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Home My WebLink AboutNC0003425_J16010049-Report_20160801DUKE Analytical Laboratory Page 1of75 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J16010049 ROXBORO - AB GW ASSESSMENT WATER Brian Wilker, Tim Hunsucker, Fred Holt, Brandon Russo, Kathy Webb, John To Anne Pifer Phone: JJ�N RGY Date: Anne Pifer Please contact the Program Manager (Anne Pifer) with any questions regarding this report. Data Flags & Calculations: 1/18/2016 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Page 2 of 75 Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2016000257 Roxboro 05-Jan-16 3:55 PM ILLEGIBLE ABMW-2 2016000258 Roxboro 05-Jan-16 1:40 PM ILLEGIBLE MW-15BR 2016000259 Roxboro 05-Jan-16 1:20 PM ILLEGIBLE MW-15D 2016000260 Roxboro 05-Jan-16 12:20 PM ILLEGIBLE BG-1BR 2016000261 Roxboro 05-Jan-16 12:15 PM ILLEGIBLE MW-4BR 2016000262 Roxboro 05-Jan-16 4:20 PM ILLEGIBLE MW-18D 2016000263 Roxboro 05-Jan-16 3:20 PM ILLEGIBLE MW-18BR 2016000264 Roxboro 05-Jan-16 1:05 PM ILLEGIBLE MW-05D 2016000265 Roxboro 05-Jan-16 11:25 AM ILLEGIBLE MW-05BR 2016000266 Roxboro 05-Jan-16 3:15 PM ILLEGIBLE MW-01 2016000267 Roxboro 05-Jan-16 4:45 PM ILLEGIBLE MW-02 2016000268 Roxboro 05-Jan-16 10:30 AM ILLEGIBLE Filter Blank 2016000269 Roxboro 05-Jan-16 10:30 AM ILLEGIBLE EQUIP BLANK 2016000270 Roxboro 05-Jan-16 11:42 AM ILLEGIBLE BG-01 2016000271 Roxboro 05-Jan-16 2:20 PM ILLEGIBLE CW-4 15 Total Samples Page 3 of 75 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification ❑ Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report OV Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries ❑ Chain of Custody ❑ Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 1/18/2016 Certificate of Laboratory Analysis Page 4 of 75 This report shall not be reproduced, except in full. Order # J16010049 Site: ABMW-2 Collection Date: 05-Jan-16 3:55 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 8.3 mg/L 0.1 Sulfate 130 mg/L 2.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 1.62 mg/L 0.005 Barium (Ba) 0.250 mg/L 0.005 Boron (B) 7.52 mg/L 0.05 Iron (Fe) 0.940 mg/L 0.01 Manganese (Mn) 0.261 mg/L 0.005 Strontium (Sr) 1.92 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 59.8 mg/L 0.01 Magnesium (Mg) 6.41 mg/L 0.005 Potassium (K) 12.0 mg/L 0.1 Sodium (Na) 3.66 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 2.41 mg/L 0.005 Barium (Ba) 0.224 mg/L 0.005 Boron (B) 7.95 mg/L 0.05 Iron (Fe) 0.374 mg/L 0.01 Manganese (Mn) 0.106 mg/L 0.005 Strontium (Sr) 2.04 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000257 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/07/2016 12:57 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/06/2016 18:14 BGN9034 25 EPA 300.0 01/06/2016 18:14 BGN9034 1 EPA 245.1 01/07/2016 09:28 ACPAYNE 1 EPA 245.1 01/07/2016 13:26 ACPAYNE 1 EPA 200.7 01/06/2016 14:14 FCJORDA 1 EPA 200.7 01/06/2016 14:14 FCJORDA 1 EPA 200.7 01/06/2016 14:14 FCJORDA 1 EPA 200.7 01/06/2016 14:14 FCJORDA 1 EPA 200.7 01/06/2016 14:14 FCJORDA 1 EPA 200.7 01/06/2016 14:14 FCJORDA 1 EPA 200.7 01/06/2016 14:14 FCJORDA 1 EPA 200.7 01/07/2016 13:21 FCJORDA 1 EPA 200.7 01/07/2016 13:21 FCJORDA 1 EPA 200.7 01/07/2016 13:21 FCJORDA 1 EPA 200.7 01/07/2016 13:21 FCJORDA 1 EPA 200.7 01/08/2016 11:07 FCJORDA 1 EPA 200.7 01/08/2016 11:07 FCJORDA 1 EPA 200.7 01/08/2016 11:07 FCJORDA 1 EPA 200.7 01/08/2016 11:07 FCJORDA 1 EPA 200.7 01/08/2016 11:07 FCJORDA 1 EPA 200.7 01/08/2016 11:07 FCJORDA 1 EPA 200.7 01/08/2016 11:07 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: ABMW-2 Collection Date: 05-Jan-16 3:55 PM Analyte Result Units Qualifiers TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) 3.15 ug/L Arsenic (As) 524 ug/L M4 Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) < 1 ug/L Cobalt (Co) < 1 ug/L Copper (Cu) < 1 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) 625 ug/L M4 Nickel (Ni) 1.65 ug/L Selenium (Se) 3.32 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level 2.76 ug/L TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) 3.91 ug/L Arsenic (As) 525 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) < 1 ug/L Cobalt (Co) < 1 ug/L Copper (Cu) < 1 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) 792 ug/L Nickel (Ni) 2.21 ug/L Selenium (Se) 3.39 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level 9.19 ug/L METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 310 mg/L Total Carbon TOC 6.9 mg/L TOTAL SUSPENDED SOLIDS TSS 6.0 mg/L Page 5 of 75 Sample #: 2016000257 Matrix: GW WW RDL DF Method Analysis Date/Time Analyst 1 1 EPA 200.8 01/08/2016 23:15 SLS2560 10 10 EPA 200.8 01/08/2016 23:15 SLS2560 1 1 EPA 200.8 01/08/2016 23:15 SLS2560 1 1 EPA 200.8 01/08/2016 23:15 SLS2560 1 1 EPA 200.8 01/08/2016 23:15 SLS2560 1 1 EPA 200.8 01/08/2016 23:15 SLS2560 1 1 EPA 200.8 01/08/2016 23:15 SLS2560 1 1 EPA 200.8 01/08/2016 23:15 SLS2560 10 10 EPA 200.8 01/08/2016 23:15 SLS2560 1 1 EPA 200.8 01/08/2016 23:15 SLS2560 1 1 EPA 200.8 01/08/2016 23:15 SLS2560 0.2 1 EPA 200.8 01/08/2016 23:15 SLS2560 0.3 1 EPA 200.8 01/08/2016 23:15 SLS2560 1 1 EPA 200.8 01/08/2016 12:22 SLS2560 10 10 EPA 200.8 01/08/2016 12:22 SLS2560 1 1 EPA 200.8 01/08/2016 12:22 SLS2560 1 1 EPA 200.8 01/08/2016 12:22 SLS2560 1 1 EPA 200.8 01/08/2016 12:22 SLS2560 1 1 EPA 200.8 01/08/2016 12:22 SLS2560 1 1 EPA 200.8 01/08/2016 12:22 SLS2560 1 1 EPA 200.8 01/08/2016 12:22 SLS2560 10 10 EPA 200.8 01/08/2016 12:22 SLS2560 1 1 EPA 200.8 01/08/2016 12:22 SLS2560 1 1 EPA 200.8 01/08/2016 12:22 SLS2560 0.2 1 EPA 200.8 01/08/2016 12:22 SLS2560 0.3 1 EPA 200.8 01/08/2016 12:22 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 25 1 SM2540C 01/07/201615:07 CJELLIO 1 10 SM5310C/EPA9060A 01/09/201615:01 GHUTCHI 5 1 SM2540D 01/07/201610:20 CJELLIO Certificate of Laboratory Analysis Page 6 of 75 This report shall not be reproduced, except in full. Order # J16010049 Site: MW-15BR Collection Date: 05-Jan-16 1:40 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.010 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 34 mg/L 1 Sulfate 22 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.009 mg/L 0.005 Barium (Ba) 0.015 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.011 mg/L 0.01 Manganese (Mn) 0.008 mg/L 0.005 Strontium (Sr) 0.090 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 38.0 mg/L 0.01 Magnesium (Mg) 7.76 mg/L 0.005 Potassium (K) 7.58 mg/L 0.1 Sodium (Na) 35.3 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.164 mg/L 0.005 Barium (Ba) 0.016 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.262 mg/L 0.01 Manganese (Mn) 0.010 mg/L 0.005 Strontium (Sr) 0.092 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000258 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/07/2016 12:59 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/06/2016 18:32 BGN9034 10 EPA 300.0 01/06/2016 18:32 BGN9034 1 EPA 245.1 01/07/2016 09:30 ACPAYNE 1 EPA 245.1 01/07/2016 13:29 ACPAYNE 1 EPA 200.7 01/06/2016 14:18 FCJORDA 1 EPA 200.7 01/06/2016 14:18 FCJORDA 1 EPA 200.7 01/06/2016 14:18 FCJORDA 1 EPA 200.7 01/06/2016 14:18 FCJORDA 1 EPA 200.7 01/06/2016 14:18 FCJORDA 1 EPA 200.7 01/06/2016 14:18 FCJORDA 1 EPA 200.7 01/06/2016 14:18 FCJORDA 1 EPA 200.7 01/07/2016 13:25 FCJORDA 1 EPA 200.7 01/07/2016 13:25 FCJORDA 1 EPA 200.7 01/07/2016 13:25 FCJORDA 1 EPA 200.7 01/07/2016 13:25 FCJORDA 1 EPA 200.7 01/08/2016 11:11 FCJORDA 1 EPA 200.7 01/08/2016 11:11 FCJORDA 1 EPA 200.7 01/08/2016 11:11 FCJORDA 1 EPA 200.7 01/08/2016 11:11 FCJORDA 1 EPA 200.7 01/08/2016 11:11 FCJORDA 1 EPA 200.7 01/08/2016 11:11 FCJORDA 1 EPA 200.7 01/08/2016 11:11 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: MW-15BR Collection Date: 05-Jan-16 1:40 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 12.3 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 13.8 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 280 mg/L 25 Total Carbon TOC 0.694 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 7 of 75 Sample #: 2016000258 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/08/2016 23:44 SLS2560 1 EPA 200.8 01/08/2016 23:44 SLS2560 1 EPA 200.8 01/08/2016 23:44 SLS2560 1 EPA 200.8 01/08/2016 23:44 SLS2560 1 EPA 200.8 01/08/2016 23:44 SLS2560 1 EPA 200.8 01/08/2016 23:44 SLS2560 1 EPA 200.8 01/08/2016 23:44 SLS2560 1 EPA 200.8 01/08/2016 23:44 SLS2560 1 EPA 200.8 01/08/2016 23:44 SLS2560 1 EPA 200.8 01/08/2016 23:44 SLS2560 1 EPA 200.8 01/08/2016 23:44 SLS2560 1 EPA 200.8 01/08/2016 23:44 SLS2560 1 EPA 200.8 01/08/2016 23:44 SLS2560 1 EPA 200.8 01/08/2016 12:26 SLS2560 1 EPA 200.8 01/08/2016 12:26 SLS2560 1 EPA 200.8 01/08/2016 12:26 SLS2560 1 EPA 200.8 01/08/2016 12:26 SLS2560 1 EPA 200.8 01/08/2016 12:26 SLS2560 1 EPA 200.8 01/08/2016 12:26 SLS2560 1 EPA 200.8 01/08/2016 12:26 SLS2560 1 EPA 200.8 01/08/2016 12:26 SLS2560 1 EPA 200.8 01/08/2016 12:26 SLS2560 1 EPA 200.8 01/08/2016 12:26 SLS2560 1 EPA 200.8 01/08/2016 12:26 SLS2560 1 EPA 200.8 01/08/2016 12:26 SLS2560 1 EPA 200.8 01/08/2016 12:26 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/07/201615:07 CJELLIO 1 SM5310C/EPA9060A 01/09/201615:01 GHUTCHI 1 SM2540D 01/07/201610:20 CJELLIO Certificate of Laboratory Analysis Page 8 of 75 This report shall not be reproduced, except in full. Order # J16010049 Site: MW-15D Collection Date: 05-Jan-16 1:20 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 3.0 mg-N/L 0.05 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 40 mg/L 1 Sulfate 24 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.007 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.048 mg/L 0.005 Strontium (Sr) 0.230 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 60.4 mg/L 0.1 Magnesium (Mg) 24.3 mg/L 0.05 Potassium (K) < 1 mg/L 1 Sodium (Na) 26.3 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.201 mg/L 0.005 Barium (Ba) 0.008 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.240 mg/L 0.01 Manganese (Mn) 0.048 mg/L 0.005 Strontium (Sr) 0.231 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000259 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 5 EPA 353.2 01/07/2016 13:07 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/06/2016 18:50 BGN9034 10 EPA 300.0 01/06/2016 18:50 BGN9034 1 EPA 245.1 01/07/2016 09:33 ACPAYNE 1 EPA 245.1 01/07/2016 13:36 ACPAYNE 1 EPA 200.7 01/06/2016 14:22 FCJORDA 1 EPA 200.7 01/06/2016 14:22 FCJORDA 1 EPA 200.7 01/06/2016 14:22 FCJORDA 1 EPA 200.7 01/06/2016 14:22 FCJORDA 1 EPA 200.7 01/06/2016 14:22 FCJORDA 1 EPA 200.7 01/06/2016 14:22 FCJORDA 1 EPA 200.7 01/06/2016 14:22 FCJORDA 10 EPA 200.7 01/07/2016 13:29 FCJORDA 10 EPA 200.7 01/07/2016 13:29 FCJORDA 10 EPA 200.7 01/07/2016 13:29 FCJORDA 10 EPA 200.7 01/07/2016 13:29 FCJORDA 1 EPA 200.7 01/08/2016 11:20 FCJORDA 1 EPA 200.7 01/08/2016 11:20 FCJORDA 1 EPA 200.7 01/08/2016 11:20 FCJORDA 1 EPA 200.7 01/08/2016 11:20 FCJORDA 1 EPA 200.7 01/08/2016 11:20 FCJORDA 1 EPA 200.7 01/08/2016 11:20 FCJORDA 1 EPA 200.7 01/08/2016 11:20 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: MW-15D Collection Date: 05-Jan-16 1:20 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 1.43 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 14.9 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 7.37 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 1.77 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 15.2 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 8.03 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 430 mg/L 25 Total Carbon TOC 0.935 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 9 of 75 Sample #: 2016000259 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/08/2016 23:49 SLS2560 1 EPA 200.8 01/08/2016 23:49 SLS2560 1 EPA 200.8 01/08/2016 23:49 SLS2560 1 EPA 200.8 01/08/2016 23:49 SLS2560 1 EPA 200.8 01/08/2016 23:49 SLS2560 1 EPA 200.8 01/08/2016 23:49 SLS2560 1 EPA 200.8 01/08/2016 23:49 SLS2560 1 EPA 200.8 01/08/2016 23:49 SLS2560 1 EPA 200.8 01/08/2016 23:49 SLS2560 1 EPA 200.8 01/08/2016 23:49 SLS2560 1 EPA 200.8 01/08/2016 23:49 SLS2560 1 EPA 200.8 01/08/2016 23:49 SLS2560 1 EPA 200.8 01/08/2016 23:49 SLS2560 1 EPA 200.8 01/08/2016 12:31 SLS2560 1 EPA 200.8 01/08/2016 12:31 SLS2560 1 EPA 200.8 01/08/2016 12:31 SLS2560 1 EPA 200.8 01/08/2016 12:31 SLS2560 1 EPA 200.8 01/08/2016 12:31 SLS2560 1 EPA 200.8 01/08/2016 12:31 SLS2560 1 EPA 200.8 01/08/2016 12:31 SLS2560 1 EPA 200.8 01/08/2016 12:31 SLS2560 1 EPA 200.8 01/08/2016 12:31 SLS2560 1 EPA 200.8 01/08/2016 12:31 SLS2560 1 EPA 200.8 01/08/2016 12:31 SLS2560 1 EPA 200.8 01/08/2016 12:31 SLS2560 1 EPA 200.8 01/08/2016 12:31 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/07/201615:07 CJELLIO 1 SM5310C/EPA9060A 01/09/201615:01 GHUTCHI 1 SM2540D 01/07/201610:20 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: BG-1 BR Collection Date: 05-Jan-16 12:20 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.295 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 12 mg/L 0.5 Sulfate 21 mg/L 0.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.027 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.073 mg/L 0.01 Manganese (Mn) 0.402 mg/L 0.005 Strontium (Sr) 0.166 mg/L 0.005 Zinc (Zn) 0.058 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 58.2 mg/L 0.01 Magnesium (Mg) 13.5 mg/L 0.005 Potassium (K) 5.09 mg/L 0.1 Sodium (Na) 21.9 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.118 mg/L 0.005 Barium (Ba) 0.033 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.375 mg/L 0.01 Manganese (Mn) 0.445 mg/L 0.005 Strontium (Sr) 0.163 mg/L 0.005 Zinc (Zn) 0.051 mg/L 0.005 Sample #: 2016000260 Matrix: GW WW Page 10 of 75 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/07/2016 13:01 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/06/2016 19:08 BGN9034 5 EPA 300.0 01/06/2016 19:08 BGN9034 1 EPA 245.1 01/07/2016 09:35 ACPAYNE 1 EPA 245.1 01/07/2016 13:40 ACPAYNE 1 EPA 200.7 01/06/2016 14:26 FCJORDA 1 EPA 200.7 01/06/2016 14:26 FCJORDA 1 EPA 200.7 01/06/2016 14:26 FCJORDA 1 EPA 200.7 01/06/2016 14:26 FCJORDA 1 EPA 200.7 01/06/2016 14:26 FCJORDA 1 EPA 200.7 01/06/2016 14:26 FCJORDA 1 EPA 200.7 01/06/2016 14:26 FCJORDA 1 EPA 200.7 01/07/2016 13:33 FCJORDA 1 EPA 200.7 01/07/2016 13:33 FCJORDA 1 EPA 200.7 01/07/2016 13:33 FCJORDA 1 EPA 200.7 01/07/2016 13:33 FCJORDA 1 EPA 200.7 01/08/2016 11:43 FCJORDA 1 EPA 200.7 01/08/2016 11:43 FCJORDA 1 EPA 200.7 01/08/2016 11:43 FCJORDA 1 EPA 200.7 01/08/2016 11:43 FCJORDA 1 EPA 200.7 01/08/2016 11:43 FCJORDA 1 EPA 200.7 01/08/2016 11:43 FCJORDA 1 EPA 200.7 01/08/2016 11:43 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: BG-1 BR Collection Date: 05-Jan-16 12:20 PM Analyte Result Units Qualifiers TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L Arsenic (As) < 1 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) < 1 ug/L Cobalt (Co) < 1 ug/L Copper (Cu) < 1 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) 14.8 ug/L Nickel (Ni) 1.43 ug/L Selenium (Se) < 1 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level 1.03 ug/L TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L Arsenic (As) < 1 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) 1.96 ug/L Cobalt (Co) < 1 ug/L Copper (Cu) < 1 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) 9.26 ug/L Nickel (Ni) 2.10 ug/L Selenium (Se) < 1 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level 1.25 ug/L METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 330 mg/L Total Carbon TOC 0.693 mg/L TOTAL SUSPENDED SOLIDS TSS < 5 mg/L Page 11 of 75 Sample #: 2016000260 Matrix: GW WW RDL DF Method Analysis Date/Time Analyst 1 1 EPA 200.8 01/08/2016 23:54 SLS2560 1 1 EPA 200.8 01/08/2016 23:54 SLS2560 1 1 EPA 200.8 01/08/2016 23:54 SLS2560 1 1 EPA 200.8 01/08/2016 23:54 SLS2560 1 1 EPA 200.8 01/08/2016 23:54 SLS2560 1 1 EPA 200.8 01/08/2016 23:54 SLS2560 1 1 EPA 200.8 01/08/2016 23:54 SLS2560 1 1 EPA 200.8 01/08/2016 23:54 SLS2560 1 1 EPA 200.8 01/08/2016 23:54 SLS2560 1 1 EPA 200.8 01/08/2016 23:54 SLS2560 1 1 EPA 200.8 01/08/2016 23:54 SLS2560 0.2 1 EPA 200.8 01/08/2016 23:54 SLS2560 0.3 1 EPA 200.8 01/08/2016 23:54 SLS2560 1 1 EPA 200.8 01/08/2016 12:48 SLS2560 1 1 EPA 200.8 01/08/2016 12:48 SLS2560 1 1 EPA 200.8 01/08/2016 12:48 SLS2560 1 1 EPA 200.8 01/08/2016 12:48 SLS2560 1 1 EPA 200.8 01/08/2016 12:48 SLS2560 1 1 EPA 200.8 01/08/2016 12:48 SLS2560 1 1 EPA 200.8 01/08/2016 12:48 SLS2560 1 1 EPA 200.8 01/08/2016 12:48 SLS2560 1 1 EPA 200.8 01/08/2016 12:48 SLS2560 1 1 EPA 200.8 01/08/2016 12:48 SLS2560 1 1 EPA 200.8 01/08/2016 12:48 SLS2560 0.2 1 EPA 200.8 01/08/2016 12:48 SLS2560 0.3 1 EPA 200.8 01/08/2016 12:48 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 25 1 SM2540C 01/07/201615:07 CJELLIO 0.1 1 SM5310C/EPA9060A 01/09/201615:01 GHUTCHI 5 1 SM2540D 01/07/201610:20 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: MW-4BR Collection Date: 05-Jan-16 12:15 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.156 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 19 mg/L 1 Sulfate 39 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.008 mg/L 0.005 Barium (Ba) 0.036 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.011 mg/L 0.005 Strontium (Sr) 0.225 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 23.6 mg/L 0.01 Magnesium (Mg) 10.1 mg/L 0.005 Potassium (K) 11.0 mg/L 0.1 Sodium (Na) 35.0 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.085 mg/L 0.005 Barium (Ba) 0.044 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.078 mg/L 0.01 Manganese (Mn) 0.017 mg/L 0.005 Strontium (Sr) 0.246 mg/L 0.005 Zinc (Zn) 0.008 mg/L 0.005 Sample #: 2016000261 Matrix: GW WW Page 12 of 75 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/07/2016 13:02 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/06/2016 20:55 BGN9034 10 EPA 300.0 01/06/2016 20:55 BGN9034 1 EPA 245.1 01/07/2016 09:37 ACPAYNE 1 EPA 245.1 01/07/2016 13:43 ACPAYNE 1 EPA 200.7 01/06/2016 14:38 FCJORDA 1 EPA 200.7 01/06/2016 14:38 FCJORDA 1 EPA 200.7 01/06/2016 14:38 FCJORDA 1 EPA 200.7 01/06/2016 14:38 FCJORDA 1 EPA 200.7 01/06/2016 14:38 FCJORDA 1 EPA 200.7 01/06/2016 14:38 FCJORDA 1 EPA 200.7 01/06/2016 14:38 FCJORDA 1 EPA 200.7 01/07/2016 13:46 FCJORDA 1 EPA 200.7 01/07/2016 13:46 FCJORDA 1 EPA 200.7 01/07/2016 13:46 FCJORDA 1 EPA 200.7 01/07/2016 13:46 FCJORDA 1 EPA 200.7 01/08/2016 10:33 FCJORDA 1 EPA 200.7 01/08/2016 10:33 FCJORDA 1 EPA 200.7 01/08/2016 10:33 FCJORDA 1 EPA 200.7 01/08/2016 10:33 FCJORDA 1 EPA 200.7 01/08/2016 10:33 FCJORDA 1 EPA 200.7 01/08/2016 10:33 FCJORDA 1 EPA 200.7 01/08/2016 10:33 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: MW-4BR Collection Date: 05-Jan-16 12:15 PM Analyte Result Units Qualifiers TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) 1.63 ug/L Arsenic (As) 1.27 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) 1.40 ug/L Cobalt (Co) < 1 ug/L Copper (Cu) < 1 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) 8.10 ug/L Nickel (Ni) < 1 ug/L Selenium (Se) < 1 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level 2.44 ug/L TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) 1.10 ug/L Arsenic (As) 1.15 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) 1.75 ug/L Cobalt (Co) < 1 ug/L Copper (Cu) < 1 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) 8.53 ug/L Nickel (Ni) < 1 ug/L Selenium (Se) < 1 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level 1.85 ug/L METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 220 mg/L Total Carbon TOC 1.0 mg/L TOTAL SUSPENDED SOLIDS TSS < 5 mg/L Page 13 of 75 Sample #: 2016000261 Matrix: GW WW RDL DF Method Analysis Date/Time Analyst 1 1 EPA 200.8 01/08/2016 23:58 SLS2560 1 1 EPA 200.8 01/08/2016 23:58 SLS2560 1 1 EPA 200.8 01/08/2016 23:58 SLS2560 1 1 EPA 200.8 01/08/2016 23:58 SLS2560 1 1 EPA 200.8 01/08/2016 23:58 SLS2560 1 1 EPA 200.8 01/08/2016 23:58 SLS2560 1 1 EPA 200.8 01/08/2016 23:58 SLS2560 1 1 EPA 200.8 01/08/2016 23:58 SLS2560 1 1 EPA 200.8 01/08/2016 23:58 SLS2560 1 1 EPA 200.8 01/08/2016 23:58 SLS2560 1 1 EPA 200.8 01/08/2016 23:58 SLS2560 0.2 1 EPA 200.8 01/08/2016 23:58 SLS2560 0.3 1 EPA 200.8 01/08/2016 23:58 SLS2560 1 1 EPA 200.8 01/08/2016 12:53 SLS2560 1 1 EPA 200.8 01/08/2016 12:53 SLS2560 1 1 EPA 200.8 01/08/2016 12:53 SLS2560 1 1 EPA 200.8 01/08/2016 12:53 SLS2560 1 1 EPA 200.8 01/08/2016 12:53 SLS2560 1 1 EPA 200.8 01/08/2016 12:53 SLS2560 1 1 EPA 200.8 01/08/2016 12:53 SLS2560 1 1 EPA 200.8 01/08/2016 12:53 SLS2560 1 1 EPA 200.8 01/08/2016 12:53 SLS2560 1 1 EPA 200.8 01/08/2016 12:53 SLS2560 1 1 EPA 200.8 01/08/2016 12:53 SLS2560 0.2 1 EPA 200.8 01/08/2016 12:53 SLS2560 0.3 1 EPA 200.8 01/08/2016 12:53 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 25 1 SM2540C 01/07/201615:07 CJELLIO 0.1 1 SM5310C/EPA9060A 01/09/201615:01 GHUTCHI 5 1 SM2540D 01/07/201610:20 CJELLIO Certificate of Laboratory Analysis Page 14 of 75 This report shall not be reproduced, except in full. Order # J16010049 Site: MW-18D Collection Date: 05-Jan-16 4:20 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.198 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 170 mg/L 2.5 Sulfate 39 mg/L 2.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.016 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.262 mg/L 0.01 Manganese (Mn) 0.955 mg/L 0.005 Strontium (Sr) 0.616 mg/L 0.005 Zinc (Zn) 0.007 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 85.3 mg/L 0.1 Magnesium (Mg) 42.3 mg/L 0.05 Potassium (K) 2.96 mg/L 1 Sodium (Na) 21.9 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.031 mg/L 0.005 Barium (Ba) 0.019 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.334 mg/L 0.01 Manganese (Mn) 0.978 mg/L 0.005 Strontium (Sr) 0.629 mg/L 0.005 Zinc (Zn) 0.008 mg/L 0.005 Sample #: 2016000262 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/07/2016 13:03 LSTARL1 Vendor Method V_PACE 25 EPA 300.0 01/06/2016 21:49 BGN9034 25 EPA 300.0 01/06/2016 21:49 BGN9034 1 EPA 245.1 01/07/2016 09:40 ACPAYNE 1 EPA 245.1 01/07/2016 13:45 ACPAYNE 1 EPA 200.7 01/06/2016 14:42 FCJORDA 1 EPA 200.7 01/06/2016 14:42 FCJORDA 1 EPA 200.7 01/06/2016 14:42 FCJORDA 1 EPA 200.7 01/06/2016 14:42 FCJORDA 1 EPA 200.7 01/06/2016 14:42 FCJORDA 1 EPA 200.7 01/06/2016 14:42 FCJORDA 1 EPA 200.7 01/06/2016 14:42 FCJORDA 10 EPA 200.7 01/07/2016 13:50 FCJORDA 10 EPA 200.7 01/07/2016 13:50 FCJORDA 10 EPA 200.7 01/07/2016 13:50 FCJORDA 10 EPA 200.7 01/07/2016 13:50 FCJORDA 1 EPA 200.7 01/08/2016 11:46 FCJORDA 1 EPA 200.7 01/08/2016 11:46 FCJORDA 1 EPA 200.7 01/08/2016 11:46 FCJORDA 1 EPA 200.7 01/08/2016 11:46 FCJORDA 1 EPA 200.7 01/08/2016 11:46 FCJORDA 1 EPA 200.7 01/08/2016 11:46 FCJORDA 1 EPA 200.7 01/08/2016 11:46 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: MW-18D Collection Date: 05-Jan-16 4:20 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 1.58 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 6.21 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) 1.75 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.900 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 2.00 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 6.08 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) 1.64 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 1.10 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 610 mg/L 25 Total Carbon TOC 2.4 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 15 of 75 Sample #: 2016000262 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 00:03 SLS2560 1 EPA 200.8 01/09/2016 00:03 SLS2560 1 EPA 200.8 01/09/2016 00:03 SLS2560 1 EPA 200.8 01/09/2016 00:03 SLS2560 1 EPA 200.8 01/09/2016 00:03 SLS2560 1 EPA 200.8 01/09/2016 00:03 SLS2560 1 EPA 200.8 01/09/2016 00:03 SLS2560 1 EPA 200.8 01/09/2016 00:03 SLS2560 1 EPA 200.8 01/09/2016 00:03 SLS2560 1 EPA 200.8 01/09/2016 00:03 SLS2560 1 EPA 200.8 01/09/2016 00:03 SLS2560 1 EPA 200.8 01/09/2016 00:03 SLS2560 1 EPA 200.8 01/09/2016 00:03 SLS2560 1 EPA 200.8 01/08/2016 12:57 SLS2560 1 EPA 200.8 01/08/2016 12:57 SLS2560 1 EPA 200.8 01/08/2016 12:57 SLS2560 1 EPA 200.8 01/08/2016 12:57 SLS2560 1 EPA 200.8 01/08/2016 12:57 SLS2560 1 EPA 200.8 01/08/2016 12:57 SLS2560 1 EPA 200.8 01/08/2016 12:57 SLS2560 1 EPA 200.8 01/08/2016 12:57 SLS2560 1 EPA 200.8 01/08/2016 12:57 SLS2560 1 EPA 200.8 01/08/2016 12:57 SLS2560 1 EPA 200.8 01/08/2016 12:57 SLS2560 1 EPA 200.8 01/08/2016 12:57 SLS2560 1 EPA 200.8 01/08/2016 12:57 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/07/201615:07 CJELLIO 1 SM5310C/EPA9060A 01/09/201615:01 GHUTCHI 1 SM2540D 01/07/201610:20 CJELLIO Certificate of Laboratory Analysis Page 16 of 75 This report shall not be reproduced, except in full. Order # J16010049 Site: MW-18BR Collection Date: 05-Jan-16 3:20 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 120 mg/L 2.5 Sulfate 5.0 mg/L 0.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.056 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 1.06 mg/L 0.01 Manganese (Mn) 0.875 mg/L 0.005 Strontium (Sr) 0.221 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 94.5 mg/L 0.1 Magnesium (Mg) 21.7 mg/L 0.05 Potassium (K) 4.52 mg/L 1 Sodium (Na) 18.8 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.071 mg/L 0.005 Barium (Ba) 0.062 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 1.26 mg/L 0.01 Manganese (Mn) 0.874 mg/L 0.005 Strontium (Sr) 0.232 mg/L 0.005 Zinc (Zn) 0.007 mg/L 0.005 Sample #: 2016000263 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/07/2016 13:05 LSTARL1 Vendor Method V_PACE 25 EPA 300.0 01/07/2016 00:12 BGN9034 5 EPA 300.0 01/07/2016 00:12 BGN9034 1 EPA 245.1 01/07/2016 09:42 ACPAYNE 1 EPA 245.1 01/07/2016 13:52 ACPAYNE 1 EPA 200.7 01/06/2016 14:45 FCJORDA 1 EPA 200.7 01/06/2016 14:45 FCJORDA 1 EPA 200.7 01/06/2016 14:45 FCJORDA 1 EPA 200.7 01/06/2016 14:45 FCJORDA 1 EPA 200.7 01/06/2016 14:45 FCJORDA 1 EPA 200.7 01/06/2016 14:45 FCJORDA 1 EPA 200.7 01/06/2016 14:45 FCJORDA 10 EPA 200.7 01/07/2016 13:55 FCJORDA 10 EPA 200.7 01/07/2016 13:55 FCJORDA 10 EPA 200.7 01/07/2016 13:55 FCJORDA 10 EPA 200.7 01/07/2016 13:55 FCJORDA 1 EPA 200.7 01/08/2016 11:50 FCJORDA 1 EPA 200.7 01/08/2016 11:50 FCJORDA 1 EPA 200.7 01/08/2016 11:50 FCJORDA 1 EPA 200.7 01/08/2016 11:50 FCJORDA 1 EPA 200.7 01/08/2016 11:50 FCJORDA 1 EPA 200.7 01/08/2016 11:50 FCJORDA 1 EPA 200.7 01/08/2016 11:50 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: MW-18BR Collection Date: 05-Jan-16 3:20 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 3.73 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 4.24 ug/L 1 Cobalt (Co) 1.63 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 4.92 ug/L 1 Nickel (Ni) 2.11 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 530 mg/L 25 Total Carbon TOC 3.0 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 8.0 mg/L 5 Page 17 of 75 Sample #: 2016000263 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 00:08 SLS2560 1 EPA 200.8 01/09/2016 00:08 SLS2560 1 EPA 200.8 01/09/2016 00:08 SLS2560 1 EPA 200.8 01/09/2016 00:08 SLS2560 1 EPA 200.8 01/09/2016 00:08 SLS2560 1 EPA 200.8 01/09/2016 00:08 SLS2560 1 EPA 200.8 01/09/2016 00:08 SLS2560 1 EPA 200.8 01/09/2016 00:08 SLS2560 1 EPA 200.8 01/09/2016 00:08 SLS2560 1 EPA 200.8 01/09/2016 00:08 SLS2560 1 EPA 200.8 01/09/2016 00:08 SLS2560 1 EPA 200.8 01/09/2016 00:08 SLS2560 1 EPA 200.8 01/09/2016 00:08 SLS2560 1 EPA 200.8 01/08/2016 13:01 SLS2560 1 EPA 200.8 01/08/2016 13:01 SLS2560 1 EPA 200.8 01/08/2016 13:01 SLS2560 1 EPA 200.8 01/08/2016 13:01 SLS2560 1 EPA 200.8 01/08/2016 13:01 SLS2560 1 EPA 200.8 01/08/2016 13:01 SLS2560 1 EPA 200.8 01/08/2016 13:01 SLS2560 1 EPA 200.8 01/08/2016 13:01 SLS2560 1 EPA 200.8 01/08/2016 13:01 SLS2560 1 EPA 200.8 01/08/2016 13:01 SLS2560 1 EPA 200.8 01/08/2016 13:01 SLS2560 1 EPA 200.8 01/08/2016 13:01 SLS2560 1 EPA 200.8 01/08/2016 13:01 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/07/201615:07 CJELLIO 1 SM5310C/EPA9060A 01/09/201615:01 GHUTCHI 1 SM2540D 01/07/201610:20 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: MW-05D Collection Date: 05-Jan-16 1:05 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.838 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 14 mg/L 1 Sulfate 470 mg/L 10 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.039 mg/L 0.005 Boron (B) 0.945 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.063 mg/L 0.005 Strontium (Sr) 0.439 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 84.9 mg/L 0.01 Magnesium (Mg) 20.7 mg/L 0.005 Potassium (K) 2.18 mg/L 0.1 Sodium (Na) 87.8 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.007 mg/L 0.005 Barium (Ba) 0.041 mg/L 0.005 Boron (B) 0.950 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.057 mg/L 0.005 Strontium (Sr) 0.440 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Page 18 of 75 Sample #: 2016000264 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/07/2016 13:14 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/07/2016 00:30 BGN9034 100 EPA 300.0 01/07/2016 00:30 BGN9034 1 EPA 245.1 01/07/2016 09:44 ACPAYNE 1 EPA 245.1 01/07/2016 13:59 ACPAYNE 1 EPA 200.7 01/06/2016 14:54 FCJORDA 1 EPA 200.7 01/06/2016 14:54 FCJORDA 1 EPA 200.7 01/06/2016 14:54 FCJORDA 1 EPA 200.7 01/06/2016 14:54 FCJORDA 1 EPA 200.7 01/06/2016 14:54 FCJORDA 1 EPA 200.7 01/06/2016 14:54 FCJORDA 1 EPA 200.7 01/06/2016 14:54 FCJORDA 1 EPA 200.7 01/07/2016 13:59 FCJORDA 1 EPA 200.7 01/07/2016 13:59 FCJORDA 1 EPA 200.7 01/07/2016 13:59 FCJORDA 1 EPA 200.7 01/07/2016 13:59 FCJORDA 1 EPA 200.7 01/08/2016 11:57 FCJORDA 1 EPA 200.7 01/08/2016 11:57 FCJORDA 1 EPA 200.7 01/08/2016 11:57 FCJORDA 1 EPA 200.7 01/08/2016 11:57 FCJORDA 1 EPA 200.7 01/08/2016 11:57 FCJORDA 1 EPA 200.7 01/08/2016 11:57 FCJORDA 1 EPA 200.7 01/08/2016 11:57 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: MW-05D Collection Date: 05-Jan-16 1:05 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 19.4 ug/L 1 Nickel (Ni) 1.88 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 9.14 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 20.2 ug/L 1 Nickel (Ni) 1.76 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 9.23 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 900 mg/L 25 Total Carbon TOC 1.2 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 19 of 75 Sample #: 2016000264 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 00:23 SLS2560 1 EPA 200.8 01/09/2016 00:23 SLS2560 1 EPA 200.8 01/09/2016 00:23 SLS2560 1 EPA 200.8 01/09/2016 00:23 SLS2560 1 EPA 200.8 01/09/2016 00:23 SLS2560 1 EPA 200.8 01/09/2016 00:23 SLS2560 1 EPA 200.8 01/09/2016 00:23 SLS2560 1 EPA 200.8 01/09/2016 00:23 SLS2560 1 EPA 200.8 01/09/2016 00:23 SLS2560 1 EPA 200.8 01/09/2016 00:23 SLS2560 1 EPA 200.8 01/09/2016 00:23 SLS2560 1 EPA 200.8 01/09/2016 00:23 SLS2560 1 EPA 200.8 01/09/2016 00:23 SLS2560 1 EPA 200.8 01/08/2016 12:04 SLS2560 1 EPA 200.8 01/08/2016 12:04 SLS2560 1 EPA 200.8 01/08/2016 12:04 SLS2560 1 EPA 200.8 01/08/2016 12:04 SLS2560 1 EPA 200.8 01/08/2016 12:04 SLS2560 1 EPA 200.8 01/08/2016 12:04 SLS2560 1 EPA 200.8 01/08/2016 12:04 SLS2560 1 EPA 200.8 01/08/2016 12:04 SLS2560 1 EPA 200.8 01/08/2016 12:04 SLS2560 1 EPA 200.8 01/08/2016 12:04 SLS2560 1 EPA 200.8 01/08/2016 12:04 SLS2560 1 EPA 200.8 01/08/2016 12:04 SLS2560 1 EPA 200.8 01/08/2016 12:04 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/07/201615:07 CJELLIO 1 SM5310C/EPA9060A 01/09/201615:01 GHUTCHI 1 SM2540D 01/07/201610:20 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: MW-05BR Collection Date: 05-Jan-16 11:25 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.026 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 14 mg/L 0.5 Sulfate 160 mg/L 2.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.007 mg/L 0.005 Barium (Ba) 0.016 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.348 mg/L 0.01 Manganese (Mn) 0.194 mg/L 0.005 Strontium (Sr) 0.287 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 84.0 mg/L 0.01 Magnesium (Mg) 20.8 mg/L 0.005 Potassium (K) 4.66 mg/L 0.1 Sodium (Na) 16.1 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.023 mg/L 0.005 Barium (Ba) 0.018 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.594 mg/L 0.01 Manganese (Mn) 0.196 mg/L 0.005 Strontium (Sr) 0.290 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000265 Matrix: GW WW Page 20 of 75 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/07/2016 13:18 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/07/2016 00:48 BGN9034 25 EPA 300.0 01/07/2016 00:48 BGN9034 1 EPA 245.1 01/07/2016 09:56 ACPAYNE 1 EPA 245.1 01/07/2016 14:01 ACPAYNE 1 EPA 200.7 01/06/2016 14:58 FCJORDA 1 EPA 200.7 01/06/2016 14:58 FCJORDA 1 EPA 200.7 01/06/2016 14:58 FCJORDA 1 EPA 200.7 01/06/2016 14:58 FCJORDA 1 EPA 200.7 01/06/2016 14:58 FCJORDA 1 EPA 200.7 01/06/2016 14:58 FCJORDA 1 EPA 200.7 01/06/2016 14:58 FCJORDA 1 EPA 200.7 01/07/2016 14:03 FCJORDA 1 EPA 200.7 01/07/2016 14:03 FCJORDA 1 EPA 200.7 01/07/2016 14:03 FCJORDA 1 EPA 200.7 01/07/2016 14:03 FCJORDA 1 EPA 200.7 01/08/2016 11:31 FCJORDA 1 EPA 200.7 01/08/2016 11:31 FCJORDA 1 EPA 200.7 01/08/2016 11:31 FCJORDA 1 EPA 200.7 01/08/2016 11:31 FCJORDA 1 EPA 200.7 01/08/2016 11:31 FCJORDA 1 EPA 200.7 01/08/2016 11:31 FCJORDA 1 EPA 200.7 01/08/2016 11:31 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: MW-05BR Collection Date: 05-Jan-16 11:25 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 4.95 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 4.39 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 4.42 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 4.64 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 470 mg/L 25 Total Carbon TOC 1.2 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 21 of 75 Sample #: 2016000265 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 00:13 SLS2560 1 EPA 200.8 01/09/2016 00:13 SLS2560 1 EPA 200.8 01/09/2016 00:13 SLS2560 1 EPA 200.8 01/09/2016 00:13 SLS2560 1 EPA 200.8 01/09/2016 00:13 SLS2560 1 EPA 200.8 01/09/2016 00:13 SLS2560 1 EPA 200.8 01/09/2016 00:13 SLS2560 1 EPA 200.8 01/09/2016 00:13 SLS2560 1 EPA 200.8 01/09/2016 00:13 SLS2560 1 EPA 200.8 01/09/2016 00:13 SLS2560 1 EPA 200.8 01/09/2016 00:13 SLS2560 1 EPA 200.8 01/09/2016 00:13 SLS2560 1 EPA 200.8 01/09/2016 00:13 SLS2560 1 EPA 200.8 01/08/2016 14:17 SLS2560 1 EPA 200.8 01/08/2016 14:17 SLS2560 1 EPA 200.8 01/08/2016 14:17 SLS2560 1 EPA 200.8 01/08/2016 14:17 SLS2560 1 EPA 200.8 01/08/2016 14:17 SLS2560 1 EPA 200.8 01/08/2016 14:17 SLS2560 1 EPA 200.8 01/08/2016 14:17 SLS2560 1 EPA 200.8 01/08/2016 14:17 SLS2560 1 EPA 200.8 01/08/2016 14:17 SLS2560 1 EPA 200.8 01/08/2016 14:17 SLS2560 1 EPA 200.8 01/08/2016 14:17 SLS2560 1 EPA 200.8 01/08/2016 14:17 SLS2560 1 EPA 200.8 01/08/2016 14:17 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/07/201615:07 CJELLIO 1 SM5310C/EPA9060A 01/09/201615:01 GHUTCHI 1 SM2540D 01/07/201610:20 CJELLIO Certificate of Laboratory Analysis Page 22 of 75 This report shall not be reproduced, except in full. Order # J16010049 Site: MW-01 Collection Date: 05-Jan-16 3:15 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 47 mg/L 1 Sulfate 120 mg/L 2.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.116 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.073 mg/L 0.005 Strontium (Sr) 0.494 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 53.8 mg/L 0.01 Magnesium (Mg) 20.8 mg/L 0.005 Potassium (K) 1.47 mg/L 0.1 Sodium (Na) 30.2 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.029 mg/L 0.005 Barium (Ba) 0.124 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.035 mg/L 0.01 Manganese (Mn) 0.100 mg/L 0.005 Strontium (Sr) 0.509 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 Sample #: 2016000266 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/07/2016 13:19 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/07/2016 01:06 BGN9034 25 EPA 300.0 01/07/2016 01:06 BGN9034 1 EPA 245.1 01/07/2016 10:03 ACPAYNE 1 EPA 245.1 01/07/2016 14:04 ACPAYNE 1 EPA 200.7 01/06/2016 15:02 FCJORDA 1 EPA 200.7 01/06/2016 15:02 FCJORDA 1 EPA 200.7 01/06/2016 15:02 FCJORDA 1 EPA 200.7 01/06/2016 15:02 FCJORDA 1 EPA 200.7 01/06/2016 15:02 FCJORDA 1 EPA 200.7 01/06/2016 15:02 FCJORDA 1 EPA 200.7 01/06/2016 15:02 FCJORDA 1 EPA 200.7 01/07/2016 14:07 FCJORDA 1 EPA 200.7 01/07/2016 14:07 FCJORDA 1 EPA 200.7 01/07/2016 14:07 FCJORDA 1 EPA 200.7 01/07/2016 14:07 FCJORDA 1 EPA 200.7 01/08/2016 12:01 FCJORDA 1 EPA 200.7 01/08/2016 12:01 FCJORDA 1 EPA 200.7 01/08/2016 12:01 FCJORDA 1 EPA 200.7 01/08/2016 12:01 FCJORDA 1 EPA 200.7 01/08/2016 12:01 FCJORDA 1 EPA 200.7 01/08/2016 12:01 FCJORDA 1 EPA 200.7 01/08/2016 12:01 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: MW-01 Collection Date: 05-Jan-16 3:15 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 6.09 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 6.30 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 450 mg/L 25 Total Carbon TOC 1.6 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 23 of 75 Sample #: 2016000266 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 00:18 SLS2560 1 EPA 200.8 01/09/2016 00:18 SLS2560 1 EPA 200.8 01/09/2016 00:18 SLS2560 1 EPA 200.8 01/09/2016 00:18 SLS2560 1 EPA 200.8 01/09/2016 00:18 SLS2560 1 EPA 200.8 01/09/2016 00:18 SLS2560 1 EPA 200.8 01/09/2016 00:18 SLS2560 1 EPA 200.8 01/09/2016 00:18 SLS2560 1 EPA 200.8 01/09/2016 00:18 SLS2560 1 EPA 200.8 01/09/2016 00:18 SLS2560 1 EPA 200.8 01/09/2016 00:18 SLS2560 1 EPA 200.8 01/09/2016 00:18 SLS2560 1 EPA 200.8 01/09/2016 00:18 SLS2560 1 EPA 200.8 01/08/2016 13:23 SLS2560 1 EPA 200.8 01/08/2016 13:23 SLS2560 1 EPA 200.8 01/08/2016 13:23 SLS2560 1 EPA 200.8 01/08/2016 13:23 SLS2560 1 EPA 200.8 01/08/2016 13:23 SLS2560 1 EPA 200.8 01/08/2016 13:23 SLS2560 1 EPA 200.8 01/08/2016 13:23 SLS2560 1 EPA 200.8 01/08/2016 13:23 SLS2560 1 EPA 200.8 01/08/2016 13:23 SLS2560 1 EPA 200.8 01/08/2016 13:23 SLS2560 1 EPA 200.8 01/08/2016 13:23 SLS2560 1 EPA 200.8 01/08/2016 13:23 SLS2560 1 EPA 200.8 01/08/2016 13:23 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/07/201615:07 CJELLIO 1 SM5310C/EPA9060A 01/09/201615:01 GHUTCHI 1 SM2540D 01/07/201610:20 CJELLIO Certificate of Laboratory Analysis Page 24 of 75 This report shall not be reproduced, except in full. Order # J16010049 Site: MW-02 Collection Date: 05-Jan-16 4:45 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.109 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 90 mg/L 2 Sulfate 63 mg/L 2 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 0.09 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.212 mg/L 0.005 Boron (B) 0.182 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.027 mg/L 0.005 Strontium (Sr) 0.614 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 46.8 mg/L 0.01 Magnesium (Mg) 19.1 mg/L 0.005 Potassium (K) 1.64 mg/L 0.1 Sodium (Na) 28.3 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.007 mg/L 0.005 Barium (Ba) 0.197 mg/L 0.005 Boron (B) 0.105 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.022 mg/L 0.005 Strontium (Sr) 0.497 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000267 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/07/2016 13:20 LSTARL1 Vendor Method V_PACE 20 EPA 300.0 01/06/2016 23:19 BGN9034 20 EPA 300.0 01/06/2016 23:19 BGN9034 1 EPA 245.1 01/07/2016 10:06 ACPAYNE 1 EPA 245.1 01/07/2016 14:06 ACPAYNE 1 EPA 200.7 01/06/2016 15:06 FCJORDA 1 EPA 200.7 01/06/2016 15:06 FCJORDA 1 EPA 200.7 01/06/2016 15:06 FCJORDA 1 EPA 200.7 01/06/2016 15:06 FCJORDA 1 EPA 200.7 01/06/2016 15:06 FCJORDA 1 EPA 200.7 01/06/2016 15:06 FCJORDA 1 EPA 200.7 01/06/2016 15:06 FCJORDA 1 EPA 200.7 01/07/2016 14:12 FCJORDA 1 EPA 200.7 01/07/2016 14:12 FCJORDA 1 EPA 200.7 01/07/2016 14:12 FCJORDA 1 EPA 200.7 01/07/2016 14:12 FCJORDA 1 EPA 200.7 01/08/2016 12:05 FCJORDA 1 EPA 200.7 01/08/2016 12:05 FCJORDA 1 EPA 200.7 01/08/2016 12:05 FCJORDA 1 EPA 200.7 01/08/2016 12:05 FCJORDA 1 EPA 200.7 01/08/2016 12:05 FCJORDA 1 EPA 200.7 01/08/2016 12:05 FCJORDA 1 EPA 200.7 01/08/2016 12:05 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: MW-02 Collection Date: 05-Jan-16 4:45 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 5.62 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 6.18 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 440 mg/L 25 Total Carbon TOC 0.737 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 25 of 75 Sample #: 2016000267 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 00:52 SLS2560 1 EPA 200.8 01/09/2016 00:52 SLS2560 1 EPA 200.8 01/09/2016 00:52 SLS2560 1 EPA 200.8 01/09/2016 00:52 SLS2560 1 EPA 200.8 01/09/2016 00:52 SLS2560 1 EPA 200.8 01/09/2016 00:52 SLS2560 1 EPA 200.8 01/09/2016 00:52 SLS2560 1 EPA 200.8 01/09/2016 00:52 SLS2560 1 EPA 200.8 01/09/2016 00:52 SLS2560 1 EPA 200.8 01/09/2016 00:52 SLS2560 1 EPA 200.8 01/09/2016 00:52 SLS2560 1 EPA 200.8 01/09/2016 00:52 SLS2560 1 EPA 200.8 01/09/2016 00:52 SLS2560 1 EPA 200.8 01/08/2016 13:06 SLS2560 1 EPA 200.8 01/08/2016 13:06 SLS2560 1 EPA 200.8 01/08/2016 13:06 SLS2560 1 EPA 200.8 01/08/2016 13:06 SLS2560 1 EPA 200.8 01/08/2016 13:06 SLS2560 1 EPA 200.8 01/08/2016 13:06 SLS2560 1 EPA 200.8 01/08/2016 13:06 SLS2560 1 EPA 200.8 01/08/2016 13:06 SLS2560 1 EPA 200.8 01/08/2016 13:06 SLS2560 1 EPA 200.8 01/08/2016 13:06 SLS2560 1 EPA 200.8 01/08/2016 13:06 SLS2560 1 EPA 200.8 01/08/2016 13:06 SLS2560 1 EPA 200.8 01/08/2016 13:06 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/07/201615:07 CJELLIO 1 SM5310C/EPA9060A 01/09/201615:01 GHUTCHI 1 SM2540D 01/07/201610:20 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: Filter Blank Collection Date: 05-Jan-16 10:30 AM Analyte Result Units Qualifiers RDL Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2016000268 Matrix: GW WW Page 26 of 75 DF Method Analysis Date/Time Analyst 1 EPA 245.1 01/07/2016 14:09 ACPAYNE 1 EPA 200.7 01/06/2016 15:09 FCJORDA 1 EPA 200.7 01/06/2016 15:09 FCJORDA 1 EPA 200.7 01/06/2016 15:09 FCJORDA 1 EPA 200.7 01/06/2016 15:09 FCJORDA 1 EPA 200.7 01/06/2016 15:09 FCJORDA 1 EPA 200.7 01/06/2016 15:09 FCJORDA 1 EPA 200.7 01/06/2016 15:09 FCJORDA 1 EPA 200.8 01/09/2016 00:57 SLS2560 1 EPA 200.8 01/09/2016 00:57 SLS2560 1 EPA 200.8 01/09/2016 00:57 SLS2560 1 EPA 200.8 01/09/2016 00:57 SLS2560 1 EPA 200.8 01/09/2016 00:57 SLS2560 1 EPA 200.8 01/09/2016 00:57 SLS2560 1 EPA 200.8 01/09/2016 00:57 SLS2560 1 EPA 200.8 01/09/2016 00:57 SLS2560 1 EPA 200.8 01/09/2016 00:57 SLS2560 1 EPA 200.8 01/09/2016 00:57 SLS2560 1 EPA 200.8 01/09/2016 00:57 SLS2560 1 EPA 200.8 01/09/2016 00:57 SLS2560 1 EPA 200.8 01/09/2016 00:57 SLS2560 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: EQUIP BLANK Collection Date: 05-Jan-16 10:30 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analvsis Performed by Pace Laboratories Vendor Parameter Complete INORGANIC IONS BY IC Chloride < 0.1 mg/L 0.1 Sulfate < 0.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 UNDIGESTED METALS BY ICP Calcium (Ca) 0.016 mg/L 0.01 Magnesium (Mg) < 0.005 mg/L 0.005 Potassium (K) < 0.1 mg/L 0.1 Sodium (Na) < 0.05 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2016000269 Matrix: GW WW Page 27 of 75 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/07/2016 12:51 LSTARL1 Vendor Method V_PACE 1 EPA 300.0 01/06/2016 20:37 BGN9034 1 EPA 300.0 01/06/2016 20:37 BGN9034 1 EPA 245.1 01/07/2016 10:08 ACPAYNE 1 EPA 200.7 01/07/2016 14:16 FCJORDA 1 EPA 200.7 01/07/2016 14:16 FCJORDA 1 EPA 200.7 01/07/2016 14:16 FCJORDA 1 EPA 200.7 01/07/2016 14:16 FCJORDA 1 EPA 200.7 01/08/2016 12:08 FCJORDA 1 EPA 200.7 01/08/2016 12:08 FCJORDA 1 EPA 200.7 01/08/2016 12:08 FCJORDA 1 EPA 200.7 01/08/2016 12:08 FCJORDA 1 EPA 200.7 01/08/2016 12:08 FCJORDA 1 EPA 200.7 01/08/2016 12:08 FCJORDA 1 EPA 200.7 01/08/2016 12:08 FCJORDA 1 EPA 200.8 01/08/2016 13:27 SLS2560 1 EPA 200.8 01/08/2016 13:27 SLS2560 1 EPA 200.8 01/08/2016 13:27 SLS2560 1 EPA 200.8 01/08/2016 13:27 SLS2560 1 EPA 200.8 01/08/2016 13:27 SLS2560 1 EPA 200.8 01/08/2016 13:27 SLS2560 1 EPA 200.8 01/08/2016 13:27 SLS2560 1 EPA 200.8 01/08/2016 13:27 SLS2560 1 EPA 200.8 01/08/2016 13:27 SLS2560 1 EPA 200.8 01/08/2016 13:27 SLS2560 1 EPA 200.8 01/08/2016 13:27 SLS2560 1 EPA 200.8 01/08/2016 13:27 SLS2560 1 EPA 200.8 01/08/2016 13:27 SLS2560 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: EQUIP BLANK Collection Date: 05-Jan-16 10:30 AM Analyte Result Units Qualifiers RDL DF METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 Total Carbon Page 28 of 75 Sample #: 2016000269 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE SM2540C 01/07/201615:07 CJELLIO TOC 0.199 mg/L 0.1 1 SM5310C/EPA9060A 01/09/201615:01 GHUTCHI TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 01/07/2016 10:20 CJELLIO Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: BG-01 Collection Date: 05-Jan-16 11:42 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 2.6 mg-N/L 0.02 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 18 mg/L 0.5 Sulfate 23 mg/L 0.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.085 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.008 mg/L 0.005 Strontium (Sr) 0.436 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 43.4 mg/L 0.01 Magnesium (Mg) 20.6 mg/L 0.005 Potassium (K) 1.87 mg/L 0.1 Sodium (Na) 31.6 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.434 mg/L 0.005 Barium (Ba) 0.091 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.484 mg/L 0.01 Manganese (Mn) 0.017 mg/L 0.005 Strontium (Sr) 0.445 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000270 Matrix: GW WW Page 29 of 75 DF Method Analysis Date/Time Analyst Vendor Method V_PACE 2 EPA 353.2 01/07/2016 13:06 LSTARL1 Vendor Method V_PACE 5 EPA 300.0 01/06/2016 23:37 BGN9034 5 EPA 300.0 01/06/2016 23:37 BGN9034 1 EPA 245.1 01/07/2016 10:10 ACPAYNE 1 EPA 245.1 01/07/2016 14:11 ACPAYNE 1 EPA 200.7 01/06/2016 15:13 FCJORDA 1 EPA 200.7 01/06/2016 15:13 FCJORDA 1 EPA 200.7 01/06/2016 15:13 FCJORDA 1 EPA 200.7 01/06/2016 15:13 FCJORDA 1 EPA 200.7 01/06/2016 15:13 FCJORDA 1 EPA 200.7 01/06/2016 15:13 FCJORDA 1 EPA 200.7 01/06/2016 15:13 FCJORDA 1 EPA 200.7 01/07/2016 14:20 FCJORDA 1 EPA 200.7 01/07/2016 14:20 FCJORDA 1 EPA 200.7 01/07/2016 14:20 FCJORDA 1 EPA 200.7 01/07/2016 14:20 FCJORDA 1 EPA 200.7 01/08/2016 12:12 FCJORDA 1 EPA 200.7 01/08/2016 12:12 FCJORDA 1 EPA 200.7 01/08/2016 12:12 FCJORDA 1 EPA 200.7 01/08/2016 12:12 FCJORDA 1 EPA 200.7 01/08/2016 12:12 FCJORDA 1 EPA 200.7 01/08/2016 12:12 FCJORDA 1 EPA 200.7 01/08/2016 12:12 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: BG-01 Collection Date: 05-Jan-16 11:42 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 4.88 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 1.51 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 15.4 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 9.02 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) 2.49 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 2.96 ug/L 1 Selenium (Se) 1.01 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 17.5 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 350 mg/L 25 Total Carbon TOC 0.579 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 8.0 mg/L 5 Page 30 of 75 Sample #: 2016000270 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 01:02 SLS2560 1 EPA 200.8 01/09/2016 01:02 SLS2560 1 EPA 200.8 01/09/2016 01:02 SLS2560 1 EPA 200.8 01/09/2016 01:02 SLS2560 1 EPA 200.8 01/09/2016 01:02 SLS2560 1 EPA 200.8 01/09/2016 01:02 SLS2560 1 EPA 200.8 01/09/2016 01:02 SLS2560 1 EPA 200.8 01/09/2016 01:02 SLS2560 1 EPA 200.8 01/09/2016 01:02 SLS2560 1 EPA 200.8 01/09/2016 01:02 SLS2560 1 EPA 200.8 01/09/2016 01:02 SLS2560 1 EPA 200.8 01/09/2016 01:02 SLS2560 1 EPA 200.8 01/09/2016 01:02 SLS2560 1 EPA 200.8 01/08/2016 13:45 SLS2560 1 EPA 200.8 01/08/2016 13:45 SLS2560 1 EPA 200.8 01/08/2016 13:45 SLS2560 1 EPA 200.8 01/08/2016 13:45 SLS2560 1 EPA 200.8 01/08/2016 13:45 SLS2560 1 EPA 200.8 01/08/2016 13:45 SLS2560 1 EPA 200.8 01/08/2016 13:45 SLS2560 1 EPA 200.8 01/08/2016 13:45 SLS2560 1 EPA 200.8 01/08/2016 13:45 SLS2560 1 EPA 200.8 01/08/2016 13:45 SLS2560 1 EPA 200.8 01/08/2016 13:45 SLS2560 1 EPA 200.8 01/08/2016 13:45 SLS2560 1 EPA 200.8 01/08/2016 13:45 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/07/201615:07 CJELLIO 1 SM5310C/EPA9060A 01/09/201615:01 GHUTCHI 1 SM2540D 01/07/201610:20 CJELLIO Certificate of Laboratory Analysis Page 31 of 75 This report shall not be reproduced, except in full. Order # J16010049 Site: CW-4 Collection Date: 05-Jan-16 2:20 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.438 mg-N/L 0.01 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete INORGANIC IONS BY IC Chloride 26 mg/L 1 Sulfate 36 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.127 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) 0.185 mg/L 0.005 Zinc (Zn) 0.007 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 42.9 mg/L 0.1 Magnesium (Mg) 27.4 mg/L 0.05 Potassium (K) 3.98 mg/L 1 Sodium (Na) 46.0 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.033 mg/L 0.005 Barium (Ba) 0.131 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.029 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) 0.189 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2016000271 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_PACE 1 EPA 353.2 01/07/2016 12:56 LSTARL1 Vendor Method V_PACE 10 EPA 300.0 01/06/2016 23:55 BGN9034 10 EPA 300.0 01/06/2016 23:55 BGN9034 1 EPA 245.1 01/07/2016 10:13 ACPAYNE 1 EPA 245.1 01/11/2016 16:39 ACPAYNE 1 EPA 200.7 01/06/2016 15:25 FCJORDA 1 EPA 200.7 01/06/2016 15:25 FCJORDA 1 EPA 200.7 01/06/2016 15:25 FCJORDA 1 EPA 200.7 01/06/2016 15:25 FCJORDA 1 EPA 200.7 01/06/2016 15:25 FCJORDA 1 EPA 200.7 01/06/2016 15:25 FCJORDA 1 EPA 200.7 01/06/2016 15:25 FCJORDA 10 EPA 200.7 01/07/2016 14:24 FCJORDA 10 EPA 200.7 01/07/2016 14:24 FCJORDA 10 EPA 200.7 01/07/2016 14:24 FCJORDA 10 EPA 200.7 01/07/2016 14:24 FCJORDA 1 EPA 200.7 01/08/2016 12:16 FCJORDA 1 EPA 200.7 01/08/2016 12:16 FCJORDA 1 EPA 200.7 01/08/2016 12:16 FCJORDA 1 EPA 200.7 01/08/2016 12:16 FCJORDA 1 EPA 200.7 01/08/2016 12:16 FCJORDA 1 EPA 200.7 01/08/2016 12:16 FCJORDA 1 EPA 200.7 01/08/2016 12:16 FCJORDA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16010049 Site: CW-4 Collection Date: 05-Jan-16 2:20 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 5.76 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 1.86 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 5.98 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 2.07 ug/L 0.3 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 360 mg/L 25 Total Carbon TOC 0.788 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Page 32 of 75 Sample #: 2016000271 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 01/09/2016 02:20 SLS2560 1 EPA 200.8 01/09/2016 02:20 SLS2560 1 EPA 200.8 01/09/2016 02:20 SLS2560 1 EPA 200.8 01/09/2016 02:20 SLS2560 1 EPA 200.8 01/09/2016 02:20 SLS2560 1 EPA 200.8 01/09/2016 02:20 SLS2560 1 EPA 200.8 01/09/2016 02:20 SLS2560 1 EPA 200.8 01/09/2016 02:20 SLS2560 1 EPA 200.8 01/09/2016 02:20 SLS2560 1 EPA 200.8 01/09/2016 02:20 SLS2560 1 EPA 200.8 01/09/2016 02:20 SLS2560 1 EPA 200.8 01/09/2016 02:20 SLS2560 1 EPA 200.8 01/09/2016 02:20 SLS2560 1 EPA 200.8 01/08/2016 13:49 SLS2560 1 EPA 200.8 01/08/2016 13:49 SLS2560 1 EPA 200.8 01/08/2016 13:49 SLS2560 1 EPA 200.8 01/08/2016 13:49 SLS2560 1 EPA 200.8 01/08/2016 13:49 SLS2560 1 EPA 200.8 01/08/2016 13:49 SLS2560 1 EPA 200.8 01/08/2016 13:49 SLS2560 1 EPA 200.8 01/08/2016 13:49 SLS2560 1 EPA 200.8 01/08/2016 13:49 SLS2560 1 EPA 200.8 01/08/2016 13:49 SLS2560 1 EPA 200.8 01/08/2016 13:49 SLS2560 1 EPA 200.8 01/08/2016 13:49 SLS2560 1 EPA 200.8 01/08/2016 13:49 SLS2560 Vendor Method V_PACE Vendor Method V_PACE 1 SM2540C 01/07/201615:07 CJELLIO 1 SM5310C/EPA9060A 01/09/201615:01 GHUTCHI 1 SM2540D 01/07/201610:20 CJELLIO Certificate of Laboratory Analysis Page 33 of 75 This report shall not be reproduced, except in full. Order # J16010049 Qualifiers: M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to the spike level. The associated Laboratory Control Spike recovery was acceptable. aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K�i vfte. Suite 100 y Huntersville, INC 28078 (704)875-9092 January 11, 2016 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J16010049 ROXBORO Pace Project No.: 92281984 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on January 06, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Program Manager, Duke Energy Anne Pifer Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 40 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. OQ9l9gC8f fge. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J16010049 ROXBORO Pace Project No.: 92281984 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 525 N 8th Street, Salina, KS 67401 A21-A Certification M 2926.01 Alaska Certification M UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification M 88-0680 California Certification M 01155CA Colorado Certification #Pace Connecticut Certification M PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification M 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification M 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification M 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification M 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification M E83079 Georgia Certification M 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification M 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification M E-10383 Kentucky Certification #: 90050 Louisiana Certification M FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification M Cert 0074 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification M TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification M 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J16010049 ROXBORO Pace Project No.: 92281984 Lab ID Sample ID Matrix Date Collected Date Received 92281984001 2016000257 Water 01/05/1615:55 01/06/1611:11 92281984002 2016000258 Water 01/05/1613:40 01/06/1611:11 92281984003 2016000259 Water 01/05/1613:20 01/06/1611:11 92281984004 2016000260 Water 01/05/1612:20 01/06/1611:11 92281984005 2016000261 Water 01/05/1612:15 01/06/1611:11 92281984006 2016000262 Water 01/05/1616:20 01/06/1611:11 92281984007 2016000263 Water 01/05/1615:20 01/06/1611:11 92281984008 2016000264 Water 01/05/1613:05 01/06/1611:11 92281984009 2016000265 Water 01/05/1611:25 01/06/1611:11 92281984010 2016000266 Water 01/05/1615:15 01/06/1611:11 92281984011 2016000267 Water 01/05/1616:45 01/06/1611:11 92281984012 2016000269 Water 01/05/1610:30 01/06/1611:11 92281984013 2016000270 Water 01/05/1611:42 01/06/1611:11 92281984014 2016000271 Water 01/05/1614:20 01/06/1611:11 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098v i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J16010049 ROXBORO 92281984 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92281984001 2016000257 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92281984002 2016000258 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92281984003 2016000259 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92281984004 2016000260 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92281984005 2016000261 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92281984006 2016000262 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92281984007 2016000263 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92281984008 2016000264 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92281984009 2016000265 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92281984010 2016000266 RSK 175 DR1 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J16010049 ROXBORO Pace Project No.: 92281984 Analytes Lab ID Sample ID Method Analysts Reported Laboratory SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92281984011 2016000267 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92281984012 2016000269 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92281984013 2016000270 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O 92281984014 2016000271 RSK 175 DR1 1 PASI-M SM 2320B MLS 3 PASI-A SM 4500-S2D MJP 1 PASI-A EPA 218.7 TK1 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J16010049 ROXBORO 92281984 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92281984001 2016000257 RSK 175 Methane 10800 ug/L 10.0 01/07/16 17:23 SM 2320B Alkalinity, Bicarbonate (CaCO3) 83.7 mg/L 5.0 01/07/16 17:13 SM 2320B Alkalinity, Total as CaCO3 83.7 mg/L 5.0 01/07/16 17:13 92281984002 2016000258 SM 2320B Alkalinity, Bicarbonate (CaCO3) 145 mg/L 5.0 01/07/16 17:26 SM 2320B Alkalinity, Total as CaCO3 145 mg/L 5.0 01/07/16 17:26 92281984003 2016000259 SM 2320B Alkalinity, Bicarbonate (CaCO3) 233 mg/L 5.0 01/07/16 18:17 SM 2320B Alkalinity, Total as CaCO3 233 mg/L 5.0 01/07/16 18:17 EPA 218.7 Chromium, Hexavalent 1.5 ug/L 0.30 01/08/1610:18 M6 92281984004 2016000260 SM 2320B Alkalinity, Bicarbonate (CaCO3) 227 mg/L 5.0 01/07/16 19:02 SM 2320B Alkalinity, Total as CaCO3 227 mg/L 5.0 01/07/16 19:02 92281984005 2016000261 SM 2320B Alkalinity, Bicarbonate (CaCO3) 123 mg/L 5.0 01/07/16 19:17 SM 2320B Alkalinity, Total as CaCO3 123 mg/L 5.0 01/07/16 19:17 EPA 218.7 Chromium, Hexavalent 0.43 ug/L 0.15 01/08/1610:57 92281984006 2016000262 SM 2320B Alkalinity, Bicarbonate (CaCO3) 237 mg/L 5.0 01/07/16 19:28 SM 2320B Alkalinity, Total as CaCO3 237 mg/L 5.0 01/07/16 19:28 EPA 218.7 Chromium, Hexavalent 0.78 ug/L 0.15 01/08/1611:10 92281984007 2016000263 RSK 175 Methane 11.7 ug/L 10.0 01/07/16 18:37 SM 2320B Alkalinity, Bicarbonate (CaCO3) 195 mg/L 5.0 01/07/16 19:43 SM 2320B Alkalinity, Total as CaCO3 195 mg/L 5.0 01/07/16 19:43 92281984008 2016000264 SM 2320B Alkalinity, Bicarbonate (CaCO3) 104 mg/L 5.0 01/07/16 19:56 SM 2320B Alkalinity, Total as CaCO3 104 mg/L 5.0 01/07/16 19:56 EPA 218.7 Chromium, Hexavalent 0.15 ug/L 0.030 01/08/16 01:15 92281984009 2016000265 SM 2320B Alkalinity, Bicarbonate (CaCO3) 186 mg/L 5.0 01/07/16 20:28 SM 2320B Alkalinity, Total as CaCO3 186 mg/L 5.0 01/07/16 20:28 92281984010 2016000266 SM 2320B Alkalinity, Bicarbonate (CaCO3) 120 mg/L 5.0 01/07/16 20:40 SM 2320B Alkalinity, Total as CaCO3 120 mg/L 5.0 01/07/16 20:40 EPA 218.7 Chromium, Hexavalent 0.081 ug/L 0.030 01/08/16 01:41 92281984011 2016000267 SM 2320B Alkalinity, Bicarbonate (CaCO3) 91.1 mg/L 5.0 01/07/16 20:53 SM 2320B Alkalinity, Total as CaCO3 91.1 mg/L 5.0 01/07/16 20:53 EPA 218.7 Chromium, Hexavalent 0.072 ug/L 0.030 01/08/16 01:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J16010049 ROXBORO Pace Project No.: 92281984 Lab Sample ID Method 92281984013 SM 2320B SM 2320B EPA 218.7 92281984014 SM 2320B SM 2320B EPA 218.7 SUMMARY OF DETECTION Client Sample ID Parameters 2016000270 Alkalinity, Bicarbonate (CaCO3) Alkalinity, Total as CaCO3 Chromium, Hexavalent 2016000271 Alkalinity, Bicarbonate (CaCO3) Alkalinity, Total as CaCO3 Chromium, Hexavalent Result Units 231 mg/L 231 mg/L 4.5 ug/L 236 mg/L 236 mg/L 0.29 ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Report Limit Analyzed Qualifiers 5.0 01/07/1621:14 5.0 01/07/1621:14 0.60 01/08/1611:23 5.0 01/07/1622:00 5.0 01/07/16 22:00 0.030 01/08/16 08:21 Page 7 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gWinlc8)r fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010049 ROXBORO Pace Project No.: 92281984 Method: RSK 175 Description: RSK 175 AIR Headspace Client: Duke Energy Date: January 11, 2016 General Information: 14 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinffte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010049 ROXBORO Pace Project No.: 92281984 Method: SM 2320B Description: 2320E Alkalinity Client: Duke Energy Date: January 11, 2016 General Information: 14 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WET/42338 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92281981001,92281981011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1642344) • Alkalinity, Total as CaCO3 • MSD (Lab ID: 1642345) • Alkalinity, Total as CaCO3 Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010049 ROXBORO Pace Project No.: 92281984 Method: SM 4500-S213 Description: 4500S2D Sulfide Water Client: Duke Energy Date: January 11, 2016 General Information: 14 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WET/42341 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92281981001,92281981011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1642358) • Sulfide • MS (Lab ID: 1642360) • Sulfide • MSD (Lab ID: 1642359) • Sulfide • MSD (Lab ID: 1642361) • Sulfide QC Batch: WET/42342 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92281984003,92281984013 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1642364) • Sulfide • MSD (Lab ID: 1642365) • Sulfide Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J16010049 ROXBORO Pace Project No.: 92281984 Method: EPA 218.7 Description: Hexavalent Chromium by IC Client: Duke Energy Date: January 11, 2016 General Information: 14 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010049 ROXBORO Pace Project No.: 92281984 Sample: 2016000257 Lab ID: 92281984001 Collected: 01/05/16 15:55 Received: 01/06/16 11:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 10800 ug/L 10.0 1 01/07/1617:23 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 83.7 mg/L 5.0 1 01/07/16 17:13 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/07/16 17:13 Alkalinity, Total as CaCO3 83.7 mg/L 5.0 1 01/07/16 17:13 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/07/1617:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/07/16 22:52 18540-29-9 Date: 01/11/2016 02:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010049 ROXBORO Pace Project No.: 92281984 Sample: 2016000258 Lab ID: 92281984002 Collected: 01/05/16 13:40 Received: 01/06/16 11:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/07/1617:32 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 145 mg/L 5.0 1 01/07/16 17:26 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/07/16 17:26 Alkalinity, Total as CaCO3 145 mg/L 5.0 1 01/07/16 17:26 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/07/1617:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/07/16 23:05 18540-29-9 Date: 01/11/2016 02:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010049 ROXBORO Pace Project No.: 92281984 Sample: 2016000259 Lab ID: 92281984003 Collected: 01/05/16 13:20 Received: 01/06/16 11:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/07/1617:40 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 233 mg/L 5.0 1 01/07/16 18:17 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/07/16 18:17 Alkalinity, Total as CaCO3 233 mg/L 5.0 1 01/07/16 18:17 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/07/1617:00 18496-25-8 M1 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 1.5 ug/L 0.30 10 01/08/16 10:18 18540-29-9 M6 Date: 01/11/2016 02:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010049 ROXBORO Pace Project No.: 92281984 Sample: 2016000260 Lab ID: 92281984004 Collected: 01/05/16 12:20 Received: 01/06/16 11:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/07/1618:04 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 227 mg/L 5.0 1 01/07/16 19:02 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/07/16 19:02 Alkalinity, Total as CaCO3 227 mg/L 5.0 1 01/07/16 19:02 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/07/1617:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/08/16 00:23 18540-29-9 Date: 01/11/2016 02:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010049 ROXBORO Pace Project No.: 92281984 Sample: 2016000261 Lab ID: 92281984005 Collected: 01/05/16 12:15 Received: 01/06/16 11:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/07/1618:21 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 123 mg/L 5.0 1 01/07/16 19:17 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/07/16 19:17 Alkalinity, Total as CaCO3 123 mg/L 5.0 1 01/07/16 19:17 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/07/1617:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.43 ug/L 0.15 5 01/08/16 10:57 18540-29-9 Date: 01/11/2016 02:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010049 ROXBORO Pace Project No.: 92281984 Sample: 2016000262 Lab ID: 92281984006 Collected: 01/05/16 16:20 Received: 01/06/16 11:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/07/1618:29 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 237 mg/L 5.0 1 01/07/16 19:28 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/07/16 19:28 Alkalinity, Total as CaCO3 237 mg/L 5.0 1 01/07/16 19:28 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/07/1617:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.78 ug/L 0.15 5 01/08/16 11:10 18540-29-9 Date: 01/11/2016 02:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010049 ROXBORO Pace Project No.: 92281984 Sample: 2016000263 Lab ID: 92281984007 Collected: 01/05/16 15:20 Received: 01/06/16 11:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane 11.7 ug/L 10.0 1 01/07/1618:37 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 195 mg/L 5.0 1 01/07/16 19:43 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/07/16 19:43 Alkalinity, Total as CaCO3 195 mg/L 5.0 1 01/07/16 19:43 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/07/1617:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/08/16 01:02 18540-29-9 Date: 01/11/2016 02:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010049 ROXBORO Pace Project No.: 92281984 Sample: 2016000264 Lab ID: 92281984008 Collected: 01/05/16 13:05 Received: 01/06/16 11:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/07/1618:45 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 104 mg/L 5.0 1 01/07/16 19:56 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/07/16 19:56 Alkalinity, Total as CaCO3 104 mg/L 5.0 1 01/07/16 19:56 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/07/1617:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.15 ug/L 0.030 1 01/08/16 01:15 18540-29-9 Date: 01/11/2016 02:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010049 ROXBORO Pace Project No.: 92281984 Sample: 2016000265 Lab ID: 92281984009 Collected: 01/05/16 11:25 Received: 01/06/16 11:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/07/1618:53 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 186 mg/L 5.0 1 01/07/16 20:28 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/07/16 20:28 Alkalinity, Total as CaCO3 186 mg/L 5.0 1 01/07/16 20:28 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/07/1617:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/08/16 01:28 18540-29-9 Date: 01/11/2016 02:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010049 ROXBORO Pace Project No.: 92281984 Sample: 2016000266 Lab ID: 92281984010 Collected: 01/05/16 15:15 Received: 01/06/16 11:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/07/1619:02 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 120 mg/L 5.0 1 01/07/16 20:40 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/07/16 20:40 Alkalinity, Total as CaCO3 120 mg/L 5.0 1 01/07/16 20:40 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/07/1617:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.081 ug/L 0.030 1 01/08/16 01:41 18540-29-9 Date: 01/11/2016 02:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010049 ROXBORO Pace Project No.: 92281984 Sample: 2016000267 Lab ID: 92281984011 Collected: 01/05/16 16:45 Received: 01/06/16 11:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/07/1619:10 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 91.1 mg/L 5.0 1 01/07/16 20:53 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/07/16 20:53 Alkalinity, Total as CaCO3 91.1 mg/L 5.0 1 01/07/16 20:53 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/07/1617:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.072 ug/L 0.030 1 01/08/16 01:54 18540-29-9 Date: 01/11/2016 02:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010049 ROXBORO Pace Project No.: 92281984 Sample: 2016000269 Lab ID: 92281984012 Collected: 01/05/16 10:30 Received: 01/06/16 11:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/07/1619:18 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) ND mg/L 5.0 1 01/07/16 21:06 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/07/16 21:06 Alkalinity, Total as CaCO3 ND mg/L 5.0 1 01/07/16 21:06 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/07/1617:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent ND ug/L 0.030 1 01/08/16 02:07 18540-29-9 Date: 01/11/2016 02:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010049 ROXBORO Pace Project No.: 92281984 Sample: 2016000270 Lab ID: 92281984013 Collected: 01/05/16 11:42 Received: 01/06/16 11:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/08/1610:52 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 231 mg/L 5.0 1 01/07/16 21:14 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/07/16 21:14 Alkalinity, Total as CaCO3 231 mg/L 5.0 1 01/07/16 21:14 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/07/1617:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 4.5 ug/L 0.60 20 01/08/16 11:23 18540-29-9 Date: 01/11/2016 02:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J16010049 ROXBORO Pace Project No.: 92281984 Sample: 2016000271 Lab ID: 92281984014 Collected: 01/05/16 14:20 Received: 01/06/16 11:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual RSK 175 AIR Headspace Analytical Method: RSK 175 Methane ND ug/L 10.0 1 01/08/1611:08 74-82-8 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Bicarbonate (CaCO3) 236 mg/L 5.0 1 01/07/16 22:00 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 01/07/16 22:00 Alkalinity, Total as CaCO3 236 mg/L 5.0 1 01/07/16 22:00 4500S21) Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 01/07/1617:00 18496-25-8 Hexavalent Chromium by IC Analytical Method: EPA 218.7 Chromium, Hexavalent 0.29 ug/L 0.030 1 01/08/16 08:21 18540-29-9 Date: 01/11/2016 02:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010049 ROXBORO Pace Project No.: 92281984 QC Batch: AIR/24980 Analysis Method: RSK 175 QC Batch Method: RSK 175 Analysis Description: RSK 175 AIR HEADSPACE Associated Lab Samples: 92281984001, 92281984002, 92281984003 METHOD BLANK: 2171402 Matrix: Water Associated Lab Samples: 92281984001, 92281984002, 92281984003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Methane ug/L ND 10.0 01/07/1614:16 LABORATORY CONTROL SAMPLE & LCSD: 2171403 2171404 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Methane ug/L 60.7 57.2 59.6 94 98 85-115 4 20 SAMPLE DUPLICATE: 2172103 92281981010 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 3AJ 20 SAMPLE DUPLICATE: 2172104 92281987001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L 17400 19500 12 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/11/2016 02:29 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010049 ROXBORO Pace Project No.: 92281984 QC Batch: AIR/24981 Analysis Method: RSK 175 QC Batch Method: RSK 175 Analysis Description: RSK 175 AIR HEADSPACE Associated Lab Samples: 92281984004, 92281984005, 92281984006, 92281984007, 92281984008, 92281984009, 92281984010, 92281984011,92281984012 METHOD BLANK: 2171495 Matrix: Water Associated Lab Samples: 92281984004, 92281984005, 92281984006, 92281984007, 92281984008, 92281984009, 92281984010, 92281984011,92281984012 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Methane ug/L ND 10.0 01/07/1617:56 LABORATORY CONTROL SAMPLE & LCSD: 2171496 2171497 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Methane ug/L 60.7 59.6 59.4 98 98 85-115 0 20 SAMPLE DUPLICATE: 2172105 92281984004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 3.2J 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/11/2016 02:29 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinic&�r fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010049 ROXBORO Pace Project No.: 92281984 QC Batch: AIR/24990 Analysis Method: RSK 175 QC Batch Method: RSK 175 Analysis Description: RSK 175 AIR HEADSPACE Associated Lab Samples: 92281984013, 92281984014 METHOD BLANK: 2172145 Matrix: Water Associated Lab Samples: 92281984013, 92281984014 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Methane ug/L ND 10.0 01/08/16 09:20 LABORATORY CONTROL SAMPLE & LCSD: 2172146 2172147 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Methane ug/L 60.7 57.7 59.9 95 99 85-115 4 20 SAMPLE DUPLICATE: 2172518 92281984013 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 1.2J 20 SAMPLE DUPLICATE: 2172519 92282172005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND 1.6J 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/11/2016 02:29 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010049 ROXBORO Pace Project No.: 92281984 QC Batch: WET/42338 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 92281984001, 92281984002 METHOD BLANK: 1642340 Associated Lab Samples: 92281984001, 92281984002 Parameter Units Alkalinity, Carbonate (CaCO3) mg/L Alkalinity, Total as CaCO3 mg/L Alkalinity, Bicarbonate (CaCO3) mg/L LABORATORY CONTROL SAMPLE: 1642341 Parameter Units Alkalinity, Total as CaCO3 mg/L Matrix: Water Blank Reporting Result Limit Analyzed ND 5.0 01/07/1611:52 ND 5.0 01/07/1611:52 ND 5.0 01/07/1611:52 Spike LCS Conc. Result 50 48.4 Qualifiers LCS % Rec % Rec Limits Qualifiers 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1642342 1642343 MS MSD 92281981001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 107 50 50 158 154 102 93 80-120 3 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1642344 1642345 MS MSD 92281981011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Alkalinity, Total as CaCO3 mg/L 52.9 50 50 89.6 87.2 73 69 80-120 3 25 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/11/2016 02:29 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010049 ROXBORO Pace Project No.: 92281984 QC Batch: WET/42339 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 92281984003, 92281984004, 92281984005, 92281984006, 92281984007, 92281984008, 92281984009, 92281984010,92281984011,92281984012,92281984013,92281984014 METHOD BLANK: 1642346 Matrix: Water Associated Lab Samples: 92281984003, 92281984004, 92281984005, 92281984006, 92281984007, 92281984008, 92281984009, 92281984010,92281984011,92281984012,92281984013,92281984014 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Alkalinity, Carbonate (CaCO3) mg/L ND 5.0 01/07/16 17:57 Alkalinity, Total as CaCO3 mg/L ND 5.0 01/07/16 17:57 Alkalinity, Bicarbonate (CaCO3) mg/L ND 5.0 01/07/16 17:57 LABORATORY CONTROL SAMPLE: 1642347 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 mg/L 50 48.2 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1642348 1642349 MS MSD 92281984003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Alkalinity, Total as CaCO3 mg/L 233 50 50 281 277 95 88 80-120 1 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1642350 1642351 MS MSD 92281984013 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 231 50 50 274 280 85 96 80-120 2 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/11/2016 02:29 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010049 ROXBORO Pace Project No.: 92281984 QC Batch: WET/42341 Analysis Method: SM 4500-S2D QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 92281984001, 92281984002 METHOD BLANK: 1642356 Matrix: Water Associated Lab Samples: 92281984001, 92281984002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide mg/L ND 0.10 01/07/1617:00 LABORATORY CONTROL SAMPLE: 1642357 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide mg/L .5 0.50 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1642358 1642359 MS MSD 92281981001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide mg/L 0.36 .5 .5 0.62 0.62 53 53 90-110 0 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1642360 1642361 MS MSD 92281981011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide mg/L ND .5 .5 0.43 0.43 86 86 90-110 0 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/11/2016 02:29 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010049 ROXBORO Pace Project No.: 92281984 QC Batch: WET/42342 Analysis Method: SM 4500-S2D QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 92281984003, 92281984004, 92281984005, 92281984006, 92281984007, 92281984008, 92281984009, 92281984010,92281984011,92281984012,92281984013,92281984014 METHOD BLANK: 1642362 Matrix: Water Associated Lab Samples: 92281984003, 92281984004, 92281984005, 92281984006, 92281984007, 92281984008, 92281984009, 92281984010,92281984011,92281984012,92281984013,92281984014 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide mg/L ND 0.10 01/07/1617:00 LABORATORY CONTROL SAMPLE: 1642363 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide mg/L .5 0.50 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1642364 1642365 MS MSD 92281984003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Sulfide mg/L ND .5 .5 0.43 0.43 86 86 90-110 0 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1642366 1642367 MS MSD 92281984013 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Sulfide mg/L ND .5 .5 0.46 0.46 92 92 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/11/2016 02:29 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010049 ROXBORO Pace Project No.: 92281984 QC Batch: WETA/53591 Analysis Method: EPA 218.7 QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC Associated Lab Samples: 92281984001, 92281984002 METHOD BLANK: 1440769 Matrix: Water Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chromium, Hexavalent ug/L ND 0.030 01/07/16 17:14 LABORATORY CONTROL SAMPLE: 1440770 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chromium, Hexavalent ug/L .075 0.081 107 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1440771 1440772 MS MSD 92281981001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent ug/L 0.091 .075 .075 0.16 0.16 88 90 85-115 1 20 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1440773 1440774 MS MSD 92281981011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent ug/L ND .025 .025 .024J .024J 96 94 85-115 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/11/2016 02:29 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J16010049 ROXBORO Pace Project No.: 92281984 QC Batch: WETA/53592 Analysis Method: EPA 218.7 QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC Associated Lab Samples: 92281984003, 92281984004, 92281984005, 92281984006, 92281984007, 92281984008, 92281984009, 92281984010,92281984011,92281984012,92281984013,92281984014 METHOD BLANK: 1440775 Matrix: Water Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chromium, Hexavalent ug/L ND 0.030 01/08/16 12:02 LABORATORY CONTROL SAMPLE: 1440776 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chromium, Hexavalent ug/L .075 0.076 102 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1440777 1440778 MS MSD 92281984003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent ug/L 1.5 .25 .25 1.8 1.7 112 80 85-115 5 20 M6 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1440779 1440780 MS MSD 92281984013 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium, Hexavalent ug/L 4.5 1.5 1.5 6.0 5.9 98 94 85-115 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/11/2016 02:29 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 40 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J16010049 ROXBORO Pace Project No.: 92281984 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/11/2016 02:29 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 40 acmnalytical www.pacelabs.com Pace Analytical Services, Inc. og6g I�§c&f fte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J16010049 ROXBORO Pace Project No.: 92281984 Lab ID Sample ID QC Batch Method QC Batch 92281984001 2016000257 RSK 175 AIR/24980 92281984002 2016000258 RSK 175 AIR/24980 92281984003 2016000259 RSK 175 AIR/24980 92281984004 2016000260 RSK 175 AIR/24981 92281984005 2016000261 RSK 175 AIR/24981 92281984006 2016000262 RSK 175 AIR/24981 92281984007 2016000263 RSK 175 AIR/24981 92281984008 2016000264 RSK 175 AIR/24981 92281984009 2016000265 RSK 175 AIR/24981 92281984010 2016000266 RSK 175 AIR/24981 92281984011 2016000267 RSK 175 AIR/24981 92281984012 2016000269 RSK 175 AIR/24981 92281984013 2016000270 RSK 175 AIR/24990 92281984014 2016000271 RSK 175 AIR/24990 92281984001 2016000257 SM 2320B WET/42338 92281984002 2016000258 SM 2320B WET/42338 92281984003 2016000259 SM 2320B WET/42339 92281984004 2016000260 SM 2320B WET/42339 92281984005 2016000261 SM 2320B WET/42339 92281984006 2016000262 SM 2320B WET/42339 92281984007 2016000263 SM 2320B WET/42339 92281984008 2016000264 SM 2320B WET/42339 92281984009 2016000265 SM 2320B WET/42339 92281984010 2016000266 SM 2320B WET/42339 92281984011 2016000267 SM 2320B WET/42339 92281984012 2016000269 SM 2320B WET/42339 92281984013 2016000270 SM 2320B WET/42339 92281984014 2016000271 SM 2320B WET/42339 92281984001 2016000257 SM 4500-S2D WET/42341 92281984002 2016000258 SM 4500-S2D WET/42341 92281984003 2016000259 SM 4500-S2D WET/42342 92281984004 2016000260 SM 4500-S2D WET/42342 92281984005 2016000261 SM 4500-S2D WET/42342 92281984006 2016000262 SM 4500-S2D WET/42342 92281984007 2016000263 SM 4500-S2D WET/42342 92281984008 2016000264 SM 4500-S2D WET/42342 92281984009 2016000265 SM 4500-S2D WET/42342 92281984010 2016000266 SM 4500-S2D WET/42342 92281984011 2016000267 SM 4500-S2D WET/42342 92281984012 2016000269 SM 4500-S2D WET/42342 92281984013 2016000270 SM 4500-S2D WET/42342 92281984014 2016000271 SM 4500-S2D WET/42342 92281984001 2016000257 EPA 218.7 WETA/53591 92281984002 2016000258 EPA 218.7 WETA/53591 92281984003 2016000259 EPA 218.7 WETA/53592 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/11/2016 02:29 PM without the written consent of Pace Analytical Services, Inc.. Analytical Analytical Method Batch Page 36 of 40 acmnalytical www.pacelabs.com Pace Analytical Services, Inc. og6g I�bc&f fte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J16010049 ROXBORO Pace Project No.: 92281984 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92281984004 2016000260 EPA 218.7 WETA/53592 92281984005 2016000261 EPA 218.7 WETA/53592 92281984006 2016000262 EPA 218.7 WETA/53592 92281984007 2016000263 EPA 218.7 WETA/53592 92281984008 2016000264 EPA 218.7 WETA/53592 92281984009 2016000265 EPA 218.7 WETA/53592 92281984010 2016000266 EPA 218.7 WETA/53592 92281984011 2016000267 EPA 218.7 WETA/53592 92281984012 2016000269 EPA 218.7 WETA/53592 92281984013 2016000270 EPA 218.7 WETA/53592 92281984014 2016000271 EPA 218.7 WETA/53592 Date: 01/11/2016 02:29 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch Page 37 of 40 Document Name: Document Revised: 260CT2015 2ceAr�alytica! Sample Condition Upon Receipt(SCUR) Page 1 of 2 Page 71 of 7 ' Document No.: Issuing Authority: F•CFIR-CS-003-rev.17 Pace Huntersville Quality Office Client Name: Project #: 1 �Vo Courier: []Fed Ex ❑UPS ❑USPS ❑Client ❑Commercial [Trace ❑0ther: Custody Seal on Cooler/Box Present? ❑Yes [5No Packing Material: ❑Bubble Wrap ❑Bubble Bags Th.- met- -WOi1:91281984 1111111111111111111111 92281984 Seals intact? ❑Yes ❑No ❑None ❑Other: Used: ❑ �A } 1 tType of Ice: ]Wet []Blue ❑None ❑Samples on ice, cooling process has begun Cooler Temp Corrected (°C}: l- i \1 Biological Tissue Frozen? ❑Yes ❑No]N/A: Temp should be above freezing to 6°C Correction Factor: 0.0 °C Date and Initials of Person Examining Contents: - i,(Y1 USDA Regulated Soil (❑�/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a.foreign source (internationally, Dyes [4No including Hawaii and Puerto Rlca)? ❑Yeses❑No If Yes to either question, fill out a Regulated Soil Checklist and Include with SCUR/CDC paperwork, COMMENTS: Chain of Custody Present? 2Yes ❑No ❑N/A 1. Chain of Custody Filled Out? PYes ❑No ❑N/A 2. Chain of Custody Relinquished? ❑'Yes []NO ❑N/A 3. Sampler Name and/or Signature on COC? ?es []No ❑N/A 4. Samples Arrived within Hold Time? EfYes ❑No ❑N/A 5. Short Hold Time Analysis (<72 hr)? yes ❑ o ❑N/A 6. Rush Turn Around Time Requested? Des No ❑N/A 7. Sufficient Volume? Yes ❑No ❑N/A 8. Correct Containers Used? ❑Yes ❑No ❑N/A 9. -Pace Containers Used? ©Yes 1(jNo ❑N/A Containers Intact? es ❑No ❑N/A 10. Filtered Volume Received for Dissolved Tests? ❑Yes ❑No N/A 11. Note if sediment is visible in the dissolved container Sample Labels Match COO ',dYes ❑No El N/A 12, -includes Date/Time/ID/Analysis Matrix:__ _ �'A�__� All containers needing acid/base preservation have been / 13. checked? E . ❑No containers needing preservation are found to be incompliance with EPA recommendation? jN/AAll (HNO3, HzSO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide) Yes ❑No A Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/801S (water) DOC,LLHg Des ❑No MN/A Samples checked for dechlorization []Yes []No N/A 14. Headspace in VOA Vials (>5-6mm)? ❑Yes [24 QN/A 15. Trip Blank Present? []Yes ❑No [ /A, 16. Trip Blank Custody Seals Present? ❑Yes [:]No ON/A Pace Trip Blank Lot tt (if purchased): CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Field Data-Requlred? ❑Yes [—]No Date/Time: Project Manager SCURF Review: _ �(�-� _ Date: � W Note: Whenever there is a discrepancy affecting Worth Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers). Page 38 of 40 N V ."!VpIOO p tvJO.L �: 0 o 0 a o 0 0 0 o a o 0 o w o o F N a a �DZ Ua SIB -A T ; E54.0 slew" -' N I o r-I>- ° PeAJOSsla o a MOfaq F U W i aas) slelaw IWm 5 o a (809d-A) 5 N o = IA AD T ^+ "! O O oO C? 0 i RI'I i11 i Ibaua eels n ) r U z 1 i i AIoa4S A op &4Ya4g1p°j I 'AyIuIIQHIv 1 oY a i rR a .84aji,WOOL 1 � � E 2 Al-tisi [Slt � I I C� CC M C•� � N a I � 2 m Nstif euv4�aw 'AS-d)A 1 !p Sal'SSi -� •t�� N �du+O t y a c r I L IT LL OD N � •' u M M C� � ! � C�71 ' la7 QI Y N © 1. N In t, I L) Lh jp. ! N o � i 8 !¢ O a O u m t0 « ci i 6 w 0 O m ! a LU b m I � AS 7-L u I ti 1 4_.. _._ .._.....J.._.._._._ _.._..._....__ .._.._._.._ ..... ...... .._..._.._._.._._.._....__ .._. __.._.___. !]61✓t'�a] 11 �� 11UI9] I h] Page 72 of 75 � 1 � m E a= Fy- � ci VS ¢� Q o yy L) E d punoiewnl poilsop o4Eolptll esvold ;luej1odu14'mw01sn;y S I ! I S 4 w z J y[ r l 'o J D N 4 13 13 CL I (j t �I~ aa• n z z > w w V w N wwb yy a Page 39 of 40 Page 73 of 75 I 1BU14]UOj �'. IB]O� Q p Q Q Q P O O 4 P P O G 4i O O '. N N $ a iovo s¢1EIem — - - w `s N-- u r € $ (s4'4 sletaw �]� D IO a&. , = PaAlossl© r ao p D u m ILI .J i �+ = aes) slejew "` s ` T ' a o (aaed Al m �]y3 G£ ti ,o o J r� IAJO ffT E a N 3 a C z �/ Of 0 o Q N ° - n0 "Z 4 U Q O I V \ �t3� v p Q Q i e 3I `I 1 S l o �liueul013 Al ' _ N ' ePllln& uI I F 2 V' i lA3@a3US A 2 chi I a @]@v@gJea GSe7I�1UI punonto 068 nj poiISBN' �Id :ll]�alpoli�j 'JB LUOl6n� I h s 'e]@MWODIS N a �i41uI1�11V )IN w k a s' n '&�ei3lN `9Ol ,,(r r l 'pOS'IO n a S I N N r�j i E FI@B46 A N { g 3I81il A SOVSSl E y �+ x: 4�0 Te 'AWO'J P " c � a jj1 sLL00 \3 r co ° a ' n 'V O ✓i [Ri 1si O J I I c N .� n 0. 3 C9 N N I r N zZ Vim„ sab k �iT IciN /C�) na dl - i �... _. jj chi i x m IN Lp WLu t3 6— ...... ..... ...... . C VCIE Page 40 of 40 CHAIN OF CUSTODY RECORD {ANC`? ANA . _... ._..._ I I-� e+..rt1M us.lyti.af, uebarlltavyr L Duke Eimorgy so y...mw Owl"W,0* eed #A.uix AulalytiealLaboratury lum*l.e.r.....+le Chain of Gaalpdy a YY�d~ft M. € aer+ jl' i, iktw r+ao ■ 411110 g "PW Lfla Fr- .PFtl41R ._ _ r•�I��+w+» A@ 4 W AslsesSnYan1 Yrat�9r '�` ... Pfuse 3-1s.r31Ee1� __. arr�r isnp I' "WPI,f M4?rrc" Grmmwwer_e VI.tr, IlS"lt%, 14ivAn — ,_ Page 74 of 75 MTRI13UTION SYnterra EDD CQIG REV DATE 7ii22120-in Clirri7iq ac d 9$U �7fi-fi�32 c, �f Rktrauan {0,4.5 urnj 1J - AO114208 R.R +rrTe� 1 Pff�xlp�'etlMi 15L1.61f1d"}S Unit' !1 - �i M1lfli!!] C.PFl17fIFW ISITII TX}ie r--- S„ F$ pj ; [) aCFipSICin 4r I 1',..2m„ner 1 r.+r,rµJrr dA1 apR^r-Arra[a non .,r-ded .,.&& _ .._... .,_.,_.. " GP$ Locaticlm G�ylYc4iax_lp►y € a3 S i [Mlle7f2-�to UrFf�llmnnd - b rad fei � Irs Ye � iA±� km � aJrh .�.•. �1� h PET.. pltlT �07 `. g1 PET PET PSY — H PPr. 9+ _ CL I i5 FIGPE Y11 '�.. m a g s. m th q' .n �a !_ 114 p - rpm} F 3�cq ¢ _ i j fa - U 4 -.. [j k- m eY R +r A R +- ,Ly1 — 7 i � � I . f ? r r 1 r o A C� `- � + -- Zip Filter Blank_ k Euipment Blank .% ,3'_ — a 4 & x i47+>VL 2 a" 2 2 2 1 Z 0 1 � 2 p 1s o Y ,r BIa1PYT TI 1 G { '` / H@q"ei1ed lumumund TOW20 .hod Uy[" a a '10 fhdys w ed -- nor:,, �- oxlarrella � z Dsys LO E� _ v p s ELEMENTS by ICR,IAB (T 'RId): Au, 60, Cd, Cd, Cr, Cu, Mo. NI. Pb, W $e, TI (LL), W iLL3 ELEMIENTS bj IGP {TRWS: M, far. B., ", Mn, Sr, %n ICP_Undjgeeled Ca• N1g, K, No Nq by Z"3 I ' Ada cote will Apm t7i.aalve'd mabb : 1111 rFW1*19 1CP,1415,1^69 ti CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM --j-- . IN" )�;& ftwg� AmlytK,.1 La I L"Albw:eLIM Only Duke Energy OWN C�3� jr Mmlrkm GW-ww AsAalytico I Labora" 1311« r � :: Be- MPLE PIROGIR&W Samp4o Ln -Ko' Vkvpsm]!.. I ! - NPOES ... . A19 GIN 71 RUL4.0-1, "Olt f. Po: Pace -G FINTatiael (0,45 UMIUrrfrltered PO 1142D81 LNdslalr U K: wv CahllwinOr V61MM IreleJ 2W 40 ml SM Coroninm Ty" MT glam P" PIT PU "T Sample DescrfpUon or ID 0 E GPS LbtOon Ca1WCUan mtorrneuonE L) 2 —7- 1 — F-0- --00 1 -4--k3 2 TMAL 'R a to bokw I Dtbbrn" -Pod C*kff Ir" Erv. nokirTh" 4: "-m" SaQi*&Lc k Opamd By CWF-w ELEMENTS by ICP-00 JTRMP. AS, Ov, Cal, Ca, CF. Cu, 6110, Ni, Pb, Sb. 54,. -171 MO. V 4LLO ELE MV-NTA by JCP �TRIP): A4 92, 8, F2. VM 8F, Zn MP_Unehgc&tLA Ga, Ug. K. tka tip 4V 2461 DOosdived rkwokalls: all MAftio ICP, MAO 2- Page 75 of 75 jI Dmi-RIBUTMW ORK3ML lxa LAB, GO!"Y M I.A 1� P41 SVriterra EDD cor, REV DATE 112VZD' 2N 11 n n � ice' LIM 0 1 1 '1 0 Know R&OW"Jad Tv ftiouad T" 24 -14 nwo - ffte'F ? Days vi----7 jq-� out — /3 '44 * - `ftw __fiSAR- ' Add. CAI. Will A;Vly