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Home My WebLink AboutNC0003425_J16010082-F_20160801DUKE Analytical Laboratory Page 1of87 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J16010082 ROXBORO - AB GW ASSESSMENT WATER Brian Wilker, Tim Hunsucker, Fred Holt, Brandon Russo, Kathy Webb, John To Anne Pifer Phone: At � o(Date: f Anne Pifer Please contact the Program Manager (Anne Pifer) with any questions regarding this report. Data Flags & Calculations: 1/18/2016 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Page 2 of 87 Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2016000390 Roxboro 06-Jan-16 4:22 PM ILLEGIBLE MW-17BR 2016000392 Roxboro 06-Jan-16 2:48 PM ILLEGIBLE MW-2BR 2016000393 Roxboro 06-Jan-16 9:05 AM ILLEGIBLE MW-14BR 2016000394 Roxboro 06-Jan-16 1:40 PM ILLEGIBLE MW-16BR 2016000395 Roxboro 06-Jan-16 12:30 PM ILLEGIBLE MW-10BR 2016000396 Roxboro 06-Jan-16 10:31 AM ILLEGIBLE MW-13BR 2016000397 Roxboro 06-Jan-16 9:05 AM ILLEGIBLE ABMW-2BR 2016000398 Roxboro 06-Jan-16 10:40 AM ILLEGIBLE ABMW-1 2016000399 Roxboro 06-Jan-16 11:45AM ILLEGIBLE ABMW-1BR 2016000400 Roxboro 06-Jan-16 3:45 PM ILLEGIBLE ABMW-4 2016000401 Roxboro 06-Jan-16 2:35 PM ILLEGIBLE ABMW-6BR 2016000402 Roxboro 06-Jan-16 4:30 PM ILLEGIBLE ABMW-5D 2016000403 Roxboro 06-Jan-16 1:30 PM ILLEGIBLE ABMW-05 2016000404 Roxboro 06-Jan-16 10:30 AM ILLEGIBLE MW-1BR 2016000405 Roxboro 06-Jan-16 10:30 AM ILLEGIBLE Filter Blank 2016000406 Roxboro 06-Jan-16 10:30 AM ILLEGIBLE EQUIP BLANK 2016000407 Roxboro 06-Jan-16 11:50 AM ILLEGIBLE CW-1 2016000408 Roxboro 06-Jan-16 9:10 AM ILLEGIBLE MW-3BR 2016000409 Roxboro 06-Jan-16 10:31 AM ILLEGIBLE MW-13BR Dup 19 Total Samples Page 3 of 87 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification ❑ Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report OV Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries ❑ Chain of Custody ❑ Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 1/15/2016 Certificate of Laboratory Analysis Page 4 of 87 This report shall not be reproduced, except in full. Order # J16010082 Site: MW-17BR Collection Date: 06-Jan-16 4:22 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.011 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 15 mg/L 1 Sulfate 39 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.095 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.574 mg/L 0.01 Manganese (Mn) 0.358 mg/L 0.005 Strontium (Sr) 0.891 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 85.8 mg/L 0.01 Magnesium (Mg) 20.1 mg/L 0.005 Potassium (K) 4.60 mg/L 0.1 Sodium (Na) 18.5 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.081 mg/L 0.005 Barium (Ba) 0.100 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.756 mg/L 0.01 Manganese (Mn) 0.359 mg/L 0.005 Strontium (Sr) 0.917 mg/L 0.005 Zinc (Zn) 0.015 mg/L 0.005 Sample #: 2016000390 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 13:29 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/07/2016 23:17 BGN9034 10 EPA 300.0 01/07/2016 23:17 BGN9034 1 EPA 245.1 01/08/2016 13:42 ACPAYNE 1 EPA 245.1 01/09/2016 10:58 ACPAYNE 1 EPA 200.7 01/07/2016 14:49 FCJORDA 1 EPA 200.7 01/07/2016 14:49 FCJORDA 1 EPA 200.7 01/07/2016 14:49 FCJORDA 1 EPA 200.7 01/07/2016 14:49 FCJORDA 1 EPA 200.7 01/07/2016 14:49 FCJORDA 1 EPA 200.7 01/07/2016 14:49 FCJORDA 1 EPA 200.7 01/07/2016 14:49 FCJORDA 1 EPA 200.7 01/08/2016 11:11 FCJORDA 1 EPA 200.7 01/08/2016 11:11 FCJORDA 1 EPA 200.7 01/08/2016 11:11 FCJORDA 1 EPA 200.7 01/08/2016 11:11 FCJORDA 1 EPA 200.7 01/08/2016 15:25 FCJORDA 1 EPA 200.7 01/08/2016 15:25 FCJORDA 1 EPA 200.7 01/08/2016 15:25 FCJORDA 1 EPA 200.7 01/08/2016 15:25 FCJORDA 1 EPA 200.7 01/08/2016 15:25 FCJORDA 1 EPA 200.7 01/08/2016 15:25 FCJORDA 1 EPA 200.7 01/08/2016 15:25 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: MW-17BR Collection Date: 06-Jan-16 4:22 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 2.08 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 2.75 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.454 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 380 mg/L 25 Total Carbon TOC 0.783 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 5 of 87 Sample #: 2016000390 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/11/2016 12:58 SLS2560 1 EPA 200.8 01/11/2016 12:58 SLS2560 1 EPA 200.8 01/11/2016 12:58 SLS2560 1 EPA 200.8 01/11/2016 12:58 SLS2560 1 EPA 200.8 01/11/2016 12:58 SLS2560 1 EPA 200.8 01/11/2016 12:58 SLS2560 1 EPA 200.8 01/11/2016 12:58 SLS2560 1 EPA 200.8 01/11/2016 12:58 SLS2560 1 EPA 200.8 01/11/2016 12:58 SLS2560 1 EPA 200.8 01/11/2016 12:58 SLS2560 1 EPA 200.8 01/11/2016 12:58 SLS2560 1 EPA 200.8 01/11/2016 12:58 SLS2560 1 EPA 200.8 01/11/2016 12:58 SLS2560 1 EPA 200.8 01/11/2016 13:08 SLS2560 1 EPA 200.8 01/11/2016 13:08 SLS2560 1 EPA 200.8 01/11/2016 13:08 SLS2560 1 EPA 200.8 01/11/2016 13:08 SLS2560 1 EPA 200.8 01/11/2016 13:08 SLS2560 1 EPA 200.8 01/11/2016 13:08 SLS2560 1 EPA 200.8 01/11/2016 13:08 SLS2560 1 EPA 200.8 01/11/2016 13:08 SLS2560 1 EPA 200.8 01/11/2016 13:08 SLS2560 1 EPA 200.8 01/11/2016 13:08 SLS2560 1 EPA 200.8 01/11/2016 13:08 SLS2560 1 EPA 200.8 01/11/2016 13:08 SLS2560 1 EPA 200.8 01/11/2016 13:08 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis Page 6 of 87 This report shall not be reproduced, except in full. Order # J16010082 Site: MW-2BR Collection Date: 06-Jan-16 2:48 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.048 mg-N/L M2 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 120 mg/L 2 Sulfate 32 mg/L 2 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.019 mg/L 0.005 Barium (Ba) 1.16 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 15.3 mg/L 0.01 Manganese (Mn) 0.998 mg/L 0.005 Strontium (Sr) 0.550 mg/L 0.005 Zinc (Zn) 0.015 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 68.2 mg/L 0.01 Magnesium (Mg) 33.4 mg/L 0.005 Potassium (K) 5.01 mg/L 0.1 Sodium (Na) 45.0 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.045 mg/L 0.005 Barium (Ba) 1.18 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 16.0 mg/L 0.01 Manganese (Mn) 0.967 mg/L 0.005 Strontium (Sr) 0.556 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000392 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 13:37 LSTARL1 Vendor Method V_PACE 20 EPA 300.0 01/08/2016 00:11 BGN9034 20 EPA 300.0 01/08/2016 00:11 BGN9034 1 EPA 245.1 01/08/2016 13:44 ACPAYNE 1 EPA 245.1 01/09/2016 11:00 ACPAYNE 1 EPA 200.7 01/07/2016 15:01 FCJORDA 1 EPA 200.7 01/07/2016 15:01 FCJORDA 1 EPA 200.7 01/07/2016 15:01 FCJORDA 1 EPA 200.7 01/07/2016 15:01 FCJORDA 1 EPA 200.7 01/07/2016 15:01 FCJORDA 1 EPA 200.7 01/07/2016 15:01 FCJORDA 1 EPA 200.7 01/07/2016 15:01 FCJORDA 1 EPA 200.7 01/08/2016 11:23 FCJORDA 1 EPA 200.7 01/08/2016 11:23 FCJORDA 1 EPA 200.7 01/08/2016 11:23 FCJORDA 1 EPA 200.7 01/08/2016 11:23 FCJORDA 1 EPA 200.7 01/08/2016 15:36 FCJORDA 1 EPA 200.7 01/08/2016 15:36 FCJORDA 1 EPA 200.7 01/08/2016 15:36 FCJORDA 1 EPA 200.7 01/08/2016 15:36 FCJORDA 1 EPA 200.7 01/08/2016 15:36 FCJORDA 1 EPA 200.7 01/08/2016 15:36 FCJORDA 1 EPA 200.7 01/08/2016 15:36 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: MW-2BR Collection Date: 06-Jan-16 2:48 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) 2.31 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 4.85 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 2.07 ug/L 1 Nickel (Ni) 1.40 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) 2.32 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 5.27 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 2.26 ug/L 1 Nickel (Ni) 1.47 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.357 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 500 mg/L 25 Total Carbon TOC 2.5 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 22 mg/L 5 Page 7 of 87 Sample #: 2016000392 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/11/2016 13:03 SLS2560 1 EPA 200.8 01/11/2016 13:03 SLS2560 1 EPA 200.8 01/11/2016 13:03 SLS2560 1 EPA 200.8 01/11/2016 13:03 SLS2560 1 EPA 200.8 01/11/2016 13:03 SLS2560 1 EPA 200.8 01/11/2016 13:03 SLS2560 1 EPA 200.8 01/11/2016 13:03 SLS2560 1 EPA 200.8 01/11/2016 13:03 SLS2560 1 EPA 200.8 01/11/2016 13:03 SLS2560 1 EPA 200.8 01/11/2016 13:03 SLS2560 1 EPA 200.8 01/11/2016 13:03 SLS2560 1 EPA 200.8 01/11/2016 13:03 SLS2560 1 EPA 200.8 01/11/2016 13:03 SLS2560 1 EPA 200.8 01/09/2016 17:32 SLS2560 1 EPA 200.8 01/09/2016 17:32 SLS2560 1 EPA 200.8 01/09/2016 17:32 SLS2560 1 EPA 200.8 01/09/2016 17:32 SLS2560 1 EPA 200.8 01/09/2016 17:32 SLS2560 1 EPA 200.8 01/09/2016 17:32 SLS2560 1 EPA 200.8 01/09/2016 17:32 SLS2560 1 EPA 200.8 01/09/2016 17:32 SLS2560 1 EPA 200.8 01/09/2016 17:32 SLS2560 1 EPA 200.8 01/09/2016 17:32 SLS2560 1 EPA 200.8 01/09/2016 17:32 SLS2560 1 EPA 200.8 01/09/2016 17:32 SLS2560 1 EPA 200.8 01/09/2016 17:32 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis Page 8 of 87 This report shall not be reproduced, except in full. Order # J16010082 Site: MW-14BR Collection Date: 06-Jan-16 9:05 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.014 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 43 mg/L 1 Sulfate 12 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.035 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 1.20 mg/L 0.01 Manganese (Mn) 0.279 mg/L 0.005 Strontium (Sr) 0.165 mg/L 0.005 Zinc (Zn) 0.051 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 67.6 mg/L 0.01 Magnesium (Mg) 27.2 mg/L 0.005 Potassium (K) 7.19 mg/L 0.1 Sodium (Na) 22.1 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.057 mg/L 0.005 Barium (Ba) 0.038 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 1.78 mg/L 0.01 Manganese (Mn) 0.291 mg/L 0.005 Strontium (Sr) 0.175 mg/L 0.005 Zinc (Zn) 0.045 mg/L 0.005 Sample #: 2016000393 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 13:40 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/08/2016 00:29 BGN9034 10 EPA 300.0 01/08/2016 00:29 BGN9034 1 EPA 245.1 01/08/2016 13:47 ACPAYNE 1 EPA 245.1 01/09/2016 11:03 ACPAYNE 1 EPA 200.7 01/07/2016 15:13 FCJORDA 1 EPA 200.7 01/07/2016 15:13 FCJORDA 1 EPA 200.7 01/07/2016 15:13 FCJORDA 1 EPA 200.7 01/07/2016 15:13 FCJORDA 1 EPA 200.7 01/07/2016 15:13 FCJORDA 1 EPA 200.7 01/07/2016 15:13 FCJORDA 1 EPA 200.7 01/07/2016 15:13 FCJORDA 1 EPA 200.7 01/08/2016 11:36 FCJORDA 1 EPA 200.7 01/08/2016 11:36 FCJORDA 1 EPA 200.7 01/08/2016 11:36 FCJORDA 1 EPA 200.7 01/08/2016 11:36 FCJORDA 1 EPA 200.7 01/08/2016 15:40 FCJORDA 1 EPA 200.7 01/08/2016 15:40 FCJORDA 1 EPA 200.7 01/08/2016 15:40 FCJORDA 1 EPA 200.7 01/08/2016 15:40 FCJORDA 1 EPA 200.7 01/08/2016 15:40 FCJORDA 1 EPA 200.7 01/08/2016 15:40 FCJORDA 1 EPA 200.7 01/08/2016 15:40 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: MW-14BR Collection Date: 06-Jan-16 9:05 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.47 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1.36 ug/L 1 Nickel (Ni) 1.28 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.319 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 1.98 ug/L 1 Cobalt (Co) 1.25 ug/L 1 Copper (Cu) 2.16 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1.44 ug/L 1 Nickel (Ni) 1.80 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.362 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 390 mg/L 25 Total Carbon TOC 0.943 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 5.0 mg/L 5 Page 9 of 87 Sample #: 2016000393 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 15:25 SLS2560 1 EPA 200.8 01/09/2016 15:25 SLS2560 1 EPA 200.8 01/09/2016 15:25 SLS2560 1 EPA 200.8 01/09/2016 15:25 SLS2560 1 EPA 200.8 01/09/2016 15:25 SLS2560 1 EPA 200.8 01/09/2016 15:25 SLS2560 1 EPA 200.8 01/09/2016 15:25 SLS2560 1 EPA 200.8 01/09/2016 15:25 SLS2560 1 EPA 200.8 01/09/2016 15:25 SLS2560 1 EPA 200.8 01/09/2016 15:25 SLS2560 1 EPA 200.8 01/09/2016 15:25 SLS2560 1 EPA 200.8 01/09/2016 15:25 SLS2560 1 EPA 200.8 01/09/2016 15:25 SLS2560 1 EPA 200.8 01/09/2016 17:52 SLS2560 1 EPA 200.8 01/09/2016 17:52 SLS2560 1 EPA 200.8 01/09/2016 17:52 SLS2560 1 EPA 200.8 01/09/2016 17:52 SLS2560 1 EPA 200.8 01/09/2016 17:52 SLS2560 1 EPA 200.8 01/09/2016 17:52 SLS2560 1 EPA 200.8 01/09/2016 17:52 SLS2560 1 EPA 200.8 01/09/2016 17:52 SLS2560 1 EPA 200.8 01/09/2016 17:52 SLS2560 1 EPA 200.8 01/09/2016 17:52 SLS2560 1 EPA 200.8 01/09/2016 17:52 SLS2560 1 EPA 200.8 01/09/2016 17:52 SLS2560 1 EPA 200.8 01/09/2016 17:52 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis Page 10 of 87 This report shall not be reproduced, except in full. Order # J16010082 Site: MW-16BR Collection Date: 06-Jan-16 1:40 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.078 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 13 mg/L 0.5 Sulfate 26 mg/L 0.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.066 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.014 mg/L 0.01 Manganese (Mn) 0.125 mg/L 0.005 Strontium (Sr) 0.160 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 53.3 mg/L 0.01 Magnesium (Mg) 23.5 mg/L 0.005 Potassium (K) 3.89 mg/L 0.1 Sodium (Na) 18.5 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.093 mg/L 0.005 Barium (Ba) 0.075 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.116 mg/L 0.01 Manganese (Mn) 0.138 mg/L 0.005 Strontium (Sr) 0.171 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000394 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 13:41 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/08/2016 00:47 BGN9034 5 EPA 300.0 01/08/2016 00:47 BGN9034 1 EPA 245.1 01/08/2016 13:49 ACPAYNE 1 EPA 245.1 01/09/2016 11:05 ACPAYNE 1 EPA 200.7 01/07/2016 15:17 FCJORDA 1 EPA 200.7 01/07/2016 15:17 FCJORDA 1 EPA 200.7 01/07/2016 15:17 FCJORDA 1 EPA 200.7 01/07/2016 15:17 FCJORDA 1 EPA 200.7 01/07/2016 15:17 FCJORDA 1 EPA 200.7 01/07/2016 15:17 FCJORDA 1 EPA 200.7 01/07/2016 15:17 FCJORDA 1 EPA 200.7 01/08/2016 11:40 FCJORDA 1 EPA 200.7 01/08/2016 11:40 FCJORDA 1 EPA 200.7 01/08/2016 11:40 FCJORDA 1 EPA 200.7 01/08/2016 11:40 FCJORDA 1 EPA 200.7 01/08/2016 15:44 FCJORDA 1 EPA 200.7 01/08/2016 15:44 FCJORDA 1 EPA 200.7 01/08/2016 15:44 FCJORDA 1 EPA 200.7 01/08/2016 15:44 FCJORDA 1 EPA 200.7 01/08/2016 15:44 FCJORDA 1 EPA 200.7 01/08/2016 15:44 FCJORDA 1 EPA 200.7 01/08/2016 15:44 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: MW-16BR Collection Date: 06-Jan-16 1:40 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.14 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 2.74 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) 1.28 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.22 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 3.08 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 310 mg/L 25 Total Carbon TOC 0.454 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 11 of 87 Sample #: 2016000394 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 15:30 SLS2560 1 EPA 200.8 01/09/2016 15:30 SLS2560 1 EPA 200.8 01/09/2016 15:30 SLS2560 1 EPA 200.8 01/09/2016 15:30 SLS2560 1 EPA 200.8 01/09/2016 15:30 SLS2560 1 EPA 200.8 01/09/2016 15:30 SLS2560 1 EPA 200.8 01/09/2016 15:30 SLS2560 1 EPA 200.8 01/09/2016 15:30 SLS2560 1 EPA 200.8 01/09/2016 15:30 SLS2560 1 EPA 200.8 01/09/2016 15:30 SLS2560 1 EPA 200.8 01/09/2016 15:30 SLS2560 1 EPA 200.8 01/09/2016 15:30 SLS2560 1 EPA 200.8 01/09/2016 15:30 SLS2560 1 EPA 200.8 01/09/2016 17:57 SLS2560 1 EPA 200.8 01/09/2016 17:57 SLS2560 1 EPA 200.8 01/09/2016 17:57 SLS2560 1 EPA 200.8 01/09/2016 17:57 SLS2560 1 EPA 200.8 01/09/2016 17:57 SLS2560 1 EPA 200.8 01/09/2016 17:57 SLS2560 1 EPA 200.8 01/09/2016 17:57 SLS2560 1 EPA 200.8 01/09/2016 17:57 SLS2560 1 EPA 200.8 01/09/2016 17:57 SLS2560 1 EPA 200.8 01/09/2016 17:57 SLS2560 1 EPA 200.8 01/09/2016 17:57 SLS2560 1 EPA 200.8 01/09/2016 17:57 SLS2560 1 EPA 200.8 01/09/2016 17:57 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/2016 15:30 CJELLIO 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: MW-10BR Collection Date: 06-Jan-16 12:30 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.049 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 18 mg/L 0.5 Sulfate 42 mg/L 0.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.108 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.064 mg/L 0.01 Manganese (Mn) 0.676 mg/L 0.005 Strontium (Sr) 0.184 mg/L 0.005 Zinc (Zn) 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 57.7 mg/L 0.01 Magnesium (Mg) 19.8 mg/L 0.005 Potassium (K) 9.21 mg/L 0.1 Sodium (Na) 36.7 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.008 mg/L 0.005 Barium (Ba) 0.120 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.087 mg/L 0.01 Manganese (Mn) 0.752 mg/L 0.005 Strontium (Sr) 0.196 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000395 Matrix: GW WW Page 12 of 87 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 13:43 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/08/2016 01:05 BGN9034 5 EPA 300.0 01/08/2016 01:05 BGN9034 1 EPA 245.1 01/08/2016 13:56 ACPAYNE 1 EPA 245.1 01/09/2016 11:12 ACPAYNE 1 EPA 200.7 01/07/2016 15:20 FCJORDA 1 EPA 200.7 01/07/2016 15:20 FCJORDA 1 EPA 200.7 01/07/2016 15:20 FCJORDA 1 EPA 200.7 01/07/2016 15:20 FCJORDA 1 EPA 200.7 01/07/2016 15:20 FCJORDA 1 EPA 200.7 01/07/2016 15:20 FCJORDA 1 EPA 200.7 01/07/2016 15:20 FCJORDA 1 EPA 200.7 01/08/2016 11:44 FCJORDA 1 EPA 200.7 01/08/2016 11:44 FCJORDA 1 EPA 200.7 01/08/2016 11:44 FCJORDA 1 EPA 200.7 01/08/2016 11:44 FCJORDA 1 EPA 200.7 01/08/2016 15:48 FCJORDA 1 EPA 200.7 01/08/2016 15:48 FCJORDA 1 EPA 200.7 01/08/2016 15:48 FCJORDA 1 EPA 200.7 01/08/2016 15:48 FCJORDA 1 EPA 200.7 01/08/2016 15:48 FCJORDA 1 EPA 200.7 01/08/2016 15:48 FCJORDA 1 EPA 200.7 01/08/2016 15:48 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: MW-10BR Collection Date: 06-Jan-16 12:30 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 6.18 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 21.1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 1.31 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 6.38 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 22.7 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 1.28 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 370 mg/L 25 Total Carbon TOC 0.902 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 13 of 87 Sample #: 2016000395 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 15:35 SLS2560 1 EPA 200.8 01/09/2016 15:35 SLS2560 1 EPA 200.8 01/09/2016 15:35 SLS2560 1 EPA 200.8 01/09/2016 15:35 SLS2560 1 EPA 200.8 01/09/2016 15:35 SLS2560 1 EPA 200.8 01/09/2016 15:35 SLS2560 1 EPA 200.8 01/09/2016 15:35 SLS2560 1 EPA 200.8 01/09/2016 15:35 SLS2560 1 EPA 200.8 01/09/2016 15:35 SLS2560 1 EPA 200.8 01/09/2016 15:35 SLS2560 1 EPA 200.8 01/09/2016 15:35 SLS2560 1 EPA 200.8 01/09/2016 15:35 SLS2560 1 EPA 200.8 01/09/2016 15:35 SLS2560 1 EPA 200.8 01/09/2016 18:02 SLS2560 1 EPA 200.8 01/09/2016 18:02 SLS2560 1 EPA 200.8 01/09/2016 18:02 SLS2560 1 EPA 200.8 01/09/2016 18:02 SLS2560 1 EPA 200.8 01/09/2016 18:02 SLS2560 1 EPA 200.8 01/09/2016 18:02 SLS2560 1 EPA 200.8 01/09/2016 18:02 SLS2560 1 EPA 200.8 01/09/2016 18:02 SLS2560 1 EPA 200.8 01/09/2016 18:02 SLS2560 1 EPA 200.8 01/09/2016 18:02 SLS2560 1 EPA 200.8 01/09/2016 18:02 SLS2560 1 EPA 200.8 01/09/2016 18:02 SLS2560 1 EPA 200.8 01/09/2016 18:02 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: MW-13BR Collection Date: 06-Jan-16 10:31 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.017 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 93 mg/L 1 Sulfate 29 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.007 mg/L 0.005 Barium (Ba) 0.354 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 4.96 mg/L 0.01 Manganese (Mn) 0.879 mg/L 0.005 Strontium (Sr) 0.411 mg/L 0.005 Zinc (Zn) 0.007 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 54.4 mg/L 0.01 Magnesium (Mg) 23.3 mg/L 0.005 Potassium (K) 5.60 mg/L 0.1 Sodium (Na) 39.8 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.041 mg/L 0.005 Barium (Ba) 0.349 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 6.08 mg/L 0.01 Manganese (Mn) 1.20 mg/L 0.005 Strontium (Sr) 0.416 mg/L 0.005 Zinc (Zn) 0.032 mg/L 0.005 Sample #: 2016000396 Matrix: GW WW Page 14 of 87 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 13:44 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/08/2016 01:22 BGN9034 10 EPA 300.0 01/08/2016 01:22 BGN9034 1 EPA 245.1 01/08/2016 14:03 ACPAYNE 1 EPA 245.1 01/09/2016 11:19 ACPAYNE 1 EPA 200.7 01/07/2016 15:24 FCJORDA 1 EPA 200.7 01/07/2016 15:24 FCJORDA 1 EPA 200.7 01/07/2016 15:24 FCJORDA 1 EPA 200.7 01/07/2016 15:24 FCJORDA 1 EPA 200.7 01/07/2016 15:24 FCJORDA 1 EPA 200.7 01/07/2016 15:24 FCJORDA 1 EPA 200.7 01/07/2016 15:24 FCJORDA 1 EPA 200.7 01/08/2016 11:48 FCJORDA 1 EPA 200.7 01/08/2016 11:48 FCJORDA 1 EPA 200.7 01/08/2016 11:48 FCJORDA 1 EPA 200.7 01/08/2016 11:48 FCJORDA 1 EPA 200.7 01/08/2016 15:52 FCJORDA 1 EPA 200.7 01/08/2016 15:52 FCJORDA 1 EPA 200.7 01/08/2016 15:52 FCJORDA 1 EPA 200.7 01/08/2016 15:52 FCJORDA 1 EPA 200.7 01/08/2016 15:52 FCJORDA 1 EPA 200.7 01/08/2016 15:52 FCJORDA 1 EPA 200.7 01/08/2016 15:52 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: MW-13BR Collection Date: 06-Jan-16 10:31 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 5.44 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1.01 ug/L 1 Nickel (Ni) 1.59 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) 1.06 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 5.31 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1.09 ug/L 1 Nickel (Ni) 1.07 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.398 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 420 mg/L 25 Total Carbon TOC 3.8 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 15 of 87 Sample #: 2016000396 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 15:40 SLS2560 1 EPA 200.8 01/09/2016 15:40 SLS2560 1 EPA 200.8 01/09/2016 15:40 SLS2560 1 EPA 200.8 01/09/2016 15:40 SLS2560 1 EPA 200.8 01/09/2016 15:40 SLS2560 1 EPA 200.8 01/09/2016 15:40 SLS2560 1 EPA 200.8 01/09/2016 15:40 SLS2560 1 EPA 200.8 01/09/2016 15:40 SLS2560 1 EPA 200.8 01/09/2016 15:40 SLS2560 1 EPA 200.8 01/09/2016 15:40 SLS2560 1 EPA 200.8 01/09/2016 15:40 SLS2560 1 EPA 200.8 01/09/2016 15:40 SLS2560 1 EPA 200.8 01/09/2016 15:40 SLS2560 1 EPA 200.8 01/09/2016 18:21 SLS2560 1 EPA 200.8 01/09/2016 18:21 SLS2560 1 EPA 200.8 01/09/2016 18:21 SLS2560 1 EPA 200.8 01/09/2016 18:21 SLS2560 1 EPA 200.8 01/09/2016 18:21 SLS2560 1 EPA 200.8 01/09/2016 18:21 SLS2560 1 EPA 200.8 01/09/2016 18:21 SLS2560 1 EPA 200.8 01/09/2016 18:21 SLS2560 1 EPA 200.8 01/09/2016 18:21 SLS2560 1 EPA 200.8 01/09/2016 18:21 SLS2560 1 EPA 200.8 01/09/2016 18:21 SLS2560 1 EPA 200.8 01/09/2016 18:21 SLS2560 1 EPA 200.8 01/09/2016 18:21 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis Page 16 of 87 This report shall not be reproduced, except in full. Order # J16010082 Site: ABMW-2BR Collection Date: 06-Jan-16 9:05 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.048 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 31 mg/L 1 Sulfate 90 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.059 mg/L 0.005 Barium (Ba) 0.210 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.074 mg/L 0.01 Manganese (Mn) 1.18 mg/L 0.005 Strontium (Sr) 0.823 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 97.2 mg/L 0.01 Magnesium (Mg) 7.73 mg/L 0.005 Potassium (K) 8.55 mg/L 0.1 Sodium (Na) 27.0 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.222 mg/L 0.005 Barium (Ba) 0.280 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.262 mg/L 0.01 Manganese (Mn) 0.868 mg/L 0.005 Strontium (Sr) 0.958 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000397 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 13:45 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/08/2016 01:40 BGN9034 10 EPA 300.0 01/08/2016 01:40 BGN9034 1 EPA 245.1 01/08/2016 14:06 ACPAYNE 1 EPA 245.1 01/09/2016 11:21 ACPAYNE 1 EPA 200.7 01/07/2016 15:30 FCJORDA 1 EPA 200.7 01/07/2016 15:30 FCJORDA 1 EPA 200.7 01/07/2016 15:30 FCJORDA 1 EPA 200.7 01/07/2016 15:30 FCJORDA 1 EPA 200.7 01/07/2016 15:30 FCJORDA 1 EPA 200.7 01/07/2016 15:30 FCJORDA 1 EPA 200.7 01/07/2016 15:30 FCJORDA 1 EPA 200.7 01/08/2016 11:53 FCJORDA 1 EPA 200.7 01/08/2016 11:53 FCJORDA 1 EPA 200.7 01/08/2016 11:53 FCJORDA 1 EPA 200.7 01/08/2016 11:53 FCJORDA 1 EPA 200.7 01/08/2016 15:56 FCJORDA 1 EPA 200.7 01/08/2016 15:56 FCJORDA 1 EPA 200.7 01/08/2016 15:56 FCJORDA 1 EPA 200.7 01/08/2016 15:56 FCJORDA 1 EPA 200.7 01/08/2016 15:56 FCJORDA 1 EPA 200.7 01/08/2016 15:56 FCJORDA 1 EPA 200.7 01/08/2016 15:56 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: ABMW-2BR Collection Date: 06-Jan-16 9:05 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 20.6 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.350 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 1.41 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 18.5 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 1.44 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 340 mg/L 25 Total Carbon TOC 1.7 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 73 mg/L 5 Page 17 of 87 Sample #: 2016000397 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 15:45 SLS2560 1 EPA 200.8 01/09/2016 15:45 SLS2560 1 EPA 200.8 01/09/2016 15:45 SLS2560 1 EPA 200.8 01/09/2016 15:45 SLS2560 1 EPA 200.8 01/09/2016 15:45 SLS2560 1 EPA 200.8 01/09/2016 15:45 SLS2560 1 EPA 200.8 01/09/2016 15:45 SLS2560 1 EPA 200.8 01/09/2016 15:45 SLS2560 1 EPA 200.8 01/09/2016 15:45 SLS2560 1 EPA 200.8 01/09/2016 15:45 SLS2560 1 EPA 200.8 01/09/2016 15:45 SLS2560 1 EPA 200.8 01/09/2016 15:45 SLS2560 1 EPA 200.8 01/09/2016 15:45 SLS2560 1 EPA 200.8 01/09/2016 18:26 SLS2560 1 EPA 200.8 01/09/2016 18:26 SLS2560 1 EPA 200.8 01/09/2016 18:26 SLS2560 1 EPA 200.8 01/09/2016 18:26 SLS2560 1 EPA 200.8 01/09/2016 18:26 SLS2560 1 EPA 200.8 01/09/2016 18:26 SLS2560 1 EPA 200.8 01/09/2016 18:26 SLS2560 1 EPA 200.8 01/09/2016 18:26 SLS2560 1 EPA 200.8 01/09/2016 18:26 SLS2560 1 EPA 200.8 01/09/2016 18:26 SLS2560 1 EPA 200.8 01/09/2016 18:26 SLS2560 1 EPA 200.8 01/09/2016 18:26 SLS2560 1 EPA 200.8 01/09/2016 18:26 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: ABMW-1 Collection Date: 06-Jan-16 10:40 AM Analyte Result Units Qualifiers RDL NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 11 mg/L 0.5 Sulfate 190 mg/L 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 2.92 mg/L 0.005 Barium (Ba) 0.186 mg/L 0.005 Boron (B) 11.4 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) 2.12 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 93.4 mg/L 0.01 Magnesium (Mg) 0.441 mg/L 0.005 Potassium (K) 12.7 mg/L 0.1 Sodium (Na) 11.1 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 2.94 mg/L 0.005 Barium (Ba) 0.192 mg/L 0.005 Boron (B) 11.4 mg/L 0.05 Iron (Fe) 0.039 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) 2.16 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000398 Matrix: GW WW Page 18 of 87 DF Method Analysis Date/Time Analyst 1 EPA 353.2 01/08/2016 13:48 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/08/2016 02:52 BGN9034 50 EPA 300.0 01/08/2016 02:52 BGN9034 1 EPA 245.1 01/08/2016 14:08 ACPAYNE 1 EPA 245.1 01/09/2016 11:24 ACPAYNE 1 EPA 200.7 01/07/2016 15:33 FCJORDA 1 EPA 200.7 01/07/2016 15:33 FCJORDA 1 EPA 200.7 01/07/2016 15:33 FCJORDA 1 EPA 200.7 01/07/2016 15:33 FCJORDA 1 EPA 200.7 01/07/2016 15:33 FCJORDA 1 EPA 200.7 01/07/2016 15:33 FCJORDA 1 EPA 200.7 01/07/2016 15:33 FCJORDA 1 EPA 200.7 01/08/2016 11:57 FCJORDA 1 EPA 200.7 01/08/2016 11:57 FCJORDA 1 EPA 200.7 01/08/2016 11:57 FCJORDA 1 EPA 200.7 01/08/2016 11:57 FCJORDA 1 EPA 200.7 01/08/2016 16:00 FCJORDA 1 EPA 200.7 01/08/2016 16:00 FCJORDA 1 EPA 200.7 01/08/2016 16:00 FCJORDA 1 EPA 200.7 01/08/2016 16:00 FCJORDA 1 EPA 200.7 01/08/2016 16:00 FCJORDA 1 EPA 200.7 01/08/2016 16:00 FCJORDA 1 EPA 200.7 01/08/2016 16:00 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: ABMW-1 Collection Date: 06-Jan-16 10:40 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) 4.50 ug/L 1 Arsenic (As) 699 ug/L 10 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 2340 ug/L 10 Nickel (Ni) 3.23 ug/L 1 Selenium (Se) 7.53 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 5.68 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) 4.65 ug/L 1 Arsenic (As) 658 ug/L 10 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 2230 ug/L 10 Nickel (Ni) 3.28 ug/L 1 Selenium (Se) 7.99 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 6.93 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 420 mg/L 25 Total Carbon TOC 9.3 mg/L 0.5 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 19 of 87 Sample #: 2016000398 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 15:50 SLS2560 10 EPA 200.8 01/09/2016 15:50 SLS2560 1 EPA 200.8 01/09/2016 15:50 SLS2560 1 EPA 200.8 01/09/2016 15:50 SLS2560 1 EPA 200.8 01/09/2016 15:50 SLS2560 1 EPA 200.8 01/09/2016 15:50 SLS2560 1 EPA 200.8 01/09/2016 15:50 SLS2560 1 EPA 200.8 01/09/2016 15:50 SLS2560 10 EPA 200.8 01/09/2016 15:50 SLS2560 1 EPA 200.8 01/09/2016 15:50 SLS2560 1 EPA 200.8 01/09/2016 15:50 SLS2560 1 EPA 200.8 01/09/2016 15:50 SLS2560 1 EPA 200.8 01/09/2016 15:50 SLS2560 1 EPA 200.8 01/09/2016 18:31 SLS2560 10 EPA 200.8 01/09/2016 18:31 SLS2560 1 EPA 200.8 01/09/2016 18:31 SLS2560 1 EPA 200.8 01/09/2016 18:31 SLS2560 1 EPA 200.8 01/09/2016 18:31 SLS2560 1 EPA 200.8 01/09/2016 18:31 SLS2560 1 EPA 200.8 01/09/2016 18:31 SLS2560 1 EPA 200.8 01/09/2016 18:31 SLS2560 10 EPA 200.8 01/09/2016 18:31 SLS2560 1 EPA 200.8 01/09/2016 18:31 SLS2560 1 EPA 200.8 01/09/2016 18:31 SLS2560 1 EPA 200.8 01/09/2016 18:31 SLS2560 1 EPA 200.8 01/09/2016 18:31 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 5 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: ABMW-1 BR Collection Date: 06-Jan-16 11:45 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 14 mg/L 0.5 Sulfate 20 mg/L 0.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.029 mg/L 0.005 Boron (B) 0.286 mg/L 0.05 Iron (Fe) 1.58 mg/L 0.01 Manganese (Mn) 0.943 mg/L 0.005 Strontium (Sr) 0.171 mg/L 0.005 Zinc (Zn) 0.028 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 60.7 mg/L 0.01 Magnesium (Mg) 16.3 mg/L 0.005 Potassium (K) 5.78 mg/L 0.1 Sodium (Na) 17.7 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.039 mg/L 0.005 Barium (Ba) 0.032 mg/L 0.005 Boron (B) 0.255 mg/L 0.05 Iron (Fe) 1.74 mg/L 0.01 Manganese (Mn) 0.944 mg/L 0.005 Strontium (Sr) 0.176 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000399 Matrix: GW WW Page 20 of 87 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 13:50 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/08/2016 02:16 BGN9034 5 EPA 300.0 01/08/2016 02:16 BGN9034 1 EPA 245.1 01/08/2016 14:10 ACPAYNE 1 EPA 245.1 01/09/2016 11:26 ACPAYNE 1 EPA 200.7 01/07/2016 15:37 FCJORDA 1 EPA 200.7 01/07/2016 15:37 FCJORDA 1 EPA 200.7 01/07/2016 15:37 FCJORDA 1 EPA 200.7 01/07/2016 15:37 FCJORDA 1 EPA 200.7 01/07/2016 15:37 FCJORDA 1 EPA 200.7 01/07/2016 15:37 FCJORDA 1 EPA 200.7 01/07/2016 15:37 FCJORDA 1 EPA 200.7 01/08/2016 12:01 FCJORDA 1 EPA 200.7 01/08/2016 12:01 FCJORDA 1 EPA 200.7 01/08/2016 12:01 FCJORDA 1 EPA 200.7 01/08/2016 12:01 FCJORDA 1 EPA 200.7 01/08/2016 16:04 FCJORDA 1 EPA 200.7 01/08/2016 16:04 FCJORDA 1 EPA 200.7 01/08/2016 16:04 FCJORDA 1 EPA 200.7 01/08/2016 16:04 FCJORDA 1 EPA 200.7 01/08/2016 16:04 FCJORDA 1 EPA 200.7 01/08/2016 16:04 FCJORDA 1 EPA 200.7 01/08/2016 16:04 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: ABMW-1 BR Collection Date: 06-Jan-16 11:45 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.56 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 3.46 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.12 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 4.16 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.346 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 350 mg/L 25 Total Carbon TOC 0.377 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 7.0 mg/L 5 Page 21 of 87 Sample #: 2016000399 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 15:54 SLS2560 1 EPA 200.8 01/09/2016 15:54 SLS2560 1 EPA 200.8 01/09/2016 15:54 SLS2560 1 EPA 200.8 01/09/2016 15:54 SLS2560 1 EPA 200.8 01/09/2016 15:54 SLS2560 1 EPA 200.8 01/09/2016 15:54 SLS2560 1 EPA 200.8 01/09/2016 15:54 SLS2560 1 EPA 200.8 01/09/2016 15:54 SLS2560 1 EPA 200.8 01/09/2016 15:54 SLS2560 1 EPA 200.8 01/09/2016 15:54 SLS2560 1 EPA 200.8 01/09/2016 15:54 SLS2560 1 EPA 200.8 01/09/2016 15:54 SLS2560 1 EPA 200.8 01/09/2016 15:54 SLS2560 1 EPA 200.8 01/09/2016 18:36 SLS2560 1 EPA 200.8 01/09/2016 18:36 SLS2560 1 EPA 200.8 01/09/2016 18:36 SLS2560 1 EPA 200.8 01/09/2016 18:36 SLS2560 1 EPA 200.8 01/09/2016 18:36 SLS2560 1 EPA 200.8 01/09/2016 18:36 SLS2560 1 EPA 200.8 01/09/2016 18:36 SLS2560 1 EPA 200.8 01/09/2016 18:36 SLS2560 1 EPA 200.8 01/09/2016 18:36 SLS2560 1 EPA 200.8 01/09/2016 18:36 SLS2560 1 EPA 200.8 01/09/2016 18:36 SLS2560 1 EPA 200.8 01/09/2016 18:36 SLS2560 1 EPA 200.8 01/09/2016 18:36 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis Page 22 of 87 This report shall not be reproduced, except in full. Order # J16010082 Site: ABMW-4 Collection Date: 06-Jan-16 3:45 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.015 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 76 mg/L 1 Sulfate 2100 mg/L 50 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.052 mg/L 0.005 Barium (Ba) 0.041 mg/L 0.005 Boron (B) 39.5 mg/L 0.5 Iron (Fe) 44.6 mg/L 0.01 Manganese (Mn) 6.80 mg/L 0.005 Strontium (Sr) 9.34 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 502 mg/L 0.1 Magnesium (Mg) 199 mg/L 0.05 Potassium (K) 127 mg/L 1 Sodium (Na) 205 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.102 mg/L 0.005 Barium (Ba) 0.043 mg/L 0.005 Boron (B) 38.6 mg/L 0.5 Iron (Fe) 51.7 mg/L 0.1 Manganese (Mn) 7.27 mg/L 0.005 Strontium (Sr) 9.30 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000400 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 13:51 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/08/2016 03:10 BGN9034 500 EPA 300.0 01/08/2016 03:10 BGN9034 1 EPA 245.1 01/08/2016 14:13 ACPAYNE 1 EPA 245.1 01/09/2016 11:29 ACPAYNE 1 EPA 200.7 01/07/2016 15:41 FCJORDA 1 EPA 200.7 01/07/2016 15:41 FCJORDA 10 EPA 200.7 01/07/2016 15:41 FCJORDA 1 EPA 200.7 01/07/2016 15:41 FCJORDA 1 EPA 200.7 01/07/2016 15:41 FCJORDA 1 EPA 200.7 01/07/2016 15:41 FCJORDA 1 EPA 200.7 01/07/2016 15:41 FCJORDA 10 EPA 200.7 01/08/2016 12:14 FCJORDA 10 EPA 200.7 01/08/2016 12:14 FCJORDA 10 EPA 200.7 01/08/2016 12:14 FCJORDA 10 EPA 200.7 01/08/2016 12:14 FCJORDA 1 EPA 200.7 01/08/2016 17:14 FCJORDA 1 EPA 200.7 01/08/2016 17:14 FCJORDA 10 EPA 200.7 01/08/2016 17:14 FCJORDA 10 EPA 200.7 01/08/2016 17:14 FCJORDA 1 EPA 200.7 01/08/2016 17:14 FCJORDA 1 EPA 200.7 01/08/2016 17:14 FCJORDA 1 EPA 200.7 01/08/2016 17:14 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: ABMW-4 Collection Date: 06-Jan-16 3:45 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) 928 ug/L 10 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 2.42 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 495 ug/L 1 Nickel (Ni) 1.45 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.940 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) 1160 ug/L M4 10 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 2.23 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 466 ug/L M4 1 Nickel (Ni) 1.18 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L M2 0.2 Vanadium (V) Low Level 1.07 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 3300 mg/L 50 Total Carbon TOC 1.3 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 100 mg/L 5 Page 23 of 87 Sample #: 2016000400 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 16:29 SLS2560 10 EPA 200.8 01/09/2016 16:29 SLS2560 1 EPA 200.8 01/09/2016 16:29 SLS2560 1 EPA 200.8 01/09/2016 16:29 SLS2560 1 EPA 200.8 01/09/2016 16:29 SLS2560 1 EPA 200.8 01/09/2016 16:29 SLS2560 1 EPA 200.8 01/09/2016 16:29 SLS2560 1 EPA 200.8 01/09/2016 16:29 SLS2560 1 EPA 200.8 01/09/2016 16:29 SLS2560 1 EPA 200.8 01/09/2016 16:29 SLS2560 1 EPA 200.8 01/09/2016 16:29 SLS2560 1 EPA 200.8 01/09/2016 16:29 SLS2560 1 EPA 200.8 01/09/2016 16:29 SLS2560 1 EPA 200.8 01/09/2016 18:45 SLS2560 10 EPA 200.8 01/09/2016 18:45 SLS2560 1 EPA 200.8 01/09/2016 18:45 SLS2560 1 EPA 200.8 01/09/2016 18:45 SLS2560 1 EPA 200.8 01/09/2016 18:45 SLS2560 1 EPA 200.8 01/09/2016 18:45 SLS2560 1 EPA 200.8 01/09/2016 18:45 SLS2560 1 EPA 200.8 01/09/2016 18:45 SLS2560 1 EPA 200.8 01/09/2016 18:45 SLS2560 1 EPA 200.8 01/09/2016 18:45 SLS2560 1 EPA 200.8 01/09/2016 18:45 SLS2560 1 EPA 200.8 01/09/2016 18:45 SLS2560 1 EPA 200.8 01/09/2016 18:45 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis Page 24 of 87 This report shall not be reproduced, except in full. Order # J16010082 Site: ABMW-6BR Collection Date: 06-Jan-16 2:35 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.925 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 9.8 mg/L 0.2 Sulfate 58 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.155 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.323 mg/L 0.01 Manganese (Mn) 2.69 mg/L 0.005 Strontium (Sr) 0.210 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 67.1 mg/L 0.01 Magnesium (Mg) 19.9 mg/L 0.005 Potassium (K) 6.08 mg/L 0.1 Sodium (Na) 19.4 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.020 mg/L 0.005 Barium (Ba) 0.061 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.167 mg/L 0.01 Manganese (Mn) 1.71 mg/L 0.005 Strontium (Sr) 0.208 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000401 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 13:52 LSTARL1 Vendor Method V_PACE 2 EPA 300.0 01/08/2016 13:58 BGN9034 10 EPA 300.0 01/08/2016 13:58 BGN9034 1 EPA 245.1 01/08/2016 14:15 ACPAYNE 1 EPA 245.1 01/09/2016 11:31 ACPAYNE 1 EPA 200.7 01/07/2016 16:12 FCJORDA 1 EPA 200.7 01/07/2016 16:12 FCJORDA 1 EPA 200.7 01/07/2016 16:12 FCJORDA 1 EPA 200.7 01/07/2016 16:12 FCJORDA 1 EPA 200.7 01/07/2016 16:12 FCJORDA 1 EPA 200.7 01/07/2016 16:12 FCJORDA 1 EPA 200.7 01/07/2016 16:12 FCJORDA 1 EPA 200.7 01/08/2016 12:26 FCJORDA 1 EPA 200.7 01/08/2016 12:26 FCJORDA 1 EPA 200.7 01/08/2016 12:26 FCJORDA 1 EPA 200.7 01/08/2016 12:26 FCJORDA 1 EPA 200.7 01/08/2016 16:23 FCJORDA 1 EPA 200.7 01/08/2016 16:23 FCJORDA 1 EPA 200.7 01/08/2016 16:23 FCJORDA 1 EPA 200.7 01/08/2016 16:23 FCJORDA 1 EPA 200.7 01/08/2016 16:23 FCJORDA 1 EPA 200.7 01/08/2016 16:23 FCJORDA 1 EPA 200.7 01/08/2016 16:23 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: ABMW-6BR Collection Date: 06-Jan-16 2:35 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L M1 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.17 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 5.29 ug/L 1 Nickel (Ni) 2.91 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 3.18 ug/L 1 Nickel (Ni) 3.33 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.308 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 400 mg/L 25 Total Carbon TOC 0.684 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 25 of 87 Sample #: 2016000401 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 16:34 SLS2560 1 EPA 200.8 01/09/2016 16:34 SLS2560 1 EPA 200.8 01/09/2016 16:34 SLS2560 1 EPA 200.8 01/09/2016 16:34 SLS2560 1 EPA 200.8 01/09/2016 16:34 SLS2560 1 EPA 200.8 01/09/2016 16:34 SLS2560 1 EPA 200.8 01/09/2016 16:34 SLS2560 1 EPA 200.8 01/09/2016 16:34 SLS2560 1 EPA 200.8 01/09/2016 16:34 SLS2560 1 EPA 200.8 01/09/2016 16:34 SLS2560 1 EPA 200.8 01/09/2016 16:34 SLS2560 1 EPA 200.8 01/09/2016 16:34 SLS2560 1 EPA 200.8 01/09/2016 16:34 SLS2560 1 EPA 200.8 01/09/2016 18:41 SLS2560 1 EPA 200.8 01/09/2016 18:41 SLS2560 1 EPA 200.8 01/09/2016 18:41 SLS2560 1 EPA 200.8 01/09/2016 18:41 SLS2560 1 EPA 200.8 01/09/2016 18:41 SLS2560 1 EPA 200.8 01/09/2016 18:41 SLS2560 1 EPA 200.8 01/09/2016 18:41 SLS2560 1 EPA 200.8 01/09/2016 18:41 SLS2560 1 EPA 200.8 01/09/2016 18:41 SLS2560 1 EPA 200.8 01/09/2016 18:41 SLS2560 1 EPA 200.8 01/09/2016 18:41 SLS2560 1 EPA 200.8 01/09/2016 18:41 SLS2560 1 EPA 200.8 01/09/2016 18:41 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis Page 26 of 87 This report shall not be reproduced, except in full. Order # J16010082 Site: ABMW-5D Collection Date: 06-Jan-16 4:30 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.014 mg-N/L M2 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 11 mg/L 0.2 Sulfate < 0.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.026 mg/L 0.005 Barium (Ba) 0.127 mg/L 0.005 Boron (B) 2.16 mg/L 0.05 Iron (Fe) 25.2 mg/L 0.01 Manganese (Mn) 5.38 mg/L 0.005 Strontium (Sr) 0.420 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 37.4 mg/L 0.01 Magnesium (Mg) 12.3 mg/L 0.005 Potassium (K) 9.67 mg/L 0.1 Sodium (Na) 12.5 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.122 mg/L 0.005 Barium (Ba) 0.147 mg/L 0.005 Boron (B) 2.16 mg/L 0.05 Iron (Fe) 30.0 mg/L 0.01 Manganese (Mn) 5.69 mg/L 0.005 Strontium (Sr) 0.464 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000402 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 13:59 LSTARL1 Vendor Method V_PACE 2 EPA 300.0 01/08/2016 13:40 BGN9034 1 EPA 300.0 01/08/2016 13:40 BGN9034 1 EPA 245.1 01/08/2016 14:17 ACPAYNE 1 EPA 245.1 01/09/2016 11:33 ACPAYNE 1 EPA 200.7 01/07/2016 16:15 FCJORDA 1 EPA 200.7 01/07/2016 16:15 FCJORDA 1 EPA 200.7 01/07/2016 16:15 FCJORDA 1 EPA 200.7 01/07/2016 16:15 FCJORDA 1 EPA 200.7 01/07/2016 16:15 FCJORDA 1 EPA 200.7 01/07/2016 16:15 FCJORDA 1 EPA 200.7 01/07/2016 16:15 FCJORDA 1 EPA 200.7 01/08/2016 12:31 FCJORDA 1 EPA 200.7 01/08/2016 12:31 FCJORDA 1 EPA 200.7 01/08/2016 12:31 FCJORDA 1 EPA 200.7 01/08/2016 12:31 FCJORDA 1 EPA 200.7 01/08/2016 16:35 FCJORDA 1 EPA 200.7 01/08/2016 16:35 FCJORDA 1 EPA 200.7 01/08/2016 16:35 FCJORDA 1 EPA 200.7 01/08/2016 16:35 FCJORDA 1 EPA 200.7 01/08/2016 16:35 FCJORDA 1 EPA 200.7 01/08/2016 16:35 FCJORDA 1 EPA 200.7 01/08/2016 16:35 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: ABMW-5D Collection Date: 06-Jan-16 4:30 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) 2.36 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 16.9 ug/L 1 Nickel (Ni) 1.96 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) 1.24 ug/L 1 Arsenic (As) 2.69 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 1.03 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 15.8 ug/L 1 Nickel (Ni) 2.06 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.556 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 220 mg/L 25 Total Carbon TOC 6.9 mg/L 0.5 TOTAL SUSPENDED SOLIDS TSS 70 mg/L 5 Page 27 of 87 Sample #: 2016000402 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 14:39 SLS2560 1 EPA 200.8 01/09/2016 14:39 SLS2560 1 EPA 200.8 01/09/2016 14:39 SLS2560 1 EPA 200.8 01/09/2016 14:39 SLS2560 1 EPA 200.8 01/09/2016 14:39 SLS2560 1 EPA 200.8 01/09/2016 14:39 SLS2560 1 EPA 200.8 01/09/2016 14:39 SLS2560 1 EPA 200.8 01/09/2016 14:39 SLS2560 1 EPA 200.8 01/09/2016 14:39 SLS2560 1 EPA 200.8 01/09/2016 14:39 SLS2560 1 EPA 200.8 01/09/2016 14:39 SLS2560 1 EPA 200.8 01/09/2016 14:39 SLS2560 1 EPA 200.8 01/09/2016 14:39 SLS2560 1 EPA 200.8 01/11/2016 13:13 SLS2560 1 EPA 200.8 01/11/2016 13:13 SLS2560 1 EPA 200.8 01/11/2016 13:13 SLS2560 1 EPA 200.8 01/11/2016 13:13 SLS2560 1 EPA 200.8 01/11/2016 13:13 SLS2560 1 EPA 200.8 01/11/2016 13:13 SLS2560 1 EPA 200.8 01/11/2016 13:13 SLS2560 1 EPA 200.8 01/11/2016 13:13 SLS2560 1 EPA 200.8 01/11/2016 13:13 SLS2560 1 EPA 200.8 01/11/2016 13:13 SLS2560 1 EPA 200.8 01/11/2016 13:13 SLS2560 1 EPA 200.8 01/11/2016 13:13 SLS2560 1 EPA 200.8 01/11/2016 13:13 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 5 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: ABMW-05 Collection Date: 06-Jan-16 1:30 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 58 mg/L 2 Sulfate 1200 mg/L 20 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.063 mg/L 0.005 Boron (B) 19.8 mg/L 0.05 Iron (Fe) 1.67 mg/L 0.01 Manganese (Mn) 0.970 mg/L 0.005 Strontium (Sr) 4.22 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 321 mg/L 0.1 Magnesium (Mg) 78.0 mg/L 0.005 Potassium (K) 83.2 mg/L 1 Sodium (Na) 96.8 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.046 mg/L 0.005 Barium (Ba) 0.071 mg/L 0.005 Boron (B) 19.9 mg/L 0.05 Iron (Fe) 1.62 mg/L 0.01 Manganese (Mn) 1.11 mg/L 0.005 Strontium (Sr) 4.36 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Page 28 of 87 Sample #: 2016000403 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 14:03 LSTARL1 Vendor Method V_PACE 20 EPA 300.0 01/08/2016 14:16 BGN9034 200 EPA 300.0 01/08/2016 14:16 BGN9034 1 EPA 245.1 01/08/2016 14:20 ACPAYNE 1 EPA 245.1 01/09/2016 11:36 ACPAYNE 1 EPA 200.7 01/07/2016 16:19 FCJORDA 1 EPA 200.7 01/07/2016 16:19 FCJORDA 1 EPA 200.7 01/07/2016 16:19 FCJORDA 1 EPA 200.7 01/07/2016 16:19 FCJORDA 1 EPA 200.7 01/07/2016 16:19 FCJORDA 1 EPA 200.7 01/07/2016 16:19 FCJORDA 1 EPA 200.7 01/07/2016 16:19 FCJORDA 10 EPA 200.7 01/08/2016 12:35 FCJORDA 1 EPA 200.7 01/08/2016 12:35 FCJORDA 10 EPA 200.7 01/08/2016 12:35 FCJORDA 10 EPA 200.7 01/08/2016 12:35 FCJORDA 1 EPA 200.7 01/08/2016 16:39 FCJORDA 1 EPA 200.7 01/08/2016 16:39 FCJORDA 1 EPA 200.7 01/08/2016 16:39 FCJORDA 1 EPA 200.7 01/08/2016 16:39 FCJORDA 1 EPA 200.7 01/08/2016 16:39 FCJORDA 1 EPA 200.7 01/08/2016 16:39 FCJORDA 1 EPA 200.7 01/08/2016 16:39 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: ABMW-05 Collection Date: 06-Jan-16 1:30 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) 231 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.05 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1080 ug/L 10 Nickel (Ni) 1.39 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) 214 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.08 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1200 ug/L 10 Nickel (Ni) 1.41 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.371 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 2000 mg/L 50 Total Carbon TOC 0.641 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 5.0 mg/L 5 Page 29 of 87 Sample #: 2016000403 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 16:39 SLS2560 1 EPA 200.8 01/09/2016 16:39 SLS2560 1 EPA 200.8 01/09/2016 16:39 SLS2560 1 EPA 200.8 01/09/2016 16:39 SLS2560 1 EPA 200.8 01/09/2016 16:39 SLS2560 1 EPA 200.8 01/09/2016 16:39 SLS2560 1 EPA 200.8 01/09/2016 16:39 SLS2560 1 EPA 200.8 01/09/2016 16:39 SLS2560 10 EPA 200.8 01/09/2016 16:39 SLS2560 1 EPA 200.8 01/09/2016 16:39 SLS2560 1 EPA 200.8 01/09/2016 16:39 SLS2560 1 EPA 200.8 01/09/2016 16:39 SLS2560 1 EPA 200.8 01/09/2016 16:39 SLS2560 1 EPA 200.8 01/11/2016 13:18 SLS2560 1 EPA 200.8 01/11/2016 13:18 SLS2560 1 EPA 200.8 01/11/2016 13:18 SLS2560 1 EPA 200.8 01/11/2016 13:18 SLS2560 1 EPA 200.8 01/11/2016 13:18 SLS2560 1 EPA 200.8 01/11/2016 13:18 SLS2560 1 EPA 200.8 01/11/2016 13:18 SLS2560 1 EPA 200.8 01/11/2016 13:18 SLS2560 10 EPA 200.8 01/11/2016 13:18 SLS2560 1 EPA 200.8 01/11/2016 13:18 SLS2560 1 EPA 200.8 01/11/2016 13:18 SLS2560 1 EPA 200.8 01/11/2016 13:18 SLS2560 1 EPA 200.8 01/11/2016 13:18 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: MW-1 BR Collection Date: 06-Jan-16 10:30 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.045 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 40 mg/L 1 Sulfate 47 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.529 mg/L 0.005 Boron (B) 0.732 mg/L 0.05 Iron (Fe) 0.041 mg/L 0.01 Manganese (Mn) 1.06 mg/L 0.005 Strontium (Sr) 0.479 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 75.4 mg/L 0.01 Magnesium (Mg) 40.2 mg/L 0.005 Potassium (K) 9.49 mg/L 0.1 Sodium (Na) 54.0 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.108 mg/L 0.005 Barium (Ba) 0.543 mg/L 0.005 Boron (B) 0.589 mg/L 0.05 Iron (Fe) 0.234 mg/L 0.01 Manganese (Mn) 1.82 mg/L 0.005 Strontium (Sr) 0.487 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 Sample #: 2016000404 Matrix: GW WW Page 30 of 87 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 14:04 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/08/2016 11:00 BGN9034 10 EPA 300.0 01/08/2016 11:00 BGN9034 1 EPA 245.1 01/08/2016 14:22 ACPAYNE 1 EPA 245.1 01/09/2016 11:38 ACPAYNE 1 EPA 200.7 01/07/2016 16:23 FCJORDA 1 EPA 200.7 01/07/2016 16:23 FCJORDA 1 EPA 200.7 01/07/2016 16:23 FCJORDA 1 EPA 200.7 01/07/2016 16:23 FCJORDA 1 EPA 200.7 01/07/2016 16:23 FCJORDA 1 EPA 200.7 01/07/2016 16:23 FCJORDA 1 EPA 200.7 01/07/2016 16:23 FCJORDA 1 EPA 200.7 01/08/2016 12:39 FCJORDA 1 EPA 200.7 01/08/2016 12:39 FCJORDA 1 EPA 200.7 01/08/2016 12:39 FCJORDA 1 EPA 200.7 01/08/2016 12:39 FCJORDA 1 EPA 200.7 01/08/2016 16:43 FCJORDA 1 EPA 200.7 01/08/2016 16:43 FCJORDA 1 EPA 200.7 01/08/2016 16:43 FCJORDA 1 EPA 200.7 01/08/2016 16:43 FCJORDA 1 EPA 200.7 01/08/2016 16:43 FCJORDA 1 EPA 200.7 01/08/2016 16:43 FCJORDA 1 EPA 200.7 01/08/2016 16:43 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: MW-1 BR Collection Date: 06-Jan-16 10:30 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 2.45 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1.14 ug/L 1 Nickel (Ni) 5.50 ug/L 1 Selenium (Se) 1.80 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 15.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 3.37 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 9.72 ug/L 1 Selenium (Se) 1.03 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 8.41 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 580 mg/L 25 Total Carbon TOC 1.8 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 31 of 87 Sample #: 2016000404 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 16:43 SLS2560 1 EPA 200.8 01/09/2016 16:43 SLS2560 1 EPA 200.8 01/09/2016 16:43 SLS2560 1 EPA 200.8 01/09/2016 16:43 SLS2560 1 EPA 200.8 01/09/2016 16:43 SLS2560 1 EPA 200.8 01/09/2016 16:43 SLS2560 1 EPA 200.8 01/09/2016 16:43 SLS2560 1 EPA 200.8 01/09/2016 16:43 SLS2560 1 EPA 200.8 01/09/2016 16:43 SLS2560 1 EPA 200.8 01/09/2016 16:43 SLS2560 1 EPA 200.8 01/09/2016 16:43 SLS2560 1 EPA 200.8 01/09/2016 16:43 SLS2560 1 EPA 200.8 01/09/2016 16:43 SLS2560 1 EPA 200.8 01/09/2016 19:25 SLS2560 1 EPA 200.8 01/09/2016 19:25 SLS2560 1 EPA 200.8 01/09/2016 19:25 SLS2560 1 EPA 200.8 01/09/2016 19:25 SLS2560 1 EPA 200.8 01/09/2016 19:25 SLS2560 1 EPA 200.8 01/09/2016 19:25 SLS2560 1 EPA 200.8 01/09/2016 19:25 SLS2560 1 EPA 200.8 01/09/2016 19:25 SLS2560 1 EPA 200.8 01/09/2016 19:25 SLS2560 1 EPA 200.8 01/09/2016 19:25 SLS2560 1 EPA 200.8 01/09/2016 19:25 SLS2560 1 EPA 200.8 01/09/2016 19:25 SLS2560 1 EPA 200.8 01/09/2016 19:25 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: Filter Blank Collection Date: 06-Jan-16 10:30 AM Analyte Result Units Qualifiers RDL Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2016000405 Matrix: GW WW Page 32 of 87 DF Method Analysis Date/Time Analyst 1 EPA 245.1 01/09/2016 11:57 ACPAYNE 1 EPA 200.7 01/07/2016 16:27 FCJORDA 1 EPA 200.7 01/07/2016 16:27 FCJORDA 1 EPA 200.7 01/07/2016 16:27 FCJORDA 1 EPA 200.7 01/07/2016 16:27 FCJORDA 1 EPA 200.7 01/07/2016 16:27 FCJORDA 1 EPA 200.7 01/07/2016 16:27 FCJORDA 1 EPA 200.7 01/07/2016 16:27 FCJORDA 1 EPA 200.8 01/09/2016 16:48 SLS2560 1 EPA 200.8 01/09/2016 16:48 SLS2560 1 EPA 200.8 01/09/2016 16:48 SLS2560 1 EPA 200.8 01/09/2016 16:48 SLS2560 1 EPA 200.8 01/09/2016 16:48 SLS2560 1 EPA 200.8 01/09/2016 16:48 SLS2560 1 EPA 200.8 01/09/2016 16:48 SLS2560 1 EPA 200.8 01/09/2016 16:48 SLS2560 1 EPA 200.8 01/09/2016 16:48 SLS2560 1 EPA 200.8 01/09/2016 16:48 SLS2560 1 EPA 200.8 01/09/2016 16:48 SLS2560 1 EPA 200.8 01/09/2016 16:48 SLS2560 1 EPA 200.8 01/09/2016 16:48 SLS2560 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: EQUIP BLANK Collection Date: 06-Jan-16 10:30 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride < 0.1 mg/L 0.1 Sulfate < 0.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 UNDIGESTED METALS BY ICP Calcium (Ca) 0.036 mg/L 0.01 Magnesium (Mg) 0.013 mg/L 0.005 Potassium (K) < 0.1 mg/L 0.1 Sodium (Na) < 0.05 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Page 33 of 87 Sample #: 2016000406 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 14:05 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/08/2016 10:42 BGN9034 1 EPA 300.0 01/08/2016 10:42 BGN9034 1 EPA 245.1 01/08/2016 14:41 ACPAYNE 1 EPA 200.7 01/08/2016 12:43 FCJORDA 1 EPA 200.7 01/08/2016 12:43 FCJORDA 1 EPA 200.7 01/08/2016 12:43 FCJORDA 1 EPA 200.7 01/08/2016 12:43 FCJORDA 1 EPA 200.7 01/08/2016 16:46 FCJORDA 1 EPA 200.7 01/08/2016 16:46 FCJORDA 1 EPA 200.7 01/08/2016 16:46 FCJORDA 1 EPA 200.7 01/08/2016 16:46 FCJORDA 1 EPA 200.7 01/08/2016 16:46 FCJORDA 1 EPA 200.7 01/08/2016 16:46 FCJORDA 1 EPA 200.7 01/08/2016 16:46 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: EQUIP BLANK Collection Date: 06-Jan-16 10:30 AM Analyte Result Units Qualifiers RDL DF TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 Arsenic (As) < 1 ug/L 1 1 Beryllium (Be) < 1 ug/L 1 1 Cadmium (Cd) < 1 ug/L 1 1 Chromium (Cr) < 1 ug/L 1 1 Cobalt (Co) < 1 ug/L 1 1 Copper (Cu) < 1 ug/L 1 1 Lead (Pb) < 1 ug/L 1 1 Molybdenum (Mo) < 1 ug/L 1 1 Nickel (Ni) < 1 ug/L 1 1 Selenium (Se) < 1 ug/L 1 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 Vanadium (V) Low Level < 0.3 ug/L 0.3 1 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 Total Carbon Page 34 of 87 Sample #: 2016000406 Matrix: GW WW Method Analysis Date/Time Analyst EPA 200.8 01/09/2016 19:29 SLS2560 EPA 200.8 01/09/2016 19:29 SLS2560 EPA 200.8 01/09/2016 19:29 SLS2560 EPA 200.8 01/09/2016 19:29 SLS2560 EPA 200.8 01/09/2016 19:29 SLS2560 EPA 200.8 01/09/2016 19:29 SLS2560 EPA 200.8 01/09/2016 19:29 SLS2560 EPA 200.8 01/09/2016 19:29 SLS2560 EPA 200.8 01/09/2016 19:29 SLS2560 EPA 200.8 01/09/2016 19:29 SLS2560 EPA 200.8 01/09/2016 19:29 SLS2560 EPA 200.8 01/09/2016 19:29 SLS2560 EPA 200.8 01/09/2016 19:29 SLS2560 Vendor Method V_PACE Vendor Method V_PACE SM2540C 01/09/201615:30 CJELLIO TOC 0.227 mg/L 0.1 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 01/09/2016 10:01 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: CW-1 Collection Date: 06-Jan-16 11:50 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.023 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 10 mg/L 0.5 Sulfate 170 mg/L 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.005 mg/L 0.005 Barium (Ba) 0.071 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 1.20 mg/L 0.01 Manganese (Mn) 0.137 mg/L 0.005 Strontium (Sr) 0.284 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 27.6 mg/L 0.01 Magnesium (Mg) 12.3 mg/L 0.005 Potassium (K) 2.76 mg/L 0.1 Sodium (Na) 71.8 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.061 mg/L 0.005 Barium (Ba) 0.082 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 1.40 mg/L 0.01 Manganese (Mn) 0.153 mg/L 0.005 Strontium (Sr) 0.303 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000407 Matrix: GW WW Page 35 of 87 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 14:09 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/08/2016 14:34 BGN9034 50 EPA 300.0 01/08/2016 14:34 BGN9034 1 EPA 245.1 01/08/2016 14:43 ACPAYNE 1 EPA 245.1 01/09/2016 11:59 ACPAYNE 1 EPA 200.7 01/07/2016 16:30 FCJORDA 1 EPA 200.7 01/07/2016 16:30 FCJORDA 1 EPA 200.7 01/07/2016 16:30 FCJORDA 1 EPA 200.7 01/07/2016 16:30 FCJORDA 1 EPA 200.7 01/07/2016 16:30 FCJORDA 1 EPA 200.7 01/07/2016 16:30 FCJORDA 1 EPA 200.7 01/07/2016 16:30 FCJORDA 1 EPA 200.7 01/08/2016 12:47 FCJORDA 1 EPA 200.7 01/08/2016 12:47 FCJORDA 1 EPA 200.7 01/08/2016 12:47 FCJORDA 1 EPA 200.7 01/08/2016 12:47 FCJORDA 1 EPA 200.7 01/08/2016 16:50 FCJORDA 1 EPA 200.7 01/08/2016 16:50 FCJORDA 1 EPA 200.7 01/08/2016 16:50 FCJORDA 1 EPA 200.7 01/08/2016 16:50 FCJORDA 1 EPA 200.7 01/08/2016 16:50 FCJORDA 1 EPA 200.7 01/08/2016 16:50 FCJORDA 1 EPA 200.7 01/08/2016 16:50 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: CW-1 Collection Date: 06-Jan-16 11:50 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.12 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L M2 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 13.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.29 ug/L 1 Copper (Cu) 1.62 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 14.8 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 430 mg/L 25 Total Carbon TOC 3.0 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 36 of 87 Sample #: 2016000407 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 16:14 SLS2560 1 EPA 200.8 01/09/2016 16:14 SLS2560 1 EPA 200.8 01/09/2016 16:14 SLS2560 1 EPA 200.8 01/09/2016 16:14 SLS2560 1 EPA 200.8 01/09/2016 16:14 SLS2560 1 EPA 200.8 01/09/2016 16:14 SLS2560 1 EPA 200.8 01/09/2016 16:14 SLS2560 1 EPA 200.8 01/09/2016 16:14 SLS2560 1 EPA 200.8 01/09/2016 16:14 SLS2560 1 EPA 200.8 01/09/2016 16:14 SLS2560 1 EPA 200.8 01/09/2016 16:14 SLS2560 1 EPA 200.8 01/09/2016 16:14 SLS2560 1 EPA 200.8 01/09/2016 16:14 SLS2560 1 EPA 200.8 01/09/2016 19:34 SLS2560 1 EPA 200.8 01/09/2016 19:34 SLS2560 1 EPA 200.8 01/09/2016 19:34 SLS2560 1 EPA 200.8 01/09/2016 19:34 SLS2560 1 EPA 200.8 01/09/2016 19:34 SLS2560 1 EPA 200.8 01/09/2016 19:34 SLS2560 1 EPA 200.8 01/09/2016 19:34 SLS2560 1 EPA 200.8 01/09/2016 19:34 SLS2560 1 EPA 200.8 01/09/2016 19:34 SLS2560 1 EPA 200.8 01/09/2016 19:34 SLS2560 1 EPA 200.8 01/09/2016 19:34 SLS2560 1 EPA 200.8 01/09/2016 19:34 SLS2560 1 EPA 200.8 01/09/2016 19:34 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: MW-3BR Collection Date: 06-Jan-16 9:10 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.081 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 76 mg/L 2 Sulfate 1400 mg/L 20 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L M2 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L M2 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.037 mg/L 0.005 Boron (B) 2.76 mg/L 0.05 Iron (Fe) 0.010 mg/L 0.01 Manganese (Mn) 0.037 mg/L 0.005 Strontium (Sr) 1.41 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 374 mg/L 0.1 Magnesium (Mg) 173 mg/L 0.05 Potassium (K) 3.31 mg/L 0.1 Sodium (Na) 56.3 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.125 mg/L 0.005 Barium (Ba) 0.041 mg/L 0.005 Boron (B) 2.68 mg/L 0.05 Iron (Fe) 0.140 mg/L 0.01 Manganese (Mn) 0.044 mg/L 0.005 Strontium (Sr) 1.47 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Page 37 of 87 Sample #: 2016000408 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 14:10 LSTARL1 Vendor Method V_PACE 20 EPA 300.0 01/08/2016 14:52 BGN9034 200 EPA 300.0 01/08/2016 14:52 BGN9034 1 EPA 245.1 01/08/2016 14:34 ACPAYNE 1 EPA 245.1 01/09/2016 11:50 ACPAYNE 1 EPA 200.7 01/07/2016 16:34 FCJORDA 1 EPA 200.7 01/07/2016 16:34 FCJORDA 1 EPA 200.7 01/07/2016 16:34 FCJORDA 1 EPA 200.7 01/07/2016 16:34 FCJORDA 1 EPA 200.7 01/07/2016 16:34 FCJORDA 1 EPA 200.7 01/07/2016 16:34 FCJORDA 1 EPA 200.7 01/07/2016 16:34 FCJORDA 10 EPA 200.7 01/08/2016 12:51 FCJORDA 10 EPA 200.7 01/08/2016 12:51 FCJORDA 1 EPA 200.7 01/08/2016 12:51 FCJORDA 1 EPA 200.7 01/08/2016 12:51 FCJORDA 1 EPA 200.7 01/08/2016 16:54 FCJORDA 1 EPA 200.7 01/08/2016 16:54 FCJORDA 1 EPA 200.7 01/08/2016 16:54 FCJORDA 1 EPA 200.7 01/08/2016 16:54 FCJORDA 1 EPA 200.7 01/08/2016 16:54 FCJORDA 1 EPA 200.7 01/08/2016 16:54 FCJORDA 1 EPA 200.7 01/08/2016 16:54 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: MW-3BR Collection Date: 06-Jan-16 9:10 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 2.02 ug/L 1 Copper (Cu) 11.2 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.12 ug/L 1 Selenium (Se) 5.31 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 13.9 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 2.44 ug/L 1 Copper (Cu) 11.2 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.19 ug/L 1 Selenium (Se) 5.03 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 14.0 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 2300 mg/L 50 Total Carbon TOC 1.4 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 38 of 87 Sample #: 2016000408 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 16:53 SLS2560 1 EPA 200.8 01/09/2016 16:53 SLS2560 1 EPA 200.8 01/09/2016 16:53 SLS2560 1 EPA 200.8 01/09/2016 16:53 SLS2560 1 EPA 200.8 01/09/2016 16:53 SLS2560 1 EPA 200.8 01/09/2016 16:53 SLS2560 1 EPA 200.8 01/09/2016 16:53 SLS2560 1 EPA 200.8 01/09/2016 16:53 SLS2560 1 EPA 200.8 01/09/2016 16:53 SLS2560 1 EPA 200.8 01/09/2016 16:53 SLS2560 1 EPA 200.8 01/09/2016 16:53 SLS2560 1 EPA 200.8 01/09/2016 16:53 SLS2560 1 EPA 200.8 01/09/2016 16:53 SLS2560 1 EPA 200.8 01/09/2016 19:39 SLS2560 1 EPA 200.8 01/09/2016 19:39 SLS2560 1 EPA 200.8 01/09/2016 19:39 SLS2560 1 EPA 200.8 01/09/2016 19:39 SLS2560 1 EPA 200.8 01/09/2016 19:39 SLS2560 1 EPA 200.8 01/09/2016 19:39 SLS2560 1 EPA 200.8 01/09/2016 19:39 SLS2560 1 EPA 200.8 01/09/2016 19:39 SLS2560 1 EPA 200.8 01/09/2016 19:39 SLS2560 1 EPA 200.8 01/09/2016 19:39 SLS2560 1 EPA 200.8 01/09/2016 19:39 SLS2560 1 EPA 200.8 01/09/2016 19:39 SLS2560 1 EPA 200.8 01/09/2016 19:39 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: MW-13BR Dup Collection Date: 06-Jan-16 10:31 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.018 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 92 mg/L 1 Sulfate 29 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.007 mg/L 0.005 Barium (Ba) 0.350 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 4.81 mg/L 0.01 Manganese (Mn) 0.874 mg/L 0.005 Strontium (Sr) 0.408 mg/L 0.005 Zinc (Zn) 0.007 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 47.6 mg/L 0.01 Magnesium (Mg) 20.9 mg/L 0.005 Potassium (K) 4.97 mg/L 0.1 Sodium (Na) 34.9 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.044 mg/L 0.005 Barium (Ba) 0.349 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 6.14 mg/L 0.01 Manganese (Mn) 1.22 mg/L 0.005 Strontium (Sr) 0.417 mg/L 0.005 Zinc (Zn) 0.031 mg/L 0.005 Sample #: 2016000409 Matrix: GW WW Page 39 of 87 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/08/2016 14:11 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/08/2016 13:23 BGN9034 10 EPA 300.0 01/08/2016 13:23 BGN9034 1 EPA 245.1 01/08/2016 14:46 ACPAYNE 1 EPA 245.1 01/09/2016 12:02 ACPAYNE 1 EPA 200.7 01/07/2016 16:38 FCJORDA 1 EPA 200.7 01/07/2016 16:38 FCJORDA 1 EPA 200.7 01/07/2016 16:38 FCJORDA 1 EPA 200.7 01/07/2016 16:38 FCJORDA 1 EPA 200.7 01/07/2016 16:38 FCJORDA 1 EPA 200.7 01/07/2016 16:38 FCJORDA 1 EPA 200.7 01/07/2016 16:38 FCJORDA 1 EPA 200.7 01/08/2016 12:56 FCJORDA 1 EPA 200.7 01/08/2016 12:56 FCJORDA 1 EPA 200.7 01/08/2016 12:56 FCJORDA 1 EPA 200.7 01/08/2016 12:56 FCJORDA 1 EPA 200.7 01/08/2016 16:58 FCJORDA 1 EPA 200.7 01/08/2016 16:58 FCJORDA 1 EPA 200.7 01/08/2016 16:58 FCJORDA 1 EPA 200.7 01/08/2016 16:58 FCJORDA 1 EPA 200.7 01/08/2016 16:58 FCJORDA 1 EPA 200.7 01/08/2016 16:58 FCJORDA 1 EPA 200.7 01/08/2016 16:58 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: MW-13BR Dup Collection Date: 06-Jan-16 10:31 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 5.40 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.47 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.348 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) 1.12 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 5.50 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1.19 ug/L 1 Nickel (Ni) 1.13 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.386 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 410 mg/L 25 Total Carbon TOC 3.8 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 40 of 87 Sample #: 2016000409 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 16:58 SLS2560 1 EPA 200.8 01/09/2016 16:58 SLS2560 1 EPA 200.8 01/09/2016 16:58 SLS2560 1 EPA 200.8 01/09/2016 16:58 SLS2560 1 EPA 200.8 01/09/2016 16:58 SLS2560 1 EPA 200.8 01/09/2016 16:58 SLS2560 1 EPA 200.8 01/09/2016 16:58 SLS2560 1 EPA 200.8 01/09/2016 16:58 SLS2560 1 EPA 200.8 01/09/2016 16:58 SLS2560 1 EPA 200.8 01/09/2016 16:58 SLS2560 1 EPA 200.8 01/09/2016 16:58 SLS2560 1 EPA 200.8 01/09/2016 16:58 SLS2560 1 EPA 200.8 01/09/2016 16:58 SLS2560 1 EPA 200.8 01/09/2016 19:44 SLS2560 1 EPA 200.8 01/09/2016 19:44 SLS2560 1 EPA 200.8 01/09/2016 19:44 SLS2560 1 EPA 200.8 01/09/2016 19:44 SLS2560 1 EPA 200.8 01/09/2016 19:44 SLS2560 1 EPA 200.8 01/09/2016 19:44 SLS2560 1 EPA 200.8 01/09/2016 19:44 SLS2560 1 EPA 200.8 01/09/2016 19:44 SLS2560 1 EPA 200.8 01/09/2016 19:44 SLS2560 1 EPA 200.8 01/09/2016 19:44 SLS2560 1 EPA 200.8 01/09/2016 19:44 SLS2560 1 EPA 200.8 01/09/2016 19:44 SLS2560 1 EPA 200.8 01/09/2016 19:44 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/09/201615:30 CJELLIO 1 SM5310C/EPA9060A 01/10/201612:14 GHUTCHI 1 SM2540D 01/09/201610:01 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010082 Site: MW-13BR Dup Collection Date: 06-Jan-16 10:31 AM Sample #: 2016000409 Matrix: GW WW Page 41 of 87 Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Qualifiers: M1 Matrix spike recovery was High: the associated Laboratory Control Spike (LCS) was acceptable. M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to the spike level. The associated Laboratory Control Spike recovery was acceptable. aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gW2.8yee. Suite 100 Huntersville, INC 28078 (704)875-9092 January 13, 2016 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 16010082 Pace Project No.: 92282178 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on January 07, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Program Manager, Duke Energy Anne Pifer Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 43 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. OQ9Wigcsfee. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J16010082 Pace Project No.: 92282178 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 525 N 8th Street, Salina, KS 67401 A21-A Certification M 2926.01 Alaska Certification M UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification M 88-0680 California Certification M 01155CA Colorado Certification #Pace Connecticut Certification M PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification M 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification M 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification M 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification M 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification M E83079 Georgia Certification M 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification M 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification M E-10383 Kentucky Certification #: 90050 Louisiana Certification M FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification M Cert 0074 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification M TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification M 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8yee. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J16010082 Pace Project No.: 92282178 Lab ID Sample ID Matrix Date Collected Date Received 92282178001 2016000390 Water 01/06/1616:22 01/07/1614:05 92282178002 2016000392 Water 01/06/1614:48 01/07/1614:05 92282178003 2016000393 Water 01/06/16 09:05 01/07/1614:05 92282178004 2016000394 Water 01/06/1613:40 01/07/1614:05 92282178005 2016000395 Water 01/06/1612:30 01/07/1614:05 92282178006 2016000396 Water 01/06/1610:31 01/07/1614:05 92282178007 2016000397 Water 01/06/16 09:05 01/07/1614:05 92282178008 2016000398 Water 01/06/1610:40 01/07/1614:05 92282178009 2016000399 Water 01/06/1611:45 01/07/1614:05 92282178010 2016000400 Water 01/06/1615:45 01/07/1614:05 92282178011 2016000401 Water 01/06/1614:35 01/07/1614:05 92282178012 2016000402 Water 01/06/1616:30 01/07/1614:05 92282178013 2016000403 Water 01/06/1613:30 01/07/1614:05 92282178014 2016000404 Water 01/06/1610:30 01/07/1614:05 92282178015 2016000406 Water 01/06/1610:30 01/07/1614:05 92282178016 2016000407 Water 01/06/1611:50 01/07/1614:05 92282178017 2016000408 Water 01/06/16 07:10 01/07/16 14:05 92282178018 2016000409 Water 01/06/1610:31 01/07/1614:05 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8yee. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J16010082 92282178 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92282178001 2016000390 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178002 2016000392 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178003 2016000393 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178004 2016000394 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178005 2016000395 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178006 2016000396 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178007 2016000397 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178008 2016000398 RSK 175 DR1 1 PASI-M SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178009 2016000399 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178010 2016000400 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8yee. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J16010082 Pace Project No.: 92282178 Analytes Lab ID Sample ID Method Analysts Reported Laboratory SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178011 2016000401 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178012 2016000402 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178013 2016000403 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178014 2016000404 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178015 2016000406 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178016 2016000407 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178017 2016000408 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92282178018 2016000409 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J16010082 92282178 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92282178001 2016000390 SM 2320B Alkalinity, Bicarbonate (CaCO3) 277 mg/L 5.0 01/10/16 17:59 SM 2320B Alkalinity, Total as CaCO3 277 mg/L 5.0 01/10/16 17:59 92282178002 2016000392 SM 2320B Alkalinity, Bicarbonate (CaCO3) 220 mg/L 5.0 01/10/16 18:33 SM 2320B Alkalinity, Total as CaCO3 220 mg/L 5.0 01/10/16 18:33 92282178003 2016000393 RSK 175 Methane 25.8 ug/L 10.0 01/08/16 16:07 SM 2320B Alkalinity, Bicarbonate (CaCO3) 269 mg/L 5.0 01/10/16 18:48 SM 2320B Alkalinity, Total as CaCO3 269 mg/L 5.0 01/10/16 18:48 92282178004 2016000394 SM 2320B Alkalinity, Bicarbonate (CaCO3) 238 mg/L 5.0 01/10/16 19:03 SM 2320B Alkalinity, Total as CaCO3 238 mg/L 5.0 01/10/16 19:03 EPA 218.7 Chromium, Hexavalent 0.099 ug/L 0.030 01/08/16 21:28 92282178005 2016000395 SM 2320B Alkalinity, Bicarbonate (CaCO3) 250 mg/L 5.0 01/10/16 19:18 SM 2320B Alkalinity, Total as CaCO3 250 mg/L 5.0 01/10/16 19:18 92282178006 2016000396 RSK 175 Methane 40.6 ug/L 10.0 01/08/16 16:32 SM 2320B Alkalinity, Bicarbonate (CaCO3) 140 mg/L 5.0 01/10/16 19:33 SM 2320B Alkalinity, Total as CaCO3 140 mg/L 5.0 01/10/16 19:33 92282178007 2016000397 RSK 175 Methane 13.9 ug/L 10.0 01/08/16 16:40 SM 2320B Alkalinity, Bicarbonate (CaCO3) 145 mg/L 5.0 01/10/16 19:46 SM 2320B Alkalinity, Total as CaCO3 145 mg/L 5.0 01/10/16 19:46 92282178008 2016000398 RSK 175 Methane 1900 ug/L 10.0 01/08/16 16:48 SM 4500-S21D Sulfide 1.5 mg/L 0.50 01/08/16 15:00 EPA 218.7 Chromium, Hexavalent 0.19 ug/L 0.030 01/08/16 22:20 92282178009 2016000399 RSK 175 Methane 22.6 ug/L 10.0 01/08/16 16:57 SM 2320B Alkalinity, Bicarbonate (CaCO3) 246 mg/L 5.0 01/10/16 20:59 SM 2320B Alkalinity, Total as CaCO3 246 mg/L 5.0 01/10/16 20:59 M1 92282178010 2016000400 RSK 175 Methane 570 ug/L 10.0 01/08/16 17:21 SM 2320B Alkalinity, Bicarbonate (CaCO3) 538 mg/L 5.0 01/10/16 21:41 SM 2320B Alkalinity, Total as CaCO3 538 mg/L 5.0 01/10/16 21:41 92282178011 2016000401 SM 2320B Alkalinity, Bicarbonate (CaCO3) 231 mg/L 5.0 01/10/16 22:08 SM 2320B Alkalinity, Total as CaCO3 231 mg/L 5.0 01/10/16 22:08 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8yee. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J16010082 92282178 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92282178012 2016000402 RSK 175 Methane 7280 ug/L 10.0 01/08/16 17:46 SM 2320B Alkalinity, Bicarbonate (CaCO3) 175 mg/L 5.0 01/10/16 22:23 SM 2320B Alkalinity, Total as CaCO3 175 mg/L 5.0 01/10/16 22:23 92282178013 2016000403 RSK 175 Methane 168 ug/L 10.0 01/08/16 17:54 SM 2320B Alkalinity, Bicarbonate (CaCO3) 260 mg/L 5.0 01/10/16 22:38 SM 2320B Alkalinity, Total as CaCO3 260 mg/L 5.0 01/10/16 22:38 92282178014 2016000404 SM 2320B Alkalinity, Bicarbonate (CaCO3) 380 mg/L 5.0 01/10/16 22:52 SM 2320B Alkalinity, Total as CaCO3 380 mg/L 5.0 01/10/16 22:52 92282178016 2016000407 RSK 175 Methane 75.2 ug/L 10.0 01/08/16 18:19 SM 2320B Alkalinity, Bicarbonate (CaCO3) 93.2 mg/L 5.0 01/10/16 23:34 SM 2320B Alkalinity, Total as CaCO3 93.2 mg/L 5.0 01/10/16 23:34 SM 4500-S21D Sulfide 0.26 mg/L 0.10 01/08/16 15:00 92282178017 2016000408 RSK 175 Methane 144 ug/L 10.0 01/08/16 18:27 SM 2320B Alkalinity, Bicarbonate (CaCO3) 269 mg/L 5.0 01/10/16 23:45 SM 2320B Alkalinity, Total as CaCO3 269 mg/L 5.0 01/10/16 23:45 EPA 218.7 Chromium, Hexavalent 0.26 ug/L 0.030 01/09/16 01:35 92282178018 2016000409 RSK 175 Methane 41.2 ug/L 10.0 01/08/16 18:35 SM 2320B Alkalinity, Bicarbonate (CaCO3) 140 mg/L 5.0 01/11/16 00:00 SM 2320B Alkalinity, Total as CaCO3 140 mg/L 5.0 01/11/16 00:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098�t�i .8yee. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010082 Pace Project No.: 92282178 Method: RSK 175 Description: RSK 175 AIR Headspace Client: Duke Energy Date: January 13, 2016 General Information: 18 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010082 Pace Project No.: 92282178 Method: SM 2320B Description: 2320E Alkalinity Client: Duke Energy Date: January 13, 2016 General Information: 17 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WET/42371 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92282172001,92282172011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1643733) • Alkalinity, Total as CaCO3 • MSD (Lab ID: 1643734) • Alkalinity, Total as CaCO3 QC Batch: WET/42372 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92282178009,92282184001 M1: Matrix spike recovery exceeded QC limits. • MS (Lab ID: 1643741) • Alkalinity, Total as CaCO3 • MSD (Lab ID: 1643742) • Alkalinity, Total as CaCO3 • MSD (Lab ID: 1643744) • Alkalinity, Total as CaCO3 Additional Comments: Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onic8yee. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010082 Pace Project No.: 92282178 Method: SM 4500-S213 Description: 4500S2D Sulfide Water Client: Duke Energy Date: January 13, 2016 General Information: 18 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WET/42367 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92282172001,92282172011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1643318) • Sulfide • MSD (Lab ID: 1643319) • Sulfide Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010082 Pace Project No.: 92282178 Method: EPA 218.7 Description: Hexavalent Chromium by IC Client: Duke Energy Date: January 13, 2016 General Information: 18 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000390 Lab ID: 92282178001 Collected: 01/06/16 16:22 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/08/1615:43 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 277 mg/L 5.0 1 01/10/16 17:59 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 17:59 Alkalinity, Total as CaCO3 277 mg/L 5.0 1 01/10/16 17:59 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/08/16 20:49 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000392 Lab ID: 92282178002 Collected: 01/06/16 14:48 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/08/1615:59 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 220 mg/L 5.0 1 01/10/16 18:33 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 18:33 Alkalinity, Total as CaCO3 220 mg/L 5.0 1 01/10/16 18:33 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/08/16 21:02 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000393 Lab ID: 92282178003 Collected: 01/06/16 09:05 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 25.8 ug/L 10.0 1 01/08/1616:07 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 269 mg/L 5.0 1 01/10/16 18:48 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 18:48 Alkalinity, Total as CaCO3 269 mg/L 5.0 1 01/10/16 18:48 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/08/16 21:15 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000394 Lab ID: 92282178004 Collected: 01/06/16 13:40 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/08/1616:15 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 238 mg/L 5.0 1 01/10/16 19:03 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 19:03 Alkalinity, Total as CaCO3 238 mg/L 5.0 1 01/10/16 19:03 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.099 ug/L 0.030 1 01/08/16 21:28 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i .8yee. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000395 Lab ID: 92282178005 Collected: 01/06/16 12:30 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/08/1616:24 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 250 mg/L 5.0 1 01/10/16 19:18 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 19:18 Alkalinity, Total as CaCO3 250 mg/L 5.0 1 01/10/16 19:18 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/08/16 21:41 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000396 Lab ID: 92282178006 Collected: 01/06/16 10:31 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 40.6 ug/L 10.0 1 01/08/1616:32 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 140 mg/L 5.0 1 01/10/16 19:33 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 19:33 Alkalinity, Total as CaCO3 140 mg/L 5.0 1 01/10/16 19:33 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/08/16 21:54 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000397 Lab ID: 92282178007 Collected: 01/06/16 09:05 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 13.9 ug/L 10.0 1 01/08/1616:40 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 145 mg/L 5.0 1 01/10/16 19:46 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 19:46 Alkalinity, Total as CaCO3 145 mg/L 5.0 1 01/10/16 19:46 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/08/16 22:07 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000398 Lab ID: 92282178008 Collected: 01/06/16 10:40 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 1900 ug/L 10.0 1 01/08/1616:48 74-82-8 4500S21) Sulfide Water Analytical Method: SM 4500-S2D Sulfide 1.5 mg/L 0.50 5 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.19 ug/L 0.030 1 01/08/16 22:20 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinlc&�ree. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000399 Lab ID: 92282178009 Collected: 01/06/16 11:45 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 22.6 ug/L 10.0 1 01/08/1616:57 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 246 mg/L 5.0 1 01/10/16 20:59 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 20:59 Alkalinity, Total as CaCO3 246 mg/L 5.0 1 01/10/16 20:59 M1 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/08/16 23:25 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000400 Lab ID: 92282178010 Collected: 01/06/16 15:45 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 570 ug/L 10.0 1 01/08/1617:21 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 538 mg/L 5.0 1 01/10/16 21:41 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 21:41 Alkalinity, Total as CaCO3 538 mg/L 5.0 1 01/10/16 21:41 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/09/16 00:04 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000401 Lab ID: 92282178011 Collected: 01/06/16 14:35 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/08/1617:38 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 231 mg/L 5.0 1 01/10/16 22:08 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 22:08 Alkalinity, Total as CaCO3 231 mg/L 5.0 1 01/10/16 22:08 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/09/16 00:17 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000402 Lab ID: 92282178012 Collected: 01/06/16 16:30 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 7280 ug/L 10.0 1 01/08/1617:46 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 175 mg/L 5.0 1 01/10/16 22:23 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 22:23 Alkalinity, Total as CaCO3 175 mg/L 5.0 1 01/10/16 22:23 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/09/16 00:30 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000403 Lab ID: 92282178013 Collected: 01/06/16 13:30 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 168 ug/L 10.0 1 01/08/1617:54 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 260 mg/L 5.0 1 01/10/16 22:38 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 22:38 Alkalinity, Total as CaCO3 260 mg/L 5.0 1 01/10/16 22:38 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/09/16 00:43 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000404 Lab ID: 92282178014 Collected: 01/06/16 10:30 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/08/1618:02 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 380 mg/L 5.0 1 01/10/16 22:52 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 22:52 Alkalinity, Total as CaCO3 380 mg/L 5.0 1 01/10/16 22:52 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/09/16 00:56 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i .8yee. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000406 Lab ID: 92282178015 Collected: 01/06/16 10:30 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/08/1618:10 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/10/16 23:28 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 23:28 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/10/16 23:28 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/09/16 01:09 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000407 Lab ID: 92282178016 Collected: 01/06/16 11:50 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 75.2 ug/L 10.0 1 01/08/1618:19 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 93.2 mg/L 5.0 1 01/10/16 23:34 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 23:34 Alkalinity, Total as CaCO3 93.2 mg/L 5.0 1 01/10/16 23:34 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide 0.26 mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/09/16 01:22 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000408 Lab ID: 92282178017 Collected: 01/06/16 07:10 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 144 ug/L 10.0 1 01/08/1618:27 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 269 mg/L 5.0 1 01/10/16 23:45 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/10/16 23:45 Alkalinity, Total as CaCO3 269 mg/L 5.0 1 01/10/16 23:45 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.26 ug/L 0.030 1 01/09/16 01:35 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010082 Pace Project No.: 92282178 Sample: 2016000409 Lab ID: 92282178018 Collected: 01/06/16 10:31 Received: 01/07/16 14:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 41.2 ug/L 10.0 1 01/08/1618:35 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 140 mg/L 5.0 1 01/11/16 00:00 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/11/16 00:00 Alkalinity, Total as CaCO3 140 mg/L 5.0 1 01/11/16 00:00 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/08/1615:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/09/16 01:48 18540-29-9 Date: 01/13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098�t�inic&�ree. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010082 Pace Project No.: 92282178 QC Batch: AIR/24992 Analysis Method: RSK 175 QC Batch Method: RSK 175 Analysis Description: RSK 175 AIR HEADSPACE Associated Lab Samples: 92282178001, 92282178002, 92282178003, 92282178004, 92282178005, 92282178006, 92282178007, 92282178008,92282178009,92282178010,92282178011,92282178012,92282178013,92282178014, 92282178015,92282178016,92282178017,92282178018 METHOD BLANK: 2172202 Matrix: Water Associated Lab Samples: 92282178001, 92282178002, 92282178003, 92282178004, 92282178005, 92282178006, 92282178007, 92282178008,92282178009,92282178010,92282178011,92282178012,92282178013,92282178014, 92282178015,92282178016,92282178017,92282178018 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Methane ug/L ND 10.0 01/08/1615:27 LABORATORY CONTROL SAMPLE & LCSD: 2172203 2172204 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Methane ug/L 60.7 59.9 60.0 99 99 85-115 0 20 SAMPLE DUPLICATE: 2173194 92282178001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 2.9J 20 SAMPLE DUPLICATE: 2173195 92282178010 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L 570 534 7 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/13/2016 11:48 AM without the written consent of Pace Analytical Services, Inc.. Page 30 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010082 Pace Project No.: 92282178 QC Batch: WET/42371 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 92282178001,92282178002,92282178003,92282178004,92282178005,92282178006,92282178007 METHOD BLANK: 1643729 Matrix: Water Associated Lab Samples: 92282178001, 92282178002, 92282178003, 92282178004, 92282178005, 92282178006, 92282178007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Alkalinity, Carbonate (CaCO3) mg/L ND 5.0 01/10/16 12:34 Alkalinity, Total as CaCO3 mg/L ND 5.0 01/10/16 12:34 Alkalinity, Bicarbonate (CaCO3) mg/L ND 5.0 01/10/16 12:34 LABORATORY CONTROL SAMPLE: 1643730 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 47.3 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1643731 1643732 MS MSD 92282172001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 71.0 50 50 118 116 93 89 80-120 2 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1643733 1643734 MS MSD 92282172011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Alkalinity, Total as CaCO3 mg/L ND 50 50 314 316 628 633 80-120 1 25 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/13/2016 11:48 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i .8yee. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010082 Pace Project No.: 92282178 QC Batch: WET/42372 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 92282178009,92282178010,92282178011,92282178012,92282178013,92282178014,92282178015, 92282178016,92282178017,92282178018 METHOD BLANK: 1643739 Matrix: Water Associated Lab Samples: 92282178009,92282178010,92282178011,92282178012,92282178013,92282178014,92282178015, 92282178016,92282178017,92282178018 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Alkalinity, Carbonate (CaCO3) mg/L ND 5.0 01/10/16 20:39 Alkalinity, Total as CaCO3 mg/L ND 5.0 01/10/16 20:39 Alkalinity, Bicarbonate (CaCO3) mg/L ND 5.0 01/10/16 20:39 LABORATORY CONTROL SAMPLE: 1643740 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 47.7 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1643741 1643742 MS MSD 92282178009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Alkalinity, Total as CaCO3 mg/L 246 50 50 282 269 72 45 80-120 5 25 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1643743 1643744 MS MSD 92282184001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 193 50 50 233 232 80 78 80-120 1 25 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/13/2016 11:48 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010082 Pace Project No.: 92282178 QC Batch: WET/42367 Analysis Method: SM 4500-S2D QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 92282178001,92282178002,92282178003,92282178004,92282178005,92282178006,92282178007 METHOD BLANK: 1643316 Matrix: Water Associated Lab Samples: 92282178001, 92282178002, 92282178003, 92282178004, 92282178005, 92282178006, 92282178007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide mg/L ND 0.10 01/08/1615:00 LABORATORY CONTROL SAMPLE: 1643317 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide mg/L .5 0.49 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1643318 1643319 MS MSD 92282172001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide mg/L ND .5 .5 0.22 0.22 44 44 90-110 0 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1643320 1643321 MS MSD 92282172011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide mg/L ND .5 .5 0.48 0.48 96 96 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/13/2016 11:48 AM without the written consent of Pace Analytical Services, Inc.. Page 33 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010082 Pace Project No.: 92282178 QC Batch: WET/42368 Analysis Method: SM 4500-S2D QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 92282178008, 92282178009, 92282178010, 92282178011, 92282178012, 92282178013, 92282178014, 92282178015,92282178016,92282178017,92282178018 METHOD BLANK: 1643322 Matrix: Water Associated Lab Samples: 92282178008, 92282178009, 92282178010, 92282178011, 92282178012, 92282178013, 92282178014, 92282178015,92282178016,92282178017,92282178018 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide mg/L ND 0.10 01/08/1615:00 LABORATORY CONTROL SAMPLE: 1643323 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide mg/L .5 0.49 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1643324 1643325 MS MSD 92282178008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Sulfide mg/L 1.5 2.5 2.5 4.0 4.0 102 102 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1643326 1643327 MS MSD 92282178018 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Sulfide mg/L ND .5 .5 0.54 0.54 108 108 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/13/2016 11:48 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010082 Pace Project No.: 92282178 QC Batch: WETA/53610 Analysis Method: EPA 218.7 QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC Associated Lab Samples: 92282178001, 92282178002, 92282178003, 92282178004, 92282178005, 92282178006, 92282178007, 92282178008 METHOD BLANK: 1441930 Matrix: Water Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chromium, Hexavalent ug/L ND 0.030 01/08/16 16:29 LABORATORY CONTROL SAMPLE: 1441931 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chromium, Hexavalent ug/L .075 0.076 101 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1441932 1441933 MS MSD 92282184009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent ug/L ND .025 .025 .026J .025J 106 100 85-115 20 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1441934 1441935 MS MSD 92282184018 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent ug/L ND .075 .075 0.070 0.072 93 96 85-115 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/13/2016 11:48 AM without the written consent of Pace Analytical Services, Inc.. Page 35 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i .8yee. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010082 Pace Project No.: 92282178 QC Batch: WETA/53612 Analysis Method: EPA 218.7 QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC Associated Lab Samples: 92282178009,92282178010,92282178011,92282178012,92282178013,92282178014,92282178015, 92282178016,92282178017,92282178018 METHOD BLANK: 1441984 Matrix: Water Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chromium, Hexavalent ug/L ND 0.030 01/08/16 22:59 LABORATORY CONTROL SAMPLE: 1441985 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chromium, Hexavalent ug/L .075 0.071 95 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1441986 1441987 MS MSD 92282178009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent ug/L ND .075 .075 0.074 0.075 98 99 85-115 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/13/2016 11:48 AM without the written consent of Pace Analytical Services, Inc.. Page 36 of 43 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J16010082 Pace Project No.: 92282178 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/13/2016 11:48 AM without the written consent of Pace Analytical Services, Inc.. Page 37 of 43 acmnalytical www.pacelabs.com Pace Analytical Services, Inc. ogp %ggf0.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J16010082 Pace Project No.: 92282178 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92282178001 2016000390 RSK 175 AIR/24992 92282178002 2016000392 RSK 175 AIR/24992 92282178003 2016000393 RSK 175 AIR/24992 92282178004 2016000394 RSK 175 AIR/24992 92282178005 2016000395 RSK 175 AIR/24992 92282178006 2016000396 RSK 175 AIR/24992 92282178007 2016000397 RSK 175 AIR/24992 92282178008 2016000398 RSK 175 AIR/24992 92282178009 2016000399 RSK 175 AIR/24992 92282178010 2016000400 RSK 175 AIR/24992 92282178011 2016000401 RSK 175 AIR/24992 92282178012 2016000402 RSK 175 AIR/24992 92282178013 2016000403 RSK 175 AIR/24992 92282178014 2016000404 RSK 175 AIR/24992 92282178015 2016000406 RSK 175 AIR/24992 92282178016 2016000407 RSK 175 AIR/24992 92282178017 2016000408 RSK 175 AIR/24992 92282178018 2016000409 RSK 175 AIR/24992 92282178001 2016000390 SM 2320B WET/42371 92282178002 2016000392 SM 2320B WET/42371 92282178003 2016000393 SM 2320B WET/42371 92282178004 2016000394 SM 2320B WET/42371 92282178005 2016000395 SM 2320B WET/42371 92282178006 2016000396 SM 2320B WET/42371 92282178007 2016000397 SM 2320B WET/42371 92282178009 2016000399 SM 2320B WET/42372 92282178010 2016000400 SM 2320B WET/42372 92282178011 2016000401 SM 2320B WET/42372 92282178012 2016000402 SM 2320B WET/42372 92282178013 2016000403 SM 2320B WET/42372 92282178014 2016000404 SM 2320B WET/42372 92282178015 2016000406 SM 2320B WET/42372 92282178016 2016000407 SM 2320B WET/42372 92282178017 2016000408 SM 2320B WET/42372 92282178018 2016000409 SM 2320B WET/42372 92282178001 2016000390 SM 4500-S2D WET/42367 92282178002 2016000392 SM 4500-S2D WET/42367 92282178003 2016000393 SM 4500-S2D WET/42367 92282178004 2016000394 SM 4500-S2D WET/42367 92282178005 2016000395 SM 4500-S2D WET/42367 92282178006 2016000396 SM 4500-S2D WET/42367 92282178007 2016000397 SM 4500-S2D WET/42367 92282178008 2016000398 SM 4500-S2D WET/42368 92282178009 2016000399 SM 4500-S2D WET/42368 92282178010 2016000400 SM 4500-S2D WET/42368 92282178011 2016000401 SM 4500-S2D WET/42368 92282178012 2016000402 SM 4500-S2D WET/42368 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /13/2016 11:48 AM without the written consent of Pace Analytical Services, Inc.. Page 38 of 43 acmnalytical www.pacelabs.com Pace Analytical Services, Inc. og6g I bcgf0e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J16010082 Pace Project No.: 92282178 Lab ID Sample ID QC Batch Method QC Batch 92282178013 2016000403 SM 4500-S2D WET/42368 92282178014 2016000404 SM 4500-S2D WET/42368 92282178015 2016000406 SM 4500-S2D WET/42368 92282178016 2016000407 SM 4500-S2D WET/42368 92282178017 2016000408 SM 4500-S2D WET/42368 92282178018 2016000409 SM 4500-S2D WET/42368 92282178001 2016000390 EPA 218.7 WETA/53610 92282178002 2016000392 EPA 218.7 WETA/53610 92282178003 2016000393 EPA 218.7 WETA/53610 92282178004 2016000394 EPA 218.7 WETA/53610 92282178005 2016000395 EPA 218.7 WETA/53610 92282178006 2016000396 EPA 218.7 WETA/53610 92282178007 2016000397 EPA 218.7 WETA/53610 92282178008 2016000398 EPA 218.7 WETA/53610 92282178009 2016000399 EPA 218.7 WETA/53612 92282178010 2016000400 EPA 218.7 WETA/53612 92282178011 2016000401 EPA 218.7 WETA/53612 92282178012 2016000402 EPA 218.7 WETA/53612 92282178013 2016000403 EPA 218.7 WETA/53612 92282178014 2016000404 EPA 218.7 WETA/53612 92282178015 2016000406 EPA 218.7 WETA/53612 92282178016 2016000407 EPA 218.7 WETA/53612 92282178017 2016000408 EPA 218.7 WETA/53612 92282178018 2016000409 EPA 218.7 WETA/53612 Date: 01 /13/2016 11:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Method Analytical Batch Page 39 of 43 Document Name: Document Revised: 260CT2015 /� r !� ic6~nalXica+Document Sample Condition Upon Receipt(SCUR) Page 1 of 2 Page 81 of 8 No.: Issuing Authority: F-CHR-CS-003-rev.17 Pace Huntersville Quality Office Sample Condition .: Client Name. Project #: Upon, Receipt Courier: []Fed Ex []UPS ❑LISPS ❑Client ❑Commercial �]Ilace []Other: Custody Seat on Cooler/Box Present? []Yes QNo Packing Material: ❑Bubble Wrap [JBubble Bags WO#:92282A78 III1111111111111111111111IN Seals Intact? Des ONo ❑None ❑Other: Thermometer 7 T1505 Used: ° Type of ice: ❑Wet' j ❑Blue ❑None ❑bamples on ice, cooling process has begun Cooler Temp Corrected (°C): Biological Tissue Frozen? ❑Yes Temp should be aboveJfreezing to 6°C Correction Factor: 0.0 °C Date and Initials of Person Examining Contents: V USDA Regulated Soil(❑ N/A, water sample) Did samples origij'�e in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (international) .. ❑Yes El including Hawaii and Puerto Rico)? Oyes allo If Yes to either question, fill out a Regulated Soil Checklist and include with SCUR/COC paperwork, COMMENTS: Chain of Custody Present? s Yees ❑No ❑N/A 1. Chain of Custody Filled Out? Ye/s ❑ No ❑N/A 2. Chain of Custody Relinquished? Yes ❑No []NIA 3. Sampler Name and/or Signature on COC? Y ❑No ❑N/A 4. Samples Arrived within Hold Time? Y s ❑No []N/A S. Short Hold Time Analysis (<72 hr)? Yes ❑No ❑N/A 6. Rush Turn Around Time Requested? []Yes ,EJN" o ❑N/A 7. Sufficient Volume? ,i IYes ❑No ❑N/A S. Correct Containers Used? Yes ❑No ❑N/A 9. -Pace Containers Used? ❑Yes %6No ❑N/A Containers Intact? E Yes ❑No ❑N/ . 10. Filtered Volume Received for Dissolved Tests? ❑ Yes ❑No ❑N/A 11. Note if sediment is visible in the dissolved container Sample Labels Match COC? _,'❑Pes ❑No ❑N/A 12. -Includes Date/Time/ID/Analysis Matrix:_ All containers needing acid/base preservation have been checked? ❑Yeg/ ❑No ❑N/A 13. All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2SO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide) ❑Yes ❑No ❑N/A Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC,LLHg ❑Yes []No ❑N%A Samples checked for dechlorization ❑Yes ❑No ❑N/A 14. Headspace in VOA Vials (>5-6mm)? ❑yes ❑N- ❑N/A 15. Trip Blank Present? ❑Yes [-]No djni/ 16. Trip Blank Custody Seals Present? ❑Yes ❑No l 1N/A Pace Trip Blank Lot # (if purchased): CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Field Data Required? []Yes ©No Date/Time: Project Manager SCURF Review " / _ _ Date: f ! Note: Whenever there is a discrepancy a e ting Nof th Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers). Page 40 of 43 a a LLLl >r Page 82 of 87 i I 1BYIRIUO'J / JB!Oj .- 6 4 O O O O O O R D 6 O W O O r H C ` o �' DG'0} SlElallJ �anlossl w ' z I F ! P AID >- = panlosSlp ! a molaq ° z aas) N = (03ed�A) Ili J,J r rs \ K„ �'' G p W ro — Q ' 0. Z - qI ; p � p av- i w� ! a1 6 i44UBW013�A, epllln5 heel x I I +`c 9 PUnoJe ulna perisoP BIR�IPU! BSL®j� :I.UC1JOdQII'JOI1Jp1S11D F '�I98f16 n BSRu6gJB� u I s Q ` N f I I 931+IIN � x � � I a •e3eJ11N '�!?t � r 3 m ! .s n 6OS'13 g{ I E JslReus E, (s[4 AA iTh 7 �; E quo" E -•., o a k� k g N ° t x � ! 'dwB3 g N g IT Z LL Oz 00 J p a o a y C4, +Z' 14 [ • (, t ` Cry j yG] [jj L} G1 co 0 Ol' m' ad Q N V LL a" ® u 3I fx w CC,� k h i R a �T o w Ui .Y it H ! '� l� '•J _ CSS I •'Y Y V L 4_`- m _ _._ Page 41 of 43 c 41 1, 4 �pule'U. / telol I P a �U) Blow Oi w F IN = panlossl❑ F 5tr'0 sle;atlr o = panlossl© N'lo a o nnolaq c . LLJ i aas) sle;aW mm p o a (83ed A) a� N IA JO Z 0 V — o ;U 4 P (l ;uawal3-A) 8 1 ` d eplllns ! $ I � 6 eieeq� uOgj ea � � .41suoq.+eeIS i '�1lullv>IIV ! g aiIAIN 's A1e846 n (;a N U �ppp NSU) ... LD-aW1 .`9 c qw M J� a I< a e e a q € ' 00 o c QJ �- 12 1 1- rL E O Q d 0. C H+HP�III!ti Page 83 of 87 T N >- N N 60 U C �' \�J� P 9-: n punoJeuml pailsap Q11,0IPul Mold �luelJodlul'JawoGsn3 N lV iH �• p \ N i �� N E E I� i} i� 2 C fp N ' C a ,I o o0) u� P •Rjjl B � � }. E ��y G a F b ZZ> W U W W � c ( IIiIIi�'� Page 42 of 43 Page 84 of 87 a IA, t N [ G F W { N F + p Y10 > a i o» a z 0.' 0 WOO / Viol ''�1�lel�au QanlosSlp 1'01 SlSfaw paAlasSlp r. ()Ioq sleaay� IA lO o G WOW9f9 Al (10114 "A w a 'alavoq]eo-lg ']GIulS�lltl a31AIN $ $ti toS'13 Rleag6 A 011 N MSd) ava4]aN R �+ S41'SBl " � E F j � c Ii 4 4 b � S� oc N P T � Q � F . d- U 2 a a h N A s° L N C � E N T a a V ] E ,� a o punoieuml poinap al431puL eanald ,luelioduq'iawolen3 N 44 — -- -F(-� ' 1 (n v N T a fl ya�a' z -r 0. �1 a X V c U � 9gC+ u a p� ai r E O 3 N � Y ul mil. N W W O Page 43 of 43 CHAIN OF CUSTODY RECORD AND ANALYSM REQUE51 FORM DL&m P.mrwv AmatylAw - - --. r ------------- — ------------- - ------- -- — ---- -- - - - ------- . ..... ...... — -------- . ....... I ry i U" Of* Duka 15nargy Mwfflx K— �C-w""�4u rsak�v Two go W" AnstrMell Laboraftry IMP 11"�l F" M1 i 10 v Cholm 04 OUMOdy & —W Mc, 114" IUiF jyQdjjn41 U (e MMES vMw crwmq'wakm— UST_ AS GW AS&R45FrWO waAar IIIT Pace . ............. ....... .. . re tb: PO 1142091 &Z-2- -- --T— *W k* tin"s UM: mom WD& 6bn(slmvVvlumsjmL) RDm 40 mi'l 300 MG03AJ Pei SO*" PET PET PET "T samp - to Description'or ID casm.w to P—y-?-Pk AV AAVwn`Aft -A .juded ffmma. Pam T". r MwAh" F) x )e t IV V#35 �)330 030 Jos, 4-9 tS� niterBlank Euipmurbli Blank -z- I TGTkkL--- IL ant, I DWWT Aau By", I54 ock 'YFwn d By ELEMCNTS by "-ms [T$60: Am. Be. Gd, Co. Cr, Cu, Mot Mj Pb. Sb, So, -D (LLJ, V tLILI ELEMENTS by lep IiRm): AI, am. 9. rook, *% Sr, zn ICP Unfflq"tW C;4L M% K, M& HI) by 245.1 U*tW"4rn*tA).v: Page DISTMOUMN 85 of 87 SyntE!Tra EDD ORIONAL Ln i i%a, COPY Lo CLIEN I r IILW— IFOC kiV DATE 1122il201 zoo MW 50 SM "E HOM mtqv Hs" ZR V, 0 J I 0 1 2 z R"westrd Turnaround roW L20 -14 Days 7 0sys vV-� OVt j-l14-1Y 148 w -Oaw _ASAP Add. Cr i Will Apply Dubs Energy Answy iftw1 LabundDry chmm of Cukkgly F: ! Log GWAssoss Rha-�w d fwaral Client j 'x' b__ Bum.,p%s Unit: CHAIN OF CUSTODY REGCiRO AND ANALYSIS RFQUEST F4]RM •------- DWK& eWly Amlytical Lebplrlery ' ; Am.r sn_LAlso-+aimy llRa crnt rc J p _t— or _ 1_ Page 86 of 87 ar coi. w;saur ae+lrtw r.ln ' �figgqF� } Matria GW_Y'✓A'd `�rw' 8G_ TRIWTiaN i'11M Mgss l�'ly ra► ti' _. WAI*v ft 1w c 1ii1! - - -. __ - .-,.�- r?RICiIM144L to LAIi. COPY k9 GLlthi i. Flep lT�-!$+li L 'y I$Mla rx 3h►Ir1€ Paaofap�l�+y�� Syr+terra F_DD _ i�F L7�i/i#Sl .. i,12'a12J I • -� � ialali�}iI{�f kFF�E5 COY wcRaw.a.— C REV DATE 1J22l .._..�..._... ..__..._ - e eas-�v�a PO 1142081 -0 •� � •`"" fir•: a..R. C�nax 18; i P[e3lrlP�YeYK fnn In � �, � ��!I� C4nWiMFY014Nn59ImW 20" ml mm I IN 6413 5w �$(F 3$6 S64 3QQ -- _ QpdrWTylsa PET glass PET !Fit PET Pfft OWL nrarEH6PE nMfE rU 7y SanpleDesmiptionor10 cvp<o wtorDnRrw-+ff.pfDpfWff01nn r 76 a n U m 0 wF sriadaaa -�.j o Lperilon CaN. llnn AdoFm!llon gFFa�-i- __ +�' S i°• o I - J2 r C Dim F "ilrlt+ Slp��nura f Q V F- Z 3 r _> ry+ � L} x' [3 Zi E F -. - -kill& = Q Elrf 0 G - „r Requwlmci Tu tbat un4 T'KlW 20 .�DOWTOW- e r nays ' y a . _ - S4 f_LEMENT$ by1CPM5ITRMI An, Ba,.1~d, Ca, Cc C .Ira, Ni, Ph, 3b. 54,. Tl ILLI, V {LL9 E 'orihw _ASAP ELEMENTS by ICP_(TRUr : Al, Ha, lb, Fo,M�,n, Sr. ZM rCP Undggui On, Mg. K. No Hp 2�p UA � *,aid. Cn9k 4� �pIY dlesol�ra+i iarra9s : all rmt is lCP. IMS ft cy CHAIN OF CUSTODY RECORD AND ANALYSIS — -----[irWi5vrerW'--- �+iwlLabarrtsrr i -ram - ---- -h� �+c�j� _ ieyr tea. Isammo?�[I I * _ fi Matrix G WW -1- AN�mlytical LNabo�atary r733404W.F. " K— �I$TRtBUTfaFI �Iyln of Cua1mA N: r+. 014 lie. awl I QRIGIM(kL 10 LAB, DOPY t9 CLI�MT � a j _ RAWILE N'RCRRAM amply Lep I q! b 4 u q Z-Lt gmv'g -_ M1Pi]E7— , _._.._.fPMfwwMMYww_ _ ` O4Fkkg W.ti�i _ ust 4.t1r+llFk. ccowrrmeiG7_..- - ............... .. _ Ckfrrte 9alwg75'aur Fid"Nion0.0um) tk UniWlwrd � HII►�.d !>-ynterrBEDD PO1142081 7- - ..,� BveinsfrUnll: _.- I .t l .PC-1.r1n QreA.g{s/J1tIYe t• Mew W - t Coraeainer Yo4omsr {mLj Bobo NIiD rrl# 360 1N1 110'Q t31d tSQO 6I1ti C.ranEtYnsr TypoP4T gum p" nn IroaE w Sprn a afterlpdon or II} Gps Lot*uon 40 _, r r. �5r�m,Krit �wrApiaieaNappr®"r*n alrra'ad any■ - Callecllan 4ntonn�Cioei _. _ par« Twin 91 rs. 1 L r :c - co - Wd- x roc" m } 10 2 M 7 c a 4 9 I 7OTJUL 3-4 1 Z R - La I 1 2 Y ti co - { iL Rt�qu66t+pd TurnttunW Tolal L29 y u 1 '14 (Ifa ys - 1 1..� sari uoPo -k iz ► + 11 4''F' �asFJ {{ 1 - '�# 6 dS }k Y ELEMENTS by ICp M& r MPAJ: As, 84, Cd, Co, OF. GLL Mo- Ni, Pb. sin. So. TI {LL),, V (LLk "il154er ^,qg, �T ELEMENTS by ICP ITRM)': All per. '3', Fe. Mq Sr- Zak 1L P_.4rydlgeelad Ca. ft t4, Na Hg by MA 'AM. CQat, VM ApiNy 3 IN1F3$IY!'d 1n9[i MJ YI m6f 9rld pFr'P, IMS,Hg 0