NC0038377_App B Fourth Round Analytical Rpts_20160701

Comprehensive Site Assessment Supplement 1 July 2016
Mayo Steam Electric Plant
APPENDIX B
FOURTH ROUND MONITORING EVENT
SynTerra
(.7ANUARY 2016) LABORATORY REPORTS
P: \Duke Energy Progress.1026\ 105. Mayo Ash Basin GW Assessment Plan\ 19.EG_CSASUP\MAYO CSA Supplement 1 July
2016.docx

Lab
DUI E Analytical Laboratory APage11aof40
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J16010048
MAYO STEAM - AB GW ASSESSMENT WATER
Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy Webb, John Toep
Anne Pifer
Anne Pifer
Phone:
Date:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
1 /15/2016
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2016000243
2016000244
2016000245
2016000246
2016000247
2016000248
2016000249
7 Total Samples
MAYO STEAM
MAYO STEAM
MAYO STEAM
MAYO STEAM
MAYO STEAM
MAYO STEAM
MAYO STEAM
05-Jan-16 10:55 AM
05-Jan-16 1:15 PM
05-Jan-16 2:28 PM
05-Jan-16 12:36 PM
05-Jan-16 10:52 AM
05-Jan-16 2:45 PM
05-Jan-16 2:45 PM
Collected By
Daniel M Youngblood
Daniel M Youngblood
Daniel M Youngblood
Daniel M Youngblood
Daniel M Youngblood
Daniel M Youngblood
Daniel M Youngblood
Sample Description
ABMW-02
ABMW-02BR
ABMW-4D
ABMW-4BR
ABMW-04
Filter Blank
Equipment Blank
Analytical Lab
Page 2 of 40

Analytical Lab
Page 3 of 40
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
CI Job Summary Report
❑� Sample Identification
Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
El Analytical Laboratory QC Report
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Mary Ann Ogle Date: 1/15/2016

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
Site: ABMW-02
Collection Date: 05-Jan-16 10:55 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.011 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
13
mg/L
0.5
Sulfate
20
mg/L
0.5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
M2 0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.024
mg/L
0.005
Barium (Ba)
0.156
mg/L
0.005
Boron (B)
7.92
mg/L
0.05
Iron (Fe)
0.415
mg/L
0.01
Manganese (Mn)
0.986
mg/L
0.005
Strontium (Sr)
1.49
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
71.9
mg/L
0.01
Magnesium (Mg)
20.0
mg/L
M4 0.005
Potassium (K)
18.3
mg/L
0.1
Sodium (Na)
35.2
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.032
mg/L
0.005
Barium (Ba)
0.173
mg/L
0.005
Boron (B)
8.44
mg/L
0.05
Iron (Fe)
0.502
mg/L
0.01
Manganese (Mn)
1.09
mg/L
0.005
Strontium (Sr)
1.61
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000243
Matrix: GW WW
Analytical Lab
Page 4 of 40
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 11:18 LSTARL1
Vendor Method V_PACE
5 EPA 300.0
01/06/2016 16:45
BGN9034
5 EPA 300.0
01/06/2016 16:45
BGN9034
1 EPA 245.1
01/08/2016 13:13
ACPAYNE
1 EPA 245.1
01/07/2016 12:58
ACPAYNE
1 EPA 200.7
01/06/2016 13:44
FCJORDA
1 EPA 200.7
01/06/2016 13:44
FCJORDA
1 EPA 200.7
01/06/2016 13:44
FCJORDA
1 EPA 200.7
01/06/2016 13:44
FCJORDA
1 EPA 200.7
01/06/2016 13:44
FCJORDA
1 EPA 200.7
01/06/2016 13:44
FCJORDA
1 EPA 200.7
01/06/2016 13:44
FCJORDA
1 EPA 200.7
01/07/2016 12:38
FCJORDA
1 EPA 200.7
01/07/2016 12:38
FCJORDA
1 EPA 200.7
01/07/2016 12:38
FCJORDA
1 EPA 200.7
01/07/2016 12:38
FCJORDA
1 EPA 200.7
01/08/2016 10:44
FCJORDA
1 EPA 200.7
01/08/2016 10:44
FCJORDA
1 EPA 200.7
01/08/2016 10:44
FCJORDA
1 EPA 200.7
01/08/2016 10:44
FCJORDA
1 EPA 200.7
01/08/2016 10:44
FCJORDA
1 EPA 200.7
01/08/2016 10:44
FCJORDA
1 EPA 200.7
01/08/2016 10:44
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
Site: ABMW-02
Collection Date: 05-Jan-16 10:55 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
425
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1040
ug/L
10
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.25
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
394
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1130
ug/L
10
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.42
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
440
mg/L
25
Total Carbon
TOC
9.4
mg/L
1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2016000243
Matrix: GW WW
Analytical Lab
Page 5 of 40
DF
Method
Analysis Date/Time
Analyst
1
EPA
200.8
01/09/2016 02:10
SLS2560
1
EPA
200.8
01/09/2016 02:10
SLS2560
1
EPA
200.8
01/09/2016 02:10
SLS2560
1
EPA
200.8
01/09/2016 02:10
SLS2560
1
EPA
200.8
01/09/2016 02:10
SLS2560
1
EPA
200.8
01/09/2016 02:10
SLS2560
1
EPA
200.8
01/09/2016 02:10
SLS2560
1
EPA
200.8
01/09/2016 02:10
SLS2560
10
EPA
200.8
01/09/2016 02:10
SLS2560
1
EPA
200.8
01/09/2016 02:10
SLS2560
1
EPA
200.8
01/09/2016 02:10
SLS2560
1
EPA
200.8
01/09/2016 02:10
SLS2560
1
EPA
200.8
01/09/2016 02:10
SLS2560
1
EPA
200.8
01/08/2016 12:18
SLS2560
1
EPA
200.8
01/08/2016 12:18
SLS2560
1
EPA
200.8
01/08/2016 12:18
SLS2560
1
EPA
200.8
01/08/2016 12:18
SLS2560
1
EPA
200.8
01/08/2016 12:18
SLS2560
1
EPA
200.8
01/08/2016 12:18
SLS2560
1
EPA
200.8
01/08/2016 12:18
SLS2560
1
EPA
200.8
01/08/2016 12:18
SLS2560
10
EPA
200.8
01/08/2016 12:18
SLS2560
1
EPA
200.8
01/08/2016 12:18
SLS2560
1
EPA
200.8
01/08/2016 12:18
SLS2560
1
EPA
200.8
01/08/2016 12:18
SLS2560
1
EPA
200.8
01/08/2016 12:18
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/07/201615:07 CJELLIO
10 SM5310C/EPA9060A 01/07/201614:01 GHUTCHI
1 SM2540D 01/07/201610:20 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
Site: ABMW-02BR
Collection Date: 05-Jan-16 1:15 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
26
mg/L
0.5
Sulfate
1.3
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.006
mg/L
0.005
Barium (Ba)
0.132
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.697
mg/L
0.01
Manganese (Mn)
0.223
mg/L
0.005
Strontium (Sr)
1.20
mg/L
0.005
Zinc (Zn)
0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
75.4
mg/L
0.01
Magnesium (Mg)
12.4
mg/L
0.005
Potassium (K)
5.65
mg/L
0.1
Sodium (Na)
29.3
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.075
mg/L
0.005
Barium (Ba)
0.123
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.10
mg/L
0.01
Manganese (Mn)
0.237
mg/L
0.005
Strontium (Sr)
1.09
mg/L
0.005
Zinc (Zn)
0.016
mg/L
0.005
Sample #: 2016000244
Matrix: GW WW
Analytical Lab
Page 6 of 40
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 11:22 LSTARL1
Vendor Method V_PACE
5 EPA 300.0
01/07/2016 08:19
BGN9034
1 EPA 300.0
01/07/2016 08:19
BGN9034
1 EPA 245.1
01/08/2016 13:23
ACPAYNE
1 EPA 245.1
01/07/2016 13:00
ACPAYNE
1 EPA 200.7
01/06/2016 13:55
FCJORDA
1 EPA 200.7
01/06/2016 13:55
FCJORDA
1 EPA 200.7
01/06/2016 13:55
FCJORDA
1 EPA 200.7
01/06/2016 13:55
FCJORDA
1 EPA 200.7
01/06/2016 13:55
FCJORDA
1 EPA 200.7
01/06/2016 13:55
FCJORDA
1 EPA 200.7
01/06/2016 13:55
FCJORDA
1 EPA 200.7
01/07/2016 12:51
FCJORDA
1 EPA 200.7
01/07/2016 12:51
FCJORDA
1 EPA 200.7
01/07/2016 12:51
FCJORDA
1 EPA 200.7
01/07/2016 12:51
FCJORDA
1 EPA 200.7
01/08/2016 10:48
FCJORDA
1 EPA 200.7
01/08/2016 10:48
FCJORDA
1 EPA 200.7
01/08/2016 10:48
FCJORDA
1 EPA 200.7
01/08/2016 10:48
FCJORDA
1 EPA 200.7
01/08/2016 10:48
FCJORDA
1 EPA 200.7
01/08/2016 10:48
FCJORDA
1 EPA 200.7
01/08/2016 10:48
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
Site: ABMW-02BR
Collection Date: 05-Jan-16 1:15 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
1.29
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.98
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
2.02
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
3.26
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.315
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
350
mg/L
25
Total Carbon
TOC
1.3
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
6.0
mg/L
5
Sample #: 2016000244
Matrix: GW WW
Analytical Lab
Page 7 of 40
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/08/2016 17:47
SLS2560
1
EPA 200.8
01/08/2016 17:47
SLS2560
1
EPA 200.8
01/08/2016 17:47
SLS2560
1
EPA 200.8
01/08/2016 17:47
SLS2560
1
EPA 200.8
01/08/2016 17:47
SLS2560
1
EPA 200.8
01/08/2016 17:47
SLS2560
1
EPA 200.8
01/08/2016 17:47
SLS2560
1
EPA 200.8
01/08/2016 17:47
SLS2560
1
EPA 200.8
01/08/2016 17:47
SLS2560
1
EPA 200.8
01/08/2016 17:47
SLS2560
1
EPA 200.8
01/08/2016 17:47
SLS2560
1
EPA 200.8
01/08/2016 17:47
SLS2560
1
EPA 200.8
01/08/2016 17:47
SLS2560
1
EPA 200.8
01/08/2016 10:07
SLS2560
1
EPA 200.8
01/08/2016 10:07
SLS2560
1
EPA 200.8
01/08/2016 10:07
SLS2560
1
EPA 200.8
01/08/2016 10:07
SLS2560
1
EPA 200.8
01/08/2016 10:07
SLS2560
1
EPA 200.8
01/08/2016 10:07
SLS2560
1
EPA 200.8
01/08/2016 10:07
SLS2560
1
EPA 200.8
01/08/2016 10:07
SLS2560
1
EPA 200.8
01/08/2016 10:07
SLS2560
1
EPA 200.8
01/08/2016 10:07
SLS2560
1
EPA 200.8
01/08/2016 10:07
SLS2560
1
EPA 200.8
01/08/2016 10:07
SLS2560
1
EPA 200.8
01/08/2016 10:07
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/07/201615:07 CJELLIO
1 SM5310C/EPA9060A 01/07/201614:01 GHUTCHI
1 SM2540D 01/07/201610:20 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
Site: ABMW-4D
Collection Date: 05-Jan-16 2:28 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.015 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
12
mg/L
0.5
Sulfate
0.94
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
M2 0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.131
mg/L
0.005
Barium (Ba)
1.28
mg/L
0.005
Boron (B)
5.06
mg/L
0.05
Iron (Fe)
65.8
mg/L
0.1
Manganese (Mn)
7.32
mg/L
0.005
Strontium (Sr)
2.63
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
134
mg/L
0.1
Magnesium (Mg)
38.0
mg/L
0.05
Potassium (K)
18.4
mg/L
1
Sodium (Na)
18.2
mg/L
0.5
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.253
mg/L
0.005
Barium (Ba)
1.08
mg/L
0.005
Boron (B)
4.01
mg/L
0.05
Iron (Fe)
72.1
mg/L
0.1
Manganese (Mn)
6.65
mg/L
0.005
Strontium (Sr)
2.07
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000245
Matrix: GW WW
Analytical Lab
Page 8 of 40
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 11:27 LSTARL1
Vendor Method V_PACE
5
EPA 300.0
01/07/2016 08:37
BGN9034
1
EPA 300.0
01/07/2016 08:37
BGN9034
1
EPA 245.1
01/08/2016 13:25
ACPAYNE
1
EPA 245.1
01/07/2016 13:12
ACPAYNE
1
EPA 200.7
01/06/2016 13:59
FCJORDA
1
EPA 200.7
01/06/2016 13:59
FCJORDA
1
EPA 200.7
01/06/2016 13:59
FCJORDA
10
EPA 200.7
01/06/2016 13:59
FCJORDA
1
EPA 200.7
01/06/2016 13:59
FCJORDA
1
EPA 200.7
01/06/2016 13:59
FCJORDA
1
EPA 200.7
01/06/2016 13:59
FCJORDA
10
EPA 200.7
01/07/2016 13:04
FCJORDA
10
EPA 200.7
01/07/2016 13:04
FCJORDA
10
EPA 200.7
01/07/2016 13:04
FCJORDA
10
EPA 200.7
01/07/2016 13:04
FCJORDA
1
EPA 200.7
01/08/2016 10:52
FCJORDA
1
EPA 200.7
01/08/2016 10:52
FCJORDA
1
EPA 200.7
01/08/2016 10:52
FCJORDA
10
EPA 200.7
01/08/2016 10:52
FCJORDA
1
EPA 200.7
01/08/2016 10:52
FCJORDA
1
EPA 200.7
01/08/2016 10:52
FCJORDA
1
EPA 200.7
01/08/2016 10:52
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
Site: ABMW-4D
Collection Date: 05-Jan-16 2:28 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
53.5
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
3.42
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
33.7
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
5.77
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
60.9
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
3.95
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
39.8
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
6.01
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
630
mg/L
25
Total Carbon
TOC
6.5
mg/L
1
TOTAL SUSPENDED SOLIDS
TSS
120
mg/L
5
Sample #: 2016000245
Matrix: GW WW
Analytical Lab
Page 9 of 40
DF
Method
Analysis Date/Time
Analyst
1
EPA
200.8
01/09/2016 02:15
SLS2560
1
EPA
200.8
01/09/2016 02:15
SLS2560
1
EPA
200.8
01/09/2016 02:15
SLS2560
1
EPA
200.8
01/09/2016 02:15
SLS2560
1
EPA
200.8
01/09/2016 02:15
SLS2560
1
EPA
200.8
01/09/2016 02:15
SLS2560
1
EPA
200.8
01/09/2016 02:15
SLS2560
1
EPA
200.8
01/09/2016 02:15
SLS2560
1
EPA
200.8
01/09/2016 02:15
SLS2560
1
EPA
200.8
01/09/2016 02:15
SLS2560
1
EPA
200.8
01/09/2016 02:15
SLS2560
1
EPA
200.8
01/09/2016 02:15
SLS2560
1
EPA
200.8
01/09/2016 02:15
SLS2560
1
EPA
200.8
01/08/2016 11:12
SLS2560
1
EPA
200.8
01/08/2016 11:12
SLS2560
1
EPA
200.8
01/08/2016 11:12
SLS2560
1
EPA
200.8
01/08/2016 11:12
SLS2560
1
EPA
200.8
01/08/2016 11:12
SLS2560
1
EPA
200.8
01/08/2016 11:12
SLS2560
1
EPA
200.8
01/08/2016 11:12
SLS2560
1
EPA
200.8
01/08/2016 11:12
SLS2560
1
EPA
200.8
01/08/2016 11:12
SLS2560
1
EPA
200.8
01/08/2016 11:12
SLS2560
1
EPA
200.8
01/08/2016 11:12
SLS2560
1
EPA
200.8
01/08/2016 11:12
SLS2560
1
EPA
200.8
01/08/2016 11:12
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/07/201615:07 CJELLIO
10 SM5310C/EPA9060A 01/07/201614:01 GHUTCHI
1 SM2540D 01/07/201610:20 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
Site: ABMW-4BR
Collection Date: 05-Jan-16 12:36 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
4.9
mg/L
0.1
Sulfate
21
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.013
mg/L
0.005
Barium (Ba)
0.103
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.014
mg/L
0.01
Manganese (Mn)
0.350
mg/L
0.005
Strontium (Sr)
1.72
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
75.6
mg/L
0.01
Magnesium (Mg)
5.36
mg/L
0.005
Potassium (K)
8.53
mg/L
0.1
Sodium (Na)
21.7
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.080
mg/L
0.005
Barium (Ba)
0.110
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.295
mg/L
0.01
Manganese (Mn)
0.364
mg/L
0.005
Strontium (Sr)
1.78
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000246
Matrix: GW WW
Analytical Lab
Page 10 of 40
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 11:28 LSTARL1
Vendor Method V_PACE
1
EPA 300.0
01/06/2016 19:26
BGN9034
10
EPA 300.0
01/06/2016 19:26
BGN9034
1
EPA 245.1
01/08/2016 13:32
ACPAYNE
1
EPA 245.1
01/07/2016 13:19
ACPAYNE
1
EPA 200.7
01/06/2016 14:03
FCJORDA
1
EPA 200.7
01/06/2016 14:03
FCJORDA
1
EPA 200.7
01/06/2016 14:03
FCJORDA
1
EPA 200.7
01/06/2016 14:03
FCJORDA
1
EPA 200.7
01/06/2016 14:03
FCJORDA
1
EPA 200.7
01/06/2016 14:03
FCJORDA
1
EPA 200.7
01/06/2016 14:03
FCJORDA
1
EPA 200.7
01/07/2016 13:08
FCJORDA
1
EPA 200.7
01/07/2016 13:08
FCJORDA
1
EPA 200.7
01/07/2016 13:08
FCJORDA
1
EPA 200.7
01/07/2016 13:08
FCJORDA
1
EPA 200.7
01/08/2016 10:56
FCJORDA
1
EPA 200.7
01/08/2016 10:56
FCJORDA
1
EPA 200.7
01/08/2016 10:56
FCJORDA
1
EPA 200.7
01/08/2016 10:56
FCJORDA
1
EPA 200.7
01/08/2016 10:56
FCJORDA
1
EPA 200.7
01/08/2016 10:56
FCJORDA
1
EPA 200.7
01/08/2016 10:56
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
Site: ABMW-4BR
Collection Date: 05-Jan-16 12:36 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
2.09
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
3.94
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.438
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
300
mg/L
25
Total Carbon
TOC
1.1
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
6.0
mg/L
5
Sample #: 2016000246
Matrix: GW WW
Analytical Lab
Page 11 of 40
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/08/2016 18:31
SLS2560
1
EPA 200.8
01/08/2016 18:31
SLS2560
1
EPA 200.8
01/08/2016 18:31
SLS2560
1
EPA 200.8
01/08/2016 18:31
SLS2560
1
EPA 200.8
01/08/2016 18:31
SLS2560
1
EPA 200.8
01/08/2016 18:31
SLS2560
1
EPA 200.8
01/08/2016 18:31
SLS2560
1
EPA 200.8
01/08/2016 18:31
SLS2560
1
EPA 200.8
01/08/2016 18:31
SLS2560
1
EPA 200.8
01/08/2016 18:31
SLS2560
1
EPA 200.8
01/08/2016 18:31
SLS2560
1
EPA 200.8
01/08/2016 18:31
SLS2560
1
EPA 200.8
01/08/2016 18:31
SLS2560
1
EPA 200.8
01/08/2016 11:17
SLS2560
1
EPA 200.8
01/08/2016 11:17
SLS2560
1
EPA 200.8
01/08/2016 11:17
SLS2560
1
EPA 200.8
01/08/2016 11:17
SLS2560
1
EPA 200.8
01/08/2016 11:17
SLS2560
1
EPA 200.8
01/08/2016 11:17
SLS2560
1
EPA 200.8
01/08/2016 11:17
SLS2560
1
EPA 200.8
01/08/2016 11:17
SLS2560
1
EPA 200.8
01/08/2016 11:17
SLS2560
1
EPA 200.8
01/08/2016 11:17
SLS2560
1
EPA 200.8
01/08/2016 11:17
SLS2560
1
EPA 200.8
01/08/2016 11:17
SLS2560
1
EPA 200.8
01/08/2016 11:17
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/07/201615:07 CJELLIO
1 SM5310C/EPA9060A 01/07/201614:01 GHUTCHI
1 SM2540D 01/07/201610:20 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
Site: ABMW-04
Collection Date: 05-Jan-16 10:52 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.011 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
12
mg/L
0.5
Sulfate
44
mg/L
0.5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.022
mg/L
0.005
Barium (Ba)
0.495
mg/L
0.005
Boron (B)
5.65
mg/L
0.05
Iron (Fe)
2.53
mg/L
0.01
Manganese (Mn)
1.07
mg/L
0.005
Strontium (Sr)
2.64
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
121
mg/L
0.1
Magnesium (Mg)
33.5
mg/L
0.05
Potassium (K)
22.8
mg/L
1
Sodium (Na)
11.9
mg/L
0.5
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.039
mg/L
0.005
Barium (Ba)
0.472
mg/L
0.005
Boron (B)
5.36
mg/L
0.05
Iron (Fe)
2.51
mg/L
0.01
Manganese (Mn)
1.03
mg/L
0.005
Strontium (Sr)
2.54
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000247
Matrix: GW WW
Analytical Lab
Page 12 of 40
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 11:29 LSTARL1
Vendor Method V_PACE
5
EPA 300.0
01/06/2016 17:56
BGN9034
5
EPA 300.0
01/06/2016 17:56
BGN9034
1
EPA 245.1
01/08/2016 13:37
ACPAYNE
1
EPA 245.1
01/07/2016 13:22
ACPAYNE
1
EPA 200.7
01/06/2016 14:07
FCJORDA
1
EPA 200.7
01/06/2016 14:07
FCJORDA
1
EPA 200.7
01/06/2016 14:07
FCJORDA
1
EPA 200.7
01/06/2016 14:07
FCJORDA
1
EPA 200.7
01/06/2016 14:07
FCJORDA
1
EPA 200.7
01/06/2016 14:07
FCJORDA
1
EPA 200.7
01/06/2016 14:07
FCJORDA
10
EPA 200.7
01/07/2016 13:12
FCJORDA
10
EPA 200.7
01/07/2016 13:12
FCJORDA
10
EPA 200.7
01/07/2016 13:12
FCJORDA
10
EPA 200.7
01/07/2016 13:12
FCJORDA
1
EPA 200.7
01/08/2016 11:00
FCJORDA
1
EPA 200.7
01/08/2016 11:00
FCJORDA
1
EPA 200.7
01/08/2016 11:00
FCJORDA
1
EPA 200.7
01/08/2016 11:00
FCJORDA
1
EPA 200.7
01/08/2016 11:00
FCJORDA
1
EPA 200.7
01/08/2016 11:00
FCJORDA
1
EPA 200.7
01/08/2016 11:00
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
Site: ABMW-04
Collection Date: 05-Jan-16 10:52 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
763
ug/L
10
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.26
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
424
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.84
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
708
ug/L
10
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.19
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
418
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.88
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
550
mg/L
25
Total Carbon
TOC
2.6
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
8.0
mg/L
5
Sample #: 2016000247
Matrix: GW WW
Analytical Lab
Page 13 of 40
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/08/2016 18:36
SLS2560
10
EPA 200.8
01/08/2016 18:36
SLS2560
1
EPA 200.8
01/08/2016 18:36
SLS2560
1
EPA 200.8
01/08/2016 18:36
SLS2560
1
EPA 200.8
01/08/2016 18:36
SLS2560
1
EPA 200.8
01/08/2016 18:36
SLS2560
1
EPA 200.8
01/08/2016 18:36
SLS2560
1
EPA 200.8
01/08/2016 18:36
SLS2560
1
EPA 200.8
01/08/2016 18:36
SLS2560
1
EPA 200.8
01/08/2016 18:36
SLS2560
1
EPA 200.8
01/08/2016 18:36
SLS2560
1
EPA 200.8
01/08/2016 18:36
SLS2560
1
EPA 200.8
01/08/2016 18:36
SLS2560
1
EPA 200.8
01/08/2016 11:21
SLS2560
10
EPA 200.8
01/08/2016 11:21
SLS2560
1
EPA 200.8
01/08/2016 11:21
SLS2560
1
EPA 200.8
01/08/2016 11:21
SLS2560
1
EPA 200.8
01/08/2016 11:21
SLS2560
1
EPA 200.8
01/08/2016 11:21
SLS2560
1
EPA 200.8
01/08/2016 11:21
SLS2560
1
EPA 200.8
01/08/2016 11:21
SLS2560
1
EPA 200.8
01/08/2016 11:21
SLS2560
1
EPA 200.8
01/08/2016 11:21
SLS2560
1
EPA 200.8
01/08/2016 11:21
SLS2560
1
EPA 200.8
01/08/2016 11:21
SLS2560
1
EPA 200.8
01/08/2016 11:21
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/07/201615:07 CJELLIO
1 SM5310C/EPA9060A 01/07/201614:01 GHUTCHI
1 SM2540D 01/07/201610:20 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
Site: Filter Blank
Collection Date: 05-Jan-16 2:45 PM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2016000248
Matrix: GW WW
Analytical Lab
Page 14 of 40
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
01/07/2016 13:24
ACPAYNE
1
EPA 200.7
01/06/2016 14:11
FCJORDA
1
EPA 200.7
01/06/2016 14:11
FCJORDA
1
EPA 200.7
01/06/2016 14:11
FCJORDA
1
EPA 200.7
01/06/2016 14:11
FCJORDA
1
EPA 200.7
01/06/2016 14:11
FCJORDA
1
EPA 200.7
01/06/2016 14:11
FCJORDA
1
EPA 200.7
01/06/2016 14:11
FCJORDA
1
EPA 200.8
01/08/2016 18:41
SLS2560
1
EPA 200.8
01/08/2016 18:41
SLS2560
1
EPA 200.8
01/08/2016 18:41
SLS2560
1
EPA 200.8
01/08/2016 18:41
SLS2560
1
EPA 200.8
01/08/2016 18:41
SLS2560
1
EPA 200.8
01/08/2016 18:41
SLS2560
1
EPA 200.8
01/08/2016 18:41
SLS2560
1
EPA 200.8
01/08/2016 18:41
SLS2560
1
EPA 200.8
01/08/2016 18:41
SLS2560
1
EPA 200.8
01/08/2016 18:41
SLS2560
1
EPA 200.8
01/08/2016 18:41
SLS2560
1
EPA 200.8
01/08/2016 18:41
SLS2560
1
EPA 200.8
01/08/2016 18:41
SLS2560

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
Site: Equipment Blank
Collection Date: 05-Jan-16 2:45 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
Calcium (Ca)
0.013
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2016000249
Matrix: GW WW
Analytical Lab
Page 15 of 40
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 11:30 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
01/06/2016 15:33
BGN9034
1 EPA 300.0
01/06/2016 15:33
BGN9034
1 EPA 245.1
01/08/2016 13:40
ACPAYNE
1 EPA 200.7
01/07/2016 13:16
FCJORDA
1 EPA 200.7
01/07/2016 13:16
FCJORDA
1 EPA 200.7
01/07/2016 13:16
FCJORDA
1 EPA 200.7
01/07/2016 13:16
FCJORDA
1 EPA 200.7
01/08/2016 11:04
FCJORDA
1 EPA 200.7
01/08/2016 11:04
FCJORDA
1 EPA 200.7
01/08/2016 11:04
FCJORDA
1 EPA 200.7
01/08/2016 11:04
FCJORDA
1 EPA 200.7
01/08/2016 11:04
FCJORDA
1 EPA 200.7
01/08/2016 11:04
FCJORDA
1 EPA 200.7
01/08/2016 11:04
FCJORDA
1 EPA 200.8
01/08/2016 11:51
SLS2560
1 EPA 200.8
01/08/2016 11:51
SLS2560
1 EPA 200.8
01/08/2016 11:51
SLS2560
1 EPA 200.8
01/08/2016 11:51
SLS2560
1 EPA 200.8
01/08/2016 11:51
SLS2560
1 EPA 200.8
01/08/2016 11:51
SLS2560
1 EPA 200.8
01/08/2016 11:51
SLS2560
1 EPA 200.8
01/08/2016 11:51
SLS2560
1 EPA 200.8
01/08/2016 11:51
SLS2560
1 EPA 200.8
01/08/2016 11:51
SLS2560
1 EPA 200.8
01/08/2016 11:51
SLS2560
1 EPA 200.8
01/08/2016 11:51
SLS2560
1 EPA 200.8
01/08/2016 11:51
SLS2560

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
Site: Equipment Blank
Collection Date: 05-Jan-16 2:45 PM
Analyte Result Units Qualifiers RDL DF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L 25 1
Total Carbon
Analytical Lab
Page 16 of 40
Sample #: 2016000249
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method
V_PACE
SM2540C 01/07/201615:07 CJELLIO
TOC 0.129 mg/L 0.1 1 SM5310C/EPA9060A 01/07/201614:01 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS <5 mg/L 5 1 SM2540D 01/07/201610:20 CJELLIO
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to
the spike level. The associated Laboratory Control Spike recovery was acceptable.

aceAnalyical
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January 12, 2016
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 16010048 MAYO
Pace Project No.: 92281987
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 06, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Anne Pifer
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
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Project: J16010048 MAYO
Pace Project No.: 92281987
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A21-A Certification M 2926.01
Alaska Certification M UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification M 88-0680
California Certification M 01155CA
Colorado Certification #Pace
Connecticut Certification M PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification M 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification M 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification M 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification M 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification M E83079
Georgia Certification M 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification M 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification M E-10383
Kentucky Certification #: 90050
Louisiana Certification M FL NELAC Reciprocity
Louisiana Environmental Certificate M 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification M Cert 0074
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification M TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification M 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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SAMPLE SUMMARY
Project: J16010048 MAYO
Pace Project No.: 92281987
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92281987001
2016000243
Water
01/05/1610:55
01/06/1611:11
92281987002
2016000244
Water
01/05/1613:15
01/06/1611:11
92281987003
2016000245
Water
01/05/1614:28
01/06/1611:11
92281987004
2016000246
Water
01/05/1612:36
01/06/1611:11
92281987005
2016000247
Water
01/05/1610:52
01/06/1611:11
92281987006
2016000249
Water
01/05/1614:45
01/06/1611:11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 23

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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16010048 MAYO
92281987
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92281987001
2016000243
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92281987002
2016000244
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92281987003
2016000245
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92281987004
2016000246
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92281987005
2016000247
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92281987006
2016000249
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 4 of 23

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SUMMARY OF DETECTION
Project:
Pace Project No.:
J16010048 MAYO
92281987
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92281987001
2016000243
RSK 175
Methane
17400
ug/L
10.0
01/07/16 16:26
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
335
mg/L
5.0
01/07/16 22:14
SM 2320B
Alkalinity, Total as CaCO3
335
mg/L
5.0
01/07/16 22:14
92281987002
2016000244
RSK 175
Methane
288
ug/L
10.0
01/07/16 16:42
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
284
mg/L
5.0
01/07/16 22:30
SM 2320B
Alkalinity, Total as CaCO3
284
mg/L
5.0
01/07/16 22:30
92281987003
2016000245
RSK 175
Methane
17900
ug/L
10.0
01/07/16 16:51
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
596
mg/L
5.0
01/07/16 23:03
SM 2320B
Alkalinity, Total as CaCO3
596
mg/L
5.0
01/07/16 23:03
92281987004
2016000246
RSK 175
Methane
1000
ug/L
10.0
01/07/16 16:59
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
243
mg/L
5.0
01/07/16 23:33
SM 2320B
Alkalinity, Total as CaCO3
243
mg/L
5.0
01/07/16 23:33
SM 4500-S21D
Sulfide
3.9
mg/L
0.50
01/07/16 17:00
92281987005
2016000247
RSK 175
Methane
8000
ug/L
10.0
01/07/16 17:07
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
425
mg/L
5.0
01/07/16 23:46
SM 2320B
Alkalinity, Total as CaCO3
425
mg/L
5.0
01/07/16 23:46
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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PROJECT NARRATIVE
Project: J16010048 MAYO
Pace Project No.: 92281987
Method: RSK 175
Description: RSK 175 AIR Headspace
Client: Duke Energy
Date: January 12, 2016
General Information:
6 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 6 of 23

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PROJECT NARRATIVE
Project: J16010048 MAYO
Pace Project No.: 92281987
Method: SM 2320B
Description: 2320E Alkalinity
Client: Duke Energy
Date: January 12, 2016
General Information:
6 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 7 of 23

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PROJECT NARRATIVE
Project: J16010048 MAYO
Pace Project No.: 92281987
Method: SM 4500-S213
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: January 12, 2016
General Information:
6 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/42342
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92281984003,92281984013
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1642364)
• Sulfide
• MSD (Lab ID: 1642365)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16010048 MAYO
Pace Project No.: 92281987
Method: EPA 218.7
Description: Hexavalent Chromium by IC
Client: Duke Energy
Date: January 12, 2016
General Information:
6 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 9 of 23

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ANALYTICAL RESULTS
Project: J16010048 MAYO
Pace Project No.: 92281987
Sample: 2016000243
Lab ID: 92281987001 Collected:
01/05/16 10:55
Received: 01/06/16 11:11 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
17400 ug/L
10.0
1
01/07/1616:26
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
335 mg/L
5.0
1
01/07/16 22:14
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/07/16 22:14
Alkalinity, Total as CaCO3
335 mg/L
5.0
1
01/07/16 22:14
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/07/1617:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/08/16 08:34
18540-29-9
Date: 01/12/2016 08:26 AM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Ana ,1i�tifr
098 998 de. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: J16010048 MAYO
Pace Project No.: 92281987
Sample: 2016000244
Lab ID: 92281987002 Collected:
01/05/16 13:15
Received: 01/06/16 11:11 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
288 ug/L
10.0
1
01/07/1616:42
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
284 mg/L
5.0
1
01/07/16 22:30
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/07/16 22:30
Alkalinity, Total as CaCO3
284 mg/L
5.0
1
01/07/16 22:30
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/07/1617:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/08/16 08:47
18540-29-9
Date: 01/12/2016 08:26 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 11 of 23

aceAnalyical
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Pa ti I ervices, Inc.
Aena1.11i al��a
0989 9898M de. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: J16010048 MAYO
Pace Project No.: 92281987
Sample: 2016000245
Lab ID: 92281987003 Collected:
01/05/16 14:28
Received: 01/06/16 11:11 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
17900 ug/L
10.0
1
01/07/1616:51
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
596 mg/L
5.0
1
01/07/16 23:03
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/07/16 23:03
Alkalinity, Total as CaCO3
596 mg/L
5.0
1
01/07/16 23:03
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/07/1617:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/08/16 09:00
18540-29-9
Date: 01/12/2016 08:26 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 23

aceAnalyical
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Pa e 1 ti I ervices, Inc.
Ana ,1i�tifr
098 9998 de. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: J16010048 MAYO
Pace Project No.: 92281987
Sample: 2016000246
Lab ID: 92281987004 Collected:
01/05/16 12:36
Received: 01/06/16 11:11 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
1000 ug/L
10.0
1
01/07/1616:59
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
243 mg/L
5.0
1
01/07/16 23:33
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/07/16 23:33
Alkalinity, Total as CaCO3
243 mg/L
5.0
1
01/07/16 23:33
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
3.9 mg/L
0.50
5
01/07/1617:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/08/16 09:13
18540-29-9
Date: 01/12/2016 08:26 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 23

aceAnalyical
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Pa ti I ervices, Inc.
Aena1.11i al��a
0989%98M de. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010048 MAYO
Pace Project No.: 92281987
Sample: 2016000247
Lab ID: 92281987005 Collected:
01/05/16 10:52
Received: 01/06/16 11:11 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
8000 ug/L
10.0
1
01/07/1617:07
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
425 mg/L
5.0
1
01/07/16 23:46
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/07/16 23:46
Alkalinity, Total as CaCO3
425 mg/L
5.0
1
01/07/16 23:46
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/07/1617:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/08/16 09:26
18540-29-9
Date: 01/12/2016 08:26 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 14 of 23

aceAnalyical
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Pa ti I ervices, Inc.
Aena1.11i al��a
0989 K nl 98f4"de. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010048 MAYO
Pace Project No.: 92281987
Sample: 2016000249
Lab ID: 92281987006 Collected:
01/05/16 14:45
Received: 01/06/16 11:11 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/07/1617:15
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
01/08/16 00:03
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/08/16 00:03
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
01/08/16 00:03
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/07/1617:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/08/16 09:39
18540-29-9
Date: 01/12/2016 08:26 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 23

aceAnaiXical
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Paca alytical ervices, Inc.
Hna ii al La
0989Ki298Mde. Suite100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010048 MAYO
Pace Project No.: 92281987
QC Batch: AIR/24980
Analysis Method: RSK 175
QC Batch Method: RSK 175
Analysis Description: RSK 175 AIR HEADSPACE
Associated Lab Samples: 92281987001, 92281987002,
92281987003, 92281987004, 92281987005, 92281987006
METHOD BLANK: 2171402
Matrix: Water
Associated Lab Samples: 92281987001, 92281987002,
92281987003, 92281987004, 92281987005, 92281987006
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Methane
ug/L
ND 10.0 01/07/1614:16
LABORATORY CONTROL SAMPLE & LCSD:
2171403
2171404
Spike LCS LCSD LCS LCSD
% Rec
Max
Parameter
Units
Conc. Result Result % Rec % Rec
Limits RPD
RPD Qualifiers
Methane
ug/L
60.7 57.2 59.6 94 98
85-115
4 20
SAMPLE DUPLICATE: 2172103
92281981010 Dup
Max
Parameter
Units
Result Result RPD
RPD
Qualifiers
Methane
ug/L
ND 3AJ
20
SAMPLE DUPLICATE: 2172104
92281987001 Dup
Max
Parameter
Units
Result Result RPD
RPD
Qualifiers
Methane
ug/L
17400 19500 12
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/12/2016 08:26 AM without the written consent of Pace Analytical Services, Inc.. Page 16 of 23

aceAnaiXical
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Paca alytical ervices, Inc.
Hna ilcal La
0989ISS- de. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010048 MAYO
Pace Project No.: 92281987
QC Batch: WET/42339 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92281987001, 92281987002, 92281987003, 92281987004, 92281987005, 92281987006
METHOD BLANK: 1642346
Matrix: Water
Associated Lab Samples: 92281987001, 92281987002, 92281987003, 92281987004, 92281987005,
92281987006
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Alkalinity, Carbonate (CaCO3)
mg/L
ND 5.0
01/07/16 17:57
Alkalinity, Total as CaCO3
mg/L
ND 5.0
01/07/16 17:57
Alkalinity, Bicarbonate (CaCO3)
mg/L
ND 5.0
01/07/16 17:57
LABORATORY CONTROL SAMPLE: 1642347
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 48.2 96 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1642348 1642349
MS MSD
92281984003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 233 50 50 281 277 95 88 80-120 1 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1642350 1642351
MS MSD
92281984013 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Alkalinity, Total as CaCO3 mg/L 231 50 50 274 280 85 96 80-120 2 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/12/2016 08:26 AM without the written consent of Pace Analytical Services, Inc..
Page 17 of 23

aceAnaiXical
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Paca alytical ervices, Inc.
Hna ilcal La
0989Ki498Mde. Suite100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010048 MAYO
Pace Project No.: 92281987
QC Batch: WET/42342 Analysis Method: SM 4500-S2D
QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92281987001, 92281987002, 92281987003, 92281987004, 92281987005, 92281987006
METHOD BLANK: 1642362 Matrix: Water
Associated Lab Samples: 92281987001, 92281987002, 92281987003, 92281987004, 92281987005, 92281987006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 01/07/1617:00
LABORATORY CONTROL SAMPLE: 1642363
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.50 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1642364 1642365
MS MSD
92281984003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.43 0.43 86 86 90-110 0 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1642366 1642367
MS MSD
92281984013 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.46 0.46 92 92 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/12/2016 08:26 AM without the written consent of Pace Analytical Services, Inc..
Page 18 of 23

aceAnaiXical
www.pacelabs.com
Paca alytical ervices, Inc.
Hna ilcal La
0989%98M de. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010048 MAYO
Pace Project No.: 92281987
QC Batch: WETA/53592 Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC
Associated Lab Samples: 92281987001, 92281987002, 92281987003, 92281987004, 92281987005, 92281987006
METHOD BLANK: 1440775 Matrix: Water
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chromium, Hexavalent ug/L ND 0.030 01/08/16 12:02
LABORATORY CONTROL SAMPLE: 1440776
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chromium, Hexavalent ug/L .075 0.076 102 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1440777 1440778
MS MSD
92281984003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L 1.5 .25 .25 1.8 1.7 112 80 85-115 5 20 M6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1440779 1440780
MS MSD
92281984013 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L 4.5 1.5 1.5 6.0 5.9 98 94 85-115 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/12/2016 08:26 AM without the written consent of Pace Analytical Services, Inc..
Page 19 of 23

aceAnalyical
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Pa 1 ti I ervices, Inc.
Aena i alo�a
0989%98M de. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J16010048 MAYO
Pace Project No.: 92281987
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-M Pace Analytical Services - Minneapolis
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
REPORT OF LABORATORY ANALYSIS
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Date: 01/12/2016 08:26 AM without the written consent of Pace Analytical Services, Inc.. Page 20 of 23

acmnalytical
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Pa e i I ervices, Inc.
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,Q If�gw,W. Suite 100
yy Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16010048 MAYO
Pace Project No.: 92281987
Lab ID Sample ID QC Batch Method QC Batch
92281987001
2016000243
RSK 175
AIR/24980
92281987002
2016000244
RSK 175
AIR/24980
92281987003
2016000245
RSK 175
AIR/24980
92281987004
2016000246
RSK 175
AIR/24980
92281987005
2016000247
RSK 175
AIR/24980
92281987006
2016000249
RSK 175
AIR/24980
92281987001
2016000243
SM 2320B
WET/42339
92281987002
2016000244
SM 2320B
WET/42339
92281987003
2016000245
SM 2320B
WET/42339
92281987004
2016000246
SM 2320B
WET/42339
92281987005
2016000247
SM 2320B
WET/42339
92281987006
2016000249
SM 2320B
WET/42339
92281987001
2016000243
SM 4500-S2D
WET/42342
92281987002
2016000244
SM 4500-S2D
WET/42342
92281987003
2016000245
SM 4500-S2D
WET/42342
92281987004
2016000246
SM 4500-S2D
WET/42342
92281987005
2016000247
SM 4500-S2D
WET/42342
92281987006
2016000249
SM 4500-S2D
WET/42342
92281987001
2016000243
EPA 218.7
WETA/53592
92281987002
2016000244
EPA 218.7
WETA/53592
92281987003
2016000245
EPA 218.7
WETA/53592
92281987004
2016000246
EPA 218.7
WETA/53592
92281987005
2016000247
EPA 218.7
WETA/53592
92281987006
2016000249
EPA 218.7
WETA/53592
Date: 01 /12/2016 08:26 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 21 of 23

Document Name:
Document Revised: 260 Lab
�2eAnalyficalo
Sample Condition Upon Receipt(SCUR)
Page 1 of 2 papp g nf An
Document No.:
Issuing Authority:
F-CHR-CS-003-rev.17
Pace Huntersville Quality Office
S ample Condition I Client Name; Project #:� v o°"28 1 1387
p.
A
Courier: []Fed Ex ❑UPS ❑USPS ❑Client11
❑Commercial ❑Pace ❑Other:
92281967
Custody Seal on Cooler/Box Present? Dyes ❑No
Packing Material: []]Bubble Wrap 0136bble Bags
1
Seals Intact? ❑Yes ['NNo
❑None ❑Other:
Thermometer ❑ T 505
Used: Type of Ice: ❑t ❑BEue ❑None ❑Samples on ice, cooling process has begun
Il ,4
Cooler Temp Corrected (*CDC Biological Tissue Frozen? ❑Yes []No [:]N/A' 1
Temp should be above fre zing to 6°C Correction Factor: 0.0 °C Date and Initials of Person Examining Contents: �Y) y
USDA Regulated Soil ( f N/A, water sample)
Did samples origi ate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (international y,
Fly"❑V including Hawaii and Puerto Rico)? ❑Yes ONO
If Yes to either question, fill out a Regulated Soil Checklist and include with SOUR/COC paperwork. -
COMMENTS:
Chain of Custody Present?
Ely'-
Elmo
❑N/A
1.
Chain of Custody Filled Out?
[31es
❑No
❑N/A
2.
Chain of Custody Relinquished?s
❑No
❑N/A
3.
Sampler Name and/or Signature on COC?
❑Yes
[:]No
❑N/A
4.
Samples Arrived within Hold Time?
Yes
❑No
❑N/A
5.
Short Hold Time Analysis (<72 hr)?
©Yes
❑No
❑N/A
6.
Rush Turn Around Time Requested?
[]Yes
[rNo
❑N/A
7.
Sufficient Volume?
❑fes
❑No
[]NIA
8.
Correct Containers Used?
❑Y'es
❑No
❑N/A
9.
-Pace Containers Used?
❑Yes
❑No
❑N/A
Containers Intact?
.-EfYes
❑No
[]NIA
10.
Filtered Volume Received for Dissolved Tests?
[]Yes
[:]No
d/A
11. Note if sediment Is visible in the dissolved container
Sample Labels Match COC?
❑Yes
❑No
[]N/A
12.
-Includes Date/Time/ID/Analysis Matrix:
All containers needing acid/base preservation have been
checked?
Efes
❑No
N'A
13
All containers needing preservation are found to be in
� t
compliance with EPA recommendation?
%
1�
i
(HNO3, H250,, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide)
.[Yes
❑No
Q /AJ
Exceptions: VOA, Coliform, TOC, Oil and Grease,
DR0/8015 (water) DOC,LLHg
[]Yes
❑No
❑N/A
Samples checked for dechlorization
❑Yes
❑No
[j'N/A
14.
Headspace in VOA Vials (>5-6mm)?
[I Yes
❑iqo
[-]N/A
15.
Trip Blank Present?
[]Yes
❑No
[fN/A
16.
Trip Blank Custody Seals Present?
❑Yes
[]No
❑N/A
Pace Trip Blank Lot # (if purchased):
CLIENT NOTIFICATION/RESOLUTION Field Data -Required? ❑Yes ❑No
Person Contacted: Date/Time:
Comments/Resolution:
Project Manager SCURF Review: C
�,J. Date:
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of
hold, incorrect preservative, out of temp, incorrect containers). Page 22 of 23

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DUKE Analytical Laboratory Page 1of67
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Ma
Data Flags & Calculations:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J16010086
MAYO STEAM - AB GW ASSESSMENT WATER
Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy Webb, John Toep
Anne Pifer Phone:
Date: 1 /15/2016
Pifer) with any questions regarding this report.
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Page 2 of 67
Sample ID Plant/Station
Collection
Date and Time Collected By
Sample Description
2016000429
MAYO STEAM
06-Jan-16 9:38 AM
illegible
MW-3
2016000430
MAYO STEAM
06-Jan-16 12:25 PM
illegible
MW-2
2016000431
MAYO STEAM
06-Jan-16 10:32 AM
illegible
MW-08BR
2016000432
MAYO STEAM
06-Jan-16 9:38 AM
illegible
MW-3 Dup
2016000433
MAYO STEAM
06-Jan-16 12:10 PM
illegible
MW-7D
2016000434
MAYO STEAM
06-Jan-16 1:38 PM
illegible
MW-7BR
2016000435
MAYO STEAM
06-Jan-16 11:45 AM
illegible
MW-04
2016000436
MAYO STEAM
05-Jan-16 11:10 AM
illegible
ABMW-3
2016000437
MAYO STEAM
05-Jan-16 10:35 AM
illegible
ABMW-3S
2016000438
MAYO STEAM
06-Jan-16 4:45 PM
illegible
Filter Blank
2016000439
MAYO STEAM
06-Jan-16 4:45 PM
illegible
Equipment Blank
2016000440
MAYO STEAM
06-Jan-16 4:40 PM
illegible
CW-6
2016000441
MAYO STEAM
06-Jan-16 3:35 PM
illegible
CW-2
2016000442
MAYO STEAM
06-Jan-16 3:00 PM
illegible
CW-21D
14 Total Samples

Page 3 of 67
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 1/15/2016

Certificate of Laboratory Analysis Page 4 of 67
This report shall not be reproduced, except in full.
Order # J16010086
Site: MW-3
Collection Date: 06-Jan-16 9:38 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.055 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
46
mg/L
0.5
Sulfate
22
mg/L
0.5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.058
mg/L
0.005
Boron (B)
0.911
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
1.23
mg/L
0.005
Strontium (Sr)
0.326
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
26.2
mg/L
0.01
Magnesium (Mg)
8.75
mg/L
0.005
Potassium (K)
2.13
mg/L
0.1
Sodium (Na)
22.8
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.007
mg/L
0.005
Barium (Ba)
0.057
mg/L
0.005
Boron (B)
0.896
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
1.42
mg/L
0.005
Strontium (Sr)
0.328
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000429
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 13:21 LSTARL1
Vendor Method V_PACE
5 EPA 300.0
01/08/2016 20:58
BGN9034
5 EPA 300.0
01/08/2016 20:58
BGN9034
1 EPA 245.1
01/08/2016 15:00
ACPAYNE
1 EPA 245.1
01/09/2016 12:04
ACPAYNE
1 EPA 200.7
01/08/2016 12:32
FCJORDA
1 EPA 200.7
01/08/2016 12:32
FCJORDA
1 EPA 200.7
01/08/2016 12:32
FCJORDA
1 EPA 200.7
01/08/2016 12:32
FCJORDA
1 EPA 200.7
01/08/2016 12:32
FCJORDA
1 EPA 200.7
01/08/2016 12:32
FCJORDA
1 EPA 200.7
01/08/2016 12:32
FCJORDA
1 EPA 200.7
01/11/2016 10:54
FCJORDA
1 EPA 200.7
01/11/2016 10:54
FCJORDA
1 EPA 200.7
01/11/2016 10:54
FCJORDA
1 EPA 200.7
01/11/2016 10:54
FCJORDA
1 EPA 200.7
01/08/2016 14:36
FCJORDA
1 EPA 200.7
01/08/2016 14:36
FCJORDA
1 EPA 200.7
01/08/2016 14:36
FCJORDA
1 EPA 200.7
01/08/2016 14:36
FCJORDA
1 EPA 200.7
01/08/2016 14:36
FCJORDA
1 EPA 200.7
01/08/2016 14:36
FCJORDA
1 EPA 200.7
01/08/2016 14:36
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: MW-3
Collection Date: 06-Jan-16 9:38 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
2.98
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
2.82
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
200
mg/L
25
Total Carbon
TOC
0.919
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 5 of 67
Sample #:
2016000429
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/09/2016 13:01
SLS2560
1
EPA 200.8
01/09/2016 13:01
SLS2560
1
EPA 200.8
01/09/2016 13:01
SLS2560
1
EPA 200.8
01/09/2016 13:01
SLS2560
1
EPA 200.8
01/09/2016 13:01
SLS2560
1
EPA 200.8
01/09/2016 13:01
SLS2560
1
EPA 200.8
01/09/2016 13:01
SLS2560
1
EPA 200.8
01/09/2016 13:01
SLS2560
1
EPA 200.8
01/09/2016 13:01
SLS2560
1
EPA 200.8
01/09/2016 13:01
SLS2560
1
EPA 200.8
01/09/2016 13:01
SLS2560
1
EPA 200.8
01/09/2016 13:01
SLS2560
1
EPA 200.8
01/09/2016 13:01
SLS2560
1 EPA 200.8
01/10/2016 09:48
SLS2560
1 EPA 200.8
01/10/2016 09:48
SLS2560
1 EPA 200.8
01/10/2016 09:48
SLS2560
1 EPA 200.8
01/10/2016 09:48
SLS2560
1 EPA 200.8
01/10/2016 09:48
SLS2560
1 EPA 200.8
01/10/2016 09:48
SLS2560
1 EPA 200.8
01/10/2016 09:48
SLS2560
1 EPA 200.8
01/10/2016 09:48
SLS2560
1 EPA 200.8
01/10/2016 09:48
SLS2560
1 EPA 200.8
01/10/2016 09:48
SLS2560
1 EPA 200.8
01/10/2016 09:48
SLS2560
1 EPA 200.8
01/10/2016 09:48
SLS2560
1 EPA 200.8
01/10/2016 09:48
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/08/201615:47 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/08/2016 09:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: MW-2
Collection Date: 06-Jan-16 12:25 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.119 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
16
mg/L
1
Sulfate
18
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.058
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.561
mg/L
0.01
Manganese (Mn)
0.979
mg/L
0.005
Strontium (Sr)
0.186
mg/L
0.005
Zinc (Zn)
0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
17.8
mg/L
0.01
Magnesium (Mg)
7.34
mg/L
0.005
Potassium (K)
4.74
mg/L
0.1
Sodium (Na)
26.7
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.531
mg/L
0.005
Barium (Ba)
0.059
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.813
mg/L
0.01
Manganese (Mn)
1.12
mg/L
0.005
Strontium (Sr)
0.189
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000430
Matrix: GW WW
Page 6 of 67
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 13:23 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
01/08/2016 18:17
BGN9034
10
EPA 300.0
01/08/2016 18:17
BGN9034
1
EPA 245.1
01/08/2016 15:02
ACPAYNE
1
EPA 245.1
01/09/2016 12:06
ACPAYNE
1
EPA 200.7
01/08/2016 12:43
FCJORDA
1
EPA 200.7
01/08/2016 12:43
FCJORDA
1
EPA 200.7
01/08/2016 12:43
FCJORDA
1
EPA 200.7
01/08/2016 12:43
FCJORDA
1
EPA 200.7
01/08/2016 12:43
FCJORDA
1
EPA 200.7
01/08/2016 12:43
FCJORDA
1
EPA 200.7
01/08/2016 12:43
FCJORDA
1
EPA 200.7
01/11/2016 10:57
FCJORDA
1
EPA 200.7
01/11/2016 10:57
FCJORDA
1
EPA 200.7
01/11/2016 10:57
FCJORDA
1
EPA 200.7
01/11/2016 10:57
FCJORDA
1
EPA 200.7
01/08/2016 14:48
FCJORDA
1
EPA 200.7
01/08/2016 14:48
FCJORDA
1
EPA 200.7
01/08/2016 14:48
FCJORDA
1
EPA 200.7
01/08/2016 14:48
FCJORDA
1
EPA 200.7
01/08/2016 14:48
FCJORDA
1
EPA 200.7
01/08/2016 14:48
FCJORDA
1
EPA 200.7
01/08/2016 14:48
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: MW-2
Collection Date: 06-Jan-16 12:25 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
3.34
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
2.62
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.443
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
3.81
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
2.68
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.678
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
200
mg/L
25
Total Carbon
TOC
1.5
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 7 of 67
Sample #:
2016000430
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/09/2016 13:06
SLS2560
1
EPA 200.8
01/09/2016 13:06
SLS2560
1
EPA 200.8
01/09/2016 13:06
SLS2560
1
EPA 200.8
01/09/2016 13:06
SLS2560
1
EPA 200.8
01/09/2016 13:06
SLS2560
1
EPA 200.8
01/09/2016 13:06
SLS2560
1
EPA 200.8
01/09/2016 13:06
SLS2560
1
EPA 200.8
01/09/2016 13:06
SLS2560
1
EPA 200.8
01/09/2016 13:06
SLS2560
1
EPA 200.8
01/09/2016 13:06
SLS2560
1
EPA 200.8
01/09/2016 13:06
SLS2560
1
EPA 200.8
01/09/2016 13:06
SLS2560
1
EPA 200.8
01/09/2016 13:06
SLS2560
1 EPA 200.8
01/09/2016 20:04
SLS2560
1 EPA 200.8
01/09/2016 20:04
SLS2560
1 EPA 200.8
01/09/2016 20:04
SLS2560
1 EPA 200.8
01/09/2016 20:04
SLS2560
1 EPA 200.8
01/09/2016 20:04
SLS2560
1 EPA 200.8
01/09/2016 20:04
SLS2560
1 EPA 200.8
01/09/2016 20:04
SLS2560
1 EPA 200.8
01/09/2016 20:04
SLS2560
1 EPA 200.8
01/09/2016 20:04
SLS2560
1 EPA 200.8
01/09/2016 20:04
SLS2560
1 EPA 200.8
01/09/2016 20:04
SLS2560
1 EPA 200.8
01/09/2016 20:04
SLS2560
1 EPA 200.8
01/09/2016 20:04
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/08/201615:47 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/08/2016 09:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: MW-08BR
Collection Date: 06-Jan-16 10:32 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.123 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
130
mg/L
2
Sulfate
37
mg/L
2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.037
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.163
mg/L
0.01
Manganese (Mn)
0.748
mg/L
0.005
Strontium (Sr)
0.380
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
77.5
mg/L
0.01
Magnesium (Mg)
23.3
mg/L
M4 0.05
Potassium (K)
6.02
mg/L
0.1
Sodium (Na)
33.4
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.185
mg/L
0.005
Barium (Ba)
0.034
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.417
mg/L
0.01
Manganese (Mn)
0.681
mg/L
0.005
Strontium (Sr)
0.372
mg/L
0.005
Zinc (Zn)
0.005
mg/L
0.005
Sample #: 2016000431
Matrix: GW WW
Page 8 of 67
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 13:24 LSTARL1
Vendor Method V_PACE
20
EPA 300.0
01/08/2016 18:35
BGN9034
20
EPA 300.0
01/08/2016 18:35
BGN9034
1
EPA 245.1
01/08/2016 15:04
ACPAYNE
1
EPA 245.1
01/09/2016 12:16
ACPAYNE
1
EPA 200.7
01/08/2016 12:55
FCJORDA
1
EPA 200.7
01/08/2016 12:55
FCJORDA
1
EPA 200.7
01/08/2016 12:55
FCJORDA
1
EPA 200.7
01/08/2016 12:55
FCJORDA
1
EPA 200.7
01/08/2016 12:55
FCJORDA
1
EPA 200.7
01/08/2016 12:55
FCJORDA
1
EPA 200.7
01/08/2016 12:55
FCJORDA
1
EPA 200.7
01/11/2016 11:09
FCJORDA
10
EPA 200.7
01/11/2016 11:09
FCJORDA
1
EPA 200.7
01/11/2016 11:09
FCJORDA
1
EPA 200.7
01/11/2016 11:09
FCJORDA
1
EPA 200.7
01/08/2016 14:53
FCJORDA
1
EPA 200.7
01/08/2016 14:53
FCJORDA
1
EPA 200.7
01/08/2016 14:53
FCJORDA
1
EPA 200.7
01/08/2016 14:53
FCJORDA
1
EPA 200.7
01/08/2016 14:53
FCJORDA
1
EPA 200.7
01/08/2016 14:53
FCJORDA
1
EPA 200.7
01/08/2016 14:53
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: MW-08BR
Collection Date: 06-Jan-16 10:32 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
3.43
ug/L
1
Nickel (Ni)
3.91
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
4.73
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
3.54
ug/L
1
Nickel (Ni)
4.24
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.432
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
480
mg/L
25
Total Carbon
TOC
1.4
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
6.0
mg/L
5
Page 9 of 67
Sample #:
2016000431
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/09/2016 21:56
SLS2560
1
EPA 200.8
01/09/2016 21:56
SLS2560
1
EPA 200.8
01/09/2016 21:56
SLS2560
1
EPA 200.8
01/09/2016 21:56
SLS2560
1
EPA 200.8
01/09/2016 21:56
SLS2560
1
EPA 200.8
01/09/2016 21:56
SLS2560
1
EPA 200.8
01/09/2016 21:56
SLS2560
1
EPA 200.8
01/09/2016 21:56
SLS2560
1
EPA 200.8
01/09/2016 21:56
SLS2560
1
EPA 200.8
01/09/2016 21:56
SLS2560
1
EPA 200.8
01/09/2016 21:56
SLS2560
1
EPA 200.8
01/09/2016 21:56
SLS2560
1
EPA 200.8
01/09/2016 21:56
SLS2560
1 EPA 200.8
01/09/2016 20:38
SLS2560
1 EPA 200.8
01/09/2016 20:38
SLS2560
1 EPA 200.8
01/09/2016 20:38
SLS2560
1 EPA 200.8
01/09/2016 20:38
SLS2560
1 EPA 200.8
01/09/2016 20:38
SLS2560
1 EPA 200.8
01/09/2016 20:38
SLS2560
1 EPA 200.8
01/09/2016 20:38
SLS2560
1 EPA 200.8
01/09/2016 20:38
SLS2560
1 EPA 200.8
01/09/2016 20:38
SLS2560
1 EPA 200.8
01/09/2016 20:38
SLS2560
1 EPA 200.8
01/09/2016 20:38
SLS2560
1 EPA 200.8
01/09/2016 20:38
SLS2560
1 EPA 200.8
01/09/2016 20:38
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/08/201615:47 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/08/2016 09:37 CJELLIO

Certificate of Laboratory Analysis Page 10 of 67
This report shall not be reproduced, except in full.
Order # J16010086
Site: MW-3 Dup
Collection Date: 06-Jan-16 9:38 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.056 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
46
mg/L
2
Sulfate
22
mg/L
0.5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.058
mg/L
0.005
Boron (B)
0.909
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
1.22
mg/L
0.005
Strontium (Sr)
0.323
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
26.3
mg/L
0.01
Magnesium (Mg)
8.84
mg/L
0.005
Potassium (K)
2.12
mg/L
0.1
Sodium (Na)
22.7
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.007
mg/L
0.005
Barium (Ba)
0.057
mg/L
0.005
Boron (B)
0.889
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
1.42
mg/L
0.005
Strontium (Sr)
0.326
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000432
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 13:25 LSTARL1
Vendor Method V_PACE
20
EPA 300.0
01/08/2016 21:16
BGN9034
5
EPA 300.0
01/08/2016 21:16
BGN9034
1
EPA 245.1
01/08/2016 15:07
ACPAYNE
1
EPA 245.1
01/09/2016 12:18
ACPAYNE
1
EPA 200.7
01/08/2016 13:07
FCJORDA
1
EPA 200.7
01/08/2016 13:07
FCJORDA
1
EPA 200.7
01/08/2016 13:07
FCJORDA
1
EPA 200.7
01/08/2016 13:07
FCJORDA
1
EPA 200.7
01/08/2016 13:07
FCJORDA
1
EPA 200.7
01/08/2016 13:07
FCJORDA
1
EPA 200.7
01/08/2016 13:07
FCJORDA
1
EPA 200.7
01/11/2016 11:24
FCJORDA
1
EPA 200.7
01/11/2016 11:24
FCJORDA
1
EPA 200.7
01/11/2016 11:24
FCJORDA
1
EPA 200.7
01/11/2016 11:24
FCJORDA
1
EPA 200.7
01/08/2016 14:57
FCJORDA
1
EPA 200.7
01/08/2016 14:57
FCJORDA
1
EPA 200.7
01/08/2016 14:57
FCJORDA
1
EPA 200.7
01/08/2016 14:57
FCJORDA
1
EPA 200.7
01/08/2016 14:57
FCJORDA
1
EPA 200.7
01/08/2016 14:57
FCJORDA
1
EPA 200.7
01/08/2016 14:57
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: MW-3 Dup
Collection Date: 06-Jan-16 9:38 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
3.03
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
3.01
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
180
mg/L
25
Total Carbon
TOC
0.886
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 11 of 67
Sample #:
2016000432
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/09/2016 13:10
SLS2560
1
EPA 200.8
01/09/2016 13:10
SLS2560
1
EPA 200.8
01/09/2016 13:10
SLS2560
1
EPA 200.8
01/09/2016 13:10
SLS2560
1
EPA 200.8
01/09/2016 13:10
SLS2560
1
EPA 200.8
01/09/2016 13:10
SLS2560
1
EPA 200.8
01/09/2016 13:10
SLS2560
1
EPA 200.8
01/09/2016 13:10
SLS2560
1
EPA 200.8
01/09/2016 13:10
SLS2560
1
EPA 200.8
01/09/2016 13:10
SLS2560
1
EPA 200.8
01/09/2016 13:10
SLS2560
1
EPA 200.8
01/09/2016 13:10
SLS2560
1
EPA 200.8
01/09/2016 13:10
SLS2560
1 EPA 200.8
01/09/2016 20:43
SLS2560
1 EPA 200.8
01/09/2016 20:43
SLS2560
1 EPA 200.8
01/09/2016 20:43
SLS2560
1 EPA 200.8
01/09/2016 20:43
SLS2560
1 EPA 200.8
01/09/2016 20:43
SLS2560
1 EPA 200.8
01/09/2016 20:43
SLS2560
1 EPA 200.8
01/09/2016 20:43
SLS2560
1 EPA 200.8
01/09/2016 20:43
SLS2560
1 EPA 200.8
01/09/2016 20:43
SLS2560
1 EPA 200.8
01/09/2016 20:43
SLS2560
1 EPA 200.8
01/09/2016 20:43
SLS2560
1 EPA 200.8
01/09/2016 20:43
SLS2560
1 EPA 200.8
01/09/2016 20:43
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/08/201615:47 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/08/2016 09:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: MW-71D
Collection Date: 06-Jan-16 12:10 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
73
mg/L
1
Sulfate
11
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.020
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.010
mg/L
0.01
Manganese (Mn)
0.070
mg/L
0.005
Strontium (Sr)
0.417
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
54.1
mg/L
0.01
Magnesium (Mg)
22.9
mg/L
0.05
Potassium (K)
1.98
mg/L
0.1
Sodium (Na)
32.3
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.052
mg/L
0.005
Barium (Ba)
0.019
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.154
mg/L
0.01
Manganese (Mn)
0.069
mg/L
0.005
Strontium (Sr)
0.417
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000433
Matrix: GW WW
Page 12 of 67
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 13:26 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
01/08/2016 19:10
BGN9034
10
EPA 300.0
01/08/2016 19:10
BGN9034
1
EPA 245.1
01/08/2016 15:09
ACPAYNE
1
EPA 245.1
01/09/2016 12:20
ACPAYNE
1
EPA 200.7
01/08/2016 13:10
FCJORDA
1
EPA 200.7
01/08/2016 13:10
FCJORDA
1
EPA 200.7
01/08/2016 13:10
FCJORDA
1
EPA 200.7
01/08/2016 13:10
FCJORDA
1
EPA 200.7
01/08/2016 13:10
FCJORDA
1
EPA 200.7
01/08/2016 13:10
FCJORDA
1
EPA 200.7
01/08/2016 13:10
FCJORDA
1
EPA 200.7
01/11/2016 11:35
FCJORDA
10
EPA 200.7
01/11/2016 11:35
FCJORDA
1
EPA 200.7
01/11/2016 11:35
FCJORDA
1
EPA 200.7
01/11/2016 11:35
FCJORDA
1
EPA 200.7
01/08/2016 15:01
FCJORDA
1
EPA 200.7
01/08/2016 15:01
FCJORDA
1
EPA 200.7
01/08/2016 15:01
FCJORDA
1
EPA 200.7
01/08/2016 15:01
FCJORDA
1
EPA 200.7
01/08/2016 15:01
FCJORDA
1
EPA 200.7
01/08/2016 15:01
FCJORDA
1
EPA 200.7
01/08/2016 15:01
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: MW-71D
Collection Date: 06-Jan-16 12:10 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.678
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.757
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
340
mg/L
25
Total Carbon
TOC
1.2
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 13 of 67
Sample #:
2016000433
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/09/2016 13:25
SLS2560
1
EPA 200.8
01/09/2016 13:25
SLS2560
1
EPA 200.8
01/09/2016 13:25
SLS2560
1
EPA 200.8
01/09/2016 13:25
SLS2560
1
EPA 200.8
01/09/2016 13:25
SLS2560
1
EPA 200.8
01/09/2016 13:25
SLS2560
1
EPA 200.8
01/09/2016 13:25
SLS2560
1
EPA 200.8
01/09/2016 13:25
SLS2560
1
EPA 200.8
01/09/2016 13:25
SLS2560
1
EPA 200.8
01/09/2016 13:25
SLS2560
1
EPA 200.8
01/09/2016 13:25
SLS2560
1
EPA 200.8
01/09/2016 13:25
SLS2560
1
EPA 200.8
01/09/2016 13:25
SLS2560
1 EPA 200.8
01/09/2016 20:48
SLS2560
1 EPA 200.8
01/09/2016 20:48
SLS2560
1 EPA 200.8
01/09/2016 20:48
SLS2560
1 EPA 200.8
01/09/2016 20:48
SLS2560
1 EPA 200.8
01/09/2016 20:48
SLS2560
1 EPA 200.8
01/09/2016 20:48
SLS2560
1 EPA 200.8
01/09/2016 20:48
SLS2560
1 EPA 200.8
01/09/2016 20:48
SLS2560
1 EPA 200.8
01/09/2016 20:48
SLS2560
1 EPA 200.8
01/09/2016 20:48
SLS2560
1 EPA 200.8
01/09/2016 20:48
SLS2560
1 EPA 200.8
01/09/2016 20:48
SLS2560
1 EPA 200.8
01/09/2016 20:48
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/08/201615:47 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/08/2016 09:37 CJELLIO

Certificate of Laboratory Analysis Page 14 of 67
This report shall not be reproduced, except in full.
Order # J16010086
Site: MW-7BR
Collection Date: 06-Jan-16 1:38 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.098 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
12
mg/L
0.2
Sulfate
2.3
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.151
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.405
mg/L
0.01
Manganese (Mn)
0.218
mg/L
0.005
Strontium (Sr)
1.04
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
60.1
mg/L
0.1
Magnesium (Mg)
13.5
mg/L
0.05
Potassium (K)
4.30
mg/L
1
Sodium (Na)
17.6
mg/L
0.5
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.017
mg/L
0.005
Barium (Ba)
0.150
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.422
mg/L
0.01
Manganese (Mn)
0.210
mg/L
0.005
Strontium (Sr)
1.02
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000434
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 13:27 LSTARL1
Vendor Method V_PACE
2
EPA 300.0
01/08/2016 20:40
BGN9034
1
EPA 300.0
01/08/2016 20:40
BGN9034
1
EPA 245.1
01/08/2016 15:12
ACPAYNE
1
EPA 245.1
01/09/2016 12:23
ACPAYNE
1
EPA 200.7
01/08/2016 13:14
FCJORDA
1
EPA 200.7
01/08/2016 13:14
FCJORDA
1
EPA 200.7
01/08/2016 13:14
FCJORDA
1
EPA 200.7
01/08/2016 13:14
FCJORDA
1
EPA 200.7
01/08/2016 13:14
FCJORDA
1
EPA 200.7
01/08/2016 13:14
FCJORDA
1
EPA 200.7
01/08/2016 13:14
FCJORDA
10
EPA 200.7
01/11/2016 11:39
FCJORDA
10
EPA 200.7
01/11/2016 11:39
FCJORDA
10
EPA 200.7
01/11/2016 11:39
FCJORDA
10
EPA 200.7
01/11/2016 11:39
FCJORDA
1
EPA 200.7
01/08/2016 15:05
FCJORDA
1
EPA 200.7
01/08/2016 15:05
FCJORDA
1
EPA 200.7
01/08/2016 15:05
FCJORDA
1
EPA 200.7
01/08/2016 15:05
FCJORDA
1
EPA 200.7
01/08/2016 15:05
FCJORDA
1
EPA 200.7
01/08/2016 15:05
FCJORDA
1
EPA 200.7
01/08/2016 15:05
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: MW-7BR
Collection Date: 06-Jan-16 1:38 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.93
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.98
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
260
mg/L
25
Total Carbon
TOC
0.854
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 15 of 67
Sample #:
2016000434
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/09/2016 13:15
SLS2560
1
EPA 200.8
01/09/2016 13:15
SLS2560
1
EPA 200.8
01/09/2016 13:15
SLS2560
1
EPA 200.8
01/09/2016 13:15
SLS2560
1
EPA 200.8
01/09/2016 13:15
SLS2560
1
EPA 200.8
01/09/2016 13:15
SLS2560
1
EPA 200.8
01/09/2016 13:15
SLS2560
1
EPA 200.8
01/09/2016 13:15
SLS2560
1
EPA 200.8
01/09/2016 13:15
SLS2560
1
EPA 200.8
01/09/2016 13:15
SLS2560
1
EPA 200.8
01/09/2016 13:15
SLS2560
1
EPA 200.8
01/09/2016 13:15
SLS2560
1
EPA 200.8
01/09/2016 13:15
SLS2560
1 EPA 200.8
01/09/2016 20:53
SLS2560
1 EPA 200.8
01/09/2016 20:53
SLS2560
1 EPA 200.8
01/09/2016 20:53
SLS2560
1 EPA 200.8
01/09/2016 20:53
SLS2560
1 EPA 200.8
01/09/2016 20:53
SLS2560
1 EPA 200.8
01/09/2016 20:53
SLS2560
1 EPA 200.8
01/09/2016 20:53
SLS2560
1 EPA 200.8
01/09/2016 20:53
SLS2560
1 EPA 200.8
01/09/2016 20:53
SLS2560
1 EPA 200.8
01/09/2016 20:53
SLS2560
1 EPA 200.8
01/09/2016 20:53
SLS2560
1 EPA 200.8
01/09/2016 20:53
SLS2560
1 EPA 200.8
01/09/2016 20:53
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/08/201615:47 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/08/2016 09:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: MW-04
Collection Date: 06-Jan-16 11:45 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.322 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
7.5
mg/L
0.1
Sulfate
38
mg/L
2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.008
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.067
mg/L
0.005
Strontium (Sr)
0.101
mg/L
0.005
Zinc (Zn)
0.058
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
26.2
mg/L
0.01
Magnesium (Mg)
7.54
mg/L
0.005
Potassium (K)
5.80
mg/L
0.1
Sodium (Na)
18.9
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.232
mg/L
0.005
Barium (Ba)
0.009
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.141
mg/L
0.01
Manganese (Mn)
0.079
mg/L
0.005
Strontium (Sr)
0.095
mg/L
0.005
Zinc (Zn)
0.053
mg/L
0.005
Sample #: 2016000435
Matrix: GW WW
Page 16 of 67
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 13:35 LSTARL1
Vendor Method V_PACE
1
EPA 300.0
01/09/2016 09:43
BGN9034
20
EPA 300.0
01/09/2016 09:43
BGN9034
1
EPA 245.1
01/08/2016 15:19
ACPAYNE
1
EPA 245.1
01/09/2016 12:30
ACPAYNE
1
EPA 200.7
01/08/2016 13:18
FCJORDA
1
EPA 200.7
01/08/2016 13:18
FCJORDA
1
EPA 200.7
01/08/2016 13:18
FCJORDA
1
EPA 200.7
01/08/2016 13:18
FCJORDA
1
EPA 200.7
01/08/2016 13:18
FCJORDA
1
EPA 200.7
01/08/2016 13:18
FCJORDA
1
EPA 200.7
01/08/2016 13:18
FCJORDA
1
EPA 200.7
01/11/2016 11:43
FCJORDA
1
EPA 200.7
01/11/2016 11:43
FCJORDA
1
EPA 200.7
01/11/2016 11:43
FCJORDA
1
EPA 200.7
01/11/2016 11:43
FCJORDA
1
EPA 200.7
01/08/2016 15:09
FCJORDA
1
EPA 200.7
01/08/2016 15:09
FCJORDA
1
EPA 200.7
01/08/2016 15:09
FCJORDA
1
EPA 200.7
01/08/2016 15:09
FCJORDA
1
EPA 200.7
01/08/2016 15:09
FCJORDA
1
EPA 200.7
01/08/2016 15:09
FCJORDA
1
EPA 200.7
01/08/2016 15:09
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: MW-04
Collection Date: 06-Jan-16 11:45 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.55
ug/L
1
Nickel (Ni)
2.06
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.579
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
4.21
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
1.66
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.80
ug/L
1
Nickel (Ni)
3.06
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.803
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
210
mg/L
25
Total Carbon
TOC
0.717
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 17 of 67
Sample #:
2016000435
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/09/2016 13:20
SLS2560
1
EPA 200.8
01/09/2016 13:20
SLS2560
1
EPA 200.8
01/09/2016 13:20
SLS2560
1
EPA 200.8
01/09/2016 13:20
SLS2560
1
EPA 200.8
01/09/2016 13:20
SLS2560
1
EPA 200.8
01/09/2016 13:20
SLS2560
1
EPA 200.8
01/09/2016 13:20
SLS2560
1
EPA 200.8
01/09/2016 13:20
SLS2560
1
EPA 200.8
01/09/2016 13:20
SLS2560
1
EPA 200.8
01/09/2016 13:20
SLS2560
1
EPA 200.8
01/09/2016 13:20
SLS2560
1
EPA 200.8
01/09/2016 13:20
SLS2560
1
EPA 200.8
01/09/2016 13:20
SLS2560
1 EPA 200.8
01/09/2016 20:57
SLS2560
1 EPA 200.8
01/09/2016 20:57
SLS2560
1 EPA 200.8
01/09/2016 20:57
SLS2560
1 EPA 200.8
01/09/2016 20:57
SLS2560
1 EPA 200.8
01/09/2016 20:57
SLS2560
1 EPA 200.8
01/09/2016 20:57
SLS2560
1 EPA 200.8
01/09/2016 20:57
SLS2560
1 EPA 200.8
01/09/2016 20:57
SLS2560
1 EPA 200.8
01/09/2016 20:57
SLS2560
1 EPA 200.8
01/09/2016 20:57
SLS2560
1 EPA 200.8
01/09/2016 20:57
SLS2560
1 EPA 200.8
01/09/2016 20:57
SLS2560
1 EPA 200.8
01/09/2016 20:57
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/08/201615:47 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/08/2016 09:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: ABMW-3
Collection Date: 05-Jan-16 11:10 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.011 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
62
mg/L
1
Sulfate
3.7
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.037
mg/L
0.005
Barium (Ba)
0.277
mg/L
0.005
Boron (B)
1.77
mg/L
0.05
Iron (Fe)
22.5
mg/L
0.01
Manganese (Mn)
1.09
mg/L
0.005
Strontium (Sr)
1.60
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
62.5
mg/L
0.01
Magnesium (Mg)
13.7
mg/L
0.005
Potassium (K)
12.7
mg/L
0.1
Sodium (Na)
10.3
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.098
mg/L
0.005
Barium (Ba)
0.292
mg/L
0.005
Boron (B)
1.80
mg/L
0.05
Iron (Fe)
26.2
mg/L
0.01
Manganese (Mn)
1.21
mg/L
0.005
Strontium (Sr)
1.66
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000436
Matrix: GW WW
Page 18 of 67
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 13:38 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
01/08/2016 21:34
BGN9034
1
EPA 300.0
01/08/2016 21:34
BGN9034
1
EPA 245.1
01/08/2016 15:26
ACPAYNE
1
EPA 245.1
01/09/2016 12:37
ACPAYNE
1
EPA 200.7
01/08/2016 13:22
FCJORDA
1
EPA 200.7
01/08/2016 13:22
FCJORDA
1
EPA 200.7
01/08/2016 13:22
FCJORDA
1
EPA 200.7
01/08/2016 13:22
FCJORDA
1
EPA 200.7
01/08/2016 13:22
FCJORDA
1
EPA 200.7
01/08/2016 13:22
FCJORDA
1
EPA 200.7
01/08/2016 13:22
FCJORDA
1
EPA 200.7
01/11/2016 11:47
FCJORDA
1
EPA 200.7
01/11/2016 11:47
FCJORDA
1
EPA 200.7
01/11/2016 11:47
FCJORDA
1
EPA 200.7
01/11/2016 11:47
FCJORDA
1
EPA 200.7
01/08/2016 15:14
FCJORDA
1
EPA 200.7
01/08/2016 15:14
FCJORDA
1
EPA 200.7
01/08/2016 15:14
FCJORDA
1
EPA 200.7
01/08/2016 15:14
FCJORDA
1
EPA 200.7
01/08/2016 15:14
FCJORDA
1
EPA 200.7
01/08/2016 15:14
FCJORDA
1
EPA 200.7
01/08/2016 15:14
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: ABMW-3
Collection Date: 05-Jan-16 11:10 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
82.7
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
11.8
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.302
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
79.8
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
1.29
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
10.6
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.603
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
310
mg/L
25
Total Carbon
TOC
3.0
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
43
mg/L
5
Page 19 of 67
Sample #:
2016000436
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/11/2016 12:53
SLS2560
1
EPA 200.8
01/11/2016 12:53
SLS2560
1
EPA 200.8
01/11/2016 12:53
SLS2560
1
EPA 200.8
01/11/2016 12:53
SLS2560
1
EPA 200.8
01/11/2016 12:53
SLS2560
1
EPA 200.8
01/11/2016 12:53
SLS2560
1
EPA 200.8
01/11/2016 12:53
SLS2560
1
EPA 200.8
01/11/2016 12:53
SLS2560
1
EPA 200.8
01/11/2016 12:53
SLS2560
1
EPA 200.8
01/11/2016 12:53
SLS2560
1
EPA 200.8
01/11/2016 12:53
SLS2560
1
EPA 200.8
01/11/2016 12:53
SLS2560
1
EPA 200.8
01/11/2016 12:53
SLS2560
1 EPA 200.8
01/09/2016 21:02
SLS2560
1 EPA 200.8
01/09/2016 21:02
SLS2560
1 EPA 200.8
01/09/2016 21:02
SLS2560
1 EPA 200.8
01/09/2016 21:02
SLS2560
1 EPA 200.8
01/09/2016 21:02
SLS2560
1 EPA 200.8
01/09/2016 21:02
SLS2560
1 EPA 200.8
01/09/2016 21:02
SLS2560
1 EPA 200.8
01/09/2016 21:02
SLS2560
1 EPA 200.8
01/09/2016 21:02
SLS2560
1 EPA 200.8
01/09/2016 21:02
SLS2560
1 EPA 200.8
01/09/2016 21:02
SLS2560
1 EPA 200.8
01/09/2016 21:02
SLS2560
1 EPA 200.8
01/09/2016 21:02
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/08/201615:47 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/08/2016 09:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: ABMW-3S
Collection Date: 05-Jan-16 10:35 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
12
mg/L
0.2
Sulfate
0.24
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.012
mg/L
0.005
Barium (Ba)
0.018
mg/L
0.005
Boron (B)
1.23
mg/L
0.05
Iron (Fe)
3.70
mg/L
0.01
Manganese (Mn)
0.529
mg/L
0.005
Strontium (Sr)
0.073
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
4.06
mg/L
0.01
Magnesium (Mg)
0.863
mg/L
0.005
Potassium (K)
1.03
mg/L
0.1
Sodium (Na)
17.1
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.042
mg/L
0.005
Barium (Ba)
0.020
mg/L
0.005
Boron (B)
1.22
mg/L
0.05
Iron (Fe)
4.34
mg/L
0.01
Manganese (Mn)
0.531
mg/L
0.005
Strontium (Sr)
0.078
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000437
Matrix: GW WW
Page 20 of 67
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 13:39 LSTARL1
Vendor Method V_PACE
2 EPA 300.0
01/09/2016 10:01
BGN9034
1 EPA 300.0
01/09/2016 10:01
BGN9034
1 EPA 245.1
01/08/2016 15:28
ACPAYNE
1 EPA 245.1
01/09/2016 12:39
ACPAYNE
1 EPA 200.7
01/08/2016 13:26
FCJORDA
1 EPA 200.7
01/08/2016 13:26
FCJORDA
1 EPA 200.7
01/08/2016 13:26
FCJORDA
1 EPA 200.7
01/08/2016 13:26
FCJORDA
1 EPA 200.7
01/08/2016 13:26
FCJORDA
1 EPA 200.7
01/08/2016 13:26
FCJORDA
1 EPA 200.7
01/08/2016 13:26
FCJORDA
1 EPA 200.7
01/11/2016 11:51
FCJORDA
1 EPA 200.7
01/11/2016 11:51
FCJORDA
1 EPA 200.7
01/11/2016 11:51
FCJORDA
1 EPA 200.7
01/11/2016 11:51
FCJORDA
1 EPA 200.7
01/08/2016 15:35
FCJORDA
1 EPA 200.7
01/08/2016 15:35
FCJORDA
1 EPA 200.7
01/08/2016 15:35
FCJORDA
1 EPA 200.7
01/08/2016 15:35
FCJORDA
1 EPA 200.7
01/08/2016 15:35
FCJORDA
1 EPA 200.7
01/08/2016 15:35
FCJORDA
1 EPA 200.7
01/08/2016 15:35
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: ABMW-3S
Collection Date: 05-Jan-16 10:35 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
1.28
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
3.39
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
1.35
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
3.42
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.19
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
97
mg/L
25
Total Carbon
TOC
0.498
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 21 of 67
Sample #:
2016000437
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/09/2016 13:59
SLS2560
1
EPA 200.8
01/09/2016 13:59
SLS2560
1
EPA 200.8
01/09/2016 13:59
SLS2560
1
EPA 200.8
01/09/2016 13:59
SLS2560
1
EPA 200.8
01/09/2016 13:59
SLS2560
1
EPA 200.8
01/09/2016 13:59
SLS2560
1
EPA 200.8
01/09/2016 13:59
SLS2560
1
EPA 200.8
01/09/2016 13:59
SLS2560
1
EPA 200.8
01/09/2016 13:59
SLS2560
1
EPA 200.8
01/09/2016 13:59
SLS2560
1
EPA 200.8
01/09/2016 13:59
SLS2560
1
EPA 200.8
01/09/2016 13:59
SLS2560
1
EPA 200.8
01/09/2016 13:59
SLS2560
1 EPA 200.8
01/09/2016 21:07
SLS2560
1 EPA 200.8
01/09/2016 21:07
SLS2560
1 EPA 200.8
01/09/2016 21:07
SLS2560
1 EPA 200.8
01/09/2016 21:07
SLS2560
1 EPA 200.8
01/09/2016 21:07
SLS2560
1 EPA 200.8
01/09/2016 21:07
SLS2560
1 EPA 200.8
01/09/2016 21:07
SLS2560
1 EPA 200.8
01/09/2016 21:07
SLS2560
1 EPA 200.8
01/09/2016 21:07
SLS2560
1 EPA 200.8
01/09/2016 21:07
SLS2560
1 EPA 200.8
01/09/2016 21:07
SLS2560
1 EPA 200.8
01/09/2016 21:07
SLS2560
1 EPA 200.8
01/09/2016 21:07
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/08/201615:47 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/08/2016 09:37 CJELLIO

Certificate of Laboratory Analysis Page 22 of 67
This report shall not be reproduced, except in full.
Order # J16010086
Site: Filter Blank
Collection Date: 06-Jan-16 4:45 PM
Analyte
Result
Units Qualifiers
RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2016000438
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
01/09/2016 12:41
ACPAYNE
1
EPA 200.7
01/08/2016 13:30
FCJORDA
1
EPA 200.7
01/08/2016 13:30
FCJORDA
1
EPA 200.7
01/08/2016 13:30
FCJORDA
1
EPA 200.7
01/08/2016 13:30
FCJORDA
1
EPA 200.7
01/08/2016 13:30
FCJORDA
1
EPA 200.7
01/08/2016 13:30
FCJORDA
1
EPA 200.7
01/08/2016 13:30
FCJORDA
1
EPA 200.8
01/09/2016 14:04
SLS2560
1
EPA 200.8
01/09/2016 14:04
SLS2560
1
EPA 200.8
01/09/2016 14:04
SLS2560
1
EPA 200.8
01/09/2016 14:04
SLS2560
1
EPA 200.8
01/09/2016 14:04
SLS2560
1
EPA 200.8
01/09/2016 14:04
SLS2560
1
EPA 200.8
01/09/2016 14:04
SLS2560
1
EPA 200.8
01/09/2016 14:04
SLS2560
1
EPA 200.8
01/09/2016 14:04
SLS2560
1
EPA 200.8
01/09/2016 14:04
SLS2560
1
EPA 200.8
01/09/2016 14:04
SLS2560
1
EPA 200.8
01/09/2016 14:04
SLS2560
1
EPA 200.8
01/09/2016 14:04
SLS2560

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: Equipment Blank
Collection Date: 06-Jan-16 4:45 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.111 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
Calcium (Ca)
< 0.01
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Page 23 of 67
Sample #: 2016000439
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_PACE
1 EPA 353.2
01/07/2016 13:41
LSTARL1
Vendor Method
V_PACE
1 EPA 300.0
01/08/2016 16:57
BGN9034
1 EPA 300.0
01/08/2016 16:57
BGN9034
1 EPA 245.1
01/08/2016 15:30
ACPAYNE
1 EPA 200.7
01/11/2016 11:55
FCJORDA
1 EPA 200.7
01/11/2016 11:55
FCJORDA
1 EPA 200.7
01/11/2016 11:55
FCJORDA
1 EPA 200.7
01/11/2016 11:55
FCJORDA
1 EPA 200.7
01/08/2016 15:18
FCJORDA
1 EPA 200.7
01/08/2016 15:18
FCJORDA
1 EPA 200.7
01/08/2016 15:18
FCJORDA
1 EPA 200.7
01/08/2016 15:18
FCJORDA
1 EPA 200.7
01/08/2016 15:18
FCJORDA
1 EPA 200.7
01/08/2016 15:18
FCJORDA
1 EPA 200.7
01/08/2016 15:18
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: Equipment Blank
Collection Date: 06-Jan-16 4:45 PM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
< 25
mg/L
25
1
Total Carbon
Page 24 of 67
Sample #:
2016000439
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
01/09/2016 21:12
SLS2560
EPA 200.8
01/09/2016 21:12
SLS2560
EPA 200.8
01/09/2016 21:12
SLS2560
EPA 200.8
01/09/2016 21:12
SLS2560
EPA 200.8
01/09/2016 21:12
SLS2560
EPA 200.8
01/09/2016 21:12
SLS2560
EPA 200.8
01/09/2016 21:12
SLS2560
EPA 200.8
01/09/2016 21:12
SLS2560
EPA 200.8
01/09/2016 21:12
SLS2560
EPA 200.8
01/09/2016 21:12
SLS2560
EPA 200.8
01/09/2016 21:12
SLS2560
EPA 200.8
01/09/2016 21:12
SLS2560
EPA 200.8
01/09/2016 21:12
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
SM2540C 01/08/201615:47 CJELLIO
TOC 0.245 mg/L 0.1 1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 01/08/2016 09:37 CJELLIO

Certificate of Laboratory Analysis Page 25 of 67
This report shall not be reproduced, except in full.
Order # J16010086
Site: CW-6
Collection Date: 06-Jan-16 4:40 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.182 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
100
mg/L
2
Sulfate
41
mg/L
2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.044
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.82
mg/L
0.01
Manganese (Mn)
1.43
mg/L
0.005
Strontium (Sr)
0.332
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
107
mg/L
0.1
Magnesium (Mg)
22.1
mg/L
0.05
Potassium (K)
10.4
mg/L
1
Sodium (Na)
39.0
mg/L
0.5
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.040
mg/L
0.005
Barium (Ba)
0.041
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.79
mg/L
0.01
Manganese (Mn)
1.44
mg/L
0.005
Strontium (Sr)
0.329
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000440
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 13:42 LSTARL1
Vendor Method V_PACE
20
EPA 300.0
01/08/2016 15:10
BGN9034
20
EPA 300.0
01/08/2016 15:10
BGN9034
1
EPA 245.1
01/08/2016 15:33
ACPAYNE
1
EPA 245.1
01/09/2016 12:44
ACPAYNE
1
EPA 200.7
01/08/2016 13:41
FCJORDA
1
EPA 200.7
01/08/2016 13:41
FCJORDA
1
EPA 200.7
01/08/2016 13:41
FCJORDA
1
EPA 200.7
01/08/2016 13:41
FCJORDA
1
EPA 200.7
01/08/2016 13:41
FCJORDA
1
EPA 200.7
01/08/2016 13:41
FCJORDA
1
EPA 200.7
01/08/2016 13:41
FCJORDA
10
EPA 200.7
01/11/2016 12:11
FCJORDA
10
EPA 200.7
01/11/2016 12:11
FCJORDA
10
EPA 200.7
01/11/2016 12:11
FCJORDA
10
EPA 200.7
01/11/2016 12:11
FCJORDA
1
EPA 200.7
01/08/2016 15:22
FCJORDA
1
EPA 200.7
01/08/2016 15:22
FCJORDA
1
EPA 200.7
01/08/2016 15:22
FCJORDA
1
EPA 200.7
01/08/2016 15:22
FCJORDA
1
EPA 200.7
01/08/2016 15:22
FCJORDA
1
EPA 200.7
01/08/2016 15:22
FCJORDA
1
EPA 200.7
01/08/2016 15:22
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: CW-6
Collection Date: 06-Jan-16 4:40 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
3.36
ug/L
1
Nickel (Ni)
1.03
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
3.55
ug/L
1
Nickel (Ni)
1.10
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
520
mg/L
25
Total Carbon
TOC
1.7
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 26 of 67
Sample #:
2016000440
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/09/2016 14:09
SLS2560
1
EPA 200.8
01/09/2016 14:09
SLS2560
1
EPA 200.8
01/09/2016 14:09
SLS2560
1
EPA 200.8
01/09/2016 14:09
SLS2560
1
EPA 200.8
01/09/2016 14:09
SLS2560
1
EPA 200.8
01/09/2016 14:09
SLS2560
1
EPA 200.8
01/09/2016 14:09
SLS2560
1
EPA 200.8
01/09/2016 14:09
SLS2560
1
EPA 200.8
01/09/2016 14:09
SLS2560
1
EPA 200.8
01/09/2016 14:09
SLS2560
1
EPA 200.8
01/09/2016 14:09
SLS2560
1
EPA 200.8
01/09/2016 14:09
SLS2560
1
EPA 200.8
01/09/2016 14:09
SLS2560
1 EPA 200.8
01/09/2016 21:32
SLS2560
1 EPA 200.8
01/09/2016 21:32
SLS2560
1 EPA 200.8
01/09/2016 21:32
SLS2560
1 EPA 200.8
01/09/2016 21:32
SLS2560
1 EPA 200.8
01/09/2016 21:32
SLS2560
1 EPA 200.8
01/09/2016 21:32
SLS2560
1 EPA 200.8
01/09/2016 21:32
SLS2560
1 EPA 200.8
01/09/2016 21:32
SLS2560
1 EPA 200.8
01/09/2016 21:32
SLS2560
1 EPA 200.8
01/09/2016 21:32
SLS2560
1 EPA 200.8
01/09/2016 21:32
SLS2560
1 EPA 200.8
01/09/2016 21:32
SLS2560
1 EPA 200.8
01/09/2016 21:32
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/08/201615:47 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/08/2016 09:37 CJELLIO

Certificate of Laboratory Analysis Page 27 of 67
This report shall not be reproduced, except in full.
Order # J16010086
Site: CW-2
Collection Date: 06-Jan-16 3:35 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.019 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
40
mg/L
1
Sulfate
35
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.010
mg/L
0.005
Barium (Ba)
0.100
mg/L
0.005
Boron (B)
0.552
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.182
mg/L
0.005
Strontium (Sr)
0.177
mg/L
0.005
Zinc (Zn)
0.007
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
12.9
mg/L
0.01
Magnesium (Mg)
6.70
mg/L
0.005
Potassium (K)
1.79
mg/L
0.1
Sodium (Na)
12.9
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.028
mg/L
0.005
Barium (Ba)
0.099
mg/L
0.005
Boron (B)
0.539
mg/L
0.05
Iron (Fe)
0.011
mg/L
0.01
Manganese (Mn)
0.173
mg/L
0.005
Strontium (Sr)
0.177
mg/L
0.005
Zinc (Zn)
0.007
mg/L
0.005
Sample #: 2016000441
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 13:43 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
01/08/2016 15:27
BGN9034
10
EPA 300.0
01/08/2016 15:27
BGN9034
1
EPA 245.1
01/08/2016 15:35
ACPAYNE
1
EPA 245.1
01/09/2016 12:46
ACPAYNE
1
EPA 200.7
01/08/2016 13:45
FCJORDA
1
EPA 200.7
01/08/2016 13:45
FCJORDA
1
EPA 200.7
01/08/2016 13:45
FCJORDA
1
EPA 200.7
01/08/2016 13:45
FCJORDA
1
EPA 200.7
01/08/2016 13:45
FCJORDA
1
EPA 200.7
01/08/2016 13:45
FCJORDA
1
EPA 200.7
01/08/2016 13:45
FCJORDA
1
EPA 200.7
01/11/2016 12:14
FCJORDA
1
EPA 200.7
01/11/2016 12:14
FCJORDA
1
EPA 200.7
01/11/2016 12:14
FCJORDA
1
EPA 200.7
01/11/2016 12:14
FCJORDA
1
EPA 200.7
01/08/2016 15:47
FCJORDA
1
EPA 200.7
01/08/2016 15:47
FCJORDA
1
EPA 200.7
01/08/2016 15:47
FCJORDA
1
EPA 200.7
01/08/2016 15:47
FCJORDA
1
EPA 200.7
01/08/2016 15:47
FCJORDA
1
EPA 200.7
01/08/2016 15:47
FCJORDA
1
EPA 200.7
01/08/2016 15:47
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: CW-2
Collection Date: 06-Jan-16 3:35 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.58
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.49
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
130
mg/L
25
Total Carbon
TOC
1.2
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 28 of 67
Sample #:
2016000441
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/09/2016 14:14
SLS2560
1
EPA 200.8
01/09/2016 14:14
SLS2560
1
EPA 200.8
01/09/2016 14:14
SLS2560
1
EPA 200.8
01/09/2016 14:14
SLS2560
1
EPA 200.8
01/09/2016 14:14
SLS2560
1
EPA 200.8
01/09/2016 14:14
SLS2560
1
EPA 200.8
01/09/2016 14:14
SLS2560
1
EPA 200.8
01/09/2016 14:14
SLS2560
1
EPA 200.8
01/09/2016 14:14
SLS2560
1
EPA 200.8
01/09/2016 14:14
SLS2560
1
EPA 200.8
01/09/2016 14:14
SLS2560
1
EPA 200.8
01/09/2016 14:14
SLS2560
1
EPA 200.8
01/09/2016 14:14
SLS2560
1 EPA 200.8
01/10/2016 10:08
SLS2560
1 EPA 200.8
01/10/2016 10:08
SLS2560
1 EPA 200.8
01/10/2016 10:08
SLS2560
1 EPA 200.8
01/10/2016 10:08
SLS2560
1 EPA 200.8
01/10/2016 10:08
SLS2560
1 EPA 200.8
01/10/2016 10:08
SLS2560
1 EPA 200.8
01/10/2016 10:08
SLS2560
1 EPA 200.8
01/10/2016 10:08
SLS2560
1 EPA 200.8
01/10/2016 10:08
SLS2560
1 EPA 200.8
01/10/2016 10:08
SLS2560
1 EPA 200.8
01/10/2016 10:08
SLS2560
1 EPA 200.8
01/10/2016 10:08
SLS2560
1 EPA 200.8
01/10/2016 10:08
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/08/201615:47 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/08/2016 09:37 CJELLIO

Certificate of Laboratory Analysis Page 29 of 67
This report shall not be reproduced, except in full.
Order # J16010086
Site: CW-21D
Collection Date: 06-Jan-16 3:00 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.040 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
56
mg/L
1
Sulfate
43
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.050
mg/L
0.005
Boron (B)
0.507
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.077
mg/L
0.005
Strontium (Sr)
0.245
mg/L
0.005
Zinc (Zn)
0.029
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
25.4
mg/L
0.01
Magnesium (Mg)
6.84
mg/L
0.005
Potassium (K)
2.70
mg/L
0.1
Sodium (Na)
23.1
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.724
mg/L
0.005
Barium (Ba)
0.051
mg/L
0.005
Boron (B)
0.484
mg/L
0.05
Iron (Fe)
0.332
mg/L
0.01
Manganese (Mn)
0.148
mg/L
0.005
Strontium (Sr)
0.255
mg/L
0.005
Zinc (Zn)
0.026
mg/L
0.005
Sample #: 2016000442
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/07/2016 13:44 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
01/08/2016 15:45
BGN9034
10
EPA 300.0
01/08/2016 15:45
BGN9034
1
EPA 245.1
01/08/2016 15:37
ACPAYNE
1
EPA 245.1
01/09/2016 12:49
ACPAYNE
1
EPA 200.7
01/08/2016 13:49
FCJORDA
1
EPA 200.7
01/08/2016 13:49
FCJORDA
1
EPA 200.7
01/08/2016 13:49
FCJORDA
1
EPA 200.7
01/08/2016 13:49
FCJORDA
1
EPA 200.7
01/08/2016 13:49
FCJORDA
1
EPA 200.7
01/08/2016 13:49
FCJORDA
1
EPA 200.7
01/08/2016 13:49
FCJORDA
1
EPA 200.7
01/11/2016 12:18
FCJORDA
1
EPA 200.7
01/11/2016 12:18
FCJORDA
1
EPA 200.7
01/11/2016 12:18
FCJORDA
1
EPA 200.7
01/11/2016 12:18
FCJORDA
1
EPA 200.7
01/08/2016 15:51
FCJORDA
1
EPA 200.7
01/08/2016 15:51
FCJORDA
1
EPA 200.7
01/08/2016 15:51
FCJORDA
1
EPA 200.7
01/08/2016 15:51
FCJORDA
1
EPA 200.7
01/08/2016 15:51
FCJORDA
1
EPA 200.7
01/08/2016 15:51
FCJORDA
1
EPA 200.7
01/08/2016 15:51
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
Site: CW-21D
Collection Date: 06-Jan-16 3:00 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.01
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.594
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
220
mg/L
25
Total Carbon
TOC
0.538
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
13
mg/L
5
Page 30 of 67
Sample #:
2016000442
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/09/2016 14:19
SLS2560
1
EPA 200.8
01/09/2016 14:19
SLS2560
1
EPA 200.8
01/09/2016 14:19
SLS2560
1
EPA 200.8
01/09/2016 14:19
SLS2560
1
EPA 200.8
01/09/2016 14:19
SLS2560
1
EPA 200.8
01/09/2016 14:19
SLS2560
1
EPA 200.8
01/09/2016 14:19
SLS2560
1
EPA 200.8
01/09/2016 14:19
SLS2560
1
EPA 200.8
01/09/2016 14:19
SLS2560
1
EPA 200.8
01/09/2016 14:19
SLS2560
1
EPA 200.8
01/09/2016 14:19
SLS2560
1
EPA 200.8
01/09/2016 14:19
SLS2560
1
EPA 200.8
01/09/2016 14:19
SLS2560
1 EPA 200.8
01/09/2016 21:51
SLS2560
1 EPA 200.8
01/09/2016 21:51
SLS2560
1 EPA 200.8
01/09/2016 21:51
SLS2560
1 EPA 200.8
01/09/2016 21:51
SLS2560
1 EPA 200.8
01/09/2016 21:51
SLS2560
1 EPA 200.8
01/09/2016 21:51
SLS2560
1 EPA 200.8
01/09/2016 21:51
SLS2560
1 EPA 200.8
01/09/2016 21:51
SLS2560
1 EPA 200.8
01/09/2016 21:51
SLS2560
1 EPA 200.8
01/09/2016 21:51
SLS2560
1 EPA 200.8
01/09/2016 21:51
SLS2560
1 EPA 200.8
01/09/2016 21:51
SLS2560
1 EPA 200.8
01/09/2016 21:51
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/08/201615:47 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/08/2016 09:37 CJELLIO

Site: CW-21D
Collection Date: 06-Jan-16 3:00 PM
Certificate of Laboratory Analysis Page 31 of 67
This report shall not be reproduced, except in full.
Order # J16010086
Sample #: 2016000442
Matrix: GW WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
Qualifiers:
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098nn roe. Suite 100
Huntersville, INC 28078
[phone]
January 12, 2016
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 16010086
Pace Project No.: 92282172
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 07, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Anne Pifer
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 34

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
OQ9l9gcsfoe. Suite 100
Huntersville, NC 28078
[phone]
Project: J16010086
Pace Project No.: 92282172
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A21-A Certification M 2926.01
Alaska Certification M UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification M 88-0680
California Certification M 01155CA
Colorado Certification #Pace
Connecticut Certification M PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification M 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
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Indiana Certification#C-MN-01
Iowa Certification M 368
Kansas Certification #: E-10167
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Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification M 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification M 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification M E83079
Georgia Certification M 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification M 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification M E-10383
Kentucky Certification #: 90050
Louisiana Certification M FL NELAC Reciprocity
Louisiana Environmental Certificate M 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification M Cert 0074
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification M TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification M 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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SAMPLE SUMMARY
Project: J16010086
Pace Project No.: 92282172
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92282172001
2016000429
Water
01/06/16 09:38
01/07/1614:05
92282172002
2016000430
Water
01/06/1612:25
01/07/1614:05
92282172003
2016000431
Water
01/06/1610:32
01/07/1614:05
92282172004
2016000432
Water
01/06/16 09:38
01/07/1614:05
92282172005
2016000433
Water
01/06/1612:10
01/07/1614:05
92282172006
2016000434
Water
01/06/1613:38
01/07/1614:05
92282172007
2016000435
Water
01/06/1611:45
01/07/1614:05
92282172008
2016000436
Water
01/05/1611:10
01/07/1614:05
92282172009
2016000437
Water
01/05/1610:35
01/07/1614:05
92282172010
2016000439
Water
01/06/1616:45
01/07/1614:05
92282172011
2016000440
Water
01/06/1616:40
01/07/1614:05
92282172012
2016000441
Water
01/06/1615:35
01/07/1614:05
92282172013
2016000442
Water
01/06/1615:00
01/07/1614:05
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 34

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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16010086
92282172
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92282172001
2016000429
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282172002
2016000430
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282172003
2016000431
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282172004
2016000432
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282172005
2016000433
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282172006
2016000434
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282172007
2016000435
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282172008
2016000436
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282172009
2016000437
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282172010
2016000439
RSK 175
DR1
1
PASI-M
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project:
J16010086
Pace Project No.:
92282172
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282172011
2016000440
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282172012
2016000441
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282172013
2016000442
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 5 of 34

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SUMMARY OF DETECTION
Project:
Pace Project No.:
J16010086
92282172
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92282172001
2016000429
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
71.0
mg/L
5.0
01/10/16 12:55
SM 2320B
Alkalinity, Total as CaCO3
71.0
mg/L
5.0
01/10/16 12:55
EPA218.7
Chromium, Hexavalent
0.17
ug/L
0.030
01/08/1616:36 M1
92282172002
2016000430
RSK 175
Methane
802
ug/L
10.0
01/08/16 13:03
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
95.5
mg/L
5.0
01/10/16 13:34
SM 2320B
Alkalinity, Total as CaCO3
95.5
mg/L
5.0
01/10/16 13:34
92282172003
2016000431
RSK 175
Methane
14.4
ug/L
10.0
01/08/16 13:11
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
156
mg/L
5.0
01/10/16 13:46
SM 2320B
Alkalinity, Total as CaCO3
156
mg/L
5.0
01/10/16 13:46
92282172004
2016000432
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
69.5
mg/L
5.0
01/10/16 14:00
SM 2320B
Alkalinity, Total as CaCO3
69.5
mg/L
5.0
01/10/16 14:00
EPA218.7
Chromium, Hexavalent
0.17
ug/L
0.030
01/08/1617:41
92282172005
2016000433
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
181
mg/L
5.0
01/10/16 14:12
SM 2320B
Alkalinity, Total as CaCO3
181
mg/L
5.0
01/10/16 14:12
92282172006
2016000434
RSK 175
Methane
59.7
ug/L
10.0
01/08/16 14:10
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
218
mg/L
5.0
01/10/16 14:26
SM 2320B
Alkalinity, Total as CaCO3
218
mg/L
5.0
01/10/16 14:26
92282172007
2016000435
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
93.2
mg/L
5.0
01/10/16 15:00
SM 2320B
Alkalinity, Total as CaCO3
93.2
mg/L
5.0
01/10/16 15:00
EPA218.7
Chromium, Hexavalent
0.16
ug/L
0.030
01/08/1618:20
92282172008
2016000436
RSK 175
Methane
7850
ug/L
10.0
01/08/16 14:26
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
181
mg/L
5.0
01/10/16 15:13
SM 2320B
Alkalinity, Total as CaCO3
181
mg/L
5.0
01/10/16 15:13
92282172009
2016000437
RSK 175
Methane
108
ug/L
10.0
01/08/16 14:34
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
40.4
mg/L
5.0
01/10/16 15:28
SM 2320B
Alkalinity, Total as CaCO3
40.4
mg/L
5.0
01/10/16 15:28
92282172011
2016000440
RSK 175
Methane
90.8
ug/L
10.0
01/08/16 14:51
92282172012
2016000441
EPA 218.7
Chromium, Hexavalent
0.087
ug/L
0.030
01/08/16 20:17
92282172013
2016000442
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
25.4
mg/L
5.0
01/10/16 17:48
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Project: J16010086
Pace Project No.: 92282172
Lab Sample ID
Client Sample ID
Method
Parameters
92282172013
2016000442
SM 2320B
Alkalinity, Total as CaCO3
EPA 218.7
Chromium, Hexavalent
SUMMARY OF DETECTION
Result
Units
25.4
mg/L
0.089
ug/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Report Limit Analyzed Qualifiers
5.0 01/10/1617:48
0.030 01/08/1620:30
Page 7 of 34

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Pace Analytical Services, Inc.
098nn roe. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16010086
Pace Project No.: 92282172
Method: RSK 175
Description: RSK 175 AIR Headspace
Client: Duke Energy
Date: January 12, 2016
General Information:
13 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16010086
Pace Project No.: 92282172
Method: SM 2320B
Description: 2320E Alkalinity
Client: Duke Energy
Date: January 12, 2016
General Information:
13 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/42371
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92282172001,92282172011
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1643733)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1643734)
• Alkalinity, Total as CaCO3
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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[phone]
PROJECT NARRATIVE
Project: J16010086
Pace Project No.: 92282172
Method: SM 4500-S213
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: January 12, 2016
General Information:
13 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/42367
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92282172001,92282172011
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1643318)
• Sulfide
• MSD (Lab ID: 1643319)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16010086
Pace Project No.: 92282172
Method: EPA 218.7
Description: Hexavalent Chromium by IC
Client: Duke Energy
Date: January 12, 2016
General Information:
13 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 11 of 34

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ANALYTICAL RESULTS
Project: J16010086
Pace Project No.: 92282172
Sample: 2016000429
Lab ID: 92282172001 Collected:
01/06/16 09:38
Received: 01/07/16 14:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/08/1612:55
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
71.0 mg/L
5.0
1
01/10/16 12:55
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 12:55
Alkalinity, Total as CaCO3
71.0 mg/L
5.0
1
01/10/16 12:55
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/08/1615:00
18496-25-8 M1
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.17 ug/L
0.030
1
01/08/16 16:36
18540-29-9 M1
Date: 01 /12/2016 10:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 34

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[phone]
ANALYTICAL RESULTS
Project: J16010086
Pace Project No.: 92282172
Sample: 2016000430
Lab ID: 92282172002 Collected:
01/06/16 12:25
Received: 01/07/16 14:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
802 ug/L
10.0
1
01/08/1613:03
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
95.5 mg/L
5.0
1
01/10/16 13:34
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 13:34
Alkalinity, Total as CaCO3
95.5 mg/L
5.0
1
01/10/16 13:34
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/08/1615:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/08/16 17:15
18540-29-9
Date: 01 /12/2016 10:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 34

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Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010086
Pace Project No.: 92282172
Sample: 2016000431
Lab ID: 92282172003 Collected:
01/06/16 10:32
Received: 01/07/16 14:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
14.4 ug/L
10.0
1
01/08/1613:11
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
156 mg/L
5.0
1
01/10/16 13:46
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 13:46
Alkalinity, Total as CaCO3
156 mg/L
5.0
1
01/10/16 13:46
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/08/1615:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/08/16 17:28
18540-29-9
Date: 01 /12/2016 10:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 14 of 34

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Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010086
Pace Project No.: 92282172
Sample: 2016000432
Lab ID: 92282172004 Collected:
01/06/16 09:38
Received: 01/07/16 14:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/08/1613:19
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
69.5 mg/L
5.0
1
01/10/16 14:00
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 14:00
Alkalinity, Total as CaCO3
69.5 mg/L
5.0
1
01/10/16 14:00
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/08/1615:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.17 ug/L
0.030
1
01/08/16 17:41
18540-29-9
Date: 01 /12/2016 10:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 34

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Pace Analytical Services, Inc.
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ANALYTICAL RESULTS
Project: J16010086
Pace Project No.: 92282172
Sample: 2016000433
Lab ID: 92282172005 Collected:
01/06/16 12:10
Received: 01/07/16 14:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/08/1613:53
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
181 mg/L
5.0
1
01/10/16 14:12
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 14:12
Alkalinity, Total as CaCO3
181 mg/L
5.0
1
01/10/16 14:12
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/08/1615:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/08/16 17:54
18540-29-9
Date: 01 /12/2016 10:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 16 of 34

aceAnaiXical
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Pace Analytical Services, Inc.
098m.8yee. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010086
Pace Project No.: 92282172
Sample: 2016000434
Lab ID: 92282172006 Collected:
01/06/16 13:38
Received: 01/07/16 14:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
59.7 ug/L
10.0
1
01/08/1614:10
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
218 mg/L
5.0
1
01/10/16 14:26
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 14:26
Alkalinity, Total as CaCO3
218 mg/L
5.0
1
01/10/16 14:26
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/08/1615:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/08/16 18:07
18540-29-9
Date: 01 /12/2016 10:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 17 of 34

aceAnaiXical
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Pace Analytical Services, Inc.
098m.8yee. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010086
Pace Project No.: 92282172
Sample: 2016000435
Lab ID: 92282172007 Collected:
01/06/16 11:45
Received: 01/07/16 14:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/08/1614:18
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
93.2 mg/L
5.0
1
01/10/16 15:00
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 15:00
Alkalinity, Total as CaCO3
93.2 mg/L
5.0
1
01/10/16 15:00
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/08/1615:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.16 ug/L
0.030
1
01/08/16 18:20
18540-29-9
Date: 01 /12/2016 10:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 18 of 34

aceAnaiXical
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Pace Analytical Services, Inc.
098onroe. Suite100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010086
Pace Project No.: 92282172
Sample: 2016000436
Lab ID: 92282172008 Collected:
01/05/16 11:10
Received: 01/07/16 14:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
7850 ug/L
10.0
1
01/08/1614:26
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
181 mg/L
5.0
1
01/10/16 15:13
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 15:13
Alkalinity, Total as CaCO3
181 mg/L
5.0
1
01/10/16 15:13
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/08/1615:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/08/16 18:33
18540-29-9
Date: 01 /12/2016 10:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 19 of 34

aceAnaiXical
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Pace Analytical Services, Inc.
098oy roe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010086
Pace Project No.: 92282172
Sample: 2016000437
Lab ID: 92282172009 Collected:
01/05/16 10:35
Received: 01/07/16 14:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
108 ug/L
10.0
1
01/08/1614:34
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
40.4 mg/L
5.0
1
01/10/16 15:28
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 15:28
Alkalinity, Total as CaCO3
40.4 mg/L
5.0
1
01/10/16 15:28
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/08/1615:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/08/16 18:46
18540-29-9
Date: 01 /12/2016 10:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 20 of 34

aceAnaiXical
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Pace Analytical Services, Inc.
098onroe. Suite100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010086
Pace Project No.: 92282172
Sample: 2016000439
Lab ID: 92282172010 Collected:
01/06/16 16:45
Received: 01/07/16 14:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/08/1614:43
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 15:40
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 15:40
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
01/10/16 15:40
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/08/1615:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/08/16 18:59
18540-29-9
Date: 01 /12/2016 10:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 21 of 34

aceAnaiXical
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Pace Analytical Services, Inc.
098nnroe. Suite100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010086
Pace Project No.: 92282172
Sample: 2016000440
Lab ID: 92282172011 Collected:
01/06/16 16:40
Received: 01/07/16 14:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
90.8 ug/L
10.0
1
01/08/1614:51
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 17:00
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 17:00
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
01/10/16 17:00
M1
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/08/1615:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/08/16 19:38
18540-29-9
Date: 01 /12/2016 10:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 22 of 34

aceAnaiXical
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Pace Analytical Services, Inc.
098mc&roe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010086
Pace Project No.: 92282172
Sample: 2016000441
Lab ID: 92282172012 Collected:
01/06/16 15:35
Received: 01/07/16 14:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/08/1614:59
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 17:39
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 17:39
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
01/10/16 17:39
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/08/1615:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.087 ug/L
0.030
1
01/08/16 20:17
18540-29-9
Date: 01 /12/2016 10:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 23 of 34

aceAnaiXical
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Pace Analytical Services, Inc.
098nnroe. Suite100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010086
Pace Project No.: 92282172
Sample: 2016000442
Lab ID: 92282172013 Collected:
01/06/16 15:00
Received: 01/07/16 14:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/08/1615:07
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
25.4 mg/L
5.0
1
01/10/16 17:48
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/10/16 17:48
Alkalinity, Total as CaCO3
25.4 mg/L
5.0
1
01/10/16 17:48
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/08/1615:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.089 ug/L
0.030
1
01/08/16 20:30
18540-29-9
Date: 01 /12/2016 10:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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Page 24 of 34

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Pace Analytical Services, Inc.
098onroe. Suite100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010086
Pace Project No.: 92282172
QC Batch: AIR/24990
Analysis Method: RSK 175
QC Batch Method: RSK 175
Analysis Description: RSK 175 AIR HEADSPACE
Associated Lab Samples: 92282172001, 92282172002,
92282172003, 92282172004, 92282172005, 92282172006, 92282172007,
92282172008,92282172009,92282172010,92282172011,92282172012,92282172013
METHOD BLANK: 2172145
Matrix: Water
Associated Lab Samples: 92282172001, 92282172002,
92282172003, 92282172004, 92282172005, 92282172006, 92282172007,
92282172008,92282172009,92282172010,92282172011,92282172012,92282172013
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers
Methane
ug/L
ND 10.0 01/08/16 09:20
LABORATORY CONTROL SAMPLE & LCSD:
2172146
2172147
Spike LCS LCSD LCS LCSD % Rec Max
Parameter
Units
Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Methane
ug/L
60.7 57.7 59.9 95 99 85-115 4 20
SAMPLE DUPLICATE: 2172518
92281984013 Dup Max
Parameter
Units
Result Result RPD RPD Qualifiers
Methane
ug/L
ND 1.2J 20
SAMPLE DUPLICATE: 2172519
92282172005 Dup Max
Parameter
Units
Result Result RPD RPD Qualifiers
Methane
ug/L
ND 1.6J 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/12/2016 10:37 AM without the written consent of Pace Analytical Services, Inc..
Page 25 of 34

aceAnaiXical
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Pace Analytical Services, Inc.
098g"c& roe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010086
Pace Project No.: 92282172
QC Batch: WET/42371 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92282172001, 92282172002, 92282172003, 92282172004, 92282172005, 92282172006, 92282172007,
92282172008,92282172009,92282172010,92282172011,92282172012,92282172013
METHOD BLANK: 1643729 Matrix: Water
Associated Lab Samples: 92282172001, 92282172002, 92282172003, 92282172004, 92282172005, 92282172006, 92282172007,
92282172008,92282172009,92282172010,92282172011,92282172012,92282172013
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Alkalinity, Carbonate (CaCO3) mg/L ND 5.0 01/10/16 12:34
Alkalinity, Total as CaCO3 mg/L ND 5.0 01/10/16 12:34
Alkalinity, Bicarbonate (CaCO3) mg/L ND 5.0 01/10/16 12:34
LABORATORY CONTROL SAMPLE: 1643730
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 47.3 95 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1643731 1643732
MS MSD
92282172001 Spike Spike MS MSD MS MSD % Rec
Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits
RPD RPD Qua]
Alkalinity, Total as CaCO3 mg/L 71.0 50 50 118 116 93 89 80-120
2 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1643733 1643734
MS MSD
92282172011 Spike Spike MS MSD MS MSD % Rec
Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits
RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L ND 50 50 314 316 628 633 80-120
1 25 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/12/2016 10:37 AM without the written consent of Pace Analytical Services, Inc..
Page 26 of 34

aceAnaiXical
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Pace Analytical Services, Inc.
098onroe. Suite100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010086
Pace Project No.: 92282172
QC Batch: WET/42367 Analysis Method: SM 4500-S2D
QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92282172001, 92282172002, 92282172003, 92282172004, 92282172005, 92282172006, 92282172007,
92282172008,92282172009,92282172010,92282172011,92282172012,92282172013
METHOD BLANK: 1643316 Matrix: Water
Associated Lab Samples: 92282172001, 92282172002, 92282172003, 92282172004, 92282172005, 92282172006, 92282172007,
92282172008,92282172009,92282172010,92282172011,92282172012,92282172013
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 01/08/1615:00
LABORATORY CONTROL SAMPLE: 1643317
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.49 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1643318 1643319
MS MSD
92282172001 Spike Spike MS MSD MS MSD % Rec
Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits
RPD RPD Qua]
Sulfide mg/L ND .5 .5 0.22 0.22 44 44 90-110
0 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1643320 1643321
MS MSD
92282172011 Spike Spike MS MSD MS MSD % Rec
Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits
RPD RPD Qua]
Sulfide mg/L ND .5 .5 0.48 0.48 96 96 90-110
0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/12/2016 10:37 AM without the written consent of Pace Analytical Services, Inc..
Page 27 of 34

aceAnaiXical
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Pace Analytical Services, Inc.
098onroe. Suite100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010086
Pace Project No.: 92282172
QC Batch: WETA/53609
Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7
Analysis Description: Chromium, Hexavalent IC
Associated Lab Samples: 92282172001, 92282172002,
92282172003, 92282172004, 92282172005, 92282172006, 92282172007,
92282172008,92282172009,92282172010,92282172011,92282172012,92282172013
METHOD BLANK: 1441880
Matrix: Water
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Chromium, Hexavalent ug/L
ND 0.030 01/08/16 16:10
LABORATORY CONTROL SAMPLE: 1441881
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Chromium, Hexavalent ug/L
.075 0.077 103 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1441882 1441883
MS MSD
92282172001
Spike Spike MS MSD MS MSD
% Rec
Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits
RPD RPD Qual
Chromium, Hexavalent ug/L 0.17
.025 .025 0.20 0.19 117 80
85-115
5 20 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1441884 1441885
MS MSD
92282172011
Spike Spike MS MSD MS MSD
% Rec
Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits
RPD RPD Qual
Chromium, Hexavalent ug/L ND
.075 .075 0.076 0.074 101 99
85-115
3 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 01/12/2016 10:37 AM without the written consent of Pace Analytical Services, Inc..
Page 28 of 34

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Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J16010086
Pace Project No.: 92282172
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-M Pace Analytical Services - Minneapolis
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/12/2016 10:37 AM without the written consent of Pace Analytical Services, Inc.. Page 29 of 34

acmnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
og6gI inlc&f&e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16010086
Pace Project No.: 92282172
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92282172001
2016000429
RSK 175
AIR/24990
92282172002
2016000430
RSK 175
AIR/24990
92282172003
2016000431
RSK 175
AIR/24990
92282172004
2016000432
RSK 175
AIR/24990
92282172005
2016000433
RSK 175
AIR/24990
92282172006
2016000434
RSK 175
AIR/24990
92282172007
2016000435
RSK 175
AIR/24990
92282172008
2016000436
RSK 175
AIR/24990
92282172009
2016000437
RSK 175
AIR/24990
92282172010
2016000439
RSK 175
AIR/24990
92282172011
2016000440
RSK 175
AIR/24990
92282172012
2016000441
RSK 175
AIR/24990
92282172013
2016000442
RSK 175
AIR/24990
92282172001
2016000429
SM 2320B
WET/42371
92282172002
2016000430
SM 2320B
WET/42371
92282172003
2016000431
SM 2320B
WET/42371
92282172004
2016000432
SM 2320B
WET/42371
92282172005
2016000433
SM 2320B
WET/42371
92282172006
2016000434
SM 2320B
WET/42371
92282172007
2016000435
SM 2320B
WET/42371
92282172008
2016000436
SM 2320B
WET/42371
92282172009
2016000437
SM 2320B
WET/42371
92282172010
2016000439
SM 2320B
WET/42371
92282172011
2016000440
SM 2320B
WET/42371
92282172012
2016000441
SM 2320B
WET/42371
92282172013
2016000442
SM 2320B
WET/42371
92282172001
2016000429
SM 4500-S2D
WET/42367
92282172002
2016000430
SM 4500-S2D
WET/42367
92282172003
2016000431
SM 4500-S2D
WET/42367
92282172004
2016000432
SM 4500-S2D
WET/42367
92282172005
2016000433
SM 4500-S2D
WET/42367
92282172006
2016000434
SM 4500-S2D
WET/42367
92282172007
2016000435
SM 4500-S2D
WET/42367
92282172008
2016000436
SM 4500-S2D
WET/42367
92282172009
2016000437
SM 4500-S2D
WET/42367
92282172010
2016000439
SM 4500-S2D
WET/42367
92282172011
2016000440
SM 4500-S2D
WET/42367
92282172012
2016000441
SM 4500-S2D
WET/42367
92282172013
2016000442
SM 4500-S2D
WET/42367
92282172001
2016000429
EPA 218.7
WETA/53609
92282172002
2016000430
EPA 218.7
WETA/53609
92282172003
2016000431
EPA 218.7
WETA/53609
92282172004
2016000432
EPA 218.7
WETA/53609
92282172005
2016000433
EPA 218.7
WETA/53609
92282172006
2016000434
EPA 218.7
WETA/53609
92282172007
2016000435
EPA 218.7
WETA/53609
92282172008
2016000436
EPA 218.7
WETA/53609
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /12/2016 10:37 AM without the written consent of Pace Analytical Services, Inc.. Page 30 of 34

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098on roe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16010086
Pace Project No.: 92282172
Lab ID Sample ID QC Batch Method QC Batch
92282172009
2016000437
EPA 218.7
WETA/53609
92282172010
2016000439
EPA 218.7
WETA/53609
92282172011
2016000440
EPA 218.7
WETA/53609
92282172012
2016000441
EPA 218.7
WETA/53609
92282172013
2016000442
EPA 218.7
WETA/53609
Date: 01 /12/2016 10:37 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 31 of 34

Document Name:
Document Revised: 26OCT2015
a
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
F-CHR-CS-003-rev.17
Issuing Authority-
Pace Huntersville Quality Office
aWnalXical
° ++ • Client Name. Project #:
ELM gum, - W. W4,
Courier: ❑Fe x ❑UPS ❑USPS ❑Client
❑Commercial El ace ❑Other:
Custody Seal on Cooler/Box Present? Des dNN0
Packing Material: ❑Bubble Wrap /❑Bubble Bags
:9i:282172
WO#
IIIIII,IIIIIIII IUNIII
Seals Intact? ❑Yes ❑No
[—]None ❑Other:,
Thermometer BT1505 Type of Ice: []Wet ❑Blue []None Samples on ice, cooling process has begun
Used:
Cooler Temp Corrected (°C): ?) Biological Tissue Frozen? ❑Yes „ ©No • []N/A' 1
Temp should be above freezing to VC Correction Factor: 0.0 °C Date and Initials of Person Examining Contents: —
USDA Regulated Soil ( 0 N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source {internationally,
Dyes [JN6' including Hawaii and Puerto Rico)? ❑Yes -4allo
If Yes to either question, fill out a Regulated Soil Checklist and include with SCUR/COC paperwork.
COMMENTS:
Chain of Custody Present?
/by-,s
❑No
El N/A
1.
Chain of Custody Filled Out?
.©Yes
❑No
❑N/A
2.
Chain of Custody Relinquished?
JJYss
❑No
❑N/A
3.
Sampler Name and/or Signature on COC?
®Yes
❑No
❑N/A
4.
Samples Arrived within Hold Time?
©Yes
[—]No
El N/A
5.
Short Hold Time Analysis (<72 hr)?
Dyes
ZNo
❑NJA
6.
Rush Turn Around Time Requested?
Dyes
06ro
❑N/A
7.
Sufficient Volume?
❑Ygs
❑No
❑N/A
8.
Correct Containers Used?
Yes
[:]No
❑N/A
9.
-Pace Containers Used? 1.
%
t
El go'
❑N/A
Containers Intact?
'❑Yes
❑No
[QN/A
10.
Filtered Volume Received for Dissolved Tests?
[]Yes
❑No
[]N/A
11. Note if sediment is visible in the dissolved container
Sample Labels Match COC? 1
_[]Yes
[:]No
❑N/A
12.
-Includes Date/Time/ID/Analysis Matrix:
All containers needing acid/base preservation have been'
13
checked?
Dyes
❑No
❑N/A
All containers needing preservation are found to be in
compliance with EPA recommendation?
(HNO3i H2SO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide)
ayes
[:]No
❑NIA
Exceptions: VOA, Coliform, TOC, Oil and Grease,
DRO/8015 (water) DOC,LLHg
❑Yes
❑No
N/A
Samples checked for dechlorization
Dyes
❑ o-:-'
❑N/A
14.
Headspace in VOA Vials (>5.6mm)?
❑Yes
❑No
QN/A
15,
Trip Blank Present?
Dyes
[:]No
❑N/A'
16.
Trip Blank Custody Seals Present?
❑Yes
[:]No
EIN/A
Pace Trip Blank Lot # (if purchased):
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Resolution:
Field Data Required? ❑Yes ❑No
Date/Time:
Project Manager SCURF Review:
affecting Date:
Note: Whenever there is a discrepancy g North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le, Out of
hold, incorrect preservative, out of temp, incorrect containers).
Page 32 of 34

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CHAIN OF CUSTODY RF1CORD AND ANALYSIS REQUEST FORM
---- ---------- --------------- ---------------------- - ----------------------------------------------------
TA051 Page I
KWI UM M003A2 Mwidwe .,,.W-..�--.-Page 66 J67
Analo"I LabDratory 1b3,M HKWJ F—V Rd RC
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ELEMENTS by JCP (TRM I: Al. Ba. 6. Fe_ Mn, Sr- Zn 1CP�_"nc1lW%tvd Ca, Mg, K. Nib Hq by 245.1
Disawyed metals : all mptalip ICP. IM,;,Hg
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---------------- — CHAIN OF CUSTODY Rr7CCIRC AX0 ANALYSIS RFOUES1 FORM
T, -r>um- Anm'NrUc,4-r,Labm . at"
Duke Lcaargy
------ - -------------------
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f)ft!i.OpVod all f"C"rS JCP' PR4"g
Page 67 of 67
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DUKE Analytical Laboratory Page 1of68
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J16010101
MAYO STEAM - AB GW ASSESSMENT WATER
Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy Webb, John Toep
Anne Pifer
Phone:
Date:
ell
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
1/15/2016
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Page 2 of 68
Sample ID Plant/Station
Collection
Date and Time Collected By
Sample Description
2016000520
MAYO STEAM
07-Jan-16 3:12 PM
Unknown
ABMW-1
2016000523
MAYO STEAM
07-Jan-16 12:50 PM
Unknown
MW-3BR
2016000524
MAYO STEAM
07-Jan-16 8:52 AM
Unknown
MW-513R
2016000525
MAYO STEAM
07-Jan-16 1:25 PM
Unknown
MW-10BR
2016000526
MAYO STEAM
07-Jan-16 3:20 PM
Unknown
MW-11BR
2016000527
MAYO STEAM
07-Jan-16 12:35 PM
Unknown
MW-12S
2016000528
MAYO STEAM
07-Jan-16 3:51 PM
Unknown
MW-12D
2016000529
MAYO STEAM
07-Jan-16 11:35 AM
Unknown
MW-13BR
2016000530
MAYO STEAM
07-Jan-16 10:35 AM
Unknown
MW-14BR
2016000531
MAYO STEAM
07-Jan-16 9:55 AM
Unknown
MW-16D
2016000532
MAYO STEAM
07-Jan-16 9:20 AM
Unknown
MW-16S
2016000533
MAYO STEAM
07-Jan-16 9:09 AM
Unknown
MW-16BR
2016000534
MAYO STEAM
07-Jan-16 9:55 AM
Unknown
MW-16D Dup
2016000535
MAYO STEAM
Filter Blank
2016000536
MAYO STEAM
Equipment Blank
15 Total Samples

Page 3 of 68
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 1/15/2016

Certificate of Laboratory Analysis Page 4 of 68
This report shall not be reproduced, except in full.
Order # J16010101
Site: ABMW-1
Collection Date: 07-Jan-16 3:12 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
15
mg/L
1
Sulfate
24
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.275
mg/L
0.005
Barium (Ba)
0.462
mg/L
0.005
Boron (B)
6.18
mg/L
0.05
Iron (Fe)
0.157
mg/L
0.01
Manganese (Mn)
0.750
mg/L
0.005
Strontium (Sr)
1.72
mg/L
0.005
Zinc (Zn)
0.008
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
54.4
mg/L
0.1
Magnesium (Mg)
32.3
mg/L
0.05
Potassium (K)
22.8
mg/L
1
Sodium (Na)
17.8
mg/L
0.5
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.372
mg/L
0.005
Barium (Ba)
0.502
mg/L
0.005
Boron (B)
5.84
mg/L
0.05
Iron (Fe)
0.724
mg/L
0.01
Manganese (Mn)
0.815
mg/L
0.005
Strontium (Sr)
1.79
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000520
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 11:07 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
01/08/2016 22:45
BGN9034
10
EPA 300.0
01/08/2016 22:45
BGN9034
1
EPA 245.1
01/08/2016 15:40
ACPAYNE
1
EPA 245.1
01/09/2016 12:51
ACPAYNE
1
EPA 200.7
01/08/2016 13:53
FCJORDA
1
EPA 200.7
01/08/2016 13:53
FCJORDA
1
EPA 200.7
01/08/2016 13:53
FCJORDA
1
EPA 200.7
01/08/2016 13:53
FCJORDA
1
EPA 200.7
01/08/2016 13:53
FCJORDA
1
EPA 200.7
01/08/2016 13:53
FCJORDA
1
EPA 200.7
01/08/2016 13:53
FCJORDA
10
EPA 200.7
01/11/2016 13:15
FCJORDA
10
EPA 200.7
01/11/2016 13:15
FCJORDA
10
EPA 200.7
01/11/2016 13:15
FCJORDA
10
EPA 200.7
01/11/2016 13:15
FCJORDA
1
EPA 200.7
01/10/2016 17:13
FCJORDA
1
EPA 200.7
01/10/2016 17:13
FCJORDA
1
EPA 200.7
01/10/2016 17:13
FCJORDA
1
EPA 200.7
01/10/2016 17:13
FCJORDA
1
EPA 200.7
01/10/2016 17:13
FCJORDA
1
EPA 200.7
01/10/2016 17:13
FCJORDA
1
EPA 200.7
01/10/2016 17:13
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: ABMW-1
Collection Date: 07-Jan-16 3:12 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
19.5
ug/L
1
Arsenic (As)
408
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.57
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
290
ug/L
1
Nickel (Ni)
1.22
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
0.387
ug/L
0.2
Vanadium (V) Low Level
79.1
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
18.8
ug/L
1
Arsenic (As)
498
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
2.06
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
286
ug/L
1
Nickel (Ni)
1.36
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
0.670
ug/L
0.2
Vanadium (V) Low Level
98.7
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
340
mg/L
25
Total Carbon
TOC
4.0
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 5 of 68
Sample #:
2016000520
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 16:09
SLS2560
1
EPA 200.8
01/10/2016 16:09
SLS2560
1
EPA 200.8
01/10/2016 16:09
SLS2560
1
EPA 200.8
01/10/2016 16:09
SLS2560
1
EPA 200.8
01/10/2016 16:09
SLS2560
1
EPA 200.8
01/10/2016 16:09
SLS2560
1
EPA 200.8
01/10/2016 16:09
SLS2560
1
EPA 200.8
01/10/2016 16:09
SLS2560
1
EPA 200.8
01/10/2016 16:09
SLS2560
1
EPA 200.8
01/10/2016 16:09
SLS2560
1
EPA 200.8
01/10/2016 16:09
SLS2560
1
EPA 200.8
01/10/2016 16:09
SLS2560
1
EPA 200.8
01/10/2016 16:09
SLS2560
1 EPA 200.8
01/10/2016 20:19
SLS2560
1 EPA 200.8
01/10/2016 20:19
SLS2560
1 EPA 200.8
01/10/2016 20:19
SLS2560
1 EPA 200.8
01/10/2016 20:19
SLS2560
1 EPA 200.8
01/10/2016 20:19
SLS2560
1 EPA 200.8
01/10/2016 20:19
SLS2560
1 EPA 200.8
01/10/2016 20:19
SLS2560
1 EPA 200.8
01/10/2016 20:19
SLS2560
1 EPA 200.8
01/10/2016 20:19
SLS2560
1 EPA 200.8
01/10/2016 20:19
SLS2560
1 EPA 200.8
01/10/2016 20:19
SLS2560
1 EPA 200.8
01/10/2016 20:19
SLS2560
1 EPA 200.8
01/10/2016 20:19
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/10/201614:09 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/10/2016 08:30 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-3BR
Collection Date: 07-Jan-16 12:50 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.012 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
160
mg/L
2
Sulfate
9.9
mg/L
0.5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.043
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.377
mg/L
0.01
Manganese (Mn)
0.628
mg/L
0.005
Strontium (Sr)
0.404
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
141
mg/L
0.1
Magnesium (Mg)
11.7
mg/L
0.05
Potassium (K)
7.58
mg/L
1
Sodium (Na)
21.9
mg/L
0.5
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.168
mg/L
0.005
Barium (Ba)
0.042
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.401
mg/L
0.01
Manganese (Mn)
0.635
mg/L
0.005
Strontium (Sr)
0.394
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000523
Matrix: GW WW
Page 6 of 68
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 11:10 LSTARL1
Vendor Method V_PACE
20
EPA 300.0
01/09/2016 02:38
BGN9034
5
EPA 300.0
01/09/2016 02:38
BGN9034
1
EPA 245.1
01/08/2016 15:42
ACPAYNE
1
EPA 245.1
01/09/2016 12:54
ACPAYNE
1
EPA 200.7
01/08/2016 13:57
FCJORDA
1
EPA 200.7
01/08/2016 13:57
FCJORDA
1
EPA 200.7
01/08/2016 13:57
FCJORDA
1
EPA 200.7
01/08/2016 13:57
FCJORDA
1
EPA 200.7
01/08/2016 13:57
FCJORDA
1
EPA 200.7
01/08/2016 13:57
FCJORDA
1
EPA 200.7
01/08/2016 13:57
FCJORDA
10
EPA 200.7
01/11/2016 13:19
FCJORDA
10
EPA 200.7
01/11/2016 13:19
FCJORDA
10
EPA 200.7
01/11/2016 13:19
FCJORDA
10
EPA 200.7
01/11/2016 13:19
FCJORDA
1
EPA 200.7
01/10/2016 17:24
FCJORDA
1
EPA 200.7
01/10/2016 17:24
FCJORDA
1
EPA 200.7
01/10/2016 17:24
FCJORDA
1
EPA 200.7
01/10/2016 17:24
FCJORDA
1
EPA 200.7
01/10/2016 17:24
FCJORDA
1
EPA 200.7
01/10/2016 17:24
FCJORDA
1
EPA 200.7
01/10/2016 17:24
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-3BR
Collection Date: 07-Jan-16 12:50 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.14
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
550
mg/L
25
Total Carbon
TOC
1.7
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 7 of 68
Sample #:
2016000523
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 16:29
SLS2560
1
EPA 200.8
01/10/2016 16:29
SLS2560
1
EPA 200.8
01/10/2016 16:29
SLS2560
1
EPA 200.8
01/10/2016 16:29
SLS2560
1
EPA 200.8
01/10/2016 16:29
SLS2560
1
EPA 200.8
01/10/2016 16:29
SLS2560
1
EPA 200.8
01/10/2016 16:29
SLS2560
1
EPA 200.8
01/10/2016 16:29
SLS2560
1
EPA 200.8
01/10/2016 16:29
SLS2560
1
EPA 200.8
01/10/2016 16:29
SLS2560
1
EPA 200.8
01/10/2016 16:29
SLS2560
1
EPA 200.8
01/10/2016 16:29
SLS2560
1
EPA 200.8
01/10/2016 16:29
SLS2560
1 EPA 200.8
01/10/2016 19:59
SLS2560
1 EPA 200.8
01/10/2016 19:59
SLS2560
1 EPA 200.8
01/10/2016 19:59
SLS2560
1 EPA 200.8
01/10/2016 19:59
SLS2560
1 EPA 200.8
01/10/2016 19:59
SLS2560
1 EPA 200.8
01/10/2016 19:59
SLS2560
1 EPA 200.8
01/10/2016 19:59
SLS2560
1 EPA 200.8
01/10/2016 19:59
SLS2560
1 EPA 200.8
01/10/2016 19:59
SLS2560
1 EPA 200.8
01/10/2016 19:59
SLS2560
1 EPA 200.8
01/10/2016 19:59
SLS2560
1 EPA 200.8
01/10/2016 19:59
SLS2560
1 EPA 200.8
01/10/2016 19:59
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/10/201614:09 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/10/2016 08:30 CJELLIO

Certificate of Laboratory Analysis Page 8 of 68
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-5BR
Collection Date: 07-Jan-16 8:52 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.154 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
66
mg/L
1
Sulfate
0.57
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.015
mg/L
0.005
Barium (Ba)
0.038
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
8.39
mg/L
0.01
Manganese (Mn)
1.76
mg/L
0.005
Strontium (Sr)
0.208
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
89.8
mg/L
0.01
Magnesium (Mg)
6.84
mg/L
0.005
Potassium (K)
6.00
mg/L
0.1
Sodium (Na)
17.9
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.130
mg/L
0.005
Barium (Ba)
0.039
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
9.69
mg/L
0.01
Manganese (Mn)
1.88
mg/L
0.005
Strontium (Sr)
0.205
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000524
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 11:12 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
01/09/2016 02:56
BGN9034
1
EPA 300.0
01/09/2016 02:56
BGN9034
1
EPA 245.1
01/08/2016 15:45
ACPAYNE
1
EPA 245.1
01/09/2016 12:56
ACPAYNE
1
EPA 200.7
01/08/2016 14:01
FCJORDA
1
EPA 200.7
01/08/2016 14:01
FCJORDA
1
EPA 200.7
01/08/2016 14:01
FCJORDA
1
EPA 200.7
01/08/2016 14:01
FCJORDA
1
EPA 200.7
01/08/2016 14:01
FCJORDA
1
EPA 200.7
01/08/2016 14:01
FCJORDA
1
EPA 200.7
01/08/2016 14:01
FCJORDA
1
EPA 200.7
01/11/2016 12:22
FCJORDA
1
EPA 200.7
01/11/2016 12:22
FCJORDA
1
EPA 200.7
01/11/2016 12:22
FCJORDA
1
EPA 200.7
01/11/2016 12:22
FCJORDA
1
EPA 200.7
01/10/2016 17:28
FCJORDA
1
EPA 200.7
01/10/2016 17:28
FCJORDA
1
EPA 200.7
01/10/2016 17:28
FCJORDA
1
EPA 200.7
01/10/2016 17:28
FCJORDA
1
EPA 200.7
01/10/2016 17:28
FCJORDA
1
EPA 200.7
01/10/2016 17:28
FCJORDA
1
EPA 200.7
01/10/2016 17:28
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-5BR
Collection Date: 07-Jan-16 8:52 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.88
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.61
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
360
mg/L
25
Total Carbon
TOC
2.4
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
26
mg/L
5
Page 9 of 68
Sample #:
2016000524
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 16:34
SLS2560
1
EPA 200.8
01/10/2016 16:34
SLS2560
1
EPA 200.8
01/10/2016 16:34
SLS2560
1
EPA 200.8
01/10/2016 16:34
SLS2560
1
EPA 200.8
01/10/2016 16:34
SLS2560
1
EPA 200.8
01/10/2016 16:34
SLS2560
1
EPA 200.8
01/10/2016 16:34
SLS2560
1
EPA 200.8
01/10/2016 16:34
SLS2560
1
EPA 200.8
01/10/2016 16:34
SLS2560
1
EPA 200.8
01/10/2016 16:34
SLS2560
1
EPA 200.8
01/10/2016 16:34
SLS2560
1
EPA 200.8
01/10/2016 16:34
SLS2560
1
EPA 200.8
01/10/2016 16:34
SLS2560
1 EPA 200.8
01/10/2016 20:24
SLS2560
1 EPA 200.8
01/10/2016 20:24
SLS2560
1 EPA 200.8
01/10/2016 20:24
SLS2560
1 EPA 200.8
01/10/2016 20:24
SLS2560
1 EPA 200.8
01/10/2016 20:24
SLS2560
1 EPA 200.8
01/10/2016 20:24
SLS2560
1 EPA 200.8
01/10/2016 20:24
SLS2560
1 EPA 200.8
01/10/2016 20:24
SLS2560
1 EPA 200.8
01/10/2016 20:24
SLS2560
1 EPA 200.8
01/10/2016 20:24
SLS2560
1 EPA 200.8
01/10/2016 20:24
SLS2560
1 EPA 200.8
01/10/2016 20:24
SLS2560
1 EPA 200.8
01/10/2016 20:24
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/10/201614:09 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/10/2016 08:30 CJELLIO

Certificate of Laboratory Analysis Page 10 of 68
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-10BR
Collection Date: 07-Jan-16 1:25 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.017 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
21
mg/L
1
Sulfate
90
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
M2 0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
M2 0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.006
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.090
mg/L
0.005
Strontium (Sr)
0.201
mg/L
0.005
Zinc (Zn)
0.009
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
28.8
mg/L
0.01
Magnesium (Mg)
13.1
mg/L
0.005
Potassium (K)
4.15
mg/L
0.1
Sodium (Na)
39.5
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.062
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.033
mg/L
0.01
Manganese (Mn)
0.103
mg/L
0.005
Strontium (Sr)
0.195
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000525
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 11:13 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
01/09/2016 00:15
BGN9034
10
EPA 300.0
01/09/2016 00:15
BGN9034
1
EPA 245.1
01/08/2016 15:56
ACPAYNE
1
EPA 245.1
01/09/2016 13:08
ACPAYNE
1
EPA 200.7
01/08/2016 14:05
FCJORDA
1
EPA 200.7
01/08/2016 14:05
FCJORDA
1
EPA 200.7
01/08/2016 14:05
FCJORDA
1
EPA 200.7
01/08/2016 14:05
FCJORDA
1
EPA 200.7
01/08/2016 14:05
FCJORDA
1
EPA 200.7
01/08/2016 14:05
FCJORDA
1
EPA 200.7
01/08/2016 14:05
FCJORDA
1
EPA 200.7
01/11/2016 12:26
FCJORDA
1
EPA 200.7
01/11/2016 12:26
FCJORDA
1
EPA 200.7
01/11/2016 12:26
FCJORDA
1
EPA 200.7
01/11/2016 12:26
FCJORDA
1
EPA 200.7
01/10/2016 17:32
FCJORDA
1
EPA 200.7
01/10/2016 17:32
FCJORDA
1
EPA 200.7
01/10/2016 17:32
FCJORDA
1
EPA 200.7
01/10/2016 17:32
FCJORDA
1
EPA 200.7
01/10/2016 17:32
FCJORDA
1
EPA 200.7
01/10/2016 17:32
FCJORDA
1
EPA 200.7
01/10/2016 17:32
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-10BR
Collection Date: 07-Jan-16 1:25 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.88
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.57
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.76
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.68
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
300
mg/L
25
Total Carbon
TOC
1.8
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 11 of 68
Sample #:
2016000525
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 16:39
SLS2560
1
EPA 200.8
01/10/2016 16:39
SLS2560
1
EPA 200.8
01/10/2016 16:39
SLS2560
1
EPA 200.8
01/10/2016 16:39
SLS2560
1
EPA 200.8
01/10/2016 16:39
SLS2560
1
EPA 200.8
01/10/2016 16:39
SLS2560
1
EPA 200.8
01/10/2016 16:39
SLS2560
1
EPA 200.8
01/10/2016 16:39
SLS2560
1
EPA 200.8
01/10/2016 16:39
SLS2560
1
EPA 200.8
01/10/2016 16:39
SLS2560
1
EPA 200.8
01/10/2016 16:39
SLS2560
1
EPA 200.8
01/10/2016 16:39
SLS2560
1
EPA 200.8
01/10/2016 16:39
SLS2560
1 EPA 200.8
01/10/2016 20:43
SLS2560
1 EPA 200.8
01/10/2016 20:43
SLS2560
1 EPA 200.8
01/10/2016 20:43
SLS2560
1 EPA 200.8
01/10/2016 20:43
SLS2560
1 EPA 200.8
01/10/2016 20:43
SLS2560
1 EPA 200.8
01/10/2016 20:43
SLS2560
1 EPA 200.8
01/10/2016 20:43
SLS2560
1 EPA 200.8
01/10/2016 20:43
SLS2560
1 EPA 200.8
01/10/2016 20:43
SLS2560
1 EPA 200.8
01/10/2016 20:43
SLS2560
1 EPA 200.8
01/10/2016 20:43
SLS2560
1 EPA 200.8
01/10/2016 20:43
SLS2560
1 EPA 200.8
01/10/2016 20:43
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/10/201614:09 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/10/2016 08:30 CJELLIO

Certificate of Laboratory Analysis Page 12 of 68
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-11 BR
Collection Date: 07-Jan-16 3:20 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.272 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
16
mg/L
0.5
Sulfate
16
mg/L
0.5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.078
mg/L
0.005
Barium (Ba)
0.022
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
0.259
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
18.7
mg/L
0.01
Magnesium (Mg)
3.51
mg/L
0.005
Potassium (K)
7.93
mg/L
0.1
Sodium (Na)
16.6
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.170
mg/L
0.005
Barium (Ba)
0.024
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.098
mg/L
0.01
Manganese (Mn)
0.017
mg/L
0.005
Strontium (Sr)
0.253
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000526
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 11:15 LSTARL1
Vendor Method V_PACE
5 EPA 300.0
01/09/2016 00:33
BGN9034
5 EPA 300.0
01/09/2016 00:33
BGN9034
1 EPA 245.1
01/08/2016 16:03
ACPAYNE
1 EPA 245.1
01/09/2016 13:15
ACPAYNE
1 EPA 200.7
01/08/2016 14:09
FCJORDA
1 EPA 200.7
01/08/2016 14:09
FCJORDA
1 EPA 200.7
01/08/2016 14:09
FCJORDA
1 EPA 200.7
01/08/2016 14:09
FCJORDA
1 EPA 200.7
01/08/2016 14:09
FCJORDA
1 EPA 200.7
01/08/2016 14:09
FCJORDA
1 EPA 200.7
01/08/2016 14:09
FCJORDA
1 EPA 200.7
01/11/2016 12:30
FCJORDA
1 EPA 200.7
01/11/2016 12:30
FCJORDA
1 EPA 200.7
01/11/2016 12:30
FCJORDA
1 EPA 200.7
01/11/2016 12:30
FCJORDA
1 EPA 200.7
01/10/2016 17:36
FCJORDA
1 EPA 200.7
01/10/2016 17:36
FCJORDA
1 EPA 200.7
01/10/2016 17:36
FCJORDA
1 EPA 200.7
01/10/2016 17:36
FCJORDA
1 EPA 200.7
01/10/2016 17:36
FCJORDA
1 EPA 200.7
01/10/2016 17:36
FCJORDA
1 EPA 200.7
01/10/2016 17:36
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-11 BR
Collection Date: 07-Jan-16 3:20 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
1.58
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
14.7
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
8.14
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
7.65
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
12.0
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
1.90
ug/L
1
Arsenic (As)
1.02
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
15.1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
3.96
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
7.72
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
12.7
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
130
mg/L
25
Total Carbon
TOC
0.835
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 13 of 68
Sample #:
2016000526
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 16:44
SLS2560
1
EPA 200.8
01/10/2016 16:44
SLS2560
1
EPA 200.8
01/10/2016 16:44
SLS2560
1
EPA 200.8
01/10/2016 16:44
SLS2560
1
EPA 200.8
01/10/2016 16:44
SLS2560
1
EPA 200.8
01/10/2016 16:44
SLS2560
1
EPA 200.8
01/10/2016 16:44
SLS2560
1
EPA 200.8
01/10/2016 16:44
SLS2560
1
EPA 200.8
01/10/2016 16:44
SLS2560
1
EPA 200.8
01/10/2016 16:44
SLS2560
1
EPA 200.8
01/10/2016 16:44
SLS2560
1
EPA 200.8
01/10/2016 16:44
SLS2560
1
EPA 200.8
01/10/2016 16:44
SLS2560
1 EPA 200.8
01/10/2016 20:48
SLS2560
1 EPA 200.8
01/10/2016 20:48
SLS2560
1 EPA 200.8
01/10/2016 20:48
SLS2560
1 EPA 200.8
01/10/2016 20:48
SLS2560
1 EPA 200.8
01/10/2016 20:48
SLS2560
1 EPA 200.8
01/10/2016 20:48
SLS2560
1 EPA 200.8
01/10/2016 20:48
SLS2560
1 EPA 200.8
01/10/2016 20:48
SLS2560
1 EPA 200.8
01/10/2016 20:48
SLS2560
1 EPA 200.8
01/10/2016 20:48
SLS2560
1 EPA 200.8
01/10/2016 20:48
SLS2560
1 EPA 200.8
01/10/2016 20:48
SLS2560
1 EPA 200.8
01/10/2016 20:48
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/10/201614:09 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/10/2016 08:30 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-12S
Collection Date: 07-Jan-16 12:35 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.599 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
3.1
mg/L
0.1
Sulfate
1.4
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.025
mg/L
0.005
Barium (Ba)
0.010
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.028
mg/L
0.01
Manganese (Mn)
0.080
mg/L
0.005
Strontium (Sr)
0.018
mg/L
0.005
Zinc (Zn)
0.144
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
1.96
mg/L
0.01
Magnesium (Mg)
0.753
mg/L
0.005
Potassium (K)
1.58
mg/L
0.1
Sodium (Na)
4.76
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.220
mg/L
0.005
Barium (Ba)
0.011
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.178
mg/L
0.01
Manganese (Mn)
0.068
mg/L
0.005
Strontium (Sr)
0.018
mg/L
0.005
Zinc (Zn)
0.157
mg/L
0.005
Sample #: 2016000527
Matrix: GW WW
Page 14 of 68
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 11:16 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
01/09/2016 00:51
BGN9034
1 EPA 300.0
01/09/2016 00:51
BGN9034
1 EPA 245.1
01/08/2016 16:06
ACPAYNE
1 EPA 245.1
01/09/2016 13:24
ACPAYNE
1 EPA 200.7
01/08/2016 14:12
FCJORDA
1 EPA 200.7
01/08/2016 14:12
FCJORDA
1 EPA 200.7
01/08/2016 14:12
FCJORDA
1 EPA 200.7
01/08/2016 14:12
FCJORDA
1 EPA 200.7
01/08/2016 14:12
FCJORDA
1 EPA 200.7
01/08/2016 14:12
FCJORDA
1 EPA 200.7
01/08/2016 14:12
FCJORDA
1 EPA 200.7
01/11/2016 12:34
FCJORDA
1 EPA 200.7
01/11/2016 12:34
FCJORDA
1 EPA 200.7
01/11/2016 12:34
FCJORDA
1 EPA 200.7
01/11/2016 12:34
FCJORDA
1 EPA 200.7
01/10/2016 17:40
FCJORDA
1 EPA 200.7
01/10/2016 17:40
FCJORDA
1 EPA 200.7
01/10/2016 17:40
FCJORDA
1 EPA 200.7
01/10/2016 17:40
FCJORDA
1 EPA 200.7
01/10/2016 17:40
FCJORDA
1 EPA 200.7
01/10/2016 17:40
FCJORDA
1 EPA 200.7
01/10/2016 17:40
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-12S
Collection Date: 07-Jan-16 12:35 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.36
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
1.43
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.60
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
35
mg/L
25
Total Carbon
TOC
1.6
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 15 of 68
Sample #:
2016000527
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 16:49
SLS2560
1
EPA 200.8
01/10/2016 16:49
SLS2560
1
EPA 200.8
01/10/2016 16:49
SLS2560
1
EPA 200.8
01/10/2016 16:49
SLS2560
1
EPA 200.8
01/10/2016 16:49
SLS2560
1
EPA 200.8
01/10/2016 16:49
SLS2560
1
EPA 200.8
01/10/2016 16:49
SLS2560
1
EPA 200.8
01/10/2016 16:49
SLS2560
1
EPA 200.8
01/10/2016 16:49
SLS2560
1
EPA 200.8
01/10/2016 16:49
SLS2560
1
EPA 200.8
01/10/2016 16:49
SLS2560
1
EPA 200.8
01/10/2016 16:49
SLS2560
1
EPA 200.8
01/10/2016 16:49
SLS2560
1 EPA 200.8
01/10/2016 20:53
SLS2560
1 EPA 200.8
01/10/2016 20:53
SLS2560
1 EPA 200.8
01/10/2016 20:53
SLS2560
1 EPA 200.8
01/10/2016 20:53
SLS2560
1 EPA 200.8
01/10/2016 20:53
SLS2560
1 EPA 200.8
01/10/2016 20:53
SLS2560
1 EPA 200.8
01/10/2016 20:53
SLS2560
1 EPA 200.8
01/10/2016 20:53
SLS2560
1 EPA 200.8
01/10/2016 20:53
SLS2560
1 EPA 200.8
01/10/2016 20:53
SLS2560
1 EPA 200.8
01/10/2016 20:53
SLS2560
1 EPA 200.8
01/10/2016 20:53
SLS2560
1 EPA 200.8
01/10/2016 20:53
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/10/201614:09 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/10/2016 08:30 CJELLIO

Certificate of Laboratory Analysis Page 16 of 68
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-12D
Collection Date: 07-Jan-16 3:51 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.139 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
4.5
mg/L
0.1
Sulfate
1.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.015
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.112
mg/L
0.005
Strontium (Sr)
0.090
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
11.7
mg/L
0.01
Magnesium (Mg)
3.28
mg/L
0.005
Potassium (K)
1.39
mg/L
0.1
Sodium (Na)
8.76
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.678
mg/L
0.005
Barium (Ba)
0.022
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.968
mg/L
0.01
Manganese (Mn)
0.131
mg/L
0.005
Strontium (Sr)
0.087
mg/L
0.005
Zinc (Zn)
0.005
mg/L
0.005
Sample #: 2016000528
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 11:18 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
01/09/2016 01:09
BGN9034
1 EPA 300.0
01/09/2016 01:09
BGN9034
1 EPA 245.1
01/08/2016 16:13
ACPAYNE
1 EPA 245.1
01/09/2016 13:26
ACPAYNE
1 EPA 200.7
01/08/2016 14:16
FCJORDA
1 EPA 200.7
01/08/2016 14:16
FCJORDA
1 EPA 200.7
01/08/2016 14:16
FCJORDA
1 EPA 200.7
01/08/2016 14:16
FCJORDA
1 EPA 200.7
01/08/2016 14:16
FCJORDA
1 EPA 200.7
01/08/2016 14:16
FCJORDA
1 EPA 200.7
01/08/2016 14:16
FCJORDA
1 EPA 200.7
01/11/2016 12:37
FCJORDA
1 EPA 200.7
01/11/2016 12:37
FCJORDA
1 EPA 200.7
01/11/2016 12:37
FCJORDA
1 EPA 200.7
01/11/2016 12:37
FCJORDA
1 EPA 200.7
01/10/2016 17:44
FCJORDA
1 EPA 200.7
01/10/2016 17:44
FCJORDA
1 EPA 200.7
01/10/2016 17:44
FCJORDA
1 EPA 200.7
01/10/2016 17:44
FCJORDA
1 EPA 200.7
01/10/2016 17:44
FCJORDA
1 EPA 200.7
01/10/2016 17:44
FCJORDA
1 EPA 200.7
01/10/2016 17:44
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-12D
Collection Date: 07-Jan-16 3:51 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.18
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.386
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
2.99
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
1.54
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
2.23
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.65
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
82
mg/L
25
Total Carbon
TOC
0.184
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
47
mg/L
5
Page 17 of 68
Sample #:
2016000528
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 16:53
SLS2560
1
EPA 200.8
01/10/2016 16:53
SLS2560
1
EPA 200.8
01/10/2016 16:53
SLS2560
1
EPA 200.8
01/10/2016 16:53
SLS2560
1
EPA 200.8
01/10/2016 16:53
SLS2560
1
EPA 200.8
01/10/2016 16:53
SLS2560
1
EPA 200.8
01/10/2016 16:53
SLS2560
1
EPA 200.8
01/10/2016 16:53
SLS2560
1
EPA 200.8
01/10/2016 16:53
SLS2560
1
EPA 200.8
01/10/2016 16:53
SLS2560
1
EPA 200.8
01/10/2016 16:53
SLS2560
1
EPA 200.8
01/10/2016 16:53
SLS2560
1
EPA 200.8
01/10/2016 16:53
SLS2560
1 EPA 200.8
01/10/2016 20:58
SLS2560
1 EPA 200.8
01/10/2016 20:58
SLS2560
1 EPA 200.8
01/10/2016 20:58
SLS2560
1 EPA 200.8
01/10/2016 20:58
SLS2560
1 EPA 200.8
01/10/2016 20:58
SLS2560
1 EPA 200.8
01/10/2016 20:58
SLS2560
1 EPA 200.8
01/10/2016 20:58
SLS2560
1 EPA 200.8
01/10/2016 20:58
SLS2560
1 EPA 200.8
01/10/2016 20:58
SLS2560
1 EPA 200.8
01/10/2016 20:58
SLS2560
1 EPA 200.8
01/10/2016 20:58
SLS2560
1 EPA 200.8
01/10/2016 20:58
SLS2560
1 EPA 200.8
01/10/2016 20:58
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/10/201614:09 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/10/2016 08:30 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-13BR
Collection Date: 07-Jan-16 11:35 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
45
mg/L
1
Sulfate
15
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.007
mg/L
0.005
Barium (Ba)
0.044
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
2.47
mg/L
0.01
Manganese (Mn)
0.539
mg/L
0.005
Strontium (Sr)
0.402
mg/L
0.005
Zinc (Zn)
0.008
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
73.3
mg/L
0.01
Magnesium (Mg)
12.9
mg/L
0.005
Potassium (K)
5.12
mg/L
0.1
Sodium (Na)
23.7
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.230
mg/L
0.005
Barium (Ba)
0.042
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
2.55
mg/L
0.01
Manganese (Mn)
0.519
mg/L
0.005
Strontium (Sr)
0.389
mg/L
0.005
Zinc (Zn)
0.037
mg/L
0.005
Sample #: 2016000529
Matrix: GW WW
Page 18 of 68
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 11:19 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
01/09/2016 01:26
BGN9034
10
EPA 300.0
01/09/2016 01:26
BGN9034
1
EPA 245.1
01/08/2016 16:18
ACPAYNE
1
EPA 245.1
01/09/2016 13:29
ACPAYNE
1
EPA 200.7
01/08/2016 14:28
FCJORDA
1
EPA 200.7
01/08/2016 14:28
FCJORDA
1
EPA 200.7
01/08/2016 14:28
FCJORDA
1
EPA 200.7
01/08/2016 14:28
FCJORDA
1
EPA 200.7
01/08/2016 14:28
FCJORDA
1
EPA 200.7
01/08/2016 14:28
FCJORDA
1
EPA 200.7
01/08/2016 14:28
FCJORDA
1
EPA 200.7
01/11/2016 12:41
FCJORDA
1
EPA 200.7
01/11/2016 12:41
FCJORDA
1
EPA 200.7
01/11/2016 12:41
FCJORDA
1
EPA 200.7
01/11/2016 12:41
FCJORDA
1
EPA 200.7
01/10/2016 17:47
FCJORDA
1
EPA 200.7
01/10/2016 17:47
FCJORDA
1
EPA 200.7
01/10/2016 17:47
FCJORDA
1
EPA 200.7
01/10/2016 17:47
FCJORDA
1
EPA 200.7
01/10/2016 17:47
FCJORDA
1
EPA 200.7
01/10/2016 17:47
FCJORDA
1
EPA 200.7
01/10/2016 17:47
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-13BR
Collection Date: 07-Jan-16 11:35 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
5.55
ug/L
1
Nickel (Ni)
1.30
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
7.65
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
5.81
ug/L
1
Nickel (Ni)
4.98
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
330
mg/L
25
Total Carbon
TOC
0.647
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
9.0
mg/L
5
Page 19 of 68
Sample #:
2016000529
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 16:58
SLS2560
1
EPA 200.8
01/10/2016 16:58
SLS2560
1
EPA 200.8
01/10/2016 16:58
SLS2560
1
EPA 200.8
01/10/2016 16:58
SLS2560
1
EPA 200.8
01/10/2016 16:58
SLS2560
1
EPA 200.8
01/10/2016 16:58
SLS2560
1
EPA 200.8
01/10/2016 16:58
SLS2560
1
EPA 200.8
01/10/2016 16:58
SLS2560
1
EPA 200.8
01/10/2016 16:58
SLS2560
1
EPA 200.8
01/10/2016 16:58
SLS2560
1
EPA 200.8
01/10/2016 16:58
SLS2560
1
EPA 200.8
01/10/2016 16:58
SLS2560
1
EPA 200.8
01/10/2016 16:58
SLS2560
1 EPA 200.8
01/10/2016 21:03
SLS2560
1 EPA 200.8
01/10/2016 21:03
SLS2560
1 EPA 200.8
01/10/2016 21:03
SLS2560
1 EPA 200.8
01/10/2016 21:03
SLS2560
1 EPA 200.8
01/10/2016 21:03
SLS2560
1 EPA 200.8
01/10/2016 21:03
SLS2560
1 EPA 200.8
01/10/2016 21:03
SLS2560
1 EPA 200.8
01/10/2016 21:03
SLS2560
1 EPA 200.8
01/10/2016 21:03
SLS2560
1 EPA 200.8
01/10/2016 21:03
SLS2560
1 EPA 200.8
01/10/2016 21:03
SLS2560
1 EPA 200.8
01/10/2016 21:03
SLS2560
1 EPA 200.8
01/10/2016 21:03
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/10/201614:09 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/10/2016 08:30 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-14BR
Collection Date: 07-Jan-16 10:35 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.384 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
13
mg/L
0.2
Sulfate
10
mg/L
0.2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.017
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.011
mg/L
0.01
Manganese (Mn)
0.212
mg/L
0.005
Strontium (Sr)
0.134
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
13.0
mg/L
0.01
Magnesium (Mg)
2.36
mg/L
0.005
Potassium (K)
4.49
mg/L
0.1
Sodium (Na)
37.4
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.163
mg/L
0.005
Barium (Ba)
0.017
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.098
mg/L
0.01
Manganese (Mn)
0.199
mg/L
0.005
Strontium (Sr)
0.131
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000530
Matrix: GW WW
Page 20 of 68
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 11:20 LSTARL1
Vendor Method V_PACE
2 EPA 300.0
01/09/2016 01:44
BGN9034
2 EPA 300.0
01/09/2016 01:44
BGN9034
1 EPA 245.1
01/08/2016 16:20
ACPAYNE
1 EPA 245.1
01/09/2016 13:31
ACPAYNE
1 EPA 200.7
01/08/2016 14:32
FCJORDA
1 EPA 200.7
01/08/2016 14:32
FCJORDA
1 EPA 200.7
01/08/2016 14:32
FCJORDA
1 EPA 200.7
01/08/2016 14:32
FCJORDA
1 EPA 200.7
01/08/2016 14:32
FCJORDA
1 EPA 200.7
01/08/2016 14:32
FCJORDA
1 EPA 200.7
01/08/2016 14:32
FCJORDA
1 EPA 200.7
01/11/2016 12:45
FCJORDA
1 EPA 200.7
01/11/2016 12:45
FCJORDA
1 EPA 200.7
01/11/2016 12:45
FCJORDA
1 EPA 200.7
01/11/2016 12:45
FCJORDA
1 EPA 200.7
01/10/2016 17:51
FCJORDA
1 EPA 200.7
01/10/2016 17:51
FCJORDA
1 EPA 200.7
01/10/2016 17:51
FCJORDA
1 EPA 200.7
01/10/2016 17:51
FCJORDA
1 EPA 200.7
01/10/2016 17:51
FCJORDA
1 EPA 200.7
01/10/2016 17:51
FCJORDA
1 EPA 200.7
01/10/2016 17:51
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-14BR
Collection Date: 07-Jan-16 10:35 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
3.97
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
2.34
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
1.21
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
4.56
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
2.45
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
180
mg/L
25
Total Carbon
TOC
0.855
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 21 of 68
Sample #:
2016000530
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 15:50
SLS2560
1
EPA 200.8
01/10/2016 15:50
SLS2560
1
EPA 200.8
01/10/2016 15:50
SLS2560
1
EPA 200.8
01/10/2016 15:50
SLS2560
1
EPA 200.8
01/10/2016 15:50
SLS2560
1
EPA 200.8
01/10/2016 15:50
SLS2560
1
EPA 200.8
01/10/2016 15:50
SLS2560
1
EPA 200.8
01/10/2016 15:50
SLS2560
1
EPA 200.8
01/10/2016 15:50
SLS2560
1
EPA 200.8
01/10/2016 15:50
SLS2560
1
EPA 200.8
01/10/2016 15:50
SLS2560
1
EPA 200.8
01/10/2016 15:50
SLS2560
1
EPA 200.8
01/10/2016 15:50
SLS2560
1 EPA 200.8
01/10/2016 21:08
SLS2560
1 EPA 200.8
01/10/2016 21:08
SLS2560
1 EPA 200.8
01/10/2016 21:08
SLS2560
1 EPA 200.8
01/10/2016 21:08
SLS2560
1 EPA 200.8
01/10/2016 21:08
SLS2560
1 EPA 200.8
01/10/2016 21:08
SLS2560
1 EPA 200.8
01/10/2016 21:08
SLS2560
1 EPA 200.8
01/10/2016 21:08
SLS2560
1 EPA 200.8
01/10/2016 21:08
SLS2560
1 EPA 200.8
01/10/2016 21:08
SLS2560
1 EPA 200.8
01/10/2016 21:08
SLS2560
1 EPA 200.8
01/10/2016 21:08
SLS2560
1 EPA 200.8
01/10/2016 21:08
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/10/201614:09 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/10/2016 08:30 CJELLIO

Certificate of Laboratory Analysis Page 22 of 68
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-16D
Collection Date: 07-Jan-16 9:55 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 3.1 mg-N/L 0.05
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
9.8
mg/L
0.1
Sulfate
7.3
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.006
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.017
mg/L
0.005
Strontium (Sr)
0.166
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
25.3
mg/L
0.01
Magnesium (Mg)
5.06
mg/L
0.005
Potassium (K)
1.94
mg/L
0.1
Sodium (Na)
9.62
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.192
mg/L
0.005
Barium (Ba)
0.007
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.203
mg/L
0.01
Manganese (Mn)
0.028
mg/L
0.005
Strontium (Sr)
0.161
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000531
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
5 EPA 353.2 01/10/2016 12:51 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
01/09/2016 02:02
BGN9034
1 EPA 300.0
01/09/2016 02:02
BGN9034
1 EPA 245.1
01/08/2016 16:22
ACPAYNE
1 EPA 245.1
01/09/2016 13:34
ACPAYNE
1 EPA 200.7
01/08/2016 14:36
FCJORDA
1 EPA 200.7
01/08/2016 14:36
FCJORDA
1 EPA 200.7
01/08/2016 14:36
FCJORDA
1 EPA 200.7
01/08/2016 14:36
FCJORDA
1 EPA 200.7
01/08/2016 14:36
FCJORDA
1 EPA 200.7
01/08/2016 14:36
FCJORDA
1 EPA 200.7
01/08/2016 14:36
FCJORDA
1 EPA 200.7
01/11/2016 12:56
FCJORDA
1 EPA 200.7
01/11/2016 12:56
FCJORDA
1 EPA 200.7
01/11/2016 12:56
FCJORDA
1 EPA 200.7
01/11/2016 12:56
FCJORDA
1 EPA 200.7
01/10/2016 17:55
FCJORDA
1 EPA 200.7
01/10/2016 17:55
FCJORDA
1 EPA 200.7
01/10/2016 17:55
FCJORDA
1 EPA 200.7
01/10/2016 17:55
FCJORDA
1 EPA 200.7
01/10/2016 17:55
FCJORDA
1 EPA 200.7
01/10/2016 17:55
FCJORDA
1 EPA 200.7
01/10/2016 17:55
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-16D
Collection Date: 07-Jan-16 9:55 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
5.76
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.462
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
5.86
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.678
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
130
mg/L
25
Total Carbon
TOC
< 0.1
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
7.0
mg/L
5
Page 23 of 68
Sample #:
2016000531
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 17:03
SLS2560
1
EPA 200.8
01/10/2016 17:03
SLS2560
1
EPA 200.8
01/10/2016 17:03
SLS2560
1
EPA 200.8
01/10/2016 17:03
SLS2560
1
EPA 200.8
01/10/2016 17:03
SLS2560
1
EPA 200.8
01/10/2016 17:03
SLS2560
1
EPA 200.8
01/10/2016 17:03
SLS2560
1
EPA 200.8
01/10/2016 17:03
SLS2560
1
EPA 200.8
01/10/2016 17:03
SLS2560
1
EPA 200.8
01/10/2016 17:03
SLS2560
1
EPA 200.8
01/10/2016 17:03
SLS2560
1
EPA 200.8
01/10/2016 17:03
SLS2560
1
EPA 200.8
01/10/2016 17:03
SLS2560
1 EPA 200.8
01/10/2016 21:12
SLS2560
1 EPA 200.8
01/10/2016 21:12
SLS2560
1 EPA 200.8
01/10/2016 21:12
SLS2560
1 EPA 200.8
01/10/2016 21:12
SLS2560
1 EPA 200.8
01/10/2016 21:12
SLS2560
1 EPA 200.8
01/10/2016 21:12
SLS2560
1 EPA 200.8
01/10/2016 21:12
SLS2560
1 EPA 200.8
01/10/2016 21:12
SLS2560
1 EPA 200.8
01/10/2016 21:12
SLS2560
1 EPA 200.8
01/10/2016 21:12
SLS2560
1 EPA 200.8
01/10/2016 21:12
SLS2560
1 EPA 200.8
01/10/2016 21:12
SLS2560
1 EPA 200.8
01/10/2016 21:12
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/10/201614:09 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/10/2016 08:30 CJELLIO

Certificate of Laboratory Analysis Page 24 of 68
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-16S
Collection Date: 07-Jan-16 9:20 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.015 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
14
mg/L
0.5
Sulfate
4.8
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.044
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.285
mg/L
0.01
Manganese (Mn)
0.284
mg/L
0.005
Strontium (Sr)
0.118
mg/L
0.005
Zinc (Zn)
0.025
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
9.53
mg/L
0.01
Magnesium (Mg)
3.60
mg/L
0.005
Potassium (K)
1.64
mg/L
0.1
Sodium (Na)
15.6
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.105
mg/L
0.005
Barium (Ba)
0.045
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.520
mg/L
0.01
Manganese (Mn)
0.252
mg/L
0.005
Strontium (Sr)
0.113
mg/L
0.005
Zinc (Zn)
0.014
mg/L
0.005
Sample #: 2016000532
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 11:28 LSTARL1
Vendor Method V_PACE
5 EPA 300.0
01/09/2016 15:06
BGN9034
1 EPA 300.0
01/09/2016 15:06
BGN9034
1 EPA 245.1
01/08/2016 16:25
ACPAYNE
1 EPA 245.1
01/09/2016 13:36
ACPAYNE
1 EPA 200.7
01/08/2016 14:40
FCJORDA
1 EPA 200.7
01/08/2016 14:40
FCJORDA
1 EPA 200.7
01/08/2016 14:40
FCJORDA
1 EPA 200.7
01/08/2016 14:40
FCJORDA
1 EPA 200.7
01/08/2016 14:40
FCJORDA
1 EPA 200.7
01/08/2016 14:40
FCJORDA
1 EPA 200.7
01/08/2016 14:40
FCJORDA
1 EPA 200.7
01/11/2016 13:00
FCJORDA
1 EPA 200.7
01/11/2016 13:00
FCJORDA
1 EPA 200.7
01/11/2016 13:00
FCJORDA
1 EPA 200.7
01/11/2016 13:00
FCJORDA
1 EPA 200.7
01/10/2016 18:07
FCJORDA
1 EPA 200.7
01/10/2016 18:07
FCJORDA
1 EPA 200.7
01/10/2016 18:07
FCJORDA
1 EPA 200.7
01/10/2016 18:07
FCJORDA
1 EPA 200.7
01/10/2016 18:07
FCJORDA
1 EPA 200.7
01/10/2016 18:07
FCJORDA
1 EPA 200.7
01/10/2016 18:07
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-16S
Collection Date: 07-Jan-16 9:20 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
2.08
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.11
ug/L
1
Nickel (Ni)
2.95
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
4.57
ug/L
1
Cobalt (Co)
2.11
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.48
ug/L
1
Nickel (Ni)
3.83
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
86
mg/L
25
Total Carbon
TOC
0.316
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 25 of 68
Sample #:
2016000532
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 17:08
SLS2560
1
EPA 200.8
01/10/2016 17:08
SLS2560
1
EPA 200.8
01/10/2016 17:08
SLS2560
1
EPA 200.8
01/10/2016 17:08
SLS2560
1
EPA 200.8
01/10/2016 17:08
SLS2560
1
EPA 200.8
01/10/2016 17:08
SLS2560
1
EPA 200.8
01/10/2016 17:08
SLS2560
1
EPA 200.8
01/10/2016 17:08
SLS2560
1
EPA 200.8
01/10/2016 17:08
SLS2560
1
EPA 200.8
01/10/2016 17:08
SLS2560
1
EPA 200.8
01/10/2016 17:08
SLS2560
1
EPA 200.8
01/10/2016 17:08
SLS2560
1
EPA 200.8
01/10/2016 17:08
SLS2560
1 EPA 200.8
01/10/2016 21:52
SLS2560
1 EPA 200.8
01/10/2016 21:52
SLS2560
1 EPA 200.8
01/10/2016 21:52
SLS2560
1 EPA 200.8
01/10/2016 21:52
SLS2560
1 EPA 200.8
01/10/2016 21:52
SLS2560
1 EPA 200.8
01/10/2016 21:52
SLS2560
1 EPA 200.8
01/10/2016 21:52
SLS2560
1 EPA 200.8
01/10/2016 21:52
SLS2560
1 EPA 200.8
01/10/2016 21:52
SLS2560
1 EPA 200.8
01/10/2016 21:52
SLS2560
1 EPA 200.8
01/10/2016 21:52
SLS2560
1 EPA 200.8
01/10/2016 21:52
SLS2560
1 EPA 200.8
01/10/2016 21:52
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/10/201614:09 CJELLIO
1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/10/2016 08:30 CJELLIO

Certificate of Laboratory Analysis Page 26 of 68
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-16BR
Collection Date: 07-Jan-16 9:09 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
7.7
mg/L
0.1
Sulfate
6.2
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.027
mg/L
0.005
Barium (Ba)
0.007
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.029
mg/L
0.005
Strontium (Sr)
0.074
mg/L
0.005
Zinc (Zn)
0.025
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
18.3
mg/L
0.01
Magnesium (Mg)
2.09
mg/L
0.005
Potassium (K)
2.20
mg/L
0.1
Sodium (Na)
30.3
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.136
mg/L
0.005
Barium (Ba)
0.009
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.126
mg/L
0.01
Manganese (Mn)
0.032
mg/L
0.005
Strontium (Sr)
0.074
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000533
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 11:32 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
01/09/2016 12:42
BGN9034
1 EPA 300.0
01/09/2016 12:42
BGN9034
1 EPA 245.1
01/08/2016 16:27
ACPAYNE
1 EPA 245.1
01/09/2016 13:48
ACPAYNE
1 EPA 200.7
01/08/2016 14:43
FCJORDA
1 EPA 200.7
01/08/2016 14:43
FCJORDA
1 EPA 200.7
01/08/2016 14:43
FCJORDA
1 EPA 200.7
01/08/2016 14:43
FCJORDA
1 EPA 200.7
01/08/2016 14:43
FCJORDA
1 EPA 200.7
01/08/2016 14:43
FCJORDA
1 EPA 200.7
01/08/2016 14:43
FCJORDA
1 EPA 200.7
01/11/2016 13:04
FCJORDA
1 EPA 200.7
01/11/2016 13:04
FCJORDA
1 EPA 200.7
01/11/2016 13:04
FCJORDA
1 EPA 200.7
01/11/2016 13:04
FCJORDA
1 EPA 200.7
01/10/2016 18:18
FCJORDA
1 EPA 200.7
01/10/2016 18:18
FCJORDA
1 EPA 200.7
01/10/2016 18:18
FCJORDA
1 EPA 200.7
01/10/2016 18:18
FCJORDA
1 EPA 200.7
01/10/2016 18:18
FCJORDA
1 EPA 200.7
01/10/2016 18:18
FCJORDA
1 EPA 200.7
01/10/2016 18:18
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-16BR
Collection Date: 07-Jan-16 9:09 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
1.27
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
42.6
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.666
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
1.34
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
42.6
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L M2
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.06
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
150
mg/L
25
Total Carbon
TOC
9.7
mg/L
1
TOTAL SUSPENDED SOLIDS
TSS
12
mg/L
5
Page 27 of 68
Sample #:
2016000533
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 17:42
SLS2560
1
EPA 200.8
01/10/2016 17:42
SLS2560
1
EPA 200.8
01/10/2016 17:42
SLS2560
1
EPA 200.8
01/10/2016 17:42
SLS2560
1
EPA 200.8
01/10/2016 17:42
SLS2560
1
EPA 200.8
01/10/2016 17:42
SLS2560
1
EPA 200.8
01/10/2016 17:42
SLS2560
1
EPA 200.8
01/10/2016 17:42
SLS2560
1
EPA 200.8
01/10/2016 17:42
SLS2560
1
EPA 200.8
01/10/2016 17:42
SLS2560
1
EPA 200.8
01/10/2016 17:42
SLS2560
1
EPA 200.8
01/10/2016 17:42
SLS2560
1
EPA 200.8
01/10/2016 17:42
SLS2560
1 EPA 200.8
01/10/2016 21:17
SLS2560
1 EPA 200.8
01/10/2016 21:17
SLS2560
1 EPA 200.8
01/10/2016 21:17
SLS2560
1 EPA 200.8
01/10/2016 21:17
SLS2560
1 EPA 200.8
01/10/2016 21:17
SLS2560
1 EPA 200.8
01/10/2016 21:17
SLS2560
1 EPA 200.8
01/10/2016 21:17
SLS2560
1 EPA 200.8
01/10/2016 21:17
SLS2560
1 EPA 200.8
01/10/2016 21:17
SLS2560
1 EPA 200.8
01/10/2016 21:17
SLS2560
1 EPA 200.8
01/10/2016 21:17
SLS2560
1 EPA 200.8
01/10/2016 21:17
SLS2560
1 EPA 200.8
01/10/2016 21:17
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/10/201614:09 CJELLIO
10 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
1 SM2540D 01/10/2016 08:30 CJELLIO

Certificate of Laboratory Analysis Page 28 of 68
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-16D Dup
Collection Date: 07-Jan-16 9:55 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 3.2 mg-N/L 0.05
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
9.8
mg/L
0.1
Sulfate
7.3
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.007
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.018
mg/L
0.005
Strontium (Sr)
0.173
mg/L
0.005
Zinc (Zn)
0.010
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
25.5
mg/L
0.01
Magnesium (Mg)
5.10
mg/L
0.005
Potassium (K)
1.92
mg/L
0.1
Sodium (Na)
9.56
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.196
mg/L
0.005
Barium (Ba)
0.007
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.200
mg/L
0.01
Manganese (Mn)
0.027
mg/L
0.005
Strontium (Sr)
0.159
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000534
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
5 EPA 353.2 01/10/2016 11:43 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
01/09/2016 13:00
BGN9034
1 EPA 300.0
01/09/2016 13:00
BGN9034
1 EPA 245.1
01/08/2016 16:29
ACPAYNE
1 EPA 245.1
01/09/2016 13:41
ACPAYNE
1 EPA 200.7
01/08/2016 14:47
FCJORDA
1 EPA 200.7
01/08/2016 14:47
FCJORDA
1 EPA 200.7
01/08/2016 14:47
FCJORDA
1 EPA 200.7
01/08/2016 14:47
FCJORDA
1 EPA 200.7
01/08/2016 14:47
FCJORDA
1 EPA 200.7
01/08/2016 14:47
FCJORDA
1 EPA 200.7
01/08/2016 14:47
FCJORDA
1 EPA 200.7
01/11/2016 13:08
FCJORDA
1 EPA 200.7
01/11/2016 13:08
FCJORDA
1 EPA 200.7
01/11/2016 13:08
FCJORDA
1 EPA 200.7
01/11/2016 13:08
FCJORDA
1 EPA 200.7
01/10/2016 18:22
FCJORDA
1 EPA 200.7
01/10/2016 18:22
FCJORDA
1 EPA 200.7
01/10/2016 18:22
FCJORDA
1 EPA 200.7
01/10/2016 18:22
FCJORDA
1 EPA 200.7
01/10/2016 18:22
FCJORDA
1 EPA 200.7
01/10/2016 18:22
FCJORDA
1 EPA 200.7
01/10/2016 18:22
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: MW-16D Dup
Collection Date: 07-Jan-16 9:55 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
5.77
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.473
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
5.95
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.598
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
140
mg/L
25
Total Carbon
TOC
< 0.1
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
7.0
mg/L
5
Page 29 of 68
Sample #:
2016000534
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 17:47
SLS2560
1
EPA 200.8
01/10/2016 17:47
SLS2560
1
EPA 200.8
01/10/2016 17:47
SLS2560
1
EPA 200.8
01/10/2016 17:47
SLS2560
1
EPA 200.8
01/10/2016 17:47
SLS2560
1
EPA 200.8
01/10/2016 17:47
SLS2560
1
EPA 200.8
01/10/2016 17:47
SLS2560
1
EPA 200.8
01/10/2016 17:47
SLS2560
1
EPA 200.8
01/10/2016 17:47
SLS2560
1
EPA 200.8
01/10/2016 17:47
SLS2560
1
EPA 200.8
01/10/2016 17:47
SLS2560
1
EPA 200.8
01/10/2016 17:47
SLS2560
1
EPA 200.8
01/10/2016 17:47
SLS2560
1 EPA 200.8
01/10/2016 21:57
SLS2560
1 EPA 200.8
01/10/2016 21:57
SLS2560
1 EPA 200.8
01/10/2016 21:57
SLS2560
1 EPA 200.8
01/10/2016 21:57
SLS2560
1 EPA 200.8
01/10/2016 21:57
SLS2560
1 EPA 200.8
01/10/2016 21:57
SLS2560
1 EPA 200.8
01/10/2016 21:57
SLS2560
1 EPA 200.8
01/10/2016 21:57
SLS2560
1 EPA 200.8
01/10/2016 21:57
SLS2560
1 EPA 200.8
01/10/2016 21:57
SLS2560
1 EPA 200.8
01/10/2016 21:57
SLS2560
1 EPA 200.8
01/10/2016 21:57
SLS2560
1 EPA 200.8
01/10/2016 21:57
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/10/201614:09 CJELLIO
1 SM5310C/EPA9060A 01/13/201615:59 GHUTCHI
1 SM2540D 01/10/2016 08:30 CJELLIO

Certificate of Laboratory Analysis Page 30 of 68
This report shall not be reproduced, except in full.
Order # J16010101
Site: Filter Blank
Collection Date:
Analyte
Result
Units Qualifiers
RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2016000535
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
01/09/2016 13:38
ACPAYNE
1
EPA 200.7
01/08/2016 14:51
FCJORDA
1
EPA 200.7
01/08/2016 14:51
FCJORDA
1
EPA 200.7
01/08/2016 14:51
FCJORDA
1
EPA 200.7
01/08/2016 14:51
FCJORDA
1
EPA 200.7
01/08/2016 14:51
FCJORDA
1
EPA 200.7
01/08/2016 14:51
FCJORDA
1
EPA 200.7
01/08/2016 14:51
FCJORDA
1
EPA 200.8
01/10/2016 17:52
SLS2560
1
EPA 200.8
01/10/2016 17:52
SLS2560
1
EPA 200.8
01/10/2016 17:52
SLS2560
1
EPA 200.8
01/10/2016 17:52
SLS2560
1
EPA 200.8
01/10/2016 17:52
SLS2560
1
EPA 200.8
01/10/2016 17:52
SLS2560
1
EPA 200.8
01/10/2016 17:52
SLS2560
1
EPA 200.8
01/10/2016 17:52
SLS2560
1
EPA 200.8
01/10/2016 17:52
SLS2560
1
EPA 200.8
01/10/2016 17:52
SLS2560
1
EPA 200.8
01/10/2016 17:52
SLS2560
1
EPA 200.8
01/10/2016 17:52
SLS2560
1
EPA 200.8
01/10/2016 17:52
SLS2560

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: Equipment Blank
Collection Date:
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.012 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
Calcium (Ca)
0.022
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Page 31 of 68
Sample #: 2016000536
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_PACE
1 EPA 353.2
01/10/2016 11:34
LSTARL1
Vendor Method
V_PACE
1 EPA 300.0
01/09/2016 11:31
BGN9034
1 EPA 300.0
01/09/2016 11:31
BGN9034
1 EPA 245.1
01/08/2016 16:37
ACPAYNE
1 EPA 200.7
01/11/2016 13:12
FCJORDA
1 EPA 200.7
01/11/2016 13:12
FCJORDA
1 EPA 200.7
01/11/2016 13:12
FCJORDA
1 EPA 200.7
01/11/2016 13:12
FCJORDA
1 EPA 200.7
01/10/2016 18:26
FCJORDA
1 EPA 200.7
01/10/2016 18:26
FCJORDA
1 EPA 200.7
01/10/2016 18:26
FCJORDA
1 EPA 200.7
01/10/2016 18:26
FCJORDA
1 EPA 200.7
01/10/2016 18:26
FCJORDA
1 EPA 200.7
01/10/2016 18:26
FCJORDA
1 EPA 200.7
01/10/2016 18:26
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
Site: Equipment Blank
Collection Date:
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
< 25
mg/L
25
1
Total Carbon
Page 32 of 68
Sample #:
2016000536
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
01/10/2016 22:01
SLS2560
EPA 200.8
01/10/2016 22:01
SLS2560
EPA 200.8
01/10/2016 22:01
SLS2560
EPA 200.8
01/10/2016 22:01
SLS2560
EPA 200.8
01/10/2016 22:01
SLS2560
EPA 200.8
01/10/2016 22:01
SLS2560
EPA 200.8
01/10/2016 22:01
SLS2560
EPA 200.8
01/10/2016 22:01
SLS2560
EPA 200.8
01/10/2016 22:01
SLS2560
EPA 200.8
01/10/2016 22:01
SLS2560
EPA 200.8
01/10/2016 22:01
SLS2560
EPA 200.8
01/10/2016 22:01
SLS2560
EPA 200.8
01/10/2016 22:01
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
SM2540C 01/10/201614:09 CJELLIO
TOC 0.172 mg/L 0.1 1 SM5310C/EPA9060A 01/11/201615:18 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 01/10/2016 08:30 CJELLIO
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098ni�c yoe. Suite 100
y Huntersville, INC 28078
[phone]
January 14, 2016
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 16010101
Pace Project No.: 92282353
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 08, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Anne Pifer
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 35

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
OQ9K3i SW. Suite 100
Huntersville, NC 28078
[phone]
Project: J16010101
Pace Project No.: 92282353
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West Virginia Certification #: 356
Virginia/VELAP Certification M 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE SUMMARY
Project: J16010101
Pace Project No.: 92282353
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92282353001
2016000520
Water
01/07/1615:12
01/08/1613:00
92282353002
2016000523
Water
01/07/1612:50
01/08/1613:00
92282353003
2016000524
Water
01/07/16 08:52
01/08/1613:00
92282353004
2016000525
Water
01/07/1613:25
01/08/1613:00
92282353005
2016000526
Water
01/07/1615:20
01/08/1613:00
92282353006
2016000527
Water
01/07/1612:35
01/08/1613:00
92282353007
2016000528
Water
01/07/1615:51
01/08/1613:00
92282353008
2016000529
Water
01/07/1611:35
01/08/1613:00
92282353009
2016000530
Water
01/07/1610:35
01/08/1613:00
92282353010
2016000531
Water
01/07/16 09:55
01/08/1613:00
92282353011
2016000532
Water
01/07/16 09:20
01/08/1613:00
92282353012
2016000533
Water
01/07/16 09:07
01/08/1613:00
92282353013
2016000534
Water
01/07/16 09:55
01/08/1613:00
92282353014
2016000536
Water
01/07/16 00:00
01/08/1613:00
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16010101
92282353
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92282353001
2016000520
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282353002
2016000523
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282353003
2016000524
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282353004
2016000525
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282353005
2016000526
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282353006
2016000527
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282353007
2016000528
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282353008
2016000529
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282353009
2016000530
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282353010
2016000531
RSK 175
DR1
1
PASI-M
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project:
J16010101
Pace Project No.:
92282353
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
SM 2320B
MLS
3
PASI-A
SM 4500-S21D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282353011
2016000532
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S21D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282353012
2016000533
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S21D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282353013
2016000534
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S21D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282353014
2016000536
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S21D
SAM
1
PASI-A
EPA 218.7
TK1
1
PASI-O
REPORT OF LABORATORY ANALYSIS
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SUMMARY OF DETECTION
Project:
Pace Project No.:
J16010101
92282353
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92282353001
2016000520
RSK 175
Methane
3680
ug/L
10.0
01/11/16 11:03
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
297
mg/L
5.0
01/12/16 12:23
SM 2320B
Alkalinity, Total as CaCO3
297
mg/L
5.0
01/12/16 12:23
92282353002
2016000523
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
223
mg/L
5.0
01/12/16 12:37
SM 2320B
Alkalinity, Total as CaCO3
223
mg/L
5.0
01/12/16 12:37
92282353003
2016000524
RSK 175
Methane
912
ug/L
10.0
01/11/16 11:28
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
212
mg/L
5.0
01/12/16 12:50
SM 2320B
Alkalinity, Total as CaCO3
212
mg/L
5.0
01/12/16 12:50
92282353004
2016000525
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
103
mg/L
5.0
01/12/16 13:24
SM 2320B
Alkalinity, Total as CaCO3
103
mg/L
5.0
01/12/16 13:24
92282353005
2016000526
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
36.4
mg/L
5.0
01/12/16 13:37
SM 2320B
Alkalinity, Carbonate (CaCO3)
28.3
mg/L
5.0
01/12/16 13:37
SM 2320B
Alkalinity, Total as CaCO3
64.8
mg/L
5.0
01/12/16 13:37
EPA 218.7
Chromium, Hexavalent
12.2
ug/L
3.0
01/12/1610:02
92282353006
2016000527
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
11.1
mg/L
5.0
01/12/16 13:48
SM 2320B
Alkalinity, Total as CaCO3
11.1
mg/L
5.0
01/12/16 13:48
EPA 218.7
Chromium, Hexavalent
0.038
ug/L
0.030
01/12/16 00:28
92282353007
2016000528
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
53.5
mg/L
5.0
01/12/16 13:57
SM 2320B
Alkalinity, Total as CaCO3
53.5
mg/L
5.0
01/12/16 13:57
EPA 218.7
Chromium, Hexavalent
0.52
ug/L
0.15
01/12/1610:15 M1
92282353008
2016000529
RSK 175
Methane
25.9
ug/L
10.0
01/11/16 12:10
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
223
mg/L
5.0
01/12/16 14:09
SM 2320B
Alkalinity, Total as CaCO3
223
mg/L
5.0
01/12/16 14:09 M1
92282353009
2016000530
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
94.8
mg/L
5.0
01/12/16 14:50
SM 2320B
Alkalinity, Total as CaCO3
94.8
mg/L
5.0
01/12/16 14:50
92282353010
2016000531
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
74.3
mg/L
5.0
01/12/16 15:03
SM 2320B
Alkalinity, Total as CaCO3
74.3
mg/L
5.0
01/12/16 15:03
EPA 218.7
Chromium, Hexavalent
0.097
ug/L
0.030
01/12/16 02:12
92282353011
2016000532
SM 2320B
Alkalinity, Bicarbonate (CaCO3)
49.0
mg/L
5.0
01/12/16 15:13
SM 2320B
Alkalinity, Total as CaCO3
49.0
mg/L
5.0
01/12/16 15:13
EPA 218.7
Chromium, Hexavalent
0.083
ug/L
0.030
01/12/16 02:25
REPORT OF LABORATORY ANALYSIS
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Project: J16010101
Pace Project No.: 92282353
Lab Sample ID
Method
92282353012
SM 2320B
SM 2320B
SM 4500-S21D
92282353013
SM 2320B
SM 2320B
EPA 218.7
SUMMARY OF DETECTION
Client Sample ID
Parameters
2016000533
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
Sulfide
2016000534
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
Chromium, Hexavalent
Result Units
103 mg/L
103 mg/L
1.2 mg/L
77.6 mg/L
77.6 mg/L
0.10 ug/L
REPORT OF LABORATORY ANALYSIS
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Report Limit Analyzed Qualifiers
5.0 01/12/1615:44
5.0 01/12/1615:44
0.20 01/10/1611:30
5.0 01/12/1615:56
5.0 01/12/1615:56
0.030 01/12/16 02:51
Page 7 of 35

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PROJECT NARRATIVE
Project: J16010101
Pace Project No.: 92282353
Method: RSK 175
Description: RSK 175 AIR Headspace
Client: Duke Energy
Date: January 14, 2016
General Information:
14 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
QC Batch: AIR/25000
R1: RPD value was outside control limits.
• DUP (Lab ID: 2173348)
• Methane
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16010101
Pace Project No.: 92282353
Method: SM 2320B
Description: 2320E Alkalinity
Client: Duke Energy
Date: January 14, 2016
General Information:
14 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/42413
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92282350004,92282353008
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 1644935)
• Alkalinity, Total as CaCO3
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16010101
Pace Project No.: 92282353
Method: SM 4500-S213
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: January 14, 2016
General Information:
14 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16010101
Pace Project No.: 92282353
Method: EPA 218.7
Description: Hexavalent Chromium by IC
Client: Duke Energy
Date: January 14, 2016
General Information:
14 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16010101
Pace Project No.: 92282353
Sample: 2016000520
Lab ID: 92282353001 Collected:
01/07/16 15:12
Received: 01/08/16 13:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
3680 ug/L
10.0
1
01/11/1611:03
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
297 mg/L
5.0
1
01/12/16 12:23
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 12:23
Alkalinity, Total as CaCO3
297 mg/L
5.0
1
01/12/16 12:23
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/11/16 23:23
18540-29-9
Date: 01/14/2016 06:01 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 12 of 35

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ANALYTICAL RESULTS
Project: J16010101
Pace Project No.: 92282353
Sample: 2016000523
Lab ID: 92282353002 Collected:
01/07/16 12:50
Received: 01/08/16 13:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/11/1611:20
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
223 mg/L
5.0
1
01/12/16 12:37
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 12:37
Alkalinity, Total as CaCO3
223 mg/L
5.0
1
01/12/16 12:37
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/11/16 23:36
18540-29-9
Date: 01/14/2016 06:01 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 13 of 35

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Pace Analytical Services, Inc.
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[phone]
ANALYTICAL RESULTS
Project: J16010101
Pace Project No.: 92282353
Sample: 2016000524
Lab ID: 92282353003 Collected:
01/07/16 08:52
Received: 01/08/16 13:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
912 ug/L
10.0
1
01/11/1611:28
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
212 mg/L
5.0
1
01/12/16 12:50
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 12:50
Alkalinity, Total as CaCO3
212 mg/L
5.0
1
01/12/16 12:50
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/11/16 23:49
18540-29-9
Date: 01/14/2016 06:01 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 14 of 35

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ANALYTICAL RESULTS
Project: J16010101
Pace Project No.: 92282353
Sample: 2016000525
Lab ID: 92282353004 Collected:
01/07/16 13:25
Received: 01/08/16 13:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/11/1611:37
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
103 mg/L
5.0
1
01/12/16 13:24
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 13:24
Alkalinity, Total as CaCO3
103 mg/L
5.0
1
01/12/16 13:24
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/12/16 00:02
18540-29-9
Date: 01/14/2016 06:01 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 15 of 35

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ANALYTICAL RESULTS
Project: J16010101
Pace Project No.: 92282353
Sample: 2016000526
Lab ID: 92282353005 Collected:
01/07/16 15:20
Received: 01/08/16 13:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/11/1611:45
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
36.4 mg/L
5.0
1
01/12/16 13:37
Alkalinity, Carbonate (CaCO3)
28.3 mg/L
5.0
1
01/12/16 13:37
Alkalinity, Total as CaCO3
64.8 mg/L
5.0
1
01/12/16 13:37
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
12.2 ug/L
3.0
100
01/12/16 10:02
18540-29-9
Date: 01/14/2016 06:01 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 16 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098m.8foie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010101
Pace Project No.: 92282353
Sample: 2016000527
Lab ID: 92282353006 Collected:
01/07/16 12:35
Received: 01/08/16 13:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/11/1611:53
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
11.1 mg/L
5.0
1
01/12/16 13:48
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 13:48
Alkalinity, Total as CaCO3
11.1 mg/L
5.0
1
01/12/16 13:48
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.038 ug/L
0.030
1
01/12/16 00:28
18540-29-9
Date: 01/14/2016 06:01 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 17 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyoe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010101
Pace Project No.: 92282353
Sample: 2016000528
Lab ID: 92282353007 Collected:
01/07/16 15:51
Received: 01/08/16 13:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/11/1612:01
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
53.5 mg/L
5.0
1
01/12/16 13:57
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 13:57
Alkalinity, Total as CaCO3
53.5 mg/L
5.0
1
01/12/16 13:57
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.52 ug/L
0.15
5
01/12/16 10:15
18540-29-9 M1
Date: 01/14/2016 06:01 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 18 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
09Q�Ijin�c& oe. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010101
Pace Project No.: 92282353
Sample: 2016000529
Lab ID: 92282353008 Collected:
01/07/16 11:35
Received: 01/08/16 13:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
25.9 ug/L
10.0
1
01/11/1612:10
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
223 mg/L
5.0
1
01/12/16 14:09
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 14:09
Alkalinity, Total as CaCO3
223 mg/L
5.0
1
01/12/16 14:09
M1
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/12/16 01:46
18540-29-9
Date: 01/14/2016 06:01 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 19 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyoe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010101
Pace Project No.: 92282353
Sample: 2016000530
Lab ID: 92282353009 Collected:
01/07/16 10:35
Received: 01/08/16 13:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/11/1612:18
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
94.8 mg/L
5.0
1
01/12/16 14:50
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 14:50
Alkalinity, Total as CaCO3
94.8 mg/L
5.0
1
01/12/16 14:50
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/12/16 01:59
18540-29-9
Date: 01/14/2016 06:01 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 20 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098nnyoe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010101
Pace Project No.: 92282353
Sample: 2016000531
Lab ID: 92282353010 Collected:
01/07/16 09:55
Received: 01/08/16 13:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/11/1612:46
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
74.3 mg/L
5.0
1
01/12/16 15:03
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 15:03
Alkalinity, Total as CaCO3
74.3 mg/L
5.0
1
01/12/16 15:03
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.097 ug/L
0.030
1
01/12/16 02:12
18540-29-9
Date: 01/14/2016 06:01 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 21 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098mc& oe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010101
Pace Project No.: 92282353
Sample: 2016000532
Lab ID: 92282353011 Collected:
01/07/16 09:20
Received: 01/08/16 13:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/11/1613:03
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
49.0 mg/L
5.0
1
01/12/16 15:13
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 15:13
Alkalinity, Total as CaCO3
49.0 mg/L
5.0
1
01/12/16 15:13
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.083 ug/L
0.030
1
01/12/16 02:25
18540-29-9
Date: 01/14/2016 06:01 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 22 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098nnyoe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010101
Pace Project No.: 92282353
Sample: 2016000533
Lab ID: 92282353012 Collected:
01/07/16 09:07
Received: 01/08/16 13:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/11/1613:11
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
103 mg/L
5.0
1
01/12/16 15:44
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 15:44
Alkalinity, Total as CaCO3
103 mg/L
5.0
1
01/12/16 15:44
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
1.2 mg/L
0.20
2
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/12/16 02:38
18540-29-9
Date: 01/14/2016 06:01 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 23 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyoe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010101
Pace Project No.: 92282353
Sample: 2016000534
Lab ID: 92282353013 Collected:
01/07/16 09:55
Received: 01/08/16 13:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/11/1613:19
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
77.6 mg/L
5.0
1
01/12/16 15:56
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 15:56
Alkalinity, Total as CaCO3
77.6 mg/L
5.0
1
01/12/16 15:56
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.10 ug/L
0.030
1
01/12/16 02:51
18540-29-9
Date: 01/14/2016 06:01 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 24 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g i .8foie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16010101
Pace Project No.: 92282353
Sample: 2016000536
Lab ID: 92282353014 Collected:
01/07/16 00:00
Received: 01/08/16 13:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/11/1613:28
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 16:06
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/12/16 16:06
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
01/12/16 16:06
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/10/1611:30
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/12/16 03:04
18540-29-9
Date: 01/14/2016 06:01 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 25 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098ogc yoe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010101
Pace Project No.: 92282353
QC Batch: AIR/25000
Analysis Method: RSK 175
QC Batch Method: RSK 175
Analysis Description: RSK 175 AIR HEADSPACE
Associated Lab Samples: 92282353001,
92282353002,
92282353003, 92282353004, 92282353005, 92282353006, 92282353007,
92282353008,92282353009,92282353010,92282353011,92282353012,92282353013,92282353014
METHOD BLANK: 2173085
Matrix: Water
Associated Lab Samples: 92282353001,
92282353002,
92282353003, 92282353004, 92282353005, 92282353006, 92282353007,
92282353008,92282353009,92282353010,92282353011,92282353012,92282353013,92282353014
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers
Methane
ug/L
ND 10.0 01/11/1610:11
LABORATORY CONTROL SAMPLE &
LCSD: 2173086
2173087
Spike LCS LCSD LCS LCSD % Rec Max
Parameter
Units
Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Methane
ug/L
60.7 54.5 54.6 90 90 85-115 0 20
SAMPLE DUPLICATE: 2173348
92282353001 Dup Max
Parameter
Units
Result Result RPD RPD Qualifiers
Methane
ug/L
3680 4600 22 20 R1
SAMPLE DUPLICATE: 2173349
92282353010 Dup Max
Parameter
Units
Result Result RPD RPD Qualifiers
Methane
ug/L
ND 1.8J 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/14/2016 06:01 PM without the written consent of Pace Analytical Services, Inc..
Page 26 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyoe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010101
Pace Project No.: 92282353
QC Batch: WET/42413 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92282353001, 92282353002, 92282353003, 92282353004, 92282353005, 92282353006, 92282353007,
92282353008,92282353009,92282353010,92282353011,92282353012,92282353013,92282353014
METHOD BLANK: 1644930 Matrix: Water
Associated Lab Samples: 92282353001, 92282353002, 92282353003, 92282353004, 92282353005, 92282353006, 92282353007,
92282353008,92282353009,92282353010,92282353011,92282353012,92282353013,92282353014
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Alkalinity, Carbonate (CaCO3) mg/L ND 5.0 01/12/16 11:00
Alkalinity, Total as CaCO3 mg/L ND 5.0 01/12/16 11:00
Alkalinity, Bicarbonate (CaCO3) mg/L ND 5.0 01/12/16 11:00
LABORATORY CONTROL SAMPLE: 1644931
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 47.5 95 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1644932 1644933
MS MSD
92282350004 Spike Spike MS MSD MS MSD % Rec
Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits
RPD RPD Qua]
Alkalinity, Total as CaCO3 mg/L 127 50 50 175 175 95 96 80-120
0 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1644934 1644935
MS MSD
92282353008 Spike Spike MS MSD MS MSD % Rec
Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits
RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 223 50 50 263 260 80 74 80-120
1 25 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/14/2016 06:01 PM without the written consent of Pace Analytical Services, Inc..
Page 27 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oi�c yoe. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010101
Pace Project No.: 92282353
QC Batch: WET/42390 Analysis Method: SM 4500-S2D
QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92282353001, 92282353002, 92282353003, 92282353004, 92282353005, 92282353006, 92282353007,
92282353008,92282353009,92282353010,92282353011,92282353012,92282353013,92282353014
METHOD BLANK: 1644370 Matrix: Water
Associated Lab Samples: 92282353001, 92282353002, 92282353003, 92282353004, 92282353005, 92282353006, 92282353007,
92282353008,92282353009,92282353010,92282353011,92282353012,92282353013,92282353014
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 01/10/1611:30
LABORATORY CONTROL SAMPLE: 1644371
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.50 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1644372 1644373
MS MSD
92282350002 Spike Spike MS MSD MS MSD % Rec
Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits
RPD RPD Qua]
Sulfide mg/L ND .5 .5 0.51 0.51 101 101 90-110
0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1644374 1644375
MS MSD
92282353006 Spike Spike MS MSD MS MSD % Rec
Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits
RPD RPD Qua]
Sulfide mg/L ND .5 .5 0.49 0.49 98 98 90-110
0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/14/2016 06:01 PM without the written consent of Pace Analytical Services, Inc..
Page 28 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinlc& oe. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010101
Pace Project No.: 92282353
QC Batch: WETA/53663
Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7
Analysis Description: Chromium, Hexavalent IC
Associated Lab Samples: 92282353001, 92282353002,
92282353003, 92282353004, 92282353005, 92282353006
METHOD BLANK: 1443677
Matrix: Water
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Chromium, Hexavalent ug/L
ND 0.030 01/11/16 18:37
LABORATORY CONTROL SAMPLE: 1443678
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Chromium, Hexavalent ug/L
.075 0.076 101 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1443679 1443680
MS MSD
92282355023
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L 0.087
.025 .025 0.11 0.11 101 90 85-115 2 20
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1443681 1443682
MS MSD
92282350003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND .075 .075 0.075 0.073 99 97 85-115 3 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/14/2016 06:01 PM without the written consent of Pace Analytical Services, Inc..
Page 29 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oi�c yoe. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16010101
Pace Project No.: 92282353
QC Batch: WETA/53703 Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7 Analysis Description: Chromium, Hexavalent IC
Associated Lab Samples: 92282353007,92282353008,92282353009,92282353010,92282353011,92282353012,92282353013,
92282353014
METHOD BLANK: 1444452 Matrix: Water
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chromium, Hexavalent ug/L ND 0.030 01/12/16 03:17
LABORATORY CONTROL SAMPLE: 1444453
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chromium, Hexavalent ug/L .075 0.074 99 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1444454 1444455
MS MSD
92282353007 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L 0.52 .38 .38 0.82 0.89 80 97 85-115 7 20 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/14/2016 06:01 PM without the written consent of Pace Analytical Services, Inc..
Page 30 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oi�c yoe. Suite 100
y Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J16010101
Pace Project No.: 92282353
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-M Pace Analytical Services - Minneapolis
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/14/2016 06:01 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 35

acmnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
og6g I�Cafore. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16010101
Pace Project No.: 92282353
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92282353001
2016000520
RSK 175
AIR/25000
92282353002
2016000523
RSK 175
AIR/25000
92282353003
2016000524
RSK 175
AIR/25000
92282353004
2016000525
RSK 175
AIR/25000
92282353005
2016000526
RSK 175
AIR/25000
92282353006
2016000527
RSK 175
AIR/25000
92282353007
2016000528
RSK 175
AIR/25000
92282353008
2016000529
RSK 175
AIR/25000
92282353009
2016000530
RSK 175
AIR/25000
92282353010
2016000531
RSK 175
AIR/25000
92282353011
2016000532
RSK 175
AIR/25000
92282353012
2016000533
RSK 175
AIR/25000
92282353013
2016000534
RSK 175
AIR/25000
92282353014
2016000536
RSK 175
AIR/25000
92282353001
2016000520
SM
2320B
WET/42413
92282353002
2016000523
SM
2320B
WET/42413
92282353003
2016000524
SM
2320B
WET/42413
92282353004
2016000525
SM
2320B
WET/42413
92282353005
2016000526
SM
2320B
WET/42413
92282353006
2016000527
SM
2320B
WET/42413
92282353007
2016000528
SM
2320B
WET/42413
92282353008
2016000529
SM
2320B
WET/42413
92282353009
2016000530
SM
2320B
WET/42413
92282353010
2016000531
SM
2320B
WET/42413
92282353011
2016000532
SM
2320B
WET/42413
92282353012
2016000533
SM
2320B
WET/42413
92282353013
2016000534
SM
2320B
WET/42413
92282353014
2016000536
SM
2320B
WET/42413
92282353001
2016000520
SM
4500-S2D
WET/42390
92282353002
2016000523
SM
4500-S2D
WET/42390
92282353003
2016000524
SM
4500-S2D
WET/42390
92282353004
2016000525
SM
4500-S2D
WET/42390
92282353005
2016000526
SM
4500-S2D
WET/42390
92282353006
2016000527
SM
4500-S2D
WET/42390
92282353007
2016000528
SM
4500-S2D
WET/42390
92282353008
2016000529
SM
4500-S2D
WET/42390
92282353009
2016000530
SM
4500-S2D
WET/42390
92282353010
2016000531
SM
4500-S2D
WET/42390
92282353011
2016000532
SM
4500-S2D
WET/42390
92282353012
2016000533
SM
4500-S2D
WET/42390
92282353013
2016000534
SM
4500-S2D
WET/42390
92282353014
2016000536
SM
4500-S2D
WET/42390
92282353001
2016000520
EPA 218.7
WETA/53663
92282353002
2016000523
EPA 218.7
WETA/53663
92282353003
2016000524
EPA 218.7
WETA/53663
92282353004
2016000525
EPA 218.7
WETA/53663
92282353005
2016000526
EPA 218.7
WETA/53663
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /14/2016 06:01 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 35

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oi�c yoe. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16010101
Pace Project No.: 92282353
Lab ID
Sample ID
QC Batch Method
QC Batch
92282353006
2016000527
EPA 218.7
WETA/53663
92282353007
2016000528
EPA 218.7
WETA/53703
92282353008
2016000529
EPA 218.7
WETA/53703
92282353009
2016000530
EPA 218.7
WETA/53703
92282353010
2016000531
EPA 218.7
WETA/53703
92282353011
2016000532
EPA 218.7
WETA/53703
92282353012
2016000533
EPA 218.7
WETA/53703
92282353013
2016000534
EPA 218.7
WETA/53703
92282353014
2016000536
EPA 218.7
WETA/53703
Date: 01/14/2016 06:01 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 33 of 35

Document Name:
Document Revised: 260CT2015
aeeAnalyticalo
Sample Condition Upon Receipt(SCUR)
Page i of 2
Document No.:
Issuing Authority: °
F•CHR-CS-003-rev.17
Pace Huntersville Quality Office
38
Courier:
❑Commercia[
Client Name: Project #:
3
❑F�Ex ❑UPS ❑LISPS ❑Client 111111111111111111�
❑Pace ❑Other: 929R91e' ��
Custody Seal on Cooler/Box Present?
Packing Material: ZZ
ble Wrap
Thermometer '
Used:
[]Yes No o Seals Intact? []Yes ❑No
f
❑Bubble Bags ❑None ❑other:
bamples on Ice, ceoling process has begun
Cooler Temp Corrected (TI.- Lr" BiologicalTissue'Frozen? ❑Yes:;;[]Na�- 'ON/a I
Temp should be above freezing to 6°C Correction Factor: 0.0 °C Bate and initials of Person Examining.Gohteants:�
USDA Regulated Soil (❑ N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate froga,fofeinsource{Internationally,
❑Yes ['fNo including Hawaii and Puerto RicC)? Des
If Yes to either question, fill out a Regulated Soil Checklist and Include with SCUR/CDC paperwork,
Type of Ice: ❑wet []Blue ❑None
COMMENTS:
Chain of Custody Present?
Ye
❑No
❑N/A
1.
Chain of Custody Filled Out?
Y
❑No
[I N/A
2.
Chain of Custody Relinquished?
f5yes
ONO
N/A
3.
Sampler Name and/or Signature on COC?
❑Yes
C3o
❑N/A
4.
Samples Arrived within Hold Time?
d es ❑No
❑N/A
5.
Short Hold Time Analysis (<72 hr)?
Yes
❑No
El N/A
6.
Rush Turn Around Time Requested?
[]Yes
'f:]
❑N/A
7.
Sufficient Volume?
[]Yes
:- []No
❑N/A
8.
Correct Containers Used?
[]Yes
❑No�EE]N/A
9.
-Pace Containers Used?
❑Yes
© 0
❑N/A
Containers Intact?
❑ es
❑No
[I N/A
10,
Filtered Volume Received for Dissolved Tests?
❑Yes _ -6No
❑N/A
11. Note if sediment invisible In the dissoivedcontainer
Sample Labels Match COC?
Ries
❑No
❑N/A
12.
-Includes Date/Time/ID/Analysis Matrix:- U,/
A!1 containers needing acid/base preservation have been
checked?
0 eY s
❑Na
❑N/A
13
All containers needing preservation are found to be In
compliance with EPA recommendation?
(HN0$, H2SO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide)
[]Yes
❑No
[]N/A
Exceptions: VOA, Coliform, TOC, Oil and Grease,
DRO/8015 (water) DOC,LLHg
El Yes
❑No
❑Lu% ,
Samples checked for dechlorization
[—]Yes
[]NO
❑iV//q.
14.
Headspace in VOA Vials (>5-6mm)?
❑Yes
[]No
❑NJ
15.
Trip Blank Present?
[]Yes❑No
❑Nf/A�
16.
Trip Blank Custody Seals Present?
❑Yes
❑No
❑N/A
Pace Trip Blank Lot # (if purchased):
CLIENT NOTIFICATION/RESOLUTION Field Data Required? ❑Yes []No
Person Contacted: Date/Time:
Comments/Resolution: !
Project Manager SCURF Review: Date: 1 1 f
Note: whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEWNR Certification Office (i.e. Out of
hold, incorrect preservative, out of temp, incorrect containers). Page 34 of 35

Page 67 of 68
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Page 3 of 35

CHAIN OF CUSTODY RECORD AND ANALYSIS__ REQUEST FORM
--------------------------------
Duke Energy
-Duke Energy Analytical Laboratory --i
i.-.---.------------------------- '------Anal -cal ------ -
Labor
Use -------------------------------------------
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68 of 68
! Analytical Laboratory
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Chain of Custody S
Mail CodeMG03A2 Building74051 !
13339Ha (Building
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Huntersvule, N. a 28078
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PROGRAM
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Fax: [phone]
Project Name Phone No:
AB GW Assessment water
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Ground WaterNPDES
Drinking Water _
UST _
` Phase 3 wells
F _•___. Cgoler7emg(Cj..........................................
RCRA
Waste
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Fax No:
980-875-5032
1 Pace Filtration (0.45 um)
PO
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Business Unit:
Prou Reep. Center To:
1142081 Preservative
Ice
Ice Ice
low
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H2SO4
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Activity to: Mail Coda: M
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container Volume(mL)
2000
40 ml 300
125
500
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PET
glass PET
PET
PET
PET
HDPE HDPE HDPE HDPE
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ELEMENTS
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d
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`Other
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by ICP (TRM): Al, Be, B, Fe, Mn, Sr, Zn
ICP_Undigested Ca, Mg, K, Na Hg by 245.1
m
_ASAP
'Add. Cost Will Apply
Dissolved metals : all metals ICP, IMS,Hg
U

DUKE Analytical Laboratory Page 1of33
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J16010140
MAYO STEAM - AB GW ASSESSMENT WATER
Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy Webb, John Toep
Anne Pifer
Anne Pifer
Phone:
Date:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
1 /20/2016
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2016000737
2016000738
2016000739
2016000740
4 Total Samples
Collected By
Sample Description
MAYO STEAM
O8-Jan-16 9:45 AM
Richard Jacobs
BG-2
MAYO STEAM
08-Jan-16 10:15 AM
Richard Jacobs
BG-1
MAYO STEAM
08-Jan-16
Richard Jacobs
Filter Blank 04
MAYO STEAM
O8-Jan-16
Richard Jacobs
Equipment Blank 04
Page 2 of 33

Page 3 of 33
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
OV Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Therona T James Date: 1/20/2016

Certificate of Laboratory Analysis Page 4 of 33
This report shall not be reproduced, except in full.
Order # J16010140
Site: BG-2
Collection Date: 08-Jan-16 9:45 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
33
mg/L
0.5
Sulfate
5.5
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.054
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.320
mg/L
0.01
Manganese (Mn)
0.172
mg/L
0.005
Strontium (Sr)
0.325
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
57.3
mg/L
0.01
Magnesium (Mg)
12.6
mg/L
0.005
Potassium (K)
3.40
mg/L
0.1
Sodium (Na)
50.6
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.080
mg/L
0.005
Barium (Ba)
0.058
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.471
mg/L
0.01
Manganese (Mn)
0.196
mg/L
0.005
Strontium (Sr)
0.350
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000737
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 12:34 LSTARL1
Vendor Method V_PACE
5 EPA 300.0
01/11/2016 14:53
BGN9034
1 EPA 300.0
01/11/2016 14:53
BGN9034
1 EPA 245.1
01/12/2016 13:26
ACPAYNE
1 EPA 245.1
01/13/2016 12:19
ACPAYNE
1 EPA 200.7
01/10/2016 15:21
FCJORDA
1 EPA 200.7
01/10/2016 15:21
FCJORDA
1 EPA 200.7
01/10/2016 15:21
FCJORDA
1 EPA 200.7
01/10/2016 15:21
FCJORDA
1 EPA 200.7
01/10/2016 15:21
FCJORDA
1 EPA 200.7
01/10/2016 15:21
FCJORDA
1 EPA 200.7
01/10/2016 15:21
FCJORDA
1 EPA 200.7
01/11/2016 17:46
FCJORDA
1 EPA 200.7
01/11/2016 17:46
FCJORDA
1 EPA 200.7
01/11/2016 17:46
FCJORDA
1 EPA 200.7
01/11/2016 17:46
FCJORDA
1 EPA 200.7
01/11/2016 10:35
MHH7131
1 EPA 200.7
01/11/2016 10:35
MHH7131
1 EPA 200.7
01/11/2016 10:35
MHH7131
1 EPA 200.7
01/11/2016 10:35
MHH7131
1 EPA 200.7
01/11/2016 10:35
MHH7131
1 EPA 200.7
01/11/2016 10:35
MHH7131
1 EPA 200.7
01/11/2016 10:35
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010140
Site: BG-2
Collection Date: 08-Jan-16 9:45 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
3.49
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
1.21
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
4.20
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
370
mg/L
25
Total Carbon
TOC
1.3
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 5 of 33
Sample #:
2016000737
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 19:10
SLS2560
1
EPA 200.8
01/10/2016 19:10
SLS2560
1
EPA 200.8
01/10/2016 19:10
SLS2560
1
EPA 200.8
01/10/2016 19:10
SLS2560
1
EPA 200.8
01/10/2016 19:10
SLS2560
1
EPA 200.8
01/10/2016 19:10
SLS2560
1
EPA 200.8
01/10/2016 19:10
SLS2560
1
EPA 200.8
01/10/2016 19:10
SLS2560
1
EPA 200.8
01/10/2016 19:10
SLS2560
1
EPA 200.8
01/10/2016 19:10
SLS2560
1
EPA 200.8
01/10/2016 19:10
SLS2560
1
EPA 200.8
01/10/2016 19:10
SLS2560
1
EPA 200.8
01/10/2016 19:10
SLS2560
1 EPA 200.8
01/10/2016 23:20
SLS2560
1 EPA 200.8
01/10/2016 23:20
SLS2560
1 EPA 200.8
01/10/2016 23:20
SLS2560
1 EPA 200.8
01/10/2016 23:20
SLS2560
1 EPA 200.8
01/10/2016 23:20
SLS2560
1 EPA 200.8
01/10/2016 23:20
SLS2560
1 EPA 200.8
01/10/2016 23:20
SLS2560
1 EPA 200.8
01/10/2016 23:20
SLS2560
1 EPA 200.8
01/10/2016 23:20
SLS2560
1 EPA 200.8
01/10/2016 23:20
SLS2560
1 EPA 200.8
01/10/2016 23:20
SLS2560
1 EPA 200.8
01/10/2016 23:20
SLS2560
1 EPA 200.8
01/10/2016 23:20
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/09/201615:30 CJELLIO
1 SM5310C/EPA9060A 01/12/201615:28 GHUTCHI
1 SM2540D 01/10/2016 08:30 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Page 6 of 33
Order # J16010140
Site: BG-2
Collection Date: 08-Jan-16 9:45 AM
Sample #: 2016000737
Matrix: GW WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010140
Site: BG-1
Collection Date: 08-Jan-16 10:15 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.643 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
12
mg/L
0.5
Sulfate
0.24
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.083
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.006
mg/L
0.005
Strontium (Sr)
0.161
mg/L
0.005
Zinc (Zn)
0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
12.6
mg/L
0.01
Magnesium (Mg)
3.36
mg/L
0.005
Potassium (K)
1.39
mg/L
0.1
Sodium (Na)
11.9
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.227
mg/L
0.005
Barium (Ba)
0.087
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.272
mg/L
0.01
Manganese (Mn)
0.011
mg/L
0.005
Strontium (Sr)
0.166
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2016000738
Matrix: GW WW
Page 7 of 33
DF Method Analysis Date/Time Analyst
Vendor Method V_PACE
1 EPA 353.2 01/10/2016 12:14 LSTARL1
Vendor Method V_PACE
5 EPA 300.0
01/11/2016 14:35
BGN9034
1 EPA 300.0
01/11/2016 14:35
BGN9034
1 EPA 245.1
01/12/2016 13:23
ACPAYNE
1 EPA 245.1
01/11/2016 16:41
ACPAYNE
1 EPA 200.7
01/10/2016 15:25
FCJORDA
1 EPA 200.7
01/10/2016 15:25
FCJORDA
1 EPA 200.7
01/10/2016 15:25
FCJORDA
1 EPA 200.7
01/10/2016 15:25
FCJORDA
1 EPA 200.7
01/10/2016 15:25
FCJORDA
1 EPA 200.7
01/10/2016 15:25
FCJORDA
1 EPA 200.7
01/10/2016 15:25
FCJORDA
1 EPA 200.7
01/11/2016 17:50
FCJORDA
1 EPA 200.7
01/11/2016 17:50
FCJORDA
1 EPA 200.7
01/11/2016 17:50
FCJORDA
1 EPA 200.7
01/11/2016 17:50
FCJORDA
1 EPA 200.7
01/11/2016 10:39
MHH7131
1 EPA 200.7
01/11/2016 10:39
MHH7131
1 EPA 200.7
01/11/2016 10:39
MHH7131
1 EPA 200.7
01/11/2016 10:39
MHH7131
1 EPA 200.7
01/11/2016 10:39
MHH7131
1 EPA 200.7
01/11/2016 10:39
MHH7131
1 EPA 200.7
01/11/2016 10:39
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010140
Site: BG-1
Collection Date: 08-Jan-16 10:15 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.28
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
3.08
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.24
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
3.94
ug/L
0.3
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
130
mg/L
25
Total Carbon
TOC
0.558
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 8 of 33
Sample #:
2016000738
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
01/10/2016 19:15
SLS2560
1
EPA 200.8
01/10/2016 19:15
SLS2560
1
EPA 200.8
01/10/2016 19:15
SLS2560
1
EPA 200.8
01/10/2016 19:15
SLS2560
1
EPA 200.8
01/10/2016 19:15
SLS2560
1
EPA 200.8
01/10/2016 19:15
SLS2560
1
EPA 200.8
01/10/2016 19:15
SLS2560
1
EPA 200.8
01/10/2016 19:15
SLS2560
1
EPA 200.8
01/10/2016 19:15
SLS2560
1
EPA 200.8
01/10/2016 19:15
SLS2560
1
EPA 200.8
01/10/2016 19:15
SLS2560
1
EPA 200.8
01/10/2016 19:15
SLS2560
1
EPA 200.8
01/10/2016 19:15
SLS2560
1 EPA 200.8
01/10/2016 23:24
SLS2560
1 EPA 200.8
01/10/2016 23:24
SLS2560
1 EPA 200.8
01/10/2016 23:24
SLS2560
1 EPA 200.8
01/10/2016 23:24
SLS2560
1 EPA 200.8
01/10/2016 23:24
SLS2560
1 EPA 200.8
01/10/2016 23:24
SLS2560
1 EPA 200.8
01/10/2016 23:24
SLS2560
1 EPA 200.8
01/10/2016 23:24
SLS2560
1 EPA 200.8
01/10/2016 23:24
SLS2560
1 EPA 200.8
01/10/2016 23:24
SLS2560
1 EPA 200.8
01/10/2016 23:24
SLS2560
1 EPA 200.8
01/10/2016 23:24
SLS2560
1 EPA 200.8
01/10/2016 23:24
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
1 SM2540C 01/09/201615:30 CJELLIO
1 SM5310C/EPA9060A 01/12/201615:28 GHUTCHI
1 SM2540D 01/10/2016 08:30 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Page 9 of 33
Order # J16010140
Site: BG-1
Collection Date: 08-Jan-16 10:15 AM
Sample #: 2016000738
Matrix: GW WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst

Certificate of Laboratory Analysis Page 10 of 33
This report shall not be reproduced, except in full.
Order # J16010140
Site: Filter Blank 04
Collection Date: 08-Jan-16
Analyte
Result
Units Qualifiers
RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2016000739
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
01/11/2016 16:44
ACPAYNE
1
EPA 200.7
01/10/2016 15:28
FCJORDA
1
EPA 200.7
01/10/2016 15:28
FCJORDA
1
EPA 200.7
01/10/2016 15:28
FCJORDA
1
EPA 200.7
01/10/2016 15:28
FCJORDA
1
EPA 200.7
01/10/2016 15:28
FCJORDA
1
EPA 200.7
01/10/2016 15:28
FCJORDA
1
EPA 200.7
01/10/2016 15:28
FCJORDA
1
EPA 200.8
01/10/2016 19:20
SLS2560
1
EPA 200.8
01/10/2016 19:20
SLS2560
1
EPA 200.8
01/10/2016 19:20
SLS2560
1
EPA 200.8
01/10/2016 19:20
SLS2560
1
EPA 200.8
01/10/2016 19:20
SLS2560
1
EPA 200.8
01/10/2016 19:20
SLS2560
1
EPA 200.8
01/10/2016 19:20
SLS2560
1
EPA 200.8
01/10/2016 19:20
SLS2560
1
EPA 200.8
01/10/2016 19:20
SLS2560
1
EPA 200.8
01/10/2016 19:20
SLS2560
1
EPA 200.8
01/10/2016 19:20
SLS2560
1
EPA 200.8
01/10/2016 19:20
SLS2560
1
EPA 200.8
01/10/2016 19:20
SLS2560

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010140
Site: Equipment Blank 04
Collection Date: 08-Jan-16
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
Calcium (Ca)
0.019
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Page 11 of 33
Sample #: 2016000740
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_PACE
1 EPA 353.2
01/10/2016 11:57
LSTARL1
Vendor Method
V_PACE
1 EPA 300.0
01/12/2016 08:34
BGN9034
1 EPA 300.0
01/12/2016 08:34
BGN9034
1 EPA 245.1
01/12/2016 13:21
ACPAYNE
1 EPA 200.7
01/11/2016 17:53
FCJORDA
1 EPA 200.7
01/11/2016 17:53
FCJORDA
1 EPA 200.7
01/11/2016 17:53
FCJORDA
1 EPA 200.7
01/11/2016 17:53
FCJORDA
1 EPA 200.7
01/11/2016 10:43
MHH7131
1 EPA 200.7
01/11/2016 10:43
MHH7131
1 EPA 200.7
01/11/2016 10:43
MHH7131
1 EPA 200.7
01/11/2016 10:43
MHH7131
1 EPA 200.7
01/11/2016 10:43
MHH7131
1 EPA 200.7
01/11/2016 10:43
MHH7131
1 EPA 200.7
01/11/2016 10:43
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010140
Site: Equipment Blank 04
Collection Date: 08-Jan-16
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
METHANE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
< 25
mg/L
25
1
Total Carbon
Page 12 of 33
Sample #:
2016000740
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
01/10/2016 23:29
SLS2560
EPA 200.8
01/10/2016 23:29
SLS2560
EPA 200.8
01/10/2016 23:29
SLS2560
EPA 200.8
01/10/2016 23:29
SLS2560
EPA 200.8
01/10/2016 23:29
SLS2560
EPA 200.8
01/10/2016 23:29
SLS2560
EPA 200.8
01/10/2016 23:29
SLS2560
EPA 200.8
01/10/2016 23:29
SLS2560
EPA 200.8
01/10/2016 23:29
SLS2560
EPA 200.8
01/10/2016 23:29
SLS2560
EPA 200.8
01/10/2016 23:29
SLS2560
EPA 200.8
01/10/2016 23:29
SLS2560
EPA 200.8
01/10/2016 23:29
SLS2560
Vendor Method V_PACE
Vendor Method V_PACE
SM2540C 01/09/201615:30 CJELLIO
TOC < 0.1 mg/L 0.1 1 SM5310C/EPA9060A 01/12/2016 15:28 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 01/10/2016 08:30 CJELLIO

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
�Q�ff�i�c&fie. Suite 100
y Huntersville, INC 28078
[phone]
January 19, 2016
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 16010140
Pace Project No.: 92282443
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 11, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Anne Pifer
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
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Project: J16010140
Pace Project No.: 92282443
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A21-A Certification M 2926.01
Alaska Certification M UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification M 88-0680
California Certification M 01155CA
Colorado Certification #Pace
Connecticut Certification M PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification M 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification M 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification M 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification M 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification M E83079
Georgia Certification M 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification M 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification M E-10383
Kentucky Certification #: 90050
Louisiana Certification M FL NELAC Reciprocity
Louisiana Environmental Certificate M 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification M Cert 0074
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification M TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification M 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE SUMMARY
Project: J16010140
Pace Project No.: 92282443
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92282443001
2016000737
Water
01/08/16 09:45
01/11/16 12:10
92282443002
2016000738
Water
01/08/1610:15
01/11/16 12:10
92282443003
2016000740
Water
01/08/16 00:00
01/11/16 12:10
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16010140
92282443
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92282443001
2016000737
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282443002
2016000738
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
92282443003
2016000740
RSK 175
DR1
1
PASI-M
SM 2320B
MLS
3
PASI-A
SM 4500-S2D
MJP
1
PASI-A
EPA 218.7
TK1
1
PASI-O
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Project: J16010140
Pace Project No.: 92282443
Lab Sample ID
Method
92282443001
RSK 175
SM 2320B
SM 2320B
92282443002
SM 2320B
SM 2320B
EPA 218.7
SUMMARY OF DETECTION
Client Sample ID
Parameters
2016000737
Methane
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
2016000738
Alkalinity, Bicarbonate (CaCO3)
Alkalinity, Total as CaCO3
Chromium, Hexavalent
Result Units
477 ug/L
263 mg/L
263 mg/L
51.1 mg/L
51.1 mg/L
0.20 ug/L
REPORT OF LABORATORY ANALYSIS
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Report Limit Analyzed Qualifiers
10.0 01/13/1610:48
5.0 01/13/16 01:15
5.0 01/13/16 01:15
5.0 01/13/16 01:30
5.0 01/13/16 01:30
0.030 01/12/1614:54
Page 5 of 20

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PROJECT NARRATIVE
Project: J16010140
Pace Project No.: 92282443
Method: RSK 175
Description: RSK 175 AIR Headspace
Client: Duke Energy
Date: January 19, 2016
General Information:
3 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16010140
Pace Project No.: 92282443
Method: SM 2320B
Description: 2320E Alkalinity
Client: Duke Energy
Date: January 19, 2016
General Information:
3 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16010140
Pace Project No.: 92282443
Method: SM 4500-S213
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: January 19, 2016
General Information:
3 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J16010140
Pace Project No.: 92282443
Method: EPA 218.7
Description: Hexavalent Chromium by IC
Client: Duke Energy
Date: January 19, 2016
General Information:
3 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16010140
Pace Project No.: 92282443
Sample: 2016000737
Lab ID: 92282443001 Collected:
01/08/16 09:45
Received: 01/11/16 12:10 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
477 ug/L
10.0
1
01/13/1610:48
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
263 mg/L
5.0
1
01/13/16 01:15
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/13/16 01:15
Alkalinity, Total as CaCO3
263 mg/L
5.0
1
01/13/16 01:15
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/12/1615:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/12/16 14:15
18540-29-9
Date: 01/19/2016 09:49 AM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16010140
Pace Project No.: 92282443
Sample: 2016000738
Lab ID: 92282443002 Collected:
01/08/16 10:15
Received: 01/11/16 12:10 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/13/1611:05
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
51.1 mg/L
5.0
1
01/13/16 01:30
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/13/16 01:30
Alkalinity, Total as CaCO3
51.1 mg/L
5.0
1
01/13/16 01:30
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/12/1615:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
0.20 ug/L
0.030
1
01/12/16 14:54
18540-29-9
Date: 01/19/2016 09:49 AM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J16010140
Pace Project No.: 92282443
Sample: 2016000740
Lab ID: 92282443003 Collected:
01/08/16 00:00
Received: 01/11/16 12:10 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Methane
ND ug/L
10.0
1
01/13/1611:13
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B
Alkalinity, Bicarbonate (CaCO3)
ND mg/L
5.0
1
01/13/16 01:41
Alkalinity, Carbonate (CaCO3)
ND mg/L
5.0
1
01/13/16 01:41
Alkalinity, Total as CaCO3
ND mg/L
5.0
1
01/13/16 01:41
4500S21) Sulfide Water
Analytical Method: SM 4500-S21D
Sulfide
ND mg/L
0.10
1
01/12/1615:00
18496-25-8
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
01/12/16 15:07
18540-29-9
Date: 01/19/2016 09:49 AM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J16010140
Pace Project No.: 92282443
QC Batch: AIR/25013
Analysis Method: RSK 175
QC Batch Method: RSK 175
Analysis Description: RSK 175 AIR HEADSPACE
Associated Lab Samples: 92282443001, 92282443002,
92282443003
METHOD BLANK: 2174179
Matrix: Water
Associated Lab Samples: 92282443001, 92282443002,
92282443003
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Methane
ug/L
ND 10.0
01/13/1610:33
LABORATORY CONTROL SAMPLE & LCSD:
2174180
2174181
Spike LCS LCSD
LCS LCSD
% Rec
Max
Parameter
Units
Conc. Result Result
% Rec % Rec
Limits RPD
RPD Qualifiers
Methane
ug/L
60.7 56.7 52.3
94 86
85-115
8 20
SAMPLE DUPLICATE: 2174638
92282551007 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Methane
ug/L
17.8 18.0
1
20
SAMPLE DUPLICATE: 2174639
92282443001 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Methane
ug/L
477 584
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J16010140
Pace Project No.: 92282443
QC Batch: WET/42417 Analysis Method: SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92282443001, 92282443002, 92282443003
METHOD BLANK: 1644957
Matrix: Water
Associated Lab Samples: 92282443001, 92282443002, 92282443003
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Alkalinity, Carbonate (CaCO3)
mg/L
ND 5.0
01/12/16 23:41
Alkalinity, Total as CaCO3
mg/L
ND 5.0
01/12/16 23:41
Alkalinity, Bicarbonate (CaCO3)
mg/L
ND 5.0
01/12/16 23:41
LABORATORY CONTROL SAMPLE: 1644958
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 49.0 98 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1644959 1644960
MS MSD
92282355024 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 49.4 50 50 99.5 99.0 100 99 80-120 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J16010140
Pace Project No.: 92282443
QC Batch: WET/42419 Analysis Method: SM 4500-S2D
QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92282443001, 92282443002, 92282443003
METHOD BLANK: 1645025 Matrix: Water
Associated Lab Samples: 92282443001, 92282443002, 92282443003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 01/12/1615:00
LABORATORY CONTROL SAMPLE: 1645026
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.51 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1645027 1645028
MS MSD
92282443001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND .5 .5 0.51 0.51 101 101 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J16010140
Pace Project No.: 92282443
QC Batch: WETA/53722
Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7
Analysis Description: Chromium,
Hexavalent IC
Associated Lab Samples: 92282443001, 92282443002,
92282443003
METHOD BLANK: 1445061
Matrix: Water
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chromium, Hexavalent ug/L
ND 0.030
01/12/16 13:49
LABORATORY CONTROL SAMPLE: 1445062
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chromium, Hexavalent ug/L
.075 0.072
96 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1445063 1445064
MS MSD
92282443001
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND
.075 .075 0.070
0.066 94 88 85-115 7 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
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QUALIFIERS
Project: J16010140
Pace Project No.: 92282443
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-M Pace Analytical Services - Minneapolis
PASI-O Pace Analytical Services - Ormond Beach
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Date: 01/19/2016 09:49 AM without the written consent of Pace Analytical Services, Inc.. Page 17 of 20

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098ni� yhe. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16010140
Pace Project No.: 92282443
Lab ID
Sample ID
QC Batch Method
QC Batch
92282443001
2016000737
RSK 175
AIR/25013
92282443002
2016000738
RSK 175
AIR/25013
92282443003
2016000740
RSK 175
AIR/25013
92282443001
2016000737
SM 2320B
WET/42417
92282443002
2016000738
SM 2320B
WET/42417
92282443003
2016000740
SM 2320B
WET/42417
92282443001
2016000737
SM 4500-S2D
WET/42419
92282443002
2016000738
SM 4500-S2D
WET/42419
92282443003
2016000740
SM 4500-S2D
WET/42419
92282443001
2016000737
EPA 218.7
WETA/53722
92282443002
2016000738
EPA 218.7
WETA/53722
92282443003
2016000740
EPA 218.7
WETA/53722
Date: 01/19/2016 09:49 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 18 of 20

aceAnalyr`ical@
Document Name:
Condition Upon Recei
Document No.: .
F-CH R-CS-003-rev.17
Document Revised: 26OCT201-5.
Pagel of 2
IssuingAuthotity: Page 3�1 of 33
Pace Huntersville Quality Office . II
j Client Name: Project #:
.0ti,- e--
Courier. []Fed ❑UPS USPS
® ❑Client
❑Commercial ace ❑other:
Custody Seal on Cooler/Box Present? []Yes [t6
WIN: ae2aaa
111111111111111111111111II
Seals Intact? ❑Yes o
—r
Packing Material: u ble Wrap ff8ubble Bags ❑None ❑Other:
Thermometer 15015
Used: Type of ice: et ❑glue []None amp]es on Ice, cooling process h s begun
Cooler Temp Corrected (°C): BlologlcaI Tissue Frozen?' Eyes
4..❑ 4 .= A ;
Temp should be ab�ee0 VC Correction Factor: 0.0 °C Date and Initials of Person Examining Contgnts C—
USDA Regulated Sater sample)
Did samples o igIne zone within the United States: CA, NY, or SC (check maps)? Did sarnples originate from] a fafeign source (internationally, f
❑Yes o Including Hawaii and Puerto RIO ? °° ❑Yes [ a
If Yes to either question, fill out a Regulated Soil Checklist and Include with SCUR/CDC paperwork,
COMMENTS:
Chain of Custody Present?
Yes No
[I N/A
1.
Chain of Custody Filled Out?
s ON
❑N/A
2.
Chain of Custody Relinquished?
Lis CI NO
❑N/A
S.
Sampler Name and/or Signature on COC?
❑No
❑N/A
4.
Samples Arrived within Hold Time?
MWel'[]
(I N/A
5.
Short Hold Time Analysis (<72 hr)?
,.,No
❑Yes mPIS—❑N/A
6,
Rush Turn Around Time Requested?
[]Yes &:. ❑N/A
7.
Sufficient Volume?
es ❑No
❑N/A
8.
Correct Containers Used?
es []No
[]NIA
9,
-Pace Containers Used?
es ❑No
❑N/A
Containers Intact?
No
10.
Filtered Volume Received for Dissolved Tests?
[]Yes❑No
,❑,,N/A
[§W11.
Note if sediment Isvlsible in the di55olvecfcontainer .
Sample Labels Match COC?
[IN0
[--]N/A
12.
-Includes Date/Time/ID/Analysis Matrix:
All containers needing acid/base preservation have been
checked?
[]Yes[]NO�Ift
�.�
13.
All containers needing preservation are found to be in
compliance with EPA recommendation?
(HNO3, H7,SO4, HCI<2, NaOH >9 Sulfide, NaOH>12 Cyanide)
❑Yes []No
tIN A
Exceptions: VOA, Coliform, TOC, Oil and Grease,
DRO/8015 (water) DOC,LLHg
[]Yes ❑No
A
Samples checked for dechlorization
[]Yes []No
A
14,
Headspace in VOA Vials (>5-6mm)?
Dyes dIN,
❑N/A
5,
Trip Blank Present?
Des [--]No
A
6.
Trip 81ank Custody Seals Present?
[]Yes []No
A
Pace Trip Blank Lot 4 (if purchased):
CLIENT NOTIFICATION/RESOLUTION Field ❑Yes ❑No
Person Contacted: Date/Time:
Comments/Resolution:
Project Manager SCURF Review:. to } Date:
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Off ce (i,e, put of
hold, Incorrect preservative, out of temp, Incorrect containers).
Page 19 of 20

_ _ _ _ CHAIN OF CUSTODY RECORD AND ANALYSIS
P ge o 0
__R_ REQUEST FORM
b._ ..._ _._.._._----------- ----- Duka Energy AnaiyGcai Ladorrtory - i--------._.._._..-------.--_._._.._._._._. l cal Latwrato Use Onl._._._._._,_._._._._._._._._.-...---.---.: - O
Ana
Duke Energy _ _ S nterra EDD
Analytical Laboratory M.itCo MGWA2(auIIdit7S05) !Order# `�/�� atrlx GW_WIN sm..o Wn.lnvr,a NC_ ! Page
t Y (V
)� t•]r 1737aHaganFerryRe ! ! / SCE- ° DISTRIBUTION a>
Chain of Custody S HueunW14. N. C. xeo7a
t7os7 E7sd2{S 1 eLoppatl �y Data 71 0 SAMPLE. PROGRAM ORIGINAL to LAB, COPY to CL1
i Sample Log i 1 1'n i
Fa%: ad e7_Aq:!a C..Kwrtd Water NPDE$ IL
F-J—Nurn AB GW Assessment water
Pl—No:
Client
Fat N.:
980-875-5032
Business Unit:
Procsa;
R—p, C�rTm
P'O.0 10:
S y~f 7A
M,n Cow:
MG03A3
Wa4rEotl�:
5411wr:
-ve DArsking Water_ UST_= +►S/*�wP%��4 `Se... I
' PacQ
.RCRA Waste iGX "(2212�R1 1 -
c .erTemesc�.._.._.
flltr.'J.n (.45 um)
Ice Ice Ic. -'- Ice
....................
PO 1142081 r r L
e
kN
L..._.._.._.._.-------- H25oa 1e•.ca w1aM
Container Volume (mL) 2000 40 ml 30o 127 Soo Soo 250 WO 500 500
Contalner Type PET glass PET PET PET PET HOPE HDPE HD PE HOPE
Sample Description or ID Customer to complete all eppropnatc
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non-shadedareas.
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ELEMENTS by ICP MS (TRM). As, Be, Cd, Co, Cr,
Cu. Mo, NI, Pb, Sb, Se, TI (LL), V (LL)
o
-Other
ELEMENTS by ICP (TRM)_ Al, Ba, B, Fe, Mn, Sr, 2n ICP_Undigested Ca, Mg, K. Na
Hg by 245-1
'Add. Cost Will Apply
Dissolved metals: all metals ICP, IMS,Hg
U

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FCIRM
"aEnewgyAmAIyjxaJt-mbaratary - i Amelvillc4i Labusl=
------------------- ----------- ---- ------------
Duke EJunq OFOV
Aq-iallytical L tft QW-ww NC--
VD30 -4g&k F.ir,
Chain or Custody iL Hwdwo11*. 4 r
S�mlplv Lag (7061 an 574r. SAMPLE P140GR4m
....... ........ ... JYmAj'!75 !p3s
Giowo walar NPOE-9
P"—1 r1-1 A8 C3W Ass.qs%menj water P4- "W
UST
P112149 3 ryn'l IS1 Pac'� Cooler Tona RCRA Vg�zfte
GhentZm
IOW41175,N32 ! P01142081 i Eh Unfiltered
--,- -
Business unit. FMP'4;*r#wT.; i
po Cpiii: L ------- —.— -------- HZ&04 k-A
;GD&A3 Ent-dMnW Volume (rnl�j Z009 Q FnI U* 14S :r— EEL, 1 1 $00 sw
C-amal r Type PET glass PET FF7 PET M7
SaMp* D4Svrlptfun or 1ID
CUOMO- r-, —rwfore aji ajxvcyxn m
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ripment Shank
1 1 2 1 1 1 1 11 1 1 1
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Page 33 of 33
plage-11-0-1-
SynterraEDD
DISTRIBUTION
ORIGINAi. [a I Afl.
fQPY;la CL
COC REV DATE 1122121)15
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HDPE
MbPF
HtW1f
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'14 D"s
of ieJTIrn0
7 Vgrys
z1W9
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me
"IeO.rack Opencai By DaWFIrne
r
E
48 Hr
ELEMENTS bY1CF�-40SITRMM! Aa,Rv, W. Co. Cr, Cu, Mo, Ni, Pb.Sra. Se. TI fl-L�, VIIQ
ELEMENTS by 1CP (TRIM), AJ, Ra. S. Fa, Mn, Sr, Z0 ICP Uncligrsiorl Ca, Mg, K- Na Hq by 246 1
Ekissolllefid 1116uls - RIJ metals. 1cP. Ius'"g
Add, Cwt %Mll Apply
ImEN
i In IGJ
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