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HomeMy WebLinkAboutWQ0003396_Monitoring - 11-2023_20240806uco CERTIFIED MAIL Return Receipt Requested Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: NDMR and NDAR for Permit # WQ0003396 985 Corinth Road Moncure, North Carolina 27559 Tel: 919-642-6600 Toll Free: 855-427-2826 Fax: 919-545-5822 July 18, 2024 >�� AUG 0,6 �J�f F1P( Please find attached the 3rd Triannual Groundwater Quality Monitoring Compliance Reports 2023 (GW-59 and GW-59A) are also attached for each Groundwater Monitoring Well listed in Permit No. WQ 0003396, as well as the nearest Surface Water (Creek) down gradient to the Spray Irrigation fields. Please see the Compliance Report Form (GW-59A) for an explanation of the historical exceedances of chlorides, TDS, and pH in the wells. The facility apologizes for the delay in getting this information to the Division of Water Resources, as it was brought to our attention by the Division that the November 2023 Groundwater sampling records could not be located. Arauco would like to express our gratitude to the Division for bringing this to our attention so that we could provide the necessary information to remain in compliance following a gap in staffing and subsequent submittal oversight. If you have any questions, please contact me at savannah.carroll@arauco.com or (843) 544-3025. Sincerely, Savannah Carroll Corporate Environme tal Manager AEG 0 6 202� GW-59A COMPLIANCE REPORT FORM Permit # OQ0"73`t(v (Submit one each monitoring period with GW-59 forms-) 1 Enter date monitoring results were due. ( // 0 1 Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date(? 2 Was am required information missing on the GW-59 report forms? YES O IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are and of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES O identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Officefor guidance. 4 Are any monitored constituents equal to or above the established standards? YE NO If the answer to question 4 is "NO", skip to section B. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: S �� a-rc-v.��•+�n � 5 For the constituents identified in question 4 above, have standards been exceeded previously for the NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). 5a-*- 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES O If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES O groundwater quality problem? If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation, fines, and/or penalties. R The person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form. I hereby acknowledge that the above information was evaluated and the information submitted in this report (Compliance Report GW-59A) is trueand complete to the best of my knowledge. � Si ure of Permi e o tho ized Agent) 14 I�� Date a GW-59A 12/8/2003 Attachment A GW-59a ATTACHMENT PREVIOUS 2 YEARS Chlorides (mg/L) ' Well Limit 7/27/2021 11/17/2021 3/21/2022 7/27/2022 11/21/2022 3/7/2023 7/19/2023 11/9/2023 4/4/2024 SMW-4 250 590 640 580 610 580 536 NE 569 551 SMW-5 720 750 730 720 790 730 701 690 NT SMW-8 480 490 500 530 550 404 461 469 448 SMW-19 320 NE 340 320 NT NT NT NT NT SMW-21 270 NE 320 NE NE 532 NE NE NE TDS (mg/L) Well Limit 7/27/2021 11/17/2021 3/21/2022 7/27/2022 11/21/2022 3/7/2023 7/19/2023 11/9/2023 4/4/2024 SMW-4 500 1600 1600 1300 1100 1300 1200 1350 1190 1310 SMW-5 1700 1600 1700 1500 1600 1680 1630 1610 NT SMW-8 1100 1200 1100 1100 1200 1090 1070 1130 1040 SMW-9 560 640 710 560 630 660 624 626 650 SMW-19 830 NE 690 670 NT NT NT NT NT SMW-21 700 NE 700 560 NE 1260 1250 NE NE TOC (ms/L) Well Limit 11/8/2023 4/4/2024 SCMS 18 55.7 35.6 SMW-19 NT NT SMW-20 NE NE pH Well Limit 7/27/2021 11/17/2021 3/21/2022 7/27/2022 11/21/2022 3/7/2023 7/19/2023 11/9/2023 4/4/2024 SMW-3 6.5 - 8.5 5.06 5.96 5.42 5.7 5.54 4.7 4.86 4.7 NE SMW-4 6.45 NE NE NE NE 6.3 NE NE NE SMW-5 NE NE NE NE NE NE NE NE NT SMW-18R 5.23 5.95 5.27 5.6 5.83 4.9 5.6 5.6 5.5 SMW-19 NE NE NE NE NT NT NT NT NT SMW-20 NE NE NE NE NE NE NE NE NE SMW-21 NE NE NE NE NE NE NE NE _ NE *NT - not enough water for testing; N *NE - No exceedance SUBMIT FORM ON YELLOW PAPER ONLY • DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge WQ0003396 UIC Permit Name (if different): NPDES Other Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Moncure, NC 27555 County Chatham (state) (zip) ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 843-544-3025 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): CREEK (SCMS) Date sample collected: 11/8/2023 FIELD ANALYSES: WAS Well Depth: ft. Well Diameter: in. pH 00400: units Temp. 000lo: °C DRY at Depth to Water Level 82546: ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: µMhos time of Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR sampling, check Volume of water pumped/bailed before sampling: gallons ' Appearance ONFLUENCE OF STREAMS, FLOhere: Samples for metals were collected unfiltered: ❑ YES ElNO and field acidified: ElYES ElNO LABORATORY INFORMATION Date sample analyzed: 11/10 11/13 11/14, 11/21, 11/22 Laboratory Name: Waypoint Analytical Certification No. NC415 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 <.076 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 >2400 /100mL Phosphorus: Total as P 00665 1.83 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 248 mg/L Al - Aluminum 01105 mg/L Nitrate/Nitrite as N: mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 55.7 mg/L Ca - Calcium 00916 mg/L Chloride 00940 27.6 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 21 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3 as N, Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Jeff McMillian - Moncure Plant M Permittee (or Authorized Aqent) Name and Title - Please print or tvoe SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge WQ0003396 UIC NPDES Other Permit Name (if different): Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Moncure, NC 2755 County Chatham (state) (ZIP) ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 843-544-3025 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-3 Date sample collected: 11/9/2023 FIELD ANALYSES: WAS Well Depth: 23 ft. Well Diameter: 2 in. pH 00400: 4.7 units Temp. 000lc 18.91 °C DRY at Depth to Water Level 82546: 20 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: 600 µMhos time of Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR sampling, check Volume of water pumped/bailed before sampling: 1.5 gallons Appearance very slightly cloudy here: Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 11/10, 11/13, 11/14, 11/21, 11/22 Laboratory Name: Waypoint Analytical Certification No. NC415 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1 /100mL Nitrate (NO3) as N 00620 2.74 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <.212 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 48 mg/L Al - Aluminum 01105 mg/L Nitrate/Nitrite as N: mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 1.48 mg/L Ca - Calcium 00916 mg/L Chloride 00940 7.13 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.04 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3 as N, Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Jeff McMillian - Moncure Plant M, For Authorized Aqent) Name and Title - Please print or tvpe GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge WQ0003396 UIC NPDES Other Permit Name (if different): Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Moncure. NC 2755-_ County Chatham (state ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 843-544-3025 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-4 Date sample collected: 11/9/2023 FIELD ANALYSES: WAS Well Depth: 20 ft. Well Diameter: 2 in. pH 00400: 6.66 units Temp. 0001c 20.87 0C DRY at Depth to Water Level 82546: 17 ft. below measuring point Screened Interval: ft, to ft. Spec. Cond. 00094: 2110000 µMhos time of Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR sampling, Volume of water pumped/bailed before sampling: 1.1 gallons Appearance CLEAR check here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 11/10, 11/13, 11/14, 11/21, 11/22 Laboratory Name: Waypoint Analytical Certification No. NC415 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1 /100mL Nitrate (NO3) as N 00620 0.126 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <.212 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): Dissolved Solids:Total 70300 1190 mg/L Al - Aluminum 01105 mg/L Nitrate/Nitrite as N: mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 1.88 mg/L Ca - Calcium 00916 mg/L Chloride 00940 569 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.04 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3asN: Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Jeff McMillian - Moncure Plant Ma Permittee (or Authorized Aqent) Name and Title - Please print or type Influent Total VOCs: Totalmg/L Effluent • and that the laboratory analytical data wa ibility of fines and imprisonment for knowi on, mg/L VOC Removal% to 7/18/2024 GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge WQ0003396 UIC NPDES Other Permit Name (if different): Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery County Chatham ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 843-544-3025 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-5 Date sample collected: 11/8/2023 FIELD ANALYSES: WAS Well Depth: 20 ft. Well Diameter: 2 in. pH 00400: 7.4 units Temp. 000lc 1871 °C DRY at Depth to Water Level 82546: 10 Screened Interval: ft. to ft. Spec. Cond. 00094: 2929000 µMhos time of Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR sampling, check Volume of water pumped/bailed before sampling: 4.9 gallons Appearance CLEAR here: Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ElNO LABORATORY INFORMATION Date sample analyzed: 11/10 11/13 11/14, 11/21, 11/22 Laboratory Name: Waypoint Analytical Certification No. NC415 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 0.105 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <.212 mg/L (Note Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 1610 mg/L Al - Aluminum 01105 mg/L Nitrate/Nitrite as IN: mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 1.81 mg/L Ca - Calcium 00916 mg/L Chloride 00940 690 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 tiMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <.040 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3 as N, Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% vVv ov IV- U-V I SUBMIT FORM ON YELLOW PAPER ONLY �, DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919.807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge WQ0003396 UIC NPDES Other Permit Name (if different). Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED County Chatham ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 843-544-3025 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-8 Date sample collected: 11/8/2023 FIELD ANALYSES: WAS Well Depth: 23 ft. Well Diameter: 2 in. pH 00400: 7.1 units Temp. 000ic 1114 °C DRY at Depth to Water Level 82546: 10 Screened Interval: ft. to ft. Spec. Cond. 00094: 2105000 µMhos time of Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR sampling, check Volume of water pumped/bailed before sampling: 6 gallons Appearance CLEAR here: Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 11/10 11/13, 11/14, 11121, 11122 Laboratory Name: Waypoint Analytical Certification No. NC415 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1 /100mL Nitrate (NO3) as N 00620 <.076 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <.212 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 1130 mg/L Al - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 1.04 mg/L Ca - Calcium 00916 mg/L Chloride 00940 469 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.04 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen: NH3 as N: Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Jeff McMillian - Moncure Plant Manager Permittee (or Authorized Aqent) Name and Title - Please print or type Signature/611Perm ittee (or Authorized Aqent) to 7/18/2024 GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge WQ0003396 UIC NPDES Other Permit Name (if different): Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery 0.4orcure, NC 2755s County Chatham ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 843-544-3025 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-9 Date sample collected: 11/9/2023 FIELD ANALYSES: WAS Well Depth: 22 ft. Well Diameter: 2 in. pH 00400: 6.41 units Temp. 000lc 161 °C DRY at Depth to Water Level 82546: 9.2 ft Screened Interval: ft. to ft. Spec. Cond. 00094: 1131000 µMhos time of Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR sampling, check Volume of water pumped/bailed before sampling: 6.38 gallons Appearance CLEAR here: Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ElNO LABORATORY INFORMATION Date sample analyzed: 11/10 11/13, 11/14 11121, 11/22 Laboratory Name: Waypoint Analytical Certification No. NC415 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1 /100mL Nitrate (NO3) as N 00620 <.076 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <.212 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 626 mg/L Al - Aluminum 01105 mg/L Nitrate/Nitrite as N: mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 2.36 mg/L Ca - Calcium 00916 mg/L Chloride oo94o 192 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.04 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen. NH3 as N. Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge WQ0003396 UIC NPDES Other Permit Name (if different): Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Moncure, NC 27559 County Chatham State ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 843-544-3025 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-18R Date sample collected: 11/9/2023 FIELD ANALYSES: WAS Well Depth: 21 ft. Well Diameter: 2 in. pH 00400: 5.6 units Temp. 000lc 19,46 °C DRY at Depth to Water Level 82546: 11 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: 6600 µMhos time of Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR sampling, Volume of water pumped/bailed before sampling: 4.8 gallons very slightly cloudy_check Appearance ry g y here: Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ElYES ❑ NO LABORATORY INFORMATION Date sample analyzed: 11/10, 11/13, 11/14, 11/21, 11/22 Laboratory Name: Waypoint Analytical Certification No. NC415 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1 /100mL Nitrate (NO3) as N 00620 0.077 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.212 mg/L (Note. Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 70 mg/L Al - Aluminum 01105 mg/L Nitrate/Nitrite as N: mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 1.02 mg/L Ca - Calcium 00916 mg/L Chloride 00940 12.1 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <.040 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3 as N, Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Jeff McMillian - Moncure Plant Manager Permittee (or Authorized Agent) Name and Title - Please print or type (or Authorized Aqent) (Date) 7/18/2024 GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY , DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES •INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge WQ0003396 UIC NPDES Other Permit Name (if different): Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Moncure. NC 27559 County Chatham (state ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 843-544-3025 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-19 Date sample collected: 11/8/2023 FIELD ANALYSES: WAS Well Depth: 16 ft. Well Diameter: 2 in. pH 00400: 6.8 units Temp. 000lc 172 °C DRY at Depth to Water Level 82546. 13 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: 1302000 µMhos time of Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR sampling, check Volume of water pumped/bailed before sampling: 2.1 gallons Appearance LIGHT YELLOW BROWN, SILTY here: El Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: Laboratory Name: Certification No PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 mg/L (NoteUse MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): Dissolved Solids:Total 70300 mg/L Al - Aluminum 01105 mg/L Nitrate/Nitrite as N: pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 mg/L Ca - Calcium 00916 mg/L NO SAMPLE Chloride oo94o mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen. NH3 as N, Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Jeff McMillian - Moncure Plant Manager Permittee (or Authorized Aqent) Name and Title - Please print or type UVV-59 Kev.8/1UIJ SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge WQ0003396 UIC NPDES Other Permit Name (if different): Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED Moncure, NC 2755; County Chatham ❑ Lagoon ❑ Remediation: Infiltration Gallery (City) (state) (zip) ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 843-544-3025 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-20 Date sample collected: 11/9/2023 FIELD ANALYSES: WAS Well Depth: 43 ft. Well Diameter: 2 in. pH 00400: units Temp. 000lo: °C DRY at Depth to Water Level 82546: ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: µMhos time of Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR sampling, check Volume of water pumped/bailed before sampling: gallons Appearance CLEAR here: Samples for metals were collected unfiltered: ❑ YES El NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 11/09, 11/13, 11/14, 11120 Laboratory Name: Waypoint Analytical Certification No. NC415 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1 /100mL Nitrate (NO3) as N 00620 <.076 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <.212 mg/L (Note. Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): Dissolved Solids:Total 70300 432 mg/L Al - Aluminum 01105 mg/L Nitrate/Nitrite as N: mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 2.24 mg/L Ca - Calcium 00916 mg/L Chloride 00940 127 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 0.133 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen. NH, as N, Ammonia Nitrogen. Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES- INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge WQ0003396 UIC NPDES Other Permit Name (if different): Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery County Chatham ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 843-544-3025 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-21 Date sample collected: 11/9/2023 FIELD ANALYSES: WAS Well Depth: 16 ft. Well Diameter: 2 in. pH 00400. 6.9 units Temp. 000lc 16.83 °C DRY at Depth to Water Level 82546: 12 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: 679000 µMhos time of Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR sampling, check Volume of water pumped/bailed before sampling: 2.256 gallons Appearance Cloud y here: Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO Dry LABORATORY INFORMATION Date sample analyzed: 11/10, 11/13, 11/14, 11121, 11122 Laboratory Name: Waypoint Analytical Certification No NC415 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1 /100ml- Nitrate (NO3) as N 00620 0.391 mg/L Zn - Zinc 01092 mg/L Coliform: IMF Total 31504 /100mL Phosphorus: Total as P 00665 1.02 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 318 mg/L Al - Aluminum 01105 mg/L Nitrate/Nitrite as N: mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 5.42 mg/L Ca - Calcium 00916 mg/L Chloride 00940 117 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <.04 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH, as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Jeff McMillian - Moncure Plant Man Permittee (or Authorized Aqent) Name and Title - Please print or type or Authorized Agent) (Date) 7/18/2024 GW-59 Rev.8/2013 FALCON ENGINEERING GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project G23014.02 Date 11/4 2023 Client Arauco Time 8am Permit No. WQ0003396 Weather 70's-sunny Sampled By CJB/SB/EB Well ID .S M \'J s Diameter Screen interval Total Depth `Z 3 -ice ft Depth to Water - �q - ft Water Column -3-• 2 x 0.16= Volume of water Purge Volume Purge Method Bailer Sample Method 2" S�Z g x3= S 9 Bailer Purge time pH Temp mS/cm �-/.q I�<<� G3 2 Sample Time ! 7 a V Comments: Sampled for: Carbon, Total Organic (TOC) Chloride (as Cl), Nitrogen, Ammonia Total (as N), Nitrogen, Nitrate Total (as N), Phosphorus, Total (as P) Solids, Total Dissolved - 180 9C, Methanal (Formaldehyde), Fecal Coliform, Volatile Compounds (GW), pH FALCON ENGINEERING GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project G23014.02 Client Arauco Permit No. WQ0003396 Date Time Weather Sampled By Well ID �j( W `7 Diameter Screen interval Total Depth 1 Je" ft Depth to Water - ' , r�, ft Water Column s 3 x 0.16= Volume of water Purge Volume Purge Method Bailer Sample Method 11/92023 8am 70's-sunny CJB/SB/EB 2' 4D g x3- �o 9 Bailer Purge time pH Temp mS/cm 1 b 9 a.- q 1011p 20 2 In7-7 3 1(',2'5- (�.C� Z�•81 Z110 Sample Time I V-3- 7 Comments: Sampled for: Carbon, Total Organic (TOC) Chloride (as Cl), Nitrogen, Ammonia Total (as N), Nitrogen, Nitrate Total (as N), Phosphorus, Total (as P) Solids, Total Dissolved - 180 °C, Methanal (Formaldehyde), Fecal Coliform, Volatile Compounds (GW), pH FALCON ENGINEERING GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Client Permit No. G23014.02 Arauco WQ0003396 Date 11/0 023 Time Sam Weather 70's-sunny Sampled By CJB/SB/EB Well ID m �J Diameter Screen interval 1� Total Depth , G� ft Depth to Water ft Water Column 1 Q, �j x 0.16= Volume of water Purge Volume Purge Method Bailer Sample Method 2" Ij 6-/�g x3= 9 Bailer Purge time pH Temp mS/cm 2 3 Sample Time ; 2 . I o Comments: Sampled for: Carbon, Total Organic (TOC) Chloride (as Cl), Nitrogen, Ammonia Total (as N), Nitrogen, Nitrate Total (as N), Phosphorus, Total (as P) Solids, Total Dissolved - 180 °C, Methanal (Formaldehyde), Fecal Coliform, Volatile Compounds (GW), pH FALCON ENGINEERING GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project G23014.02 Date 11/0f/2023 Client Arauco Time 8am Permit No. WQ0003396 Weather 70's-sunny Sampled By CJB/SB/EB Well ID Diameter 2" Screen interval Total Depth ft Depth to Water b • ft Water Column x 0.16= Volume of water g x 3 = Purge Volume CD g Purge Method Bailer Sample Method Bailer Purge time pH Temp mS/cm 1 / : 2 II��� �� ' T'� +1 r 2302- 3 /l o 5 Sample Time Comments: Sampled for: Carbon, Total Organic (TOC) Chloride (as CI), Nitrogen, Ammonia Total (as N), Nitrogen, Nitrate Total (as N), Phosphorus, Total (as P) Solids, Total Dissolved - 180 °C, Methanal (Formaldehyde), Fecal Coliform, Volatile Compounds (GW), pH FALCON ENGINEERING GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project G23014.02 Date 11/01/2023 Client Arauco Time 8am Permit No. WQ0003396 Weather 70's-sunny Sampled By CJB/SB/EB Well ID 5M tllq Diameter 2" Screen interval Total Depth -2 Z . S ft Depth to Water - d ft Water Column 3 x 0.16= Volume of water ) 2 Y g x 3= Purge Volume 38 g Purge Method Bailer Sample Method Bailer Purge time pH Temp m``S/cm 1 0 T1 3 j�At G J 1 1-7, ('1 1, 3 Sample Time t J o 3-7 r Comments: Sampled for: Carbon, Total Organic (TOC) Chloride (as Cl), Nitrogen, Ammonia Total (as N), Nitrogen, Nitrate Total (as N), Phosphorus, Total (as P) Solids, Total Dissolved - 180 °C, Methanal (Formaldehyde), Fecal Coliform, Volatile Compounds (GW), pH FALCON ENGINEERING GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project G23014.02 Date 11/N2023 Client Arauco Time 8am Permit No. WQ0003396 Weather 70's-sunny Sampled By CJB/SB/EB Well ID `gym V Diameter 2" Screen interval Total Depth 1 ft Depth to Water - ft Water Column U x 0.16= Volume of water Purge Volume Purge Method Bailer Sample Method i V g x3= 9 Bailer Purge time pH Temp mS/cm 1 �l 'T �-� d LJ 2 n(2 5,67 AZ 3 3 12 NS 3116 16146 ('6 Sample Time Comments: Sampled for: Carbon, Total Organic (TOC) Chloride (as CI), Nitrogen, Ammonia Total (as N), Nitrogen, Nitrate Total (as N), Phosphorus, Total (as P) Solids, Total Dissolved - 180 °C, Methanal (Formaldehyde), Fecal Coliform, Volatile Compounds (GW), pH FALCON ENGINEERING GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project G23014.02 Date 11/062023 Client Arauco Time 8am Permit No. WQ0003396 Weather 70's-sunny Sampled By CJB/SB/EB Well ID SMW to1 Diameter 2" Screen interval JU /5 Total Depth ,� ft Depth to Water - I'L.Cj ft Water Column x 0.16= Volume of water O, Cj 12— g x 3 - Purge Volume 1 , 53 to g Purge Method Bailer Sample Method Bailer Purge time pH Temp�l� mS/cm 1 (j I U0 (_q-S 2 3 Sample Time _� �Y 0 Sq/,lpL� Comments: Sampled for: Carbon, Total Organic (TOC) Chloride (as Cl), Nitrogen, Ammonia Total (as N), Nitrogen, Nitrate Total (as N), Phosphorus, Total (as P) Solids, Total Dissolved - 180 °C, Methanal (Formaldehyde), Fecal Coliform, Volatile Compounds (GW), pH *No rechafzC-- D" * N'0 RtcHkR�E�D�y FALCON ENGINEERING GROUNDWATER SAMPLING FIELD DATA WORKSHEET Project Client Permit No Well ID Screen interval G23014.02 Arauco W00003396 Date Time Weather Sampled By S/ " i 2—( Diameter Total Depth I &5 ft Depth to Water - H , 9 ft Water Column ��� 7 x 0.16= Volume of water Purge Volume Purge Method Bailer Sample Method 11/0�(2023 Sam 70's-sunny CJB/SB/EB NO ,71�Z g x 3 = -�), Q56 g Bailer Purge time pH Temp mS/cm 1 2:�9 CV.9 i0-7q 2 `. 2-0 3 Sample Time ��.� N Comments: Sampled for: Carbon, Total Organic (TOC) Chloride (as Cl), Nitrogen, Ammonia Total (as N), Nitrogen, Nitrate Total (as N), Phosphorus, Total (as P) Solids, Total Dissolved - 180 °C, Methanal (Formaldehyde), Fecal Coliform, Volatile Compounds (GW), pH * 0.� ?4. only ct"Jd bC fft�' -1 ALCO N ENGINEEONG November 30, 2023 Mr. Larry Durgin Arauco Environmental Manager 985 Corinth Road Moncure North Carolina 27559 Re: Arauco — Moncure WWTF November 2023 Sampling Results 985 Corinth Road Moncure North Carolina 27559 Proposal No. F2022-066 Larry: Falcon Engineering, Inc. (Falcon) is pleased to present the laboratory results of the November 2023 water sampling event. Specifically, Falcon sampled the groundwater from eight existing monitoring wells and one surface water sample point in general accordance with Arauco's Wastewater Irrigation System Permit No. WQ0003396. The laboratory sample results are attached. It should be noted that MW-19 and MW21 could not be sampled. Both wells were purged until dry and did not recharge in time to sample. We appreciate the opportunity to provide our services and look forward to working with you on this and many other future projects. If you have any questions or desire additional information about Falcon and the many ways in which we may benefit you, please contact us at 919.871.0800. Respectfully submitted: FALCON ENGINEERING, INC. Christopher J. Burkhardt Environmental Services Manager ATTACHMENTS: Laboratory Results Waypoint(l) ANALYTICAL 11 /20/2023 Falcon Engineering Christopher Burkhardt 1210 Trinity Road Suite 110 Cary, NC, 27513 Ref: Analytical Testing Lab Report Number: 23-313-0014 Client Project Description: G23014.02 Dear Christopher Burkhardt: 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Waypoint Analytical, LLC (Charlotte) received sample(s) on 11/9/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, a,j Angela D Overcash Senior Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 44 Waypoint. ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.S29.6364 www.waypointanalytical.com Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date North Carolina State Program 37735 07/31/2024 North Carolina State Program 402 12/31/2023 South Carolina State Program 99012 07/31/2024 South Carolina State Program 99012 12/31/2023 Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/29/2024 Arkansas State Program 88-0650 02/07/2024 California State Program 2904 06/30/2024 Florida State Program - NELAP E871157 06/30/2024 Georgia State Program C044 11/14/2025 Georgia State Program 04015 06/30/2024 Illinois State Program - NELAP 200078 10/31/2024 Kentucky State Program 80215 06/30/2024 Kentucky State Program KY90047 12/31/2023 Louisiana State Program - NELAP LA037 12/31/2023 Louisiana State Program - NELAP 04015 06/30/2024 Mississippi State Program MS 11/14/2025 North Carolina State Program 47701 07/31/2024 North Carolina State Program 415 12/31/2023 Pennsylvania State Program - NELAP 68-03195 05/31/2024 South Carolina State Program 84002 06/30/2024 Tennessee State Program 02027 11/14/2025 Texas State Program - NELAP T104704180 09/30/2024 Virginia State Program 00106 06/30/2024 Virginia State Program - NELAP 460181 09/14/2024 Page 1 of 1 00016/23-313-0014 Page 2 of 44 0 Waypoint. 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 23-313-0014 Client Project Description: G23O14.O2 Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 99696 SW1 Aqueous 11/08/2023 11:16 11/09/2023 13:30 99696 SW1 Aqueous 11/08/2023 11:16 11/09/2023 13:30 365.4 WP MTN 99696 SW1 Aqueous 11/08/2023 11:16 11/09/2023 13:30 4500NH3D-2011 WP MTN 99696 SW1 Aqueous 11/08/2023 11:16 11/09/2023 13:30 5310C-2011 WP MTN 99696 SW1 Aqueous 11/08/2023 11:16 11/09/2023 13:30 8315A WP MTN 99697 SMW20 Aqueous 11/08/2023 11:45 11/09/2023 13:30 99697 SMW20 Aqueous 11/08/2023 11:45 11/09/2023 13:30 8315A WP MTN 99697 SMW20 Aqueous 11/08/2023 11:45 11/09/2023 13:30 5310C-2011 WP MTN 99697 SMW20 Aqueous 11/08/2023 11:45 11/09/2023 13:30 4500NH3D-2011 WP MTN 99697 SMW20 Aqueous 11/08/2023 11:45 11/09/2023 13:30 365.4 WP MTN 99698 SMW5 Aqueous 11/08/2023 12:10 11/09/2023 13:30 99698 SMW5 Aqueous 11/08/2023 12:10 11/09/2023 13:30 4500NH3D-2011 WP MTN 99698 SMW5 Aqueous 11/08/2023 12:10 11/09/2023 13:30 365.4 WP MTN 99698 SMW5 Aqueous 11/08/2023 12:10 11/09/2023 13:30 5310C-2011 WP MTN 99698 SMW5 Aqueous 11/08/2023 12:10 11/09/2023 13:30 8315A WP MTN 99699 SMW8 Aqueous 11/08/2023 12:29 11/09/2023 13:30 99699 SMW8 Aqueous 11/08/2023 12:29 11/09/2023 13:30 5310C-2011 WP MTN 99699 SMW8 Aqueous 11/08/2023 12:29 11/09/2023 13:30 4500NH3D-2011 WP MTN 99699 SMW8 Aqueous 11/08/2023 12:29 11/09/2023 13:30 365.4 WP MTN 99699 SMW8 Aqueous 11/08/2023 12:29 11/09/2023 13:30 8315A WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 3 of 44 Waypoint(2) ANALYTICAL Client: Falcon Engineering Project: G23014.02 Lab Report Number: 23-313-0014 Date: 11 /20/2023 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com CASE NARRATIVE Anions by Ion Chromatography Method 300.0 Sample 99680 (Effluent 1) Analyte: Nitrate-N QC Batch No: V40210/V40106 The MS/MSD recoveries are outside QC limits due to the level of analyte present in the parent sample relative to the spike level. RPD is based on the MS/MSD results and should be evaluated as laboratory duplicates. Volatile Organic Compounds - GC/MS Method 8260D Analyte: Acetone QC Batch No: V40208/V40139 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Page 4 of 44 • Poi nt . 449 Springbrook Rd, Ch(2) arlotte, NC 28217 Way Main 704.529.6364 ANALYTICAL www.waypointanatocal.com 00122 Falcon Engineering Project G23014.02 Christopher Burkhardt Report Date : 11/20/2023 1210 Trinity Road Information : Received : 11/09/2023 Suite 110 Cary , NC 27513 Report Number : 23-313-0014 REPORTOFANALYSIS Lab No : 99696 Sample ID: SW1 Matrix: Aqueous Sampled: 11/8/2023 11:16 Test Results Units MDL MOL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen 21.0 mg/L 0.200 0.500 1 11/20/23 11:24 JFM 4500NH3D-2011 Chloride 27.6 mg/L 0.370 1.00 1 11/09/2317:01 NDL 300.0 Nitrate (NO3-N) <0.076 mg/L 0.076 0.200 1 11/09/23 17:01 NDL 300.0 Total Dissolved Solids 248 mg/L 36 50 1 11/13/23 11:32 RLW 254OC-2015 Phosphorus 1.833 mg/L 1.06 2.50 1 11/20/23 13:55 ANH 365.4 TOC 55.7 mg/L 6.82 10.0 10 11/14/2316:12 ELM 531OC-2011 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 5 of 44 Waypoint.0 ANALYTICAL 00122 Falcon Engineering Project Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-313-0014 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com G23014.02 REPORT OFANAL YSIS Report Date : 11/20/2023 Received : 11/09/2023 Lab No : 99696 Matrix: Aqueous Sample ID: SWi Sampled: 11/8/2023 11:16 Analytical Method: 8260D Prep Batch(es): V40139 11/10/23 14:00 Prep Method: 5030B Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 35.7 N9/L 1.80 5.00 1 11/11/23 06:41 MSA V40140 Acrolein <2.00 Ng/L 2.00 5.00 1 11/11/23 06:41 MSA V40140 Acrylonitrile <0.230 Ng/L 0.230 5.00 1 11/11/23 06:41 MSA V40140 Benzene <0.180 Ng/L 0.180 0.500 1 11/11/23 06:41 MSA V40140 Bromobenzene <0.210 Ng/L 0.210 0.500 1 11/11/23 06:41 MSA V40140 Bromochloromethane <0.420 ug/L 0.420 1.00 1 11/11/23 06:41 MSA V40140 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 11/11/23 06:41 MSA V40140 Bromoform <1.50 ug/L 1.50 5.00 1 11/11/23 06:41 MSA V40140 Bromomethane <0.280 Ng/L 0.280 1.00 1 11/11/23 06:41 MSA V40140 n-Butylbenzene <0.185 Ng/L 0.185 1.00 1 11/11/23 06:41 MSA V40140 sec -Butyl benzene <0.200 ug/L 0.200 0.500 1 11/11/23 06:41 MSA V40140 tert-Butyl benzene <0.920 Ng/L 0.920 2.00 1 11/11/23 06:41 MSA V40140 Carbon Disulfide <0.150 Ng/L 0.150 5.00 1 11/11/23 06:41 MSA V40140 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 11/11/23 06:41 MSA V40140 Chlorobenzene <0.190 ug/L 0.190 0.500 1 11/11/23 06:41 MSA V40140 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 11/11/23 06:41 MSA V40140 Chloroethane <0.430 Ng/L 0.430 1.00 1 11/11/23 06:41 MSA V40140 Chloroform <0.220 pg/L 0.220 0.500 1 11/11/23 06:41 MSA V40140 Chloromethane <0.220 N9/L 0.220 0.500 1 11/11/23 06:41 MSA V40140 2-Chlorotoluene <0.200 N9/L 0.200 0.500 1 11/11/23 06:41 MSA V40140 4-Chlorotoluene <0.200 Ng/L 0.200 0.500 1 11/11/23 06:41 MSA V40140 Di -Isopropyl Ether (DIPE) <0.960 Ug/L 0.960 5.00 1 11/11/23 06:41 MSA V40140 Qualifiers/ DF Dilution Factor ] Estimated value Definitions MQL Method Quantitation Limit Page 6 of 44 (2) • Poi nt . 449 Springbrook Rd, Charlotte, NC 28217 Way Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 00122 Falcon Engineering Project G23014.02 Christopher Burkhardt Report Date : 11/20/2023 1210 Trinity Road Information : Received : 11/09/2023 Suite 110 Cary , NC 27513 Report Number: 23-313-0014 REPORT OPANALYSIS Lab No : 99696 Sample ID: SW1 Matrix: Aqueous Sampled: 11/8/2023 11:16 Analytical Method: 8260D Prep Batch(es): V40139 11/10/23 14:00 Prep Method: 5030E Test Results Units MDL MOIL DF Date / Time By Analytical Analyzed Batch 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 11/11/23 06:41 MSA V40140 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 11/11/23 06:41 MSA V40140 Dibromomethane <0.230 ug/L 0.230 0.500 1 11/11/23 06:41 MSA V40140 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 11/11/23 06:41 MSA V40140 1,3-Dichlorobenzene <0.190 ug/L 0.190 0.500 1 11/11/23 06:41 MSA V40140 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 11/11/23 06:41 MSA V40140 Dichlorodifluoromethane <1.20 Ng/L 1.20 5.00 1 11/11/23 06:41 MSA V40140 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 11/11/23 06:41 MSA V40140 1,2-Dichloroethane <0.150 Ng/L 0.150 0.500 1 11/11/23 06:41 MSA V40140 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 11/11/23 06:41 MSA V40140 cis-1,2-Dichloroethene <0.200 Ng/L 0.200 0.500 1 11/11/23 06:41 MSA V40140 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 11/11/23 06:41 MSA V40140 1,2-Dichloropropane <0.190 Ng/L 0.190 0.500 1 11/11/23 06:41 MSA V40140 1,3-Dichloropropane <0.130 Ng/L 0.130 0.500 1 11/11/23 06:41 MSA V40140 2,2-Dichloropropane <0.210 ug/L 0.210 2.00 1 11/11/23 06:41 MSA V40140 1,1-Dichloropropene <0.200 Ng/L 0.200 0.500 1 11/11/23 06:41 MSA V40140 cis- 1,3-Dichloropropene <0.210 Ng/L 0.210 0.500 1 11/11/23 06:41 MSA V40140 trans- 1,3-Dichloropropene <0.150 Ng/L 0.150 0.500 1 11/11/23 06:41 MSA V40140 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 11/11/23 06:41 MSA V40140 Ethyl Tertiary Butyl Ether (ETBE) <1.80 Ng/L 1.80 10.0 1 11/11/23 06:41 MSA V40140 Hexachlorobutadiene <0.350 ug/L 0.350 2.00 1 11/11/23 06:41 MSA V40140 n-Hexane <1.30 Ng/L 1.30 10.0 1 11/11/23 06:41 MSA V40140 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 7 of 44 WayPAoint. NALYTICAL 00122 Falcon Engineering Project Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-313-0014 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com G23014.02 REPORT OFANAL PSIS Report Date : 11/20/2023 Received : 11/09/2023 Lab No : 99696 Matrix: Aqueous Sample ID: SW1 Sampled: 11/8/2023 11:16 Analytical Method: 8260D Prep Batch(es): V40139 11/10/23 14:00 Prep Method: 5030E Test Results Units MDL MOL DF Date / Time By Analytical Analyzed Batch 2-Hexanone 6.66 ug/L 0.380 5.00 1 11/11/23 06:41 MSA V40140 Isopropylbenzene <0.180 ug/L 0.180 5.00 1 11/11/23 06:41 MSA V40140 4-Isopropyl toluene 0.3681 ug/L 0.089 0.500 1 11/11/23 06:41 MSA V40140 Methyl Ethyl Ketone (MEK) 8.38 ug/L 0.710 5.00 1 11/11/23 06:41 MSA V40140 Methyl tert-butyl ether (MTBE) <0.140 ug/L 0.140 0.500 1 11/11/23 06:41 MSA V40140 4-Methyl-2-Pentanone <1.00 Ng/L 1.00 5.00 1 11/11/23 06:41 MSA V40140 Methylene Chloride <0.330 ug/L 0.330 1.00 1 11/11/23 06:41 MSA V40140 Naphthalene <0.470 Ng/L 0.470 1.00 1 11/11/23 06:41 MSA V40140 n-Propylbenzene <0.190 Ng/L 0.190 0.500 1 11/11/23 06:41 MSA V40140 Styrene <0.220 ug/L 0.220 0.500 1 11/11/23 06:41 MSA V40140 1, 1, 1,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 11/11/23 06:41 MSA V40140 1,1,2,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 11/11/23 06:41 MSA V40140 Tetrachloroethene <0.220 ug/L 0.220 0.500 1 11/11/23 06:41 MSA V40140 Toluene 3.46 ug/L 0.220 0.500 1 11/11/23 06:41 MSA V40140 1,2,3-Trichlorobenzene <0.380 Ng/L 0.380 2.00 1 11/11/23 06:41 MSA V40140 1,2,4-Trichlorobenzene <0.310 Ng/L 0.310 1.00 1 11/11/23 06:41 MSA V40140 1, 1, 1-Trichloroethane <0.160 Ng/L 0.160 0.500 1 11/11/23 06:41 MSA V40140 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 11/11/23 06:41 MSA V40140 Trichloroethene <0.180 Ng/L 0.180 0.500 1 11/11/23 06:41 MSA V40140 Trichlorofluoromethane <0.180 Ng/L 0.180 0.500 1 11/11/23 06:41 MSA V40140 1,2,3-Trichloropropane <0.270 Ng/L 0.270 1.00 1 11/11/23 06:41 MSA V40140 1,3,5-Trimethylbenzene <0.180 Ng/L 0.180 0.500 1 11/11/23 06:41 MSA V40140 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 8 of 44 • Po� nt . 449 Springbrook Rd, Ch(D arlotte, NC 28217 Way Main 704.529.6364 A N A LYT I CAL www.waypointanalytical.com 00122 Falcon Engineering Project G23014.02 Christopher Burkhardt Report Date : 11/20/2023 1210 Trinity Road Information : Received : 11/09/2023 Suite 110 Cary , NC 27513 Report Number : 23-313-0014 Lab No : 99696 Sample ID: SW1 REPORT OFANAL YSIS Matrix: Aqueous Sampled: 11/8/2023 11:16 Analytical Method: 8260D Prep Batch(es): V40139 11/10/23 14:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Vinyl Acetate <1.00 pg/L 1.00 2.00 1 11/11/23 06:41 MSA V40140 Vinyl Chloride <0.170 pg/L 0.170 0.500 1 11/11/23 06:41 MSA V40140 o-Xylene <0.210 pg/L 0.210 0.500 1 11/11/23 06:41 MSA V40140 m,p-Xylene <0.420 pg/L 0.420 1.00 1 11/11/23 06:41 MSA V40140 Xylene (Total) <0.21 pg/L 0.210 0.500 1 11/11/23 06:41 V40140 Surrogate: 4-Bromofluorobenzene 99.6 Limits: 80-124% 1 11/11/23 06:41 MSA V40140 Surrogate: Dibromofluoromethane 97.2 Limits: 75-129% 1 11/11/23 06:41 MSA V40140 Surrogate: 1,2-Dichloroethane - d4 94.8 Limits: 63-136% 1 11/11/23 06:41 MSA V40140 Surrogate: Toluene-d8 96.6 Limits: 77-123% 1 11/11/23 06:41 MSA V40140 Analytical Method: 8315A Prep Batch(es): L716464 11/11/23 14:15 Prep Method: 8315A Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Formaldehyde 9620 pg/L 10.0 10.0 1 11/11/23 20:54 KDL L716755 Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit J Estimated value Page 9 of 44 • Poi nt . 449 Springbrook Rd, Ch(D arlotte, NC 28217 Way Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 00122 Falcon Engineering Project G23014.02 Christopher Burkhardt Report Date : 11/20/2023 1210 Trinity Road Information : Received : 11/09/2023 Suite 110 Cary , NC 27513 Report Number :23-313-0014 REPORT OFANAL YSIS Lab No : 99697 Sample ID: SMW20 Matrix: Aqueous Sampled: 11/8/2023 11:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen 0.133 mg/L 0.040 0.100 1 11/20/23 11:24 JFM 4500NH3D-2011 Chloride 127 mg/L 0.370 1.00 1 11/09/2317:14 NDL 300.0 Nitrate (NO3-N) <0.076 mg/L 0.076 0.200 1 11/09/23 17:14 NDL 300.0 Total Dissolved Solids 432 mg/L 36 50 1 11/13/23 11:32 RLW 2540C-2015 Phosphorus <0.212 mg/L 0.212 0.500 1 11/20/2313:56 ANH 365.4 TOC 2.24 mg/L 0.682 1.00 1 11/14/2316:50 ELM 531OC-2011 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 10 of 44 (D WayPAoint. NALYTICAL 00122 Falcon Engineering Project Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-313-0014 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com G23014.02 REPORT OFANALYSIS Report Date : 11/20/2023 Received : 11/09/2023 Lab No : 99697 Matrix: Aqueous Sample ID: SMW20 Sampled: 11/8/2023 11:45 Analytical Method: 8260D Prep Batch(es): V40139 11/10/23 14:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 3.233 pg/L 1.80 5.00 1 11/11/23 06:16 MSA V40140 Acrolein <2.00 pg/L 2.00 5.00 1 11/11/23 06:16 MSA V40140 Acrylonitrile <0.230 p9/L 0.230 5.00 1 11/11/23 06:16 MSA V40140 Benzene <0.180 pg/L 0.180 0.500 1 11/11/23 06:16 MSA V40140 Bromobenzene <0.210 pg/L 0.210 0.500 1 11/11/23 06:16 MSA V40140 Bromochloromethane <0.420 pg/L 0.420 1.00 1 11/11/23 06:16 MSA V40140 Bromodichloromethane <0.160 pg/L 0.160 0.500 1 11/11/23 06:16 MSA V40140 Bromoform <1.50 pg/L 1.50 5.00 1 11/11/23 06:16 MSA V40140 Bromomethane <0.280 pg/L 0.280 1.00 1 11/11/23 06:16 MSA V40140 n-Butylbenzene <0.185 pg/L 0.185 1.00 1 11/11/23 06:16 MSA V40140 sec -Butyl benzene <0.200 pg/L 0.200 0.500 1 11/11/23 06:16 MSA V40140 tert-Butyl benzene <0.920 pg/L 0.920 2.00 1 11/11/23 06:16 MSA V40140 Carbon Disulfide <0.150 pg/L 0.150 5.00 1 11/11/23 06:16 MSA V40140 Carbon Tetrachloride <0.180 p9/L 0.180 0.500 1 11/11/23 06:16 MSA V40140 Chlorobenzene <0.190 pg/L 0.190 0.500 1 11/11/23 06:16 MSA V40140 Chlorodibromomethane <0.190 pg/L 0.190 0.500 1 11/11/23 06:16 MSA V40140 Chloroethane <0.430 pg/L 0.430 1.00 1 11/11/23 06:16 MSA V40140 Chloroform <0.220 pg/L 0.220 0.500 1 11/11/23 06:16 MSA V40140 Chloromethane <0.220 pg/L 0.220 0.500 1 11/11/23 06:16 MSA V40140 2-Chlorotoluene <0.200 pg/L 0.200 0.500 1 11/11/23 06:16 MSA V40140 4-Chlorotoluene <0.200 pg/L 0.200 0.500 1 11/11/23 06:16 MSA V40140 Di -Isopropyl Ether (DIPE) <0.960 pg/L 0.960 5.00 1 11/11/23 06:16 MSA V40140 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 11 of 44 (2) WayPAoint. NALYTICAL 00122 Falcon Engineering Project Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-313-0014 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com G23014.02 REPORT OP ANAL YSIS Report Date : 11/20/2023 Received : 11/09/2023 Lab No : 99697 Sample ID: SMW20 Matrix: Aqueous Sampled: 11/8/2023 11:45 Analytical Method: 8260D Prep Batch(es): V40139 11/10/23 14:00 Prep Method: 5030E Test Results Units MDL MOL DF Date / Time By Analytical Analyzed Batch 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 11/11/23 06:16 MSA V40140 1,2-Dibromoethane <0.200 ug/L 0.200 0.500 1 11/11/23 06:16 MSA V40140 Dibromomethane <0.230 ug/L 0.230 0.500 1 11/11/23 06:16 MSA V40140 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 11/11/23 06:16 MSA V40140 1,3-Dichlorobenzene <0.190 Ng/L 0.190 0.500 1 11/11/23 06:16 MSA V40140 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 11/11/23 06:16 MSA V40140 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 11/11/23 06:16 MSA V40140 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 11/11/23 06:16 MSA V40140 1,2-Dichloroethane <0.150 Ng/L 0.150 0.500 1 11/11/23 06:16 MSA V40140 1,1-Dichloroethene <0.150 ug/L 0.150 0.500 1 11/11/23 06:16 MSA V40140 cis-1,2-Dichloroethene <0.200 ug/L 0.200 0.500 1 11/11/23 06:16 MSA V40140 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 11/11/23 06:16 MSA V40140 1,2-Dichloropropane <0.190 Ng/L 0.190 0.500 1 11/11/23 06:16 MSA V40140 1,3-Dichloropropane <0.130 ug/L 0.130 0.500 1 11/11/23 06:16 MSA V40140 2,2-Dichloropropane <0.210 ug/L 0.210 2.00 1 11/11/23 06:16 MSA V40140 1,1-Dichloropropene <0.200 Ng/L 0.200 0.500 1 11/11/23 06:16 MSA V40140 cis- 1,3-Dichloropropene <0.210 Ng/L 0.210 0.500 1 11/11/23 06:16 MSA V40140 trans- 1,3-Dichloropropene <0.150 pg/L 0.150 0.500 1 11/11/23 06:16 MSA V40140 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 11/11/23 06:16 MSA V40140 Ethyl Tertiary Butyl Ether (ETBE) <1.80 ug/L 1.80 10.0 1 11/11/23 06:16 MSA V40140 Hexachlorobutadiene <0.350 Ng/L 0.350 2.00 1 11/11/23 06:16 MSA V40140 n-Hexane <1.30 ug/L 1.30 10.0 1 11/11/23 06:16 MSA V40140 Qualifiers/ DF Dilution Factor ] Estimated value Definitions MQL Method Quantitation Limit Page 12 of 44 (D WayPAoint. NALYTICAL 00122 Falcon Engineering Project Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-313-0014 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com G23014.02 REPORT OPANALYSIS Report Date : 11/20/2023 Received : 11/09/2023 Lab No : 99697 Sample ID: SMW20 Matrix: Aqueous Sampled: 11/8/2023 11:45 Analytical Method: 8260D Prep Batch(es): V40139 11/10/23 14:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 2-Hexanone <0.380 Ng/L 0.380 5.00 1 11/11/23 06:16 MSA V40140 Isopropylbenzene <0.180 ug/L 0.180 5.00 1 11/11/23 06:16 MSA V40140 4-Isopropyl toluene <0.089 ug/L 0.089 0.500 1 11/11/23 06:16 MSA V40140 Methyl Ethyl Ketone (MEK) 4.703 Ng/L 0.710 5.00 1 11/11/23 06:16 MSA V40140 Methyl tert-butyl ether (MTBE) <0.140 u9/L 0.140 0.500 1 11/11/23 06:16 MSA V40140 4-Methyl-2-Pentanone <1.00 Ng/L 1.00 5.00 1 11/11/23 06:16 MSA V40140 Methylene Chloride <0.330 ug/L 0.330 1.00 1 11/11/23 06:16 MSA V40140 Naphthalene <0.470 Ng/L. 0.470 1.00 1 11/11/23 06:16 MSA V40140 n-Propylbenzene <0.190 Ng/L 0.190 0.500 1 11/11/23 06:16 MSA V40140 Styrene <0.220 ug/L 0.220 0.500 1 11/11/23 06:16 MSA V40140 1,1,1,2-Tetrachloroethane <0.160 u9/L 0.160 0.500 1 11/11/23 06:16 MSA V40140 1,1,2,2-Tetrachloroethane <0.160 N9/L 0.160 0.500 1 11/11/23 06:16 MSA V40140 Tetrachloroethene <0.220 Ug/L 0.220 0.500 1 11/11/23 06:16 MSA V40140 Toluene <0.220 ug/L 0.220 0.500 1 11/11/23 06:16 MSA V40140 1,2,3-Trichlorobenzene <0.380 Ng/L 0.380 2.00 1 11/11/23 06:16 MSA V40140 1,2,4-Trichlorobenzene <0.310 Ng/L 0.310 1.00 1 11/11/23 06:16 MSA V40140 1,1,1-Trichloroethane <0.160 Ng/L 0.160 0.500 1 11/11/23 06:16 MSA V40140 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 11/11/23 06:16 MSA V40140 Trichloroethene <0.180 u9/L 0.180 0.500 1 11/11/23 06:16 MSA V40140 Trichlorofluoromethane <0.180 N9/L 0.180 0.500 1 11/11/23 06:16 MSA V40140 1,2,3-Trichloropropane <0.270 Ng/L 0.270 1.00 1 11/11/23 06:16 MSA V40140 1,3,5-Trimethylbenzene <0.180 ug/L 0.180 0.500 1 11/11/23 06:16 MSA V40140 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 13 of 44 WayPAoint. NALYTICAL 00122 Falcon Engineering Christopher Burkhardt 1210 Trinity Road Suite 110 Cary , NC 27513 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Project G23014.02 Information : Report Date : 11/20/2023 Received : 11/09/2023 Report Number: 23-313-0014 Lab No: 99697 Sample ID: SMW20 REPORT OFANAL YSIS Matrix: Aqueous Sampled: 11/8/2023 11:45 Analytical Method: 8260D Prep Batch(es): V40139 11/10/23 14:00 Prep Method: 5030B Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Vinyl Acetate <1.00 pg/L 1.00 2.00 1 11/11/23 06:16 MSA V40140 Vinyl Chloride <0.170 pg/L 0.170 0.500 1 11/11/23 06:16 MSA V40140 o-Xylene <0.210 pg/L 0.210 0.500 1 11/11/23 06:16 MSA V40140 m,p-Xylene <0.420 pg/L 0.420 1.00 1 11/11/23 06:16 MSA V40140 Xylene (Total) <0.21 pg/L 0.210 0.500 1 11/11/23 06:16 V40140 Surrogate: 4-Bromofluorobenzene 103 Limits: 80-124% 1 11/11/23 06:16 MSA V40140 Surrogate: Dibromofluoromethane 97.0 Limits: 75-129% 1 11/11/23 06:16 MSA V40140 Surrogate: 1,2-Dichloroethane - d4 94.8 Limits: 63-136% 1 11/11/23 06:16 MSA V40140 Surrogate: Toluene-d8 97.4 Limits: 77-123% 1 11/11/23 06:16 MSA V40140 Analytical Method: 8315A Prep Batch(es): L716464 11/11/23 14:15 Prep Method: 8315A Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Formaldehyde <10.0 pg/L 10.0 10.0 1 11/11/23 21:04 KDL L716755 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 14 of 44 (2) WayPAoi nt . 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 NALYTICAL www.waypointanalytical.com 00122 Falcon Engineering Project G23014.02 Christopher Burkhardt Report Date : 11/20/2023 1210 Trinity Road Information : Received : 11/09/2023 Suite 110 Cary , NC 27513 Report Number : 23-313-0014 REPORT OFANAL YSIS Lab No: 99698 Sample ID: SMWS Matrix: Aqueous Sampled: 11/8/2023 12:10 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen <0.040 mg/L 0.040 0.100 1 11/20/23 11:24 JFM 4500NH3D-2011 Chloride 690 mg/L 3.70 10.0 10 11/14/23 00:38 NDL 300.0 Nitrate (NO3-N) 0.1051 mg/L 0.076 0.200 1 11/09/23 17:26 NDL 300.0 Total Dissolved Solids 1610 mg/L 36 50 1 11/13/23 11:32 RLW 2540C-2015 Phosphorus <0.212 mg/L 0.212 0.500 1 11/20/2313:57 ANH 365.4 TOC 1.81 mg/L 0.682 1.00 1 11/14/2317:28 ELM 531OC-2011 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 15 of 44 (2) WayPAoint. NALYTICAL 00122 Falcon Engineering Project Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com G23014.02 Report Number : 23-313-0014 REPORT OFANAL YSIS Report Date : 11/20/2023 Received : 11/09/2023 Lab No : 99698 Matrix: Aqueous Sample ID: SMWS Sampled: 11/8/2023 12:10 Analytical Method: 8260D Prep Batch(es): V40207 11/13/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 2.173 p9/L 1.80 5.00 1 11/13/23 15:52 MSA V40208 Acrolein <2.00 pg/L 2.00 5.00 1 11/13/23 15:52 MSA V40208 Acrylonitrile <0.230 pg/L 0.230 5.00 1 11/13/23 15:52 MSA V40208 Benzene <0.180 pg/L 0.180 0.500 1 11/13/23 15:52 MSA V40208 Bromobenzene <0.210 pg/L 0.210 0.500 1 11/13/23 15:52 MSA V40208 Bromochloromethane <0.420 pg/L 0.420 1.00 1 11/13/23 15:52 MSA V40208 Bromodichloromethane <0.160 pg/L 0.160 0.500 1 11/13/23 15:52 MSA V40208 Bromoform <1.50 pg/L 1.50 5.00 1 11/13/23 15:52 MSA V40208 Bromomethane <0.280 pg/L 0.280 1.00 1 11/13/23 15:52 MSA V40208 n-Butylbenzene <0.185 pg/L 0.185 1.00 1 11/13/23 15:52 MSA V40208 sec -Butyl benzene <0.200 pg/L 0.200 0.500 1 11/13/23 15:52 MSA V40208 tert-Butyl benzene <0.920 pg/L 0.920 2.00 1 11/13/23 15:52 MSA V40208 Carbon Disulfide <0.150 pg/L 0.150 5.00 1 11/13/23 15:52 MSA V40208 Carbon Tetrachloride <0.180 p9/L 0.180 0.500 1 11/13/23 15:52 MSA V40208 Chlorobenzene <0.190 pg/L 0.190 0.500 1 11/13/23 15:52 MSA V40208 Chlorodibromomethane <0.190 pg/L 0.190 0.500 1 11/13/23 15:52 MSA V40208 Chloroethane <0.430 pg/L 0.430 1.00 1 11/13/23 15:52 MSA V40208 Chloroform <0.220 pg/L 0.220 0.500 1 11/13/23 15:52 MSA V40208 Chloromethane <0.220 pg/L 0.220 0.500 1 11/13/2315:52 MSA V40208 2-Chlorotoluene <0.200 pg/L 0.200 0.500 1 11/13/23 15:52 MSA V40208 4-Chlorotoluene <0.200 pg/L 0.200 0.500 1 11/13/23 15:52 MSA V40208 Di -Isopropyl Ether (RIPE) <0.960 pg/L 0.960 5.00 1 11/13/23 15:52 MSA V40208 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 16 of 44 Waypointo ANALYTICAL 00122 Falcon Engineering Project Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number:23-313-0014 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com G23014.02 REPORT OP ANAL YSIS Report Date : 11/20/2023 Received : 11/09/2023 Lab No: 99698 Matrix: Aqueous Sample ID: SMW5 Sampled: 11/8/2023 12:10 Analytical Method: 8260D Prep Batch(es): V40207 11/13/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,2-Dibromo-3-Chloropropane <1.10 Ng/L 1.10 2.00 1 11/13/23 15:52 MSA V40208 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 11/13/23 15:52 MSA V40208 Dibromomethane <0.230 ug/L 0.230 0.500 1 11/13/23 15:52 MSA V40208 1,2-Dichlorobenzene <0.220 Ng/L 0.220 0.500 1 11/13/23 15:52 MSA V40208 1,3-Dichlorobenzene <0.190 ug/L 0.190 0.500 1 11/13/23 15:52 MSA V40208 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 11/13/23 15:52 MSA V40208 Dichlorodifluoromethane <1.20 Ng/L 1.20 5.00 1 11/13/23 15:52 MSA V40208 1,1-Dichloroethane <0.240 ug/L 0.240 0.500 1 11/13/23 15:52 MSA V40208 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 11/13/23 15:52 MSA V40208 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 11/13/23 15:52 MSA V40208 cis-1,2-Dichloroethene <0.200 Ng/L 0.200 0.500 1 11/13/23 15:52 MSA V40208 trans- 1,2-Dichloroethene <0.180 ug/L 0.180 0.500 1 11/13/23 15:52 MSA V40208 1,2-Dichloropropane <0.190 Ng/L 0.190 0.500 1 11/13/23 15:52 MSA V40208 1,3-Dichloropropane <0.130 Ng/L 0.130 0.500 1 11/13/23 15:52 MSA V40208 2,2-Dichloropropane <0.210 Ng/L 0.210 2.00 1 11/13/23 15:52 MSA V40208 1,1-Dichloropropene <0.200 ug/L 0.200 0.500 1 11/13/23 15:52 MSA V40208 cis-1,3-Dichloropropene <0.210 Ng/L 0.210 0.500 1 11/13/23 15:52 MSA V40208 trans- 1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 11/13/23 15:52 MSA V40208 Ethylbenzene <0.170 ug/L 0.170 0.500 1 11/13/23 15:52 MSA V40208 Ethyl Tertiary Butyl Ether (ETBE) <1.80 N9/L 1.80 10.0 1 11/13/23 15:52 MSA V40208 Hexachlorobutadiene <0.350 Ng/L 0.350 2.00 1 11/13/23 15:52 MSA V40208 n-Hexane <1.30 Ng/L 1.30 10.0 1 11/13/23 15:52 MSA V40208 Qualifiers/ DF Dilution Factor I Estimated value Definitions MQL Method Quantitation Limit Page 17 of 44 (2) WayPAoint. NALYTICAL 00122 Falcon Engineering Project Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-313-0014 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com G23014.02 REPORT OFANAL YSIS Report Date : 11/20/2023 Received : 11/09/2023 Lab No : 99698 Matrix: Aqueous Sample ID: SMWS Sampled: 11/8/2023 12:10 Analytical Method: 8260D Prep Batch(es): V40207 11/13/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 2-Hexanone <0.380 pg/L 0.380 5.00 1 11/13/23 15:52 MSA V40208 Isopropylbenzene <0.180 pg/L 0.180 5.00 1 11/13/23 15:52 MSA V40208 4-Isopropyl toluene <0.089 pg/L 0.089 0.500 1 11/13/23 15:52 MSA V40208 Methyl Ethyl Ketone (MEK) <0.710 pg/L 0.710 5.00 1 11/13/23 15:52 MSA V40208 Methyl tert-butyl ether (MTBE) <0.140 p9/L 0.140 0.500 1 11/13/23 15:52 MSA V40208 4-Methyl-2-Pentanone <1.00 pg/L 1.00 5.00 1 11/13/23 15:52 MSA V40208 Methylene Chloride <0.330 pg/L 0.330 1.00 1 11/13/23 15:52 MSA V40208 Naphthalene <0.470 pg/L 0.470 1.00 1 11/13/23 15:52 MSA V40208 n-Propylbenzene <0.190 pg/L 0.190 0.500 1 11/13/23 15:52 MSA V40208 Styrene <0.220 p9/L 0.220 0.500 1 11/13/23 15:52 MSA V40208 1,1,1,2-Tetrachloroethane <0.160 pg/L 0.160 0.500 1 11/13/23 15:52 MSA V40208 1,1,2,2-Tetrachloroethane <0.160 pg/L 0.160 0.500 1 11/13/23 15:52 MSA V40208 Tetrachloroethene <0.220 pg/L 0.220 0.500 1 11/13/23 15:52 MSA V40208 Toluene <0.220 pg/L 0.220 0.500 1 11/13/23 15:52 MSA V40208 1,2,3-Trichlorobenzene <0380 p9/L 0.380 2.00 1 11/13/23 15:52 MSA V40208 1,2,4-Trichlorobenzene <0.310 pg/L 0.310 1.00 1 11/13/23 15:52 MSA V40208 1, 1, 1-Trichloroethane <0.160 pg/L 0.160 0.500 1 11/13/23 15:52 MSA V40208 1,1,2-Trichloroethane <0.096 pg/L 0.096 0.500 1 11/13/23 15:52 MSA V40208 Trichloroethene <0.180 pg/L 0.180 0.500 1 11/13/23 15:52 MSA V40208 Trichlorofluoromethane <0.180 pg/L 0.180 0.500 1 11/13/23 15:52 MSA V40208 1,2,3-Trichloropropane <0.270 pg/L 0.270 1.00 1 11/13/23 15:52 MSA V40208 1,3,5-Trimethylbenzene <0.180 pg/L 0.180 0.500 1 11/13/23 15:52 MSA V40208 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 18 of 44 Waypoint, 0 449 Springbrook Rd, Charlotte, INC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 00122 Falcon Engineering Project G23014.02 Christopher Burkhardt Report Date : 11/20/2023 1210 Trinity Road Information : Received : 11/09/2023 Suite 110 Cary , NC 27513 Report Number : 23-313-0014 REPORT OFANALYSlS Lab No : 99698 Matrix: Aqueous Sample ID: SMWS Sampled: 11/8/2023 12:10 Analytical Method: 8260D Prep Batch(es): V40207 11/13/23 09:00 Prep Method: 5030B Test Results Units MDL MOIL DF Date / Time By Analytical Analyzed Batch Vinyl Acetate <1.00 Ng/L 1.00 2.00 1 11/13/23 15:52 MSA V40208 Vinyl Chloride <0.170 Ng/L 0.170 0.500 1 11/13/23 15:52 MSA V40208 o-Xylene <0.210 Ng/L 0.210 0.500 1 11/13/23 15:52 MSA V40208 m,p-Xylene <0.420 Ng/L 0.420 1.00 1 11/13/23 15:52 MSA V40208 Xylene (Total) <0.21 Ng/L 0.210 0.500 1 11/13/23 15:52 V40208 Surrogate:4-Bromofluorobenzene 97.8 Limits:80-124% 1 11/13/23 15:52 MSA V40208 Surrogate: Dibromofluoromethane 101 Limits: 75-129% 1 11/13/23 15:52 MSA V40208 Surrogate: 1,2-Dichloroethane - d4 98.8 Limits: 63-136% 1 11/13/23 15:52 MSA V40208 Surrogate: Toluene-d8 101 Limits: 77-123% 1 11/13/23 15:52 MSA V40208 Analytical Method: 8315A Prep Batch(es): L716464 11/11/23 14:15 Prep Method: 8315A Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Formaldehyde 190 ug/L 10.0 10.0 1 11/11/23 21:15 KDL L716755 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 19 of 44 • Way 449 Springbrook Rd, Ch(D arlotte, NC 28217 Pnt. Main 704.529.6364 A N A LYT I CAL www.waypointanalytical.com 00122 Falcon Engineering Project G23014.02 Christopher Burkhardt Report Date : 11/20/2023 1210 Trinity Road Information : Received : 11/09/2023 Suite 110 Cary , NC 27513 Report Number : 23-313-0014 REPORT OPANALYSIS Lab No : 99699 Matrix: Aqueous Sample ID: SMW8 Sampled: 11/8/2023 12:29 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen <0.040 mg/L 0.040 0.100 1 11/20/23 11:24 JFM 4500NH3D-2011 Chloride 469 mg/L 3.70 10.0 10 11/14/23 00:26 NDL 300.0 Nitrate (NO3-N) <0.076 mg/L 0.076 0.200 1 11/09/23 17:38 NDL 300.0 Total Dissolved Solids 1130 mg/L 36 50 1 11/13/23 11:32 RLW 2540C-2015 Phosphorus <0.212 mg/L 0.212 0.500 1 11/20/2314:13 ANH 365.4 TOC 1.04 mg/L 0.682 1.00 1 11/14/23 18:06 ELM 531OC-2011 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 20 of 44 0 Waypoeint, 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 00122 Falcon Engineering Project G23014.02 Christopher Burkhardt Report Date : 11/20/2023 1210 Trinity Road Information : Received : 11/09/2023 Suite 110 Cary , NC 27513 Report Number : 23-313-0014 REPORT OFANALYSIS Lab No : 99699 Sample ID: SMWS Matrix: Aqueous Sampled: 11/8/2023 12:29 Analytical Method: 8260D Prep Method: 5030E Test Results Prep Batch(es): Units V40207 MDL 11/13/23 09:00 MQL DF Date / Time Analyzed By Analytical Batch Acetone <1.80 Ug/L 1.80 5.00 1 11/13/23 16:16 MSA V40208 Acrolein <2.00 Ng/L 2.00 5.00 1 11/13/23 16:16 MSA V40208 Acrylonitrile <0.230 Ng/L 0.230 5.00 1 11/13/23 16:16 MSA V40208 Benzene <0.180 ug/L 0.180 0.500 1 11/13/23 16:16 MSA V40208 Bromobenzene <0.210 ug/L 0.210 0.500 1 11/13/23 16:16 MSA V40208 Bromochloromethane <0.420 Ng/L 0.420 1.00 1 11/13/23 16:16 MSA V40208 Bromodichloromethane <0.160 ug/L 0.160 0.500 1 11/13/23 16:16 MSA V40208 Bromoform <1.50 Ng/L 1.50 5.00 1 11/13/23 16:16 MSA V40208 Bromomethane <0.280 Ng/L 0.280 1.00 1 11/13/23 16:16 MSA V40208 n-Butylbenzene <0.185 ug/L 0.185 1.00 1 11/13/23 16:16 MSA V40208 sec -Butyl benzene <0.200 Ng/L 0.200 0.500 1 11/13/23 16:16 MSA V40208 tert-Butyl benzene <0.920 N9/L 0.920 2.00 1 11/13/23 16:16 MSA V40208 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 11/13/23 16:16 MSA V40208 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 11/13/23 16:16 MSA V40208 Chlorobenzene <0.190 Ng/L 0.190 0.500 1 11/13/23 16:16 MSA V40208 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 11/13/23 16:16 MSA V40208 Chloroethane <0.430 Ng/L 0.430 1.00 1 11/13/23 16:16 MSA V40208 Chloroform <0.220 ug/L 0.220 0.500 1 11/13/23 16:16 MSA V40208 Chloromethane <0.220 Ng/L 0.220 0.500 1 11/13/23 16:16 MSA V40208 2-Chlorotoluene <0.200 Ng/L 0.200 0.500 1 11/13/23 16:16 MSA V40208 4-Chlorotoluene <0.200 Ng/L 0.200 0.500 1 11/13/23 16:16 MSA V40208 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 11/13/23 16:16 MSA V40208 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 21 of 44 Waypointo ANALYTICAL 00122 Falcon Engineering Project Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-313-0014 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com G23014.02 REPORT OFANAL YSIS Report Date: 11/20/2023 Received : 11/09/2023 Lab No : 99699 Matrix: Aqueous Sample ID: SMW8 Sampled: 11/8/2023 12:29 Analytical Method: 8260D Prep Batch(es): V40207 11/13/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,2-Dibromo-3-Chloropropane <1.10 Ng/L 1.10 2.00 1 11/13/2316:16 MSA V40208 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 11/13/2316:16 MSA V40208 Dibromomethane <0.230 Ng/L 0.230 0.500 1 11/13/2316:16 MSA V40208 1,2-Dichlorobenzene <0.220 N9/L 0.220 0.500 1 11/13/2316:16 MSA V40208 1,3-Dichlorobenzene <0.190 Ng/L 0.190 0.500 1 11/13/2316:16 MSA V40208 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 11/13/2316:16 MSA V40208 Dichlorodifluoromethane <1.20 Ng/L 1.20 5.00 1 11/13/2316:16 MSA V40208 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 11/13/2316:16 MSA V40208 1,2-Dichloroethane <0.150 Ng/L 0.150 0.500 1 11/13/2316:16 MSA V40208 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 11/13/2316:16 MSA V40208 cis-1,2-Dichloroethene <0.200 Ng/L 0.200 0.500 1 11/13/2316:16 MSA V40208 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 11/13/2316:16 MSA V40208 1,2-Dichloropropane <0.190 Ng/L 0.190 0.500 1 11/13/2316:16 MSA V40208 1,3-Dichloropropane <0.130 Ng/L 0.130 0.500 1 11/13/2316:16 MSA V40208 2,2-Dichloropropane <0.210 Ng/L 0.210 2.00 1 11/13/2316:16 MSA V40208 1,1-Dichloropropene <0.200 ug/L 0.200 0.500 1 11/13/2316:16 MSA V40208 cis- 1,3-Dichloropropene <0.210 ug/L 0.210 0.500 1 11/13/2316:16 MSA V40208 trans- 1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 11/13/2316:16 MSA V40208 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 11/13/2316:16 MSA V40208 Ethyl Tertiary Butyl Ether (ETBE) <1.80 N9/L 1.80 10.0 1 11/13/23 16:16 MSA V40208 Hexachlorobutadiene <0.350 Ng/L 0.350 2.00 1 11/13/2316:16 MSA V40208 n-Hexane <1.30 ug/L 1.30 10.0 1 11/13/2316:16 MSA V40208 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 22 of 44 WayPAoi nt . NALYTICAL 00122 Falcon Engineering Project Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-313-0014 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com G23014.02 REPORT Of ANAL YSIS Report Date : 11/20/2023 Received : 11/09/2023 Lab No : 99699 Matrix: Aqueous Sample ID: SMW8 Sampled: 11/8/2023 12:29 Analytical Method: 8260D Prep Batch(es): V40207 11/13/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 2-Hexanone <0.380 Ng/L 0.380 5.00 1 11/13/23 16:16 MSA V40208 Isopropylbenzene <0.180 Ng/L 0.180 5.00 1 11/13/23 16:16 MSA V40208 4-Isopropyl toluene <0.089 Ng/L 0.089 0.500 1 11/13/23 16:16 MSA V40208 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 11/13/23 16:16 MSA V40208 Methyl tert-butyl ether (MTBE) <0.140 Ng/L 0.140 0.500 1 11/13/23 16:16 MSA V40208 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 11/13/23 16:16 MSA V40208 Methylene Chloride <0.330 ug/L 0.330 1.00 1 11/13/23 16:16 MSA V40208 Naphthalene <0.470 Ng/L 0.470 1.00 1 11/13/23 16:16 MSA V40208 n-Propylbenzene <0.190 Ng/L 0.190 0.500 1 11/13/23 16:16 MSA V40208 Styrene <0.220 Ng/L 0.220 0.500 1 11/13/23 16:16 MSA V40208 1, 1, 1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 11/13/23 16:16 MSA V40208 1,1,2,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 11/13/23 16:16 MSA V40208 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 11/13/23 16:16 MSA V40208 Toluene <0.220 Ng/L 0.220 0.500 1 11/13/23 16:16 MSA V40208 1,2,3-Trichlorobenzene <0.380 Ng/L 0.380 2.00 1 11/13/23 16:16 MSA V40208 1,2,4-Trichlorobenzene <0.310 Ng/L 0.310 1.00 1 11/13/23 16:16 MSA V40208 1, 1, 1-Trichloroethane <0.160 Ng/L 0.160 0.500 1 11/13/23 16:16 MSA V40208 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 11/13/23 16:16 MSA V40208 Trichloroethene <0.180 ug/L 0.180 0.500 1 11/13/23 16:16 MSA V40208 Trichlorofluoromethane <0.180 Ng/L 0.180 0.500 1 11/13/23 16:16 MSA V40208 1,2,3-Trichloropropane <0.270 ug/L 0.270 1.00 1 11/13/23 16:16 MSA V40208 1,3,5-Trimethylbenzene <0.180 Ng/L 0.180 0.500 1 11/13/23 16:16 MSA V40208 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 23 of 44 0 Waypoint. 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 00122 Falcon Engineering Project G23014.02 Christopher Burkhardt Report Date : 11/20/2023 1210 Trinity Road Information : Received : 11/09/2023 Suite 110 Cary , NC 27513 Report Number : 23-313-0014 Lab No : 99699 Sample ID: SMW8 REPORT OFANAL YSIS Matrix: Aqueous Sampled: 11/8/2023 12:29 Analytical Method: 8260D Prep Batch(es): V40207 11/13/23 09:00 Prep Method: 5030B Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Vinyl Acetate <1.00 Ng/L 1.00 2.00 1 11/13/23 16:16 MSA V40208 Vinyl Chloride <0.170 Ng/L 0.170 0.500 1 11/13/23 16:16 MSA V40208 o-Xylene <0.210 Ng/L 0.210 0.500 1 11/13/23 16:16 MSA V40208 m,p-Xylene <0.420 Ng/L 0.420 1.00 1 11/13/23 16:16 MSA V40208 Xylene (Total) <0.21 Ng/L 0.210 0.500 1 11/13/23 16:16 V40208 Surrogate:4-Bromofluorobenzene 98.8 Limits:80-124% 1 11/13/23 16:16 MSA V40208 Surrogate: Dibromofluoromethane 98.6 Limits: 75-129% 1 11/13/23 16:16 MSA V40208 Surrogate: 1,2-Dichloroethane - d4 97.4 Limits: 63-136% 1 11/13/23 16:16 MSA V40208 Surrogate: Toluene-d8 101 Limits: 77-123% 1 11/13/23 16:16 MSA V40208 Analytical Method: 8315A Prep Batch(es): L716464 11/11/23 14:15 Prep Method: 8315A Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Formaldehyde <10.0 Ng/L 10.0 10.0 1 11/11/23 21:26 KDL L716755 Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit I Estimated value Page 24 of 44 Waypo�nt0 • 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: G23014.02 Report No: 23-313-0014 QC Analytical Batch: V40127 Analysis Method: 2540C-2015 Analysis Description: Total Dissolved Solids Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 99696, 99697, 99698, 99699 Blank MDL MQL Analyzed Parameter Units Result Total Dissolved Solids mg/L <36 36 50 11/13/23 11:32 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Total Dissolved Solids mg/L 1000 990 99.0 90-110 Duplicate V 99699-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Total Dissolved Solids mg/L 1130 1090 3.6 10 11/13/23 11:32 Date: 11/20/2023 04:05 PM Page 1 of 18 Page 25 of 44 0 Waypoint. 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: G23014.02 Report No: 23-313-0014 QC Prep: V40106 QC Analytical Batch(es): V40112,V40210 QC Prep Batch Method: 300.0 (Prep) Analysis Method: 300.0 Analysis Description: Anions by Ion Chromatography Lab Reagent Blank LRB-V40106 Matrix: AQU Associated Lab Samples: 99696, 99697, 99698, 99699 Blank MDL MQL Analyzed Parameter Units Result Chloride mg/L <0.370 0.370 1.00 11/09/2315:37 Nitrate (NO3-N) mg/L <0.076 0.076 0.200 11/09/23 15:37 Laboratory Control Sample LCS-V40106 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Chloride mg/L 40.0 38.5 96.0 90-110 Nitrate (NO3-N) mg/L 4.00 4.00 100 90-110 Matrix Spike & Matrix Spike Duplicate V 99680-MS-V40106 V 99680-MSD-V40106 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Chloride mg/L 88.2 40.0 40.0 128 126 100 95.0 90-110 1.5 20.0 Nitrate (NO3-N) mg/L 83.5 4.00 4.00 93.4 94.0 248* 263* 90-110 0.6 20.0 * QC Fail Date: 11/20/2023 04:05 PM Page 2 of 18 Page 26 of 44 0 Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: G23014.02 Report No: 23-313-0014 QC Prep: L717661 QC Analytical Batch(es): L717989 QC Prep Batch Method: TKN/TKP Digestion Analysis Method: 365.4 Analysis Description: Total Phosphorus Lab Reagent Blank LRB-1-717661 Matrix: AQU Associated Lab Samples: 99696, 99697, 99698 Blank MDL MQL Analyzed Parameter Units Result Phosphorus mg/L <0.212 0.212 0.500 11/20/23 13:37 Laboratory Control Sample LCS-L717661 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Phosphorus mg/L 2.00 1.89 95.0 80-120 Duplicate L 99682-DUP-L717661 Result DUP RPD Max RPD Analyzed Parameter Units Result Phosphorus mg/L 3.94 3.97 0.7 20.0 11/20/2313:41 Matrix Spike L 99682-MS-L717661 MS Spike MSD MS Result MSD MS %Rec Max Parameter Units Result Conc. Spike Result %Rec Limits RPD Conc. Phosphorus mg/L 3.94 2.00 5.86 96.0 70-130 Date: 11/20/2023 04:05 PM Page 3 of 18 Page 27 of 44 0 449 Springbrook Rd, Charlotte, NC 28217 Waypoint.Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: G23014.02 Report No: 23-313-0014 QC Prep: L717689 QC AnalyticalBatch(es): L717991 QC Prep Batch Method: TKN/TKP Digestion Analysis Method: 365.4 Analysis Description: Total Phosphorus Lab Reagent Blank LRB-1-717689 Matrix: AQU Associated Lab Samples: 99699 Blank MDL MQL Analyzed Parameter Units Result Phosphorus mg/L <0.212 0.212 0.500 11/20/23 14:06 Laboratory Control Sample LCS-1-717689 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Phosphorus mg/L 2.00 2.08 104 80-120 Duplicate A 66353-DUP-L717689 Result DUP RPD Max RPD Analyzed Parameter Units Result Phosphorus mg/L < 0.500 <0.500 0.0 20.0 11/20/23 14:10 Matrix Spike A 66353-MS-1-717689 MS Spike MSD MS Result MSD MS %Rec Max Parameter Units Result Conc. Spike Result %Rec Limits RPD Conc. Phosphorus mg/L 0.264 2.00 2.29 115 70-130 Date: 11/20/2023 04:05 PM Page 4 of 18 Page 28 of 44 0 Waypoint 449 Springbrook Rd, Charlotte, NC 28217 . Main 704.529.6364 ANALYTICAL www.waypointanalocal.com Quality Control Data Client ID: Falcon Engineering Project Description: G23014.02 Report No: 23-313-0014 QC Analytical Batch: L718092 Analysis Method: 4500NH3D-2011 Analysis Description: Ammonia Nitrogen (ISE) Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 99696, 99697, 99698, 99699 Blank MDL MQL Analyzed Parameter Units Result Ammonia Nitrogen mg/L <0.040 0.040 0.100 11/20/23 11:24 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Ammonia Nitrogen mg/L 5.00 4.81 96.0 90-110 Matrix Spike & Matrix Spike Duplicate V 99680-MS V 99680-MSD MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Ammonia Nitrogen mg/L 7.71 2.04 2.04 9.96 10.1 110 117 70-130 1.3 20.0 Date: 11/20/2023 04:05 PM Page 5 of 18 Page 29 of 44 •n W�ypOI■ ■�.. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: G23014.02 Report No: 23-313-0014 QC Prep: L717280 QC Analytical Batch(es): L717281 QC Prep Batch Method: 531OC-2011 Analysis Method: 531OC-2011 Analysis Description: Total Organic Carbon Lab Reagent Blank LRB-L717280 Matrix: AQU Associated Lab Samples: 99696, 99697, 99698, 99699 Blank MDL MQL Analyzed Parameter Units Result TOC mg/L <0.682 0.682 1.00 11/14/23 11:07 Laboratory Control Sample LCS-1-717280 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits TOC mg/L 5.00 5.23 105 85-115 Duplicate Q 94748-DUP-L717280 Result DUP RPD Max RPD Analyzed Parameter Units Result TOC mg/L < 1.00 <1.00 37.8* 15.0 11/14/23 14:17 Matrix Spike L 90424-MS-L717280 MS Spike MSD MS Result MSD MS %Rec Max Parameter Units Result Conc. Spike Result %Rec Limits RPD Conc. TOC mg/L 1.92 5.26 7.65 109 85-115 * QC Fail Date: 11/20/2023 04:05 PM Page 6 of 18 Page 30 of 44 Waypointo ANALYTICAL Client ID: Project Description: Report No: Falcon Engineering G23O14.O2 23-313-0014 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data QC Prep: V40139 QC Analytical Batch(es): V40140 QC Prep Batch Method: 5030E Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V40139 Matrix: AQU Associated Lab Samples: 99696, 99697 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Acetone pg/L <1.80 1.80 5.00 11/11/23 02:34 Acrolein pg/L <2.00 2.00 5.00 11/11/23 02:34 Acrylonitrile pg/L <0.230 0.230 5.00 11/11/23 02:34 Benzene pg/L <0.180 0.180 0.500 11/11/23 02:34 Bromobenzene pg/L <0.210 0.210 0.500 11/11/23 02:34 Bromochloromethane pg/L <0.420 0.420 1.00 11/11/23 02:34 Bromodichloromethane pg/L <0.160 0.160 0.500 11/11/23 02:34 Bromoform pg/L <1.50 1.50 5.00 11/11/23 02:34 Bromomethane pg/L <0.280 0.280 1.00 11/11/23 02:34 n-Butylbenzene pg/L <0.185 0.185 1.00 11/11/23 02:34 sec -Butyl benzene pg/L <0.200 0.200 0.500 11/11/23 02:34 tert-Butyl benzene pg/L <0.920 0.920 2.00 11/11/23 02:34 Carbon Disulfide pg/L <0.150 0.150 5.00 11/11/23 02:34 Carbon Tetrachloride pg/L <0.180 0.180 0.500 11/11/23 02:34 Chlorobenzene pg/L <0.190 0.190 0.500 11/11/23 02:34 Chlorodibromomethane pg/L <0.190 0.190 0.500 11/11/23 02:34 Chloroethane pg/L <0.430 0.430 1.00 11/11/23 02:34 Chloroform pg/L <0.220 0.220 0.500 11/11/23 02:34 Chloromethane pg/L <0.220 0.220 0.500 11/11/23 02:34 2-Chlorotoluene pg/L <0.200 0.200 0.500 11/11/23 02:34 4-Chlorotoluene pg/L <0.200 0.200 0.500 11/11/23 02:34 Di -Isopropyl Ether(DIPE) pg/L <0.960 0.960 5.00 11/11/23 02:34 1,2-Dibromo-3-Chloropropane pg/L < 1.10 1.10 2.00 11/11/23 02:34 1,2-Dibromoethane pg/L <0.200 0.200 0.500 11/11/23 02:34 Dibromomethane pg/L <0.230 0.230 0.500 11/11/23 02:34 1,2-Dichlorobenzene pg/L <0.220 0.220 0.500 11/11/23 02:34 1,3-Dichlorobenzene pg/L <0.190 0.190 0.500 11/11/23 02:34 Date: 11/20/2023 04:05 PM Page 7 of 18 Page 31 of 44 Waypointo ANALYTICAL Client ID: Project Description: Report No: Falcon Engineering G23O14.O2 23-313-0014 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data QC Prep: V40139 QC Analytical Batch(es): V40140 QC Prep Batch Method: 5030E Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V40139 Matrix: AQU Associated Lab Samples: 99696, 99697 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,4-Dichiorobenzene pg/L <0.210 0.210 0.500 11/11/23 02:34 Dichlorodifluoromethane pg/L <1.20 1.20 5.00 11/11/23 02:34 1,1-Dichloroethane pg/L <0.240 0.240 0.500 11/11/23 02:34 1,2-Dichloroethane pg/L <0.150 0.150 0.500 11/11/23 02:34 1,1-Dichloroethene pg/L <0.150 0.150 0.500 11/11/23 02:34 cis- 1,2-Dichloroethene pg/L <0.200 0.200 0.500 11/11/23 02:34 trans- 1, 2-Dichloroethene pg/L <0.180 0.180 0.500 11/11/23 02:34 1,2-Dichloropropane pg/L <0.190 0.190 0.500 11/11/23 02:34 1,3-Dichloropropane pg/L <0.130 0.130 0.500 11/11/23 02:34 2,2-Dichloropropane pg/L <0.210 0.210 2.00 11/11/23 02:34 1,1-Dichloropropene pg/L <0.200 0.200 0.500 11/11/23 02:34 cis-1,3-Dichloropropene pg/L <0.210 0.210 0.500 11/11/23 02:34 trans-1,3-Dichloropropene pg/L <0.150 0.150 0.500 11/11/23 02:34 Ethylbenzene pg/L <0.170 0.170 0.500 11/11/23 02:34 Ethyl Tertiary Butyl Ether (ETBE) pg/L <1.80 1.80 10.0 11/11/23 02:34 Hexachlorobutadiene pg/L <0.350 0.350 2.00 11/11/23 02:34 n-Hexane pg/L <1.30 1.30 10.0 11/11/23 02:34 2-Hexanone pg/L <0.380 0.380 5.00 11/11/23 02:34 Isopropylbenzene pg/L <0.180 0.180 5.00 11/11/23 02:34 4-Isopropyl toluene pg/L <0.089 0.089 0.500 11/11/23 02:34 Methyl Ethyl Ketone (MEK) pg/L <0.710 0.710 5.00 11/11/23 02:34 Methyl tert-butyl ether (MTBE) pg/L <0.140 0.140 0.500 11/11/23 02:34 4-Methyl-2-Pentanone pg/L <1.00 1.00 5.00 11/11/23 02:34 Methylene Chloride pg/L <0.330 0.330 1.00 11/11/23 02:34 Naphthalene pg/L <0.470 0.470 1.00 11/11/23 02:34 n-Propyibenzene pg/L <0.190 0.190 0.500 11/11/23 02:34 Styrene pg/L <0.220 0.220 0.500 11/11/23 02:34 Date: 11/20/2023 04:05 PM Page 8 of 18 Page 32 of 44 0 Waypoint,449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: G23O14.O2 Report No: 23-313-0014 QC Prep: V40139 QC Analytical Batch(es): V40140 QC Prep Batch Method: 5030E Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V40139 Matrix: AQU Associated Lab Samples: 99696, 99697 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1, 1, 1,2-Tetrachloroethane pg/L <0.160 0.160 0.500 11/11/23 02:34 1,1,2,2-Tetrachloroethane pg/L <0.160 0.160 0.500 11/11/23 02:34 Tetrachloroethene pg/L <0.220 0.220 0.500 11/11/23 02:34 Toluene pg/L <0.220 0.220 0.500 11/11/23 02:34 1,2,3-Trichlorobenzene pg/L <0.380 0.380 2.00 11/11/23 02:34 1,2,4-Trichlorobenzene pg/L <0.310 0.310 1.00 11/11/23 02:34 1, 1, 1-Trichloroethane pg/L <0.160 0.160 0.500 11/11/23 02:34 1, 1, 2-Trichloroethane pg/L <0.096 0.096 0.500 11/11/23 02:34 Trichloroethene pg/L <0.180 0.180 0.500 11/11/23 02:34 Trichlorofluoromethane pg/L <0.180 0.180 0.500 11/11/23 02:34 1,2,3-Trichloropropane pg/L <0.270 0.270 1.00 11/11/23 02:34 1,3,5-Trimethylbenzene pg/L <0.180 0.180 0.500 11/11/23 02:34 Vinyl Acetate pg/L <1.00 1.00 2.00 11/11/23 02:34 Vinyl Chloride pg/L <0.170 0.170 0.500 11/11/23 02:34 o-Xylene pg/L <0.210 0.210 0.500 11/11/23 02:34 m,p-Xylene pg/L <0.420 0.420 1.00 11/11/23 02:34 4-Bromofluorobenzene (S) 11/11/23 02:34 102 80-124 Dibromofluoromethane (S) 11/11/23 02:34 95.4 75-129 1,2-Dichloroethane - d4 (S) 11/11/23 02:34 92.0 63-136 Toluene-d8 (S) 11/11/23 02:34 98.6 77-123 Laboratory Control Sample & LCSD LCS-V40139 LCSD-V40139 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Acetone pg/L 40.0 58.1 55.6 145 139 40-166 4.3 20.0 Acrolein pg/L 40.0 35.4 34.7 88.5 86.7 70-130 1.9 20.0 Date: 11/20/2023 04:05 PM Page 9 of 18 Page 33 of 44 0 Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: G23014.02 Report No: 23-313-0014 QC Prep: V40139 QC Analytical Batch(es): V40140 QC Prep Batch Method: 5030E Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V40139 LCSD-V40139 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Acrylonitrile pg/L 40.0 39.8 40.3 99.5 101 81-127 1.2 20.0 Benzene pg/L 20.0 22.1 22.0 111 110 77-128 0.4 20.0 Bromobenzene pg/L 20.0 20.7 20.5 104 103 78-129 0.9 20.0 Bromochloromethane pg/L 20.0 21.0 21.1 105 106 78-135 0.4 20.0 Bromodichloromethane pg/L 20.0 20.7 20.6 104 103 76-138 0.4 20.0 Bromoform pg/L 20.0 18.4 18.5 92.0 92.5 71-135 0.5 20.0 Bromomethane pg/L 20.0 15.9 18.6 79.5 93.0 41-168 15.6 20.0 n-Butylbenzene pg/L 20.0 21.4 21.3 107 107 68-134 0.4 20.0 sec -Butyl benzene pg/L 20.0 21.5 20.8 108 104 71-131 3.3 20.0 tert-Butyl benzene pg/L 20.0 21.0 20.6 105 103 70-132 1.9 20.0 Carbon Disulfide pg/L 20.0 21.4 21.2 107 106 59-135 0.9 20.0 Carbon Tetrachloride pg/L 20.0 22.4 21.9 112 110 72-142 2.2 20.0 Chlorobenzene pg/L 20.0 20.8 20.9 104 105 78-119 0.4 20.0 Chlorodibromomethane pg/L 20.0 19.8 19.7 99.0 98.5 75-134 0.5 20.0 Chloroethane pg/L 20.0 20.0 20.7 100 104 57-142 3.4 20.0 Chloroform pg/L 20.0 21.4 21.0 107 105 77-130 1.8 20.0 Chloromethane pg/L 20.0 19.2 20.4 96.0 102 47-145 6.0 20.0 2-Chlorotoluene pg/L 20.0 20.6 20.3 103 102 74-126 1.4 20.0 4-Chlorotoluene pg/L 20.0 21.0 20.5 105 103 78-129 2.4 20.0 Di -Isopropyl Ether (DIPE) pg/L 20.0 22.1 21.6 111 108 60-154 2.2 20.0 1,2-Dibromo-3-Chloropropane pg/L 20.0 20.6 19.2 103 96.0 63-134 7.0 20.0 1,2-Dibromoethane pg/L 20.0 19.6 19.1 98.0 95.5 77-135 2.5 20.0 Dibromomethane pg/L 20.0 20.9 20.5 105 103 76-138 1.9 20.0 1,2-Dichlorobenzene pg/L 20.0 20.4 19.9 102 99.5 78-128 2.4 20.0 1,3-Dichlorobenzene pg/L 20.0 20.7 20.4 104 102 77-125 1.4 20.0 1,4-Dichlorobenzene pg/L 20.0 20.3 20.3 102 102 75-126 0.0 20.0 Date: 11/20/2023 04:05 PM Page 10 of 18 Page 34 of 44 0 Waypoi nt 449 Springbrook Rd, Charlotte, NC 28217 � Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: G23O14.O2 Report No: 23-313-0014 QC Prep: V40139 QC Analytical Batch(es): V40140 QC Prep Batch Method: 5030E Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V40139 LCSD-V40139 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Dichlorodifluoromethane pg/L 20.0 12.5 12.0 62.5 60.0 28-163 4.0 20.0 1,1-Dichloroethane pg/L 20.0 22.3 22.1 112 ill 70-130 0.9 20.0 1,2-Dichloroethane pg/L 20.0 20.7 20.3 104 102 68-131 1.9 20.0 1,1-Dichloroethene pg/L 20.0 23.4 23.2 117 116 70-154 0.8 20.0 cis- 1,2-Dichloroethene pg/L 20.0 21.5 21.1 108 106 76-141 1.8 20.0 trans- 1, 2-Dichloroethene pg/L 20.0 21.7 22.1 109 ill 76-135 1.8 20.0 1,2-Dichloropropane pg/L 20.0 21.2 21.2 106 106 77-130 0.0 20.0 1,3-Dichloropropane pg/L 20.0 19.8 19.5 99.0 97.5 76-132 1.5 20.0 2,2-Dichloropropane pg/L 20.0 19.8 19.1 99.0 95.5 29-149 3.5 20.0 1,1-Dichloropropene pg/L 20.0 23.3 23.3 117 117 71-136 0.0 20.0 cis- 1,3-Dichloropropene pg/L 20.0 19.9 19.7 99.5 98.5 65-140 1.0 20.0 trans-1,3-Dichloropropene pg/L 20.0 19.0 18.9 95.0 94.5 67-140 0.5 20.0 Ethylbenzene pg/L 20.0 20.9 20.8 105 104 80-127 0.4 20.0 Ethyl Tertiary Butyl Ether (ETBE) pg/L 40.0 44.0 43.7 110 109 70-130 0.6 20.0 Hexachlorobutadiene pg/L 20.0 20.0 19.2 100 96.0 61-134 4.0 20.0 n-Hexane pg/L 20.0 19.5 19.4 97.5 97.0 70-130 0.5 20.0 2-Hexanone pg/L 20.0 24.0 23.2 120 116 64-137 3.3 20.0 Isopropylbenzene pg/L 20.0 22.2 21.9 ill 110 70-130 1.3 20.0 4-Isopropyl toluene pg/L 20.0 21.8 21.5 109 108 69-132 1.3 20.0 Methyl Ethyl Ketone (MEK) pg/L 20.0 23.9 24.9 120 125 71-134 4.0 20.0 Methyl tert-butyl ether (MTBE) pg/L 20.0 20.1 20.2 101 101 68-135 0.4 20.0 4-Methyl-2-Pentanone pg/L 20.0 20.7 21.1 104 106 69-134 1.9 20.0 Methylene Chloride pg/L 20.0 21.6 21.4 108 107 73-131 0.9 20.0 Naphthalene pg/L 20.0 19.9 18.8 99.5 94.0 64-136 5.6 20.0 n-Propylbenzene pg/L 20.0 21.6 21.3 108 107 72-132 1.3 20.0 Styrene pg/L 20.0 21.1 21.2 106 106 78-129 0.4 20.0 Date: 11/20/2023 04:05 PM Page 11 of 18 Page 35 of 44 Waypoint 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: G23O14.O2 Report No: 23-313-0014 QC Prep: V40139 QC Analytical Batch(es): V40140 QC Prep Batch Method: 5030E Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V40139 LCSD-V40139 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD 1, 1, 1,2-Tetrachloroethane pg/L 20.0 20.9 20.5 105 103 79-134 1.9 20.0 1,1,2,2-Tetrachloroethane pg/L 20.0 19.6 18.9 98.0 94.5 62-127 3.6 20.0 Tetrachloroethene pg/L 20.0 21.5 21.1 108 106 80-129 1.8 20.0 Toluene pg/L 20.0 21.8 21.5 109 108 76-131 1.3 20.0 1,2,3-Trichlorobenzene pg/L 20.0 20.5 18.6 103 93.0 58-144 9.7 20.0 1,2,4-Trichlorobenzene pg/L 20.0 20.6 19.3 103 96.5 66-139 6.5 20.0 1, 1, 1-Trichloroethane pg/L 20.0 22.0 21.4 110 107 75-135 2.7 20.0 1,1,2-Trichloroethane pg/L 20.0 21.2 20.7 106 104 70-140 2.3 20.0 Trichloroethene pg/L 20.0 21.8 22.5 109 113 77-133 3.1 20.0 Trichlorofluoromethane pg/L 20.0 21.3 20.7 107 104 62-148 2.8 20.0 1,2,3-Trichloropropane pg/L 20.0 20.0 20.1 100 101 71-127 0.4 20.0 1,3,5-Trimethylbenzene pg/L 20.0 21.8 21.2 109 106 75-131 2.7 20.0 Vinyl Acetate pg/L 20.0 16.3 14.4 81.5 72.0 34-167 12.3 20.0 Vinyl Chloride pg/L 20.0 20.8 20.4 104 102 57-141 1.9 20.0 o-Xylene pg/L 20.0 21.3 21.0 107 105 78-128 1.4 20.0 m,p-Xylene pg/L 40.0 44.4 44.4 ill ill 77-133 0.0 20.0 4-13romofluorobenzene (S) 100 100 80-124 Dibromofluoromethane (S) 97.4 96.4 75-129 1,2-Dichloroethane - d4 (S) 95.8 94.2 63-136 Toluene-d8 (S) 98.8 98.4 77-123 Date: 11/20/2023 04:05 PM Page 12 of 18 Page 36 of 44 Waypointo ANALYTICAL Client ID: Falcon Engineering Project Description: G23O14.O2 Report No: 23-313-0014 QC Prep: V40207 QC Prep Batch Method: 5030E 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data QC Analytical Batch(es): V40208 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V40207 Matrix: AQU Associated Lab Samples: 99698, 99699 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Acetone pg/L <1.80 1.80 5.00 11/13/23 15:03 Acrolein pg/L <2.00 2.00 5.00 11/13/23 15:03 Acrylonitrile pg/L <0.230 0.230 5.00 11/13/23 15:03 Benzene pg/L <0.180 0.180 0.500 11/13/23 15:03 Bromobenzene pg/L <0.210 0.210 0.500 11/13/23 15:03 Bromochloromethane pg/L <0.420 0.420 1.00 11/13/23 15:03 Bromodichloromethane pg/L <0.160 0.160 0.500 11/13/23 15:03 Bromoform pg/L <1.50 1.50 5.00 11/13/23 15:03 Bromomethane pg/L <0.280 0.280 1.00 11/13/23 15:03 n-Butylbenzene pg/L <0.185 0.185 1.00 11/13/23 15:03 sec -Butyl benzene pg/L <0.200 0.200 0.500 11/13/23 15:03 tert-Butyl benzene pg/L <0.920 0.920 2.00 11/13/23 15:03 Carbon Disulfide pg/L <0.150 0.150 5.00 11/13/23 15:03 Carbon Tetrachloride pg/L <0.180 0.180 0.500 11/13/23 15:03 Chlorobenzene pg/L <0.190 0.190 0.500 11/13/23 15:03 Chlorodibromomethane pg/L <0.190 0.190 0.500 11/13/23 15:03 Chloroethane pg/L <0.430 0.430 1.00 11/13/23 15:03 Chloroform pg/L <0.220 0.220 0.500 11/13/23 15:03 Chloromethane pg/L <0.220 0.220 0.500 11/13/23 15:03 2-Chlorotoluene pg/L <0.200 0.200 0.500 11/13/23 15:03 4-Chlorotoluene pg/L <0.200 0.200 0.500 11/13/23 15:03 Di -Isopropyl Ether (DIPE) pg/L <0.960 0.960 5.00 11/13/23 15:03 1,2-Dibromo-3-Chloropropane pg/L < 1.10 1.10 2.00 11/13/23 15:03 1,2-Dibromoethane pg/L <0.200 0.200 0.500 11/13/23 15:03 Dibromomethane pg/L <0.230 0.230 0.500 11/13/23 15:03 1,2-Dichlorobenzene pg/L <0.220 0.220 0.500 11/13/23 15:03 1,3-Dichlorobenzene pg/L <0.190 0.190 0.500 11/13/23 15:03 Date: 11/20/2023 04:05 PM Page 13 of 18 Page 37 of 44 Waypointo ANALYTICAL Client ID: Falcon Engineering Project Description: G23O14.O2 Report No: 23-313-0014 QC Prep: V40207 QC Prep Batch Method: 5030E 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data QC Analytical Batch(es): V40208 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank Associated Lab Samples: 99698, 99699 Parameter Units LRB-V40207 Blank MDL Result MQL Matrix: AQU Analyzed % % Rec Recovery Limits 1,4-Dichlorobenzene pg/L <0.210 0.210 0.500 11/13/23 15:03 Dichlorodifluoromethane pg/L <1.20 1.20 5.00 11/13/23 15:03 1,1-Dichloroethane pg/L <0.240 0.240 0.500 11/13/23 15:03 1,2-Dichloroethane pg/L <0.150 0.150 0.500 11/13/23 15:03 1,1-Dichloroethene pg/L <0.150 0.150 0.500 11/13/23 15:03 cis-1,2-Dichloroethene pg/L <0.200 0.200 0.500 11/13/23 15:03 trans-1,2-Dichloroethene pg/L <0.180 0.180 0.500 11/13/23 15:03 1,2-Dichloropropane pg/L <0.190 0.190 0.500 11/13/23 15:03 1,3-Dichloropropane pg/L <0.130 0.130 0.500 11/13/23 15:03 2,2-Dichloropropane pg/L <0.210 0.210 2.00 11/13/23 15:03 1,1-Dichloropropene pg/L <0.200 0.200 0.500 11/13/23 15:03 cis-1,3-Dichloropropene pg/L <0.210 0.210 0.500 11/13/23 15:03 trans- 1,3-Dichloropropene pg/L <0.150 0.150 0.500 11/13/23 15:03 Ethylbenzene pg/L <0.170 0.170 0.500 11/13/23 15:03 Ethyl Tertiary Butyl Ether (ETBE) pg/L <1.80 1.80 10.0 11/13/23 15:03 Hexachlorobutadiene pg/L <0.350 0.350 2.00 11/13/23 15:03 n-Hexane pg/L <1.30 1.30 10.0 11/13/23 15:03 2-Hexanone pg/L <0.380 0.380 5.00 11/13/23 15:03 Isopropyl benzene pg/L <0.180 0.180 5.00 11/13/23 15:03 4-Isopropyl toluene pg/L <0.089 0.089 0.500 11/13/23 15:03 Methyl Ethyl Ketone (MEK) pg/L <0.710 0.710 5.00 11/13/23 15:03 Methyl tert-butyl ether (MTBE) pg/L <0.140 0.140 0.500 11/13/23 15:03 4-M ethyl-2 -Penta none pg/L <1.00 1.00 5.00 11/13/23 15:03 Methylene Chloride pg/L <0.330 0.330 1.00 11/13/23 15:03 Naphthalene pg/L <0.470 0.470 1.00 11/13/23 15:03 n-Propylbenzene pg/L <0.190 0.190 0.500 11/13/23 15:03 Styrene pg/L <0.220 0.220 0.500 11/13/23 15:03 Date: 11/20/2023 04:05 PM Page 14 of 18 Page 38 of 44 Waypointo ANALYTICAL Client ID: Falcon Engineering Project Description: G23O14.O2 Report No: 23-313-0014 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data QC Prep: V40207 QC Analytical Batch(es): V40208 QC Prep Batch Method: 5030E Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V40207 Matrix: AQU Associated Lab Samples: 99698, 99699 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,1,1,2-Tetrachloroethane pg/L <0.160 0.160 0.500 11/13/23 15:03 1,1,2,2-Tetrachloroethane pg/L <0.160 0.160 0.500 11/13/23 15:03 Tetrachloroethene pg/L <0.220 0.220 0.500 11/13/23 15:03 Toluene pg/L <0.220 0.220 0.500 11/13/23 15:03 1,2,3-Trichlorobenzene pg/L <0.380 0.380 2.00 11/13/23 15:03 1,2,4-Trichlorobenzene pg/L <0.310 0.310 1.00 11/13/23 15:03 1, 1, 1-Trichloroethane pg/L <0.160 0.160 0.500 11/13/23 15:03 1,1,2-Trichloroethane pg/L <0.096 0.096 0.500 11/13/23 15:03 Trichloroethene pg/L <0.180 0.180 0.500 11/13/23 15:03 Trichlorofluoromethane pg/L <0.180 0.180 0.500 11/13/23 15:03 1,2,3-Trichloropropane pg/L <0.270 0.270 1.00 11/13/23 15:03 1,3,5-Trimethylbenzene pg/L <0.180 0.180 0.500 11/13/23 15:03 Vinyl Acetate pg/L <1.00 1.00 2.00 11/13/23 15:03 Vinyl Chloride pg/L <0.170 0.170 0.500 11/13/23 15:03 o-Xylene pg/L <0.210 0.210 0.500 11/13/23 15:03 m,p-Xylene pg/L <0.420 0.420 1.00 11/13/23 15:03 4-Bromofluorobenzene (S) 11/13/23 15:03 99.2 80-124 Dibromofluoromethane (S) 11/13/23 15:03 99.2 75-129 1,2-Dichloroethane - d4 (S) 11/13/23 15:03 99.4 63-136 Toluene-d8 (S) 11/13/23 15:03 100 77-123 Laboratory Control Sample & LCSD LCS-V40207 LCSD-V40207 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Acetone pg/L 40.0 59.5 42.0 149 105 40-166 Acrolein pg/L 40.0 44.2 50.2 111 126 70-130 34.4* 20.0 12.7 20.0 * QC Fail Date: 11/20/2023 04:05 PM Page 39 of 44 Page 15 of 18 0 Waypoint, 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: G23014.02 Report No: 23-313-0014 QC Prep: V40207 QC Analytical Batch(es): V40208 QC Prep Batch Method: 5030E Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V40207 LCSD-V40207 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Acrylonitrile pg/L 40.0 38.2 42.2 95.5 106 81-127 9.9 20.0 Benzene pg/L 20.0 22.1 21.6 111 108 77-128 2.2 20.0 Bromobenzene pg/L 20.0 21.6 20.4 108 102 78-129 5.7 20.0 Bromochloromethane pg/L 20.0 21.2 21.2 106 106 78-135 0.0 20.0 Bromodichloromethane pg/L 20.0 21.5 21.0 108 105 76-138 2.3 20.0 Bromoform pg/L 20.0 20.0 20.5 100 103 71-135 2.4 20.0 Bromomethane pg/L 20.0 20.5 18.8 103 94.0 41-168 8.6 20.0 n-Butylbenzene pg/L 20.0 22.6 21.3 113 107 68-134 5.9 20.0 sec -Butyl benzene pg/L 20.0 22.1 21.1 111 106 71-131 4.6 20.0 tert-Butyl benzene pg/L 20.0 22.0 21.1 110 106 70-132 4.1 20.0 Carbon Disulfide pg/L 20.0 22.6 21.9 113 110 59-135 3.1 20.0 Carbon Tetrachloride pg/L 20.0 23.4 22.3 117 112 72-142 4.8 20.0 Chlorobenzene pg/L 20.0 22.1 21.2 111 106 78-119 4.1 20.0 Chlorodibromomethane pg/L 20.0 21.3 21.5 107 108 75-134 0.9 20.0 Chloroethane pg/L 20.0 18.5 18.3 92.5 91.5 57-142 1.0 20.0 Chloroform pg/L 20.0 21.8 20.7 109 104 77-130 5.1 20.0 Chloromethane pg/L 20.0 22.0 21.3 110 107 47-145 3.2 20.0 2-Chlorotoluene pg/L 20.0 21.9 21.2 110 106 74-126 3.2 20.0 4-Chlorotoluene pg/L 20.0 21.6 21.0 108 105 78-129 2.8 20.0 Di -Isopropyl Ether (DIPE) pg/L 20.0 22.2 22.0 111 110 60-154 0.9 20.0 1,2-Dibromo-3-Chloropropane pg/L 20.0 20.6 22.9 103 115 63-134 10.5 20.0 1,2-Dibromoethane pg/L 20.0 20.9 21.2 105 106 77-135 1.4 20.0 Dibromomethane pg/L 20.0 21.4 21.3 107 107 76-138 0.4 20.0 1,2-Dichlorobenzene pg/L 20.0 21.4 21.0 107 105 78-128 1.8 20.0 1,3-Dichlorobenzene pg/L 20.0 21.8 20.8 109 104 77-125 4.6 20.0 1,4-Dichlorobenzene pg/L 20.0 21.3 20.9 107 105 75-126 1.8 20.0 Date: 11/20/2023 04:05 PM Page 16 of 18 Page 40 of 44 Waypointo ANALYTICAL Client ID: Project Description Report No: Falcon Engineering G 23014.02 23-313-0014 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data QC Prep: V40207 QC Analytical Batch(es): V40208 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V40207 LCSD-V40207 Parameter Units Spike Conc. LCS Result LCSD Result LCS %Rec LCSD % Rec % Rec Limits RPD Max RPD Dichlorodifluoromethane pg/L 20.0 14.7 14.0 73.5 70.0 28-163 4.8 20.0 1,1-Dichloroethane pg/L 20.0 22.2 21.6 111 108 70-130 2.7 20.0 1,2-Dichloroethane pg/L 20.0 20.2 20.0 101 100 68-131 0.9 20.0 1,1-Dichloroethene pg/L 20.0 24.6 24.1 123 121 70-154 2.0 20.0 cis-1,2-Dichloroethene pg/L 20.0 21.7 20.9 109 105 76-141 3.7 20.0 trans-1,2-Dichloroethene pg/L 20.0 22.6 22.0 113 110 76-135 2.6 20.0 1,2-Dichloropropane pg/L 20.0 21.7 21.2 109 106 77-130 2.3 20.0 1,3-Dichloropropane pg/L 20.0 20.5 21.0 103 105 76-132 2.4 20.0 2,2-Dichloropropane pg/L 20.0 22.3 21.6 112 108 29-149 3.1 20.0 1,1-Dichloropropene pg/L 20.0 23.7 23.5 119 118 71-136 0.8 20.0 cis- 1,3-Dichloropropene pg/L 20.0 21.2 21.0 106 105 65-140 0.9 20.0 trans-1,3-Dichloropropene pg/L 20.0 20.3 20.6 102 103 67-140 1.4 20.0 Ethylbenzene pg/L 20.0 21.2 20.8 106 104 80-127 1.9 20.0 Ethyl Tertiary Butyl Ether (ETBE) pg/L 40.0 43.2 43.5 108 109 70-130 0.6 20.0 Hexachlorobutadiene pg/L 20.0 22.6 21.8 113 109 61-134 3.6 20.0 n-Hexane pg/L 20.0 21.3 21.4 107 107 70-130 0.4 20.0 2-Hexanone pg/L 20.0 22.9 22.6 115 113 64-137 1.3 20.0 Isopropylbenzene pg/L 20.0 22.6 21.8 113 109 70-130 3.6 20.0 4-Isopropyl toluene pg/L 20.0 22.7 21.5 114 108 69-132 5.4 20.0 Methyl Ethyl Ketone (MEK) pg/L 20.0 25.6 23.4 128 117 71-134 8.9 20.0 Methyl tert-butyl ether (MTBE) pg/L 20.0 20.5 20.8 103 104 68-135 1.4 20.0 4-Methyl-2-Pentanone pg/L 20.0 20.2 22.2 101 111 69-134 9.4 20.0 Methylene Chloride pg/L 20.0 21.7 20.9 109 105 73-131 3.7 20.0 Naphthalene pg/L 20.0 19.9 21.3 99.5 107 64-136 6.7 20.0 n-Propylbenzene pg/L 20.0 22.5 21.6 113 108 72-132 4.0 20.0 Styrene pg/L 20.0 21.3 20.8 107 104 78-129 2.3 20.0 Date: 11/20/2023 04:05 PM Page 17 of 18 Page 41 of 44 Waypo�nt0 • 449 Springbrook Rd, Charlotte, NC 2$217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: G23O14.O2 Report No: 23-313-0014 QC Prep: V40207 QC AnalyticalBatch(es): V40208 QC Prep Batch Method: 5030E Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V40207 LCSD-V40207 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD 1, 1, 1,2-Tetrachloroethane pg/L 20.0 22.4 22.0 112 110 79-134 1.8 20.0 1,1,2,2-Tetrachloroethane pg/L 20.0 21.5 22.2 108 ill 62-127 3.2 20.0 Tetrachloroethene pg/L 20.0 22.7 22.6 114 113 80-129 0.4 20.0 Toluene pg/L 20.0 21.9 21.4 110 107 76-131 2.3 20.0 1,2,3-Trichlorobenzene pg/L 20.0 23.3 24.5 117 123 58-144 5.0 20.0 1,2,4-Trichlorobenzene pg/L 20.0 23.1 23.2 116 116 66-139 0.4 20.0 1, 1, 1-Trichloroethane pg/L 20.0 22.5 22.1 113 111 75-135 1.7 20.0 1,1,2-Trichloroethane pg/L 20.0 21.2 21.4 106 107 70-140 0.9 20.0 Trichloroethene pg/L 20.0 23.5 22.6 118 113 77-133 3.9 20.0 Trichlorofluoromethane pg/L 20.0 21.1 20.8 106 104 62-148 1.4 20.0 1,2,3-Trichloropropane pg/L 20.0 18.9 20.5 94.5 103 71-127 8.1 20.0 1,3,5-Trimethylbenzene pg/L 20.0 22.3 21.4 112 107 75-131 4.1 20.0 Vinyl Acetate pg/L 20.0 21.1 21.6 106 108 34-167 2.3 20.0 Vinyl Chloride pg/L 20.0 22.1 21.8 ill 109 57-141 1.3 20.0 o-Xylene pg/L 20.0 21.6 21.0 108 105 78-128 2.8 20.0 m,p-Xylene pg/L 40.0 44.6 43.5 112 109 77-133 2.4 20.0 4-Bromofluorobenzene (S) 98.4 97.8 80-124 Dibromofluoromethane (S) 99.2 102 75-129 1,2-Dichloroethane - d4 (S) 97.0 99.0 63-136 Toluene-d8 (S) 101 101 77-123 Date: 11/20/2023 04:05 PM Page 18 of 18 Page 42 of 44 Waypoint(D ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Shipment Receipt Form Customer Number: 00122 Customer Name: Falcon Engineering Report Number: 23-313-0014 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client # Courier 0 Other: Thermometer ID: IFIT 15 3AC Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F 1 Custody seals intact on shipping container/cooler? (* Yes 0 No 0 Not Present Custody seals intact on sample bottles? 0 Yes 0 No # Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? Yes 0 No Sample containers intact? Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? (* Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved Yes 0 No 0 N/A Water - VOA vials free of headspace # Yes 0 No 0 N/A Trip Blanks received with VOAs 0 Yes (* No 0 N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) [_ Low concentration EnCore samplers (48 hr) F High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? Comments: 0 Yes (* No Signature: ngelo Norvell _ _ _j Date & Time: I'11/09/2023 13:36:27 Page 43 of 44 CHAIN OF CUSTODY RECORD LAB USE ONLY Waypoint PAGE 1._ OF QUOTE 9 TOENSM PROPER BILLING: YES NO N A _t_ r�/ 2 Samples INTACT upon arrival? ANALYTICAL Project Name: C7 01 - .0 Received IN ICE? 449 Spnngbrook Road • Charlotte, NC 28217 Short Hold Analyses (Yes) UST Project: (Yes) PROPER PRESERVATIVES indicated'.) • Phone 7041529 6364 fax: 704/$25 0409 Company Name: N 'Please ATTACH any project specific reporting (OC LEVEL I II III IV) ( Received WITHIN HOLDING TIMES? CUSTODY SEALS INTACT? Client provisions and/or CC Requgements •� 6 Report To/Contact Name:_' Q[]�1•j%&1 Invoice To: �_� _ VOLATILES rec'd WIOUT HEADSPACE'? _ k-- X Reporting Address: Address: --- - _-- - ICONT� d? _ PROPER Therm3„ TEMP: Therm ID: Observed S•`{ °C 1Cwr G ,,^ Phone: Fax Yes04. Purchase OrderNo.Billing Reference TO BE FILLEDIN BY CLIENT/SAMPLING PERSONNEL Email Address: Requested Due Date J 1 Day J 2 Days J 3 Days J 4 Days J 5 Days Certification: NC_ Sc EDD Type: PDF Excelk—Other "Working Days" J 6.9 Days *Standard 10 days J Pfsh Work Must Be !/ �- Approved other__- NIA - Site Location NaMe: /'ULb Samples received attar t 5:00 will be processed next business day Site Location Physical Address: _ (J Turnaround time is based on business days, excluding weekends and holidays REVERSE FOR TERMS S CONDITIONS REGARDING SERVICES Water Chlorinated: YES_ _-_ NO (SEE RENDERED BY WAYPOINT ANALYTICAL. LLC TO CLIENT) Samples IC peen Collection: YES NO_ TIME MATRIX SAMPLE CONTAINER I ANNAAL,YSIS REOU "]P gN` CLIENT DATE COLLECTED (SOIL, PRESERVA•� (J►1 t�J`�+ SAMPLE DESCRIPTION COLLECTED MILITARY WATER, OR��EO.SIZETIVES (%x,j' eT' REMARKS ID NO. HOURS SLUDGE) \A / AyP.j a4- in L.2s�„r U-.0c L y 1nJF �C l,�rjlt� 23-313-0014 0101ig2023 13 1934 Fa+c;n c❑amcernW --� � G2301 a I Sampler's Slgnatur Sampled By (Print Name) kSIJmIV�(1/ I tion Affilia Upon relinquishing, is Chai of Cu ody is your authorization for Waypoint Analytical to proceed with the analyses as requested above. Any changes must be submitted in writing to th Waypoint Analytical Project Manager. There will be charges for any c ges after analyses have been initialized. Site Arrival Tkrw: Relinquished By: (Signature Re By i I Date iv1d-ylHows Additional Comments: � & /S- 4 Site Departure Time: - iredBy'(Spnatui - --- - - 1(443 APK R �JSVVw) rKpashed By. Received For Waypoxn c;al By. �1= %9 1330 Field Tech Fee: Mileage: Method of ShpTWnt NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTODY SEALS FOR RTATION TO THE LABORATORY. COC Group No SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COC UNTIL RECENED AT THE LABORATORY. F•d Ex J UPS J Hend4elhWed J W"nf Anay" Freed Service J Other_ __ I _ . ___ _-- "--- I FLD OU DWA a NC J SC I ❑ NC J SC J NC J SC TER DRINKING J SC I 0 NC SC 00 NCN I J SC o C LANDFILL J SC WATER : IJ NC 0 SC IR NCB J SC I 0 ❑ _ '> J 'CONTAINER TYPE CODES: A ■ Amber C = Clear G= Glass P = Plastic; TL o Teflon•Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) IFEWJ • ' ORIGINAL W O a Waypoint(2) ANALYTICAL 11 /27/2023 Falcon Engineering Christopher Burkhardt 1210 Trinity Road Suite 110 Cary, NC, 27513 Ref: Analytical Testing Lab Report Number: 23-314-0019 Client Project Description: Arulo Dear Christopher Burkhardt: 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Waypoint Analytical, LLC (Charlotte) received sample(s) on 11 /10/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, a,_1 Angela D Overcash Senior Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 39 0 Waypoint. ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date North Carolina State Program 37735 07/31/2024 North Carolina State Program 402 12/31/2023 South Carolina State Program 99012 07/31/2024 South Carolina State Program 99012 12/31/2023 Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Alabama State Program 40750 Arkansas State Program 88-0650 California State Program 2904 Florida State Program - NELAP E871157 Georgia State Program C044 Georgia State Program 04015 Illinois State Program - NELAP 200078 Kentucky State Program 80215 Kentucky State Program KY90047 Louisiana State Program - NELAP LA037 Louisiana State Program - NELAP 04015 Mississippi State Program MS North Carolina State Program 47701 North Carolina State Program 415 Pennsylvania State Program - NELAP 68-03195 South Carolina State Program 84002 Tennessee State Program 02027 Texas State Program - NELAP T104704180 Virginia State Program 00106 Virginia State Program - NELAP 460181 Expiration Date 02/29/2024 02/07/2024 06/30/2024 06/30/2024 11 /14/2025 06/30/2024 10/31 /2024 06/30/2024 12/31/2023 12/31/2023 06/30/2024 11 /14/2025 07/31/2024 12/31/2023 05/31 /2024 06/30/2024 11 /14/2025 09/30/2024 06/30/2024 09/14/2024 Page 1 of 1 00016/23-314-0019 Page 2 of 39 0 Waypoint. 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 23-314-0019 Client Project Description: Arulo Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 99899 SMW9 Aqueous 11/09/2023 11:37 11/10/2023 11:30 99899 SMW9 Aqueous 11/09/2023 11:37 11/10/2023 11:30 365.4 WP MTN 99899 SMW9 Aqueous 11/09/2023 11:37 11/10/2023 11:30 4500NH3D-2011 WP MTN 99899 SMW9 Aqueous 11/09/2023 11:37 11/10/2023 11:30 5310C-2011 WP MTN 99899 SMW9 Aqueous 11/09/2023 11:37 11/10/2023 11:30 8315A WP MTN 99900 SMW4 Aqueous 11/09/2023 12:07 11/10/2023 11:30 99900 SMW4 Aqueous 11/09/2023 12:07 11/10/2023 11:30 8315A WP MTN 99900 SMW4 Aqueous 11/09/2023 12:07 11/10/2023 11:30 5310C-2011 WP MTN 99900 SMW4 Aqueous 11/09/2023 12:07 11/10/2023 11:30 4500NH3D-2011 WP MTN 99900 SMW4 Aqueous 11/09/2023 12:07 11/10/2023 11:30 365.4 WP MTN 99901 SMW3 Aqueous 11/09/2023 12:24 11/10/2023 11:30 99901 SMW3 Aqueous 11/09/2023 12:24 11/10/2023 11:30 4500NH3D-2011 WP MTN 99901 SMW3 Aqueous 11/09/2023 12:24 11/10/2023 11:30 365.4 WP MTN 99901 SMW3 Aqueous 11/09/2023 12:24 11/10/2023 11:30 5310C-2011 WP MTN 99901 SMW3 Aqueous 11/09/2023 12:24 11/10/2023 11:30 8315A WP MTN 99902 SMW18R Aqueous 11/09/2023 12:58 11/10/2023 11:30 99902 SMW18R Aqueous 11/09/2023 12:58 11/10/2023 11:30 5310C-2011 WP MTN 99902 SMW18R Aqueous 11/09/2023 12:58 11/10/2023 11:30 4500NH3D-2011 WP MTN 99902 SMW18R Aqueous 11/09/2023 12:58 11/10/2023 11:30 365.4 WP MTN 99902 SMW18R Aqueous 11/09/2023 12:58 11/10/2023 11:30 8315A WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 3 of 39 Waypoint(2) ANALYTICAL Client: Falcon Engineering Project: Arulo Lab Report Number. 23-314-0019 Date: 11 /27/2023 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com CASE NARRATIVE Carbonyl Compounds - HPLC Method 1667A Analyte: Formaldehyde QC Batch No: L717054 Target analyte(s) was identified in the method blank associated with this project. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected in the method blank. Anions by Ion Chromatography Method 300.0 QC Batch No: V40185N40157 LLC, LCS, and CCV failed low due to sample matrix. Sample 99759 (Clarifier) Analyte: Chloride QC Batch No: V40163N40157 The MS/MSD recoveries are outside QC limits due to the level of analyte present in the parent sample relative to the spike level. RPD is based on the MS/MSD results and should be evaluated as laboratory duplicates. Sample 99899 (SMW9) Analyte: Nitrate-N QC Batch No: V40185N40157 Sample result confirmed with re -analysis out of hold with passing QC. Sample 99900 (SMW4) Analyte: Nitrate-N QC Batch No: V40185N40157 Sample result may be biased low. Sample 99901 (SMW3) Analyte: Nitrate-N QC Batch No: V40185IV40157 Sample result confirmed with re -analysis out of hold with passing QC. Sample 99902 (SMW18R) Analyte: Nitrate-N QC Batch No: V40185N40157 Sample result may be biased low. Sample 99759 (Clarifier) Analyte: Nitrate-N QC Batch No: V40211N40157 LCS failed on initial run due to matrix interference from sample. Sample re -run at dilution out of hold with passing QC. Sample 99759 (Clarifier) Analyte: Nitrate-N Page 4 of 39 Waypoint(D ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com QC Batch No: V40211N40157 The MS/MSD recoveries are outside QC limits due to the level of analyte present in the parent sample relative to the spike level. RPD is based on the MS/MSD results and should be evaluated as laboratory duplicates. Page 5 of 39 WayPAoint. NALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalyrical.com Report Number : 23-314-0019 REPORT OFANALYSI.9 Report Date : 11/27/2023 Received : 11/10/2023 Lab No : 99899 Sample ID: SMW9 Matrix: Aqueous Sampled: 11/9/2023 11:37 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen <0.040 mg/L 0.040 0.100 1 11/22/23 15:30 JFM 4500NH3D-2011 Chloride 192 mg/L 0.370 1.00 1 11/13/2319:17 NDL 300.0 Nitrate (NO3-N) <0.076 mg/L 0.076 0.200 1 11/10/23 21:51 KNC 300.0 Total Dissolved Solids 626 mg/L 36 50 1 11/13/23 11:32 RLW 2540C-2015 Phosphorus <0.212 mg/L 0.212 0.500 1 11/21/2313:17 ANH 365.4 TOC 2.36 mg/L 0.682 1.00 1 11/14/23 21:17 ELM 531OC-2011 Qualifiers/ B Analyte detected in blank Definitions J Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 6 of 39 Waypointo ANALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Report Number :23-314-0019 REPORT OFANAL YSIS Report Date : 11/27/2023 Received : 11/10/2023 Lab No : 99899 Matrix: Aqueous Sample ID: SMW9 Sampled: 11/9/2023 11:37 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030B Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 11/14/23 22:48 MSA V40250 Acrolein <2.00 Ng/L 2.00 5.00 1 11/14/23 22:48 MSA V40250 Acrylonitrile <0.230 Ng/L 0.230 5.00 1 11/14/23 22:48 MSA V40250 Benzene <0.180 N9/L 0.180 0.500 1 11/14/23 22:48 MSA V40250 Bromobenzene <0.210 ug/L 0.210 0.500 1 11/14/23 22:48 MSA V40250 Bromochloromethane <0.420 Ng/L 0.420 1.00 1 11/14/23 22:48 MSA V40250 Bromodichloromethane <0.160 N9/L 0.160 0.500 1 11/14/23 22:48 MSA V40250 Bromoform <1.50 u9/L 1.50 5.00 1 11/14/23 22:48 MSA V40250 Bromomethane <0.280 Ng/L 0.280 1.00 1 11/14/23 22:48 MSA V40250 n-Butylbenzene <0.185 N9/L 0.185 1.00 1 11/14/23 22:48 MSA V40250 sec -Butyl benzene <0.200 Ng/L 0.200 0.500 1 11/14/23 22:48 MSA V40250 tert-Butyl benzene <0.920 N9/L 0.920 2.00 1 11/14/23 22:48 MSA V40250 Carbon Disulfide <0.150 Ng/L 0.150 5.00 1 11/14/23 22:48 MSA V40250 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 11/14/23 22:48 MSA V40250 Chlorobenzene <0.190 N9/L 0.190 0.500 1 11/14/23 22:48 MSA V40250 Chlorodibromomethane <0.190 N9/L 0.190 0.500 1 11/14/23 22:48 MSA V40250 Chloroethane <0.430 N9/L 0.430 1.00 1 11/14/23 22:48 MSA V40250 Chloroform <0.220 Ng/L 0.220 0.500 1 11/14/23 22:48 MSA V40250 Chloromethane <0.220 N9/L 0.220 0.500 1 11/14/23 22:48 MSA V40250 2-Chlorotoluene <0.200 N9/L 0.200 0.500 1 11/14/23 22:48 MSA V40250 4-Chlorotoluene <0.200 ug/L 0.200 0.500 1 11/14/23 22:48 MSA V40250 Di -Isopropyl Ether (DIPE) <0.960 ug/L 0.960 5.00 1 11/14/23 22:48 MSA V40250 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 7 of 39 WayPAoint. NALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number:23-314-0019 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com REPORT OFANALY515 Report Date : 11/27/2023 Received : 11/10/2023 Lab No : 99899 Matrix: Aqueous Sample ID: SMW9 Sampled: 11/9/2023 11:37 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030B Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,2-Dibromo-3-Chloropropane <1.10 pg/L 1.10 2.00 1 11/14/23 22:48 MSA V40250 1,2-Dibromoethane <0.200 pg/L 0.200 0.500 1 11/14/23 22:48 MSA V40250 Dibromomethane <0.230 pg/L 0.230 0.500 1 11/14/23 22:48 MSA V40250 1,2-Dichlorobenzene <0.220 pg/L 0.220 0.500 1 11/14/23 22:48 MSA V40250 1,3-Dichlorobenzene <0.190 p9/L 0.190 0.500 1 11/14/23 22:48 MSA V40250 1,4-Dichlorobenzene <0.210 pg/L 0.210 0.500 1 11/14/23 22:48 MSA V40250 Dichlorodifluoromethane <1.20 pg/L 1.20 5.00 1 11/14/23 22:48 MSA V40250 1,1-Dichloroethane <0.240 pg/L 0.240 0.500 1 11/14/23 22:48 MSA V40250 1,2-Dichloroethane <0.150 pg/L 0.150 0.500 1 11/14/23 22:48 MSA V40250 1,1-Dichloroethene <0.150 pg/L 0.150 0.500 1 11/14/23 22:48 MSA V40250 cis- 1,2-Dichloroethene <0.200 pg/L 0.200 0.500 1 11/14/23 22:48 MSA V40250 trans- 1,2-Dichloroethene <0.180 pg/L 0.180 0.500 1 11/14/23 22:48 MSA V40250 1,2-Dichloropropane <0.190 pg/L 0.190 0.500 1 11/14/23 22:48 MSA V40250 1,3-Dichloropropane <0.130 pg/L 0.130 0.500 1 11/14/23 22:48 MSA V40250 2,2-Dichloropropane <0.210 pg/L 0.210 2.00 1 11/14/23 22:48 MSA V40250 1,1-Dichloropropene <0.200 pg/L 0.200 0.500 1 11/14/23 22:48 MSA V40250 cis-1,3-Dichloropropene <0.210 pg/L 0.210 0.500 1 11/14/23 22:48 MSA V40250 trans-1,3-Dichloropropene <0.150 pg/L 0.150 0.500 1 11/14/23 22:48 MSA V40250 Ethylbenzene <0.170 pg/L 0.170 0.500 1 11/14/23 22:48 MSA V40250 Ethyl Tertiary Butyl Ether (ETBE) <1.80 pg/L 1.80 10.0 1 11/14/23 22:48 MSA V40250 Hexachlorobutadiene <0.350 pg/L 0.350 2.00 1 11/14/23 22:48 MSA V40250 n-Hexane <1.30 pg/L 1.30 10.0 1 11/14/23 22:48 MSA V40250 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 8 of 39 WayPAoint. NALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-314-0019 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com REPORT Of ANAL YSIS Report Date : 11/27/2023 Received : 11/10/2023 Lab No : 99899 Matrix: Aqueous Sample ID: SMW9 Sampled: 11/9/2023 11:37 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030E Test Results Units MDL MOL DF Date / Time By Analytical Analyzed Batch 2-Hexanone <0.380 pg/L 0.380 5.00 1 11/14/23 22:48 MSA V40250 Isopropylbenzene <0.180 pg/L 0.180 5.00 1 11/14/23 22:48 MSA V40250 4-Isopropyl toluene <0.089 pg/L 0.089 0.500 1 11/14/23 22:48 MSA V40250 Methyl Ethyl Ketone (MEK) 1.793 pg/L 0.710 5.00 1 11/14/23 22:48 MSA V40250 Methyl tert-butyl ether (MTBE) <0.140 pg/L 0.140 0.500 1 11/14/23 22:48 MSA V40250 4-Methyl-2-Pentanone <1.00 pg/L 1.00 5.00 1 11/14/23 22:48 MSA V40250 Methylene Chloride <0.330 pg/L 0.330 1.00 1 11/14/23 22:48 MSA V40250 Naphthalene <0.470 pg/L 0.470 1.00 1 11/14/23 22:48 MSA V40250 n-Propylbenzene <0.190 pg/L 0.190 0.500 1 11/14/23 22:48 MSA V40250 Styrene <0.220 pg/L 0.220 0.500 1 11/14/23 22:48 MSA V40250 1,1,1,2-Tetrachloroethane <0.160 pg/L 0.160 0.500 1 11/14/23 22:48 MSA V40250 1,1,2,2-Tetrachloroethane <0.160 pg/L 0.160 0.500 1 11/14/23 22:48 MSA V40250 Tetrachloroethene <0.220 pg/L 0.220 0.500 1 11/14/23 22:48 MSA V40250 Toluene <0.220 pg/L 0.220 0.500 1 11/14/23 22:48 MSA V40250 1,2,3-Trichlorobenzene <0.380 pg/L 0.380 2.00 1 11/14/23 22:48 MSA V40250 1,2,4-Trichlorobenzene <0.310 pg/L 0.310 1.00 1 11/14/23 22:48 MSA V40250 1, 1, 1-Trichloroethane <0.160 pg/L 0.160 0.500 1 11/14/23 22:48 MSA V40250 1,1,2-Trichloroethane <0.096 pg/L 0.096 0.500 1 11/14/23 22:48 MSA V40250 Trichloroethene <0.180 p9/L 0.180 0.500 1 11/14/23 22:48 MSA V40250 Trichlorofluoromethane <0.180 pg/L 0.180 0.500 1 11/14/23 22:48 MSA V40250 1,2,3-Trichloropropane <0.270 pg/L 0.270 1.00 1 11/14/23 22:48 MSA V40250 1,3,5-Trimethylbenzene <0.180 pg/L 0.180 0.500 1 11/14/23 22:48 MSA V40250 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 9 of 39 • Way 449 Springbrook Rd, Ch0 arlotte, NC 28217 Pnt. Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 00122 Falcon Engineering Project Arulo Christopher Burkhardt Report Date : 11/27/2023 1210 Trinity Road Information : Received : 11/10/2023 Suite 110 Cary , NC 27513 Report Number : 23-314-0019 REPORTOPANALYSIS Lab No : 99899 Matrix: Aqueous Sample ID: SMW9 Sampled: 11/9/2023 11:37 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030B Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Vinyl Acetate <1.00 N9/L 1.00 2.00 1 11/14/23 22:48 MSA V40250 Vinyl Chloride <0.170 Ng/L 0.170 0.500 1 11/14/23 22:48 MSA V40250 o-Xylene <0.210 Ng/L 0.210 0.500 1 11/14/23 22:48 MSA V40250 m,p-Xylene <0.420 Ng/L 0.420 1.00 1 11/14/23 22:48 MSA V40250 Xylene (Total) <0.21 Ng/L 0.210 0.500 1 11/14/23 22:48 V40250 Surrogate: 4-Bromofluorobenzene 102 Limits: 80-124% 1 11/14/23 22:48 MSA V40250 Surrogate: Dibromofluoromethane 96.6 Limits: 75-129% 1 11/14/23 22:48 MSA V40250 Surrogate: 1,2-Dichloroethane - d4 92.2 Limits: 63-136% 1 11/14/23 22:48 MSA V40250 Surrogate: Toluene-d8 95.6 Limits: 77-123% 1 11/14/23 22:48 MSA V40250 Analytical Method: 8315A Prep Batch(es): L716914 11/12/23 12:00 Prep Method: 8315A Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Formaldehyde 21.1 B pg/L 10.0 10.0 1 11/14/23 17:21 KDL L717054 Qualifiers/ B Analyte detected in blank Definitions I Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 10 of 39 • Way nt 449 5pringbrook Rd, Ch(2) arlotte, NC 28217 Poi . Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 00122 Falcon Engineering Project Arulo Christopher Burkhardt Report Date : 11/27/2023 1210 Trinity Road Information : Received : 11/10/2023 Suite 110 Cary , NC 27513 Report Number : 23-314-0019 REPORTOFANALYSIS Lab No : 99900 Matrix: Aqueous Sample ID: SMW4 Sampled: 11/9/2023 12:07 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen <0.040 mg/L 0.040 0.100 1 11/22/23 15:30 JFM 4500NH3D-2011 Chloride 569 mg/L 3.70 10.0 10 11/13/2319:42 NDL 300.0 Nitrate (NO3-N) 0.1261 mg/L 0.076 0.200 1 11/10/23 22:04 KNC 300.0 Total Dissolved Solids 1190 mg/L 36 50 1 11/13/23 11:32 RLW 2540C-2015 Phosphorus <0.212 mg/L 0.212 0.500 1 11/21/2313:18 ANH 365.4 TOC 1.88 mg/L 0.682 1.00 1 11/14/23 21:55 ELM 531OC-2011 Qualifiers/ B Analyte detected in blank Definitions J Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 11 of 39 Waypointo ANALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-314-0019 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com REPORT OFANAL YSIS Report Date : 11/27/2023 Received : 11/10/2023 Lab No : 99900 Matrix: Aqueous Sample ID: SMW4 Sampled: 11/9/2023 12:07 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030B Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 pg/L 1.80 5.00 1 11/14/23 23:13 MSA V40250 Acrolein <2.00 pg/L 2.00 5.00 1 11/14/23 23:13 MSA V40250 Acrylonitrile <0.230 pg/L 0.230 5.00 1 11/14/23 23:13 MSA V40250 Benzene <0.180 pg/L 0.180 0.500 1 11/14/23 23:13 MSA V40250 Bromobenzene <0.210 pg/L 0.210 0.500 1 11/14/23 23:13 MSA V40250 Bromochloromethane <0.420 pg/L 0.420 1.00 1 11/14/23 23:13 MSA V40250 Bromodichloromethane <0.160 pg/L 0.160 0.500 1 11/14/23 23:13 MSA V40250 Bromoform <1.50 pg/L 1.50 5.00 1 11/14/23 23:13 MSA V40250 Bromomethane <0.280 pg/L 0.280 1.00 1 11/14/23 23:13 MSA V40250 n-Butylbenzene <0.185 pg/L 0.185 1.00 1 11/14/23 23:13 MSA V40250 sec -Butyl benzene <0.200 pg/L 0.200 0.500 1 11/14/23 23:13 MSA V40250 tert-Butyl benzene <0.920 pg/L 0.920 2.00 1 11/14/23 23:13 MSA V40250 Carbon Disulfide <0.150 pg/L 0.150 5.00 1 11/14/23 23:13 MSA V40250 Carbon Tetrachloride <0.180 pg/L 0.180 0.500 1 11/14/23 23:13 MSA V40250 Chlorobenzene <0.190 pg/L 0.190 0.500 1 11/14/23 23:13 MSA V40250 Chlorodibromomethane <0.190 pg/L 0.190 0.500 1 11/14/23 23:13 MSA V40250 Chloroethane <0.430 pg/L 0.430 1.00 1 11/14/23 23:13 MSA V40250 Chloroform <0.220 pg/L 0.220 0.500 1 11/14/23 23:13 MSA V40250 Chloromethane <0.220 pg/L 0.220 0.500 1 11/14/23 23:13 MSA V40250 2-Chlorotoluene <0.200 pg/L 0.200 0.500 1 11/14/23 23:13 MSA V40250 4-Chlorotoluene <0.200 pg/L 0.200 0.500 1 11/14/23 23:13 MSA V40250 Di -Isopropyl Ether (DIPE) <0.960 pg/L 0.960 5.00 1 11/14/23 23:13 MSA V40250 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 12 of 39 WayPAoint. NALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-314-0019 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com REPORT OFANAL YSIS Report Date : 11/27/2023 Received : 11/10/2023 Lab No : 99900 Matrix: Aqueous Sample ID: SMW4 Sampled: 11/9/2023 12:07 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,2-Dibromo-3-Chloropropane <1.10 pg/L 1.10 2.00 1 11/14/23 23:13 MSA V40250 1,2-Dibromoethane <0.200 pg/L 0.200 0.500 1 11/14/23 23:13 MSA V40250 Dibromomethane <0.230 pg/L 0.230 0.500 1 11/14/23 23:13 MSA V40250 1,2-Dichlorobenzene <0.220 pg/L 0.220 0.500 1 11/14/23 23:13 MSA V40250 1,3-Dichlorobenzene <0.190 pg/L 0.190 0.500 1 11/14/23 23:13 MSA V40250 1,4-Dichlorobenzene <0.210 pg/L 0.210 0.500 1 11/14/23 23:13 MSA V40250 Dichlorodifluoromethane <1.20 pg/L 1.20 5.00 1 11/14/23 23:13 MSA V40250 1,1-Dichloroethane <0.240 pg/L 0.240 0.500 1 11/14/23 23:13 MSA V40250 1,2-Dichloroethane <0.150 pg/L 0.150 0.500 1 11/14/23 23:13 MSA V40250 1,1-Dichloroethene <0.150 pg/L 0.150 0.500 1 11/14/23 23:13 MSA V40250 cis- 1,2-Dichloroethene <0.200 pg/L 0.200 0.500 1 11/14/23 23:13 MSA V40250 trans- 1,2-Dichloroethene <0.180 pg/L 0.180 0.500 1 11/14/23 23:13 MSA V40250 1,2-Dichloropropane <0.190 pg/L 0.190 0.500 1 11/14/23 23:13 MSA V40250 1,3-Dichloropropane <0.130 pg/L 0.130 0.500 1 11/14/23 23:13 MSA V40250 2,2-Dichloropropane <0.210 pg/L 0.210 2.00 1 11/14/23 23:13 MSA V40250 1,1-Dichloropropene <0.200 pg/L 0.200 0.500 1 11/14/23 23:13 MSA V40250 cis-1,3-Dichloropropene <0.210 pg/L 0.210 0.500 1 11/14/23 23:13 MSA V40250 trans-1,3-Dichloropropene <0.150 pg/L 0.150 0.500 1 11/14/23 23:13 MSA V40250 Ethylbenzene <0.170 p9/L 0.170 0.500 1 11/14/23 23:13 MSA V40250 Ethyl Tertiary Butyl Ether (ETBE) <1.80 pg/L 1.80 10.0 1 11/14/23 23:13 MSA V40250 Hexachlorobutadiene <0.350 pg/L 0.350 2.00 1 11/14/23 23:13 MSA V40250 n-Hexane <1.30 pg/L 1.30 10.0 1 11/14/23 23:13 MSA V40250 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 13 of 39 WayPAoint. NALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-314-0019 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytica Isom REPORT OFANAL YSIS Report Date : 11/27/2023 Received : 11/10/2023 Lab No : 99900 Matrix: Aqueous Sample ID: SMW4 Sampled: 11/9/2023 12:07 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 2-Hexanone <0.380 pg/L 0.380 5.00 1 11/14/23 23:13 MSA V40250 Isopropyl benzene <0.180 pg/L 0.180 5.00 1 11/14/23 23:13 MSA V40250 4-Isopropyl toluene <0.089 pg/L 0.089 0.500 1 11/14/23 23:13 MSA V40250 Methyl Ethyl Ketone (MEK) 1.613 p9/L 0.710 5.00 1 11/14/23 23:13 MSA V40250 Methyl tert-butyl ether (MTBE) <0.140 pg/L 0.140 0.500 1 11/14/23 23:13 MSA V40250 4-Methyl-2-Pentanone <1.00 pg/L 1.00 5.00 1 11/14/23 23:13 MSA V40250 Methylene Chloride <0330 pg/L 0.330 1.00 1 11/14/23 23:13 MSA V40250 Naphthalene <0.470 p9/L 0.470 1.00 1 11/14/23 23:13 MSA V40250 n-Propylbenzene <0.190 p9/L 0.190 0.500 1 11/14/23 23:13 MSA V40250 Styrene <0.220 pg/L 0.220 0.500 1 11/14/23 23:13 MSA V40250 1, 1, 1,2-Tetrachloroethane <0.160 pg/L 0.160 0.500 1 11/14/23 23:13 MSA V40250 1,1,2,2-Tetrachloroethane <0.160 p9/L 0.160 0.500 1 11/14/23 23:13 MSA V40250 Tetrachloroethene <0.220 pg/L 0.220 0.500 1 11/14/23 23:13 MSA V40250 Toluene <0.220 pg/L 0.220 0.500 1 11/14/23 23:13 MSA V40250 1,2,3-Trichlorobenzene <0.380 pg/L 0.380 2.00 1 11/14/23 23:13 MSA V40250 1,2,4-Trichlorobenzene <0.310 pg/L 0.310 1.00 1 11/14/23 23:13 MSA V40250 1, 1, 1-Trichloroethane <0.160 pg/L 0.160 0.500 1 11/14/23 23:13 MSA V40250 1,1,2-Trichloroethane <0.096 pg/L 0.096 0.500 1 11/14/23 23:13 MSA V40250 Trichloroethene <0.180 pg/L 0.180 0.500 1 11/14/23 23:13 MSA V40250 Trichlorofluoromethane <0.180 pg/L 0.180 0.500 1 11/14/23 23:13 MSA V40250 1,2,3-Trichloropropane <0.270 pg/L 0.270 1.00 1 11/14/23 23:13 MSA V40250 1,3,5-Trimethylbenzene <0.180 pg/L 0.180 0.500 1 11/14/23 23:13 MSA V40250 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 14 of 39 • WayPoint. 449 Springbrook Rd, Ch(2) arlotte, NC 28217 Main 704.529.6364 A N A LYT I CA L www.waypointanalytica I-com 00122 Falcon Engineering Project Arulo Christopher Burkhardt Report Date : 11/27/2023 1210 Trinity Road Information : Received : 11/10/2023 Suite 110 Cary , NC 27513 Report Number :23-314-0019 REPORTOFANALYSIS Lab No : 99900 Matrix: Aqueous Sample ID: SMW4 Sampled: 11/9/2023 12:07 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Vinyl Acetate <1.00 Ng/L 1.00 2.00 1 11/14/23 23:13 MSA V40250 Vinyl Chloride <0.170 ug/L 0.170 0.500 1 11/14/23 23:13 MSA V40250 o-Xylene <0.210 Ng/L 0.210 0.500 1 11/14/23 23:13 MSA V40250 m,p-Xylene <0.420 Ng/L 0.420 1.00 1 11/14/23 23:13 MSA V40250 Xylene (Total) <0.21 Ng/L 0.210 0.500 1 11/14/23 23:13 V40250 Surrogate: 4-Bromofluorobenzene 101 Limits: 80-124% 1 11/14/23 23:13 MSA V40250 Surrogate: Dibromofluoromethane 97.0 Limits: 75-129% 1 11/14/23 23:13 MSA V40250 Surrogate: 1,2-Dichloroethane - d4 94.6 Limits: 63-136% 1 11/14/23 23:13 MSA V40250 Surrogate: Toluene-d8 95.8 Limits: 77-123% 1 11/14/23 23:13 MSA V40250 Analytical Method: 8315A Prep Batch(es): L716914 11/12/23 12:00 Prep Method: 8315A Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Formaldehyde 22.9 B Ng/L 10.0 10.0 1 11/14/23 17:32 KDL L717054 Qualifiers/ B Analyte detected in blank Definitions 3 Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 15 of 39 • Way nt 449 Springbrook Rd, Ch0 arlotte, NC 28217 PAoi . Main 704.529.6364 N A LYT I CAL www.waypointanalytical.com 00122 Falcon Engineering Project Arulo Christopher Burkhardt Report Date : 11/27/2023 1210 Trinity Road Information : Received : 11/10/2023 Suite 110 Cary , NC 27513 Report Number : 23-314-0019 REPORT OFANAL YSIS Lab No : 99901 Matrix: Aqueous Sample ID: SMW3 Sampled: 11/9/2023 12:24 Test Results Units MDL MOL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen <0.040 mg/L 0.040 0.100 1 11/22/23 15:30 JFM 4500NH3D-2011 Chloride 7.13 mg/L 0.370 1.00 1 11/13/2319:54 NDL 300.0 Nitrate (NO3-N) 2.74 mg/L 0.076 0.200 1 11/10/23 22:16 KNC 300.0 Total Dissolved Solids 481 mg/L 36 50 1 11/13/23 11:32 RLW 2540C-2015 Phosphorus <0.212 mg/L 0.212 0.500 1 11/21/2313:19 ANH 365.4 TOC 1.48 mg/L 0.682 1.00 1 11/14/23 22:33 ELM 531OC-2011 Qualifiers/ B Analyte detected in blank Definitions J Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 16 of 39 Waypoint.0 ANALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number:23-314-0019 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com REPORT OPANAL YSIS Report Date : 11/27/2023 Received : 11/10/2023 Lab No : 99901 Matrix: Aqueous Sample ID: SMW3 Sampled: 11/9/2023 12:24 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030B Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 pg/L 1.80 5.00 1 11/14/23 23:37 MSA V40250 Acrolein <2.00 pg/L 2.00 5.00 1 11/14/23 23:37 MSA V40250 Acrylonitrile <0.230 pg/L 0.230 5.00 1 11/14/23 23:37 MSA V40250 Benzene <0.180 p9/L 0.180 0.500 1 11/14/23 23:37 MSA V40250 Bromobenzene <0.210 pg/L 0.210 0.500 1 11/14/23 23:37 MSA V40250 Bromochloromethane <0.420 pg/L 0.420 1.00 1 11/14/23 23:37 MSA V40250 Bromodichloromethane <0.160 pg/L 0.160 0.500 1 11/14/23 23:37 MSA V40250 Bromoform <1.50 pg/L 1.50 5.00 1 11/14/23 23:37 MSA V40250 Bromomethane <0.280 pg/L 0.280 1.00 1 11/14/23 23:37 MSA V40250 n-Butylbenzene <0.185 pg/L 0.185 1.00 1 11/14/23 23:37 MSA V40250 sec -Butyl benzene <0.200 pg/L 0.200 0.500 1 11/14/23 23:37 MSA V40250 tert-Butyl benzene <0.920 pg/L 0.920 2.00 1 11/14/23 23:37 MSA V40250 Carbon Disulfide <0.150 pg/L 0.150 5.00 1 11/14/23 23:37 MSA V40250 Carbon Tetrachloride <0.180 pg/L 0.180 0.500 1 11/14/23 23:37 MSA V40250 Chlorobenzene <0.190 pg/L 0.190 0.500 1 11/14/23 23:37 MSA V40250 Chlorodibromomethane <0.190 pg/L 0.190 0.500 1 11/14/23 23:37 MSA V40250 Chloroethane <0.430 pg/L 0.430 1.00 1 11/14/23 23:37 MSA V40250 Chloroform <0.220 pg/L 0.220 0.500 1 11/14/23 23:37 MSA V40250 Chloromethane <0.220 pg/L 0.220 0.500 1 11/14/23 23:37 MSA V40250 2-Chlorotoluene <0.200 pg/L 0.200 0.500 1 11/14/23 23:37 MSA V40250 4-Chlorotoluene <0.200 pg/L 0.200 0.500 1 11/14/23 23:37 MSA V40250 Di -Isopropyl Ether (DIPE) <0.960 pg/L 0.960 5.00 1 11/14/23 23:37 MSA V40250 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 17 of 39 Waypointo ANALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-314-0019 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com REPORT OPANAL YSIS Report Date : 11/27/2023 Received : 11/10/2023 Lab No : 99901 Sample ID: SMW3 Matrix: Aqueous Sampled: 11/9/2023 12:24 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030B Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,2-Dibromo-3-Chloropropane <1.10 pg/L 1.10 2.00 1 11/14/23 23:37 MSA V40250 1,2-Dibromoethane <0.200 pg/L 0.200 0.500 1 11/14/23 23:37 MSA V40250 Dibromomethane <0.230 pg/L 0.230 0.500 1 11/14/23 23:37 MSA V40250 1,2-Dichlorobenzene <0.220 pg/L 0.220 0.500 1 11/14/23 23:37 MSA V40250 1,3-Dichlorobenzene <0.190 pg/L 0.190 0.500 1 11/14/23 23:37 MSA V40250 1,4-Dichlorobenzene <0.210 pg/L 0.210 0.500 1 11/14/23 23:37 MSA V40250 Dichlorodifluoromethane <1.20 pg/L 1.20 5.00 1 11/14/23 23:37 MSA V40250 1,1-Dichloroethane <0.240 pg/L 0.240 0.500 1 11/14/23 23:37 MSA V40250 1,2-Dichloroethane <0.150 pg/L 0.150 0.500 1 11/14/23 23:37 MSA V40250 1,1-Dichloroethene <0.150 pg/L 0.150 0.500 1 11/14/23 23:37 MSA V40250 cis-1,2-Dichloroethene <0.200 p9/L 0.200 0.500 1 11/14/23 23:37 MSA V40250 trans- 1, 2-Dich loroethene <0.180 p9/L 0.180 0.500 1 11/14/23 23:37 MSA V40250 1,2-Dichloropropane <0.190 pg/L 0.190 0.500 1 11/14/23 23:37 MSA V40250 1,3-Dichloropropane <0.130 pg/L 0.130 0.500 1 11/14/23 23:37 MSA V40250 2,2-Dichloropropane <0.210 pg/L 0.210 2.00 1 11/14/23 23:37 MSA V40250 1,1-Dichloropropene <0.200 p9/L 0.200 0.500 1 11/14/23 23:37 MSA V40250 cis- 1,3-Dichloropropene <0.210 pg/L 0.210 0.500 1 11/14/23 23:37 MSA V40250 trans- 1,3-Dichloropropene <0.150 pg/L 0.150 0.500 1 11/14/23 23:37 MSA V40250 Ethylbenzene <0.170 pg/L 0.170 0.500 1 11/14/23 23:37 MSA V40250 Ethyl Tertiary Butyl Ether (ETBE) <1.80 pg/L 1.80 10.0 1 11/14/23 23:37 MSA V40250 Hexachlorobutadiene <0.350 pg/L 0.350 2.00 1 11/14/23 23:37 MSA V40250 n-Hexane <1.30 pg/L 1.30 10.0 1 11/14/23 23:37 MSA V40250 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions 3 Estimated value MQL Method Quantitation Limit Page 18 of 39 WayPAoint. NALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-314-0019 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com REPORTOFANALYSIS Report Date : 11/27/2023 Received : 11/10/2023 Lab No : 99901 Matrix: Aqueous Sample ID: SMW3 Sampled: 11/9/2023 12:24 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 2-Hexanone <0.380 pg/L 0.380 5.00 1 11/14/23 23:37 MSA V40250 Isopropylbenzene <0.180 p9/L 0.180 5.00 1 11/14/23 23:37 MSA V40250 4-Isopropyl toluene <0.089 pg/L 0.089 0.500 1 11/14/23 23:37 MSA V40250 Methyl Ethyl Ketone (MEK) <0.710 pg/L 0.710 5.00 1 11/14/23 23:37 MSA V40250 Methyl tert-butyl ether (MTBE) <0.140 p9/L 0.140 0.500 1 11/14/23 23:37 MSA V40250 4-Methyl-2-Pentanone <1.00 pg/L 1.00 5.00 1 11/14/23 23:37 MSA V40250 Methylene Chloride <0.330 pg/L 0.330 1.00 1 11/14/23 23:37 MSA V40250 Naphthalene <0.470 pg/L 0.470 1.00 1 11/14/23 23:37 MSA V40250 n-Propylbenzene <0.190 pg/L 0.190 0.500 1 11/14/23 23:37 MSA V40250 Styrene <0.220 pg/L 0.220 0.500 1 11/14/23 23:37 MSA V40250 1,1,1,2-Tetrachloroethane <0.160 p9/L 0.160 0.500 1 11/14/23 23:37 MSA V40250 1,1,2,2-Tetrachloroethane <0.160 pg/L 0.160 0.500 1 11/14/23 23:37 MSA V40250 Tetrachloroethene <0.220 pg/L 0.220 0.500 1 11/14/23 23:37 MSA V40250 Toluene <0.220 pg/L 0.220 0.500 1 11/14/23 23:37 MSA V40250 1,2,3-Trichlorobenzene <0.380 pg/L 0.380 2.00 1 11/14/23 23:37 MSA V40250 1,2,4-Trichlorobenzene <0.310 pg/L 0.310 1.00 1 11/14/23 23:37 MSA V40250 1, 1, 1-Trichloroethane <0.160 pg/L 0.160 0.500 1 11/14/23 23:37 MSA V40250 1,1,2-Trichloroethane <0.096 pg/L 0.096 0.500 1 11/14/23 23:37 MSA V40250 Trichloroethene <0.180 pg/L 0.180 0.500 1 11/14/23 23:37 MSA V40250 Trichlorofluoromethane <0.180 pg/L 0.180 0.500 1 11/14/23 23:37 MSA V40250 1,2,3-Trichloropropane <0.270 p9/L 0.270 1.00 1 11/14/23 23:37 MSA V40250 1,3,5-Trimethylbenzene <0.180 p9/L 0.180 0.500 1 11/14/23 23:37 MSA V40250 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 19 of 39 Waypointo ANALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Report Date : 11/27/2023 Received : 11/10/2023 Report Number : 23-314-0019 REPORT OFANALYBIS Lab No : 99901 Matrix: Aqueous Sample ID: SMW3 Sampled: 11/9/2023 12:24 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Vinyl Acetate <1.00 Vg/L 1.00 2.00 1 11/14/23 23:37 MSA V40250 Vinyl Chloride <0.170 Ng/L 0.170 0.500 1 11/14/23 23:37 MSA V40250 o-Xylene <0.210 ug/L 0.210 0.500 1 11/14/23 23:37 MSA V40250 m,p-Xylene <0.420 Ng/L 0.420 1.00 1 11/14/23 23:37 MSA V40250 Xylene (Total) <0.21 Ng/L 0.210 0.500 1 11/14/23 23:37 V40250 Surrogate: 4-Bromofluorobenzene 103 Limits: 80-124% 1 11/14/23 23:37 MSA V40250 Surrogate: Dibromofluoromethane 96.8 Limits: 75-129% 1 11/14/23 23:37 MSA V40250 Surrogate: 1,2-Dichloroethane - d4 90.8 Limits: 63-136% 1 11/14/23 23:37 MSA V40250 Surrogate: Toluene-d8 96.6 Limits: 77-123% 1 11/14/23 23:37 MSA V40250 Analytical Method: 8315A Prep Batch(es): L716914 11/12/23 12:00 Prep Method: 8315A Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Formaldehyde 23.8 B Ng/L 10.0 10.0 1 11/14/23 17:43 KDL L717054 Qualifiers/ B Analyte detected in blank Definitions I Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 20 of 39 Waypointo ANALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Report Number :23-314-0019 REPORT OFANAL YSIS Report Date : 11/27/2023 Received : 11/10/2023 Lab No : 99902 Sample ID: SMW18R Matrix: Aqueous Sampled: 11/9/2023 12:58 Test Results Units MDL MOL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen <0.040 mg/L 0.040 0.100 1 11/22/23 15:30 JFM 4500NH3D-2011 Chloride 12.1 mg/L 0.370 1.00 1 11/13/23 20:06 NDL 300.0 Nitrate (NO3-N) 0.0773 mg/L 0.076 0.200 1 11/10/23 22:29 KNC 300.0 Total Dissolved Solids 70 mg/L 36 50 1 11/13/23 11:32 RLW 2540C-2015 Phosphorus <0.212 mg/L 0.212 0.500 1 11/21/2313:20 ANH 365.4 TOC 1.02 mg/L 0.682 1.00 1 11/14/23 23:11 ELM 531OC-2011 Qualifiers/ B Analyte detected in blank Definitions J Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 21 of 39 (D WayPAoint. NALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-314-0019 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com REPORT OFANAL Y.414 Report Date : 11/27/2023 Received : 11/10/2023 Lab No : 99902 Matrix: Aqueous Sample ID : SMW18R Sampled: 11/9/2023 12:58 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030B Test Results Units MDL M01. DF Date / Time By Analytical Analyzed Batch Acetone 1.883 ug/L 1.80 5.00 1 11/15/23 00:02 MSA V40250 Acrolein <2.00 Ng/L 2.00 5.00 1 11/15/23 00:02 MSA V40250 Acrylonitrile <0.230 ug/L 0.230 5.00 1 11/15/23 00:02 MSA V40250 Benzene <0.180 ug/L 0.180 0.500 1 11/15/23 00:02 MSA V40250 Bromobenzene <0.210 Ng/L 0.210 0.500 1 11/15/23 00:02 MSA V40250 Bromochloromethane <0.420 Ng/L 0.420 1.00 1 11/15/23 00:02 MSA V40250 Bromodichloromethane <0.160 ug/L 0.160 0.500 1 11/15/23 00:02 MSA V40250 Bromoform <1.50 Ng/L 1.50 5.00 1 11/15/23 00:02 MSA V40250 Bromomethane <0.280 Ng/L 0.280 1.00 1 11/15/23 00:02 MSA V40250 n-Butylbenzene <0.185 Ng/L 0.185 1.00 1 11/15/23 00:02 MSA V40250 sec -Butyl benzene <0.200 Ng/L 0.200 0.500 1 11/15/23 00:02 MSA V40250 tert-Butyl benzene <0.920 Ng/L 0.920 2.00 1 11/15/23 00:02 MSA V40250 Carbon Disulfide <0.150 Ng/L 0.150 5.00 1 11/15/23 00:02 MSA V40250 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 11/15/23 00:02 MSA V40250 Chlorobenzene <0.190 ug/L 0.190 0.500 1 11/15/23 00:02 MSA V40250 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 11/15/23 00:02 MSA V40250 Chloroethane <0.430 Ng/L 0.430 1.00 1 11/15/23 00:02 MSA V40250 Chloroform <0.220 ug/L 0.220 0.500 1 11/15/23 00:02 MSA V40250 Chloromethane <0.220 Ng/L 0.220 0.500 1 11/15/23 00:02 MSA V40250 2-Chlorotoluene <0.200 Ng/L 0.200 0.500 1 11/15/23 00:02 MSA V40250 4-Chlorotoluene <0.200 ug/L 0.200 0.500 1 11/15/23 00:02 MSA V40250 Di -Isopropyl Ether (DIPE) <0.960 ug/L 0.960 5.00 1 11/15/23 00:02 MSA V40250 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 22 of 39 Waypointo ANALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number:23-314-0019 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com REPORT OFANAL YSIS Report Date : 11/27/2023 Received : 11/10/2023 Lab No : 99902 Matrix: Aqueous Sample ID: SMW18R Sampled: 11/9/2023 12:58 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030B Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,2-Dibromo-3-Chloropropane <1.10 pg/L 1.10 2.00 1 11/15/23 00:02 MSA V40250 1,2-Dibromoethane <0.200 pg/L 0.200 0.500 1 11/15/23 00:02 MSA V40250 Dibromomethane <0.230 pg/L 0.230 0.500 1 11/15/23 00:02 MSA V40250 1,2-Dichlorobenzene <0.220 pg/L 0.220 0.500 1 11/15/23 00:02 MSA V40250 1,3-Dichlorobenzene <0.190 pg/L 0.190 0.500 1 11/15/23 00:02 MSA V40250 1,4-Dichlorobenzene <0.210 pg/L 0.210 0.500 1 11/15/23 00:02 MSA V40250 Dichlorodifluoromethane <1.20 pg/L 1.20 5.00 1 11/15/23 00:02 MSA V40250 1,1-Dichloroethane <0.240 pg/L 0.240 0.500 1 11/15/23 00:02 MSA V40250 1,2-Dichloroethane <0.150 pg/L 0.150 0.500 1 11/15/23 00:02 MSA V40250 1,1-Dichloroethene <0.150 pg/L 0.150 0.500 1 11/15/23 00:02 MSA V40250 cis-1,2-Dichloroethene <0.200 pg/L 0.200 0.500 1 11/15/23 00:02 MSA V40250 trans- 1,2-Dichloroethene <0.180 pg/L 0.180 0.500 1 11/15/23 00:02 MSA V40250 1,2-Dichloropropane <0.190 pg/L 0.190 0.500 1 11/15/23 00:02 MSA V40250 1,3-Dichloropropane <0.130 pg/L 0.130 0.500 1 11/15/23 00:02 MSA V40250 2,2-Dichloropropane <0.210 pg/L 0.210 2.00 1 11/15/23 00:02 MSA V40250 1,1-Dichloropropene <0.200 pg/L 0.200 0.500 1 11/15/23 00:02 MSA V40250 cis-1,3-Dichloropropene <0.210 pg/L 0.210 0.500 1 11/15/23 00:02 MSA V40250 trans-1,3-Dichloropropene <0.150 pg/L 0.150 0.500 1 11/15/23 00:02 MSA V40250 Ethylbenzene <0.170 pg/L 0.170 0.500 1 11/15/23 00:02 MSA V40250 Ethyl Tertiary Butyl Ether (ETBE) <1.80 pg/L 1.80 10.0 1 11/15/23 00:02 MSA V40250 Hexachlorobutadiene <0.350 pg/L 0.350 2.00 1 11/15/23 00:02 MSA V40250 n-Hexane <1.30 pg/L 1.30 10.0 1 11/15/23 00:02 MSA V40250 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 23 of 39 Waypointo ANALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 Report Number : 23-314-0019 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com REPORT OFANALYSIS Report Date : 11/27/2023 Received : 11/10/2023 Lab No : 99902 Matrix: Aqueous Sample ID: SMW18R Sampled: 11/9/2023 12:58 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030E Test Results Units MDL MOIL DF Date / Time By Analytical Analyzed Batch 2-Hexanone <0.380 pg/L 0.380 5.00 1 11/15/23 00:02 MSA V40250 Isopropyl benzene <0.180 pg/L 0.180 5.00 1 11/15/23 00:02 MSA V40250 4-Isopropyl toluene <0.089 pg/L 0.089 0.500 1 11/15/23 00:02 MSA V40250 Methyl Ethyl Ketone (MEK) 1.673 pg/L 0.710 5.00 1 11/15/23 00:02 MSA V40250 Methyl tert-butyl ether (MTBE) <0.140 pg/L 0.140 0.500 1 11/15/23 00:02 MSA V40250 4-Methyl-2-Pentanone <1.00 pg/L 1.00 5.00 1 11/15/23 00:02 MSA V40250 Methylene Chloride <0.330 pg/L 0.330 1.00 1 11/15/23 00:02 MSA V40250 Naphthalene <0.470 pg/L 0.470 1.00 1 11/15/23 00:02 MSA V40250 n-Propylbenzene <0.190 pg/L 0.190 0.500 1 11/15/23 00:02 MSA V40250 Styrene <0.220 pg/L 0.220 0.500 1 11/15/23 00:02 MSA V40250 1, 1, 1,2-Tetrachloroethane <0.160 pg/L 0.160 0.500 1 11/15/23 00:02 MSA V40250 1,1,2,2-Tetrachloroethane <0.160 pg/L 0.160 0.500 1 11/15/23 00:02 MSA V40250 Tetrachloroethene <0.220 pg/L 0.220 0.500 1 11/15/23 00:02 MSA V40250 Toluene <0.220 pg/L 0.220 0.500 1 11/15/23 00:02 MSA V40250 1,2,3-Trichlorobenzene <0.380 pg/L 0.380 2.00 1 11/15/23 00:02 MSA V40250 1,2,4-Trichlorobenzene <0.310 pg/L 0.310 1.00 1 11/15/23 00:02 MSA V40250 1,1,1-Trichloroethane <0.160 pg/L 0.160 0.500 1 11/15/23 00:02 MSA V40250 1,1,2-Trichloroethane <0.096 pg/L 0.096 0.500 1 11/15/23 00:02 MSA V40250 Trichloroethene <0.180 pg/L 0.180 0.500 1 11/15/23 00:02 MSA V40250 Trichlorofluoromethane <0.180 pg/L 0.180 0.500 1 11/15/23 00:02 MSA V40250 1,2,3-Trichloropropane <0.270 pg/L 0.270 1.00 1 11/15/23 00:02 MSA V40250 1,3,5-Trimethylbenzene <0.180 pg/L 0.180 0.500 1 11/15/23 00:02 MSA V40250 Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions 3 Estimated value MQL Method Quantitation Limit Page 24 of 39 (D WayPAoint. NALYTICAL 00122 Falcon Engineering Project Arulo Christopher Burkhardt 1210 Trinity Road Information Suite 110 Cary , NC 27513 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Report Date : 11/27/2023 Received : 11/10/2023 Report Number : 23-314-0019 REPORT OPANALYSIS Lab No : 99902 Matrix: Aqueous Sample ID : SMW18R Sampled: 11/9/2023 12:58 Analytical Method: 8260D Prep Batch(es): V40247 11/14/23 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Vinyl Acetate <1.00 ug/L 1.00 2.00 1 11/15/23 00:02 MSA V40250 Vinyl Chloride <0.170 Ng/L 0.170 0.500 1 11/15/23 00:02 MSA V40250 o-Xylene <0.210 Ng/L 0.210 0.500 1 11/15/23 00:02 MSA V40250 m,p-Xylene <0.420 u9/L 0.420 1.00 1 11/15/23 00:02 MSA V40250 Xylene (Total) <0.21 Ng/L 0.210 0.500 1 11/15/23 00:02 V40250 Surrogate: 4-Bromofluorobenzene 101 Limits: 80-124% 1 11/15/23 00:02 MSA V40250 Surrogate: Dibromofluoromethane 98.6 Limits: 75-129% 1 11/15/23 00:02 MSA V40250 Surrogate: 1,2-Dichloroethane - d4 93.4 Limits: 63-136% 1 11/15/23 00:02 MSA V40250 Surrogate: Toluene-d8 96.0 Limits: 77-123% 1 11/15/23 00:02 MSA V40250 Analytical Method: 8315A Prep Batch(es): L716914 11/12/23 12:00 Prep Method: 8315A Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Formaldehyde 29.8 B Ng/L 10.0 10.0 1 11/14/23 17:54 KDL L717054 Qualifiers/ B Analyte detected in blank Definitions 3 Estimated value DF Dilution Factor MQL Method Quantitation Limit Page 25 of 39 0 Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: Arulo Report No: 23-314-0019 QC Analytical Batch: V40127 Analysis Method: 2540C-2015 Analysis Description: Total Dissolved Solids Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 99899, 99900, 99901, 99902 Blank MDL MQL Analyzed Parameter Units Result Total Dissolved Solids mg/L <36 36 50 11/13/23 11:32 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Total Dissolved Solids mg/L 1000 990 99.0 90-110 Duplicate V 99699-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Total Dissolved Solids mg/L 1130 1090 3.6 10 11/13/23 11:32 Date: 11/27/2023 10:50 AM Page 1 of 12 Page 26 of 39 0 Waypoint, 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: Arulo Report No: 23-314-0019 QC Prep: V40157 QC Analytical Batch(es): V40163,V40185,V40211 QC Prep Batch Method: 300.0 (Prep) Analysis Method: 300.0 Analysis Description: Anions by Ion Chromatography Lab Reagent Blank LRB-V40157 Matrix: AQU Associated Lab Samples: 99899, 99900, 99901, 99902 Blank MDL MQL Analyzed Parameter Units Result Chloride mg/L <0.370 0.370 1.00 11/13/2318:52 Nitrate (NO3-N) mg/L <0.076 0.076 0.200 11/10/23 21:27 Laboratory Control Sample LCS-V40157 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Chloride mg/L 40.0 38.1 95.0 90-110 Nitrate (NO3-N) mg/L 4.00 3.38 85.0* 90-110 Matrix Spike & Matrix Spike Duplicate V 99759-MS-V40157 V 99759-MSD-V40157 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Chloride mg/L 583 40.0 40.0 578 582 0.0* 0.0* 90-110 0.6 20.0 Nitrate (NO3-N) mg/L 38.0 4.00 4.00 38.9 39.2 23.0* 30.0* 90-110 0.7 20.0 Matrix Spike & Matrix Spike Duplicate V 99902-MS-V40157 V 99902-MSD-V40157 Parameter Chloride Nitrate (NO3-N) MS Spike MSD MS Result MSD MS MSD %Rec Max Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. mg/L 12.1 40.0 40.0 50.5 49.6 96.0 94.0 90-110 1.7 20.0 mg/L < 0.079 4.00 4.00 3.79 3.78 93.0 93.0 90-110 0.2 20.0 * QC Fail Date: 11/27/2023 10:50 AM Page 2 of 12 Page 27 of 39 0 Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: Arulo Report No: 23-314-0019 QC Prep: L717992 QC Analytical Batch(es): L718334 QC Prep Batch Method: TKN/TKP Digestion Analysis Method: 365.4 Analysis Description: Total Phosphorus Lab Reagent Blank LRB-1-717992 Matrix: AQU Associated Lab Samples: 99899, 99900, 99901, 99902 Blank MDL MQL Analyzed Parameter Units Result Phosphorus mg/L <0.212 0.212 0.500 11/21/23 13:10 Laboratory Control Sample LCS-1-717992 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Phosphorus mg/L 2.00 2.00 100 80-120 Duplicate L 96287-DUP-L717992 Result DUP RPD Max RPD Analyzed Parameter Units Result Phosphorus mg/L 2.71 2.69 0.7 20.0 11/21/23 13:14 Matrix Spike L 96287-MS-L717992 MS Spike MSD MS Result MSD MS %Rec Max Parameter Units Result Conc. Spike Result %Rec Limits RPD Conc. Phosphorus mg/L 2.71 2.00 4.69 99.0 70-130 Date: 11/27/2023 10:50 AM Page 3 of 12 Page 28 of 39 0 Waypoint, 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: Arulo Report No: 23-314-0019 QC Analytical Batch: L718477 Analysis Method: 4500NH3D-2011 Analysis Description: Ammonia Nitrogen (ISE) Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 99899, 99900, 99901, 99902 Blank MDL MQL Analyzed Parameter Units Result Ammonia Nitrogen mg/L <0.040 0.040 0.100 11/22/23 15:30 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Ammonia Nitrogen mg/L 5.00 5.31 106 90-110 Matrix Spike & Matrix Spike Duplicate V 99899-MS V 99899-MSD MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD Conc. Ammonia Nitrogen mg/L < 0.040 2.04 2.04 1.98 2.12 97.0 104 70-130 6.8 20.0 Date: 11/27/2023 10:50 AM Page 4 of 12 Page 29 of 39 0 Waypoint,449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: Arulo Report No: 23-314-0019 QC Prep: L717280 QC Analytical Batch(es): L717281 QC Prep Batch Method: 5310C-2011 Analysis Method: 5310C-2011 Analysis Description: Total Organic Carbon Lab Reagent Blank LRB-1-717280 Matrix: AQU Associated Lab Samples: 99899, 99900 Blank MDL MQL Analyzed Parameter Units Result TOC mg/L <0.682 0.682 1.00 11/14/2311:07 Laboratory Control Sample LCS-1-717280 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits TOC mg/L 5.00 5.23 105 85-115 Duplicate Q 94748-DUP-L717280 Result DUP RPD Max RPD Analyzed Parameter Units Result TOC mg/L < 1.00 <1.00 37.8* 15.0 11/14/23 14:17 Matrix Spike L 90424-MS-L717280 MS Spike MSD MS Result MSD MS %Rec Max Parameter Units Result Conc. Spike Result %Rec Limits RPD Conc. TOC mg/L 1.92 5.26 7.65 109 85-115 * QC Fail Date: 11/27/2023 10:50 AM Page 5 of 12 Page 30 of 39 0 Waypoint, 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: Arulo Report No: 23-314-0019 QC Prep: L717282 QC Analytical Batch(es): L717283 QC Prep Batch Method: 5310C-2011 Analysis Method: 5310C-2011 Analysis Description: Total Organic Carbon Lab Reagent Blank LRB-1-717282 Matrix: AQU Associated Lab Samples: 99901, 99902 Blank MDL MQL Analyzed Parameter Units Result TOC mg/L <0.682 0.682 1.00 11/14/23 18:44 Laboratory Control Sample & LCSD LCS-1-717282 LCSD-L717282 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD TOC mg/L 5.00 5.18 5.27 104 105 85-115 1.7 20.0 Date: 11/27/2023 10:50 AM Page 6 of 12 Page 31 of 39 Waypointo ANALYTICAL Client ID: Project Description: Report No: Falcon Engineering Arulo 23-314-0019 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data QC Prep: V40247 QC Analytical Batch(es): V40250 QC Prep Batch Method: 5030E Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V40247 Associated Lab Samples: 99899, 99900, 99901, 99902 Matrix: AQU Parameter Units Blank Result MDL MQL Analyzed Acetone pg/L <1.80 1.80 5.00 11/14/23 21:35 Acrolein pg/L <2.00 2.00 5.00 11/14/23 21:35 Acrylonitrile pg/L <0.230 0.230 5.00 11/14/23 21:35 Benzene pg/L <0.180 0.180 0.500 11/14/23 21:35 Bromobenzene pg/L <0.210 0.210 0.500 11/14/23 21:35 Bromochloromethane pg/L <0.420 0.420 1.00 11/14/23 21:35 Bromodichloromethane pg/L <0.160 0.160 0.500 11/14/23 21:35 Bromoform pg/L <1.50 1.50 5.00 11/14/23 21:35 Bromomethane pg/L <0.280 0.280 1.00 11/14/23 21:35 n-Butylbenzene pg/L <0.185 0.185 1.00 11/14/23 21:35 sec -Butyl benzene pg/L <0.200 0.200 0.500 11/14/23 21:35 tert-Butyl benzene pg/L <0.920 0.920 2.00 11/14/23 21:35 Carbon Disulfide pg/L <0.150 0.150 5.00 11/14/23 21:35 Carbon Tetrachloride pg/L <0.180 0.180 0.500 11/14/23 21:35 Chlorobenzene pg/L <0.190 0.190 0.500 11/14/23 21:35 Chlorodibromomethane pg/L <0.190 0.190 0.500 11/14/23 21:35 Chloroethane pg/L <0.430 0.430 1.00 11/14/23 21:35 Chloroform pg/L <0.220 0.220 0.500 11/14/23 21:35 Chloromethane pg/L <0.220 0.220 0.500 11/14/23 21:35 2-Chlorotoluene pg/L <0.200 0.200 0.500 11/14/23 21:35 4-Chlorotoluene pg/L <0.200 0.200 0.500 11/14/23 21:35 Di -Isopropyl Ether (DIPE) pg/L <0.960 0.960 5.00 11/14/23 21:35 1,2-Dibromo-3-Chloropropane pg/L <1.10 1.10 2.00 11/14/23 21:35 1,2-Dibromoethane pg/L <0.200 0.200 0.500 11/14/23 21:35 Dibromomethane pg/L <0.230 0.230 0.500 11/14/23 21:35 1,2-Dichlorobenzene pg/L <0.220 0.220 0.500 11/14/23 21:35 1,3-Dichlorobenzene pg/L <0.190 0.190 0.500 11/14/23 21:35 Rec Recovery Limits Date: 11/27/2023 10:50 AM Page 32 of 39 Page 7 of 12 Waypoint.0 ANALYTICAL Client ID: Falcon Engineering Project Description: Arulo Report No: 23-314-0019 QC Prep: V40247 QC Prep Batch Method: 5030B 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data QC Analytical Batch(es): V40250 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V40247 Associated Lab Samples: 99899, 99900, 99901, 99902 Blank MDL Parameter Units Result MQL Matrix: AQU Analyzed % % Rec Recovery Limits 1,4-Dichlorobenzene pg/L <0.210 0.210 0.500 11/14/23 21:35 Dichlorodifluoromethane pg/L <1.20 1.20 5.00 11/14/23 21:35 1,1-Dichloroethane pg/L <0.240 0.240 0.500 11/14/23 21:35 1,2-Dichloroethane pg/L <0.150 0.150 0.500 11/14/23 21:35 1,1-Dichloroethene pg/L <0.150 0.150 0.500 11/14/23 21:35 cis-1,2-Dichloroethene pg/L <0.200 0.200 0.500 11/14/23 21:35 trans-1,2-Dichloroethene pg/L <0.180 0.180 0.500 11/14/23 21:35 1,2-Dichloropropane pg/L <0.190 0.190 0.500 11/14/23 21:35 1,3-Dichloropropane pg/L <0.130 0.130 0.500 11/14/23 21:35 2,2-Dichloropropane pg/L <0.210 0.210 2.00 11/14/23 21:35 1,1-Dichloropropene pg/L <0.200 0.200 0.500 11/14/23 21:35 cis-1,3-Dichloropropene pg/L <0.210 0.210 0.500 11/14/23 21:35 trans-1,3-Dichloropropene pg/L <0.150 0.150 0.500 11/14/23 21:35 Ethylbenzene pg/L <0.170 0.170 0.500 11/14/23 21:35 Ethyl Tertiary Butyl Ether (ETBE) pg/L <1.80 1.80 10.0 11/14/23 21:35 Hexachlorobutadiene pg/L <0.350 0.350 2.00 11/14/23 21:35 n-Hexane pg/L <1.30 1.30 10.0 11/14/23 21:35 2-Hexanone pg/L <0.380 0.380 5.00 11/14/23 21:35 Isopropylbenzene pg/L <0.180 0.180 5.00 11/14/23 21:35 4-Isopropyl toluene pg/L <0.089 0.089 0.500 11/14/23 21:35 Methyl Ethyl Ketone (MEK) pg/L <0.710 0.710 5.00 11/14/23 21:35 Methyl tert-butyl ether (MTBE) pg/L <0.140 0.140 0.500 11/14/23 21:35 4-Methyl-2-Pentanone pg/L <1.00 1.00 5.00 11/14/23 21:35 Methylene Chloride pg/L <0.330 0.330 1.00 11/14/23 21:35 Naphthalene pg/L <0.470 0.470 1.00 11/14/23 21:35 n-Propylbenzene pg/L <0.190 0.190 0.500 11/14/23 21:35 Styrene pg/L <0.220 0.220 0.500 11/14/23 21:35 Date: 11/27/2023 10:50 AM Page 8 of 12 Page 33 of 39 0 Waypoint, 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: Arulo Report No: 23-314-0019 QC Prep: V40247 QC Analytical Batch(es): V40250 QC Prep Batch Method: 5030E Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V40247 Matrix: AQU Associated Lab Samples: 99899, 99900, 99901, 99902 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,1,1,2-Tetrachloroethane pg/L <0.160 0.160 0.500 11/14/23 21:35 1,1,2,2-Tetrachloroethane pg/L <0.160 0.160 0.500 11/14/23 21:35 Tetrachloroethene pg/L <0.220 0.220 0.500 11/14/23 21:35 Toluene pg/L <0.220 0.220 0.500 11/14/23 21:35 1,2,3-Trichlorobenzene pg/L <0.380 0.380 2.00 11/14/23 21:35 1,2,4-Trichlorobenzene pg/L <0.310 0.310 1.00 11/14/23 21:35 1,1,1-Trichloroethane pg/L <0.160 0.160 0.500 11/14/23 21:35 1,1,2-Trichloroethane pg/L <0.096 0.096 0.500 11/14/23 21:35 Trichloroethene pg/L <0.180 0.180 0.500 11/14/23 21:35 Trichlorofluoromethane pg/L <0.180 0.180 0.500 11/14/23 21:35 1,2,3-Trichloropropane pg/L <0.270 0.270 1.00 11/14/23 21:35 1,3,5-Trimethylbenzene pg/L <0.180 0.180 0.500 11/14/23 21:35 Vinyl Acetate pg/L <1.00 1.00 2.00 11/14/23 21:35 Vinyl Chloride pg/L <0.170 0.170 0.500 11/14/23 21:35 o-Xylene pg/L <0.210 0.210 0.500 11/14/23 21:35 m,p-Xylene pg/L <0.420 0.420 1.00 11/14/23 21:35 4-Bromofluorobenzene (S) 11/14/23 21:35 1O1 80-124 Dibromofluoromethane (S) 11/14/23 21:35 97.6 75-129 1,2-Dichloroethane - d4 (S) 11/14/23 21:35 91.2 63-136 Toluene-d8 (S) 11/14/23 21:35 97.6 77-123 Laboratory Control Sample & LCSD LCS-V40247 LCSD-V40247 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Acetone pg/L 40.0 40.4 46.8 101 117 40-166 14.6 20.0 Acrolein pg/L 40.0 41.1 42.7 103 107 70-130 3.8 20.0 Date: 11/27/2023 10:50 AM Page 9 of 12 Page 34 of 39 0 Waypoint,449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: Arulo Report No: 23-314-0019 QC Prep: V40247 QC Analytical Batch(es): V40250 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V40247 LCSD-V40247 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Acrylonitrile pg/L 40.0 41.3 41.8 103 105 81-127 1.2 20.0 Benzene pg/L 20.0 22.2 22.3 111 112 77-128 0.4 20.0 Bromobenzene pg/L 20.0 21.4 20.7 107 104 78-129 3.3 20.0 Bromochloromethane pg/L 20.0 21.5 21.5 108 108 78-135 0.0 20.0 Bromodichloromethane pg/L 20.0 21.1 21.5 106 108 76-138 1.8 20.0 Bromoform pg/L 20.0 19.8 20.1 99.0 101 71-135 1.5 20.0 Bromomethane pg/L 20.0 20.3 20.3 102 102 41-168 0.0 20.0 n-Butylbenzene pg/L 20.0 21.2 20.9 106 105 68-134 1.4 20.0 sec -Butyl benzene pg/L 20.0 21.0 20.7 105 104 71-131 1.4 20.0 tert-Butyl benzene pg/L 20.0 21.1 20.7 106 104 70-132 1.9 20.0 Carbon Disulfide pg/L 20.0 20.9 21.2 105 106 59-135 1.4 20.0 Carbon Tetrachloride pg/L 20.0 22.4 22.4 112 112 72-142 0.0 20.0 Chlorobenzene pg/L 20.0 21.1 21.0 106 105 78-119 0.4 20.0 Chlorodibromomethane pg/L 20.0 20.2 20.1 101 101 75-134 0.4 20.0 Chloroethane pg/L 20.0 20.2 20.3 101 102 57-142 0.4 20.0 Chloroform pg/L 20.0 21.0 21.2 105 106 77-130 0.9 20.0 Chloromethane pg/L 20.0 20.4 20.9 102 105 47-145 2.4 20.0 2-Chlorotoluene pg/L 20.0 20.6 20.2 103 101 74-126 1.9 20.0 4-Chlorotoluene pg/L 20.0 21.4 20.8 107 104 78-129 2.8 20.0 Di -Isopropyl Ether (DIPE) pg/L 20.0 21.9 22.2 110 111 60-154 1.3 20.0 1,2-Dibromo-3-Chloropropane pg/L 20.0 21.7 20.3 109 102 63-134 6.6 20.0 1,2-Dibromoethane pg/L 20.0 20.4 19.7 102 98.5 77-135 3.4 20.0 Dibromomethane pg/L 20.0 21.5 21.6 108 108 76-138 0.4 20.0 1,2-Dichlorobenzene pg/L 20.0 20.4 20.1 102 101 78-128 1.4 20.0 1,3-Dichlorobenzene pg/L 20.0 20.8 20.4 104 102 77-125 1.9 20.0 1,4-Dichlorobenzene pg/L 20.0 20.7 20.1 104 101 75-126 2.9 20.0 Date: 11/27/2023 10:50 AM Page 10 of 12 Page 35 of 39 Waypointo ANALYTICAL Client ID: Project Description: Report No: Falcon Engineering Arulo 23-314-0019 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data QC Prep: V40247 QC Analytical Batch(es): V40250 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V40247 LCSD-V40247 Parameter Units Spike Conc. LCS Result LCSD Result LCS %Rec LCSD % Rec % Rec Limits RPD Max RPD Dichlorodifluoromethane pg/L 20.0 13.4 13.6 67.0 68.0 28-163 1.4 20.0 1,1-Dichloroethane pg/L 20.0 22.3 22.4 112 112 70-130 0.4 20.0 1,2-Dichloroethane pg/L 20.0 20.8 20.6 104 103 68-131 0.9 20.0 1,1-Dichloroethene pg/L 20.0 23.5 23.9 118 120 70-154 1.6 20.0 cis- 1,2-Dichloroethene pg/L 20.0 21.3 21.6 107 108 76-141 1.3 20.0 trans-1,2-Dichloroethene pg/L 20.0 22.3 22.4 112 112 76-135 0.4 20.0 1,2-Dichloropropane pg/L 20.0 21.4 21.9 107 110 77-130 2.3 20.0 1,3-Dichloropropane pg/L 20.0 19.7 20.1 98.5 101 76-132 2.0 20.0 2,2-Dichloropropane pg/L 20.0 21.4 22.0 107 110 29-149 2.7 20.0 1,1-Dichloropropene pg/L 20.0 23.7 23.8 119 119 71-136 0.4 20.0 cis-1,3-Dichloropropene pg/L 20.0 20.6 21.0 103 105 65-140 1.9 20.0 trans-1,3-Dichloropropene pg/L 20.0 19.5 20.2 97.5 101 67-140 3.5 20.0 Ethylbenzene pg/L 20.0 21.0 21.0 105 105 80-127 0.0 20.0 Ethyl Tertiary Butyl Ether (ETBE) pg/L 40.0 44.2 44.6 111 112 70-130 0.9 20.0 Hexachlorobutadiene pg/L 20.0 19.4 18.7 97.0 93.5 61-134 3.6 20.0 n-Hexane pg/L 20.0 19.8 19.3 99.0 96.5 70-130 2.5 20.0 2-Hexanone pg/L 20.0 20.1 21.1 101 106 64-137 4.8 20.0 Isopropylbenzene pg/L 20.0 22.2 21.5 111 108 70-130 3.2 20.0 4-Isopropyl toluene pg/L 20.0 21.9 21.4 110 107 69-132 2.3 20.0 Methyl Ethyl Ketone (MEK) pg/L 20.0 19.9 21.4 99.5 107 71-134 7.2 20.0 Methyl tert-butyl ether (MTBE) pg/L 20.0 20.7 20.8 104 104 68-135 0.4 20.0 4-Methyl-2-Pentanone pg/L 20.0 20.7 21.9 104 110 69-134 5.6 20.0 Methylene Chloride pg/L 20.0 21.4 21.9 107 110 73-131 2.3 20.0 Naphthalene pg/L 20.0 20.5 20.1 103 101 64-136 1.9 20.0 n-Propylbenzene pg/L 20.0 21.7 21.0 109 105 72-132 3.2 20.0 Styrene pg/L 20.0 21.1 21.3 106 107 78-129 0.9 20.0 Date: 11/27/2023 10:50 AM Page 11 of 12 Page 36 of 39 0 Waypoint 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Quality Control Data Client ID: Falcon Engineering Project Description: Arulo Report No: 23-314-0019 QC Prep: V40247 QC AnalyticalBatch(es): V40250 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V40247 LCSD-V40247 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD 1,1,1,2-Tetrachloroethane pg/L 20.0 21.1 20.6 106 103 79-134 2.3 20.0 1,1,2,2-Tetrachloroethane pg/L 20.0 21.7 21.3 109 107 62-127 1.8 20.0 Tetrachloroethene pg/L 20.0 21.4 21.1 107 106 80-129 1.4 20.0 Toluene pg/L 20.0 22.0 22.4 110 112 76-131 1.8 20.0 1,2,3-Trichlorobenzene pg/L 20.0 20.3 20.6 102 103 58-144 1.4 20.0 1,2,4-Trichlorobenzene pg/L 20.0 19.9 19.8 99.5 99.0 66-139 0.5 20.0 1,1,1-Trichloroethane pg/L 20.0 21.6 21.6 108 108 75-135 0.0 20.0 1,1,2-Trichloroethane pg/L 20.0 21.7 21.9 109 110 70-140 0.9 20.0 Trichloroethene pg/L 20.0 20.8 21.2 104 106 77-133 1.9 20.0 Trichlorofluoromethane pg/L 20.0 21.7 22.2 109 111 62-148 2.2 20.0 1,2,3-Trichloropropane pg/L 20.0 21.0 19.5 105 97.5 71-127 7.4 20.0 1,3,5-Trimethylbenzene pg/L 20.0 21.7 21.1 109 106 75-131 2.8 20.0 Vinyl Acetate pg/L 20.0 25.6 27.1 128 136 34-167 5.6 20.0 Vinyl Chloride pg/L 20.0 21.2 20.9 106 105 57-141 1.4 20.0 o-Xylene pg/L 20.0 21.2 21.3 106 107 78-128 0.4 20.0 m,p-Xylene pg/L 40.0 44.8 44.5 112 111 77-133 0.6 20.0 4-Bromofluorobenzene(S) 100 98.6 80-124 Dibromofluoromethane (S) 95.8 96.8 75-129 1,2-Dichloroethane - d4 (S) 91.4 93.8 63-136 Toluene-d8 (S) 97.6 96.8 77-123 Date: 11/27/2023 10:50 AM Page 12 of 12 Page 37 of 39 Waypoint(2) ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Shipment Receipt Form Customer Number: 00122 Customer Name: Falcon Engineering Report Number: 23-314-0019 Shipping Method 0 Fed Ex 0 US Postal # Lab 0 UPS 0 Client O Courier 0 Other: Thermometer ID: IRT15 5.00 Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F 1 Custody seals intact on shipping container/cooler? 0 Yes 0 No 0 Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? 0 Yes 0 No COC agrees with sample label(s)? Yes 0 No COC properly completed Yes 0 No Samples in proper containers? Yes 0 No Sample containers intact? Yes 0 No Sufficient sample volume for indicated test(s)? Yes 0 No All samples received within holding time? Yes 0 No Cooler temperature in compliance? Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. 0 Yes 0 No Water - Sample containers properly preserved Yes 0 No 0 N/A Water - VOA vials free of headspace Yes 0 No 0 N/A Trip Blanks received with VOAs 0 Yes 0 No # N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No * N/A F_ High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr) High concentration pre -weighed (methanol -14 d) I Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes 0 No Comments: 1 Signature: ngelo Norvell Date & Time: [1/10/2023 13:14:33] Page 38 of 39 Waypoint . ANALYTICAL 449 Spnngbrook Road • Charlotte, NC 28217 Phone 7041529-6364 Fax: 70M525-0409 Client Company Name: C ( �E.:e Name: k _ Report To/Contact L r i u Reporting Address: 1 Z4.1 rr•i*1,'fti St-, 100, Lov--% . 27 s) 3) 3 Phone: -lIQ -•7 30-K,�ax (Yes)(No): A)n Email Address: EDD Type: PDF__ Excel —Other Site Location Name: /4 ruLO _ Site Location Physical Address: M OIIL., rZ ------ TIME MATRIX CLIENT DATE COLLECTED (SOIL, SAMPLE DESCRIPTION COLLECTED MILITARY WATER, OR HOURS SLUDGE) ,�MWl 3 - Lu Lj SIZ 58 CHAIN OF CUSTODY RECORDLAS USE ONLY YES NO WA PAGE 1 Oi I QUOTE 0 TOENSURE PROPER BILLING. Project Name: _A rtu, t _— Short Hold Analysis (Yes) No UST Project: (Yes) `Please ATTACH any project spe Ific reporting (CIC LEVEL I It I provisions and/or CIC Requirements Invoice To: Address: Purchase Order NoJBilllng Reference-- --- ­ - Requested Due Date J 1 Day J 2 Days J 3 Days J 4 Days J 5 Days "Working Days" J 6-9 Days Standard 10 days J Pre Ap�k Must Be ved Samples received after 15-00 will processed next business day. Turnaround time is based on business days. excluding weekends and holidays (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY WAYPOINT ANALYTICAL. LLC TO CLIENT) SAMPLE CONTAINER T- PRESERVA- `TYPE fI NO. SIZE TIVES SEE BELOW X P, VOA io Y&s ANALYSIS i Samples INTACT upon arrival? — I Received IN ICE? -_ No) PROPER PRESERVATIVES indicated? Received WITHIN HOLDING TIMES? CUSTODY SEALS INTACT? �- ___ VOLATILES reed W/OUT HEADSPACE? PROPER CONT�S ed' ' -- TEMP' Therm ID: Observed Opp d C /Corr J O C TO BE FILLEDIN BY CLIENTISAMPLING PERSONNEL Certification: NC ✓ SC Other NIA Water Chlorinated: YES_. NO ✓ Samples Iced Upon Collection: YESL NO REQUESTED 10010111111111 00122 �9 3 Falcon Enain . , 13 12:45 Arulo REMARKS ID NO Sampler's Signature _ _ Sampled By (Print Name) %. / h� 8n, k,- Affiliation Upon relinquishing, this Chain of Custody is your authorization for Waypoint Analytical to proceed with the analyses as requested above. Any changes must be submitted in writing to the Waypoint Analytical Project Manager. There will be charges for any ch s after analyses have been initialized. Reknqurehed By. (Sgnauae) R _ - �oatr -- Additional Comments- 7 1 1 /70 SAMPLES ARE NOT ACCEPTED AND VERRzIlED AGAINST CDC UNTIL RECEIVED AT THE LABORATORY. I I J Fed Ea J rwJ UPS J Hand-deired Waypoint Anelytoai Field Service J Other- ----- - ---- J NC U SC IJJ S C J SC J NCGROU J SCATER� D NCKIN SC ATER: I LI NLCD W SCTE. -RC": NC J SC I ] NC ❑ SC I NC FJ SCI OTHER: J NC J SC 'CONTAINER TYPE CODES: A - Amber C = Clear G= Glass P = Plastic; TL a Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) Ske Arrival Time: Site Departure Tune: Field Tech Fee: Mileage ORIGINAL tiff eurofins 0 Environment Testing ANALYTICAL REPORT PREPARED FOR Attn: Christopher J Burkhardt Falcon Engineering Inc 1210 Trinity Road Suite 110 Raleigh, North Carolina 27607 DESCRIPTION NUMBER 752-13518-1 This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project Manager. �r Qvrio_. Generated 11/14/2023 3:28:51 PM Authorized for release by Amanda Gaines, Project Manager amanda.gaines@et.eurofinsus.com (919)677-1669 Eurofins Savannah is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies Page 2 of 14 11/14/2023 Client: Falcon Engineering Inc Project/Site: Arauco Laboratory Job ID: 752-13518-1 Table of Contents Cover Page .............................................. Table of Contents ......................................... 3 Definitions/Glossary....................................... 4 Case Narrative ........................................... 5 Detection Summary ........................................ 6 Client Sample Results ...................................... 7 QC Association Summary ................................... 8 Lab Chronicle ............................................ 9 Certification Summary ...................................... 10 Method Summary ......................................... 11 Sample Summary ......................................... 12 Chain of Custody .......................................... 13 Receipt Checklists ......................................... 14 Page 3 of 14 Eurofins Raleigh 11 /14/2023 Definitions/Glossary Client: Falcon Engineering Inc Job ID: 752-13518-1 Project/Site: Arauco Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. a Listed under the "D" column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CFU Colony Forming Unit CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MCL EPA recommended "Maximum Contaminant Level' MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) MPN Most Probable Number MQL Method Quantitation Limit NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) NEG Negative / Absent POS Positive / Present PQL Practical Quantitation Limit PRES Presumptive QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TNTC Too Numerous To Count Eurofins Raleigh Page 4 of 14 11/14/2023 Case Narrative Client: Falcon Engineering Inc Project/Site: Arauco Job ID: 752-13518-1 Laboratory: Eurofins Raleigh Narrative Job ID: 752-13518-1 ❑a Job Narrative 752-13518-1 Analytical test results meet all requirements of the associated regulatory program listed on the Accreditation/Certification Summary Page unless otherwise noted under the individual analysis. Data qualifiers are applied to indicate exceptions. Noncompliant quality control (QC) is further explained in narrative comments. Matrix QC may not be reported if insufficient sample or site -specific QC samples were not submitted. In these situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD may be performed, unless otherwise specified in the method. Surrogate and/or isotope dilution analyte recoveries (if applicable) which are outside of the QC window are confirmed unless attributed to a dilution or otherwise noted in the narrative. Regulated compliance samples (e.g. SDWA, NPDES) must comply with the associated agency requirements/permits. Receipt The samples were received on 11/8/2023 2:36 PM. Unless otherwise noted below, the samples arrived in good condition, and, where required, properly preserved and on ice. The temperature of the cooler at receipt time was 3.0°C Biology No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page. Eurofins Raleigh Page 5 of 14 11/14/2023 Detection Summary Client: Falcon Engineering Inc Project/Site: Arauco Job ID: 752-13518-1 Client Sample ID: SW1 Lab Sample ID: 752-13518-1 Analyte Result Qualifier RL RL Unit Dil Fac D Method Prep Type Coliform, Fecal >2400 1.0 1.0 MPN/100mL 1 Coliform TotaUNA Client Sample ID: SMW 20 Lab Sample ID: 752-13518-2 INo Detections. Client Sample ID: SMW 5 Lab Sample ID: 752-13518-3 L No Detections. Client Sample ID: SMW 8 Lab Sample ID: 752-135184 C No Detections. This Detection Summary does not include radiochemical test results. Eurofins Raleigh Page 6 of 14 11/14/2023 Client Sample Results Client: Falcon Engineering Inc Project/Site: Arauco Client Sample ID: SW1 Date Collected: 11/08/23 11:16 Date Received: 11/08/23 14:36 Method: IDEXX Coliform - Coliforms, Fecal Ana" Result Qualifier Coliform, Fecal >2400 Client Sample ID: SMW 20 Date Collected: 11/08/23 11:45 Date Received: 11/08/23 14:36 Job ID: 752-13518-1 Lab Sample ID: 752-13518-1 Matrix: Water RL RL Unit D Prepared Analyzed Dill Fac 1.0 1.0 MPN/100mL 11/08/2316:20 1 Lab Sample ID: 752-13518-2 Matrix: Water Method: IDEXX Coliform - Coliforms, Fecal Ana" Result Qualifier RL Colifonn, Fecal <1.0 1.0 Client Sample ID: SMW 5 Date Collected: 11/08/23 12:10 Date Received: 11/08/23 14:36 Method: IDEXX Coliform - Coliforms, Fecal [Ana" Result Qualifier Coliform, Fecal <1.0 Client Sample ID: SMW 8 Date Collected: 11/08/23 12:29 Date Received: 11/08/23 14:36 RL 1.0 RL Unit D Prepared Analyzed Dil Fac 1.0 MPN/100mL 11/08/2316:20 1 Lab Sample ID: 752-13518-3 Matrix: Water RL Unit D Prepared Analyzed Dil Fac 1.0 MPN/100mL 11/08/2316:20 1 Lab Sample ID: 752-13518-4 Matrix: Water Method: IDEXX Coliform - Coliforms, Fecal �Analyte Result Qualifier RL RL Unit D Prepared Analyzed DII Fac Coliform, Fecal <1.0 1.0 1.0 MPN/100mL 11/08/2316:20 1 Page 7 of 14 Eurofins Raleigh 11 /14/2023 QC Association Summary Client: Falcon Engineering Inc Project/Site: Arauco -!-I- -.- Analysis Batch: 5127 Lab Sample ID Client Sample ID 752-13518-1 SW1 752-13518-2 SMW 20 752-13518-3 SMW 5 752-13518-4 SMW 8 Job ID: 752-13518-1 Prep Type Matrix Method Prep Batch Total/NA Water Coliform Total/NA Water Coliform Total/NA Water Coliform Total/NA Water Coliform Page 8 of 14 Eurofins Raleigh 11 /14/2023 7 Lab Chronicle Client: Falcon Engineering Inc Project/Site. Arauco Client Sample ID: SW1 Date Collected: 11/08/23 11:16 Date Received: 11/08/23 14:36 Batch Batch Prep Type Type Method Total/NA Analysis Coliform Client Sample ID: SMW 20 Date Collected: 11/08/23 11:45 Date Received: 11/08/23 14:36 F- Batch Batch LPrep Type Type Method TotaVNA Analysis Coliform Client Sample ID: SMW 5 Date Collected: 11/08/23 12:10 Date Received: 11/08/23 14:36 Batch Batch Prep Type Type Method Total/NA Analysis Coliform Client Sample ID: SMW 8 Date Collected: 11/08/23 12:29 Date Received: 11/08/23 14:36 Job ID: 752-13518-1 Lab Sample ID: 752-13518-1 Matrix: Water Dilution Batch Prepared Run Factor Number Analyst Lab or Analyzed 1 5127 CB EET ESC 11/08/23 16:20 -11/09/23 10:35' Lab Sample ID: 752-13518-2 Matrix: Water Dilution Batch Prepared Run Factor Number Analyst Lab or Analyzed 1 5127 CB EET ESC 11/08/23 16:20 - 11/09/23 10:35' Lab Sample ID: 752-13518-3 Matrix: Water Dilution Batch Prepared Run Factor Number Analyst Lab or Analyzed 1 5127 CB EET ESC 11/08/23 16:20 - 11/09/23 10:35' Lab Sample ID: 752-13518-4 Matrix: Water Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis Coliform 1 5127 CB EET ESC 11/08/23 16:20 -11/09/23 10:35 ' ' This procedure uses a method stipulated length of time for the process. Both start and end times are displayed. Laboratory References: EET ESC = Eurofins Raleigh, 102-A Woodwinds Industrial Court, Cary, NC 27511, TEL (919)677-1669 Eurofins Raleigh Page 9 of 14 11/14/2023 Accreditation/Certification Summary Client: Falcon Engineering Inc Project/Site: Arauco Laboratory: Eurofins Raleigh The accreditations/certifications listed below are applicable to this report. Authority Program North Carolina (VWV/SW) State Identification Number Expiration Date 591 12-31-23 Job ID: 752-13518-1 Eurofins Raleigh 0 Page 10 of 14 11/14/2023 Method Summary Client: Falcon Engineering Inc Job ID: 752-13518-1 Project/Site: Arauco Method Method Description Protocol Laboratory Coliform Coliforms, Fecal IDEXX EET ESC Protocol References: IDEXX = IDEXX Laboratories Laboratory References: EET ESC = Eurofins Raleigh, 102-A Woodwinds Industrial Court, Cary, NC 27511, TEL (919)677-1669 4,01 Eurofins Raleigh Page 11 of 14 11/14/2023 Sample Summary Client: Falcon Engineering Inc Job ID: 752-13518-1 Project/Site: Arauco Lab Sample ID Client Sample ID Matrix Collected Received 752-13518-1 SW1 Water 11/08/2311:16 11/08/23 14:36 752-13518-2 SMW 20 Water 11/08/23 11:45 11/08/23 14:36 752-13518-3 SMW 5 Water 11/08/23 12:10 11/08/23 14:36 752-13518-4 SMW 8 Water 11/08/23 12:29 11/08/23 14:36 Eurofins Raleigh Page 12 of 14 11/14/20g3 v O W O IV O fJ W Eurofins Raleigh 102-A Woodwinds Industrial Court Chain of Custody Record titieurofins i Environment Testing Cary NC 27511 ..... ,.. _ .,, ... , .-..._ Sampler T lab PM: Carrier TrxkI No(s): COC No: Client Information gkh 40( Gaines, Amanda 752-10' gknt Contact Phone: 'e•Mai State of Origin: / Page: Christopher Burkhardt arnarda.galnes(§eteurofins Lis. com Page 1 Job #: Company Falcon Engineering Inc Analysis Requested Presery 752-13518 COC Andress: Due Date Requested: 1 e 1210 Trinity Road Suite 110 A HCL 3 NaOH 0 AsNa02 Ciy TAT Requested (days): Raleigh 0 Z" Acetate P Na204S 0 Nitric Add 0 Na2S03 E State ZC: Dompoanee Project a Yes a No NC, 27607 McOHNaHSR Na2S203 F McOH S 1,QSO4 eahydAte Plane: PO #: 919-730.0064(Tel) Purchase Order not required o` 2 , $ rG+ AscorblcAcid U Acetone I ito V MCAA J DI Water Email: wo # cburKhardt@falconengineers.com m u =° m -E W pH 4S K EOTA L EDA Z other (sped'y) Protect Name: Project 0: Fecal 75202116 7 9 U �i .0 o Other site: rvGa SSOwA: n Sample Matrix ' a E y Type (w..... w chi Z �1 Sample (C=comp, a W Q Sample Identification Sam le Date Time G= rab eT n...,wo- w 2 1- Special InstructionslNote: Preservation Code: X R ., .. ' _ ;y.. Water • 5' Water Water (A-' Water Water Water Water Water Water Water Possible Hazard ldentlflcation Sample Disposal (A fee may be assessed /f samples are retained longer than 1 month} = = 0 Archive For Months =Retum Non -Hazard Flammable Skin lnitent Poison B Unknown Radiological To Client Disposal By Lab Deliverable Requested. I, II III, IV Other (specify) Special InstructioIfWQC Requirements: Empty Kit Relinquished by Date: Time: Me nA or Shipment I ReungOshed by. Datemme:i Company Received L' Dal1 '/� Company „ V L 7/L .Relinquished b . itt2i DateTime: Compan Received by' Oa Company Renngirtshed try DateTme: Company Received by: DateTme' Company Custody Seals Intact Custody Sea! No. Cooler Temperature(s)'C and Other Remarks: v A Yes e No ' V Login Sample Receipt Checklist Client: Falcon Engineering Inc Login Number: 13518 List Number: 1 Creator: Hyatt, Samantha Question Answer Radioactivity wasn't checked or is </= background as measured by a survey True meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. True Comment Job Number: 752-13518-1 List Source: Eurofins Raleigh 13 Eurofins Raleigh Page 14 of 14 11/14/2023 tiff eurofins Environment Testing 0 ANALYTICAL REPORT PREPARED FOR Attn: Christopher J Burkhardt Falcon Engineering Inc 1210 Trinity Road Suite 110 Raleigh, North Carolina 27607 DESCRIPTION NUMBER 752-13554-1 1j This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project Manager. Q� Generated 11/14/2023 3:49:26 PM Authorized for release by Amanda Gaines, Project Manager amanda.gainestgDet.eurofinsus.com (919)677-1669 Eurofins Savannah is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies Page 2 of 14 11/14/2023 Client: Falcon Engineering Inc Project/Site: Arauco Laboratory Job ID: 752-13554-1 Table of Contents Cover Page .............................................. 1 Table of Contents ......................................... 3 Definitions/Glossary....................................... 4 Case Narrative ........................................... 5 Detection Summary ........................................ 6 Client Sample Results ...................................... 7 QC Association Summary ................................... 8 Lab Chronicle ............................................ 9 Certification Summary ...................................... 10 Method Summary ......................................... 11 Sample Summary ......................................... 12 Chain of Custody .......................................... 13 Receipt Checklists ......................................... 14 Page 3 of 14 Eurofins Raleigh 11 /14/2023 Definitions/Glossary Client: Falcon Engineering Inc Project/Site: Arauco Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. v Listed under the "D" column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CFU Colony Forming Unit CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MCL EPA recommended "Maximum Contaminant Level' MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) MPN Most Probable Number MQL Method Quantitation Limit NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) NEG Negative / Absent POS Positive / Present PQL Practical Quantitation Limit PRES Presumptive QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TNTC Too Numerous To Count Job ID: 752-13554-1 Eurofins Raleigh C Page 4 of 14 11/14/2023 Case Narrative Client: Falcon Engineering Inc Job ID: 752-13554-1 Project/Site: Arauco Job ID: 752-13554-1 Laboratory: Eurofins Raleigh Narrative , Job Narrative 752-13554-1 Analytical test results meet all requirements of the associated regulatory program listed on the Accreditation/Certification Summary Page unless otherwise noted under the individual analysis. Data qualifiers are applied to indicate exceptions. Noncompliant quality control (QC) is further explained in narrative comments. Matrix QC may not be reported if insufficient sample or site -specific QC samples were not submitted. In these situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD may be performed, unless otherwise specified in the method. Surrogate and/or isotope dilution analyte recoveries (if applicable) which are outside of the QC window are confirmed unless attributed to a dilution or otherwise noted in the narrative. Regulated compliance samples (e.g. SDWA, NPDES) must comply with the associated agency requirements/permits. Receipt The samples were received on 11/9/2023 1:53 PM. Unless otherwise noted below, the samples arrived in good condition, and, where required, properly preserved and on ice. The temperature of the cooler at receipt time was 3.9°C Biology No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page. Eurofins Raleigh Page 5 of 14 11/14/203 Detection Summary Client: Falcon Engineering Inc Project/Site: Arauco Client Sample ID: SMW 9 C No Detections. Job ID: 752-13554-1 Lab Sample ID: 752-13554-1 Client Sample ID: SMW 4 Lab Sample ID: 752-13554-2 [Ana" Result Qualifier RL RL Unit Dil Fac D Method Prep Type Colifonn, Fecal 1.0 1.0 1.0 MPN/100mL 1 Coliform TotaVNA • Client Sample ID: SMW 3 Lab Sample ID: 752-13554-3 No Detections. Client Sample ID: SMW 18R Lab Sample ID: 752-13554-4 No Detections. • This Detection Summary does not include radiochemical test results. Eurofins Raleigh Page 6 of 14 11/14/2023 Client Sample Results Client: Falcon Engineering Inc Project/Site. Arauco Client Sample ID: SMW 9 Date Collected: 11/09/23 11:37 Date Received: 11/09/23 13:53 Method: IDEXX Coliform - Coliforms, Fecal Analyte Result Qualifier Coliform, Fecal <1.0 Client Sample ID: SMW 4 Date Collected: 11/09/23 12:07 Date Received: 11/09/23 13:53 Method: IDEXX Coliform - Coliforms, Fecal Analyte Result Qualifier Coliform, Fecal 1.0 Client Sample ID: SMW 3 Date Collected: 11/09/23 12:24 Date Received: 11/09/23 13:53 [Method: IDEXX Coliform - Coliforms, Fecal Anare Result Qualifier Coliform, Fecal <1.0 Client Sample ID: SMW 18R Date Collected: 11/09/23 12:58 Date Received: 11/09/23 13:53 Method: IDEXX Coliform - Coliforms, Fecal Ana" Resuit Qualifier Coliform, Fecal <1.0 Job ID: 752-13554-1 Lau Jdrtlplu 1LJ. / U4- 1 auu-t- 1 Matrix: Water RL RL Unit D Prepared Analyzed Dill Fac 1.0 1.0 MPN/100mL 11/09/2314:58 1 Lab Sample ID: 752-13554-2 Matrix: Water RL RL Unit D Prepared Analyzed DII Fac 1.0 1.0 MPN/100mL 11/09/2314:58 1 Lab Sample ID: 752-13554-3 Matrix: Water RL RL Unit D Prepared Analyzed Dill Fac 1.0 1.0 MPN/100ml- 11/09/2314:58 1 Lab Sample ID: 752-13554-4 Matrix: Water RL RL Unit D Prepared Analyzed Dill Fac 1.0 1.0 MPN/100mL 11/09/2314:58 1 Eurofins Raleigh Page 7 of 14 11/14/2023 QC Association Summary Client: Falcon Engineering Inc Project/Site: Arauco Biology Analysis Batch: 5136 Lab Sample ID _ Client Sample ID Prep Type 752-13554-1 SMW 9 Total/NA 752-13554-2 SMW 4 Total/NA 752-13554-3 SMW 3 Total/NA 752-13554-4 SMW 18R Total/NA Page 8 of 14 Job ID: 752-13554-1 Matrix Method Prep BatchY Water Coliform Water Coliform Water Coliform Water Coliform Eurofins Raleigh 11 /14/2023 Lab Chronicle Client: Falcon Engineering Inc Project/Site: Arauco Client Sample ID: SMW 9 Date Collected: 11/09/23 11:37 Date Received: 11/09/23 13:53 Batch Batch Prep Type Type Method Run Total/NA Analysis Coliform Client Sample ID: SMW 4 Date Collected: 11/09/23 12:07 Date Received: 11/09/23 13:53 Batch Batch Prep Type Type Method Run TotaVNA Analysis Coliform Job ID: 752-13554-1 Lab Sample ID: 752-13554-1 Matrix: Water Dilution Batch Prepared Factor Number Analyst Lab or Analyzed 1 5136 CB EET ESC 11/09/23 14:58-11/10/23 10:53 ' Lab Sample ID: 752-13554-2 Matrix: Water Dilution Batch Prepared Factor Number Analyst Lab or Analyzed 1 5136 CB EET ESC 11 /09/23 14:58 - 11/10/23 10:53' Client Sample ID: SMW 3 Date Collected: 11/09/23 12:24 Date Received: 11/09/23 13:53 Batch Batch Dilution Prep Type Type Method Run Factor Total/NA Analysis Coliform 1 Client Sample ID: SMW 18R Date Collected: 11/09/23 12:58 Date Received: 11/09/23 13:53 Lab Sample ID: 752-13554-3 Matrix: Water Batch Prepared Number Analyst Lab or Analyzed 5136 CB EET ESC 11/09/23 14:58 -11/10/23 10:53' Lab Sample ID: 752-13554-4 Matrix: Water Batch Batch Dilution Batch Prepared Prep Type Type Method Run Factor Number Analyst Lab or Analyzed Total/NA Analysis Coliform 1 5136 CB EET ESC 11/09/23 14:58 - 11/10/23 10:53 ' 4 This procedure uses a method stipulated length of time for the process. Both start and end times are displayed. Laboratory References: EET ESC = Eurofins Raleigh, 102-A Woodwinds Industrial Court. Cary, NC 27511, TEL (919)677-1669 Eurofins Raleigh Page 9 of 14 11 /14/2023 Accreditation/Certification Summary Client: Falcon Engineering Inc Project/Site: Arauco Laboratory: Eurogns Raleigh The accreditations/certifications listed below are applicable to this report. C!"thorlity _ Program North Carolina (WW/SW) State Identification Number Expiration Date 591 12-31-23 Job ID:752-13554-1 Eurofins Raleigh Page 10 of 14 11/14/2023 Method Summary Client: Falcon Engineering Inc Job ID: 752-13554-1 Project/Site: Arauco Method Method Description Protocol Laboratory Coliform Coliforms, Fecal IDEXX EET ESC Protocol References: IDEXX = IDEXX Laboratories Laboratory References: EET ESC = Eurofins Raleigh, 102-A Woodwinds Industrial Court, Cary, NC 27511, TEL (919)677-1669 110 Eurofins Raleigh Page 11 of 14 11/14/2023 Sample Summary Client: Falcon Engineering Inc Job ID: 752-13554-1 Project/Site: Arauco Lab Sample ID Client Sample ID Matrix Collected Received 752-13554-1 SMW 9 Water 11/09/23 11:37 11/09/23 13:53 752-13554-2 SMW 4 Water 11/09/23 12:07 11/09/23 13:53 752-13554-3 SMW 3 Water 11/09/23 12:24 11/09/23 13:53 752-13554-4 SMW 18R Water 11/09/23 12:58 11/09/23 13:53 Eurofins Raleigh Page 12 of 14 11/14/2093 a A N O N W Eurofins Raleigh 1G4 Woodwinds Industrial Court, Suite Cary NC 27511 Dl.nn.- /01'T AC7 !n0r1 Chain of Custody Record ti eurofins Environment Testing America Client Information Sampler /1 )'f'� L// l.aD ?M. :arrsr Tracking No;s): COC No: Client Confn:t „ , /� yrmr. e� Phone: `�, Aa I S rate of Origin Pagelari Company(c�WSID: j(L!Ff Analysis Requested — Press B Ns C Zn D N@ E Na 752-13554 COC F Me G Arno,_ H Ascorbk Acid T TSP Dodewttydnte I Ice U Acetone CAA J DI Water W p K EDTAfirs L EDA Y TdUna z other (specify) other S ecial Instructlons/Note: Address'. e} / O. Due Date Requested: I ^.; 2 o: �, � /V[l7 f; - �y.;. ':.a, �, ,¢ i City TAT Requested (days): State. Tip: compriance Project a Yes A No Phone: l , > ©� � PO )) n (� y ...� Emai: t k' •X' �°i141r�s. vvC #: Project Nama. V In EuroProject #: Sdet �f—w/ � SSOW R Sample Identification Sample Date Sample Time Sample T YPQ (C=comp, G= ratr) s-,one.` st-;;;­ A-at, Presemlion Code: '7 t Possible Hazard /deiffificaflon C Non -Hazard =1 Flammable Skin Irritant � Poison B � Unknown � RadloLa7cal Sample Disposal (A fee may be assessed if samples are retained longer than 1 month) =Return To Client =Disposal By Lab � Archive For Months Deliverable Requested: 1, II III, W Other (specify) Special Instructions/QC Requirements: n Empty Kit Relinquished by Date: Time: nee od er snpmen[ Relinquiened by: Date/rime: r Compa mcex RecniwC D . Date l if Company Relmquisned by Date/Time: company Rece.ved by: Da: �me: ComDa,,ty Relinquished by. Daterrime: Company Received by DataRme: Company Custody Seals Intact A Yes e No Custody Seal No. CoolerTemperature(s) -C and Other Remarks: j } ^ 1 \ / VCT V!(10/ _ Login Sample Receipt Checklist Client: Falcon Engineering Inc Login Number: 13554 List Number: 1 Creator: Hyatt, Samantha Question Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey True meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. True Job Nt List Sourc( [173 Eurofins Raleigh Page 14 of 14 11/14/2023