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Home My WebLink AboutWQ0003698_Monitoring - 11-2022_20221213GW-59A COMPLIANCE REPORT FORM Permit # k1QOW 309 (Submit one each monitoring period with GW-59 forms.) 1 Enter date monitoring results were due. ( Dee 2017-) Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date? X 2 Was any required information missing on the GW-59 report forms? YES NO IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? If the answer is "Yes ", contact the Regional Of ce for guidance. 4 Are any monitored constituents equal to or above the established standards? Ye NO If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: S et. A A-ra cVed 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? x If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). See, AttaGkeA Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO x If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. 12e9 ior,,l a-PPtce, Corn-W4ea. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? X If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Reoiona/ Offic6 within 90 days; an evaluation may be wired to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subiect the oermittee to a Notice of Violation, fines, and/or penalties. �t l b-Ice- Co n� � ;f- e9 o r,a �; o �. �; N III DEC 1 2022 g The person completing this portion (G W-59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current G W-59 form. 1 hereby acknowledge that the above information was evaluated and the information submitted in this report (Compliance Report GW-69A) is true and complete to the best of my knowledge. Signat of Permittee (or A oriz Agent) Date GW-59A 12/8/2003 Question #4 LAB DATA WHICH EXCEEDS PERMIT DATE MONITORING WELL # PARAMETER REPORTED DATA 11.3.22 1 pH 5.9 2 Ammonia 5.4 mg/L Iron 27,100ug/L Manganese 1,250 ug/L pH 6.4 3 Cobalt 2.5 ug/L Manganese 98.5 ug/L pH 5.1 4 Manganese 86 ug/L PH 4.9 -w QUESTION #5 LAB DATA WHICH EXCEEDS PERMIT FOR LAST 2 PREVIOUS YEARS REPORTED DATE MW # PARAMETER DATA 11/16/2020 1 Iron 0.691 mg/L Manganese 50.6 ug/L pH 6 2 Ammonia 5.6 mg/L Iron 21.6 mg/L Manganese 1490 ug/L pH 6.4 3 Nitrate 32.1 mg/L Iron 1.07 mg/L Manganese 434 ug/L _ pH 5 _ _ 4 Manganese 127 ug/L pH 5.1 5/18 & 6/1/2021 1 Iron 0.948 mg/L �. _pH 5.9 2 Ammonia 7.3 mg/L _ Iron 39.5mg/L _ Manganese 1060 ug/L 3 Nitrate 21.2mg/L Iron 0.937mg/L _ Manganese 265 ug/L �pH 4.9 _ 4 Manganese 207 ug/L _ pH 5 11.30.21 1 pH 5.9 2 Ammonia 6.0 mg/L Iron 28.4mg/L Manganese 1080 ug/L pH 6 3 Nitrate 12.1mg/L Manganese 132 ug/L pH 5 4 Manganese 119 ug/L pH 5.1 5/27-6/9/2022 1 pH 5.7 2 Ammonia 6.4 mg/L Iron 43.9 mg/L Manganese 1,200 ug/L pH 6.3 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING:'"INPOF3NJiTIo1V' • • DEP -'. IR . OF WATER Fd $ o`ce8 ;NG UNIT COMPLIANCE REPORT FORM CENTER, RALEIGH, NC 27699.1617 Phone: 919.807.6306 FACILITY INFORMATION Please Pnnf Clearly or Type PERMIT Number: Expiration Date Facility Name: Corpening Creek WWTP--City of Marion Non -Discharge WQ00003698 UIC NPDES Other Permit Name (if different): Facility Address: Marion NC 28752 TYPE OF PERMITTED OPERATION BEING MONITORED Marion "tfe`' NC 28752 County McDowell El Lagoon ❑Remediation: Infiltration Gallery (Cilyt (Staf ei Qq'a ❑ Spray Field ❑Remediation: Contact Person: Tim Horton Telephone#: (828) 652-8843 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Monitoring Well #1 R No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Monitoring Well #1 R Date sample collected: 11 /3/2022 FIELD ANALYSES: WAS Well Depth: 65 ft. Well Diameter: 2 in. pH 00400: 5.9 units Temp. 000lo: 23 °C DRY at Depth to Water Level 82546:28.45 ft. below measuring point Screened Interval: 55 ft. to 65 ft. Spec. Cond. 00094: µMhos time of sampling, Measuring Point is 1.5 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume of water pumped/bailed before sampling: 4.3 gallons Appearance White Particulates here: ❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ■❑ YES El NO LABORATORY INFORMATION Date sample analyzed: 1114 - 17/2022 Laboratory Name: Pace Analytical Certification No. 12 & 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.04 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 0.068 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 mg/L (Note. Use MPN method for highly turbid samples) Orthophosphate 70507 0.025 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 mg/L Al -Aluminum 01105 mg/L Boron: <50 ug/L pH (Lab) 00403 units Ba - Barium 01007 34.6 ug/L Cobalt: 0.30 ug/L Di TOC 00680 mg/L Ca - Calcium 00916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 <0.20 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L b -° Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 86.9 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ■❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # SM6200B Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3asN. Ammonia Nitrogen, Total) Mn - Manganese 01055 17.5 ug/L , method # TKN as N 00625 <0.50 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Tim Horton WWTP Superintendent Perm ittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.05-02-2017 SUBMIT FORM ON YELLOW PAPER ONLY NIT ITY - DIV, OF WATER RSV GROUNDWATER QUALITY MONITORING: : wr` fi OCEssING UNIT - COMPLIANCE REPORT FORM 617 MAIL SERVICE CENTER, RALEIGH, NC 27699.16117 Phone: 919 807 6346 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date Facility Name: Corpening Creek WWTP--City of Marion Non -Discharge WQ00003698 UIC Permit Name (if different): NPDES Other Facility Address: Marion NC 28752 TYPE OF PERMITTED OPERATION BEING MONITORED Marion I"""" NC 28752 County McDowell ❑ Lagoon El Remediation: Infiltration Gallery (C"V' ha" ❑ Spray Field ❑ Remediation: Contact Person: Tim Horton Telephone#: (828) 652-8843 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Monitoring Well #2 No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: (From Pe1-0 SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Monitoring Well #2 Date sample collected: 11/3/2022 FIELD ANALYSES: WAS Well Depth: 40 ft. Well Diameter: 2 in. pH 00400: 6.4 units Temp. 000lo. 18.5 °C DRY at Depth to Water Level 82546:19.37 ft. below measuring point Screened Interval: 30 ft. to 40 — ft. Spec. Cond. 00094: µMhos time of sampling, Measuring Point is 0.22 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: Sulfur check Volume of water pumped/bailed before sampling: 0.40 gallons Appearance Clear here: ❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 1114 - 17/2022 Laboratory Name: Pace Analytical Certification No. 12 & 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 0.045 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 <0.40 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 rrlg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 0.043 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 mg/L Al - Aluminum 01105 mg/L Boron: 41.0 ug/L pH (Lab) 00403 units Ba - Barium 01007 44.3 ug/L Cobalt: 0.80 ug/L 0.1 TOC 00680 mg/L Ca - Calcium 00915 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 <0.20 ug/L ' 4 2022� `C'ri—Cvr DEC Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 27,100 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? 0 Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # SM6200B Total Ammonia 00610 5.4 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3 as N, Ammonia Nitrogen, Total) Mn - Manganese 01055 1,250 ug/L method # TKN as N 00625 4.7 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Tim Horton WWTP Superintendent Permittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.05-02-2017 SUBMIT FORM ON YELLOW PAPER ONLY NT OF ENVIRQN • DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFO MATION'PROCESSING UNIT COMPLIANCE REPORT FORM tjjA_r p INTER, RALEIsj fd z76� -1¢17 Phone: 9187607-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date. Facility Name: Corpening Creek WWTP--City of Marion Non -Discharge W000003698 UIC NPDES Other Permit Name (if different): Facility Address: Marion NC 28752 TYPE OF PERMITTED OPERATION BEING MONITORED Marion (s`r-1) NC 28752 County McDowell ❑ Lagoon ❑ Remediation: Infiltration Gallery ($tale) (Zip) ❑ Spray Field El Remediation: Contact Person: Tim Horton Telephone#: (828) 652-8843 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Monitoring Well # 3 No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Monitoring Well #3 Date sample collected: 11/3/2022 FIELD ANALYSES: WAS Well Depth: 52 ft. Well Diameter: 2 in. pH 00400: 5.1 units Temp. 000lo. 1 7. 1 °C DRY at Depth to Water Level 82546:34.18 ft. below measuring point Screened Interval: 30 ft. to 40 ft. Spec. Cond. 00094: µMhos time of sampling, Measuring Point is 1.09 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume of water pumped/bailed before sampling: 0.37 gallons Appearance Clear here: ❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ■❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed:11/4 - 17/2022 Laboratory Name: Pace Analytical Certification No. 12 & 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NOZ) as N 00615 <0.040 mg/L Pb - Lead o1o51 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 10 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.050 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 mg/L Al -Aluminum oiim mg/L Boron: <50 ug/L pH (Lab) 00403 units Ba - Barium 01007 441 ug/L Cobalt: 2.5 ug/L TOC 00680 mg/L Ca - Calcium 00916 mg/L Dj Chloride 00940 mg/L Cd - Cadmium 01027 0.69 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 214 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ■❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # SM6200B Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3asN, Ammonia Nitrogen, Total) Mn - Manganese 01055 98.5 ug/L , method # TKN as N 00625 <0.50 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Tim Horton WWTP Superintendent Permittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.05-02-2017 SUBMIT FORM ON YELLOW PAPER ONLY RCES DIV, OF 10 GROUNDWATER QUALITY MONITORING: . — $SING UNIT `a w_ r COMPLIANCE REPORT FORM 817 MAIL SERVJCE CENTER RALEIGH, NC 27690-1617 ; Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: Facility Name: Corpening Creek WWTP--City of Marion Non -Discharge W000003698 UIC Permit Name (if different): NPDES Other Facility Address: Marion NC 28752 TYPE OF PERMITTED OPERATION BEING MONITORED Marion '"�0 NC 28752 County McDowell ❑ Lagoon ❑ Remediation: Infiltration Gallery (Cry) !3uae) i7-7pi ❑ Spray Field El Remediation: Contact Person: Tim Horton Telephone#: (828) 652-8843 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Monitoring Well #4 No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Monitoring Well #4 Date sample collected: 11/3/2022 FIELD ANALYSES: WAS Well Depth: 33 ft. Well Diameter: 2 in. pH 00400: 54.9 units Temp. 000lo: 15.9 °C DRY at Depth to Water Level 82546:21.03 ft. below measuring point Screened Interval: 18.5 ft. to 33 ft. Spec. Cond. 00094: µMhos time of sampling, Measuring Point is 0.51 ft. above land surface Relative M.P. Elevation: ft. Odor 000m None check Volume of water pumped/bailed before sampling: 0.40 gallons Appearance Clear here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: 0 YES ❑ NO LABORATORY INFORMATION Date sample analyzed:11/4-17/2022 Laboratory Name: Pace Analytical Certification No. 12 & 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00515 <0.040 mg/L Pb - Lead o1o5i ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 2.9 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P oo665 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 0.015 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 mg/L Al - Aluminum 01105 mg/L Boron: <50 ug/L pH (Lab) 00403 units Ba - Barium 01007 108 ug/L Cobalt: 2.5 ug/L r'1 TOC 00680 mg/L Ca - Calcium 00916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 0.098 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 <50.0 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? 0 Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # SM6200B Total Ammonia ooslo <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3asN; Ammonia Nitrogen, Total) Mn - Manganese 01055 86.0 ug/L method # TKN as N 00625 <0.50 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Tim Horton VV TP Superintendent Permittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.05-02-2017 'ceAnalytical ww.pocwlbs.com November 28, 2022 Mr. Tim Horton City of Marion 3982 NC Hwy 226 South Marion, NC 28752 RE: Project: Monitoring Wells November 2022 Pace Project No.: 92634703 Dear Mr. Horton: Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Enclosed are the analytical results for sample(s) received by the laboratory on November 03, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, C 7:g _ Lord Patton lorii.pafton@pacelabs.com 1(828)254-7176 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Wthout the written consent of Pace Analytical Services, LLC. Page 1 of 34 `-aceAnalytical Wn".perlob.eom Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Monitoring Wells November 2022 Pace Project No.: 92634703 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 KinceyAve. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification* E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 VrginiaA/ELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 UrginiaA/ELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 34 Pace Analytical Services, LLC 1 _ !2eAnalytical' 2225 Riverside 04 Asheville, NC 28804 www.pacolabs.com l� (828)254-7176 SAMPLE SUMMARY Project Pace Project No. Monitoring Wells November 2022 92634703 Lab ID Sample ID Matrix Date Collected Date Received 92634703001 MW-1 R Water 11 /03/22 11:50 11 /03/22 1735 92634703002 MW-2 Water 11/03/2215:00 11/03/221735 92634703003 MW-3 Water 11/03/221410 11/03/221735 92634703004 MW-4 Water 11/03/2215:45 11/03/221735 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 34 IeC, AnalytiCal WWW.WNlb.COM SAMPLE ANALYTE COUNT Project: Monitoring Wells November 2022 Pace Project No.: 92634703 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92634703001 MW-1R EPA 200.8 Rev 5.4 DBB1 6 PASI-A SM 6200B SAS 63 PASI-C EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.01993 MFO 2 PASI-A SM 4500-P E-2011 JIM 1 PASI-A 92634703002 MW-2 EPA 200.8 Rev 5.4 CRW, DBB1 6 PASI-A SM 6200B SAS 63 PASI-C EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 2 PASI-A SM 4500-P E-2011 JP1 1 PASI-A 92634703003 MW-3 EPA 200.8 Rev 5.4 CRW, D13131 6 PASI-A SM 6200B SAS 63 PASI-C EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 2 PASI-A SM 4500-P E-2011 JP1 1 PASI-A 92634703004 MW-4 EPA 200.8 Rev 5.4 DBB1 6 PASI-A SM 6200B SAS 63 PASI-C EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 2 PASI-A SM 4500-P E-2011 JP1 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 34 ` 9ceAnalyticai" wwwwwalismn ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Monitoring Wells November 2022 Pace Project No.: 92634703 Sample: MWAR Lab ID: 92634703001 Collected: 11/03/22 11:50 Received: 11/03/22 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qua[ Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 11/10/22 11:37 Collected By R. Byas 1 11/10/22 11:37 Collected Date 11/3/22 1 11/10/22 11:37 Collected Time 11:50 1 11/10/22 11:37 pH 5.9 Std. Units 1 11/10/22 11:37 Temperature 23.0 deg C 1 11/10/22 11:37 Static Water Level 28.45 feet 1 11/10/22 11:37 Specific Conductance 24.9 umhos/cm 1 11/10/22 11:37 Oxygen, Dissolved 5.6 mg/L 1 11/10/22 11:37 7782-44-7 Total Well Depth 62.62 feet 1 11/10/22 11:37 Turbidity 21.9 NTU 1 11/10/22 11:37 Odor None 1 11/10/22 11:37 Appearance White 1 11/10/22 11:37 particulat es 200.8 MET ICPMS Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4 Pace Analytical Services -Asheville Barium 34.6 ug/L 1.0 0.21 1 11/12/22 11:26 11/13/22 22:25 7440-39-3 Boron ND ug/L 50.0 8.5 1 11/12/22 11:26 11/13/22 22:25 7440-42-8 Cadmium ND ug/L 0.20 0.060 1 11/12/22 11:26 11/13/22 22:25 7440-43-9 Cobalt 0.30J ug/L 1.0 0.050 1 11/12/22 11:26 11/13/22 22:25 7440-48-4 B Iron 86.9 ug/L 50.0 20.9 1 11/12/22 11:26 11/13/22 22:25 7439-89-6 Manganese 17.5 ug/L 2.0 1.0 1 11/12/22 11:26 11/13/22 22:25 7439-96-5 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 0.34 1 11/13/22 14:07 71-43-2 Bromobenzene ND ug/L 0.50 0.29 1 11/13/22 14:07 108-86-1 Bromochloromethane ND ug/L 0.50 0.47 1 11/13/22 14:07 74-97-5 Bromodichloromethane NO ug/L 0.50 0.31 1 11/13/22 14:07 75-27-4 Bromoform ND ug/L 0.50 0.34 1 11/13/22 14:07 75-25-2 Bromomethane ND ug/L 5.0 1.7 1 11/13/22 14:07 74-83-9 n-Butylbenzene ND ug/L 0.50 0.49 1 11/13/22 14:07 104-51-8 seo-Butylbenzene ND ug/L 0.50 0.40 1 11/13/22 14:07 135-98-8 tert-Butylbenzene ND ug/L 0.50 0.32 1 11/13/22 14:07 98-06-6 Carbon tetrachloride ND ug/L 0.50 0.33 1 11/13/22 14:07 56-23-5 Chlorobenzene ND ug/L 0.50 0.28 1 11/13/22 14:07 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/13/22 14:07 75-00-3 Chloroform ND ug/L 0.50 0.43 1 11/13/22 14:07 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/13/22 14:07 74-87-3 2-Chlorotoluene ND ug/L 0.50 0.32 1 11/13/22 14:07 95-49-8 4-Chlorotoluene ND ug/L 0.50 0.32 1 11/13/22 14:07 106-43-4 1,2-Dibromo-3-chloropropane NO ug/L 1.0 0.34 1 11/13/22 14:07 96-12-8 Dibromochloromethane ND ug/L 0.50 0.36 1 11/13/22 14:07 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 34 iceAnalytical ANALYTICAL RESULTS Project: Monitoring Wells November 2022 Pace Project No.: 92634703 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW-1R Lab ID: 92634703001 Collected: 11/03/22 11:50 Received: 11/03/22 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte 1,2-Dibromoethane (EDB) ND ug/L 0.50 0.27 1 11/13/22 14:07 106-934 Dibromomethane ND ug/L 0.50 0.39 1 11/13/22 14:07 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 0.34 1 11/13/22 14:07 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 0.34 1 11/13/22 14:07 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 0.33 1 11/13/22 14:07 10646-7 Dichlorodifluoromethane ND ug/L 0.50 0.35 1 11/13/22 14:07 75-71-8 1,1-Dichloroethane ND ug/L 0.50 0.37 1 11/13/22 14:07 75-34-3 1,2-Dichloroethane ND ug/L 0.50 0.32 1 11/1312214:07 107-06-2 1,1-Dichloroethene ND ug/L 0.50 0.35 1 11/13/22 14:07 75-354 cis- 1, 2-Dich loroethene ND ug/L 0.50 0.38 1 11/13/22 14:07 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 0.40 1 11/13/22 14:07 156-60-5 1,2-Dichloropropane ND ug/L 0.50 0.36 1 11/13/22 14:07 78-87-5 1,3-Dichloropropane ND ug/L 0.50 0.28 1 11/13/22 14:07 142-28-9 2,2-Dichloropropane ND ug/L 0.50 0.39 1 11/13/22 14:07 594-20-7 1,1-Dichloropropene ND ug/L 0.50 0.43 1 11/13/22 14:07 563-58-6 cis- 1, 3-Dich lo rop ropene ND ug/L 0.50 0.36 1 11/13/22 14:07 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 0.36 1 11/13/22 14:07 10061-02-6 Diisopropyl ether ND ug/L 0.50 0.31 1 11/13/22 14:07 108-20-3 Ethylbenzene ND ug/L 0.50 0.30 1 11/13/22 14:07 100-41-4 Flexachloro-1,3-butadiene ND ug/L 2.0 1.5 1 11/13/22 14:07 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 0.33 1 11/13/22 14:07 98-82-8 Methylene Chloride ND ug/L 2.0 2.0 1 11/13/22 14:07 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 0.42 1 11/13/22 14:07 1634-044 Naphthalene ND ug/L 2.0 0.64 1 11/13/22 14:07 91-20-3 n-Propylbenzene ND ug/L 0.50 0.34 1 11/13/22 14:07 103-65-1 Styrene ND ug/L 0.50 0.29 1 11/13/22 14:07 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 0.31 1 11/13/22 14:07 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 0.22 1 11/13/22 14:07 79-34-5 Tetrachloroethene ND ug/L 0.50 0.29 1 11/13/22 14:07 127-18-4 Toluene ND ug/L 0.50 0.24 1 11/13/22 14:07 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 0.81 1 11/13/22 14:07 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 0.64 1 11/13/22 14:07 120-82-1 1, 1, 1 -Trichloroethane ND ug/L 0.50 0.33 1 11/13/22 14:07 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 0.32 1 11/13/22 14:07 79-00-5 Trichloroethene ND ug/L 0.50 0.38 1 11/13/22 14:07 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 11/13/22 14:07 75-694 1,2,3-Trichloropropane ND ug/L 0.50 0.26 1 11/13/22 14:07 96-184 1,2,4-Trimethylbenzene ND ug/L 0.50 0.50 1 11/13/22 14:07 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 0.33 1 11/13/22 14:07 108-67-8 Vinyl chloride ND ug/L 1.0 0.39 1 11/13/22 14:07 75-014 m&p-Xylene ND ug/L 1.0 0.71 1 11/13/22 14:07 179601-23-1 o-Xylene ND ug/L 0.50 0.34 1 11/13/22 14:07 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 103 % 70-130 1 11/13/22 14:07 17060-07-0 4-Bromofluorobenzene (S) 100 % 70-130 1 11/13/22 14:07 460-004 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 34 aceAnalytical e ANALYTICAL RESULTS Project: Monitoring Wells November 2022 Pace Project No.: 92634703 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MWAR Lab ID: 92634703001 Collected: 11/03/22 11:50 Received: 11/03/22 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Surrogates Toluene-d8 (S) 102 % 70-130 1 11/13/22 14:07 2037-26-5 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 0.031 1 11/11/22 14:07 7664-41-7 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Kjeldahl, Total ND mg/L 0.50 0.25 1 11/16/22 19:28 11/17/22 05:56 7727-37-9 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 0.068 mg/L 0.040 0.010 1 11/04/22 03:08 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 0.031 1 11/04/22 03:08 14797-65-0 SM4500P-E, Phosphate, Ortho Analytical Method: SM 4500-P E-2011 Pace Analytical Services -Asheville Orthophosphate as P 0.025J mg/L 0.050 0.012 1 11/04/22 04:38 Date: 11/28/2022 12:26 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 34 JCeAnaiytical www pacWlq.eem ANALYTICAL RESULTS Project: Monitoring Wells November 2022 Pace Project No.: 92634703 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW-2 Lab ID: 92634703002 Collected: 11/03/22 15:00 Received: 11/03/22 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 11/10/22 11:39 Collected By R. Byas 1 11/10/22 11:39 Collected Date 11/3/22 1 11/10/22 11:39 Collected Time 15:00 1 11/10/22 11:39 pH 6.4 Std. Units 1 11/10/22 11:39 Temperature 18.5 deg C 1 11/10/22 11:39 Static Water Level 19.37 feet 1 11/10/22 11:39 Specific Conductance 289.3 umhos/cm 1 11/10/22 11:39 Oxygen, Dissolved 0.6 mg/L 1 11/10/22 11:39 7782-44-7 Total Well Depth 38.02 feet 1 11/10/22 11:39 Turbidity 3.9 NTU 1 11/10/22 11:39 Odor Sulfur 1 11/10/22 11:39 Appearance Clear 1 11/10/22 11:39 200.8 MET ICPMS Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4 Pace Analytical Services -Asheville Barium 44.3 ug/L 1.0 0.21 1 11/12/22 11:26 11/13/22 22:29 7440-39-3 Boron 41.OJ ug/L 50.0 8.5 1 11/12/22 11:26 11/13/22 22:29 7440-42-8 Cadmium ND ug/L 0.20 0.060 1 11/12/22 11:26 11/13/22 22:29 7440-43-9 Cobalt 0.801 ug/L 1.0 0.050 1 11/12/22 11:26 11/13/22 22:29 7440-48-4 Iron 27100 ug/L 1000 419 20 11/12/22 11:26 11/14/2217:28 7439-89-6 Manganese 1250 ug/L 40.0 20.4 20 11/12/22 11:26 11/14/2217:28 7439-96-5 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 0.34 1 11/13/22 14:25 71-43-2 Bromobenzene ND ug/L 0.50 0.29 1 11/13/22 14:25 108-86-1 Bromochloromethane ND ug/L 0.50 0.47 1 11/13/22 14:25 74-97-5 Bromodichloromethane ND ug/L 0.50 0.31 1 11/13/22 14:25 75-27-4 Bromoform ND ug/L 0.50 0.34 1 11/13/22 14:25 75-25-2 Bromomethane ND ug/L 5.0 1.7 1 11/13/22 14:25 74-83-9 n-Butylbenzene ND ug/L 0.50 0.49 1 11/13/22 14:25 104-51-8 seo-Butylbenzene ND ug/L 0.50 0.40 1 11/13/22 14:25 135-98-8 tert-Butylbenzene ND ug/L 0.50 0.32 1 11/13/22 14:25 98-06-6 Carbon tetrachloride ND ug/L 0.50 0.33 1 11/13/22 14:25 56-23-5 Chlorobenzene ND ug/L 0.50 0.28 1 11/13/22 14:25 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/13/22 14:25 75-00-3 Chloroform ND ug/L 0.50 0.43 1 11/13/22 14:25 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/13/22 14:25 74-87-3 2-Chlorotoluene ND ug/L 0.50 0.32 1 11/13/22 14:25 95-49-8 4-Chlorotoluene ND ug/L 0.50 0.32 1 11/13/22 14:25 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 0.34 1 11/13/22 14:25 96-12-8 Dibromochloromethane ND ug/L 0.50 0.36 1 11/13/22 14:25 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 0.27 1 11/13/22 14:25 106-93-4 Dibromomethane ND ug/L 0.50 0.39 1 11/13/22 14:25 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 34 aceMalytical www.pacelabs.com Project: Pace Project No.: Sample: MW-2 6200E MSV Monitoring Wells November 2022 92634703 Parameters 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dich lorod ifl uoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1, 3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1, 3-Dichloropropene trans-1,3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trich lorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1, 3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Lab ID: 92634703002 Collected: 11/03/22 15:00 Received: 11/03/22 17:35 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Analytical Method: SM 6200B Pace Analytical Services - Charlotte ND ug/L 0.50 0.34 1 11/13/2214:25 95-50-1 ND ug/L 0.50 0.34 1 11/13/2214:25 541-73-1 ND ug/L 0.50 0.33 1 11/13/2214:25 106-46-7 ND ug/L 0.50 0.35 1 11 /13/22 14:25 75-71-8 ND ug/L 0.50 0.37 1 11/13/2214:25 75-34-3 ND ug/L 0.50 0.32 1 11/13/2214:25 107-06-2 ND ug/L 0.50 0.35 1 11/13/2214:25 75-35-4 ND ug/L 0.50 0.38 1 11/13/2214:25 156-59-2 ND ug/L 0.50 0.40 1 11/13/2214:25 156-60-5 ND ug/L 0.50 0.36 1 11 /13/22 14:25 78-87-5 ND ug/L 0.50 0.28 1 11/13/2214:25 142-28-9 ND ug/L 0.50 0.39 1 11/13/2214:25 594-20-7 ND ug/L 0.50 0.43 1 11/13/2214:25 563-58-6 ND ug/L 0.50 0.36 1 11/13/2214:25 10061-01-5 ND ug/L 0.50 0.36 1 11/13/2214:25 10061-02-6 ND ug/L 0.50 0.31 1 11/13/2214:25 108-20-3 ND ug/L 0.50 0.30 1 11/13/2214:25 100-41-4 ND ug/L 2.0 1.5 1 11/13/2214:25 87-68-3 ND ug/L 0.50 0.33 1 11/13/2214:25 98-82-8 ND ug/L 2.0 2.0 1 11/13/2214:25 75-09-2 ND ug/L 0.50 0.42 1 11/13/2214:25 1634-04-4 ND ug/L 2.0 0.64 1 11/13/2214:25 91-20-3 ND ug/L 0.50 0.34 1 11/13/2214:25 103-65-1 ND ug/L 0.50 0.29 1 11/13/2214:25 100-42-5 ND ug/L 0.50 0.31 1 11 /13/22 14:25 630-20-6 ND ug/L 0.50 0.22 1 11 /13/22 14:25 79-34-5 ND ug/L 0.50 0.29 1 11/13/2214:25 127-18-4 ND ug/L 0.50 0.24 1 11/13/2214:25 108-88-3 ND ug/L 2.0 0.81 1 11/13/2214:25 87-61-6 ND ug/L 2.0 0.64 1 11/13/2214:25 120-82-1 ND ug/L 0.50 0.33 1 11/13/2214:25 71-55-6 ND ug/L 0.50 0.32 1 11/13/2214:25 79-00-5 ND ug/L 0.50 0.38 1 11/13/2214:25 79-01-6 ND ug/L 1.0 0.30 1 11/13/2214:25 75-69-4 ND ug/L 0.50 0.26 1 11/13/2214:25 96-18-4 ND ug/L 0.50 0.50 1 11/13/2214:25 95-63-6 ND ug/L 0.50 0.33 1 11/13/2214:25 108-67-8 ND ug/L 1.0 0.39 1 11/13/2214:25 75-01-4 ND ug/L 1.0 0.71 1 11/13/2214:25 179601-23-1 ND ug/L 0.50 0.34 1 11 /13/22 14:25 95-47-6 106 % 70-130 1 11 /13/22 14:25 17060-07-0 100 % 70-130 1 11 /13/22 14:25 460-00-4 102 % 70-130 1 11/13/2214:25 2037-26-5 REPORT OF LABORATORY ANALYSIS Qual This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 34 Pace Analytical Services, LLC eAnal}rtical ® 2225 Riverside Dr. Asheville, NC 28804 ac www.psewabsx0m (828)254-7176 ANALYTICAL RESULTS Project: Monitoring Wells November 2022 Pace Project No.: 92634703 Sample: MW-2 Lab ID: 92634703002 Collected: 11/03/22 15:00 Received: 11/03/22 17:35 Matrix: Water Parameters 350.1 Ammonia Nitrogen, Ammonia 351.2 Total Kjeldahl Nitrogen Nitrogen, Neldahl, Total 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Nitrogen, Nitrite SM4500P-E, Phosphate, Ortho Orthophosphate as P Date: 11 /28/2022 12:26 PM Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville 5.4 mg/L 0.10 0.031 1 11/11/2214:08 7664-41-7 Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville 4.7 mg/L 0.50 0.25 1 11/16/22 19:28 11/17/22 05:58 7727-37-9 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.040 0.010 1 11 /04/22 03:16 14797-55-8 0.045 mg/L 0.040 0.031 1 11 /04/22 03:16 14797-65-0 Analytical Method: SM 4500-P E-2011 Pace Analytical Services - Asheville 0.043J mg/L 0.050 0.012 1 11 /04/22 04:39 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 34 JceAnalytical www.pscwabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Monitoring Wells November 2022 Pace Project No.: 92634703 Sample: MW-3 Lab ID: 92634703003 Collected: 11/03/22 14:10 Received: 11/03/22 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 11/10/22 11:41 Collected By R. Byas 1 11/10/22 11:41 Collected Date 11/3/22 1 11/10/22 11:41 Collected Time 14:10 1 11/10/22 11:41 pH 5.1 Std. Units 1 11/10/22 11:41 Temperature 17.1 deg C 1 11/10/22 11:41 Static Water Level 34.18 feet 1 11/10/22 11:41 Specific Conductance 141.8 umhos/cm 1 11/10/22 11:41 Oxygen, Dissolved 3.6 mg/L 1 11/10/22 11:41 7782-44-7 Total Well Depth 50.02 feet 1 11/10/22 11:41 Turbidity 9.8 NTU 1 11/10/22 11:41 Odor None 1 11/10/22 11:41 Appearance Clear 1 11/10/22 11:41 200.8 MET ICPMS Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4 Pace Analytical Services -Asheville Barium 441 ug/L 10.0 2.1 10 11/12/22 11:26 11/14/2217:32 7440-39-3 Boron ND ug/L 50.0 8.5 1 11/12/22 11:26 11/13/22 22:32 7440-42-8 Cadmium 0.69 ug/L 0.20 0.060 1 11/12/22 11:26 11/13/22 22:32 7440-43-9 Cobalt 2.5 ug/L 1.0 0.050 1 11/12/22 11:26 11/13/22 22:32 7440-48-4 Iron 214 ug/L 50.0 20.9 1 11/12/22 11:26 11/13/22 22:32 7439-89-6 Manganese 98.5 ug/L 2.0 1.0 1 11/12/22 11:26 11/13/22 22:32 7439-96-5 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 0.34 1 11/13/22 14:43 71-43-2 Bromobenzene ND ug/L 0.50 0.29 1 11/13/22 14:43 108-86-1 Bromochloromethane ND ug/L 0.50 0.47 1 11/13/22 14:43 74-97-5 Bromodichloromethane ND ug/L 0.50 0.31 1 11/13/22 14:43 75-27-4 Bromoform ND ug/L 0.50 0.34 1 11/13/22 14:43 75-25-2 Bromomethane ND ug/L 5.0 1.7 1 11/13/22 14:43 74-83-9 n-Butylbenzene ND ug/L 0.50 0.49 1 11/13/22 14:43 104-51-8 sec-Butylbenzene ND ug/L 0.50 0.40 1 11/1312214:43 135-98-8 tert-Butylbenzene ND ug/L 0.50 0.32 1 11/13/22 14:43 98-06-6 Carbon tetrachloride ND ug/L 0.50 0.33 1 11/13/22 14:43 56-23-5 Chlorobenzene ND ug/L 0.50 0.28 1 11/13/22 14:43 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/13/22 14:43 75-00-3 Chloroform ND ug/L 0.50 0.43 1 11/13/22 14:43 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/13/22 14:43 74-87-3 2-Chlorotoluene ND ug/L 0.50 0.32 1 11/13/22 14:43 95-49-8 4-Chlorotoluene ND ug/L 0.50 0.32 1 11/13/22 14:43 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 0.34 1 11/13/22 14:43 96-12-8 Dibromochloromethane ND ug/L 0.50 0.36 1 11/13/22 14:43 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 0.27 1 11/13/22 14:43 106-93-4 Dibromomethane ND ug/L 0.50 0.39 1 11/13/22 14:43 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 34 aceAnalyfical www.pacoiaks.com ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Monitoring Wells November 2022 Pace Project No.: 92634703 Sample: MW-3 Lab ID: 92634703003 Collected: 11/03/22 14:10 Received: 11/03/22 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte 1,2-Dichlorobenzene ND ug/L 0.50 0.34 1 11/13/22 14:43 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 0.34 1 11/13/22 14:43 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 0.33 1 11/13/22 14:43 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 0.35 1 11/13/22 14:43 75-71-8 1,1-Dichloroethane ND ug/L 0.50 0.37 1 11/13/22 14:43 75-34-3 1,2-Dichloroethane ND ug/L 0.50 0.32 1 11/13/22 14:43 107-06-2 1,1-Dichloroethene ND ug/L 0.50 0.35 1 11/13/22 14:43 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 0.38 1 11/13/22 14:43 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 0.40 1 11/13/22 14:43 156-60-5 1,2-Dichloropropane ND ug/L 0.50 0.36 1 11/13/22 14:43 78-87-5 1,3-Dichloropropane ND ug/L 0.50 0.28 1 11/13/22 14:43 142-28-9 2,2-Dichloropropane ND ug/L 0.50 0.39 1 11/13/22 14:43 594-20-7 1,1-Dichloropropene ND ug/L 0.50 0.43 1 11/13/22 14:43 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 0.36 1 11/13/22 14:43 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 0.36 1 11/13/22 14:43 10061-02-6 Diisopropyl ether ND ug/L 0.50 0.31 1 11/13/22 14:43 108-20-3 Ethylbenzene ND ug/L 0.50 0.30 1 11/13/22 14:43 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1.5 1 11/13/22 14:43 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 0.33 1 11/13/22 14:43 98-82-8 Methylene Chloride ND ug/L 2.0 2.0 1 11/13/22 14:43 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 0.42 1 11/13/22 14:43 1634-04-4 Naphthalene ND ug/L 2.0 0.64 1 11/13/22 14:43 91-20-3 n-Propylbenzene ND ug/L 0.50 0.34 1 11/13/22 14:43 103-65-1 Styrene ND ug/L 0.50 0.29 1 11/13/22 14:43 100-42-5 1, 1, 1,2-Tetrachloroethane ND ug/L 0.50 0.31 1 11/13/22 14:43 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 0.22 1 11/13/22 14:43 79-34-5 Tetrachloroethene ND ug/L 0.50 0.29 1 11/13/22 14:43 127-18-4 Toluene ND ug/L 0.50 0.24 1 11/13/22 14:43 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 0.81 1 11/13/22 14:43 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 0.64 1 11/13/22 14:43 120-82-1 1, 1, 1 -Trich loroetha ne ND ug/L 0.50 0.33 1 11/13/22 14:43 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 0.32 1 11/13/22 14:43 79-00-5 Trichloroethene ND ug/L 0.50 0.38 1 11/13/22 14:43 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 11/13/22 14:43 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 0.26 1 11/13/22 14:43 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 0.50 1 11/13/22 14:43 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 0.33 1 11/13/22 14:43 108-67-8 Vinyl chloride ND ug/L 1.0 0.39 1 11/13/22 14:43 75-01-4 rrAp-Xylene ND ug/L 1.0 0.71 1 11/13/22 14:43 179601-23-1 o-Xylene ND ug/L 0.50 0.34 1 11/13/22 14:43 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 104 % 70-130 1 11/13/22 14:43 17060-07-0 4-Bromofluorobenzene (S) 99 % 70-130 1 11/13/22 14:43 460-00-4 Toluene-d8 (S) 103 % 70-130 1 11/13/22 14:43 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 34 Pace Analytical Services, LLC JcemalXical ® 2225 Riverside Asheville, NC 28804 www.pscslakm.com (828)254-7176 ANALYTICAL RESULTS Project: Monitoring Wells November 2022 Pace Project No.: 92634703 Sample: MW-3 Lab ID: 92634703003 Collected: 11/03/22 14:10 Received: 11/03/22 17:35 Matrix: Water Parameters 350.1 Ammonia Nitrogen, Ammonia 351.2 Total Kjeldahl Nitrogen Nitrogen, Neldahl, Total 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Nitrogen, Nitrite SM4500P-E, Phosphate, Ortho Orthophosphate as P Date: 11 /28/2022 12:26 PM Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.10 0.031 1 11/11/2214:10 7664-41-7 Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.50 0.25 1 11 /16/22 19:28 11 /17/22 06:00 7727-37-9 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville 10.0 mg/L 0.20 0.050 5 11/04/22 03:38 14797-55-8 ND mg/L 0.040 0.031 1 11/04/22 03:13 14797-65-0 Analytical Method: SM 4500-P E-2011 Pace Analytical Services -Asheville ND mg/L 0.050 0.012 1 11/04/22 04:38 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 34 t �` ceAnal}rfical wrrtr.Pscelabs.ewl ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Monitoring Wells November 2022 Pace Project No.: 92634703 Sample: MW-4 Lab ID: 92634703004 Collected: 11/03/22 15:45 Received: 11/03/22 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 11/10/22 11:42 Collected By R. Byas 1 11/10/22 11:42 Collected Date 1113/22 1 11/10/22 11:42 Collected Time 16:45 1 11/10/22 11:42 pH 4.9 Std. Units 1 11/10/22 11:42 Temperature 15.9 deg C 1 11/10/22 11:42 Static Water Level 21.03 feet 1 11/10/22 11:42 Specific Conductance 60.1 umhos/cm 1 11/10/22 11:42 Oxygen, Dissolved 0.7 mg/L 1 11/10/22 11:42 7782-44-7 Total Well Depth 35.37 feet 1 11/10/22 11:42 Turbidity 0.8 NTU 1 11/10/22 11:42 Odor None 1 11/10/22 11:42 Appearance Clear 1 11/10/22 11:42 200.8 MET ICPMS Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4 Pace Analytical Services - Asheville Barium 108 ug/L 1.0 0.21 1 11/12/22 11:26 11/13/22 22:36 7440-39-3 Boron ND ug/L 50.0 8.5 1 11/12/22 11:26 11/13/22 22:36 7440-42-8 Cadmium 0.098J ug/L 0.20 0.060 1 11/12/22 11:26 11/13/22 22:36 7440-43-9 Cobalt 2.5 ug/L 1.0 0.050 1 11/12/22 11:26 11/13/22 22:36 7440-48-4 Iron ND ug/L 50.0 20.9 1 11/12/22 11:26 11/13/22 22:36 7439-89-6 Manganese 86.0 ug/L 2.0 1.0 1 11/12/22 11:26 11/13/22 22:36 7439-96-5 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 0.34 1 11/13/22 15:01 71-43-2 Bromobenzene ND ug/L 0.50 0.29 1 11/13/22 15:01 108-86-1 Bromochloromethane ND ug/L 0.50 0.47 1 11/13/22 15:01 74-97-5 Bromodichloromethane ND ug/L 0.50 0.31 1 11/13/22 15:01 75-27-4 Bromoform ND ug/L 0.50 0.34 1 11/13/22 15:01 75-25-2 Bromomethane ND ug/L 5.0 1.7 1 11/13/22 15:01 74-83-9 n-Butylbenzene ND ug/L 0.50 0.49 1 11/13/22 15:01 104-51-8 sec-Butylbenzene ND ug/L 0.50 0.40 1 11/13/22 15:01 135-98-8 tert-Butylbenzene ND ug/L 0.50 0.32 1 11/13/22 15:01 98-06-6 Carbon tetrachloride ND ug/L 0.50 0.33 1 11/13/22 15:01 56-23-5 Chlorobenzene ND ug/L 0.50 0.28 1 11/13/22 15:01 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/13/22 15:01 75-00-3 Chloroform ND ug/L 0.50 0.43 1 11/13/22 15:01 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/13/22 15:01 74-87-3 2-Chlorotoluene ND ug/L 0.50 0.32 1 11/13/22 15:01 95-49-8 4-Chlorotoluene ND ug/L 0.50 0.32 1 11/13/22 15:01 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 0.34 1 11/1312215:01 96-12-8 Dibromochloromethane ND ug/L 0.50 0.36 1 11/13/22 15:01 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 0.27 1 11/13/22 15:01 106-93-4 Dibromomethane ND ug/L 0.50 0.39 1 11/13/22 15:01 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 34 �acMnalytical www.pacolabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Monitoring Wells November 2022 Pace Project No.: 92634703 Sample: MW-4 Lab ID: 92634703004 Collected: 11/03/22 15:45 Received: 11/03/22 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte 1,2-Dichlorobenzene ND ug/L 0.50 0.34 1 11/13/22 15:01 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 0.34 1 11/13/22 15:01 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 0.33 1 11/13/22 15:01 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 0.35 1 11/13/22 15:01 75-71-8 1,1-Dichloroethane ND ug/L 0.50 0.37 1 11/13/22 15:01 75-34-3 1,2-Dichloroethane ND ug/L 0.50 0.32 1 11/13/22 15:01 107-06-2 1,1-Dichloroethene ND ug/L 0.50 0.35 1 11/13/22 15:01 75-35-4 cis- 1, 2-Dich loroethene ND ug/L 0.50 0.38 1 11/13/22 15:01 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 0.40 1 11/13/22 15:01 156-60-5 1,2-Dichloropropane ND ug/L 0.50 0.36 1 11/13/22 15:01 78-87-5 1,3-Dichloropropane ND ug/L 0.50 0.28 1 11/13/22 15:01 142-28-9 2,2-Dichloropropane ND ug/L 0.50 0.39 1 11/13/22 15:01 594-20-7 1,1-Dichloropropene ND ug/L 0.50 0.43 1 11/13/22 15:01 563-58-6 cis- 1, 3-Dich loropropene ND ug/L 0.50 0.36 1 11/13/22 15:01 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 0.36 1 11/13/22 15:01 10061-02-6 Diisopropyl ether ND ug/L 0.50 0.31 1 11/13/22 15:01 108-20-3 Ethylbenzene ND ug/L 0.50 0.30 1 11/13/22 15:01 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1.5 1 11/13/22 15:01 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 0.33 1 11/13/22 15:01 98-82-8 Methylene Chloride ND ug/L 2.0 2.0 1 11/13/22 15:01 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 0.42 1 11/13/22 15:01 1634-04-4 Naphthalene ND ug/L 2.0 0.64 1 11/13/22 15:01 91-20-3 n-Propylbenzene ND ug/L 0.50 0.34 1 11/13/22 15:01 103-65-1 Styrene ND ug/L 0.50 0.29 1 11/13/22 15:01 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 0.31 1 11/13/22 15:01 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 0.22 1 11/13/22 15:01 79-34-5 Tetrachloroethene ND ug/L 0.50 0.29 1 11/13/22 15:01 127-18-4 Toluene ND ug/L 0.50 0.24 1 11/13/22 15:01 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 0.81 1 11/13/22 15:01 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 0.64 1 11/13/22 15:01 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 0.33 1 11/13/22 15:01 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 0.32 1 11/13/22 15:01 79-00-5 Trichloroethene ND ug/L 0.50 0.38 1 11/13/22 15:01 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 11/13/22 15:01 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 0.26 1 11/13/22 15:01 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 0.50 1 11/13/22 15:01 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 0.33 1 11/13/22 15:01 108-67-8 Vinyl chloride ND ug/L 1.0 0.39 1 11/13/22 15:01 75-01-4 m&p-Xylene ND ug/L 1.0 0.71 1 11/13/22 15:01 179601-23-1 o-Xylene ND ug/L 0.50 0.34 1 11/13/22 15:01 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 11/13/22 15:01 17060-07-0 4-Bromofluorobenzene (S) 101 % 70-130 1 11/13/22 15:01 460-00-4 Toluene-d8 (S) 103 % 70-130 1 11/13/22 15:01 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 34 Pace Analytical Services, LLC ' aceAnaiytical 2225 Riverside Dr. Asheville, NC 28804 www.wslabs.com (828)254-7176 ANALYTICAL RESULTS Project: Monitoring Wells November 2022 Pace Project No.: 92634703 Sample: MW-4 Lab ID: 92634703004 Collected: 11/03/22 15:45 Received: 11/03/22 17:35 Matrix: Water Parameters 350.1 Ammonia Nitrogen, Ammonia 351.2 Total Kjeldahl Nitrogen Nitrogen, Neldahl, Total 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Nitrogen, Nitrite SM4500P-E, Phosphate, Ortho Orthophosphate as P Date: 11 /28/2022 12:26 PM Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville ND mg/L 0.10 0.031 1 11/11/2214:14 7664-41-7 Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.50 0.25 1 11/16/22 19:28 11/17/22 06:01 7727-37-9 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville 2.9 mg/L 0.040 0.010 1 11/04/22 03:17 14797-55-8 ND mg/L 0.040 0.031 1 11/04/22 03:17 14797-65-0 Analytical Method: SM 4500-P E-2011 Pace Analytical Services -Asheville 0.015J mg/L 0.050 0.012 1 11/04/22 04:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 34 aceAnalyNo WWW.PICW@b$.COM QUALITY CONTROL DATA Project: Monitoring Wells November 2022 Pace Project No.: 92634703 QC Batch: 736695 Analysis Method: EPA 200.8 Rev 5.4 QC Batch Method: EPA 200.8 Rev 5.4 Analysis Description: 200.8 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92634703001, 92634703002, 92634703003, 92634703004 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 METHOD BLANK: 3834138 Matra: Water Associated Lab Samples: 92634703001, 92634703002, 92634703003, 92634703004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Barium ug/L ND 1.0 0.21 11/13/22 22:18 Boron ug/L ND 50.0 8.5 11/13/22 22:18 Cadmium ug/L ND 0.20 0.060 11/13/22 22:18 Cobalt ug/L 0.12J 1.0 0.050 11/13/22 22:18 Iron ug/L ND 50.0 20.9 11/13/22 22:18 Manganese ug/L ND 2.0 1.0 11/13/22 22:18 LABORATORY CONTROL SAMPLE: 3834139 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Barium ug/L 50 48.8 98 85-115 Boron ug/L 50 48.1J 96 85-115 Cadmium ug/L 50 50.2 100 85-115 Cobalt ug/L 50 50.9 102 85-115 Iron ug/L 1250 1280 102 85-115 Manganese ug/L 50 50.3 101 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3834140 3834141 MS MSD 92634594005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Barium ug/L ND 50 50 47.8 48.8 96 98 70-130 2 20 Boron ug/L ND 50 50 52.5 54.0 97 100 70-130 3 20 CH Cadmium ug/L ND 50 50 49.3 49.9 99 100 70-130 1 20 Cobalt ug/L ND 50 50 49.7 50.2 99 100 70-130 1 20 Iron ug/L ND 1250 1250 1260 1270 99 101 70-130 1 20 Manganese ug/L ND 50 50 49.1 50.1 98 100 70-130 2 20 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3834142 3834143 MS MSD 92634682001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Barium ug/L 13.1 50 50 63.3 62.7 100 99 70-130 1 20 Boron ug/L 378 50 50 431 410 107 65 70-130 5 20 CH,E, M1 Cadmium ug/L ND 50 50 43.4 42.9 87 86 70-130 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 34 i airieA alyt cal rrrw.wcN>tYs.eam QUALITY CONTROL DATA Project: Monitoring Wells November 2022 Pace Project No.: 92634703 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3834142 MS 92634682001 Spike Parameter Units Result Conc. Cobalt ug/L ND 50 Iron ug/L 545 1250 Manganese ug/L 10 50 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 3834143 MSD Spike MS MSD MS MSD % Rec Max Conc. Result Result % Rec % Rec Limits RPD RPD Qual 50 47.7 47.2 95 94 70-130 1 20 1250 1740 1720 96 94 70-130 1 20 50 59.5 58.4 99 97 70-130 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 34 t acmnalytical www.pcdabs.eom QUALITY CONTROL DATA Project: Monitoring Wells November 2022 Pace Project No.: 92634703 QC Batch: 736729 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 6200E MSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92634703001, 92634703002, 92634703003, 92634703004 METHOD BLANK: 3834279 Matrix: Water Associated Lab Samples: 92634703001, 92634703002, 92634703003, 92634703004 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 0.50 0.31 11/13/22 09:19 1,1,1-Trichloroethane ug/L ND 0.50 0.33 11/13/22 09:19 1,1,2,2-Tetrachloroethane ug/L ND 0.50 0.22 11/13/22 09:19 1,1,2-Trichloroethane ug/L ND 0.50 0.32 11/13/22 09:19 1,1-Dichloroethane ug/L ND 0.50 0.37 11/13/22 09:19 1,1-Dichloroethene ug/L ND 0.50 0.35 11/13/22 09:19 1,1-Dichloropropene ug/L ND 0.50 0.43 11/13/22 09:19 1,2,3-Trichlorobenzene ug/L ND 2.0 0.81 11/13/22 09:19 1,2,3-Trichloropropane ug/L ND 0.50 0.26 11/13/22 09:19 1,2,4-Trichlorobenzene ug/L ND 2.0 0.64 11/13/22 09:19 1,2,4-Trimethylbenzene ug/L ND 0.50 0.50 11/13/22 09:19 1,2-Dibromo-3-chloropropane ug/L ND 1.0 0.34 11/13/22 09:19 1,2-Dibromoethane (EDB) ug/L ND 0.50 0.27 11/13/22 09:19 1,2-Dichlorobenzene ug/L ND 0.50 0.34 11/13/22 09:19 1,2-Dichloroethane ug/L ND 0.50 0.32 11/13/22 09:19 1,2-Dichloropropane ug/L ND 0.50 0.36 11/13/22 09:19 1,3,5-Trin-ethylbenzene ug/L ND 0.50 0.33 11/13/22 09:19 1,3-Dichlorobenzene ug/L ND 0.50 0.34 11/13/22 09:19 1,3-Dichloropropane ug/L ND 0.50 0.28 11/13/22 09:19 1,4-Dichlorobenzene ug/L ND 0.50 0.33 11/13/22 09:19 2,2-Dichloropropane ug/L ND 0.50 0.39 11/13/22 09:19 2-Chlorotoluene ug/L ND 0.50 0.32 11/13/22 09:19 4-Chlorotoluene ug/L ND 0.50 0.32 11/13/22 09:19 Benzene ug/L ND 0.50 0.34 11/13/22 09:19 Bromobenzene ug/L ND 0.50 0.29 11/13/22 09:19 Bromochloromethane ug/L ND 0.50 0.47 11/13/22 09:19 Bromodichloromethane ug/L ND 0.50 0.31 11/13/22 09:19 Bromoform ug/L ND 0.50 0.34 11/13/22 09:19 Bromomethane ug/L ND 5.0 1.7 11/13/22 09:19 Carbon tetrachloride ug/L ND 0.50 0.33 11/13/22 09:19 Chlorobenzene ug/L ND 0.50 0.28 11/13/22 09:19 Chloroethane ug/L ND 1.0 0.65 11/13/22 09:19 Chloroform ug/L ND 0.50 0.43 11/13/22 09:19 Chloromethane ug/L ND 1.0 0,54 11/13/22 09:19 cis- 1,2-Dichloroethene ug/L ND 0.50 0.38 11/13/22 09:19 cis- 1, 3-Dich loropropene ug/L ND 0.50 0.36 11/13/22 09:19 Dibromochloromethane ug/L ND 0.50 0.36 11/13/22 09:19 Dibromomethane ug/L ND 0.50 0.39 11/13/22 09:19 Dichlorodifluoromethane ug/L ND 0.50 0.35 11/13/22 09:19 Diisopropyl ether ug/L ND 0.50 0.31 11/13/22 09:19 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 34 ceAnalytical WWW.OscWabs.com QUALITY CONTROL DATA Project: Monitoring Wells November 2022 Pace Project No.: 92634703 METHOD BLANK: 3834279 Matrix: Water Associated Lab Samples: 92634703001, 92634703002, 92634703003, 92634703004 Blank Reporting Parameter Units Result Limit MDL Analyzed Ethylbenzene ug/L ND 0.50 0.30 11/13/22 09:19 Hexachloro-1,3-butadiene ug/L ND 2.0 1.5 11/13/22 09:19 Isopropylbenzene (Cumene) ug/L ND 0.50 0.33 11/13/22 09:19 m&p-Xylene ug/L ND 1.0 0.71 11/13/22 09:19 Methyl-tert-butyl ether ug/L ND 0.50 0.42 11/13/22 09:19 Methylene Chloride ug/L ND 2.0 2.0 11/13/22 09:19 n-Butylbenzene ug/L ND 0.50 0.49 11/13/22 09:19 n-Propylbenzene ug/L ND 0.50 0.34 11/13/22 09:19 Naphthalene ug/L ND 2.0 0.64 11/13/22 09:19 o-Xylene ug/L ND 0.50 0.34 11/13/22 09:19 seo-Butylbenzene ug/L ND 0.50 0.40 11/13/22 09:19 Styrene ug/L ND 0.50 0.29 11/13/22 09:19 tert-Butylbenzene ug/L ND 0.50 0.32 11/13/22 09:19 Tetrachloroethene ug/L ND 0.50 0.29 11/13/22 09:19 Toluene ug/L ND 0.50 0.24 11/13/22 09:19 trans-1,2-Dichloroethene ug/L ND 0.50 0.40 11/13/22 09:19 trans-1,3-Dichloropropene ug/L ND 0.50 0.36 11/13/22 09:19 Trichloroethene ug/L ND 0.50 0.38 11/13/22 09:19 Trichlorofluoromethane ug/L ND 1.0 0.30 11/13/22 09:19 Vinyl chloride ug/L ND 1.0 0.39 11/13/22 09:19 1,2-Dichloroethane-d4 (S) % 102 70-130 11/13/22 09:19 4-Bromofluorobenzene (S) % 103 70-130 11/13/22 09:19 Toluene-d8 (S) % 102 70-130 11/13/22 09:19 LABORATORY CONTROL SAMPLE: Parameter 3834280 Units Spike Conc. LCS Result LCS %Rec % Rec Limits 1, 1, 1,2-Tetrachloroethane ug/L 50 53.2 106 60-140 1, 1, 1 -Trichloroethane ug/L 50 53.9 108 60-140 1,1,2,2-Tetrachloroethane ug/L 50 51.8 104 60-140 1,1,2-Trichloroethane ug/L 50 50.5 101 60-140 1,1-Dichloroethane ug/L 50 50.2 100 60-140 1,1-Dichloroethene ug/L 50 52.6 105 60-140 1,1-Dichloropropene ug/L 50 57.6 115 60-140 1,2,3-Trichlorobenzene ug/L 50 47.8 96 60-140 1,2,3-Trichloropropane ug/L 50 52.2 104 60-140 1,2,4-Trichlorobenzene ug/L 50 49.5 99 60-140 1,2,4-Trimethylbenzene ug/L 50 49.7 99 60-140 1,2-Dibromo-3-chloropropane ug/L 50 48.5 97 60-140 1,2-Dibromoethane (EDB) ug/L 50 53.1 106 60-140 1,2-Dichlorobenzene ug/L 50 50.7 101 60-140 1,2-Dichloroethane ug/L 50 50.3 101 60-140 1,2-Dichloropropane ug/L 50 49.5 99 60-140 1,3,5-Trimethylbenzene ug/L 50 52.1 104 60-140 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 34 eAnalytical www.pocelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville. NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Monitoring Wells November 2022 Pace Project No.: 92634703 LABORATORY CONTROL SAMPLE: Parameter 3834280 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,3-Dichlorobenzene ug/L 50 51.1 102 60-140 1,3-Dichloropropane ug/L 50 50.7 101 60-140 1,4-Dichlorobenzene ug/L 50 49.4 99 60-140 2,2-Dichloropropane ug/L 50 53.8 108 60-140 2-Chlorotoluene ug/L 50 48.1 96 60-140 4-Chlorotoluene ug/L 50 48.1 96 60-140 Benzene ug/L 50 47.8 96 60-140 Bromobenzene ug/L 50 51.3 103 60-140 Bromochloromethane ug/L 50 54.1 108 60-140 Bromodichloromethane ug/L 50 51.8 104 60-140 Bromoform ug/L 50 55.8 112 60-140 Bromomethane ug/L 50 47.5 95 60-140 Carbon tetrachloride ug/L 50 53.1 106 60-140 Chlorobenzene ug/L 50 51.6 103 60-140 Chloroethane ug/L 50 46.1 92 60-140 Chloroform ug/L 50 50.8 102 60-140 Chloromethane ug/L 50 58.1 116 60-140 cis- 1, 2-Dich loroethene ug/L 50 52.0 104 60-140 cis- 1, 3-Dich loropropene ug/L 50 52.3 105 60-140 Dibromochloromethane ug/L 50 53.9 108 60-140 Dibromomethane ug/L 50 50.2 100 60-140 Dichlorodifluoromethane ug/L 50 56.8 114 60-140 Diisopropyl ether ug/L 50 51.7 103 60-140 Ethylbenzene ug/L 50 50.4 101 60-140 Hexachloro-1,3-butadiene ug/L 50 52.6 105 60-140 Isopropylbenzene (Cumene) ug/L 50 50.7 101 60-140 m&p-Xylene ug/L 100 102 102 60-140 Methyl-tert-butyl ether ug/L 50 51.4 103 60-140 Methylene Chloride ug/L 50 49.5 99 60-140 n-Butylbenzene ug/L 50 52.1 104 60-140 n-Propylbenzene ug/L 50 50.4 101 60-140 Naphthalene ug/L 50 48.8 98 60-140 o-Xylene ug/L 50 52.1 104 60-140 sec-Butylbenzene ug/L 50 50.5 101 60-140 Styrene ug/L 50 52.5 105 60-140 tert-Butylbenzene ug/L 50 43.8 88 60-140 Tetrachloroethene ug/L 50 53.0 106 60-140 Toluene ug/L 50 49.6 99 60-140 trans-1,2-Dichloroethene ug/L 50 53.2 106 60-140 trans-1,3-Dichloropropene ug/L 50 51.6 103 60-140 Trichloroethene ug/L 50 51.9 104 60-140 Trichlorofluoromethane ug/L 50 49.1 98 60-140 Vinyl chloride ug/L 50 57.9 116 60-140 1,2-Dichloroethane-d4 (S) % 99 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8 (S) % 98 70-130 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 34 Y aceAnalytical WWW.PCWaks com QUALITY CONTROL DATA Project: Monitoring Wells November 2022 Pace Project No.: 92634703 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3834648 MS 92634524004 Spike Parameter Units Result Conc. MSD Spike Conc. 3834649 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.0 17.5 105 88 60-140 18 30 1, 1, 1 -Trichloroethane ug/L ND 20 20 22.2 19.4 111 97 60-140 13 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 20.8 17.3 104 87 60-140 19 30 1,1,2-Trichloroethane ug/L ND 20 20 20.7 18.5 103 92 60-140 11 30 1,1-Dichloroethane ug/L ND 20 20 21.0 18.2 105 91 60-140 14 30 1,1-Dichloroethene ug/L ND 20 20 22.4 19.9 112 99 60-140 12 30 1,1-Dichloropropene ug/L ND 20 20 24.4 21.2 122 106 60-140 14 30 1,2,3-Trichlorobenzene ug/L ND 20 20 19.5 17.1 97 86 60-140 13 30 1,2,3-Trichloropropane ug/L ND 20 20 17.1 15.0 86 75 60-140 13 30 1,2,4-Trichlorobenzene ug/L ND 20 20 19.7 16.6 99 83 60-140 17 30 1,2,4-Trimethylbenzene ug/L ND 20 20 19.8 16.7 99 83 60-140 17 30 1,2-Dibromo-3- ug/L ND 20 20 19.5 15.4 97 77 60-140 24 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.1 18.0 106 90 60-140 16 30 1,2-Dichlorobenzene ug/L ND 20 20 19.6 17.1 98 86 60-140 13 30 1,2-Dichloroethane ug/L ND 20 20 20.7 18.1 104 91 60-140 13 30 1,2-Dichloropropane ug/L ND 20 20 20.2 17.4 101 87 60-140 15 30 1,3,5-Trimethylbenzene ug/L ND 20 20 21.2 18.0 106 90 60-140 16 30 1,3-Dichlorobenzene ug/L ND 20 20 20.1 17.2 100 86 60-140 16 30 1,3-Dichloropropane ug/L ND 20 20 20.2 16.7 101 83 60-140 19 30 1,4-Dichlorobenzene ug/L ND 20 20 19.1 16.7 95 84 60-140 13 30 2,2-Dichloropropane ug/L ND 20 20 22.4 18.8 112 94 60-140 18 30 2-Chlorotoluene ug/L ND 20 20 20.5 17.4 103 87 60-140 16 30 4-Chlorotoluene ug/L ND 20 20 20.5 17.4 103 87 60-140 16 30 Benzene ug/L ND 20 20 20.2 17.4 101 87 60-140 15 30 Bromobenzene ug/L ND 20 20 19.9 16.8 100 84 60-140 17 30 Bromochloromethane ug/L ND 20 20 21.8 18.9 109 95 60-140 14 30 Bromodichloromethane ug/L ND 20 20 21.3 18.5 107 92 60-140 14 30 Bromoform ug/L ND 20 20 21.3 16.9 107 85 60-140 23 30 Bromomethane ug/L ND 20 20 22.2 20.5 111 103 60-140 8 30 Carbon tetrachloride ug/L ND 20 20 22.6 19.7 113 98 60-140 14 30 Chlorobenzene ug/L ND 20 20 20.8 17.2 104 86 60-140 19 30 Chloroethane ug/L ND 20 20 24.8 22.2 124 111 60-140 11 30 Chloroform ug/L ND 20 20 21.4 18.0 107 90 60-140 18 30 Chloromethane ug/L ND 20 20 23.7 21.2 119 106 60-140 11 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.7 19.0 109 95 60-140 14 30 cis- 1,3-Dichloropropene ug/L ND 20 20 21.4 18.1 107 90 60-140 17 30 Dibromochloromethane ug/L ND 20 20 20.6 17.7 103 88 60-140 15 30 Dibromomethane ug/L ND 20 20 21.0 17.6 105 88 60-140 18 30 Dichlorodifluoromethane ug/L ND 20 20 22.0 19.7 110 98 60-140 11 30 Diisopropyl ether ug/L ND 20 20 19.9 16.6 99 83 60-140 18 30 Ethylbenzene ug/L ND 20 20 20.6 17.7 103 89 60-140 15 30 Hexachloro-1,3-butadiene ug/L ND 20 20 22.4 19.0 112 95 60-140 16 30 Isopropylbenzene ug/L ND 20 20 20.6 17.5 103 88 60-140 16 30 (Cumene) m&p-Xylene ug/L ND 40 40 41.1 35.0 103 88 60-140 16 30 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 34 r aceAnalytical WWW.pn:Nebs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Monitoring Wells November 2022 Pace Project No.: 92634703 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3834648 3834649 MS MSD 92634524004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Methyl-tert-butyl ether ug/L ND 20 20 20.0 17.0 100 85 60-140 17 30 Methylene Chloride ug/L ND 20 20 18.1 15.3 91 76 60-140 17 30 n-Butylbenzene ug/L ND 20 20 21.6 18.3 108 92 60-140 16 30 n-Propylbenzene ug/L ND 20 20 20.8 17.6 104 88 60-140 17 30 Naphthalene ug/L ND 20 20 19.7 16.3 98 82 60-140 19 30 o-Xylene ug/L ND 20 20 20.8 17.8 104 89 60-140 16 30 sec-Butylbenzene ug/L ND 20 20 21.1 17.8 106 89 60-140 17 30 Styrene ug/L ND 20 20 19.9 16.7 100 84 60-140 18 30 tert-Butylbenzene ug/L ND 20 20 18.6 15.8 93 79 60-140 17 30 Tetrachloroethene ug/L ND 20 20 21.0 17.5 105 88 60-140 18 30 Toluene ug/L ND 20 20 20.8 17.9 104 90 60-140 15 30 trans-1,2-Dichloroethene ug/L ND 20 20 22.3 19.7 111 98 60-140 12 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.2 18.1 106 90 60-140 16 30 Trichloroethene ug/L ND 20 20 21.6 18.5 108 93 60-140 15 30 Trichlorofluoromethane ug/L ND 20 20 22.3 19.6 111 98 60-140 13 30 Vinyl chloride ug/L ND 20 20 24.6 21.2 123 106 60-140 15 30 1,2-Dichloroethane-d4 (S) % 99 105 70-130 4-Bromofluorobenzene (S) % 102 102 70-130 Toluene-d8 (S) % 101 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 34 t aceAnalytical .W.pacelala.com QUALITY CONTROL DATA Project: Monitoring Wells November 2022 Pace Project No.: 92634703 QC Batch: 736446 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92634703001, 92634703002, 92634703003 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 METHOD BLANK: 3832778 Matra: Water Associated Lab Samples: 92634703001, 92634703002, 92634703003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Ammonia n-g/L ND 0.10 0.031 11/11/2213:26 LABORATORY CONTROL SAMPLE: 3832779 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia n-g/L 5 5.1 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3832780 3832781 MS MSD 92634724001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia mg/L 0.21 5 5 5.7 5.7 110 110 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3832782 3832783 MS MSD 92636033001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia n-g/L ND 5 5 5.4 5.4 106 107 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 34 aceAnalytical www.oacelals.com QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Monitoring Wells November 2022 Pace Project No.: 92634703 QC Batch: 736448 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92634703004 METHOD BLANK: 3832788 Matrix: Water Associated Lab Samples: 92634703004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 0.031 11/11/22 14:11 LABORATORY CONTROL SAMPLE: 3832789 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.3 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3832790 3832791 MS MSD 92634703004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.4 5.4 109 108 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3832792 3832793 MS MSD 92635117001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia mg/L 0.40 5 5 5.8 5.8 109 109 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 34 ti aceAnalytical wtaar.pacalab.eom QUALITY CONTROL DATA Project: Monitoring Wells November 2022 Pace Project No.: 92634703 QC Batch: 737616 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92634703001, 92634703002, 92634703003, 92634703004 METHOD BLANK: 3838884 Matrix: Water Associated Lab Samples: 92634703001, 92634703002, 92634703003, 92634703004 Blank Reporting Parameter Units Result Limit MDL Analyzed Nitrogen, Kjeldahl, Total mg/L ND 0.50 0.25 11/17/22 05:52 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers LABORATORY CONTROL SAMPLE: 3838885 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Neldahl, Total mg/L 10 9.5 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3838886 3838887 MS MSD 92635215002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Neldahl, Total mg/L ND 10 10 9.2 9.1 89 88 90-110 1 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3838888 3838889 MS MSD 92635215003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Neldahl, Total mg/L 0.90 10 10 10.3 10.9 94 100 90-110 6 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 34 CeAnalytical wwPacelab.ca® QUALITY CONTROL DATA Project: Monitoring Wells November 2022 Pace Project No.: 92634703 QC Batch: 734865 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92634703001 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 METHOD BLANK: 3824825 Matrix: Water Associated Lab Samples: 92634703001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.040 0.010 11/04/22 02:34 Nitrogen, Nitrite mg/L ND 0.040 0.031 11/04/22 02:34 LABORATORY CONTROL SAMPLE: 3824826 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.5 99 90-110 Nitrogen, Nitrite mg/L 1 1.0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3824827 3824828 MS MSD 92634699011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 5.2 1.5 1.5 6.8 6.7 108 101 90-110 1 10 Nitrogen, Nitrite mg/L ND 1 1 1.0 1.0 103 102 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3824829 3824830 MS MSD 92634699014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 1.2 1.5 1.5 2.7 2.7 99 98 90-110 0 10 Nitrogen, Nitrite mg/L ND 1 1 1.0 1.0 102 101 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 34 aceAnalytical WWW.pacalabs.com QUALITY CONTROL DATA Project: Monitoring Wells November 2022 Pace Project No.: 92634703 QC Batch: 734866 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92634703002, 92634703003, 92634703004 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 METHOD BLANK: 3824831 Matrix: Water Associated Lab Samples: 92634703002, 92634703003, 92634703004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.040 0.010 11/04/22 03:41 Nitrogen, Nitrite mg/L ND 0.040 0.031 11/04/22 03:41 LABORATORY CONTROL SAMPLE: 3824832 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.5 99 90-110 Nitrogen, Nitrite mg/L 1 1.0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3824833 3824834 MS MSD 92634703003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 10.0 1.5 1.5 11.4 11.5 94 97 90-110 0 10 Nitrogen, Nitrite mg/L ND 1 1 1.0 1.0 100 102 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 34 ?�Ia'cieAnalytical QUALITY CONTROL DATA Project: Monitoring Wells November 2022 Pace Project No.: 92634703 QC Batch: 734868 Analysis Method: SM 4500-P E-2011 QC Batch Method: SM 4500-P E-2011 Analysis Description: SM450OP-E Phosphorus, Ortho Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92634703001, 92634703002, 92634703003, 92634703004 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 METHOD BLANK: 3824835 Matrix: Water Associated Lab Samples: 92634703001, 92634703002, 92634703003, 92634703004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Orthophosphate as P mg/L ND 0.050 0.012 11/04/22 04:27 LABORATORY CONTROL SAMPLE & LCSD: 3824836 3824837 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Orthophosphate as P mg/L 0.25 0.25 0.26 100 102 90-110 2 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3824838 3824839 MS MSD 92634534006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Orthophosphate as P mg/L ND 0.25 0.25 0.27 0.24 93 79 90-110 14 10 M1, R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 34 �aceAnalytical www.pacelabs.com QUALIFIERS Project: Monitoring Wells November 2022 Pace Project No.: 92634703 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 PQL- Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270 The result for each analyte is a combined concentration Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as 'Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. CH The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased high_ E Analyte concentration exceeded the calibration range. The reported result is estimated. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 11 /28/2022 12:26 PM without the written consent of Pace Analytical Services, LLC Page 30 of 34 i eAnalytical www.pacolabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Pace Project No. Monitoring Wells November 2022 92634703 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92634703001 MW-1 R 92634703002 MW-2 92634703003 MW-3 92634703004 MW-4 92634703001 MW-1 R EPA 200.8 Rev 5.4 736695 EPA 200.8 Rev 5.4 736721 92634703002 MW-2 EPA 200.8 Rev 5.4 736695 EPA 200.8 Rev 5.4 736721 92634703003 MW-3 EPA 200 8 Rev 5.4 736695 EPA 200.8 Rev 5.4 736721 92634703004 MW-4 EPA 200.8 Rev 5.4 736695 EPA 200.8 Rev 5.4 736721 92634703001 MW-1 R SM 6200E 736729 92634703002 MW-2 SM 6200B 736729 92634703003 MW-3 SM 6200B 736729 92634703004 MW-4 SM 6200B 736729 92634703001 MW-1 R EPA 350.1 Rev 2.0 1993 736446 92634703002 MW-2 EPA 350.1 Rev 2.0 1993 736446 92634703003 MW-3 EPA 350.1 Rev 2.0 1993 736446 92634703004 MW-4 EPA 350.1 Rev 2.0 1993 736448 92634703001 MW-1 R EPA 351.2 Rev 2.0 1993 737616 EPA 351.2 Rev 2.0 1993 737659 92634703002 MW-2 EPA 351.2 Rev 2.0 1993 737616 EPA 351.2 Rev 2 0 1993 737659 92634703003 MW-3 EPA 351.2 Rev 2.0 1993 737616 EPA 351.2 Rev 2.0 1993 737659 92634703004 MW-4 EPA 351.2 Rev 2.0 1993 737616 EPA 351.2 Rev 2.0 1993 737659 92634703001 MW-1 R EPA 353.2 Rev 2.0 1993 734865 92634703002 MW-2 EPA 353.2 Rev 2.0 1993 734866 92634703003 MW-3 EPA 353.2 Rev 2.0 1993 734866 92634703004 MW-4 EPA 353.2 Rev 2.0 1993 734866 92634703001 MW-1 R SM 4500-P E-2011 734868 92634703002 MW-2 SM 4500-P E-2011 734868 92634703003 MW-3 SM 4500-P E-2011 734868 92634703004 MW-4 SM 4500-P E-2011 734868 Date: 11/28/2022 12:26 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 34 ll-?ace DC#_Title: ENV-FRM-HUN1-0083 01 - m Saple Condition Upon Receipt /14ii[i.Q FYd Ci Effective Date: 05/121202205/12/2022 Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville ]� Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑ Sam•, Condition Client Nam&r� PO a'� Project # Wp�# : 92634703 y Courier: ❑F Ex ❑U S ❑USpS ❑Client ❑ Commercial Pace []Other: /'� 92634*703 Custody Seal Present? ❑Yes ❑tdo Seals Intact? ❑Yes ErNo^ / L_ Date/Initials Person Examining Contents: ) t Packing Material: []Bubble Wrap []Bubble Bags ❑None ❑ Other Biological Tissue fro n? ThermometgY ❑Yes ❑No N/A IR Gun ID:� �' Type of Ice: QG/-et ❑Blue ❑None C Correction factor: Cooler Temp: lr Add/Subtract (°C) _�� Temp should be above freezing to 6"C ❑Samples out of temp criteria. Samples on ice, cooling process Cooler Temp Corrected ('C): �/ / has begun USDA Regulated Soil ( /A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC Did samples originate from a foreign source (internationally, (check maos)? nYes nNo including Hawaii and Puerto Rico)? nYes nNo Comments/Discrepancy: Chain of Custody Present? EJYes [IN. ❑N/A 1. Samples Arrived within Hold Time? es ❑No ❑N/A 2. Short Hold Time Analysis (02 hr.)? Yes ❑No [_1 N/A 3. Rush Turn Around Time Requested? ❑Yes EToNo ❑N/A 4. Sufficient Volume? es ❑No ❑N/A 5. Correct Containers Used? -Pace Containers Used? ZYes []No es [:]No [-]N/A ❑N/A 6. Containers Intact? es ❑No ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No 3<A 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: EKI ON. ❑N/A 9. Headspace in VOA Vials (>5-6mm)? ❑Yes j6 ❑N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes EINo ❑Yes ❑No ❑N/A N/A 11, COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Lot ID of split containers: Date/Time: Field Data Required? LJYes UNo Date: ' () LQ-1 1W ;LQ Date: '' ��( Page 32 of 34 Qualtrax ID: 69614 Page 1 of 2 IIII ,,lace DC# Title: ENV-FRM-HUN1-0083 v01 Sample Condition Upon Receipt Effective Date: 05/12/202205/12/2022 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine Project WO# : 92'634703 ___� PM: UP Due Date: 11/17/22 CLIENT: 93-MARION E 4Ei a Z Z c > o E �n N .i a m a Z Z w > a E o Vl N 7 Q. Co a Z 2 of O it E g V1 14 d m a Z v io a` — ,--1 7 a m u N = O a E ,n N •..� V1 a m _ p n E o Vl N Z a m = O Z ni a E ,n N ,..f N a m ry _ «. a E N .y m Q. Co w v n L ° a 3 - a z v pl E v "'f ti l7 ¢ N N E d = r1 H 0 ¢ Q z a 2 6/ ¢ E o ul N M l� ¢ N = • = Ql E ._ — '-1 - l7 ¢ v a O N SJ Q E o Vy N M C7 ¢ a y .O ¢ E o yr N M �' Z _ V = O ' E O V O� �' a O z O E O �} O�1 (A > v ` C O E O ct 01 C7 > ?N M 2 O J E O V M l7 o O N 2 p — E V 01 l7 o a N Y Y v 'i L. t,7 �. > a v E VI .N{ N a v, ¢ v E O N N a V) ( rJ o v Z U E o N cc cc a m a Z y d ¢ E S "a l7 ¢ z >?a c oc !C - ,� J o N Ji > ? l v da2i d E J 0 Gf 2 3 4 I — 5 6 \NE 8 9 10 11 12 N\N pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot N •�•�• •-••� �•� ••o��«.�,�� wuI u1 --Auld wmpudnce sdrnpies, a copy of tms rurm wm oe sent to the Nortn Carolina MNR Certitication Othce (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 33 of 34 Qualtrax ID: 69614 Page 2 of 2 CHAIN -OF -CUSTODY / Analytical Request Document ace The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Submitting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace Terms and Conditions found at https:Uinfo.pacelabs.com/hubfs/pas-standard-terms.pdf. won .a section 8 Section C ;wired Client Information: Required Project Information: Invoice Information: Page : 1 Of 1 tpany; City of Marion Report To: Tim Horton ttenbon, ress: 3982 NC Hwy 226 South opy To: ompany Name: ion, NC 28752 ddress. Requiatory Agency III: thorton marlonnc.Org urchase Order #; ace Quote. ne. (828)803-5736 JFax: roJect Name: Cityof Manon MWs NOV 2021 _ ace Project Manager: I 9 � bmipatton pacelaDs.com. State i Location uested Due Date: rolecl #: ace Profile #: 13150 NC Requested Analysis Filtered fN a = _ o O U COLLECTED Preservatives >- W7RIx COO=_ D,-r,g W.I" Dw w'aler WT y 3 U °' O 0 ware wmr vwv Rotluct P SAMPLE ID 5L _ � J Y ai oL v `• START END w _ ~ o m One Character per box. Wye wP a w y t ff c lA Z 0-9 1 •) Ov or o w F v a 3 Sample Ids must be unique Tom, TS O F s O o j >., ; g C� U ¢ a a O S y o o v `0n O L Q © U E _ y v� VJ U t �.. L �� C � — y DATE TIME DATE TIME 0 a � x Z Z i O � � m Z a � r � h, � J t MW-1R ivy lii so is � }S ' �iL 3 T X x X X X x X X x Z MW-2 o �j Z I ,` y R ) X X X X X X X Ix 3 MW-3 14 -L 1 N X X X X x X X X X 4 MW-4 vTi7y5 it{ -it I-, t 3 x x x x x x x x 5 0 7 3 3 0 2 ADDrn0NAL COMMENTS. RELINOWSNED BY I AFF&AT10N. DATE TIME ACCEPTED BY J AFFILIATION DATE TIME SAMPLE CONDITIONS in = At, CO, Fe, Pb, Mn 6 ,2 ,. a ►v3r2.Z 103S %f 2-L t7 - f1 C_ SAMPLER NAME AND SIGNATURE o n w = PRINT Name of SAMPLER: E z m z E z SIGNATURE of SAMPLER: DATE Signed: ` 113 J ZZ r [Y} V V Y NY tT a Document Nnon: Field (lain Shirt Date lssued: March 9, 2019 llj_ ,?COAnalylical 1'a ,c: 1 of2 fhtcuntent Numtxr, F-CAR-I LI)-Wl•rev.0.1 Issuing Autlioriiy: Pace Hunlersville Quality Office Field Data Sheet Client:_b; f y Of rtar ; en _i.ocatinn:_ s.+�tN C -_ Project #: G: 4Y or oar; erL oxvl i A Nov.202z Name and Affiliation (Sanipler(s): R^6 fe ci2 Field Data Sheet Review: Nanseand Affiliation (Inspector):_ N 1A it-M-2JL Mt `2- Well Information Date: 1) `o A By: Well ID: #A- - (Q Well Locked: CYES NO / Flushnsount ) Well Diameter: 1 ^ Construction: Steel/Stainless Steel) Total Well Depth: Jz.�o , -Vz ft Static Water Level:- ZS3 .w_i__ft Height of Water Colunin:_?i �.-Q ft Multi Factor*: 0.16 3 l'(Rat i us/12)2 x 3.14 x 7.49] Casing Volume: 5 , 5 7 gallons Cal. 3 Volumes: k6,71 gallons Pump Intake:__ ~ 6 O ft Purge Information 0 Date Purged:_ 11 /_ -_/'L Z Start:. '?a_y S -- Pinish: l I �i 5_ Purge Rate: +04-MIS/A, 1 a8 iu30 2 PurgiigMethod: r'c P-A _Total Volume Purged: _j�24o._._ (gallons nsis ) So tripling Information Date Collected:I_/-1-/-Z Time Collected: I Is o am pn1) SannplingEquipmentUsed: PiLe-,y+eJ4o/- QLuT InstrumentiD: MoS6g/TPvbe64 Bottle Type Field Measurementa/Observations Preservation Analysis Required �r` ;o.iSr =O4lAr•� AQnial UtAj M;A(-4e, woe je,— ,rot r.+•.t ,TD�5 Sample'remp (OC): Z3.Q Time: 1i S9 Turbidity (ntu): 'Z1'9 Time: ) l S 0 Diss Oxy (mg/L): 5• L 'Time: Pe 2+ mg/L: Time: Specific Cond. (uS): 2 Tune: _ Res. Cl (ing/Lu(jig/L): - Tune:__'— Sample pH (s.u.):. qk_ _ Time: ___.-�----Odor: K Okp —_---- Tiine: i 15O ReDox (mV): ---- Time: Appearance:c;; 'rinse:_ J- ReDox (F.H vaiue):YSI ProPlus +200nnV Other: 'Pime: I-- General/WeatherObservations; vet% Le av Jttr FJ 4•o S+.ZK. us+ FrA,n Fiush no.let s;„e. *jr avant sunn cloudy/rainy) Temp._-6--(*F) Wind a- S (mph) Sampler Signature,.__ayaA__8--i_;Lj .-.___Date:__ if/312 Stabilization Teat Spec. Volume Time Temp. e Diss Oxy, Cond. pH (s.u.) ReDox Turbiditj removed Water Other Purged (C) (mg/L) (us) (111V) (ntu)gallons nsls level (ft) L agSU ►1,0 7. Z 27.1 S.'7 --14 7 00 Du I7.Q 7. 2-1, S,7 •-- z 400 291,62 S I 2 7 q 217- •o 3,03 go 19,61, 00 27,2 --- 52 0 27,2 b 40, 2 o 0 2 t, j, 2. w Document Manic: Document Issued: March 8, 2019 Field Data Sheet Page 2of 1— 14CBAti,'71yf a?I � � Document Number: Issueing Authority: ( F-CAR-FLD-001.rev.03 Pence Iimitersville Quality Office Client: C , 4y . °F /fir ,0 Location: N ( Project: L; ay OF /A!t r; o A M y ii A TI Ov. to 22 Well ID: M v/ Reviewed Date and By: I l " A " d 3, /M E✓'— Stabilization Test lt\ 0�1�-1 11rell Diameter 'Multiplication Factor" 1 0.0408 1.2 0.0918 1.625 0.1080 2 0.1630 3 0.3670 4 0.6530 6 1.4680 3 2.6100 Time Purged Temp. (°C) Diss Oxy. (mg/L) Spec. Cond. (uS) pH (s.u.) ReDox (mv) Turbidity (ntu) Volume Removed ) (gallonsVoe circle Water level (ft) Other 107.5 1,1 6-7 27.1 6.0 -- 4'A 3 Z4ctz 2 �6 , G f sv.IJ to 0 Iq, .0 zb. 16.0 "— ) '2 17 oo Z 7 ►o 1 A . 6.0 2 6 .3 0.0 S 7.7 6100 28 loss U.b 5.5 tv -- 70a z 7 005 _Q 5. 4 25,b 5 . --LA LA4 i 200 -28 . III z4. s . ---- 3 %, I I 10,D za 25 zz.l S. u. S. 3'3. 13200 2 B,9S 113 z S. 2q, S . 30,$14700 tt 0 2 an �, = 1S,4 2a. 2Z i S. IN 25.-0 2 0011 z� 5 F LOhbN }; 1 A W, T &J,eA (-. M N r4 n s, M Document Wine; Field dola Sh°cl Date lmued: March 8, 2019 Page: 1 off AWlyflC31 Document Number: F-CAR-1L11-001-rev.03 Issuing Authority: Pace i-luntersville Quality Office Field Data Sheet Client: i 7 o F /�or� all LOcaHOn: Mar�'o�• ��_ _Project it:_[ , ry vKi 01 MW S a F10v, to Z 2 Name and Affiliation (Sampler(s): A"A Pa L-P Field Data Sheet Review: Name and Affiliation (inspector): /A Date: `1 jowl �a By: �JF Well Information Well ID: r►•w . Z Well Locked: YES NO / Flushmount ) Well Diameter: t n..__ Construction: PVC , teem/Stainless Steel) Total Well Depth: ft Static Water Level: 1q % _ft Height of Water Column:-_ 8_b5 ft Multi Factor*: 0-10 ("(Radius/12)2x3.14x7.48) Casing Volume: 3.04 _ gallons Cal. 3 Volumes: gallons Pump Intake: ,--1 b ft Purge Information G Date Purged:- �I /�—/ Zz Start :-_L�N�. Finish: 1 4 51 Purge Rate:_ f oohli M , ON (gallons nuts L Purging Method _Qd�; S tsLfi�l'� Total Volume Purged: 5��__. (g ) Sampling Information Date Collected: 11 / 3 / Z Z Time Collected: _�S� (am)& Sampling Equipment Used: PNAe Instrument 1D: Y Slc�s ba �TP✓boa n-1 _ Bottle Type Preservation Analysis Required pojejs0 jot , A^^oni IILN--! KAto.t�i 14:��i4?. P46aol 101i 1 I TDS, Niy—, 1�3L L2oo� Or�t.o—_4S 1�+9 Field Measurements/Observations Sample Temp (°C)• f $ S Time. 15 oD Turbidity (ntu): • °� Time: _1500 (' Time: Diss Oxy (mg/L): 0 ' Time: _ Fe 2+ nlg/L: Specific Cond. (uS): �� .— Time: _ Res. Cl (mg/L)/(pg/L):. ! Time:. Sample pH (s.u.): ___ 6. ' . Time: •--__.---. Odor:---_ a ti,,%kPJ-/ OT�7;r21- __.Tine: 15 � 9' ReDox (mV): Time: Appearance: WNy / j Time: •Y _ ReDox (EH value):YSI ProPlus +200mV Other: _ Tinie: r GenerauWeather Observations: 5 Sampler Signature: (y" eya5 y/rainy) Temp.•Z,—(°h) Wmd 4— (Inph) (( /3 /2L a1d VIII&OLlVi! acw Diss Oxy. (mg/ Spec. Cond. (u5) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume renmove (gallons/ nis Water level (ft) Other Temp. (°C) 6rged 1t. LO (,.4 --, 6. Lt S4o Stottbtkp tb �.b 188. -- Ll1 . 4 '2 'i -0 15,00 ft A Date Issued: March 8, 2019 Document Nnme: field data Sheet Pn *e: 1 of Z , ,1CeAiolyficaI i Document Numb,v: F-CAR-171.t).001-rev.03 issuing Autltotily: Pace Huntersville Quality Office Field Data 5lteet Client: L; 4y e( t!!�!P •A __Location:.- M.tp-al Name and Affiliation (Sanlpler(s):. R"' 8 PA /P Narne and Affiliation (inspector): N / A Well Information Well 1D: _- MMt''�i - Well Diameter: Z Total Well Depth: 5 O,Q 2.. ft Static Water Level:-I4_15b ft Height of Water Column:-! S by_ft Well Locked: k( YES Construction: #:h:�Y 9t�le.r%o1 /Aw I II�Jv,2o2� Id Data Sheet Review: Date: II I 1 �� a By: )NO / Flushnlotntt ) eel/Stainless Steel) Multi Factor*: °•t b-�_ i'(Rad1us/12)2 x 3.14 x 7.481 Casing Volume: - ,IS , _ gallons Cal. 3 Volumes: ,' 7 5 gallons Pump Intake: ^' 4 4-' ft Purge Information Date Purged: �,-_//.-- �_. Start :-1242—_. Pin ish: 1 4�1 5 Purge Rate: lOoMiS/� i Purging Method: eogs- r"on yoy it _ Total Volume Purged: 500.____.. (gallons/Af Tss L) Sampling Information Date Collected: ► I / 3 / Z Time Collected: it i o (allQr6pol) Sampling Equipment llsed:�G9$ _-�o&Soon _Instrument ID: Y SIoTP v Bottle Type Preservation Analysis Required ....----.--__.---------- _ r►.rrngt.T�.t.t ,TDy,TtiS �94�xZaoj t +l•o� MgSpA.4- Field Measurementa/Observations Sample Temp (oC): I . + Time: I y (O Turbidity (ntu): -- 9 . g Time: I 10 Diss Oxy (mg/L): 7 17 'lime: — Fe 2+ nig/L: Time: — Specific Cond. (US): 1 `41 , _._ Time: Res. Cl Sample pH (s.u.): _-- �i . _� Time: --------- Odor:----- N `• 1 P _ _Tillie: - t Li IfO -- ReDox (mV): �� Thne: Appearance: L196Li Time:- .� YSI P Pl +20t)niv ---� Other: _ -_ Tillie: ReDOX (FH value). to us General/Weather Observations, __-- y/rainy) Wind 0=(mph) Sampler Signature;i*^ Bxws Date:_ 1I /3 /? z_- Tillie Tenlp. Purged (°C) Diss Ox y' Spec. Cond. pH (s.u.) Revox (mv) Turbidity&vel'e(ft) (ntu) Other (mg/L) (u5) J(gallons)o 161.0 -- 77 Ibl 4. -- 1-7S.'1 fS 0 34,6 IQ2 2504 iy.7 U6,5 350 4 'r 'r Ir Document Name: Dmuntent Issued: March 8, 2019 Field Data Sheet Paget of i aceAnalyticrll - Document Number. Issueing Authority: ( F-CAR-FLD-001.rev,03 Pace Huntersville Quality Office Client: C 4-1 or - Location: Project: L;4r of rya": 4n MW y A Moy, zoz.Z Well ID: M \A✓ - Reviewed Date and By: , - ti " 2L ME 2 Stabilization Test 1 c" k�} 6Y-L" Nell Diameter Multiplication Factor* 1 0.0408 1.2 0.0918 1.625 0.1080 2 0.1630 3 0.3670 4 0.6530 6 1.4680 8 2.6100 Time Purged Temp. (°C) Diss Oxy. (mg/L) Spec. ius;' PN (s.u.) ReDox (mV) Turbidity (ntu) Volume Re oved (gallons mis ) circle one Water level (fti Other 1315 t'1,o 'i,s lyo.`7 y. fo3,% 440dz 3H,86 1335 1`7, 3. S 13gg `). 67. 5500 34.9 13 ti 1-1. 13 . 5 . 3 `b, 500 3 ,f. 9 I`i55 t7 13q•1 51,0 19.5 5O0 -3S-ob 1Ko 5 1 3,-7 0131 as oCJ 35.1 'd at. It lhxument Name: Multi dala Sheet mate Issued: March 8, 2019 . ,?CCAlh7V C:11 Page: 1 of Documeni Number: RCAWFLD-001-rev.03 Issuing Authority: [ am tluntersville Q.-lily Office Field Data Sheet Name and Affiliation (Sampler(s): RM d Pm W Name and Affiliation (Inspector): N /A Well Information Well ID: Well Diameter: Total Well Depth: 3SIV7 ft Static Water Level: lot .01 ft Height of Water Column: —I `_ .3 \ .ft Well Locked: Construction: M w s A M o,,. 2022 Field Data Sheet Review: Date: By: 'r� tli O�t�Y� YES/NO / Flushmount ) Steel) Multi Factor`: 4I i I ('(Radius/12)2 x 3.14 x 7.481 Casing Volume: 2 .) � gallons Cal.3 Volumes 7.01 gallons Puinp Intake: r '� I _{t Purge Infornation Date Purged: It / / 22 Start; ISIS Finish:I S O ('urge Rate: I floMfy/^i1 Purging Method: `��'f fa Its C P P Total Volume Purged: 1600 (gallons/rfSf , Sampling Information �� Date Collected: 11 / 3 / ZZ Time Collected:_t 5►�S_ (aQ/pni)Sampling Equipment Used:Pi1Mp InstrumentID:vS Bottle Type Field Measurenients/Observations Preservation Analysis Required SKAI� N:fie.�t r�Ae _ _P_biaoyTa—t110, 10, SanlpleTemp(°C):_-_�-S • 9 Time: 5_4_s Turbidity (ntu): 0• a —� Time: IS4S Diss Oxy (mg/4 Time: _ Fe 2+ mg/L: Time: Specific Cond. (uS): 601 Time: Res. Cl (mg/L)/(ltg/L): 'Thee: nl SapiepH(s.u.):Time:- Odor:--,----IA_----------Time: ISGS ReDox (mV): Time: — Appearance: L I t° I,'— 'Time:_ ReDox (EH value):YSI ProPlus +200mV___,.Other: -----'— Time: General/Weather Observations: eunny01oudy/rainy) Temp. yo_(°F) Wind 0-5 (mph) Sampler Signature:__Qy._Q,f% �y S_ _Date:. 1 I 3/ z Stabilization Test Time Ternp. Diss Oxy. Spec. . pH (s.u.) ReDox Turbidity me o u remov Water other Purged (aC) (mg/L) (os) (n1V) (ntu) (gallons tls level (ft) eftlk L IS34 I ,I �J•'� Z • 600 �w ,'l (,2 t .z Sop > ,• 1111.10 t3.00 o 4. cj-- 0 4k 1000