HomeMy WebLinkAboutNC0078000_Renewal Application_20160216 0 ARAD1S
Infrastructure, environment, facilities
Arcadis G&M of North Carolina,
Inc.
801 Corporate Center Drive
Suite 300
Ms. Wren Thedford Raleigh,
NCDEQ RECEIVEDINCDEQIDWR North Carolina 27607-5073
Division of Water Resources Tel 919 854 1282
NPDES Unit FEB 17 2016 Fax 919 854 5448
1617 Mail Service Centerwww.arcadis.com
lRaleigh, NC 27699-1617 Water Qua ecy
Permitting Section
ENVIRONMENTAL
Subject:
NPDES Permit Renewal Application, Groundwater Remediation System,Brenntag Date:
Mid-South, Inc., (Former Worth Chemical Facility),Greensboro,North Carolina. February 9, 2016
NPDES Permit No. NC0078000
Contact:
Jim Shilliday
Dear Ms. Thedford:
Phone:
919-854-1282
On behalf of Brenntag Mid-South, Inc. (Brenntag), Arcadis G&M of North Carolina,
Inc. (Arcadis) has enclosed one original and two copies of the National Pollutant E-mail:
Discharge Elimination System(NPDES)permit renewal application for the jshilliday@arcadis.com
continued discharge of effluent from a groundwater remediation system at the
Brenntag facility(former Worth Chemical facility) in Greensboro,North Carolina. Our ref:
Treated groundwater from the remediation system is discharged directly to an un- NC102030.0015
named tributary of South Buffalo Creek located along the eastern boundary of the
site. No significant changes have been made to the existing treatment facility since
issuance of the last permit.
Please note that sludge is neither generated nor discharged by the groundwater
remediation system; therefore, a sludge management plan has not been included with
this application. Any solids(i.e. silt, iron and manganese precipitate)generated
during the groundwater extraction process are filtered from the treatment stream
using bag filters. The existing NPDES permit for the facility does not have an
effluent monitoring requirement for suspended solids.
Other items enclosed with this letter in support of the NPDES permit renewal
application include the following:
• Figure 1 -USGS topographic map of the project area that depicts the location of
the system outfall;
• Figure 2 - site map that depicts the route of the treated water to the discharge
point;
ARCADIS
• Attachment A—a copy of the October 2015 Discharge Monitoring Report which
summarizes the most recent analytical data for the system effluent.
If you have any questions regarding the information presented in the NPDES permit
application or any of the supporting material, please call us at (919)854-1282.
Sincerely,
Arcadis G&M of North Carolina, Inc.
(Awe , ' � �►
David Twamley, L.G. es E. Shilliday,III, .G.
Staff Scientist 'rincipal Scientist, Pro'ect Manager
Copies:
Mr. Bruce Biehl(Brenntag Mid-South)
Mr. Bill Mesar(Brenntag Mid-South)
NCDEQ/DWR/NPDES Unit
File
G lENVVWOrth Chemica0Greensboro Facility1NC 102030.0015\NPDES\Permit Renewal Application\Cover Letter for NPDES Permit Renewal.door
Page:
2/2
NPDES PERMIT APPLICATION - SHORT FORM C - GW
For discharges associated with groundwater treatment facilities.
Mail the complete application to:
N. C. Department of Environment and Natural Resources
Division of Water Quality / NPDES Unit
1617 Mail Service Center, Raleigh, NC 27699-1617
NPDES Permit Number NC0078000
If you are completing this form in computer use the TAB key or the up - down arrows to move from one
field to the next. To check the boxes, click your mouse on top of the box. Otherwise,please print or type.
1. Contact Information:
Owner Name Bruce Biehl
Facility Name Brenntag Mid-South, Inc. RECEIVEDr'NCDEQlD1NR
Mailing Address 2000 East Pettigrew Street EB 17 1 u'F
City Durham Water Quality
permitting Section
State / Zip Code North Carolina 27703
Telephone Number (919)596 0681
Fax Number (919)596 5441
e-mail Address Bbiehl@brenntag.com
2. Location of facility producing discharge:
Check here if same as above ❑
Street Address or State Road 2 HCI Boulevard
City Greensboro
State / Zip Code North Carolina / 27409
County Guilford
3. Operator Information:
Name of the firm, consultant or other entity that operates the facility. (Note that this is not referring to the
Operator in Responsible Charge or ORC)
Name Arcadis
Mailing Address 801 Corporate Center Drive, Suite 300
City Raleigh
State / Zip Code North Carolina / 27607
Telephone Number (919)854 1282
Fax Number (919)854 5448
4. Ownership Status:
Federal ❑ State ❑ Private ® Public ❑
Page I of 3 C-GW 03/05
NPDES PERMIT APPLICATION - SHORT FORM C - GW
For discharges associated with groundwater treatment facilities.
5. Products recovered:
Gasoline ❑ Diesel fuel ❑ Solvents ® Other chlorinated and
nonchlorinated solvents
6. Number of separate discharge points: 1
Outfall Identification number(s) 001
7. Frequency of discharge: Continuous ® Intermittent ❑
If intermittent:
Days per week discharge occurs: Duration:
8. Treatment System Design flow 0.216 MGD
9. Name of receiving stream(s) (Provide a map showing the exact location of each outfall, including
latitude and longitudes
Unnamed Tributary to South Buffalo Creek
36 03 51.92N
79 52 37.38W
10. Please list all additives to the treatment system, including chemicals or nutrients, that have
the potential to be discharged.
No chemical additives are addeded to the treatment system
11. Is this facility located on Indian country? (check one)
Yes ❑ No
12. Additional Information
All applicants (including renewals
• A USGS topographical map (or copy of the relevant portion) which shows all outfalls
• A summary of the most recent analytical results (effluent data, if available) containing the
maximum values for each chemical detected
NEW Applicants only:
Engineering Alternative Analysis
• Description of remediation treatment system components, capacities, and removal efficiency
for detected compounds.
If the treatment system will discharge to a storm sewer, written approval from the
municipality responsible for the sewer.
A list of any chemicals found in detectable amounts at the site, with the maximum observed
concentration reported for each chemical (the most recent sample must be collected less
than one year prior to the date of this application)
For petroleum-contaminated sites- Analyses for Volatile Organic Compounds (VOC) should
be performed. Analyses for any fuel additives likely to be present at the site and for phenol
and lead should also be performed.
For sites contaminated with solvents or other contaminants - EPA Method 624/625
analysis should be performed.
Page 2 of 3 C-GW 03/05
NPDES PERMIT APPLICATION - SHORT FORM C - GW
For discharges associated with groundwater treatment facilities.
13. Applicant Certification
I certify that I am familiar with the information contained in the application and that to the
best of my knowledge and belief such information is true, complete, and accurate.
Bruce Biehl Director of Regulatory Affairs
Printed name of Person Signing Title
-0/,/.7-6"77-6
Signature of App icant Date
North Carolina General Statute 143-215.6 (b)(2) provides that: Any person who knowingly makes any false
statement representation, or certification in any application, record, report, plan, or other document files or
required to be maintained under Article 21 or regulations of the Environmental Management Commission
implementing that Article, or who falsifies, tampers with, or knowingly renders inaccurate any recording or
monitoring device or method required to be operated or maintained under Article 21 or regulations of the
Environmental Management Commission implementing that Article, shall be guilty of a misdemeanor punishable
by a fine not to exceed $25,000, or by imprisonment not to exceed six months, or by both. (18 U.S.C. Section
1001 provides a punishment by a fine of not more than $25,000 or imprisonment not more than 5 years, or both,
for a similar offense.)
Page 3 of 3 C-GW 03/05
T
Gl
C
z
m
I
FIGURES
f<�
St
A
�f1
ny�
ld t
801 Corporate Center Drive,
C2919-854-1282
Suite 300
ARCADIS
Raleigh, NC 27607
Infrastructure
buildin s environment
communications
REV.
DRAWING DATE:
ACAD FILE:
1/9/06
QUADRANGLE LOCATION N
SCALE 1:24000
SITE LOCATION MAP
0 2000 4000
CLIENT:
PM.
BRENNTAG SOUTHEAST, INC.
JS
LOCATION:
2 HCI BOULEVARD
PEIRG:
SOURCE: TOPOGRAPHY TAKEN FROM USGS 7.5 MINUTE QUADRANGLL
GREENSBORO, NC
GUILFORD AND GREENSBORO, NC MAPS
DESIGNED:
DETAILED:
PROJECT NO:
FIGURE:
1951 AND PHOTOREVISED IN 1994
CJK
NC102030.0010
1
1:o
0
N
0
N
O
M
Al
AREA
OF
-------___-__-_____ CONCERN
�r
t
1 /l
/ Groundwater
Treatment r j Treatment
/ System System
NPDES
Discharge
Point
••� ' � Outfall 001)
RAS \.
Building \ "\
Greensboro Auto
Auction Shop
0
LEGEND
BUILDINGS/STRUCTURES
RAILROAD TRACKS
FENCE
— — — —
PROPERTY LINE
— — —
CREEK
CULVERTED SECTION OF
CREEK
'
AREA OF CONCERN
C
SWMU LOCATION
_ — _
CLOSED SURFACE
IMPOUNDMENT
SCALE IN FEET
0
100 200
OMER
PRJT MANAGER, CHECKED BY- DRAFTER, PROJECT NUNBERe NC1O2O30.001S FIGURE:
ARCADIS J. SHILLIDAY D. TVANLEY
NOTES:
Infrastructure, environment, facilities 1. Bullding Locations 0 Watt Locations are based on site nap BRENNTAG MID —SOUTH, INC. SITE MAP ^
A�O15 CSY or North p� provided by Duncklee L Dunham P.C. May 2002. 1
eo1l corporate c.it r D,w.. Suft aoo GREENSBORO, NORTH CAROLINA
277
T.I.• 914854-1122E2 Fox 919-854-5448
amodi- --
I
D
I
mr
Z
A
ATTACHMENT A
DISCHARGE MONITORING
REPORT-OCTOBER 2015
ARCADIS
ARCADIS G&M of North Carolina,
Infrastructure, envtronrnenI, farritnes Inc.
801 Corporate Center Drive
Suite 300
ATTN: Central Files Raleigh,
North Carolina Department of Environmental Quality North Carolina 27607-5073
Division of Water Resources Tel 919 854 1282
1617 Mail Service Center Fax 919 854 5448
Raleigh, North Carolina 27699-1617 www.arcadis-us.com
Subject: ENVIRONMENTAL
Discharge Monitoring Report for October 2015, Brenntag Mid-South Facility
2 HCI Boulevard, Greensboro, North Carolina
NPDES Permit No. NC0078000
Guilford County
Date:
November 24,2015
Dear Sir or Madam:
Contact:
ARCADIS is pleased to submit the attached Discharge Monitoring Report (DMR) for Jim Shilliday
the month of October 2015 on behalf of Brenntag Mid-South, Inc. for the facility
located at 2 HCI Boulevard in Greensboro, North Carolina. Also attached is the Phone
laboratory analytical data report for the parameters shown on the DMR and a copy of Ext. 52302
the Effluent Aquatic Toxicity Report Form(Form AT-1).
Email:
During October 2015,the groundwater remediation system operated throughout the jshilliday@arcadis.com
month with approximately 7 days of"downtime"due to maintenance associated with
the blower unit for the groundwater remediation system's air stripper tower. A total Our ref:
of 1,066,610 gallons of water were extracted and treated by the groundwater NC102030.0015
remediation system from September 30, 2015 through October 30, 2015. As of
October 30, 2015, approximately 371,273,870 gallons of water had been extracted
and treated by the groundwater remediation system since activation of the system in
October 1992.
The pH of the effluent from the groundwater remediation system was analyzed on
October 16, 2015. The measurement indicated an effluent pH of 7.87 standard units,
which is in compliance with the stipulated range of 6 to 9 standard units.
The groundwater remediation system effluent was sampled on October 27, 2015, and
the effluent sample was analyzed for selected volatile organic compounds(VOCs)by
EPA Method 8260 as required by the NPDES permit. All parameters were in
compliance with permit requirements.
The remediation system effluent was sampled for the chronic toxicity test on October
27 and 29, 2015. The grab samples were transported on ice to Research& Analytical
Laboratories, Inc. in Kernersville, North Carolina. The samples were analyzed in
accordance with the test procedures outlined in the North Carolina Ceriodaphnia
Part of a bigger picture
ARCADIS
Chronic Effluent Toxicity Procedure(revised February 1998). The effluent samples
passed the chronic toxicity test.
As required by the NPDES permit, the remediation system effluent will be sampled
again for VOCs and chronic toxicity testing during the next quarterly sampling event
in January 2016.
If you have any questions regarding the information presented in this letter or on the
DMR,please call one of the individuals listed below.
Sincerely,
ARCADIS G&M of North Carolina, Inc.
044.j /
David Twamley, L.G. James E. Shilliday, ✓�
Staff Scientist Principal Scientist/ ._._
Project Manager
Copies:
Bruce Biehl —Brenntag Mid-South(Durham)
Bill Mesar—Brenntag Mid-South(Greensboro)
Project File
Page:
0 ENV Worth Chemical Greensboro Facility NO.102030 0015 NEDIS.2015-10 October DMR and C l report Oct 2015 DRB tetter dot: 2/2
EFFLUENT
NPDES PERMIT NO. NC0078000 DISCHARGE NO. 001 MONTH October YEAR 2015
FACILITY NAME Brenntag Mid-South,Inc CLASS PC-1 COUNTY Guilford
CERTIFIED LABORATORY(1) Test America,Inc. CERTIFICATION NO. 269
(list additional laboratories on the backside/page 2 of this form)
OPERATOR IN RESPONSIBLE CHARGE(ORC) William Mesar GRADE PC-1 CERTIFICATION NO. 985455
PERSON(S)COLLECTING SAMPLES Dave Twamley(ARCADIS G&M) ORC PHONE (336)292-5166
CHECK BOX IF ORC HAS CHANGED* 0 NO FLOW/DISCHARGE FROM SITE
Mail ORIGINAL and ONE COPY to: j����"/ 1�ry /9
ATTN:CENTRAL FILES a G lw,.,, , , 7/// 7/5
DIVISION OF WATER QUALITY (SIGNATURE OF,OPERATOR IIyRESPONSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THAT THIS REPORT IS
RALEIGH, NC 27699-1617 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE.
50050 00400 34010 34030 34546 78391 TGP3B
E k FLOW d a
.,
e
Zs
s y C> o ° EFF 1g a
w cAy
FQ INF ❑ 0du ° [" H L. C h ` 6a
v p
a
o L
a Q a c ,9F- u .`
Op Cl. IO G s
U
HRS HRS Y/B/N MGD
1 0.0490
2 1103 1 Y 0.0490
3 0.0456
4 0.0456
5 1116 1 Y 0.0456
6 0.0000
7 0.0000
8 0.0000
9 0.0000
10 0.0000
11 0.0000
12 0.0000
13 1243 1 Y 0.0059 _
14 0.0562
15 846 1 Y 0.0562
16 1430 1 Y 0.0652 7.87
17 0.0483
18 0.0483
19 0.0483
20 916 1 Y 0.0483
121 1641 1 Y 0.0648
22 0.0423
23 1018 1 Y 0.0423
24 0.0150
25 0.0150
26 839 1 Y 0.0150
27 0.0586 <1.0 <1.0 <1.0 1.2 pass
128 1110 1 Y 0.0586
29 0.0513
30 1637 1 Y 0.0513
131_ 0.0513
AVERAGE 0.0347 7.87 <1.0 <1.0 <1.0 1.2 pass
MAXIMUM 0.0652 7.87 <1.0 <1.0 <1.0 1.2 pass
MINIMUM 1)MOO 7.87 <1.0 <1.0 <1.0 1.2 pass
Comp.(C)/Grab(G) G G G G G G
Monthly Limit 0.21 6 6-9 NA NA NA NA NA
DWQ Form MR-1.1 (11/04)
Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements X
(including weekly averages,if applicable)
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially
threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the
permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the
permittee becomes aware of the circumstances.
If the facility is noncompliant,please attach a list of corrective actions being taken and a time-table for
improvements to be made as required by Part II.E.6 of the NPDES permit.
"I certify, under penalty of law,that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who managed the system,or those persons directly responsible
for gathering the information,the information submitted is,to the best of my knowledge and belief,true,accurate,and
complete. I am aware that there are significant penalties for submitting false information,including the possibility of
fines and imprisonment for knowing violations."
William Mesar
Permittee (Please print or type)
ignature of P7rmittee***q.
Date
(Required unless submitted electronically)
Brenntag Mid-South, Inc. 2000 East Pettigrew
Street,Durham,NC 27703 (919) 596-0681 May 31,2016
Permittee Address Phone Number e-mail address Permit Expiration Date
ADDITIONAL CERTIFIED LABORATORIES
Certified Laboratory(2) R&A Laboratories Certification No. 34
Certified Laboratory(3) Certification No.
Certified Laboratory(4) Certification No.
Certified Laboratory(5) Certification No.
PARAMETER CODES
Parameter Code assistance may be obtained by calling the NPDES Unit at(919)733-5083 or by visiting the Surface
Water Protection Section's web site at h2o.enr.state.nc.us/wqs and linking to the unit's information pages.
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flow/Discharge From Site: Check this box if no discharge occurs and,as a result,there are no data to be
entered for all of the parameters on the DMR for the entire monitoring period.
** ORC On Site?: ORC must visit facility and document visitation of facility as required per I5A NCAC 8G.0204.
***Signature of Permittee: If signed by other than the permittee,then the delegation of the signatory authority must be on
file with the state per 15A NCAC 2B .0506(b)(2)(D).
Page 2
Client Sample Results
Client: ARCADIS U.S.. Inc. TestAmerica Job ID: 680-118349-1
Project/Site: Brenntag/FVVC/Greensboro (Effluent)
Client Sample ID: Effluent Lab Sample ID: 680.118349.1
Date Collected: 10/27/15 13:00 Matrix:Water
Date Received: 10/28/15 10:00
Method: 8260B . Volatile Organic Compounds (GC/MS)
Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac
Benzene - 1.0 U 1.0 ug/L 11/03/15 17:24 1
Toluene 1.0 U 1.0 ug/L 11/03/15 17:24 1
trans-1,2-Dichloroethene 1.0 U 1.0 ug/L 11/03/15 17:24 1
Trichloroethene 1.2 1.0 ug/L 11/03/15 17:24 1
Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1
Toluene-d8(Surr) 97 70-130 11/03/15 17:24 1
1,2-Dichloroethane-d4(Surr) 88 70-130 11/03/15 17:24 1
Dibromofluoromethane(Surr) 92 70-130 11/03/15 17:24 1
4-Bromofluorobenzene(Surr) 98 70-130 11/03/15 17.24 1
TestAmerica Savannah
Page 8 of 15 11/10/2015
Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 11/05/15
' Facility: BRENNTAG MIDSOUTH NPDES#: NC0078000 Pipe#: 001 County: GUILFORD
Laboratory Per = i : Test: R & A LABORATORIES, INC.
Comments: Final Effluent An
�
X . .
Sign- , re�_ Aper-tor n Responsi. e C arge Arcadis Project
X ./. A
S`• at-re o- . .oratory Supervisor * PASSED: 2.54% Reduction *
ork Order: 10844/10942 Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Environmental Management
N.C. Dept. of EHNR
1621 Mail Service Ctr
Raleigh, North Carolina 27699-1621
)rth Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test Chronic Test Results
Calculated t = 0.888
Tabular t = 2.508
)NTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 % Reduction = 2.54
% Mortality Avg.Reprod.
# Young Produced 25 22 27. 23 23 21. 125 21 22 24 24 25
0.00 23 .00
Control Control
Adult (L)ive (D)ead L L L L L L L L L L L L
- 0.00 22.42
Treatment 2 Treatment 2
'fluent %: 90%
tEATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV
6.937% PASS FAIL
# Young Produced 24 21 22 23 25 21 22 25 21 20 22 23 % control orgs X
producing 3rd
brood Check One
' Adult (L) ive (D)ead L L L L L L L L L L L L 100%
1st sample 1st sample 2nd sample Complete This For Either Test
pH Test Start Date: 10/28/15
Control 6.94 6.99 6.91 7.00 6.96 7.04 Collection (Start) Date
Sample 1: 10/27/15 Sample 2: 10/29/15
eatment 2 7.81 7.88 6.96 7.04 6.97 7.05 Sample Type/Duration 2nd
1st P/F
s s s Grab Comp. Duration D
t e t e t e I S S
a n a n a n Sample 1 X hrs L A A
r d r d r d U M M
t t t Sample 2 X hrs T P P
1st sample 1st sample 2nd sample
D. - Hardness(mg/1) 47
Control 8 .6 8.4 8.6 18.3 8.6 8.4
Spec. Cond. (pmhos) 186 443 439
treatment 2 8.5 8.3 8 .5 18.2 8.5 8 .3
Chlorine(mg/1) 0.02 0.02
250/Acute Toxicity Test Sample temp. at receipt(°C) 2.0 3.0
(Mortality expressed as %, combining replicates) )
Note: Please
% % % % % % % % % % Concentration Complete This
Section Also
% % % % % % % % % % Mortality
start/end start/end
750 = % Method of Determination Control
95% Confidence Limits Moving Average Probit
% -- % Spearman Karber = Other - High
Conc.
pH D.O.
Organism Tested: Ceriodaphnia dubia Duration(hrs) :
spied from DEM form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.32)
ARCADIS
ARCADIS G&M of North Carolina,
Inflastllictute, Pnvitonruent, fact/lies Inc.
801 Corporate Center Drive
Suite 300
North Carolina Department of Environmental Quality Raleigh,
Division of Water Resources North Carolina 27607-5073
Aquatic Toxicology Branch Tel 919 854 1282
1623 Mail Service Center Fax 919 854 5448
Raleigh,North Carolina 27699-1623 www.arcadis-us.com
Subject: ENVIRONMENTAL
Chronic Toxicity Testing Report for October 2015, Brenntag Mid-South Facility,
2 HCI Boulevard, Greensboro,North Carolina
NPDES Permit No. NC0078000
Guilford County
Date:
November 24, 2015
Dear Sir or Madam:
Contact:
ARCADIS is pleased to submit the attached Division of Environmental Management Jim Shilliday
(DEM)form AT-1 for the month of October 2015 on behalf of Brenntag Mid-South,
Inc. for the facility located at 2 HCI Boulevard in Greensboro, North Carolina. Also Phone:
attached is the laboratory analytical data report for the analytical parameters required Ext. 2302
by the NPDES permit.
Email:
During October 2015,the groundwater remediation system operated throughout the jshilliday@arcadis.com
month with approximately 7 days of"downtime"due to maintenance associated with
the blower unit for the groundwater remediation system's air stripper tower. A total Our ret:
of 1,066,610 gallons of water were extracted and treated by the groundwater NC102030.0015
remediation system from September 30,2015 through October 30,2015. As of
October 30, 2015, approximately 371,273,870 gallons of water had been extracted
and treated by the groundwater remediation system since activation of the system in
October 1992.
The pH of the effluent from the groundwater remediation system was analyzed on
October 16, 2015. The measurement indicated an effluent pH of 7.87 standard units,
which is in compliance with the stipulated range of 6 to 9 standard units.
The groundwater remediation system effluent was sampled on October 27, 2015, and
the effluent sample was analyzed for selected volatile organic compounds(VOCs)by
EPA Method 8260 as required by the NPDES permit. All parameters were in
compliance with permit requirements.
The remediation system effluent was sampled for the chronic toxicity test on October
27 and 29, 2015. The grab samples were transported on ice to Research& Analytical
Laboratories, Inc. in Kernersville,North Carolina. The samples were analyzed in
accordance with the test procedures outlined in the North Carolina Ceriodaphnia
Part of a bigger picture
ARCADIS
Chronic Effluent Toxicity Procedure(revised February 1998). The effluent samples
passed the chronic toxicity test.
As required by the NPDES permit,the remediation system effluent will be sampled
again for VOCs and chronic toxicity testing during the next quarterly sampling event
in January 2016.
If you have any questions regarding the information presented in this letter or on the
attached effluent toxicity report form(form AT-1), please call one of the individuals
listed below.
Sincerely,
ARCADIS G&M of North Carolina, Inc.
Afj, /
•
David Twamley, L.G. James E. Shilliday, III, E.G.
Staff Scientist Principal Scientist/
. Project Manager
Copies:
Bruce Biehl—Brenntag Mid-South(Durham)
Bill Mesar—Brenntag Mid-South (Greensboro)
Project File
Page:
G:1ENV1Worth Chemical\Greensboro Facility'NC102030 00151NPDES12015-10 October DMR and CT reportlOct 2015 Toxicity Letter.doc 2/2
Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 11/05/15
IFacility: BRENNTAG MIDSOUTH NPDES#: NC0078000 Pipe#: 001 County: GUILFORD
Laboratory PerFeli4 - Test: R & A LABORATORIES, INC.
IX /f l/`' Comments: Final Effluent An
Sign. re% eper.tor n Responsi. e C arge Arcadis Project
X L.
S • at-re o' . .oratory Supervisor * PASSED: 2.54% Reduction *
ork Order: 10844/10942 Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Environmental Management
N.C. Dept. of EHNR
1621 Mail Service Ctr
Raleigh, North Carolina 27699-1621
Orth Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test Chronic Test Results
Calculated t = 0.888
Tabular t = 2.508
)NTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 % Reduction = 2 .54
% Mortality Avg.Reprod.
# Young Produced 25 22 27. 23 23 22 25 21 22 24 24 25 -
• 0.00 23.00
Control Control
Adult (L)ive (D)ead L L L L L L L L L L L L
l 0.00 22.42
Treatment 2 Treatment 2
fluent %: 90%
?EATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV
1 6.937% PASS FAIL
# Young Produced 24 21 22 23 25 21 22 25 21 20 22 23 % control orgs X
producing 3rd
brood Check One
Adult (L)ive (D)ead L L L L L L L L L L L L 100%
1st sample 1st sample 2nd sample Complete This For Either Test
pH Test Start Date: 10/28/15
Control 6.94 6.99 6.91 7.00 6.96 7.04 Collection (Start) Date
Sample 1: 10/27/15 Sample 2: 10/29/15
eatment 2 7.81 7.88 6.96 7.04 6.97 7.05 Sample Type/Duration 2nd
1st P/F
s s s Grab Comp. Duration D
t e t e t e I S S
a n a n a n Sample 1 X hrs L A A
r d r d r d U M M
t t t Sample 2 X hrs T P P
1st sample 1st sample 2nd sample
D. Hardness(mg/1) 47
Control 8.6 8.4 8.6 18.3 8.6 8.4
Spec. Cond. (pmhos) 186 443 439
Creatment 2 8.5 8.3 8.5 18.2 8.5 8.3
Chlorine(mg/1) 0.02 0.02
250/Acute Toxicity Test Sample temp. at receipt (°C) 2.0 3.0
'mortality expressed as %, combining replicates) 1
Note: Please
% % % % % % % % % % Concentration Complete This
Section Also
% % % % % % % % % % Mortality
start/end start/end
'50 = % Method of Determination Control
95% Confidence Limits Moving Average Probit
% -- % Spearman Karber - Other - High
Conc.
pH D.O.
irganism Tested: Ceriodaphnia dubia Duration(hrs) :
pied from DEM form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.32)
Client Sample Results
Client: ARCADIS U.S., Inc. TestAmerica Job ID: 680-118349-1
Project/Site: Brenntag/FWC/Greensboro (Effluent)
Client Sample 1b: Effluent - Lab Sample 6b: 680-118349
Date Collected: 10/27115 13:00 Matrix:Water
Date Received: 10/28/16 10:00
Method: 82608 • Volatile Organic Compounds (GC/MS)
Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac
Benzene 1.0 U 1.0 ug/L 11/03/15 17:24 1
Toluene 1.0 U 1.0 ug/L 11/03/15 17:24 1
trans-1,2-Dichloroethene 1.0 U 1.0 ug/L 11/03/15 17:24 1
Trichloroethene 1.2 1.0 ug/L 11/03/15 17:24 1
Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac
Toluene-d8(Surr) 97 70-130 11/03/15 17:24 1
1,2-Dichloroethane-d4(Surr) 88 70-130 11/03/15 17:24 1
Dibromofluoromethane(Surr) 92 70-130 11/03/15 17:24 1
4-Bromofluorobenzene(Surr) 98 70-130 11/03/15 17:24 1
TestAmerica Savannah
Page 8 of 15 11/10/2015
r„y PAT MCCRORY
DONALD R. VAN DER VAART
S. JAY ZIMMERMAN
Water Resources
ENVIRONMENTAL QUALITY
February 23, 2016
Mr. Bruce Biehl
Brenntag Mid-South, Inc.
2000 East Pettigrew Street
Durham, NC 27703
Subject: Acknowledgement of Permit Renewal
Application No. NC0078000
Brenntag/Greensboro Remediation
Guilford County
Dear Permittee:
The Water Quality Permitting Section has received your permit renewal application on February 17,
2016. A member of the NPDES Unit will review your application. They will contact you if additional
information is required to complete your permit renewal. Per G.S. 150B-3 your current permit does not
expire until permit decision on the application is made. Continuation of the current permit is contingent on
timely and sufficient application for renewal of the current permit. Please respond in a timely manner to
requests for additional information necessary to complete the permit application.
If you have any additional questions concerning renewal of the subject permit, please contact Joe
Corporon at 919-807-6394 or Joe.Corporon@nedenr.gov.
Sincerely,
W rZw Tke-0L0-Y0/
Wren Thedford
Wastewater Branch
cc: Central Files
NPDES
Winston-Salem Regional Office
State of North Carolina Environmental Quality Water Resources
1617 Mail Service Center Raleigh,North Carolina 27699-1617
919-807-6300