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HomeMy WebLinkAboutNC0022406_BCSS Interim Action Plan_20160502F)2 Interim Action Plan Belews Creek Steam Station Accelerated Remediation April 29, 2016 Prepared for: (� DUKE �' ENERGY Duke Energy Carolinas, LLC I Accelerated Remediation Interim Action Plan — Belews Creek Steam Station �� Background Table of Contents 1 Background............................................................................................................................. 1.1 Area of Interest.............................................................................................................. 1.2 Constituents of Interest................................................................................................. 1.3 On-site Landfills and Structural Fill............................................................................... 2 Interim Action Objectives......................................................................................................... 3 Additional Assessment Activities............................................................................................. 3.1 Status............................................................................................................................ 4 Interim Action Tasks................................................................................................................ 4.1 Property Acquisition...................................................................................................... 4.2 Proposed Interim Action................................................................................................ 4.3 Evaluation of Potential Groundwater Impacts from Onsite Landfills and Structural Fill 4.3.1 Findings............................................................................................................ 5 Schedule.................................................................................................................................. Tables Table 1 Groundwater Analytical Results (Accelerated Remediation AOI) Table 2 AOW Analytical Results (Accelerated Remediation AOI) Figures Figure 1 Site Location Map Figure 2 Additional Assessment Wells and Accelerated Remediation AOI Figure 3 Interim Action Field Investigation .1 .1 .1 .2 .3 .4 .4 .5 .5 .5 .6 .8 10 Duke Energy Carolinas, LLC I Accelerated Remediation Interim Action Plan — Belews Creek Steam Station �� Background 1 Background The North Carolina Department of Environmental Quality (NCDEQ) provided Duke Energy Carolinas, LLC (Duke Energy) a letter on March 28, 2016 regarding accelerated remediation at the Belews Creek Steam Station (BCSS) site (Figure 1). The Settlement Agreement (Agreement) between NCDEQ and Duke Energy dated September 29, 2015 required Duke Energy to implement accelerated remediation at BCSS to address off-site groundwater impacts. The off-site groundwater impacts are limited to an area northwest of the ash basin. Duke Energy provided an "accelerated remediation summary" to NCDEQ on February 17, 2016 for BCSS that outlined the proposed actions for accelerated remediation. The NCDEQ letter dated March 28, 2016 provided technical direction regarding the path forward for accelerated remediation and requested responses to specified items be submitted to NCDEQ by April 30, 2016. This Interim Action Plan (Plan) was developed to provide those responses. For BCSS, the accelerated remediation summary provided on February 17, 2016 indicated that accelerated remediation was contingent on the purchase of an adjacent 2.23 -acre parcel located northwest of the BCSS ash basin. The 2.23 -acre parcel is located within the area referred to as the Area of Interest (AOI) for the purposes of accelerated remediation at BCSS. 1.1 Area of Interest Groundwater and area of wetness (AOW) sampling results presented in the 2015 Comprehensive Site Assessment (CSA) indicated that offsite groundwater impacts attributable to the ash basin were present northwest of the ash basin in the area of the 2.23 -acre parcel not owned by Duke Energy. This parcel is located immediately west of Middleton Loop Road and northwest of the ash basin. For purposes of accelerated remediation for offsite groundwater impacts at BCSS, the AOI is considered to be the area northwest of the ash basin in the immediate vicinity of the 2.23 -acre parcel not owned by Duke Energy, and is depicted on Figure 2. Groundwater flow direction in this area is to the northwest toward the Dan River. The receptor survey included in the CSA indicated: 1) there are no private water supply wells located within or downgradient from the AOI, and 2) the nearest receptor downgradient of the northwest corner of the ash basin is the Dan River, located approximately 2,000 feet northwest of this area. The CSA recommended installation of additional groundwater monitoring wells and collection of additional assessment data to further delineate the extent of groundwater impacts west/northwest and downgradient of the ash basin and Middleton Loop Road. 1.2 Constituents of Interest Groundwater sampling results from the 2015 CSA found exceedances of 2L Standards or IMACs for beryllium, cobalt, manganese, iron, thallium, and total dissolved solids in Duke Energy Carolinas, LLC I Accelerated Remediation Interim Action Plan — Belews Creek Steam Station FN monitoring wells located northwest of the ash basin. Exceedances of 2L Standards or IMACs were also reported for antimony, manganese, iron, vanadium however these results were less than the proposed provisional site background concentrations. The monitoring wells are located on Duke Energy property west of Middleton Loop Road. The AOI (containing the 2.23 -acre parcel) is located between these wells and the ash basin. The CSA also sampled AOW locations downgradient of the monitoring wells with exceedances and the AOI. Samples collected at the AOWs showed exceedances of 2L Standards or IMACs for cobalt, chromium, manganese, and vanadium, and elevated concentrations of boron, chloride, and total dissolved solids. 1.3 On-site Landfills and Structural Fill The March 28, 2016 letter from DEQ also requested an evaluation of the potential contribution of the on-site landfills and structural fill to groundwater at and off-site of the facility. This evaluation is provided in Section 4.3. As described in the CSA, there are three landfills and one structural fill at the BCSS site. The Craig Road Ash Landfill and FGD Residue Landfill are located south of the BCSS and are not hydrogeologically connected with the ash basin. The Pine Hall Road Ash Landfill is located adjacent to and hydrogeologically upgradient of the ash basin. The ash structural fill is located south of Pine Hall Road and the ash basin, and based on 2015 CSA data it appears groundwater does not flow from the ash basin toward the structural fill. The locations of these facilities are shown on Figure 1. Duke Energy Carolinas, LLC I Accelerated Remediation Interim Action Plan — Belews Creek Steam Station �� Interim Action Objectives 2 Interim Action Objectives The following items were requested to be submitted to NCDEQ by April 30, 2016: 1. A report that summarizes the results of post -CSA additional assessment characterization effort; 2. A status report that provides details concerning the pending property purchase in order to assess the viability of remedial action strategy; and 3. An evaluation of potential off-site migration of impacted groundwater, including any analyses of a hydraulic capture system, and an evaluation of the potential contribution of the on-site landfills and structural fill to impacted groundwater at and offsite of the facility. A status summary of the post -CSA additional assessment effort is provided in Section 3. In addition, NCDEQ indicated that if the adjacent offsite property cannot be acquired by April 30, 2016, then a revised Plan should be submitted with a reasonable timeframe. At the time of this Plan submittal, Duke Energy is contemplating purchase of the 2.23 -acre parcel as described in Section 4. As requested by NCDEQ, Duke Energy plans to implement additional field investigation to evaluate viable accelerated remediation alternatives to address offsite groundwater impacts associated with the AOI. Following completion of the additional field investigation, a feasible and appropriate remedial alternative will be chosen if the offsite property is not acquired by Duke Energy. The additional field investigation and remedial alternatives currently under consideration are described in Section 4. Duke Energy Carolinas, LLC I Accelerated Remediation Interim Action Plan — Belews Creek Steam Station �� Additional Assessment Activities 3 Additional Assessment Activities Based on 2015 site investigation results, areas at the site were identified where the installation of additional monitoring wells may refine site information. Duke Energy is currently installing an additional 23 groundwater monitoring wells to provide this additional information. 3.1 Status As of April 21, 2016, 14 of the 23 proposed additional groundwater monitoring wells have been installed at the site. Duke Energy plans to complete installation of the remaining proposed additional monitoring wells before May 31, 2016. Of the 14 wells installed, Duke Energy collected groundwater samples from 5 wells located in the accelerated remediation AOI. The additional wells, which were sampled on March 30 and 31, 2016, include GWA-18D, GWA-19S, GWA-20D, GWA-21 S, and GWA-21 D. The analytical results are provided in Table 1. Along with results from the additional wells, Table 1 also includes analytical results for samples collected from other existing CSA monitoring wells located in the vicinity of the accelerated remediation AOI during the CSA and March/April 2016 sampling events. The recent sample results indicate concentrations of boron, chloride, and TDS exceed their 2L Standards in the deep flow layer (in GWA-20D) on Duke Energy property between the ash basin and the 2.23 -acre parcel. Boron also exceeded its 2L Standard in the shallow flow layer (in GWA-19S) downgradient and west of the 2.23 -acre parcel. Due to these new findings, Duke Energy is planning to install three additional monitoring wells (shallow, deep, and bedrock) immediately west of the 2.23 -acre parcel to better assess groundwater quality and flow conditions surrounding the offsite property. The proposed well nest (GWA-27S/D/BR) is depicted on Figure 2. In addition to groundwater monitoring wells, the AOWs located downgradient and northwest of the ash basin (S-2 through S-5) were sampled in March/April 2016 and the analytical results are provided in Table 2. The results from March/April 2016 are similar to the results included in the 2015 CSA. Duke Energy Carolinas, LLC I Accelerated Remediation Interim Action Plan — Belews Creek Steam Station �� Interim Action Tasks 4 Interim Action Tasks Duke Energy has been actively pursuing purchase of the adjacent 2.23 -acre parcel not owned by Duke Energy located northwest of the ash basin. The timeframe in which the property acquisition will occur is uncertain at this time. Due to this uncertainty, Duke Energy is planning to conduct an additional field investigation as an interim action to evaluate groundwater remedial alternatives. A summary of the property acquisition status and the proposed interim action are provided in the sections below. An estimated schedule for the interim action is provided in Section 5. 4.1 Property Acquisition Duke Energy is contemplating purchase of the 2.23 -acre parcel northwest of the ash basin with the intent to control property use. If property purchase is not made, Duke Energy is committed to accelerating the proposed interim actions described below such that the offsite groundwater impacts will be addressed in the timeframe provided in Section 5. 4.2 Proposed Interim Action The purpose of additional field investigation is to determine the most suitable groundwater remediation approach for the AOI. The selected measure will be implemented on Duke Energy property upgradient of the 2.23 -acre parcel, between the parcel and the BCSS ash basin. Options to be evaluated include: Installation of a groundwater extraction system between the parcel and ash basin. 2. Installation of a subsurface barrier wall (e.g., slurry trench barrier wall, grout curtain, sheet pile barrier wall, or deep soil mixing barrier wall) between the parcel and ash basin. 3. A combination of options 1 and 2. The optimal configuration of a barrier wall and/or location and number of extraction wells will be evaluated through the incorporation of newly acquired data into the groundwater flow model that was constructed for the BCSS Corrective Action Plan (CAP2 model). Proposed field efforts for the investigation consist of advancement of five soil borings, installation of one 6 -inch diameter pumping well, installation of two temporary observation wells, and performing an aquifer pump test. The locations of proposed soil borings, extraction well, and observation wells are depicted on Figure 3. During initial stages of the project, necessary NCDEQ permit applications will be submitted and obtained. After investigation field efforts, project data will be evaluated to provide a recommended approach for addressing groundwater impacts in the accelerated remediation AOI. Duke Energy will provide an evaluation and recommended remedial approach report to NCDEQ for review prior to implementing full-scale remedial design. Duke Energy Carolinas, LLC I Accelerated Remediation Interim Action Plan — Belews Creek Steam Station �� Interim Action Tasks 4.3 Evaluation of Potential Groundwater Impacts from Onsite Landfills and Structural Fill Provided below are descriptions of each landfill unit and the structural fill as well as summaries of previously conducted assessments and findings. Craig Road Ash Landfill (NCDEQ DWM Permit No. 8504) This landfill is in operation and accepts coal combustion products generated at BCSS. The landfill was constructed with an engineered liner system and is located on the south side of Belews Lake and therefore not hydrogeologically connected with the ash basin. Semi-annual groundwater monitoring is performed in accordance with the requirements of the permit and the results are submitted to NCDEQ Division of Waste Management. In 2012, HDR prepared and submitted an assessment report to NCDEQ for exceedances of 2L and 2B Standards at Phase 1 of the landfill (Groundwater Assessment, Belews Creek Steam Station, Craig Road Ash Landfill, December 21, 2012). The assessment report concluded that the exceedances evaluated were naturally occurring and not related to impacts from the landfill. FGD Residue Landfill (NCDEQ DWM Permit No. 8505) This landfill is in operation and accepts coal combustion products generated at BCSS. The landfill was constructed with an engineered liner system and is located on the south side of Belews Lake and therefore not hydrogeologically connected with the ash basin. Semi-annual groundwater monitoring is performed in accordance with the requirements of the permit and the results are submitted to NCDEQ Division of Waste Management. HDR previously prepared and submitted a groundwater assessment report to NCDEQ DWM for exceedances of 2L Standards at the landfill (Groundwater Assessment Belews Creek Steam Station FGD Residue Landfill, Permit No. 8505. October 5, 2012). The assessment concluded, with the exception of exceedances for iron, manganese, sulfate and total dissolved solids (TDS) at two monitoring wells, the groundwater exceedances were due to naturally occurring conditions. The assessment recommended the installation of an additional monitoring well. The additional well was installed and a supplemental groundwater assessment report (dated June 4, 2015) was submitted to NCDEQ DWM. The supplemental assessment found that the exceedances for iron and manganese were naturally occurring but that the exceedances for sulfate, TDS, and the newly occurring exceedances for selenium could be attributed to either deposition of gypsum adjacent to the landfill or leachate leaking from the landfill. Due to these variables, and in some cases decreasing concentrations of these constituents, the supplemental assessment recommended that if the exceedances continued for the subsequent three sampling events, an additional assessment should be conducted. As exceedances of the 2L Standards have persisted in some of the subject monitoring wells, Duke Energy has communicated to NCDEQ DWM that an additional investigation and assessment will be initiated at the landfill. HDR is preparing the assessment plan at this time and plans to submit the assessment plan to NCDEQ DWM by May 31, 2016. Duke Energy Carolinas, LLC I Accelerated Remediation Interim Action Plan — Belews Creek Steam Station �� Interim Action Tasks Pine Hall Road Ash Landfill (NCDEQ DWM Permit No. 8505 The Pine Hall Road Ash Landfill (NCDNR Permit No. 8503) is located adjacent to the ash basin. The landfill was originally permitted in 1983. The original landfill was unlined and was permitted with a soil cap 1 -foot thick on the side slopes and 2 feet thick on flatter areas. A subsequent expansion (Phase I Expansion) was permitted in 2003. This phase was also unlined but was permitted with a synthetic cap system to be installed at closure. After groundwater exceedances were observed in wells installed near the landfill, the placement of additional ash in the Phase I Expansion was halted. The closure design was changed to utilize an engineered cover system for a portion of the landfill. The engineered cover system consists of a 40 -mil linear low density polyethylene geomembrane, a geonet composite, 18 inches of compacted soil, and 6 inches of vegetative soil cover. The engineered cover system was installed over a 37.9 acre area. An adjacent 14.5 acre area, located to the northeast, had additional soil cover applied and was graded to improve surface drainage. The construction of the engineered cover system and additional soil cover on the 14.5 acre area was completed in December 2008. HDR previously prepared and submitted an assessment to NCDEQ DWM for exceedances of 2L Standards at the landfill (Groundwater Assessment Belews Creek Steam Station Pine Hall Road Ash Landfill, Permit No. 8503, dated October 1, 2012). The report assessed 2L Standard exceedances at wells MW -3 and MW -6 and found those exceedances to be attributed to naturally occurring conditions. The assessment report reviewed the location of wells and surface water sample locations with exceedances of 2L Standards (MW -4, MW -7, MW2-7, MW2-9, SW -1A, and SW -2) and found that the hydrologic boundaries and the groundwater flow at the site was such that groundwater at these locations was discharging to the ash basin. The report also concluded that with the reduced infiltration, due to the engineered cover system installed in 2008, the concentrations of constituents in groundwater attributable to fly ash in these wells will likely continue to decrease over time. The groundwater model included as part of the BCSS CAP 2, which was submitted to NCDEQ on March 8, 2016, applied a recharge rate of 0 inches per year to this landfill area outside of the engineered cover system. The 14.5 acre area of the landfill with the additional soil cover should have received approximately 9 inches of infiltration per year as recharge in the model. It is likely that the additional recharge would have a negligible effect on the model results; however, the correct recharge value will be applied during upcoming groundwater model revisions. Structural Fill An ash structural fill comprised of compacted fly ash was constructed southeast of the ash basin under the structural fill rules found in 15A NCAC 13B .1700. The ash structural fill is located south of the Pine Hall Road topographic divide and therefore groundwater flow beneath the fill should be predominantly away from the ash basin. After completion of the fill, an engineered cover system consisting of a geomembrane cover system capped with soil and vegetation was installed over the ash structural fill. The structural fill is currently used as an equipment/material staging area and for overflow parking. Duke Energy Carolinas, LLC I Accelerated Remediation Interim Action Plan — Belews Creek Steam Station FN Action Tasks AOW sample location S-9 (from the CSA) exhibited 2L Standard or IMAC exceedances for boron, cobalt, sulfate, and TDS. As stated in the CSA, due to the location of S-9, it does not appear that the exceedances at S-9 are related to the ash basin. Additional inspections were performed in this area to determine if visible sources of ash, possibly related to the structural fill, could be observed, however none were detected. Analytical results for S-9 are provided in Table 2. Round 2 data was collected on October 5, 2015 and Round 5 data was collected on March 31, 2016. A review of the Round 2 and Round 5 analytical data for S-9 shows the following: • Boron — the concentration in Round 2 was less than the method detection limit of 50 pg/L. The boron concentration in Round 5 was greater than the 2L Standard at 1,000 pg/L. • Cobalt — the concentration in Round 2 was 2.7 pg/L, greater than the IMAC of 1 pg/L; however, in Round 5, cobalt was reported at a concentration less than the IMAC at 0.23 pg/L. • Sulfate — the concentration in Round 2 decreased to 3,600 pg/L, less than the 2L Standard of 250,000 pg/L. The sulfate concentration in Round 5 was also less than the 2L Standard at 197,000 pg/L. • TDS — the concentration in Round 2 decreased to 54,000 pg/L, less than the 2L Standard of 500,000 pg/L. The TDS concentration in Round 5 was also less than the 2L Standard at 257,000 pg/L. Exceedances were also reported at S-9 in Round 5 for manganese (56 pg/L) and vanadium (0.41 pg/L). The site proposed provisional background concentrations (PPBCs) as provided in CAP 1 Table 2-2 for these constituents are 96.2 pg/L and 7.4 pg/L, respectively. Groundwater monitoring wells GWA-23S/D were installed north of S-9 in April 2016 and will be used to evaluate if exceedances observed at S-9 are likely due to the ash basin or the structural fill. These wells are anticipated to be sampled in early May 2016. 4.3.1 Findings The following findings are based on the descriptions above for each landfill unit and the structural fill: • The Craig Road Ash Landfill and FGD Residue Landfill are lined landfills, with groundwater monitoring programs conducted under the requirements of NCDEQ DWM, and are located such that they are not hydrogeologically connected with the ash basin. Therefore, additional evaluation of the potential contribution of these landfills to impacted groundwater is not needed. • Previous assessment at the Pine Hall Road ash landfill indicated groundwater flows from the area beneath the landfill toward the ash basin. Duke Energy is planning to install additional assessment monitoring wells GWA-25BR and GWA- 26S/D/BR (shown on Figure 2) to further evaluate groundwater quality immediately southwest of the landfill, on Duke Energy property between the landfill and potential offsite receptors. Additional evaluation of the potential contribution of this landfill to impacted groundwater is not needed. Duke Energy Carolinas, LLC I Accelerated Remediation Interim Action Plan — Belews Creek Steam Station �� Interim Action Tasks • Additional evaluation of the potential contribution of the structural fill to impacted groundwater should be deferred until evaluation of the groundwater analytical results from monitoring wells GWA-23S/D is completed. 9 Duke Energy Carolinas, LLC I Accelerated Remediation Interim Action Plan — Belews Creek Steam Station Schedule Schedule Task Description Complete Additional Assessment Field Activities Complete Evaluation of Additional Assessment Results Initiate Interim Action Field Investigation Perform Aquifer Pump Test Provide NCDEQ with Accelerated Groundwater Remediation Evaluation Report Taraet Date May 31, 2016 June 30, 2016 May 23, 2016 June 13, 2016 July 15, 2016 FN Fez Table 1: Groundwater Analvtical Results (Accelerated Remediation AOI) c: �pwworking � tpa �d0915075 � Copy of DRAFT Belews_R5_2016Q1_PlusPriorityWells_Groundwater 20160413_REVOO.xIs Page 1 of 2 Location: GWA-1S GWA-1D GWA-10S GWA-10D GWA-11S GWA-11D Event: Round 1 Round 2 Round 5 Round 1 Round 2 Round 5 Round 1 Round 2 Round 5 Round 1 Round 2 Round 5 Round 1 Round 2 Round 5 Round 1 Round 2 Round 5 Sample Date: 7/12/2015 9/30/2015 4/1/2016 7/12/2015 9/30/2015 4/1/2016 7/18/2015 10/2/2015 3/29/2016 7/18/2015 10/2/2015 3/29/2016 7/18/2015 10/2/2015 3/29/2016 7/18/2015 10/2/2015 3/29/2016 Constituent Fraction 2L Standard,IMAC, or DHHS Unit Aluminum D NS u /I 340 190 115 150 100 U 88.5 J 690 630 810 1100 110 780 100 U 190 200 100 U 100 U 100 U Aluminum T NS u /I 760 320 1210 580 870 176 700 1200 885 1300 300 908 1 170 7400 220 1 170 2700 125 Antimony D NS u /I 0.5 U 0.5 U 0.5 U 1 0.62 0.68 0.98 0.5 U 0.5 U 0.5 U 0.98 J+ 3.8 5 U 0.5 U 0.5 U 0.5 U 0.82 1 3 2.2 J Antimony T 1 u /I 0.5 U 0.5 U 0.5 U 0.63 0.82 1.3 0.5 U 0.5 U 0.5 U 1.6 4.9 5 U 0.5 U 0.5 U 0.5 U 0.8 2.8 2 J Arsenic D NS u /I 0.25 J 0.5 U 0.078 J 2.3 1.2 1.9 3.5 3.2 5.5 1.5 0.29 J 1.2 1.1 0.9 0.47 2 3.1 3.8 Arsenic T 10 u /I 0.49 J 0.48 J 1.6 2.4 2.5 2 5 6.2 5.6 1.7 0.56 1.3 1.3 7.5 0.5 2.1 4.2 4.5 J+ Barium D NS u /I 340 280 124 6.4 6.3 5.6 260 280 300 24 11 21 500 530 330 20 22 20 Barium T 700 u /I 340 320 124 11 19 4.6 J 260 280 320 23 10 1 23.8 490 570 1 333 22 40 27.9 Beryllium D NS u /I 6.3 5.5 3.5 0.2 U 0.2 U 0.021 J 1.3 1.4 1.8 0.2 U 0.2 U 1 U 6.9 9.7 7.2 0.2 U 0.2 U 0.79 J Beryllium T 4 u /I 6 6.5 3.3 1 0.2 U 0.2 U 0.072 J+ 1.4 1.4 1.7 0.2 U 0.2 U 1 U 6.6 10.9 6.8 J 0.068 J 0.11 J 1 UJ Boron D NS u /I 440 420 261 50 U 50 U 50 U 49 J 49 J 43 J 50 U 50 U 50 U 170 130 180 29 J 29 J 50 U Boron T 700 u /I 430 390 254 50 U 50 U 29.6 J 46 J 41 J 47.6 J 50 U 50 U 50 U 160 120 185 50 U 26 J 25 J Cadmium D NS u /I 0.46 0.47 0.14 0.2 0.043 J 0.05 J 0.14 0.12 0.18 0.08 U 0.08 U 0.8 U 0.62 0.76 0.38 0.067 J 0.14 0.8 U Cadmium T 2 u /I 1 0.46 0.47 0.16 0.2 0.037 J 0.15 0.14 0.17 0.24 J+ 0.08 U 0.08 U 0.8 U 0.61 0.77 0.38 J+ 0.062 J 0.13 0.8 UJ Calcium T NS u /I 8680 10900 2040 9780 10900 6400 1520 1390 1990 68800 21300 85200 38700 30900 15000 58000 56200 55000 Chromium D NS u /I 12.5 7.7 1.3 1.3 0.5 U 1 4.7 0.54 J+ 0.35 J 0.16 J 1.3 J+ 0.75 0.9 J 0.75 J+ 36.2 0.23 J+ 0.37 J+ 4.5 2.7 J Chromium T 10 u /I 29.7 32.1 11.2 4 37.1 11.1 1.4 J+ 1.2 J+ 0.42 J+ 1 J+ 0.96 J+ 5 U 0.52 J+ 66.2 0.19 1 1.5 J+ 24.1 17.3 J Cobalt D NS u /I 8.4 6.3 6.8 1.4 2.6 6 30.6 30.8 40.7 0.5 U 0.5 U 1 U 7.4 10.2 11.1 1.5 2.3 2.4 Cobalt T 1 u /I 10 7.4 7.6 1.6 3.4 5.2 30.4 32.2 42.2 0.5 UJ 0.29 J 1 U 7.4 13.2 11.2 J 1.6 3 3.2 J Copper D NS u /I 4.7 1.1 3.5 1.6 1.9 1 8.3 J+ 2.3 11.6 2.1 J+ 0.49 J 5.8 8.7 J+ 4.2 10.3 J 6.8 J+ 4.8 3.2 J Copper T 1000 u /I 1 0.96 J 1.3 4.6 1.1 3.5 0.95 1.4 J+ 1 2.1 1.6 0.94 J+ 0.54 J 5 U 0.35 J+ 4.5 0.76 1 UJ 2.9 5 U Iron D NS u /I 82 47 J 50 U 140 1 50 U 112 50 U 50 U 50 U 50 U 50 U 50 U 50 U 200 50 U 570 350 1000 Iron T 300 u /I 780 230 1700 620 1400 167 35 J 1100 33.7 J 50 UJ 26 J 50 U 120 11700 26.5 J 810 4200 1410 Lead D NS u /I 0.37 0.28 0.14 0.16 0.16 1 0.32 1.8 J+ 1.3 0.8 0.074 J+ 0.089 J 1 U 0.84 J+ 0.54 0.11 0.48 J+ 0.67 1 U Lead T 15 u /I 0.37 0.38 1 0.46 0.76 0.5 1.2 2.5 0.83 0.062 J 0.057 J 1 U 0.053 J 3.8 0.11 0.11 0.6 1 U Magnesium T NS u /I 29200 29700 10400 4000 4710 2840 5650 5930 7990 575 929 272 31100 32400 18100 16700 20300 21300 Manganese D NS u /I 350 280 214 21 26 16.6 810 790 1000 5 U 5 U 5 U 330 260 180 180 240 220 Manganese T 50 u /I 390 270 240 25 44 21.6 1 800 790 1110 5 U 3.3 J 5 U 320 370 178 190 270 221 Mercury D NS u /I 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.25 0.191 0.54 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U Mercury T 1 u /I 0.075 J+ 0.2U 0.2U 0.2U 0.2U 0.2U 0.47 0.37 0.7 0.2U 0.2U 0.2U 0.2U 0.25 0.2U 0.2U 0.2U 0.2U Methane N NS u /I 2.5 J+ 2.5 J+ 1.6 J+ 1.5 J+ 1.3 J+ 2.2 J+ 1.2 J+ 3J+ 1.6 J+ 2.1 J+ 3.9 J+ 1.8 J+ 1 J+ 1.1 J+ 1.6 J+ 1 10 U 4.8 J+ 3.3 J+ Molybdenum D NS u /I 0.26 J 0.13 J 0.5 U 5.2 3.8 4 0.5 U 0.5 U 0.5 U 6.4 2.2 2.9 J 0.5 U 0.36 J 0.5 U 2.3 3 2.4 J Molybdenum T NS u /I 0.55 0.59 0.25 J 5.2 4.6 5 0.12 J 0.15 J 0.5 U 5.5 2.4 2.8 J 0.5 U 0.88 0.5 U 2.3 2.9 2.8 J Nickel D NS u /I 35.8 28.9 14.2 8.2 16.6 19.3 7.6 7.1 10.4 0.6 J+ 0.34 J 5 U 13.8 48.9 12.3 12.2 22.3 24.5 Nickel T 100 u /I 45.2 43.1 17 8.6 28.4 15.8 7.8 7.8 10.6 0.71 0.88 J+ 5 U 13.5 57.4 11.6 13 24.5 29.2 Potassium T NS u /I 5180 5000 J 5000 U 5000 U 3280 J 2830 J 3540 J 3900 J 3400 J 19300 13100 19700 6690 7230 4290 J 9180 10300 8470 Selenium D NS u /I 0.5 U 0.5 U 0.69 1 0.5 U 0.5 U 0.45 J 2.3 1.1 55.8 0.46 J 0.5 U 5 U 0.5 U 0.35 J 5.8 0.5 U 0.5 U 5 U Selenium T 20 u /I 0.5 U 0.5 U 0.79 0.5 U 0.5 U 0.64 10.6 1.7 55.5 0.38 J 0.22 J 5 U 0.52 0.53 5.8 0.5 U 0.5 U 5 U Sodium T NS u /I 15000 16100 5170 20100 18000 50200 11500 11800 11600 15300 12800 15500 22600 1 21700 13600 18000 21000 20600 Strontium D NS u /I 180 240 47.9 66 75 57.6 15 15 17 570 360 590 480 480 170 270 300 290 Strontium T NS u /I 180 200 46.5 70 80 44.6 15 1 15 18 560 340 640 460 450 172 280 310 286 Thallium D NS u /I 0.34 0.37 0.14 0.022 J 0.051 J 0.1 U 0.18 0.24 0.18 0.022 J 0.035 J 1 U 0.27 0.38 0.24 0.029 J 0.033 J 1 U Thallium T 0.2 u /I 0.34 0.41 0.15 0.07 J 0.051 J 0.018 J 0.2 J 0.25 0.22 0.017 J+ 0.017 J 1 U 0.3 0.53 0.23 0.041 J+ 0.088 J 1 U Uranium, Natural T NS u /I - 0.084 J - - 0.35 J - - 0.53 - - 5 U - - 0.099 J - - 0.5 U Vanadium D NS u /I 1 U 1 U 0.3 U 1.1 0.45 J 0.74 1 U 1 U 0.3 U 7.4 2.6 2J 1 U 1 U 0.3 U 0.76 J+ 1 U 3 U Vanadium T 0.3 u /I 0.29 J 0.57 J 1.7 1.5 1.7 0.87 1 U 1.1 0.3 U 7.9 2.9 1.9 J 1 U 1 6.3 0.3 U 0.75 J 4.2 3 U Zinc D NS u /I 19 15 16.6 J+ 6.6 J 15 11.2 J+ 22 J+ 35 32 4.8 J+ 10 U 10 U 43 100 47 16J+ 42 12J+ Zinc T 1000 ug/11 21 17 32.6 6.9 J 9.7 J 5.6 J 20 33 26.2 10 U 2.9 J 2.9 J 38 140 40.2 14 55 J+ 24.8 Total Dissolved Solids N 500000 u /I 380000 251000 75000 158000 135000 180000 138000 81000 109000 265000 120000 249000 578000 484000 225000 526000 541000 445000 Total Organic Carbon N NS u /I 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1400 1000 U 980 J 1000 U 1000 U 1000 U 1000 U 11600 J 11100 1000 U 1 ono U Total Suspended Solids N NS u /I 18400 10800 11700 46200 8300 14000 29400 113000 2500 U 18600 86300 9300 6300 565000 2500 U 2600 312000 5000 U Alkalinity, CO3 N NS u /I 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 155000 53800 177000 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N NS u /I 1400 J 1200 J 5000 U 37200 33600 44600 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 19900 2800 J 1200 J 55900 49800 49500 Alkalinity, lab N NS u /I 1400 J 1200 J 5000 U 37200 33600 44600 5000 U 5000 U 5000 U 200000 67400 216000 19900 2800 J 1200 J 55900 49800 49500 Chloride N 250000 u /I 1 127000 133000 36900 27300 28200 50300 46500 48300 56300 12800 19000 16200 175000 188000 95000 137000 145000 141000 Nitrogen, NO2 plus NO3 N NS u /I 640 660 1100 420 650 870 270 270 280 200 280 27 270 240 230 170 1 94 69 Sulfate N 250000 u /I 1000 U 540 J 650 J 4300 8800 6400 1000 U 1000 U 1400 2700 1800 2200 660 J 580 J 1000 U 5000 7600 6800 Sulfide N NS u /I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 UJ 100 U 100 U 100 U 100 U 100 U 100 UJ 100 U 100 U 100 UJ 100 U Chromium VI T 0.07 u /I - - 0.063 - - 0.047 - - 0.01 J - - 0.13 - - 0.03 U - - 0.019 J+ Dissolved Oxygen N NS m /I 3.98 4.4 7.1 5.64 3.22 1.8 3.08 2.2 3.5 2.99 0.5 0.4 5.06 4.29 5.0 2.92 0.68 0.5 Temperature N NS Deg C 23.1 17.5 18.6 23 22.5 17.4 1 15.9 14.6 13.6 19.3 14.7 13.3 15.97 13.7 16.1 16.51 13.8 17 pH N 6.5-8.5 SU 1 4.94 4.9 5.0 6.72 6.6 6.7 4.14 4.4 4.5 11.98 11.4 12.6 5.59 5.2 5.0 6.4 6.5 6.4 Turbidity, field N NS NTU 8.32 2.0 8.2 11.66 9.9 7.2 7.14 8.9 1.7 7.21 9.2 8.0 3.13 6.28 2.1 9.5 11.91 6.0 Specific Conductivity field N NS PS/cm 406.9 500.5 137.9 168.9 197.4 284 200.7 193.5 218 979 332 1076 704 649 362 644 630 663 Oxidation Reduction Potential N NS mV 345.1 320.7 300.5 221.8 163.7 87.3 272.3 375.2 419.9 -45.4 -48.1 1 -72.1 226.1 207.1 174 56.9 15.2 1 89.4 c: �pwworking � tpa �d0915075 � Copy of DRAFT Belews_R5_2016Q1_PlusPriorityWells_Groundwater 20160413_REVOO.xIs Page 1 of 2 Fez Table 1: Groundwater Analvtical Results (Accelerated Remediation AOI) c: �pwworking � tpa �d0915075 � Copy of DRAFT Belews_R5_2016Q1_PlusPriorityWells_Groundwater 20160413_REVOO.xIs Page 2 of 2 Location: GWA-16S GWA-16D GWA-17S GWA-17D GWA-18D GWA-19S GWA-20D GWA-21S GWA-21D Event: Round 1 Round 2 Round 5 Round 1 Round 2 Round 5 Round 1 Round 2 Round 5 Round 1 Round 2 Round 5 Round 5 Round 5 Round 5 Round 5 Round 5 Sample Date: 7/16/2015 9/29/2015 3/31/2016 7/16/2015 9/29/2015 3/30/2016 7/15/2015 9/29/2015 3/31/2016 7/15/2015 9/29/2015 3/30/2016 3/31/2016 3/31/2016 3/30/2016 3/30/2016 3/30/2016 Constituent Fraction 2L Standard,IMAC, or DHHS Unit Aluminum D NS u /I 100 U 100 U 100 U 770 410 500 100 U 85 J 54 J 150 100 U 60 J 88 J+ 1200 100 U 170 100 U Aluminum T NS u /l 330 88 J 449 810 480 512 400 11700 127 190 180 82.6 J 133 1260 1 147 228 59.8 J Antimony D NS u /I 1 0.2 J+ 0.5 U 0.11 J 1.6 J+ 2.2 1.2 J 0.5 U 0.5 U 0.5 U 0.22 J+ 0.98 0.28 J 0.21 J 0.12 J 5 U 0.5 U 0.5 U Antimony T 1 u /I 0.25 J+ 0.5U 0.111 1.5 J+ 2.3 5U 0.5U 0.27J 0.5U 0.191 1 0.21J 0.3J 0.12J 5U 0.5U 0.5U Arsenic D NS u /1 0.5 U 0.5 U 0.1 U 1.8 2.3 1.2 0.14 J+ 0.13 J 0.072 J 0.76 J+ 0.64 0.21 1.3 3.8 2.1 0.4 0.45 Arsenic T 10 u /1 0.5 U 0.5 U 0.19 2.1 2 1.1 0.16 J 0.54 0.1 0.8 0.68 0.29 1.8 4.4 2.6 0.58 0.47 Barium D NS u /1 56 41 30 38 21 29 20 31 29 7.2 7.2 6.1 2.5 J+ 530 63 240 5 U Barium T 700 u /1 57 44 33.6 40 23 30.4 1 25 130 34.6 1 7.6 7.7 7 1 2.8 J 519 69.8 1 260 114 Beryllium D NS u /l 0.071 J 0.095 J 0.075 J 0.2 U 0.2 U 1 U 0.2 U 0.2 U 0.028 J 0.2 U 0.2 U 0.028 J 0.025 J 7.4 0.42 J 5.9 2.4 Beryllium T 4 u /l 0.2U 0.098J 0.12 0.2U 0.2U 1 U 0.2U 0.15J 0.0181 0.2U 0.2U 0.14 0.014 J+ 7.3 0.12J 6.3 2.6 Boron D NS u /l 50 U 50 U 25 J 50 U 37 J 28 J 50 U 50 U 25 J 50 U 110 50 U 50 U 1300 5300 48 J 50 U Boron T 700 u /I 50 U 50 U 50 U 50 U 31 J 50 U 50 U 40 J 26.1 J 50 U 93 50 U 50 U 1300 5990 48.6 J 44.2 J Cadmium D NS u /l 0.09 0.067 J 0.08 U 0.08 U 0.08 U 0.8 U 0.08 U 0.08 U 0.11 0.08 U 0.08 U 0.21 0.08 U 0.45 0.67 J 0.39 0.55 Cadmium T 2 u /l 0.08 U 0.067 J 0.051 J 0.12 0.063 J 0.8 U 0.08 U 0.05 J 0.16 0.08 U 0.07 J 0.08 U 0.08 U 0.55 0.63 J 0.38 0.58 Calcium T NS u /l 1380 1110 303 26100 12200 6290 5200 7020 4510 20000 17200 19000 16100 15100 1 118000 10200 24700 Chromium D NS u /l 0.48 J+ 0.4 J 0.51 0.92 J+ 1.2 1.2 J 0.23 J+ 0.98 1.4 0.2 J+ 0.32 J 1.4 1.4 3.9 5 U 0.27 J 0.19 J Chromium T 10 u /l 6 1 22.7 3.1 J+ 1.1 1.6 J 50.7 27.6 5.9 0.73 J+ 1.4 J+ 1.4 J+ 3.1 6.2 1.6 J 0.64 J+ 0.73 J+ Cobalt D NS u /l 5.5 4.5 2.7 0.5 U 0.5 U 1 U 1.4 2.8 16.1 0.5 U 0.5 U 0.071 J 0.53 37.5 8.5 24 2.1 Cobalt T 1 u /I 5.6 4.2 3.3 0.5 U 0.5 U 1 U 2.6 6.4 16.8 0.5 U 0.5 U 0.13 0.65 42.7 9.6 29 2.3 Copper D NS u /l 0.85 J+ 2.8 1.5 1.9 J+ 1.1 1 5 U 1 U 2 1 4.6 1 U 0.4 J 16.8 1.1 6.1 3.9 J 9.5 3.2 Copper T 1000 u /l 0.89 J+ 5.3 2.2 2.3 J+ 3.2 5 U 1.4 11.2 9.9 0.43 J 1.6 J+ 215 1 1.3 4.4 1.6 J 1.1 0.93 Iron D NS u /l 50 U 50 U 29 J 50 U 50 U 50 U 510 1300 250 50 U 50 U 80 55 J+ 30 J 600 35 J 50 U Iron T 300 u /I 610 140 957 79 74 28.4 J 1500 18800 266 39 J+ 190 828 136 97.3 1130 90 44 J Lead D NS u /I 0.058 J+ 0.1 U 0.1 U 0.059 J+ 0.1 U 1 U 0.1 U 0.059 J 0.1 U 0.051 J 0.1 U 0.1 U 0.1 U 0.34 1 U 0.098 J 0.1 U Lead T 15 u /l 0.22 0.068 J 0.51 0.082 J 0.074 J 1 U 0.091 J+ 2.4 0.1 U 0.1 U 0.15 J+ 0.096 J 0.1 U 0.4 1 U 0.15 0.1 U Magnesium T NS u /I 1230 1120 929 305 1 105 77.8J 3350 1 7330 4100 296 1 1100 1660 2120 25500 53600 18800 21400 Manganese D NS u /I 140 110 70 5 U 5 U 5 U 380 630 360 5 U 2.5 J 15 33 J+ 1200 980 560 5 U Manganese T 50 u /l 130 110 70.4 5 U 5 U 5 U 430 740 330 5 U 4.9 J 15 35.8 1230 1040 559 83.5 Mercury D NS u /l 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U Mercury T 1 u /I 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U Methane N NS u /I 2J+ 3.5 J 1.8 J+ 10 U 2.9 J 2.5 J+ 2.2 J+ 2.9 J+ 2.5 J+ 1.9 J+ 1.4 J+ 3.8 J+ 1.9 J+ 1.6 J+ 3.1 J+ 2.2 J+ 1.8 J+ Molybdenum D NS u /I 0.5 U 0.31 J 0.5 U 8.4 18.2 12.8 5.8 2.8 2.8 1.4 1.2 2 1.7 0.5 U 3.1 J 0.5 U 0.5 U Molybdenum T NS u /l 0.17 J 0.26 J 0.64 8.9 1 15.2 14.1 5.9 4.1 6.3 1.5 1.3 7.4 2.1 0.5 U 3.1 J 0.5 U 0.14 J Nickel D NS u /I 3.6 2.5 3.3 0.69 J+ 0.9 5 U 14.5 5.5 17 0.5 U 0.47 J 2.1 1 1.7 24.9 15.5 1 11.5 6.5 Nickel T 100 u /I 5.7 2.3 14.3 1.7 J+ 0.74 5 U 28.7 12.5 19.8 0.36 J 0.58 1.2 1.9 32.5 15.6 13.2 6.5 Potassium T NS u /I 5000 U 5000 U 5000 U 41500 40600 71500 3710 J 6960 3110 J 4860 J 3500 J 5000 U 2850 J 6140 10400 4110 J 6050 Selenium D NS u /l 0.5 U 0.5 U 0.5 U 0.4 J 0.69 5 U 0.5 U 0.5 U 0.57 0.5 U 0.5 U 0.5 U 0.5 U 44.3 5 U 4.5 0.5 U Selenium T 20 u /I 0.5 U 0.5 U 0.58 0.53 0.6 5 U 0.5 U 0.32 J 0.54 0.5 U 0.5 U 0.5 U 0.5 U 53.8 5 U 5.4 0.5 U Sodium T NS u /I 5000 U 5000 U 5000 U 32600 53700 53100 4340J 5180 5090 7860 6840 6070 10600 9820 36500 19500 25000 Strontium D NS u /I 16 13 7.2 580 260 390 22 22 20 75 66 57 84 J+ 91 670 140 5 U Strontium T NS u /l 15 15 7.5 570 270 381 23 37 21.1 79 64 59.2 84.3 92.1 1 724 145 304 Thallium D NS u /I 0.051 J+ 0.07 J 0.038 J 0.1 U 0.1 U 1 U 0.028 J+ 0.1 U 0.1 U 0.021 J+ 0.1 U 0.1 U 0.016 J 0.35 1 U 0.16 0.15 Thallium T 0.2 u /I 0.054 J 0.06 J 0.036 J 0.1 U 0.1 U 1 U 0.1 U 0.1 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.34 1 U 0.19 0.17 Uranium, Natural T NS u /I - - - - - - - - 0.5 U - - 0.25 J 0.83 0.14 J 5 U 0.5 U 0.5 U Vanadium D NS u /l 1 U 1 U 0.073 J 9.6 11.3 1 2.5 J 1 U 0.88 J 0.2 J 2.8 1.3 0.38 1.3 0.3 U 3 U 0.3 U 0.073 J Vanadium T 0.3 u /l 0.64 J 0.31 J 2.1 10.2 9.7 3.6 1.8 33.9 0.34 3.4 1.6 1 0.62 2 0.13 J+ 3 U 0.12 J 0.12 J Zinc D NS u /I 9.1 J 21 47 10 U 2.8 J 3.8 J 10 U 1 6.5 J 56 10 U 10 U 86 4.1 J+ 42 61 20 10 U Zinc T 1000 u /l 8.5 J 22 44 10 U 69 3.9 J 14 J+ 47 65.8 10 U 10 U 53.2 5.8 J 1 41.4 70.1 20 7.7 J Total Dissolved Solids N 500000 u /l 30000 34000 25000 U 256000 257000 255000 70000 44000 49000 109000 59000 83000 79000 251000 814000 186000 226000 Total Organic Carbon N NS u /I 1 1000 U 1000 U 1000 U 2500 1200 900 J 1000 U 510 J 1000 U 510 J 1000 U 1000 U 580 J 1000 U 550 J 1000 U 1000 U Total Suspended Solids N NS u /I 29400 2500 U 6900 16400 5000 2500 U 58700 915000 2500 U 2500 U 5500 6700 2500 U 2500 U 3900 2500 U 2500 U Alkalinity, CO3 N NS u /l 5000 U 5000 U 5000 U 57400 46600 111000 5000 U 5000 U 5000 U 52000 1 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N NS u /l 10700 7000 5500 113000 88600 50005 32200 28700 21900 12700 41800 1 54600 53000 5000 U 17200 2400 J 7500 Alkalinit,lab N NS u /l 10700 7000 5500 170000 135000 201000 32200 1 28700 21900 64700 41800 54600 53000 5000 U 17200 2400J 7500 Chloride N 250000 u /I 670J 1100 690J 3000 2900 1800 1100 1600 1200 1400 1700 950J 7200 159000 369000 104000 138000 Nitrogen, NO2 plus NO3 N NS u /I 20 UJ 20 J 11 J 14 J+ 430 67 100 J- 56 11 J 20 UJ 20 U 20 U 220 J+ 120 J+ 101 250 460 Sulfate N 250000 u /I I 430J 980J 820 J+ 25900 1 38400 19900 5600 8100 19500 13500 14400 13300 5800 740J 44100 1000 2300 Sulfide N NS u /I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Chromium VI T 0.07 u /I - 0.039 0.041 - 0.77 0.65 - 0.02 U 2.2 - 0.013 J 0.03 J 0.47 0.025 J 0.03 U 0.03 U 0.078 Dissolved Oxygen N NS m /I 5.91 4.9 4.7 4.81 3 0.9 0.76 1.49 0.9 0.56 1.69 1.1 3.7 5.1 0.8 4.9 2.6 Temperature N NS Deg C 21.4 21.6 18.7 20.1 21.4 18.8 23.6 1 24.5 18.8 18.3 22.3 17.9 18.7 16.4 20.4 15.1 16.1 pH N 6.5-8.5 SU 5.43 5.2 4.7 11.52 11 11.2 6.7 6.37 6.0 10.29 8.68 8.2 8.1 4.4 5.7 4.8 5.1 Turbidity, field N NS NTU 70 9 9.7 9.6 5.4 4.5 21.7 7.94 9.2 3.25 13.13 9.4 1.8 7.6 7.1 1.4 2.4 Specific Conductivity field N NSPS/Cm 32 25.3 20.6 63 592 832 102 116.1 91 172 133.7 150 150.4 559.8 1330 375.9 505.4 Oxidation Reduction Potential N NS mV 140 1 74.7 1 294.8 96.8 2.4 116.3 13.7 -14.7 139.3 103.4 -26.4 44.9 21.6 366 -19.9 127.8 1 194.9 c: �pwworking � tpa �d0915075 � Copy of DRAFT Belews_R5_2016Q1_PlusPriorityWells_Groundwater 20160413_REVOO.xIs Page 2 of 2 07Z Table 2: Area of Wetness Analytical Results (Accelerated Remediation AOI) c:tpwworkingttpatd0915075iCopy of DRAFT Belews_Areos Of Wetness Results to Date (02L)_20160414_REVOO.xls Page 1 Of 1 Location: S-2 S-3 S-4 S-5 Event: Round 1 Round 2 Round 5 Round 1 Round 2 Round 5 Round 1 Round 2 Round 5 Round 1 Round 2 Round 5 Sample Date: 7/16/2015 10/5/2015 3/31/2016 7/17/2015 10/5/2015 3/31/2016 7/17/2015 10/5/2015 3/31/2016 7/17/2015 10/5/2015 3/31/2016 Constituent Fraction 2L Standard, IMAC, or DHHS EUnit Aluminum D NS ug/I 100 U 100 U 100 U 100 U 80 J 100 U 100 U 100 U Aluminum T NS u /I 50 J 87 J 230 79.1 J 3000 509 330 106 Anti mon D NS u /I 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Antimony T 1 u /I 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Arsenic D NS u /I 0.68 0.51 0.31 0.55 0.42 J 0.27 0.38 J 0.54 0.16 1.1 0.73 0.25 Arsenic T 10 u /I 0.81 0.64 0.48 1.2 0.98 0.39 0.53 4 1.9 1.3 0.73 0.42 Barium D NS u /I 130 110 145 12 15 11.3 44 52 90.5 11 10 7.6 Barium T 700 u /I 130 97 139 13 16 11.4 48 130 86.9 12 11 7.5 Beryllium D NS u /I 0.18 J 0.53 0.58 0.2 U 0.072 J 0.015 J+ 0.31 0.5 1.4 0.2 U 0.071 J 0.034 J+ Beryllium T d u /I 0.18 J 0.6 0.8 0.1 J 0.16 J 0.069 J+ 0.48 5.1 2.6 0.2 U 0.2 U 0.041 J+ Boron D NS u /I 110 110 118 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U Boron T 700 u /I 120 89 111 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U Cadmium D NS u /I 0.08 U 0.1 0.13 0.08 U 0.08 U 0.08 U 0.075 J 0.081 0.18 0.08 U 0.08 U 0.08 U Cadmium T 2 u /I 0.069 J 0.11 0.18 0.08 U 0.08 U 0.08 U 0.072 J+ 0.62 0.22 0.08 U 0.08 U 0.08 U Calcium T NS u /I 7530 5460 7300 1290 1250 1110 9440 8420 12000 2690 1520 1700 Chromium D NS u /I 0.54 0.27 J 0.18 J+ 0.36 J 0.32 J 0.38 J+ 0.46 J 0.32 J 0.15 J+ 0.4 J 0.53 0.42 J+ Chromium T 10 u /I 0.27 J 0.37 J 0.65 J+ 11.5 0.33 J 0.25 J+ 0.35 J 0.52 0.96 J+ 0.51 0.36 J 0.34 J+ Cobalt D NS u /I 0.75 1 1.2 0.87 0.19 J 0.09 J 0.8 1.1 2.3 0.76 0.5 J 0.13 Cobalt T 1 u /I 0.79 1.3 1.3 1.1 0.5 J 0.16 0.86 9.8 3.2 0.92 0.43 J 0.2 Copper D NS u /I 0.34 J+ 1.5 1 J+ 1.3 1.5 1.2 J+ 1.1 0.24 J 1.8 J+ 2.2 7.1 0.55 J+ Copper T 1000 u /I 0.39 J 0.38 J 0.38 J 1.8 1.2 0.33 J 0.28 J 3.2 1.1 5.6 1.1 0.4 J Iron D NS u /I 120 58 73 42.2 J 630 41.7 J 120 53 Iron T 300 u /I 160 243 740 186 13400 1730 620 218 Lead D NS u /I 0.1 U 0.2 0.1 U 0.09 J+ 0.16 0.1 U 0.076 J+ 0.057 J 0.1 U 0.11 J+ 0.83 0.1 U Lead T 15 u /I 0.1 U 0.15 0.22 0.43 J+ 0.42 0.12 0.13 J+ 2.7 1 0.25 J+ 0.3 0.17 Magnesium T NS u /I 8580 6180 8260 880 1030 1050 6530 6190 10200 1640 1070 1240 Manganese D NS u /I 320 210 136 110 23 5.1 70 140 64.5 130 78 8.5 Manganese T 501 u /I 270 180 141 110 34 9.4 75 340 79.8 140 1 56 11.2 Mercury T 1 u /I 0.000726 0.00121 J+ 0.00126 0.00433 0.00221 J+ 0.00117 0.00664 0.000676 0.00194 0.00284 0.00161 0.0013 J+ Methane N NS u /I 11 J+ 26.7 12.6 J+ 4.9 J+ 3.4 J+ 1.9 J+ 13.5 25.2 3.9 J+ 11.7 7.8 J+ 5.3 J+ Molybdenum D NS u /I 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Molybdenum T NS u /I 0.5U 0.5U 0.5U 0.13J 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Nickel D NS u /I 3.4 3.3 5.1 0.5 U 0.46 J 0.5 U 1.5 1.1 4.1 0.4 J 0.53 0.7 Nickel T 100 u /I 3.5 4 5.1 4.1 0.59 0.5 U 1.5 7.4 3.5 0.38 J 0.38 J 0.5 U Potassium T NS u /I 3860 J 2990 J 3090 J 5000 U 5000 U 5000 U 2940 J 3020 J 3330 J 5000 U 5000 U 5000 U Selenium D NS u /I 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Selenium T 20 u/I 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.41J 0.5U 0.5U 0.5U Sodium T NS u /I 10500 7760 8800 3000 J 2750 J 2550 J 8860 8690 11100 2880 J 2520 J 2570 J Strontium D NS u /I 98 64 85.8 14 16 13.5 120 110 154 28 19 18.8 Strontium T NS u /I 99 58 78.7 15 15 12.4 130 160 138 29 17 17.3 Thallium D NS u /I 0.17 0.087 J 0.039 J 0.043 J 0.018 J 0.1 U 0.11 0.11 0.076 J 0.041 J 0.029 J 0.1 U Thallium T 0.2 u /I 0.15 0.11 0.037 J 0.056 J+ 0.056 J 0.1 U 0.12 J+ 0.35 0.12 0.059 J+ 0.039 J 0.1 U Vanadium D NS u /I 1 U 1 U 0.074 J+ 1 U 1 U 0.12 J+ 1 U 1 U 0.3 U 1 U 1 U 0.16 J+ Vanadium T 0.3 u /I 0.46 J 1 U 0.31 0.5 J 0.34 J 0.18 J 1 U 2.6 1.2 0.47 J 0.41 J 0.34 Zinc D NS u /I 10U 16 12.2 101-1 12 10U 10U 7.3J 6J 101-1 7.4J 101-1 Zinc T 1000 u/I 10U 4.1J 5.1J 1OU 10U 10U 3.8J 19 5.6J 1OU 2.6J 1OU Total Dissolved Solids N 500000 u /I 152000 80000 99000 37000 45000 25000 U 143000 138000 140000 49000 41000 25000 U Total Organic Carbon N NS u /I 1100 1700 1000 U 2900 3700 510 J 740 J 1900 1000 U 700 J 2300 1000 U Total Suspended Solids N NS u /I 2700 5000 U 9900 4000 198000 4200 7000 58100 32600 6800 3900 5000 U Percent Moisture N NS % 44 37.5 75.1 40.2 Alkalinity, CO3 N NS u /I 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U 5000 U Alkalinity, HCO3 N NS u /I 3200 J 2100 J 3300 J 9200 3800 J 5300 6800 4500 J 3800 J 15000 8200 9100 Alkalinity, lab N NS u /I 3200 J 2100 J- 3300 J 9200 3800 J- 5300 6800 4500 J- 3800 J 15000 8200 J- 9100 Cation Exchange Capacity N NS mecill00 31 30 27 Chloride N 250000 u /I 55000 38400 53400 2800 5900 4500 42600 43700 70200 2700 3200 2800 Nitrogen, NO2 plus NO3 N NS u /I 76 181 42J+ 26 11 J 14 J+ 71 26 67 J+ 27 34 160 J+ Sulfate N 250000 u /I 1000 U 1300 1000 1100 2400 1300 1000 U 1000 770J 1400 3000 1500 Sulfide N NS u /I 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U Chromium VI T 0.07 u /I - 0.03 U - 0.018 J - 0.03 U - 0.034 H N 8.5 SU 5.1 J 5.5 J 5.8 J 5.1 J Oxidation Reduction Potential N NS mV 240 J 250 J 210 J Chromium VI D 0.07 u /I 0.02 U 0.01 J 0.02 U Chromium VI T 0.07 u /I 0.02 U - Dissolved Oxygen N NS m /I 7.23 5.6 7.2 2.54 7.2 7.9 6.29 5.8 7.9 8.55 4.5 8.5 Temperature N NS Deg C 22.5 15.8 17.8 20.4 16 16.5 18.2 16.4 16.7 21.99 16.1 16 H N 6.5-8.5 SU 5.6 6 6.3 5.91 6.4 7.2 6.14 6 6.2 6.92 6.3 6.8 Turbidity, field N NS NTU 3.25 5.21 16.3 10.6 16.9 3.4 10.5 93.2 45.8 5.98 7.61 2.7 Sp ecific Conductivity field N NS pS/cm 215 148.8 192 39.2 37.1 36.9 185.8 172.3 249.8 162 38.2 37.5 Oxidation Reduction Potential N NS mV 1119 156.9 152.1 137.5 170.3 203.2 134 160 190.4 169.9 122.4 188.8 c:tpwworkingttpatd0915075iCopy of DRAFT Belews_Areos Of Wetness Results to Date (02L)_20160414_REVOO.xls Page 1 Of 1 F)l SITE LOCATION MAP BELEWS CREEK STEAM STATION SITE LANDFILLS AND STRUCTURAL FILL STOKES COUNTY, NORTH CAROLINA DATE FIGURE APRIL 2016 � •F •.. _ //ems V� i � . � ---, �\� � ! II �J ) I \ ��--� - ,.-�\\ � / / I IIi � . ' \\� � � ��.-.�: � _ -- � � /� l; 1 / - / � <: • f -�\� �� �� >> ,_ _�\\ \� � 111 �... �� \� / �� // �1�� 43\1 1 \� ) omylc t � � � i ((�� � X\ \ \�;\\�, //� \� �\ �I li ��%f \ SW -BL D/SD-BL-D \ I IJ SW -DR -U SD -DR -U \ �\ \ (\\ � Ujo m � roN GN Df ` ` DUKE EN'\ \ \ _ Ifll \ �r,� , �• J \\ �\ 1\�� \ . •.� OPERTY: �A \ 2.23 -ACRE PARCEL NOT �\ �� �_ A 'MWD /� � i ��\ �• fi•� I(� 7 1 PROPERTY��- - -: �/—��\ \ .3 \� / / ED BY DUKE ENERGY ��\ Tlr-'�j 20 �\�\\��\�� �� 1 �\.� ACCELERATED REMEDIATION \. _� A.� �. �� AREA OF INTEREST (AOI) 1. ,` r f J �/ G A- 8 ASH BASIN %�\\1��� ELEVATION 750 FT\\j —•-N ` � �\ I �((APPROXIMATE) > \ �� \�✓= � -�J�� � .. _\l�. �✓ 1�1�/\ ti �1\_�Y I ( a 4D��" �/ GWA-5D l�' i,' -'--•. Ul/ it, \ /. GW A- ` R�� \� BELEWS LAKE IIr%�� �4B 65B ELEVATION 725 FT 1 `\�� `• (/ \\�.. �\� i k ,.+,/�\ AB -5D QUA �! 6SL S (APPROXIMATE) Fp AS 5D D L AS -5 �1i/ .S � Fa % S -AB4 AS -SS 0 \ — �yAB-4BRD AB-4BR / �AB-4D MW -20351 AB -4 MW -203D AB -4S, /���?//�/�J/�����\ \� \���\'✓� ��_�\ \ `\amu � S K Wso)-f U�g 5 W GWA-9S GWA-9Q 9D iii` //✓/i ,\\ � \ % -'. \. I lad a - � �% W All lr CHEMICAL. \ 13 ( ( ( \��f 11 \ , , 12 1 W2-9� _"� i 26 �:� - -� .;��� �\�► '� v . -� \\� � l � I�C� PINE HALL ROADASHW-� �/ ���\�� `� ,.,%Aj,:_/� 1` ��� ��/' .► �1�\\ \. ` I \��((I (� \ LANDFILL PERMIT N �� \\� A�) i \\ / ' CR STA - _ STRUCTURAL J FILL22 • _ 14fa W-1 SNE ✓ �, "�� �_ �� �� i� 49 )17 1 20 24 J C l �II l (: ` - h, GWA-12Sl.\\ GWA 1268. n .• ��s � _,, u... \ � f, • I 4 BG -3S, / J GWA 12D BG DUKE ENERC PROPERTY ,, � �� � f ���—�> : i \ �-- � , •. _ / , ,...J/��� �\-J � � / ��\� : % \ r_ , \�-46RO1V�(I _ ,Y NV or lk SW-BL-U/SD-BL-U ) {WEST OF CRAIG ROAD ASH LANDFILL} ��-- �� � ) / = � `\ � /• \' �`, � \\ 1 _ It I]VA1[011wAo 1111 M 1 Ii ADDITIONAL ASSESSI AND ACCELERATED F DUKE ENERGY CAROI BELEWS CREEK STEP It I]VA1[011wAo 1111 M 1 Ii NOTES: 1. PARCEL DATA FOR THE SITE WAS OBTAINED FROM DUKE ENERGY REAL ESTATE AND IS APPROXIMATE. 2. SHALLOW MONITORING WELLS (S) ARE SCREENED ACROSS THE SHALLOW FLOW LAYER. 3. DEEP MONITORING WELLS (D) ARE SCREENED IN THE DEEP FLOW LAYER. 4. TOPOGRAPHY DATA FOR THE SITE WAS OBTAINED FROM NCDOT WEB SITE (DATED 2010). S. AERIAL PHOTOGRAPHY WAS OBTAINED FROM WSP (DATED APRIL 2014). 6. THE COMPLIANCE BOUNDARY IS ESTABLISHED ACCORDING TO THE DEFINITION FOUND IN 15A NCAC 02L.0107 (a). SCALE (FEET) 300' 0 300' 600' /" = 600' CSA GROUNDWATER MONITORING WELL 10 LOCATION INTERIM ACTION FIELD INVESTIGATION ACCELERATED REMEDIATION AOI DUKE ENERGY CAROLINAS, LLC BELEWS CREEK STEAM STATION ASH BASIN STOKES COUNTY, NORTH CAROLINA NT AOW AND SEDIMENT SAMPLE LOCATION POST -CSA ADDITIONAL ASSESSMENT GROUNDWATER MONITORING WELL PROPOSED SOIL BORING (INTERIM ACTION) PROPOSED OBSERVATION WELL (INTERIM ACTION) DATE APRIL 2016 FIGURE 3