
5
98.3 70
130
1
5
96.2 70
130
1
5
102 70
130
1
5
96.2 70
130
1
5
100 70
130
Parent Sample:
J16060665
-- 2016018444
DiI
Spike
% Recovery LCL
UCL
RPD Qualifier
1
5
108 70
130
0.0554
1
5
101 70
130
0.395
1
5
98.7 70
130
0.386
1
5
96.4 70
130
0.166
1
5
103 70
130
0.215
1
5
95.9 70
130
0.25
1
5
100 70
130
0.16
Parent Sample:
J16060724
-- 2016018727
Dil
Spike
% Recovery LCL
UCL
Qualifier
1
5
107 70
130

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical4Lab
y Page 24 of 71
This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060728 ICP Dissolved DISSOLVED METALS BY ICP
MS # 2
Parameter
Measured
Final
Units:
Dil
Spike
Barium (Ba)
4.84
4.84
mg/L
1
5
Boron (B)
5.07
5.07
mg/L
1
5
Iron (Fe)
5.16
5.16
mg/L
1
5
Manganese (Mn)
5.32
5.32
mg/L
1
5
Strontium (Sr)
5.53
5.53
mg/L
1
5
Zinc (Zn)
4.93
4.93
mg/L
1
5
MSD # 2
Parameter
Measured
Final
Units:
Dil
Spike
Aluminum (Al)
5.34
5.34
mg/L
1
5
Barium (Ba)
4.83
4.83
mg/L
1
5
Boron (B)
5.08
5.08
mg/L
1
5
Iron (Fe)
5.16
5.16
mg/L
1
5
Manganese (Mn)
5.29
5.29
mg/L
1
5
Strontium (Sr)
5.52
5.52
mg/L
1
5
Zinc (Zn)
4.9
4.9
mg/L
1
5
Parent Sample: J16060724 -- 2016018727
% Recovery
LCL
UCL
Qualifier
96.2
70
130
98.7
70
130
95.6
70
130
101
70
130
95.7
70
130
98.5
70
130
Parent Sample:
J16060724
-- 2016018727
% Recovery
LCL
UCL
RPD Qualifier
107
70
130
0.655
95.9
70
130
0.396
99
70
130
0.243
95.6
70
130
0.0418
101
70
130
0.436
95.6
70
130
0.0418
97.9
70
130
0.611

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical5Lab
y Page 25 of 71
This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060669 ICP Undigested UNDIGESTED METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Calcium (Ca)
0.00325
0.00325
mg/L
1
0.01
< 1/2 RDL
Magnesium (Mg)
0.000559
0.000559
mg/L
1
0.005
< 1/2 RDL
Potassium (K)
0.00439
0.00439
mg/L
1
0.1
< 1/2 RDL
Sodium (Na)
-0.0129
-0.0129
mg/L
1
0.05
< 1/2 RDL
Blank # 2
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Calcium (Ca)
0.00126
0.00126
mg/L
1
0.01
< 1/2 RDL
Magnesium (Mg)
0.000032
0.000032
mg/L
1
0.005
< 1/2 RDL
Potassium (K)
0.00158
0.00158
mg/L
1
0.1
< 1/2 RDL
Sodium (Na)
-0.0114
-0.0114
mg/L
1
0.05
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Calcium (Ca)
1.97
1.97
mg/L
1
2
98.7
85
115
Magnesium (Mg)
1.96
1.96
mg/L
1
2
97.8
85
115
Potassium (K)
3.88
3.88
mg/L
1
4
96.9
85
115
Sodium (Na)
8.05
8.05
mg/L
1
8.1
99.4
85
115
LCS # 2
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Calcium (Ca)
2
2
mg/L
1
2
100
85
115
Magnesium (Mg)
1.98
1.98
mg/L
1
2
99
85
115
Potassium (K)
3.91
3.91
mg/L
1
4
97.8
85
115
Sodium (Na)
8.1
8.1
mg/L
1
8.1
99.9
85
115
MS # 1
Parent Sample:
J16060542
-- 2016018104
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Calcium (Ca)
10.8
108
mg/L
10
5
123
70
130
Magnesium (Mg)
4.94
49.4
mg/L
10
5
114
70
130
Potassium (K)
12.8
12.8
mg/L
1
5
94.9
70
130
Sodium (Na)
30.9
30.9
mg/L
1
5
108
70
130
MSD # 1
Parent Sample:
J16060542
-- 2016018104
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD Qualifier
Calcium (Ca)
10.8
108
mg/L
10
5
122
70
130
0.245
Magnesium (Mg)
4.94
49.4
mg/L
10
5
114
70
130
0.281
Potassium (K)
12.8
12.8
mg/L
1
5
96.6
70
130
1.75
Sodium (Na)
30.8
30.8
mg/L
1
5
105
70
130
2.68

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical6Lab
y Page 26 of 71
This report shall not be reproduced, except in full.
Order # A 6060542
Level I1 QC Summary
Q16060669 ICP Undigested UNDIGESTED METALS BY ICP
MS # 2
Parent Sample:
J16060538
-- 2016018088
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Calcium (Ca)
13.5
13.5
mg/L
1
5
103 70
130
Magnesium (Mg)
6.6
6.6
mg/L
1
5
106 70
130
Potassium (K)
8.14
8.14
mg/L
1
5
101 70
130
Sodium (Na)
10.7
10.7
mg/L
1
5
93.5 70
130
MSD # 2
Parent Sample:
J16060538
-- 2016018088
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
RPD Qualifier
Calcium (Ca)
13.6
13.6
mg/L
1
5
104 70
130
0.579
Magnesium (Mg)
6.6
6.6
mg/L
1
5
106 70
130
0.0756
Potassium (K)
8.13
8.13
mg/L
1
5
101 70
130
0.218
Sodium (Na)
10.7
10.7
mg/L
1
5
94.4 70
130
1.04
MS # 3
Parent Sample:
J16060523
-- 2016017981
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Calcium (Ca)
22.1
22.1
mg/L
1
5
103 70
130
Magnesium (Mg)
17.4
17.4
mg/L
1
5
90 70
130
Potassium (K)
2.49
24.9
mg/L
10
5
113 70
130
Sodium (Na)
60.2
602
mg/L
10
5
363 70
130
MSD # 3
Parent Sample:
J16060523
-- 2016017981
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
RPD Qualifier
Calcium (Ca)
22
22
mg/L
1
5
101 70
130
1.24
Magnesium (Mg)
17.5
17.5
mg/L
1
5
92.1 70
130
2.26
Potassium (K)
2.47
24.7
mg/L
10
5
109 70
130
3.59
Sodium (Na)
59.8
598
mg/L
10
5
274 70
130
28

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical7Lab
y Page 27 of 71
This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060587 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Aluminum (Al)
0.000704
0.000704
mg/L
1
0.005
< 1/2 RDL
Barium (Ba)
-0.000137
-0.000137
mg/L
1
0.005
< 1/2 RDL
Boron (B)
0.000125
0.000125
mg/L
1
0.05
< 1/2 RDL
Iron (Fe)
-0.000391
-0.000391
mg/L
1
0.01
< 1/2 RDL
Manganese (Mn)
-0.00027
-0.00027
mg/L
1
0.005
< 1/2 RDL
Strontium (Sr)
-0.000066
-0.000066
mg/L
1
0.005
< 1/2 RDL
Zinc (Zn)
-0.000499
-0.000499
mg/L
1
0.005
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Aluminum (Al)
4.79
4.79
mg/L
1
5
95.9
85
115
Barium (Ba)
4.84
4.84
mg/L
1
5
96.9
85
115
Boron (B)
4.96
4.96
mg/L
1
5
99.2
85
115
Iron (Fe)
4.99
4.99
mg/L
1
5
99.8
85
115
Manganese (Mn)
4.95
4.95
mg/L
1
5
99
85
115
Strontium (Sr)
4.72
4.72
mg/L
1
5
94.4
85
115
Zinc (Zn)
4.99
4.99
mg/L
1
5
99.9
85
115
MS # 1
Parent Sample:
J16060542
-- 2016018104
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Aluminum (Al)
4.79
4.79
mg/L
1
5
93.1
70
130
Barium (Ba)
4.86
4.86
mg/L
1
5
95.9
70
130
Boron (B)
5.02
5.02
mg/L
1
5
100
70
130
Iron (Fe)
5.32
5.32
mg/L
1
5
97.9
70
130
Manganese (Mn)
5.38
5.38
mg/L
1
5
95.7
70
130
Strontium (Sr)
4.98
4.98
mg/L
1
5
94
70
130
Zinc (Zn)
4.79
4.79
mg/L
1
5
95.7
70
130
MSD # 1
Parent Sample:
J16060542
-- 2016018104
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD Qualifier
Aluminum (Al)
4.88
4.88
mg/L
1
5
95
70
130
2.02
Barium (Ba)
4.96
4.96
mg/L
1
5
97.9
70
130
2.09
Boron (B)
5.09
5.09
mg/L
1
5
102
70
130
1.41
Iron (Fe)
5.34
5.34
mg/L
1
5
98.4
70
130
0.489
Manganese (Mn)
5.48
5.48
mg/L
1
5
97.8
70
130
2.19
Strontium (Sr)
5.08
5.08
mg/L
1
5
96
70
130
2.11
Zinc (Zn)
4.83
4.83
mg/L
1
5
96.5
70
130
0.833

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical8Lab
y Page 28 of 71
This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060589 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Antimony (Sb)
0.0036
0.0036
ug/L
1
1
< 1/2 RDL
Arsenic (As)
-0.028
-0.028
ug/L
1
1
< 1/2 RDL
Beryllium (Be)
-0.0523
-0.0523
ug/L
1
1
< 1/2 RDL
Cadmium (Cd)
-0.0019
-0.0019
ug/L
1
1
< 1/2 RDL
Chromium (Cr)
0.0329
0.0329
ug/L
1
1
< 1/2 RDL
Cobalt (Co)
0.003
0.003
ug/L
1
1
< 1/2 RDL
Copper (Cu)
-0.0008
-0.0008
ug/L
1
1
< 1/2 RDL
Lead (Pb)
-0.0015
-0.0015
ug/L
1
1
< 1/2 RDL
Molybdenum (Mo)
0.0259
0.0259
ug/L
1
1
< 1/2 RDL
Nickel (Ni)
-0.0745
-0.0745
ug/L
1
1
< 1/2 RDL
Selenium (Se)
0.0434
0.0434
ug/L
1
1
< 1/2 RDL
Thallium (TI) Low Level
0.0089
0.0089
ug/L
1
0.2
< 1/2 RDL
Vanadium (V) Low Level
0.0715
0.0715
ug/L
1
0.3
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
48.7
48.7
ug/L
1
50
97.4
85
115
Arsenic (As)
48.8
48.8
ug/L
1
50
97.6
85
115
Beryllium (Be)
46.7
46.7
ug/L
1
50
93.3
85
115
Cadmium (Cd)
48.5
48.5
ug/L
1
50
97
85
115
Chromium (Cr)
48.8
48.8
ug/L
1
50
97.6
85
115
Cobalt (Co)
48.7
48.7
ug/L
1
50
97.4
85
115
Copper (Cu)
48.2
48.2
ug/L
1
50
96.4
85
115
Lead (Pb)
49.3
49.3
ug/L
1
50
98.7
85
115
Molybdenum (Mo)
47.5
47.5
ug/L
1
50
95.1
85
115
Nickel (Ni)
48.4
48.4
ug/L
1
50
96.7
85
115
Selenium (Se)
49
49
ug/L
1
50
98
85
115
Thallium (TI) Low Level
49.2
49.2
ug/L
1
50
98.4
85
115
MS # 1
Parent Sample:
J16060542 -- 2016018106
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
49.8
49.8
ug/L
1
50
98.8
70
130
Arsenic (As)
49.8
49.8
ug/L
1
50
98.9
70
130
Beryllium (Be)
49.2
49.2
ug/L
1
50
98.6
70
130
Cadmium (Cd)
48.3
48.3
ug/L
1
50
96.6
70
130
Chromium (Cr)
48.4
48.4
ug/L
1
50
96.5
70
130
Cobalt (Co)
48.6
48.6
ug/L
1
50
97.1
70
130
Copper (Cu)
53.9
53.9
ug/L
1
50
95.5
70
130
Lead (Pb)
50.9
50.9
ug/L
1
50
99.8
70
130
Molybdenum (Mo)
52.5
52.5
ug/L
1
50
100
70
130

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical9Lab
y Page 29 of 71
This report shall not be reproduced, except in full.
Order # A 6060542
Level I1 QC Summary
Q16060589 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
MS # 1
Parent Sample:
J16060542
-- 2016018106
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Nickel (Ni)
47.6
47.6
ug/L
1
50
93.9
70
130
Selenium (Se)
52.6
52.6
ug/L
1
50
105
70
130
Thallium (TI) Low Level
47
47
ug/L
1
50
94
70
130
MSD # 1
Parent Sample:
J16060542
-- 2016018106
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD Qualifier
Antimony (Sb)
49.4
49.4
ug/L
1
50
98.2
70
130
0.65
Arsenic (As)
49.3
49.3
ug/L
1
50
97.8
70
130
1.18
Beryllium (Be)
49.1
49.1
ug/L
1
50
98.4
70
130
0.162
Cadmium (Cd)
47.9
47.9
ug/L
1
50
95.7
70
130
0.936
Chromium (Cr)
47.7
47.7
ug/L
1
50
95.2
70
130
1.38
Cobalt (Co)
46.1
46.1
ug/L
1
50
92.1
70
130
5.27
Copper (Cu)
53.7
53.7
ug/L
1
50
95
70
130
0.525
Lead (Pb)
49.4
49.4
ug/L
1
50
96.7
70
130
3.22
Molybdenum (Mo)
50.6
50.6
ug/L
1
50
96.2
70
130
3.89
Nickel (Ni)
47.2
47.2
ug/L
1
50
93.1
70
130
0.855
Selenium (Se)
47.1
47.1
ug/L
1
50
94.1
70
130
11.1
Thallium (TI) Low Level
46.6
46.6
ug/L
1
50
93.2
70
130
0.876

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical0Lab
y Page 30 of 71
This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060590 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration Qualifier
Antimony (Sb)
-0.0019
-0.0019
ug/L
1
1
< 1/2 RDL
Arsenic (As)
-0.0402
-0.0402
ug/L
1
1
< 1/2 RDL
Beryllium (Be)
-0.0767
-0.0767
ug/L
1
1
< 1/2 RDL
Cadmium (Cd)
-0.0019
-0.0019
ug/L
1
1
< 1/2 RDL
Chromium (Cr)
0.0043
0.0043
ug/L
1
1
< 1/2 RDL
Cobalt (Co)
0.006
0.006
ug/L
1
1
< 1/2 RDL
Copper (Cu)
-0.0393
-0.0393
ug/L
1
1
< 1/2 RDL
Lead (Pb)
-0.0079
-0.0079
ug/L
1
1
< 1/2 RDL
Molybdenum (Mo)
0.01
0.01
ug/L
1
1
< 1/2 RDL
Nickel (Ni)
-0.0516
-0.0516
ug/L
1
1
< 1/2 RDL
Selenium (Se)
0.0068
0.0068
ug/L
1
1
< 1/2 RDL
Thallium (TI) Low Level
-0.0065
-0.0065
ug/L
1
0.2
< 1/2 RDL
Vanadium (V) Low Level
0.157
0.157
ug/L
1
0.3
> 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
48.6
48.6
ug/L
1
50
97.2
85
115
Arsenic (As)
49.6
49.6
ug/L
1
50
99.1
85
115
Beryllium (Be)
49.3
49.3
ug/L
1
50
98.7
85
115
Cadmium (Cd)
50
50
ug/L
1
50
99.9
85
115
Chromium (Cr)
49.2
49.2
ug/L
1
50
98.4
85
115
Cobalt (Co)
49.3
49.3
ug/L
1
50
98.6
85
115
Copper (Cu)
49.2
49.2
ug/L
1
50
98.4
85
115
Lead (Pb)
49.3
49.3
ug/L
1
50
98.5
85
115
Molybdenum (Mo)
48.9
48.9
ug/L
1
50
97.7
85
115
Nickel (Ni)
47.9
47.9
ug/L
1
50
95.9
85
115
Selenium (Se)
49.2
49.2
ug/L
1
50
98.3
85
115
Thallium (TI) Low Level
49
49
ug/L
1
50
98
85
115
Vanadium (V) Low Level
49
49
ug/L
1
50
98
85
115
MS #1
Parent Sample:
J16060542 -- 2016018105
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
50
50
ug/L
1
50
100
70
130
Arsenic (As)
49.9
49.9
ug/L
1
50
99.4
70
130
Beryllium (Be)
46.6
46.6
ug/L
1
50
93.2
70
130
Cadmium (Cd)
48.5
48.5
ug/L
1
50
97.1
70
130
Chromium (Cr)
48
48
ug/L
1
50
95.8
70
130
Cobalt (Co)
46.9
46.9
ug/L
1
50
93.7
70
130
Copper(Cu)
47
47
ug/L
1
50
94
70
130
Lead (Pb)
49
49
ug/L
1
50
97.9
70
130

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060590 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units:
Dil
Spike
Molybdenum (Mo)
50.6
50.6
ug/L
1
50
Nickel (Ni)
46.3
46.3
ug/L
1
50
Selenium (Se)
48.5
48.5
ug/L
1
50
Thallium (TI) Low Level
49.1
49.1
ug/L
1
50
Vanadium (V) Low Level
48.4
48.4
ug/L
1
50
MSD # 1
Parameter
Measured
Final
Units:
Dil
Spike
Antimony (Sb)
49.1
49.1
ug/L
1
50
Arsenic (As)
48.3
48.3
ug/L
1
50
Beryllium (Be)
48.9
48.9
ug/L
1
50
Cadmium (Cd)
48.6
48.6
ug/L
1
50
Chromium (Cr)
48.3
48.3
ug/L
1
50
Cobalt (Co)
46.4
46.4
ug/L
1
50
Copper (Cu)
47.6
47.6
ug/L
1
50
Lead (Pb)
49.2
49.2
ug/L
1
50
Molybdenum (Mo)
49.9
49.9
ug/L
1
50
Nickel (Ni)
46.6
46.6
ug/L
1
50
Selenium (Se)
48.3
48.3
ug/L
1
50
Thallium (TI) Low Level
49.5
49.5
ug/L
1
50
Vanadium (V) Low Level
48.1
48.1
ug/L
1
50
Duke Energy Analytical Lab
Page 31 of 71
Parent Sample: J16060542 -- 2016018105
% Recovery
LCL
UCL Qualifier
98.5
70
130
92.5
70
130
97
70
130
98.1
70
130
96.3
70
130
Parent Sample: J16060542 -- 2016018105
% Recovery
LCL
UCL
RPD Qualifier
98.2
70
130
1.88
96.2
70
130
3.27
97.7
70
130
4.71
97.1
70
130
0.0412
96.5
70
130
0.77
92.8
70
130
1.01
95.3
70
130
1.39
98.3
70
130
0.387
97.1
70
130
1.43
93.1
70
130
0.582
96.6
70
130
0.372
99
70
130
0.872
95.7
70
130
0.542

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical2Lab
y Page 32 of 71
This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060558 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Parameter Measured Final
TDS 0
Blank # 2
Parameter Measured Final
TDS -1
Duplicate # 1
Parameter Measured Final
TDS 542
Duplicate # 2
Parameter Measured Final
TDS 210
Duplicate # 3
Parameter Measured Final
TDS 297
LCS # 1
Parameter Measured Final
TDS 101
Units:
Dil
RDL
Relative Concentration
Qualifier
mg/L
1
25
< 1/2 RDL
Units:
Dil
RDL
Relative Concentration
Qualifier
mg/L
1
25
< 1/2 RDL
Parent Sample:
J16060542
-- 2016018104
Units:
Dil
RPD Qualifier
mg/L
1
1.47
Parent Sample:
J16060542
-- 2016018105
Units:
Dil
RPD Qualifier
mg/L
1
4.2
Parent Sample:
J16060542 -- 2016018106
Units:
Dil
RPD Qualifier
mg/L
1
3.42
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
mg/L
1
100
101 90
110

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical3Lab
y Page 33 of 71
This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060585 Total Carbon Total Carbon
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
TOC
0.016
mg/L
1
0.1
< 1/2 RDL
Blank # 2
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
TOC
0.031
mg/L
1
0.1
< 1/2 RDL
IS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
TOC
2.71
mg/L
1
2
105
80
120
ISD # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD
Qualifier
TOC
2.81
mg/L
1
2
109
80
120
4.49
IS # 2
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
TOC
2.89
mg/L
1
2
102
80
120
ISD # 2
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD
Qualifier
TOC
2.81
mg/L
1
2
98.3
80
120
4.09
IS # 3
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
TOC
3.3
mg/L
1
2
96.8
80
120
ISD # 3
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD
Qualifier
TOC
3.38
mg/L
1
2
100
80
120
3.7
LCS # 1.
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
TOC
2.92
mg/L
1
2.87
102
85
115
LCS # 2
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
TOC
2.92
mg/L
1
2.87
102
85
115

Certificate of LaboratoryAnalysis Duke Energy PageAnalytical4Lab
y Page 34 of 71
This report shall not be reproduced, except in full.
Order # A 6060542
Level II QC Summary
Q16060584 TSS TOTAL SUSPENDED SOLIDS
Blank # 1
Parameter Measured
TSS
Duplicate # 1
Parameter Measured
TSS
Duplicate # 2
Parameter Measured
TSS
LCS # 1
Parameter Measured
TSS
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
0
mg/L
1
5
< 1/2 RDL
Parent Sample: J16060542
-- 2016018105
Final
Units:
Dil
RPD Qualifier
0.2
mg/L
1
0
Parent Sample: J16060542
-- 2016018106
Final
Units:
Dil
RPD Qualifier
93.4
mg/L
1
3.78
Final
Units:
Dil
Spike
% Recovery LCL UCL
Qualifier
46.8
mg/L
1
50
93.6

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
098oinffte. Suite 100
y Huntersville, INC 28078
[phone]
June 27, 2016
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 16060542
Pace Project No.: 92302053
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on June 20, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 22

aceAnaiXical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
098oinffte. Suite 100
y Huntersville, NC 28078
[phone]
Project: J16060542
Pace Project No.: 92302053
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Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
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Indiana Certification: FL NELAC Reciprocity
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Louisiana Certification #: FL NELAC Reciprocity
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Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
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Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification M 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
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Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
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Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 2 of 22

aceAnalyical
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SAMPLE SUMMARY
Project: J16060542
Pace Project No.: 92302053
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92302053001
2016018104
Water
06/17/1611:51
06/20/1613:05
92302053002
2016018105
Water
06/17/1610:16
06/20/1613:05
92302053003
2016018106
Water
06/17/16 09:00
06/20/16 13:05
92302053004
2016018108
Water
06/17/1611:40
06/20/1613:05
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16060542
92302053
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92302053001
2016018104
RSK 175 Modified
ZDO
1
PASI-C
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
KEK
1
PASI-O
92302053002
2016018105
RSK 175 Modified
ZDO
1
PASI-C
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
KEK
1
PASI-O
92302053003
2016018106
RSK 175 Modified
ZDO
1
PASI-C
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
WRC
1
PASI-A
EPA 218.7
KEK
1
PASI-O
92302053004
2016018108
RSK 175 Modified
ZDO
1
PASI-C
SM 2320B
TEP
3
PASI-A
SM 4500-S2D
EWS
1
PASI-A
REPORT OF LABORATORY ANALYSIS
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Project: J16060542
Pace Project No.: 92302053
Lab Sample ID
Method
92302053001
SM 2320B
SM 2320B
92302053002
SM 2320B
SM 2320B
92302053003
SM 2320B
SM 2320B
SUMMARY OF DETECTION
Client Sample ID
Parameters
2016018104
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
2016018105
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
2016018106
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
Result Units
364 mg/L
364 mg/L
148 mg/L
148 mg/L
216 mg/L
216 mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Report Limit Analyzed Qualifiers
5.0
06/24/16 06:35
5.0
06/24/16 06:35
5.0
06/24/16 06:51
5.0
06/24/16 06:51
5.0 06/24/16 07:02
5.0 06/24/16 07:02
Page 5 of 22

aceAnalyical
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Duke Energy Xnal i alcrabervices, Inc.
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[phone]
PROJECT NARRATIVE
Project: J16060542
Pace Project No.: 92302053
Method: RSK 175 Modified
Description: RSK 175 Headspace
Client: Duke Energy
Date: June 27, 2016
General Information:
4 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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aceAnalyical
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PROJECT NARRATIVE
Project: J16060542
Pace Project No.: 92302053
Method: SM 2320B
Description: 2320E Alkalinity
Client: Duke Energy
Date: June 27, 2016
General Information:
4 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/45711
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92301918001,92301918002
M1: Matrix spike recovery exceeded QC limits.
• MS (Lab ID: 1762606)
• Alkalinity, Total as CaCO3
• MS (Lab ID: 1762608)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1762607)
• Alkalinity, Total as CaCO3
Additional Comments:
Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16060542
Pace Project No.: 92302053
Method: SM 4500-S213
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: June 27, 2016
General Information:
4 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/45724
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92301976002,92302525001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1763092)
• Sulfide
• MSD (Lab ID: 1763093)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16060542
Pace Project No.: 92302053
Method: EPA 218.7
Description: Hexavalent Chromium by IC
Client: Duke Energy
Date: June 27, 2016
General Information:
3 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16060542
Pace Project No.: 92302053
Sample: 2016018104
Lab ID: 92302053001 Collected:
06/17/16 11:51
Received: 06/20/16 13:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Methane
ND ug/L
10.0
1
06/21/1616:05
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
364 mg/L
5.0
1
06/24/16 06:35
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
06/24/16 06:35
Alkalinity, Total as CaCO3
364 mg/L
5.0
1
06/24/16 06:35
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
06/21/1617:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
06/21/16 19:30
18540-29-9
Date: 06/27/2016 02:54 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 10 of 22

aceAnalyical
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Duke Energy Xnal i alc�abervices, Inc.
199 H1i999f fte. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: J16060542
Pace Project No.: 92302053
Sample: 2016018105
Lab ID: 92302053002 Collected:
06/17/16 10:16
Received: 06/20/16 13:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Methane
ND ug/L
10.0
1
06/21/1616:20
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
148 mg/L
5.0
1
06/24/16 06:51
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
06/24/16 06:51
Alkalinity, Total as CaCO3
148 mg/L
5.0
1
06/24/16 06:51
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
06/21/1617:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
06/21/16 20:10
18540-29-9
Date: 06/27/2016 02:54 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 11 of 22

aceAnalyical
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Duke Energy Xnal i alc�abervices, Inc.
199 H1i699f fte. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: J16060542
Pace Project No.: 92302053
Sample: 2016018106
Lab ID: 92302053003 Collected:
06/17/16 09:00
Received: 06/20/16 13:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Methane
ND ug/L
10.0
1
06/21/1616:35
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
216 mg/L
5.0
1
06/24/16 07:02
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
06/24/16 07:02
Alkalinity, Total as CaCO3
216 mg/L
5.0
1
06/24/16 07:02
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
06/21/1617:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
06/21/16 20:23
18540-29-9
Date: 06/27/2016 02:54 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16060542
Pace Project No.: 92302053
Sample: 2016018108
Lab ID: 92302053004 Collected:
06/17/16 11:40
Received: 06/20/16 13:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Methane
ND ug/L
10.0
1
06/21/1616:50 74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
06/24/16 07:37
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
06/24/16 07:37
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
06/24/16 07:37
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
06/23/1616:00 18496-25-8
Date: 06/27/2016 02:54 PM
REPORT OF LABORATORY ANALYSIS
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Page 13 of 22

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QUALITY CONTROL DATA
Project: J16060542
Pace Project No.: 92302053
QC Batch: GCV/10695
Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified
Analysis Description: RSK
175 HEADSPACE
Associated Lab Samples: 92302053001, 92302053002, 92302053003, 92302053004
METHOD BLANK: 1760203
Matrix: Water
Associated Lab Samples: 92302053001, 92302053002, 92302053003, 92302053004
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Methane
ug/L
ND 10.0
06/21/1612:45
LABORATORY CONTROL SAMPLE:
1760204
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits
Qualifiers
Methane
ug/L
396 360
91 70-130
MATRIX SPIKE SAMPLE:
1760205
92301974001 Spike
MS MS
% Rec
Parameter
Units
Result Conc.
Result % Rec
Limits Qualifiers
Methane
ug/L
ND 396
361
91 70-130
SAMPLE DUPLICATE: 1760206
92301974002 Dup
Max
Parameter
Units
Result Result
RPD RPD
Qualifiers
Methane
ug/L
ND ND
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 06/27/2016 02:54 PM without the written consent of Pace Analytical Services, Inc.. Page 14 of 22

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[phone]
QUALITY CONTROL DATA
Project: J16060542
Pace Project No.: 92302053
QC Batch: WET/45711 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92302053001, 92302053002, 92302053003, 92302053004
METHOD BLANK: 1762604
Matrix: Water
Associated Lab Samples: 92302053001, 92302053002, 92302053003, 92302053004
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Alkalinity, Carbonate (CaCO3)
mg/L
ND 5.0
06/24/16 03:49
Alkalinity, Total as CaCO3
mg/L
ND 5.0
06/24/16 03:49
Alkalinity, Bicarbonate (CaCO3)
mg/L
ND 5.0
06/24/16 03:49
LABORATORY CONTROL SAMPLE: 1762605
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 47.2 94 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1762606 1762607
MS MSD
92301918001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 333 50 50 372 371 78 75 80-120 0 25 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1762608 1762609
MS MSD
92301918002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Alkalinity, Total as CaCO3 mg/L 190 50 50 229 235 78 90 80-120 3 25 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 06/27/2016 02:54 PM without the written consent of Pace Analytical Services, Inc..
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QUALITY CONTROL DATA
Project: J16060542
Pace Project No.: 92302053
QC Batch: WET/45660 Analysis Method: SM 4500-S21D
QC Batch Method: SM 4500-S21D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92302053001, 92302053002, 92302053003
METHOD BLANK: 1760448 Matrix: Water
Associated Lab Samples: 92302053001, 92302053002, 92302053003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 06/21/1617:00
LABORATORY CONTROL SAMPLE: 1760449
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.48 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1760450 1760451
MS MSD
92301913001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.50 0.50 97 97 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1760452 1760453
MS MSD
92301918002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.49 0.49 97 97 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 06/27/2016 02:54 PM without the written consent of Pace Analytical Services, Inc..
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Duke Energy Xnal i alc�a
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[phone]
QUALITY CONTROL DATA
Project: J16060542
Pace Project No.: 92302053
QC Batch: WET/45724 Analysis Method: SM 4500-S21D
QC Batch Method: SM 4500-S21D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92302053004
METHOD BLANK: 1763090 Matrix: Water
Associated Lab Samples: 92302053004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 06/23/1616:00
LABORATORY CONTROL SAMPLE: 1763091
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.51 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1763092 1763093
MS MSD
92302525001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.46 0.47 77 78 90-110 1 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1763094 1763095
MS MSD
92301976002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.46 0.47 92 93 90-110 2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 06/27/2016 02:54 PM without the written consent of Pace Analytical Services, Inc..
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QUALITY CONTROL DATA
Project: J16060542
Pace Project No.: 92302053
QC Batch: WETA/58924
Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7
Analysis Description: Chromium,
Hexavalent IC
Associated Lab Samples: 92302053001, 92302053002,
92302053003
METHOD BLANK: 1614049
Matrix: Water
Associated Lab Samples: 92302053001, 92302053002,
92302053003
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chromium, Hexavalent ug/L
ND 0.030
06/21/16 19:03
LABORATORY CONTROL SAMPLE: 1614050
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chromium, Hexavalent ug/L
.075 0.075
99 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1614051 1614052
MS MSD
92302053001
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND
.075 .075 0.074
0.070 99 93 85-115 7 20
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1614053 1614054
MS MSD
92301913008 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND .025 .025 0.034 0.032 91 85 85-115 4 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 06/27/2016 02:54 PM without the written consent of Pace Analytical Services, Inc..
Page 18 of 22

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QUALIFIERS
Project: J16060542
Pace Project No.: 92302053
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/27/2016 02:54 PM without the written consent of Pace Analytical Services, Inc.. Page 19 of 22

aceAnalyical
www.pacelabs.com
Duke Energy Xnal i alc�abervices, Inc.
199 V1 499f fte. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16060542
Pace Project No.: 92302053
Lab ID Sample ID QC Batch Method QC Batch
92302053001
2016018104
RSK 175
Modified
GCV/10695
92302053002
2016018105
RSK 175
Modified
GCV/10695
92302053003
2016018106
RSK 175
Modified
GCV/10695
92302053004
2016018108
RSK 175
Modified
GCV/10695
92302053001
2016018104
SM 2320B
WET/45711
92302053002
2016018105
SM 2320B
WET/45711
92302053003
2016018106
SM 2320B
WET/45711
92302053004
2016018108
SM 2320B
WET/45711
92302053001
2016018104
SM 4500-S2D
WET/45660
92302053002
2016018105
SM 4500-S2D
WET/45660
92302053003
2016018106
SM 4500-S2D
WET/45660
92302053004
2016018108
SM 4500-S2D
WET/45724
92302053001
2016018104
EPA 218.7
WETA/58924
92302053002
2016018105
EPA 218.7
WETA/58924
92302053003
2016018106
EPA 218.7
WETA/58924
Date: 06/27/2016 02:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 20 of 22

Document Name: Document Revised:April 25, 2016
72cleAnalytical Sample Condition Upon Receipt(SCUR) Dukp&gglgyfk1nalytical Lab
Document No.: IssuingAuth ° r ,
F-CHR-CS-003-rev.19 Pace Huntersville Quality Office
Sample Condition Upon Client Name:
Receipt
K e Project t!
Courier: ❑Fe Ex ❑UPS ❑USPs ❑Client
❑ Commercial ace []Other:
Custody Seal Present? Dyes [� No Seals intact? Dyes []No
Page 2 of 2 for Internal Use ONLY
WO#:92302053
1111111111111111111111
92302053
Date/Initials Person Examining Contents:C1•J/a
Packing Material: ❑Bubble Wrap Bubble Bags []None / ❑Other:
Thermometer: T1505 Type of Ice: [DWet ❑Blue []None ®Samples on ice, cooling process has be un
Correction Factor: CIVIC Cooler Temp Corrected (°C): �, Biological Tissue Frozen? [-]Yes []No N/A
Temp should be above fre ing to 6°C
USDA Regulated Soil ( N/A, water sample)
Did samp�les� figinate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (intergdonally,
[]Yes"� No including Hawaii and Puerto Rico)? ❑Yes E16
_. Comments/Discrepancy:
Chain of Custody Present?
Samples Arrived within Hold Time?
Short Hold Time Analysis (<72 hr.)'
Rush Turn Around Time Requestec
Sufficient Volume?
Correct Containers Used?
-Pace Containers Used?
Containers Intact?
Samples Field Filtered?
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis Matrix: L-1
All containers needing acid/base preservation have been
checked?
All containers needing preservation are found to be in
compliance with EPA recommendation?
(HN031 H2504, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide)
Exceptions: VOA, Coliform, TOC, Oil and Grease,
DRO/8015 (water) DOC.LLHE
Samples checked for dechlorination?
Headspace in VOA Vials (>5-6mm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
Pace Trip Blank Lot # (if purchased);
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Sample
Discrepancy:
IJNo ❑N/A 1.
❑Na ❑N/A 2.
No [—]N/A 3.
or ❑N/A 4.
[]No ❑N/A S.
❑No ❑N/A 6.
mil ❑N/A
7.
8. Note if sediment is visible in the dissolved container
❑No ❑N/A 1 9.
1�' HNC3 pHsZ
�s ❑No ❑N/A
es ❑No ❑N/A
EJYev LjNo LJN/A 11.
Yes ❑No ❑N/A 12.
❑Yes ❑No 0N A 13.
[]Yes[:]NorA
H[I pK�2
HZ504 pHa
Na6H pH>12
Na01f/Zn0Ac pH>9
U;
Date/Time;
J'n ;: 6460) -e
Field Data Required? Des ❑No
Project Manager SCURF Review: Date:
Project Manager SRF Review: Date:
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers)
Page 21 of 22

Duke Energy Onalytical Lab
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Page 22 of 22

® Laboratories LLC
Duke Energ . nalytical Lab
�i ge 57 of 71 is
a member of The GEL Group IN'.
IP4 Box 30712 Charleston, SC 29417
2040 Savage Road Charlestan. SC 25407
F 843.556.8171
F 843.766.1178
gel.com
June 27, 2016
Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078
Re: AB GW Assessment Water
Work Order: 399696
SDG: J16060542
Dear Mary:
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on June 20, 2016. This original data report has been prepared and reviewed in accordance
with GEL's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.
Sincerely,
Chelsea Seagle for
Lindsay Fabra
Project Manager
Purchase Order: 1142110
Enclosures
IIII11I�IIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIII

Duke Energy Analytical Lab
Page 58 of 71
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
for
DUP0002 Duke Energy
Client SDG: J16060542 GEL Work Order: 399696
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the 'U' qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
Reviewed by
Page 2 of 14

Duke Energy Analytical Lab
GEL LABORATORIES LLC Page 59 of 71
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016018104
399696001
Water
17-JUN-16 11:51
20-JUN-16
Client
Report Date: June 27, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Uranium Liquid "As Received"
Uranium-238 0.00335
0.000067
0.0002
ug/mL
1
SKJ 06/23/16
1038 1575947 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1
SKJ 06/24/16
0820 1575947 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1
SKJ 06/24/16
1104 1575947 3
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 0.894
0.617
1.00
pCi/L
AXM6 06/24/16
1235 1576017 4
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 6.00
0.485
1.00
pCi/L
LXP1 06/27/16
0940 1575592 5
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
SXWl
06/21/16
0756
1575946
The following Analytical Methods were performed:
Method Description Analyst Comments
I SW846 3010A/6020A
2 SW846 3010A/6020A
3 SW846 3010A/6020A
4 EPA 904.0/SW846 9320 Modified
5 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 69.6 (15%-125%)
Notes:
Page 3 of 14

Duke Energy Analytical Lab
GEL LABORATORIES LLC Page 60 of 71
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016018105
399696002
Water
17-JUN-16 10:16
20-JUN-16
Client
Report Date: June 27, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Uranium Liquid "As Received"
Uranium-238 0.000717
0.000067
0.0002
ug/mL
1
SKJ 06/23/16
1047 1575947 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1
SKJ 06/24/16
0829 1575947 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 U ND
0.637
1.00
pCi/L
AXM6 06/24/16
1235 1576017 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 2.85
0.435
1.00
pCi/L
LXP1 06/27/16
1015 1575592 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
SXWl
06/21/16
0756
1575946
The following Analytical Methods were performed:
Method Description Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 69.7 (15%-125%)
Notes:
Page 4 of 14

Duke Energy Analytical Lab
GEL LABORATORIES LLC Page 61 of 71
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2016018106
399696003
Water
17-JUN-16 09:00
20-JUN-16
Client
Report Date: June 27, 2016
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Uranium Liquid "As Received"
Uranium-238 J 0.000158
0.000067
0.0002
ug/mL
1
SKJ 06/23/16
1048 1575947 1
Uranium-233 U ND
0.00001
0.00005
ug/mL
1
SKJ 06/24/16
0831 1575947 2
Uranium-234 U ND
0.00001
0.00005
ug/mL
1
Uranium-236 U ND
0.00001
0.00005
ug/mL
1
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 U ND
0.773
1.00
pCi/L
AXM6 06/24/16
1235 1576017 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 2.23
0.254
1.00
pCi/L
LXP1 06/27/16
1015 1575592 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
SXWl
06/21/16
0756
1575946
The following Analytical Methods were performed:
Method Description Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 86.9 (15%-125%)
Notes:
Page 5 of 14

Duke Energy Analytical Lab
Page 62 of 71
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina
Contact: Mary Ann Ogle
Workorder: 399696
Report Date: June 27, 2016
Page 1 of 3
Parmname
NOM
Sample
Qual
QC
Units
RPD%o
REC%
Range Anlst
Date Time
Metals Analysis - ICPMS
Batch 1575947
QC1203571089
399696001
DUP
Uranium-233
U
ND
U
ND
ug/mL
N/A
SKJ
06/24/16 08:22
Uranium-234
U
ND
U
ND
ug/mL
N/A
Uranium-236
U
ND
U
ND
ug/mL
N/A
06/24/1611:05
Uranium-238
0.00335
0.00346
ug/mL
3.19
(0%-20%)
06/23/1610:39
QC1203571087
LCS
Uranium-238
0.0496
0.054
ug/mL
109
(80%-120%)
06/23/1610:36
QC1203571088
LCS
Uranium-233
0.0005
0.000534
ug/mL
107
(80%-120%)
06/24/16 08:19
Uranium-234
0.00055
0.000648
ug/mL
118
(80%-120%)
Uranium-236
0.005
0.00525
u9/mL
105
(80%-120%)
06/24/1611:02
QC1203571086
MB
Uranium-233
U
ND
ug/mL
06/24/16 08:17
Uranium-234
U
ND
ug/mL
Uranium-236
U
ND
ug/mL
06/24/1611:01
Uranium-238
U
ND
ug/mL
06/23/1610:35
QC1203571090
399696001
MS
Uranium-238
0.0496
0.00335
0.0565
ug/mL
107
(75%-125%)
06/23/1610:41
QC1203571091
399696001
MS
Uranium-233
0.0005
U
ND
0.000533
ug/mL
107
(75%-125%)
06/24/16 08:23
Uranium-234
0.00055
U
ND
0.000656
ug/mL
119
(75%-125%)
Uranium-236
0.005
U
ND
0.00347
ug/mL
69.3 *
(75%-125%)
06/24/16 11:07
QC1203573962
399696001
PS
Uranium-236
5.00
U
ND
5.31
ug/L
106
(80%-120%)
06/24/1611:09
Page 6of14

Duke Energy Analytical Lab
Page 63 of 71
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 399696 Page 2 of 3
Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Time
Metals Analysis - ICPMS
Batch 1575947
QC1203571092 399696001 SDILT
Uranium-233
U ND U
ND
ug/L
N/A
Uranium-234
U ND U
ND
ug/L
N/A
Uranium-236
U ND U
ND
ug/L
N/A (0%-10%)
Uranium-238
3.35
0.664
ug/L
.836 (0%-10%)
Rad Gas Flow
Batch 1576017
QC1203571243 399697003 DUP
Radium-228 U 0.600 U
0.394
pCi/L N/A
QC1203571244 LCS
Radium-228 15.2
18.8
pCi/L
QC1203571242 MB
Radium-228 U
0.248
pCi/L
Rad Ra-226
Batch 1575592
QC1203570063 399659001 DUP
Radium-226 0.584
0.636
pCi/L 8.5
QC1203570065 LCS
Radium-226 24.4
19.0
pCi/L
QC1203570062 MB
Radium-226 U
0.130
pCi/L
QC1203570064 399659001 MS
Radium-226 122 0.584
117
pCi/L
Notes:
The Qualifiers in this report are defined as follows:
** Analyte is a Tracer compound
< Result is less than value reported
> Result is greater than value reported
BD Results are either below the MDC or tracer recovery is low
E %difference of sample and SD is >10%. Sample concentration must
meet flagging criteria
FA Failed analysis.
SKJ 06/24/16 08:25
06/24/16 11:10
06/23/16 10:42
N/AAXM6 06/24/1614:23
124 (75%-125%) 06/24/1612:35
06/24/16 12:35
(0% - 100%) LXP1 06/27/16 10:45
77.7 (75%-125%) 06/27/1610:45
06/27/16 10:15
95.3 (75%-125%) 06/27/1610:45
Page 7 of 14

Duke Energy Analytical Lab
Page 64 of 71
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 399696 Page 3 of 3
Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Time
FB Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
H Analytical holding time was exceeded
J Value is estimated
K Analyte present. Reported value may be biased high. Actual value is expected to be lower.
L Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M M if above MDC and less than LLD
M REMP Result > MDC/CL and < RDL
N Metals --The Matrix spike sample recovery is not within specified control limits
N/A RPD or %Recovery limits do not apply.
N1 See case narrative
ND Analyte concentration is not detected above the detection limit
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
R Sample results are rejected
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
UI Gamma Spectroscopy --Uncertain identification
UJ Gamma Spectroscopy --Uncertain identification
UL Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Y Other specific qualifiers were required to properly define the results. Consult case narrative.
^ RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
h Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
Page 8 of 14

Duke Energy AftalyticaLA ab
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Page 9 of 14

Duke Energy Analytical Lab
Page 66 of 71
Laboratories LLc
SAMPLE RECEIPT & REVIEW FORM
Client: VtI -»
SDG/AR/COC(Work Order: (67
Received By:
Date Received: f
Suspected Hazard Information
;
o
*If Net Counts > 100cpm on samples not marked "radioactive", contact the Radiation Safety Gioup for further
>'
Z
investigation.
COC/Samples marked as radioactive?
aximum Net Counts Observed* (Observed Counts - Area Background Counts):
Classified Radioactive 11 or III by RSO?
f yes, Were swipes taken of sample containers < action levels?
COC/Samples marked containing PCBs?
Package; COC, and/or Samples marked as
beryllium or.asbestos containing?
If yes, sam les areto be segregated as Safety Controlled Samples and opened by the GEL Safety Grou .,,
Shipped as a DOT Hazardous?
azard Class Shipped: UN#:
Sam les identified as Foreign Soil?
Sample Receipt Criteria
4�
Z
Comments/Qualifrers (Required for Non -Conforming Items)
Shipping containers received intact and
Circle Applicable: Seals broken Damaged container Leaking container Other (describe)
1
sealed?
2
Samples requiring cold preservation
Preservation Method: Ice bags Blue ice Dry ice Other (describe) 4
within (0 < 6 deg. C)?*
*all temperatures are recorded in Celsius
�...
Daily check performed and passed on IR
Temperature Device Serial #:
22
temperature gun?
Secondary Temperature Device Serial # (IfApplicable): 4V
of custody documents included
3Chain
with shi ment?
j
Circle Applicable: Seals broken Damaged container Leaking container Other (describe)
4
Sample containers intact and sealed?
Samples requiring chemical preservationSample
ID's, containers affected and observed pH:
5
at proper pH?
If Peservatim added. t,t#:
Do Low Level Perchlorate samples have
Sample ID's and containers affected:
6
headspace as required?
7
VOA vials contain acid preservation?
(If unknown, select No)
VOA vials free of headspaee (defined as
Sample ID's and containers affected:
8
< 6n m bubble)?
9
Are Encore containers present?
(if yes, immediately deliver to Volatites laboratory)
ID's and tests affected:
Samples received within holding time?
it
Sample ID's on COC match ID's on
Sample ID's and containers affected:
110
bottles?
Date & time on COC match date & time
Sample ID's affected:
12
on bottles?
Number of containers received match
Sample ID's affected:
13
number indicated on COC?
14
Are sample containers identifiable as
GELprovided?
15
COC form is properly signed in
relinquished/received sections?
Circle Applicable:
FedEx Air FedEx Ground UPS Field Services Courier Other
P
16
Carrier and tracking number.
P a
L✓vri C 6--
Comments (Use Continuation'Form if needed):
PM (or PMA) review: Initials C - Date �T, ,� { Page R of
GL-CHL-SR-001 Rev 3
Page 10 of 14

Duke Energy Analytical Lab
Page 67 of 71
Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16060542
Work Order #: 399696
Metals
Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1575947
Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1575946
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID#
Client Sample Identification
399696001
2016018104
399696002
2016018105
399696003
2016018106
1203571086
Method Blank (MB)ICP-MS
1203571087
Laboratory Control Sample (LCS)
1203571088
Laboratory Control Sample (LCS)
1203571092
399696001(2016018104L) Serial Dilution (SD)
1203571089
399696001(2016018104D) Sample Duplicate (DUP)
1203571090
399696001(2016018104S) Matrix Spike (MS)
1203571091
399696001(2016018104S) Matrix Spike (MS)
1203573962
399696001(2016018104PS) Post Spike (PS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Quality Control (QQ Information
Matrix Spike (MS/MSD) Recovery Statement
The percent recoveries (%R) obtained from the MS/MSD analyses are evaluated when the sample concentration
is less than four times (4X) the spike concentration added. The MS/MSD (See Below) did not meet the
recommended quality control acceptance criteria for percent recoveries for the following applicable analyte. The
post spike recovery was within the required control limits. This verifies the absence of a matrix interference in
the post -spike digested sample. The recovery may be attributed to possible sample matrix interference and/or
non -homogeneity.
Sample
Analyte
Value
1203571091 (2016018104MS)
Uranium-236
69.3* (75%-125%)
Page 11 of 14

Duke Energy Analytical Lab
Page 68 of 71
Radiochemistry
Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1576017
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID# Client Sample Identification
399696001 2016018104
399696002
2016018105
399696003
2016018106
1203571242
Method Blank (MB)
1203571243
399697003(2016018090) Sample Duplicate (DUP)
1203571244
Laboratory Control Sample (LCS)
The samples in this SDG were analyzed on an "as received" basis.
Data Summary•
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Technical Information
Recounts
Sample 1203571243 (2016018090DUP) was recounted due to high relative percent difference/relative error
ratio. The recount is reported.
Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1575592
The following samples were analyzed using the above methods and analytical procedure(s).
GEL Sample ID# Client Sample Identification
399696001 2016018104
399696002 2016018105
399696003 2016018106
1203570062 Method Blank (MB)
1203570063 399659001(2016017980) Sample Duplicate (DUP)
1203570064 399659001(2016017980) Matrix Spike (MS)
1203570065 Laboratory Control Sample (LCS)
Page 12 of 14

Duke Energy Analytical Lab
Page 69 of 71
The samples in this SDG were analyzed on an "as received" basis.
Data Summary:
All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.
Miscellaneous Information
Additional Comments
The matrix spike, 1203570064 (2016017980MS), aliquot was reduced to conserve sample volume.
Certification Statement
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 13 of 14

Duke Energy Analytical Lab
Page 70 of 71
List of current GEL Certifications as of 27 June 2016
State
Certification
Alaska
UST-0110
Arkansas
88-0651
CLIA
42D0904046
California
2940
Colorado
SC00012
Connecticut
PH-0169
Delaware
SC00012
DoD ELAP/ ISO17025 A2LA
2567.01
Florida NELAP
E87156
Foreign Soils Permit
P330-15-00283, P330-15-00253
Georgia
SC00012
Georgia SDWA
967
Hawaii
SC00012
Idaho Chemistry
SC00012
Idaho Radiochemistry
SC00012
Illinois NELAP
200029
Indiana
C—SC-01
Kansas NELAP
E-10332
Kentucky SDWA
90129
Kentucky Wastewater
90129
Louisiana NELAP
03046 (A133904)
Louisiana SDWA
LA160006
Maryland
270
Massachusetts
M—SC012
Michigan
9976
Mississippi
SC00012
Nebraska
NE—OS-26-13
Nevada
SC000122016-1
New Hampshire NELAP
205415
New Jersey NELAP
SC002
New Mexico
SC00012
New York NELAP
11501
North Carolina
233
North Carolina SDWA
45709
North Dakota
R-158
Oklahoma
9904
Pennsylvania NELAP
68-00485
S.Carolina Radchem
10120002
South Carolina Chemistry
10120001
Tennessee
TN 02934
Texas NELAP
T104704235-16-11
Utah NELAP
SC000122016-20
Vermont
VT87156
Virginia NELAP
460202
Washington
C780
West Virginia
997404
Page 14 of 14

Duke Energy Analytical Lab
Page 71 of 71
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