WQ0003698_Groundwater Monitoring Report July 2024_20240823

#=CL#
August 20, 2024
LIMS USE: FR - TIM HORTON
LIMS OBJECT ID: 92741682
92741682
Project:
Pace Project No.:
RE:
Mr. Tim Horton
City of Marion
3982 NC Hwy 226 South
Marion, NC 28752
Monitoring Wells
Dear Mr. Horton:
Enclosed are the analytical results for sample(s) received by the laboratory on July 12, 2024. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Ormond Beach
Report revised to remove VOCs JWB 8/20/24
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Jonathan W Biddix
[e-mail]
Project Manager
704-977-0978
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 27
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92741682
Monitoring Wells
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
California Certification# 3096
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
DoD-ANAB #:ADE-3199
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maine Certification #: FL01264
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Ohio DEP 87780
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Utah FL NELAC Reciprocity
Utah
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 27
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92741682
Monitoring Wells
Lab ID Sample ID Matrix Date Collected Date Received
92741682001 MW-1R Water 07/12/24 11:45 07/12/24 17:02
92741682002 MW-2 Water 07/12/24 13:15 07/12/24 17:02
92741682003 MW-3 Water 07/12/24 15:15 07/12/24 17:02
92741682004 MW-4 Water 07/12/24 12:30 07/12/24 17:02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 27
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92741682
Monitoring Wells
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92741682001 MW-1R EPA 200.7 2 PASI-OAF
EPA 200.8 4 PASI-OBSL
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 4 PASI-AJCM
EPA 350.1 Rev 2.0 1993 1 PASI-ANCF
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 2 PASI-AMFO
SM 4500-P E-2011 1 PASI-AKQB
92741682002 MW-2 EPA 200.7 2 PASI-OAF, TMA
EPA 200.8 4 PASI-OBSL, EAP
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 4 PASI-AJCM
EPA 350.1 Rev 2.0 1993 1 PASI-ANCF
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 2 PASI-AMFO
SM 4500-P E-2011 1 PASI-AKQB
92741682003 MW-3 EPA 200.7 2 PASI-OAF
EPA 200.8 4 PASI-OEAP
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 4 PASI-AJCM
EPA 350.1 Rev 2.0 1993 1 PASI-ANCF
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 2 PASI-AMFO
SM 4500-P E-2011 1 PASI-AKQB
92741682004 MW-4 EPA 200.7 2 PASI-OAF
EPA 200.8 4 PASI-OEAP
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 4 PASI-AJCM
EPA 350.1 Rev 2.0 1993 1 PASI-ANCF
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 2 PASI-AMFO
SM 4500-P E-2011 1 PASI-AKQB
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92741682
Monitoring Wells
Sample:MW-1R Lab ID:92741682001 Collected:07/12/24 11:45 Received:07/12/24 17:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method:
Pace Analytical Services - Charlotte
Monitoring Well Data
Performed by PACE 07/29/24 16:181
Collected By Mattew
Reusch
07/29/24 16:181
Collected Date 7/12/24 07/29/24 16:181
Collected Time 11:45 07/29/24 16:181
pH 5.8 Std. Units 07/29/24 16:181
Temperature 21.2 deg C 07/29/24 16:181
Static Water Level 25.85 feet 07/29/24 16:181
Specific Conductance 21.5 umhos/cm 07/29/24 16:181
Oxygen, Dissolved 6.9 mg/L 07/29/24 16:18 7782-44-71
Total Well Depth 62.62 feet 07/29/24 16:181
Turbidity 9.9 NTU 07/29/24 16:181
Odor ND 07/29/24 16:181
Appearance CLEAR 07/29/24 16:181
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7
Pace Analytical Services - Ormond Beach
200.7 MET ICP
Boron ND ug/L 07/23/24 22:41 7440-42-807/23/24 09:4050.0 12.4 1
Iron 396 ug/L 07/23/24 22:41 7439-89-607/23/24 09:4040.0 25.0 1
Analytical Method: EPA 200.8 Preparation Method: EPA 200.8
Pace Analytical Services - Ormond Beach
200.8 MET ICPMS
Barium 35.2 ug/L 07/24/24 16:06 7440-39-307/23/24 09:401.0 0.50 1
Cadmium ND ug/L 07/24/24 16:06 7440-43-907/23/24 09:400.10 0.067 1
Cobalt ND ug/L 07/24/24 16:06 7440-48-407/23/24 09:401.0 0.24 1
Manganese 10.0 ug/L 07/24/24 16:06 7439-96-507/23/24 09:401.0 0.29 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.2 Std. Units 07/19/24 12:39 H30.10 0.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Bromide ND mg/L 07/15/24 00:57 24959-67-90.10 0.060 1
Chloride ND mg/L 07/15/24 00:57 16887-00-61.0 0.60 1
Fluoride 0.060J mg/L 07/15/24 00:57 16984-48-80.10 0.050 1
Sulfate 0.68J mg/L 07/15/24 00:57 14808-79-81.0 0.50 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 07/26/24 17:59 7664-41-70.10 0.031 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 5 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92741682
Monitoring Wells
Sample:MW-1R Lab ID:92741682001 Collected:07/12/24 11:45 Received:07/12/24 17:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 07/26/24 04:57 7727-37-907/25/24 18:140.50 0.25 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 0.052 mg/L 07/13/24 02:50 14797-55-80.020 0.0039 1
Nitrogen, Nitrite 0.0019J mg/L 07/13/24 02:50 14797-65-0 B0.020 0.0012 1
Analytical Method: SM 4500-P E-2011
Pace Analytical Services - Asheville
SM4500P-E, Phosphate, Ortho
Orthophosphate as P 0.014J mg/L 07/13/24 03:410.050 0.012 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92741682
Monitoring Wells
Sample:MW-2 Lab ID:92741682002 Collected:07/12/24 13:15 Received:07/12/24 17:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method:
Pace Analytical Services - Charlotte
Monitoring Well Data
Performed by PACE 07/29/24 16:211
Collected By Mattew
Reusch
07/29/24 16:211
Collected Date 7/12/24 07/29/24 16:211
Collected Time 12:54 07/29/24 16:211
pH 6.4 Std. Units 07/29/24 16:211
Temperature 20.9 deg C 07/29/24 16:211
Static Water Level 18.38 feet 07/29/24 16:211
Specific Conductance 418.4 umhos/cm 07/29/24 16:211
Oxygen, Dissolved 1.1 mg/L 07/29/24 16:21 7782-44-71
Total Well Depth 38.02 feet 07/29/24 16:211
Turbidity 5.3 NTU 07/29/24 16:211
Odor ND 07/29/24 16:211
Appearance CLEAR 07/29/24 16:211
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7
Pace Analytical Services - Ormond Beach
200.7 MET ICP
Boron 47.5J ug/L 07/23/24 22:45 7440-42-807/23/24 09:4050.0 12.4 1
Iron 42100 ug/L 07/24/24 19:54 7439-89-607/23/24 09:4080.0 50.0 2
Analytical Method: EPA 200.8 Preparation Method: EPA 200.8
Pace Analytical Services - Ormond Beach
200.8 MET ICPMS
Barium 56.8 ug/L 07/24/24 16:17 7440-39-307/23/24 09:401.0 0.50 1
Cadmium ND ug/L 07/24/24 16:17 7440-43-907/23/24 09:400.10 0.067 1
Cobalt 0.69J ug/L 07/24/24 16:17 7440-48-407/23/24 09:401.0 0.24 1
Manganese 1230 ug/L 07/26/24 14:58 7439-96-507/23/24 09:405.0 1.5 5
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.6 Std. Units 07/19/24 12:47 H30.10 0.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Bromide 0.078J mg/L 07/15/24 01:12 24959-67-90.10 0.060 1
Chloride 2.1 mg/L 07/15/24 01:12 16887-00-61.0 0.60 1
Fluoride 0.075J mg/L 07/15/24 01:12 16984-48-80.10 0.050 1
Sulfate 0.59J mg/L 07/15/24 01:12 14808-79-81.0 0.50 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 5.7 mg/L 07/26/24 18:01 7664-41-70.10 0.031 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92741682
Monitoring Wells
Sample:MW-2 Lab ID:92741682002 Collected:07/12/24 13:15 Received:07/12/24 17:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 6.8 mg/L 07/26/24 04:58 7727-37-907/25/24 18:140.50 0.25 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 0.021 mg/L 07/13/24 02:55 14797-55-80.020 0.0039 1
Nitrogen, Nitrite 0.0099J mg/L 07/13/24 02:55 14797-65-0 B0.020 0.0012 1
Analytical Method: SM 4500-P E-2011
Pace Analytical Services - Asheville
SM4500P-E, Phosphate, Ortho
Orthophosphate as P 0.023J mg/L 07/13/24 03:430.050 0.012 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92741682
Monitoring Wells
Sample:MW-3 Lab ID:92741682003 Collected:07/12/24 15:15 Received:07/12/24 17:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method:
Pace Analytical Services - Charlotte
Monitoring Well Data
Performed by PACE 07/29/24 16:241
Collected By Mattew
Reusch
07/29/24 16:241
Collected Date 7/12/24 07/29/24 16:241
Collected Time 15:15 07/29/24 16:241
pH 5.0 Std. Units 07/29/24 16:241
Temperature 19.3 deg C 07/29/24 16:241
Static Water Level 34.07 feet 07/29/24 16:241
Specific Conductance 119.0 umhos/cm 07/29/24 16:241
Oxygen, Dissolved 5.8 mg/L 07/29/24 16:24 7782-44-71
Total Well Depth 50.02 feet 07/29/24 16:241
Turbidity 9.9 NTU 07/29/24 16:241
Odor ND 07/29/24 16:241
Appearance Clear 07/29/24 16:241
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7
Pace Analytical Services - Ormond Beach
200.7 MET ICP
Boron ND ug/L 07/25/24 03:31 7440-42-807/24/24 09:4850.0 12.4 1
Iron 438 ug/L 07/25/24 03:31 7439-89-607/24/24 09:4840.0 25.0 1
Analytical Method: EPA 200.8 Preparation Method: EPA 200.8
Pace Analytical Services - Ormond Beach
200.8 MET ICPMS
Barium 405 ug/L 07/26/24 00:22 7440-39-307/24/24 09:471.0 0.50 1
Cadmium 0.54 ug/L 07/26/24 00:22 7440-43-907/24/24 09:470.10 0.067 1
Cobalt 3.1 ug/L 07/26/24 00:22 7440-48-407/24/24 09:471.0 0.24 1
Manganese 96.7 ug/L 07/26/24 00:22 7439-96-507/24/24 09:471.0 0.29 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 5.3 Std. Units 07/19/24 13:01 H30.10 0.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Bromide 0.13 mg/L 07/15/24 01:27 24959-67-90.10 0.060 1
Chloride 7.3 mg/L 07/15/24 01:27 16887-00-61.0 0.60 1
Fluoride ND mg/L 07/15/24 01:27 16984-48-80.10 0.050 1
Sulfate ND mg/L 07/15/24 01:27 14808-79-81.0 0.50 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 07/26/24 18:05 7664-41-70.10 0.031 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92741682
Monitoring Wells
Sample:MW-3 Lab ID:92741682003 Collected:07/12/24 15:15 Received:07/12/24 17:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 07/26/24 04:59 7727-37-9 M107/25/24 18:140.50 0.25 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 8.6 mg/L 07/13/24 03:24 14797-55-80.10 0.020 5
Nitrogen, Nitrite 0.0018J mg/L 07/13/24 02:56 14797-65-0 B0.020 0.0012 1
Analytical Method: SM 4500-P E-2011
Pace Analytical Services - Asheville
SM4500P-E, Phosphate, Ortho
Orthophosphate as P ND mg/L 07/13/24 03:440.050 0.012 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92741682
Monitoring Wells
Sample:MW-4 Lab ID:92741682004 Collected:07/12/24 12:30 Received:07/12/24 17:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method:
Pace Analytical Services - Charlotte
Monitoring Well Data
Performed by PACE 07/29/24 16:271
Collected By Matthew
Reusch
07/29/24 16:271
Collected Date 7/12/24 07/29/24 16:271
Collected Time 12:08 07/29/24 16:271
pH 4.9 Std. Units 07/29/24 16:271
Temperature 23.0 deg C 07/29/24 16:271
Static Water Level 20.82 feet 07/29/24 16:271
Specific Conductance 70.2 umhos/cm 07/29/24 16:271
Oxygen, Dissolved 2.0 mg/L 07/29/24 16:27 7782-44-71
Total Well Depth 35.37 feet 07/29/24 16:271
Turbidity 3.4 NTU 07/29/24 16:271
Odor ND 07/29/24 16:271
Appearance Clear 07/29/24 16:271
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7
Pace Analytical Services - Ormond Beach
200.7 MET ICP
Boron ND ug/L 07/25/24 03:34 7440-42-807/24/24 09:4850.0 12.4 1
Iron 109 ug/L 07/25/24 03:34 7439-89-607/24/24 09:4840.0 25.0 1
Analytical Method: EPA 200.8 Preparation Method: EPA 200.8
Pace Analytical Services - Ormond Beach
200.8 MET ICPMS
Barium 144 ug/L 07/26/24 00:27 7440-39-307/24/24 09:471.0 0.50 1
Cadmium 0.11 ug/L 07/26/24 00:27 7440-43-907/24/24 09:470.10 0.067 1
Cobalt 3.0 ug/L 07/26/24 00:27 7440-48-407/24/24 09:471.0 0.24 1
Manganese 131 ug/L 07/26/24 00:27 7439-96-507/24/24 09:471.0 0.29 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 5.2 Std. Units 07/19/24 12:43 H30.10 0.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Bromide 0.19 mg/L 07/15/24 01:42 24959-67-90.10 0.060 1
Chloride 2.3 mg/L 07/15/24 01:42 16887-00-61.0 0.60 1
Fluoride ND mg/L 07/15/24 01:42 16984-48-80.10 0.050 1
Sulfate ND mg/L 07/15/24 01:42 14808-79-81.0 0.50 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 07/26/24 18:06 7664-41-70.10 0.031 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92741682
Monitoring Wells
Sample:MW-4 Lab ID:92741682004 Collected:07/12/24 12:30 Received:07/12/24 17:02 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 07/26/24 05:03 7727-37-9 M107/25/24 18:140.50 0.25 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 4.1 mg/L 07/13/24 02:53 14797-55-80.020 0.0039 1
Nitrogen, Nitrite ND mg/L 07/13/24 02:53 14797-65-00.020 0.0012 1
Analytical Method: SM 4500-P E-2011
Pace Analytical Services - Asheville
SM4500P-E, Phosphate, Ortho
Orthophosphate as P ND mg/L 07/13/24 03:420.050 0.012 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92741682
Monitoring Wells
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
1028302
EPA 200.7
EPA 200.7
200.7 MET
Laboratory:Pace Analytical Services - Ormond Beach
Associated Lab Samples:92741682001, 92741682002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:5651585
Associated Lab Samples:92741682001, 92741682002
Matrix:Water
AnalyzedMDL
Boron ug/L ND 50.0 07/23/24 20:5512.4
Iron ug/L ND 40.0 07/23/24 20:5525.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
5651586LABORATORY CONTROL SAMPLE:
LCSSpike
Boron ug/L 12401250 99 85-115
Iron ug/L 25402500 102 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
5651587MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35891259001
5651588
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Boron ug/L 1250 100 70-130104 3 20125070.7 1320 1360
Iron ug/L 2500 101 70-130105 4 20250026.8J 2550 2650
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
5651589MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35893228004
5651590
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Boron ug/L 1250 100 70-130101 1 20125013.4J 1270 1280
Iron ug/L 2500 103 70-130104 1 20250043430003040
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 13 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92741682
Monitoring Wells
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
1028627
EPA 200.7
EPA 200.7
200.7 MET
Laboratory:Pace Analytical Services - Ormond Beach
Associated Lab Samples:92741682003, 92741682004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:5653455
Associated Lab Samples:92741682003, 92741682004
Matrix:Water
AnalyzedMDL
Boron ug/L ND 50.0 07/25/24 02:1512.4
Iron ug/L ND 40.0 07/25/24 02:1525.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
5653456LABORATORY CONTROL SAMPLE:
LCSSpike
Boron ug/L 12001250 96 85-115
Iron ug/L 24902500 99 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
5653457MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35889218001
5653458
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Boron ug/L 1250 98 70-13099 1 2012500.21 mg/L 1440 1450
Iron ug/L 2500 99 70-13099 1 2025000.030J
mg/L
2490 2510
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
5653459MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92741322001
5653460
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Boron ug/L 1250 96 70-13096 0 201250ND12001200
Iron ug/L 2500 100 70-130100 0 202500ND25002500
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 14 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92741682
Monitoring Wells
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
1028303
EPA 200.8
EPA 200.8
200.8 MET
Laboratory:Pace Analytical Services - Ormond Beach
Associated Lab Samples:92741682001, 92741682002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:5651591
Associated Lab Samples:92741682001, 92741682002
Matrix:Water
AnalyzedMDL
Barium ug/L ND 1.0 07/24/24 13:550.50
Cadmium ug/L ND 0.10 07/24/24 13:550.067
Cobalt ug/L ND 1.0 07/24/24 13:550.24
Manganese ug/L ND 1.0 07/24/24 13:550.29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
5651592LABORATORY CONTROL SAMPLE:
LCSSpike
Barium ug/L 46.250 92 85-115
Cadmium ug/L 5.15 102 85-115
Cobalt ug/L 48.350 97 85-115
Manganese ug/L 47.550 95 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
5651593MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35892652002
5651594
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Barium ug/L M1,R15013270-13096 27 205010.9 76.9 58.8
Cadmium ug/L 5 92 70-13094 2 2050.067U 4.6 4.7
Cobalt ug/L 50 92 70-13094 2 20500.24U 46.0 47.0
Manganese ug/L 50 101 70-13091 8 205014.2 64.8 59.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 15 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92741682
Monitoring Wells
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
1028625
EPA 200.8
EPA 200.8
200.8 MET
Laboratory:Pace Analytical Services - Ormond Beach
Associated Lab Samples:92741682003, 92741682004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:5653449
Associated Lab Samples:92741682003, 92741682004
Matrix:Water
AnalyzedMDL
Barium ug/L ND 1.0 07/25/24 23:470.50
Cadmium ug/L ND 0.10 07/26/24 13:190.067
Cobalt ug/L ND 1.0 07/25/24 23:470.24
Manganese ug/L ND 1.0 07/26/24 13:190.29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
5653450LABORATORY CONTROL SAMPLE:
LCSSpike
Barium ug/L 52.850 106 85-115
Cadmium ug/L 5.45 108 85-115
Cobalt ug/L 54.350 109 85-115
Manganese ug/L 52.450 105 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
5653451MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35889599001
5653452
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Barium ug/L 50 109 70-130102 2 20500.15 mg/L 203 199
Cadmium ug/L 5 109 70-130108 1 2050.000067
U mg/L
5.5 5.4
Cobalt ug/L 50 111 70-130108 3 20500.00024U
mg/L
55.5 54.1
Manganese ug/L 50 107 70-130104 3 20500.00092J
mg/L
54.4 52.7
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
5653453MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92742060010
5653454
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Barium ug/L 50 103 70-130102 1 205011.3 62.8 62.3
Cadmium ug/L 5 106 70-130109 3 205ND5.3 5.5
Cobalt ug/L 50 109 70-130106 2 2050ND54.5 53.4
Manganese ug/L 50 106 70-130104 2 20505.0 57.8 56.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 16 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92741682
Monitoring Wells
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
869359
SM 4500-H+B-2011
SM 4500-H+B-2011
4500H+B pH
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92741682001, 92741682002, 92741682003, 92741682004
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92741646001
4480883SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 6.9 H30106.9
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92741646002
4480884SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 6.9 H31106.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 17 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92741682
Monitoring Wells
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
868148
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92741682001, 92741682002, 92741682003, 92741682004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4474732
Associated Lab Samples:92741682001, 92741682002, 92741682003, 92741682004
Matrix:Water
AnalyzedMDL
Bromide mg/L ND 0.10 07/14/24 18:020.060
Chloride mg/L ND 1.0 07/14/24 18:020.60
Fluoride mg/L ND 0.10 07/14/24 18:020.050
Sulfate mg/L ND 1.0 07/14/24 18:020.50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4474733LABORATORY CONTROL SAMPLE:
LCSSpike
Bromide mg/L 2.52.5 101 90-110
Chloride mg/L 53.050 106 90-110
Fluoride mg/L 2.52.5 101 90-110
Sulfate mg/L 53.250 106 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4474734MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92741511003
4474735
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromide mg/L 2.5 98 90-110101 3 102.5ND 2.4 2.5
Chloride mg/L 50 103 90-110105 2 10502.2 53.5 54.8
Fluoride mg/L 2.5 98 90-110102 4 102.5ND 2.5 2.6
Sulfate mg/L 50 102 90-110105 2 10502.4 53.5 54.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4474736MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92741640002
4474737
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromide mg/L M12.5 10 90-11010 1 102.50.11 0.37 0.36
Chloride mg/L M1508490-11084 0 105091.9 134 134
Fluoride mg/L M12.5 107 90-110115 6 102.50.14 2.8 3.0
Sulfate mg/L M1507390-11056 1 1050160016401630
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 18 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92741682
Monitoring Wells
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
870767
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
350.1 Ammonia
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92741682001, 92741682002, 92741682003, 92741682004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4487533
Associated Lab Samples:92741682001, 92741682002, 92741682003, 92741682004
Matrix:Water
AnalyzedMDL
Nitrogen, Ammonia mg/L ND 0.10 07/26/24 17:220.031
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4487534LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Ammonia mg/L 5.35 105 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4487535MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92742858001
4487536
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L M1511090-110112 0 10526.0 31.5 31.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4487537MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92742858002
4487538
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 98 90-11099 0 10527.0 31.9 31.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 19 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92741682
Monitoring Wells
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
870960
EPA 351.2 Rev 2.0 1993
EPA 351.2 Rev 2.0 1993
351.2 TKN
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92741682001, 92741682002, 92741682003, 92741682004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4488187
Associated Lab Samples:92741682001, 92741682002, 92741682003, 92741682004
Matrix:Water
AnalyzedMDL
Nitrogen, Kjeldahl, Total mg/L ND 0.50 07/26/24 04:530.25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4488188LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Kjeldahl, Total mg/L 10.710 107 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4488189MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92741682003
4488190
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L M11011190-110105 6 1010ND11.2 10.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4488191MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92741682004
4488192
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L M11010290-110111 9 1010ND10.2 11.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 20 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92741682
Monitoring Wells
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
868003
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
353.2 Nitrate + Nitrite, Unpres.
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92741682001, 92741682002, 92741682003, 92741682004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4474376
Associated Lab Samples:92741682001, 92741682002, 92741682003, 92741682004
Matrix:Water
AnalyzedMDL
Nitrogen, Nitrate mg/L ND 0.020 07/13/24 02:270.0039
Nitrogen, Nitrite mg/L 0.0012J 0.020 07/13/24 02:270.0012
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4474377LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate mg/L 1.41.5 96 90-110
Nitrogen, Nitrite mg/L 1.01 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4474378MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92741472001
4474379
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate mg/L 1.5 102 90-110100 1 101.50.84 2.4 2.4
Nitrogen, Nitrite mg/L 1 110 90-110109 0 1010.39 1.5 1.5
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4474380MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92741682001
4474381
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate mg/L 1.5 98 90-11098 0 101.50.052 1.5 1.5
Nitrogen, Nitrite mg/L 1 103 90-110102 1 1010.0019J 1.0 1.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 21 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92741682
Monitoring Wells
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
868008
SM 4500-P E-2011
SM 4500-P E-2011
SM4500P-E Phosphorus, Ortho
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92741682001, 92741682002, 92741682003, 92741682004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4474394
Associated Lab Samples:92741682001, 92741682002, 92741682003, 92741682004
Matrix:Water
AnalyzedMDL
Orthophosphate as P mg/L ND 0.050 07/13/24 03:250.012
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4474395LABORATORY CONTROL SAMPLE:
LCSSpike
Orthophosphate as P mg/L 0.250.25 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4474396MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92741177001
4474397
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Orthophosphate as P mg/L M10.25 120 90-110128 1 100.253.4 3.7 3.7
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4474398MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92741177002
4474399
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Orthophosphate as P mg/L 0.25 94 90-11096 1 100.250.52 0.76 0.76
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 22 of 27
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92741682
Monitoring Wells
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analyte was detected in the associated method blank.B
Sample was received or analysis requested beyond the recognized method holding time.H3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 23 of 27
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92741682
Monitoring Wells
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92741682001 MW-1R
92741682002 MW-2
92741682003 MW-3
92741682004 MW-4
92741682001 1028302 1028425MW-1R EPA 200.7 EPA 200.7
92741682002 1028302 1028425MW-2 EPA 200.7 EPA 200.7
92741682003 1028627 1028756MW-3 EPA 200.7 EPA 200.7
92741682004 1028627 1028756MW-4 EPA 200.7 EPA 200.7
92741682001 1028303 1028423MW-1R EPA 200.8 EPA 200.8
92741682002 1028303 1028423MW-2 EPA 200.8 EPA 200.8
92741682003 1028625 1028758MW-3 EPA 200.8 EPA 200.8
92741682004 1028625 1028758MW-4 EPA 200.8 EPA 200.8
92741682001 869359MW-1R SM 4500-H+B-2011
92741682002 869359MW-2 SM 4500-H+B-2011
92741682003 869359MW-3 SM 4500-H+B-2011
92741682004 869359MW-4 SM 4500-H+B-2011
92741682001 868148MW-1R EPA 300.0 Rev 2.1 1993
92741682002 868148MW-2 EPA 300.0 Rev 2.1 1993
92741682003 868148MW-3 EPA 300.0 Rev 2.1 1993
92741682004 868148MW-4 EPA 300.0 Rev 2.1 1993
92741682001 870767MW-1R EPA 350.1 Rev 2.0 1993
92741682002 870767MW-2 EPA 350.1 Rev 2.0 1993
92741682003 870767MW-3 EPA 350.1 Rev 2.0 1993
92741682004 870767MW-4 EPA 350.1 Rev 2.0 1993
92741682001 870960 871200MW-1R EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92741682002 870960 871200MW-2 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92741682003 870960 871200MW-3 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92741682004 870960 871200MW-4 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92741682001 868003MW-1R EPA 353.2 Rev 2.0 1993
92741682002 868003MW-2 EPA 353.2 Rev 2.0 1993
92741682003 868003MW-3 EPA 353.2 Rev 2.0 1993
92741682004 868003MW-4 EPA 353.2 Rev 2.0 1993
92741682001 868008MW-1R SM 4500-P E-2011
92741682002 868008MW-2 SM 4500-P E-2011
92741682003 868008MW-3 SM 4500-P E-2011
92741682004 868008MW-4 SM 4500-P E-2011
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 08/20/2024 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 24 of 27
Page 25 of 27
Page 26 of 27
Page 27 of 27