NC0005363_App E Data Gap Results_20160701

,fa., CLUE ENERGYCertificate of Laboratory Analysis
Order ID
Weatherspoon: AB GW ASSESSMENT SOIL J16040066
Program Manager: Rodney Wike
Please contact the Program Manager, Rodney Wike, at 980-875-5186 with any questions regarding this report.
Sample Number: 2016009393 CCR-111SB 19'-21'
Collected Date: 03/31/2016 02:20 PM Collected By: JHG
Date Received:
04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
Sample Number: 2016009396 CCR-107SB 13'-15'
Collected Date: 03/30/2016 02:40 PM Collected By: JHG
Date Received:
04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
Sample Number: 2016009397 CCR-104SB 13'-15'
Collected Date: 03/30/2016 03:40 PM Collected By: JHG
Date Received:
04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
This report should not be reproduced, except in its entirety, without the written consent of Duke Energy Corporation. All results are reported on dry
weight unless otherwise noted. This report is not to be used for regulatory purposes. These results meet method requirements except where
noted with qualifiers or program comments.
Mail Code MG03A2 -- 13339 Hagers Ferry Road, Huntersville, NC 28078. -- Phone: [phone] Fax [phone]
Monday, 02 May 2016, 09:24 AM Page # 1 of 8

CLUE Certificate of Laboratory Analysis
" ENERGY
Weatherspoon: AB GW ASSESSMENT SOIL
Program Manager: Rodney Wike
Order ID
J16040066
Sample Number: 2016009397 CCR-104SB 13'-15'
Collected Date: 03/30/2016 03:40 PM Collected By: JHG Date Received: 04/05/16
Result: Units: Qualifier: RDL: Dilution: Method:
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete 1 V_PACE
Sample Number: 2016009398 CCR-109SB 18'-20'
Collected Date: 03/31/2016 02:40 PM Collected By: JHG
Result: Units: Qualifier:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Date Received: 04/05/16
RDL: Dilution: Method:
1 V_PACE
1 V_PACE
1 V_PACE
1 V_PACE
Sample Number: 2016009399 CCR-103SB 23'-25'
Collected Date: 03/29/2016 05:25 PM Collected By: JHG Date Received: 04/05/16
Result: Units: Qualifier:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample Number: 2016009400 CCR-103SB DUP 23'-25'
Collected Date: 03/29/2016 05:25 PM Collected By: JHG
Result: Units: Qualifier:
PERCENT SOLIDS - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
RDL: Dilution: Method:
1 V_PACE
1 V_PACE
1 V_PACE
1 V_PACE
Date Received: 04/05/16
RDL: Dilution: Method:
1 V_PACE
This report should not be reproduced, except in its entirety, without the written consent of Duke Energy Corporation. All results are reported on dry
weight unless otherwise noted. This report is not to be used for regulatory purposes. These results meet method requirements except where
noted with qualifiers or program comments.
Mail Code MG03A2 -- 13339 Hagers Ferry Road, Huntersville, NC 28078. -- Phone: [phone] Fax [phone]
Monday, 02 May 2016, 09:24 AM Page # 2 of 8

CAE ENERGYCertificate of Laboratory Analysis
Order ID
Weatherspoon: AB GW ASSESSMENT SOIL
J16040066
Program Manager: Rodney Wike
Sample Number: 2016009400 CCR-103SB DUP 23'-25'
Collected Date: 03/29/2016 05:25 PM Collected By: JHG
Date Received: 04/05/16
Result: Units: Qualifier: RDL:
Dilution: Method:
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1 V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1 V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1 V_PACE
Sample Number: 2016009401 CCR-102SB 14'-16'
Collected Date: 03/30/2016 10:25 AM Collected By: JHG
Date Received: 04/05/16
Result: Units: Qualifier: RDL: Dilution: Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete 1 V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete 1 V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete 1 V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete 1 V_PACE
Sample Number: 2016009402 CCR-105SB 13'-15'
Collected Date: 03/31/2016 11:05 AM Collected By: JHG
Date Received:
04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
This report should not be reproduced, except in its entirety, without the written consent of Duke Energy Corporation. All results are reported on dry
weight unless otherwise noted. This report is not to be used for regulatory purposes. These results meet method requirements except where
noted with qualifiers or program comments.
Mail Code MG03A2 -- 13339 Hagers Ferry Road, Huntersville, NC 28078. -- Phone: [phone] Fax [phone]
Monday, 02 May 2016, 09:24 AM Page # 3 of 8

CAE ENERGYCertificate of Laboratory Analysis
Order ID
Weatherspoon: AB GW ASSESSMENT SOIL J16040066
Program Manager: Rodney Wike
Sample Number: 2016009403 CCR-106SB 13'-15'
Collected Date: 03/30/2016 11:40 AM Collected By: JHG Date Received: 04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
Sample Number: 2016009404 CCR-110SB 19'-21'
Collected Date: 03/31/2016 10:25 AM Collected By: JHG
Date Received:
04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
Sample Number: 2016009409 CCR-104 Eq. Blank
Collected Date: 03/30/2016 02:50 PM Collected By: JHG
Date Received:
04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
This report should not be reproduced, except in its entirety, without the written consent of Duke Energy Corporation. All results are reported on dry
weight unless otherwise noted. This report is not to be used for regulatory purposes. These results meet method requirements except where
noted with qualifiers or program comments.
Mail Code MG03A2 -- 13339 Hagers Ferry Road, Huntersville, NC 28078. -- Phone: [phone] Fax [phone]
Monday, 02 May 2016, 09:24 AM Page # 4 of 8

CAE ENERGYCertificate of Laboratory Analysis
Order ID
Weatherspoon: AB GW ASSESSMENT SOIL J16040066
Program Manager: Rodney Wike
Sample Number: 2016009410 CCR-110 Eq. Blank
Collected Date: 03/31/2016 09:40 AM Collected By: JHG Date Received: 04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
Sample Number: 2016009411 Eq. Blank (Drill)
Collected Date: 03/29/2016 03:45 PM Collected By: JHG
Date Received:
04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
Sample Number: 2016009412 CCR-105 Eq. Blank
Collected Date: 03/30/2016 07:40 AM Collected By: JHG
Date Received:
04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
This report should not be reproduced, except in its entirety, without the written consent of Duke Energy Corporation. All results are reported on dry
weight unless otherwise noted. This report is not to be used for regulatory purposes. These results meet method requirements except where
noted with qualifiers or program comments.
Mail Code MG03A2 -- 13339 Hagers Ferry Road, Huntersville, NC 28078. -- Phone: [phone] Fax [phone]
Monday, 02 May 2016, 09:24 AM Page # 5 of 8

CAE ENERGYCertificate of Laboratory Analysis
Order ID
Weatherspoon: AB GW ASSESSMENT SOIL J16040066
Program Manager: Rodney Wike
Sample Number: 2016009413 Eq. Blank (Dril 2)
Collected Date: 03/30/2016 09:50 AM Collected By: JHG Date Received: 04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
Sample Number: 2016009414 CCR-109 Eq. Blank
Collected Date: 03/31/2016 01:15 PM Collected By: JHG
Date Received:
04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
Sample Number: 2016009415 CCR-106 Eq. Blank
Collected Date: 03/30/2016 09:55 AM Collected By: JHG
Date Received:
04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
This report should not be reproduced, except in its entirety, without the written consent of Duke Energy Corporation. All results are reported on dry
weight unless otherwise noted. This report is not to be used for regulatory purposes. These results meet method requirements except where
noted with qualifiers or program comments.
Mail Code MG03A2 -- 13339 Hagers Ferry Road, Huntersville, NC 28078. -- Phone: [phone] Fax [phone]
Monday, 02 May 2016, 09:24 AM Page # 6 of 8

CAE ENERGYCertificate of Laboratory Analysis
Order ID
Weatherspoon: AB GW ASSESSMENT SOIL
J16040066
Program Manager: Rodney Wike
Sample Number: 2016009416 CCR-111 Eq. Blank
Collected Date: 03/31/2016 01:31 PM Collected By: JHG
Date Received: 04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
Sample Number: 2016009417 CCR-107 Eq. Blank
Collected Date: 03/30/2016 01:53 PM Collected By: JHG
Date Received:
04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
Sample Number: 2016009418 Potable Water #1
Collected Date: 03/29/2016 03:45 PM Collected By: JHG
Date Received:
04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
This report should not be reproduced, except in its entirety, without the written consent of Duke Energy Corporation. All results are reported on dry
weight unless otherwise noted. This report is not to be used for regulatory purposes. These results meet method requirements except where
noted with qualifiers or program comments.
Mail Code MG03A2 -- 13339 Hagers Ferry Road, Huntersville, NC 28078. -- Phone: [phone] Fax [phone]
Monday, 02 May 2016, 09:24 AM Page # 7 of 8

CLUE Certificate of Laboratory Analysis
"
ENERGY
Order ID
Weatherspoon: AB GW ASSESSMENT SOIL
J16040066
Program Manager: Rodney Wike
Sample Number: 2016009419 Potable Water #2
Collected Date: 03/30/2016 10:20 AM Collected By: JHG
Date Received:
04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
Sample Number: 2016009420 Potable Water #3
Collected Date: 03/31/2016 01:35 PM Collected By: JHG
Date Received:
04/05/16
Result: Units: Qualifier: RDL:
Dilution:
Method:
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
1
V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete 1 V_PACE
Program Manager: Rodney Wike Report Authorized By:
980-875-5186 (Signature) qI, .
An EDD has been included with this report. 7
This report should not be reproduced, except in its entirety, without the written consent of Duke Energy Corporation. All results are reported on dry
weight unless otherwise noted. This report is not to be used for regulatory purposes. These results meet method requirements except where
noted with qualifiers or program comments.
Mail Code MG03A2 -- 13339 Hagers Ferry Road, Huntersville, NC 28078. -- Phone: [phone] Fax [phone]
Monday, 02 May 2016, 09:24 AM Page # 8 of 8

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, INC 28078
[phone]
April 20, 2016
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 16040066
Pace Project No.: 92292703
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 06, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Rodney Wilke, Duke Energy
pie p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
A
Page 1 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: J16040066
Pace Project No.: 92292703
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification M PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 2 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J16040066
Pace Project No.: 92292703
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92292703001
2016009393
Solid
03/31/1614:20
04/06/16 13:25
92292703002
2016009396
Solid
03/30/1614:46
04/06/16 13:25
92292703003
2016009397
Solid
03/30/1615:40
04/06/16 13:25
92292703004
2016009398
Solid
03/31/1614:40
04/06/16 13:25
92292703005
2016009399
Solid
03/29/1617:25
04/06/16 13:25
92292703006
2016009400
Solid
03/29/1617:25
04/06/16 13:25
92292703007
2016009401
Solid
03/30/1610:25
04/06/16 13:25
92292703008
2016009402
Solid
03/31/1611:05
04/06/16 13:25
92292703009
2016009403
Solid
03/30/1611:40
04/06/16 13:25
92292703010
2016009404
Solid
03/31/1610:25
04/06/16 13:25
92292703011
2016009409
Water
03/30/1614:50
04/06/16 13:25
92292703012
2016009410
Water
03/31/16 09:40
04/06/16 13:25
92292703013
2016009411
Water
03/29/1615:45
04/06/16 13:25
92292703014
2016009412
Water
03/30/16 07:40
04/06/16 13:25
92292703015
2016009413
Water
03/30/16 09:50
04/06/16 13:25
92292703016
2016009414
Water
03/31/1613:15
04/06/16 13:25
92292703017
2016009415
Water
03/30/16 09:55
04/06/16 13:25
92292703018
2016009416
Water
03/31/1613:31
04/06/16 13:25
92292703019
2016009417
Water
03/30/1613:53
04/06/16 13:25
92292703020
2016009418
Water
03/29/1615:45
04/06/16 13:25
92292703021
2016009419
Water
03/30/1610:20
04/06/16 13:25
92292703022
2016009420
Water
03/31/1613:25
04/06/16 13:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 3 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16040066
92292703
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92292703001
2016009393
EPA 6010
MEW
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
MEW
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
92292703002
2016009396
EPA 6010
MEW
16
PASI-0
EPA 6020
CKJ, DRS
8
PASI-O
EPA 7471
MEW
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
92292703003
2016009397
EPA 6010
MEW
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
MEW
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
92292703004
2016009398
EPA 6010
MEW
16
PASI-0
EPA 6020
CKJ, DRS
8
PASI-O
EPA 7471
MEW
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
92292703005
2016009399
EPA 6010
MEW
16
PASI-0
EPA 6020
CKJ, DRS
8
PASI-O
EPA 7471
MEW
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
92292703006
2016009400
EPA 6010
MEW
16
PASI-0
EPA 6020
CKJ, DRS
8
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 4 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J16040066
92292703
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 7471
MEW
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
92292703007
2016009401
EPA 6010
MEW
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
MEW
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
92292703008
2016009402
EPA 6010
MEW
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
MEW
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
92292703009
2016009403
EPA 6010
MEW
16
PASI-0
EPA 6020
CKJ, DRS
8
PASI-O
EPA 7471
MEW
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
92292703010
2016009404
EPA 6010
MEW
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
MEW
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
92292703011
2016009409
EPA 6010
CDF
13
PASI-A
EPA 6020E
JMW
11
PASI-A
EPA 7470
HVK
1
PASI-A
92292703012
2016009410
EPA 6010
CDF
13
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 5 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
J16040066
Pace Project No.:
92292703
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 6020E
JMW
11
PASI-A
EPA 7470
HVK
1
PASI-A
92292703013
2016009411
EPA 6010
CDF
13
PASI-A
EPA 6020E
JMW
11
PASI-A
EPA 7470
HVK
1
PASI-A
92292703014
2016009412
EPA 6010
CDF
13
PASI-A
EPA 6020E
JMW
11
PASI-A
EPA 7470
HVK
1
PASI-A
92292703015
2016009413
EPA 6010
CDF
13
PASI-A
EPA 6020E
JMW
11
PASI-A
EPA 7470
HVK
1
PASI-A
92292703016
2016009414
EPA 6010
CDF
13
PASI-A
EPA 6020E
JMW
11
PASI-A
EPA 7470
HVK
1
PASI-A
92292703017
2016009415
EPA 6010
CDF
13
PASI-A
EPA 6020E
JMW
11
PASI-A
EPA 7470
HVK
1
PASI-A
92292703018
2016009416
EPA 6010
CDF
13
PASI-A
EPA 6020E
JMW
11
PASI-A
EPA 7470
HVK
1
PASI-A
92292703019
2016009417
EPA 6010
CDF
13
PASI-A
EPA 6020E
JMW
11
PASI-A
EPA 7470
HVK
1
PASI-A
92292703020
2016009418
EPA 6010
CDF
13
PASI-A
EPA 6020E
JMW
11
PASI-A
EPA 7470
HVK
1
PASI-A
92292703021
2016009419
EPA 6010
CDF
13
PASI-A
EPA 6020E
JMW
11
PASI-A
EPA 7470
HVK
1
PASI-A
92292703022
2016009420
EPA 6010
CDF
13
PASI-A
EPA 6020E
JMW
11
PASI-A
EPA 7470
HVK
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 6 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J16040066
92292703
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92292703001
2016009393
EPA 6010
Aluminum
5970
mg/kg
7.1
04/13/16 06:45
M1,R1
EPA 6010
Barium
37.2
mg/kg
0.71
04/13/16 06:45
EPA 6010
Beryllium
0.44
mg/kg
0.071
04/13/16 06:45
M1
EPA 6010
Boron
4.6
mg/kg
3.5
04/13/16 06:45
M1
EPA 6010
Calcium
190000
mg/kg
354
04/13/16 08:18
M6
EPA 6010
Chromium
19.8
mg/kg
0.35
04/13/16 06:45
M1
EPA 6010
Copper
4.4
mg/kg
0.35
04/13/16 06:45
EPA 6010
Iron
9460
mg/kg
2.8
04/13/16 06:45
M1,R1
EPA 6010
Magnesium
1810
mg/kg
35.4
04/13/16 06:45
M1,R1
EPA 6010
Manganese
109
mg/kg
0.35
04/13/16 06:45
M1
EPA 6010
Molybdenum
6.6
mg/kg
0.71
04/13/16 06:45
M1
EPA 6010
Nickel
4.2
mg/kg
0.35
04/13/16 06:45
M1
EPA 6010
Potassium
594
mg/kg
70.7
04/13/16 06:45
R1
EPA 6010
Sodium
1620
mg/kg
70.7
04/13/16 06:45
EPA 6010
Strontium
1030
mg/kg
7.1
04/13/16 08:18
M6
EPA 6010
Zinc
16.9
mg/kg
1.4
04/13/16 06:45
EPA 6020
Arsenic
10.7
mg/kg
1.4
04/13/16 03:07
EPA 6020
Cobalt
2.4
mg/kg
1.4
04/13/16 03:07
EPA 6020
Lead
3.7
mg/kg
1.4
04/13/16 03:07
EPA 6020
Vanadium
17.3
mg/kg
1.4
04/13/16 03:07
ASTM D2974-87
Percent Moisture
31.3
%
0.10
04/12/16 15:15
EPA 9045
pH at 25 Degrees C
8.7
Std. Units
0.10
04/08/16 15:40
H6
92292703002
2016009396
EPA 6010
Aluminum
7830
mg/kg
6.3
04/13/16 07:09
EPA 6010
Barium
18.1
mg/kg
0.63
04/13/16 07:09
EPA 6010
Beryllium
0.37
mg/kg
0.063
04/13/16 07:09
EPA 6010
Boron
1.91
mg/kg
3.2
04/13/16 07:09
EPA 6010
Calcium
562
mg/kg
31.6
04/13/16 07:09
EPA 6010
Chromium
17.6
mg/kg
0.32
04/13/16 07:09
EPA 6010
Copper
3.1
mg/kg
0.32
04/13/16 07:09
EPA 6010
Iron
8200
mg/kg
2.5
04/13/16 07:09
EPA 6010
Magnesium
201
mg/kg
31.6
04/13/16 07:09
EPA 6010
Manganese
24.0
mg/kg
0.32
04/13/16 07:09
EPA 6010
Molybdenum
0.66
mg/kg
0.63
04/13/16 07:09
EPA 6010
Nickel
2.9
mg/kg
0.32
04/13/16 07:09
EPA 6010
Potassium
179
mg/kg
63.2
04/13/16 07:09
EPA 6010
Strontium
11.2
mg/kg
0.63
04/13/16 07:09
EPA 6010
Zinc
2.8
mg/kg
1.3
04/13/16 07:09
EPA 6020
Arsenic
3.2
mg/kg
1.3
04/13/16 03:10
EPA 6020
Lead
4.0
mg/kg
1.3
04/13/16 03:10
EPA 6020
Selenium
1.7J
mg/kg
3.2
04/13/16 13:46
EPA 6020
Vanadium
34.8
mg/kg
3.2
04/13/16 13:46
ASTM D2974-87
Percent Moisture
23.3
%
0.10
04/12/16 15:15
EPA 9045
pH at 25 Degrees C
6.0
Std. Units
0.10
04/08/16 15:40
H6
92292703003
2016009397
EPA 6010
Aluminum
8970
mg/kg
6.4
04/13/16 07:13
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: J16040066
Pace Project No.: 92292703
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92292703003
2016009397
EPA 6010
Barium
16.0
mg/kg
0.64
04/13/16 07:13
EPA 6010
Beryllium
0.33
mg/kg
0.064
04/13/16 07:13
EPA 6010
Calcium
791
mg/kg
31.9
04/13/16 07:13
EPA 6010
Chromium
16.4
mg/kg
0.32
04/13/16 07:13
EPA 6010
Copper
5.5
mg/kg
0.32
04/13/16 07:13
EPA 6010
Iron
11100
mg/kg
2.6
04/13/16 07:13
EPA 6010
Magnesium
335
mg/kg
31.9
04/13/16 07:13
EPA 6010
Manganese
36.8
mg/kg
0.32
04/13/16 07:13
EPA 6010
Molybdenum
5.7
mg/kg
0.64
04/13/16 07:13
EPA 6010
Nickel
9.4
mg/kg
0.32
04/13/16 07:13
EPA 6010
Potassium
356
mg/kg
63.9
04/13/16 07:13
EPA 6010
Strontium
7.4
mg/kg
0.64
04/13/16 07:13
EPA 6010
Zinc
16.0
mg/kg
1.3
04/13/16 07:13
EPA 6020
Arsenic
13.7
mg/kg
1.3
04/13/16 03:13
EPA 6020
Cadmium
0.36
mg/kg
0.15
04/13/16 03:13
EPA 6020
Cobalt
11.4
mg/kg
1.3
04/13/16 03:13
EPA 6020
Lead
7.8
mg/kg
1.3
04/13/16 03:13
EPA 6020
Selenium
1.6
mg/kg
1.3
04/13/16 03:13
EPA 6020
Vanadium
19.6
mg/kg
1.3
04/13/16 03:13
EPA 7471
Mercury
0.0085J
mg/kg
0.011
04/13/16 17:11
ASTM D2974-87
Percent Moisture
22.9
%
0.10
04/12/16 15:15
EPA 9045
pH at 25 Degrees C
7.5
Std. Units
0.10
04/08/16 15:40 H6
92292703004
2016009398
EPA 6010
Aluminum
2120
mg/kg
6.2
04/13/16 07:17
EPA 6010
Barium
36.3
mg/kg
0.62
04/13/16 07:17
EPA 6010
Beryllium
0.27
mg/kg
0.062
04/13/16 07:17
EPA 6010
Boron
6.9
mg/kg
3.1
04/13/16 07:17
EPA 6010
Calcium
281000
mg/kg
620
04/13/16 08:42
EPA 6010
Chromium
13.5
mg/kg
0.31
04/13/16 07:17
EPA 6010
Copper
1.8
mg/kg
0.31
04/13/16 07:17
EPA 6010
Iron
5280
mg/kg
2.5
04/13/16 07:17
EPA 6010
Magnesium
1360
mg/kg
31.0
04/13/16 07:17
EPA 6010
Manganese
57.3
mg/kg
0.31
04/13/16 07:17
EPA 6010
Molybdenum
2.9
mg/kg
0.62
04/13/16 07:17
EPA 6010
Nickel
1.7
mg/kg
0.31
04/13/16 07:17
EPA 6010
Potassium
272
mg/kg
62.0
04/13/16 07:17
EPA 6010
Sodium
2430
mg/kg
62.0
04/13/16 07:17
EPA 6010
Strontium
1400
mg/kg
12.4
04/13/16 08:42
EPA 6010
Zinc
7.0
mg/kg
1.2
04/13/16 07:17
EPA 6020
Arsenic
10.1
mg/kg
1.2
04/13/16 03:17
EPA 6020
Lead
1.7
mg/kg
1.2
04/13/16 03:17
EPA 6020
Vanadium
15.0
mg/kg
3.1
04/13/16 13:50
ASTM D2974-87
Percent Moisture
19.0
%
0.10
04/12/16 15:16
EPA 9045
pH at 25 Degrees C
8.0
Std. Units
0.10
04/08/16 15:40 H6
EPA 9056
Sulfate
205J
mg/kg
309
04/09/16 16:10 D3
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: J16040066
Pace Project No.: 92292703
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92292703005
2016009399
EPA 6010
Aluminum
8690
mg/kg
63.4
04/13/16 16:25
EPA 6010
Barium
10.3
mg/kg
6.3
04/13/16 16:25
EPA 6010
Beryllium
0.70
mg/kg
0.63
04/13/16 16:25
EPA 6010
Calcium
740
mg/kg
317
04/13/16 16:25
EPA 6010
Chromium
33.0
mg/kg
3.2
04/13/16 16:25
EPA 6010
Copper
7.2
mg/kg
3.2
04/13/16 16:25
EPA 6010
Iron
20800
mg/kg
25.4
04/13/16 16:25
EPA 6010
Magnesium
537
mg/kg
317
04/13/16 16:25
EPA 6010
Manganese
67.1
mg/kg
3.2
04/13/16 16:25
EPA 6010
Molybdenum
10.6
mg/kg
6.3
04/13/16 16:25
EPA 6010
Nickel
10.1
mg/kg
3.2
04/13/16 16:25
EPA 6010
Potassium
439J
mg/kg
634
04/13/16 16:25
EPA 6010
Strontium
7.6
mg/kg
6.3
04/13/16 16:25
EPA 6010
Zinc
24.9
mg/kg
12.7
04/13/16 16:25
EPA 6020
Arsenic
17.0
mg/kg
1.3
04/13/16 03:20
EPA 6020
Cadmium
0.45
mg/kg
0.38
04/13/16 13:53
EPA 6020
Cobalt
5.9
mg/kg
3.2
04/13/16 13:53
EPA 6020
Lead
7.8
mg/kg
1.3
04/13/16 03:20
EPA 6020
Selenium
3.7
mg/kg
3.2
04/13/16 13:53
EPA 6020
Vanadium
31.8
mg/kg
3.2
04/13/16 13:53
EPA 7471
Mercury
0.011
mg/kg
0.011
04/13/16 17:16
ASTM D2974-87
Percent Moisture
22.5
%
0.10
04/12/16 15:16
EPA 9045
pH at 25 Degrees C
5.5
Std. Units
0.10
04/08/16 15:40 H6
92292703006
2016009400
EPA 6010
Aluminum
9030
mg/kg
66.8
04/13/16 16:29
EPA 6010
Barium
10.8
mg/kg
6.7
04/13/16 16:29
EPA 6010
Beryllium
0.62J
mg/kg
0.67
04/13/16 16:29
EPA 6010
Calcium
568
mg/kg
334
04/13/16 16:29
EPA 6010
Chromium
29.7
mg/kg
3.3
04/13/16 16:29
EPA 6010
Copper
8.6
mg/kg
3.3
04/13/16 16:29
EPA 6010
Iron
13100
mg/kg
26.7
04/13/16 16:29
EPA 6010
Magnesium
385
mg/kg
334
04/13/16 16:29
EPA 6010
Manganese
30.8
mg/kg
3.3
04/13/16 16:29
EPA 6010
Nickel
10.8
mg/kg
3.3
04/13/16 16:29
EPA 6010
Potassium
458J
mg/kg
668
04/13/16 16:29
EPA 6010
Strontium
6.9
mg/kg
6.7
04/13/16 16:29
EPA 6010
Zinc
26.8
mg/kg
13.4
04/13/16 16:29
EPA 6020
Arsenic
12.8
mg/kg
1.3
04/13/16 03:23
EPA 6020
Cadmium
0.42
mg/kg
0.40
04/13/16 13:56
EPA 6020
Cobalt
5.2
mg/kg
3.3
04/13/16 13:56
EPA 6020
Lead
9.5
mg/kg
1.3
04/13/16 03:23
EPA 6020
Selenium
2.9J
mg/kg
3.3
04/13/16 13:56
EPA 6020
Vanadium
24.2
mg/kg
3.3
04/13/16 13:56
EPA 7471
Mercury
0.011
mg/kg
0.010
04/13/16 17:18
ASTM D2974-87
Percent Moisture
21.2
%
0.10
04/12/16 15:16
EPA 9045
pH at 25 Degrees C
5.0
Std. Units
0.10
04/08/16 15:40 H6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: J16040066
Pace Project No.: 92292703
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92292703007
2016009401
EPA 6010
Aluminum
5910
mg/kg
6.4
04/13/16 07:29
EPA 6010
Barium
9.4
mg/kg
0.64
04/13/16 07:29
EPA 6010
Beryllium
0.077
mg/kg
0.064
04/13/16 07:29
EPA 6010
Calcium
89.2
mg/kg
32.0
04/13/16 07:29
EPA 6010
Chromium
4.7
mg/kg
0.32
04/13/16 07:29
EPA 6010
Copper
1.7
mg/kg
0.32
04/13/16 07:29
EPA 6010
Iron
966
mg/kg
2.6
04/13/16 07:29
EPA 6010
Magnesium
90.4
mg/kg
32.0
04/13/16 07:29
EPA 6010
Manganese
4.3
mg/kg
0.32
04/13/16 07:29
EPA 6010
Nickel
5.5
mg/kg
0.32
04/13/16 07:29
EPA 6010
Potassium
82.7
mg/kg
64.0
04/13/16 07:29
EPA 6010
Strontium
6.7
mg/kg
0.64
04/13/16 07:29
EPA 6010
Zinc
1.2J
mg/kg
1.3
04/13/16 07:29
EPA 6020
Arsenic
0.93J
mg/kg
1.3
04/13/16 03:27
EPA 6020
Lead
3.2
mg/kg
1.3
04/13/16 03:27
EPA 6020
Vanadium
3.6
mg/kg
1.3
04/13/16 03:27
EPA 7471
Mercury
0.0086J
mg/kg
0.010
04/13/16 17:24
ASTM D2974-87
Percent Moisture
17.8
%
0.10
04/12/16 15:16
EPA 9045
pH at 25 Degrees C
5.5
Std. Units
0.10
04/08/16 15:40
EPA 9056
Sulfate
152J
mg/kg
302
04/09/16 17:57
92292703008
2016009402
EPA 6010
Aluminum
13400
mg/kg
6.3
04/13/16 07:34
EPA 6010
Barium
8.6
mg/kg
0.63
04/13/16 07:34
EPA 6010
Beryllium
0.11
mg/kg
0.063
04/13/16 07:34
EPA 6010
Calcium
75.6
mg/kg
31.5
04/13/16 07:34
EPA 6010
Chromium
12.4
mg/kg
0.32
04/13/16 07:34
EPA 6010
Copper
1.1
mg/kg
0.32
04/13/16 07:34
EPA 6010
Iron
1250
mg/kg
2.5
04/13/16 07:34
EPA 6010
Magnesium
168
mg/kg
31.5
04/13/16 07:34
EPA 6010
Manganese
6.1
mg/kg
0.32
04/13/16 07:34
EPA 6010
Molybdenum
0.58J
mg/kg
0.63
04/13/16 07:34
EPA 6010
Nickel
3.5
mg/kg
0.32
04/13/16 07:34
EPA 6010
Potassium
137
mg/kg
63.1
04/13/16 07:34
EPA 6010
Strontium
3.1
mg/kg
0.63
04/13/16 07:34
EPA 6010
Zinc
2.7
mg/kg
1.3
04/13/16 07:34
EPA 6020
Cobalt
0.68J
mg/kg
1.3
04/13/16 03:30
EPA 6020
Lead
8.2
mg/kg
1.3
04/13/16 03:30
EPA 6020
Vanadium
18.1
mg/kg
1.3
04/13/16 03:30
EPA 7471
Mercury
0.011
mg/kg
0.0097
04/13/16 17:26
ASTM D2974-87
Percent Moisture
18.9
%
0.10
04/12/16 15:16
EPA 9045
pH at 25 Degrees C
4.9
Std. Units
0.10
04/08/16 15:40
92292703009
2016009403
EPA 6010
Aluminum
9200
mg/kg
62.8
04/13/16 16:33
EPA 6010
Barium
59.4
mg/kg
6.3
04/13/16 16:33
EPA 6010
Beryllium
1.8
mg/kg
0.63
04/13/16 16:33
EPA 6010
Calcium
2180
mg/kg
314
04/13/16 16:33
REPORT OF LABORATORY ANALYSIS
H6
D3
1:19,
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: J16040066
Pace Project No.: 92292703
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92292703009
2016009403
EPA 6010
Chromium
25.9
mg/kg
3.1
04/13/16 16:33
EPA 6010
Copper
8.3
mg/kg
3.1
04/13/16 16:33
EPA 6010
Iron
8940
mg/kg
25.1
04/13/16 16:33
EPA 6010
Magnesium
486
mg/kg
314
04/13/16 16:33
EPA 6010
Manganese
44.5
mg/kg
3.1
04/13/16 16:33
EPA 6010
Molybdenum
3.5J
mg/kg
6.3
04/13/16 16:33
EPA 6010
Nickel
12.4
mg/kg
3.1
04/13/16 16:33
EPA 6010
Potassium
375J
mg/kg
628
04/13/16 16:33
EPA 6010
Strontium
23.4
mg/kg
6.3
04/13/16 16:33
EPA 6010
Zinc
62.2
mg/kg
12.6
04/13/16 16:33
EPA 6020
Arsenic
12.6
mg/kg
1.3
04/13/16 03:33
EPA 6020
Cadmium
0.29J
mg/kg
0.38
04/13/16 14:00
EPA 6020
Cobalt
9.3
mg/kg
3.1
04/13/16 14:00
EPA 6020
Lead
6.7
mg/kg
1.3
04/13/16 03:33
EPA 6020
Selenium
4.2
mg/kg
3.1
04/13/16 14:00
EPA 6020
Vanadium
21.4
mg/kg
3.1
04/13/16 14:00
EPA 7471
Mercury
0.021
mg/kg
0.0099
04/13/16 17:28
ASTM D2974-87
Percent Moisture
21.0
%
0.10
04/12/16 15:16
EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
04/08/16 15:40
92292703010
2016009404
EPA 6010
Aluminum
17700
mg/kg
6.2
04/13/16 07:50
EPA 6010
Barium
12.4
mg/kg
0.62
04/13/16 07:50
EPA 6010
Beryllium
0.10
mg/kg
0.062
04/13/16 07:50
EPA 6010
Boron
2.8J
mg/kg
3.1
04/13/16 07:50
EPA 6010
Calcium
257
mg/kg
30.8
04/13/16 07:50
EPA 6010
Chromium
14.3
mg/kg
0.31
04/13/16 07:50
EPA 6010
Copper
3.3
mg/kg
0.31
04/13/16 07:50
EPA 6010
Iron
878
mg/kg
2.5
04/13/16 07:50
EPA 6010
Magnesium
194
mg/kg
30.8
04/13/16 07:50
EPA 6010
Manganese
3.9
mg/kg
0.31
04/13/16 07:50
EPA 6010
Molybdenum
0.85
mg/kg
0.62
04/13/16 07:50
EPA 6010
Nickel
3.8
mg/kg
0.31
04/13/16 07:50
EPA 6010
Potassium
148
mg/kg
61.6
04/13/16 07:50
EPA 6010
Strontium
5.0
mg/kg
0.62
04/13/16 07:50
EPA 6010
Zinc
2.0
mg/kg
1.2
04/13/16 07:50
EPA 6020
Arsenic
0.63J
mg/kg
1.2
04/13/16 03:50
EPA 6020
Cobalt
0.65J
mg/kg
1.2
04/13/16 03:50
EPA 6020
Lead
1.3
mg/kg
1.2
04/13/16 03:50
EPA 6020
Vanadium
5.6
mg/kg
1.2
04/13/16 03:50
EPA 7471
Mercury
0.048
mg/kg
0.010
04/13/16 17:31
ASTM D2974-87
Percent Moisture
22.5
%
0.10
04/12/16 15:16
EPA 9045
pH at 25 Degrees C
6.0
Std. Units
0.10
04/08/16 15:40
EPA 9056
Sulfate
227J
mg/kg
320
04/09/16 19:02
92292703011
2016009409
EPA 6010
Aluminum
911
ug/L
100
04/12/16 00:20
EPA 6010
Barium
21.4
ug/L
5.0
04/12/16 00:20
REPORT OF LABORATORY ANALYSIS
0.
H6
D3
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 11 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: J16040066
Pace Project No.: 92292703
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92292703011
2016009409
EPA 6010
Calcium
1070
ug/L
100
04/12/16 00:20
EPA 6010
Iron
6290
ug/L
50.0
04/12/16 00:20
EPA 6010
Magnesium
134
ug/L
100
04/12/16 00:20
EPA 6010
Manganese
31.2
ug/L
5.0
04/12/16 00:20
EPA 6010
Molybdenum
5.7
ug/L
5.0
04/12/16 00:20
EPA 6010
Nickel
11.8
ug/L
5.0
04/12/16 00:20
EPA 6010
Strontium
6.8
ug/L
5.0
04/12/16 00:20
EPA 6010
Zinc
44.4
ug/L
10.0
04/12/16 00:20
EPA 6020B
Antimony
0.74
ug/L
0.50
04/20/16 03:56
EPA 6020B
Arsenic
9.1
ug/L
0.10
04/20/16 03:56
EPA 6020B
Beryllium
0.21
ug/L
0.10
04/20/16 03:56
EPA 6020B
Cadmium
0.34
ug/L
0.080
04/20/16 03:56
EPA 6020B
Chromium
25.0
ug/L
0.50
04/20/16 03:56
EPA 6020B
Cobalt
11.7
ug/L
0.10
04/20/16 03:56
EPA 6020B
Copper
20.4
ug/L
0.50
04/20/16 03:56
EPA 6020B
Lead
3.4
ug/L
0.10
04/20/16 03:56
EPA 6020B
Selenium
4.3
ug/L
0.50
04/20/16 03:56
EPA 6020B
Thallium
0.19
ug/L
0.10
04/20/16 03:56
EPA 6020B
Vanadium
7.9
ug/L
0.50
04/20/16 03:56
92292703012
2016009410
EPA 6010
Aluminum
382
ug/L
100
04/12/16 00:23
EPA 6010
Barium
3.8J
ug/L
5.0
04/12/16 00:23
EPA 6010
Calcium
924
ug/L
100
04/12/16 00:23
EPA 6010
Iron
3960
ug/L
50.0
04/12/16 00:23
EPA 6010
Magnesium
71.5J
ug/L
100
04/12/16 00:23
EPA 6010
Manganese
28.4
ug/L
5.0
04/12/16 00:23
EPA 6010
Molybdenum
2.7J
ug/L
5.0
04/12/16 00:23
EPA 6010
Nickel
4.OJ
ug/L
5.0
04/12/16 00:23
EPA 6010
Strontium
2.7J
ug/L
5.0
04/12/16 00:23
EPA 6020B
Arsenic
1.1
ug/L
0.10
04/20/16 04:01
EPA 6020B
Beryllium
0.0981
ug/L
0.10
04/20/16 04:01
EPA 6020E
Chromium
12.1
ug/L
0.50
04/20/16 04:01
EPA 6020B
Cobalt
0.73
ug/L
0.10
04/20/16 04:01
EPA 6020B
Copper
4.5
ug/L
0.50
04/20/16 04:01
EPA 6020B
Lead
1.9
ug/L
0.10
04/20/16 04:01
EPA 6020B
Selenium
0.96
ug/L
0.50
04/20/16 04:01
EPA 6020B
Vanadium
2.0
ug/L
0.50
04/20/16 04:01
92292703013
2016009411
EPA 6010
Aluminum
502
ug/L
100
04/12/16 00:26
EPA 6010
Barium
5.2
ug/L
5.0
04/12/16 00:26
EPA 6010
Calcium
930
ug/L
100
04/12/16 00:26
EPA 6010
Iron
1990
ug/L
50.0
04/12/16 00:26
EPA 6010
Magnesium
256
ug/L
100
04/12/16 00:26
EPA 6010
Manganese
29.5
ug/L
5.0
04/12/16 00:26
EPA 6010
Nickel
2.5J
ug/L
5.0
04/12/16 00:26
EPA 6010
Zinc
19.6
ug/L
10.0
04/12/16 00:26
REPORT OF LABORATORY ANALYSIS
B
B
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: J16040066
Pace Project No.: 92292703
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92292703013
2016009411
EPA 6020B
Arsenic
0.16
ug/L
0.10
04/20/16 04:05
EPA 6020B
Beryllium
0.030J
ug/L
0.10
04/20/16 04:05
EPA 6020B
Chromium
4.3
ug/L
0.50
04/20/16 04:05
EPA 6020B
Cobalt
0.51
ug/L
0.10
04/20/16 04:05
EPA 6020B
Copper
13.8
ug/L
0.50
04/20/16 04:05
EPA 6020B
Lead
4.7
ug/L
0.10
04/20/16 04:05
EPA 6020B
Vanadium
1.3
ug/L
0.50
04/20/16 04:05
92292703014
2016009412
EPA 6010
Aluminum
600
ug/L
100
04/12/16 00:30
EPA 6010
Barium
4.3J
ug/L
5.0
04/12/16 00:30
EPA 6010
Calcium
1480
ug/L
100
04/12/16 00:30
EPA 6010
Iron
3530
ug/L
50.0
04/12/16 00:30
EPA 6010
Magnesium
120
ug/L
100
04/12/16 00:30
EPA 6010
Manganese
20.8
ug/L
5.0
04/12/16 00:30
EPA 6010
Molybdenum
4.OJ
ug/L
5.0
04/12/16 00:30
EPA 6010
Nickel
3.7J
ug/L
5.0
04/12/16 00:30
EPA 6010
Strontium
5.5
ug/L
5.0
04/12/16 00:30
EPA 6010
Zinc
11.9
ug/L
10.0
04/12/16 00:30
EPA 6020B
Antimony
0.18J
ug/L
0.50
04/20/16 04:19
EPA 6020B
Arsenic
0.83
ug/L
0.10
04/20/16 04:19
EPA 6020B
Beryllium
0.049J
ug/L
0.10
04/20/16 04:19
EPA 6020B
Chromium
16.0
ug/L
0.50
04/20/16 04:19
EPA 6020B
Cobalt
0.65
ug/L
0.10
04/20/16 04:19
EPA 6020B
Copper
14.8
ug/L
0.50
04/20/16 04:19
EPA 6020B
Lead
1.6
ug/L
0.10
04/20/16 04:19
EPA 6020B
Vanadium
1.7
ug/L
0.50
04/20/16 04:19
92292703015
2016009413
EPA 6010
Aluminum
3460
ug/L
100
04/12/16 00:33
EPA 6010
Barium
7.9
ug/L
5.0
04/12/16 00:33
EPA 6010
Calcium
1580
ug/L
100
04/12/16 00:33
EPA 6010
Iron
4130
ug/L
50.0
04/12/16 00:33
EPA 6010
Magnesium
174
ug/L
100
04/12/16 00:33
EPA 6010
Manganese
27.1
ug/L
5.0
04/12/16 00:33
EPA 6010
Molybdenum
4.3J
ug/L
5.0
04/12/16 00:33
EPA 6010
Nickel
5.3
ug/L
5.0
04/12/16 00:33
EPA 6010
Strontium
6.9
ug/L
5.0
04/12/16 00:33
EPA 6010
Zinc
20.4
ug/L
10.0
04/12/16 00:33
EPA 6020B
Antimony
0.25J
ug/L
0.50
04/20/16 04:23
EPA 6020B
Arsenic
1.4
ug/L
0.10
04/20/16 04:23
EPA 6020B
Beryllium
0.069J
ug/L
0.10
04/20/16 04:23
EPA 6020B
Cadmium
0.12
ug/L
0.080
04/20/16 04:23
EPA 6020B
Chromium
12.8
ug/L
0.50
04/20/16 04:23
EPA 6020B
Cobalt
0.92
ug/L
0.10
04/20/16 04:23
EPA 6020B
Copper
20.6
ug/L
0.50
04/20/16 04:23
EPA 6020B
Lead
11.3
ug/L
0.10
04/20/16 04:23
EPA 6020B
Selenium
1.2
ug/L
0.50
04/20/16 04:23
REPORT OF LABORATORY ANALYSIS
B
B
B
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: J16040066
Pace Project No.: 92292703
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92292703015
2016009413
EPA 6020B
Thallium
0.036J
ug/L
0.10
04/20/16 04:23
EPA 6020B
Vanadium
3.4
ug/L
0.50
04/20/16 04:23
92292703016
2016009414
EPA 6010
Aluminum
222
ug/L
100
04/12/16 00:45
EPA 6010
Calcium
346
ug/L
100
04/12/16 00:45
EPA 6010
Iron
854
ug/L
50.0
04/12/16 00:45
EPA 6010
Manganese
5.3
ug/L
5.0
04/12/16 00:45
EPA 6010
Zinc
6.1 J
ug/L
10.0
04/12/16 00:45
EPA 6020B
Arsenic
0.32
ug/L
0.10
04/20/16 04:28
EPA 6020B
Chromium
5.3
ug/L
0.50
04/20/16 04:28
EPA 6020B
Cobalt
0.11
ug/L
0.10
04/20/16 04:28
EPA 6020B
Copper
2.9
ug/L
0.50
04/20/16 04:28
EPA 6020B
Lead
0.49
ug/L
0.10
04/20/16 04:28
EPA 6020B
Vanadium
0.60
ug/L
0.50
04/20/16 04:28
92292703017
2016009415
EPA 6010
Aluminum
564
ug/L
100
04/12/16 00:48
EPA 6010
Barium
9.4
ug/L
5.0
04/12/16 00:48
EPA 6010
Calcium
696
ug/L
100
04/12/16 00:48
EPA 6010
Iron
6020
ug/L
50.0
04/12/16 00:48
EPA 6010
Magnesium
174
ug/L
100
04/12/16 00:48
EPA 6010
Manganese
42.6
ug/L
5.0
04/12/16 00:48
EPA 6010
Molybdenum
4.8J
ug/L
5.0
04/12/16 00:48
EPA 6010
Nickel
4.1 J
ug/L
5.0
04/12/16 00:48
EPA 6010
Strontium
3AJ
ug/L
5.0
04/12/16 00:48
EPA 6010
Zinc
20.4
ug/L
10.0
04/12/16 00:48
EPA 6020E
Antimony
0.12J
ug/L
0.50
04/20/16 04:32
EPA 6020B
Arsenic
0.30
ug/L
0.10
04/20/16 04:32
EPA 6020B
Cadmium
0.16
ug/L
0.080
04/20/16 04:32
EPA 6020B
Chromium
28.6
ug/L
0.50
04/20/16 04:32
EPA 6020B
Cobalt
0.85
ug/L
0.10
04/20/16 04:32
EPA 6020B
Copper
12.5
ug/L
0.50
04/20/16 04:32
EPA 6020B
Lead
1.3
ug/L
0.10
04/20/16 04:32
EPA 6020B
Vanadium
1.6
ug/L
0.50
04/20/16 04:32
92292703018
2016009416
EPA 6010
Aluminum
233
ug/L
100
04/12/16 00:52
EPA 6010
Barium
3.7J
ug/L
5.0
04/12/16 00:52
EPA 6010
Calcium
1130
ug/L
100
04/12/16 00:52
EPA 6010
Iron
1290
ug/L
50.0
04/12/16 00:52
EPA 6010
Magnesium
67.9J
ug/L
100
04/12/16 00:52
EPA 6010
Manganese
13.1
ug/L
5.0
04/12/16 00:52
EPA 6010
Strontium
2.6J
ug/L
5.0
04/12/16 00:52
EPA 6020B
Arsenic
0.0911
ug/L
0.10
04/20/16 04:37
EPA 6020B
Chromium
3.6
ug/L
0.50
04/20/16 04:37 B
EPA 6020B
Cobalt
0.22
ug/L
0.10
04/20/16 04:37
EPA 6020B
Copper
2.6
ug/L
0.50
04/20/16 04:37
EPA 6020B
Lead
1.1
ug/L
0.10
04/20/16 04:37
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 14 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: J16040066
Pace Project No.: 92292703
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92292703018
2016009416
EPA 6020B
Vanadium
0.29J
ug/L
0.50
04/20/16 04:37
92292703019
2016009417
EPA 6010
Aluminum
852
ug/L
100
04/12/16 00:55
EPA 6010
Barium
7.9
ug/L
5.0
04/12/16 00:55
EPA 6010
Calcium
1320
ug/L
100
04/12/16 00:55
EPA 6010
Iron
1320
ug/L
50.0
04/12/16 00:55
EPA 6010
Magnesium
80.2J
ug/L
100
04/12/16 00:55
EPA 6010
Manganese
16.2
ug/L
5.0
04/12/16 00:55
EPA 6010
Nickel
2.5J
ug/L
5.0
04/12/16 00:55
EPA 6010
Strontium
4.6J
ug/L
5.0
04/12/16 00:55
EPA 6010
Zinc
8.5J
ug/L
10.0
04/12/16 00:55
EPA 6020B
Arsenic
1.4
ug/L
0.10
04/20/16 04:50
EPA 6020B
Beryllium
0.039J
ug/L
0.10
04/20/16 04:50 B
EPA 6020B
Chromium
2.7
ug/L
0.50
04/20/16 04:50 B
EPA 6020B
Cobalt
0.95
ug/L
0.10
04/20/16 04:50
EPA 6020B
Copper
2.4
ug/L
0.50
04/20/16 04:50
EPA 6020B
Lead
6.0
ug/L
0.10
04/20/16 04:50
EPA 6020B
Thallium
0.10
ug/L
0.10
04/20/16 04:50
EPA 6020B
Vanadium
1.2
ug/L
0.50
04/20/16 04:50
92292703020
2016009418
EPA 6010
Aluminum
6080
ug/L
100
04/12/16 00:58
EPA 6010
Barium
88.7
ug/L
5.0
04/12/16 00:58
EPA 6010
Boron
32.1 J
ug/L
50.0
04/12/16 00:58
EPA 6010
Calcium
87500
ug/L
100
04/12/16 00:58
EPA 6010
Iron
10800
ug/L
50.0
04/12/16 00:58
EPA 6010
Magnesium
7260
ug/L
100
04/12/16 00:58
EPA 6010
Manganese
391
ug/L
5.0
04/12/16 00:58
EPA 6010
Nickel
13.2
ug/L
5.0
04/12/16 00:58
EPA 6010
Potassium
5400
ug/L
5000
04/12/16 00:58
EPA 6010
Sodium
16100
ug/L
5000
04/12/16 00:58
EPA 6010
Strontium
158
ug/L
5.0
04/12/16 00:58
EPA 6010
Zinc
362
ug/L
10.0
04/12/16 00:58
EPA 6020B
Antimony
0.26J
ug/L
0.50
04/20/16 04:55
EPA 6020B
Arsenic
2.9
ug/L
0.10
04/20/16 04:55
EPA 6020B
Beryllium
0.40
ug/L
0.10
04/20/16 04:55
EPA 6020B
Cadmium
0.24
ug/L
0.080
04/20/16 04:55
EPA 6020B
Chromium
20.4
ug/L
0.50
04/20/16 04:55
EPA 6020B
Cobalt
3.9
ug/L
0.10
04/20/16 04:55
EPA 6020B
Copper
126
ug/L
0.50
04/20/16 04:55
EPA 6020B
Lead
19.8
ug/L
0.10
04/20/16 04:55
EPA 6020B
Selenium
3.0
ug/L
0.50
04/20/16 04:55
EPA 6020B
Thallium
0.15
ug/L
0.10
04/20/16 04:55
EPA 6020B
Vanadium
10.2
ug/L
0.50
04/20/16 04:55
92292703021
2016009419
EPA 6010
Aluminum
203
ug/L
100
04/12/16 01:01
EPA 6010
Barium
100
ug/L
5.0
04/12/16 01:01
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: J16040066
Pace Project No.: 92292703
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92292703021
2016009419
EPA 6010
Calcium
36600
ug/L
100
04/12/16 01:01
EPA 6010
Iron
1970
ug/L
50.0
04/12/16 01:01
EPA 6010
Magnesium
2200
ug/L
100
04/12/16 01:01
EPA 6010
Manganese
15.6
ug/L
5.0
04/12/16 01:01
EPA 6010
Potassium
2830J
ug/L
5000
04/12/16 01:01
EPA 6010
Sodium
13000
ug/L
5000
04/12/16 01:01
EPA 6010
Strontium
213
ug/L
5.0
04/12/16 01:01
EPA 6010
Zinc
52.3
ug/L
10.0
04/12/16 01:01
EPA 6020B
Antimony
0.12J
ug/L
0.50
04/20/16 04:59
EPA 6020B
Arsenic
4.7
ug/L
0.10
04/20/16 04:59
EPA 6020B
Beryllium
0.079J
ug/L
0.10
04/20/16 04:59 B
EPA 6020B
Chromium
0.32J
ug/L
0.50
04/20/16 04:59 B
EPA 6020B
Cobalt
0.19
ug/L
0.10
04/20/16 04:59
EPA 6020B
Copper
80.4
ug/L
0.50
04/20/16 04:59
EPA 6020B
Lead
12.9
ug/L
0.10
04/20/16 04:59
EPA 6020B
Selenium
0.70
ug/L
0.50
04/20/16 04:59
EPA 6020B
Vanadium
2.1
ug/L
0.50
04/20/16 04:59
92292703022
2016009420
EPA 6010
Barium
99.8
ug/L
5.0
04/12/16 01:04
EPA 6010
Calcium
36300
ug/L
100
04/12/16 01:04
EPA 6010
Iron
94.1
ug/L
50.0
04/12/16 01:04
EPA 6010
Magnesium
2090
ug/L
100
04/12/16 01:04
EPA 6010
Molybdenum
2.9J
ug/L
5.0
04/12/16 01:04
EPA 6010
Potassium
2670J
ug/L
5000
04/12/16 01:04
EPA 6010
Sodium
12700
ug/L
5000
04/12/16 01:04
EPA 6010
Strontium
210
ug/L
5.0
04/12/16 01:04
EPA 6010
Zinc
19.6
ug/L
10.0
04/12/16 01:04
EPA 6020B
Antimony
0.13J
ug/L
0.50
04/20/16 05:13
EPA 6020B
Arsenic
4.6
ug/L
0.10
04/20/16 05:13
EPA 6020B
Chromium
0.18J
ug/L
0.50
04/20/16 05:13 B
EPA 6020B
Copper
4.2
ug/L
0.50
04/20/16 05:13
EPA 6020E
Lead
1.1
ug/L
0.10
04/20/16 05:13
EPA 6020B
Selenium
0.83
ug/L
0.50
04/20/16 05:13
EPA 6020B
Vanadium
1.4
ug/L
0.50
04/20/16 05:13
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 16 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040066
Pace Project No.: 92292703
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 20, 2016
General Information:
22 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3010A with any exceptions noted below.
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/21291
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92292420002
M1: Matrix spike recovery exceeded QC limits.
• MS (Lab ID: 1704463)
• Calcium
• Sodium
• MSD (Lab ID: 1704464)
• Calcium
• Sodium
QC Batch: MPRP/29721
Batch accepted based on laboratory control sample (LCS) recovery.
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92292703001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1536636)
• Aluminum
• Iron
• Magnesium
• Manganese
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 17 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040066
Pace Project No.: 92292703
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 20, 2016
QC Batch: MPRP/29721
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92292703001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 1536637)
• Aluminum
• Beryllium
• Boron
• Chromium
• Iron
• Magnesium
• Manganese
• Molybdenum
• Nickel
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1536636)
• Calcium
• Strontium
• MSD (Lab ID: 1536637)
• Calcium
• Strontium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1536637)
• Aluminum
• Iron
• Magnesium
• Potassium
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 18 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040066
Pace Project No.: 92292703
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 20, 2016
General Information:
10 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
The samples were prepared in accordance with EPA 3010A with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: MPRP/21339
B: Analyte was detected in the associated method blank.
• BLANK for HBN 308383 [MPRP/213 (Lab ID: 1707723)
• Beryllium
• Chromium
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/29707
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35238147001
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1536510)
• Antimony
• Cadmium
• Selenium
• MSD (Lab ID: 1536511)
• Antimony
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 19 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040066
Pace Project No.: 92292703
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 20, 2016
QC Batch: MPRP/29707
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35238147001
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• Selenium
Additional Comments:
General Information:
12 samples were analyzed for EPA 6020B. All samples were received in acceptable condition with any exceptions noted below or on
the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
The samples were prepared in accordance with EPA 3010A with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: MPRP/21339
B: Analyte was detected in the associated method blank.
• BLANK for HBN 308383 [MPRP/213 (Lab ID: 1707723)
• Beryllium
• Chromium
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 20 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040066
Pace Project No.: 92292703
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 20, 2016
QC Batch: MPRP/29707
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35238147001
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1536510)
• Antimony
• Cadmium
• Selenium
• MSD (Lab ID: 1536511)
• Antimony
• Selenium
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 21 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040066
Pace Project No.: 92292703
Method: EPA 7470
Description: 7470 Mercury
Client: Duke Energy
Date: April 20, 2016
General Information:
12 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 22 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040066
Pace Project No.: 92292703
Method: EPA 7471
Description: 7471 Mercury
Client: Duke Energy
Date: April 20, 2016
General Information:
10 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 23 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040066
Pace Project No.: 92292703
Method: EPA 9045
Description: 9045 pH Soil
Client: Duke Energy
Date: April 20, 2016
General Information:
10 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1­16: Analysis initiated outside of the 15 minute EPA required holding time.
•2016009393 (Lab ID:92292703001)
•2016009396 (Lab ID:92292703002)
•2016009397 (Lab ID:92292703003)
•2016009398 (Lab ID:92292703004)
•2016009399 (Lab ID:92292703005)
•2016009400 (Lab ID:92292703006)
•2016009401 (Lab ID:92292703007)
•2016009402 (Lab ID:92292703008)
•2016009403 (Lab ID:92292703009)
•2016009404 (Lab ID:92292703010)
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 24 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040066
Pace Project No.: 92292703
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: April 20, 2016
General Information:
10 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/56664
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2016009393 (Lab ID:92292703001)
• Chloride
• Sulfate
•2016009396 (Lab ID:92292703002)
• Chloride
• Sulfate
•2016009397 (Lab ID:92292703003)
• Chloride
• Sulfate
•2016009398 (Lab ID:92292703004)
• Chloride
• Sulfate
•2016009399 (Lab ID:92292703005)
• Chloride
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 25 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040066
Pace Project No.: 92292703
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: April 20, 2016
Analyte Comments:
QC Batch: WETA/56664
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2016009399 (Lab ID:92292703005)
• Sulfate
•2016009400 (Lab ID:92292703006)
• Chloride
• Sulfate
•2016009401 (Lab ID:92292703007)
• Chloride
• Sulfate
•2016009402 (Lab ID:92292703008)
• Chloride
• Sulfate
•2016009403 (Lab ID:92292703009)
• Chloride
• Sulfate
•2016009404 (Lab ID:92292703010)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 26 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040066
Pace Project No.: 92292703
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: April 20, 2016
General Information:
10 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1­13: Sample was received or analysis requested beyond the recognized method holding time.
•2016009393 (Lab ID:92292703001)
•2016009396 (Lab ID:92292703002)
•2016009397 (Lab ID:92292703003)
•2016009398 (Lab ID:92292703004)
•2016009399 (Lab ID:92292703005)
•2016009400 (Lab ID:92292703006)
•2016009401 (Lab ID:92292703007)
•2016009402 (Lab ID:92292703008)
•2016009403 (Lab ID:92292703009)
•2016009404 (Lab ID:92292703010)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/56665
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2016009393 (Lab ID:92292703001)
• Nitrate as N
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 27 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J16040066
Pace Project No.: 92292703
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: April 20, 2016
Analyte Comments:
QC Batch: WETA/56665
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2016009396 (Lab ID:92292703002)
• Nitrate as N
•2016009397 (Lab ID:92292703003)
• Nitrate as N
•2016009398 (Lab ID:92292703004)
• Nitrate as N
•2016009399 (Lab ID:92292703005)
• Nitrate as N
•2016009400 (Lab ID:92292703006)
• Nitrate as N
•2016009401 (Lab ID:92292703007)
• Nitrate as N
•2016009402 (Lab ID:92292703008)
• Nitrate as N
•2016009403 (Lab ID:92292703009)
• Nitrate as N
•2016009404 (Lab ID:92292703010)
• Nitrate as N
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 28 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009393 Lab ID: 92292703001 Collected: 03/31/16 14:20 Received: 04/06/16 13:25 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 04/20/2016 04:50 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
5970
mg/kg
7.1
3.5
1
04/12/16 14:11
04/13/16 06:45
7429-90-5
37.2
mg/kg
0.71
0.35
1
04/12/16 14:11
04/13/16 06:45
7440-39-3
0.44
mg/kg
0.071
0.035
1
04/12/16 14:11
04/13/16 06:45
7440-41-7
4.6
mg/kg
3.5
1.8
1
04/12/16 14:11
04/13/16 06:45
7440-42-8
190000
mg/kg
354
177
10
04/12/16 14:11
04/13/16 08:18
7440-70-2
19.8
mg/kg
0.35
0.18
1
04/12/16 14:11
04/13/16 06:45
7440-47-3
4.4
mg/kg
0.35
0.18
1
04/12/16 14:11
04/13/16 06:45
7440-50-8
9460
mg/kg
2.8
1.4
1
04/12/16 14:11
04/13/16 06:45
7439-89-6
1810
mg/kg
35.4
17.7
1
04/12/16 14:11
04/13/16 06:45
7439-95-4
109
mg/kg
0.35
0.18
1
04/12/16 14:11
04/13/16 06:45
7439-96-5
6.6
mg/kg
0.71
0.35
1
04/12/16 14:11
04/13/16 06:45
7439-98-7
4.2
mg/kg
0.35
0.18
1
04/12/16 14:11
04/13/16 06:45
7440-02-0
594
mg/kg
70.7
35.4
1
04/12/16 14:11
04/13/16 06:45
7440-09-7
1620
mg/kg
70.7
35.4
1
04/12/16 14:11
04/13/16 06:45
7440-23-5
1030
mg/kg
7.1
3.5
10
04/12/16 14:11
04/13/16 08:18
7440-24-6
16.9
mg/kg
1.4
0.71
1
04/12/16 14:11
04/13/16 06:45
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
2.8
1.4
20
04/12/16 14:11
04/13/16 03:07
7440-36-0
10.7
mg/kg
1.4
0.71
20
04/12/16 14:11
04/13/16 03:07
7440-38-2
ND
mg/kg
0.17
0.10
20
04/12/16 14:11
04/13/16 03:07
7440-43-9
2.4
mg/kg
1.4
0.71
20
04/12/16 14:11
04/13/16 03:07
7440-48-4
3.7
mg/kg
1.4
1.4
20
04/12/16 14:11
04/13/16 03:07
7439-92-1
ND
mg/kg
1.4
0.71
20
04/12/16 14:11
04/13/16 03:07
7782-49-2
ND
mg/kg
1.4
0.71
20
04/12/16 14:11
04/13/16 03:07
7440-28-0
17.3
mg/kg
1.4
0.71
20
04/12/16 14:11
04/13/16 03:07
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
ND mg/kg 0.011 0.0055 1 04/13/1612:36 04/13/1617:07 7439-97-6
Analytical Method: ASTM D2974-87
31.3 % 0.10 0.10 1 04/12/1615:15
Analytical Method: EPA 9045
8.7 Std. Units 0.10 0.10 1
Analytical Method: EPA 9056
ND mg/kg 364 182 5
ND mg/kg 364 182 5
Analytical Method: EPA 9056
ND mg/kg 36.4 18.2 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
M1,R1
M1
M1
M6
M1
M1,R1
M1,R1
M1
M1
M1
R1
M6
N2
04/09/1614:23 16887-00-6 D3
04/09/1614:23 14808-79-8 D3
04/09/1614:23 14797-55-8 D3,H3
Page 29 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009396 Lab ID: 92292703002 Collected: 03/30/16 14:46 Received: 04/06/16 13:25 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 04/20/2016 04:50 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
7830
mg/kg
6.3
3.2
1
04/12/16 14:11
04/13/16 07:09
7429-90-5
18.1
mg/kg
0.63
0.32
1
04/12/16 14:11
04/13/16 07:09
7440-39-3
0.37
mg/kg
0.063
0.032
1
04/12/16 14:11
04/13/16 07:09
7440-41-7
1.91
mg/kg
3.2
1.6
1
04/12/16 14:11
04/13/16 07:09
7440-42-8
562
mg/kg
31.6
15.8
1
04/12/16 14:11
04/13/16 07:09
7440-70-2
17.6
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:09
7440-47-3
3.1
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:09
7440-50-8
8200
mg/kg
2.5
1.3
1
04/12/16 14:11
04/13/16 07:09
7439-89-6
201
mg/kg
31.6
15.8
1
04/12/16 14:11
04/13/16 07:09
7439-95-4
24.0
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:09
7439-96-5
0.66
mg/kg
0.63
0.32
1
04/12/16 14:11
04/13/16 07:09
7439-98-7
2.9
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:09
7440-02-0
179
mg/kg
63.2
31.6
1
04/12/16 14:11
04/13/16 07:09
7440-09-7
ND
mg/kg
63.2
31.6
1
04/12/16 14:11
04/13/16 07:09
7440-23-5
11.2
mg/kg
0.63
0.32
1
04/12/16 14:11
04/13/16 07:09
7440-24-6
2.8
mg/kg
1.3
0.63
1
04/12/16 14:11
04/13/16 07:09
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
2.5
1.2
20
04/12/16 14:11
04/13/16 03:10
7440-36-0
3.2
mg/kg
1.3
0.63
20
04/12/16 14:11
04/13/16 03:10
7440-38-2
ND
mg/kg
0.38
0.23
50
04/12/16 14:11
04/13/1613:46
7440-43-9
ND
mg/kg
3.2
1.6
50
04/12/16 14:11
04/13/1613:46
7440-48-4
4.0
mg/kg
1.3
1.3
20
04/12/16 14:11
04/13/16 03:10
7439-92-1
1.7J
mg/kg
3.2
1.6
50
04/12/16 14:11
04/13/1613:46
7782-49-2
ND
mg/kg
1.3
0.63
20
04/12/16 14:11
04/13/16 03:10
7440-28-0
34.8
mg/kg
3.2
1.6
50
04/12/16 14:11
04/13/1613:46
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
ND mg/kg 0.011 0.0053 1 04/13/1612:36 04/13/1617:09 7439-97-6
Analytical Method: ASTM D2974-87
23.3 % 0.10 0.10 1 04/12/1615:15
Analytical Method: EPA 9045
6.0 Std. Units 0.10 0.10 1
Analytical Method: EPA 9056
ND mg/kg 325 162 5
ND mg/kg 325 162 5
Analytical Method: EPA 9056
ND mg/kg 32.5 16.2 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
N2
04/09/1615:28 16887-00-6 D3
04/09/1615:28 14808-79-8 D3
04/09/1615:28 14797-55-8 D3,H3
Page 30 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009397 Lab ID: 92292703003 Collected: 03/30/16 15:40 Received: 04/06/16 13:25 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 04/20/2016 04:50 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
8970
mg/kg
6.4
3.2
1
04/12/16 14:11
04/13/16 07:13
7429-90-5
16.0
mg/kg
0.64
0.32
1
04/12/16 14:11
04/13/16 07:13
7440-39-3
0.33
mg/kg
0.064
0.032
1
04/12/16 14:11
04/13/16 07:13
7440-41-7
ND
mg/kg
3.2
1.6
1
04/12/16 14:11
04/13/16 07:13
7440-42-8
791
mg/kg
31.9
16.0
1
04/12/16 14:11
04/13/16 07:13
7440-70-2
16.4
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:13
7440-47-3
5.5
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:13
7440-50-8
11100
mg/kg
2.6
1.3
1
04/12/16 14:11
04/13/16 07:13
7439-89-6
335
mg/kg
31.9
16.0
1
04/12/16 14:11
04/13/16 07:13
7439-95-4
36.8
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:13
7439-96-5
5.7
mg/kg
0.64
0.32
1
04/12/16 14:11
04/13/16 07:13
7439-98-7
9.4
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:13
7440-02-0
356
mg/kg
63.9
31.9
1
04/12/16 14:11
04/13/16 07:13
7440-09-7
ND
mg/kg
63.9
31.9
1
04/12/16 14:11
04/13/16 07:13
7440-23-5
7.4
mg/kg
0.64
0.32
1
04/12/16 14:11
04/13/16 07:13
7440-24-6
16.0
mg/kg
1.3
0.64
1
04/12/16 14:11
04/13/16 07:13
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
2.6
1.3
20
04/12/16 14:11
04/13/16 03:13
7440-36-0
13.7
mg/kg
1.3
0.64
20
04/12/16 14:11
04/13/16 03:13
7440-38-2
0.36
mg/kg
0.15
0.092
20
04/12/16 14:11
04/13/16 03:13
7440-43-9
11.4
mg/kg
1.3
0.64
20
04/12/16 14:11
04/13/16 03:13
7440-48-4
7.8
mg/kg
1.3
1.3
20
04/12/16 14:11
04/13/16 03:13
7439-92-1
1.6
mg/kg
1.3
0.64
20
04/12/16 14:11
04/13/16 03:13
7782-49-2
ND
mg/kg
1.3
0.64
20
04/12/16 14:11
04/13/16 03:13
7440-28-0
19.6
mg/kg
1.3
0.64
20
04/12/16 14:11
04/13/16 03:13
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.0085J mg/kg 0.011 0.0053 1 04/13/1612:36 04/13/1617:11 7439-97-6
Analytical Method: ASTM D2974-87
22.9 % 0.10 0.10 1 04/12/1615:15
Analytical Method: EPA 9045
7.5 Std. Units 0.10 0.10 1
Analytical Method: EPA 9056
ND mg/kg 324 162 5
ND mg/kg 324 162 5
Analytical Method: EPA 9056
ND mg/kg 32.4 16.2 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
N2
04/09/1615:49 16887-00-6 D3
04/09/1615:49 14808-79-8 D3
04/09/1615:49 14797-55-8 D3,H3
Page 31 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009398 Lab ID: 92292703004 Collected: 03/31/16 14:40 Received: 04/06/16 13:25 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 04/20/2016 04:50 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
2120
mg/kg
6.2
3.1
1
04/12/16 14:11
04/13/16 07:17
7429-90-5
36.3
mg/kg
0.62
0.31
1
04/12/16 14:11
04/13/16 07:17
7440-39-3
0.27
mg/kg
0.062
0.031
1
04/12/16 14:11
04/13/16 07:17
7440-41-7
6.9
mg/kg
3.1
1.5
1
04/12/16 14:11
04/13/16 07:17
7440-42-8
281000
mg/kg
620
310
20
04/12/16 14:11
04/13/16 08:42
7440-70-2
13.5
mg/kg
0.31
0.15
1
04/12/16 14:11
04/13/16 07:17
7440-47-3
1.8
mg/kg
0.31
0.15
1
04/12/16 14:11
04/13/16 07:17
7440-50-8
5280
mg/kg
2.5
1.2
1
04/12/16 14:11
04/13/16 07:17
7439-89-6
1360
mg/kg
31.0
15.5
1
04/12/16 14:11
04/13/16 07:17
7439-95-4
57.3
mg/kg
0.31
0.15
1
04/12/16 14:11
04/13/16 07:17
7439-96-5
2.9
mg/kg
0.62
0.31
1
04/12/16 14:11
04/13/16 07:17
7439-98-7
1.7
mg/kg
0.31
0.15
1
04/12/16 14:11
04/13/16 07:17
7440-02-0
272
mg/kg
62.0
31.0
1
04/12/16 14:11
04/13/16 07:17
7440-09-7
2430
mg/kg
62.0
31.0
1
04/12/16 14:11
04/13/16 07:17
7440-23-5
1400
mg/kg
12.4
6.2
20
04/12/16 14:11
04/13/16 08:42
7440-24-6
7.0
mg/kg
1.2
0.62
1
04/12/16 14:11
04/13/16 07:17
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
2.5
1.2
20
04/12/16 14:11
04/13/16 03:17
7440-36-0
10.1
mg/kg
1.2
0.62
20
04/12/16 14:11
04/13/16 03:17
7440-38-2
ND
mg/kg
0.37
0.22
50
04/12/16 14:11
04/13/1613:50
7440-43-9
ND
mg/kg
3.1
1.5
50
04/12/16 14:11
04/13/1613:50
7440-48-4
1.7
mg/kg
1.2
1.2
20
04/12/16 14:11
04/13/16 03:17
7439-92-1
ND
mg/kg
3.1
1.5
50
04/12/16 14:11
04/13/1613:50
7782-49-2
ND
mg/kg
1.2
0.62
20
04/12/16 14:11
04/13/16 03:17
7440-28-0
15.0
mg/kg
3.1
1.5
50
04/12/16 14:11
04/13/1613:50
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
ND mg/kg 0.0095 0.0047 1 04/13/1612:36 04/13/1617:13 7439-97-6
Analytical Method: ASTM D2974-87
19.0 % 0.10 0.10 1 04/12/1615:16
Analytical Method: EPA 9045
8.0 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
309
154 5
205J mg/kg
309
154 5
Analytical Method: EPA 9056
ND mg/kg
30.9
15.4 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
N2
04/09/1616:10 16887-00-6 D3
04/09/1616:10 14808-79-8 D3
04/09/1616:10 14797-55-8 D3,H3
Page 32 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009399 Lab ID: 92292703005 Collected: 03/29/16 17:25 Received: 04/06/16 13:25 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 04/20/2016 04:50 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
8690
mg/kg
63.4
31.7
10
04/12/16 14:11
04/13/1616:25
7429-90-5
10.3
mg/kg
6.3
3.2
10
04/12/16 14:11
04/13/1616:25
7440-39-3
0.70
mg/kg
0.63
0.32
10
04/12/16 14:11
04/13/1616:25
7440-41-7
ND
mg/kg
31.7
15.8
10
04/12/16 14:11
04/13/1616:25
7440-42-8
740
mg/kg
317
158
10
04/12/16 14:11
04/13/1616:25
7440-70-2
33.0
mg/kg
3.2
1.6
10
04/12/16 14:11
04/13/1616:25
7440-47-3
7.2
mg/kg
3.2
1.6
10
04/12/16 14:11
04/13/1616:25
7440-50-8
20800
mg/kg
25.4
12.7
10
04/12/16 14:11
04/13/1616:25
7439-89-6
537
mg/kg
317
158
10
04/12/16 14:11
04/13/1616:25
7439-95-4
67.1
mg/kg
3.2
1.6
10
04/12/16 14:11
04/13/1616:25
7439-96-5
10.6
mg/kg
6.3
3.2
10
04/12/16 14:11
04/13/1616:25
7439-98-7
10.1
mg/kg
3.2
1.6
10
04/12/16 14:11
04/13/1616:25
7440-02-0
439J
mg/kg
634
317
10
04/12/16 14:11
04/13/1616:25
7440-09-7
ND
mg/kg
634
317
10
04/12/16 14:11
04/13/1616:25
7440-23-5
7.6
mg/kg
6.3
3.2
10
04/12/16 14:11
04/13/1616:25
7440-24-6
24.9
mg/kg
12.7
6.3
10
04/12/16 14:11
04/13/1616:25
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
2.5
1.3
20
04/12/16 14:11
04/13/16 03:20
7440-36-0
17.0
mg/kg
1.3
0.63
20
04/12/16 14:11
04/13/16 03:20
7440-38-2
0.45
mg/kg
0.38
0.23
50
04/12/16 14:11
04/13/1613:53
7440-43-9
5.9
mg/kg
3.2
1.6
50
04/12/16 14:11
04/13/1613:53
7440-48-4
7.8
mg/kg
1.3
1.3
20
04/12/16 14:11
04/13/16 03:20
7439-92-1
3.7
mg/kg
3.2
1.6
50
04/12/16 14:11
04/13/1613:53
7782-49-2
ND
mg/kg
1.3
0.63
20
04/12/16 14:11
04/13/16 03:20
7440-28-0
31.8
mg/kg
3.2
1.6
50
04/12/16 14:11
04/13/1613:53
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.011 mg/kg 0.011 0.0053 1 04/13/1612:36 04/13/1617:16 7439-97-6
Analytical Method: ASTM D2974-87
22.5 % 0.10 0.10 1 04/12/1615:16
Analytical Method: EPA 9045
5.5 Std. Units 0.10 0.10 1
Analytical Method: EPA 9056
ND mg/kg 321 161 5
ND mg/kg 321 161 5
Analytical Method: EPA 9056
ND mg/kg 32.1 16.1 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
N2
04/09/1617:15 16887-00-6 D3
04/09/1617:15 14808-79-8 D3
04/09/1617:15 14797-55-8 D3,H3
Page 33 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009400 Lab ID: 92292703006 Collected: 03/29/16 17:25 Received: 04/06/16 13:25 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 04/20/2016 04:50 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
9030
mg/kg
66.8
33.4
10
04/12/16 14:11
04/13/1616:29
7429-90-5
10.8
mg/kg
6.7
3.3
10
04/12/16 14:11
04/13/1616:29
7440-39-3
0.62J
mg/kg
0.67
0.33
10
04/12/16 14:11
04/13/1616:29
7440-41-7
ND
mg/kg
33.4
16.7
10
04/12/16 14:11
04/13/1616:29
7440-42-8
568
mg/kg
334
167
10
04/12/16 14:11
04/13/1616:29
7440-70-2
29.7
mg/kg
3.3
1.7
10
04/12/16 14:11
04/13/1616:29
7440-47-3
8.6
mg/kg
3.3
1.7
10
04/12/16 14:11
04/13/1616:29
7440-50-8
13100
mg/kg
26.7
13.4
10
04/12/16 14:11
04/13/1616:29
7439-89-6
385
mg/kg
334
167
10
04/12/16 14:11
04/13/1616:29
7439-95-4
30.8
mg/kg
3.3
1.7
10
04/12/16 14:11
04/13/1616:29
7439-96-5
ND
mg/kg
6.7
3.3
10
04/12/16 14:11
04/13/1616:29
7439-98-7
10.8
mg/kg
3.3
1.7
10
04/12/16 14:11
04/13/1616:29
7440-02-0
458J
mg/kg
668
334
10
04/12/16 14:11
04/13/1616:29
7440-09-7
ND
mg/kg
668
334
10
04/12/16 14:11
04/13/1616:29
7440-23-5
6.9
mg/kg
6.7
3.3
10
04/12/16 14:11
04/13/1616:29
7440-24-6
26.8
mg/kg
13.4
6.7
10
04/12/16 14:11
04/13/1616:29
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
2.7
1.3
20
04/12/16 14:11
04/13/16 03:23
7440-36-0
12.8
mg/kg
1.3
0.67
20
04/12/16 14:11
04/13/16 03:23
7440-38-2
0.42
mg/kg
0.40
0.24
50
04/12/16 14:11
04/13/1613:56
7440-43-9
5.2
mg/kg
3.3
1.7
50
04/12/16 14:11
04/13/1613:56
7440-48-4
9.5
mg/kg
1.3
1.3
20
04/12/16 14:11
04/13/16 03:23
7439-92-1
2.9J
mg/kg
3.3
1.7
50
04/12/16 14:11
04/13/1613:56
7782-49-2
ND
mg/kg
1.3
0.67
20
04/12/16 14:11
04/13/16 03:23
7440-28-0
24.2
mg/kg
3.3
1.7
50
04/12/16 14:11
04/13/1613:56
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.011 mg/kg 0.010 0.0052 1 04/13/1612:36 04/13/1617:18 7439-97-6
Analytical Method: ASTM D2974-87
21.2 % 0.10 0.10 1 04/12/1615:16
Analytical Method: EPA 9045
5.0 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
314
157 5
ND mg/kg
314
157 5
Analytical Method: EPA 9056
ND mg/kg
31.4
15.7 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
N2
04/09/1617:36 16887-00-6 D3
04/09/1617:36 14808-79-8 D3
04/09/1617:36 14797-55-8 D3,H3
Page 34 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009401 Lab ID: 92292703007 Collected: 03/30/16 10:25 Received: 04/06/16 13:25 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 04/20/2016 04:50 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
5910
mg/kg
6.4
3.2
1
04/12/16 14:11
04/13/16 07:29
7429-90-5
9.4
mg/kg
0.64
0.32
1
04/12/16 14:11
04/13/16 07:29
7440-39-3
0.077
mg/kg
0.064
0.032
1
04/12/16 14:11
04/13/16 07:29
7440-41-7
ND
mg/kg
3.2
1.6
1
04/12/16 14:11
04/13/16 07:29
7440-42-8
89.2
mg/kg
32.0
16.0
1
04/12/16 14:11
04/13/16 07:29
7440-70-2
4.7
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:29
7440-47-3
1.7
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:29
7440-50-8
966
mg/kg
2.6
1.3
1
04/12/16 14:11
04/13/16 07:29
7439-89-6
90.4
mg/kg
32.0
16.0
1
04/12/16 14:11
04/13/16 07:29
7439-95-4
4.3
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:29
7439-96-5
ND
mg/kg
0.64
0.32
1
04/12/16 14:11
04/13/16 07:29
7439-98-7
5.5
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:29
7440-02-0
82.7
mg/kg
64.0
32.0
1
04/12/16 14:11
04/13/16 07:29
7440-09-7
ND
mg/kg
64.0
32.0
1
04/12/16 14:11
04/13/16 07:29
7440-23-5
6.7
mg/kg
0.64
0.32
1
04/12/16 14:11
04/13/16 07:29
7440-24-6
1.2J
mg/kg
1.3
0.64
1
04/12/16 14:11
04/13/16 07:29
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
2.6
1.3
20
04/12/16 14:11
04/13/16 03:27
7440-36-0
0.93J
mg/kg
1.3
0.64
20
04/12/16 14:11
04/13/16 03:27
7440-38-2
ND
mg/kg
0.15
0.092
20
04/12/16 14:11
04/13/16 03:27
7440-43-9
ND
mg/kg
1.3
0.64
20
04/12/16 14:11
04/13/16 03:27
7440-48-4
3.2
mg/kg
1.3
1.3
20
04/12/16 14:11
04/13/16 03:27
7439-92-1
ND
mg/kg
1.3
0.64
20
04/12/16 14:11
04/13/16 03:27
7782-49-2
ND
mg/kg
1.3
0.64
20
04/12/16 14:11
04/13/16 03:27
7440-28-0
3.6
mg/kg
1.3
0.64
20
04/12/16 14:11
04/13/16 03:27
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.0086J mg/kg 0.010 0.0051 1 04/13/1612:36 04/13/1617:24 7439-97-6
Analytical Method: ASTM D2974-87
17.8 % 0.10 0.10 1 04/12/1615:16
Analytical Method: EPA 9045
5.5 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
302
151 5
152J mg/kg
302
151 5
Analytical Method: EPA 9056
ND mg/kg
30.2
15.1 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
N2
04/09/1617:57 16887-00-6 D3
04/09/1617:57 14808-79-8 D3
04/09/1617:57 14797-55-8 D3,H3
Page 35 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009402 Lab ID: 92292703008 Collected: 03/31/16 11:05 Received: 04/06/16 13:25 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 04/20/2016 04:50 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
13400
mg/kg
6.3
3.2
1
04/12/16 14:11
04/13/16 07:34
7429-90-5
8.6
mg/kg
0.63
0.32
1
04/12/16 14:11
04/13/16 07:34
7440-39-3
0.11
mg/kg
0.063
0.032
1
04/12/16 14:11
04/13/16 07:34
7440-41-7
ND
mg/kg
3.2
1.6
1
04/12/16 14:11
04/13/16 07:34
7440-42-8
75.6
mg/kg
31.5
15.8
1
04/12/16 14:11
04/13/16 07:34
7440-70-2
12.4
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:34
7440-47-3
1.1
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:34
7440-50-8
1250
mg/kg
2.5
1.3
1
04/12/16 14:11
04/13/16 07:34
7439-89-6
168
mg/kg
31.5
15.8
1
04/12/16 14:11
04/13/16 07:34
7439-95-4
6.1
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:34
7439-96-5
0.58J
mg/kg
0.63
0.32
1
04/12/16 14:11
04/13/16 07:34
7439-98-7
3.5
mg/kg
0.32
0.16
1
04/12/16 14:11
04/13/16 07:34
7440-02-0
137
mg/kg
63.1
31.5
1
04/12/16 14:11
04/13/16 07:34
7440-09-7
ND
mg/kg
63.1
31.5
1
04/12/16 14:11
04/13/16 07:34
7440-23-5
3.1
mg/kg
0.63
0.32
1
04/12/16 14:11
04/13/16 07:34
7440-24-6
2.7
mg/kg
1.3
0.63
1
04/12/16 14:11
04/13/16 07:34
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
2.5
1.2
20
04/12/16 14:11
04/13/16 03:30
7440-36-0
ND
mg/kg
1.3
0.63
20
04/12/16 14:11
04/13/16 03:30
7440-38-2
ND
mg/kg
0.15
0.091
20
04/12/16 14:11
04/13/16 03:30
7440-43-9
0.68J
mg/kg
1.3
0.63
20
04/12/16 14:11
04/13/16 03:30
7440-48-4
8.2
mg/kg
1.3
1.2
20
04/12/16 14:11
04/13/16 03:30
7439-92-1
ND
mg/kg
1.3
0.63
20
04/12/16 14:11
04/13/16 03:30
7782-49-2
ND
mg/kg
1.3
0.63
20
04/12/16 14:11
04/13/16 03:30
7440-28-0
18.1
mg/kg
1.3
0.63
20
04/12/16 14:11
04/13/16 03:30
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.011 mg/kg 0.0097 0.0048 1 04/13/1612:36 04/13/1617:26 7439-97-6
Analytical Method: ASTM D2974-87
18.9 % 0.10 0.10 1 04/12/1615:16
Analytical Method: EPA 9045
4.9 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
305
153 5
ND mg/kg
305
153 5
Analytical Method: EPA 9056
ND mg/kg
30.5
15.3 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
N2
04/09/1618:19 16887-00-6 D3
04/09/1618:19 14808-79-8 D3
04/09/1618:19 14797-55-8 D3,H3
Page 36 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009403 Lab ID: 92292703009 Collected: 03/30/16 11:40 Received: 04/06/16 13:25 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 04/20/2016 04:50 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
9200
mg/kg
62.8
31.4
10
04/12/16 14:11
04/13/1616:33
7429-90-5
59.4
mg/kg
6.3
3.1
10
04/12/16 14:11
04/13/1616:33
7440-39-3
1.8
mg/kg
0.63
0.31
10
04/12/16 14:11
04/13/1616:33
7440-41-7
ND
mg/kg
31.4
15.7
10
04/12/16 14:11
04/13/1616:33
7440-42-8
2180
mg/kg
314
157
10
04/12/16 14:11
04/13/1616:33
7440-70-2
25.9
mg/kg
3.1
1.6
10
04/12/16 14:11
04/13/1616:33
7440-47-3
8.3
mg/kg
3.1
1.6
10
04/12/16 14:11
04/13/1616:33
7440-50-8
8940
mg/kg
25.1
12.6
10
04/12/16 14:11
04/13/1616:33
7439-89-6
486
mg/kg
314
157
10
04/12/16 14:11
04/13/1616:33
7439-95-4
44.5
mg/kg
3.1
1.6
10
04/12/16 14:11
04/13/1616:33
7439-96-5
3.5J
mg/kg
6.3
3.1
10
04/12/16 14:11
04/13/1616:33
7439-98-7
12.4
mg/kg
3.1
1.6
10
04/12/16 14:11
04/13/1616:33
7440-02-0
375J
mg/kg
628
314
10
04/12/16 14:11
04/13/1616:33
7440-09-7
ND
mg/kg
628
314
10
04/12/16 14:11
04/13/1616:33
7440-23-5
23.4
mg/kg
6.3
3.1
10
04/12/16 14:11
04/13/1616:33
7440-24-6
62.2
mg/kg
12.6
6.3
10
04/12/16 14:11
04/13/1616:33
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
2.5
1.2
20
04/12/16 14:11
04/13/16 03:33
7440-36-0
12.6
mg/kg
1.3
0.63
20
04/12/16 14:11
04/13/16 03:33
7440-38-2
0.29J
mg/kg
0.38
0.23
50
04/12/16 14:11
04/13/1614:00
7440-43-9
9.3
mg/kg
3.1
1.6
50
04/12/16 14:11
04/13/1614:00
7440-48-4
6.7
mg/kg
1.3
1.2
20
04/12/16 14:11
04/13/16 03:33
7439-92-1
4.2
mg/kg
3.1
1.6
50
04/12/16 14:11
04/13/1614:00
7782-49-2
ND
mg/kg
1.3
0.63
20
04/12/16 14:11
04/13/16 03:33
7440-28-0
21.4
mg/kg
3.1
1.6
50
04/12/16 14:11
04/13/1614:00
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.021 mg/kg 0.0099 0.0050 1 04/13/1612:36 04/13/1617:28 7439-97-6
Analytical Method: ASTM D2974-87
21.0 % 0.10 0.10 1 04/12/1615:16
Analytical Method: EPA 9045
6.4 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
317
158 5
ND mg/kg
317
158 5
Analytical Method: EPA 9056
ND mg/kg
31.7
15.8 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
N2
04/09/1618:40 16887-00-6 D3
04/09/1618:40 14808-79-8 D3
04/09/1618:40 14797-55-8 D3,H3
Page 37 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009404 Lab ID: 92292703010 Collected: 03/31/16 10:25 Received: 04/06/16 13:25 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 04/20/2016 04:50 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
17700
mg/kg
6.2
3.1
1
04/12/16 14:11
04/13/16 07:50
7429-90-5
12.4
mg/kg
0.62
0.31
1
04/12/16 14:11
04/13/16 07:50
7440-39-3
0.10
mg/kg
0.062
0.031
1
04/12/16 14:11
04/13/16 07:50
7440-41-7
2.8J
mg/kg
3.1
1.5
1
04/12/16 14:11
04/13/16 07:50
7440-42-8
257
mg/kg
30.8
15.4
1
04/12/16 14:11
04/13/16 07:50
7440-70-2
14.3
mg/kg
0.31
0.15
1
04/12/16 14:11
04/13/16 07:50
7440-47-3
3.3
mg/kg
0.31
0.15
1
04/12/16 14:11
04/13/16 07:50
7440-50-8
878
mg/kg
2.5
1.2
1
04/12/16 14:11
04/13/16 07:50
7439-89-6
194
mg/kg
30.8
15.4
1
04/12/16 14:11
04/13/16 07:50
7439-95-4
3.9
mg/kg
0.31
0.15
1
04/12/16 14:11
04/13/16 07:50
7439-96-5
0.85
mg/kg
0.62
0.31
1
04/12/16 14:11
04/13/16 07:50
7439-98-7
3.8
mg/kg
0.31
0.15
1
04/12/16 14:11
04/13/16 07:50
7440-02-0
148
mg/kg
61.6
30.8
1
04/12/16 14:11
04/13/16 07:50
7440-09-7
ND
mg/kg
61.6
30.8
1
04/12/16 14:11
04/13/16 07:50
7440-23-5
5.0
mg/kg
0.62
0.31
1
04/12/16 14:11
04/13/16 07:50
7440-24-6
2.0
mg/kg
1.2
0.62
1
04/12/16 14:11
04/13/16 07:50
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
2.5
1.2
20
04/12/16 14:11
04/13/16 03:50
7440-36-0
0.63J
mg/kg
1.2
0.62
20
04/12/16 14:11
04/13/16 03:50
7440-38-2
ND
mg/kg
0.15
0.089
20
04/12/16 14:11
04/13/16 03:50
7440-43-9
0.65J
mg/kg
1.2
0.62
20
04/12/16 14:11
04/13/16 03:50
7440-48-4
1.3
mg/kg
1.2
1.2
20
04/12/16 14:11
04/13/16 03:50
7439-92-1
ND
mg/kg
1.2
0.62
20
04/12/16 14:11
04/13/16 03:50
7782-49-2
ND
mg/kg
1.2
0.62
20
04/12/16 14:11
04/13/16 03:50
7440-28-0
5.6
mg/kg
1.2
0.62
20
04/12/16 14:11
04/13/16 03:50
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.048 mg/kg 0.010 0.0050 1 04/13/1612:36 04/13/1617:31 7439-97-6
Analytical Method: ASTM D2974-87
22.5 % 0.10 0.10 1 04/12/1615:16
Analytical Method: EPA 9045
6.0 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
320
160 5
227J mg/kg
320
160 5
Analytical Method: EPA 9056
ND mg/kg
32.0
16.0 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
N2
04/09/1619:02 16887-00-6 D3
04/09/1619:02 14808-79-8 D3
04/09/1619:02 14797-55-8 D3,H3
Page 38 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009409 Lab ID: 92292703011 Collected: 03/30/16 14:50 Received: 04/06/16 13:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010A
Aluminum
911
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:20
7429-90-5
Barium
21.4
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:20
7440-39-3
Boron
ND
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:20
7440-42-8
Calcium
1070
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:20
7440-70-2
Iron
6290
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:20
7439-89-6
Magnesium
134
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:20
7439-95-4
Manganese
31.2
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:20
7439-96-5
Molybdenum
5.7
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:20
7439-98-7
Nickel
11.8
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:20
7440-02-0
Potassium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:20
7440-09-7
Sodium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:20
7440-23-5
Strontium
6.8
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:20
7440-24-6
Zinc
44.4
ug/L
10.0
5.0
1
04/08/16 15:10
04/12/16 00:20
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A
Antimony
0.74
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 03:56
7440-36-0
Arsenic
9.1
ug/L
0.10
0.050
1
04/13/16 14:30
04/20/16 03:56
7440-38-2
Beryllium
0.21
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 03:56
7440-41-7 B
Cadmium
0.34
ug/L
0.080
0.060
1
04/13/16 14:30
04/20/16 03:56
7440-43-9
Chromium
25.0
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 03:56
7440-47-3
Cobalt
11.7
ug/L
0.10
0.010
1
04/13/16 14:30
04/20/16 03:56
7440-48-4
Copper
20.4
ug/L
0.50
0.12
1
04/13/16 14:30
04/20/16 03:56
7440-50-8
Lead
3.4
ug/L
0.10
0.080
1
04/13/16 14:30
04/20/16 03:56
7439-92-1
Selenium
4.3
ug/L
0.50
0.32
1
04/13/16 14:30
04/20/16 03:56
7782-49-2
Thallium
0.19
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 03:56
7440-28-0
Vanadium
7.9
ug/L
0.50
0.070
1
04/13/16 14:30
04/20/16 03:56
7440-62-2
7470 Mercury
Analytical Method: EPA
7470 Preparation Method: EPA 7470
Mercury
ND
ug/L
0.20
0.10
1
04/11/1617:20
04/13/1616:50
7439-97-6
Date: 04/20/2016 04:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 39 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009410 Lab ID: 92292703012 Collected: 03/31/16 09:40 Received: 04/06/16 13:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010A
Aluminum
382
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:23
7429-90-5
Barium
3.8J
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:23
7440-39-3
Boron
ND
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:23
7440-42-8
Calcium
924
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:23
7440-70-2
Iron
3960
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:23
7439-89-6
Magnesium
71.5J
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:23
7439-95-4
Manganese
28.4
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:23
7439-96-5
Molybdenum
2.7J
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:23
7439-98-7
Nickel
4.OJ
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:23
7440-02-0
Potassium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:23
7440-09-7
Sodium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:23
7440-23-5
Strontium
2.7J
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:23
7440-24-6
Zinc
ND
ug/L
10.0
5.0
1
04/08/16 15:10
04/12/16 00:23
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A
Antimony
ND
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:01
7440-36-0
Arsenic
1.1
ug/L
0.10
0.050
1
04/13/16 14:30
04/20/16 04:01
7440-38-2
Beryllium
0.098J
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:01
7440-41-7 B
Cadmium
ND
ug/L
0.080
0.060
1
04/13/16 14:30
04/20/16 04:01
7440-43-9
Chromium
12.1
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:01
7440-47-3
Cobalt
0.73
ug/L
0.10
0.010
1
04/13/16 14:30
04/20/16 04:01
7440-48-4
Copper
4.5
ug/L
0.50
0.12
1
04/13/16 14:30
04/20/16 04:01
7440-50-8
Lead
1.9
ug/L
0.10
0.080
1
04/13/16 14:30
04/20/16 04:01
7439-92-1
Selenium
0.96
ug/L
0.50
0.32
1
04/13/16 14:30
04/20/16 04:01
7782-49-2
Thallium
ND
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:01
7440-28-0
Vanadium
2.0
ug/L
0.50
0.070
1
04/13/16 14:30
04/20/16 04:01
7440-62-2
7470 Mercury
Analytical Method: EPA
7470 Preparation Method: EPA 7470
Mercury
ND
ug/L
0.20
0.10
1
04/11/1617:20
04/13/1616:52
7439-97-6
Date: 04/20/2016 04:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 40 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009411 Lab ID: 92292703013 Collected: 03/29/16 15:45 Received: 04/06/16 13:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010A
Aluminum
502
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:26
7429-90-5
Barium
5.2
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:26
7440-39-3
Boron
ND
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:26
7440-42-8
Calcium
930
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:26
7440-70-2
Iron
1990
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:26
7439-89-6
Magnesium
256
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:26
7439-95-4
Manganese
29.5
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:26
7439-96-5
Molybdenum
ND
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:26
7439-98-7
Nickel
2.5J
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:26
7440-02-0
Potassium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:26
7440-09-7
Sodium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:26
7440-23-5
Strontium
ND
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:26
7440-24-6
Zinc
19.6
ug/L
10.0
5.0
1
04/08/16 15:10
04/12/16 00:26
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A
Antimony
ND
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:05
7440-36-0
Arsenic
0.16
ug/L
0.10
0.050
1
04/13/16 14:30
04/20/16 04:05
7440-38-2
Beryllium
0.030J
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:05
7440-41-7 B
Cadmium
ND
ug/L
0.080
0.060
1
04/13/16 14:30
04/20/16 04:05
7440-43-9
Chromium
4.3
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:05
7440-47-3
Cobalt
0.51
ug/L
0.10
0.010
1
04/13/16 14:30
04/20/16 04:05
7440-48-4
Copper
13.8
ug/L
0.50
0.12
1
04/13/16 14:30
04/20/16 04:05
7440-50-8
Lead
4.7
ug/L
0.10
0.080
1
04/13/16 14:30
04/20/16 04:05
7439-92-1
Selenium
ND
ug/L
0.50
0.32
1
04/13/16 14:30
04/20/16 04:05
7782-49-2
Thallium
ND
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:05
7440-28-0
Vanadium
1.3
ug/L
0.50
0.070
1
04/13/16 14:30
04/20/16 04:05
7440-62-2
7470 Mercury
Analytical Method: EPA
7470 Preparation Method: EPA 7470
Mercury
ND
ug/L
0.20
0.10
1
04/11/1617:20
04/13/1616:55
7439-97-6
Date: 04/20/2016 04:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 41 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009412 Lab ID: 92292703014 Collected: 03/30/16 07:40 Received: 04/06/16 13:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010A
Aluminum
600
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:30
7429-90-5
Barium
4.3J
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:30
7440-39-3
Boron
ND
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:30
7440-42-8
Calcium
1480
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:30
7440-70-2
Iron
3530
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:30
7439-89-6
Magnesium
120
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:30
7439-95-4
Manganese
20.8
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:30
7439-96-5
Molybdenum
4.OJ
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:30
7439-98-7
Nickel
3.7J
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:30
7440-02-0
Potassium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:30
7440-09-7
Sodium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:30
7440-23-5
Strontium
5.5
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:30
7440-24-6
Zinc
11.9
ug/L
10.0
5.0
1
04/08/16 15:10
04/12/16 00:30
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A
Antimony
0.18J
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:19
7440-36-0
Arsenic
0.83
ug/L
0.10
0.050
1
04/13/16 14:30
04/20/16 04:19
7440-38-2
Beryllium
0.049J
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:19
7440-41-7 B
Cadmium
ND
ug/L
0.080
0.060
1
04/13/16 14:30
04/20/16 04:19
7440-43-9
Chromium
16.0
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:19
7440-47-3
Cobalt
0.65
ug/L
0.10
0.010
1
04/13/16 14:30
04/20/16 04:19
7440-48-4
Copper
14.8
ug/L
0.50
0.12
1
04/13/16 14:30
04/20/16 04:19
7440-50-8
Lead
1.6
ug/L
0.10
0.080
1
04/13/16 14:30
04/20/16 04:19
7439-92-1
Selenium
ND
ug/L
0.50
0.32
1
04/13/16 14:30
04/20/16 04:19
7782-49-2
Thallium
ND
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:19
7440-28-0
Vanadium
1.7
ug/L
0.50
0.070
1
04/13/16 14:30
04/20/16 04:19
7440-62-2
7470 Mercury
Analytical Method: EPA
7470 Preparation Method: EPA 7470
Mercury
ND
ug/L
0.20
0.10
1
04/11/1617:20
04/13/1616:57
7439-97-6
Date: 04/20/2016 04:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 42 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009413 Lab ID: 92292703015 Collected: 03/30/16 09:50 Received: 04/06/16 13:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010A
Aluminum
3460
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:33
7429-90-5
Barium
7.9
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:33
7440-39-3
Boron
ND
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:33
7440-42-8
Calcium
1580
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:33
7440-70-2
Iron
4130
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:33
7439-89-6
Magnesium
174
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:33
7439-95-4
Manganese
27.1
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:33
7439-96-5
Molybdenum
4.3J
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:33
7439-98-7
Nickel
5.3
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:33
7440-02-0
Potassium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:33
7440-09-7
Sodium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:33
7440-23-5
Strontium
6.9
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:33
7440-24-6
Zinc
20.4
ug/L
10.0
5.0
1
04/08/16 15:10
04/12/16 00:33
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A
Antimony
0.25.1
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:23
7440-36-0
Arsenic
1.4
ug/L
0.10
0.050
1
04/13/16 14:30
04/20/16 04:23
7440-38-2
Beryllium
0.069J
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:23
7440-41-7 B
Cadmium
0.12
ug/L
0.080
0.060
1
04/13/16 14:30
04/20/16 04:23
7440-43-9
Chromium
12.8
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:23
7440-47-3
Cobalt
0.92
ug/L
0.10
0.010
1
04/13/16 14:30
04/20/16 04:23
7440-48-4
Copper
20.6
ug/L
0.50
0.12
1
04/13/16 14:30
04/20/16 04:23
7440-50-8
Lead
11.3
ug/L
0.10
0.080
1
04/13/16 14:30
04/20/16 04:23
7439-92-1
Selenium
1.2
ug/L
0.50
0.32
1
04/13/16 14:30
04/20/16 04:23
7782-49-2
Thallium
0.036J
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:23
7440-28-0
Vanadium
3.4
ug/L
0.50
0.070
1
04/13/16 14:30
04/20/16 04:23
7440-62-2
7470 Mercury
Analytical Method: EPA
7470 Preparation Method: EPA 7470
Mercury
ND
ug/L
0.20
0.10
1
04/11/1617:20
04/13/1616:59
7439-97-6
Date: 04/20/2016 04:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 43 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009414 Lab ID: 92292703016 Collected: 03/31/16 13:15 Received: 04/06/16 13:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010A
Aluminum
222
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:45
7429-90-5
Barium
ND
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:45
7440-39-3
Boron
ND
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:45
7440-42-8
Calcium
346
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:45
7440-70-2
Iron
854
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:45
7439-89-6
Magnesium
ND
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:45
7439-95-4
Manganese
5.3
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:45
7439-96-5
Molybdenum
ND
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:45
7439-98-7
Nickel
ND
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:45
7440-02-0
Potassium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:45
7440-09-7
Sodium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:45
7440-23-5
Strontium
ND
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:45
7440-24-6
Zinc
6.1J
ug/L
10.0
5.0
1
04/08/16 15:10
04/12/16 00:45
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A
Antimony
ND
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:28
7440-36-0
Arsenic
0.32
ug/L
0.10
0.050
1
04/13/16 14:30
04/20/16 04:28
7440-38-2
Beryllium
ND
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:28
7440-41-7
Cadmium
ND
ug/L
0.080
0.060
1
04/13/16 14:30
04/20/16 04:28
7440-43-9
Chromium
5.3
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:28
7440-47-3
Cobalt
0.11
ug/L
0.10
0.010
1
04/13/16 14:30
04/20/16 04:28
7440-48-4
Copper
2.9
ug/L
0.50
0.12
1
04/13/16 14:30
04/20/16 04:28
7440-50-8
Lead
0.49
ug/L
0.10
0.080
1
04/13/16 14:30
04/20/16 04:28
7439-92-1
Selenium
ND
ug/L
0.50
0.32
1
04/13/16 14:30
04/20/16 04:28
7782-49-2
Thallium
ND
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:28
7440-28-0
Vanadium
0.60
ug/L
0.50
0.070
1
04/13/16 14:30
04/20/16 04:28
7440-62-2
7470 Mercury
Analytical Method: EPA
7470 Preparation Method: EPA 7470
Mercury
ND
ug/L
0.20
0.10
1
04/11/1617:20
04/13/1617:07
7439-97-6
Date: 04/20/2016 04:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 44 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009415 Lab ID: 92292703017 Collected: 03/30/16 09:55 Received: 04/06/16 13:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010A
Aluminum
564
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:48
7429-90-5
Barium
9.4
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:48
7440-39-3
Boron
ND
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:48
7440-42-8
Calcium
696
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:48
7440-70-2
Iron
6020
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:48
7439-89-6
Magnesium
174
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:48
7439-95-4
Manganese
42.6
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:48
7439-96-5
Molybdenum
4.8J
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:48
7439-98-7
Nickel
4.1J
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:48
7440-02-0
Potassium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:48
7440-09-7
Sodium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:48
7440-23-5
Strontium
3.4J
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:48
7440-24-6
Zinc
20.4
ug/L
10.0
5.0
1
04/08/16 15:10
04/12/16 00:48
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A
Antimony
0.12J
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:32
7440-36-0
Arsenic
0.30
ug/L
0.10
0.050
1
04/13/16 14:30
04/20/16 04:32
7440-38-2
Beryllium
ND
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:32
7440-41-7
Cadmium
0.16
ug/L
0.080
0.060
1
04/13/16 14:30
04/20/16 04:32
7440-43-9
Chromium
28.6
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:32
7440-47-3
Cobalt
0.85
ug/L
0.10
0.010
1
04/13/16 14:30
04/20/16 04:32
7440-48-4
Copper
12.5
ug/L
0.50
0.12
1
04/13/16 14:30
04/20/16 04:32
7440-50-8
Lead
1.3
ug/L
0.10
0.080
1
04/13/16 14:30
04/20/16 04:32
7439-92-1
Selenium
ND
ug/L
0.50
0.32
1
04/13/16 14:30
04/20/16 04:32
7782-49-2
Thallium
ND
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:32
7440-28-0
Vanadium
1.6
ug/L
0.50
0.070
1
04/13/16 14:30
04/20/16 04:32
7440-62-2
7470 Mercury
Analytical Method: EPA
7470 Preparation Method: EPA 7470
Mercury
ND
ug/L
0.20
0.10
1
04/11/1617:20
04/13/1617:09
7439-97-6
Date: 04/20/2016 04:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 45 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009416 Lab ID: 92292703018 Collected: 03/31/16 13:31 Received: 04/06/16 13:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Boron
Calcium
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
Analytical Method: EPA 6010 Preparation Method: EPA 3010A
233
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:52
7429-90-5
3.7J
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:52
7440-39-3
ND
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:52
7440-42-8
1130
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:52
7440-70-2
1290
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:52
7439-89-6
67.9J
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:52
7439-95-4
13.1
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:52
7439-96-5
ND
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:52
7439-98-7
ND
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:52
7440-02-0
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:52
7440-09-7
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:52
7440-23-5
2.6J
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:52
7440-24-6
ND
ug/L
10.0
5.0
1
04/08/16 15:10
04/12/16 00:52
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A
Antimony
ND
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:37
7440-36-0
Arsenic
0.0911
ug/L
0.10
0.050
1
04/13/16 14:30
04/20/16 04:37
7440-38-2
Beryllium
ND
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:37
7440-41-7
Cadmium
ND
ug/L
0.080
0.060
1
04/13/16 14:30
04/20/16 04:37
7440-43-9
Chromium
3.6
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:37
7440-47-3
Cobalt
0.22
ug/L
0.10
0.010
1
04/13/16 14:30
04/20/16 04:37
7440-48-4
Copper
2.6
ug/L
0.50
0.12
1
04/13/16 14:30
04/20/16 04:37
7440-50-8
Lead
1.1
ug/L
0.10
0.080
1
04/13/16 14:30
04/20/16 04:37
7439-92-1
Selenium
ND
ug/L
0.50
0.32
1
04/13/16 14:30
04/20/16 04:37
7782-49-2
Thallium
ND
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:37
7440-28-0
Vanadium
0.29J
ug/L
0.50
0.070
1
04/13/16 14:30
04/20/16 04:37
7440-62-2
7470 Mercury
Analytical Method: EPA
7470 Preparation Method: EPA 7470
Mercury
ND
ug/L
0.20
0.10
1
04/11/1617:20
04/13/1617:11
7439-97-6
Date: 04/20/2016 04:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
B
Page 46 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009417 Lab ID: 92292703019 Collected: 03/30/16 13:53 Received: 04/06/16 13:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010A
Aluminum
852
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:55
7429-90-5
Barium
7.9
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:55
7440-39-3
Boron
ND
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:55
7440-42-8
Calcium
1320
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:55
7440-70-2
Iron
1320
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:55
7439-89-6
Magnesium
80.2J
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:55
7439-95-4
Manganese
16.2
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:55
7439-96-5
Molybdenum
ND
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:55
7439-98-7
Nickel
2.5J
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:55
7440-02-0
Potassium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:55
7440-09-7
Sodium
ND
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:55
7440-23-5
Strontium
4.6J
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:55
7440-24-6
Zinc
8.5J
ug/L
10.0
5.0
1
04/08/16 15:10
04/12/16 00:55
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A
Antimony
ND
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:50
7440-36-0
Arsenic
1.4
ug/L
0.10
0.050
1
04/13/16 14:30
04/20/16 04:50
7440-38-2
Beryllium
0.039J
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:50
7440-41-7 B
Cadmium
ND
ug/L
0.080
0.060
1
04/13/16 14:30
04/20/16 04:50
7440-43-9
Chromium
2.7
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:50
7440-47-3 B
Cobalt
0.95
ug/L
0.10
0.010
1
04/13/16 14:30
04/20/16 04:50
7440-48-4
Copper
2.4
ug/L
0.50
0.12
1
04/13/16 14:30
04/20/16 04:50
7440-50-8
Lead
6.0
ug/L
0.10
0.080
1
04/13/16 14:30
04/20/16 04:50
7439-92-1
Selenium
ND
ug/L
0.50
0.32
1
04/13/16 14:30
04/20/16 04:50
7782-49-2
Thallium
0.10
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:50
7440-28-0
Vanadium
1.2
ug/L
0.50
0.070
1
04/13/16 14:30
04/20/16 04:50
7440-62-2
7470 Mercury
Analytical Method: EPA
7470 Preparation Method: EPA 7470
Mercury
ND
ug/L
0.20
0.10
1
04/11/1617:20
04/13/1617:14
7439-97-6
Date: 04/20/2016 04:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 47 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009418 Lab ID: 92292703020 Collected: 03/29/16 15:45 Received: 04/06/16 13:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010A
Aluminum
6080
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:58
7429-90-5
Barium
88.7
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:58
7440-39-3
Boron
32.1J
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:58
7440-42-8
Calcium
87500
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:58
7440-70-2
Iron
10800
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 00:58
7439-89-6
Magnesium
7260
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 00:58
7439-95-4
Manganese
391
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:58
7439-96-5
Molybdenum
ND
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:58
7439-98-7
Nickel
13.2
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:58
7440-02-0
Potassium
5400
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:58
7440-09-7
Sodium
16100
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 00:58
7440-23-5
Strontium
158
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 00:58
7440-24-6
Zinc
362
ug/L
10.0
5.0
1
04/08/16 15:10
04/12/16 00:58
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A
Antimony
0.26J
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:55
7440-36-0
Arsenic
2.9
ug/L
0.10
0.050
1
04/13/16 14:30
04/20/16 04:55
7440-38-2
Beryllium
0.40
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:55
7440-41-7
Cadmium
0.24
ug/L
0.080
0.060
1
04/13/16 14:30
04/20/16 04:55
7440-43-9
Chromium
20.4
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:55
7440-47-3
Cobalt
3.9
ug/L
0.10
0.010
1
04/13/16 14:30
04/20/16 04:55
7440-48-4
Copper
126
ug/L
0.50
0.12
1
04/13/16 14:30
04/20/16 04:55
7440-50-8
Lead
19.8
ug/L
0.10
0.080
1
04/13/16 14:30
04/20/16 04:55
7439-92-1
Selenium
3.0
ug/L
0.50
0.32
1
04/13/16 14:30
04/20/16 04:55
7782-49-2
Thallium
0.15
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:55
7440-28-0
Vanadium
10.2
ug/L
0.50
0.070
1
04/13/16 14:30
04/20/16 04:55
7440-62-2
7470 Mercury
Analytical Method: EPA
7470 Preparation Method: EPA 7470
Mercury
ND
ug/L
0.20
0.10
1
04/11/1617:20
04/13/1617:16
7439-97-6
Date: 04/20/2016 04:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 48 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009419 Lab ID: 92292703021 Collected: 03/30/16 10:20 Received: 04/06/16 13:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010A
Aluminum
203
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 01:01
7429-90-5
Barium
100
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 01:01
7440-39-3
Boron
ND
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 01:01
7440-42-8
Calcium
36600
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 01:01
7440-70-2
Iron
1970
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 01:01
7439-89-6
Magnesium
2200
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 01:01
7439-95-4
Manganese
15.6
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 01:01
7439-96-5
Molybdenum
ND
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 01:01
7439-98-7
Nickel
ND
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 01:01
7440-02-0
Potassium
2830J
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 01:01
7440-09-7
Sodium
13000
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 01:01
7440-23-5
Strontium
213
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 01:01
7440-24-6
Zinc
52.3
ug/L
10.0
5.0
1
04/08/16 15:10
04/12/16 01:01
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A
Antimony
0.12J
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:59
7440-36-0
Arsenic
4.7
ug/L
0.10
0.050
1
04/13/16 14:30
04/20/16 04:59
7440-38-2
Beryllium
0.079J
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:59
7440-41-7 B
Cadmium
ND
ug/L
0.080
0.060
1
04/13/16 14:30
04/20/16 04:59
7440-43-9
Chromium
0.32J
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 04:59
7440-47-3 B
Cobalt
0.19
ug/L
0.10
0.010
1
04/13/16 14:30
04/20/16 04:59
7440-48-4
Copper
80.4
ug/L
0.50
0.12
1
04/13/16 14:30
04/20/16 04:59
7440-50-8
Lead
12.9
ug/L
0.10
0.080
1
04/13/16 14:30
04/20/16 04:59
7439-92-1
Selenium
0.70
ug/L
0.50
0.32
1
04/13/16 14:30
04/20/16 04:59
7782-49-2
Thallium
ND
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 04:59
7440-28-0
Vanadium
2.1
ug/L
0.50
0.070
1
04/13/16 14:30
04/20/16 04:59
7440-62-2
7470 Mercury
Analytical Method: EPA
7470 Preparation Method: EPA 7470
Mercury
ND
ug/L
0.20
0.10
1
04/11/1617:20
04/13/1617:18
7439-97-6
Date: 04/20/2016 04:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 49 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J16040066
Pace Project No.: 92292703
Sample: 2016009420 Lab ID: 92292703022 Collected: 03/31/16 13:25 Received: 04/06/16 13:25 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010A
Aluminum
ND
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 01:04
7429-90-5
Barium
99.8
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 01:04
7440-39-3
Boron
ND
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 01:04
7440-42-8
Calcium
36300
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 01:04
7440-70-2
Iron
94.1
ug/L
50.0
25.0
1
04/08/16 15:10
04/12/16 01:04
7439-89-6
Magnesium
2090
ug/L
100
50.0
1
04/08/16 15:10
04/12/16 01:04
7439-95-4
Manganese
ND
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 01:04
7439-96-5
Molybdenum
2.9J
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 01:04
7439-98-7
Nickel
ND
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 01:04
7440-02-0
Potassium
2670J
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 01:04
7440-09-7
Sodium
12700
ug/L
5000
2500
1
04/08/16 15:10
04/12/16 01:04
7440-23-5
Strontium
210
ug/L
5.0
2.5
1
04/08/16 15:10
04/12/16 01:04
7440-24-6
Zinc
19.6
ug/L
10.0
5.0
1
04/08/16 15:10
04/12/16 01:04
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A
Antimony
0.13J
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 05:13
7440-36-0
Arsenic
4.6
ug/L
0.10
0.050
1
04/13/16 14:30
04/20/16 05:13
7440-38-2
Beryllium
ND
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 05:13
7440-41-7
Cadmium
ND
ug/L
0.080
0.060
1
04/13/16 14:30
04/20/16 05:13
7440-43-9
Chromium
0.18J
ug/L
0.50
0.10
1
04/13/16 14:30
04/20/16 05:13
7440-47-3 B
Cobalt
ND
ug/L
0.10
0.010
1
04/13/16 14:30
04/20/16 05:13
7440-48-4
Copper
4.2
ug/L
0.50
0.12
1
04/13/16 14:30
04/20/16 05:13
7440-50-8
Lead
1.1
ug/L
0.10
0.080
1
04/13/16 14:30
04/20/16 05:13
7439-92-1
Selenium
0.83
ug/L
0.50
0.32
1
04/13/16 14:30
04/20/16 05:13
7782-49-2
Thallium
ND
ug/L
0.10
0.020
1
04/13/16 14:30
04/20/16 05:13
7440-28-0
Vanadium
1.4
ug/L
0.50
0.070
1
04/13/16 14:30
04/20/16 05:13
7440-62-2
7470 Mercury
Analytical Method: EPA
7470 Preparation Method: EPA 7470
Mercury
ND
ug/L
0.20
0.10
1
04/11/1617:20
04/13/1617:21
7439-97-6
Date: 04/20/2016 04:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 50 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040066
Pace Project No.: 92292703
QC Batch: MERP/9234 Analysis Method: EPA 7470
QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury
Associated Lab Samples: 92292703011,92292703012,92292703013,92292703014,92292703015,92292703016,92292703017,
92292703018,92292703019,92292703020,92292703021,92292703022
METHOD BLANK: 1706328 Matrix: Water
Associated Lab Samples: 92292703011,92292703012,92292703013,92292703014,92292703015,92292703016,92292703017,
92292703018,92292703019,92292703020,92292703021,92292703022
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Mercury ug/L ND 0.20 0.10 04/13/1616:38
LABORATORY CONTROL SAMPLE: 1706329
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.3 90 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1706330 1706331
MS MSD
92292603002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Mercury ug/L ND 2.5 2.5 2.3 2.5 93 98 75-125 6 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 04:50 PM without the written consent of Pace Analytical Services, Inc..
Page 51 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040066
Pace Project No.: 92292703
QC Batch: MERP/6790 Analysis Method: EPA 7471
QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury
Associated Lab Samples: 92292703001, 92292703002, 92292703003, 92292703004, 92292703005, 92292703006, 92292703007,
92292703008,92292703009,92292703010
METHOD BLANK: 1538417 Matrix: Solid
Associated Lab Samples: 92292703001, 92292703002, 92292703003, 92292703004, 92292703005, 92292703006, 92292703007,
92292703008,92292703009,92292703010
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Mercury mg/kg ND 0.0077 0.0039 04/13/1616:33
LABORATORY CONTROL SAMPLE: 1538418
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury mg/kg .083 0.086 104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1538419 1538420
MS MSD
35237913002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Mercury mg/kg 0.028 .0869 .0827 0.12 0.098 103 84 80-120 18 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 04:50 PM without the written consent of Pace Analytical Services, Inc..
Page 52 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040066
Pace Project No.: 92292703
QC Batch: MPRP/29721 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92292703001, 92292703002, 92292703003, 92292703004, 92292703005, 92292703006, 92292703007,
92292703008,92292703009,92292703010
METHOD BLANK: 1536634 Matrix: Solid
Associated Lab Samples: 92292703001, 92292703002, 92292703003, 92292703004, 92292703005, 92292703006, 92292703007,
92292703008,92292703009,92292703010
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Aluminum
mg/kg
ND
5.1
2.6
04/13/16 06:37
Barium
mg/kg
ND
0.51
0.26
04/13/16 06:37
Beryllium
mg/kg
ND
0.051
0.026
04/13/16 06:37
Boron
mg/kg
ND
2.6
1.3
04/13/16 06:37
Calcium
mg/kg
ND
25.7
12.9
04/13/16 06:37
Chromium
mg/kg
ND
0.26
0.13
04/13/16 06:37
Copper
mg/kg
ND
0.26
0.13
04/13/16 06:37
Iron
mg/kg
ND
2.1
1.0
04/13/16 06:37
Magnesium
mg/kg
ND
25.7
12.9
04/13/16 06:37
Manganese
mg/kg
ND
0.26
0.13
04/13/16 06:37
Molybdenum
mg/kg
ND
0.51
0.26
04/13/16 06:37
Nickel
mg/kg
ND
0.26
0.13
04/13/16 06:37
Potassium
mg/kg
ND
51.4
25.7
04/13/16 06:37
Sodium
mg/kg
ND
51.4
25.7
04/13/16 06:37
Strontium
mg/kg
ND
0.51
0.26
04/13/16 06:37
Zinc
mg/kg
ND
1.0
0.51
04/13/16 06:37
LABORATORY CONTROL SAMPLE:
1536635
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Aluminum
mg/kg
121
119
99
80-120
Barium
mg/kg
12.1
12.3
102
80-120
Beryllium
mg/kg
1.2
1.2
100
80-120
Boron
mg/kg
121
109
90
80-120
Calcium
mg/kg
606
612
101
80-120
Chromium
mg/kg
12.1
12.8
106
80-120
Copper
mg/kg
12.1
12.7
105
80-120
Iron
mg/kg
121
123
101
80-120
Magnesium
mg/kg
606
605
100
80-120
Manganese
mg/kg
12.1
13.1
109
80-120
Molybdenum
mg/kg
12.1
12.5
103
80-120
Nickel
mg/kg
12.1
12.4
103
80-120
Potassium
mg/kg
606
608
100
80-120
Sodium
mg/kg
606
618
102
80-120
Strontium
mg/kg
12.1
12.1
100
80-120
Zinc
mg/kg
60.6
58.0
96
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 04:50 PM without the written consent of Pace Analytical Services, Inc.. Page 53 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040066
Pace Project No.: 92292703
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1536636
1536637
MS
MSD
92292703001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
5970
186
175
12000
7600
3220
929
75-125
45
20 M1,R1
Barium
mg/kg
37.2
18.6
17.5
59.3
51.6
119
82
75-125
14
20
Beryllium
mg/kg
0.44
1.89
1.75
2.0
1.7
85
74
75-125
15
20 M1
Boron
mg/kg
4.6
186
175
145
134
76
74
75-125
8
20 M1
Calcium
mg/kg
190000
930
874
193000
191000
332
170
75-125
1
20 M6
Chromium
mg/kg
19.8
18.6
17.5
38.4
31.5
100
67
75-125
20
20 M1
Copper
mg/kg
4.4
18.6
17.5
21.9
18.4
94
80
75-125
17
20
Iron
mg/kg
9460
186
175
10200
6850
412
-1490
75-125
40
20 M1,R1
Magnesium
mg/kg
1810
930
874
3060
2000
135
22
75-125
42
20 M1,R1
Manganese
mg/kg
109
18.6
17.5
117
103
42
-36
75-125
13
20 M1
Molybdenum
mg/kg
6.6
18.6
17.5
21.1
18.3
78
67
75-125
14
20 M1
Nickel
mg/kg
4.2
18.6
17.5
19.3
16.2
81
69
75-125
17
20 M1
Potassium
mg/kg
594
930
874
1740
1370
123
88
75-125
24
20 R1
Sodium
mg/kg
1620
930
874
2550
2310
100
79
75-125
10
20
Strontium
mg/kg
1030
18.6
17.5
1040
1220
28
1090
75-125
16
20 M6
Zinc
mg/kg
16.9
93
87.4
96.7
83.6
86
76
75-125
15
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 04:50 PM without the written consent of Pace Analytical Services, Inc..
Page 54 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040066
Pace Project No.: 92292703
QC Batch: MPRP/21291 Analysis Method: EPA 6010
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92292703011,92292703012,92292703013,92292703014,92292703015,92292703016,92292703017,
92292703018,92292703019,92292703020,92292703021,92292703022
METHOD BLANK: 1704461 Matrix: Water
Associated Lab Samples: 92292703011,92292703012,92292703013,92292703014,92292703015,92292703016,92292703017,
92292703018,92292703019,92292703020,92292703021,92292703022
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Aluminum
ug/L
ND
100
50.0
04/11/16 23:53
Barium
ug/L
ND
5.0
2.5
04/11/16 23:53
Boron
ug/L
ND
50.0
25.0
04/11/16 23:53
Calcium
ug/L
ND
100
50.0
04/11/16 23:53
Iron
ug/L
ND
50.0
25.0
04/11/16 23:53
Magnesium
ug/L
ND
100
50.0
04/11/16 23:53
Manganese
ug/L
ND
5.0
2.5
04/11/16 23:53
Molybdenum
ug/L
ND
5.0
2.5
04/11/16 23:53
Nickel
ug/L
ND
5.0
2.5
04/11/16 23:53
Potassium
ug/L
ND
5000
2500
04/11/16 23:53
Sodium
ug/L
ND
5000
500
04/11/16 23:53
Strontium
ug/L
ND
5.0
2.5
04/11/16 23:53
Zinc
ug/L
ND
10.0
5.0
04/11/16 23:53
LABORATORY CONTROL SAMPLE:
Parameter
1704462
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug/L
5000
5050
101
80-120
Barium
ug/L
500
510
102
80-120
Boron
ug/L
500
507
101
80-120
Calcium
ug/L
5000
5100
102
80-120
Iron
ug/L
5000
5190
104
80-120
Magnesium
ug/L
5000
4940
99
80-120
Manganese
ug/L
500
472
94
80-120
Molybdenum
ug/L
500
516
103
80-120
Nickel
ug/L
500
486
97
80-120
Potassium
ug/L
5000
5220
104
80-120
Sodium
ug/L
5000
5070
101
80-120
Strontium
ug/L
500
497
99
80-120
Zinc
ug/L
500
467
93
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1704463
1704464
MS
MSD
92292420002 Spike
Spike
MS
MSD MS
MSD
% Rec Max
Parameter Units Result Conc.
Conc.
Result
Result % Rec
% Rec
Limits RPD RPD Qua]
Aluminum ug/L ND 5000
5000
4900
5010 97
100
75-125 2 20
Barium ug/L 30.8 500
500
519
532 98
100
75-125 2 20
Results presented on this page are in the units indicated by the
"Units" column except where
an alternate unit is presented to the right
of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 04:50 PM without the written consent of Pace Analytical Services, Inc..
Page 55 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040066
Pace Project No.: 92292703
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 1704463
1704464
MS
MSD
92292420002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Boron
ug/L
38.8J
500
500
537
545
100
101
75-125
1
20
Calcium
ug/L
37500
5000
5000
40500
40900
60
69
75-125
1
20 M1
Iron
ug/L
44.8J
5000
5000
5030
5150
100
102
75-125
2
20
Magnesium
ug/L
6290
5000
5000
10800
10900
89
92
75-125
1
20
Manganese
ug/L
132
500
500
581
591
90
92
75-125
2
20
Molybdenum
ug/L
ND
500
500
502
516
100
103
75-125
3
20
Nickel
ug/L
ND
500
500
461
472
92
94
75-125
2
20
Potassium
ug/L
13200
5000
5000
17700
17900
90
93
75-125
1
20
Sodium
ug/L
61900
5000
5000
64200
64300
46
48
75-125
0
20 M1
Strontium
ug/L
214
500
500
683
694
94
96
75-125
2
20
Zinc
ug/L
5.7J
500
500
456
466
90
92
75-125
2
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 04:50 PM without the written consent of Pace Analytical Services, Inc..
Page 56 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040066
Pace Project No.: 92292703
QC Batch: MPRP/29707 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92292703001, 92292703002, 92292703003, 92292703004, 92292703005, 92292703006, 92292703007,
92292703008,92292703009,92292703010
METHOD BLANK: 1536508
Matrix:
Solid
Associated Lab Samples:
92292703001, 92292703002,
92292703003, 92292703004, 92292703005, 92292703006,
92292703007,
92292703008,92292703009,92292703010
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
Antimony
mg/kg
ND
2.1
1.0
04/13/16 02:20 N2
Arsenic
mg/kg
ND
1.0
0.52
04/13/16 02:20
Cadmium
mg/kg
ND
0.12
0.074
04/13/16 02:20
Cobalt
mg/kg
ND
1.0
0.52
04/13/16 02:20
Lead
mg/kg
ND
1.0
1.0
04/13/16 02:20
Selenium
mg/kg
ND
1.0
0.52
04/13/16 02:20
Thallium
mg/kg
ND
1.0
0.52
04/13/16 02:20
Vanadium
mg/kg
ND
1.0
0.52
04/13/16 02:20
LABORATORY CONTROL SAMPLE:
Parameter
1536509
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
mg/kg
2.6
2.4
93
80-120 N2
Arsenic
mg/kg
2.6
2.5
98
80-120
Cadmium
mg/kg
.26
0.25
96
80-120
Cobalt
mg/kg
2.6
2.8
108
80-120
Lead
mg/kg
2.6
2.6
102
80-120
Selenium
mg/kg
2.6
2.4
94
80-120
Thallium
mg/kg
2.6
2.7
103
80-120
Vanadium
mg/kg
2.6
2.8
109
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1536510
1536511
MS
MSD
35238147001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
mg/kg
1.0U
2.54
2.44
1.91
1.7J
72
69
75-125
20 M6, N2
Arsenic
mg/kg
0.51 U
2.54
2.44
2.5
2.4
81
81
75-125
3
20
Cadmium
mg/kg
0.18U
.254
.244
0.24
0.28J
65
86
75-125
20 M6
Cobalt
mg/kg
1.3U
2.54
2.44
2.2
2.3J
81
91
75-125
20
Lead
mg/kg
1.0U
2.54
2.44
2.9
2.8
83
82
75-125
4
20
Selenium
mg/kg
1.3U
2.54
2.44
1.9
2.2J
60
73
75-125
20 M6
Thallium
mg/kg
0.51 U
2.54
2.44
2.3
2.2
90
90
75-125
3
20
Vanadium
mg/kg
4.0
2.54
2.44
6.0
6.4
76
97
75-125
7
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 04:50 PM without the written consent of Pace Analytical Services, Inc..
Page 57 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040066
Pace Project No.: 92292703
QC Batch: MPRP/21339 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Associated Lab Samples: 92292703011,92292703012,92292703013,92292703014,92292703015,92292703016,92292703017,
92292703018,92292703019,92292703020,92292703021,92292703022
METHOD BLANK: 1707723 Matrix: Water
Associated Lab Samples: 92292703011,92292703012,92292703013,92292703014,92292703015,92292703016,92292703017,
92292703018,92292703019,92292703020,92292703021,92292703022
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Antimony
ug/L
ND
0.50
0.10
04/20/16 03:25
Arsenic
ug/L
ND
0.10
0.050
04/20/16 03:25
Beryllium
ug/L
0.030J
0.10
0.020
04/20/16 03:25
Cadmium
ug/L
ND
0.080
0.060
04/20/16 03:25
Chromium
ug/L
0.37J
0.50
0.10
04/20/16 03:25
Cobalt
ug/L
ND
0.10
0.010
04/20/16 03:25
Copper
ug/L
ND
0.50
0.12
04/20/16 03:25
Lead
ug/L
ND
0.10
0.080
04/20/16 03:25
Selenium
ug/L
ND
0.50
0.32
04/20/16 03:25
Thallium
ug/L
ND
0.10
0.020
04/20/16 03:25
Vanadium
ug/L
ND
0.50
0.070
04/20/16 03:25
LABORATORY CONTROL SAMPLE:
Parameter
1707724
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
ug/L
100
104
104
80-120
Arsenic
ug/L
100
98.9
99
80-120
Beryllium
ug/L
100
95.5
96
80-120
Cadmium
ug/L
100
104
104
80-120
Chromium
ug/L
100
97.1
97
80-120
Cobalt
ug/L
100
100
100
80-120
Copper
ug/L
100
102
102
80-120
Lead
ug/L
100
107
107
80-120
Selenium
ug/L
100
99.9
100
80-120
Thallium
ug/L
100
107
107
80-120
Vanadium
ug/L
100
97.1
97
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1707725
1707726
MS
MSD
92292612007
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qua]
Antimony
ug/L
0.30J
100
100
102
97.8
102
97
75-125
4
20
Arsenic
ug/L
0.18
100
100
96.4
92.4
96
92
75-125
4
20
Beryllium
ug/L
0.059J
100
100
91.9
89.0
92
89
75-125
3
20
Cadmium
ug/L
ND
100
100
101
96.1
101
96
75-125
5
20
Chromium
ug/L
0.70
100
100
92.3
87.0
92
86
75-125
6
20
Cobalt
ug/L
0.42
100
100
93.4
88.6
93
88
75-125
5
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 04:50 PM without the written consent of Pace Analytical Services, Inc..
Page 58 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040066
Pace Project No.: 92292703
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1707725
1707726
MS
MSD
92292612007
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qua]
Copper
ug/L
3.6
100
100
98.2
93.3
95
90
75-125
5
20
Lead
ug/L
ND
100
100
103
98.8
103
99
75-125
4
20
Selenium
ug/L
ND
100
100
98.5
94.1
99
94
75-125
5
20
Thallium
ug/L
ND
100
100
103
100
103
100
75-125
3
20
Vanadium
ug/L
2.2
100
100
96.2
90.6
94
88
75-125
6
20
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1707727
1707728
MS
MSD
92292703018
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
100
100
101
98.5
101
98
75-125
3
20
Arsenic
ug/L
0.0911
100
100
96.3
92.7
96
93
75-125
4
20
Beryllium
ug/L
ND
100
100
91.1
88.7
91
89
75-125
3
20
Cadmium
ug/L
ND
100
100
102
98.1
102
98
75-125
4
20
Chromium
ug/L
3.6
100
100
97.4
92.5
94
89
75-125
5
20
Cobalt
ug/L
0.22
100
100
97.2
92.9
97
93
75-125
5
20
Copper
ug/L
2.6
100
100
101
96.7
99
94
75-125
4
20
Lead
ug/L
1.1
100
100
106
102
105
101
75-125
3
20
Selenium
ug/L
ND
100
100
100
96.0
100
96
75-125
4
20
Thallium
ug/L
ND
100
100
105
101
105
101
75-125
3
20
Vanadium
ug/L
0.29J
100
100
94.5
89.8
94
90
75-125
5
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 04:50 PM without the written consent of Pace Analytical Services, Inc..
Page 59 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040066
Pace Project No.: 92292703
QC Batch: PMST/4397
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples: 92292703001,
92292703002, 92292703003, 92292703004,
92292703005, 92292703006,
92292703007,
92292703008,92292703009,92292703010
SAMPLE DUPLICATE: 1537214
35238412001
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
42.7
44.4 4
10
SAMPLE DUPLICATE: 1537215
35238412011
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
29.0
28.5 2
10
SAMPLE DUPLICATE: 1537216
35238416008
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
9.0
9.4 4
10
SAMPLE DUPLICATE: 1537217
92292703007
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
17.8
18.1 2
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 04:50 PM without the written consent of Pace Analytical Services, Inc.. Page 60 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040066
Pace Project No.: 92292703
QC Batch: WETA/56664
Analysis Method: EPA 9056
QC Batch Method: EPA 9056
Analysis Description: 9056 IC Anions
Associated Lab Samples: 92292703001, 92292703002, 92292703003, 92292703004, 92292703005, 92292703006, 92292703007,
92292703008,92292703009,92292703010
METHOD BLANK: 1534827
Matrix: Solid
Associated Lab Samples: 92292703001, 92292703002, 92292703003, 92292703004, 92292703005, 92292703006, 92292703007,
92292703008,92292703009,92292703010
Blank Reporting
Parameter
Units
Result Limit MDL
Analyzed Qualifiers
Chloride
mg/kg
ND 49.9 25.0
04/09/1611:32
Sulfate
mg/kg
ND 49.9 25.0
04/09/1611:32
LABORATORY CONTROL SAMPLE:
1534828
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Chloride
mg/kg
495 472 95
80-120
Sulfate
mg/kg
495 468 95
80-120
MATRIX SPIKE SAMPLE:
1534830
92292703001 Spike MS
MS % Rec
Parameter
Units
Result Conc. Result
% Rec Limits Qualifiers
Chloride
mg/kg
ND 723 638
88 80-120
Sulfate
mg/kg
ND 723 701
80 80-120
SAMPLE DUPLICATE: 1534829
92292703001 Dup
Max
Parameter
Units
Result Result RPD
RPD Qualifiers
Chloride
mg/kg
ND ND
20
Sulfate
mg/kg
ND ND
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 04:50 PM without the written consent of Pace Analytical Services, Inc.. Page 61 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J16040066
Pace Project No.: 92292703
QC Batch: WETA/56665
Analysis Method: EPA 9056
QC Batch Method: EPA 9056
Analysis Description: 9056 IC Anions
Associated Lab Samples: 92292703001, 92292703002, 92292703003, 92292703004, 92292703005, 92292703006,
92292703007,
92292703008,92292703009,92292703010
METHOD BLANK: 1534831
Matrix: Solid
Associated Lab Samples: 92292703001, 92292703002, 92292703003, 92292703004, 92292703005, 92292703006,
92292703007,
92292703008,92292703009,92292703010
Blank Reporting
Parameter
Units
Result Limit MDL
Analyzed Qualifiers
Nitrate as N
mg/kg
ND 5.0 2.5
04/09/16 11:32
LABORATORY CONTROL SAMPLE:
1534832
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Nitrate as N
mg/kg
49.5 48.5 98
80-120
MATRIX SPIKE SAMPLE:
1534834
92292703001 Spike MS
MS % Rec
Parameter
Units
Result Conc. Result
% Rec Limits Qualifiers
Nitrate as N
mg/kg
ND 72.3 64.9
90 80-120 H3
SAMPLE DUPLICATE: 1534833
92292703001 Dup
Max
Parameter
Units
Result Result RPD
RPD Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 04:50 PM without the written consent of Pace Analytical Services, Inc.. Page 62 of 69

Pace Analytical Services, Inc
aceAnalXical ® 9800 Kiney Ave. Suite 100
Huntersville, NC 28078078
www.pacelabs.com [phone]
QUALIFIERS
Project: J16040066
Pace Project No.: 92292703
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
B Analyte was detected in the associated method blank.
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
H3 Sample was received or analysis requested beyond the recognized method holding time.
H6 Analysis initiated outside of the 15 minute EPA required holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold TN accreditation for this parameter.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 04:50 PM without the written consent of Pace Analytical Services, Inc.. Page 63 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16040066
Pace Project No.: 92292703
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92292703001
2016009393
EPA 3050
MPRP/29721
EPA 6010
ICP/17789
92292703002
2016009396
EPA 3050
MPRP/29721
EPA 6010
ICP/17789
92292703003
2016009397
EPA 3050
MPRP/29721
EPA 6010
ICP/17789
92292703004
2016009398
EPA 3050
MPRP/29721
EPA 6010
ICP/17789
92292703005
2016009399
EPA 3050
MPRP/29721
EPA 6010
ICP/17789
92292703006
2016009400
EPA 3050
MPRP/29721
EPA6010
ICP/17789
92292703007
2016009401
EPA 3050
MPRP/29721
EPA6010
ICP/17789
92292703008
2016009402
EPA 3050
MPRP/29721
EPA 6010
ICP/17789
92292703009
2016009403
EPA 3050
MPRP/29721
EPA 6010
ICP/17789
92292703010
2016009404
EPA 3050
MPRP/29721
EPA 6010
ICP/17789
92292703011
2016009409
EPA 3010A
MPRP/21291
EPA6010
ICP/19152
92292703012
2016009410
EPA 3010A
MPRP/21291
EPA6010
ICP/19152
92292703013
2016009411
EPA 3010A
MPRP/21291
EPA6010
ICP/19152
92292703014
2016009412
EPA 3010A
MPRP/21291
EPA6010
ICP/19152
92292703015
2016009413
EPA 3010A
MPRP/21291
EPA 6010
ICP/19152
92292703016
2016009414
EPA 3010A
MPRP/21291
EPA6010
ICP/19152
92292703017
2016009415
EPA 3010A
MPRP/21291
EPA 6010
ICP/19152
92292703018
2016009416
EPA 3010A
MPRP/21291
EPA 6010
ICP/19152
92292703019
2016009417
EPA 3010A
MPRP/21291
EPA6010
ICP/19152
92292703020
2016009418
EPA 3010A
MPRP/21291
EPA6010
ICP/19152
92292703021
2016009419
EPA 3010A
MPRP/21291
EPA6010
ICP/19152
92292703022
2016009420
EPA 3010A
MPRP/21291
EPA 6010
ICP/19152
92292703001
2016009393
EPA 3050
MPRP/29707
EPA 6020
ICPM/12019
92292703002
2016009396
EPA 3050
MPRP/29707
EPA 6020
ICPM/12019
92292703003
2016009397
EPA 3050
MPRP/29707
EPA 6020
ICPM/12019
92292703004
2016009398
EPA 3050
MPRP/29707
EPA 6020
ICPM/12019
92292703005
2016009399
EPA 3050
MPRP/29707
EPA 6020
ICPM/12019
92292703006
2016009400
EPA 3050
MPRP/29707
EPA 6020
ICPM/12019
92292703007
2016009401
EPA 3050
MPRP/29707
EPA 6020
ICPM/12019
92292703008
2016009402
EPA 3050
MPRP/29707
EPA 6020
ICPM/12019
92292703009
2016009403
EPA 3050
MPRP/29707
EPA 6020
ICPM/12019
92292703010
2016009404
EPA 3050
MPRP/29707
EPA 6020
ICPM/12019
92292703011
2016009409
EPA 3010A
MPRP/21339
EPA 6020B
ICPM/1155
92292703012
2016009410
EPA 3010A
MPRP/21339
EPA 6020B
ICPM/1155
92292703013
2016009411
EPA 3010A
MPRP/21339
EPA 6020B
ICPM/1155
92292703014
2016009412
EPA 3010A
MPRP/21339
EPA 6020E
ICPM/1155
92292703015
2016009413
EPA 3010A
MPRP/21339
EPA 6020B
ICPM/1155
92292703016
2016009414
EPA 3010A
MPRP/21339
EPA 6020B
ICPM/1155
92292703017
2016009415
EPA 3010A
MPRP/21339
EPA 6020B
ICPM/1155
92292703018
2016009416
EPA 3010A
MPRP/21339
EPA 6020B
ICPM/1155
92292703019
2016009417
EPA 3010A
MPRP/21339
EPA 6020B
ICPM/1155
92292703020
2016009418
EPA 3010A
MPRP/21339
EPA 6020B
ICPM/1155
92292703021
2016009419
EPA 3010A
MPRP/21339
EPA 6020B
ICPM/1155
92292703022
2016009420
EPA 3010A
MPRP/21339
EPA 6020E
ICPM/1155
92292703011
2016009409
EPA 7470
MERP/9234
EPA 7470
MERC/8876
92292703012
2016009410
EPA 7470
MERP/9234
EPA 7470
MERC/8876
92292703013
2016009411
EPA 7470
MERP/9234
EPA 7470
MERC/8876
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 04:50 PM without the written consent of Pace Analytical Services, Inc.. Page 64 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16040066
Pace Project No.: 92292703
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92292703014
2016009412
EPA 7470
MERP/9234
EPA 7470
MERC/8876
92292703015
2016009413
EPA 7470
MERP/9234
EPA 7470
MERC/8876
92292703016
2016009414
EPA 7470
MERP/9234
EPA 7470
MERC/8876
92292703017
2016009415
EPA 7470
MERP/9234
EPA 7470
MERC/8876
92292703018
2016009416
EPA 7470
MERP/9234
EPA 7470
MERC/8876
92292703019
2016009417
EPA 7470
MERP/9234
EPA 7470
MERC/8876
92292703020
2016009418
EPA 7470
MERP/9234
EPA 7470
MERC/8876
92292703021
2016009419
EPA 7470
MERP/9234
EPA 7470
MERC/8876
92292703022
2016009420
EPA 7470
MERP/9234
EPA 7470
MERC/8876
92292703001
2016009393
EPA 7471
MERP/6790
EPA 7471
MERC/6759
92292703002
2016009396
EPA 7471
MERP/6790
EPA 7471
MERC/6759
92292703003
2016009397
EPA 7471
MERP/6790
EPA 7471
MERC/6759
92292703004
2016009398
EPA 7471
MERP/6790
EPA 7471
MERC/6759
92292703005
2016009399
EPA 7471
MERP/6790
EPA 7471
MERC/6759
92292703006
2016009400
EPA 7471
MERP/6790
EPA 7471
MERC/6759
92292703007
2016009401
EPA 7471
MERP/6790
EPA 7471
MERC/6759
92292703008
2016009402
EPA 7471
MERP/6790
EPA 7471
MERC/6759
92292703009
2016009403
EPA 7471
MERP/6790
EPA 7471
MERC/6759
92292703010
2016009404
EPA 7471
MERP/6790
EPA 7471
MERC/6759
92292703001
2016009393
ASTM D2974-87
PMST/4397
92292703002
2016009396
ASTM D2974-87
PMST/4397
92292703003
2016009397
ASTM D2974-87
PMST/4397
92292703004
2016009398
ASTM D2974-87
PMST/4397
92292703005
2016009399
ASTM D2974-87
PMST/4397
92292703006
2016009400
ASTM D2974-87
PMST/4397
92292703007
2016009401
ASTM D2974-87
PMST/4397
92292703008
2016009402
ASTM D2974-87
PMST/4397
92292703009
2016009403
ASTM D2974-87
PMST/4397
92292703010
2016009404
ASTM D2974-87
PMST/4397
92292703001
2016009393
EPA 9045
WET/36998
92292703002
2016009396
EPA 9045
WET/36998
92292703003
2016009397
EPA 9045
WET/36998
92292703004
2016009398
EPA 9045
WET/36998
92292703005
2016009399
EPA 9045
WET/36998
92292703006
2016009400
EPA 9045
WET/36998
92292703007
2016009401
EPA 9045
WET/36998
92292703008
2016009402
EPA 9045
WET/36998
92292703009
2016009403
EPA 9045
WET/36998
92292703010
2016009404
EPA 9045
WET/36998
92292703001
2016009393
EPA 9056
WETA/56664
92292703002
2016009396
EPA 9056
WETA/56664
92292703003
2016009397
EPA 9056
WETA/56664
92292703004
2016009398
EPA 9056
WETA/56664
92292703005
2016009399
EPA 9056
WETA/56664
92292703006
2016009400
EPA 9056
WETA/56664
92292703007
2016009401
EPA 9056
WETA/56664
92292703008
2016009402
EPA 9056
WETA/56664
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/20/2016 04:50 PM without the written consent of Pace Analytical Services, Inc.. Page 65 of 69

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J16040066
Pace Project No.: 92292703
Lab ID
Sample ID
QC Batch Method
QC Batch
92292703009
2016009403
EPA 9056
WETA/56664
92292703010
2016009404
EPA 9056
WETA/56664
92292703001
2016009393
EPA 9056
WETA/56665
92292703002
2016009396
EPA 9056
WETA/56665
92292703003
2016009397
EPA 9056
WETA/56665
92292703004
2016009398
EPA 9056
WETA/56665
92292703005
2016009399
EPA 9056
WETA/56665
92292703006
2016009400
EPA 9056
WETA/56665
92292703007
2016009401
EPA 9056
WETA/56665
92292703008
2016009402
EPA 9056
WETA/56665
92292703009
2016009403
EPA 9056
WETA/56665
92292703010
2016009404
EPA 9056
WETA/56665
Date: 04/20/2016 04:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 66 of 69

Document Name:
Document Revised: 18FEB2016
o
Sample Condition Upon Recelpt(SCUR)
Page 1 of 2
aCEAnalyflCal
Document No.:
issuing Authority:
F-CHR-CS-003-rev.18
Pace Huntersville Quality Office
Sample . .. Client Name:
t
Wo'LL " J'0�0ilf�■9 1 03 v
Receipt
Proj4
Courier: ❑Fed Ex
y�
❑UPS ❑LISPS ❑Client
❑ Commercial [Pace
DOther:
92292703
Custody Seal Present? []Yes PNo Seals Intact? []Yes [No
Date/initials Person Examining Contents:_1� �l.�lfly
Packing Material: ❑Bubble Wrap
Bubble Bags ❑None ❑Other:
Thermometer: P T1505
❑ Type of ice: Pet ❑Blue
❑None ❑Samples on ice, cooling process has begun
Correction Factor: 0.0°C Cooler Temp Corrected
(°C): ILI
Biological Tissue Frozen? Dyes §ONo ❑N/A
Temp should be above freezing to 6°C
USDA Regulated Soil (❑ N/A, water sample)
Did samples originate In a quarantine zone within
the United States: CA, NY, or SC (check maps)?
Did samples originate from a foreign source (internationally,
F-IYPc 1V1Nn
Including Hawaii and Puerto Ricoi? F lYes IQNo
COMMENTS:
Chain of Custody Present?
Yes
[]No
❑N/A
1.
Chain of Custody Filled Out?
RYes
[]No
❑N/A
2.
Chain of Custody Relinquished?
Yes
[]No
[I N/A
3.
Sampler Name and/or Signature on COC?
❑Yes
No
❑N/A
4.
Samples Arrived within Hold Time?
Yes
]No
❑N/A
S.
Short Hold Time Analysis (<72 hr.)?
❑Yes
No
❑N/A
6.
Rush Turn Around Time Requested?
❑Yes
No
❑N/A
7.
Sufficient Volume?
Yes
[]No._.
❑N/A
8.
Correct Containers Used?
-Pace Containers Used?
(Yes
❑Yes
[]No
o
❑N/A
[]N/A
9.
Containers Intact?
Yes
❑No
❑N/A
10.
Filtered Volume Received for Dissolved Tests?
❑Yes
CgNo
[]N/A
11. Note if sediment is visible in the dissolved container
Sample Labels Match COC?
-Includes Date/Time/ID/Analysts Matrix: C
Yes
7
[:]No❑N/A
12,
All containers needing acid/base preservation have been
checked?
All.containers needing preservation are found to be in
compliance with EPA recommendation?
(HNO3, HzSOa, HCIQ; NaOH >9 Sulfide, NaOH>12 Cyanide)
Exceptions: VOA, Coliform, TOC, Oil and Grease,
DRO/8015 (water) DOC,LLHg
(Yes
[ Yes
71
❑Yes
9
®No
!!
❑No
No
W( f6
❑N/A
❑N/A
❑N/A
13.
Samples checked for dechlorination
[]Yes
No
❑N/A
14.
Headspace in VOA Vials (>5-6mm)?
❑Yes
No
❑N/A
15.
Trip Blank Present?
Trip Blank Custody Seals Present?
Pace Trip Blank Lot tt (if purchased):
[]Yes
[]Yes
PNo
[9No
%
❑N/A
❑N/A
CLIENT NOTIFICATION/RESOLUTION Field Data Required? []Yes []No
Person Contacted: Date/Time:
Comments/Resolution:
Project Manager SCURF Review: Date: &
Project Manager SRF Review: IG �p Date: q1� Ilk _
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
g
.Out of hold, incorrect preservative, out of temp, Incorrect containers)
Page 67 of 69

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