NC0003425_J16010107-F_20160801

DUKE Analytical Laboratory Page 1 of42
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J16010107
ROXBORO - AB GW ASSESSMENT WATER
Brian Wilker, Tim Hunsucker, Fred Holt, Brandon Russo, Kathy Webb, John To
Anne Pifer
Plot
. 4
Anne Pifer
Phone:
Date:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
1/18/2016
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By
Sample Description
2016000554
Roxboro
07-Jan-16 1:23 PM
Richard Jacobs
ABMW-1
2016000555
Roxboro
07-Jan-16 1:55 PM
Richard Jacobs
ABMW-1BR
2016000556
Roxboro
07-Jan-16 8:57 AM
Richard Jacobs
ABMW-6BR
2016000557
Roxboro
07-Jan-16 9:41 AM
Richard Jacobs
ABMW-4BR
2016000558
Roxboro
07-Jan-16 10:40 AM
Richard Jacobs
ABMW-7BR
2016000559
Roxboro
07-Jan-16 12:14 PM
Richard Jacobs
MW-9BR
2016000560
Roxboro
07-Jan-16 12:14 PM
Richard Jacobs
MW-9BR DUP
2016000561
Roxboro
07-Jan-16 12:00 PM
Richard Jacobs
Filter Blank
2016000562
Roxboro
07-Jan-16 12:00 PM
Richard Jacobs
EQUIP BLANK
9 Total Samples
Page 2 of 42

Page 3 of 42
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
LVI Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 1/18/2016

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010107
Site: ABMW-1
Collection Date: 07-Jan-16 1:23 PM
Analyte Result Units Qualifiers RDL DF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1
Page 4 of 42
Sample #: 2016000554
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
SM2540D 01/09/201610:01 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010107
Site: ABMW-1 BR
Collection Date: 07-Jan-16 1:55 PM
Analyte Result
TOTAL SUSPENDED SOLIDS
TSS 5.0
Units Qualifiers RDL DF
mg/L 5 1
Page 5 of 42
Sample #: 2016000555
Matrix: GW WW
Method Analysis Date/Time Analyst
SM2540D 01/09/201610:01 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010107
Site: ABMW-6BR
Collection Date: 07-Jan-16 8:57 AM
Analyte Result
TOTAL SUSPENDED SOLIDS
TSS < 5
Units Qualifiers RDL DF
mg/L 5 1
Page 6 of 42
Sample #: 2016000556
Matrix: GW WW
Method Analysis Date/Time Analyst
SM2540D 01/09/201610:01 CJELLIO

Certificate of Laboratory Analysis Page 7 of 42
This report shall not be reproduced, except in full.
Order # J16010107
Site: ABMW-4BR
Collection Date: 07-Jan-16 9:41 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.022 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
8.2
mg/L
0.1
Sulfate
1.4
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.036
mg/L
0.005
Barium (Ba)
0.147
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
17.6
mg/L
0.01
Manganese (Mn)
3.04
mg/L
0.005
Strontium (Sr)
0.178
mg/L
0.005
Zinc (Zn)
0.025
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
38.8
mg/L
0.01
Magnesium (Mg)
14.1
mg/L
0.005
Potassium (K)
3.58
mg/L
0.1
Sodium (Na)
22.5
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.130
mg/L
0.005
Barium (Ba)
0.146
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
18.6
mg/L
0.01
Manganese (Mn)
3.01
mg/L
0.005
Strontium (Sr)
0.182
mg/L
0.005
Zinc (Zn)
0.012
mg/L
0.005
Sample #: 2016000557
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 11:36 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
01/09/2016 14:30
BGN9034
1 EPA 300.0
01/09/2016 14:30
BGN9034
1 EPA 245.1
01/08/2016 16:46
ACPAYNE
1 EPA 245.1
01/09/2016 13:55
ACPAYNE
1 EPA 200.7
01/10/2016 14:49
FCJORDA
1 EPA 200.7
01/10/2016 14:49
FCJORDA
1 EPA 200.7
01/10/2016 14:49
FCJORDA
1 EPA 200.7
01/10/2016 14:49
FCJORDA
1 EPA 200.7
01/10/2016 14:49
FCJORDA
1 EPA 200.7
01/10/2016 14:49
FCJORDA
1 EPA 200.7
01/10/2016 14:49
FCJORDA
1 EPA 200.7
01/11/2016 17:19
FCJORDA
1 EPA 200.7
01/11/2016 17:19
FCJORDA
1 EPA 200.7
01/11/2016 17:19
FCJORDA
1 EPA 200.7
01/11/2016 17:19
FCJORDA
1 EPA 200.7
01/11/2016 10:06
MHH7131
1 EPA 200.7
01/11/2016 10:06
MHH7131
1 EPA 200.7
01/11/2016 10:06
MHH7131
1 EPA 200.7
01/11/2016 10:06
MHH7131
1 EPA 200.7
01/11/2016 10:06
MHH7131
1 EPA 200.7
01/11/2016 10:06
MHH7131
1 EPA 200.7
01/11/2016 10:06
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010107
Site: ABMW-4BR
Collection Date: 07-Jan-16 9:41 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
10.8
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
12.4
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
230
mg/L
25
Total Carbon
TOC
1.4
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
37
mg/L
5
Page 8 of 42
Sample #:
2016000557
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 18:17
SLS2560
1
EPA 200.8
01/10/2016 18:17
SLS2560
1
EPA 200.8
01/10/2016 18:17
SLS2560
1
EPA 200.8
01/10/2016 18:17
SLS2560
1
EPA 200.8
01/10/2016 18:17
SLS2560
1
EPA 200.8
01/10/2016 18:17
SLS2560
1
EPA 200.8
01/10/2016 18:17
SLS2560
1
EPA 200.8
01/10/2016 18:17
SLS2560
1
EPA 200.8
01/10/2016 18:17
SLS2560
1
EPA 200.8
01/10/2016 18:17
SLS2560
1
EPA 200.8
01/10/2016 18:17
SLS2560
1
EPA 200.8
01/10/2016 18:17
SLS2560
1
EPA 200.8
01/10/2016 18:17
SLS2560
1 EPA 200.8
01/10/2016 23:00
SLS2560
1 EPA 200.8
01/10/2016 23:00
SLS2560
1 EPA 200.8
01/10/2016 23:00
SLS2560
1 EPA 200.8
01/10/2016 23:00
SLS2560
1 EPA 200.8
01/10/2016 23:00
SLS2560
1 EPA 200.8
01/10/2016 23:00
SLS2560
1 EPA 200.8
01/10/2016 23:00
SLS2560
1 EPA 200.8
01/10/2016 23:00
SLS2560
1 EPA 200.8
01/10/2016 23:00
SLS2560
1 EPA 200.8
01/10/2016 23:00
SLS2560
1 EPA 200.8
01/10/2016 23:00
SLS2560
1 EPA 200.8
01/10/2016 23:00
SLS2560
1 EPA 200.8
01/10/2016 23:00
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/09/201615:30 CJELLIO
1 SM5310C/EPA9060A 01/13/201615:59 GHUTCHI
1 SM2540D 01/09/201610:01 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010107
Site: ABMW-7BR
Collection Date: 07-Jan-16 10:40 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
14
mg/L
0.5
Sulfate
150
mg/L
2.5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.017
mg/L
0.005
Boron (B)
0.951
mg/L
0.05
Iron (Fe)
0.274
mg/L
0.01
Manganese (Mn)
0.451
mg/L
0.005
Strontium (Sr)
0.237
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
83.9
mg/L
0.01
Magnesium (Mg)
30.2
mg/L
0.005
Potassium (K)
4.12
mg/L
0.1
Sodium (Na)
17.0
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.014
mg/L
0.005
Barium (Ba)
0.017
mg/L
0.005
Boron (B)
0.902
mg/L
0.05
Iron (Fe)
0.307
mg/L
0.01
Manganese (Mn)
0.432
mg/L
0.005
Strontium (Sr)
0.246
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000558
Matrix: GW WW
Page 9 of 42
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 11:37 LSTARL1
Vendor Method V_PACE
5
EPA 300.0
01/09/2016 15:23
BGN9034
25
EPA 300.0
01/09/2016 15:23
BGN9034
1
EPA 245.1
01/08/2016 16:48
ACPAYNE
1
EPA 245.1
01/09/2016 13:57
ACPAYNE
1
EPA 200.7
01/10/2016 14:53
FCJORDA
1
EPA 200.7
01/10/2016 14:53
FCJORDA
1
EPA 200.7
01/10/2016 14:53
FCJORDA
1
EPA 200.7
01/10/2016 14:53
FCJORDA
1
EPA 200.7
01/10/2016 14:53
FCJORDA
1
EPA 200.7
01/10/2016 14:53
FCJORDA
1
EPA 200.7
01/10/2016 14:53
FCJORDA
1
EPA 200.7
01/11/2016 17:31
FCJORDA
1
EPA 200.7
01/11/2016 17:31
FCJORDA
1
EPA 200.7
01/11/2016 17:31
FCJORDA
1
EPA 200.7
01/11/2016 17:31
FCJORDA
1
EPA 200.7
01/11/2016 10:18
MHH7131
1
EPA 200.7
01/11/2016 10:18
MHH7131
1
EPA 200.7
01/11/2016 10:18
MHH7131
1
EPA 200.7
01/11/2016 10:18
MHH7131
1
EPA 200.7
01/11/2016 10:18
MHH7131
1
EPA 200.7
01/11/2016 10:18
MHH7131
1
EPA 200.7
01/11/2016 10:18
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010107
Site: ABMW-7BR
Collection Date: 07-Jan-16 10:40 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
480
mg/L
25
Total Carbon
TOC
0.827
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 10 of 42
Sample #:
2016000558
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 18:51
SLS2560
1
EPA 200.8
01/10/2016 18:51
SLS2560
1
EPA 200.8
01/10/2016 18:51
SLS2560
1
EPA 200.8
01/10/2016 18:51
SLS2560
1
EPA 200.8
01/10/2016 18:51
SLS2560
1
EPA 200.8
01/10/2016 18:51
SLS2560
1
EPA 200.8
01/10/2016 18:51
SLS2560
1
EPA 200.8
01/10/2016 18:51
SLS2560
1
EPA 200.8
01/10/2016 18:51
SLS2560
1
EPA 200.8
01/10/2016 18:51
SLS2560
1
EPA 200.8
01/10/2016 18:51
SLS2560
1
EPA 200.8
01/10/2016 18:51
SLS2560
1
EPA 200.8
01/10/2016 18:51
SLS2560
1 EPA 200.8
01/10/2016 22:26
SLS2560
1 EPA 200.8
01/10/2016 22:26
SLS2560
1 EPA 200.8
01/10/2016 22:26
SLS2560
1 EPA 200.8
01/10/2016 22:26
SLS2560
1 EPA 200.8
01/10/2016 22:26
SLS2560
1 EPA 200.8
01/10/2016 22:26
SLS2560
1 EPA 200.8
01/10/2016 22:26
SLS2560
1 EPA 200.8
01/10/2016 22:26
SLS2560
1 EPA 200.8
01/10/2016 22:26
SLS2560
1 EPA 200.8
01/10/2016 22:26
SLS2560
1 EPA 200.8
01/10/2016 22:26
SLS2560
1 EPA 200.8
01/10/2016 22:26
SLS2560
1 EPA 200.8
01/10/2016 22:26
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/09/201615:30 CJELLIO
1 SM5310C/EPA9060A 01/13/201615:59 GHUTCHI
1 SM2540D 01/09/201610:01 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010107
Site: MW-9BR
Collection Date: 07-Jan-16 12:14 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.047 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
11
mg/L
0.5
Sulfate
22
mg/L
0.5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.026
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.062
mg/L
0.01
Manganese (Mn)
0.247
mg/L
0.005
Strontium (Sr)
0.173
mg/L
0.005
Zinc (Zn)
0.022
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
24.4
mg/L
0.01
Magnesium (Mg)
14.6
mg/L
0.005
Potassium (K)
2.38
mg/L
0.1
Sodium (Na)
18.3
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.175
mg/L
0.005
Barium (Ba)
0.026
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.275
mg/L
0.01
Manganese (Mn)
0.250
mg/L
0.005
Strontium (Sr)
0.178
mg/L
0.005
Zinc (Zn)
0.025
mg/L
0.005
Sample #: 2016000559
Matrix: GW WW
Page 11 of 42
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 11:38 LSTARL1
Vendor Method V_PACE
5 EPA 300.0
01/09/2016 16:53
BGN9034
5 EPA 300.0
01/09/2016 16:53
BGN9034
1 EPA 245.1
01/08/2016 16:44
ACPAYNE
1 EPA 245.1
01/09/2016 13:59
ACPAYNE
1 EPA 200.7
01/10/2016 15:09
FCJORDA
1 EPA 200.7
01/10/2016 15:09
FCJORDA
1 EPA 200.7
01/10/2016 15:09
FCJORDA
1 EPA 200.7
01/10/2016 15:09
FCJORDA
1 EPA 200.7
01/10/2016 15:09
FCJORDA
1 EPA 200.7
01/10/2016 15:09
FCJORDA
1 EPA 200.7
01/10/2016 15:09
FCJORDA
1 EPA 200.7
01/11/2016 17:34
FCJORDA
1 EPA 200.7
01/11/2016 17:34
FCJORDA
1 EPA 200.7
01/11/2016 17:34
FCJORDA
1 EPA 200.7
01/11/2016 17:34
FCJORDA
1 EPA 200.7
01/11/2016 10:23
MHH7131
1 EPA 200.7
01/11/2016 10:23
MHH7131
1 EPA 200.7
01/11/2016 10:23
MHH7131
1 EPA 200.7
01/11/2016 10:23
MHH7131
1 EPA 200.7
01/11/2016 10:23
MHH7131
1 EPA 200.7
01/11/2016 10:23
MHH7131
1 EPA 200.7
01/11/2016 10:23
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010107
Site: MW-9BR
Collection Date: 07-Jan-16 12:14 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.77
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.60
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.44
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.97
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.34
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.27
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
210
mg/L
25
Total Carbon
TOC
0.785
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 12 of 42
Sample #:
2016000559
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 18:56
SLS2560
1
EPA 200.8
01/10/2016 18:56
SLS2560
1
EPA 200.8
01/10/2016 18:56
SLS2560
1
EPA 200.8
01/10/2016 18:56
SLS2560
1
EPA 200.8
01/10/2016 18:56
SLS2560
1
EPA 200.8
01/10/2016 18:56
SLS2560
1
EPA 200.8
01/10/2016 18:56
SLS2560
1
EPA 200.8
01/10/2016 18:56
SLS2560
1
EPA 200.8
01/10/2016 18:56
SLS2560
1
EPA 200.8
01/10/2016 18:56
SLS2560
1
EPA 200.8
01/10/2016 18:56
SLS2560
1
EPA 200.8
01/10/2016 18:56
SLS2560
1
EPA 200.8
01/10/2016 18:56
SLS2560
1 EPA 200.8
01/10/2016 23:05
SLS2560
1 EPA 200.8
01/10/2016 23:05
SLS2560
1 EPA 200.8
01/10/2016 23:05
SLS2560
1 EPA 200.8
01/10/2016 23:05
SLS2560
1 EPA 200.8
01/10/2016 23:05
SLS2560
1 EPA 200.8
01/10/2016 23:05
SLS2560
1 EPA 200.8
01/10/2016 23:05
SLS2560
1 EPA 200.8
01/10/2016 23:05
SLS2560
1 EPA 200.8
01/10/2016 23:05
SLS2560
1 EPA 200.8
01/10/2016 23:05
SLS2560
1 EPA 200.8
01/10/2016 23:05
SLS2560
1 EPA 200.8
01/10/2016 23:05
SLS2560
1 EPA 200.8
01/10/2016 23:05
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/09/201615:30 CJELLIO
1 SM5310C/EPA9060A 01/13/201615:59 GHUTCHI
1 SM2540D 01/09/201610:01 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010107
Site: MW-9BR DUP
Collection Date: 07-Jan-16 12:14 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.019 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
11
mg/L
0.5
Sulfate
22
mg/L
0.5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.024
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.062
mg/L
0.01
Manganese (Mn)
0.247
mg/L
0.005
Strontium (Sr)
0.173
mg/L
0.005
Zinc (Zn)
0.021
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
24.1
mg/L
0.01
Magnesium (Mg)
14.4
mg/L
0.005
Potassium (K)
2.34
mg/L
0.1
Sodium (Na)
18.0
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.183
mg/L
0.005
Barium (Ba)
0.026
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.283
mg/L
0.01
Manganese (Mn)
0.249
mg/L
0.005
Strontium (Sr)
0.177
mg/L
0.005
Zinc (Zn)
0.024
mg/L
0.005
Sample #: 2016000560
Matrix: GW WW
Page 13 of 42
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 11:39 LSTARL1
Vendor Method V_PACE
5 EPA 300.0
01/09/2016 17:47
BGN9034
5 EPA 300.0
01/09/2016 17:47
BGN9034
1 EPA 245.1
01/08/2016 16:51
ACPAYNE
1 EPA 245.1
01/09/2016 14:02
ACPAYNE
1 EPA 200.7
01/10/2016 15:13
FCJORDA
1 EPA 200.7
01/10/2016 15:13
FCJORDA
1 EPA 200.7
01/10/2016 15:13
FCJORDA
1 EPA 200.7
01/10/2016 15:13
FCJORDA
1 EPA 200.7
01/10/2016 15:13
FCJORDA
1 EPA 200.7
01/10/2016 15:13
FCJORDA
1 EPA 200.7
01/10/2016 15:13
FCJORDA
1 EPA 200.7
01/11/2016 17:38
FCJORDA
1 EPA 200.7
01/11/2016 17:38
FCJORDA
1 EPA 200.7
01/11/2016 17:38
FCJORDA
1 EPA 200.7
01/11/2016 17:38
FCJORDA
1 EPA 200.7
01/11/2016 10:27
MHH7131
1 EPA 200.7
01/11/2016 10:27
MHH7131
1 EPA 200.7
01/11/2016 10:27
MHH7131
1 EPA 200.7
01/11/2016 10:27
MHH7131
1 EPA 200.7
01/11/2016 10:27
MHH7131
1 EPA 200.7
01/11/2016 10:27
MHH7131
1 EPA 200.7
01/11/2016 10:27
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010107
Site: MW-9BR DUP
Collection Date: 07-Jan-16 12:14 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.78
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.53
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.50
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.96
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.30
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.30
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
220
mg/L
25
Total Carbon
TOC
0.694
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 14 of 42
Sample #:
2016000560
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 19:00
SLS2560
1
EPA 200.8
01/10/2016 19:00
SLS2560
1
EPA 200.8
01/10/2016 19:00
SLS2560
1
EPA 200.8
01/10/2016 19:00
SLS2560
1
EPA 200.8
01/10/2016 19:00
SLS2560
1
EPA 200.8
01/10/2016 19:00
SLS2560
1
EPA 200.8
01/10/2016 19:00
SLS2560
1
EPA 200.8
01/10/2016 19:00
SLS2560
1
EPA 200.8
01/10/2016 19:00
SLS2560
1
EPA 200.8
01/10/2016 19:00
SLS2560
1
EPA 200.8
01/10/2016 19:00
SLS2560
1
EPA 200.8
01/10/2016 19:00
SLS2560
1
EPA 200.8
01/10/2016 19:00
SLS2560
1 EPA 200.8
01/10/2016 23:10
SLS2560
1 EPA 200.8
01/10/2016 23:10
SLS2560
1 EPA 200.8
01/10/2016 23:10
SLS2560
1 EPA 200.8
01/10/2016 23:10
SLS2560
1 EPA 200.8
01/10/2016 23:10
SLS2560
1 EPA 200.8
01/10/2016 23:10
SLS2560
1 EPA 200.8
01/10/2016 23:10
SLS2560
1 EPA 200.8
01/10/2016 23:10
SLS2560
1 EPA 200.8
01/10/2016 23:10
SLS2560
1 EPA 200.8
01/10/2016 23:10
SLS2560
1 EPA 200.8
01/10/2016 23:10
SLS2560
1 EPA 200.8
01/10/2016 23:10
SLS2560
1 EPA 200.8
01/10/2016 23:10
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/09/201615:30 CJELLIO
1 SM5310C/EPA9060A 01/13/201615:59 GHUTCHI
1 SM2540D 01/09/201610:01 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010107
Site: Filter Blank
Collection Date: 07-Jan-16 12:00 PM
Analyte
Result
Units Qualifiers
RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
0.020
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2016000561
Matrix: GW WW
Page 15 of 42
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
01/09/2016 14:04
ACPAYNE
1
EPA 200.7
01/10/2016 15:17
FCJORDA
1
EPA 200.7
01/10/2016 15:17
FCJORDA
1
EPA 200.7
01/10/2016 15:17
FCJORDA
1
EPA 200.7
01/10/2016 15:17
FCJORDA
1
EPA 200.7
01/10/2016 15:17
FCJORDA
1
EPA 200.7
01/10/2016 15:17
FCJORDA
1
EPA 200.7
01/10/2016 15:17
FCJORDA
1
EPA 200.8
01/10/2016 19:05
SLS2560
1
EPA 200.8
01/10/2016 19:05
SLS2560
1
EPA 200.8
01/10/2016 19:05
SLS2560
1
EPA 200.8
01/10/2016 19:05
SLS2560
1
EPA 200.8
01/10/2016 19:05
SLS2560
1
EPA 200.8
01/10/2016 19:05
SLS2560
1
EPA 200.8
01/10/2016 19:05
SLS2560
1
EPA 200.8
01/10/2016 19:05
SLS2560
1
EPA 200.8
01/10/2016 19:05
SLS2560
1
EPA 200.8
01/10/2016 19:05
SLS2560
1
EPA 200.8
01/10/2016 19:05
SLS2560
1
EPA 200.8
01/10/2016 19:05
SLS2560
1
EPA 200.8
01/10/2016 19:05
SLS2560

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010107
Site: EQUIP BLANK
Collection Date: 07-Jan-16 12:00 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.014 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
Calcium (Ca)
0.012
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Page 16 of 42
Sample #: 2016000562
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_PACE
1 EPA 353.2
01/10/2016 11:40
LSTARL1
Vendor Method
V_PACE
1 EPA 300.0
01/09/2016 16:35
BGN9034
1 EPA 300.0
01/09/2016 16:35
BGN9034
1 EPA 245.1
01/08/2016 16:53
ACPAYNE
1 EPA 200.7
01/11/2016 17:42
FCJORDA
1 EPA 200.7
01/11/2016 17:42
FCJORDA
1 EPA 200.7
01/11/2016 17:42
FCJORDA
1 EPA 200.7
01/11/2016 17:42
FCJORDA
1 EPA 200.7
01/11/2016 10:31
MHH7131
1 EPA 200.7
01/11/2016 10:31
MHH7131
1 EPA 200.7
01/11/2016 10:31
MHH7131
1 EPA 200.7
01/11/2016 10:31
MHH7131
1 EPA 200.7
01/11/2016 10:31
MHH7131
1 EPA 200.7
01/11/2016 10:31
MHH7131
1 EPA 200.7
01/11/2016 10:31
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010107
Site: EQUIP BLANK
Collection Date: 07-Jan-16 12:00 PM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
< 25
mg/L
25
1
Total Carbon
Page 17 of 42
Sample #:
2016000562
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
01/10/2016 23:15
SLS2560
EPA 200.8
01/10/2016 23:15
SLS2560
EPA 200.8
01/10/2016 23:15
SLS2560
EPA 200.8
01/10/2016 23:15
SLS2560
EPA 200.8
01/10/2016 23:15
SLS2560
EPA 200.8
01/10/2016 23:15
SLS2560
EPA 200.8
01/10/2016 23:15
SLS2560
EPA 200.8
01/10/2016 23:15
SLS2560
EPA 200.8
01/10/2016 23:15
SLS2560
EPA 200.8
01/10/2016 23:15
SLS2560
EPA 200.8
01/10/2016 23:15
SLS2560
EPA 200.8
01/10/2016 23:15
SLS2560
EPA 200.8
01/10/2016 23:15
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
SM2540C 01/09/201615:30 CJELLIO
TOC 0.172 mg/L 0.1 1 SM5310C/EPA9060A 01/13/201615:59 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 01/09/2016 10:01 CJELLIO

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g li ,8ybe. Suite 100
Huntersville, INC 28078
[phone]
January 13, 2016
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 16010107
Pace Project No.: 92282350
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 08, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Anne Pifer
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 24

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
OQ�%cgfbe. Suite 100
Huntersville, NC 28078
[phone]
Project: J16010107
Pace Project No.: 92282350
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A21-A Certification M 2926.01
Alaska Certification M UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification M 88-0680
California Certification M 01155CA
Colorado Certification #Pace
Connecticut Certification M PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification M 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification M 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification M 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification M 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification M E83079
Georgia Certification M 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification M 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification M E-10383
Kentucky Certification #: 90050
Louisiana Certification M FL NELAC Reciprocity
Louisiana Environmental Certificate M 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification M Cert 0074
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification M TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification M 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE SUMMARY
Project: J16010107
Pace Project No.: 92282350
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92282350001
2016000554
Water
01/07/1613:23
01/08/1613:45
92282350002
2016000557
Water
01/07/16 09:41
01/08/16 13:45
92282350003
2016000558
Water
01/07/1610:40
01/08/1613:45
92282350004
2016000559
Water
01/07/1612:14
01/08/1613:45
92282350005
2016000560
Water
01/07/1612:14
01/08/1613:45
92282350006
2016000562
Water
01/07/1612:00
01/08/1613:45
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16010107
92282350
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92282350001
2016000554
SM 2320B
MLS
3
PASI-A
92282350002
2016000557
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S21D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282350003
2016000558
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S21D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282350004
2016000559
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S21D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282350005
2016000560
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S21D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282350006
2016000562
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S21D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
REPORT OF LABORATORY ANALYSIS
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Project: J16010107
Pace Project No.: 92282350
Lab Sample ID
Method
92282350001
SM 2320B
SM 2320B
SM 2320B
92282350002
RSK 175
SM 2320B
SM 2320B
92282350003
RSK 175
SM 2320B
SM 2320B
92282350004
SM 2320B
SM 2320B
92282350005
SM 2320B
SM 2320B
SUMMARY OF DETECTION
Client Sample ID
Parameters
2016000554
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Carbonate (CaCO3)
Alkalinity, Total as CaCO3
2016000557
Methane
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
2016000558
Methane
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
2016000559
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
2016000560
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
Result
Units
5.3
mg/L
91.2
mg/L
96.5
mg/L
288
ug/L
207
mg/L
207
mg/L
74.8
ug/L
223
mg/L
223
mg/L
127
mg/L
127
mg/L
125
mg/L
125
mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Report Limit Analyzed Qualifiers
5.0 01/11/16 21:55
5.0 01/11/16 21:55
5.0 01/11/16 21:55
10.0 01/11/1619:09
5.0 01/11/16 22:11
5.0 01/11/16 22:11
10.0 01/11/16 19:17
5.0 01/11/16 22:25
5.0 01/11/16 22:25
5.0 01/12/1611:22
5.0 01/12/1611:22
5.0 01/12/1612:02
5.0 01/12/1612:02
Page 5 of 24

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PROJECT NARRATIVE
Project: J16010107
Pace Project No.: 92282350
Method: RSK 175
Description: RSK 175 AIR Headspace
Client: Duke Energy
Date: January 13, 2016
General Information:
5 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16010107
Pace Project No.: 92282350
Method: SM 2320B
Description: 2320E Alkalinity
Client: Duke Energy
Date: January 13, 2016
General Information:
6 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/42413
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92282350004,92282353008
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 1644935)
• Alkalinity, Total as CaCO3
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16010107
Pace Project No.: 92282350
Method: SM 4500-S213
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: January 13, 2016
General Information:
5 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16010107
Pace Project No.: 92282350
Method: EPA 218.7
Description: Hexavalent Chromium by IC
Client: Duke Energy
Date: January 13, 2016
General Information:
5 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16010107
Pace Project No.: 92282350
Sample: 2016000554
Lab ID: 92282350001 Collected:
01/07/16
13:23
Received: 01/08/16 13:45 Matrix: Water
Parameters
Results Units
Report Limit
DF
Prepared Analyzed CAS No. Qual
2320E Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
5.3 mg/L
5.0
1
01/11/16 21:55
Alkalinity, Carbonate (CaCO3)
91.2 mg/L
5.0
1
01/11/16 21:55
Alkalinity, Total as CaCO3
96.5 mg/L
5.0
1
01/11/16 21:55
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16010107
Pace Project No.: 92282350
Sample: 2016000557
Lab ID: 92282350002 Collected:
01/07/16 09:41
Received: 01/08/16 13:45 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
288 ug/L
10.0
1
01/11/1619:09
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
207 mg/L
5.0
1
01/11/16 22:11
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/11/16 22:11
Alkalinity, Total as CaCO3
207 mg/L
5.0
1
01/11/16 22:11
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/11/16 21:26
18540-29-9
Date: 01/13/2016 01:58 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16010107
Pace Project No.: 92282350
Sample: 2016000558
Lab ID: 92282350003 Collected:
01/07/16 10:40
Received: 01/08/16 13:45 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
74.8 ug/L
10.0
1
01/11/1619:17
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
223 mg/L
5.0
1
01/11/16 22:25
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/11/16 22:25
Alkalinity, Total as CaCO3
223 mg/L
5.0
1
01/11/16 22:25
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/11/16 22:05
18540-29-9
Date: 01/13/2016 01:58 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16010107
Pace Project No.: 92282350
Sample: 2016000559
Lab ID: 92282350004 Collected:
01/07/16 12:14
Received: 01/08/16 13:45 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/11/1619:42
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
127 mg/L
5.0
1
01/12/16 11:22
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 11:22
Alkalinity, Total as CaCO3
127 mg/L
5.0
1
01/12/16 11:22
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/11/16 22:44
18540-29-9
Date: 01/13/2016 01:58 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16010107
Pace Project No.: 92282350
Sample: 2016000560
Lab ID: 92282350005 Collected:
01/07/16 12:14
Received: 01/08/16 13:45 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/11/1619:59
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
125 mg/L
5.0
1
01/12/16 12:02
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 12:02
Alkalinity, Total as CaCO3
125 mg/L
5.0
1
01/12/16 12:02
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/11/16 22:57
18540-29-9
Date: 01/13/2016 01:58 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16010107
Pace Project No.: 92282350
Sample: 2016000562
Lab ID: 92282350006 Collected:
01/07/16 12:00
Received: 01/08/16 13:45 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/11/16 20:07
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 12:15
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 12:15
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
01/12/16 12:15
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/11/16 23:10
18540-29-9
Date: 01/13/2016 01:58 PM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J16010107
Pace Project No.: 92282350
QC Batch: AIR/25002
Analysis Method: RSK 175
QC Batch Method: RSK 175
Analysis Description: RSK 175 AIR HEADSPACE
Associated Lab Samples: 92282350002, 92282350003,
92282350004, 92282350005, 92282350006
METHOD BLANK: 2173091
Matrix: Water
Associated Lab Samples: 92282350002, 92282350003,
92282350004, 92282350005, 92282350006
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Methane
ug/L
ND 10.0 01/11/1617:55
LABORATORY CONTROL SAMPLE & LCSD:
2173092
2173093
Spike LCS LCSD LCS LCSD
% Rec
Max
Parameter
Units
Conc. Result Result % Rec % Rec
Limits RPD
RPD Qualifiers
Methane
ug/L
60.7 58.8 59.4 97 98
85-115
1 20
SAMPLE DUPLICATE: 2173516
92282355023 Dup
Max
Parameter
Units
Result Result RPD
RPD
Qualifiers
Methane
ug/L
ND 1.6J
20
SAMPLE DUPLICATE: 2173517
92282350004 Dup
Max
Parameter
Units
Result Result RPD
RPD
Qualifiers
Methane
ug/L
ND 3J
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J16010107
Pace Project No.: 92282350
QC Batch: WET/42402 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92282350001, 92282350002, 92282350003
METHOD BLANK: 1644401
Matrix: Water
Associated Lab Samples: 92282350001, 92282350002, 92282350003
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Alkalinity, Carbonate (CaCO3)
mg/L
ND 5.0
01/11/16 16:50
Alkalinity, Total as CaCO3
mg/L
ND 5.0
01/11/16 16:50
Alkalinity, Bicarbonate (CaCO3)
mg/L
ND 5.0
01/11/16 16:50
LABORATORY CONTROL SAMPLE: 1644402
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 50.2 100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1644403 1644404
MS MSD
92282184011 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 160 50 50 209 206 98 91 80-120 2 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1644405 1644406
MS MSD
92282011004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Alkalinity, Total as CaCO3 mg/L 14.1 50 50 65.3 65.7 102 103 80-120 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/13/2016 01:58 PM without the written consent of Pace Analytical Services, Inc..
Page 17 of 24

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098ninybe. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010107
Pace Project No.: 92282350
QC Batch: WET/42413 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92282350004, 92282350005, 92282350006
METHOD BLANK: 1644930
Matrix: Water
Associated Lab Samples: 92282350004, 92282350005, 92282350006
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Alkalinity, Carbonate (CaCO3)
mg/L
ND 5.0
01/12/16 11:00
Alkalinity, Total as CaCO3
mg/L
ND 5.0
01/12/16 11:00
Alkalinity, Bicarbonate (CaCO3)
mg/L
ND 5.0
01/12/16 11:00
LABORATORY CONTROL SAMPLE: 1644931
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 47.5 95 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1644932 1644933
MS MSD
92282350004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 127 50 50 175 175 95 96 80-120 0 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1644934 1644935
MS MSD
92282353008 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Alkalinity, Total as CaCO3 mg/L 223 50 50 263 260 80 74 80-120 1 25 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/13/2016 01:58 PM without the written consent of Pace Analytical Services, Inc..
Page 18 of 24

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098ninybe. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010107
Pace Project No.: 92282350
QC Batch: WET/42390 Analysis Method: SM 4500-S2D
QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92282350002, 92282350003, 92282350004, 92282350005, 92282350006
METHOD BLANK: 1644370 Matrix: Water
Associated Lab Samples: 92282350002, 92282350003, 92282350004, 92282350005, 92282350006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 01/10/1611:30
LABORATORY CONTROL SAMPLE: 1644371
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.50 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1644372 1644373
MS MSD
92282350002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.51 0.51 101 101 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1644374 1644375
MS MSD
92282353006 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.49 0.49 98 98 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/13/2016 01:58 PM without the written consent of Pace Analytical Services, Inc..
Page 19 of 24

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098v�vbe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010107
Pace Project No.: 92282350
QC Batch: WETA/53663
Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7
Analysis Description: Chromium, Hexavalent IC
Associated Lab Samples: 92282350002, 92282350003,
92282350004, 92282350005, 92282350006
METHOD BLANK: 1443677
Matrix: Water
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Chromium, Hexavalent ug/L
ND 0.030 01/11/16 18:37
LABORATORY CONTROL SAMPLE: 1443678
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Chromium, Hexavalent ug/L
.075 0.076 101 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1443679 1443680
MS MSD
92282355023
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L 0.087
.025 .025 0.11 0.11 101 90 85-115 2 20
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1443681 1443682
MS MSD
92282350003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND .075 .075 0.075 0.073 99 97 85-115 3 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/13/2016 01:58 PM without the written consent of Pace Analytical Services, Inc..
Page 20 of 24

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098ninybe. Suite 100
y Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J16010107
Pace Project No.: 92282350
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-M Pace Analytical Services - Minneapolis
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/13/2016 01:58 PM without the written consent of Pace Analytical Services, Inc.. Page 21 of 24

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098ninybe. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16010107
Pace Project No.: 92282350
Lab ID Sample ID QC Batch Method QC Batch
92282350002
2016000557
RSK 175
AIR/25002
92282350003
2016000558
RSK 175
AIR/25002
92282350004
2016000559
RSK 175
AIR/25002
92282350005
2016000560
RSK 175
AIR/25002
92282350006
2016000562
RSK 175
AIR/25002
92282350001
2016000554
SM 2320B
WET/42402
92282350002
2016000557
SM 2320B
WET/42402
92282350003
2016000558
SM 2320B
WET/42402
92282350004
2016000559
SM 2320B
WET/42413
92282350005
2016000560
SM 2320B
WET/42413
92282350006
2016000562
SM 2320B
WET/42413
92282350002
2016000557
SM 4500-S2D
WET/42390
92282350003
2016000558
SM 4500-S2D
WET/42390
92282350004
2016000559
SM 4500-S2D
WET/42390
92282350005
2016000560
SM 4500-S2D
WET/42390
92282350006
2016000562
SM 4500-S2D
WET/42390
92282350002
2016000557
EPA 218.7
WETA/53663
92282350003
2016000558
EPA 218.7
WETA/53663
92282350004
2016000559
EPA 218.7
WETA/53663
92282350005
2016000560
EPA 218.7
WETA/53663
92282350006
2016000562
EPA 218.7
WETA/53663
Date: 01/13/2016 01:58 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 22 of 24

Document Name:
Document Revised: 260CT2015.
aceAnalytical o
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
F-CHR-CS-003-rev,17
Pace Huntersv€IIe Quallty-Office
iM
Client Name: Project#:
Courier: ❑Fe x- ❑UPS ❑USPS []Client
❑Commerciai -Pace ❑Other:
Custody Seal on Cooler/Box Present? ❑yes _.-❑No
Packing Material: ❑bubble Wrap [Bubble Bags
Thermometer ❑ C15U5
waa:eraa2seo
IIIIIIIIIIIII IIII IIIII
Seals Intact? ❑Yes ❑No
❑None ❑Other.
Type of Ice: DWet❑Blue None
Used: ❑ . ©imp on ice, cooling process has begun
Confer Temp Corrected (°C): Biological Tissue Frozen? [f Yps ::: �]Nq ❑N/zC'
Temp should be above freezing to 6'C Correction Factor: 0.0 °C Date and Initials of Person Examining.Conterats:
USDA Regulated Soil (❑ N/A, water sample)
Did samples or€gi ate n a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate froMa,foreign source (Internationally,
-]Yes ©Na includingHawall and Puerto Rico ? ` ) []Yes ❑No
If Yes to either question, fill out a Regulates) Soil Checklist and Include with $CUR/COC paperwork,
COMMENTS:
Chain of Custody Present?
yes
Oho
❑N/A
1
Chain of Custody Filled Out?
Yes
❑No
❑N/A
2,
Chain of Custody Relinquished?
❑ es
ON.
❑N/A
3.
Sampler Name and/or Signature on COC?
❑V s
No
El N/A
4.
Samples Arrived within Hold Time?
es
No
[I N/A
5.
Short Hold Time Analysis (<72 hr)?
[]No
❑NIA
6.
Rush Turn Around Time Requested?
❑Yes
❑No El N/A
7.
Sufficient Volume?
Q e
❑No
❑N/A
8.
Correct Containers Used?
EfY,,
[]No El
9.
-Pace Containers Used?
Dyes
0140
❑N/A
Containers Intact?
❑Y s
❑No
[--]N/A
0.
Filtered Volume Received for Dissolved Tests?
[]Yes,Elmo
,
❑NJA
11.
Note if sediment Is visible In the dissolved container
Sample Labels Match COC?
es
o
❑N/A
12.
1 �11 C10
-Includes Date/Time/ID/Analysis Matr€k:
All containers needing acid/base preservation have been
checked?
dfe-s-
❑No
❑N/A
13
All containers needing preservation are found to be in
compliance with EPA recommendation?
(HNO3i H2SO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide)
Yes
[]Ho
❑N/A
Exceptions: VOA, Coliform, TOC, Oil and Grease,
DRO/8015 (water) DOC,LLHg
❑Yes
❑No
[3
Samples checked for dechlorizat€on
El Yes
[:]No
❑N/ ..
14.
Headspace in VOA Vials (>5-6mm)?
[]Yes
❑No
N/A
15.
Trip Blank Present?
❑Yes
❑No
❑ /A
16.
Trip Blank Custody Seals Present?
[]Yes
❑No
©N A
Pace Trip Blank Lot it (if pu(chased);
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Resolution:
Field Data:: gyired? ❑Yes ❑No
Date/Time:
Project Manager SCURF Review: _ _ Date: Ill / "
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of
hold, incorrect preservat€ve, out of temp, incorrect containers). Page 23 of 24

Page 41 of 42
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Page 24 24

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM --------------------------
----
.--- ------------•---' -Duke Energy ~Cal Laboratory • i � '- ---'-•-----'-'-•-•---•-'-'---•----Ana I IAbore _._� lis--.on.--------------------
Duke
Energy Mid, Cod. MGb3A3 (B.Ning7405) f !order Matrix GW_WW s..g4.wawrNo_
Analytical Laboratory 13339H89—Fe" Rd i eon SC_
Chain of Custody & Hunl —OW, N. C. 28078 !Logged By pap & Tie SAMPLE PROGRAM
so Log Fax: Q04)8753038
._._._._._._._._._._._._.-._._._.-._.._._._._._._._.__. _ _ _._.-.-.-._._._:.ff 0**kv Water RAW UST
4t Name Poore No: '—
B GW Assessment water R eua_ _
P tnt � 980-876-5032 PO 1142081 Filtration (0.46 um) 4 Unfiltered
Irises unit: P.«. RuP• C« T.:
Preservative we lee me H2aw Ice a oK�
mio�-- aoawryw.C�: Container Volume (mL) 2000 40 ml 300 1z9 600 600
MG03A3
rbedy: Container Type PET glass PET PET PET PET
Y
Sample Description or ID Customer to completeat/ appropriatenou W N a _
shaded areas. ___ _ 0 'y w _ ,� C �• y t //�1
f cj E�° p
..._.._.._.._.._. _ Information, Collection Information
Wi
GPS Location Date Time signature U F- Z a m Li i N Z
QS$' G srJ— -?— '\
�����•. � IZJ1_i_A/14G 1tih i*d�>�/.2J % 3„ 7 J � I
Page 42
of 42 Synterra EDD
Page _t_
of-1-
DISTRIBUTION
ORIGINAL to LAB, COPY to CLIENT
Bares
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250
500
500
HDPE
HDPE
HDPE
HD
N
N
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mV
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Filter Blank
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0
TOTAL
2
4
2
2
2
2
0
0
0
1
T
2
19
r n&
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Kv
tafTime
Accepted By:
to/Time
„ f
s7 '/V!R?
y
Requested Turnaround
Total 20
r+ /
r .�
9
}O
i
c
`14 Days
By ime
Aeespted i
a
07
Days
By Daternaw
cce em
O «
g d
"48 Hr
Daternme
Sealedll- no Do ime
0
•
ELEMENTS
by ICP;_MS (TRM): As, Be, Cd, Cc, Cu, Ni, Pb, Sib, Se. L) TI (L, V (LL)
c
"Other _ASAP
ELEMENTS
by ICP (TRM): At, Be, 8, Fe, Mn, Sr, Zn
ICP_Undigested Ca, Mg, K, No
Hg by 245.1
e
*Add. Cost Will Apply
Dissolved metals: all metals ICP, IMS,Hg
U