Loading...
HomeMy WebLinkAboutLee Email Attachments_SOUTHERN ENVIRONMENTAL LAW CENTER Telephone 919-967-1450 601 WEST ROSEMARY STREET, SUITE 220 Facsimile 919-929-9421 CHAPEL HILL, NC 27516-2356 April 18, 2016 VIA EMAIL AND U.S. MAIL N.C. Department of Environmental Quality Attn: Debra Watts Division of Water Resources, Groundwater Protection Section 1636 Mail Service Center Raleigh, NC 27699-1611 leecomments@ncdenr.gov Re: Comments on Draft Risk Classifications — H.F. Lee Dear Ms. Watts: On behalf of Sound Rivers and Waterkeeper Alliance, the Southern Environmental Law Center submits the following comments on the draft Coal Combustion Residual Impoundment Risk Classifications proposed by the N.C. Department of Environmental Quality (DEQ) for Duke Energy's H.F. Lee Steam Station facility ("Lee") near Goldsboro, N.C. Lee is a High Risk site. Duke Energy admits the impoundments are not suitable for the long-term storage of coal ash, they are constructed in wetlands and have streams running through them, they are located in the floodplain of the Neuse River, and they have caused what may be the worst groundwater arsenic contamination of any coal ash site in North Carolina. The Lee site stores nearly six million tons of coal ash in four unlined coal ash basins, plus a small polishing pond connected to the active basin. The active unlined coal ash lagoon on the bank of the Upper Neuse River was constructed in 1980. The lagoon is 143 acres in size, contains coal ash stored in a wet state, and is unlined. The Lee site also includes at least three inactive unlined pits constructed in the 1950s and 1960s according to EPA, which are full of old coal ash and also are located on the banks of the Upper Neuse River. All these impoundments are in the flood plain of the Neuse River. The Lee coal ash site and its dangerous dams, located in the floodplain of the Neuse River, and its ongoing, unpermitted discharges, are located upstream of the drinking water intake for over 34,000 people in Goldsboro and for over 93,000 people served by the Neuse Regional Water & Sewer Authority. The coal ash lagoon and inactive pits are constructed in the middle of wetlands, and the ground is swampy around these coal ash storage areas. See Wetlands Maps attached as Attachment 1. Moreover, several streams, including Half Mile Branch, run through the inactive coal ash pits at Lee. See Map Identifying Blue Line Streams, Attachment 2. Charlottesville • Chapel Hill • Atlanta • Asheville • Birmingham • Charleston • Nashville • Richmond • Washington, DC 100% recycled paper The existing Lee facility and a Cap in Place approach pollute surface water now and for decades to come; obliterate surface water resources of the state; fill and pollute groundwater forever; and contaminate for decades to come the water resources of the Neuse River Basin. Below, we set out some of the most prominent defects in the proposed classifications and Duke Energy's studies to date, all of which demonstrate that Cap in Place cannot be allowed as a closure option for the Lee impoundments. As a result, the Lee active basin with its polishing pond and three inactive basins should all be designated High Risk. I. Damages and Threats to Natural Resources A. Dam Safety Risks 1. The Lee Coal Ash Cannot Be Stored In the Floodplain of the Neuse River All the Lee impoundments are located in the Neuse River floodplain, and thus cannot be used for the long-term storage of coal ash. Duke Energy admits as much in a recent closure update, noting the flood risk and stating that "the basins are not suited for long-term permanent storage" of coal ash. Attachment 3 (emphasis added). In its January 2016 Coal Combustion Residual Impoundment Risk Classifications narrative document ("Narrative"), DEQ has correctly classified all the impoundments at Lee as High Risk for its Surface Water key factor, "Landscape Position and Floodplain." Narrative at 58. However, it has abandoned its own "key factor" approach by downgrading all five impoundments to "Intermediate" in its overall classification, without explanation or justification. All the Lee impoundments should be High Risk based on DEQ's correct determination of the flood risk to the public'at this site. When the river floods, these coal ash sites are literally surrounded by water and are at great risk. Their location within the river system itself underscores not only the risk of catastrophic failure, but also the fact that they inevitably pollute groundwater, surface water, and the entire river system. As set out below, the earthen dikes that contain the coal ash are dangerous, and their presence in the floodplain and directly on the river's banks makes them even more dangerous. 2. The Lee Dams Are High Risk The berm of the Active Lee coal ash lagoon was classified as "High Hazard" by the State of North Carolina and given a rating of "Significant Hazard" by the EPA. A least one section of the lagoon "does not meet the minimum standard" for slope stability according to EPA's 2011 dam inspection report. Due to its proximity to the river, the Lee active coal ash lagoon has been damaged repeatedly by flooding. EPA noted that in 1999, existing sloughing worsened and new sloughs were created on the interior of the dam, and new sloughing and cracks formed in the exterior of 2 the crest of the dam along the Upper Neuse River. The EPA report also described "significant erosion" at Inactive Ash Pond 2. A 2011 EPA dam inspection report also identified seeps discharging from the downstream berm of the coal ash lagoon. These seeps identified by EPA continue today, despite numerous attempts to repair and prevent them both before and after the EPA inspection. The Lee active coal ash lagoon has had problems for years with seeps that have caused ongoing maintenance and erosion problems around the coal ash lagoon. In 2000, the Lee lagoon suffered "significant interior slope slumping and distress" due to seepage. In 2002, contaminated water was observed leaking under the ash lagoon discharge pipe. In 2004, a riser pipe in the Lee lagoon broke off and fell over into the lagoon, causing the water level to drop rapidly. Inspections from 1990 and 2004 reported indications of slope movement on the east berm of the coal ash lagoon. In addition to these ongoing problems with the Lee coal ash lagoon, EPA has identified an "active stream" flowing from the toe of Inactive Ash Pond 2, known as Half Mile Branch. See Stream Map, Attachment 2. And multiple other blue line streams also flow through and beneath the inactive coal ash pits, as indicated in Attachment 2. These streams are surface waters being polluted illegally by Duke Energy, but they are also structural risks for the inactive impoundments that DEQ has ignored in its draft classifications. Similarly, DEQ has ignored the fact that Duke's own CAP studies show that the Inactive Basins 1-3 are submerged in the groundwater, so while they may appear dry on the surface (as claimed in the Narrative, p. 125), they are in fact largely saturated and thus have a higher risk of structural failure as well as ongoing pollution. See CAP Pt. 1, Fig. ES-3 to ES-5. 3. Proximity to Waters of the State By ignoring Half Mile Branch and the other blue line streams in and around the Inactive Basins 1-3 (as explained below), DEQ has mistakenly assigned a lower risk classification for the Dam Safety factor for Proximity to Waters of the State. The Inactive Ash Basins 1-3 are not "approximately 350 feet" away from waters of the state they are immediately adjacent to, and in some cases directly on top of, tributary streams, including Half Mile Branch and other unnamed streams as shown in Attachment 2. They are also sitting in wetlands, which are waters of the state. Attachment 1. Moreover, they are also submerged in the groundwater, which is also a water of the state. In addition, DEQ's analysis of the position of the Inactive Ash Basins relative to the Neuse River fails to take into account the significant effects of flooding, which brings the river far closer to these impoundments. Since flooding is one likely source of dam safety risk, DEQ's analysis fails to adequately evaluate the true proximity of the inactive impoundments to the Neuse River. For all these reasons, the Inactive Basins are High Risk for this factor. 4. Offsite Drainage Area DEQ has mistakenly stated that the offsite drainage area for Inactive Basin 1 is 0 acres. Narrative at 127. This is clearly an error and must be corrected. The Inactive Basin is not "Low Risk" for this factor. B. Surface Water Risks 1. "Cap in Place" Would Destroy and Pollute Surface Waters Multiple blue line streams flow through the Inactive Ash Basins. See Stream Map, Attachment 2. Duke Energy has no permit to pollute these streams, which flow around and beneath the Inactive impoundments, and also carry pollutants to the Neuse River. These streams are recharged by groundwater from the area of the inactive basins, and if the ash is capped in place in contact with the groundwater, the streams will continue to receive pollution from the basins via the connected groundwater. The contaminated groundwater at Lee also flows directly into the Upper Neuse River. In addition, several of the inactive basins have actually been constructed on top of the tributary streams. If the ash is capped in place, these streams would be buried in coal ash forever. 2. The Lee Coal Ash Is In And On Top of Natural Drainage Ways and Streams According to DEQ's classification system, if a coal ash impoundment is "sited in or located on top of... a natural drainage way or stream" then for this surface water factor the impoundment should be rated "Low/Intermediate." For this factor, all the Lee coal ash impoundments were rated "Low Risk" because of the conclusion that none of them was sited in or located on top of a natural drainage way or stream. That conclusion is not correct. As shown on the attached National Wetland Inventory map, the Lee impoundments are in, on top of, and partially surrounded by wetlands (Attachment 1). All these wetlands are connected to tributaries that flow directly into the Neuse River. Further, the Inactive Basins 1-3 are on top of tributaries that flow to the Neuse River. Attachment 2. All these impoundments should have received at least a "Low/Intermediate" risk rating under DEQ's classification system. 3. The Amount of Coal Ash at Lee Is High Risk While groundwater risk was evaluated based on the total amount of coal ash at Lee, for no apparent reason the surface water risk was evaluated separately at each lagoon based on the amount of ash in each lagoon. Narrative at 123. There is no basis for this distinction and particularly no basis for this distinction Lee. As DEQ sets out, the Lee coal ash is in a floodplain. In the case of a flood -caused catastrophe, the M entire site is at risk, not one coal ash storage site or another. By splitting the ash up among the various coal ash lagoons at this site, DEQ has artificially and wrongly reduced the risk calculation for the site. Further, Inactive Basins 1 and 2 share common dams and functionally are one coal ash storage unit, while Inactive Basin 3 is separated from them only by Half -Mile Branch stream, which is an additional risk factor. All these lagoons are in a wetlands complex. See Attachment 1. The Polishing Pond is functionally part of the Active Basin footprint, it shares dams with the Active Basin, and should not be treated any differently in terms of dam safety risk. A major flood catastrophe is likely to cause it to fail as well. There is no reason to split up these sites and thereby inaccurately understate the risk of the Cape Fear site. Under DEQ's rating system, since Cape Fear has more than 4,255,000 tons, the site should have been rated High Risk for this factor. Further, the entire system of dividing up the impoundments into tonnage categories is, as in other instances, wrongly based on the notion that DEQ is grading on a curve, where some impoundments will be low risk, some intermediate, and some high. As set out above, there is no basis in law or fact for this approach. This approach ignores the fact that every coal ash lagoon can be high risk, and this approach has no basis in CAMA. The Legislature did not mandate that some percentage of sites be designated low risk, some intermediate, and some high. DEQ's approach minimizes the risks to the public, the environment, and natural resources by artificially forcing coal ash impoundments into low and intermediate categories. Indeed, DEQ expressly did exactly that. The Narrative (page 23) expressly states that DEQ picked tonnage cutoffs for low, intermediate, and high risk so that the ratings would be distributed across the percentiles of the coal ash lagoons in the state. Thereby, DEQ forced some coal ash lagoons into a low risk category and some into an intermediate category based on arbitrary percentiles. The fallacy of this approach is demonstrated by the Dan River site. It has a total of 1.6 million tons of coal ash in two lagoons. Under DEQ's method of splitting sites and forcing sites into categories based on amount of ash stored, Dan River's two lagoons would only be considered by DEQ to be "intermediate" risks. Yet, this site is the site of the state's worst coal ash disaster that led to the enactment of CAMA itself. Dan River was and is a High Risk site based on the amount of coal ash stored there, even if there are bigger sites in the state. This DEQ-created curve for grading coal ash sites is contrary to reality. By splitting up sites and creating a curve, DEQ has said that impoundments that contain up to 4,255,000 tons of coal ash are not high risk, and that sites that do not contain a single impoundment of that more than 4,255,000 tons cannot by definition be high risk. The fact is that storing tens of thousands of tons, hundreds of thousands of tons, or millions of tons in unlined leaking pits next to waterways is High Risk. The risk of these huge coal ash storage sites cannot be diminished by the fact that Duke Energy has irresponsibly created enormous unlined coal ash storage sites. 5 In short, for this factor, Lee and all other coal ash sites are High Risk. C. Groundwater Risks There is no separation between the Lee impoundments and the groundwater at the site. Indeed, the Inactive impoundments are submerged in the surficial aquifer. See CAP Pt. 1, Fig. ES-3 to ES-5. Cap in Place would not stop the ash from leaching contaminants into the groundwater at the site and the Neuse River and its tributaries, and thereby continuing to pollute public waters for decades to come. 1. Serious Groundwater Pollution Since at least 2007, elevated levels of pollutants from the coal ash have been documented in groundwater under, at, and around the Lee facility. These substances include toxic and cancer -causing pollutants including arsenic, lead, chromium, cadmium, and beryllium; as well as other coal ash pollutants including boron, iron, manganese, and total dissolved solids. Years of groundwater monitoring well data from the site show the unlined coal ash pits have caused numerous pollutants to exceed their respective standards, including: • Arsenic at over 66 times the standard • Beryllium at over 2 times the standard • Boron at over 7 times the standard • Cadmium at over 231 times the standard • Chromium at 5 times the standard • Lead in excess of the standard • Iron at 112 times the standard • Manganese at over 61 times the standard • Total dissolved solids of almost 4 times the standard In addition, the groundwater at Lee is acidic, with a pH as low as 4.8, well below the state groundwater standard. Although Duke's consultant has claimed in the CAP Pt. 2 that the area around Lee is served by public water, residents around the inactive basins use well water, and at least nine residents nearby have received "do not drink" letters for a variety of pollutants associated with coal ash detected in their well water. CAP Pt. 2 at pp. ES-1-2. 2. DEQ's Groundwater Rating Ignores Data Gaps and Uncertainty DEQ claims the Lee impoundments are all "Low Risk" for its groundwater key factor. But DEQ explains that its rating for this factor is "[b]ased on the data provided in CSA Report and results of the groundwater modeling results presented in the CAP Report." Narrative at 57 (emphasis added). And for each of the five impoundments, DEQ says "[t]here are no reported supply wells within 1500 feet downgradient of the impoundment compliance boundary." Id. (emphasis added). In other words, DEQ has relied for its "key factor" on whether or not Duke Energy chose to admit it is contaminating neighboring wells, and DEQ has looked only at what G Duke did include in its reports, rather than evaluating the data gaps and uncertainty in these reports. In short, because Duke did not report that drinking wells were affected, DEQ gives these impoundments a "Low Risk" rating. There is no support for this approach. DEQ's own classification report recognizes that uncertainty creates more, not less, risk: "Components of the conceptual site model related to a CCR impoundment that are incomplete or inadequately characterized contribute a degree of uncertainty that translates to an increased potential risk to the classification evaluation process." Narrative at 21 (emphasis added). At Lee, for the groundwater factor "Data Gaps and Uncertainty," DEQ found that the extent of the contamination has not been adequately defined for any of the impoundments. Narrative at 122. DEQ gave the Active Ash Basin, the Polishing Pond, and Inactive Basin 1 an "Intermediate Risk" rating because of this uncertainty. For the Active Basin and Polishing Pond, DEQ noted radial flow and mounding around the basin, , which could move contaminants in the direction of nearby drinking wells. and found the horizontal extent of the contamination was not adequately defined. Id. For Inactive Basin 1, DEQ found that the vertical extent of the contamination is not defined, and also noted mounding and radial flow around this basin, which could move contaminants in the direction of nearby drinking wells. For Inactive Basin 2, DEQ found the vertical extent of the contamination is not defined. And for Inactive Basin 3, DEQ found the same gaps as listed above, and also noted that the horizontal extent of the contamination is not adequately defined. Given that the extent of the contamination has not been adequately defined for any of these five impoundments, and that there is mounding and radial flow around them, DEQ cannot give these five impoundments a "Low Risk" rating for potential contamination of drinking well receptors. DEQ should give these basins High Risk ratings unless and until Duke Energy can prove whether its coal ash is contaminating neighboring drinking wells. 3. Inadequate Groundwater Modeling The Lee model is fundamentally flawed because it ignores a dominant feature of the site, namely its location in the floodplain of the Neuse River. Ignoring this extremely significant factor, Duke Energy's model sets a constant head boundary for the Neuse River. CAP Pt: 1, Appendix E, p. 10. That means that for purposes of the model, the river never rises or falls. W In reality, the river regularly rises and falls dramatically. The USGS stream flow gauging station on the Neuse River near Goldsboro, NC shows that the elevation of water in the river routinely changes with high elevations associated with rainfall events. As the chart shows, these elevations regularly vary by more than 15 feet. USGS 02089000 NEUSE RIVER NEAR GOLDSBORO, NC 2© m 15 a� s ao •H 1© a� L 6U AO LO 5 -— Jul Jan Jul Jan Jul Jan Jul Jan 2012 2013 2013 2014 2014 2015 2015 2016 — Gage height Period of provisional data -Period of approved data When the water level in the river rises, water flows out of the river and into the floodplain sediments, causing groundwater elevations to rise and the direction of flow to be more from the river toward the uplands. The groundwater flow direction returns to the normal direction generally toward the river once river level goes back down. Reversals of groundwater flow direction in floodplains is a well-known and expected characteristic that can spread released contaminants in unexpected directions from the source area and result in high variation in groundwater quality measurements due to changes in flow direction. By ignoring this basic feature of the Lee site, Duke has set up its model with completely unrealistic conditions that do not account for groundwater movement at the site. Because of this serious deficiency in the model, it is not known how far the groundwater may be pushed up from the basins. But it is certain that Duke Energy's model is not reliable and cannot support the conclusions about groundwater flow that Duke has presented to DEQ. A second issue related to the location of the Lee ash basins in an active floodplain is that the ash in the unlined basins should be assumed to be regularly re -saturated. With each high water event in the Neuse River, the elevation of groundwater beneath the basins will increase. Since the basins have been constructed with their bottoms at the water table, increased groundwater elevations associated high water events along the river will re -saturate ash within the basins and renew generation of leachate from the buried waste. Because the groundwater regularly re -saturates the ash in the unlined impoundments, capping the waste in place cannot separate the ash from groundwater and eliminate the ongoing contamination. The effect of modeling the Lee site with a constant head boundary at the river is to impose a constant groundwater elevation and flow direction on the model of a system that can be shown to exhibit neither. The Lee groundwater model, constructed as described, is artificially constrained to show the waste located primarily just above the water table and contaminant transport consistently toward the river. Neither of these Conditions is correct in the real world. In addition, the description of the Ash Basin Capping scenario indicates that this scenario uses a zero recharge rate to the groundwater system in the vicinity of the ash basins. This is the assumption that allows the contaminant transport results for the cap in place scenario to perform similarly to the ash removal scenario. Unfortunately, zero recharge will not be achieved by capping the ash. The groundwater system beneath the ash basins is not a static system with groundwater be assumed to consistently be located beneath the bottom of the ash. As was described above, the real -world groundwater system will be influenced by the changing stage of the Neuse River. The water table will rise during high flow events causing rewetting of the ash and generation of leachate. By ignoring the groundwater movement at the site, Duke's model distorts the comparison between "Cap in Place" and excavation. In reality, excavation is the only closure method that will remove the source of the pollution — the coal ash in the basin — from direct contact with public waters, where it is burying streams and leaching out pollutants into the groundwater, the Neuse River, its tributary streams, and adjacent wetlands. 4. Faulty Provisional Background Concentrations The "background" concentrations used in the CAP to propose site -specific pollutant levels are not reliable. Duke's CAP Pt. 1 acknowledges that groundwater flows radially away from the basins, pp. 1-8 and 2-2, and that several of the monitoring wells do not represent background conditions, p. 4-3. The groundwater monitoring systems used to this point has been inadequate and reliable background values for groundwater contaminants have yet to be developed. 5. Recovery Wells/Interceptor Trenches and Attenuation Are Not Appropriate Remedial Measures At Lee The CAP Part 2, pp. 6-26 and 6-29, evaluates the use of recovery wells or an interceptor trench to control migration of ash contaminants downgradient of the active ash basin. Each of these options includes routing of the collecting water into a basin for pH buffering prior to discharge into the Neuse River under an NPDES permit. But this plan requires no treatment for the high levels of arsenic and other pollutants in the groundwater. The effect of these 6 "remediation" scenarios would be to collect the contaminated groundwater and discharge it into the river. This essentially by-passes any natural attenuation that may be happening and actually speeds discharge of contaminated water into the river. Thus, this approach is likely worse for the river and natural environment even than doing nothing would be. Nor is attenuation a valid approach at Lee. EPA and North Carolina rules require that a corrective action plan that proposes to utilize monitored natural attenuation (MNA) as a remedy demonstrate that that the contaminant has the capacity to degrade or attenuate under site -specific conditions. Section 6.6.1.3 of the CAP Pt. 2 claims that the primary attenuation mechanism at H.F. Lee is the advective groundwater flow regime, which is controlled by the close proximity of the Neuse River. However, advective groundwater flow is not the same as contaminant attenuation. Attenuation occurs when contaminants interact with the soil or rock through which the water is flowing and contaminants are removed from the groundwater. Advective now means the pollution is simply flushed beyond Duke Energy's property boundary and compliance boundary, straight into the Neuse River. Dilution of contaminants facilitated by advective flow and/or discharge into the Neuse River are not forms of attenuation. Duke has provided no data supporting attenuation as a mechanism controlling the spread of the boron plume. Section 6.6 of the CAP Pt. 2 indicates that MNA may be a potential groundwater remedy for certain areas of the site. In addition to the problems described above, MNA does not appear to be a viable closure option for this site because: • NCAC 02L .0106 (1)(1) requires a demonstration that all sources of contamination and free product have been removed or controlled. Duke is not proposing removal of the waste for disposal in a secure location. Controlling the waste will likely require active operation of remedial systems for many decades if groundwater impacts are to be controlled. The portion of the ash that is continually or intermittently saturated will continue to leach metals into groundwater that will flow toward and eventually discharge into the Neuse River. • NCAC 02L .0106 (1)(2) requires a demonstration that the contaminant has the capacity to degrade or attenuate under site -specific conditions. Many of the ash -related constituents in groundwater at this site neither degrade nor attenuate. Contrary to what is stated in this report, advective groundwater flow and discharge into the river is not a form of attenuation. Instead, DEQ must require removal of the source of the pollution: the coal ash in the unlined impoundments. D. CAMA Requires Duke Energy to Comply with the Groundwater Standard CAMA requires compliance with North Carolina's groundwater protection rules found at 15A N.C. Admin. Code 2L .0101 et. seq. ("21, Rule"). Under the 2L Rule, any polluter that contaminates groundwater must develop a corrective action plan "using the best available technology for restoration of groundwater quality to the level of the standards ...." 15A N.C. Admin. Code 2L .01060). This general mandate is subject to limited exceptions for a specific category of polluters who qualify for flexible remediation standards under 2L .0106(k) (allowing restoration to less than the standard), 2L .0106(1) (allowing restoration through natural 10 attenuation), or 2L .0106(m) (allowing termination of corrective action without achieving the standard). See 2L .01060). Each of those sections, in turn, applies only to a "person required to implement an approved corrective action plan for a non permitted site ...." See 2L .0106(k), (1), (in).' Under the plain text of the 2L Rule, facilities with state -issued NPDES permits do not qualify for the flexible remediation options afforded by 2L .0106(k), (1), and (m) because they are permitted. In the past, Duke Energy has argued that its NPDES-permitted coal ash basins are nonetheless eligible for the flexible- remediation measures reserved for "non permitted sites" because under the 2L Rule, older basins first issued permits before December 30, 1983, are "deemed not permitted" for some purposes. See 2L .0106(e). But recent legislative changes altered these rules mandating that "[w]here operation of a disposal system permitted under this section results in exceedances of the groundwater quality standards at or beyond the compliance boundary the [EMC] shall require the permittee to undertake corrective action, without regard to the date that the system was first permitted, to restore the groundwater quality ...." N.C. Sess. Laws 2014-122, § 12(a) (codified at N.C. Gen. Stat. § 143-215.1(k)) (emphasis added). In other words, the only question now is whether a facility has a permit, not when it was issued. Under this recent revision to North Carolina's water pollution control statute, Duke Energy must restore groundwater around its permitted coal ash disposal sites at the Roxboro facility to the applicable standard, without regard to the date the impoundments were first permitted. To further clarify the application of flexible remediation to coal ash ponds, the General Assembly recently declared that the benefits afforded by its risk -based remediation statute "shall not apply to contaminated sites subject to remediation pursuant to ... [t]he Coal Ash Management Act of 2014." Id. (codified at N.C. Gen. Stat. § 130A-310.67(4)). As a permitted facility subject to remediation under CAMA, Duke is barred from using flexible remediation, such as monitored natural attenuation, as a groundwater remediation method and instead must implement -the best available technology to restore groundwater to the standards. E. The Lee Impoundments Also Are Not Eligible for Closure by Capping in Place Under the CCR Rule. On October 19, 2015, the EPA's Disposal of Coal Combustion Residuals rule (the "CCR Rule") became effective, providing the first comprehensive federal regulation of coal ash disposal. DEQ asserts that "[t]he requirements set forth in CAMA ... will complement or exceed" the CCR Rule's requirements, but this is only true if DEQ demands more than cap -in - place where groundwater is already contaminated by unlined impoundments. The tension between the new federal mandates and capping -in -place at Duke's sites exists in the CCR Rule's Groundwater Monitoring and Corrective Action section. 40 C.F.R. § § 257.90-98. This section provides that if monitoring detects a statistically significant exceedance of the groundwater protection standards established for a constituent in Appendix IV of the CCR Rule, then, barring certain exceptions, the owner or operator of an unlined surface 'Flexible remediation is also available under 2L .0106(r) & (s). Those sections only apply to underground storage tanks and are inapplicable to the coal ash ponds at issue in this litigation. 11 impoundment must engage in two tracks of remedial measures. Id. § 257.95(g). First, the owner or operator of the unlined impoundment must begin the CCR Rule's normal remedial process, including the assessment of corrective measures, selection of remedy, and implementation of a corrective action plan. Id. §§ 257.95(g)(3)(i), 257.96-98. Second, within six months of the detection, the waste streams into the impoundment must cease and the process of closing or retrofitting the impoundment must begin. Id. §§ 257.95(g)(5), 257.101(a)(1). The CCR Rule's preamble makes clear that this close or retrofit requirement for leaking unlined impoundments is "in addition to complying with all of the corrective action requirements." 80 Fed. Reg. 21406 (emphasis added). Thus it is not enough to satisfy only § 257.102's closure requirements the requirements for remedies and implementation of the corrective action plan under § § 257.97-98 must also be met. This point is critical because Duke's own data show that capping -in -place will not meet the CCR Rule's requirements for remedy selection or corrective action plan implementation. Among other things, the remedy selected must "[b]e protective of human health and the environment," "[a]ttain the groundwater protection standard" set forth in § 257.95(h) (the MCL or other level, as specified therein), "[c]ontrol the source(s) of releases so as to reduce or eliminate, to the maximum extent feasible, further releases of Appendix IV constituents, and "[r]emove from the environment as much of the contaminated material that was released from the CCR unit as is feasible." 40 C.F.R. §§ 257.97(b)(1)-(4). The remedy will not be considered complete until groundwater protection standards are met for three consecutive years. § 257.98(c)(2). The CCR rule measures compliance with groundwater protection standards at the site's waste boundary, see 40 C.F.R. § 257.91(a)(2), a much closer limit that is within the compliance boundary. Therefore, capping -in -place also will not meet the CCR Rule's requirement that the remedy selected attains compliance with groundwater protection'standards, let alone for three consecutive years. Nor will capping -in -place satisfy the requirements that the remedy control the source material and remove as much contaminated material as is feasible —indeed, the cap -in - place plan seems to call for removing as little as is feasible. And leaving the toxic ash in vulnerable communities adjacent to precious waterways will certainly not protect human health and the environment. The only remedy that will meet the CCR Rule's requirements, and the only remedy DEQ should consider for these sites, is removal of the ash and placement in dry lined storage facilities. . F. Duke Energy Admits Coal Ash Must Be Separated from Groundwater On April 7, 2016, in prepared remarks at a hearing before the North Carolina Advisory Committee to the United States Civil Rights Commission, the Duke Energy representative told the Committee and thereby the Commission that Duke Energy was committed to protecting groundwater: "Duke Energy's closure work is really driven by a series of guiding principles. And the first of those is ensuring that ground water is protected. We cannot develop a closure plan that does not protect groundwater" (emphasis added). A "Low Risk" rating and Cap in Place at Roxboro would be directly contrary to this official pledge, and would deposit millions of tons of coal ash in groundwater. 12 In South Carolina, Duke Energy has acknowledged that it must remove all of its ash in the state from the unlined basins where it is currently submerged in groundwater, to lined, dry storage or recycling. Duke Energy's own public statements admit that coal ash cannot be safely stored sitting in groundwater. At a recent ex parte briefing before the South Carolina Public Service Commission, Duke Energy explained that excavating all the coal ash from its Robinson coal ash site in Darlington County, S.C. to lined, dry landfill storage on site will ensure "groundwater is protected" because "[a]sh will be removed and placed in an engineered landfill, segregated from groundwater." PSC Transcript, Attachment 4, at 18. At Robinson, the coal ash in the basin is submerged 18 feet deep in groundwater that flows directly to Lake Robinson. By comparison, the coal ash at Roxboro is submerged well over 70 feet deep in the groundwater that flows directly to Hyco Lake. DEQ must require what has already been recognized in South Carolina — coal ash cannot be safely stored unless it is separated from groundwater. In its briefing, Duke also explained that the advantages of its coal ash excavation plans for Robinson and for its W.S. Lee facility on the Saluda River include the fact that they will "eliminate[] the existing impoundments," ensuring "groundwater is protected. That landfill will be lined and capped, leachate will be collected, and we will continue to perform groundwater monitoring to ensure that these controls function as designed." Attachment 4, at 14, 18. In South Carolina — a state where the environmental agency has not hampered citizen law enforcement against coal ash pollution — Duke has been forced to recognize that even in sparsely populated areas, it cannot safely close its ash basins without eliminating all its unlined impoundments and separating the coal ash from groundwater through storage in a properly designed, synthetically lined landfill. North Carolinians deserve these same protections for Goldsboro and the Neuse River. G. Experience Has Shown that Excavation and Removal is Effective in Reducing Groundwater Pollution Experience from coal ash excavation sites in South Carolina demonstrates that excavation to dry lined storage is the effective means of eliminating serious groundwater contamination from unlined coal ash lagoons. Excavation and removal to dry lined storage also eliminates the threat of catastrophic failure and the unlined riverside storage of millions of tons of toxics-laden waste. The Wateree plant of SCE&G is on the banks of the Catawba-Wateree River — a river that runs through both South and North Carolina — near Columbia, South Carolina. Duke Energy also stores coal ash on that river, at its Marshall, Riverbend, and Allen facilities. In January 2012, the Southern Environmental Law Center filed suit against SCE&G on behalf of the Catawba Riverkeeper Foundation to require removal of coal ash from unlined pits on the banks of the River. For years, these coal ash pits had contaminated the groundwater — and thereby the adjacent Catawba-Wateree River — with large amounts of arsenic. In one test, 13 groundwater in one of the monitoring wells contained arsenic at 5,000 parts per billion (ppb), or 500 times South Carolina's standard of 10 ppb for arsenic. Attachment 5, at 12. In August of 2012, SELC and the Catawba Riverkeeper Foundation negotiated a settlement with SCE&G that requires removal of the coal ash from the riverside pits to safe, dry, lined storage away from the waterway. Since ash removal began in earnest, arsenic groundwater contamination has plummeted at the site. As of its January 2016 report, SCE&G has removed over 876,000 tons of coal ash from the site, or about one-third of the coal ash. Attachment 5, at 2. At the same time, groundwater contamination at the site has dropped significantly. In one monitoring well, arsenic had contaminated the groundwater at 432 ppb, or 43 times the legal limit. In the latest report, arsenic groundwater contamination has dropped to 2.9 ppb, or a 99 percent decrease. Id. at 6-7. In another monitoring well, arsenic contamination had been over 1,000 ppb, ranging as high as 5,000 ppb. In the latest report, arsenic contamination had dropped to 58.6 ppb, or at least a 95 percent reduction in arsenic contamination. Id. at 12. Other pollutants, including lead, cadmium, and sulfate, are also reported at lower levels. 8co 7c0 a 600 n. c 500 O 400 L 300 Qj C 200 O V 100 Arsenic Levels at Wateree May Aug 2012 May Oct 2013 Apr 2014 Oct 2014 Apr 2015 Oct 2015 2012 2013 Sampling Dates Monitoring Well —+-3 fll In June of 2012, the Southern Environmental Law Center filed suit against Santee Cooper for its coal ash pollution at its Grainger facility on the Waccamaw River in Conway, South Carolina. In this instance, SELC represented the Waccamaw Riverkeeper, a program of the Winyah Rivers Foundation; the South Carolina Coastal Conservation League; and the Southern Alliance for Clean Energy. The Waccamaw River — like the Catawba-Wateree River — flows 14 through both North and South Carolina. The Waccamaw River is also part of the Winyah Bay Watershed, which encompasses both states, including the Lumber River on which Duke Energy stores coal ash at its Weatherspoon facility. In November 2013, the parties announced the settlement of this suit, under which Santee Cooper agreed to remove all the ash from the unlined Grainger pits to safe, dry, lined storage or to recycle it for concrete. Since ash removal began at that site, coal ash groundwater contamination has dropped significantly. As of its January 2016 report, Santee Cooper had removed about 450,000 tons of ash. Attachments 6 & 7. The Grainger site has consistently reported some of the highest arsenic groundwater contamination in the region. However, as the ash is being removed, the arsenic groundwater contamination has been decreasing. One monitoring well reported arsenic in 2013 at 1,097.9 ppb, or over 109 times the South Carolina standard of 10 ppb. Attachment 8, at 5. By the end of 2015, the arsenic contamination in that monitoring well had dropped to 558.9 ppb — still very high, but about one half the level before excavation began. Attachment 9, at 4. At another monitoring well, in September 2013, arsenic groundwater contamination was measured at 941.9 ppb, or over 94 times the South Carolina standard. Attachment 8, at 5. By the end of 2015, arsenic contamination had dropped to 198.4 ppb - about an 80% reduction from pre - excavation. Attachment 9, at 4. One other monitoring well also showed an 80% reduction, from 450 in 2013 to 108.5 by the end of 2015. Attachment 8, at 5; Attachment 10, at 8. Arsenic Levels at Grainger 4000 3500 Monitoring Well .0 CI 3000 -� 1 Q t2 C 2500 O —4-3 -0-4 M 2000 -J --*-5 C 1500 ----- -t-6 U C t9 V1000 t10 tll - 500 12 0 Sept -Oct 2013 Mar -Apr 2014 Sept -Oct 2014 April 2015 Nov -Dec 2015 Sampling Dates As excavation continues, the measurements of arsenic contamination in groundwater may vary. But the trend is clear. As ash is removed, groundwater contamination from arsenic has been decreasing. 15 H. Cap in Place Increases Groundwater Contamination Far from protecting groundwater, capping in place can increase harmful contamination by creating an oxygen -free environment that makes arsenic leaching worse. Arsenic in coal ash has higher leaching potential in an anaerobic environment than in an aerobic environment because of the different potential for reduction -oxidation reactions. A recent study found dissolved arsenic concentrations under anaerobic conditions were as much as 50 times higher than they were under aerobic conditions. Grace E. Schwartz et al., Leaching potential and redox transformations of arsenic and selenium in sediment microcosms with fly ash, Applied Geochemistry 67 (2016): 177-185. DOI: 10. 10 1 6/j.apgeochem.2016.02.013, Attachment 11. Research at coal ash ponds and the TVA Kingston spill site have similarly found that oxygen conditions at a site affect the amount of arsenic leaching. The study authors conclude that "capping methods that might induce anaerobic conditions should be avoided in the closure of unlined impoundments." Id. at 184. Covering ash that remains in unlined pits, in the groundwater, could deprive the ash of . oxygen, and the resulting anaerobic conditions could increase arsenic pollution of groundwater. Around the country and in North Carolina specifically, "cap in place" has failed to remedy coal ash pollution. • Roxboro. Duke Energy has sometimes cited experience at nearby Roxboro for proof that cap in place can work, but in fact coal ash pollution has continued at Roxboro despite an attempt to cap in place. At Roxboro, a lined coal ash landfill has been constructed on top of an unlined coal ash landfill and unlined coal ash lagoon. Duke Energy has claimed this lined landfill acts as a cap over the unlined ash and that groundwater monitoring data around this lined landfill area demonstrate the success of a cap -in -place closure plan. Duke has stated that the lined landfill was designed to minimize recharge to the aquifer and act as a corrective action to improve groundwater quality. And Duke's Corrective Action Plan Part 1 (CAP Pt. 1) claims that in monitoring wells GMW-06, GMW-10, and GMW-11, "the lined landfill is reducing the migration of constituents to Site groundwater." CAP Pt. 1 at 1-8 (emphasis added) In fact, groundwater monitoring data show that this "Cap in Place" approach has failed to protect groundwater at Roxboro. First, Duke's assertion ignores the increasing concentration trends for boron, sulfate, and selenium detected in samples from wells GMW-06, GMW-09 and GMW-11 collected since 2011. Concentrations were very high initially, likely due to improper well development or sampling techniques early on, and began decreasing prior to installation of the cap/lined landfill, but in recent years, the concentrations have increased. Graphs of boron, sulfate and selenium results from wells GMW-06, GMW-09 and GMW-11 are included with the attached expert report of Mark Hutson (Attachment 12 at 26-27). The graphs show increasing concentration trends since 2011-12 for boron, sulfate and selenium in well GMW-06, and for selenium, sulfate, and total dissolved solids in GMW- 11. In well GMW-06, boron has been steadily increasing for years and in September 2015 reached 2,460 ppb, well over three times the groundwater standard. CAP Pt. 1 at Table 2-9. Contrary to Duke's claims, wells GMW-06 and GMW-11 show no consistent decreasing trend for sulfate, a pollutant that has been above standards around the lined landfill since it was constructed. Selenium in GMW-06 has also shown no consistent decreasing trend, and in fact has been increasing in recent years and was last measured at 94.3 ppb, a concentration virtually identical to that measured in 2002 when the lined landfill project began. Moreover, there is another downgradient monitoring well ignored by Duke, GMW-08, that disproves Duke's claim that the capping effect of the lined landfill is protecting groundwater. Duke has mislabeled this well as an upgradient or sidegradient well in its submissions to the state (for example, CSA Section 2.10.2), but that is plainly incorrect. The CSA's Bedrock Water Level Map (Figure 6-5) shows that well GMW-08 is located downgradient of both the unlined and lined landfills. Analytical results from GMW-08 show concentrations of boron, chloride, iron, manganese, sulfate, and total dissolved solids (TDS) that are greater than 21, standards and are increasing (Attachment 12, at 26- 27). The location of GMW-8 downgradient of the landfills is consistent with the observed elevated and increasing concentrations of ash -related constituents. In particular, boron in GMW-08 has increased dramatically since 2011, reaching shockingly high levels above 4,000 ppb, and as high as 4,240 ppb, in the sampling data from April and September 2015 included in the CAP Pt. 1 (Table 2-10). Similarly, sulfate concentrations in GMW-08 have increased steadily over the past several years and are now far higher than they were at their previous peak around the time the landfill was constructed; they are now as high as 780 mg/L, over three times the 2L standard. Id. And total dissolved solids concentrations in 'GMW-08 have been increasing as well, and are now almost twice as high as in 2002 and are four times higher than the 2L standard. Thus, contrary to Duke Energy's claims, multiple monitoring wells downgradient of the lined landfill at Roxboro show steadily increasing concentrations of coal ash pollutants, and many others show no consistent decrease in pollutant concentrations. This is unsurprising, given that the CAP Pt. 1 and CSA show that the unlined coal ash at Roxboro sits deep in the groundwater, where it will continue to leach out pollutants even if it is capped in place. Belews Creek, NC — the Pine Hall Road coal ash landfill is unlined and was closed with synthetic cap in 2008. The Pine Hall Road landfill was listed by EPA as a potential damage case in 2010 due to continuing groundwater contamination, including exceedences for arsenic, boron, iron, manganese, nitrate, selenium, and sulfate. http://www.astswmo.org/Files/Policies and Publications/Cross- program/Coal Combustion Residuals/2011.11- NODA Comments/North Carolina NODA Comments.pdf 17 Chesapeake Energy Center, VA — an unlined coal ash landfill has been capped by installing a synthetically lined landfill on top of it, so the liner is supposed to serve as a cap on top of the old coal ash. "The landfill, built over an older and unlined ash pond, was lined with polyethylene, but as The Pilot's Jeff Sheler has reported, tests of wells at the site have repeatedly detected arsenic and other pollutants at levels exceeding government safety standards." "Company reports to the state Department of Environmental Quality obtained by The Virginian -Pilot showed that arsenic in one well in 2006 was 40 times the standard," Sheler wrote. "Results in May 2013 and April 2014 showed levels 30 times the standard. Levels of cobalt and sulfide also exceeded government standards. Other pollutants, including barium, beryllium, lead, selenium and zinc, were detected at `significant levels above background."' http•//hamptonroads com/2014/08/protectin -cg hesgpeake-dominion-shuts-plant • Colstrip, MT — "Built in 1976 with a clay buffer, the Stage 1 Pond began oozing pollutants as far back as 1979 and has continued to do so — even though it was "capped"— covered over with a liner — in 1997." http://www.publicintegril.org/2009/02/19/2942/coal-ash-hidden-story • B.C. Cobb, MI — years after lowering water levels, capping, and constructing a slurry wall around a coal ash lagoon, groundwater monitoring shows extremely high boron concentrations (10,400 µg/L) and lithium concentrations (215 µg/L) continuing to enter the North Branch of the Muskegon River. • We Energies Oak Creek, WI — buried coal ash that was paved over with an industrial site on top spontaneously collapsed into Lake Michigan in 2011. http•//www.publicintegrii org/2011/11/01/7240/coal-ash-spills-lake-michigan-after- bluff-collapse I. Industry Claims About the Supposed Dangers of Transporting Coal Ash Are a Red Herring . DEQ officials have stated publicly that they have received a letter from a coal ash industry group arguing that it would be better to leave all the coal ash in Duke Energy's unlined basins across North Carolina because cleaning up and transporting coal ash is somehow unsafe. This is a hackneyed argument with no basis in fact. Industry opponents of coal ash cleanup use general statistics that include every truck driver in America, not those managed or overseen by contract by utilities, and specifically by Duke Energy. Duke Energy has never contended that it shouldn't clean up coal ash because its truck drivers or those of its contractors will kill people. If that were true, then Duke's construction, maintenance, and other activities should be severely curtailed and investigated. And Duke's management should be investigated for its dangerous operation and oversight of trucking. In fact, Duke Energy conducts extensive trucking operations every day throughout North Carolina and its service area. Duke Energy Business Services, the trucking subsidiary of Duke 18 Energy, has had just 12 injuries and zero fatalities over the past 24 months.2 Duke's trucks drove 37 million miles in the U.S. in the last reporting year alone. Moreover, Charah, the company responsible for transporting much of Duke Energy's coal ash from the sites already being cleaned up, has had zero crashes in the last 24 months with no injuries or fatalities.3 Charah has also won several awards for employee safety from the N.C. Department of Labor.4 Industry arguments about trucking fatalities are not only totally irrelevant to Duke Energy and Charah's safety records, but they also misrepresent the issue by including tractor trailer trucks and other trucks, in addition to dump trucks. According to the National Highway Traffic Safety Administration, of the large trucks involved in fatal crashes, 66% are classified as truck tractors, while only 29% are single -unit trucks, which includes the dump trucks used in coal ash transportation.5 Duke Energy has also expressed its preference for rail transport in all future offsite storage of coal ash .6 Though coal ash transportation by truck is safe, rail is an even safer alternative . Economic activity and environmental remediation cannot be stopped or hindered because of fears that incompetent coal companies or utilities will poorly manage and/or select their truckers and kill people. If they have that problem, the management should be investigated, replaced, or taken legal action against. If this problem exists, this is a feature of incompetent and unsafe management and selection, not a reason to leave another threat to human health and the environment in place. Nor is it a reason to stop economic activity or environmental cleanup because drunk drivers or other at fault drivers cause accidents with trucks. If that were an argument against doing something, it would be an argument against all economic, recreational, and personal activity that involves driving. 2 Federal Motor Carrier Safety Administration, Company Snapshot: Duke Energy Business Services, Inc., b.9p:Hsafer fmcsa dot gov/query asp?searchtype=ANY&query type=queryCarrierSnapshot&query param=USDOT &original query param=NAME&query string=94646. 3, Federal Motor Carrier Safety Administration, Company Snapshot: Charah Inc., http•//safer fncsa dot goy/query asp?searchtWe=ANY&query type=queryCarrierSnapshot&query param=USDOT &original query param=NAME&query string=671494&originalquery string=CHARAH INC 4 Charah, Inc., Charah Receives Additional Awards for Employee Safety from North Carolina Department of Labor, July 2014, hq://charah.com/charah-receives-additional-awards-employee-safety-north-carolina-department-labor/. 5 Fatality Analysis Reporting System (FARS) Encyclopedia: Vehicles http://www- fars.nhtsa.dot. govNehiclesNehiclesAll Vehicles.aspx. 6 N.C. Coal Ash Commission Meeting Transcript, November 2014, http://www.duke-energy.com/pdfs/nc-coal-ash- commission-transcript 11142014.pdf 19 II. Other Mistakes in DEQ's Risk Ratinlz Analysis A. DEQ's Method of Calculating Risk Ratings for the December 31, 2015 Ratings Violates CAMA and Ignores the Environmental Damages and Risks at Lee A risk ranking process was specified in CAMA to determine the type of closure permitted at each facility. The law specifically requires NCDEQ to classify each impoundment as either high -risk, intermediate -risk, or low -risk, based on consideration, at a minimum, of all of the following criteria. (1) Any hazards to public health, safety, or welfare resulting from the impoundment. (2) The structural condition and hazard potential of the impoundment. (3) The proximity of surface waters to the impoundment and whether any surface waters are contaminated or threatened by contamination as a result of the impoundment. (4) Information concerning the horizontal and vertical extent of soil and groundwater contamination for all contaminants confirmed to be present in groundwater in exceedance of groundwater quality standards and all significant factors affecting contaminant transport. (5) The location and nature of all receptors and significant exposure pathways. (6) The geological and hydrogeological features influencing the movement and chemical and physical character of the contaminants. (7) The amount and characteristics of coal combustion residuals in the impoundment. (8) Whether the impoundment is located within an area subject to a 100-year flood. (9) Any other factor the Department deems relevant to establishment of risk. Environmental and ecologic damages and risks posed by the Lee site — and the factors designated by the legislature in CAMA — were not fully considered by DEQ when establishing the overall site risk and clean-up priority for Lee. This resulted in an overall Intermediate Risk rating, which requires excavation and removal, but does not fully recognize the risks of the Lee coal ash pits. For example, ten groundwater risk factors were established and received ratings by DEQ. Of the 10 rated factors for old and failing 1956 lagoon, 5 received low ratings because of the lack of drinking water wells or residents nearby. And the one "Key" factor that DEQ established for groundwater turns on the number of people using well water within 1500 feet. This approach fails to take into account the overall dangers of the Lee site, set out above, as well as the fact that this contaminated groundwater flows directly into one of the state's most important rivers, just upstream of a drinking water intake for thousands of people. In magnitude and importance, those factors overwhelm issues such as the number of people who may ingest soil. Yet, location near a drinking water intake is treated as just one factor in a process, and is not a "Key" factor. This approach prevents an accurate evaluation in two different ways: on the one hand, it picks out three "Key" factors when the entire site needs to be evaluated for all risks with an eye to the magnitude of risks, and it analyzes the site by counting a list of factors, when in general and as applied to a site, one or two factors may in fact be much more important that many or all of the rest. FIX Further, an approach that emphasizes current human use by key factors and a number of individual factors effectively ignores impacts to the natural environmental and natural resources. The General Assembly tasked DEQ with assessing the risk posed by these failing impoundments and directed DEQ to base its classifications on these sites' "risks to public health, safety, and welfare; the environment; and natural resources ...." N.C. Gen. Stat. § 130A-309.211(a) (emphasis added). To that end, CAMA requires consideration of "all receptors," which includes ecological receptors. DEQ failed to adequately consider these impacts. DEQ's approach also looks only at current human users and ignores future users of the groundwater and surface water resources. The purpose of CAMA and any environmental protection has to include protecting resources for future uses, not just current ones. Overall, DEQ did not consider adequately all the factors, as required by CAMA. If all factors are appropriately examined, Lee is a High Risk site. B. It is Irrational to Reduce the Risk Rating of a Site With Millions of Tons of Coal Ash Based on the Quantity of Coal Ash Stored In its January 2016 Report, DEQ states that it assessed risk at coal ash sites based on volume, and through unexplained and arbitrary distinctions DEQ thus lowered the groundwater risk at many sites below high risk for this factor. According to the DEQ treatment of this risk factor, any site under 3,240,10,3 tons is considered low risk; and any site (including Lee) under 12,512,755 tons is considered intermediate risk. There is no basis in law or fact for these distinctions, and the DEQ Report offers no scientific or legal basis for these distinctions. This analysis is based on the faulty assumption that some of the coal ash lagoons in the state will be low risk, some intermediate, and some high. There is no basis for this assumption in CAMA or in fact. CAMA does not grade on a curve, presuming some As, some Bs, and some Cs, Ds, and Fs. There is no reason to assume that there is any coal ash lagoon that is low risk. By making this assumption, the DEQ rankings rewrite the CAMA statute to guarantee that some sites will be low risk, rather than consider the true risk of every site. In fact, at least any unlined pit where millions of tons of coal ash are stored is high risk for groundwater contamination. One, two, or three million tons — and of course Lee's nearly six million tons — of coal ash are huge amounts of coal ash; they only appear to be lesser amounts when compared to the tremendous quantities of ash that Duke Energy has irresponsibly placed in some unlined pits over the years. When millions of tons of coal ash and other pollutants are in contact with a large surface area of unlined soil near bodies of water (as at Lee), then there is a high risk of coal ash groundwater contamination. Under this analysis, the Dan River site — which was the site of the catastrophic spill, which has serious groundwater contamination including arsenic, and which the Legislature itself ranked as a high risk site — is a low risk site for this groundwater contamination risk factor. Asheville, which the Legislature also determined to be high risk, is almost low risk and barely 21 rates intermediate. Sutton and Riverbend, which the Legislature also ranked as high risk, get only an intermediate ranking for this feature. Further, DEQ's own 2013 enforcement actions details serious groundwater contamination at sites throughout the state, regardless of the amount of ash stored at a particular site. Another striking example is Grainger in South Carolina. Less than 2 million tons of coal ash are stored at that site, yet it has had some of the highest — if not the highest — arsenic contamination of groundwater in the region. Its arsenic groundwater contamination has reached over 3000 ppb, or over 300 times the legal standard. One, two, or three million tons of coal ash, stored in unlined pits next to waterways, by definition pose a high risk to groundwater. That is certainly true of the nearly six million tons of coal ash stored at Lee directly on the river's banks, as demonstrated by the serious seeps at the site, the poor status of the dams, the site's presence in a floodplain, and established groundwater contamination. There is no basis for finding otherwise. In short, for this factor, Lee and all other coal ash sites are High Risk. C. DEQ's Groundwater Risk Evaluation Methodology Is Fundamentally Flawed DEQ's approach to classifying groundwater risk is fundamentally flawed because it is arbitrary, is not authorized by the CAMA statute, and it ignores the data gaps and uncertainty in Duke's reports. 1. Arbitrary Cutoff DEQ has decided arbitrarily that 10 North Carolinians' well water can be poisoned without requiring Duke to excavate its coal ash to lined, dry storage. DEQ only requires excavation — via an "Intermediate" risk classification — if 11 or more people's drinking water is actually or potentially contaminated. Narrative at 15. There is no support for such an arbitrary cutoff. Allowing even one North Carolinian's water to be poisoned is unacceptable. For DEQ to knowingly allow the actual or potential contamination of any family's drinking water fails the agency's most basic responsibility to the state. Allowing Duke Energy to leave coal ash in contact with groundwater supplies under a cap -in -place scenario would be just such a failing. This arbitrary approach also ignores the likelihood that a family served by contaminated well water could have more children, or the house could be sold to a larger family, so that more than 10 people would now be affected. Basing the key decision about lined storage of coal ash on an arbitrary snapshot is short-sighted and indefensible. More fundamentally, DEQ's approach ignores the importance of protecting groundwater as a public resource. If groundwater is being contaminated beyond Duke Energy's property boundary, an important public resource that belongs to all North Carolinians is being harmed. In addition, future economic development and new housing in rural areas not served by municipal 22 water depend on clean drinking water supplies. Duke cannot be allowed to leave its coal ash in contact with these groundwater supplies in perpetuity — it must be required to place the ash in lined, dry storage. For the same reasons, DEQ's claim that a "Low Risk" classification for groundwater is appropriate if "alternate water is made available to all residents whose wells are being impacted by coal ash impoundments" is unsupportable. Narrative at 70. This approach ignores the importance of protecting the resource for future uses, and of protecting the Neuse River, its tributaries and adjacent wetlands, and the natural environment for all North Carolinians. It is also inconsistent with the General Assembly's approach under CAMA. CAMA separately requires the provision of alternate water where a coal ash impoundment has contaminated a drinking water well. NCGS § 130A-309.211(c). That requirement applies irrespective of the impoundment risk classification required by CAMA, and there is no basis for using the separately required provision of alternate water to downgrade the risk rating for an impoundment. In addition, at Duke Energy's Sutton site in Wilmington, Duke was forced under public pressure to agree to fund a water line to residents of the Flemington community, yet even after that announcement, the General Assembly still rated the site High Priority and mandated excavation to lined, dry storage, thereby removing the source of the ongoing groundwater pollution. In a deposition this summer, DEQ Assistant Secretary Tom Reeder pointed out that Duke Energy's groundwater pollution at Sutton had "nuked this whole drinking water source for the Wilmington area." John Murawski, Top NC environmental official wanted to fine Duke Energy $50 million over coal ash, Charlotte Observer (Oct. 8, 2015), http://www.charlotteobserver.com/news/business/article38272179.html#stolylink=cpy. DEQ's groundwater risk classifications cannot use the separately required provision of alternate water to allow Duke to "nuke" public drinking water supplies and avoid having to remove the source of the pollution. 2. Invalid "Low -Intermediate" Classification For certain factors, such as if up to ten people are exposed to contaminated groundwater, and for overall ratings of sites where it says it does not have adequate information, DEQ has proposed an invented rating of "Low/Intermediate Risk." Narrative at 15. This is not a valid classification under LAMA. The statute required DEQ to propose ratings for all of Duke Energy's impoundments by December 31, 2015. N.C.G.S. § 130A-309.213(a). There are only three options — Low, Intermediate, and High Risk., id. at § 130A-309.213(b), and with good reason. After the Dan River spill and a federal criminal grand jury investigation into Duke Energy and DEQ's handling of coal ash, the law is supposed to ensure that the inaction that has characterized coal ash regulation in North Carolina for decades did not continue. The statute required DEQ to make a clear recommendation at every site whether to require lined storage, and allow the public to comment on a definite rating. Instead, DEQ has punted, avoiding that key decision and incentivizing Duke Energy to keep delaying and obscuring the extent of its contamination. 23 DEQ states, correctly, that Duke Energy's submissions have been deficient. The question is whether Duke Energy should be allowed to benefit from these shortcomings. The answer should be no. Duke appears to view uncertainty as a means to obscure risk. Duke has encouraged DEQ to act without knowing the extent of contamination to "make decisions before complete information about a site is available." Duke Energy, "Memorandum Regarding CAMA Requirements," Attachment 13, at 4. In a Duke Energy memo submitted to DEQ, Duke argues that CAMA "does not require the Department to completely know the vertical and horizontal extent for soil and groundwater contamination at each site." Id. By giving uncertainty and data gaps no real weight in the risk classifications, DEQ's key factor approach allows Duke to slant the prioritization process towards lower risk by withholding and/or obscuring unfavorable information. DEQ should take the approach that lined, dry storage is required until proven otherwise, and place the burden on Duke Energy to demonstrate that the coal ash could be safely stored without a liner. But instead, DEQ'has proposed a non -classification that fails to answer the key question for protection of groundwater: whether or not Duke will be required to store its coal ash in a lined, dry, properly designed facility. There is no legal basis for the "Low -Intermediate" classification. If there is not clear and convincing evidence to demonstrate that cap -in -place would protect public resources, excavation should be required. D. Ratings Based on "Key Factors" Are Illegal CAMA sets out an extensive list of factors that DEQ must consider in proposing its classifications. N.C.G.S. § 130A-309.213(a). CAMA requires DEQ to consider all of these factors, rather than ignoring most of them in favor of a handful of supposed "key factors." It plainly states that DEQ "shall ... at a minimum, consider all of the following" factors listed in the statute. DEQ's "key factor" approach violates this requirement. DEQ's staff compiled detailed ratings that fully analyzed these factors, but DEQ ultimately has put forward an approach that does not consider the required factors in any identifiable way. Instead, DEQ has arbitrarily invented a single "key factor" for groundwater, surface water, and dam safety, and ignored all the other factors. It has even moved these other factors to an appendix at the back of its Narrative, indicating their marginalized status. DEQ candidly admits that its discussion of other groundwater factors beyond the "key factor" is an empty exercise: "The decision -making process allows for scoring of high, intermediate, or low risk for all factors that relate to those criteria identified in CAMA, but is focused on assigning the overall groundwater risk classification based on" a single "key factor." Narrative at 13. In other words, all factors were assigned an individual rating, but only one factor determined the overall groundwater risk classification. The folly of this approach is evident from the example given in Part I.C.2 above: for the "key factor" that determined the groundwater risk rating, DEQ relied on Duke's self-serving 24 claims that it is not contaminating neighboring wells, while ignoring the uncertainties regarding groundwater flow direction and extent of the contamination that directly affect that very issue. DEQ acknowledged this uncertainty in the factors buried in the appendix, but ignored it for purposes of the groundwater key factor. Another example is dam safety. CAMA requires DEQ to consider "any hazards to public health, safety, or welfare resulting from the impoundment," the "hazard potential of the impoundment," "the proximity to surface waters to the impoundment," and "[w]hether the impoundment is located in an area subject to a 100-year flood." The Active Ash Basin is High risk based on current conditions, and is also High or Intermediate Risk for all but one of the other Dam Safety factors: • Hazard Classification: High Risk • Proximity to Waters of the State: High Risk • Volume of Facility: Intermediate Risk • Offsite Drainage Area: Intermediate Risk • Overall Dam Safety: High Risk In spite of these ratings, and solely on the basis of speculation about the effect of future repairs (discussed below), DEQ assigned the Active Basin a "Low Risk" rating for dam safety. However, the first four factors listed above are not affected by repairs — they are inherent risks of the design and location of the impoundment. That includes the flood plain issue as well. Even Duke has admitted the impoundments are not suitable for long-term storage of coal ash. Yet DEQ rated the Active Basin "Low Risk" for dam safety. Thus, the "key factor" approach has failed to meaningfully consider the factors required by CAMA for dam safety related issues. In sum, the "key factor" approach to groundwater, surface water, and dam safety adopted by DEQ fails to consider the required factors and violates LAMA. E. DEQ's Dam Safety Risk Evaluation Is Fundamentally Flawed DEQ's dam safety risk evaluation is fundamentally flawed. First, by using the "key factor" approach DEQ has given no identifiable weight to numerous dam safety considerations required by CAMA, as explained above. Second, DEQ has downgraded the dam safety risk for the Lee Active Basin based solely on the fact that Duke Energy proposes to perform various repairs. But speculations about future risk are not warranted under the Coal Ash Management Act. CAMA requires DEQ to take into account "the structural condition and hazard potential of the impoundment," among other factors. The Lee active impoundment has been given a "High Hazard" rating by the State of North Carolina. And all the impoundments have had numerous structural problems for many years, as set out in numerous inspection reports. CAMA does not ask DEQ to speculate about the possible risk level of coal ash impoundments after 25 future repairs may be approved and eventually completed; instead, it asks for a classification of the risks posed by the impoundments at the time of the evaluation. It is inappropriate to consider future repairs and speculate on their effectiveness. The Lee dams are dangerous because of their history, location, and basic design and structure. CAMA directs DEQ to consider "Any hazards to public health, safety, or welfare resulting from the impoundment" and "The structural condition and hazard potential of the impoundment." CAMA does not instruct DEQ to consider "structural condition and hazard potential if the dam is repaired at some future date," for example. DEQ must take the Lee dams as they exist. Otherwise, DEQ is looking at some future state of affairs and speculating on the effectiveness, if any, of proposed repairs over time. CAMA can be meaningful only if DEQ evaluates the Lee dams as they are, in the present, and not speculate on what may or may not transpire in the future. Indeed, the Dan River spill occurred because DEQ and Duke Energy counted on some future possible inspections or maintenance to take care of what was a dangerous and high risk coal ash storage facility. Second, the basic dangers of the Lee dams cannot be repaired. As set out above, the siting, hazard classification, volume, and other factors are inherent flaws in the Lee dams. These fundamental problems are not subject to adequate repair. And, to make matters worse, all these old, poorly designed, and failing dams are in a floodplain and most of them are directly on the Neuse River. These fundamental defects and risks cannot be repaired. In addition, elsewhere in the Narrative DEQ states that it included dewatering in its dam safety evaluation. But including speculation about the dam safety effects of dewatering is not an appropriate analysis under the CAMA statute. CAMA's classifications determine the schedule and closure methods available for each impoundment. Dewatering is part of the closure process, not part of the risk evaluation process, which logically must come before a classification and determination of a closure plan. Thus, trying to short-circuit the analysis set out in CAMA to incorporate part of the closure process into the Department's risk classifications is inappropriate. Volume, Free Water Content, and Drainage Area. The DEQ Classification system also artificially lowers the dam risk at Lee by breaking the site up into the separate impoundments for the Volume, Free Water Content, and Drainage Area factors. As set out above, Inactive Basins 1 and 2 are connected. They and Inactive Basin 3 are practically one unit, because they occupy the same wetland area, the same floodplain, and are alongside and on top o Half -Mile Branch and the other tributary streams, and the Cape Fear River as a unit. Active Basin and Polishing Pond together are separated from the Inactive Basins, but are part of the same floodplain. By breaking these impoundments apart and thereby assigning each of them a lower risk classification, the DEQ classifications for these factors tremendously understate the true risk of the Lee site. For these factors and others related to dam safety, Lee is High Risk. 26 F. Inappropriate Consideration of Cost The General Assembly did not include cost of closure and remediation in the list of studies and information Duke Energy is required to submit to DEQ in preparation for classification. See N.C. Gen. Stat. § 130A-309.209, 210. Nor is cost a factor the General Assembly identified for DEQ to consider as it develops proposed classifications. See id. § 130A- 309.213. CAMA does not permit DEQ to temper its analysis of the options and timetable for closure and remediation of coal ash impoundments. Indeed, CAMA specifically leaves any cost consideration until later in the process, at the closure plan stage: The only permissible consideration of costs under CAMA is by the Coal Ash Management Commission with respect to a coal ash impoundment closure plan — not the risk classifications. N.C. Gen. Stat. Ann. § 130A-309.214(d). Nonetheless, cost concerns permeated DEQ's prioritization analysis. The very first paragraph of DEQ's Narrative is dedicated to cost concerns: "[These classifications] are of critical importance because of the environmental impact and closure costs associated with each classification. Impoundments classified as intermediate or high must be excavated at a potential cost of up to $10 billion for all impoundments, while environmentally protective, less costly options are available for low priority impoundments. Closure costs could be passed on to the ratepayer. " Narrative at 2 (emphasis added). DEQ's own press release announcing public hearings on the draft classifications provided that "[t]he classification process is an important step in cleaning up coal ash to protect the environment and ratepayers." 7 DEQ apparently views its role in this process as integral to protecting ratepayers by insuring cleanup is not too costly. Concerns over cost permeated DEQ's analysis in violation of CAMA. Moreover, the numbers quoted by DEQ are Duke's numbers, not an independent evaluation.. Santee Cooper is excavating about 10% of the amount that Duke would be required to excavate for its entire fleet for $220 million. In fact, Duke itself has not claimed that the excavation and removal of ash will cost $10 billion. Duke admits that $2 billion of the number is the cost of going to dry storage in the future, and that excavation and removal will cost $6 to $8 billion. Duke's current activities will cost, according to Duke, $4 billion. So, the incremental cost — even according to Duke — should be $2 to $4 billion. DEQ, even according to Duke's numbers, is overstating the amount at issue tremendously. Moreover, using Santee Cooper real world experience, DEQ, by accepting Duke's numbers, is overstating the cost by 3x to 5x. hops://www.duke-energy.com/news/releases/2014042201.asp. Further, both SCE&G and Santee Cooper in South Carolina have stated that the excavations of all their coal ash will not require rate increases. An independent study of Duke Energy's claims has shown the same thing. http://www.ieefa.org/wp-content/uploads/2014/06/IEEFA-Duke-Study-Summary-Final-6-10- 141.pdf. 7 https://deq.nc.gov/press-release/deq-announces-l4-public-meetings-draft-coal-ash-pond-closure-deadlines. 27 G. The State of North Carolina Has Already Identified the Ongoing Pollution at Lee as High Risk CAMA requires DEQ to base its proposed classifications on "these sites' risks to public health, safety, and welfare; the environment; and natural resources ...." N.C.G.S. § 130A- 309.213 (a). On at least three other occasions, DEQ has determined that the Lee coal ash pollution is high risk. In March of 2014, DEQ conducted risk evaluations of all Duke Energy coal ash sites in the state. Attachment 14. Considering the factors at issue in the CAMA ratings, DEQ gave the Lee Active Basin a risk rating of 40. This rating is higher than the risk ratings for the Riverbend and Sutton sites designated by CAMA as High Priority. By definition, then, the Lee coal ash impoundments are high risk. In addition, DEQ has filed an enforcement action against Duke Energy for, among other things, unpermitted discharges to public waters at the Lee site. The State has said in its sworn complaint that these unpermitted discharges "pose[] a serious danger to the health, safety and welfare of the people of the State of North Carolina and serious harm to the water, resources of the State." State of North Carolina ex rel. North Carolina Department of Environmental Quality v. Duke Energy Progress, No. 13 CVS 11032 (Wake Co.), 1204 (emphasis added). The March 2014 evaluation and this sworn conclusion show that the "Intermediate" risk rating for the Lee impoundments does not adequately account for all the risks posed by this site. Finally, in a November 2015 comprehensive evaluation of groundwater, surface water, and dam safety factors, DEQ's professional staff rated all five of the Lee impoundments as "High Risk" after all modifications — including dam safety repairs and dewatering were taken into account — and also rated all five impoundments High Risk under current conditions. Attachment 15. Without any change in facts or law or any new information of any substance (or any new information at all, to our knowledge), DEQ has downgraded that rating to "Intermediate." There is no justification for this change. Finally, in April 2016, the North Carolina Superior Court ordered excavation and removal of ash from Lee as a remedy for water pollution at the Lee site. This ruling also amounts to a finding that the Lee site is High Risk. DEQ's risk classifications should reflect these serious threats to the public and our shared water resources, as CAMA explicitly requires. 28 Conclusion For all these reasons, the Lee Active Basin and Polishing Pond, and Inactive Basins 1-3, are High Risk and the coal ash must be excavated to lined, dry storage. Thank you for your consideration of these comments. SincqFr' rely, �— VS.ollem(a1n III Nicholas S. Torrey 29 Attachment 1 National Wetlands Inventory Map N.C. Division of Coastal Management Wetlands Map Attachment 2 H.F. Lee —Stream Map Lee Power Station t�"v— ��• '--ram/ ' i Oj�lrpj/P N ck Lake d / - L QkQ,ke ydk -� \ ' Neck; s'� • �� r �\ � fir,"/� � %- / I` � 1 � _ CZ ElPff - _ ! o ,J ens sYBreau Copyr_ight:© 2013 National_G.eograplii •_Socl'ety, i-cubed Additiornal Data Sources USGS EPA US Q DISCLAIMER: Map intended for illustrative purposes only. Ash 0 0.325 0.65 1.3 Miles pond and landfill boundaries are best estimates based on documents from EPA and the utilities themselves. Locations of existing and retired ash ponds and landfills were created by heads- Scale varies throughout map series up digitizing of aerial imagery and USGS 7.5 min. topographic Legend It maps. Outlined areas appearing to be void of a pond or landfill are thought to be retired units that are now covered in place. For Coal Ash Pond/Landfill Faciiit additional information see SoutheastCoalAsh.Org Stream/River � Southern — Y Map createdbyJovianSackett (jsackettCselcnc.org) Environmental Location Last Updated:412112014 Canal/Pipeline/other J' Law Center Attachment 3 Duke Energy — Safe Basin Closure Update Safe Basin Closure Update H.F. Lee Plant Duke Energy is committed to closing ash basins in ways that put safety first, protect the environment, minimize impacts to communities and manage costs. Building on the momentum of coal ash excavation work already underway at several Carolinas sites, the company announced its recommendations to fully excavate all five basins at the H.F. Lee Plant in Goldsboro, N.C. While the basins are currently operating safely, the basins are not suited for long-term permanent storage of the material. Based in science and engineering: Outside experts, along with Duke Energy engineers and environmental experts, conducted research at every basin, developed unique closure recommendations for each site and tested them against strict new state and federal regulations. Extensive science and engineering studies tell us that we need to excavate the 5.9 million tons of ash located in basins at the H.F. Lee Plant property and safely store the material in a fully lined solution. Studies noted the possible risk of flooding at the plant site, which makes excavation the best option for long-term safe storage of the material. Transportation: A transportation method and schedule will be determined in the coming months, but wherever possible the company wants to use rail to move the material and lessen the impact on local communities. ('DUKE ENERGY H.F. Lee Plant County: Wayne Commercial date: 1951 Retirement date: 2012 We're closing ash basins in ways that: C) 0 Put safety Protect the first environment L02 ripk. () Minimize impact Manage to communities costs Meeting state and federal standards: Duke Energy is committed to the health, safety and well-being of the communities we serve and to protecting the environment and natural resources. The company's proposed strategy is subject to the state's basin classification, public input and necessary approvals from the North Carolina Department of Environmental Quality. All recommendations comply with the U.S. Environmental Protection Agency's recently published federal Coal Combustion Residual (CCR) regulations and North Carolina's Coal Ash Management Act (CAMA). Site overview: When coal is burned, it creates multiple coal combustion products (CCPs), including fly ash, a fine material similar to the consistency of talcum powder, and bottom ash, which is a coarser, granular material collected from the bottom of coal-fired boilers. That material, totaling approximately 6 million tons at H.F. Lee, is safely stored on plant property, and the company continuously evaluates those storage methods. Because the H.F. Lee Plant has been retired, there is no coal combustion taking place and no additional ash being added to the ash basins. Over time, Duke Energy and the rest of the utility industry have changed and improved ash management practices. For more information about coal ash safe basin closure, please visit duke-energy.com/SafeBasinClosure. ©2016 Duke Energy Corporation 153890 2/16 Attachment 4 PSC-SC Duke Ex Parte Briefing re Coal Ash Disposal 2/10/16 THE PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA COLUMBIA, SOUTH CAROLINA PROCEEDING #16-11513 FEBRUARY 10, 2016 10:37 A.M. ALLOWABLE EX PARTE BRIEFING [ND-2016-5-E] REQUESTED BY DUKE ENERGY CAROLINAS, LLC (DEC) AND DUKE ENERGY PROGRESS (DEP) — COAL ASH DISPOSAL TRANSCRIPT OF ALLOWABLE EX PARTE BRIEFING COMMISSION MEMBERS PRESENT: Nikiya M. Nikki' HALL, Chairman; Swain E. WHITFIELD, Vice Chairman; and COMMISSIONERS John E. Butch' HOWARD, Elliott F. ELAM, JR. , Comer H. `Randy' RANDALL, Elizabeth B. 'Lib' FLEMING, and G. O'Neal HAMILTON, ADVISOR TO COMMISSION: Joseph Melchers, General Counsel STAFF PRESENT: F. David Butler, Senior Counsel; James Spearman, Ph.D., Executive Assistant to the Commissioners; B. Randall Dong, Esq . , Josh Mi nges , Esq . , and David W . Stark, III, Esq . , Legal Staff; Tom Ellison and Lynn Ballentine, Advisory Staff; Jo Elizabeth M. Wheat, CVR-CM/MIGNSC, Court Reporter; and Allison Minges and Deborah Easterling, Hearing Room Assistants APPEARANCES: HEATHER SHIRLEY SMITH, ESQUIRE, along with MIKE RU H E [Director, Environmental Policy and Affairs / Duke Energy (SC) ] , presenter, representing DUKE ENERGY CAROLINAS, LLC, AND DUKE ENERGY PROGRESS, LLC JEFFREY M. NELSON, ESQUIRE, representing t h e SOUTH CAROLINA OFFICE OF REGULATORY STAFF PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 10 1 EXECUTIVE CENTER DRIVE COLUMBIA, SC 29210 WWW.PSC.SC.GOV POST OFFICE BOX 1 1 649 COLUMBIA, SC 2921 1 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update 2 BRIEFING I N D E X Dnr-C PENING MATTERS ........................................... 3-6 PRESENTATION MR. MIKE RUHE [DUKE ENERGYJ ........................... 6 Question(s)/Comment by Commissioner Hamilton ............... 19 Questions)/Comment by Commissioner Howard ................. 20 Question(s)/Comment by Vice Chairman Whitfield ............. 23 Question(s)/Comment by Commissioner Fleming ................ 28 Question(s)/Comment by Commissioner Elam ................... 33 Question(s)/Comment by Vice Chairman Whitfield ............. 34 REPORTER'S CERTIFICATE ..................................... 39 Please note the following inclusions/attachments to the record: PowerPoint presentation (PDF) For identification of additional referenced materials (if any) and links for same, please see: ORS correspondence filed as part of the ex parte briefing process 2/10/16 PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 3 P R O C E E D I N G S CHAIRMAN HALL: Thank you. Be seated. Good morning, everyone. We will call this Allowable Ex Parte Briefing to order, and ask Mr. Melchers to read the docket, please. MR. MELCHERS: Thank you, Madam Chairman. Commissioners, we are here pursuant to a Notice of Request for Allowable Ex Parte Briefing. The requestors are Duke Energy Carolinas, LLC, and Duke Energy Progress, LLC. The topic is: Coal Ash Disposal. And we are here pursuant to that Notice in the Commission's hearing room, February 10th, at 10:30 in the morning. Madam Chair, if I could just make one programming note. Folks, we are having construction and remodeling done to our downstairs, so if you need to find a restroom, head up the stairs and then just keep going straight down the hall upstairs. Thanks. CHAIRMAN HALL: All riqht. Thank vou, Mr. Melchers. And who appears representing Duke Energy Carolinas? MS. SMITH: Heather Shirley Smith, on behalf PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 0 of Duke Energy Carolinas and Duke Energy Progress. CHAIRMAN HALL: Okay. Thank you. And for ORS? MR. NELSON: Good morning, Madam Chair. I'm Jeff Nelson. I represent the Office of Regulatory Staff as Mr. Dukes Scott's representative. CHAIRMAN HALL: Okay, Mr. Nelson. And do you have any remarks you wanted to give? MR. NELSON: I do. CHAIRMAN HALL: Okay. MR. NELSON: Thank you, Madam Chair. Typically, as I've tried to do in these, recently at least, I'd just like to do a little intro regarding procedures and everything, for some people maybe that haven't been here before. For those of you who don't know me, I'm Jeff Nelson, and I'm the Chief Counsel for the Office of Regulatory Staff, and I am here as the designee for the Executive Director of the Office of Regulatory Staff, this morning. As the ORS representative, it's my duty to certify the proceedings here this morning within 72 hours of them being concluded to the Chief Clerk of the Public Service Commission, so we operate on a fairly tight timeframe under the statutory framework that allows these allowable ex PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 5 partes. The requirements of the statute are, in part, the allowable ex parte be confined to the subject matter which has been noticed for this here today, and the subject matter noticed in this matter is "Coal Ash Disposal." So I, therefore, ask the presenters, the Commission, and the Staff to please keep the subject related just to coal ash disposal this morning. Additionally, the statute prohibits participants, Commissioners, or Commission Staff, from requesting or giving any commitment, predetermination, or prediction regarding any action by the Commission as to any ultimate or penultimate issue which either is or is likely to come before the Commission. We, therefore, ask the participants, Commissioners, and Staff, also, if possible, to keep from trying to refer to any additional documents or materials that aren't included in the presentation. When you do that, myself and Heather both have to try and pull this stuff together at the last minute, so we'd ask, if at all possible, that you try and refrain from referencing any documents like that. As a final note, I'd like to point out to PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 0 everybody here: Y'all should've gotten, when you came in today, a form at the table out here. You should have both signed in for the Public Service Commission and received a form. Good legal advice always is: Read the form. Read anything before you sign it. So, I would ask you to please read that, make sure you sign that form, and then turn it in before you leave today. That's all I have, Madam Chair. Thank you. CHAIRMAN HALL: Okay. Thank you. If there's nothing further, then Mr. Ruhe, if you want to go ahead with your presentation. MIKE RUHE [DUKE ENERGY]: Thank you. All right. CHAIRMAN HALL: Yeah, if you can hit that button and pull it closer, please. MIKE RUHE [DUKE ENERGY]: [Indicating.] Yeah. I see the lights now. Okay. CHAIRMAN HALL: Okay. MIKE RUHE [DUKE ENERGY]: All right. Good morning, Commissioners. [Reference: Presentation Slide 1] My name is Mike Ruhe. I'm the Environmental Policy & Affairs Director for Duke Energy here in South Carolina. Thank you for the opportunity to PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 7 provide this update on Duke Energy's coal ash management activities here in the State. It's been exactly one year since I was last here before you. Since then, much scientific and engineering work has been done at both our W.S. Lee and Robinson Plants. The results of that work have been shared with our regulators, and we worked closely with them and our local communities to finalize these ash basin closure strategies. [Reference: Presentation Slide 2] As you may recall, following the Dan River ash release in February of 2014, the company initiated a thorough engineering evaluation of all of its ash basins and related piping systems across our fleet. We are committed to the safe and reliable operations of those basins until they're ultimately closed. We've been developing a comprehensive, longer - term ash basin closure strategy for all of our ash basins. While closing these basins has always been part of our — of the company's vision, we have substantially accelerated that work. Because conditions at each site are unique, we believe that effective closure approaches should be based on site -specific science and engineering, and we've PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING engaged some of the best experts in the country to help us develop those protective closure strategies. These strategies must protect the public and they must protect groundwater. Further, we must be able to implement them safely. The results of this work has helped the company shape its overall ash management closure strategies for both Lee and Robinson, and I'm pleased to be able to share this update with you today. So let's first take a look at what we're doing at W.S. Lee. [Reference: Presentation Slide 3] To review, the Lee Steam Station was built in 1951. Units 1 and 2 were officially retired on November 6, 2014. Unit 3 was converted from coal - firing to natural gas last year. And construction of the new 750 megawatt natural-gas combined -cycle is well underway. Recall that the station has two active ash basins, a primary and secondary basin, and these basins no longer receive coal ash or coal -ash waste since those units are retired, but they do still receive processed wastewater from the plant. There's also a closed inactive basin from the PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 0 1950s, an ash structural fill, and a former borrow area where ash was placed years ago that is referred to as the ash fill area. Collectively, the site contains about 3.6 million tons of ash. [Reference: Presentation Slide 4] All right. Here's an overview picture of the site. You can see — I'll point out a couple of things. Hopefully, I don't shut the machine off. CHAIRMAN HALL: Just don't touch it. MIKE RUHE [DUKE ENERGY]: Yes. Here is the primary basin we're talking about [indicating], the secondary basin [indicating]. The structural fill [indicating] is right here. The plant proper [indicating]. The coal pile that's long been gone [indicating]. Here [indicating] is the inactive basin, right here; you can see the footprint here. And then the ash fill area is down here [indicating], just in the lower right corner. And, of course, there's the Saluda River [indicating]. [Reference: Presentation Slide 5] On September 23, 2014, the company announced that ash from the closed inactive basin and that ash fill area would be excavated and disposed of in a lined solution. Duke Energy entered into an PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 10 agreement with DHEC on September 29th of that year to do this work, and submitted an Ash Removal Plan to the agency on December 18th. We believe it will take about three years to complete the removal of the ash from these two areas. The company selected Waste Management, Incorporated, to excavate and transport ash from these two areas to a fully lined, solid -waste landfill located in Homer, Georgia. This landfill is also operated by Waste Management. Trucks started hauling that ash from the site on May 15th of last year, and so far, just over 260,000 tons have been excavated and transported off -site. That total represents about 19.2 percent of the total ash from those two areas. [Reference: Presentation Slide 6] Okay. And here, we just have highlighted those two areas a little bit more, so you can get a better idea of what we're talking about, you know. It just shows that other side of the road, where the ash fill area is. [Reference: Presentation Slide 7] All right. Here is an aerial view where — let's see, the ash fill area [indicating]. The inactive basin [indicating]. And, of course, in PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 11 the foreground here is where land was cleared for the natural gas combined -cycle plant. [Reference: Presentation Slide 8] All right. Here's the inactive basin after the trees were cleared and the topsoil removed, and you can see here, of course, the dark material is coal ash. [Reference: Presentation Slide 9] Here is a view, an overhead view, of how we're loading trucks at that site, and you can see we've got trucks that drive in, do the little loop here, and then backhoes are excavating ash and loading it into the trucks. Then they drive around to an automated truck wash, here, to help reduce dust, and then tarps are put over the truck to make sure no ash or dust gets off when it goes on the road. [Reference: Presentation Slide 10] Then the trucks would proceed out, and then they're weighed to make sure that they're in spec. on the weight. And then they go off on the road towards Georgia. [Reference: Presentation Slide 11] Of course, here's the route that we take, which is primarily Interstate highway. The company worked closely with Waste PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 12 Management, South Carolina DOT, and local municipal officials to determine the best route, or the best combination of haul routes, that would present the least impact to the local public. Obtaining meaningful community input was important to us, because we realized we'd be putting a lot of trucks on local roads as they left the station. So we met with community leaders, developed targeted messages for those neighbors, providing them updates about our plans. You know, we sent over 5000 letters to them through the mail and hosted community meetings where we had our project managers and subject -matter experts available to answer any of their questions. We also support a website, so interested parties can get the latest information about that project. You know, the information that we were able to get was invaluable to us, as we have to determine what the best routes to go from out of the — from leaving the station. [Reference: Presentation Slide 12] Okay, let's turn to discuss the other basins at the site. Recall on December 18, 2014, Duke Energy communicated to DHEC its closure strategy for the remaining ash, for the primary and PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 13 secondary basins and the structural fill. Now, based upon the results of that site - specific engineering work, the company decided, at that time, to excavate the ash from those two areas, as well, and to relocate them in a fully lined landfill. That analysis also explored options for disposing of this remaining ash at the Lee site. Duke Energy submitted a Conceptual Closure Plan for these areas on December 15, 2015, and that plan also included a design for a potential on -site, lined landfill. Currently, we are looking to site that landfill on the footprint of the existing secondary basin. Landfill siting studies are currently underway and we anticipate submitting a Landfill Permit Application to DHEC in October of this year. [Reference: Presentation Slide 13] All right. Here is a drawing of what we had in that proposed — in that Closure Plan. You can see the outline of the primary basin, secondary basin, and the structural fill. Now, our plans would be to drain the water out of the secondary basin, which is in the upper left-hand corner, and then what little ash was in there — because that secondary basin doesn't contain much ash — remove PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 14 that ash, put it in the primary basin, and then we would reconfigure that footprint to make it suitable for a landfill, and then line it, and then remove all the ash from the primary basin and that structural fill into that secondary basin footprint, and then cap it and close it. [Reference: Presentation Slide 14] So what are the advantages of the proposed closure strategy? Well, first and foremost, it eliminates the existing impoundments. Second, it consolidates the ash in a fully lined and capped location in close proximity to those existing ash management units, minimizing ash handling, and it also reduces community impacts. Third, groundwater is protected. That landfill will be lined and capped, leachate will be collected, and we will continue to perform groundwater monitoring to ensure that these controls function as designed. And, finally, we are eliminating the use of public roads for hauling ash once that landfill is operational. This is very important for our plant neighbors. [Reference: Presentation Slide 15] Now, let's take a look at the Robinson Plant. The Robinson coal unit was built in 1960 and PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTE DEC and DEP / Coal Ash Disposal Update BRIEFING 15 retired in September of 2012. The second Robinson unit is a 710 megawatt nuclear unit that continues to operate. The Robinson ash management facility includes a single -celled ash basin and what we are calling the 1960 fill area. That area's located just to the west of Units 1 and 2. The entire site contains about 4.2 million tons of ash. [Reference: Presentation Slide 16] And here's an aerial view of the site. Just to reorient you, the plant proper is down here — here's the plant proper, right down here [indicating]. The ash basin is up here [indicating] in this footprint. Here is Lake Robinson and the dam [indicating]. And the 1960 fill area — and I'll have another drawing to kind of highlight it — is in this area right here [indicating]. This part right here [indicating] is the footprint for the Darlington County CT site. That 72-acre ash basin is comprised of a 49- acre basin, itself, and then a 23-acre dry storage area located just to the western part of that basin. Ash thickness ranges anywhere between 11 to 53 feet. The surface of that ash basin is dry and has been dry for several years. [Reference: Presentation Slide 17] PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 16 The 1960 fill area was created when the plant started operating, and it received ash from Unit 1 until the current ash basin was constructed in the mid-'70s. Duke Energy contracted with an outside engineering firm in late 2013 to evaluate the extent and volume of the ash stored in that area. We've determined that this area covers approximately 25 acres and holds an estimated 330,000 tons of ash. Duke Energy entered into an agreement with DHEC on July 17, 2015, to excavate the ash from that area and relocate it to a proposed lined landfill to be built on -site. Landfill siting studies are currently underway for that landfill, and we anticipate submitting a Class 3 Landfill Permit Application to DHEC by April 1st. The agreement we signed with DHEC requires us to complete the excavation and removal of all ash from this area within eight years. [Reference: Presentation Slide 18] Okay. And here's that extra drawing I was showing you, zooming in on the plant a little bit. It's a little bit faint, but you can get an idea of where the boundary of that 1960 fill area is, right underneath part of the transmission corridor there. PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 17 [Reference: Presentation Slide 19[ So let's now take a look at the active basin at Robinson. We conducted a number of geotechnical studies in and around that basin and concluded, again, that the best closure strategy would be to excavate the ash from that area and relocate it to a lined solution. That decision was communicated to DHEC on April 30, 2015. A Conceptual Closure Plan was submitted to the agency on November 13th, and our plans are to dispose of this ash in the same landfill that's being constructed for the 1960 ash -fill ash. [Reference: Presentation Slide 20] The location of the proposed landfill's on Duke -Energy -owned land, on that adjacent Darlington County combustion turbine site. You can see, the square up there is the footprint of where we propose to put the landfill. [Reference: Presentation Slide 21] The advantages of this proposed closure strategy are very similar to those for W.S. Lee. First, it eliminates the existing impoundment and fill area. Second, it consolidates the ash on -site in a fully lined, capped location that's in close proximity to the existing ash management units. PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING Third, groundwater is protected. Ash will be removed and placed in an engineered landfill, segregated from groundwater. Leachate, again, will be collected, and we will perform groundwater monitoring to ensure that these controls function as designed. Finally, we'll be keeping ash trucks off of public roads. We're looking into the possibility of building either internal roads or possibly a conveyor system to get ash from those two areas to this new landfill. [Reference: Presentation Slide 22] As at W.S. Lee, we actively engaged the local community and our plant neighbors to obtain feedback about our site plans. We hosted community meetings there, as well, making our project leaders and subject -matter experts available to answer any questions. At Robinson, we sent out almost 1000 letters to plant neighbors, providing them information about the project. And like at Lee, we have a public website that provides the most current information about the project. Our employees live in that community also, so, you know, it's important to us to have all of our plant neighbors be knowledgeable and comfortable with the plans that we have at the site. PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 19 [Reference: Presentation Slide 23] So, in conclusion, Duke Energy is committed to closing our ash basis. We will do this safely and in a manner that protects the environment, particularly groundwater. We will do it in a way that minimizes the impacts to our communities, and we will continue to work with our neighbors to keep them informed on what we are doing. We will manage these projects in a manner that controls cost. And, finally, we will continue to work with DHEC to ensure that we meet all of our — all required regulatory standards. Thank you, so much, for your time. [Reference: Presentation Slide 24] CHAIRMAN HALL: Thank you, Mr. Ruhe. Commissioners, questions? Commissioner Hamilton. COMMISSIONER HAMILTON: Thank vou. Madam Chair. Happy to have you with us, today, sir, and we certainly appreciate the update. At this present time, are you on schedule with all DHEC requirements and time limits, et cetera? MIKE RUHE [DUKE ENERGY]: Yes, sir, we are. COMMISSIONER HAMILTON: Have we experienced PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 20 any fines in South Carolina, at this point? MIKE RUHE [DUKE ENERGY]: We have not. COMMISSIONER HAMILTON: Okay. So, as far as DHEC is concerned, the project is totally on schedule. MIKE RUHE [DUKE ENERGY]: Yes, sir. We — the project team meets with the technical folks over at DHEC monthly, you know, to keep them updated and because everything is really being fast -tracked, you know, in their minds, so we're working very closely with the agency to make sure all the reviews are working on schedule to meet the timeline. COMMISSIONER HAMILTON: Thank you, very much. Thank you, Madam Chair. CHAIRMAN HALL: Thank you. Commissioner Howard. COMMISSIONER HOWARD: Good morning. Explain to me what you mean by: still active as a wastewater treatment system. MIKE RUHE [DUKE ENERGY]: The plant has — those ponds are considered NPDES — National Pollutant Discharge System treatment systems, you know, for wastewater, and are regulated by DHEC. And so there are plant systems that still drain PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 21 water — think floor sumps, that kind of thing, that are still draining there. As part of the overall new permit that we've got, that we're just now getting from DHEC, you know, we will be closing all that down, you know, when we close down the basins, but we have to go over and have the new piping systems all ready to go before we can shut down that existing plant, because Unit 3 is still operating as a natural gas plant. COMMISSIONER HOWARD: Okay, thank you. Commissioner Hamilton asked you about any fines in South Carolina. What about fines about coal ash, in general? How many fines have you procured or are threatened with to have now for your coal ash disposal? MIKE RUHE [DUKE ENERGY]: There was the EPA fine that was announced early last year for the overall Dan River event. And then, in the press, there was a North Carolina Department of Environmental Quality fine for Dan River, also, that was between $6-$7 million, you know, for that event, too. COMMISSIONER HOWARD: How much, total, were they? MIKE RUHE [DUKE ENERGY]: How much, total? PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 22 COMMISSIONER HOWARD: Yeah, how many total fines do you have? MIKE RUHE [DUKE ENERGY]: Off the top of my head, I do not know. COMMISSIONER HOWARD: Well, how — MIKE RUHE [DUKE ENERGY]: The EPA fine was, I want to say, $100 million, you know, in that range. COMMISSIONER HOWARD: How do you plan cost recovery of these expenses? MIKE RUHE [DUKE ENERGY]: I — COMMISSIONER HOWARD: In other words, are you planning to put them in rate base or not? That's my question. MIKE RUHE [DUKE ENERGY]: Closure of ash basins, you know, since ash basins are part of the NPDES treatment system, we've always viewed eventual — we've always gone to eventual closure of those basins. I'm not the person that's really in a position to address rate questions. We'll have someone else come back, you know, at that time, when the time is right for that. COMMISSIONER HOWARD: A hundred miles comes to mind, but how long is the haul from this coal ash at the disposal to the landfill in Homer, Georgia? How long is that route? PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 23 MIKE RUHE [DUKE ENERGY]: I believe it's 75 miles. COMMISSIONER HOWARD: Thanks, very much. CHAIRMAN HALL: Commissioner Whitfield. VICE CHAIRMAN WHITFIELD: Thank you, Madam Chair. Thank you for this presentation. Appreciate having you back here again, a year later, to update us, and we appreciate you coming up to keep us informed. And I've got just a couple of quick questions. The Class 3 landfill that you said you'll be submitting the permit application in October of 2016, this year, when would that — assuming you have the application in then, when would that Class 3 landfill be operational at the Lee facility? MIKE RUHE [DUKE ENERGY]: It takes DHEC about between three and five years to approve a landfill and get it constructed, so that's why we've got eight years to dispose of — well, we have eight years to dispose of the ash from that one area. VICE CHAIRMAN WHITFIELD: So three to five years permitting, and another few years to — MIKE RUHE [DUKE ENERGY]: And — VICE CHAIRMAN WHITFIELD: — construct, so a PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 24 total of roughly eight years, is — MIKE RUHE [DUKE ENERGY]: That's correct. VICE CHAIRMAN WHITFIELD: — what you're looking at, before — MIKE RUHE [DUKE ENERGY]: And that's been the target that we've been working with DHEC, to try to get it done in eight years. VICE CHAIRMAN WHITFIELD: — before you would have on -site — MIKE RUHE [DUKE ENERGY]: Disposal capability. VICE CHAIRMAN WHITFIELD: And that's just for the active basins. The others, the inactive and the ash fill pit, all that material is all what's going to Homer, Georgia; is that correct? MIKE RUHE [DUKE ENERGY]: At W.S. Lee, that's correct. VICE CHAIRMAN WHITFIELD: Okay, those two are what's going to Homer, and the primary and secondary — the active — are the ones that you would be waiting to put in this new landfill on - site. MIKE RUHE [DUKE ENERGY]: That's correct. VICE CHAIRMAN WHITFIELD: Okay. Now, how about for the Robinson Plant? I see you're going to have that application in here in about a month PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 25 or so, in April. Is that on the same schedule, again about eight years out? MIKE RUHE [DUKE ENERGY]: Yes, sir. VICE CHAIRMAN WHITFIELD: Okay. And, obviously, it looks like, at Robinson, of course you're dealing with a lot less tonnage of ash, but you're going to be able to, as you said, do something on -site, maybe even a conveyor belt, and not actually have to put anything on the road, over at the Robinson plant. Is that the way I'm hearing it? MIKE RUHE [DUKE ENERGY]: That's what we're looking at. The decisions — the timeline decisions were based upon, you know, working through the investigation with DHEC. At W.S. Lee, there were concerns about, you know, those ash storage areas. The inactive landfill was very close to the river. VICE CHAIRMAN WHITFIELD: Right. MIKE RUHE [DUKE ENERGY]: And in discussions with them, we did not feel that it was in a stable situation for the long term, to wait until a landfill was sited. So that's why that — that determined the timeline there. Over at Robinson, it's a different situation. That 1960 fill area's not anywhere near the lake PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTE DEC and DEP / Coal Ash Disposal Update BRIEFING 26 and it's a very stable ash placement. So they were comfortable with the timeline of building a landfill on -site. VICE CHAIRMAN WHITFIELD: I see what you're saying. The inactive basin is the one that's right adjacent, like closest, to the Saluda River. MIKE RUHE [DUKE ENERGY]: Yes, sir. It's right close to the river and the dike is very steep right there. And so, because of the age of that basin, we were not as certain of the long-term stability, you know, until that time. You know, it was all heavily overgrown with trees, and our engineering folks did not think it was a stable configuration, long term, to wait that long. VICE CHAIRMAN WHITFIELD: I noticed that the tonnage you expect to move from Lee — I don't have that page right now, but I think it was 1.4 million tons — here it is — and you've moved not quite 20 percent, 19-point-something. And it looks like the timeline you're on, you're somewhat on target. Are you under a three-year contract with them to do that? Or is it an annual thing you continue to renew as the work gets done, as the ash gets hauled? Or what obligation are you under, if you could discuss that? PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 27 MIKE RUHE [DUKE ENERGY]: Well, we signed a consent agreement with DHEC, and that set up the timeline to go over and have that ash moved. And so we secured the trucking and everything else to accommodate that. And so, you know, our plans are to get it done within that three years. VICE CHAIRMAN WHITFIELD: And, of course, it's early, but it does look like you're somewhat on target — MIKE RUHE [DUKE ENERGY]: That's correct. VICE CHAIRMAN WHITFIELD: — from your percentages. Well, thank you, Mr. Ruhe. That's all I have. CHAIRMAN HALL: Thank you. Commissioner Fleming. COMMISSIONER FLEMING: Good morning, Mr. Ruhe. Nice to have you here today. MIKE RUHE [DUKE ENERGY]: Thank you. COMMISSIONER FLEMING: Commissioner Howard asked several of the questions that I wanted to ask, so — but I did want to go a little farther about how it will be paid for, the cleanup. And you've talked about the tariff has been used in the past, so the consumer would be the one responsible for paying for the cleanup. But what about the PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING fines? MIKE RUHE [DUKE ENERGY]: With all the cleanup, you know, that went with the Dan River — you know, to be honest, I'm a technical person. I've never really dealt with anything with the fines or that, so I don't have an answer for that. Heather, though, evidently does. [Laughter] MS. SMITH: Commissioner Fleming, we have stated before, publicly, that we would not seek recovery of those fines associated with the subject matter from ratepayers. And we'd be happy to provide a written statement to that effect, articulating that position, for the Commission, in conjunction with this ex parte presentation. COMMISSIONER FLEMING: Okay. And do you confirm, though, that you are planning to request the cleanup recovery in tariffs? MS. SMITH: We would request recovery for our activities, our prudent activities, related to ash disposal — not the fines, but those other activities. And we've publicly stated that, and we can include that language in anything we file with the Commission, as well. COMMISSIONER FLEMING: So the shareholders PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 29 will assume the responsibility for any fines. MS. SMITH: Yes. COMMISSIONER FLEMING: Okay. I know you had a limited timeframe, I believe in North Carolina, to remove the ash. MIKE RUHE [DUKE ENERGY]: [Nodding head.] COMMISSIONER FLEMING: And as a result of that, you said, as I recall, that that was a reason not to do recycling or reprocess of that ash, that there just wasn't enough time. Am I correct in that? MIKE RUHE [DUKE ENERGY]: In this presentation, I didn't say anything — COMMISSIONER FLEMING: No, no, no, no. In the past. MIKE RUHE [DUKE ENERGY]: The plants that we have in North Carolina are different than the ones we have in South Carolina. You know, our South Carolina plants were older plants. They did not have all of the pollution control agreement; they're not continuing to operate. So, you know, all our ash is sitting in ponds. To make ash suitable for recycling, you know, we would — there would have to be, in many cases, carbon burnout, or this, that — different PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 30 technologies done to make it suitable. And because our volumes, in the grand scheme of things, are very low at these two plants, economically it's not feasible. Now if you looked to the larger plants that have scrubbers and continue to operate, there are companies out there that will partner with utilities to go over and make ash more amenable to being recycled. But it's more difficult to do with ash that — you know, it's not worth many recyclers' time to set up an operation to do these types of volumes. COMMISSIONER FLEMING: So you would not be doing recycling or — MIKE RUHE [DUKE ENERGY]: We don't anticipate doing any recycling of this ash. COMMISSIONER FLEMING: — or reprocessing, because of the cost factor. MIKE RUHE [DUKE ENERGY]: Because of the cost, that's right. COMMISSIONER FLEMING: Okay. And I wanted to also go back — could you talk some more about the "active as a wastewater treatment" — and, I mean, because as I understood what you said, there is coal ash in that, as well, correct? PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 31 MIKE RUHE [DUKE ENERGY]: Right. COMMISSIONER FLEMING: And what are your plans for those that are still active? MIKE RUHE [DUKE ENERGY]: In South Carolina? Or in North Carolina? COMMISSIONER FLEMING: South Carolina. MIKE RUHE [DUKE ENERGY]: Well, I mean, you know, we still have active NPDES permits at both Robinson and W.S. Lee. Both those ash basins are still included in those permits. Part of the Conceptual Closure Plans for those sites are a requirement from DHEC to go over and close those ash management units. That's why we submitted them. And so we're going through closure right now, and then that — and once they're closed, they will be removed from the permit. COMMISSIONER FLEMING: Okay. So there won't be ash ponds — MIKE RUHE [DUKE ENERGY]: There'll be no — COMMISSIONER FLEMING: — once you've — MIKE RUHE [DUKE ENERGY]: — ash ponds left. COMMISSIONER FLEMING: — finished this, so they'll — MIKE RUHE [DUKE ENERGY]: That's correct. COMMISSIONER FLEMING: — be totally — PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 32 everything will be totally cleaned up. MIKE RUHE [DUKE ENERGY]: They'll be totally cleaned up. In fact, the last step will be, you know, analysis of the ground that's left, and it has to meet the criteria that DHEC sets for us, you know, to say that "You're done." COMMISSIONER FLEMING: I guess my confusion is the fact that you can continue to use it — that they continue to be active at the present time. MIKE RUHE [DUKE ENERGY]: Well, I mean, they're active until they're removed — COMMISSIONER FLEMING: Uh-huh? MIKE RUHE [DUKE ENERGY]: — you know, from the permit. And since they're still on the permit, we're still sampling them. COMMISSIONER FLEMING: So there's been no contamination, no — MIKE RUHE [DUKE ENERGY]: No — COMMISSIONER FLEMING: — release, as far as — MIKE RUHE [DUKE ENERGY]: You know, as processed water or rainwater or storm water goes into the pond, we do monitor those, and they are released like they were before, as long as they're within the specifications of our permit. But there's been no coal ash going to them for — you PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 33 know, since those plants stopped operating. COMMISSIONER FLEMING: Okay. And you're saying that both Lake Robinson and the Saluda River are — the measures that you're taking are protecting both of those water sources. MIKE RUHE [DUKE ENERGY]: Yes, ma'am. COMMISSIONER FLEMING: Okay. MIKE RUHE [DUKE ENERGY]: And groundwater, as well. COMMISSIONER FLEMING: Okay. Thank you. CHAIRMAN HALL: Commissioner Elam. COMMISSIONER ELAM: Good morning. Just one question out of curiosity, I guess. On 17 and 18 of the presentation, you were talking about the 1960 fill area. MIKE RUHE [DUKE ENERGY]: Right. COMMISSIONER ELAM: And on the picture, you had the fill area where the transmission corridor from the plant went right through it. MIKE RUHE [DUKE ENERGY]: [Nodding head.] COMMISSIONER ELAM: When you're excavating that, is that going to impact the operation of the plant? Are you going to have to move the transmission lines to keep the plant running, or... MIKE RUHE [DUKE ENERGY]: We will have to PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING coordinate that activity with plant operations. And we've had discussions with the agency about that. 34 COMMISSIONER ELAM: Okay. I just — it didn't seem like you could dig around it. [Laughter] Okay, thank you. CHAIRMAN HALL: Commissioner Whitfield. VICE CHAIRMAN WHITFIELD: Thank you, Madam Chairman. Mr. Ruhe, I've just got one quick follow-up on what we were talking about, about the ash that you are removing from the Lee facility and hauling to Homer, Georgia. Now that Ms. Smith has been real clear on what would be paid for by the shareholders and what would be paid for, or sought for payment, by the ratepayers, since you're doing this work kind of, as you would say, proactively, not as a result of any fine or not a fine in effect, and as we talked about the tonnage, you were on a percentage of almost 20 percent right now being hauled out of that facility, I guess what I was getting at when I asked you was the contract under a year, or three years — and if it's a contractual matter and you can't say, just let me know, but my PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 35 concern is, when you're dealing with a bulk item like ash and as you start to remove it, naturally, you're going to pick up dirt and other particles, and that 1.4 million tons might end up being 1.7 million tons or, you know, more than what you're estimating here, and if you find yourself a year or so down the road slipping in that percentage and as you get closer to finishing getting the remaining amounts, cleaning up all of the ash, naturally, that bulk item might be a little bigger than you think it is. And what is your out, I guess, since if you're going to potentially come seek recovery for this one day, what are you doing to manage the costs of this removal and transporting of this ash into Georgia? MIKE RUHE [DUKE ENERGY]: The volume of ash that's in that basin is just an estimate. You know, there weren't records really kept in those days to say how much was in there. So we've done geotechnical studies, probing, sticking probes in the ground and then just doing the math to figure out what an estimate of the tonnage would be. The timeline and the closure — the clean closure — requirements, you know, are outlined in the order that we have from DHEC. PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coa1 Ash Disposal Update BRIEFING VICE CHAIRMAN WHITFIELD: In the consent 36 order. MIKE RUHE [DUKE ENERGY]: Yes, in the consent order. So we're going to follow the requirements of that. VICE CHAIRMAN WHITFIELD: Well, I get — MIKE RUHE [DUKE ENERGY]: Now, as far as the details of how our contract is set up with Waste Management, I do not know those details. VICE CHAIRMAN WHITFIELD: Okay. Well, and I get that you have to abide by the DHEC consent order. I just wondered if there were any recourses you have if you see yourself slipping in where you need to be on the removal of that tonnage, or if that tonnage — you said it was an estimated number, 1.4 million tons — if it ends up being more than that, or for whatever reason — you know, I know when you're dealing with a bulk item, it's hard to get your arms around that sometimes. And I just wondered if you had any — if Duke had any management or oversight of that, to kind of manage where you are. And I do see your percentages here and you appear to be on target, but who knows if you're going to stay with that or slip or where you may be in the future, or what your recourse might PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update BRIEFING 37 be if you do. MIKE RUHE [DUKE ENERGY]: We've got a dedicated organization that is managing that project and has folks at the site, you know, to follow it. And I think right now we're probably doing 100 trips a day, you know, going back and forth. VICE CHAIRMAN WHITFIELD: Right. MIKE RUHE [DUKE ENERGY]: We believe that there's enough time in that timeline to go over and get it done within three years, you know, with the give or take. There were even some delays in the timeline just because of the heavy rains, both on our end and those rains hit Homer, Georgia, as well, and the landfills were closed for a week at a time. So, you know, we're working aggressively to go over and stay as close to that schedule as we can. VICE CHAIRMAN WHITFIELD: Well, thank you — MIKE RUHE [DUKE ENERGY]: And we think we can do it in the three years. We don't want to go back before DHEC and ask for an extension. VICE CHAIRMAN WHITFIELD: Well, I guess we'll know more at your next update. Thank you. Thank you, Madam Chair. PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ALLOWABLE EX PARTE DEC and DEP / Coal Ash Disposal Update BRIEFING CHAIRMAN HALL: Thank you. Commissioners, any other questions? [No response] Okay. Thank you, so much, for your presentation, Mr. Ruhe, and Ms. Smith, for assuring us that the fines will be absorbed by the shareholders. I think we breathe easier, hearing that. And if there's nothing else, then we are adjourned. [WHEREUPON, at 11:20 a.m., the proceedings in the above -entitled matter were adjourned.] PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA 2/10/16 ALLOWABLE EX PARTS DEC and DEP / Coal Ash Disposal Update 39 BRIEFING C E R T I F I C A T E I, Jo Elizabeth M. Wheat, CVR-CM-GNSC, do hereby certify that the foregoing is, to the best of my skill and ability, a true and correct transcript of all the proceedings had in an Allowable Ex Parte Proceeding held before THE PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA in Columbia, South Carolina, according to my verbatim record of same. Given under my hand this 101" day of February, 2016. Jo Elizabeth M. Wheat, CVR-CM/M-GNSC Court Reporter 2/10/16 PUBLIC SERVICE COMMISSION OF SOUTH CAROLINA Attachment 5 SCE&G Wateree Semi -Annual Status Report (relevant pages) July — December 2015 SOUTH CAROLINA ELECTRIC & GAS R<>WE r FUR Livrnr<; WAT E R E E STATION SEMI-ANNUAL STATUS REPORT JULY — DECEMBER 2015 January 2016 Semi -Annual Status Report SCE&G Wateree Station The purpose of this document is to present a status report for the six-month reporting period of July 1, 2015 through December 31, 2015 in accordance with the August 17, 2012, Settlement Agreement and Release ("Agreement") between the Catawba Riverkeeper Foundation, Inc. ("Riverkeeper") and South Carolina Electric & Gas Company ("SCE&G") 2 ASH REMOVED During the six-month reporting period of July 1, 2015 through December 31, 2015, approximately 131,088 dry tons of ash were removed from Pond 1. 3 RESULTS OF GROUNDWATER SAMPLING During the six-month reporting period of July 1, 2015 through December 31, 2015, groundwater sampling for wells monitored pursuant to the Mixing Zone Consent Agreement was performed, with the results presented in the following report: Semi -Annual Water Quality Monitoring Report: October 2015 Monitoring, SCE&G, Wateree Station, Eastover, South Carolina The above report has been submitted to SCDHEC. A copy of the report is attached. 4 ACTIVITIES PERFORMED During the six-month reporting period of July 1, 2015 through December 31, 2015, the following activities were performed in furtherance of the Undertakings described in Paragraph 1 of the Agreement: A. Paragraph 1.2: SCE&G continued to remove ash from Pond 1 for sale, recycling or placement in a Class 3 landfill. From January 1, 2012 to present (December 31, 2015), the cumulative net reduction of ash in Pond 1 is approximately 876,021 dry tons. SCE&G has achieved a net reduction of ash in Pond 1 of at least 240,000 tons from January 1, 2012 to January 1, 2015 as required in Paragraph 1.2 of the Agreement. July — December, 2015 Page 1 of 2 Semi -Annual Status Report SCE&G Wateree Station B. Paragraph 1.5: On December 5, 2015, the emergency ash sluice pipe for Unit #1 was removed by being capped and abandoned in place. Plans are underway for removal of the emergency sluice pipe for Unit #2 in the same manner, which will prevent the deposit of any coal ash into the Ponds and satisfy all requirements of Paragraph 1.5 of the Agreement. C. Paragraph 1.7: The final permit to construct a new synthetically lined wastewater pond to replace Pond 1 was issued by SCDHEC on October 16, 2015 (Permit Number: 19945-IW). SCE&G issued a notice to proceed for the construction of the new wastewater pond on November 9, 2015. July — December, 2015 Page 2 of 2 Table 1 Historical Summary of Constituent Concentrations in Groundwater Wateree Station South Carolina Electric & Gas Company Eastover, Richland County, South Carolina Well ID Event -T Sample Date Parameter Arsenic Cadmium Chromium Lead Sulfate MW-1 MZCL 50 5 100 50 2,000 ISM 4/17/01 <5 <1 <10 <5 2 2SO1 11/13/01 <5 <1 <10 <5 1.3 1S02 4/23/02 <5 <1 <10 <5 2.22 2SO2 10/23/02 <5 <1 <10 <5 3.88 1S03 4/15/03 <5 <1 <10 <5 0.86 2SO3 10/20/03 <5 <1 <10 <5 2.68 1SO4 3/9/04 <5 <1 <10 <5 1.1 2SO4 9/30/04 <5 <1 <10 <5 1.7 1S05 4/13/05 <5 <1 <10 6 3.05 2SO5 10/18/05 <5 <1 <10 5 5.01 1S06 3/15/06 5 <1 23 7 1.35 2SO6 10/16/06 <5 <1 <10 <5 1.2 1S07 4/30/07 <5 <1 <10 <5 0.69 2SO7 10/16/07 <5 <1 12 <5 8.9 1S08 4/16/08 <5 <1 <10 <5 1.4 2SO8 10/22/08 21.3 <1 80.3 67.5 0.56 2SO8 (Resample) 11/6/08 <5.0* NS NS NS NS 1S09 4/21/09 19 <1 93 40 11.36 1S09 (Resample) 5/7/09 24* <1* 86.0* 34.0* NS 2SO9 11/5/09 <5 <1 <10 <5 136.9 MW-IA 1510 4/20/10 <5 <1 <10 <5 0.75 2S10 10/19/10 <5 <1 <10 5.5 <0.50 1511 4/12/11 <5 <1 <5 <5 <0.50 2S11 2S11 (Resample) 11/1/11 9.3 <1 <5 <5 <0.50 2S11 (Resample) 11/22/11 <5* NS NS NS NS 1S12 5/15/12 <5 <1 <5 <5 <0.50 2S12 11/6/12 <5 <1 <5 <5 <0.50 1S13 5/13/13 <5 <1 <5 <5 <0.50 2S13 10/21/13 <5 <1 <5 <5 0.7 1S14 4/28/14 <5 <1 <5 <5 0.9 2S14 10/14/14 <5 <1 <5 <5 <0.5 1S15 4/14/15 <5 <1 <5 <5 <0.5 2S15 10/13/15 <5 <0.1 <0.5 1.6 <0.5 Page 1 of 9 Well ID Event Sample Date Parameter Arsenic Cadmium Chromium Lead Sulfate MW-2 MZCL 50 5 100 50 2,000 1501 4/17/01 <5 <1 <10 <5 66.9 2SO1 11/13/01 <5 <1 <10 <5 57.7 1S02 4/23/02 <5 <1 <10 <5 52.6 2S02 10/23/02 <5 <1 <10 <5 60.3 1S03 4/15/03 <5 <1 <10 <5 52.4 2SO3 10/20/03 <5 <1 <10 <5 54.39 1SO4 3/9/04 <5 <1 <10 <5 52 2SO4 9/30/04 <5 <1 <10 <5 45.8 1S05 4/13/05 <5 <1 <10 <5 45.9 2SO5 10/18/05 <5 <1 <10 <5 44.6 1S06 3/15/06 <5 <1 <10 <5 39.56 2SO6 10/16/06 <5 <1 <10 <5 35.9 1S07 4/30/07 <5 <1 <10 <5 32.2 2SO7 10/16/07 <5 <1 <10 <5 34 1S08 4/16/08 <5 <1 <10 <5 38.3 2SO8 10/22/08 <5 <1 <10 8.4 33.7 1S09 4/21/09 <5 <1 <10 8.4 37.7 2SO9 11/5/09 <5 <1 <10 <5 31.4 1510 4/20/10 <5 <1 <10 <5 35.8 2S10 10/19/10 <5 <1 <10 <5 27.9 1511 4/12/11 <5 <1 <5 <5 33.6 2S11 11/1/11 <5 <1 <5 <5 34 1S12 5/15/12 <5 <1 <5 <5 34.6 2S12 11/6/12 5.1 <1 <5 <5 40.7 1S13 5/13/13 <5 <1 <5 <5 44.6 2S13 10/21/13 <5 <1 <5 <5 40.4 1S14 4/28/14 <5 <1 <5 <5 28.8 2S14 10/14/14 <5 <1 <5 <5 45.2 1S15 4/15/15 <5 <1 <5 <5 44.5 Page 2 of 9 Well ID Event Sample Date Parameter Arsenic Cadmium Chromium Lead Sulfate 2S15 10/13/15 2 <0.1 <0.5 <0.5 52.76 MW-3 MZCL 3,000 5 100 50 2,000 1501 4/17/01 165 <1 <10 <5 73.4 2SO1 11/13/01 231 <1 <10 <5 57.8 1S02 4/23/02 <1 <10 <5 64.1 2SO2 10/23/02 186 <1 <10 <5 57.2 1S03 4/15/03 284 <1 <10 <5 63.9 2SO3 10/20/03 193 <1 <10 <5 56.76 1SO4 3/9/04 432.7 <1 <10 <5 38.8 2SO4 9/30/04 198 <1 <10 22.4 44.8 1S05 4/13/05 377 <1 13 6 40.1 2SO5 10/18/05 201 <1 <10 <5 52.3 1SO6 3/15/06 305 <1 <10 <5 42.35 2SO6 10/16/06 209 <1 <10 <5 45.1 1S07 4/30/07 232 <1 <10 <5 43.8 2SO7 10/16/07 179 <1 <10 <5 38.1 1S08 4/16/08 402 <1 <10 <5 47.2 2SO8 10/22/08 189 <1 <10 <5 40.98 2SO8 11/6/08 208* NS NS NS NS 1S09 4/21/09 294 <1 <10 <5 35.8 1S09 (Resample) 5/7/09 143* <1* <10* <5* NS 2SO9 11/5/09 162 <1 <10 <5 29.6 1510 4/20/10 485 <1 <10 <5 36.6 2S10 10/19/10 144 <1 <10 <5 28.1 1511 4/12/11 176 1.3 <5 <5 63 2S11 11/1/11 202 <1 <5 <5 46.7 1S12 5/15/12 164 <1 <5 <5 58.8 2S12 11/6/12 162 <1 <5 <5 41.9 1S13 5/13/13 103 <1 <5 <5 70.5 2S13 10/21/13 153 <1 <5 <5 86.4 1S14 4/28/14 82.8 1.2 <5 <5 44.6 2S14 10/14/14 122 <1 <5 <5 59.1 1S15 4/15/15 52.5 <1 <5 <5 15.6 Page 3 of 9 Well ID Event Sample Date Parameter Arsenic Cadmium Chromium Lead Sulfate 2S15 10/12/15 2.9 <0.1 <0.5 <0.5 <0.5 MWA MZCL 3,000 5 100 50 2,000 1501 4/17/01 8.1 <1 <10 <5 4.6 2SO1 11/13/01 <5 <1 <10 <5 4.4 1S02 4/23/02 8.8 <1 <10 <5 4.8 2SO2 10/23/02 <5 <1 <10 <5 4.1 1S03 4/15/03 12.3 <1 <10 <5 5.5 2SO3 10/20/03 <5 <1 <10 <5 2.91 1SO4 3/9/04 7.6 3.4 <10 <5 2.2 2SO4 9/30/04 7.9 2.2 <10 <5 12.6 1S05 4/13/05 <5 <1 <10 <5 3.39 2SO5 10/18/05 15.1 3.4 <10 <5 6.3 1SO6 3/15/06 <5 2.2 <10 <5 3.96 2SO6 10/16/06 <5 <1 <10 <5 4.3 1S07 4/30/07 <5 <1 <10 <5 <0.50 2SO7 10/16/07 <5 <1 <10 <5 <0.50 1S08 4/16/08 <5 1.1 <10 <5 <0.5 2SO8 10/22/08 <5 <1 <10 <5 <0.5 1S09 4/21/09 <5 <1 <10 <5 7.02 2SO9 11/5/09 <5 <1 <10 <5 <0.5 1510 4/20/10 <5 3.2 <10 <5 10.4 2S10 10/19/10 <5 <1 <10 <5 <0.5 1511 4/12/11 <5 <1 <5 <5 <0.5 2S11 11/1/11 <5 <1 <5 <5 3 1S12 5/15/12 <5 1.9 <5 <5 8.7 2S12 11/6/12 <5 1.5 <5 <5 <0.5 1S13 5/13/13 <5 1.5 <5 <5 1.05 2S13 10/21/13 <5 <1 <5 <5 0.9 1S14 4/28/14 <5 3.6 <5 <5 6.1 2S14 10/14/14 <5 3.7 <5 <5 0.96 1S15 4/15/15 <5 <1 <5 <5 1.4 Page 4 of 9 Well ID Event Sample Date Parameter Arsenic Cadmium Chromium Lead Sulfate 2S15 10/12/15 2 <0.1 0.5 <0.5 0.71 MW-5 MZCL 50 15 100 50 2,000 1501 4/17/01 <5 2.2 <10 <5 0.7 2SO1 11/13/01 <5 <1 <10 <5 34.6 1S02 4/23/02 5 4.2 18.5 8.5 1.93 2SO2 10/23/02 <5 <1 <10 <5 2.71 1S03 4/15/03 15.4 <1 <10 <5 <0.5 2SO3 10/20/03 <5 <1 <10 <5 <0.5 1SO4 3/9/04 8 3.1 <10 <5 <0.5 2SO4 9/30/04 7.3 5.8 <10 <5 4 1S05 4/13/05 10 <1 15 8 <0.5 2SO5 10/18/05 5.2 5.4 <10 <5 <0.5 1SO6 3/15/06 <5 5.5 <10 <5 <0.5 2SO6 10/16/06 <5 <1 <10 <5 <0.5 1S07 4/30/07 <5 <1 <10 <5 <0.50 2SO7 10/16/07 <5 1.14 <10 <5 <0.50 1S08 4/16/08 <5 1.9 <10 <5 <0.5 2SO8 10/22/08 <5 1.4 <10 6.6 <0.5 1S09 4/21/09 <5 <1 <10 <5 <0.5 2SO9 11/5/09 <5 <1 <10 <5 <0.5 1510 4/20/10 <5 3.4 <10 <5 <0.5 2S10 10/19/10 <5 <1 <10 <5 <0.5 1511 4/12/11 6.1 <1 <5 <5 <0.5 2S11 11/1/11 9.1 <1 <5 6.1 4 2S11 (Resample) 12/2/11 <5* NS NS NS NS 1S12 5/15/12 <5 3.4 <5 7 13.4 2S12 11/6/12 <5 2.9 <5 8.8 37.8 1S13 5/13/13 5.7 <1 9.5 7.2 <0.5 2S13 10/21/13 <5 1.1 <5 6.4 0.9 1S14 4/28/14 <5 3.5 5.7 <5 0.9 2S14 10/13/14 <5 <1 <5 6.2 <0.5 1S15 4/14/15 <5 2.9 <5 <5 <0.5 2S15 10/12/15 4.4 <0.1 <0.5 <0.5 <0.5 Page 5 of 9 Well ID Event Sample Date Parameter Arsenic Cadmium Chromium Lead Sulfate MW-6 MZCL 50 5 100 50 2,000 2SO1 11/13/01 <5 <1 <10 <5 48.4 1S02 4/23/02 <5 <1 <10 <5 47.9 2SO2 10/23/02 <5 <1 <10 <5 39.5 1S03 4/15/03 <5 <1 <10 <5 32.4 2SO3 10/20/03 <5 <1 <10 <5 44.92 1SO4 3/9/04 <5 2.8 <10 <5 2.9 2SO4 9/30/04 <5 <1 <10 <5 32.1 1SO5 4/13/05 <5 <1 <10 <5 29.6 2SO5 10/18/05 <5 <1 <10 <5 35.9 1S06 3/15/06 <5 <1 <10 <5 34.22 2SO6 10/16/06 <5 <1 <10 <5 30.4 1S07 4/30/07 <5 <1 <10 <5 <0.50 2SO7 10/16/07 <5 <1 187 11.6 <0.50 1S08 4/16/08 6.4 <1 <10 <5 30 2SO8 10/22/08 <5 <1 29.6 <5 24.5 1S09 4/21/09 <5 <1 <10 <5 <0.5 2SO9 11/5/09 <5 <1 <10 <5 22.5 1510 4/20/10 <5 3.4 <10 <5 1.56 2S10 10/19/10 <5 3.7 <10 <5 5.33 1511 4/12/11 <5 1.2 <5 <5 29.9 2S11 11/1/11 <5 1.2 <5 <5 29.4 1S12 5/16/12 6.7 <1 7.3 <5 35 2S12 11/6/12 <5 <1 <5 <5 37.2 1S13 5/13/13 5 <1 <5 <5 31.2 2S13 10/21/13 <5 <1 <5 <5 34.8 1S14 4/28/14 <5 <1 <5 <5 26 2S14 10/13/14 <5 <1 <5 <5 26.2 1S15 4/14/15 <5 <1 <5 <5 30.8 Page 6 of 9 Well ID Event Sample Date Parameter Arsenic Cadmium Chromium Lead Sulfate 2S15 10/12/15 0.8 <0.1 <0.5 <0.5 29.52 MW-8 MZCL 50 15 100 50 2,000 1501 4/17/01 15.1 1 <10 <5 226.8 2SO1 11/13/01 <5 <1 <10 <5 91.6 1S02 4/23/02 7.8 <1 <10 5 158.5 2SO2 10/23/02 <5 <1 <10 <5 243 1S03 4/15/03 <5 4.4 <10 <5 441.3 2SO3 10/20/03 19.8 3.4 <10 <5 164.9 1SO4 3/9/04 <5 3.9 <10 <5 99.2 2SO4 9/30/04 <5 <1 <10 <5 247.1 1S05 4/13/05 <5 <1 <10 <5 290 2SO5 10/18/05 <5 <1 <10 <5 314 1SO6 3/15/06 <5 2.8 <10 <5 207.8 2SO6 10/16/06 <5 <1 <10 <5 170 1S07 4/30/07 6 <1 <10 <5 73 2SO7 10/16/07 <5 <1 <10 <5 13 1S08 4/16/08 <5 <1 <10 <5 15.1 2SO8 10/22/08 <5 <1 <10 <5 3.2 1S09 4/21/09 <5 <1 <10 <5 37.1 2SO9 11/5/09 <5 <1 <10 <5 37.8 1510 4/20/10 <5 3.1 <10 <5 12.08 2S10 10/19/10 <5 3.1 <10 <5 1.11 1511 4/12/11 <5 <1 6.5 <5 66.3 2S11 11/1/11 <10 2.2 <10 <10 115 1S12 5/16/12 <50 <10 <50 <50 195 2S12 11/6/12 10.7 2.8 <10 <10 198 1S13 5/13/13 <5 <1 5 10.6 129.9 2S13 10/21/13 <5 <1 <5 5.6 125 1S14 4/28/14 <5 2 <5 <5 119 2S14 10/13/14 <5 <1 <5 <5 77.4 1S15 4/14/15 <5 <1 <5 5 63.8 2S15 10/12/15 1.7 <0.1 2 0.62 49.4 Page 7 of 9 Well ID Event Sample Date Parameter Arsenic Cadmium Chromium Lead Sulfate MW-9 MZCL 50 15 100 50 2,000 1501 4/17/01 <5 5.8 <10 <5 1,040 2SO1 11/13/01 <5 <1 <10 <5 1,182 1S02 4/23/02 <5 7.9 <10 5 1,044 2S02 10/23/02 <5 <1 <10 <5 1,603 1S03 4/15/03 7.7 8.8 <10 <5 775.6 2SO3 10/20/03 <5 <1 <10 <5 824.5 1SO4 3/9/04 <5 6.9 <10 <5 962 2SO4 9/30/04 <5 1 <10 <5 775.4 1S05 4/13/05 <5 <1 <10 <5 963 2SO5 10/18/05 <5 4.5 <10 <5 916 1S06 3/15/06 <5 <1 <10 <5 957 2SO6 10/16/06 <5 <1 <10 <5 861 1S07 4/30/07 <5 <1 <10 <5 241 2SO7 10/16/07 <5 <1 <10 <5 1,200 1S08 4/16/08 <5 2.4 <10 <5 9,330 2SO8 10/22/08 <5 2.4 <10 <5 1,247.30 1S09 4/21/09 <5 <1 <10 <5 432 2SO9 11/5/09 <5 <1 <10 <5 1,017 1510 4/20/10 <5 <1 <10 <5 992 2S10 10/19/10 <5 <1 <10 <5 1,045 1511 4/12/11 7.4 3.6 <5 8.8 900 2S11 11/1/11 9.6 <1 <5 10 992 2S11 (Resample) 12/2/11 <5* <1* NS NS NS 1S12 5/15/12 <5 2.2 <5 13.4 978 2S12 11/6/12 <5 8.2 <5 13.6 945 1S13 5/13/13 <5 2.2 <5 13.9 710 2S13 10/21/13 <5 3.4 <5 12 926 1S14 4/28/14 <5 <1 <5 9.1 425 2S14 10/13/14 <5 <1 <5 11.5 973 1S15 4/14/15 <5 <1 <5 11.1 761 2S15 10/13/15 3.9 0.5 0.6 <0.5 707.9 Page 8 of 9 Well ID Event Sample Date Parameter Arsenic Cadmium Chromium Lead Sulfate MW-11 MZCL 3,000 5 100 50 2,000 1SO1 4/17/01 565 <1 <10 <5 59.2 2SO1 11/13/01 1,150 <1 <10 <5 60.3 1S02 4/23/02 1,143 <1 <10 <5 63.8 2S02 10/23/02 774 <1 <10 <5 68.2 1S03 4/15/03 322 <1 <10 <5 57.7 2SO3 10/20/03 1,345 <1 <10 <5 63.9 1SO4 3/9/04 337 <1 19.2 7.9 54.3 2SO4 9/30/04 563 <1 18.7 9.7 40.7 1S05 4/13/05 891 <1 73 39 53.9 2SO5 10/18/05 1,512 <1 31.4 13.7 54.2 1S06 3/15/06 5,100 <1 40 14 36.82 1S06 (Resample) 6/1/06 968* NS NS NS NS 2SO6 10/16/06 1,492 <1 <10 <5 68.2 1S07 4/30/07 4,051 <1 10 7 27.5 1S07 (Resample) 5/7/07 252* NS NS NS NS 2SO7 10/16/07 2,452 <1 <10 5.2 26.8 1S08 4/16/08 310 <1 <10 <5 35.4 2SO8 10/22/08 2,149 <1 13.2 8 32.04 2SO8 (Resample) 11/6/08 424* NS NS NS NS 1S09 4/21/09 567 <1 <10 <5 41.9 1S09 (Resample) 5/7/09 932* <1* <10* <5* NS 2SO9 11/5/09 576 <1 <10 <5 27.6 1S10 4/20/10 796 <1 31.7 10.9 60.8 2S10 10/19/10 696 <1 <10 <5 55.7 1S11 4/12/11 380 <1 8.7 <5 44.5 1S11 (Resample) 6/15/11 1,100* <1* <5* <5* 102.4* 2S11 11/1/11 318 <1 <5 <5 107 1S12 5/15/12 690 <1 <5 <5 85.8 2S12 11/6/12 460 <1 <5 <5 43 1S13 5/13/13 94.5 <1 <5 <5 24.7 2S13 10/22/13 355 <1 <5 <5 42.4 1S14 4/28/14 97 <1 <5 <5 25.9 2S14 10/13/14 101 <1 <5 <5 22.2 1S15 4/14/15 93.8 <1 <5 <5 15.5 2S15 10/13/15 58.6 <0.1 1.8 0.61 19.35 MW-12 1S15 4/14/15 <5.0 <1.0 <5.0 <5.0 24.6 2S15 10/13/15 1.9 <0.1 0.5 <0.5 30.12 Notes: 1) All concentrations for total metals and are provided in micrograms per liter (µg/I). 2) Sulfate concentrations are provided in milligrams per liter (mg/L). 3) MZCL = Mixing Zone Contaminant Level. 4) MZCL for arsenic for wells MW-1A, MW-2, MW-5, MW-6, MW-8, and MW-9 is 50 ug/l. 5) MZCL for arsenic for wells MW-3, MW-4, and MW-11 is 3,000 ug/l. 6) MZCL for cadmium for wells MW-1, MW-2, MW-3, MW-4, MW-6, and MW-11 is 5.0 ug/I. 7) MZCL for cadmium for wells MW-5, MW-8, and MW-9 is 15.0 ug/I. 8) NS = Not analyzed. 9) Bold type indicates concentration above MZCL. 10) * = Results of resampling Page 9 of 9 Attachment 6 GGS Ash Removal Report 2014 YTD 1/14/15 psantee cooper FEDEX January 14, 2015 Jeffrey P. deBessonet, Director South Carolina Department of Health and Environmental Control Water Facilities Permitting Division 2600 Bull Street Columbia, South Carolina 29201 RE: Grainger Generating Station Ash Pond Closure: Ash Removal Report Santee Cooper's annual closure plan states that Santee Cooper will provide status reports to DHEC every six months regarding the amount of ash and underlying soil removed from Grainger Generating Station. Removal of ash for beneficial use began at Grainger on March 17, 2014. The following table provides tons of ash and soil removed for 2014. Year Month Ash tons 2014 January 0 0 2014 February 0 0 2014 March 4,700 0 2014 April 6,018 0 2014 May 11,906 0 2014 June 20,264 0 2014 July 14,886 0 2014 August 19,711 0 2014 September 25,862 0 2014 October 25,453 0 2014 November 23,022 0 2014 December 12,894 0 One Riverwood Drive I Moncks Corner, SC 29461-2901 1 (843) 761-8000 1 P.O. Box 2946101 I Moncks Corner; SC 29461-6101 Jeffrey P. deBessonet, Director SCDHEC January 14, 2015 Page 2 Sincerely, %Z Thomas L. Kiersp , Vice President Environmental, Property and Water Systems Management TLK:M :Af Wgb ,t cc: Frank Holleman Attachment 7 GGS Ash Removal Report 2015 YTD 1/11/16 Vsantee cooper CERTIFIED MAIL January 11, 2016 Jeffrey P. deBessonet, Director South Carolina Department of Health and Environmental Control Water Facilities Permitting Division 2600 Bull Street Columbia, South Carolina 29201 RE: Grainger Generating Station Ash Pond Closure: Ash Removal Report Santee Cooper's annual closure plan states that Santee Cooper will provide status reports to DHEC every six months regarding the amount of ash and underlying soil removed from Grainger Generating Station. Removal of ash for beneficial use began at Grainger on March 17, 2014. The following table provides tons of ash and soil removed for 2015. Year Month Ash (tons) Soil (tons) 2015 January 28,720 0 2015 February 19,922 0 2015 March 1,051 0 2015 Aril 31,784 0 2015 May 22,211 0 2015 June 28,964 0 2015 July 30,106 0 2015 August 12,117 0 2015 September 32,767 0 2015 October 21,676 0 2015 November 33,917 0 2015 December 21,202 0 2015 Total YTD) 284,438 Sincerely, TL Thomas L. Kiers Vice President Environmental, Property and Water Systems Management TLK: MrDM-cgb cc. Frank Holleman One R6er ood Dwe I MonCKS Corner,SC 29401-2901 1 (843) 761-8000 1 P.O. B.. 2946101 1 M=n Corner, SC 29461-6101 Attachment 8 Grainger Groundwater Monitoring Results 11/22/13 CERTIFIED MAIL November 22, 2013 Mr. Chris Forrest Groundwater Protection Section SCDHEC Bureau of Water 2600 Bull Street Columbia, South Carolina 29201 Mr. Keith Collinsworth, Manager State Voluntary Cleanup Section SCDHEC Bureau of Land and Waste Management 2600 Bull $treet Columbia, South Carolina 29201 Dear Mr. Forrest and Mr. Collingsworth: 5cantee cooper Re: South Carolina Public Service Authority Santee Cooper Grainger Generating Station, Horry County NPDES Permit# SC0001104; Site ID# 00367 NPDES Groundwater Semi-annual and Compliance Report for 2013 Enclosed are the results of the September 30-October 1, 2013, groundwater sampling event for the NPDES Permit# SC0001104 groundwater monitoring and compliance wells located at the Grainger Generating Station. Included with this report are the results from the surface water sampling, staff gauge readings, a sample location map, a potentiometric map, and an arsenic concentration map which delineates the distribution of arsenic at the site. Lab results showed measurable concentrations of arsenic in six of the eighteen locations where water samples were analyzed. Three were groundwater wells along the down gradient edge of Ash Pond 1 and three were groundwater wells along the down gradient edge of Ash Pond 2. While there is a good distribution of data points across the site, the locations with measurable concentrations are segregated from each other by the close proximity of non -detectable results in the river, the intake canal, and adjacent groundwater wells. All of these factors prevented the use of isoconcentration lines. If you have any questions or comments concerniirg this report, please contact Melanie Hill at (803) 761-8000 extension 4490. Ore Rivenvood Drive I Moncks Corner, SC 29461-2901 1 (843) 761-8000 1 P.O. Box 2946101 I Moncks Corner, SC 29461-6101 Mr. Chris Forrest/Mr. Keith Collinsworth — SCDHEC November 22, 2013 Page 2 PE Environmental Management Attachments cc: Frank S. Holleman, III, Esq Southern Environmental Law Center 601 W. Rosemary Street, Suite 220 Chapel Hill, North Carolina 27516 Grainger Generating Station NPDES Groundwater Monitoring Potentiometric Map October 2013 Groundwater Contour Interval 23 Groundwater Elevation (feet) Well ID TOC GW GW Elevation Depth Elevation (feet) (feet) (feet) MW-1 13.32 10.78 2.54 MW-2 11.06 2.6 8.46 MW-3 6.72 4.98 1.74 MW-4 12.01 10.48 1.53 MW-5 9.09 5.39 3.7 MW-6 9.2 6.59 2.61 MW-12 14.9 11.31 3.59 MW-9 8.24 7.85 0.39 MW-10 8.92 5.65 3.27 MW-11 9.63 4.61 5.02 PZ-1 6.66 5.72 0.94 PZ-2 6.82 5.65 1.17 PZ-3 7.25 5.9 1.35 Water levels collected on October 1, 2013. Staff Gauge ID Date Surface Water Elevation (Feet) G-SW-ICP Oct 2013 6.8 G-SW-Canal Oct 2013 1.3 G-SW-HDD-1 Oct 2013 1.6 G-SW-AP2-1 Oct 2013 0 G-SW-AP2-2 Oct 2013 0 G-SW-HDD-2 Oct 2013 1.46 11/20/13:MDH 4 4 InA14 b.R Al l I 3 SpIIOS J N O N O N O N O O O panlosslp Ieio1 0 E A h N N 4 A O N N V O b f` N N b O A N O v 93ellnS I v r o v rn n e m N a 6 n m N o N apu0143 E a N ri re ei a 1: N 1.i < ri J e o 0 0 o e o O o e QUIZ vv `v v 'v v 'v v' 'v v v' o e N wnlualeS z v v v v v v v v v e J N N N N m A 1y N V UOJI W e e � N m r � � 4 n o O1 a jaddoo v v v v v v J J v v v v v v v v v wnlwpeo panlossla J O O N O aM N N 0 OIUa.4iv 'J V V pN Q V N V N M N N OluaSJy J O ' O N < O M r o O G a d M M M M M M M M M M d C :�O C 0 3 3 3 3 3 3 3 3 3 3 ` O f i f g f s f f :Eg 0u a 0 0 0 0 0 d 0 CD J ED m M a ¢ a ¢ ¢ ¢ ¢ a N Q H n O O O O O O O R;ipigjnl Z U duial M N 10 N N O N N M! N ry O N N ry Q N 0 0 0 N •puoo oodS �J N W � n N W n N Iry0 W Q n n n W W W Hd N e e W e e Ie1;uayud uoi;onpaa E $ 7 W uoi;epixp N Q A N M t0 l•� N O N U014BA013 V• lV eJ N OO q Y! n 43daa LL O N Q N W A N Q M M M M M M M M M M C W T Ol Ol OJ O! N y L d Y C _ 3 _ v 3 3 3 3 3 3 3 3 3 c4 10 o s U) f w s f w f f L U yU' NU' fy9 fN'J C7 C9 (7 (7 C7 (7 a a� a Eo m ¢ a ¢ a ¢ a ¢ ¢ a y a 'Osantee cooper ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC54159 Location: GW Well GGSMW-1 Date: 09/30/2013 Loc. Code GGSMW-1 Time: 11:15 One Riverwood Drive P.O. Box 2946101 Moncks Corner, SC 29461-2901 (843} 761-8000 Sample Collector: MDH Analysis Result QUAL Units Test Date Analyst Arsenic <10 ug/L 10/31/2013 KLMUELLE Arsenic - Dissolved <10 ug/L 10/29/2013 KLMUELLE Cadmium <5 ug/L 10/31/2013 KLMUELLE Chloride 4.54 mg/L 10/0212013 LCWILLIA Spec. Cond. 557 us 09/30/2013 MDHILL Chromium <5 ug/L 10/31/2013 KLMUELLE Copper <10 ug/L 10/31/2013 KLMUELLE Depth 10.78 Feet 09/30/2013 MDHILL Elevation 2.54 Feet 10/04/2013 MDHILL Iron 6103.6 ug/L 10/31/2013 KLMUELLE Oxidation Reduction Potential -57 my 09/30/2013 MDHILL pH 6.49 SU 09/30/2013 MDHILL Selenium <10 ug/L 11/01/2013 KLMUELLE Sulfate 214 mg/L 10/02/2013 LCW ILLIA Total Dissolved Solids 397.5 mg/L 10/11/2013 AJBROWN Temp 23.35 C 09/30/2013 MDHILL Turbidity 11.2 NTU 09/30/2013 MDHILL Zinc <10 ug/L 10/31/2013 KLMUELLE Method EPA 200.7 EPA 200.7 EPA 200.7 EPA 300.0 EPA 200.7 EPA 200.7 EPA 200.7 SM2580 EPA 200.7 EPA 300.0 SM 2540C EPA 200.7 Independent Laboratory Results: "GEL" -GEL Laboratories LLC -Lab ID # 10120; 'Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001 Qualifiers: U-Value below MDL; is Estimated; M-Matrix Interference Analysis Validated: ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC54160 Location: GW Well GGSMW-2 Date: 09/30/2013 Loc. Code GGSMW-2 Time: 12:05 One Rivemood Drive P.O. Box 2946101 Moncks Corner, SC 29461-2901 (843) 761-8000 Sample Collector: MDH Analysis Result QUAL Units Test Date Analyst Arsenic <10 ug/L 10/31/2013 KLMUELLE Arsenic - Dissolved <10 ug/L 10/29/2013 KLMUELLE Cadmium <5 ug/L 10/31/2013 KLMUELLE Chloride 20.3 mg/L 10/02/2013 LCWILLIA Spec. Cond. 803 us 09/30/2013 MDHILL Chromium <5 ug/L 10/31/2013 KLMUELLE Copper <10 ug/L 10/31/2013 KLMUELLE Depth 2.6 Feet 09/30/2013 MDHILL Elevation 8.46 Feet 10/04/2013 MDHILL Iron 6353.1 ug/L 10/31/2013 KLMUELLE Oxidation Reduction Potential -87 my 09/30/2013 MDHILL pH 6.7 SU 09/30/2013 MDHILL Selenium <10 ug/L 11/01/2013 KLMUELLE Sulfate 10.4 mg/L 10/02/2013 LCWILLIA Total Dissolved Solids 505.0 mg/L 10/11/2013 AJBROWN Temp 26.63 C 09/30/2013 MDHILL Turbidity 7.5 NTU 09/30/2013 MDHILL Zinc <10 ug/L 10/31/2013 KLMUELLE Method EPA 200.7 EPA 200.7 EPA 200.7 EPA 300.0 EPA 200.7 EPA 200.7 EPA 200.7 SM2580 EPA 200.7 EPA 300.0 SM 2540C EPA 200.7 Independent Laboratory Results: "GEL" -GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc. -Lab ID# 98001 Qualifiers: U-Value below MDL; H-Holdin 'me Exceded)J-Value is Estimated; M-Matrix Interference Z" e_� Analysis Validated: One Rivemood Drive santee Moncksx orner, 1 cooper Moncks Corner, SC 29461-2901 (843)761-8000 ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC54161 Location: GW Well GGSMW-3 Date: 10/01/2013 Sample Collector: MDH Loc. Code GGSMW-3 Time: 13:40 Analysis Result QUAL Units Test Date Analyst Arsenic 941.9 ug/L 10/31/2013 KLMUELLE Arsenic - Dissolved 486.5 ug/L 10/29/2013 KLMUELLE Cadmium <5 ug/L 10/31/2013 KLMUELLE Chloride 13.9 mg/L 10/02/2013 LCWILLIA Spec. Cond. 1210 us 10/01/2013 MDHILL Chromium <5 ug/L 10/31/2013 KLMUELLE Copper <10 ug/L 10/31/2013 KLMUELLE Depth 4.98 Feet 10/01/2013 MDHILL Elevation 1.74 Feet 10/04/2013 MDHILL Iron 25861.2 ug/L 10/31/2013 KLMUELLE Oxidation Reduction Potential -98 my 10/01/2013 MDHILL pH 6.53 SU 10101/2013 MDHILL Selenium <10 ug/L 11/01/2013 KLMUELLE Sulfate <2.0 mg/L 10/02/2013 LCWILLIA Total Dissolved Solids 747.5 mg/L 10/11/2013 AJBROWN Temp 21.65 C 10/01/2013 MDHILL Turbidity 0 NTU 10/01/2013 MDHILL Zinc <10 ug/L 10/31/2013 KLMUELLE Method EPA 200.7 EPA 200.7 EPA 200.7 EPA 300.0 EPA 200.7 EPA 200.7 EPA 200.7 SM2580 EPA 200.7 EPA 300.0 SM 2540C EPA 200.7 Independent Laboratory Results: "GEL" - GEL Laboratories LLC - Lab ID # 10120; 'Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001 Qualifiers: U-Value below MDL; is Estimated; M-Matrix Interference Analysis Validated: V. race cooper ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC54162 Location: GW Well GGSMW-4 Date: 10/01/2013 Loc. Code GGSMW-4 Time: 11:45 One Rivemood Drive P.O. Box 2946101 Moncks Corner, SC 29461-2901 (84 3) 761-8000 Sample Collector: MDH Analysis Result QUAIL Units Test Date Analyst Arsenic <10 ug/L 10/31/2013 KLMUELLE Arsenic - Dissolved <10 ug/L 10/29/2013 KLMUELLE Cadmium <5 ug/L 10/31/2013 KLMUELLE Chloride 16.5 mg/L 10/02/2013 LCWILLIA Spec. Cond. 365 us 10/01/2013 MDHILL Chromium <5 ug/L 10/31/2013 KLMUELLE Copper <10 ug/L 10/31/2013 KLMUELLE Depth 10.48 Feet 10/01/2013 MDHILL Elevation 1.53 Feet 10/04/2013 MDHILL Iron 39443.2 ug/L 10/31/2013 KLMUELLE Oxidation Reduction Potential -5 my 10/01/2013 MDHILL pH 5.59 SU 10/01/2013 MDHILL Selenium <10 ug/L 11/01/2013 KLMUELLE Sulfate <2.0 mg/L 10/02/2013 LCWILLIA Total Dissolved Solids 280.0 mg/L 10/11/2013 AJBROWN Temp 20.87 C 10/01/2013 MDHILL Turbidity 0 NTU 10/01/2013 MDHILL Zinc <10 ug/L 10/31/2013 KLMUELLE Method EPA 200.7 EPA 200.7 EPA 200.7 EPA 300.0 EPA 200.7 EPA 200.7 EPA 200.7 SM2580 EPA 200.7 EPA 300.0 SM 2540C EPA 200.7 Independent Laboratory Results: "GEL" -GEL Laboratories LLC -Lab ID # 10120; 'Test America" - TestAmerica Laboratories, Inc. -Lab ID# 98001 Qualifiers: U-Value below MDL; is Estimated; M•Matrix Interference Analysis Validated: 14pantee cooper ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC54163 Location: GW Well GGSMW-5 Date: 09/30/2013 Loc. Code GGSMW-5 Time: 14:40 One Rivenmood Drive P.O. Box 2946101 Moncks Coiner, SC 29461-2901 (843) 761-8000 Sample Collector: MDH Analysis Result QUAL Units Test Date Analyst Arsenic 14.5 ug/L 10/31/2013 KLMUELLE Arsenic - Dissolved 18.2 ug/L 10/29/2013 KLMUELLE Cadmium <5 ug/L 10/31/2013 KLMUELLE Chloride 15.4 mg/L 10102/2013 LCWILLIA Spec. Cond. 539 us 09/30/2013 MDHILL Chromium <5 ug/L 10/31/2013 KLMUELLE Copper <10 ug/L 10/31/2013 KLMUELLE Depth 5.39 Feet 09/30/2013 MDHILL Elevation 3.7 Feet 10/04/2013 MDHILL Iron 3665.6 ug/L 10/31/2013 KLMUELLE Oxidation Reduction Potential -88 my 09/30/2013 MDHILL pH 5.92 SU 09/30/2013 MDHILL Selenium <10 ug/L 11/01/2013 KLMUELLE Sulfate 216 mg/L 10/08/2013 LCWILLIA Total Dissolved Solids 412.5 mg/L 10/11/2013 AJBROW N Temp 21.4 C 09/30/2013 MDHILL Turbidity 0 NTU 09/30/2013 MDHILL Zinc <10 ug/L 10/31/2013 KLMUELLE Method EPA 200.7 EPA 200.7 EPA 200.7 EPA 300.0 EPA 200.7 EPA 200.7 EPA 200.7 SM2580 EPA 200.7 EPA 300.0 SM 2540C EPA 200.7 Independent Laboratory Results: 'GEL"- GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001 Qualifiers: LI-Value below MDL; H-HoldiggJimfSxceok; J-Value is Estimated; M-Matrix Interference Analysis Validated: ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC54164 Location: GW Well GGSMW-6 Date: 09/30/2013 Loc. Code GGSMW-6 Time: 12:50 One Rivermood Drive P.O Box 2946101 Moncks Corner, SC 29461-2901 (843) 761-8000 Sample Collector: MDH Analysis Result QUAL Units Test Date Analyst Arsenic <10 ug/L 10/31/2013 KLMUELLE Arsenic - Dissolved <10 ug/L 10/29/2013 KLMUELLE Cadmium <5 ug/L 10/31/2013 KLMUELLE Chloride 49.3 mg/L 10/0212013 LCWILLIA Spec. Cond. 870 us 09/30/2013 MDHILL Chromium <5 ug/L 10/31/2013 KLMUELLE Copper <10 ug/L 10/31/2013 KLMUELLE Depth 6.59 Feet 09/30/2013 MDHILL Elevation 2.61 Feet 10/04/2013 MDHILL Iron 7412.8 ug/L 10/31/2013 KLMUELLE Oxidation Reduction Potential -62 my 09/30/2013 MDHILL pH 6.35 SU 09/30/2013 MDHILL Selenium <10 ug/L 11/01/2013 KLMUELLE Sulfate 0.93 mg/L 10/02/2013 LCWILLIA Total Dissolved Solids 680.0 mg/L 10/11/2013 AJBROWN Temp 23.17 C 09/30/2013 MDHILL Turbidity 0 NTU 09/30/2013 MDHILL Zinc <10 ug/L 10/31/2013 KLMUELLE Method EPA 200.7 EPA 200.7 EPA 200.7 EPA 300.0 EPA 200.7 EPA 200.7 EPA 200.7 SM2580 EPA 200.7 EPA 300.0 SM 2540C EPA 200.7 Independent Laboratory Results: "GEL"- GEL Laboratories LLC - Lab ID # 10120; 'Test America" - TestAmerica Laboratories, Inc. -Lab ID# 98001 Qualifiers: U-Value below MDL; H-Holding Analysis Validated: is Estimated; M•Matrix Interference 4qpantee cooper ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample# AC54165 Location: GW Well GGSMW-9 Date: 10/01/2013 Loc. Code GGSMW-9 Time: 12:30 One Rivemood Drive P.O. Box 2946101 Moncks Corner, SC 29461-2901 f643) 761-8000 Sample Collector: MDH Analysis Result QUAL Units Test Date Analyst Arsenic 3371.6 ug/L 10/31/2013 KLMUELLE Arsenic -Dissolved 1559.3 ug/L 10/31/2013 KLMUELLE Cadmium <5 ug/L 10/31/2013 KLMUELLE Chloride 57.6 mg/L 10/02/2013 LCWILLIA Spec. Cond. 783 us 10/01/2013 MDHILL Chromium <5 ug/L 10/31/2013 KLMUELLE Copper <10 ug/L 10131/2013 KLMUELLE Depth 7.85 Feet 10/01/2013 MDHILL Elevation 0.39 Feet 10/04/2013 MDHILL Iron 22352.7 ug/L 10/31/2013 KLMUELLE Oxidation Reduction Potential -44 my 10/01/2013 MDHILL pH 6.18 SU 10/01/2013 MDHILL Selenium <10 ug/L 11/01/2013 KLMUELLE Sulfate 146 mg/L 10/02/2013 LCWILLIA Total Dissolved Solids 517.5 mg/L 10/11/2013 AJBROWN Temp 21.19 C 10/01/2013 MDHILL Turbidity 114 NTU 10/01/2013 MDHILL Zinc <10 ug/L 10/31/2013 KLMUELLE Method EPA 200.7 EPA 200.7 EPA 200.7 EPA 300.0 EPA 200.7 EPA 200.7 EPA 200.7 S M2580 EPA 200.7 EPA 300.0 SM 2540C EPA 200.7 Independent Laboratory Results: "GEL" -GEL Laboratories LLC - Lab ID # 10120; 'Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001 Qualifiers: U-Value below MDL; H-HoldingJime Excede�VJ-Value is Estimated; M•Matrix Interference Analysis Validated: One Rivevood Drive sa tee cwoeC P.O. ks Corner, S Moncks Corner, SC 29461-2901 (843) 761-BOOD ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC54166 Location: GW Well GGSMW-10 Date: 10/01/2013 Sample Collector: MDH Loc. Code GGSMW-10 Time: 10:55 Analysis Result QUAL Units Test Date Analyst Arsenic 1097.9 ug/L 10/31/2013 KLMUELLE Arsenic - Dissolved 361.2 ug/L 10/29/2013 KMUELLE Cadmium <5 ug/L 10/31/2013 KLMUELLE Chloride 12.5 mg/L 10/02/2013 LCWILLIA Spec. Cond. 1250 us 10/01/2013 MDHILL Chromium <5 ug/L 10/31/2013 KLMUELLE Copper <10 ug/L 10/31/2013 KLMUELLE Depth 5.65 Feet 10/01/2013 MDHILL Elevation 3.27 Feet 10/04/2013 MDHILL Iron 32095.3 ug/L 10/31/2013 KLMUELLE Oxidation Reduction Potential -113 my 10/01/2013 MDHILL pH 6.55 SU 10/01/2013 MDHILL Selenium <10 ug/L 11/01/2013 KLMUELLE Sulfate <2.0 mg/L 10/0212013 LCWILLIA Total Dissolved Solids 675.0 mg/L 10/11/2013 AJBROWN Temp 20.07 C 10/01/2013 MDHILL Turbidity 0 NTU 10/01/2013 MDHILL Zinc <10 ug/L 10/31/2013 KLMUELLE Method EPA 200.7 EPA 200.7 EPA 200.7 EPA 300.0 EPA 200.7 EPA 200.7 EPA 200.7 SM2580 EPA 200.7 EPA 300.0 SM 2540C EPA 200.7 Independent Laboratory Results: "GEL" - GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc. -Lab ID# 98001 Qualifiers: U-Value below MDL; H-Holding TiMa-Excudud-J-Value is Estimated; M•Matrix Interference Analysis Validated: IV santee cooper ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC54167 Location: GW Well GGSMW-11 Date: 09/3012013 Loc. Code GGSMW-11 Time: 15:40 One Rivewood Drive P.O. Box 2946101 Moncks Corner, SC 29461-2901 (843)761-8000 Sample Collector: MDH Analysis Result QUAL Units Test Date Analyst Arsenic 450.0 ug/L 10/31/2013 KLMUELLE Arsenic - Dissolved 121.6 ug/L 10/29/2013 KLMUELLE Cadmium <5 ug/L 10/31/2013 KLMUELLE Chloride 14.0 mg/L 10/02/2013 LCWILLIA Spec. Cond. 1150 us 09/30/2013 MDHILL Chromium <5 ug/L 10/31/2013 KLMUELLE Copper <10 ug/L 10/31/2013 KLMUELLE Depth 4.61 Feet 09/30/2013 MDHILL Elevation 5.02 Feet 10/04/2013 MDHILL Iron 45491.5 ug/L 10/31/2013 KLMUELLE Oxidation Reduction Potential -97 my 09/30/2013 MDHILL pH 6.43 SU 09/30/2013 MDHILL Selenium <10 ug/L 11/01/2013 KLMUELLE Sulfate <2.0 mg/L 10/02/2013 LCWILLIA Total Dissolved Solids 730.0 mg/L 10/11/2013 AJBROWN Temp 22.23 C 09/30/2013 MDHILL Turbidity 0 NTU 09/30/2013 MDHILL Zinc <10 ug/L 10/31/2013 KLMUELLE Method EPA 200.7 EPA 200.7 EPA 200.7 EPA 300.0 EPA 200.7 EPA 200.7 EPA 200.7 SM2580 EPA 200.7 EPA 300.0 SM 2540C EPA 200.7 Independent Laboratory Results: "GEL"- GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc. -Lab ID# 98001 Qualifiers: U-Value below MDL; Analysis Validated: is Estimated; M-Matrix Interference `Ip%ntee cooper ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC54168 Location: GW Well GGSMW-12 Date: 09/30/2013 Loc. Code GGSMW-12 Time: 13:30 One Rivemood Drive P.O. Box 2946101 Moncks Corner, SC 29461-2901 (843)761-8000 Sample Collector: MDH Analysis Result QUAIL Units Test Date Analyst Arsenic 19.4 ug/L 10/31/2013 KLMUELLE Arsenic - Dissolved 21.9 ug/L 10/29/2013 KLMUELLE Cadmium <5 ug/L 10/31/2013 KLMUELLE Chloride 13.5 mg/L 10/02/2013 LCW ILLIA Spec. Cond. 624 us 09/30/2013 MDHILL Chromium <5 ug/L 10/31/2013 KLMUELLE Copper <10 ug/L 10/31/2013 KLMUELLE Depth 11.31 Feet 09/30/2013 MDHILL Elevation 3.59 Feet 10/04/2013 MDHILL Iron 12436.4 ug/L 10131/2013 KLMUELLE Oxidation Reduction Potential -57 my 09/30/2013 MDHILL pH 5.74 SU 09/30/2013 MDHILL Selenium 10.2 ug/L 11/01/2013 KLMUELLE Sulfate 267 mg/L 10/08/2013 LCWILLIA Total Dissolved Solids 485.0 mg/L 10/11/2013 AJBROWN Temp 24.63 C 09/30/2013 MDHILL Turbidity 0 NTU 09/30/2013 MDHILL Zinc <10 ug/L 10/31/2013 KLMUELLE Method EPA 200.7 EPA 200.7 EPA 200.7 EPA 300.0 EPA 200.7 EPA 200.7 EPA 200.7 SM2580 EPA 200.7 EPA 300.0 SM 2540C EPA 200.7 Independent Laboratory Results: 'GEL"- GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc. -Lab ID# 98001 Qualifiers: U-Value below MDL; XH-lHoIIdnime Exced &,; J-Value is Estimated; M-Matrix Interference l Analysis Validated: Bria ynch - Results Supervisor, Central Lab A III P9A7m k _ oivasjv e V ) § v § § § p _,_¥ # V § i 9 § § § ) uo!lonp9b . ! r \ / ! \ \ d ( \ JE)qAA ° § a & jaleAA § § § § \ \ ) S o m 2 S S «m 3`: S !ƒ! 2 >ƒ! § / § ) q9� q ! - - , )- \ § [ / § / / ) § * pa 7puo oa j dwai. i* ° N E ( \ \ \ \ ~ 2 E 2 ) ) § J 0 0. 0 2 § { ! / k | - | \ \ \ _ ) [ § r § § § | ) § B k¥ E ) % \ \ \ \ \ } \ / 0 - r c "santce cooper ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC53946 Location: Lower Waccamaw River Date: 09/26/2013 Loc. Code WAC LOW Time: 10:45 Analysis Result QUAL Units Test Date Air Temp 22 C 10/02/2013 Arsenic - MS <2,5 J ug/L 10/08/2013 Arsenic- Dissolved <2.5 J ug/L 10/08/2013 Collection Depth 2.2 m 10/02/2013 Field Conductivity 112 us 10/02/2013 Field pH 6.28 SU 10/02/2013 Flow 1330 cfs 10/03/2013 Gauge heigh 7.46 ft 10/03/2013 Oxidation Reduction Potential 138 my 10/02/2013 Weather 2 other 10/02/2013 Water Temp 23.23 C 10/02/2013 One Rivenvood Drive P.O. Box 2946101 Moncks Corner, SC 29461-2901 (843)761-8000 Sample Collector: CM/EG Analyst Method EHGUERRY TESTAMERICA EPA 200.8 TESTAMERICA EPA 200.8 EHGUERRY EHGUERRY EHGUERRY CWMOORER CWMOORER EHGUERRY SM2580 EHGUERRY EHGUERRY Independent Laboratory Results: "GEL" - GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001 Qualifiers: U-Value below MDL; H44olding Time xceded; J-Value is Estimated; M-Matrix Interference Analysis Validated: One Rivemood Drive JGilee cooper Moncksxorner, 1 Gi 1, l� Moncks Corner, SC 29461-2901 (843) 761-8000 ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC53947 Location: GGS Cooling Pond Date: 09/26/2013 Sample Collector:'CM/EG Loc. Code GGS CP Time: 11:09 Analysis Result QUAL Units Test Date Analyst Method Air Temp 22 C 10/02/2013 EHGUERRY Arsenic - MS <2.5 J ug/L 10/08/2013 TESTAMERICA EPA200.8 Arsenic - Dissolved <2.5 J ug/L 10/08/2013 TESTAMERICA EPA 200.8 Collection Depth 0.3 m 10/02/2013 EHGUERRY Field Conductivity 87 us 10/0212013 EHGUERRY Field pH 6.78 SU 10/02/2013 EHGUERRY Flow Not Required cfs 10/07/2013 JMDAVIS Gauge heigh Not Required ft 10/07/2013 JMDAVIS Oxidation Reduction Potential 164.6 my 10/02/2013 EHGUERRY SM2580 Weather 2 other 10/0212013 EHGUERRY Water Temp 22.74 C 10/02/2013 EHGUERRY Independent Laboratory Results: "GEL" - GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001 Qualifiers: U-Value below MDL; H-Holding is Estimated; M•Matrix Interference Analysis Validated: IV One Riverwood Drive P.O. Box 2946101 Santee cooper (843) 7 Corner, SC 29461-2901 (643) 61-8000 ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC53948 Location: Ditch beside HWY 501 off Date: 09/26/2013 Sample Collector: CM/EG Loc. Code 501_DITCH Waccamaw River Time: 11:27 Analysis Result QUAL Units Test Date Analyst Method Air Temp 23 C 10/02/2013 EHGUERRY Arsenic - MS <2.5 J ug/L 10/08/2013 TESTAMERICA EPA 200.8 Arsenic - Dissolved <2.5 J ug/L 10/0812013 TESTAMERICA EPA 200.8 Collection Depth 0.3 m 10/02/2013 EHGUERRY Field Conductivity 113 us 10/02/2013 EHGUERRY Field pH 6.35 SU 10/02/2013 EHGUERRY Flow Not Required cfs 10/07/2013 JMDAVIS Gauge heigh 2.4 ft 10/02/2013 EHGUERRY Oxidation Reduction Potential 130.6 my 10/02/2013 EHGUERRY SM2580 Weather 2 other 10/02/2013 EHGUERRY Water Temp 22.54 C 10/02/2013 EHGUERRY Independent Laboratory Results: "GEL" - GEL Laboratories LLC - Lab ID # 10120; 'Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001 Qualifiers: U-Value below MDL; H-HDldin xce e ; aalue is Estimated; M-Matrix Interference Analysis Validated: �r One Riox 294 1 Drive c n+ P.O. Box 2946101 Ja I Lee cwper Moncks Corner, SC 29461-2901 (843) 761-8000 ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC53949 Location: Waccamaw River Oxbow Date: 09/26/2013 Sample Collector: CM/EG Loc. Code WAC_OX Time: 11:34 Analysis Result QUAL Units Test Date Analyst Method Air Temp 23 C 10/0212013 EHGUERRY Arsenic - MS <2.5 J ug/L 10/08/2013 TESTAMERICA EPA 200.8 Arsenic -Dissolved <2.5 U ug/L 10/08/2013 TESTAMERICA EPA200.8 Collection Depth 0.3 m 10/02/2013 EHGUERRY Field Conductivity 113 us 10/02/2013 EHGUERRY Field pH 6.32 SU 10/02/2013 EHGUERRY Flow Not Required cfs 10107/2013 JMDAVIS Gauge heigh Not Required ft 10/07/2013 JMDAVIS Oxidation Reduction Potential 136.0 my 10/02/2013 EHGUERRY SM2580 Weather 2 other 10/02/2013 EHGUERRY Water Temp 23.41 C 10/02/2013 EHGUERRY Independent Laboratory Results: "GEL" - GEL Laboratories LLC - Lab ID # 10120; 'Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001 Qualifiers: U-Value below MDL; H-Hoi�grrime Exceded; J-V eis Estimated; M-Matrix Interference Analysis Validated: One Rivenvood Drive �Sj pp��,,ppyy !� P.O. Box 2946101 V*santes Cooper Moncks Corner, SC 29461-2901 (843)761-8000 ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC53950 Location: Waccamaw River Monitoring Date: 09/26/2013 Sample Collector: CM/EG Loc. Code WRMW_5 Well Time: 11:44 Analysis Result QUAL Units Test Date Analyst Method Air Temp 23 C 10/02/2013 EHGUERRY Arsenic- MS <2.5 J ug/L 10/08/2013 TESTAMERICA EPA 200.8 Arsenic - Dissolved <2.5 J ug/L 10/08/2013 TESTAMERICA EPA 200.8 Collection Depth 0.3 m 10/02/2013 EHGUERRY Field Conductivity 113 us 10/02/2013 EHGUERRY Field pH 6.36 Su 10/02/2013 EHGUERRY Flow 1410 cis 10/03/2013 CWMOORER Gauge heigh 7.22 ft 10/03/2013 CWMOORER Oxidation Reduction Potential 139.3 my 10/02/2013 EHGUERRY SM2580 Weather 2 other 10/02/2013 EHGUERRY Water Temp 23.39 C 10/02/2013 EHGUERRY Independent Laboratory Results: "GEL" - GEL Laboratories LLC - Lab ID # 10120; 'Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001 Qualifiers: U-Value below MDL; H-Holding T' xceded; J- alue is Estimated; M•Matrix Interference Analysis Validated:�� \� One Riverwood Drive �� yy �}pyy� ry/� P.O. Box 2946101 sa tee cooper Moncks Corner, SC 29461-2901 (843)761-8000 ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC53951 Location: Waccamaw River Monitoring Date: 09/26/2013 Sample Collector: CM/EG Loc. Code WRMW Well 4R Time: 11:50 Analysis Result QUAL Units Test Date Analyst Method Air Temp 23 C 10/02/2013 EHGUERRY Arsenic - MS <2.5 J ug/L 10/08/2013 TESTAMERICA EPA 200.8 Arsenic - Dissolved <2.5 U ug/L 10/08/2013 TESTAMERICA EPA 200.8 Collection Depth 0.3 m 10/02/2013 EHGUERRY Field Conductivity 113 us 10102/2013 EHGUERRY Field pH 6.28 SU 10/02/2013 EHGUERRY Flow 1410 ofs 10/03/2013 CWMOORER Gauge heigh 7.22 ft 10/03/2013 CWMOORER Oxidation Reduction Potential 140.1 my 10/02/2013 EHGUERRY SM2580 Weather 2 other 10/02/2013 EHGUERRY Water Temp 23.36 C 10/02/2013 EHGUERRY Independent Laboratory Results: "GEL"- GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001 Qualifiers: U-Value below MDL; H-Holding Ti�xceded; J- /e is Estimated; M•Matrix Interference Analysis Validated: santee cooper Sample # AC53952 Location Loc. Code WRMW_3R ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Waccamaw River Monitoring Date: 09/26/2013 Well Time: 11:53 One Rivemood Drive P.O. Box 2946101 Moncks Corner, SC 29461-2901 (843)761-8000 Sample Collector: CM/EG Analysis Result QUAIL Units Test Date Analyst Method Air Temp 23 C 10102/2013 EHGUERRY Arsenic - MS <2.5 J ug/L 10/08/2013 TESTAMERICA EPA200.8 Arsenic - Dissolved <2.5 J ug/L 10/08/2013 TESTAMERICA EPA 200.8 Collection Depth 0.3 m 10/02/2013 EHGUERRY Field Conductivity 114 us 10/02/2013 EHGUERRY Field pH 6.32 SU 10/02/2013 EHGUERRY Flow 1540 cfs 10/03/2013 CWMOORER Gauge heigh 7.15 ft 10/03/2013 CWMOORER Oxidation Reduction Potential 126.1 my 10/02/2013 EHGUERRY SM2580 Weather 2 other 10/02/2013 EHGUERRY Water Temp 23.51 C 10/02/2013 EHGUERRY Independent Laboratory Results: "GEL" - GEL Laboratories LLC - Lab ID # 10120; 'Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001 Qualifiers: U-Value below MDL; H-Holding Time E ed; J-Value is stimated; M-Matrix Interference Analysis Validated: One Riverwood Drive s,antLG Cooper Moncksx orner, 1 i-1 G Lhl 1 Moncks Corner, SG 29461-2901 (843)761-8000 ANALYTICAL & BIOLOGICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AC53953 Location: Upper Waccamaw River Date: 09/26/2013 Sample Collector: CM/EG Loc. Code WAC UP Time: 12:14 Analysis Result QUAL Units Test Date Analyst Method Air Temp 24 C 10/02/2013 EHGUERRY Arsenic - MS <2,5 i ug/L 10/08/2013 TESTAMERICA EPA200.8 Arsenic - Dissolved <2,5 U ug/L 10/08/2013 TESTAMERICA EPA 200.8 Collection Depth 1.3 m 10/02/2013 EHGUERRY Field Conductivity 116 us 10/02/2013 EHGUERRY Field pH 6.26 SU 10/02/2013 EHGUERRY Flow 1580 cfs 10/03/2013 CWMOORER Gauge heigh 7.09 It 10/03/2013 CWMOORER Oxidation Reduction Potential 126.4 my 10/02/2013 EHGUERRY SM2580 Weather 2 other 10/02/2013 EHGUERRY Water Temp 23.53 C 10102/2013 EHGUERRY Independent Laboratory Results: "GEL"- GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc.- Lab ID# 98001 Qualifiers: U-Value below MDL; H-Holding Time Exgetl�--Value i stimated; M•Matrix Interference Analysis Validated: Attachment 9 GGS NPDES Supplemental Sampling 3/1/16 -qCantee Cooper' CERTIFIED MAIL March 1, 2016 SCDHEC Bureau of Water/Water Pollution Control Division Data and Records Management Section 2600 Bull Street Columbia, South Carolina 29201 To whom it may concern: Re: Santee Cooper Grainger Generating Station, Horry County NPDES Permit# SC0001104 NPDES Groundwater Semi-annual Report for 2015-Addendum When the site was sampled November 2-5, 2015, two of the wells, GGSMW-10 and GGSMW-3, and the three piezometers at the site, PZ-1 through PZ-3, were inaccessible due to remaining floodwaters from the 1000-year flood in early October 2015. The two wells, both located on Ash Pond 1, were sampled on December 8, 2015, but, the three piezometers, located near Ash Pond 2, were still under water. Attached are the laboratory results and an updated arsenic concentration map. The next groundwater sampling event is scheduled for April 4, 2016. If you have any questions or comments concerning this project, please contact Melanie D. Goings, P.G., at (803) 761-8000 extension 4490. Sincerely, n W. Jack n, PE Manager CCP & Waste Management Ok SWJ:DBB:MDG: cgb One Riverwood Drive I Moncks Corner, SC 29461-2901 1 (843) 761-8000 1 P.O. Box 2946101 I Moncks Corner, SC 29461-6101 Attachments cc w/attachments: Mr. Chris Forrest Groundwater Protection Section SCDHEC Bureau of Water 2600 Bull Street Columbia, South Carolina 29201 Mr. Gary Stewart State Voluntary Cleanup Section SCDHEC Bureau of Land and Waste Management 2600 Bull Street Columbia, SC 29201 Feet M, MW-2 • �`" • 44 MW-10 ,. &ffi pad ® MW-3 MW-1 MAT ffNrho- MW-4 �•C�3 • G-SW-_Canal G-SW-ICP• • MW-6 G-SW-HDD-1 • • PZ-1 PZ-• PZ-2 •G-SW-AP2-1 MW-g G-SW-AP2-2 • C�in7F�YJL�D3`• * G-SW-HDD-2 • •sr�a rrFr C^� Industrial oolin.a Iand MOM .• IM r3 J a;e;lns m e J apyol43 m e O spllos J popuadsnSlelol e spllos J panlossld 1e40l m e J QUIZ rn 0 J wnllle4l m ' J � wnlualaS = J c PUG-1 J a uoil J O jaddoo _ J wnlwayo " J wniwpeo O V wnueg ° paniossld J - 31Uasiv O1 J ? 0! oluasw m = d N s N � a 41 E 0 N W N A N c y o m m o y 3�3 EN N L � � a m v a J E M M N lepuuiud uo!lonpaa E uogep!xo •puo3 •oadg ra fG!P!Qinl Z v y Hd U dwal uoi;en013 a " u 41da0 d LL Y_i N m a ro !7` _N cQ..d+ E � N N N L d W G O � a a N d a v <L E o 0 y ¢ a "santee cooper SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AD37435 Location: GW Well GGSMW-3 Date: 12/08/2015 Loc. Code GGSMW-3 Time: 12:15 One Rivenvood Dnve P.O. Box 2946101 Monks Comer, SC 29461-2901 (8431761-8000 Sample Collector: MDG Analysis Result DUAL Units Test Date Analyst Arsenic 198.4 ug/L 12/17/2015 KLMORAN Arsenic -Dissolved 112.821 ug/L 12/17/2015 KLMORAN Barium 85.2 ug/L 12/17/2015 KLMORAN Cadmium <5 ug/L 12/17/2015 KLMORAN Chloride 6.61 mg/L 12/09/2015 LCWILLIA Spec. Cord. 191 us 12/08/2015 MDGOINGS Chromium <5 ug/L 12/17/2015 KLMORAN Copper <10 ug/L 12/17/2015 KLMORAN Depth 3.03 Feet 12/08/2015 MDGOINGS Elevation 3.69 Feet 12/08/2015 MDGOINGS Iron 3682.4 ug/L 12/17/2015 KLMORAN Oxidation Reduction Potential 172 my 12/08/2015 MDGOINGS Lead <10 ug/L 12/17/2015 KLMORAN pH 6.5 SU 12108/2015 MDGOINGS Selenium <10 ug/L 12/17/2015 KLMORAN Sulfate 8.85 mg/L 12/09/2015 LCWILLIA Total Dissolved Solids 240.0 mg/L 12/10/2015 AJBROWN Temp 17.85 C 12/08/2015 MDGOINGS Thallium <1.0 U ug/L 12/18/2015 TESTAMERICA Total Suspended Solids 8.50 mg/L 12/10/2015 AJBROWN Turbidity 9.1 NTU 12/08/2015 MDGOINGS Zinc 61.8 ug/L 12/17/2015 KLMORAN Independent Laboratory Results: "GEL' - GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001; "DavisBrown"- Davis & Brown Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc.- Lab ID# 32010 Analysis Validated: r Debra K. Guerry - Supervisor, Analytical Services Method EPA 200.7 EPA200.7 EPA 200.7 EPA200.7 EPA 300.0 EPA200.7 EPA200.7 EPA 200.7 SM2580 EPA 200.7 EPA 200.7 EPA 300.0 SM 2540C EPA 200.7 / 6010 SM 2540D EPA 2003 santee cooper SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AD37436 Location: GW Well GGSMW-10 Date: 12/08/2015 Loc. Code GGSMW-10 Time: 13:43 One Rivemood Drive P.O. Box 2946101 Moncks Corner, SC 29461-2901 (843) 761-8000 Sample Collector: Analysis Result QUAL Units Test Date Analyst Arsenic 558.9 ug/L 12/17/2015 KLMORAN Arsenic - Dissolved 188.010 ug/L 12/17/2015 KLMORAN Barium 401.3 ug/L 12/17/2015 KLMORAN Cadmium <5 ug/L 12/17/2015 KLMORAN Chloride 24.3 mg/L 12/09/2015 LCWILLIA Spec, Cond. 1060 us 12/08/2015 MDGOINGS Chromium <5 ug/L 12/17/2015 KLMORAN Copper <10 ug/L 12/17/2015 KLMORAN Depth 5 Feet 12/08/2015 MDGOINGS Elevation 3.92 Feet 12/08/2015 MDGOINGS Iron 61180.6 ug/L 12/17/2015 KLMORAN Oxidation Reduction Potential -17 my 12/08/2015 MDGOINGS Lead <10 ug/L 12/17/2015 KLMORAN pH 6.09 SU 12/08/2015 MDGOINGS Selenium <10 ug/L 12/1712015 KLMORAN Sulfate 87.1 mg/L 12/09/2015 LCWILLIA Total Dissolved Solids 572.5 mg/L 12/10/2015 AJBROWN Temp 18.1 C 12108/2015 MDGOINGS Thallium <1.0 U ug/L 12/18/2015 TESTAMERICA Total Suspended Solids 18.79 mg/L 12/10/2015 AJBROWN Turbidity 43.4 NTU 12/08/2015 MDGOINGS Zinc 20.2 ug/L 12/17/2015 KLMORAN Independent Laboratory Results: "GEL" -GEL Laboratories LLC -Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc. -Lab ID# 98001; "DavisBrown"- Davis & Brown Lab ID # 21117;'Shealy'- Shealy,* Environmental Services, Inc.- Lab ID# 32010 Analysis Validated: Debra K. Guerry - Supervisor, Analytical Services MDG Method EPA 200.7 EPA 200.7 EPA 200.7 EPA 200.7 EPA 300.0 EPA 200.7 EPA 200.7 EPA 200.7 SM2580 EPA 200.7 EPA 200.7 EPA 300.0 SM 2540C EPA 200.7 / 6010 SM 2540D EPA 200.7 Attachment 10 GGS NPDES Sampling DHEC Transmittal 11/24/15 4q SantCE', C40pelr" CERTIFIED MAIL November 24, 2015 Mr. Chris Forrest Groundwater Protection Section SCDHEC Bureau of Water 2600 Bull Street Columbia, South Carolina 29201 Mr. Gary Stewart State Voluntary Cleanup Section SCDHEC Bureau of Land and Waste Management 2600 Bull Street Columbia, SC 29201 Dear Mr. Forrest: Re; South Carolina Public Service Authority Santee Cooper Grainger Generating Station, Horry County NPDES Permit# SCO001104 NPDES Groundwater Semi-annual Report for 2015 Attached are results from the November 2-5, 2015 groundwater and surface water sampling event. Separate maps showing sampling locations and arsenic concentrations are included. Two of the wells, GGSMW-10 and GGSMW-3, both located on Ash Pond 1, and the three piezometers, located near Ash Pond 2, were inaccessible due to remaining floodwaters from the l 000-year flood in early October 2015. Several photographs are attached. These sites will be monitored as soon as the floodwaters retreat and the wells can be safely accessed. The results will be reported as a separate transmittal. Lab results showed measurable concentrations of arsenic in four of the sixteen locations where water samples were analyzed. One was a groundwater well along the down gradient edge of Ash Pond 1 and three were groundwater wells along the down gradient edge of Ash Pond 2. An arsenic concentration map is provided to show the distribution of data points across the site. Non -detectable results in the river, the intake canal, and most of the groundwater wells prevent the use of isoconcentration lines. Ongoing ash removal activities, which began on March 17, 2014, will cause the groundwater geochemistry to fluctuate. Dne Rir omuod Drivs � Moncks Corner, SC 29461-2'901 1 (84C) 7E1.8000 { RO. Box 294B101 I Moncks Corner, SC 29461-6101 Mr. Chris Forrest— SCDHEC November 24, 2015 Page 2 If you have any questions or comments concerning this project, please contact Melanie D. Goings, P.G., at (803) 761-5000 extension 4490. Sincerely, - i, Susan W. Jackson, PE Manager CCP & Waste Management L SWJ: B MDG gib Attachments cc wlattachments: Frank S. Holleman, III, Esq Southern Environmental Law Center 601 W. Rosemary Street, Suite 220 Chapel Hill, North Carolina 27516 s m V - Aw: 4.1 1 3 _ a MW-1 ,• �".¢'�' ! .. Y a _ $m ski -..! a .. r ad`r1 •� 7r �1 zz 3- "i Grainger Generating Station NPDES Groundwater Monitoring Potentiometric Map November 2015 Groundwater Contour Interval 23 Groundwater Elevation (feet) Well ID TOC GW GW Elevation Depth Elevation (feet) (feet) (feet) MW-1 13.32 9.51 3.81 M W-2 11.06 3.32 7.74 MW-3 6.72 NA MW-4 12.01 12.01 0 M W-5 9.09 4.15 4.94 MW-6 8.19 4.75 3.44 MW-12 14.9 9.49 5.41 MW-9 8.24 2.95 5.29 MW-10 8.92 NA MW-11 9.63 4.36 5.27 PZ-1 6.66 NA PZ-2 6.82 NA PZ-3 7.25 NA Water levels collected on November 2, 2015. However, due to the 1000-year flood, several wells and piezometers were inaccessible (NA). 11/23115:MDG i 11/23/15:MDG 0 0 0 0 'Cf D 0 �YJ sPlloS JEn e a b fl e o papuodsng lejol E ^ r ^' v splloS J b o 0 0 R a o 0 panlosslp lelol E r ti N Q apP0140 IO O A 24ejlnS• J e! V m N J V O O O 4 V oulz 7 INY V V lby V N Q V J9 90 tr e uinillp4l u G v J 9 4 U! 9 N 9 C wnivalag v v v v J O O O 4 4 Q 4 q pea -I Y V v V v v v v uoll = N Q n r N A "ddo3 3 Y v Y V v v Y V J wnlwonlo 7 v Y Y b v b b N J wnlwpeo W v v v v v v I J N m 40 oc P n n O wnues m N tl A Q A A POAIOSJsIV O O 9 Q 4 A �luas�b v v v u a � q q N d � b �IuasJy T V V V Y ry O. CD n ! `n ! oo ! ! v, ! AD Y to T ! uo ! En L C N to 0 oU to 0 y H y a s� J y L rn m co m m m o o 0 m 0 0 L7 W) to LO co M CD to M (o M E O cocam- , c�i c`ro r�i cu mmmni z u dwo puo -3adS Hd ,muqud uoAnpoN & UO!IB p7o uos n : ± T-- 9 -i wi w; 4 k k \ k \ \ to to S § S S $ S E $ \ \ ƒ \ \ \ ] / 7 7 7 to cn / / / into } 2 / / / / iqpP 0 One Box 2 461 01 saood Drive M lee coupe Moncks Camer, SC 29461-2901 (843) 761-8000 SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AD34595 Location: GW Well GGSMW-1 Date: 11/02/2015 Sample Collector: Loc. Cade GGSMW-1 Time: 13:40 Analysis Result QUAL Units Test Date Analyst Method Arsenic t10 ug/L 11/12/2015 KLMORAN EPA200.7 Arsenic - Dissolved <10 ug/L 11/12/2015 KLMORAN EPA 200.7 Barium 73.2 ug/L 11/1212015 KLMORAN EPA200.7 Cadmium <5 ug/L 11112/2015 KLMORAN EPA 2003 Chloride 6.25 mg/L 11/0412015 LCWILLIA EPA 300.0 Spec. Cond. 168 us 11/02/2015 MDGOINGS Chromium <5 ug/L 11/12/2015 KLMORAN EPA200.7 Copper <10 ug/L 1111212015 KLMORAN EPA 200.7 Depth 9.51 Feet 11/02/2015 MDGOINGS Elevation 3.81 Feet 11102/2015 MDGOINGS Iron 148873.0 ug/L 11/16/2015 KLMORAN EPA200.7 Oxidation Reduction Potential 2 my 11/0212015 MDGOINGS SM2580 Lead <10 ug/L 11/12/2015 KLMORAN EPA 200.7 pH 5.93 SU 11/02/2015 MDGOINGS Selenium <10 ug/L 11/12/2015 KLMORAN EPA200.7 Sulfate 843 mg/L 11/04/2015 LCWILLIA EPA300.0 Total Dissolved Solids 1416 mg1L 11/1112015 AJBROWN SM 2540C Temp 22.53 C 11/02/2015 MDGOINGS Thallium <1.0 U ug/L 11/13/2015 TESTAMERICA EPA 200-7 / 6010 Total Suspended Solids 16.35 mg/L 11/11/2015 AJBROVVN SM 2540D Turbidity 0 NTU 11/02/2015 MDGOINGS Zinc 62.4 ug/L 11/12/2015 KLMORAN EPA200.7 Independent Laboratory Results: "GEL" - GEL Laboratories LLC - Lab ID # 10120, "Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001; "DavisBrown"- Davis & Brown Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc.- Lab ID# 32010 Analysis Validated: Debra K. Guerry - Supervisor, Analytical Services One Rx 294 Drive P.Q. Boox 2846101 'Psantee cooper MQMks Comer, 5C 29461-2901 (843) 7e1-BOOD SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AD34596 Location: GW Well GGSMW-2 Loc. Code GGSMW-2 Analysis Arsenic Arsenic - Dissolved Barium Cadmium Chloride Spec. Cond. Chromium Copper Depth Elevation Iron Oxidation Reduction Potential Lead pH Selenium Sulfate Total Dissolved Solids Temp Thallium Total Suspended Solids Turbidity Zinc Date. 11/02/2015 Sample Collector: Time: 14:25 Result QUAL Units Test Date Analyst Method <10 ug/L 11/12/2015 KLMORAN EPA200.7 <10 ug/L 11/12/2015 KLMORAN EPA 200.7 59.9 ug/L 11/12/2015 KLMORAN EPA200.7 <5 ug/L 11/12/2015 KLMORAN EPA200.7 5.15 mg/L 11/04/2015 LCWILLIA EPA 300.0 339 us 11102/2015 MDGOINGS <5 uglL 11/12/2015 KLMORAN EPA200.7 <10 uglL 11/12/2015 KLMORAN EPA200.7 3.32 Feet 11/02/2015 MDGOINGS 7.74 Feet 11/0212015 MDGOINGS 3601.4 ug/L 11/12/2015 KLMORAN EPA200.7 -61 my 11/02/2015 MDGOINGS SM2580 <10 ug/L 11/12/2015 KLMORAN EPA200.7 6.5 SU 11/02/2015 MDGOINGS <10 ug/L 11/12/2015 KLMORAN EPA200.7 3.89 mg/L 11/04/2015 LCWILLIA EPA 300.0 206.0 mg1L 11/11/2015 AJBROWN SM 2540C 22.85 C 11/02/2015 MDGOINGS <1.0 U ug/L 11/13/2015 TESTAMERICA EPA 200.7 / 6010 7.95 mg/L 11/1112015 AJBROWN SM 2540D 16.7 NTU 1V0212015 MDGOINGS <10 ug/L 1111212015 KLMORAN EPA 200.7 Independent Laboratory Results: "GEL" - GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001: "DavisBrown"- Davis & Brown Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc,- Lab ID# 32010 Analysis Validated: }� Debra K. Guerry - Supervisor, Analytical Services Santee cooper Sample # AD34598 'Location: Loc. Code GCSMW-4 Analysis Arsenic Arsenic - Dissolved Barium Cadmium Chloride Spec. Cond. Chromium Copper Depth Elevation Iron Oxidation Reduction Potential Lead pH Selenium Sulfate Total Dissolved Solids Temp Thallium Total Suspended Solids Turbidity Zinc One Riverwood Drive P_0, box 29461 a1 Moncks Comer, SC 29461-2901 (843)761-8000 SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 G1/V Well GCSMW-4 Date: 11/02/2015 Sample Collector: Time: 15:52 Result QUAL Units Test Date Analyst Method <10 ug1L 11112/2015 KLMORAN EPA200.7 <10 uglL 11/12/2015 KLMORAN EPA 200.7 29.8 ug/L 11/12/2015 KLMORAN EPA 200.7 <5 ug/L 11/1212015 KLMORAN EPA 200.7 23.5 mg/L 11/0412015 LCWILLIA EPA300.0 288 u5 11/0212015 MDGOINGS <5 ug/L 1111212015 KLMORAN EPA 200.7 <10 ug/L 11/12/2015 KLMORAN EPA200.7 8.34 Feet 11/02/2015 MDGOINGS 3.67 Feet 11/02/2015 MDGOINGS 21599.1 ug/L 11/12/2015 KLMORAN EPA 200.7 0 my 11/02/2015 MDGOINGS SM2580 <10 ug/L 11/12/2015 KLMORAN EPA 200.7 5,51 Su 11/02/2015 MDGOINGS 10.5 ug/L 11/12/2015 KLMORAN EPA200.7 2.94 mg/L 11/04/2015 LCWILLIA EPA300.0 228.0 mg/L 11f11/2015 AJBROWN SM 2540C 19.7 C 1110212015 MDGOINGS <1.0 U ug/L 11/1312015 TESTAMERICA EPA 200.7 / 6010 1.50 mg/L 11/1112015 AJBROWN SM 2540D 0 NTU 11102/2015 MDGOINGS <10 ug/L 11 /1212015 KLMORAN EPA 200.7 Irdepende,nt Laboratory Results; "GEL" - GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001; "DavisBrown"- Davis & Brown Lab ID # 21117; 'Shealy"- Shealy Environmental Services, Inc.- Lab ID# 32010 Analysis Validated: Debra K. Guerry - Supervisor, Analytical Services Santee doper SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 One Rlvern+ood Drive P.0 Box 2946101 Moncks Comer, SC 29461-2901 (843)761-BOOn Sample # AD34599 Location: GW Well GGSMW-5 Date: 11/03/2015 Sample Collector: Loc. Code GGSMW-5 Time: 12:09 Analysis Arsenic Arsenic - Dissolved Barium Cadmium Chloride Spec. Cond. Chromium Copper Depth Elevation Iron Oxidation Reduction Potential Lead pH Selenium Sulfate Totat Dissolved Solids Temp Thallium Total Suspended Solids Turbidity Zinc Result QUAL Units Test Date Analyst Method 11.9 ug/L 11/12/2015 KLMORAN EPA 200.7 14.4 ug/L 11/12/2015 KLMORAN EPA 200.7 49.8 ug/L 11/12/2015 KLMORAN EPA 200.7 C5 ug/L 11/12/2015 KLMORAN EPA 200.7 5.48 mg1L 11/06/2015 LCWILLIA EPA300.0 354 us 11103/2015 MDGOINGS <5 ug/L 1111212015 KLMORAN EPA 200.7 <10 ug/L 11/12/2015 KLMORAN EPA 200.7 4.15 Feet 11/0312015 MDGOINGS 4.94 Feet 11/03/2015 MDGOINGS 4213.1 ug/L 11/12/2015 KLMORAN EPA 200.7 -112 my 11/03/2015 MDGOINGS SM2580 <10 ug1L 11/12/2015 KLMORAN EPA 200.7 5.66 SU 11/03/2015 MDGOINGS <10 ug/L 11/1212015 KLMORAN EPA 200.7 111 MOIL 11/06/2015 LCWILLIA EPA300.0 263.0 MOIL 11/11/2015 AJBROWN SM 2540C 19.863 C 11/03/2015 MDGOINGS <1.0 U ug/L 11/13/2015 TESTAMERICA EPA 200.7 16010 <1.0 mg/L 11/11/2015 AJBROWN SM 2540D 0 NTU 11/03/2015 MDGOINGS 29.0 ugIL 11/12/2015 KLMORAN EPA 200.7 Independent Laboratory Results: "GEL" -GEL Laboratories LLC -Lob ID # 10120; 'Test America" - TestAmeriea Laboratories, Ine. -Lab ID# 96001; "DavisBrown"- Davis & Brown Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc.- Lab ID# 32010 Analysis Validated: --�, Debra K. Guerry - Supervisor, Analytical Services Cne Riverwood Drive P.Q. Box 2946101 Santee Cooper Moncks Corner, SC 29461-2901 (843) 761-800D SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AD34600 Location: G4/V Well GGSMW-6 Date: 11/0212015 Sample Collector: Loc. Code GGSMW-6 Time: 15:15 Analysis Result QUAL Units Test Date Analyst Method Arsenic <10 ug1L 11/12/2015 KLMORAN EPA 200.7 Arsenic - Dissolved <10 uglL 11/12/2015 KLMORAN EPA 2003 Barium 72.0 ug/L 11112/2015 KLMORAN EPA 200.7 Cadmium <5 ug/L 11/12/2015 KLMORAN EPA 200.7 Chloride 9.43 mglL 11/0412015 LCWILLIA EPA300.0 Spec. Cond. 928 us 11/02/2015 MDGOINGS Chromium <5 ug/L 11/12/2015 KLMORAN EPA200.7 Copper <10 ug/L 11/12/2015 KLMORAN EPA200.7 Depth 4.75 Feet 11/02/2015 MDGOINGS Elevation 3.44 Feet 11/02/2015 MDGOINGS Iron 4521.7 ug/L 11/12/2015 KLMORAN EPA 200.7 Oxidation Reduction Potential -18 my 11/0212015 MDGOINGS SM2580 Lead <10 ug/L 11/12/2015 KLMORAN EPA 200.7 pH 6.09 SU 11102/2015 MDGOINGS Selenium 11.2 ugIL 11/12/2015 KLMORAN EPA200.7 Sulfate 26.8 mg/L 11/04/2015 LCWILLIA EPA300.0 Total Dissolved Solids 651.0 mg/L 11111/2015 AJBROWN SM 25440C Temp 21.12 C 11/02/2015 MDGOINGS Thallium <1.0 U ug/L 11/1312015 TESTAMERICA EPA 200.7 / 6010 Total Suspended Solids 3,95 mglL 11/11/2015 AJBROWN SM 2540D Turbidity 0 NTU 11/02/2015 MDGOINGS Zinc <10 ugh- 11/12/2015 KLMORAN EPA200.7 Independent Laboratory Results: "GEL" - GEL Laboratories LLC - Lab ID # 10120; 'Test America" - TestAmerica Laboratories, Inc, - Lab ID# 98001; "DavisBrown"- Davis & Brown Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc.- Lab ID# 32010 Analysis Validated: - , Debra K. Guerry - Supervisor, Analytical Services erwood One Box 29461 Drive } p cooper /� [� �/ P-0. Box 29d6101 'qpsan ee k mil_ ope Marcks Comer, SC 29461-2901 (843) 761-8000 SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AD34601 Location: GW Well GGSMW-9 'Date: 11/02/2015 Sample Collector: Loc. Code GGSMW-9 Time: 00:00 Analysis Result QUAL Units Test Date Analyst Method Arsenic 1241.3 ug/L 11/12/2015 KLMORAN EPA 200.7 Arsenic -Dissolved 1077.7 ug/L 11/12/2015 KLMORAN EPA200.7 Barium 493 ug/L 11/1212015 KLMORAN EPA 200.7 Cadmium <5 ug1L 11112/2015 KLMORAN EPA 200.7 Chloride 165 mg1L 11/06/2015 LCWILLIA EPA 300.0 Spec. Cond. 1014 u8 11105/2015 MDGOINGS Chromium <5 ug/L 11/12/2015 KLMORAN EPA 2007 Copper <10 ug/L 11/12/2015 KLMORAN EPA 200.7 Depth 2.95 Feet 11/05/2015 MDGOINGS Elevation 5.29 Feet 11105/2015 MDGOINGS Iron 16768.3 ug/L 11/12/2015 KLMORAN EPA 200.7 Oxidation Reduction Potential 78 my 11/05/2015 MDGOINGS SM2580 Lead <10 ug/L 11112/2015 KLMORAN EPA 200.7 pH 5.47 SU 11/0512015 MDGOINGS Selenium <10 ug/L 11/1212015 KLMORAN EPA 200.7 Sulfate 231 mg/L 11/06/2015 LCWILLIA EPA300.0 Total Dissolved Solids 752.0 mg1L 11/11/2015 AJ13ROWN SM 2540C Temp 20.91 C 11/0512015 MDGOINGS Thallium <1.0 U ug1L 11/13/2015 TESTAMERICA EPA 200.716010 Total Suspended Solids 4.10 mg1L 11/11/2015 AJBROWN SM 2540D Turbidity 8.7 NTU 11/0512015 MDGOINGS Zinc 22.4 ug/L 11112/2015 KLMORAN EPA 200.7 Independent Laboratory Results: "GEL" - GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc. - Lab ID# 98001; "DavisBrown"- Davis & Brawn Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc.- Lab ID# 32010 r Analysis Validated: Debra K. Guerry - Supervisor, Analytical Services Santee cooper Sample # AD34603 Location Lac. Code GGSMW-11 Analysis Arsenic Arsenic - Dissolved Barium Cadmium Chloride Spec, Cond. Chromium Copper Depth Elevation Iron Oxidation Reduction Potential Lead pH Selenium Sulfate Total Dissolved Solids Temp Thallium Total Suspended Solids Turbidity Zinc One Rivenvood Drive P.O. Box 2946101 Monrks Carrer, SC 28461-2901 (843)751-8000 SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 GW Well GGSMW-11 date: 11/0312015 Sample Collector: Time: 13:53 Result QUAL Units Test Date Analyst Method 108.5 ug/L 11/12/2015 KLMORAN EPA200.7 43.3 ug/L 11/12/2015 KLMORAN EPA 200.7 78.3 ug/L 11/12/2015 KLMORAN EPA 200.7 <5 ug/L 11/12/2015 KLMORAN EPA 200.7 5.40 mg/L 11/04/2015 LCWILLIA EPA300.0 545 us 11/03/2015 MDGOINGS <5 ug/L 11/1212015 KLMORAN EPA 200.7 <10 ug/L 11/12/2015 KLMORAN EPA 200.7 4.36 Feet 11/03/2015 MDGOINGS 5.27 Feet 1110312015 MDGOINGS 10171.5 ug/L 1111212015 KLMORAN EPA 200.7 -4 my 11/03/2015 MDGOINGS SM2580 <10 ug/L 11/12/2015 KLMORAN EPA 200.7 6.24 Su 11/03/2015 MDGOINGS <10 ug/L 11/12/2015 KLMORAN EPA 200.7 65.2 mg/L 11/04/2015 LCWILLIA EPA300.0 347.0 mgll 1111V2015 AJBROWN SM 2540C 19.51 C 11/0312015 MDGOINGS <1.0 LI ug/L 1111312015 TESTAMERICA EPA 200.7 / 6010 16.08 mg1L 11/11/2015 AJBROWN SM 2540D 20 NTu 11/0312015 MDGOINGS 44.1 uglL 11/12/2015 KLMORAN EPA 200.7 Independent Laboratory Results; "GEL" - GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc. - Lab JD# 98001; "DavisBrown"- Davis & Brown Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc,- Lab ID# 32010 Analysis Validated: Debra K. Guerry - Supervisor, Analytical Services One Riverwt4od drive P.O. Box2946101'Psantee cooper Muncks Corner, SC 29461-2901 (843}761-80M SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AD34604 Location: GW Well GGSMW-12 Date: 11/03/2015 Sample Collector: Loc. Code GGSMW-12 Time: 11:19 Analysis Result QUAL Units Test Date Analyst Method Arsenic 40.8 ug/L 11112/2015 KLMORAN EPA 200.7 Arsenic- Dissolved 46.5 ug/L 11/12/2015 KLMORAN EPA 200.7 Barium 71.4 ug/L 11/12/2015 KLMORAN EPA200.7 Cadmium <5 ug/L 11/12/2015 KLMORAN EPA200.7 Chloride 5.73 mg/L 11/04/2015 LCWILLIA EPA300.0 Spec. Cond. 508 u6 11/03/2015 MDGOINGS Chromium <5 ug/L 11/12/2015 KLMORAN EPA 2007 Copper <10 ug/L 11/12/2015 KLMORAN EPA200.7 Depth 9.49 Feet 11J0312015 MDGOINGS Elevation 5.41 Feet 11/03/2015 MDGOINGS Iron 14070.7 ug/L 11/12/2015 KLMORAN EPA200.7 Oxidation Reduction Potential -50 my 11/03/2015 MDGOINGS SM2580 Lead <10 ug/L 11112/2015 KLMORAN EPA 200,7 pH 5.89 Su 11/0312015 MDGOINGS Selenium <10 ug/L 11112/2015 KLMORAN EPA 200.7 Sulfate 138 mg/L 11109/2015 LCWILLIA EPA 300.0 Total Dissolved Solids 435.0 mg/L 11/11/2015 AJBROWN SM 2540C Temp 21.32 C 11/03/2015 MDGOINGS Thaliium <1,0 U ug/L 11/13/2015 TESTAMERICA EPA200.716010 Total Suspended Solids <1.0 mg1L 11111/2015 AJBROWN SM 2540D Turbidity 0.3 NTU 11/03/2015 MDGOINGS Zinc <10 ug/L 11/1212015 KLMORAN EPA200,7 Independent Laboratory Results: "GEL" - GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc, - Lab ID# 98001; "DavisBrown"- Davis & Brown Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc.- Lab ID# 32010 Isef Analysis Validated: - Debra K. Guerry - Supervisor, Analytical Services 2 u T ssauaulj �azuanlnd slsAleuV alelnolVed SISAIUuV oualsawil Sual5oleH Ielu.0 � lu!a„ 4selj eleApuv kinIs l uarrsdh0 U�D (qd `IN 'J9'PO's-V) SISAleuV sMaH I!0 v FlinexOIdVl03!oadS 101 (SISAIauV enelS'aZIS dolt dsal az!s (49V11e00) SISA]euV IeJOUIVJ Z xapuI4111!gePuu0 anafiPJeH S SISA(euV 016U1110 'a Szx[euV ajuw!yw,d °m aon SC13 = Sod .M 0 z ag1V4 '9uala4ldeN 'X310 S N M30 HVd 'Hdl Allen01i0 'Svool v 0 � � asea�J 8Is0 uz eg qd '!N 'eN `u" f5W bH m if m N u. 000 '001 O N- HN z .'ON '."ON '.j ',g _ ro ❑og (� IAIJ 1 Oa e7d urea 10:, e o ! t%J 011 I 1 !1 -� i t I '3 dulo3lgS�J `` El E rn , xu;eW Q U � 1r I4 � m \ 3 O U w o 0 3 4. a n, - tU n 0. v 0 t (14 N N N N N N N aay}eGAA ° V cn t m v 1 v ducal as;eM r r �: r leiIua;od E LO Q2 O r N M uo!;anpay uo!}ep!xp o85 WS N N N R ur) O cn O cn O to O y6!ay a6ne� � G r � mol j co It ti It ti v n v a N m M Hd pla!-4 to uo ai ui LO in .r; LO ,Sj!n!;onpuoZ) Pla!i N M �fi R R R V y}daa uo!}aalloo N O N N r r N M d Q Q O O Q O O O panloSS!4 - o!uaSay rn 3 18'OOZ ad3 m v m v m v Cl) v Cl) v co v co v m v J O Q O O Q O O O oluaSJV 0 ' $ ooz vd3 M v m v m v M v M v M v M v M v ducal j!y LO to m m Ln kn W w co N cp N N N N ti N N w N T O O O G r O r G r OI U or I ( to Go tl� C4 It It v a a 10 levv v o n o a a o d a a a a a a a a 4q Ono Riverwnoci Drive Psantee �S P.O. Box 29461ai cooper Moncks Corner, SC 2IJ461-2901 SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AD34038 Location: Lower Waccamaw River Date: 10/26/2015 Sample Collector: CM/EG Loc. Code WAC—LOW Time: 11:52 Analysis Result QUAL Units Test Date Analyst Method Air Temp 17 C 10/29/2015 CWMOORER Arsenic e3.0 U ug/L 11/09/2015 TESTAMERICA EPA200.8 Arsenic - Dissolved <3.0 U ug/L 11/09/2015 TESTAMERICA EPA 200.8 Collection Depth 2.25 m 10/29/2015 CWMOORER Field Conductivity 59 us 1012912015 CWMOORER Field pH 5.72 su 10/29/2015 CWMOORER Flow 4660 cfs 10129/2015 CWMOORER Gauge heigh 11.07 ft 10/2912015 CWMOORER Oxidation Reduction Potential 205 my 10/29/2015 CWMOORER SM2580 Weather 2 other 10/29/2015 CWMOORER Water Temp 17.42 C 10/29/2015 CWMOORER Independent Laboratory Results: "GEL" -GEL Laboratories LLC -Lab ID # 10120; "Test America"-TestAmerica Laboratories, Inc. -Lab 0# 98001; "DavisBrown"- Davis & Brown Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc.- Lab 1D# 32010 Analysis Validated: Debra K. Guerry - Supervisor, Analytical Services One Riverwood Ddve P O, 6101 JJantecooper Moncks Comer, SC 29461-2901 SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION 408552 Sample # AD34039 Location: GGS Cooling Pond Date: 10/26/2015 Sample Collector: MEG Loc. Code GGS_CP Time: 12:18 Analysis Result QUAL Units Test Date Analyst Method Air Temp 17 C 1012912015 CWMOORER Arsenic <3.0 U ug/L 11/09/2015 TESTAMERICA EPA200.8 Arsenic - Dissolved <3.0 U ug1L 11/0912015 TESTAMERICA EPA 200.8 Collection Depth 0.3 m 10/29/2015 CWMOORER Field Conductivity 58 us 10/29/2015 CWMOORER Field pH 5.69 Su 10/29/2015 CWMOORER Gauge heigh under water ft 10/29/2015 CWMOORER Oxidation Reduction Potential 201 my 10129l2015 CWMOORER SM2580 Weather 2 other 10129/2015 CWMOORER Water Temp 18.31 C 10/29/2015 CWMOORER Independent Laboratory Results: "GEL" -GEL Laboratories LLC -Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc, -Lab ID# 98001; "DavisBrown"- Davis & Brown Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc.- Lab ID# 32010 Analysis Validated: Debra K. Guerry - Supervisor, Analytical Services One Riverwood Vve cooper Box29461©1 'qp(� santee `-"-' `�' per Moncks Corner, SC 29461-2961 SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AD34040 Location: Waccamaw River Oxbow Date: 10/26/2015 Sample Collector: CM/EG Loc. Code WAC_OX Time: 12:42 Analysis Result QUAL Units Test Date Analyst Method Air Temp 17 C 10/29/2015 CWMOORER Arsenic <3.0 U ug/L M09/2015 TESTAMERICA EPA 200.8 Arsenic - Dissolved <3.0 U ug/L 11/0912015 TESTAMERICA EPA200.8 Collection Depth 2.4 m 10/29/2015 CWMOORER Field Conductivity 59 us 10/29/2015 CWMOORER Field pH 5.45 5U 1012912015 CWMOORER Oxidation Reduction Potential 219 my 10129/2015 CWMOORER SM2580 Weather 2 other 10129/2015 CWMOORER Water Temp 17.46 C 10/29/2015 CWMOORER Independent Laboratory Results: "GEL" -GEL Laboratories LLC -Lab iD # 10120; "Test America" - TestAmerica Laboratories, Inc. -Lab ID# 98001; "DavisBrown"- Davis & Brown Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc,- Lab ID# 32010 Analysis Validated: Debra K. Guerry - Supervisor, Analytical Services One Riverwood Drive P_DBox 26461013at✓e cooper MnncksCorner. SC29461-2901 SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AD34041 Location: Ditch beside HWY 501 off Date: 10/26/2015 Sample Collector: CM/EG Waccamaw River Loc. Code 501_DITCH Time: 12:49 Analysis Result QUAD Units Test Date Analyst Method Air Temp 17 C 10/29/2015 CWMOORER Arsenic <3.0 J ug/L 11109/2015 TESTAMERICA EPA 200.8 Arsenic- Dissolved <3.0 J ug/L 11/09/2015 TESTAMERICA EPA 200.8 Collection Depth 2.5 m 10/29/2015 CWMOORER Field Conductivity 63 us 10/29/2015 CWMOORER Field pH 5.79 Su 10/29/2015 CWMOORER Gauge heigh 5.9 ft 10/29/2015 CWMOORER Oxidation Reduction Potential 186 my 1012912015 CWMOORER SM2580 Weather 2 other 10/2912015 CWMOORER Water Temp 17.36 C 10/2912015 CWMOORER Independent Laboratory Results: "GEL" -GEL Laboratories LLC -Lab ID # 10120; "Test America-TestAmerica Laboratories, Inc. - Lab 0# 98001; "DavisBrown"- Davis & Brown Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc.- Lab ID# 32010 Analysis Validated: # Debra K. Guerry - Supervisor, Analytical Services One rtiverwood Drive 'Psantee cooper P-0Box2946101 Moncks Corner, SC 29461-2901 SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AD34042 Location: Waccamaw River Monitoring Well Date: 10126/2015 Sample Collector: CM/EG Loc. Code WRMW 5 Time: 12:58 Analysis Result QUAL Units Test Date Analyst Method Air Temp 17 C 1012912015 CWMOORER Arsenic <3.0 U ug/L 11/1)9/2015 TESTAMERICA EPA200.8 Arsenic - Dissolved <3 0 U ug/L 11/09/2015 TESTAMERICA EPA 200.8 Collection Depth 1.7 m 10/29/2015 CWMOORER Field Conductivity 58 us 10/29/2015 CWMOORER Field pH 5.48 SU 10/29/2015 CWMOORER Flow 4750 cfs 10/29/2015 CWMOORER Gauge heigh 11.05 ft 10/29/2015 CWMOORER Oxidation Reduction Potential 161 my 10/29/2015 CWMOORER SM2580 Weather 2 other 10/29/2015 CWMOORER Water Temp 17.44 C 10/29/2015 CWMOORER Independent Laboratory Results: "GEL" - GEL Laboratories LLC -Lab ID # 10120; "TestAmerica' - TestAmerica Laboratories, Inc. - Lab ID# 98001; '"DavisBrown"- Davis & Brown Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc.- Lab ID# 32010 r- j�L�Ct2_ - f_dCE i}c Analysis Validated: Debra K. Guerry - Supervisor, Analytical Services One Riverwood Drive P-O.. Box2946101 'Psantee cooper Mancks Corner, SC 29451-2901 SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample ## AD34043 Location: Waccamaw River Monitoring Well Date: 10/26/2015 Sample Collector: CM/EG Lac. Code WRMW_4R Time: 13:03 Analysis Result QUAL Units Test Date Analyst Method Air Temp 17 C 1012912015 CWMOORER Arsenic <3.0 U ug1L 11/09/2015 TESTAMERICA EPA200.8 Arsenic - Dissolved <3.0 U ug/L 11/09/2015 TESTAMERICA EPA 200.8 Collection Depth 1.7 m 10/29/2015 CVMOORER Field Conductivity 59 us 10/29/2015 CWMOORER Field pH 5.33 SU 10/29/2015 CWMOORER Flow 4750 cfs 10/29/2015 CWMOORER Gauge heigh 11.05 ft 10/29/2015 CWMOORER Oxidation Reduction Potential 192 my 10/29/2015 CWMOORER SM2580 Weather 2 other 10/29/2015 CWMOORER Water Temp 17.45 C 10129/2015 CWMOORER Independent Laboratory Results: "GEL" - GEL Laboratories LLC - Lab ID # 10120; "Test America" - TestAmerica Laboratories, Inc. - Lab 1D# 98001; "DavisBrown"- Davis & Brown Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc.- Lab ID# 32010 Analysis Validated: Debra K. Guerry - Supervisor, Analytical Services One Rlverwood Drive , a 1 tee Cooper P.O, ks Corner. S 1 � L Mancks Carver, SC 29461-2909 SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AD34044 Location: Waccarnaw River Monitoring Well Date: 10/26/2015 Sample Collector: CWEG Loc. Code WRMW_3R Time: 13:07 Analysis Result QUAL Units Test date Analyst Method Air Temp 17 C 10/29/2015 CWMOORER Arsenic <3.0 U ug1L 11/0912015 TESTAMERICA EPA200.8 Arsenic -Dissolved c3.0 U ug1L 11/09/2015 TESTAMERICA EPA200.8 Collection Depth 2.7 m 10/29/2015 CWMOORER Field Conductivity 59 us 10/29/2015 CWMOORER Field pH 5.31 SU 10/29/2015 CWMOORER Flow 4750 cfs 10/29/2015 CWMOORER Gauge heigh 11.05 ft 10129/2015 CWMOORER Oxidation Reduction Potential 191 my 10129/2015 CWMOORER SM2580 Weather 2 other 1012912015 CWMOORER Water Temp 17.45 C 10/2912015 CWMOORER Independent Laboratory Results: "GEL'- GEL Laboratories LLC - Lab ID # 10120; "Test America"-TestAmerica Laboratories, Inc. - Lab ID# 98001; "DavisBrown"- Davis & Brown Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc.- Lab ID# 32010 Analysis Validated: _ } Debra K. Guerry - Supervisor, Analytical Services One Rvenvood Drive Psr7 fj� cooper r P.Q Box 2946101 ., n Cee Moncks Corner, SC 29461-2901 SANTEE COOPER ANALYTICAL SERVICES CERTIFICATE OF ANALYSIS LAB CERTIFICATION #08552 Sample # AD34045 Location: Upper Waccamaw River Date: 10126/2015 Sample Collector: Ci Loc. Code WAC`UP Time: 13:21 Analysis Result QUAL Units Test Date Analyst Method Air Temp 17 C 10/29/2015 CWMOORER Arsenic <3.0 U ug/L 11/0912015 TESTAMERICA EPA 200.8 Arsenic -Dissolved <3.0 U ug1L 1V0912015 TESTAMERICA EPA200.8 Collection Depth 3.40 m 1012912015 CWMOORER Field Conductivity 58 us 1012912015 CWMOORER Field i 5,29 SU 10/29/2015 CWMOORER Flow 4940 cfs 10/29/2015 CWMOORER Gauge heigh 11.06 it 10/29/2015 CWMOORER Oxidation Reduction Potential 213 my 10129/2015 CWMOORER SM2580 Weather 2 other 10129/2015 CWMOORER Water Temp 17.47 C 10/2912015 CWMOORER Independent Laboratory Results: "GEL" -GEL Laboratories LLC -Lab ID # 10120; 'Test America" - TestAmerica Laboratories, Inc, -Lab ID# 98001; "DavisBrown"- Davis & Brawn Lab ID # 21117; "Shealy"- Shealy Environmental Services, Inc.- Lab ID# 32010 Analysis Validated: Debra K. Guerry - Supervisor, Analytical Services Attachment 11 Schwartz, et al. Article Leaching Potential and Redox Transformations of As and Se February 2016 Applied Geochemistry 67 (2016) 177-185 Contents lists available at ScienceDirect Applied Geochemistry ELSEVIER journal homepage: www.elsevier.com/locate/apgeochem Leaching potential and redox transformations of arsenic and selenium in sediment microcosms with fly ash Grace E. Schwartz a,1, Nelson Rivera a, Sung -Woo Lee a, James M. Harrington b, James C. Hower `, Keith E. Levine b, Avner Vengosh d, Heileen Hsu -Kim a, * a Duke University, Department of Civil & Environmental Engineering, 121 Hudson Hall, Durham, NC 27708, USA b RTI International, Analytical Sciences, 3040 East Cornwallis Drive, Research Triangle Park, NC 27709, USA University of Kentucky, Center for Applied Energy Research, 2540 Research Park Drive, Lexington, KY 40511, USA a Duke University, Division of Earth and Ocean Sciences, Nicholas School of the Environment, Durham, NC 27708, USA A R T I C L E I N F O Article history: Received 6 November 2015 Received in revised form 8 February 2016 Accepted 21 February 2016 Available online 23 February 2016 Keywords: Coal combustion residuals Water quality Solid waste disposal 1. Introduction A B S T R A C T ® CrossMark The unintended release of coal ash to the environment is a concern due to the enrichment of contam- inants such as arsenic (As) and selenium (Se) in this solid waste material. Current risk assessments of coal ash disposal focus on pH as the primary driver of leaching from coal ash. However, redox speciation of As and Se is a major factor for their mobilization potential and has received much less attention for risk assessments, particularly in disposal scenarios where coal ash will likely be exposed to microbially- driven redox gradients. The aim of this study was to demonstrate the differences of aerobic and anaerobic conditions for the leaching of As and Se from coal ash. Batch sediment -ash slurry microcosms were performed to mimic an ash spill scenario and were monitored for changes in As and Se speciation and mobilization potential. The results showed that the dissolved As concentrations were up to 50 times greater in the anaerobic microcosms relative to the aerobic microcosms during the two week incubation. This trend was consistent with As redox speciation determined by X-ray absorption spectroscopy, which indicated that 55% of the As in the solid phase at the end of the experiment was present as As(III) (a more leachable form of arsenic relative to As(V)). In the aerobic microcosms, only 13% of the As was As(III) and the rest was As(V). More than half of the Se was present as Se(IV) in the original fly ash and in the aerobic microcosms, while in the anaerobic microcosms Se was gradually transformed to less soluble Se(0) species. Likewise, dissolved Se concentrations were up to 25 times greater in the aerobic microcosms relative to anaerobic conditions. While the overall observations of As and Se mobilization potential from coal ash were consistent with expectations for aqueous and solid phase speciation of these elements, the findings directly show the relevance of these processes for coal ash disposal. These results highlight the need to select appropriate environmental parameters to include in risk assessments as well as provide potential geochemical monitoring tools through the use of dissolved Se/As ratios to determine the redox conditions of ash storage and spill sites. Coal ash is the solid waste by-product of coal combustion and includes bottom ash, fly ash, and sludge from flue gas desulfur- ization units. Every year, over 60 Mt of coal ash are disposed in 300 landfills and 600 holding ponds across the United States (American * Corresponding author. E-mail address: hsukim@duke.edu (H. Hsu -Kim). Current Affiliation: Smithsonian Environmental Research Center, 647 Contees Wharf Road, Edgewater, Maryland, 21037 USA. http://dx.doi.org/10.1016/j.apgeochem.2016.02.013 0883-2927/0 2016 Elsevier Ltd. All rights reserved. © 2016 Elsevier Ltd. All rights reserved. Coal Ash Association; US EPA, 2013d). Ash wastes are enriched in many potentially toxic elements, and the presence of arsenic (As) and selenium (Se) are a particular concern because of their rela- tively high mobilization potential at neutral to alkaline pH values that are typical of ash disposal impoundments (Izquierdo and Querol, 2012; Meij, 1994). Moreover, these elements have the ten- dency to bioaccumulate in the aquatic food web and impart eco- toxicological effects (Izquierdo and Querol, 2012; Lemly, 2004; Rowe, 2014; Sharma and Sohn, 2009; Thorneloe et al., 2010). Coal ash impoundments are not always closely monitored, particularly for effluent discharge to surface waters, seepage to 178 G.E. Schwartz et al. / Applied Geochemistry 67 (2016) 177-185 groundwater, and structural integrity. Consequently, impoundment effluent discharge is a major source of As and Se contamination to certain aquatic environments, with approximately 36,000 kg of As and 102,000 kg of Se discharged annually to surface waters in the United States (US EPA, 2013a). Ash impoundments have been cited in 132 documented cases of groundwater and surface water contamination (US EPA, 2007, 2013a). Moreover, impoundment failures and direct release of ash have been reported by at least 41 different power plants in the last 15 years (US EPA, 2012a). These impoundment failures include the 2008 ash spill at the Tennessee Valley Authority (TVA) Kingston Fossil Plant. Arsenic and selenium originating from the spilled ash were two contaminants of concern at the site (Ruhl et at., 2009, 2010). The mobility of As and Se in the environment is intimately linked to redox speciation of these elements and the propensity of individual species to associate with soil and sediment particles through adsorption/desorption reactions and precipitation/disso- lution reactions (Fernandez -Martinez and Charlet, 2009; Masscheleyn et al., 1991). The As(V) oxyanion arsenate tends to sorb more strongly to mineral phases such as iron oxides when compared to the reduced As(III) arsenite form (Goldberg and Johnston, 2001; Masscheleyn et al., 1991; Raven et al., 1998). If sulfide is present in sufficient quantities, insoluble arsenic -sulfide species (As2S3(s)) and soluble thioarsenicals may form (O'Day et al., 2004; Wilkin et al., 2003). In contrast to As, the Se(VI) oxy- anion selenate has little tendency to adsorb to solids or to precip- itate out of solution compared to selenite Se(IV), which has greater sorption affinity to metal oxyhydroxides, clays, and organic matter (Fernandez -Martinez and Charlet, 2009). In anaerobic conditions, selenium can persist as elemental selenium Se(0) or metal selenide mineral phases that are sparingly soluble in water. Organo-Se compounds such as selenocysteine and selenomethionine are a reduced forms of Se that are biologically active (Lemly, 1993). Arsenic associated with coal ash exists mainly as As(V) species while Se is typically found as Se(IV) and elemental Se(0) species (Chappell et al., 2014; Deonarine et al., 2015; Huggins et al., 2007; Liu et al., 2013). The mobilization of As and Se from coal ash is typically assessed using deionized water under aerobic conditions and perhaps under a wide range of pH values (Bednar et al., 2010; Izquierdo and Querol, 2012; Liu et al., 2013; Thorneloe et al., 2010). Much less attention has been given to redox transformations that can occur during ash disposal, even though these processes are critical for As and Se mobilization, as stated above. Two studies have attempted to address redox conditions by taking ash- deionized water mixtures and purging a subset with nitrogen gas (Bednar et al., 2010; Liu et al., 2013). The results of the work showed no or minimal differences between the oxic and Nz-purged mix- tures with respect to As and Se redox speciation and leaching po- tential from the ash. These results were inconsistent with our previous field studies at the TVA Kingston ash spill site and at several North Carolina ash holding ponds, where the mobilization of As and Se from coal ash appeared to change as a function of local redox conditions (Ruhl et al., 2012, 2010, 2009). Comprehensive measurements of As and Se speciation were not available from these field sites to verify the mechanisms of leaching from the ash. This study aimed to delineate the effects of redox gradients for As and Se mobilization from coal ash using laboratory sediment microcosms that more closely mimic the complexity of biogeo- chemical redox processes in the environment. Another objective was to improve our understanding of processes that were previ- ously observed at coal ash spill sites and perhaps identify geochemical tools for monitoring coal ash contaminants in redox gradients. Batch sediment slurry microcosms were constructed with aerobic and anaerobic conditions and were amended with fly ash to simulate a coal ash spill into a benthic sediment -water system. The microcosms were monitored for total dissolved con- centrations of As and Se, speciation of these elements in the aqueous and solid phases of the microcosms, and other water chemistry variables relevant for As and Se leaching. 2. Materials and methods 2.1. Materials All chemicals for reagents were purchased from Sigma Aldrich (St. Louis, MO), unless otherwise stated. Trace metal grade acids (Fisher Scientific, Pittsburgh, PA) were used for acid digestions and pH adjustments of samples. All reagents and calibration standards were prepared with >18 MQ-cm Milli-Q grade filtered water (EMD Millipore). The microcosms comprised of mixtures of sediment and water from the Emory River (Tennessee, USA). Surface water and bottom sediment samples for the microcosms were collected in April 2014 from mile marker 10 of the Emory River near Kingston (35.9475941°,—84.53178889°), which is located several miles up- stream of the TVA Kingston ash spill (Bartov et al., 2012; Deonarine et al., 2013; Ruhl et al., 2009, 2010). The sediment was a mixture of brown, organic fines and sand. Water samples were taken at 0.15 m depth and were stored in acid -cleaned plastic jugs. Bulk sediment was collected from the top layer of sediment (approximately 15 cm) using a Ponar dredge (Wildco) and placed in screw top buckets. The sediment and water samples were stored on ice for shipment to Duke University and stored at 4 °C in the laboratory. These sedi- ment and water samples were used within one month after collection for the microcosm experiments. Prior to the construction of the microcosms, the water was analyzed for trace element concentration, pH, and conductivity. The coal ash used for the microcosm experiments was collected at the TVA John Sevier fossil plant in April 2011. The sample was a composite of fly ash collected from electrostatic precipitator hop- pers at each of the plant's four units. The composite fly ash sample was characterized for major mineral oxide content (by X-ray fluo- rescence) and for total As and Se concentrations (methods described in Section 2.3). 2.2. Microcosm preparation and sampling Sediment slurry microcosm experiments were conducted on two separate occasions: the first under aerobic conditions, followed by the second under anaerobic conditions. Each treatment type (with and without ash; aerobic and anaerobic) was performed in duplicate microcosms. The microcosms were designed to mimic a stagnant, ash - impacted environment. The sediment to surface water ratio in the microcosms was chosen to provide an environment where suffi- cient overlying water would be available for sampling and analyses but microbial activity would not be limited. Each microcosm was prepared in a 1-L acid -washed, glass jar and consisted of 240 g of sediment (wet weight basis) and 600 mL of surface water. The sediment was thoroughly homogenized by stirring before micro- cosm construction. The river water was amended with a carbon substrate for microbial activity, 0.5-mM pyruvate and 0.5-mM ac- etate, immediately prior to microcosm construction. The aerobic microcosms were continuously stirred and purged with hydrated air using Teflon tubing and aquarium air stones during the experiments. After an incubation period of three days, 56 g of coal ash was added to the microcosms designated for ash amendment. This amount of coal ash corresponded to 40% (w/w) of dry sediment, an amount that was observed at the TVA Kingston ash spill site after dredging was completed (Deonarine et al., 2013). G.E. Schwartz et al. / Applied Geochemistry 67 (2016) 177-185 179 A single replicate sediment -water microcosm containing 6 mg L-1 resazurin was also constructed to serve as an indicator of redox conditions. This indicator microcosm was not used for the ash experiments but was used only to infer aerobic conditions for the other microcosms. The anaerobic microcosm experiment was performed after the completion of the aerobic experiment. These microcosms con- tained the same amount of water and sediment (600 mL and 240 g, respectively); however, they were constructed in 1-L glass pyrex bottles with gas -tight caps and assembled inside an anaerobic chamber (Coy Labs, Grass Lake, MI) containing an ambient atmo- sphere of 90% Nzlgl, 5% COZIgy and 5% Hz(g). Surface water amended with the carbon substrate (0.5-mM pyruvate and 0.5-mM acetate) was purged with high purity NZ for at least 15 min immediately prior to addition to the microcosms. A single replicate microcosm with the resazurin redox indicator (6 mg L-1) and no ash was also prepared for the anaerobic experiment. After assembly, the sealed microcosms were stored in the laboratory under static conditions at room temperature (22 °C). The microcosms were mixed end -over - end once per day in addition to immediately prior to each sampling time point. Anaerobic conditions (EH < —50 mV) were achieved in approximately three days, as indicated by the resazurin indicator microcosm turning from pink to a clear color. At this time, 56 g of coal ash was added to the microcosms designated for the ash amendments (performed in the anaerobic chamber). At time points before (-72 h, -2 h) and after the ash amendment (4, 24, 72,168, and 336 h), samples of the microcosm slurry were collected (12-15 mL in most instances). A portion of the sample was immediately filtered through a 0.2-µm nylon syringe filter (VWR). This filtered fraction is herein referred as the "dissolved" fraction. The solid phase of the slurry sample was collected by centrifugation (3000 RPM for 15 min). For the aerobic microcosms, the air bubblers and stir plates were turned off during the sampling. For the anaerobic microcosms, the collection, filtration, and pres- ervation of the sample were performed in the anaerobic chamber. Samples for solid phase separation were capped in the anaerobic chamber, centrifuged outside the chamber, and then returned immediately to the anaerobic chamber for the remainder of the sample preparation. 2.3. Sample preservation and chemical analyses Filtered aqueous samples were split and analyzed for dissolved As and Se concentrations, the speciation of dissolved As, pH, and other relevant water quality variables. Samples for dissolved trace element analysis (e.g., As, Se, and Fe) were immediately diluted in a 2% (v/v) HNO3/0.5% (v/v) HCl solution and analyzed by inductively coupled plasma -mass spectrometry (ICP-MS, Agilent 7700). Sulfate concentration was quantified by ion chromatography (Dionex). For acid volatile sulfide (AVS), filtered water samples were preserved with the addition of 10 mM ZnSO4 and 5 mM KOH (corresponding to final concentrations in the sample) and stored at 4 °C until analysis. AVS measurements were made using the method described by Allen et al. (1993) and summarized in the Supporting Information (SI). Aliquots of the filtered sample were also analyzed for aqueous phase As speciation (i.e., arsenate and arsenite) via ultra perfor- mance liquid chromatography-ICP-MS (Waters ACQUITY UPLC) coupled with a Thermo ELEMENT 2 sector field ICP-MS (Kim et al., 2013; Milstein et al., 2003). These samples were preserved with 0.125-M EDTA, in accordance to Bednar et al. (2002). UPLC-ICP-MS instrument parameters are shown in Table S2. Additional details of aqueous sample preservation and analysis methods can be found in the SI section. Total Se and As concentrations in the original sediment and fly ash samples were quantified by heated HNO3 acid digestion (85 °C for 6 h) and analysis by ICP-MS. The same acid extraction procedure was performed for a soil standard reference material (San Joaquin Soil NIST SRM 2709) and a coal fly ash reference material (NIST SRM 1633c). The recovery of certified As concentration values were 84% and 90% for the soil and fly ash references, respectively. Se re- coveries were 84% and 105%, respectively. For the fly ash sample, the major mineral oxide content was also characterized via X-ray Fluorescence following the ASTM standard method for ash analysis. Se and As speciation in the solid phase from the ash -amended microcosms was determined using K-edge X-ray absorption near edge structure (XANES) spectroscopy. The pellets obtained after centrifugation were subsequently packed into sample holders as wet pastes, covered with Kapton tape, and stored at 4 'C until analysis. XANES analyses were also performed for the original sediment and fly ash endmembers for the microcosms but were not performed on the ash -free microcosms due to the relatively low concentration of Se (<0.5 µg g 1) and arsenic (<2.5 µg g 1) and limitations of synchrotron beamtime required for these measurements. XANES spectra were collected in fluorescence mode at Beamline 11-2 at the Stanford Synchrotron Radiation Lightsource (SSRL) in Menlo Park, CA. Samples were held in a liquid NZ cryostat during analysis, and XANES spectra were collected with the use of a Si(220) (phi = 90°) monochromator and a 100-element solid state Ge de- tector array. Successive scans were collected to ensure that no changes in the sample occurred during data collection. Speciation of As and Se in the samples was quantified by linear combination fitting (LCF) of reference spectra to the sample spectra. For sele- nium, the references included sodium selenate, sodium selenite, selenite sorbed to aluminosilicate glass (Rivera et al., 2015), SO(S), FeSe(s), and seleno-L-cystine. Arsenic references included As(V)- and As(III)-oxides, arsenate adsorbed to aluminosilicate glass (Rivera et al., 2015), arsenite adsorbed to ferrihydrite (Root et al., 2007), orpiment (As2S3) and realgar (ASS). Additional details on XANES sample preparation and analysis can be found in the SI section. 3. Results and discussion 3.1. Characteristics of the ash, sediment, and water used for the microcosms Total As and Se concentrations in the ash were 44 µg g 1 dry weight (dw) and 19 µg g 1 dw, respectively, while in the original river sediment, total As and Se were 2.38 µg g 1 wet weight (ww) and 0.27 µg g 1 ww, respectively. Characteristics of the surface water included pH 7.5, 125.6 µS cm-1 conductivity, less than 4 µg L-1 As, and <0.4 µg L-1 Se. With these concentrations quan- tified in the original materials, each sediment microcosm without ash was estimated to contain 570 µg of As and 65 µg of Se. Micro- cosms with sediment and ash each contained approximately 3040 µg total As and 1130 µg total Se, with 81% and 94% of the As and Se originating from the fly ash. The fly ash sample comprised primarily of silica-, aluminum-, and iron -oxides (56%, 28%, and 6.7%, respectively) (Table S1), characteristics that are typical for a Class F fly ash. 3.2. Leaching potential of selenium in anaerobic and aerated microcosms Upon addition of the coal ash to both anaerobic and aerobic microcosms, dissolved Se immediately increased to concentrations that were 150-times greater than pre -amendment measurements (Fig.1). The extent of dissolved Se release varied according to redox 180 G.E. Schwartz et al. / Applied Geochemistry 67 (2016) 177-185 (a) 120 J rn m a� 0 0 co 100 80 60 40 20 my Ash -100 0 100 200 300 400 Hours after Coal Ash Amendment (b) 120 Anaerobic �1 100 6) 80 -D `Sediment -Only 0 Sediment + Ash > 60 0 ij 40 20 0 -100 0 100 200 300 400 Hours after Coal Ash Amendment Fig.1. Total dissolved selenium concentrations (<0.2 µm filtered fraction) in sediment - ash microcosms: (a) Aerobic treatments; (b) Anaerobic treatments. Each data point represents the average of duplicate microcosms. Error bars represent the range of duplicates. state, but in both cases, dissolved Se concentrations were greater in microcosms with ash amendments than in the respective ash -free control microcosms (<1.5 µg L-1 throughout the experiment). Dissolved Se was generally greater in the aerobic microcosms than in the anaerobic microcosms (with the exception of the first time point at 4 h) (Fig.1). In the aerobic ash -amended microcosms, total Se concentration reached a maximum of 53 µg L-1 at 24 h after ash addition and decreased to 29 µg L-1 over the course of the two - week experiment. While a decrease in soluble Se could indicate reductive transformation of Se to less soluble, lower oxidation states such as elemental selenium, other water chemistry variables such as constant levels of dissolved sulfate (Fig. SI) and low levels of dissolved iron (<0.02 mg L-1) (Fig. S2) throughout the experi- ment indicated that aerobic conditions were maintained. The decrease in dissolved Se could instead be a result of re -adsorption of Se(IV) species onto coal ash and sediment particles, which has been shown to occur in aerobic systems (Fan et al., 2002; Simmons and Wallschlager, 2005). Measurements of dissolved Se speciation were attempted, but the concentrations were below the limit of quantification for our UPLC-ICP-MS system (<50 µg L-1). In anaerobic ash -amended microcosms (Fig. 1b), there was an immediate spike in total dissolved Se after the coal ash amend- ment, but then Se concentration decreased from 94 µg L-1 at 4 h to 1.8 µg L-1 at 336 h. This decline in dissolved Se concentration was more drastic than that observed in the aerobic microcosms amended with ash. The pH of the water could influence leaching of Se-oxyanions, which tend to desorb in greater amounts from coal ash as pH in- creases (Liu et al., 2013). In the ash -amended microcosms, the pH was 7.3-7.5 in aerobic conditions and similar to pH values in the anaerobic experiment (pH 7.1-7.4) (Fig. S3). These results indicated that the differences between the aerobic and anaerobic microcosms for dissolved Se could not be explained by pH. The measured amount of dissolved Se was always less than 5% of the total Se in the microcosm, and the bulk of the selenium remained in the solid phase. Therefore, we examined the speciation of solid phase Se as a means to determine the longer term leaching potential of Se. In the original fly ash, approximately 65% (±0.4%) of the Se was Se(IV) species, as indicated by LCF models of the Se K- edge XANES spectra (Fig. 2, Table S3). A smaller proportion, 26% (±0.4%) and 9% (±0.5%), was Se(0) and Se(VI), respectively. In all ash and microcosm samples, the best fits were obtained with the use of selenite sorbed to aluminosilicate rather than sodium selenite for the Se(IV) reference. This suggests that the sorbed selenite material was a better approximation of Se(IV) species in the coal ash - sediment matrix than the sodium selenite standard. In aerobic ash -amended microcosms, Se(IV) was the dominant form of Se in the solid phase at all time points (Fig. 2, Table S3). This result is consistent with the Se speciation of the original ash sam- ple. The proportion of Se(0) also appeared to grow over the course of the experiment (from 19 ± 0.6% at 24 h to 38 ± 0.5% at 336 h). While abiotic reduction of Se is not expected in the aerated con- ditions of the microcosms, selenite-reducing microorganisms are capable of producing Se(0) in oxic conditions (Antonioli et al., 2007; Hunter and Kuykendall, 2007; Hunter and Manter, 2009; Zheng et al., 2014). In the anaerobic microcosms amended with ash, Se speciation of the solid phase was drastically different from the original fly ash sample. LCF models of the XANES spectra showed that the majority of selenium in the solids was Se(0) and FeSe and that the proportion of Se(0)+FeSe increased from 68% at 4 h to 79% at 336 h (Fig. 2, Table S3). The formation of FeSe was further supported by the dissolved Fe data (Fig. S2). In the anaerobic experiment, dissolved Fe concentrations immediately decreased to values below 1.5 mg L-1 after the ash amendment, even though dissolved Fe in the ash -free anaerobic control was greater than 10 mg L-1 and increasing with time. Sulfate reduction was also occurring in the anaerobic microcosms (Fig. S1); thus, dissolved Fe was likely precipitating out of solution as FeS and FeSe particles. Collectively, the aqueous and solid phase Se speciation data indicated that a portion of the Se in fly ash readily leached from the ash under aerobic conditions. However, in anaerobic settings, the results indicated that Se originating from the ash was transformed to species of lower oxidation states, subsequently diminishing the leaching potential of Se. 3.3. Arsenic dissolution and speciation in aerobic and anaerobic microcosms The leaching of As in the microcosms was also dictated by redox potential, with much greater dissolved As concentrations observed in anaerobic conditions than in aerobic conditions (Fig. 3). In the aerobic microcosms (Fig. 3a), the addition of ash resulted in an increase of total dissolved As concentration to a maximum value of 12 µg L-1 at 336 h (Fig. 3a). In the anaerobic experiment (Fig. 3b), the total dissolved As concentration after the addition of ash was greater: 157 µg L-1 was detected at 4 h and a maximum dissolved As concentration of 498 µg L-1 was observed at 72 h (Fig. 3a). This amount of dissolved As represented 9.8% of the total mass of As in the microcosm container (570 µg As from the original sediment; 2460 µg As from the ash). After 72 h, total dissolved As concen- trations declined slightly over the remainder of the anaerobic G.E. Schwartz et al. / Applied Geochemistry 67 (2016) 177-185 181 (a) Sample - - - LCF (b) Aerobic:336h Aerobic:168h Aerobic:24h 117 1 li lilt l t Anaerobic:336h " Anaerobic:168h w Z �' I Anaerobic:24h Q X .I I Sediment E �� Ash o Z n i " HA Se(VI) Se(IV) Se(0) FeSe 12650 12660 12670 12680 Energy (eV) 0% 20% 40% 60% 80% 100% Percent Composition ® FeSe Elemental Se INSe(IV) MSe(VI) Fig. 2. Solid phase speciation of selenium: (a) Normalized Se K-edge XANES spectra for solids from the ash -amended microcosms and models of the data using linear combination fitting (LCF) of reference spectra; (b) The relative proportions of iron selenide (FeSe), elemental Se(0), Se(IV) (as selenite sorbed to aluminosilicate), and Se(VI) (sodium selenate). The total Se in the solid phase of the microcosm was estimated to be 3.8 µg g-1, of which 94% originated from the coal ash. experiment. The speciation of dissolved and solid phase As was largely consistent with expectations for the tested redox condition. In the aerobic ash -amended microcosms, more than 92% of the dissolved As was in the oxidized form, As(V) (Fig. 4a). Similarly, As speciation in the original fly ash and the sediment -ash mixture of the aerobic microcosm was predominantly As(V) (85-89%, Fig. 5 and Table S3). The best model fits for the As K-edge XANES spectra were obtained with arsenate-sorbed to aluminosilicate glass as the As(V) refer- ence material and with arsenite sorbed to ferrihydrite as the As(III) reference material. We observed poorer fits with the use of As - oxide compounds as the As(V) and As(III) references. This result suggested that the sorbed standards were better mimics of As species in the coal ash and ash -sediment matrices. In the anaerobic experiment, the dissolved As after the addition of ash was present mostly as arsenite (>86%) (Fig. 4b). As(V) was consistently less than 15% of the dissolved As in the anaerobic microcosms with ash. We note, however, that for the amount of dissolved sulfide in the anaerobic microcosms with fly ash (2-8 µM, Fig. S4), thioarsenite and thioarsenate species were possible. Previous studies have shown that thio-arsenic species are not preserved by the EDTA reagent and can be converted to arsenite and arsenate prior to the analysis (Suess et al., 2011). While thio- arsenicals were a possibility in the anaerobic microcosms, they nevertheless were not expected to be dominant based on ther- modynamic considerations (Wilkin et al., 2003). In the solid phase of the ash -amended anaerobic microcosms, As(III) was also the dominant form of As (55-73%) while As(V) was less than 41% at all time points (Fig. 5, Table S3). This result indi- cated relatively rapid transformation of As(V) from the fly ash to As(III) species. The amount of As -sulfide solids in the anaerobic experiment also increased from 2% at 24 h to 19% at 336 h. The formation of relatively insoluble As -sulfide minerals such as orpi- ment can result in a decrease of dissolved As (Burton et al., 2014; O'Day et al., 2004). Thus, the production of As -sulfides species in the anaerobic microcosm could explain the decrease of dissolved As after the 72-h time point (Fig. 3b). Collectively the dissolved and solid phase As species distribution in the anaerobic experiments demonstrated reductive transformation of As from the ash material and was consistent with expectations for As speciation in a strongly reducing environment where sulfate reduction was occurring (Smedley and Kinniburgh, 2002). Unexpectedly, in the anaerobic ash -free microcosms, As(V) was found to be the dominant form (70% and greater) of dissolved As (Fig. 4c). With relatively low amounts of dissolved sulfide in the ash -free microcosm (less than 0.1 µM at the end, Fig. S4), the dis- solved As(V) was likely to primarily consist of arsenate rather than thioarsenate. The total dissolved As and dissolved Fe concentra- tions were also increasing with time in the anaerobic ash -free microcosms. Thus, leaching of As was likely occurring through reductive dissolution of iron oxides and release of As(V) sorbed to these minerals. We note, however, that the reduction of Fe(III)- oxides and As(V) occur in the same Eh range (0-100 mV) for neutral pH conditions (Masscheleyn et al.,1991), and the reduction potential of the anaerobic microcosms was likely to be less than —50 mV, as indicated by the resazurin. Thus, it is unclear why As(V) remained dominant in the anaerobic ash -free microcosms. One potential explanation is that Fe(III) outcompeted As(V) as an electron acceptor for microbial respiration. The kinetics for As(V) reduction to As(III) are also known to be relatively slow, which may 182 G.E. Schwartz et al. / Applied Geochemistry 67 (2016) 177-185 (a) 16 Aerobic J 6) 12 T Q 8 I > -a -Sediment Only 0 f Sediment + Ash 0 4 - - - - 0 a - -100 0 100 200 300 400 Hours after Coal Ash Amendment (b) 600 Anaerobic m❑ -Sediment Only —W- Sediment+Ash J 400 Q Q) N O n 200 0 -------❑ 0 IT I -100 0 100 200 300 400 Hours after Coal Ash Amendment Fig. 3. Total dissolved arsenic concentrations (<0.2-µm filtered fraction) in sediment - ash microcosms: (a) Aerobic treatments; (b) Anaerobic treatments. Data points and error bars represent the average and range of duplicate microcosms. have contributed to the presence of both species in the ash -free microcosm (Masscheleyn et al., 1991; Smedley and Kinniburgh, 2002). Likewise, the ash -free microcosms were poised at moder- ately reducing conditions while the ash -amended microcosms were poised at lower redox potential (as indicated by reduction of sulfate and production of sulfide in the presence of ash, Figs. SI and S4). Lower Eh values in the ash amendments could lead to greater conversion of As(V) to As(III) compared to the ash -free control. In summary, the microcosm experiments demonstrated that the leaching potential of As from coal ash was greater in anaerobic conditions than aerobic conditions, due to redox transformations of As. However, the large amount of sulfur from the ash could contribute to secondary precipitation reactions of As -sulfides if the ash was released or stored in sufficiently reducing conditions. 3.4. Implications for ash spill settings The results of this study showed that in a system buffered at neutral pH, redox potential had a major influence on the release of Se and As from coal ash, with increased As release under anaerobic conditions and increased Se release under aerobic conditions. Furthermore, this study provided clues to the impact of coal ash on the geochemistry of the benthic environment and subsequent im- plications for As and Se speciation and solubility. For example, the microcosm experiments showed that coal ash dramatically increased dissolved sulfate concentrations. In anaerobic environ- ments with active microbial populations, reduction of sulfate can result in formation of sulfide and the sequestration of As(III) in sulfide mineral phases. The results also shed light on possible field -based tools to (a) Aerobic: Ash -Amended Microcosms 12 10 Q 6 0 n 4 2 0 (b) 600 500 400 to Q 300 0 w 200 100 0 (o) 80 -1 60 -o 40 0 Ch 0 20 0 . ... n, 'I 'I A o/ 4 24 72 168 336 Hours after Coal Ash Amendment Anaerobic: Ash -Amended Microcosms 124% 102% 10�% Ih 11 105% 105% 4 24 72 168 336 Hours after Coal Ash Amendment Anaarnhir• Cariimant r)nly Mirror-c As(V) El As(III) ■ As(V) El As(III) As(V) ElAs(III) 4 24 72 168 336 Hours after Coal Ash Amendment Fig. 4. Dissolved arsenic as arsenate As(V) and arsenite As(Ill) in: (a) Aerobic ash - amended treatment; (b) Anaerobic ash -amended treatment; (c) Anaerobic sediment only (no ash) treatment. Bars represent the average of duplicate microcosms. The percentages above each bar is the recovery of total dissolved As (quantified inde- pendently by ICP-MS). Dissolved As concentrations in the ash -free aerobic microcosms were below detection limits for speciation analysis (<12 µg L-1). evaluate the processes controlling As and Se mobilization from coal ash. The Se/As ratios in the aerobic and anaerobic experiments showed opposite trends, depending on the redox state of the experiment (Fig. 6). If the original Se/As ratio is known for a spilled coal ash, one could delineate the conditions that control Se and As mobilization based on the changes in their ratios relative to the ratios in the original coal ash. This tool might provide an indirect measurement of the redox state of the system and predictions for future fluctuation in Se and As contents based on redox conditions. The design of this study best mimics stagnant ash -impacted G.E. Schwartz et al. / Applied Geochemistry 67 (2016) 177-185 183 a () b Sample - - - LCF Aerobic:336h " Aerobic:168h Aerobic:24h VVIA,, Anaerobic:336h W Anaerobic:168h z Anaerobic: 24h � 'll N E `0 Sediment z " "' Ash As(V) 1 As(111) As -Sulfide 1XW 11840 11860 11880 11900 11920 Energy (eV) 0% 20% 40% 60% 80% 100% Percent Composition ® As -Sulfide ElAs(III) a As(V) Fig. 5. Solid phase speciation of arsenic: (a) Normalized As K-edge XANES spectra for solids from the ash -amended microcosms and models of the data using linear combination fitting (LCF); (b) The relative proportions of As(V) (arsenate sorbed to aluminosilicate glass), As(Ill) (arsenite sorbed to ferrihydrite), and As -sulfide (as orpiment). Total As in the solid phase of the microcosms was -10 µg g-1 and approximately 80% of the As originated from the coal ash. 10 aerobic • 0 1 original ash Q 0.1 A 0.01 anaerobic A I�IZI)yl 0 100 200 300 400 Hours after ash addition Fig. 6. Dissolved Se/As concentration ratios in the aerobic and anaerobic microcosms amended with ash. environments, and our results support observations from our pre- vious field studies of coal ash impacted environments with limited water exchange (Ruhl et al., 2009, 2010). For example at the TVA - Kingston ash spill site, pore water extracted from buried sediment -ash mixtures was found to have much higher total dis- solved As concentration (mean = 324 µg L-1) than standing surface water at the site (mean = 53.3 µg L-1) (Ruhl et al., 2010). Addi- tionally, a study of North Carolina surface waters receiving coal ash effluent revealed that both As and Se accumulated in lake bottom sediments and were released into the water column during sea- sonal thermal stratification and fluctuations of redox potential in the water column (Ruhl et al., 2012). Our microcosm study repre- sents only a 2 week snapshot of fly ash weathering, so some caution is warranted in extrapolating the results to the long term fate of contaminants at ash spill sites. Nevertheless, data from these ex- periments strongly suggest that redox transformations of coal ash contaminants should be considered when assessing remediation options for ash -impacted environments, especially when balancing the risks of natural attenuation and alternative measures such as dredging. Due to redox-induced adsorption/desorption reactions and precipitation/dissolution reactions, As concentrations can be very high in sediment pore water even though contaminant concen- trations in overlying oxic surface waters may be well -below EPA guidelines. These high concentrations could present a risk for bio- magnification in the benthic aquatic food web. Furthermore, the release of As from sediments into overlying surface waters during thermal stratification events has implications for communities that use the surface water for recreational use and as a drinking water reservoir. The consequences of seasonal As release would be miti- gated to some degree by dilution, but, nevertheless, the long-term cycling of As in the environment should be taken into account when communities consider plans for remediating coal ash impacted sites (Ruhl et al., 2012). In the case of Se, Se oxyanion species in the aerobic water col- umn can be taken up by aquatic biota and converted to 184 G.E. Schwartz et al. / Applied Geochemistry 67 (2016) 177-185 organoselenium species, which are highly bioaccumulative (Fan et al., 2002; Simmons and Wallschlager, 2005). Accumulation of Se in sediments also presents a risk to benthic organisms that ingest Se(0) and Se( -II) species and convert them to organo- selenium species (Fan et al., 2002). Anaerobic sediments also act as a source of selenium to the water column if the sediments are disturbed in a way that results in the oxidation and remobilization of reduced Se species (Belzile et al., 2000; Simmons and Wallschlager, 2005). The constant risk of bioaccumulation, and the latent risk of remobilization in Se -contaminated sediments should be a major consideration for ash spill remediation. 3.5. Implications for coal ash management This study's confirmation that redox potential is a key param- eter in controlling As and Se mobilization during an ash spill brings into question the applicability of the leaching tests currently used to assess environmental risks. Coal ash management is guided by the EPA's Toxicity Characteristic Leaching Protocol (US EPA,1992), a leaching test performed under aerobic conditions at a single pH value (pH = 4.9 or 2.4). Other EPA methods such as the Leaching Environmental Assessment Framework evaluates contaminant leaching over a wide range of pH values, but the tests still fail to account for complexity in the real environment (US EPA, 2012b, 2012c, 2013b, 2013c). Likewise, previous experiments with N2- purged water -ash mixtures did not result in changes to Se and As speciation in coal ash (Bednar et al., 2010; Liu et al., 2013). The data from our study suggests that the absence of oxygen, alone, is insufficient for testing contaminant mobilization in anaerobic conditions relevant for ash impoundments and ash spill sites. Instead, microbially-driven redox transitions, which can be stimu- lated by sulfate from the coal ash, are more environmentally rele- vant and necessary for attaining sufficiently reducing conditions for transformations of As, Se, and possibly other contaminants (e.g., mercury, chromium, etc.). Moreover, the impacts of the redox transitions are likely to vary in degree according to the geochemical properties of the coal ash, the sediment, as well as the composition of the microbial community. All these considerations are needed in the future improvements of standardized methods for coal ash risk assessments. Finally, these results are helpful for identifying suitable closure methods for ash impoundments. The U.S. EPA now requires the closure of ash ponds that show a risk of groundwater contamina- tion or that are improperly sited (US EPA, 2014b). Likewise, recent regulations in North Carolina require the closure of all the State's ash impoundments by 2029; those designated as high -risk must be closed by 2020 (US EPA, 2014a). One proposed closure method is the "Cap in Place" approach, where the ash pond would be de - watered and then covered with a porous or non -porous cap (Duke Energy, 2015). One concern with this method is that the cap could alter redox conditions in the impoundment, and this study shows that such changes could enhance the release of soluble arsenic into local groundwater. Thus, even if no previous ground- water contamination issues have been reported, capping methods that might induce anaerobic conditions should be avoided in the closure of unlined impoundments. Overall, this research shows the need to consider both coal ash characteristics and environmental parameters when assessing the environmental risks of ash disposal. Acknowledgments We thank the Tennessee Valley Authority, Restoration Services, and Environmental Services for their assistance with field sample collection. We also thank Kaitlyn Porter for her assistance with ICP- MS measurements. This work was supported by the National Science Foundation (CBET-1235661). G. Schwartz was also partly supported by a doctoral scholarship from the Environmental Research and Education Foundation. Appendix ASupplementary data Supplementary data related to this article can be found at http:// dx.doi.org/10.1016/j.apgeochem.2016.02.013. References Allen, H.E., Fu, G., Deng, B., 1993. Analysis of acid -volatile sulfide (AVS) and simultaneously extracted metals (SEM) for the estimation of potential toxicity in aquatic sediments. Environ. Toxicol. Chem. 12, 1441-1453. American Coal Ash Association, Coal Combustion products production & use sta- tistics; https://www.acaa-usa.org/Publications/Production-Use-Reports. Antonioli, P., Lampis, S., Chesini, L, Vallini, G., Rinalducci, S., Zolla, L., Righetti, P.G., 2007. Stenotrophomonas maltophilia SeITE02, a new bacterial strain suitable for bioremediation of selenite-contaminated environmental matrices. Appl. Environ. Microbial. 73, 6854-6863. Bartov, G., Deonarine, A., Johnson, T.M., Ruhl, L., Vengosh, A., Hsu -Kim, H., 2012. Environmental impacts of the Tennessee valley authority Kingston coal ash spill. 1. Source apportionment using mercury stable isotopes. Environ. Sci. Technol. 47, 2092-2099. Bednar, A.J., Chappell, MA., Seiter, J.M., Stanley, J.K., Averett, D.E., Jones, W.T., Pettway, B.A., Kennedy, A.J., Hendrix, S.H., Steevens, J.A., 2010. Geochemical investigations of metals release from submerged coal fly ash using extended elutriate tests. Chemosphere 81, 1393-1400. Bednar, A.J., Garbarino, J.R., Ranville, J.F., Wildeman, T.R., 2002. Preserving the dis- tribution of inorganic arsenic species in groundwater and acid mine drainage samples. Environ. Sci. Technol. 36, 2213-2218. Belzile, N., Chen, Y.-W., Xu, R., 2000. Early diagenetic behaviour of selenium in freshwater sediments. Appl. Geochem. 15, 1439-1454. Burton, E.D., Johnston, S.G., Kocar, B.D., 2014. Arsenic mobility during flooding of contaminated soil: the effect of microbial sulfate reduction. Environ. Sci. Technol. 48, 13660-13667. Chappell, M.A., Seiter, J.M., Bednar, A.J., Price, C.L., Averett, D., Lafferty, B., Tappero, R., Stanley, J.S., Kennedy, A.J., Steevens, J.A., Zhou, P., Morikawa, E., Merchan, G., Roy, A., 2014. Stability of solid -phase selenium species in fly ash after prolonged submersion in a natural river system. Chemosphere 95, 174-181. Deonarine, A., Bartov, G., Johnson, T.M., Ruhl, L., Vengosh, A., Hsu -Kim, H., 2013. Environmental impacts of the Tennessee valley authority Kingston coal ash spill. 2. Effect of coal ash on methylmercury in historically contaminated river sediments. Environ. Sci. Technol. 47, 2100-2108. Deonarine, A., Kolker, A., Doughten, M.W., 2015. Trace elements in coal ash. US Geological survey. Duke Energy, 2015. Ash Management. Fan, T.W.M., Teh, S.J., Hinton, D.E., Higashi, R.M., 2002. Selenium biotransformations into proteinaceous forms by foodweb organisms of selenium -laden drainage waters in California. Aquat. Toxicol. 57, 65-84. Fernandez -Martinez, A., Charlet, L., 2009. Selenium environmental cycling and bioavailability: a structural chemist point of view. Rev. Environ. Sci. Biotechnol. 8, 81-110. Goldberg, S., Johnston, C.T., 2001. Mechanisms of arsenic adsorption on amorphous oxides evaluated using macroscopic measurements, vibrational spectroscopy, and surface complexation modeling. J. Colloid Interface Sci. 234, 204-216. Huggins, F.E., Senior, C.L., Chu, P., Ladwig, K., Huffman, G.P., 2007. Selenium and arsenic speciation in fly ash from full-scale coal -burning utility plants. Environ. Sci. Technol. 41, 3284-3289. Hunter, W.J., Kuykendall, L.D., 2007. Reduction of selenite to elemental red selenium by Rhizobium sp. strain Bl. Curr. Microbial. 55, 344-349. Hunter, W.J., Manter, D.K., 2009. Reduction of selenite to elemental red selenium by Pseudomonas sp. strain CAS. Curr. Microbiol. 58, 493-498. Izquierdo, M., Querol, X., 2012. Leaching behaviour of elements from coal com- bustion fly ash: an overview. Int. J. Coal Geol. 94, 54-66. Kim, N.H., Mason, C.C., Nelson, R.G., Afton, S.E., Essader, A.S., Medlin, J.E., Levine, K.E., Hoppin, J.A., Lin, C., Knowler, W.C., 2013. Arsenic exposure and incidence of type 2 diabetes in southwestern American Indians. Am. J. Epi- demiol. 177, 962-969. Lemly, A.D.,1993. Guidelines for evaluating selenium data from aquatic monitoring and assessment studies. Environ. Monit. Assess. 28, 83-100. Lemly, A.D., 2004. Aquatic selenium pollution is a global environmental safety issue. Ecotoxicol. Environ. Saf. 59, 44-56. Liu, Y.-T., Chen, T.-Y., Mackebee, W.G., Ruhl, L., Vengosh, A., Hsu -Kim, H., 2013. Se- lenium speciation in coal ash spilled at the Tennessee valley authority Kingston site. Environ. Sci. Technol. 47, 14001-14009. Masscheleyn, P.H., Delaune, R.D., Patrick, W.H., 1991. Effect of redox potential and pH on arsenic speciation and solubility in a contaminated soil. Environ. Sci. Technol. 25, 1414-1419. Meij, R., 1994. Trace element behavior in coal-fired power plants. Fuel Process. G.E. Schwartz et al. / Applied Geochemistry 67 (2016) 177-185 185 Technol. 39, 199-217. Milstein, L.S., Essader, A., Pellizzari, E.D., Fernando, R.A., Raymer, J.H., Levine, K.E., Akinbo, 0., 2003. Development and application of a robust speciation method for determination of six arsenic compounds present in human urine. Environ. health Perspect. 111, 293. O'Day, P.A., Vlassopoulos, D., Root, R., Nelson, R., Turekian, K.K., 2004. The influence of sulfur and iron on dissolved arsenic concentrations in the shallow subsurface under changing redox conditions. Proc. Natl. Acad. Sci. U. S. A. 101, 13703-13708. Raven, K.P., Jain, A., Loeppert, R.H., 1998. Arsenite and arsenate adsorption on fer- rihydrite: Kinetics, equilibrium, and adsorption envelopes. Environ. Sci. Tech- nol. 32, 344-349. Rivera, N., Kaur, N., Hesterberg, D., Ward, C.R., Austin, R.E., Duckworth, O.W., 2015. Chemical composition, speciation, and elemental associations in coal fly ash samples related to the Kingston ash spill. Energy & Fuels 29, 954-967. Root, R.A., Dixit, S., Campbell, K.M., Jew, A.D., Hering, J.G., O'Day, P.A., 2007. Arsenic sequestration by sorption processes in high -iron sediments. Geochimica Cos- mochimica Acta 71, 5782-5803. Rowe, C.L., 2014. Bioaccumulation and effects of metals and trace elements from aquatic disposal of coal combustion residues: Recent advances and recom- mendations for further study. Sci. Total Environ. 485-486, 490-496. Ruhl, L., Vengosh, A., Dwyer, G., Hsu -Kim, H., Schwartz, G., Romanski, A., Smith, S.D., 2012. The impact of coal combustion residue effluent on water resources: a North Carolina example. Environ. Sci. Technol. 46, 12226-12233. Ruhl, L., Vengosh, A., Dwyer, G.S., Hsu -Kim, H., Deonarine, A., 2010. Environmental impacts of the coal ash spill in Kingston, Tennessee: an 18-Month survey. En- viron. Sci. Technol. 44, 9272-9278. Ruhl, L., Vengosh, A., Dwyer, G.S., Hsu -Kim, H., Deonarine, A., Bergin, M., Kravchenko, J., 2009. Survey of the potential environmental and health impacts in the immediate aftermath of the coal ash spill in Kingston, Tennessee. Envi- ron. Sci. Technol. 43, 6326-6333. Sharma, V.K., Sohn, M., 2009. Aquatic arsenic: Toxicity, speciation, transformations, and remediation. Environ. Int. 35, 743-759. Simmons, D.B.D., Wallschlager, D., 2005. A critical review of the biogeochemistry and ecotoxicology of selenium in lotic and lentic environments. Environ. Tox- icol. Chem. 24, 1331-1343. Smedley, P.L., Kinniburgh, D.G., 2002. A review of the source, behaviour and dis- tribution of arsenic in natural waters. Appl. Geochem. 17, 517-568. Suess, E., Wallschlager, D., Planer -Friedrich, B., 2011. Stabilization of thioarsenates in iron -rich waters. Chemosphere 83, 1524-1531. Thorneloe, S.A., Kosson, D.S., Sanchez, F., Garrabrants, A.C., Helms, G., 2010. Evalu- ating the fate of metals in air pollution control residues from coal fired power plants. Environ. Sci. Technol. 44, 7351-7356. US EPA, 1992. Method 1311: Toxicity Characteristic Leaching Procedure. United States Environmental Protection Agency, Washington, D.C. US EPA, 2007. Coal Combustion Waste Damage Assessments. United States Envi- ronmental Protection Agency, Washington, DC. US EPA, 2012a. Information Request Responses from Electric Utilities: Dataset Results. US EPA, 2012b. Method 1313: Liquid Solid Partitioning as a Function of Extract pH using a Parallel Batch Extraction Procedure. United States Environmental Pro- tection Agency, Washington, D.C. US EPA, 2012c. Method 1316: Liquid -Solid Partitioninig as a Function of Liquid -To - Solid Ratio in Solid Materials Using a Parallel Batch Procedure. United States Environmental Protection Agency, Washington, D.C. US EPA, 2013a. Environmental Assessment for the Proposed Effluent Limitations Guidelines and Standards for the Steam Electric Power Generating Point Source Category. United States Environmental Protection Agency, Washington, DC. US EPA, 2013b. Method 1314: Liquid -Solid Partitioning as a Function of Liquid -Solid Ratio for Constituents in Solid Materials Using an Up -Flow Percolation Column Procedure. United States Environmental Protection Agency, Washington, D.C. US EPA, 2013c. Method 1315: Mass Transfer Rates of Constituents in Monolithic or Compacted Granular Materials Using a Semi -Dynamic Tank Leaching Procedure. United States Environmental Protection Agency, Washington, D.C. US EPA, 2013d. Technical Development Document for the Proposed Effluent Limi- tations Guidelines and Standards for the Steam Electric Power Generating Point Source Category. United States Environmental Protection Agency, Washington, D.C. US EPA, 2014a. The Coal Ash Management Act of 2014 (Session Law 2014-122. Senate Bill 729). North Carolina State Legislature, Raleigh, NC. US EPA, 2014b. Hazardous and Solid Waste Management System; Disposal of Coal Combustion Residuals from Electric Utilities. U.S. Environmental Protection Agency, Washington, D.C. Wilkin, R.T., Wallschlager, D., Ford, R.G., 2003. Speciation of arsenic in sulfidic waters. Geochemical Transactions 4, 1-7. Zheng, S., Su, J., Wang, L., Yao, R., Wang, D., Deng, Y., Wang, R., Wang, G., Rensing, C., 2014. Selenite reduction by the obligate aerobic bacterium Comamonas tes- tosterone S44 isolated from a metal -contaminated soil. BMC microbiol.14, 204. Attachment 12 GHI Roxboro Report Final March 2016 GEO-HYDRO, INC Consulting in Geology and Hydrogeology 1928 E. 141h Avenue Denver, Colorado 80206 (303)322-3171 EXPERT REPORT OF MARK A. HUTSON, PG Roxboro Steam Electric Plant S emora, NC Prepared for: Southern Environmental Law Center 601 West Rosemary Street Suite 220 Chapel Hill, NC 27516-2356 March 2016 GEO-HYDRO, INC 1. Summary of Opinions Formed Based upon my review of the available information I have formed the following opinions on closure of the coal ash basins at the Roxboro Steam Electric Plant (Roxboro). 1. Coal ash stored in the Roxboro ash basins is the source of contamination detected in groundwater. 2. Capping coal ash located within the Roxboro ash basins will not protect groundwater quality downgradient of the basins Monitored Natural Attenuation (MNA) is not an acceptable groundwater remediation strategy at Roxboro. 4. Capping coal ash located within the Roxboro ash basins will not be protective of surface water quality. 5. Removal of the coal ash will remove the source and reduce the concentration and extent of groundwater contaminants. 6. The coal combustion residual impoundment risk classification proposed by the North Carolina Department of Environmental Quality (NCDEQ) improperly minimizes protection of environmental quality. The background and rationale behind each of these opinions are described in this report. GEO-HYDRO, INC 2. Introduction Duke Energy (Duke) reportedly stores approximately 33,390,000 tons of coal ash in various areas around the Roxboro facility, including ash stored in two unlined ash basins (East and West), lined and unlined landfills, and other ash filled areas'. An additional poorly identified and uncharacterized Unnamed Eastern Extension impoundment was recently reported to NCDEQ. The location and volume of additional coal ash contained in the Unnamed Eastern Extension impoundment was not identified in any of the documents reviewed. Pollution caused by the coal ash at this site is currently the subject of an enforcement action brought by the NCDEQ. Organizations represented by the Southern Environmental Law Center are also parties to this litigation. North Carolina General Assembly Session Law 2014-122, the Coal Ash Management Act (LAMA) of 2014, required the owner of coal combustion waste surface impoundments to conduct groundwater monitoring, assessment and remedial activities at coal ash basins across the state, as necessary. The owner of the coal ash surface impoundments was required to submit a Groundwater Assessment Plan (GAP) to NCDEQ by December 31, 2014. Comprehensive Site Assessment (CSA) reports that reported the results of site characterization activities were required to be submitted within 180 days of approval of the GAP. Information developed under the CSA provided the data to be used to prepare Corrective Action Plans (CAP) that were to be submitted to NCDEQ within 90 days of submittal of the CSA. An agreement between Duke Energy and NCDEQ resulted in breaking the CAP into Parts I and 2. As of this date only the CAP Part I has been produced for the Roxboro site. Further, CAMA specifies that any impoundments classified by NCDEQ as high -risk be closed no later than December 31, 2019 by dewatering the waste and either, a) excavating the ash and converting the impoundment to an industrial landfill, or b) excavating and transporting the waste off - site for disposal in an appropriately licensed landfill. Intermediate -risk impoundments are required to be closed similarly to high -risk impoundments, but under a relaxed closure deadline of December 31, 2024. Impoundments classified as low -risk by NCDEQ must be closed by December 31, 2029 either similarly to the high and intermediate -risk sites, or by dewatering to the extent practicable and capping the waste in place. In January 2016 the NCDEQ issued Draft Proposed Risk Classifications (NCDEQ, 2016) for 10 ash impoundment sites, including Roxboro. NCDEQ assigned separate proposed risk classifications for the West, East, and Unnamed Eastern Extension ash ponds. The East Ash Basin (EAB) was rated low to intermediate risk and the West Ash Basin (WAB) was rated low risk, thus allowing for closure of these impoundments by capping waste in place. The Unnamed Eastern Extension (UEE) ' Synterra, 2015a 2 GEO-HYDRO, INC impoundment was rated intermediate risk pending further assessment. On behalf of the Southern Environmental Law Center, I have reviewed the Groundwater Assessment Plan (SynTerra, 2014), Comprehensive Site Assessment (SynTerra, 2015a), the Corrective Action Plan Part 1 (SynTerra, 2015b), the Draft Proposed Risk Classifications (NCDEQ, 2016), and three National Pollutant Discharge Elimination System (NPDES) discharge monitoring reports (DMR's) for Roxboro (Duke Energy, 2014). This report details my opinions regarding: the source of groundwater and surface water pollution at Roxboro, potential remedies for that pollution discussed in the Corrective Action Plan, and the proposed risk classification for the Roxboro site. GEO-HYDRO, INC 3. Qualifications The opinions expressed in this document have been formulated based upon my formal education in geology and over thirty-five years of experience on a wide range of environmental characterization and remediation sites. My education includes B.S. and M.S. degrees in geology from Northern Illinois University and the University of Illinois at Chicago, respectively. I am a registered Professional Geologist (PG) in Kansas, Nebraska, Indiana, and Wisconsin, a Certified Professional Geologist by the American Institute of Professional Geologists, and am currently serving as Past President of the Colorado Ground Water Association. My entire professional career has been focused on regulatory, site characterization, and remediation issues related to waste handling and disposal practices and facilities. I have worked on contaminated sites in over 35 states and the Caribbean. My site characterization and remediation experience includes activities at sites located in a full range of geologic conditions, involving soil and groundwater contamination in both unconsolidated and consolidated geologic media, and a wide range of contaminants. I have served in various technical and managerial roles in conducting all aspects of site characterization and remediation including definition of the nature and extent of contamination, directing human health and ecological risk assessments, conducting feasibility studies for selection of appropriate remedies to meet remediation goals, and implementing remedial strategies. For the last ten years much of my consulting activity has been related to groundwater contamination and permitting issues at coal ash storage and disposal sites. 2 GEO-HYDRO, INC 4. Site Background The Roxboro plant is a coal-fired electricity -generating facility located near Semora, in Person County North Carolina. Hyco Reservoir borders the Roxboro plant to the north and west. Coal ash generated at the plant has been sluiced to the ash basins and hauled to landfill overlying the ash basins since operations commenced in 1966. The EAB was constructed in 1966 by constructing an earthen dam across two unnamed creeks located southeast of the power station (Figure 1). An unlined landfill was constructed over the top of the sluiced ash in the EAB in the late 1980s and a lined landfill was constructed over the unlined landfill in 20042. The ground surface elevation below the EAB dam was reported to be between 390 and 400 feet mean sea level (msl) 3. Groundwater elevations in EAB monitoring wells are reported to be between 464 and 469 ft ms14. The difference between the reported ash basin groundwater elevations and the natural ground surface elevations underlying the EAB indicates that from 64 to 79 feet of saturated coal ash is present within the EAB. The WAB was constructed in 1973 by installing a dam across Sargents Creek, located south of the power station. Coal combustion waste was historically sluiced into the WAB. A Flue Gas Desulfurization (FGD) System, including a lined gypsum settling pond was constructed over a portion of the WAB. The WAB currently remains in operation, receiving sluiced bottom ash from the power station and surface waters discharged from the EAB and overlying lined landfill. The ground surface elevation along the buried Sargents Creek was reported to be between 390 and 410 feet msl prior to construction of the WAB 5 Groundwater elevations in WAB monitoring wells are reported to be between 448 and 463 ft ms16. The difference between the reported ash basin groundwater elevations and the natural ground surface elevations underlying the basin indicates that from 38 to 73 feet of saturated coal ash is present within the WAB. The CSA describes three natural hydrogeologic units or zones of groundwater flow at the Roxboro Plant. Coal ash is considered as its own hydrogeologic unit that is localized to the ash basins. The zone closest to the surface is the shallow or surficial flow zone encompassing saturated conditions, where present, in the saprolite and alluvium beneath the Site. A transition zone is encountered below the shallow zone and is characterized primarily by partially weathered rock of variable thickness. The bedrock flow zone occurs below the transition zone and is characterized by the storage and 2 SynTerra, 2015b, p. 1-2. 3 SynTerra, 2015b, Appendix E, p.3. 4 SynTerra, 2015a, Figure 6-5. 5 SynTerra, 2015b, Appendix E, p.4. 6 SynTerra, 2015a, Figure 6-5. 5 GEO-HYDRO, INC transmission of groundwater in water -bearing fractures. Due to its limited occurrence and extent, the shallow zone is considered part of the transition zone. Where present, groundwater exists under unconfined conditions in each of the hydrogeologic units. The surficial/transition zone and bedrock aquifers are interconnected. On a regional scale groundwater appears to flow from highland areas in the south and southeast, to the northwest toward Hyco Lake. On a local scale groundwater flow directions are poorly defined. Large areas of the Bedrock Water Level Map included with both the CSA and CAP (Figure 2) show neither groundwater elevation data nor contours. Due to the scarcity of head data the description of the groundwater flow system included in the Groundwater Modeling Reports describes groundwater flow in terms of inferred flows. The groundwater flow system beneath the eastern lobe of the EAB is inferred to receive recharge from uplands to the south and east9, and discharge from the eastern lobe by flowing toward the water intake canal, or northeast to a stream that drains the lake (now identified as the unnamed eastern extension) that flows along the eastern side of the EAB and discharges into the water intake canal10. Groundwater flow into the western lobe of the EAB is inferred to occur from the west, south and east' 1. Groundwater discharges from the western lobe of the EAB are inferred to occur to the north toward the plant. Further, the modeling report infers that groundwater beneath the EAB flows toward discharge areas in wetlands and/or ponds located north of the EAB dam. Groundwater flow into the WAB is inferred to flow into the basin from upland areas to the east. Groundwater appears to discharge from the WAB to the north, west and south. Groundwater is inferred to discharge from the WAB by flow to the north through and around the dam, through and beneath the dam on the south end of the WAB, and to discharge into the canal located west of the WAB. Surface waters from the EAB, including groundwater that has discharged to surface water, are routed to the west where it enters the northern end of the WAB. Sluice water used to transport bottom ash to the WAB also discharges into the northern end of the WAB. Surface water from these sources, along with precipitation and groundwater that discharges from the WAB, discharges through the filter dam at the south end of the WAB and into the discharge canal. The discharge canal wraps around the west side of the WAB, ultimately discharging into Hyco Lake. The CAP indicates12 that seeps and surface 7 SynTerra, 2015a, p.26. 8 SynTerra, 2015b, Appendix E 9 The discussion of groundwater flow included in Appendix E (p. 4) erroneously indicates that flow toward the EAB is from uplands to the north and west. Examination of head distribution maps included with the modeling report make it clear that this statement in the text is in error. 10 SynTerra, 2015b, Appendix E, Section 2.2. 11 The Groundwater Modeling Report actually says recharge is from the north rather than the south. It appears that this was a mistake as the limited groundwater head data shows higher heads located south of the west lobe. 12 SynTerra, 2015b, Section 2.2.3. M GEO-HYDRO, INC water drain into NPDES-permitted surface water bodies, but fails to recognize that the parameters required for testing under the NPDES permit are not those that are elevated by coal ash impacts. Data collected during the CSA show that groundwater is impacted by the ash basins with boron, strontium, sulfate, total dissolved solids (TDS) and to a lesser extent, cobalt, iron, manganese, and vanadium.13 The CSA also determined that Hyco Lake and the plants cooling water intake and discharge canals are the primary receptors of impacted groundwater and seeps, and that groundwater flow direction data and surface water data indicate that constituents of interest are migrating to the reservoir14 Considering the various sources of water that is transferred from the WAB to Hyco Lake through the discharge canal, it is very likely that the water contains high concentrations of ash -related constituents. Unfortunately, no samples of discharge canal water were collected during the CSA. The CSA and CAP each refer to surface water monitoring conducted under NPDES Permit NC0003425 as if that monitoring augments the CSA surface water characterization. Review of three 2014 Discharge Monitoring Reports 15 (DMRs) for the Roxboro site showed that NPDES surface water monitoring requirements do not include the most common analytical parameters that are found in ash impacted waters. This means that a major discharge of likely ash -impacted water from the Roxboro site into Hyco Lake was not sampled as part of the CSA and is not being appropriately monitored under NPDES requirements. The groundwater flow and transport model of the site was constructed and used in the CAP to evaluate groundwater flow and investigate three remedial scenarios. The scenarios investigated included the No Action scenario, a Capping Ash in Place scenario, and a Complete Ash Removal scenario. The model was used to predict contaminant distributions for the next 5, 15 and 30 years, under each scenario. The No Action scenario 16 relies on natural attenuation processes to reduce contaminant concentrations over time. The ash basin remains in place without modification and "the assumption is made that current recharge and contaminant loading rates from the ash to the underlying formations are held constant". "The flow system is assumed to be at steady state with respect to the conditions in 2015." "Concentrations in the ash were held constant at the measured concentrations." Using these assumptions the model predicts that the boron plumes will continue to expand laterally and downward, and increase in concentration over time. The predicted increases in plume size are predicted to be from on the order of few hundred feet to very small. This result is likely due to constraints on plume size 13 SynTerra, 2015b, p. 3-8 14 SynTerra, 2015a, p.114 15 Duke Energy, 2014 16 The entire description of this scenario is presented in the CAP, Appendix E, Section 6.1. 7 GEO-HYDRO, INC related to known hydrologic boundaries as were described above. Once a plume reaches a hydrologic boundary the constituents migrating with groundwater are transferred to the surface water system and the groundwater plume does not continue to grow in size though contaminants continue to migrate with surface water. The Capping Ash in Place scenario17 involves placing a low permeability liner over the ash basin to prevent infiltration. The description of this scenario assumes that there is no recharge within the basin and that contaminant concentrations in the ash were allowed to vary (even though concentrations were fixed in the No Action scenario). Results of this model predict that zones of boron concentration increase in size and concentration relative to 2015 conditions, but the magnitude of the increases are less that those calculated under the No Action scenario. Concerns with the Capping Ash Basin scenario include the assumption of no recharge within the basin and changing the way that contaminant concentrations in the source material are handled. The hydrogeology of the Roxboro impoundments (see description of groundwater flow above) includes recharge into the basins from higher elevation areas to the south and east. Capping of the ash in the basin will not control influx of groundwater from upland areas. Discharges of groundwater into the ash basins are likely significant as groundwater discharges into the basin were sufficient to maintain streams prior to their being buried under coal waste. The concentration of contaminants in the ash were held constant in the No Action simulation but were allowed to vary in the Capping Ash in Place scenario. This change in assumptions allowed the concentration in the ash to decrease more rapidly in the Capping Ash in Place scenario than in the No Action simulation. The rationale for changing the method of handling source concentrations between simulations was not discussed. It is unclear if the noted reduction in plume size and concentration is a result of cap installation, or if it is an artifact of the change in assumptions. The Complete Ash Removal18 scenario represents complete removal of the ash by inactivating the upper four model layers, adding drain cells to simulate drainages, and setting recharge within the ash basin to ambient levels. The Complete Ash Removal scenario predicts the largest reduction in ash - related contaminant concentrations of any of the tested scenarios. 17 The entire description of this scenario is presented in the CAP, Appendix E, Section 6.2 18 The entire description of this scenario is presented in the CAP, Appendix E, Section 6.3 N. GEO-HYDRO, INC 5. Opinion 1: Coal Ash Stored in the Roxboro Ash Basins is the Source of Contamination Detected in Groundwater Coal ash is the source of contaminants detected in groundwater at concentrations above applicable standards in the vicinity and downgradient of the ash basin. Data collected during the CSA show that groundwater is impacted by the ash basins with boron, strontium, sulfate, TDS and to a lesser extent, cobalt, iron, manganese, and vanadium.19 The lateral extent of groundwater impacts outside of the ash basins is limited by the presence of water local discharge areas. The contaminated pore water migrates out of the ash basins and either directly into surface water, or into groundwater that subsequently discharges to surface water, and eventually into Hyco Lake. This interpretation is consistent with the CSA which states that: Hydrologic boundaries are present downgradient of the ash basins in the form of the intake canal, the discharge canal and the cooling reservoir which discharges to Hyco Lake. When the CCR constituents reach these hydrologic boundaries, they are removed from the groundwater system, and they enter the surface water system. At the Site, boron is the primary constituent that is migrating from the ash basins. 20 19 SynTerra, 2015b, p. 3-8 20 SynTerra 2015b, p.3-8 0 GEO-HYDRO, INC 6. Opinion 2: Capping Coal Ash Located Within the Roxboro Ash Basin Will Not Protect Groundwater Quality Downgradient of the Basins The CAMA process proposed designation of the Roxboro Site as low -risk creates the possibility that Duke could pursue closure of the Roxboro impoundment by capping the disposed ash in place. Capping the waste within the footprint of the ash basin will not be protective of groundwater quality downgradient of the basin. Environmental contaminants contained in coal ash are leached into groundwater when precipitation infiltrates through the waste or, when groundwater flows through waste that has been placed below the water table. In the case of the Roxboro ash basins, both of these processes are currently acting to create the contaminated ash porewater, groundwater, and surface water that discharge into local surface waters and eventually into Hyco Lake. The cap -in -place remedy would likely reduce the amount of water that enters the waste from precipitation. This remedy would however do nothing to reduce the amount of groundwater that flows laterally into the basin from surrounding geologic units, through the capped waste, into downgradient groundwater, and eventually into Hyco Lake. The lined landfill that was constructed over a portion of the EAB should function as a cap over the ash disposed in the unlined landfill and ash basin. The CSA21 indicates that construction of a lined landfill has resulted in decreasing concentrations of iron, manganese and chromium in three monitoring wells (GMW-06, GMW-10 and GMW-11). The available data set does not show a clear pattern of decreasing contaminant concentrations related to construction of the lined landfill. Review of the comprehensive analytical results from Roxboro22 shows that large decreases in several parameters were observed in some monitoring wells during the first few sampling events and prior to construction of the lined landfill. Figures 3 and 4 show graphs of boron, sulfate, selenium and TDS concentrations measured in samples from wells in the immediate vicinity of the lined landfill. Sulfate, TDS, and selenium23 concentrations in some wells were very high initially and show rapid declines in concentration between the initial sampling event in 2002 and 2004 when the lined landfill was constructed. This is an indication that decreased contaminant concentrations in wells since their early sampling events appear to have been due to improper well development or sampling techniques rather than improving water quality resulting from landfill construction. Even if it is assumed that construction of the lined landfill has had a positive effect on groundwater quality, the graphs show that concentrations of ash -related parameters in some monitoring wells has 21 SynTerra, 2015b, p.1-8 22 SynTerra, 2015a, Attachment 3 23 Note that boron was not included in the tested parameters until 2002, so the early concentrations of boron are unknown. 10 GEO-HYDRO, INC remained at or above water quality standards in wells GMW-06, GMW-08 and GMW-11 despite the presence of the lined landfill. In fact, boron, sulfate, and TDS concentrations have been increasing rapidly in monitoring well GMW-8 since 2013. Continued detections of elevated concentrations24 of ash -related contaminants at in groundwater around the lined landfill indicates that ash underlying the lined landfill continues to release contaminants to groundwater, even though most infiltration from above has presumably been eliminated by the landfill liner. This result is to be expected at any location where ash remains submerged below the local water table. Continued generation and downgradient migration of leachate will occur in the Roxboro Ash basins unless all of the ash in the basin is dewatered and remains above the high water table, a scenario that is unlikely to occur at Roxboro. Groundwater modeling performed for the CAP provided no estimation of the amount of saturated ash that would remain at Roxboro should the capping in place remediation scenario be implemented. An estimate of the thickness of the remaining thickness of saturated ash can be obtained by comparing the elevation of the natural ground surface beneath the basins to the groundwater elevation in wells just outside of the basins 25. The ground surface elevation below the EAB dam was reported to be between 390 and 400 feet ms126. Groundwater elevations in EAB monitoring wells located just outside of the basin are reported to be between 462 and 513 ft ms127. The difference between the lowest measured groundwater elevation in wells located just outside the ash basin and the highest natural ground surface elevations underlying the EAB indicates that at least 62 feet of saturated coal should be expected to be present beneath the EAB were the cap in place remediation scenario implemented. The natural ground surface elevation beneath the WAB was reported to be between 390 and 410 feet ms128. Groundwater elevations in WAB monitoring wells located just outside the ash basin are reported to be between 452 and 456 ft ms129. The difference between the lowest measured groundwater elevation in wells located just outside the ash basin and the highest natural ground surface elevations underlying the EAB indicates that at least 42 feet of saturated coal should be expected to be present beneath the EAB were the cap in place remediation scenario implemented. The relative effects of the cap in place and removal of the ash scenarios on groundwater quality were evaluated as part of the groundwater modeling exercise. The modeling report indicates that removal 24 above 2L standards 25 Estimates of the thickness of saturated ash that would likely remain were the capping ash in place scenario implemented are provided since the groundwater modeling report did not provide an estimation. Further modeling, or better model reporting, should be conducted to refine these estimates. 26 SynTerra, 2015b, Appendix E, p.3. 27 SynTerra, 2015a, Figure 6-5. 28 SynTerra, 2015b, Appendix E, p.4. 29 SynTerra, 2015a, Figure 6-5. 11 GEO-HYDRO, INC of the ash reduces the concentration of boron in groundwater more than either the No Action or Capping Ash in Place scenarios. This indicates that removal of the Roxboro coal ash is the most effective option for improving groundwater quality and minimizing future discharges to Hyco Lake. This is as would be expected considering that the cap in place scenario would leave a significant thickness of saturated ash in place that would continue to leach ash constituents into the groundwater far into the future. 12 GEO-HYDRO, INC 7. Opinion 3: Monitored Natural Attenuation Is Not An Acceptable Groundwater Remediation Strategy at Roxboro The CAp30 indicates that Duke may evaluate Monitored Natural attenuation as a potential groundwater remedy for certain area of the Roxboro site. The CAP attempts to make it appear that Monitored Natural Attenuation (MNA) is a viable remedial option for impacted groundwater downgradient of the Roxboro ash basin. From a technical standpoint, MNA remedies typically require: • That there are no current receptors, including surface water or wetland discharges and water supply wells. • That there is sufficient lateral space between the contaminant source and groundwater discharge areas to allow natural attenuation to reduce contaminant concentrations prior to reaching a receptor. • Evidence that the location of the leading edge of the contaminant plumes be stable (not be expanding). • That there is a natural reduction in contaminant concentrations along flow paths. • That there is sufficient space between the contaminant source and groundwater discharge areas to allow a monitoring system to be established, including sentry wells located ahead of the leading edge of the contaminant plume. None of these technical factors for considering MNA as an appropriate remedial strategy at the Roxboro site are met. From a scientific standpoint there is no justification for considering MNA. There are also legal requirements that must be met in North Carolina in order to utilize MNA as a groundwater remedy, including: • NCAC 02L .0106 (1)(1) requires a demonstration that all sources of contamination have been removed or controlled. So far, Duke Energy has not proposed removal of the waste for disposal in a secure location. Hydrogeologic conditions presented in this document shows that some of the ash would remain saturated after capping. Saturated ash will continue to leach metals into groundwater that will flow toward and eventually discharge into Hyco Lake. As a practical matter, in the absence of removal all sources of contamination cannot be controlled • NCAC 02L .0106 (1)(2) requires a demonstration that the contaminant has the capacity to degrade or attenuate under site -specific conditions. Many of the ash -related constituents in groundwater at this site neither degrade nor attenuate. The Geochemical Site Conceptual 30 SynTerra, 2015b, p.5-1 13 GEO-HYDRO, INC Model31 states that boron is an indicator of coal ash impacts to groundwater because it "is essentially inert, has limited potential for sorption and lacks an affinity to form complexes with other ions." The characteristics of the contaminant plumes alone are sufficient to render the Roxboro site ineligible to use MNA as a remediation strategy. 31 SynTerra, 2015b, Section 3.3 14 GEO-HYDRO, INC 8. Opinion 4: Capping Coal Ash Located Within the Roxboro Ash Basin Will Not Be Protective of Surface Water Quality The most problematic issues at the Roxboro plant are related to the interaction of groundwater and surface water bodies on and around the plant site. The CAP indicates in several locations that the lateral extent of groundwater contamination is generally limited to areas beneath or immediately downgradient of the ash basins. These statements would often be interpreted as indicating that contamination has not spread far from the source and the problem should be readily remedied. However, at the Roxboro site the ash basins are bounded by drainage features on around the perimeter of the basins that act as groundwater discharge areas. Ash -impacted groundwater plumes are not restricted to the immediate area of the basins by a lack of migration; their size is restricted only because the contaminated groundwater discharges to surface water features. This is particularly problematic since water quality in the channel that carries most of the discharge from this site has not been characterized. No surface water samples were collected from the outflow channel even though the combined drainage from the East and West Ash Basins are passed through this channel to Hyco Reservoir. In addition, surface water monitoring conducted under NPDES Permit NC0003425 does not include the most common analytical parameters that are found in ash impacted waters. This means that a major discharge of likely ash -impacted water from the Roxboro site into Hyco Lake was not sampled as part of the CSA and is not being appropriately monitored under NPDES requirements. The chemistry and volume of water that flows through canals and into Hyco Lake under current and expected closure conditions must be evaluated to assure that the selected remedy is protective of water quality in Hyco Lake. A cap -in -place remedy would not be protective of surface water quality. While a cap would likely reduce the amount of water that enters the waste from precipitation, this remedy would do nothing to reduce the amount of groundwater that flows laterally into the basin from surrounding geologic units, through the capped waste, into downgradient surface water drainages, and eventually into Hyco Lake. Groundwater would continue to flow into the ash basins from adjacent upland areas. Groundwater that flows through the ash will continue to leach metals from the ash and transport those metals down -gradient before discharging into adjacent surface water features. 15 GEO-HYDRO, INC 9. Opinion 5: Removal of the Coal Ash Will Remove the Source and Reduce the Concentration and Extent of Groundwater Contaminants Removal (excavation) of the coal ash from the Roxboro ash basin is the only remediation scenario that will separate the coal ash source materials from groundwater and eliminate flow of contaminated groundwater and surface water into Hyco Lake. Excavation of the ash will remove the source of groundwater and surface water contaminants, and reduce the concentration and extent of current contaminants. The groundwater flow and transport model of the site was used in the CAP to evaluate groundwater flow and investigate three remedial scenarios. The scenarios investigated included the Existing Conditions scenario, a Capping Ash in Place scenario, and a Removal of Ash scenario. The model was used to predict contaminant distributions for the next 5, 15 and 30 years, under each scenario. The model showed that the Removal of Ash scenario resulted in the largest reduction in ash -related contaminant concentrations of any of the modeled scenarios. 16 GEO-HYDRO, INC 10. Opinion 6: The Coal Combustion Residual Impoundment Risk Classification Proposed by NCDEQ Improperly Minimizes Protection of Environmental Quality A risk ranking process was specified in CAMA to determine the type of closure permitted at each facility. The law specifically requires NCDEQ to classify each impoundment as either high -risk, intermediate -risk, or low -risk, based on consideration, at a minimum, of all of the following criteria. (1) Any hazards to public health, safety, or welfare resulting from the impoundment. (2) The structural condition and hazard potential of the impoundment. (3) The proximity of surface waters to the impoundment and whether any surface waters are contaminated or threatened by contamination as a result of the impoundment. (4) Information concerning the horizontal and vertical extent of soil and groundwater contamination for all contaminants confirmed to be present in groundwater in exceedance of groundwater quality standards and all significant factors affecting contaminant transport. (5) The location and nature of all receptors and significant exposure pathways. (6) The geological and hydrogeological features influencing the movement and chemical and physical character of the contaminants. (7) The amount and characteristics of coal combustion residuals in the impoundment. (8) Whether the impoundment is located within an area subject to a 100-year flood. (9) Any other factor the Department deems relevant to establishment of risk. In order to evaluate each impoundment on the nine criteria the NCDEW established a risk classification group32. The Risk Classification Group was broken into three sub -groups of people based on areas of expertise (Groundwater, Surface Water, and Dam Safety) to develop a set of risk factors to address each of the nine required criteria. Each subgroup reportedly placed a primary emphasis on risk as it relates to the public from a groundwater, surface water, and dam safety perspective and established one key factor that "plays a significant role in assigning an overall classification" for that group. Other factors not identified as Key Factors were supposedly used to "refine the risk classification and address the actual or potential risk to the environment and natural resources." The result of the risk classification methodology utilized by NCDEQ is that environmental and ecologic risks posed by the Roxboro site were not fully considered by NCDEQ when establishing the overall site risk and clean-up priorities. This resulted in the West, East, and Unnamed Eastern Extension ash ponds being assigned Low, Low to Intermediate, and Intermediate risk ratings, 32 NDEQ, 2016, p. 13, Classification Methodology 17 GEO-HYDRO, INC respectively, ratings that essentially ignore the known environmental impacts of the Roxboro ash ponds. For example, Table 1 provides a listing of the groundwater risk classification factors and associated ratings for each ash pond at Roxboro. Ten groundwater risk factors were established and received ratings by NDEQ for each ash pond. Table 1 Groundwater Risk Classifications Groundwater Factors East Ash Pond West Ash Pond Unnamed Eastern Extension Number of downgradient receptors within 1500 feet of compliance boundary that are potentially or currently Low Risk Low Risk Low Risk known to be exposed to impacted water. (Key Factor) Amount of stored CCR reported in an impoundment High Risk High Risk High Risk Depth of CCR with respect to the water table High Risk High Risk High Risk Exceedance of 2L or IMAC standards at or beyond the High Risk High Risk High Risk established CCR compliance boundary Population served by water supply wells within 1,500 feet Low /Intermediate Low /Intermediate Low /Intermediate upgradient or side gradient of the compliance boundary Risk Risk Risk Population served by water supply wells within 1,500 feet Low Risk Low Risk Low Risk downgradient of the compliance boundary Proximity of 2L or IMAC exceedances beyond the High Risk Intermediate Risk High Risk compliance boundary with respect to water supply wells Groundwater emanating from the impoundment exceeds High Risk High Risk High Risk 2L or IMAC and that discharges to a surface water body Ingestion of contaminated soil or fugitive emissions Low Risk Low Risk Low Risk Data Gaps and Uncertainty High Risk High Risk High Risk The West Ash Pond received High or Intermediate ratings for 6 of the 10 groundwater risk classification factors, one factor was rated as Low/Intermediate, and only 3 received ratings of Low Risk. Only 30% of the rated groundwater risk classification factors were rated Low Risk, yet NCDEQ gave the Roxboro West Pond an overall Low Risk rating for groundwater. The East Ash Pond received 6 High Risk ratings, one factor was rated as Low/Intermediate, and only 3 received ratings of Low Risk. High risk rankings were assigned to 60% of the rated groundwater risk classification factors, yet NCDEQ gave the Roxboro East Pond an overall Low to Intermediate Risk rating for groundwater. GEO-HYDRO, INC The Unnamed Eastern Extension received High risk ratings for 6 of the 10 groundwater risk classification factors, one factor was rated Low/Intermediate, and only 3 received ratings of Low Risk. High risk rankings were assigned to 60% of the rated groundwater risk classification factors, yet NCDEQ gave the Roxboro Unnamed Eastern Extension an overall Low Risk Rating for groundwater. Table 2 provides a listing of the surface water risk classification factors and associated ratings for each of the Roxboro ash ponds. A total of eight surface water risk factors were rated by NCDEQ for each pond. The West Pond received High or Intermediate ratings for 6 of the 8 surface water risk classification factors and only 2 received ratings of Low Risk. Only 25% of the rated surface water risk classification factors were rated Low Risk, yet NCDEQ gave the Roxboro West Pond an overall Low Risk rating for surface water. Table 2 Surface Water Risk Factors Unnamed Eastern Surface Water Factors East Ash Pond West Ash Pond Extension Landscape Position and Floodplain (Key Factor) Low Risk Low Risk Low Risk NPDES Wastewater and Ash Disposal Methods Low/ Intermediate High Risk Intermediate / High Risk Risk Impoundments Footprint Siting in Natural Drainage High Risk High Risk High Risk Way or Stream Potential to Impact Surface Water Based on Total High Risk High Risk Low Risk Ash Amount at Facility Potential to Impact Surface Water Based on Dilution High Risk High Risk High Risk Development Density of Single -Family Residences Intermediate Risk Intermediate Risk Intermediate Risk along Lake/Reservoir Shoreline Classification of the Receiving Waters Intermediate Risk Intermediate Risk Intermediate Risk Proximity to Water Supply Intake Low Risk Low Risk Low Risk The East Pond received High or Intermediate ratings for 5 of the 8 surface water risk classification factors, one factor was rated as Low/Intermediate, and only 2 received ratings of Low Risk. Only 25% of the rated groundwater risk classification factors were rated Low Risk, yet NCDEQ gave the Roxboro East Pond an overall Low Risk rating for surface water. The Unnamed East Extension Pond received High or Intermediate ratings for 5 of the 8 surface water risk classification factors and only 3 received ratings of Low Risk. Only 37.5% of the rated 19 GEO-HYDRO, INC surface water risk classification factors were rated Low Risk, yet NCDEQ gave the Unnamed Eastern Extension pond an overall Low Risk rating for surface water. The preceding analysis uses the risk ratings applied by NCDEQ with no evaluation or judgment about whether they were or were not appropriately applied. The risk ratings given to the Roxboro ash basins demonstrate that protection of environmental and natural resources is not being treated as priority issues by the North Carolina agency entrusted with the responsibility to do just that. The approach utilized by NCDEQ effectively ignores impacts to the natural environmental and natural resources, and even ignores future human users of the groundwater and surface water resources. It appears that in the view of NCDEQ the only way that a site can be rated as Intermediate or High Risk is if a facility is located within a 100-year floodplain or if 11 or more people within 1,500 feet of the compliance boundary are potentially or currently known to be exposed to ash -impacted groundwater33. It is hard to imagine that exposed persons 1 through 10 would agree with this rating scheme. 33 NCDEQ, 2016, page 15, Key Factors 20 GEO-HYDRO, INC References Duke Energy, 2014, Discharge Monitoring Reports for September, October, and November 2014. National Pollutant Discharge Elimination System, Permit NC0003425. NCDEQ, 2016, Coal Combustion Residual Impoundment Risk Classifications, January 2016. SynTerra, 2014, Groundwater Assessment Work Plan for Roxboro Steam Electric Plant, Semora, NC, September 2014. SynTerra, 2015a, Comprehensive Site Assessment Report, Roxboro Steam Electric Plant, Semora, NC, September 2015. SynTerra , 2015b, Corrective Action Plan, Part 1, Roxboro Steam Electric Plant, Semora, NC, December 2015. United States Geological Survey, Olive Hill, N.C., 7.5 Minute Topographic Map, 1968, revised 1994. 21 GEO-HYDRO, INC Figures r ' r:— f 60 .x ti i a -y M _ ZZ - --.Jh _ 1�'�il �. tl -: -• e'. Ir`� `+li:{ ;IM1 `<ti.tlhJl t=~�ik1, e' t' ^. I� - ti,�4 1 '� .'+r4'c�bdlant# Bch Image taken from USGS Olive Hill, N.C. 1968 Photorevised 1994 GEO-HYDRO, INC Consulting in Geology and Hydrogeology f' Figure l Ash Basin Locations and Site Topography Roxboro Steam Electric Plant 1- ` � WWI Ln a _ —" <°� 4.MFFN4u[Y WIfFPf 85 `L .. E'• ' fit. �,� carnrrce�ekN£tildu.4 F r I 1 I A I + 1 1f l� j n s�"Terra DUNE:. V ENERGY j PROGRESS *'e � � <..eeoaueiFuw sacrnc Pe.wlr • nu»wxtrna JUME MS GEO-HYDRO, INC Consulting in Geology and Hydrogeology Image taken from Figure 2 SynTerra, 2015b Bedrock Water Level Map Figure 3-1 1 Roxboro Steam Electric Plant Boron Concentration May 2009 - April 2015 4500 4000 3500 3000 2500 rn 2000 0 o 0° 1500 1000 500 0 t°N -S&Nb, 1a k,�0^� Ob�O�'� 1,��0�� Op�Oej\ ^,��� Op�O ^,���. Sample Date Sulfate Concentration December 2002 -April 2015 1800 1600 1400 1200 1000 800 600 400 200 0 OO`L °p9 OOA °°6 °06 0Ik 000 °09 O^O O^4 0KI, ON, O^0. rye^9�0- ^�,�'1,��'1�ry 1�^1 �.\N`h\0"O\0"0" Sample Date GEO-HYDRO, INC Consulting in Geology and Hydrogeology —6 GMW-06 t GMW-07 GMW-08 --X—GMW-09 err GMW-10 +GMW-11 2L Standard (700 ug/1) Data From: SynTerra, 2015a, Attachment 3 GMW-06 f-GMW -07 GMW-08 X GMW-09 —X GMW-10 —41 W-11 2L Standard (250 mg/I) Data From: SynTerra, 2015a, Attachment 3 Figure 3 Boron and Sulfate Concentrations Lined Landfill area Monitoring Wells Roxboro Steam Electric Plant Selenium Concentration December 2002 - April 2015 400 350 300 250 rn E 200 y 150 100 50 0 \ti O19 O°� OOb 0�\19 \ti Sample Date TDS Concentration December 2002 - April 2015 2500 2000 £ 1500 500 0 o°o o°� o°�' 0°6 06 o°b o o°° o^d^ oN oN5 o� AV Sample Date o.�`y O^3 O1b GEO-HYDRO, INC Consulting in Geology and Hydrogeology $GMW-06 tGMW-07 GMW-08 GMW-09 --*— GMW-10 --0--G MW-11 2L Standard (20 ug/I) Data From: Syn Terra, 2015a, Attachment 3 —4-- GMW-06 t G M W-07 GMW-08 GMW-09 --)K—GMW-10 —e GMW-11 2L Standard (500 mg/I) Data From: S ynTe rra, 2015a, Attachment 3 Figure 4 Selenium and TDS Concentrations Lined Landfill area Monitoring Wells Roxboro Steam Electric Plant Attachment 13 Duke Energy Memorandum Regarding CAMA Requirements Memorandum Regarding LAMA Requirements I. Introduction The purpose of this document is (1) to establish Duke Energy's compliance with the groundwater assessment and corrective action requirements of the North Carolina Coal Ash Management Act ("CAMA"), and (2) to identify information relevant to the Department's assessment and prioritization of coal ash surface impoundments for closure under CAMA. As explained further below, Duke Energy has submitted all groundwater information required by CAMA to date and will continue to submit information required by the Department pursuant to CAMA authority. As a result, there is no basis for any finding by the Department that Duke Energy has failed to comply with CAMA. Further, the information submitted by Duke Energy, supplemented by other available, relevant information, is sufficient for the Department to make an evidence -based assessment of the factors that CAMA requires for impoundment prioritization; as a result, it would be legal error for the Department to prioritize the surface impoundments without full consideration of, and findings of fact on, each of the factors. II. Compliance with Groundwater Assessment and Corrective Action CAMA's groundwater assessment and corrective action provisions are located at North Carolina General Statutes § 130A-309.211. Duke Energy has complied with subsections (a) and (b) as follows: A. Subsection (a) - Groundwater Assessment Subsection (a) requires Duke Energy to, at each of its surface impoundments, do three things: (1) submit a proposed Groundwater Assessment Plan for approval by the Department, (2) begin implementing a Groundwater Assessment Plan approved by the Department, and (3) submit a Groundwater Assessment Report describing all exceedances of groundwater quality standards associated with the impoundment. Duke Energy has met each of these requirements. As you are aware, Duke Energy submitted draft Groundwater Assessment Plans for all of its surface impoundments in North Carolina on September 26, 2014. The Department provided comments on November 5, 2014, and Duke Energy submitted revised Groundwater Assessment Plans on December 30, 2014. The Department conditionally approved the Plans on various dates earlier this year, NCDENRO194488 and Duke Energy began implementing each plan within 10 days of approval. Groundwater Assessment Reports describing all exceedances of groundwater quality standards associated with the various surface impoundments were submitted to the Department -in August and September. The Department's approval of the plans reflected a determination that the {Mans met CAMA requirements. Duke Energy's implementation of the plans, including the conditions of approval, under the Department's close oversight, further supports a conclusion that the requirements of Subsection (a) were met. According to the plain language of Subsection (a), Duke Energy's compliance with the requirements does not depend on the substantive content of the Groundwater Assessment Reports. Duke Energy was required to make plans to assess various groundwater factors, which it did. The Department approved the plans, thereby determining that the Plans would assess those groundwater factors. Duke Energy diligently implemented the Plans. There is no further requirement in Subsection (a), or anywhere else in CAMA, that the results of the groundwater assessments definitively establish or disprove the existence of any condition at a site. In fact, CAMA anticipates that groundwater assessments performed under Subsection (a) may not supply all the information desired by the Department —Subsection (b)(a) requires Duke Energy to include in a proposed Groundwater Corrective Action Plan °[ajny other information related to groundwater assessment required by the Department." Had the General Assembly anticipated that Groundwater Assessment Reports would be definitive documents, there would have been no need to authorize the Department to request additional information in the proposed Corrective Action Plans. B. Subsection (b) - Corrective Action Similarly, Subsection (b) requires Duke Energy to do two things: (1) submit a proposed Groundwater Corrective Action Plan, and (2) begin implementing the Groundwater Corrective Action Plan once it has been approved by the Department. The deadline for completion of the first requirement has not yet passed. The Department and Duke Energy agreed that the corrective action plans would be submitted in two parts, and Duke Energy has submitted the first part for all fourteen sites with surface impoundments. The deadline for submission of the second part has not yet arrived. 2 NCDENRO194489 The Corrective Action Plans contain each of the elements from Subsection (b)(1) that were to be included in the first part submittals. The Corrective Action Plans were prepared by qualified professionals and contain work performed to the industry standard. Additional information will be submitted in the part two submittals. It is premature to evaluate Duke Energy's compliance with this requirement until the submittals are complete. III. Prioritization of Surface impoundments Under CAMA, the Department is charged with developing proposed classifications of surface impoundments according to the procedures in North Carolina General Statutes § 130A-309.213. The prioritization must be based on "a site's risks to public health, safety, and welfare; the environment; and natural resources." N.C. Gen. Stat. § 130A-309.213(a). In assessing the risks, the Department must evaluate groundwater data submitted under § 130A-309.211, discharge information submitted under § 130A-309.212, and any other information deemed relevant. Further, the Department must consider all of the following: oo Any hazards to public health, safety, or welfare resulting from the impoundment. oo The structural condition and hazard potential of the impoundment. oo The proximity of surface waters to the impoundment and whether any surface waters are contaminated or threatened by contamination as a result of the impoundment. ao Information concerning the horizontal and vertical extent of soil and groundwater contamination for all contaminants confirmed to be present in groundwater in exceedance of groundwater quality standards and all significant factors affecting contaminant transport. 0o The location and nature of all receptors and significant exposure pathways. ao The geological and hydrogeological features influencing the movement and chemical and physical character of the contaminants. co The amount and characteristics of coal combustion residuals in the impoundment. co Whether the impoundment is located within an area subject to a 100-year flood. ao Any other factor the Department deems relevant to establishment of risk. The Department must issue written declarations, including findings of fact, documenting a proposed risk classification. NCDENRO194490 This section requires the Department to make decisions based on the available evidence regarding each of the listed factors.' It would not be consistent with this requirement for the Department to make a classification decision based solely on one factor and disregard valid information about the others. Further, the section anticipates that the Department will make decisions before complete information about a site is available. For example, it does not require the Department to completely know the vertical and horizontal extent of soil and groundwater contamination for each site; rather it requires that the Department consider information concerning the vertical and horizontal extent. Similarly, it does not require the Department to know all factors that might conceivably affect contaminant transport or all conceivable exposure pathways; it requires the consideration only of significant factors affecting contaminant transport and significant exposure pathways. Additional support for this conclusion is found in the fact that this section defines an iterative process by which evolving data, review, and commentary are used to classify surface impoundments as low, intermediate, or high risk. This iterative process begins with a provisionally proposed classification by the Department by December 31, 2015 and extends for a minimum (no maximum) of six months while feedback and additional data are received and evaluated by the Department and the Coal Ash Management Commission. Taken as a whole, this section requires the Department to make evidence -based decisions using the best available information in the record. Duke Energy has submitted substantial evidence into the administrative record. Any classification should be based on this evidence, with the understanding that additional information requests may be relevant to the degree of certainty in the classification but do not undermine the validity of the classification. IV. Conclusion The Groundwater Assessment Plans, Groundwater Assessment Reports, and Groundwater Corrective Action Plans submitted by Duke Energy to the Department meet the requirements of CAMA and provide vast data, analysis, and findings. Chief among the findings is a determination by licensed ' Aside from CAMA, the North Carolina Administrative Procedure Act requires that agency decisions be supported "by substantial evidence ... in view of the entire record as submitted." G.S. 150B-51(b)(5). 4 NCDENRO194491 environmental geologists that none of the sites pose an imminent hazard to human health or the environment. Duke Energy is committed to meeting the Department's expectations by providing additional data, fully leveraging the time provided by CAMA's iterative process to ensure final classifications reflect the best science and engineering. Nonetheless, Duke Energy has compiled with all of CAMA's requirements to date, and available information is sufficient for the Department to develop classifications as required by CAMA. 5 NCDENRO194492 Attachment 14 DEQ Sutton Ash Pond Ratings Detailed 3/11/14 ASH POND RATING FORM FACILITY NAME: Allen REGION: Mooresville NPDES PERMIT NO.: NC0004979 COUNTY: Gaston Instructions: Rate each facility using the potential rating in the left column and the descriptions in the middle column. A score of 1 indicates the best case whereas a score of 5 indicates the worst case. For the final rating column, put the number next to the description that best matches the facility in consideration. If you believe a different rating is warranted for any category (other than what is listed), then justify alternate rating in the comment section. Section 1— Water Quality Considerations 1. Groundwater Standards Potential Rating Rating Description Final Rating 1 An exceedance of pH, iron or manganese 2 Exceedance of chloride, nitrate, sulfate, or TDS 3 Exceedance of aluminum, barium, copper, nickel or zinc 3 4 Exceedance of boron, cadmium, chromium, selenium, or antimony 5 Exceedance of arsenic, lead, mercury, or thallium Comments: Allen groundwater exceedances consist of pH, Fe, Mn, and Ni. 2. Drinking Water Intakes Potential Rating Rating Description Final Rating 0 No intake 2 Greater than 50 miles downstream 3 Greater than 20 miles, but less than orequal to 50 miles downstream 4 Greater than 10 miles, but less than orequal to 20 miles downstream 4 5 Less than orequal to 10 miles downstream Comments: The NC/SC state line is —3 miles downstream from Allen. The Rock Hill, SC, intake is located on the Catawba River/Lake Wylie —16 miles downstream. Additional SC communities with intakes located along the Catawba are expected at greater distances. March 11, 2014 Ash Pond Rating Form Page 1 of 6 4. Classification Downstream and Discharge Points (use worst case scenario) Potential Ratfnt; Description b Final. Rating Rating 1 Class C 4 Class B 4 5 High Quality Waters, Outstanding Resource Waters, Threatened or Endangered Species present Comments: Classification in the immediate vicinity of Buck is WS-V. Downstream of Buck, the classification changes to WS-IV, B in the lower portion of High Rock Lake. 5. Distance of Water Supply Wells from the Compliance Boundary (CB) Potential Rating Description Final Rating Rating i Wells greater than 1/2 mile (2,640 feet) of the CB 2 Wells within 2,000 to 2,640 feet of CB 3 Wells within 1,500 to 2,000 feet of CB 4 Wells within 1,000 to 1,500 feet of CB 5 Wells within 1,000 feet of CB 5 Comments: The area in the vicinity of the plant is served by wells and a formal well survey has not been conducted. The closest private wells are along Dukeville and Leonard Roads and a couple of small spur roads off of these. The closest private wells are roughly 200 ft from the CB and there may be roughly 50 private water supply wells within 1500 ft. Additionally, there is a public water supply well for Duke employees on site at Buck (0180647) and two PWS well systems at nearby churches (Trading Ford Baptist 0180594, Yadkin Grove Missionary Baptist 0180633). These PWS systems are roughly 800-1300 ft from the CB. Note: Hydrogeotogic considerations -- Use to adjust rating due to unique characteristics that should be considered such as wells upgradient, cross gradient, etc. March 11, 2014 Ash Pond Rating Form Page 2 of 5 ASH POND RATING FORM FACILITY NAME: Allen REGION: Mooresville NPDES PERMIT NO.: NC0004979 COUNTY: Gaston Instructions: Rate each facility using the potential rating in the left column and the descriptions in the middle column. A score of 1 indicates the best case whereas a score of 5 indicates the worst case. For the final rating column, put the number next to the description that best matches the facility in consideration. If you believe a different rating is warranted for any category (other than what is listed), then justify alternate rating in the comment section. Section 1— Water Quality Considerations 1. Groundwater Standards Potential Rating Rating Description Final Rating 1 An exceedance of pH, iron or manganese 2 Exceedance of chloride, nitrate, sulfate, or TDS 3 Exceedance of aluminum, barium, copper, nickel or zinc 3 4 Exceedance of boron, cadmium, chromium, selenium, or antimony 5 Exceedance of arsenic, lead, mercury, or thallium Comments: Allen groundwater exceedances consist of pH, Fe, Mn, and Ni. 2. Drinking Water Intakes Potential Rating Rating Description Final Rating 0 No intake 2 Greater than 50 miles downstream 3 Greater than 20 miles, but less than orequal to 50 miles downstream 4 Greater than 10 miles, but less than orequal to 20 miles downstream 4 5 Less than orequal to 10 miles downstream Comments: The NC/SC state line is —3 miles downstream from Allen. The Rock Hill, SC, intake is located on the Catawba River/Lake Wylie —16 miles downstream. Additional SC communities with intakes located along the Catawba are expected at greater distances. March 11, 2014 Ash Pond Rating Form Page 1 of 6 3. Total Population Served by Intakes Potential Rating Rating Description Final Rating 1 1 - 500 served 2 501 - 3,300 served 3 3,301 - 10,000 served 4 10,001 - 100,000 served 4 5 > 100,000 served Comments: Per Rock Hill's website, they serve —96,000 people including the communities of Fort Mill, Tega Cay, River Hills and the Catawba Indian Nation. 4. Classification Downstream and Discharge Points (use worst case scenario) Potential Rating Description Final Rating Rating 1 Class C 4 Class B 4 5 High Quality Waters, Outstanding Resource Waters, Threatened or Endangered Species present Comments: Most of Allen fronts the Catawba River/Lake Wylie, which is classified as WS-V, B. The primary thermal discharge and a number of stormwater outfalls discharge to the South Fork Catawba River/Lake Wylie, which is classified as WS-V. March 11, 2014 Ash Pond Rating Form Page 2 of 6 5. Distance of Water Supply Wells from the Compliance Boundary (CB) Potential Rating Rating Description Final Rating 1 Wells greater than 1/2 mile 2,640 feet of the CB 2 Wells within 2,000 to 2,640 feet of CB 3 Wells within 1,500 to 2,000 feet of CB 4 Wells within 1,000 to 1,500 feet of CB 5 Wells within 1,000 feet of CB 5 Comments: No formal well survey has been conducted near Allen, however DWR-WQROS has sampled 3 private water supply wells just W of the ash ponds and near monitoring well AB-141), which has shown the only Ni exceedances. The sampled supply wells did not have exceedances. The neighborhood including those private wells is also served by several dozen (40-50?) private wells and, though presumably hydraulically upgradient of the ash ponds, these supply wells are same side of a hydrologic divide as the ponds. This neighborhood's private wells are approximately located within a range of about 75 feet to 1200 feet from the compliance boundary. Though public water is available along South Point Road/NC273, and newer subdivisions are typically connected to it, there are also older homes served by wells along the road and additional private wells in a neighborhood to the S of the plant at a slightly greater distance away. There are several public water supply systems with wells in relative proximity. South Point Landing (0136192) is —1000 ft from the CB. Heather Glen/Highland S/D (0136255) has two supply wells located —1500 ft from the CB. The River Lakes S/D (0236011) is located —2900 ft from the CB. There are additional PWS well systems north of the facility at greater distances. Note: Hydrogeologic considerations -- Use to adjust rating due to unique characteristics that should be considered such as wells upgradient, cross gradient, etc. 6. Population Served by Water Supply Wells (referenced above) Potential Rating Rating Description Final Rating 1 0 population 2 0 - 25 people 3 26 - 100 people 4 101 - 200 people 5 > 200 people 5 Comments: Without a well survey, the population served by private wells was estimated in the following manner: a very rough approximation of 75 wells within 1500 feet and 3 people per well results in 225 people served. This is an estimate and the actual number could vary significantly from that value. The population served by the PWS systems mentioned in #2 totals 226. March 11, 2014 Ash Pond Rating Form Page 3 of 6 Section 2 — Dam Safety Considerations 7. Hazard Classification Potential Rating Rating Description Final Rating 1 Low hazard - Small size 2 Low Hazard - Large size 3 Intermediate Hazard 4 High Hazard - Environmental Concerns 4 5 1 High Hazard - Loss of Life Comments: 8. Proximity to Waters of the State Potential Rating Rating Description Final Rating I Located within/above a larger ash reservoir with large amount of available storage 3 Potential coal ash migration constrained by physical barrier 5 Directly adjacent 5 Comments: 9. State of Structural Stability & Maintenance (use historical worst case scenario) Potential Rating Rating Description Final Rating 1 Notice of Inspection OI with no recommendations 2 NOI with maintenance recommendations 3 Notice of Deficiency OD 3 4 Dam Safety Order DSO 5 Enforcement action required Comments: March 11, 2014 Ash Pond Rating Form Page 4 of 6 10. Volume of Facility Potential Rating Rating Description Final Rating 1 < 300 acre-feet 2 300 to 1,500 acre-feet 3 1,500 to 3,000 acre-feet 4 3,000 to 9,000 acre-feet 4 5 > 9,000 Acre-feet Comments: 11. Free Water Content Potential Rating Rating Description Final Rating 1 D - heavy natural vegetation and tree growth 2 D - no standing water, sparse tree growth 3 25% of reservoir area water covered 4 25% to 75% of reservoir area water covered 4 5 1 100% of reservoir area water covered Comments: 12. Offsite Drainage Area (DA = Drainage Area, A = Reservoir Area) Potential Rating Rating Description Final Rating 1 Drainage area = Reservoir area 2 Drainage area = 1 to 3 times reservoir area 2 3 Drainage area = 3 to 6 times reservoir area 4 Drainage area = 6 to 10 times reservoir area 5 Drainage area = > 10 times reservoir area Comments: March 11, 2014 Ash Pond Rating Form Page 5 of 6 Section 3 — Final Ratings Rating Areas irr�rl FFinal 75 Section 1: Water Quality Considerations 1. Groundwater Standards 3 2. Drinking Water Intakes 4 3. Total Population Served by Intakes 4 4. Classification Downstream and Discharge Points 4 5. Distance of Water Supply Wells from the Compliance Boundary 5 6. Population Served by Water Supply Wells 5 SECTION 1 TOTAL 25 Section 2: Dam Safety Considerations 7. Hazard Classification 4 8. Proximity to Waters of the State 5 9. State of Structural Stability & Maintenance 3 10. Volume of Facility 4 11. Free Water Content 4 12. Offsite Drainage Area 2 SECTION 2 TOTAL 22 SECTION 1 + SECTION 2 TOTAL 47 Additional Comments: March 11, 2014 Ash Pond Rating Form Page 6 of 6 ASH POND RATING FORM FACILITY NAME: Asheville NPDES PERMIT NO.: NC0000396 REGION: Asheville COUNTY: Buncombe Instructions: Rate each facility using the potential rating in the left column and the descriptions in the middle column. A score of 1 indicates the best case whereas a score of 5 indicates the worst case. For the final rating column, put the number next to the description that best matches the facility in consideration. If you believe a different rating is warranted for any category (other than what is listed), then justify alternate rating in the comment section. Section 1— Water Quality Considerations Comments' Exceedance of thallium. 2. Drinking Water Intakes Potential Rating Rating Description Final Rating 0 No intake 2 Greater than 50 miles downstream 2 3 Greater than 20 miles, but less than orequal to 50 miles downstream 4 Greater than 10 miles, but less than orequal to 20 miles downstream 5 Less than orequal to 10 miles downstream Comments: Newport Utilities per Gay Irwin, Johnson City Water Resources, TDEC 3/21/2014 (6 MGD capacity, 10,300 served). None located between Asheville Plant and State line per Jim Adams, PWS 3/19/2014. March 11, 2014 Ash Pond Rating Form Pagel of 5 3. Total Population Served by Intakes Potential Rating Rating Description Final Rating 1 1 - 500 served 2 501 - 3,300 served 3 3,301 - 10,000 served 4 10,001 - 100,000 served 4 5 > 100,000 served Comments: See comment above. 5. Distance of Water Supply Wells from the Compliance Boundary (CB) Potential Rating Rating Description Final Rating 1 Wells greater than 1/2 mile (2,640 feet) of the CB 2 Wells within 2,000 to 2,640 feet of CB 3 Wells within 1,500 to 2,000 feet of CB 4 Wells within 1,000 to 1,500 feet of CB 5 Wells within 1,000 feet of CB 5 Comments: **DENR DWR has requested Duke provide alternate water to one active well with high levels of iron and manganese. Duke is providing alternate (bottled) water to this home and the adjacent home currently. Note: Hydrogeologic considerations -- Use to adjust rating due to unique characteristics that should be considered such as wells upgradient, cross gradient, etc. March 11, 2014 Ash Pond Rating Form Page 2 of 5 6. Population Served by Water Supply Wells (referenced above) Potential Rating Rating Description Final Rating 1 0 o ulation 2 0 - 25 people 2 3 26 - 100 people 4 101 - 200 people 5 1 > 200 people Comments: See notes above. Section 2 — Dam Safety Considerations 7. Hazard Classification Comments: 8. Proximity to Waters of the State Potential Rating Rating Description Final Rating I Located within/above a larger ash reservoir with large amount of available storage 3 Potential coal ash migration constrained by physical barrier 4 5 1 Directly adjacent Comments: Interstate-26 is between the dam and the French Broad River. River is approximately 1070 feet from the dam. March 11, 2014 Ash Pond Rating Form Page 3 of 5 9. State of Structural Stability & Maintenance (use historical worst case scenario) Potential Rating Description Final Rating 1 Notice of Inspection (NOI) with no recommendations 2 NOI with maintenance recommendations 2 3 Notice of Deficiency (NOD) 4 Dam Safety Order (DSO) 5 Enforcement action required Comments: 11. Free Water Content Potential Rating Rating Description Final Rating 1 Dry - heavy natural vegetation and tree growth 2 Dry - no standing water, sparse tree growth 3 25% of reservoir area water covered 4 25% to 75% of reservoir area water covered 4 5 100% of reservoir area water covered Comments: March 11, 2014 Ash Pond Rating Form Page 4 of 5 12. Offsite Drainage Area (DA = Drainage Area, A = Reservoir Area) Potential Rating Rating Description Final Rating 1 Drainage area = Reservoir area 2 Drainage area = 1 to 3 times reservoir area 2 3 Drainage area = 3 to 6 times reservoir area 4 Drainage area = 6 to 10 times reservoir area 5 Drainage area = > 10 times reservoir area Comments: Section 3 — Final Ratings Rating Areas Final Rating Section 1: Water Quali Considerations 1. Groundwater Standards 5 2. Drinking Water Intakes 2 3. Total Population Served by Intakes 4 4. Classification Downstream and Discharge Points 4 5. Distance of Water Supply Wells from the Compliance Boundary 5 6. Population Served by Water Supply Wells 2 SECTION I TOTAL 22 Section 2: Dam Safety Considerations 7. Hazard Classification 5 S. Proximity to Waters of the State 4 9. State of Structural Stability & Maintenance 2 10. Volume of Facility 2 11. Free Water Content 4 12. ©ffsite Drainage Area 2 SECTION 2 TOTAL, 19" SECTION 1 + SECTION 2 TOTAL 41 Additional Comments: March 11, 2014 Ash Pond Rating Form Page 5 of ASH POND RATING FORM FACILITY NAME: Belews Creek NPDES PERMIT NO.: NCO024406 REGION: Winston-Salem COUNTY: Stokes Instructions: Rate each facility using the potential rating in the left column and the descriptions in the middle column. A score of 1 indicates the best case whereas a score of 5 indicates the worst case. For the final rating column, put the number next to the description that best matches the facility in consideration. If you believe a different rating is warranted for any category (other than what is listed), then justify alternate rating in the comment section. Section 1— Water Quality Considerations 1. Groundwater Standards Potential Rating Rating Description Final Rating 1 An exceedance of pH, iron or manganese 2 Exceedance of chloride, nitrate, sulfate, or TDS 3 Exceedance of aluminum, barium, copper, nickel or zinc 4 Exceedance of boron, cadmium, chromium, selenium, or antimony 5 Exceedance of arsenic, lead, mercury, or thallium 5 Comments: Exceedance of thallium. 2. Drinking Water Intakes Potential Rating Rating Description Final Rating 0 No intake 2 Greater than 50 miles downstream 3 Greater than 20 miles, but less than orequal to 50 miles downstream 4 Greater than 10 miles, but less than orequal to 20 miles downstream 4 5 Less than orequal to 10 miles downstream Comments: Town of Madison intake —12.5 miles downstream (2,787) also serves Rockingham Water pop (251) Town of Eden intake — 34 miles downstream (15, 908) also serves Dan River Water (11,890) March 11, 2014 Ash Pond Rating Form Pagel of 5 3. Total Population Served by Intakes Potential Rating Rating Description Final Rating 1 1 - 500 served 2 501 - 3,300 served 3 3,301 - 10,000 served 4 10,001 - 100,000 served 4 5 > 100,000 served Comments: Pop 3,038 served by 1" intake; 27,798 served by 2nd intake 4. Classification Downstream and Discharge Points (use worst case scenario) Potential Rating Rating Description Final Rating 1 Class C 1 4 Class B 5 High Quality Waters, Outstanding Resource Waters, Threatened or Endangered Species present Comments: Belews Lake is Class C; Dan River is WS-IV 5. Distance of Water Supply Wells from the Compliance Boundary (CB) Potential Rating Rating Description Final Rating 1 Wells greater than 1/2 mile 2,640 feet of the CB 2 Wells within 2,000 to 2,640 feet of CB 3 Wells within 1,500 to 2,000 feet of CB 4 Wells within 1,000 to 1,500 feet of CB 5 Wells within 1,000 feet of CB 5 Comments: Wells on Middleton Loop & Pine Hall Road Note: Hydrogeologic considerations -- Use to adjust rating due to unique characteristics that should be considered such as wells upgradient, cross gradient, etc. March 11, 2014 Ash Pond Rating Form Page 2 of 5 6. Population Served by Water Supply Wells (referenced above) Potential Rating Rating Description Final Rating 1 0 population 2 0 - 25 people 3 26 - 100 people 3 4 101 - 200 people 5 > 200 people Comments: Estimate 14 homes with average of 4 occupants per home Section 2 — Dam Safety Considerations 7. Hazard Classification Potential Rating Rating Description Final Rating 1 Low hazard - Small size 2 Low Hazard - Large size 3 Intermediate Hazard 4 High Hazard - Environmental Concerns 5 High Hazard - Loss of Life 5 Comments: 8. Proximity to Waters of the State Potential Rating Rating Description Final Rating 1 Located within/above a larger ash reservoir with large amount of available storage 3 Potential coal ash migration constrained by physical barrier 3 5 Directly adjacent Comments: March 11, 2014 Ash Pond Rating Form Page 3 of 5 9. State of Structural Stability & Maintenance (use historical worst case scenario) Potential Rating Rating Description Final Rating 1 Notice of Inspection OI with no recommendations 2 NOI with maintenance recommendations 2 3 Notice of Deficient OD 4 Dam Safety Order DSO 5 Enforcement action required Comments: 10. Volume of Facility Potential Rating Rating Description Final Rating 1 < 300 acre-feet 2 300 to 1,500 acre-feet 2 3 1,500 to 3,000 acre-feet 4 3,000 to 9,000 acre-feet 5 > 9,000 Acre-feet Comments: 11. Free Water Content Potential Rating Rating Description Final Rating 1 D - heavy natural vegetation and tree growth 2 D - no standing water, s arce tree growth 3 25% of reservoir area water covered 4 25% to 75% of reservoir area water covered 5 100% of reservoir area water covered 5 Comments: March 11, 2014 Ash Pond Rating Form Page 4 of 5 12. Offsite Drainage Area (DA = Drainage Area, A = Reservoir Area) Potential Rating Rating Description Final Rating 1 Drainage area = Reservoir area 2 Drainage area = 1 to 3 times reservoir area 2 3 Drainage area = 3 to 6 times reservoir area 4 Drainage area = 6 to 10 times reservoir area 5 Drainage area = > 10 times reservoir area Comments: Section 3 — Final Ratings Rating Areas Final Rating Section 1: Water Quality Considerations 1. Groundwater Standards 5 2. Drinking Water Intakes 4 3. Total Population Served by Intakes _ 4 4. Classification Downstream and Discharge Points 1 5. Distance of Water Supply Wells from the Compliance Boundary 5 6. Population Served by Water Supply Wells 3 SECTION 1 TOTAL 22 Section 2: Dam Safe Considerations 7, Hazard Classification 5 8. Proximity to Waters of the State 3 9. State of Structural Stability & Maintenance 2 10. Volume of Facility I 11. Free Water Content 5 12. Offsite Drainage Area 2 SECTION 2 TOTAL 19 SECTION 1 + SECTION 2 TOTAL 41 Additional Comments: March 11, 2014 Ash Pond Rating Form Page 5 of.s ASH POND RATING FORM FACILITY NAME: Buck REGION: Mooresville NPDES PERMIT NO.: NC0004774 COUNTY: Rowan Instructions: Rate each facility using the potential rating in the left column and the descriptions in the middle column. A score of 1 indicates the best case whereas a score of 5 indicates the worst case. For the final rating column, put the number next to the description that best matches the facility in consideration. If you believe a different rating is warranted for any category (other than what is listed), then justify alternate rating in the comment section. Section 1— Water Quality Considerations 1. Groundwater Standards Potential Rating Rating Description Final Rating 1 An exceedance of pH, iron or manganese 2 Exceedance of chloride, nitrate, sulfate, or TDS 3 Exceedance of aluminum, barium, copper, nickel or zinc 4 Exceedance of boron, cadmium, chromium, selenium, or antimony 4 5 Exceedance of arsenic, lead, mercury, or thallium Comments: o date MWs at Buck have shown consistent exceedances for pH, Fe, Mn, B, sulfate, and TDS. 2. Drinking Water Intakes Potential Rating Rating Description Final Rating 0 No intake 2 Greater than 50 miles downstream 3 Greater than 20 miles, but less than orequal to 50 miles downstream 4 Greater than 10 miles, but less than orequal to 20 miles downstream 4 5 Less than orequal to 10 miles downstream Comments: The Town of Denton intake is approximately 13 miles downstream on the lower portion of High Rock Lake. Additional intakes for communities like Albemarle would be further (-21 miles) downstream on along the Yadkin River's chain of reservoirs. March 11, 2014 Ash Pond Rating Form Page 1 of 5 3. Total Population Served by Intakes Potential Rating Rating Description Final Rating 1 1 - 500 served 2 501 - 3,300 served 2 3 3,301 - 10,000 served 4 10,001 - 100,000 served 5 > 100,000 served Comments: Denton's PWS system serves 3,080. Albemarle's two WTPs serve 16,500. Given the nature of the chain of lakes and dams that would likely capture material associated with a potential catastrophic release at Buck, the risk rating is probably best approximated by using just the population numbers for Denton 4. Classification Downstream and Discharge Points (use worst case scenario) Potential Rating .Rating Description Final Rating 1 Class C 4 Class B 4 5 High Quality Waters, Outstanding Resource Waters, Threatened or Endangered Species present Comments: Classification in the immediate vicinity of Buck is WS-V. Downstream of Buck, the classification changes to WS-IV, B in the lower portion of High Rock Lake. 5. Distance of Water Supply Wells from the Compliance Boundary (CB) Potential Rating Rating Description Final Rating 1 Wells greater than 1/2 mile 2,640 feet) of the CB 2 Wells within 2,000 to 2,640 feet of CB 3 Wells within 1,500 to 2,000 feet of CB 4 Wells within 1,000 to 1,500 feet of CB 5 Wells within 1,000 feet of CB 5 Comments: The area in the vicinity of the plant is served by wells and a formal well survey has not been conducted. The closest private wells are along Dukeville and Leonard Roads and a couple of small spur roads off of these. The closest private wells are roughly 200 ft from the CB and there may be roughly 50 private water supply wells within 1500 ft. Additionally, there is a public water supply well for Duke employees on site at Buck (0180647) and two PWS well systems at nearby churches (Trading Ford Baptist 0180594, Yadkin Grove Missionary Baptist 0180633). These PWS systems are roughly 800-1300 ft from the CB. Note: Hydrogeologic considerations -- Use to adjust rating due to unique characteristics that should be considered such as wells upgradient, cross gradient, etc. March 11, 2014 Ash Pond Rating Form Page 2 of 5 6. Population Served by Water Supply Wells (referenced above) Potential RFinal Rating Rating Description Rating 1 0 population 2 0 - 25 2eople 3 26 -100 people 4 101 - 200 people 5 f > 200 people 5 Comments: Without a well survey, the population served by private wells near Buck was estimated in the following manner: a very rough approximation of 50 wells within 1500 feet and 3 people per well results in 150 people served. This is an estimate and the actual number could vary significantly from that value. The population served by the PWS systems mentioned #2 is estimated at 200 (75 on site, 100 at Trading Ford, 25 at Yadkin Grove). Section 2 — Dann Safety Considerations March 11, 2014 Ash Pond Rating Form Page 3 of 5 9. State of Structural Stability & Maintenance (use historical worst case scenario) Potential Rating Rating Description Final Rating 1 Notice of Inspection (NOI) with no recommendations 2 NOI with maintenance recommendations 2 3 Notice of Deficient (NOD) 4 Dam Safety Order (DSO) 5 Enforcement action required Comments: 10. Volume of Facility Potential Rating Rating Description Final Rating 1 < 300 acre-feet 2 300 to 1,500 acre-feet 3 1,500 to 3,000 acre-feet 3 4 3,000 to 9,000 acre-feet 5 > 9,000 Acre-feet Comments: 11. Free Water Content Potential Rating Rating Description Final Rating 1 Dry - heavy natural vegetation and tree growth 2 D - no standing water, sparse tree gowth 3 25% of reservoir area water covered 4 25% to 75% of reservoir area water covered 4 5 100% of reservoir area water covered Comments: March 11, 2014 Ash Pond Rating Form Page 4 of 5 12. Offsite Drainage Area (DA = Drainage Area, A = Reservoir Area) Potential Rating Rating Description Final Rating 1 Drainage area = Reservoir area 2 Drainage area = 1 to 3 times reservoir area 2 3 Drainage area = 3 to 6 times reservoir area 4 Drainage area = 6 to 10 times reservoir area 5 Drainage area = > 10 times reservoir area Comments: Section 3 — Final Ratings Rating Areas Final Rating Section 1: Water Quality Considerations 1. Groundwater Standards 4 2. Drinking Water Intakes 4 3. Total Po ulation Served by Intakes 2 4. Classification Downstream and Discharge Points 4 5. Distance of Water Supply Wells from the Compliance Boundary 5 6. Population Served by Water Supply Wells 5 SECTION' l TOTAL' 4 . Section 2: Dam Safety Considerations 7. Hazard Classification 4 8. Proximity to Waters of the State 5 9. State of Structural Stability & Maintenance 2 10. Volume of Facility 3 11. Free Water Content 4 12. Offsite Drainage Area 2 SECTION 2.TOTAL 20 SECTION I + SECTION 2 TOTAL 44 Additional Comments: March 11, 2014 Ash Pond Rating Form Page 5 of 5 FACILITY NAME: Cape Fear REGION: Raleigh ASH POND RATING FORM NPDES PERMIT NO.: NC0003433 COUNTY: Chatham Instructions: Rate each facility using the potential rating in the left column and the descriptions in the middle column. A score of 1 indicates the best case whereas a score of 5 indicates the worst case. For the final rating column, put the number next to the description that best matches the facility in consideration. If you believe a different rating is warranted for any category (other than what is listed), then justify alternate rating in the comment section. Section 1— Water Quality Considerations 1. Groundwater Standards Potential Rating ` ' Rating Description Final Rating 1 An exceedance of pH, iron or manganese 2 Exceedance of chloride, nitrate, sulfate, or TDS 3 Exceedance of aluminum, barium, copper, nickel or zinc 4 Exceedance of boron; cadmium, chromium, 'selenium, or antimony 5 Exceedance of arsenic, lead, mercury, or thallium 5 Comments: Exceedance of arsenic. 2. Drinking Water Intakes Potential Rating Rating Description Final Rating 0 No intake 2 Greater than 50 miles downstream 3 Greater than 20 miles, but less than orequal to 50 miles downstream 4 Greater than 10 miles, but less than orequal to 20 miles downstream 5 Less than orequal to 10 miles downstream 5 Comments: One water supply intake is less than 10 miles downstream. March 11, 2014 Ash Pond Rating Form Page 1 of 5 3. Total Population Served by Intakes Potential Rating Rating Description Final Rating 1 1 - 500 served 2 501 - 3,300 served 3 3,301 - 10,000 served 4 10,001 - 100,000 served 4 5 > 100,000 served Comments: Based on normal population served by the surface water supply intakes downstream of the Cape Fear Facility. Potential population served through emergencyconnections not included. 4. Classification Downstream and Discharge Points (use worst case scenario) Potential Rating Description Final Rating Rating 1 Class C 1 4 Class B 5 High Quality Waters, Outstanding Resource Waters, Threatened or Endangered Species present Comments: *Cape Fear Steam Electric facility is located adjacent, to the Cape Fear River just below the confluence of the Haw and Deep Rivers. From the junction of the Deep and Haw River to a point 0.5 miles upstream of NC Hwy 42 the Cape Fear River is classified as WS-IV From 0.5 miles upstream of NC Hwy 42 to NC Hwy 42 the Cape Fear River is classified as WS-IV Critical Area (CA) and pis the location of the City of Sanford's Water Supply intake. 5. Distance of Water Supply Wells from the Compliance Boundary (CB) Potential' Rating Rating Description Final Rating 1 Wells greater than 1/2 mile 2,640 feet of the CB 1 2 Wells within 2,060 to 2,640 feet of CB 3 Wells within 1,500 to 2,000 feet of CB 4 Wells within 1,000 to 1,500 feet of CB 5 Wells within 1,000 feet of CB Comments: Cape Fear- there are several residence/structures that fall within the "Potential Rating 3" however the wells are located on the opposite site of the Cape Fear River in regards to the facility. This survey was completed with GoogleEarth with the assumption that specific structures are utilizing well water. The source of water for the plywood manufacturing plants is unknown. Note: Hydrogeologic considerations -- Use to adjust rating due to unique characteristics that should be considered such as wells upgradient, cross gradient, etc. March 11, 2014 Ash Pond Rating Form Page 2 of 5 6. Population Served by Water Supply Wells (referenced above) Potential Rating Rating Description Final Rating 1 0 population 2 0 - 25 people 3 26 - 100 people 3 4 101 - 200 people 5 >200 people Comments: Based on the assumption that there are four persons living in each residence/structure. No service population for PWS wells. Section 2 — Dam Safety Considerations 7. Hazard Classification Potential Rating Rating Description Final Rating 1 Low hazard - Small size 2 Low Hazard - Large size 3 Intermediate Hazard 4 High Hazard -Environmental Concerns 4 5 High Hazard - Loss of Life Comments: 8. Proximity to Waters of the State Potential Rating Rating Description Final Rating I Located within/above a larger ash reservoir with large amount of available storage 3 Potential coal ash migration constrained by physical barrier 5 Directly adjacent 5 Comments: March 11, 2014 Ash Pond Rating Form Page 3 of 5 9. State of Structural Stability & Maintenance (use historical worst case scenario) Potential Rating Rating Description Final Rating 1 Notice of Inspection OI with no recommendations 2 NOI with maintenance recommendations 3 Notice of Deficiency OD 3 4 Dam Safety Order DSO 5 Enforcement action required Comments: 10. Volume of Facility Potential Rating Rating Description Final Rating 1 < 300 acre-feet 2 300 to 1,500 acre-feet 3 1,500 to 3,000 acre-feet 3 4 3,000 to 9,000 acre-feet 5 > 9,000 Acre-feet Comments: 11. Free Water Content Potential Rating Rating Description Final Rating 1 D - heavy natural vegetation and tree growth 2 D - no standing water, sparse tree growth 3 25% of reservoir area water covered 4 25% to 75% of reservoir area water covered 4 5 100% of reservoir area water covered Comments: March 11, 2014 Ash Pond Rating Form Page 4 of 5 12. Offsite Drainage Area (DA = Drainage Area, A = Reservoir Area) Potential Rating Rating Description Final Rating 1 Drainage area = Reservoir area 2 Drainage area = 1 to 3 times reservoir area 2 3 Drainage area = 3 to 6 times reservoir area 4 Drainage area = 6 to 10 times reservoir area Drainage area = > 10 times reservoir area Corninents: Section 3 — Final Ratings Rating Areas Final Rating Section 1: Water Quality Considerations 1. Groundwater Standards 5 2. Drinking Water Intakes 5 3. Total Population Served by Intakes 4 4. Classification Downstream and Discharge Points _ 1 5, Distance of Water Supply Wells from the Compliance Boundary 1 6. Population Served by Water Sup -ply Wells 3 SECTION 1 TOTAL 19 Section 2: Dam Safety Considerations 7. Hazard Classification 4 8, Proximity to Waters of the State 5 9. State of Structural Stability & Maintenance 3 10. Volume of Facility 3 11. Free Water Content 4 12. Offsite Drainage Area 2 SECTION 2 TOTAL 21 SECTION 1 + SECTION 2 TOTAL 40 Additional Comments: March 11, 2014 Ash Pond Rating Form Page 5 of 5 ASH POND RATING FORM FACILITY NAME: Cliffside NPDES PERMIT NO.: NC0005088 REGION: Asheville COUNTY: Rutherford Instructions: Rate each facility using the potential rating in the left column and the descriptions in the middle column. A score of 1 indicates the best case whereas a score of 5 indicates the worst case. For the final rating column, put the number next to the description that best matches the facility in consideration. If you believe a different rating is warranted for any category (other than what is listed), then justify alternate rating in the comment section. Section 1— Water Quality Considerations 2. Drinking Water Intakes Potential Rating Rating Description Final Rating 0 No intake 2 Greater than 50 miles downstream 3 Greater than 20 miles, but less than orequal to 50 miles downstream 4 Greater than 10 miles, but less than orequal to 20 miles downstream 5 Less than orequal to 10 miles downstream 5 Comments: City of Shelby proposed intake approximately 6 miles downstream of plant. Intake developed during previous droughts, not currently used. Shelby has capability to pump from Broad during an emergency such as a drought. Next nearest intake is Gaffney, SC (18 MGD) located approx.. 18 miles from Cliffside plant per Rob Devlin, SCDHEC. 3/21/2014 March 11, 2014 Ash Pond Rating Form Pagel of 5 3. Total Population Served by Intakes Potential Rating Rating Description Final Rating 1 1 - 500 served 2 501 - 3,300 served 3 3,301 - 10,000 served 3 4 10,001 - 100,000 served 5 > 100,000 served Comments: Rating is for Gaffney, SC intake; does not account for proposed Shelby intake. 4. Classification Downstream and Discharge Points (use worst case scenario) Potential Final Rating Description Rating . Rating 5. Distance of Water Supply Wells from the Compliance Boundary (CB) Potential Rating Rating Description Final Rating 1 Wells greater than 1/2 mile (2,640 feet) of the CB 2 Wells within 2,000 to 2,640 feet of CB 3 Wells within 1,500 to 2,000 feet of CB 4 Wells within 1,000 to 1,500 feet of CB 5 Wells within 1,000 feet of CB 5 Comments: Multiple single family home wells in proximity (no water supply well survey conducted) Note: Hydrogeologic considerations -- Use to adjust rating due to unique characteristics that should be considered such as wells upgradient, cross gradient, etc. March 11, 2014 Ash Pond Rating Form Page 2 of 5 6. Population Served by Water Supply Wells (referenced above) Potential Rating Rating Description Final Rating 1 0 population 2 0 - 25 people 2 3 26 -100 people 4 101 - 200 people 5 > 200 people Comments: Estimated number only, yet to be verified with proper survey. Section 2 — Dam Safety Considerations 7. Hazard Classification PotenhaL Rating Description Final Rating Rating 1 Low hazard - Small size 2 Low Hazard - Lar a size 3 Intermediate Hazard 4 High Hazard - Environmental Concerns 5 High Hazard - Loss of Life 5 Comments: 8. Proximity to Waters of the State Potential Rating Rating Description Final Rating 1 Located within/above a larger ash reservoir with large amount of available storage 3 Potential coal ash migration constrained by physical barrier 5 Directly adjacent 5 Comments: March 11, 2014 Ash Pond Rating Form Page 3 of 5 9. State of Structural Stability & Maintenance (use historical worst case scenario) Potential Rating Rating Description Final Rating 1 Notice of Inspection (NOI) with no recommendations 2 NOI with maintenance recommendations 3 Notice of Deficiency (NOD) 3 4 Dam Safety Order (DSO) 5 Enforcement action required Comments: 10. Volume of Facility Potential Rating Description 'h`Mal Rating Rating 1 < 300 acre-feet ' 2 300 to 1500 acre-feet 3 1,500 to 3,000 acre.=feet:: 4 4 3NO t6 9,000 acre-feet 7'. 5 > 9,000 Acre-feet Comments: 11. Free Water Content Potential Rating Rating Description Final Rating 1 Dry - heavy natural vegetation and tree growth 2 D - no standing water, sparse tree growth 3 25% of reservoir area water covered 4 25% to 75% of reservoir area water covered 4 5 100% of reservoir area water covered Comments: March 11, 2014 Ash Pond Rating Form Page 4 of 5 Section 3 — Final Ratings Rating Areas Section 1: Water Quality Considerations 1. Groundwater Standards 2. Drinking Water Intakes 3. Total Population Served by Intakes _ 4. Classification Downstream and Discharge Points S. Distance of Water Supply Wells from the Compl b. Population Served by Water Supply Wells Section 2: Dam Safety Considerations 7. Hazard Classification 8. Proximity to Waters of the State 9. State of Structural Stability & Maintenance 10. Volume of Facility 11. Free Water Content 121. Offsite Drainage Area Additional Comments: Final Rating 2 5 3 1 Boundary 5 2 SECTION I TOTAL, 18 SECTION 2 TOTAL SECTION 1 + SECTION 2 TOTAL 5 5 3 4 4 4 25 43 March 11, 2014 Ash Pond Rating Form Page 5 of 5 ASH POND RATING FORM FACILITY NAME: Dan River REGION: Winston-Salem NPDES PERMIT NO.: NC0003468 COUNTY: Rockingham Instructions: Rate each facility using the potential rating in the left column and the descriptions in the middle column. A score of 1 indicates the best case whereas a score of 5 indicates the worst case. For the final rating column, put the number next to the description that best matches the facility in consideration. If you believe a different rating is warranted for any category (other than what is listed), then justify alternate rating in the comment section. Section 1— Water Quality Considerations 1. Groundwater Standards Potential Rating Rating Description Final Rating 1 An exceedance of pH, iron or manganese 2 Exceedance of chloride, nitrate, sulfate, or TDS 3 Exceedance of aluminum, barium, copper, nickel or zinc 4 Exceedance of boron, cadmium, chromium, selenium, or antimony 5 Exceedance of arsenic, lead, mercury, or thallium 5 Comments: Exceedance of arsenic. 2. Drinking Water Intakes Potential Rating Rating Description ti Final Rating 0 No intake 2 Greater than 50 miles downstream 3 Greater than 20 miles, but less than orequal to 50 miles downstream 3 4 Greater than 10 miles, but less than orequal to 20 miles downstream 5 Less than orequal to 10 miles downstream Comments: Service. City of Danville WTP is approximately 25 river miles downstream as per US Fish and Wildlife March 11, 2014 Ash Pond Rating Form Page 1 of 5 3. Total Population Served by Intakes Potential Rating Rating Description Final Rating 1 1 - 500 served 2 501 - 3,300 served 3 3,301 - 10,000 served 4 10,001 - 100,000 served 5 > 100,000 served 5 Comments: City of Danville water customers in addition to those potential users through inter -governmental agreements for emergency water supply. 4. Classification Downstream and Discharge Points (use worst case scenario) Potential Rating Rating Description Final Rating 1 Class C 4 Class B 5 High Quality Waters, Outstanding Resource Waters, Threatened or Endangered Species present 5 Comments: Actually Class C waters, but there are identified endangered species. 5. Distance of Water Supply Wells from the Compliance Boundary (CB) Potential Rating Rating Description Final Rating 1 Wells greater than 1/2 mile 2,640 feet of the CB 1 2 Wells within 2,000 to 2,640 feet of CB 3 Wells within 1,500 to 2,000 feet of CB 4 Wells within 1,000 to 1,500 feet of CB 5 Wells within 1,000 feet of CB Comments: As per Rockingham County Environmental Health Dept (RCEHD). Agricultural supply wells are not accounted for by RCEHD. Note: Hydrogeologic considerations -- Use to adjust rating due to unique characteristics that should be considered such as wells upgradient, cross gradient, etc. March 11, 2014 Ash Pond Rating Form Page 2 of 5 6. Population Served by Water Supply Wells (referenced above) Potential Rating Rating Description Final Rating 1 0 population 1 2 0 - 25 people 3 26 - 100 people 4 101 - 200 people 5 > 200 people Comments: As per Rockingham County Environmental Health Dept (RCEHD). Agricultural supply wells are not accounted for by RCEHD. Section 2 — Dam Safety Considerations 7. Hazard Classification Potential Rating Rating Description Final Rating 1 Low hazard - Small size 2 Low Hazard - Large size 3 Intermediate Hazard 4 High Hazard - Environmental Concerns 4 5 High Hazard - Loss of Life Comments: 8. Proximity to Waters of the State Potential Rating Rating Description Final Rating I Located within/above a larger ash reservoir with large amount of available storage 3 Potential coal ash migration constrained by physical barrier 5 1 Directly adjacent 5 Comments: March 11, 2014 Ash Pond Rating Form Page 3 of 5 9. State of Structural Stability & Maintenance (use historical worst case scenario) Potential Rating Rating Description Final Rating 1 Notice of Inspection (NOI) with no recommendations 2 NOI with maintenance recommendations 3 Notice of Deficiency (NOD) 4 Dam Safety Order (DSO) 5 Enforcement action re uired 5 Comments: 10. Volume of Facility Potential Rating Rating Description Final Rating 1 < 300 acre-feet 2 300 to 1,500 acre-feet 2 3 1,500 to 3,000 acre-feet 4 3,000 to 9,000 acre-feet 5 > 9,000 Acre-feet Comments: 11. Free Water Content Potential Rating Rating Description Final Rating 1 D - heavy natural vegetation and tree growth 2 D - no standing water, sparse tree growth 3 25% of reservoir area water covered 4 25% to 75% of reservoir area water covered 5 100% of reservoir area water covered 5 Comments: March 11, 2014 Ash Pond Rating Form Page 4 of 5 12. Offsite Drainage Area (DA = Drainage Area, A = Reservoir Area) Potential Ratio g Rating Description Final Rating 1 Drainage area = Reservoir area 2 Drainage area = i to 3 times reservoir area 2 3 Drainage area = 3 to 6 times reservoir area 4 Drainage area = 6 to 10 times reservoir area 5 Drainage area = > 14 times reservoir area Comments: Section 3 -- Final Ratings Rating Areas Final Rating Section 1: Water Quality Considerations 1. Groundwater Standards 5 2. Drinking Water Intakes 3 3. Total Population Served by Intakes 5 4. Classification Downstream and Discharge Points 5 5. Distance of Water Supply Wells from the Compliance Boundary 1 6. Population Served by Water Supply Wells I SECTION I TOTAL 24 Section 2: Dam Safety Considerations 7. Hazard Classification 4 8. Proximity to Waters of the State 5 9. State of Structural Stability & Maintenance 5 10. Volume of Facility 2 11. Free Water Content 5 12. Offsite Drainage Area SECTION 2 TOTAL 23 SECTION 1 + SECTION 2 TOTAL 43 Additional Comments: March 11, 2014 Ash Pond Rating Form Paige 5 of 5 ASH POND RATING FORM FACILITY NAME: Lee REGION: Washington NPDES PERMIT NO.: NC0003417 COUNTY: Wayne Instructions: Rate each facility using the potential rating in the left column and the descriptions in the middle column. A score of 1 indicates the best case whereas a score of 5 indicates the worst case. For the final rating column, put the number next to the description that best matches the facility in consideration. If you believe a different rating is warranted for any category (other than what is listed), then justify alternate rating in the comment section. Section 1— Water Quality Considerations 1. Groundwater Standards Potential Rating Rating Description Final Rating 1 An exceedance of pH, iron or manganese 2 Exceedance of chloride, nitrate, sulfate, or TDS 3 Exceedance of aluminum, barium, copper, nickel or zinc 4 Exceedance of boron, cadmium, chromium, selenium, or antimony 5 Exceedance of arsenic, lead, mercury, or thallium 5 Comments: Exceedance of arsenic and lead. 2. Drinking Water Intakes Potential Rating Rating Description Final Rating 0 No intake 2 Greater than 50 miles downstream 3 Greater than 20 miles, but less than orequal to 50 miles downstream 4 Greater than 10 miles, but less than orequal to 20 miles downstream 5 1 Less than orequal to 10 miles downstream 5 Comments: Drinking water intake is located approximately six miles downstream. L March 11, 2014 Ash Pond Rating Form Page 1 of 5 3. Total Population Served by Intakes Potential Rating Rating Description Final Rating 1 1 - 500 served 2 501 - 3,300 served 3 3,301 - 10,000 served 4 10,001 - 100,000 served 4 5 > 100,000 served Comments: According to Public Water Supply Section website, the City of Goldsboro's public water system served a year-round population of 36,437. 4. Classification Downstream and Discharge Points (use worst case scenario) Potential Rating Rating Description Final Rating 1 Class C 4 Class B 5 High Quality Waters, Outstanding Resource Waters, Threatened or Endangered Species present 5 Comments: This segment of the Neuse is classified as WS-IV; note the surface water intake located approximately six miles downstream. 5. Distance of Water Supply Wells from the Compliance Boundary (CB) Potential Rating Rating Description Final Rating 1 Wells greater than 1/2 mile (2,640 feet) of the CB 2 Wells within 2,000 to 2,640 feet of CB 2 3 Wells within 1,500 to 2,000 feet of CB 4 Wells within 1,000 to 1,500 feet of CB 5 Wells within 1,000 feet of CB Comments: This estimate is based on "drive -by" receptor survey conducted by WaRO staff. Wells may be located less than 1500 feet from Compliance Boundary; however, any supply wells would be located up - gradient of the ash pond. Note: Hydrogeologic considerations -- Use to adjust rating due to unique characteristics that should be considered such as wells upgradient, cross gradient, etc. March 11, 2014 Ash Pond Rating Form Page 2 of 5 6. Population Served by Water Supply Wells (referenced above) Potential Rating R Rating Description Final Rating 1 0 population 2 0 - 25 people 2 3 26 - 100 people 4 101 - 200 people 5 > 200 people Comments: This estimate is based on the number of pump/well houses observed in the area. It is not certain if these wells are still in service; and, as noted above, the wells are located up -gradient of the facility. Section 2 — Dam Safety Considerations 7. Hazard Classification Potential Rating R Rating Description Final Rating 1 Low hazard - Small size 2 Low Hazard - Large size 3 Intermediate Hazard 4 High Hazard - Environmental Concerns 4 5 1 High Hazard - Loss of Life Comments: 8. Proximity to Waters of the State Potential Rating Rating Description Final Rating I Located within/above a larger ash reservoir with large amount of available storage 3 Potential coal ash migration constrained by physical barrier 5 Directly adjacent 5 Comments: March 11, 2014 Ash Pond Rating Form Page 3 of 5 9. State of Structural Stability & Maintenance (use historical worst case scenario) Potential Rating Rating Description Final Rating 1 Notice of Inspection (NOI) with no recommendations 1 2 NOI with maintenance recommendations 3 Notice of Deficiency (NOD) 4 Dam Safety Order (DSO) 5 Enforcement action required Comments: 10. Volume of Facility Rating Potential Rating Description Final Rating 1 < 300 acre-feet 2 300 to 1,500 acre-feet 3 1,500 to 3,000 acre-feet 3 4 3,000 to 9,000 acre-feet 5 > 9,000 Acre-feet Comments: 11. Free Water Content Potential Rating Rating Description Final Rating 1 Dry - heavy natural vegetation and tree growth 2 Dry - no standing water, sparse tree growth 3 25% of reservoir area water covered 3 4 25% to 75% of reservoir area water covered 5 1 100% of reservoir area water covered Comments: March 11, 2014 Ash Pond Rating Form Page 4 of 5 Section 3 — Final Ratings Rating Areas Final Rating Section 1: Water Quality Considerations 1. Groundwater Standards 5 2. Drinking Water Intakes 5 3. Total Po ulation Served by Intakes 4 4. Classification Downstream and Discharge Points 5 5. Distance of Water Supply Wells from the Compliance Boundary 2 6, Population Served by Water Supply Wells 2 SECTION 1 TOTAL. 23 Section 2: Dam Safety Considerations 7. Hazard Classification 4 8, Proximity to Waters of the State 5 9. State of Structural Stability & Maintenance I 10. Volume of Facility 3 11. Free Water Content 3 12. Offsite Drainage Area I SECTION 2 TOTAL'.'17 SECTION 1 + SECTION 2 TOTAL 40 Additional Comments: A separate rating form has not been completed for the in -active ash pond down Ferry Bridge Rd. March 11, 2014 Ash Pond Rating; Form Page 5 of 5 ASH POND RATING FORM FACILITY NAME: Marshall NPDES PERMIT NO.: NC0004987 REGION: Mooresville COUNTY: Catawba Instructions: Rate each facility using the potential rating in the left column and the descriptions in the middle column. A score of 1 indicates the best case whereas a score of 5 indicates the worst case. For the final rating column, put the number next to the description that best matches the facility in consideration. If you believe a different rating is warranted for any category (other than what is listed), then justify alternate rating in the comment section. Section 1— Water Quality Considerations 1. Groundwater Standards Potential Rating Rating Description Final Rating 1 An exceedance of pH, iron or manganese 2 Exceedance of chloride, nitrate, sulfate, or TDS 3 Exceedance of aluminum, barium, copper, nickel or zinc 4 Exceedance of boron, cadmium, chromium, selenium, or antimony 4 5 Exceedance of arsenic, lead, mercury, or thallium Comments: MWs at Marshall have shown consistent exceedances for pH, B, Fe, Mn, sulfate, and TDS. 2. Drinking Water Intakes Potential Rating Description Final Rating Rating 0 No intake 2 Greater than 50 miles downstream 3 Greater than 20 miles, but less than orequal to 50 miles downstream 4 Greater than 10 miles, but less than orequal to 20 miles downstream 5 Less than orequal to 10 miles downstream 5 Comments: The Lincoln County intake is —6 miles downstream also on Catawba River/Lake Norman, however, the intake is located off the main channel in a small cove. Charlotte's Lee S. Dukes WTP intake is at the bottom of Lake Norman — 16 miles downstream. There would be additional intakes downstream from that Lee S. Dukes WTP at greater distances (that list would begin to overlap with intakes noted below Riverbend and Allen). March 11, 2014 Ash Pond Rating Form Page 1 of 6 3. Total Population Served by Intakes Potential Rating Rating Description Final Rating 1 1 - 500 served 2 501 - 3,300 served 3 3,301 - 10,000 served 4 10,001 - 100,000 served 5 > 100,000 served 5 Comments: The Lincoln County system serves 25,938. The Lee S. Dukes WTP is a portion of the Charlotte -Mecklenburg system and there is not a population estimate exclusively for this facility. The overall Charlotte system serves in excess of 800,000 people as noted under the write up for Riverbend and the risk _ has been rated accordingly. 4. Classification Downstream and Discharge Points (use worst case scenario) Potential Rating Rating Description Final Rating 1 Class C 4 Class B 4 5 High Quality Waters, Outstanding Resource Waters, Threatened or Endangered Species present Comments: Surface water in proximity to Marshall is the Catawba River/Lake Norman. Classifications include WS-IV, B; CA. March 11, 2014 Ash Pond Rating Form Page 2 of 6 5. Distance of Water Supply Wells from the Compliance Boundary (CB) Potential Rating Description Final Rating Rating 1 Wells greater than 1/2 mile (2,640 feet) of the CB 2 Wells within 2,000 to 2,640 feet of CB 3 Wells within 1,500 to 2,000 feet of CB 4 Wells within 1,000 to 1,500 feet of CB 4 5 Wells within 1,000 feet of CB Comments: There has not been a formal water supply well survey conducted for Marshall. There is public water available to portions of the area surrounding the facility and it is not clear which homes may be connected. There may be wells along HWY 150, Sherrills Ford Road, and Island Point Road and spur roads off of these. The closest locations to the CB would likely fall along Sherrills Ford Road to the W and off of Island Point Road to the N, which could be on the order of hundreds of feet or more away from the CB and hydraulically upgradient from the facility. The risk rating given is based on better known PWS well locations. Additionally, there are several PWS well systems in proximity to Marshall: • 0118589 Rehobeth UMC —4000 ft from CB • 0118622 Midway Boat House Grill —1900 ft from CB • 0115254 Riverwood S/D —4000 ft from CB • 0118168 Pine Wood Acres —2200 ft from CB • 0118780 Motts Grove UMC —1600 ft from CB • 0118676 Duke -Marshall on site well —1700 ft from CB • 0118736 Old Country Church —1200 ft from CB Note: Hydrogeologic considerations -- Use to adjust rating due to unique characteristics that should be considered such as wells upgradient, cross gradient, etc. 6. Population Served by Water Supply Wells (referenced above) Potential Rating Rating Description Final Rating 1 0 population 2 0 - 25 people 3 26 - 100 people 4 101 - 200 people 5 > 200 people 5 Comments: Combined population served by the PWS systems is >200. Without a well survey, there is not an estimate of private well users. March 11, 2014 Ash Pond Rating Form Page 3 of 6 Section 2 — Dam Safety Considerations 7. Hazard Classification Potential Rating Rating Description Final Rating 1 Low hazard - Small size 2 Low Hazard - Large size 3 Intermediate Hazard 4 High Hazard - Environmental Concerns 4 5 High Hazard - Loss of Life Comments: 8. Proximity.to Waters of the State Potential Rating Rating Description Final Rating I Located within/above a larger ash reservoir with large amount of available storage 3 Potential coal ash migration constrained by physical barrier 5 Directly adjacent S Comments: 9. State of Structural Stability & Maintenance (use historical worst case scenario) Potential Rating Rating Description Final Rating 1 Notice of Inspection (NOI) with no recommendations 2 NOI with maintenance recommendations 2 3 Notice of Deficiency (NOD) 4 Dam Safety Order (DSO) 5 Enforcement action required Comments: March 11, 2014 Ash Pond Rating Form Page 4 of 6 10. Volume of Facility Potential Rating Rating Description Final Rating 1 < 300 acre-feet 2 300 to 1,500 acre-feet 3 1,500 to 3,000 acre-feet 3 4 3,000 to 9,000 acre-feet 5 > 9,000 Acre-feet Comments: 11. Free Water Content Potential Rating Rating Description Final Rating 1 D - heavy natural vegetation and tree growth 2 D - no standing water, sparse tree gowth 3 25% of reservoir area water covered 4 25% to 75% of reservoir area water covered 4 5 100% of reservoir area water covered Comments: 12. Offsite Drainage Area (DA = Drainage Area, A = Reservoir Area) Potential Rating Rating Description Final Rating 1 Drainage area = Reservoir area 2 Drainage area = I to 3 times reservoir area 2 3 Drainage area = 3 to 6 times reservoir area 4 Drainage area = 6 to 10 times reservoir area 5 1 Drainage area = > 10 times reservoir area Comments: March 11, 2014 Ash Pond Rating Form Page 5 of 6 Section 3 Final Ratings Rating Areas Section 1: Water Quality Considerations_ Final Rating 1. 2. 3. 4. 5. Groundwater Standards Drinking Water Intakes Total Po ulation Served by Intakes Classification Downstream and Discharge Points Distance of Water Supply Wells from the Compliance Boundary 4 S 5 4 4 6. Population Served by Water Supply Wells g SECTION 1 TOTAL 27 Section 2: Dam Safety Considerations 7. Hazard Classification 4 8. Proximity to Waters of the State 5 9. State of Structural Stability & Maintenance 2 10. Volume of Facility 3 11. Free Water Content 4 12. Offsite Drainage Area 2 SECTION 2 TOTAL 20 SECTION 1 + SECTION 2 TOTAL 47 Additional Comments: March 11, 2014 Ash Pond Rating Form Page 6 of 6 ASH POND RATING FORM FACILITY NAME: Mayo NPDES PERMIT NO.: NCO038377 REGION: Raleigh COUNTY: Person Instructions: Rate each facility using the potential rating in the left column and the descriptions in the middle column. A score of 1 indicates the best case whereas a score of 5 indicates the worst case. For the final rating column, put the number next to the description that best matches the facility in consideration. If you believe a different rating is warranted for any category (other than what is listed), then justify alternate rating in the comment section. Section 1— Water Quality Considerations 1. Groundwater Standards Potential Rating RatingDri escption Final Rating 1 An exceedance of pH, iron of manganese 2 Exceedance of chloride, nitrate, sulfate, or TDS 3 Exceedance of aluminum, barium, copper, nickel or zinc 4 Exceedance of boron, cadmium, chromium, selenium, or antimony 5 Exceedance of arsenic, lead, merc , or thallium 5 Comments: Exceedance of thallium. 2. Drinking Water Intakes Potential Rating Rating Description Final Rating 0 No intake 2 Greater than 50 miles downstream 2 3 Greater than 20 miles, but less than orequal to 50 miles downstream 4 Greater than 10 miles, but less than orequal to 20 miles downstream 5 Less than orequal to 10 miles downstream Comments: There are 3 surface water supply intakes greater than 50 miles downstream of the Mayo Facility. (RRO PWS is unfamiliar with the SWTPs in Virginia.) March 11, 2014 Ash Pond Rating Form Page 1 of 6 3. Total Population Served by Intakes Potential Rating Rating Description Final Rating 1 1 - 500 served 2 501 - 3,300 served 3 3,301 - 10,000 served 4 10,001 - 100,000 served 5 > 100,000 served 5 Comments: Based on normal population served by the surface water supply intakes downstream of the Mayo Facility. Potential population served through emergency connections not included. 4. Classification Downstream and Discharge Points (use worst case scenario) Potential Rating Description Final Rating Rating 1 Class C 1 4 Class B 5 High Quality Waters, Outstanding Resource, Waters, Threatened or Endangered Species Present Comments: *Mayo Reservoir is class WS-V waters. This reservoir outlets into Mayo Creek, a Class C waters. Mayo Creek courses north into Virginia, flows into Hyco River, and then into the Dan River west of Clarksville located near, headwaters of Kerr Lake. 5. Distance of Water Supply Wells from the Compliance Boundary (CB) Potential Rating Rating Description Final Rating 1 Wells greater than 1/2 mile 2,640 feet of the CB 2 Wells within 2,000 to 2,640 feet of CB 2 3 Wells within 1,500 to 2,000 feet of CB 4 Wells within 1,000 to 1,500 feet of CB 5 Wells within 1,000 feet of CB Comments: Mayo Reservoir - This survey was completed with google earth with the assumption that specific structures are utilizing well water. City of Roxboro water serves some residences and businesses in this area; rooftops identified in GoogleEarth survey within areas of concern were counted as private wells. Note: Hydrogeologic considerations -- Use to adjust rating due to unique characteristics that should be considered such as wells upgradient, cross gradient, etc. March 11, 2014 Ash Pond Rating Form Page 2 of 6 6. Population Served by Water Supply Wells (referenced above) Potential Rating Rating Description Final Rating 1 0 population 2 0 - 25 people 3 26 - 100 people 3 4 101 - 200 people 5 >200 people Comments Section 2 — Dam Safety Considerations 7. Hazard Classification Potential Rating Rating Description Final Rating 1 Low hazard - Small size 2 Low Hazard - Large size 3 Intermediate Hazard 4 High Hazard - Environmental Concerns ` 4 5 High Hazard - Loss of Life Comments: 8. Proximity to Waters of the State Potential Rating Rating Description Final Rating 1 Located within/above a larger ash reservoir with large amount of available storage 3 Potential coal ash migration constrained by physical barrier 5 1 Directly adjacent 5 Comments: March 11, 2014 Ash Pond Rating Form Page 3 of 6 9. State of Structural Stability & Maintenance (use historical worst case scenario) Potential Rating Rating Description Final Rating 1 Notice of Inspection OI with no recommendations 2 NOI with maintenance recommendations 2 3 Notice of Deficiency OD 4 Dam Safety Order DSO 5 Enforcement action required Comments: 10. Volume of Facility Potential Rating Rating Description Final Rating 1 < 300 acre-feet 2 300 to 1,500 acre-feet. 3 1,500 to 3000 acre-feet 4 3,000 to 9,000 acre-feet ,,;: 4 5 > 9,000 Acre-feet Comments: 11. Free Water Content Potential Rating Rating Description Final Rating 1 D - heavy natural vegetation and tree growth 2 Dry - no standing water, sparse tree growth 3 25% of reservoir area water covered 4 25% to 75% of reservoir area water covered 4 5 100% of reservoir area water covered Comments: March 11, 2014 Ash Pond Rating Form Page 4 of 6 12. Offsite Drainage Area (DA = Drainage Area, A = Reservoir Area) Potential Rating Rating Description Final Rating 1 Drainage area = Reservoir area 2 Drainage area = 1 to 3 times reservoir area 2 3 Drainage area = 3 to 6 times reservoir area 4 Drainage area = 6 to 10 times reservoir area 5 Drainage area = > 10 times reservoir area Comments: Section 3 — Final Ratings Rating Areas Final Rating Section 1: Water Quality Considerations 1. Groundwater Standards 5 2. Drinking Water Intakes 2 3. Total Population Served by Intakes 5 4. Classification Downstream and Discharge Points 1 5. Distance of Water Su2ply Wells from the Compliance Boundary 2 6. Population Served by Water Supply Wells 3 SECTION 1 TOTAL 18 Section 2: Dam Safety Considerations 7. Hazard Classification 4 8. Proximity to Waters of the State 5 9. State of Structural Stability & Maintenance 10. Volume of Facility 4 11. Free Water Content 4 12. Offsite Drainage Area 2 SECTION 2 TOTAL 21 SECTION 1 + SECTION 2 TOTAL 39 Additional Comments: March 11, 2014 Ash Pond Rating Form Page 5 of 6 G� ASH POND RATING FORM FACILITY NAME: Riverbend NPDES PERMIT NO.: NC0004961 REGION: Mooresville COUNTY: Gaston Instructions: Rate each facility using the potential rating in the left column and the descriptions in the middle column. A score of 1 indicates the best case whereas a score of 5 indicates the worst case. For the final rating column, put the number next to the description that best matches the facility in consideration. If you believe a different rating is warranted for any category (other than what is listed), then justify alternate rating in the comment section. Section 1— Water Quality Considerations 1. Groundwater Standards Potential Rating Rating Description Final Rating 1 2 An exceedance of pH, iron or manganese Exceedance of chloride, nitrate, sulfate, or TDS 1 3 Exceedance of aluminum, barium, copper, nickel or zinc 4 Exceedance of boron, cadmium, chromium, selenium, or antimony 5 Exceedance of arsenic, lead, mercury, or thallium Comments: Riverbend's groundwater exceedances are so far limited to pH, iron & manganese 2. Drinking Water Intakes Potential Rating Rating Description Final Rating 0 No intake 2 Greater than 50 miles downstream 3 Greater than 20 miles, but less than orequal to 50 miles downstream 4 Greater than 10 miles, but less than orequal to 20 miles downstream 5 1 Less than orequal to 10 miles downstream S Comments: Charlotte's intake is —3.5 miles downstream, Gastonia and Mount Holly's intakes are —6.4 miles downstream all within Mountain Island Lake. Belmont's intake is next, —14 miles downstream in Lake Wylie. March 11, 2014 Ash Pond Rating Form Page 1 of 5 3. Total Population Served by Intakes Potential Rating RatingFinal Description Rating 1 1 - 500 served 2 501 - 3,300 served 3 3,301 - 10,000 served 4 10,001 - 100,000 served 5 > 100,000 served 5 Comments: that number. Charlotte system serves—805,000 or more. Additional intakes mentioned in #2 would increase 4. Classification Downstream and Discharge Points (use worst case scenario) Rating Potential Rating Description Final Rating 1 Class C 4 Class B 4 5 High Quality Waters, Outstanding Resource Waters, Threatened or Endangered Species present Comments: Surface waters near Riverbend are classified WS-IV, B; CA. S. Distance of Water Supply Wells from the Compliance Boundary (CB) Potential Rating Rating Description Final Rating g 1 Wells greater than 1/2 mile (2,640 feet) of the CB 1 2 Wells within 2,000 to 2,640 feet of CB 3 Wells within 1,500 to 2,000 feet of CB 4 Wells within 1,000 to 1,500 feet of CB 5 Wells within 1,000 feet of CB Comments: No formal well survey has been conducted near Riverbend, but the Catawba Riverkeeper reported a single old private well still in use in the neighborhood to the S of the ponds that is also served by water lines (and presumably across a hydrologic divide) approximately 3000 feet from the CB. Additionally, to the E and ESE of the ponds is a small neighborhood served by private wells, the closest of which is approximately 3500 feet from the CB. Note: Hydrogeologic considerations -- Use to adjust rating due to unique characteristics that should be considered such as wells upgradient, cross gradient, etc. March 11, 2014 Ash Pond Rating Form Page 2 of 5 6. Population Served by Water Supply Wells (referenced above) Potential Rating Rating Description Final Rating 1 0 population 1 2 0 - 25 people 3 26 - 100 people 4 101 - 200 people 5 > 200 people Comments: With no formal well survey and presumably the nearest groundwater users > 0.5 miles away, it doesn't make a lot of sense to tally well users at those distances and greater in this measure as greater distance would mean less risk. Section 2 — Dam Safety Considerations 7. Hazard Classification Potential Rating Rating Description Final Rating 1 Low hazard - Small size 2 Low Hazard - Large size 3 Intermediate Hazard 4 Hi h Hazard - Environmental Concerns 4 5 High Hazard - Loss of Life Comments: 8. Proximity to Waters of the State Potential Rating Rating Description Final Rating 1 Located within/above a larger ash reservoir with large amount of available storage 3 Potential coal ash migration constrained by physical barrier 5 Directly adjacent 5 Comments: March 11, 2014 Ash Pond Rating Form Page 3 of 5 9. State of Structural Stability & Maintenance (use historical worst case scenario) Potential Rating Rating Description Final Rating 1 Notice of Inspection (NOI) with no recommendations 2 NOI with maintenance recommendations 2 3 Notice of Deficient (NOD) 4 Dam Safety Order (DSO) 5 Enforcement action required Comments: 10. Volume of Facility Potential Rating Rating Description Final Rating 1 < 300 acre-feet 2 300 to 1,500 acre-feet 2 3 1,500 to 3,000 acre-feet 4 3,000 to 9,000 acre-feet 5 > 9,000 Acre-feet Comments: 11. Free Water Content Potential Rating Rating Description Final Rating 1 D - heavy natural vegetation and tree growth 2 Dry - no standing water, sparse tree growth 3 25% of reservoir area water covered 4 25% to 75% of reservoir area water covered 4 5 100% of reservoir area water covered Comments: March 11, 2014 Ash Pond Rating Form Page 4 of 5 12. Offsite DrainageArea (DA = Drainage Area, A = Reservoir Area) Potential Rating Rating Description Final Rating 1 Drainage area = Reservoir area 2 Drainage area = 1 to 3 times reservoir area 2 3 Drainage area = 3 to 6 times reservoir area 4 Drainage area = 6 to 10 times reservoir area 5 Drainage area = > 10 times reservoir area Comments: Section 3 — Final Ratings Rating Areas Final Rating Section 1: Water Quality Considerations 1. Groundwater Standards 1 2. Drinking Water Intakes 5 3. Total Population Served by Intakes 5 4. Classification Downstream and Discharge Points 4 5. Distance of Water Supply Wells from the Compliance Boundary 1 6. Population Served by Water Supply Wells 1 SECTION I TOTAL 17 Section 2: Darn Safety Considerations 7. Hazard Classification 4 8. Proximity to Waters of the State 9. State of Structural Stability & Maintenance 10. Volume of Facility 2 11. Free Water Content 4 12. Offsite Drainage Area 2 SECTION 2 TOTAL 19 SECTION 1 + SECTION 2 TOTAL 36 Additional Comments: March 11, 2014 Ash Pond Rating Form Page 5 of 5 FACILITY NAME: Roxboro REGION: Raleigh ASH POND RATING FORM NPDES PERMIT NO.: NCO003425 COUNTY: Person Instructions: Rate each facility using the potential rating in the left column and the descriptions in the middle column. A score of 1 indicates the best case whereas a score of 5 indicates the worst case. For the final rating column, put the number next to the description that best matches the facility in consideration. If you believe a different rating is warranted for any category (other than what is listed), then justify alternate rating in the comment section. Section 1— Water Quality Considerations 1. Groundwater Standards Potential Rating Rating Description Final Rating 1 An exceedance of pH, iron or manganese 2 Exceedance of chloride, nitrate, sulfate, or TDS 3 Exceedance of aluminum, barium, copper, nickel or zinc 4 Exceedance of boron, cadmium, chromium; selenium, or antimony 4 5 Exceedance of arsenic,�lead, mercury, or thallium Comments: Exceedance of cadmium and chromium. 2. Drinking Water Intakes Potential Rating Rating Description Final Rating 0 No intake 2 Greater than 50 miles downstream 2 3 Greater than 20 miles, but less than orequal to 50 miles downstream 4 Greater than 10 miles, but less than orequal to 20 miles downstream 5 Less than orequal to 10 miles downstream Comments: There are 3 surface water supply intakes greater than 50 miles downstream of the Roxboro Facility. (RRO PWS is unfamiliar with the SWTPs in Virginia.) March 11, 2014 Ash Pond Rating Form Page I of 6 3. Total Population Served by Intakes Potential Rating Rating Description Final Rating 1 1 - 500 served 2 501 - 3,300 served 3 3,301 - 10,000 served 4 10,001 - 100,000 served 5 > 100,000 served 5 Comments: Based on normal population served by the surface water supply intakes downstream of the Roxboro Facility. Potential population served through emergency connections not included. 4. Classification Downstream and Discharge Points (use worst case scenario) Potential Rating Description Final Rating Rating 1 Class C 4 Class B 4 (WS-V, B) 5 High Quality Waters, Outstanding Resource Waters, Threatened or Endangered Species present Comments: *Hyco Reservoir is class WS-V, B waters. This reservoir outlets into Hyco River, a Class C waters. The Hyco River courses north into Virginia and then flows into the Dan River west of Clarksville (located near headwaters of Kerr Lake). 5. Distance of Water Supply Wells from the Compliance Boundary (CB) Potential Rating Rating Description Final Rating 1 Wells greater than 1/2 mile 2,640 feet of the CB 2 Wells within 2,000 to 2,640 feet of CB 2 3 Wells within 1,500 to 2,000 feet of CB 4 Wells within 1,000 to 1,500 feet of CB 5 Wells within 1,000 feet of CB Comments: No public or private water supply wells within Y1 mile of the compliance boundary. Note: Hydrogeologic considerations -- Use to adjust rating due to unique characteristics that should be considered such as wells upgradient, cross gradient, etc. March 11, 2014 Ash Pond Rating Form Page 2 of 6 6. Population Served by Water Supply Wells (referenced above) Potential Rating Rating Description Final Rating 1 0 population 2 0 - 25 people 3 26 - 100 people 4 101 - 200 people 5 >200 eo le 5 Comments: : Woodland Elementary School has a service population of 225 located approx. 0.5 miles from edge of possible coal ash. 89 employees served by PWS well at gypsum plant as of sanitary survey (3/31/14), another approximately 50 people served by private wells, based on a GoogleEarth imagery survey counting potential residences. Section 2 — Dam Safety Considerations 7. Hazard Classification Potential Rating Rating Description Final Rating 1 Low hazard - Small size 2 Low Hazard - Large size 3 Intermediate Hazard 4 High Hazard - Environmental Concerns 4 5 High Hazard - Loss of Life Comments: 8. Proximity to Waters of the State Potential Rating Rating Description Final Rating 1 Located within/above a larger ash reservoir with large amount of available storage 3 Potential coal ash migration constrained by physical barrier 5 Directly adjacent 5 Comments: March 11, 2014 Ash Pond Rating Form Page 3 of 6 9. State of Structural Stability & Maintenance (use historical worst case scenario) Potential Rating Rating Description Final Rating 1 Notice of Inspection OI with no recommendations 2 NOI with maintenance recommendations 3 Notice of Deficiency OD 3 4 Dam Safety Order DSO 5 Enforcement action required Comments: 10. Volume of Facility Potential Rating Rating Description Final Rating 1 < 300 acre-feet 2 300 to 1,500 acre-feet 3 1,500 to 3,000 acre-feet 4 3,000'to 9,000 acre-feet 4 5 >'9,000 Acre-feet Comments: 11. Free Water Content Potential Rating Rating Description Final Rating 1 D - heavy natural vegetation and tree growth 2 D - no standing water, sparse tree growth 3 25% of reservoir area water covered 4 25% to 75% of reservoir area water covered 4 5 100% of reservoir area water covered Comments: March 11, 2014 Ash Pond Rating Form Page 4 of 6 12. Offsite Drainage Area (DA = Drainage Area, A = Reservoir Area) Potential Rating Rating Description Final Rating 1 Drainage area = Reservoir area 2 Drainage area = 1 to 3 times reservoir area 3 Drainage area = 3 to 6 times reservoir area 3 4 Drainage area = 6 to 10 times reservoir area 5 Drainage area = > 10 times reservoir area Comments: Section 3 — Final Ratings Rating Areas Final Rating Section 1: Water Quality Considerations 1. Groundwater Standards 4 2. Drinking Water Intakes 2 3. Total Population Served by Intakes _ 5 4. Classification Downstream and Discharge Points _ 4 5. Distance of Water Supply Wells from the Compliance Boundary 2 6. Population Served by Water Supply Wells 5 SECTION 1 TOTAL 22 Section 2: Dam Safe Considerations 7. Hazard Classification 4 8. Proximity to Waters of the State 5 9. State of Structural Stability & Maintenance 3 10. Volume of Facility 4 11. Free Water Content 4 12. Offsite Draina,-e Area 3 SECTION 2.TOTAL 23 SECTION 1 + SECTION 2 TOTAL Additional Comments:. March 11, 2014 Ash Pond Rating )'Form Page 5 of 6 I �J z��si ii �• �+J March 11, 2014 Ash Pond Rating Form Page 6 of 6 ASH POND RATING FORM FACILITY NAME: Sutton REGION: Wilmington NPDES PERMIT NO.: NC0001422 COUNTY: New Hanover Instructions: Rate each facility using the potential rating in the left column and the descriptions in the middle column. A score of 1 indicates the best case whereas a score of 5 indicates the worst case. For the final rating column, put the number next to the description that best matches the facility in consideration. If you believe a different rating is warranted for any category (other than what is listed), then justify alternate rating in the comment section. Section 1— Water Quality Considerations 1. Groundwater Standards Potential Rating Rating Description Final Rating 1 An exceedance of pH, iron or manganese 2 Exceedance of chloride, nitrate, sulfate, or TDS 3 Exceedance of aluminum, barium, copper, nickel or zinc 4 Exceedance of boron, cadmium, chromium, selenium, or antimony 5 Exceedance of arsenic, lead, mercury, or thallium 5 Comments: Exceedance of arsenic, lead, and thallium. 2. Drinking Water Intakes Potential Rating Rating Description Final Rating 1 No intake 0 2 Greater than 50 miles downstream 3 Greater than 20 miles, but less than orequal to 50 miles downstream 4 Greater than 10 miles, but less than orequal to 20 miles downstream 5 Less than orequal to 10 miles downstream Comments: No existing intake. Back up water supply designated at Toomer's Creek (Class WS IV) approximately 2.8 miles downstream. March 11, 2014 Ash Pond Rating Form Page 1 of 5 3. Total Population Served by Intakes Potential Rating Rating Description Final Rating 1 1 - 500 served 0 2 501 - 3,300 served 3 3,301 - 10,000 served 4 10,001 - 100,000 served 5 1 > 100,000 served Comments: See comment above. 4. Classification Downstream and Discharge Points (use worst case scenario) Potential Rating Rating Description Final Rating 1 Class C 1 4 Class B 5 High Quality Waters, Outstanding Resource Waters, Threatened or Endangered Species present Comments: Classified CSw. WS IV at Toomer's Creek located approximately 2.8 miles downstream. 5. Distance of Water Supply Wells from the Compliance Boundary (CB) Potential Rating Rating Description Final Rating 1 Wells greater than 1/2 mile 2,640 feet of the CB 2 Wells within 2,000 to 2,640 feet of CB 2 3 Wells within 1,500 to 2,000 feet of CB 4 Wells within 1,000 to 1,500 feet of CB 5 Wells within 1,000 feet of CB Comments: Cape Fear Public Utility Authority has two wells located approximately 2,200 feet from the compliance boundary and approximately 2,700 feet from the edge of the ash ponds. Note: Hydrogeologic considerations -- Use to adjust rating due to unique characteristics that should be considered such as wells upgradient, cross gradient, etc. March 11, 2014 Ash Pond Rating Form Page 2 of 5 6. Population Served by Water Supply Wells (referenced above) Potential Rating Rating Description Final Rating 1 0 population 2 0 - 25 people 3 26 - 100 people 4 101 - 200 people 5 > 200 people 5 Comments: The water supply wells listed above serve a population of approximately 700. Section 2 — Dam Safety Considerations 7. Hazard Classification Potential Rating Rating Description Final Rating 1 Low hazard - Small size 1 2 Low Hazard - Large size 3 Intermediate Hazard 4 High Hazard - Environmental Concerns 5 Hi h Hazard - Loss of Life Comments: 8. Proximity to Waters of the State Potential Rating Rating Description Final Rating 1 Located within/above a larger ash reservoir with large amount of available storage 3 Potential coal ash migration constrained by physical barrier 3 5 Directly adjacent Comments: March 11, 2014 Ash Pond Rating Form Page 3 of 5 9. State of Structural Stability & Maintenance (use historical worst case scenario) Potential Rating Rating Description Final Rating 1 Notice of Inspection OI with no recommendations 2 NOI with maintenance recommendations 2 3 Notice of Deficient OD 4 Dam Safety Order DSO 5 Enforcement action required Comments: 10. Volume of Facility Potential Rating Rating Description Final Rating 1 < 300 acre-feet 2 300 to 1,500 acre-feet 2 3 1,500 to 3,000 acre-feet 4 3,000 to 9,000 acre-feet 5 > 9,000 Acre-feet Comments: 11. Free Water Content Potential Rating Rating Description Final Rating 1 D - heavy natural vegetation and tree growth 2 D - no standing water, sparse tree growth 3 25% of reservoir area water covered 3 4 25% to 75% of reservoir area water covered 5 100% of reservoir area water covered Comments: March 11, 2014 Ash Pond Rating Form Page 4 of 5 12. Offsite Drainage Area (DA = Drainage Area, A = Reservoir Area) Potential Rating Rating Description Final Rating 1 Drainage area = Reservoir area 1 2 Drainage area = 1 to 3 times reservoir area 3 Drainage area = 3 to 6 times reservoir area 4 Drainage area = 6 to 10 times reservoir area 5 Drainage area = > 10 times reservoir area Comments: Section 3 — Final Ratings Rating Areas Final Rating Section 1: Water Quality Considerations 1. Groundwater Standards 5 2. Drinking Water Intakes [) 3. Total Population Served by Intakes 0 4. Classification Downstream and Discharge Points 1 5. Distance of Water Supply Wells from the Compliance Boundary 2 6. Population Served by Water Supply Wells 5 SECTION 1 TOTAL 13 Section 2: Dam Safety Considerations 7. Hazard Classification 1 8. Proximity to Waters of the State 3 9. State of Structural Stability & Maintenance 2 10. Volume of Facility 2 11. Free Water Content 3 12. Offsite Drainage Area 1 SECTION 2 TOTAL 12 SECTION 1 + SECTION 2 TOTAL 25 Additional Comments: March 11, 2014 Ash Pond Rating Form Page 5 of 5 ASH POND RATING FORM FACILITY NAME: Weatherspoon REGION: Fayetteville NPDES PERMIT NO.: NC0005363 COUNTY: Robeson Instructions: Rate each facility using the potential rating in the left column and the descriptions in the middle column. A score of 1 indicates the best case whereas a score of 5 indicates the worst case. For the final rating column, put the number next to the description that best matches the facility in consideration. If you believe a different rating is warranted for any category (other than what is listed), then justify alternate rating in the comment section. Section 1— Water Quality Considerations 1. Groundwater Standards Potential Rating Rating Description Final Rating 1 An exceedance of pH, iron or manganese 2 Exceedance of chloride, nitrate, sulfate, or TDS 3 Exceedance of aluminum, barium, copper, nickel or zinc 4 Exceedance of boron, cadmium, chromium, selenium, or antimony 5 Exceedance of arsenic, lead, mercury, or thallium 5 Comments: Exceedance of thallium. 2. Drinking Water Intakes Potential Rating Rating Description Final Rating 0 No intake 0 2 Greater than 50 miles downstream 3 Greater than 20 miles, but less than orequal to 50 miles downstream 4 Greater than 10 miles, but less than orequal to 20 miles downstream 5 Less than orequal to 10 miles downstream Comments: March 11, 2014 Ash Pond Rating Form Page 1 of 5 3. Total Population Served by Intakes Potential Rating Rating Description Final Rating 1 1 - 500 served 0 2 501 - 3,300 served 3 3,301 - 10,000 served 4 10,001 - 100,000 served 5 > 100,000 served Comments: 4. Classification Downstream and Discharge Points (use worst case scenario) Potential Rating Rating Description Final Rating 1 Class C 1 4 Class B 5 High Quality Waters, Outstanding Resource Waters, Threatened or Endangered Species present Comments: 5. Distance of Water Supply Wells from the Compliance Boundary (CB) Potential Rating Rating Description Final Rating 1 Wells greater than 1/2 mile 2,640 feet of the CB 2 Wells within 2,000 to 2,640 feet of CB 3 Wells within 1,500 to 2,000 feet of CB 4 Wells within 1,000 to 1,500 feet of CB 5 Wells within 1,000 feet of CB 5 Comments: Note: Hydrogeologic considerations -- Use to adjust rating due to unique characteristics that should be considered such as wells upgradient, cross gradient, etc. March 11, 2014 Ash Pond Rating Form Page 2 of 5 6. Population Served by Water Supply Wells (referenced above) Potential Rating Rating Description Final Rating 1 0 population 2 0 - 25 people 3 26 - 100 people 4 101 - 200 people 4 5 > 200 eo le Comments: Section 2 — Dam Safety Considerations 7. Hazard Classification Potential Rating Rating Description Final Rating 1 Low hazard - Small size 2 Low Hazard - Large size 3 Intermediate Hazard 3 4 1 High Hazard - Environmental Concerns 5 High Hazard - Loss of Life Comments: 8. Proximity to Waters of the State Potential Rating Rating Description Final Rating 1 Located within/above a larger ash reservoir with large amount of available storage 3 Potential coal ash migration constrained by physical barrier 3 5 Directly adjacent Comments: March 11, 2014 Ash Pond Rating Form Page 3 of 5 9. State of Structural Stability & Maintenance (use historical worst case scenario) Potential Rating Rating Description Final Rating 1 Notice of Inspection OI with no recommendations 2 NOI with maintenance recommendations 2 3 Notice of Deficiency OD 4 Dam Safety Order DSO 5 Enforcement action required Comments: 10. Volume of Facility Potential Rating Rating Description Final Rating 1 < 300 acre-feet 2 300 to 1,500 acre-feet 2 3 1,500 to 3,000 acre-feet 4 3,000 to 9,000 acre-feet 5 > 9,000 Acre-feet Comments: 11. Free Water Content Potential Rating Rating Description Final Rating 1 D - heavy natural vegetation and tree growth 2 D - no standing water, sparse tree growth 3 25% of reservoir area water covered 3 4 25% to 75% of reservoir area water covered 5 100% of reservoir area water covered Comments: March 11, 2014 Ash Pond Rating Form Page 4 of 5 12. Offsite Drainage Area (DA = Drainage Area, A = Reservoir Area) Potential Rating Rating Description Final Rating 1 Drainage area = Reservoir area 1 2 Drainage area = 1 to 3 times reservoir area 3 Drainage area = 3 to 6 times reservoir area 4 Drainage area = 6 to 10 times reservoir area 5 Drainage area = > 10 times reservoir area Comments: Section 3 — Final Ratings Rating Areas Final Rating Section 1: Water Quali Considerations 1. Groundwater Standards 5 2. Drinking Water Intakes 0 3. Total Population Served by Intakes 0 4. Classification Downstream and Discharge. Points 1 5. Distance of Water Supply Wells from the Compliance Boundary 5 6. Population Served by Water Supply Wells 4 SECTION 1 TOTAL 15 Section 2: Dam Safety Considerations 7. Hazard Classification 3 8. Proximi to Waters of the State 3 9. State of Structural Stability & Maintenance 2 10. Volume of Facility 2 11. Free Water Content 3 12. Offsite Drainage Area 1 SECTION 2 TOTAL 14 SECTION 1 + SECTION 2 TOTAL 29 Additional Comments: March 11, 2014 Ash Pond Rating Norm page 5 of 5 Attachment 15 Risk Classification Chart 11/30/15 BEGBATES = NCDENR0188619 ENDBATES = NCDENR0188624 BEGATTACH NCDENR0188619 ENDATTACH NCDENR0188624 CUSTODIAN Smith, Eric FILENAME Draft of classification chart for coal ash facilities.pdf DATECREATED = 11/30/2015 DATELASTMOD = 11/30/2015 MDSHASH 7762A494558A34EEAA2FDF1 F2593A267 DOCEXT PDF ATTACHCNT 0 RELATIVITIMA 6 TEXTFILE TEXT\TEXT001\NCDENR0188619.txt Note that the rAfat S'uMP s t�....:'Ddii Z.Allatty - 11 tic:bu<7Y�'riry;% �xC;ly'atlofS SH'NtSeasomu I figh Water 4 eve5 27 We.lj to 'esolve the Sur lion about how to PAO:,! UTIFR)undmvnts appear to have jael!;l Stlk!d On 1.0p: Of fiv$l W 1RCOMI G:rdE.,r m na I vf.�# Vaini%L wz3ys, '11?1'11r"�I.��rl�' tll"� j�!J I b;' n f�xApnnts we O'l Lop cS taN, fachtics :f! Ilse 1 00 ye8�r flood plain and what was surfm','e ww:us', 2itream orlu`..tNr: an vm of ;he as reserwir. For the ash burie'ql aI:Feaal ssg el E, the ekviAwn of die! Felii, wl ream bed thalE covrscs orougl i April 16, 2016 Public Comments Presented at the DEQ Public Hearing on Rankings for Coal Ash Clean -Up in NC H. F. Lee Plant March 10, 2016 Wayne Community College Goldsboro, NC Presented and committed by Janet Smith. Please note: I am submitting comments of what I said at the meeting, like a transcript, in first person. As I spoke I used the words 'you' and 'y'all', sometimes referring to DEQ and sometimes referring to affected residents in the audience. I will make a distinction in these written comments, as to whom I am referring, if it might not be obvious. I had not planned to speak at the Public Hearing. I planned to attend, but not to speak. I don't live in Goldsboro. I don't live in Wayne County, but I grew up on the Neuse River, and all rivers are precious. DEQ gave the Lee Plant a Risk Classification of INTERMEDIATE. I started reading the Risk Classifications for the H. F. Lee Complex in preparation for attending this Public Hearing. It's fifteen pages long and required careful study to understand. I don't know about y'all (residents in the audience); you may have read and understand this already. But there was a lot of technical terminology and I had to look up a lot of terms to know and understand them. I'd like to break it down for you (audience) in case you haven't read it or didn't understand it. Basically at the Lee Plant you have the following: • one active pond • one polishing pond • three inactive ponds Right off the bat, the first question that comes to mind is why is there an active pond if the plant is inactive? Then, DEQ looked at three Key Factors about those five ponds: 1. Groundwater Key Factor 2. Surface Water Key Factor 3. Dam Safety Key Factor • The Groundwater factor was ranked LOW, based on the information DEQ has, that there are no downgradient receptors located 1,500 feet downgradient of the impoundment compliance boundary. What they are saying is there are no contaminated wells downstream of the coal ash ponds. (We all know that is not true.) • The Surface Water factor was ranked HIGH, based on the fact that the ponds are in a 100- year floodplain. With Hurricane Floyd in 1999, the ponds and all the ground surface at the Lee Plant were underwater. • The Dam Safety Water factor ranked the plant HIGH, before repairs are made, and LOW, once the repairs are made. Since it appears these repairs have not been made, the ranking would be HIGH. One of the repairs refers to the installation of a new spillway. That doesn't sound good. Where would the spill go? That is 2 Highs to 1 Low, so the overall ranking should be HIGH. You (DEQ) said you would only consider technical facts presented at these public hearings. Well, these are technical facts. These are your facts! The next section of the report is labeled the Source Characterization Summary. It lists constituents (potentially toxic chemicals) that exist in one or more of the: • Active Basin • Lay of the Land Area • Inactive Basins Note: The Active Basin, Lay of the Land Area, and Inactive Basins comprise the Ash Management Area. This part was unnecessarily complicated but, with enough careful scrutiny, the data can be organized into a much more understandable format. Below is a table of the constituents (potentially toxic chemicals) found in the Active Basin, Lay of the Land Area and Inactive Basins. They were measured based on the Recommended Safe Levels standard. The entire Ash Management Area exceeds the Recommended Safe Levels for numerous chemicals, known to be toxic. Recommended Safe Levels Active Basin Lay of the Land Inactive Basins Aluminum Exceeded Exceeded Exceeded Antimony Exceeded Exceeded Exceeded Arsenic Exceeded Exceeded Exceeded Barium Exceeded Exceeded Exceeded Beryllium Exceeded Exceeded Exceeded Cobalt Exceeded Exceeded Exceeded Cooper Exceeded Exceeded Iron Exceeded Exceeded Exceeded Lead Exceeded Exceeded Exceeded Manganese Exceeded Mercury Exceeded Exceeded Selenium Exceeded Exceeded Exceeded Thallium Exceeded Exceeded Exceeded Vanadium Exceeded Exceeded Exceeded The next 10 pages of the report are labeled Groundwater Supporting Factors and Other Considerations. This appears to be the detailed categories and factors considered in evaluating and determining the ratings or risk. Of the many numerous factors, it includes factors such as: • How close the contamination is to North Carolina water bodies • Whether the contaminated groundwater is being released into the Neuse River • How close is the contamination to the water table • What is the potential loss of life due to a structural breach in the dam • How safe is the dam I examined each factor and each rating. But, before considering any of the others, the report ranks the Lee plant as High Risk, based simply on the Total Amount of Coal Ash at the plant. In going through the 10 pages, I made a tick mark as to whether, based on the factor, the plant was ranked Low, Intermediate, or High Risk. Of the 22 factors... • Seven were ranked as Low risk • Eight were ranked as Intermediate risk, and • Seven were ranked as High risk I guess since eight is greater than seven is how you (DEQ) ranked the plant as Intermediate. But having any ranking as High is High Risk. High Risk trumps all. Having Low or Intermediate risks do not mitigate having High risks. In terms of the safety of the dam, and the potential loss of life with a breach, the Dam Safety Risk Classification is rated HIGH RISK, again before repairs are made and low risk once repairs are made. So it's currently HIGH. And the potential loss of life was ranked HIGH RISK due to a potential breach. That clearly puts the Risk Classification at the Lee Plant as HIGH RISK. I hope this helps you (the audience) understand what DEQ tested for and the results of those tests. And I hope DEQ lives up to its commitment, which was stated in very strong language in its press release about the meetings and on its website. Curiously, Duke Energy completely changed its website during the Public Hearing process. Documentation that was available at the beginning of the Public Hearing is no longer available. On your (DEQ) original website, you (DEQ) stated that "Public participation is a critically important part of the classification process. The information gathered through the public participation process will help inform the department's final proposed classifications." On the new website, it states "The public is encouraged to provide feedback on the draft proposed classifications. Comments will be considered in determining final classification." .... Either way, I hope that's true. Re: Elected Leaders for Coal Ash Cleanup H.F. Lee Steam Station We, the undersigned elected officials, are concerned about the danger coal ash presents for our communities. Coal ash is currently found in leaking, unlined pits across the state and contains a toxic slurry of heavy metals that threaten nearby communities. We ask that state government leaders and state regulators take appropriate action to require the removal of coal ash out of all unlined pits and into safer lined storage away from our waterways. Please ensure that coal ash ponds and landfills do not put at risk the safety, health, and economic well-being of downstream communities, receiving communities, and communities along transportation routes. Signed, Joe Scott, Mt. Olive City Council Member Ray Thompson, Mt. Olive City Council Member Thomas P. Uzzell, Wayne County Soil and Water Conservation District Vice Chair COAL ASH, RACE & CLASS IN NORTH CAROLINA Libbie Weimer, MCRP April 181h, 2016 The following document presents profiles of the fourteen coal ash sites and two permitted coal ash landfills in North Carolina. The report begins with summaries of data collected across all sites. Then, the report details the sites. For each site, the report presents information about the residents within three study distances— 1km, 3km and 5km from the edge of the pond or landfill. For each site and each study distance, the profile contains data on 1) demographics including population and population density, race and ethnicity, and income; 2) cumulative impacts from other toxic facilities including number of facilities and pounds of onsite toxic releases from those facilities. Each site profile summarizes this information in the final measure, 3) an environmental justice index score that compares the 1 km, 3 km, and 5 km study level information to three regions: the state, the county, and the locality. The environmental justice index incorporates impacts on low-income communities, communities of color and cumulative impacts into one score for each site. For a more detailed explanation of the all methods used to create these profiles, please see the appendix. The accuracy of the results is limited by the data available in the U.S Census. Due to racial and economic segregation, the report may overestimate or underestimate the impact of coal ash on communities of color and/or low-income communities. While this problem exists with all small -area studies, unfortunately, the census is especially ill -suited for research involving rural communities. The limitations of this analysis highlight the importance of ground-truthing the data by collaborating with members of the communities profiled in this report. REPORT SUMMARIES A Asheville Dan River y •Roxboro 8elews Creek A Mayo Buck Marshall Cape Fe � _4 Brickhaven Riverbend Colon Mill A Lee Cliffside Alter Weatherspoor Legend Sutton A Operational Coal Plants Closed Coal Plants 0 40 80 160 Structural Fill Sites Miles Figure 1. Locations of the fourteen coal ash ponds and two permitted coal ash landfill sites, with North Carolina county borders shown for reference. POPULATION Selews Allen Asheville Creek 30K 25K 20K 10K 5K OK . E E E E E E [rt1 U') [r] U3 Site Name ( Analysis Level Suck Cape Fear Cliffs ide Ilan River Lee Marshall Mayo Riverbend Roxboro Sutton Weathers.. 1000 900 ^u00 700 600 �. 4D0 300 200 100 —��■ _ 0 E E E E E E E E E E E E E E E E E E Y Y Y s Y Y Y Y Y Y Y Y Y Y Y Y Y Y RACE/ETHNICITY Site Name ! Analysis Level Bel ews Allen Asheville Creek Buck Cape Fear ClifFside Dan River Lee Marshall Mayo Riverbend Roxboro Sutton Weathers,. 0.6 0.2 0.0 0.4 0.3 1' ST m 0.2 0.9 0.0 0.3 Q 0.2 U 0.0 NG State % Black inD MENNEN Cry ui r Cr1 LF] Cri U13 r Cr] V] Cry U3 M U3 r n n n n r n lf] r n n n n r n lf] r In M r n ul] Site Name d Arralysis Level Belem Allen Asheville Creek Buck Ca e�Fear CliFlside Dan River Lee m shall Mayo Riverbend Roxboro Sutton Weathers- St€a INCOME 80 70K as E 60K Sal( 40'K 30 K 20K 10K teMedian Income OK I I I I I I I 1 I 1111111111111 1"! E E E E E E E G E E E G c E� c E E E E E E G E E E E E E E G G G G E_ E_ E_ G E E_ E_ G Y Y Y s Y Y Y Y Y Y Y Y s1 Y - - Y - - - Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y I ['T] Lh I M Lr) I n V) I n V3 r &y U-i I M Ui r rf] U9 I M Ln r n 03 1 n 03 1 n Ul I - Ui r n V3 r M Ln LEE POWER STATION DEMOGRAPHIC ANALYSIS POPULATION Population Count Population Density (people per sq. mi.) Site Name 1km 3km 5km 1km 3km 5km Lee 362 4,155 11,138 173 215 62 RACE/ % Non -white % Black % Latino ETHNICITY Site Name 1km 3km 5km km 3km 5km 1km 3km 5km Lee 45.0% 27.2% 27.7% [38.9%21.6% 19.1% 4.3% 3.7% 7.5% INCOME Median Income Estimate Site Name 1km 3km 5km Lee $ 37,929 $ 44,019 $ 45,132 CUMULATIVE IMPACTS SITE NAME REFERENCE COUNTIES) ONE OR MORE TRI % OF COUNT(IES)' % OF COUNT(IES)' TRI (*ACTIVE COAL SITES W/IN 5KM TRI SITES W/IN ONSITE RELEASES PLANT) BUFFER 5KM BUFFER W/IN 5KM BUFFER Lee Wayne Y 14% 6% Closest City: Goldsboro Plant Status: Closed Coal Ash Pond Acreage: 516 DEQ Site Prioritization: Intermediate ENVIRONMENTAL JUSTICE INDEX — LEE Indicator Race/Ethnicity Income C Reference Census Region State County Census Tract State County Tract Demographic Information J }' t Q W W cc C N G7 Y ° Y c co Ln Ln U U U U H O °- }' c +' o � ° Z `° m v UI UI UI UI UI UI � Q vVi J o O Y = ° f6 Z ca J I I J I I W Z Z Z Z Z Z Q 3 Q V C 2 DIST. UI UI UI U U U \ \ \ � \ \ W VI z u H O O a O Z m v~iI cm~nI vJ~iI oQC oo 00 x x x x x x 6 0 x 7 362 163 141 15 37,929 1 km x 1 0 x 2 4,155 1,131 897 153 44,019 3 km x x 2 0 x 3 11,138 3,082 2,128 837 45,132 5 km MEAN 4.00 North Carolina League of Slow CONSERVATION VOTERS PO Box 12671 Raleigh, NC 27605 www.ncicv.org 1 919.839.0006 To: Debra Watts, NC Division of Water Resources, Groundwater Protection Section, NC Department of Environmental Quality From: Members of the NC League of Conservation Voters Date: April 18, 2016 Re: Reclassify H.F. Lee Power Station as "high risk" Dear Ms. Watts: We are writing to ask the NC Department of Environmental Quality to protect North Carolina's clean water and communities from the dangers posed by arsenic, chromium and other pollutants by re-classifying the H.F. Lee Power Station as "high risk." Chromium, manganese, and other dangerous pollutants have been detected at levels well above standards in groundwater near the coal ash pits. Chromium is a particularly dangerous carcinogen, while manganese is associated with nervous system and muscle problems. We simply cannot allow any additional delay in moving the dangerous coal ash from its current leaking, unlined ponds at the Lee Power Station. Nearly 128,000 people rely on drinking water intakes downstream — and they are relying on you to act now. Please reclassify the Lee Station as "high risk." Signed, 64 NCLCV members Name Zip Code Katie Todd 27703 Carrie Clark 27604 jeff mcdermott 27607 Nelida Rivas 27616-7867 Cody Cavenaugh 28466 eileen juric 27605 Tom Winstead 27606 James Bengel 27591 Victor Lowell 27614 William Larson 27534 Lynne C. 27529 Jasmina Bricic 28504 Eloise Grathwohl 27514 Peter Hickey 28590 Travis Holland 28385 Deborah Campfield 27529 Jamie Heath 27834 Jay Newhard 27858 Jean White 27604 John Hinnant 27893 Connie Headrick 27896 Diane Foster 27529 Deborah Parker 27520 Michael Eisenberg 27613 Tish Gay 27597 Richard Hammer 27613 Rebecca Burmester 27612 Mary Loughlin 28716-2613 Henrietta Jenrette 27613 Ann Campbell 27614 Celeste Winterberger 27616 James Womble 27607 Shoshana Serxner-Merchant 27607 Cindy Davenport 27614 William Dawson 27616 Erin Hebbe 28803 Dale Bridgers 27534 Elizabeth McWhorter 27278 Bradford Crumb 28590-8688 Michael Pope 27502 Paul Taylor 27604 Steven Baldwin 27712 Carson Monteith 27609 Sara Felsen 27606 Janet Smith 27858 Kristine Stochaj 27871 Richard Arnow 27803 Russell James 28405 Maggie Hurst 28573 Laura Smith 27604 Donna Etheridge 27607 Ter Wils 27530 Pam Robbins 27604 D Brown 27624 Howard Lazoff 27591 robert hartwig 27607 Ercel Dotson 27523-5611 virginia clute 27527 Darlene Hamilton 27604 Lynne Carmichael 27803 Jim Amerault 27597-7312 Erika Moss 27601 Matt Revels 27604 Fred Exit 27611 National Ash Management Advisory Board Dr. John L. Daniels, P.E. Dr. Jeffrey C. Evans, P.E. Dr. William E. Wolfe, P.E. Chair Groundwater Subcommittee Chair Closure Plan Subcommittee Chair Dr. Susan E. Burns, P.E., Member Mr. Bob Deacy, Member Dr. Garrick E. Louis, Member Dr. Patricia D. Galloway, P.E. Member and Project Management Oversight Board Chair Dr. Robert B. Jewell, Member Dr. Lawrence L. Sutter, Member Dr. Krishna R. Reddy, P.E., Member Dr. Joyce S. Tsuji, DABT, Member April 5, 2o16 Mr. Tom Reeder Assistant Secretary North Carolina Department of Environmental Quality 217 West Jones Street Raleigh, NC 27603 RE: National Ash Management Advisory Board Comments on Proposed Risk Classifications Dear Mr. Reeder, This letter is written in response to the North Carolina Department of Environmental Quality's (DEO) request for public comment on its proposed risk classifications of coal ash impoundments. Our comments are directed at impoundments which have proposed classifications of low -intermediate, intermediate, and high, according to DEQ's application of the Coal Ash Management Act (CAMA). This letter has been compiled, reviewed and endorsed by the National Ash Management Advisory Board (NAMAB). Note that Duke Energy is required to actively maintain the NAMAB for compliance with its Plea Agreement, as per United States of America v. Duke Energy Business Services, LLC, and settlement in the United States District Court for the Eastern District of North Carolina, Western Division. The NAMAB is an independent group of experts chartered through Duke Energy and managed by the University of North Carolina at Charlotte (UNC Charlotte). Board members provide advice to Duke Energy, but they are contracted with and report to UNC Charlotte. The NAMAB has been integrally involved in the review of groundwater assessment plans, comprehensive site assessments, and corrective action plans, which have been submitted to DEQ Likewise, it has participated in the review of stability and engineering related assessments and with the implementation of NAMAB-recommended health and environmental assessments of risk. While licensed professionals are responsible for these work products, the group is sufficiently aware of the site -specific conditions to which the CAMA risk classification criteria are being applied. For example, licensed engineers and geologists, with support from health and environmental risk assessors, have determined that there is no imminent hazard. Those same professionals have determined that existing conditions at these sites do not present a substantial likelihood that death, serious illness, severe personal injury, or a substantial endangerment to health, property, or the environment will occur. In the abstract, a risk classification system is logical. In reality, DEQs risk classification cannot be de -coupled from the prescriptive remedy approach defined by CAMA. A risk classification of intermediate or high (for instance high priority as prescribed in the case of Asheville, Dan River, Riverbend and Sutton) by law requires excavation and re - disposal to a new location without a scientific basis, and without consideration of broader immediate and life cycle impacts to communities and the environment. Moreover, aggressive closure schedules preclude the pursuit of beneficial use opportunities. Excavation of coal ash is one method of addressing site's groundwater or stability concerns. However, based on holistic and life cycle considerations, it may not be a safe, effective and sustainable alternative. Other alternatives either individually or in combinations, such as capping, monitored natural attenuation, slurry cutoff walls, in -place stabilization/fixation, pumping wells, permeable reactive barriers and volume reduction of impounded ash through escalation of beneficial use, should be considered and compared on an impoundment by impoundment basis to develop an effective, safe and sustainable remedial strategy. The efficacy of these alternative methods increases with the amount of ash in any given location, i.e., the larger the impoundment, the smarter we need to be. The environmental and geotechnical remediation business is very mature and has evolved beyond a "dig and haul" mentality as the best and most environmentally protective solution. The additional risk imposed by excavating and transporting ash from one location to another can exceed the potential risk posed by leaving the ash in place. Risk drivers include the statistical certainty of traffic fatalities and injuries, as tabulated by the National Highway Traffic Safety Administration. Likewise, excavation results in ecological disturbance, ongoing site releases from ash disturbance for years and broader environmental impacts from resource use and emissions, as noted by the U.S. Environmental Protection Agency (EPA). These risks and impacts should be calculated and considered before embarking on the mass movement of tens of millions of tons of material. Licensed engineers and scientists have the education and experience needed to select and design the means, methods and timeline for closure activities. It may be appropriate for legislation to define the initiation of closure activities, but it should not stipulate a prescriptive approach with specific completion dates. The latter depends on site -specific details that are encountered as data are collected and professionally evaluated. This logic is understood by the environmental professionals as well as the EPA in reference to its approach to evaluating corrective action: "EPA understands that there are a variety of activities that may be necessary in order to select the appropriate remedy (e.g., discussions with affected citizens, state and local governments; conducting on -site studies or pilot projects); and, once selected, to implement the remedy (e.g., securing on -site utilities if needed, obtaining any necessary permits, etc.). That is why EPA does not find it appropriate to set specific timeframes for selecting the remedy or to begin implementing the selected remedy." This logic was incorporated into CAMA, given the provision for the Coal Ash Management Commission (CAMC). The CAMC existed to perform several tasks, one of which was to "Review and make recommendations on statutes and rules related to the management of coal ash". That provision was intended to allow for a statutory response to evolving data and analysis as has accumulated to date. Unless the CAMA language for intermediate and high risk (and for that matter, for high priority sites) is changed, the appropriate risk classification for virtually all impoundments is "Low". This is because a risk classification of "Low" allows for all options to be considered, including full excavation, supported by the science and engineering and protective of human health and the environment. This will allow DEQto review and approve a rational closure option that is protective of the public and environment, based on site -specific conditions. We would be pleased to meet with you or other DEQstaff at any time. Our board is composed of highly credentialed and published experts with many years of experience on the relevant subjects from here and abroad. And we are independent. Respectfully, Dr. John L. Daniels, P.E., Chair (Professor and Chair of Civil and Environmental Engineering, UNC Charlotte) Signed on behalf of entire NAMAB: Dr. Jeffrey C. Evans, P.E., Groundwater Subcommittee Chair (Professor and Chair of Mechanical Engineering, Bucknell University) Dr. William E. Wolfe, P.E., Closure Plan Subcommittee Chair (Professor Emeritus of Civil, Environmental and Geodetic Engineering, The Ohio State University) Dr. Patricia D. Galloway, P.E., member and Project Management Oversight Board Chair (President and CEO of Pegasus Global Holdings, Inc.) Dr. Susan E. Burns, P.E., member (Georgia Power Distinguished Professor of Civil and Environmental Engineering, Georgia Institute of Technology) Dr. Robert B. Jewell, member (Senior Research Engineer, University of Kentucky) Dr. Lawrence L. Sutter, member (Professor of Materials Science and Engineering, Michigan Technological University) Dr. Garrick E. Louis, member (Associate Professor of Systems Engineering, University of Virginia and Science Advisor, U.S. Department of State) Mr. Bob Deacy, member (Senior Vice President, Tennessee Valley Authority) Dr. Krishna R. Reddy, P.E., member (Professor of Civil and Environmental Engineering, University of Illinois at Chicago) Dr. Joyce S. Tsuji, DABT, member (Principal and Board -Certified Toxicologist, Exponent, Inc.) cleanenergy.org Southern A111once for Clean Energy April 18, 2016 N.C. Division of Water Resources Groundwater Protection Section N.C. Department of Environmental Quality Attn: Debra Watts 1636 Mail Service Center Raleigh, NC 27699-1611 VIA E-MAIL RE: Public Comments on DEQ's Draft Ratings for Duke Energy's Coal Ash Impoundments Dear Ms. Watts, 1.866.522.SACE www.cleanenergy.org P.O. Box 1842 Knoxville, TN 37901 865.637.6055 46 Orchard Street Asheville, NC 28801 828.254.6776 250 Arizona Avenue, NE Atlanta, GA 30307 404.373.5832 P.O. Box 310 Indian Rocks Beach, FL 33785 954.295.5714 P.O. Box 13672 Charleston, SC 29422 843.225.2371 Thank you for the public comment opportunity regarding DEQ's draft ratings for Duke Energy's coal ash impoundments. I'm pleased that Duke is already required to move some of its coal ash to proper storage. I'm writing to urge you to rank every coal ash impoundment in North Carolina as high or intermediate priority. Duke Energy should be required to remove all of the coal ash at each of its 14 power plants sites to dry, lined storage away from our waterways and groundwater, and from our most vulnerable communities such as low-income communities or communities of color Duke's leaking coal ash impoundments across the state continue to threaten ground and surface water. State health officials advised communities close to Duke's facilities not to drink their well water because of harmful pollutants like vanadium and hexavalent chromium. No family should have to question the safety of their water. Yet rating impoundments as low risk would allow Duke to cap coal ash in place, with nothing to stop groundwater from mixing with the ash and carrying contamination to surrounding communities and waterways. DEQ's rating process offers the best opportunity to properly deal with Duke's coal ash pollution and ensure the health and safety of NC communities. Please ensure Duke's coal ash is moved to lined, dry storage, away from our rivers and waterways and our most vulnerable communities Thank you for your consideration, Adam Reaves High Risk Energy Coordinator Southern Alliance for Clean Energy (SACE) adam@cleaneneryg.org 828.254.6776 ext. 35 North Carolina Doug Franklin, Hayesville Sally MacMillan, Arden Jody McClung, Weaverville Greg Hamby, Kitty Hawk Doris Whitfield, Raleigh David Loven, Chapel Hill Chris Berg, Flat Rock Connie Leeper, Durham Frank Bennett, Raleigh Marcia Bennett, Raleigh Michael Morgan, Swannanoa M. Hazeltine, Sunset Beach Janet Smith, Greenville Jennifer Weiss, Raleigh Beth Ullmer, Asheville Margaret Horner, Leland Steve Miller, Asheville Jeannie McKinney, Durham Jane Laping, Asheville Ellen Chelmis, Asheville Sarah Gilliam, Asheville Sarah Davis, Raleigh Elizabeth Bonzo-Savage, Madison Mamie Colburn, Asheville Jackson Leonard, Greensboro Maxwell DeHoll, Asheville Graham March, Asheville Victoria Carlisle, Asheville Rhonda Bolton, Hendersonville Evan Willeford, Asheville Shelby Sopina, Raleigh Miles Neyen, Belmont Molly Turner, Asheville Banna Weldense, Asheville Kaia Rubin, Asheville Anna Emslie, Asheville Janet Smith, Greenville Patricia Hedrick, Charlotte Adam Reaves, Asheville Alan Spencer, Waynesville Nancy Hitchcock, Hendersonville John Coyle, Leland cleanenergy.org Clean Energy w Cathy Williams, Hayesville Gary Clontz, Clyde Doug Wingeier, Asheville Ann Karson, Candler Frank Contreras, Asheville Ann Kieffer, Asheville Elizabeth Adams, Cary Tennessee Marty Menane, Knoxville Lorraine Barker, Nashville Nicholas Stamper, Philadelphia Florida Britany Perry, Longwood Kimber Strawbridge, Jacksonville Janice Hallman, Clearwater Beach Sean McLaughlin, Clermont