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HomeMy WebLinkAboutNC0000272_Comments_20240830SOUTHERN 48 Patton Avenue, Suite 304 Telephone 828-258-2023 ENVIRONMENTAL Asheville, NC 28801 Facsimile 828-258-2024 LAW CENTER August 30, 2024 Via Electronic Mail Sergei Chernikov, Ph.D. North Carolina Department of Environmental Quality Division of Water Resources 1617 Mail Service Center Raleigh, NC 27699-1617 sergei.chemikov@ncdenr.gov publiccomments@deq.nc.gov Re: Draft NPDES Permit NC0000272 Major Modification Dear Dr. Chernikov: Please accept these comments from the Southern Environmental Law Center on behalf of MountainTrue, the French Broad Riverkeeper, the Tennessee Chapter of the Sierra Club, and the Center for Biological Diversity regarding the proposed major modification of the National Pollutant Discharge Elimination System ("NPDES") permit for Blue Ridge Paper Products, LLC ("Blue Ridge Paper"). We appreciate the Department of Environmental Quality's ("DEQ") attention to mill closure activities and we are eager to see this site remediated but this modification is premature —permit materials suggest DEQ lacks information to develop appropriate pollutant and flow limits. Until it has sufficient information, the current permit should remain in place. DEQ must also clarify that Blue Ridge Paper does not have authority to discharge groundwater remediation wastewater under the current or modified permit. I. Factual Background We provided substantial legal and factual background information in comments submitted on the 2022 renewal of Blue Ridge Paper's NPDES permit. We attach and incorporate those comments here both for reference and because DEQ failed to correct multiple errors in the previous draft permit.' Following issuance of the current NPDES permit, Blue Ridge Paper announced plans to close its Canton mill.2 Multiple entities have since been involved in assessing environmental contamination at the site. DEQ reports that it is working to "assess potential environmental impacts and determine actions to maintain compliance, continue required remediation activities, ' See Letter from Spencer Scheidt, SELC, to Sergei Chernikov, DEQ (April 30, 2021), included as Attachment 1. 2 Draft Fact Sheet, 1. Charlottesville Chapel Hill Atlanta Asheville Birmingham Charleston Nashville Richmond Washington, DC and appropriately handle the end of plant operations."3 DEQ Secretary Biser has explained that their goal is "first and foremost to make sure that the site is remediated for future productive use," adding that DEQ "will hold the company accountable for responsible closure." The North Carolina Collaboratory announced in October 2023 that it is investigating contamination from the mill in partnership with DEQ. The Collaboratory plans to "look for a wide range of compounds, including components of the toxic papermaking byproduct known as black liquor" and per- and polyfluoroalkyl substances, or PFAS.S Their assessment will take over a year. According to the Collaboratory's Executive Director, they "don't know what [they]'re going to find" but in initial tests of a contaminated groundwater seep "[1]ead levels were 2,796 times higher than the state standard. Copper was 332 times higher, chromium 21 times higher, nickel 17 times higher, zinc five times higher and arsenic nearly four times higher. Beryllium came in more than 30% above the state limit."6 The Environmental Protect Agency ("EPA") also recently initiated enforcement activities at the mill related to ground and surface water contamination. 7 Mill closure means a substantial amount of waste will no longer be channeled to the onsite wastewater treatment plant ("WWTP"), however the WWTP will continue processing some waste streams including wastewater from the City of Canton and leachate from a Blue Ridge Paper landfill. To accommodate this change in inflow, Blue Ridge Paper plans to make significant changes to the existing WWTP in three phrases. In April 2023, DEQ informed Blue Ridge Paper that "[p]rior to Phase III, [DEQ] will require permit modification based on anticipated changes in effluent volume and wastewater characteristics. The permittee ... is to submit a revised permit application at least thirty (30) calendar days in advance of the implementation of Phase III of the transition plan."8 DEQ previously explained that the permit modification would require a "full[] characteriz[ation of] the wastewater coming from the Town of Canton," "[f]urther investigation of the normal and maximum/minimum flows that would be expected from the Town of Canton," and "[c]haracterization of the landfill leachate and review 3 See DEQ, Canton Paper Mill, https://www.deq nc.gov/news/key-issues/canton-paper-mill#WasteManagement- 12687. a Holly Kays, What's left behind: Canton mill closure leaves complex environmental footprint, Smoky Mountain News (June 28, 2023), https:Hsmokymountainnews.com/archives/item/35886-what-s-left-behind-canton-mill- closure-leaves-complex-environmental-footprint. 5 Holly Kays, Research to test for contamination near Canton mill property, Smoky Mountain News (October 25, 2023), https:Hsmokymountainnews.com/outdoors/item/36625-research-to-test-for-contamination-near-canton-mill- property. 6 Id. See EPA, Civil Enforcement Case Report, Case No. 04-2024-7000, https:Hecho.epa.gov/enforcement-case- report?activity_id=3603796449. a Letter from Landon Davidson, DEQ, to John McCarthy, Blue Ridge Paper (April 12, 2023). N of the mill's last NPDES permit priority pollutant analysis."9 Specific to PFAS, DEQ previously noted that "domestic wastewater from the town of Canton ... might contain some PFAS."10 On September 11, 2023, Blue Ridge Paper submitted a permit modification request in response to DEQ's April 2023 letter but that request lacks virtually all of the information DEQ previously said was necessary.' 1 The application also requested "authorization to treat purge wastewater from the groundwater wells associated with the site investigation" into groundwater contamination, even thought that investigation is incomplete and it is unclear what contaminants may be present in that wastewater.12 Nevertheless, without the information it previously described as important to its permit decision, DEQ issued a draft permit modification on July 25, 2024. The draft permit authorizes discharges of "wastewater associated with the Blue Ridge Paper Products Inc. pulp and paper mill, the Town of Canton's chlorinated domestic wastewater and landfill leachate."13 It includes limits on only three pollutants —biological oxygen demand, total suspended solids, and fecal coliform. II. The permit may not authorize discharges of groundwater remediation wastewater. As noted above, Blue Ridge Paper's NPDES major modification application requested "authorization to treat purge wastewater from the groundwater wells associated with the site investigation" through the WWTP.14 The fact sheet accompanying the draft permit indicates that the WWTP is currently processing "groundwater remediation" wastewater and separately describes "groundwater remediation" as the "type of waste" processed by the WWTP.15 Because Blue Ridge Paper has not adequately disclosed its intention to discharge this waste stream —or the pollutants present in the waste stream —it may not discharge "groundwater remediation" wastewater under the existing NPDES permit, nor can that discharge be approved with the proposed major modification.16 The Clean Water Act prohibits the discharge of pollutants without a permit and a specific waste stream cannot be permitted if it is not disclosed in a NPDES permit application. EPA reaffirmed this requirement in December 2022, explaining that "no permit may be issued to the owner or operator of a facility unless the owner or operator submits a complete permit 9 See DEQ, Preliminary Evaluation and Recommendations for Revised WWTP Operations, Pactiv Evergreen — Canton, N. C. Mill, https://www.deq.nc.gov/water-resources/preliminary-evaluation-and-recommendations-revised- wwtp-operations-canton-mill/open. 10 DEQ, Response to Comments on Draft NPDES Permit No. NC000272, 9 (April 16, 2021) [hereafter "Response to Comments"]. 11 Letter from James Clary, Blue Ridge Paper, to Dr. Sergei Chernikov (Sept. 11, 2023). 12 Blue Ridge Paper, NPDES Permit Application, Attachment II-B (Sept. 11, 2023). 13 Draft Permit, 3. 14 Blue Ridge Paper, NPDES Permit Application, Attachment II-B. 15 Fact Sheet, 1. 16 It is unclear if DEQ is equating "purge wastewater from the groundwater wells" and "groundwater remediation" wastewater but the failure to adequately disclose either waste stream means neither can be permitted. application" providing all information "that the permitting authority may reasonably require to assess the discharges of the facility."17 At no point during the 2022 NPDES permit renewal did Blue Ridge Paper request authorization to process groundwater remediation wastewater through its WWTP. As a result, the current permit does not authorize the treatment and discharge of that waste stream. If this is happening under the current permit, it is illegal.18 For similar reasons, DEQ cannot authorize the discharge of groundwater remediation wastewater through this major modification. For a permittee to disclose a discharge sufficient to obtain coverage under a NPDES permit, it must provide enough information for the permitting agency to "be[] able to judge whether the discharge of a particular pollutant constitutes a significant threat to the environment."19 This requires providing all relevant information, including the concentration, volume, and frequency of the discharge.20 The Clean Water Act places the burden of disclosure on the permit applicant because they are in the best position to know what is in their discharge.21 If a NPDES permit applicant does not adequately disclose its release of a pollutant, the applicant does not have approval to discharge the pollutant.22 As previously explained by DEQ: Part of the permit applicant's burden in this regard is to disclose all relevant information, such as the presence of known constituents in a discharge that pose a potential risk to human health. The permit applicant is required to disclose "all known toxic components that can be reasonably expected to be in the discharge, including but not limited to those contained in a priority pollutant analysis." 15A N.C.A.C. 2H .01050) (emphasis added). [...].23 11 Memorandum from Radhika Fox, Assistant Administrator, U.S. Env't Prot. Agency, Addressing PFAS Discharges in NPDES Permits and Through the Pretreatment Program and Monitoring Programs, 2 (December 5, 2022). 18 See Piney Run Pres. Assn v. Cmy. Comm is of Carroll Cnty., MD, 268 F.3d 255, 268 (4th Cir. 2001) ("To the extent that a permit holder discharges a pollutant that it did not disclose, it violates the NPDES permit and the [Clean Water Act]."). "Piney Run, 268 F.3d. at 268 ("Because the permitting scheme is dependent on the permitting authority being able to judge whether the discharge of a particular pollutant constitutes a significant threat to the environment, discharges not within the reasonable contemplation of the permitting authority during the permit application process, whether spills or otherwise, do not come within the protection of the permit shield."). 20 See In re Ketchikan Pulp Co., 7 E.A.D. 605 (EPA) (1998) ("In explaining the provisions of 40 C.F.R. § 122.53(d)(7)(iii), which required dischargers to submit quantitative data relating to certain conventional and nonconventional pollutants that dischargers know or have reason to believe are present in their effluent, the [EPA] stated: `permit writers need to know what pollutants are present in an effluent to determine appropriate limits in the absence of effluent guidelines."'). u S. Appalachian Mountain Stewards, 758 F.3d at 566 ("The statute and regulations purposefully place the burden of disclosure on the permit applicant."). 22 See In re Ketchikan Pulp Co., 7 E.A.D. 605; Piney Run, 268 F.3d. at 268; S. Appalachian Mountain Stewards, 758 F.3d at 567. 23 Amended Complaint, N.C. Dept. of Environmental Quality v. Chemours, 17 CVS 580, 6-7 (N.C. Super. 2018) (citing 33 U.S.C. § 1342(k); Piney Run, 268 F.3d at 265), https://perma.cc/ZT3U-7QJB. 2 Blue Ridge Paper has failed to do that here. At most, it has requested "authorization to treat purge wastewater from the groundwater wells associated with the site investigation" and indicated that "[o]ne removal option being considered is a pump and treat system utilizing the [WWTP] to treat impacted groundwater. ,24 Blue Ridge Paper states that it "will continue to work with [EPA] and [DEQ] on evaluating this and other removal options. ,25 This falls leagues short of the Clean Water Act's requirements because it fails to disclose any of the constituents in groundwater remediation waste stream. DEQ must make clear in any final permitting decision that —at least based on the information currently before the agency —it is not authorizing the discharge of contaminated groundwater through the WWTP. III. DEQ must require Blue Ridge Paper to disclose the pollutants in its WWTP influent. For similar reasons, DEQ may not authorize the discharge of wastewater from the Town of Canton or landfill leachate without more information about the pollutants present in those waste streams. Like groundwater remediation wastewater, Blue Ridge Paper has not provided sufficient information about Canton's wastewater or landfill leachate for DEQ to "judge whether the discharge of a particular pollutant constitutes a significant threat to the environment. ,26 Consequently, pollutants associated with those waste streams cannot be discharged under a modified permit. DEQ previously recognized that characterization of those waste streams would be necessary before modifying the existing permit to authorize their discharge. In 2023, it explained that a modified permit would have to be informed by a "full[] characterize[ation of] the wastewater coming from the Town of Canton," "[fJurther investigation of the normal and maximum/minimum flows that would be expected from the Town of Canton," and "[c]haracterization of the landfill leachate and review of the mill's last NPDES permit priority pollutant analysis."27 DEQ now appears to be abandoning that position with no explanation. The portion of the major modification application that should include information about pollutants in the WWTP influent is blank.28 Instead, Blue Ridge Paper indicates it will provide this "required testing and analysis" information in the future -after the permit has already been issued.29 But DEQ cannot issue an NPDES permit now and subsequently obtain the information required to develop permit limits. If Blue Ridge 2' Blue Ridge Paper, NPDES Permit Application, Attachment II-B. 2s Id. 26 Piney Run, 268 F.M. at 268 ("Because the permitting scheme is dependent on the permitting authority being able to judge whether the discharge of a particular pollutant constitutes a significant threat to the environment, discharges not within the reasonable contemplation of the permitting authority during the permit application process, whether spills or otherwise, do not come within the protection of the permit shield."). 27 See supra note 9. 28 See Blue Ridge Paper, NPDES Permit Application, Attachment II-B. 29 Letter from James Clary, Blue Ridge Paper, to Dr. Sergei Chemikov (Sept. 11, 2023). 5 Paper does not know what pollutants are in its WWTP influent then DEQ cannot process its modification request and the current permit must remain in place. While this is true of all pollutants, it is particularly important that DEQ require Blue Ridge Paper to disclose the presence of any PFAS in its WWTP influent. As DEQ is aware, PFAS are a group of man-made chemicals manufactured and used broadly by industry since the 1940s.30 PFAS pose a significant threat to human health at extremely low concentrations. Two of the most studied PFAS—perfluorooctanoic acid ("PFOA") and perfluorooctane sulfonate ("PFOS")—are bioaccumulative and highly persistent in humans. 31 These chemicals build up in the human body, and have been shown to cause developmental effects to fetuses and infants, kidney and testicular cancer, liver malfunction, hypothyroidism, high cholesterol, ulcerative colitis, obesity, decreased immune response to vaccines, reduced hormone levels, delayed puberty, and lower birth weight and size.3' Recent literature also suggests PFAS exposure can result in decreased fertility in women.33 30 Lifetime Drinking Water Health Advisories for Four Perfluoroalkyl Substances, 87 Fed. Reg. 36,848, 36,849 (June 21, 2022); Our Current Understanding of the Human Health and Environmental Risks ofPFAS, U.S. ENV'T PROT. AGENCY, https://perma.cc/V6PX-2PNK (page saved Mar. 8, 2023). 31 87 Fed. Reg. at 36,849; U.S. Env't Prot. Agency, Interim Drinking Water Health Advisory: Perfluorooctanoic Acid (PFOA) CASRN 335-67-1 (June 2022), at 3-4, htt2s://perma.cc/F89R-PJUV; U.S. Env't Prot. Agency, Interim Drinking Water Health Advisory: Perfluorooctane Sulfonic Acid (PFOS) CASRN 1763-23-1 (June 2022), at 3-4, hltps://penna.cc/TQM6-57PZ. "U.S. Env't Prot. Agency, Drinking Water Health Advisories for PFAS: Fact Sheet for Communities at 1-2 (June 2022), available at htt2s://perma.cc/T7FQ-EKD6; Agency for Toxic Substances and Disease Registry, Toxicological Profile for Perfluoroalkyls (May 2021); PFAS National Primary Drinking Water Regulation Rulemaking, 88 Fed. Reg. 18,638, 18,642 (Mar. 29, 2023) (discussing developmental effects). 33 Nathan J. Cohen, Exposure to Perfluoroalkyl Substances and Women's Fertility Outcomes in a Singaporean Population -Based Preconception Cohort, 873 SCi. TOTAL ENV'T 162267 (May 15, 2023). on Exposure to other PFAS, such as perfluorobutanoic acid ("PFBA"),34 perfluorohexanoic acid ("PFHxA"),35 perfluorononanoic acid ("PFNA"),36 perfluorodecanoic acid ("PFDA") 31 perfluoropentanoic acid ("PFPeA" ),38 and perfluoroheptanoic acid ("PFHpA" )'31 is associated with many of the same health outcomes as exposure to PFOA and PFOS. While the harms to human health are extreme, PFAS are also detrimental to wildlife and the environment. The chemicals have been shown to cause damaging effects in fish,41 34 U.S. Env't Prot. Agency, IRIS Toxicological Review of Perfluorobutanoic Acid (PFBA, CASRN 375-22-4) and Related Salts at xii (Dec. 2022), https://perma.cc/7N53-6K2M (explaining that "available evidence indicates that developmental, thyroid, and liver effects in humans are likely caused by PFBA exposure in utero or during adulthood"). 35 U.S. Env't Prot. Agency, IRIS Toxicological Review of Perfluorohexanoic Acid [PFHxA, CASRN 307-24-4] and Related Salts at xiv, 14 (Apr. 2023), https://perma.cc/6562-8JA5 (concluding exposure to PFHxA "likely causes" liver, fetal development, and immune system complications, as well as decreased red blood cell counts). 36 U.S. Env't Prot. Agency, IRIS Toxicological Review of Perfluorononanoic Acid (PFNA) and Related Salts (Public Comment and External Review Draft) (Mar. 2024), hgps://perma.cc/S6KK-EBVV; Cheryl E. Rockwell et al., Acute Immunotoxic Effects of Perfluorononanoic Acid (PFNA) in C57BL/6 Mice, J. OF CLINICAL AND EXPERIMENTAL PHARMACOLOGY S4-002 7 (2013), https://perma.cc/GH27-BHL9 (concluding that PFNA can disrupt blood cell functions and alter immune system responses); Agency for Toxic Substances and Disease Registry, Toxicological Profile for Perfluoroalkyls at 7-21 (May 2021) [hereinafter "ATSDR, Toxicological Profile for PFAS"], https://penna.cc/L8PY-DYKN (noting decreased pup survival in rodents as well as developmental delays, decreases in birth weight, decreased sperm motility, and altered immune responses); Francesca Coperchini et al., Thyroid Disrupting Effects of Old and New Generation PFAS, FRONTIERS IN ENDOCRINOLOGY (Jan. 2021), https://penna.ccNSK9-KBHR; Natalie M. Crawford et al., Effects ofPerfluorinated Chemicals on Thyroid Function, Markers of Ovarian Reserve, and Natural Fertility, 69 REPRODUCTIVE TOXICOLOGY 53-59 (2017); Ryan C. Lewis et al., Serum Biomarkers of Exposure to Perfluoroalkyl Substance in Relation to Serum Testosterone and Measures of Thyroid Function Among Adults and Adolescents from NHANES 2011-2012, 12 INT'L J. ENv'T RES. PUBLIC HEALTH 6098-6114 (2015). 31 U.S. Env't Prot. Agency, Draft IRIS Toxicological Review of Perfluorodecanoic Acid (PFDA) and Related Salts (Public Comment and External Review Draft) (Apr. 2023), https://penna.cc/D75M-AWHN. 38 Xin Liu et al., Structure -Based Investigation on the Association Between Perfluoroalkyl Acids Exposure and Both Gestational Diabetes Mellitus and Glucose Homeostasis in Pregnant Women, 127 ENV'T INT'L 85-93 (2019), https://penna.ccN86G-BP4R; Surabhi Shah-Kulkarni et al., Prenatal Exposure to Perfluorinated Compounds Affects Thyroid Hormone Levels in Newborn Girls, 94 ENV'T INT'L 607-13 (2016), https://penna.ccNDR2-YAL6; Xiaofei Song et al., Biomonitoring PFAAs in Blood and Semen Samples: Investigation of a Potential Link Between PFAAs Exposure and Semen Mobility in China, 113 ENv'T INT'L 50-54 (2018). 39 European Chemicals Agency, Committee for Risk Assessment RAC Opinion: Proposing Harmonised Classification and Labelling at EU Level of Perfluoroheptanoic Acid; Tridecafluoroheptanoic Acid (Dec. 10, 2020), https://perma.cc/3N4G-S4Q9 (finding PFHpA may cause liver and thyroid damage as well as a myriad of fertility and fetal development concerns including lower birth weight, delayed mammary gland development, low sperm count and mobility, and increased risk of miscarriage). 41 Chen et al., Perfluorobutanesulfonate Exposure Causes Durable and Transgenerational Dysbiosis of Gut Microbiota in Marine Medaka, 5 ENv'T SCI. & TECH LETTERS 731-38 (2018); Chen et al., Accumulation of Perfluorobutane Sulfonate (PFBS) and Impairment of Visual Function in the Eyes of Marine Medaka After a LifeCycle Exposure, 201 AQUATIC TOXICOLOGY 1-10 (2018); Du et al., Chronic Effects of Water -Borne PFOS Exposure on Growth, Survival and Hepatotoxicity in Zebrafish: A Partial Life -Cycle Test, 74 CHEMOSPHERE 723-29 (2009); Hagenaars et al., Structure Activity Relationship Assessment of Four Perfluorinated Chemicals Using a Prolonged Zebrafish Early Life Stage Test, 82 CHEMOSPHERE 764-72 (2011); Huang et al., Toxicity, Uptake Kinetics and Behavior Assessment in Zebrafish Embryos Following Exposure to Perfluorooctanesulphonicacid (PFOS), 98 AQUATIC TOXICOLOGY 139-47 (2010); Jantzen et al., PFOS, PFNA, and PFOA Sub -Lethal Exposure to 7 amphibians,41 reptiles," mollusks,43 and other aquatic invertebrates 44—resulting in developmental and reproductive impacts, behavioral changes, adverse effects to livers, disruption to endocrine systems, and weakened immune systems. 45 The pulp and paper industry is a known consumer of PFAS.46 PFAS are incorporated into paper production in multiple ways. They can be added to the pulp to improve the internal water- resistant properties of paper products,47 or added externally as a surface coating for packaging products.48 In addition to incorporation into manufactured products, fluoropolymers are used on equipment and production processes for their non -corrosive properties, from pulp mills and Embryonic Zebrafish Have Different Toxicity Profiles in terms of Morphometrics, Behavior and Gene Expression, 175 AQUATIC TOXICOLOGY 160-70 (2016); Liu et al., The Thyroid -Disrupting Effects of Long -Term Perfluorononanoate Exposure on Zebrafish (Danio rerio), 20 ECOTOxICOLOGY 47-55 (2011); Chen et al., Multigenerational Disruption of the Thyroid Endocrine System in Marine Medaka after a Life -Cycle Exposure to Perfluorobutanesulfonate, 52 ENVT SCI. & TECH. 4432-39 (2018); Rotondo et al., Environmental Doses of Perfluorooctanoic Acid Change the Expression of Genes in Target Tissues of Common Carp, 37 ENVT TOXICOLOGY & CHEM. 942-48 (2018). 41 Ankley et al., Partial Life -Cycle Toxicity and Bioconcentration Modeling of Perfluorooctanesulfonate in the Northern Leopard Frog (Rana Pipiens), 23 ENv'T TOXICOLOGY & CHEM. 2745 (2004); Cheng et al., Thyroid Disruption Effects of Environmental Level Perfluorooctane Sulfonates (PFOS) in Xenopus Laevis, 20 ECOTOXICOLOGY 2069-78 (2011); Lou et al., Effects of Perfluorooctanesulfonate and Perfluorobutanesulfonate on the Growth and Sexual Development of Xenopus Laevis, 22 ECOTOXICOLOGY 1133-44 (2013). 42 Guillette et al., Blood Concentrations of Per- and Polyfluoroalkyl Substances are Associated with Autoimmune- like Effects in American Alligators from Wilmington, North Carolina, FRONTIER TOXICOLOGY 4:1010185 (Oct. 20, 2022). 41 Liu et al., Oxidative Toxicity of Perfluorinated Chemicals in Green Mussel and Bioaccumulation Factor Dependent Quantitative Structure -Activity Relationship, 33 ENVT TOXICOLOGY & CHEM. 2323-32 (2014); Liu et al., Immunotoxicity in Green Mussels under Perfluoroalkyl Substance (PEAS) Exposure: Reversible Response and Response Model Development, 37 ENVT TOXICOLOGY & CHEM. 1138-45 (2018). 44 Houde et al., Endocrine -Disruption Potential of Perfluoroethylcyclohexane Su fonate (PFECHS) in Chronically Exposed Daphnia Magna, 218 ENVT T POLLUTION 950-56 (2016); Liang et al., Effects of Perfluorooctane Sulfonate on Immobilization, Heartbeat, Reproductive and Biochemical Performance of Daphnia Magna, 168 CHEMOSPHERE 1613-18 (2017); Ji et al., Oxicity of Perfluorooctane Sulfonic Acid and Perfluorooctanoic Acid on Freshwater Macroinvertebrates (Daphnia Magna and Moina Macrocopa) and Fish (Oryzias Latipes), 27 ENVT TOXICOLOGY & CHEM. 2159 (2008); MacDonald et al., Toxicity of Perfluorooctane Sulfonic Acid and Perfluorooctanoic Acid to Chironomus Tentans, 23 ENVT TOXICOLOGY & CHEM. 2116 (2004). 45 See supra notes 40-44. 46 See Basic PFAS Info, supra note 29 (listing paper and packaging as known applications); Nate Seltenrich, PFAS in Food Packaging: A Hot, Greasy Exposure, 128 Envtl. Health Perspectives 054002-1 (2020) (Attachment C); see also Org. for Econ. Cooperation and Dev., Synthesis Paper on Per -and Polyfluorinated Chemicals (PFCs) (2013) (Attachment C) (listing paper and packaging among major uses of PFAS). 41 See Xenia Trier et al., PFAS in Paper and Board for Food Contact: Options for Risk Management of Poly -and Perfluorinated Substances, (Nordic Council of Ministers 2018) (Attachment C); Gregory Glenn et al., Per -and Polyfluoroalkyl Substances and their Alternatives in Paper Food Packaging, Comprehensive Reviews in Food Sci. and Food Safety (2021) (Attachment C) ("PFAS chemicals tend to coat the surfaces of fibers, including fibers located internally when internal sizing containing PFAS is used such as with molded pulp paper packaging."). 48 See supra note 45; Andrew B. Lindstrom, Mark J. Strynar, and E. Laurence Libelo, Polyfluorinated Compounds: Past, Present, and Future, 45 Envtl. Sci. & Tech. 7954 (2011) (Attachment C). N. recovery operations to the paper machines themselves.49 EPA recognized in its PFAS Action Plan that "pulp and paper" was among the point -source dischargers "likely to be discharging PFAS in their wastewater" and prioritized the industry for detailed study." It is possible —if not likely —that that PFAS are present in Blue Ridge Paper's landfills and may be present in the landfill leachate which is processed through the WWTP. In our comments on the 2022 NPDES permit renewal for Blue Ridge Paper, we informed DEQ that PFAS had been found in seeps from the landfills.51 DEQ responded that it would "work with [the Division of Waste Management] to address the issue" but we are unaware of any steps taken to address this problem.52 DEQ has also previously explained that influent to the WWTP from the Town of Canton "might contain some PFAS."53 DEQ must require Blue Ridge Paper to submit a full accounting of the pollutants present in the WWTP's influent —including PFAS—before it can process this major modification request. Moreover, this information must be incorporated into the permit application itself because the public relies on the information submitted in the publicly available application to participate in the permitting process. 54 Finally, we encourage DEQ to incorporate a permit condition making clear that Blue Ridge Paper does not have permission to discharge PFAS. The South Carolina Department of Health and Environmental Control has incorporated such language in permits. For example, the permit issued to Inman Mills's Ramey Plant states that the "permittee acknowledges the permit shield only applies where the discharge of pollutants are adequately disclosed and within the reasonable contemplation of the permitting authority at the time the permit was issued."55 The Tennessee Department of Environment and Conservation has included similar language in permits providing that the "permittee has no permit shield for the discharge of PFAS compounds because no such chemicals were disclosed in the permit application or otherwise under TCA 69- 3-108(Vy,56 Here, DEQ should make clear that Blue Ridge Paper may not discharge PFAS and other pollutants which are not disclosed in its NPDES permit application. " See Leon Magdzinski, Fluoropolymer Use in the Pulp and Paper Industry, CORROSION 99 (1999) (noting "fluoropolymer have become ubiquitous in the pulp and paper industry"); Rainer Lohmann et al., Are Fluoropolymers Really of Low Concern for Human and Environmental Health and Separate from Other PFAS?, 54 Envtl. Sci. & Tech. 12,820 (2020) (Attachment C). 51 U.S. Envtl. Protection Agency, EPA's Per- and Polyfluoroalkyl Substances (PFAS) Action Plan (2019), https:// www. epa. gov/sites/production/files/2019-02/documents/pfas_action_plan_021319_508compliant_ 1.pdf 51 See supra note 1 at 43-45. 52 Response to Comments, 10. 53 Id. at 9. 54 See 15A N.C. Admin. Code 2H.0109, 2H.0115. 55 Inman Mills Ramey Plant, NPDES Permit No. SC0002496 (April 28, 2021). 56 Holliston Holdings, LLC, NPDES Permit No. TN0002330 (January 30, 2020). 9 IV. DEQ must evaluate and impose technology -based effluent requirements. The absence of information regarding pollutants in the WWTP's influent leads to another legal error: DEQ's abdication of its responsibility to impose technology -based effluent limits in the draft permit. One of the primary functions of the Clean Water Act is that is prohibits the discharge of pollutants without a permit which, in turn, must include limits on pollutant discharges. These limits are required to get stricter over time ultimately phasing out pollutant discharges in order to accomplish "the national goal that the discharge of pollutants into the navigable waters be eliminated."57 NPDES permits include two primary types of pollutant limits: technology -based effluent limits and water quality -based effluent limits (discussed more below). DEQ may only issue a NPDES permit if it assures compliance with all technology -based and water -quality -based effluent limits.58 Technology -based limits set the minimum level of control required in every NPDES permit.59 A permittee must implement technology -based limits, even if doing so goes beyond the level necessary to meet water quality standards.60 However, if technology -based limits are insufficient to meet water quality standards, dischargers must implement additional limits —water quality -based effluent limitsto ensure compliance with water quality standards.61 Technology -based limits are derived from one of two sources: (1) national effluent limitation guidelines ("ELGs") issued by EPA for various industries,62 or (2) case -by -case determinations using the "best professional judgment" ("BPJ") of permit writers when EPA has not issued an ELG specific to industry discharges.63 When EPA has promulgated ELGs but they only apply to certain pollutants or activities, other pollutants or activities "are subject to regulation on a case -by -case basis" using BPJ as well.64 North Carolina rules also require technology -based limits, and in the absence of a promulgated ELG, direct agency staff to calculate a limit using EPA development documents and other available information.65 Whether establishing limits using ELGs or BPJ, the fact sheet that accompanies the draft permit reveals that DEQ made virtually no effort to develop and impose technology -based 57 33 U.S.C. § 1251(a)(1). 5133 U.S.C. § 1342(a)(1)(A); 40 C.F.R. § 122.43(a). 59 40 C.F.R. § 125.3(a). 60 U.S. Envtl. Protection Agency, NPDES Permit Writers' Manual at § 5.1 (2010) [hereinafter "Permit Writers' Manual"], https://www.epa.gov/sites/production/files/2015-09/documents/pwm_2010.pdf. 61 Id. 62 33 U.S.C. § 1314(b). 63 See 33 U.S.C. § 1342(a)(1)(B); 40 C.F.R. § 125.3(c)(2). 64 40 C.F.R. § 125.3(c)(3). 65 See 15A N.C. Admin. Code 0213.0406(b)(3). 10 limits.66 This is unlawful. The Clean Water Act requires DEQ to assess and impose technology - based effluent limits. We raised similar concerns in comments on the 2021 draft NPDES permit for Blue Ridge Paper. There, DEQ justified its refusal to impose technology -based limits by explaining that limits "for all parameters of concern are not necessary ... to ensure that the pollutants are adequately controlled because many of the pollutants originate from similar sources, have similar treatabilities, and are removed by similar mechanisms. Because of this, it may be sufficient to establish effluent limits for one pollutant as a surrogate or indicator pollutant that ensures the removal of other pollutants of concern."67 The Clean Water Act leaves no room for this approach as implemented by DEQ. In any event, DEQ has made no effort to establish that the few limits it includes in the draft permit —for fecal coliform, total suspended solids, and biological oxygen demand —are "surrogates" for technology -based controls of other pollutants. It may not justify its failure to impose technology -based limits in the draft modified permit using the same (inadequate) justification it used for the final 2022 NPDES permit. V. DEQ's assessment of water quality -based effluent limits is unlawful. Instead of imposing technology -based limits, DEQ jumps directly to evaluating the need for water quality -based limits. Water quality -based limits are only required if technology -based limits are insufficient to meet water quality standards.61 In other words, the Clean Water Act requires DEQ to impose technology -based standards first and impose water quality -based limits subsequently, only if the technology -based limits are insufficient to ensure compliance with water quality standards. DEQ must go back, impose technology -based standards and then evaluate whether water quality -based standards are necessary. Unfortunately, DEQ's attempt to develop water quality -based limits also falls short. DEQ evaluated the need for those limits purportedly by "conduct[ing] EPA -recommended analyses to determine the reasonable potential for toxicants to be discharged at levels exceeding water quality standards/EPA criteria."69 DEQ explains that it used the "discharge data on the EPA Form 2C and DMR reports" to complete this analysis which "indicate[d] no reasonable potential to violate the surface water quality standards or EPA criteria."70 These representations are borderline misleading. First, DEQ states that it used EPA Form 2C to complete this analysis but the portion of that form with pollutant level data is blank. It includes no data for DEQ to use when performing a reasonable potential analysis. Second, for most constituents DEQ completed its reasonable potential analysis with a single data point. DEQ cannot complete a defensible reasonable potential analysis with such 66 The sole exceptions here may be biological oxygen demand and total suspended solids. It is unclear from the fact sheet if those limits were developed using technology -based or water quality -based standards. 67 Response to Comments, 6. 6s Id. 69 Fact Sheet, 3. 70 Id. 11 limited data. DEQ's reasonable potential analysis spreadsheet makes clear that anything less than nine data points feeds a default value into DEQ's reasonable potential equation which may not be reflective of actual water quality. Even Blue Ridge Paper seems to concede that DEQ cannot complete a reasonable potential analysis with the data in hand. Instead, it explains that it will "conduct the required testing and analysis in the applicable sections of Form 2C"—the same section DEQ claims here it used to complete its reasonable potential analysis —after the permit is issued. DEQ's approach cannot be squared with the Clean Water Act's requirements. As explained above, the first step here is to apply technology -based limits. If those limits are insufficient to protect water quality, the agency must impose water quality -based limits using a process that can detect the "reasonable potential" to violate water quality standards. This requires using actual data —not a blank Form 2C—and having enough data points to complete its analysis. Alternatively, DEQ could assess "reasonable potential" using one of the qualitative assessment processes discussed in EPA's Permit Writers' Manual.71 But its current approach — attempting to complete a quantitative reasonable potential analysis with virtually no data —is unreasonable. There are multiple other problems with DEQ's assessment of water quality -based limits. DEQ committed these same errors when developing the current permit and we incorporate our prior comments on that permit here, specifically problems raised in Sections II(C) and II(K). VI. The draft permit violates the anti -backsliding provisions of the Clean Water Act. Another effect of DEQ's failure to collect data regarding pollutants in the WWTP's influent and impose appropriate technology -based and water quality -based limits is that pollutant limits in the current permit are either reduced or abandoned in the draft permit. This violates the Clean Water Act's anti -backsliding provision which requires that "effluent limitations, standards or conditions [in a new permit] must be at least as stringent as the final effluent limitations, standards, or conditions in the previous permit" unless "the circumstances on which the previous permit was based have materially and substantially changed since the time the permit. ,12 To be sure, Blue Ridge Paper may be able to meet this standard based on changed circumstances but as explained above —it has yet to provide information necessary to determine what any new permit limits should be. Until Blue Ridge Paper provides information showing that circumstances have "materially and substantially changed" in a way that justifies new permit limits —and provides sufficient information to enable DEQ to calculate those limits —the limits in the existing permit cannot be removed without violating anti -backsliding requirements. VII. DEQ has failed to justify the use of a mixing zone. The draft permit purports to authorize a mixing zone "defined as 0.4 miles between the diffuser and the Fiberville Bridge" but fails to justify the use of that mixing zone consistent with 71 See Permit Writers' Manual § 6.3.3. 72 40 C.F.R. § 122.44(1). 12 North Carolina regulations.73 Those regulations provide that mixing zones may be established "on a case -by -case basis after consideration of the magnitude and character of the waste discharge and the size and character of the receiving waters."74 "Mixing zones shall be designated such that discharges will not ... result in acute toxicity to aquatic life ... or prevent free passage of aquatic organisms around the mixing zone; ... result in offensive conditions; ... produce undesirable aquatic life or result in a dominance of nuisance species outside of the assigned mixing zone; or ... endanger the public health or welfare." 75 DEQ has made no effort to show those requirements are met here and we are unaware of any reason the discharge authorized in the draft permit would require a mixing zone, or at least a mixing zone of the size authorized. We raised these same concerns in comments on the last permit renewal and DEQ responded that the "mixing zone in the permit is a de facto determination of the mixing zone that existed in the permit for years."76 This is incorrect. There are no "de facto" mixing zones in North Carolina —one must be established in the permit according to North Carolina regulations or it does not exist. Even if DEQ had properly established a mixing zone in the last permit, it has provided no justification for maintaining the mixing zone in this permit. Indeed, if changes to the facility justify a major modification to permit limits, they also require revisiting the necessity of the mixing zone. VIII. DEQ may not authorize the proposed modification without an Engineering Alternatives Analysis. We commend DEQ for recognizing that an Engineering Alternatives Analysis ("EAA") is required to process this major modification request but again the agency puts the cart before the horse —this time by attempting to excuse the requirement to prepare an EAA until after DEQ has issued the permit.77 This is practically unworkable —the EAA cannot inform permit development if it is not submitted until after the permit is issued —and unlawful. EAAs provide critical information necessary to DEQ's permitting decisions including the "rationale and a demonstration of need for the projected flow volumes," "a summary of the available waste treatment and disposal options that were considered and why the proposed system and point of discharge were selected," and "a narrative description of the proposed treatment works, including type and arrangement of major components, in sufficient detail to ensure that the proposed facility has the capability to comply with the permit limits."78 Regarding groundwater remediation systems such as the one discussed briefly in Blue Ridge Paper's NPDES permit application, EAAs must "evaluate whether WWTP connection, land application, infiltration galleries, in -situ groundwater remediation wells, or closed -loop 73 Draft Permit, 8. 74 15A N.C. Admin. Code 2B.0204(b). 75 15A N.C. Admin. Code 2B.0204(b). 76 Response to Comments, 9. 77 Fact Sheet, 1. 78 15A N.C. Admin. Code 2H.0105. 13 groundwater remediation wells are viable disposal alternatives."79 Because this information is critical to permit development, EAAs must be submitted with NPDES permit applications.80 DEQ "most frequently returns [EAAs] as incomplete due to inadequate flow justification, inadequate alternatives evaluations, and/or lack of documentation/references used to design and cost alternatives."81 Here, DEQ should have returned Blue Ridge Paper's permit application as incomplete for numerous reasons including the absence of an EAA. Instead, the permit fact sheet explains that Blue Ridge Paper "is currently negotiating the sale of the property [including the WWTP] to a redevelopment company. Upon completion of the sale, the new owner would have to submit the Engineering Alternative Analysis to justify the requested flow limit."82 In other words, DEQ proposes to establish new flow and pollutants limits in this permit and then require the owner of the WWTP to subsequently prepare an EAA to justify the limits that DEQ has already imposed. This unlawfully defeats the purpose of preparing an EAA. DEQ may not issue a new permit with significant changes until that decision can be informed by an EAA as required by North Carolina law. IX. Conclusion We are eager to see the Canton mill site remediated and redeveloped and stand ready to help the town and other parties in that process. To expedite cleanup, DEQ must implement its Clean Water Act obligations without controversy. We appreciate the agency's apparent desire to move this process along but this major modification is premature because DEQ lacks the information necessary to develop permit limits consistent with state and federal law. Until Blue Ridge Paper can provide that information, the current permit should remain in place. As always, if we can answer questions about our concerns please do not hesitate to let us know. Thank you for your consideration. Sincerely, pa,� ;,YT Patrick Hunter Managing Attorney 79 DEQ, Engineering Alternatives Analysis (EAA) Guidance Document, 5 (Jan. 30, 2024). 80 15A N.C. Admin. Code 211.0105(c). 81 DEQ, Engineering Alternatives Analysis (EAA) Guidance Document, 1. 82 Fact Sheet, 1. 14