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HomeMy WebLinkAboutWI0800219_Permit (Completion)_20241002 (4) Final TECHNICAL MEMORANDUM C 24n- Solid Waste Management Unit 350 Downgradient Former AST Plume Biosparging Treatability Study Marine Corps Base Camp Lejeune, North Carolina PREPARED FOR: Bryan Beck/NAVFAC Mid-Atlantic Charity Delaney/MCB Camp Lejeune Beth Hartzell/North Carolina Department of Environmental Quality \\\\CARO y�ya Thomas Richard/MCB Camp Lejeune `��.``�,.•••••.�/ ds� @., "SS/n PREPARED BY: CH21VI HILL, Inc. (CH2M) 0•p�?�'"�D ,r• • s 14120 Ballantyne Corporate Place, Suite 200 =Z:cr�J�SEAi- f a 43749 Charlotte, NC NC Engineering License#F-0699 gr�,iN� DATE: March 2017 ���//lIIl1��, >e,4 CONTRACT: Comprehensive Long-term Environmental Action—Navy (CLEAN) rc Contract N62470-11-8012 Contract Task Order (CTO) WE2A Introduction This Technical Memorandum presents a summary of the second phase of the Naphthalene Biosparging Treatability Study, referred to as the Treatability Study, conducted between June 2015 and June 2016 at Resource Conservation and Recovery Act (RCRA) Solid Waste Management Unit (SWMU) 350, Marine Corps Base (MCB) Camp Lejeune, North Carolina (Figure 1). Overview SWMU 350 is a former aboveground storage tank (AST) facility, which consisted of Tanks STT-61 through STT-66, and is located approximately 400 feet east of Iwo Jima Boulevard, a former entrance to the Tarawa Terrace housing development of MCB Camp Lejeune, and 100 feet south of North Carolina State Highway 24 (Figure 1). The site previously accommodated six 30,000-ga lion-capacity ASTs that were used to store liquid propane from 1942 to 1984 and waste oil from 1984 to 1993.The ASTs were removed in 1993 and the associated subsurface fuel lines were removed in 2005. While elevated concentrations of various volatile organic compounds (VOCs) and semivolatile organic compounds have been detected in groundwater in the vicinity of the former ASTs and fuel lines since site investigations began in 1991, more recent data have shown a well-defined naphthalene plume in the 30-foot zone of the surficial aquifer referred to as the former AST plume. Following completion of a RCRA Facility Investigation (RFI), biosparging was identified as a remedial alternative for consideration in the removal of naphthalene from the former AST plume. Since site-specific data would improve evaluating the effectiveness of biosparging in the Corrective Measures Study (CMS), this Treatability Study was proposed and implemented in a phased approach within the former AST plume area (Figure 2). In 2013, the first phase of the biosparging treatability study was conducted in the surficial aquifer zone in the former AST plume source area and included installation of six biosparging wells, five new groundwater monitoring wells, one soil vapor extraction (SVE) well, and five soil gas sampling points. Based on the success of the first phase (CH2M, 2015), a second phase was conducted in the deeper, downgradient southern portion of the plume. Objectives The objectives of the Downgradient Former AST Plume Treatability Study were as follows: • Evaluate the feasibility and effectiveness of biosparging in a deeper and more diffuse naphthalene groundwater plume with observed lithological heterogeneity (deeper silty sand and clay lenses) located in the southern portion of SWMU 350. EN0623'6112ICLT Enclosure 3 SOLID WASTE MANAGEMENT UNIT 350 DOWNGRADIENT FORMER AST PLUME BIOSPARGING TREATABILITY STUDY MARINE CORPS BASE CAMP LEJEUNE,NORTH CAROLINA • Evaluate whether biosparging with increased well spacing (from 30 to 80 feet) and deeper biosparging screened intervals (from 40 to 45 feet) will result in treatment of the naphthalene groundwater plume. • Assess VOC concentrations in soil gas to evaluate the vapor intrusion pathway near Building TT84 during biosparging activities. Treatability Study Implementation In accordance with the Naphthalene Biosparging Treatability Study Work Plan Addendum, SWMU 350(referred to as the Work Plan) (CH2M, 2015),the Treatability Study and associated field activities were conducted between June 2015 and June 2016. A chronology of the primary activities conducted for the Treatability Study is presented in Table 1 and details are provided in the following subsections. TABLE 1 Treatability Study Chronology Date Event Notice of Intent May 6,2015 Submittal of Notification of Intent to Construct or Operate Injection Wells to the North Carolina Department of Environment and Quality(NCDEQ) June 2,2015 Utility locating June 9-June 18,2015 Construction and Startup June 9-12,2015 Biosparge wells and soil gas probes installation June 12-14, 2015 Biosparging System installation June 15-18, 2015 Biosparging System Startup Performance Monitoring July 15,2015 1-Month sampling August 21,2015 Biosparging system turned off August 25, 2015 2-Month sampling November 2 to 6,2015 5-Month sampling May 31 to June 3,2016 12-Month sampling North Carolina Department of Environmental Quality Notification of Intent to Construct On May 7, 2015, MCB Camp Lejeune submitted a Notification of Intent to Construct or Operate Injection Wells to NCDEQ(formerly known as North Carolina Department of Environment and Natural Resources) in accordance with 15A North Carolina Administrative Code 02C.0217, Permitting by Rule. The Notification detailed the need for installation and operation of air injection wells at SWMU 350 for the purpose of evaluating enhanced in situ biodegradation of naphthalene in groundwater in the surficial aquifer. Utility Locating Utility locating,that consisted of marking subsurface utilities and obstructions within 20 feet in each direction of any proposed subsurface work to be conducted during installation, was completed on June 2, 2015.This included the area near the proposed biosparging wells and soil gas monitoring points, and along the proposed air conveyance line (Figure 2).A third-party professional utility locating subcontractor identified subsurface structures that could be affected by drilling or trenching activities. In addition, the North Carolina One Call Center was called to mark out utilities. 2 EN0623161127CLT 2 SOLID WASTE MANAGEMENT UNIT 350 DOWNGRADIENT FORMER AST PLUME BIOSPARGING TREATABILITY STUDY MARINE CORPS BASE CAMP LEJEUNE,NORTH CAROLINA Construction and Startup Biosparging Well Installation The expanded biosparging system for the Treatability Study included four biosparging wells within the former AST plume in the southern portion of SWMU 350, and one biosparging well within the former AST plume in the northern portion of SWMU 350 (Figure 2).The biosparging wells in the southern portion were installed 80 feet apart (over twice the distance between biosparging wells for the 2013 Naphthalene Biosparging Treatability Study [CH2M, 2013]). Since biosparging creates a cone of air that emanates from the biosparging well screen and fans out laterally as the air travels upwards to the ground surface, the biosparging wells were installed at 45 feet below ground surface (bgs).This depth was selected to evaluate if deeper biosparge wells would provide a larger lateral zone of influence to compensate for the increased distance between biosparging wells. Biosparging well locations and depths were selected to target the area encompassing the more diffuse downgradient portion of the former AST plume (Figure 2). The five biosparging wells were installed to 45 feet bgs using roto-sonic drilling methods.The biosparging wells were constructed of 2-inch inner diameter Schedule 40 polyvinyl chloride (PVC) casing and a 2-foot section 0.006- inch machine slotted Schedule 40 PVC screen,with a bottom cap. The relatively small slot size was intended to promote more uniform distribution of air across the biosparging well screen.The screen was connected to new, threaded,flush-jointed PVC casing. A 30/70 silica sand filter pack was added to 6 inches above the screen,then a 2-feet thick bentonite seal was placed, and then the boring was grouted to the surface.Table 2 summarizes well construction details. Well construction diagrams of the five installed biosparging wells are provided in Attachment 1. The biosparging wells were completed slightly below grade and connected to the conveyance piping from the equipment compound. Soil Gas Monitoring Point Installation Four permanent soil gas monitoring points (SWMU350-SG06 through SWMU350-SG09) were installed using direct-push technology(Figure 2).The basic implant system consisted of a probe rod, an anchor point, and an implant screen with various connections to attach to the anchor point and the sample Teflon tubing. Prior to setting the 6-inch long screens,the depth to water in the area at the time of sampling was gauged in nearby wells to ensure that the bottoms of the soil gas monitoring points were placed between 1 and 2 feet above the water table. Since the depth to water in the Treatability Study area is typically between 8 and 10 feet bgs,the soil gas monitoring point screened intervals were installed approximately 5.5 to 6 feet bgs.The tops of the screens were placed at least 5 feet bgs, in accordance with the United States Environmental Protection Agency's (USEPA's) vapor intrusion guidance (2015). The implant was installed after the borehole was advanced to the desired depth by placing the anchor point and tubing into the boring.A Swagelock plug was affixed to the end of the tubing above ground so that soil gas does not escape from the implant into ambient air or vice versa.The soil gas monitoring points were completed slightly below ground surface with a 6-inch steel, manhole type protective cover.A filter pack of glass beads was added to 6 inches above the screen and then the boring was grouted to the surface with a bentonite mixture. The implant was allowed to equilibrate for 24 hours after installation before collecting a soil gas sample. A helium leak check was performed at each new soil gas monitoring point to make sure that the probes were installed correctly, and all checks passed.Table 2 summarizes soil gas monitoring point construction details. Biosparging System Installation The existing rotary screw air compressor used during the 2013 Naphthalene Biosparging Treatability Study(CH2M, 2013) (50 horsepower, 460 volt/3 phase/60 hertz), capable of producing 75 standard cubic feet per minute (scfm) at 110 pounds per square inch (psi), was used to supply compressed air to the biosparging wells.The in-line pressure regulator was set to approximately 50 psi, with a maximum of 60 psi. A total of approximately 500 feet of conveyance piping (1-inch-diameter air hose)was extended from the air compressor enclosure to each well within the treatment area (Figure 2). Conveyance lines were directly buried, with the exception of the conveyance lines that run through an above ground conduit across the Piedmont Natural Gas pipeline right-of-way. ENO623161127CLT 3 3 SOLID WASTE MANAGEMENT UNIT 350 DOWNGRADIENT FORMER AST PLUME BIOSPARGING TREATABILITY STUDY MARINE CORPS BASE CAMP LEJEUNE,NORTH CAROLINA Biosparging wells were constructed so that flow rates could be adjusted independently. Pressure gauges,flow meters, and ball valves were installed above ground.Air compressor supporting equipment, including valves, hoses, pressure regulators,flow meters, and fittings, is referenced in the Piping and Instrumentation Diagram (Figure 3). Biosparging System Startup The system was started on June 15, 2015, and the start-up process of gradually increasing the air flow to the target flow rate continued through June 18, 2015. During the startup period, dissolved oxygen (DO) and groundwater level monitoring was performed as explained below. Initially, air was injected into each vertical biosparging well at rates of approximately 3 to 5 scfm for 24 hours.The purpose of this initial period of low-flow injection is to monitor aquifer response, particularly with regard to water table displacement, which is related to capillary resistance of the formation. Groundwater elevations were checked in three groundwater monitoring wells (SWMU350-MW16, SWMU350-MW47-18, and SWMU350-MW47- 30) using an In Situ Troll 9500 for the first 2 to 3 days to assess whether water level stabilization has occurred. After the initial 24 hours of operation at 3 to 5 scfm,flow rates were gradually increased, up to a maximum of 15 scfm. Operations and Maintenance System parameters including regulator pressure, air compressor flow rate,total system flow rate and pressure, and individual biosparging well flow rates and pressures were recorded weekly to monitor the operation of the biosparging system and are included in Attachment 2. Performance Monitoring Eight existing monitoring wells (Table 2)were used for performance monitoring during the Treatability Study. Groundwater sampling and gauging was conducted during a baseline event (November 2013), prior to the startup of the biosparging system,followed by four post-startup sampling events (1, 2, 5, and 12 months after startup). The system was turned off on August 21, 2015, before the 2-month sampling event was conducted.The 5-month and 12-month events were conducted 3 and 10 months, respectively, after the system had been shut down to evaluate for potential rebound.The water quality parameters measured during the monitoring events except the 12- month sampling event which was conducted using passive diffusion bags (PDBs) are summarized in Table 3. The groundwater elevations measured during these monitoring events are summarized in Table 4. Soil gas samples were collected during the baseline, 1-month, and 2-month post-startup events. Groundwater Sampling Four rounds of groundwater sampling were conducted to assess performance, after 1 month of operation, after 2 months of operation, and after 5 and 12 months when the system had been shut down for 3 and 10 months. The November 2013 groundwater monitoring results were used as a baseline. To conduct the groundwater sampling, the monitoring wells listed in Table 2 were opened and allowed to equilibrate before being gauged. Once wells adequately equilibrated, the monitoring wells were gauged for depth to groundwater and depth to bottom. Following gauging,the monitoring wells were sampled. Groundwater quality parameters, listed below,were collected in the field during sampling and samples were sent to an analytical laboratory to be analyzed for naphthalene by USEPA Method 826013. Field-analyzed natural attenuation indication parameters and groundwater quality parameters (Table 3): • Temperature • Specific conductivity • DO • pH • Oxidation-reduction potential (ORP) • Turbidity 4 EN0623161127CLT 4 SOLID WASTE MANAGEMENT UNIT 350 DOWNGRADIENT FORMER AST PLUME BIOSPARGING TREATABILITY STUDY MARINE CORPS BASE CAMP LEJEUNE,NORTH CAROLINA Groundwater Sampling Results The groundwater data from post-startup samples were compared to baseline conditions to evaluate performance of the Treatability Study. During the baseline sampling event, naphthalene was detected above the North Carolina Groundwater Quality Standards (NCGWQS) in groundwater samples collected from SWMU350-MW06, SWMU350-MW16, and SWMU350-MW47-30 (Table 5) and plume maps are shown on Figure 5. Naphthalene was not detected at concentrations exceeding NCGWQS in groundwater samples collected after 1-month operation of biosparging. Naphthalene concentration trends are included on Figure 4. During the 1-month and 2-month monitoring events, naphthalene was only detected in samples collected from monitoring well SWMU350-MW47-30, screened in the 30-foot zone, at estimated concentrations of 2.4 J micrograms per liter(µg/L) and 2.6 J µg/L respectively.These concentrations are below the NCGWQS of 6 µg/L for naphthalene. Naphthalene was not detected above method detection limits in samples collected from the 15-foot zone aquifer wells. To evaluate for potential naphthalene rebound groundwater samples were collected during the 5-month and 12- month monitoring period after system startup (3-months and 10 months after the system shut down). Naphthalene concentrations in the groundwater samples collected in the treatment area were not detected above the method detection limits. Zone of Influence Monitoring Water levels and field parameters, including DO, ORP, and pH, were monitored continuously with In Situ Troll 9500 water quality instruments with data logging capability during the startup of the biosparging system to evaluate the zone of influence. On June 15, 2015,the data loggers were deployed in wells SWMU350-MW16, SWMU350-MW47-18, and SWMU350-MW47-30 prior to the startup of the biosparging system to establish baseline conditions. Data logging was discontinued on June 17, 2015,following approximately 2 days of data collection.The DO and water table displacement data are shown in Attachment 3. Due to the introduction of air bubbles directly into the well casing of SWMU350-MW16, water pressure measurements were distorted and do not represent actual feet of water level change.The initial continuous DO measurements along with periodic water quality parameter data collected during performance monitoring were used to assess the zone of influence for biosparging which overall indicated that oxygen was successfully introduced to the target area. Specific observations of zone of influence include: • DO levels were observed to increase within 3 hours of system startup (Attachment 3) in SWMU350-MW16 located approximately 20 feet from SWMU350-IW59-45 (Figure 4). • DO levels were observed to increase within 7 hours of system startup in SWMU350-MW47-18 and within 24 hours of system startup in SWMU350-MW47-30 (Attachment 3) which are located approximately 40 feet from SWMU350-IW61-45 (Figure 4). • In the 15-foot surficial aquifer zone groundwater, the highest detected DO concentration during performance monitoring was 6.94 milligrams per liter(mg/L) in SWMU350-MW49-18 (roughly 100 feet side gradient from SWMU350-IW59-45). • In the 30-foot zone,the highest detected DO concentration during performance monitoring was 10.30 mg/L in SWMU350-MW06 (roughly 20 feet from SWMU350-IW63-45). Site-wide data collected during the 5-month post-startup monitoring event (3 months after system had been turned off) showed elevated DO concentrations persisted for all of the wells monitored during this study except SWMU350-MW47-18, SWMU350-MW48-18, and SWMU350-MW48-30 when compared against the 2011 RCRA Facility Investigation data (CH2M, 2012). These lines of evidence suggest a zone of influence of up to 100 feet can be assumed for estimates in the Corrective Measures Study evaluation. Soil Gas Sampling Soil gas samples were collected from three of the four soil gas monitoring points prior to startup and from two of the four soil gas monitoring points at the 1-and 2-month post-startup monitoring events (Figure 2,Table 2).The samples were analyzed for benzene and naphthalene by USEPA Method TO-15. Samples were unable to be EN0623161127CLT 5 5 SOLID WASTE MANAGEMENT UNIT 350 DOWNGRADIENT FORMER AST PLUME BIOSPARGING TREATABILITY STUDY MARINE CORPS BASE CAMP LEJEUNE,NORTH CAROLINA collected from SWMU350-SG08 during all three of the events, along with SWMU350-SG09 during the 1-month and 2-month event due to water being present in the soil gas monitoring point tubing, indicating the water table had risen above the probe depth. Soil Gas Sampling Results Naphthalene was not detected in soil gas samples above the method reporting limit and benzene was not detected above the North Carolina Division of Waste Management Residential Vapor Intrusion Screening Level for Sub Slab and Exterior Soil Gas (October 2016). No exceedances were detected in soil gas during the baseline, 1- month, or 2-month post-startup event. A summary of the naphthalene soil gas sampling results is shown in Table 6. Conclusions Based on an analysis of data collected during the Treatability Study, a summary of the objectives and corresponding conclusions are included below in Table 7. TABLE 7 Objectives and Conclusions Summary Table Objectives Conclusions Evaluate the feasibility and effectiveness of biosparging in a Biosparging is feasible and effective since naphthalene deeper and more diffuse naphthalene groundwater plume concentrations in groundwater samples collected from with observed lithological heterogeneity(deeper silty sand performance monitoring wells were observed to decrease and clay lenses) located in the southern portion of SWMU to below NCGWQS from the baseline event to the 2-month 350. post-startup event.After shutting down the system for 3 months, naphthalene concentrations were below method reporting limits and no rebound was observed throughout the study. Evaluate whether biosparging with increased well spacing Both increased well spacing(up to 80 feet)and deeper (from 30 to 80 feet)and deeper biosparging screened biosparging screened intervals were shown to be effective intervals(from 40 to 45 feet)will result in treatment of the at treating naphthalene within the target treatment area. naphthalene groundwater plume. Assess VOC concentrations in soil gas to evaluate the vapor Naphthalene was not detected in soil gas samples intrusion pathway near Building TT84 during biosparging collected near Building TT84 and therefore the vapor activities. intrusion pathway was determined to be incomplete. Recommendations Based on the analytical results and conclusions discussed above the following is recommended: • Conduct two more groundwater sampling events representative of the seasonal changes to confirm the concentration levels remain below the NCGWQS. 6 EN0623161127CLT 6 SOLID WASTE MANAGEMENT UNIT 350 DOWNGRADIENT FORMER AST PLUME BIOSPARGING TREATABILITY STUDY MARINE CORPS BASE CAMP LEJEUNE,NORTH CAROLINA References CH2M HILL, Inc. (CH2M). 2012. RCRA Facility Investigation Report, SWMU 350. Marine Corps Base Camp Lejeune, Jacksonville, North Carolina. May. CH2M. 2013. Naphthalene Biosparging Treatability Study Work Plan. Marine Corps Installations East—Marine Corps Base Camp Lejeune,Jacksonville, North Carolina. April. CH2M. 2015. Naphthalene Biosparging Treatability Study Solid Waste Management Unit 350. Marine Corps Installations East—Marine Corps Base Camp Lejeune, North Carolina. May. CH2M. 2015. Naphthalene Biosparging Treatability Study Work Plan Addendum. Marine Corps Installations East— Marine Corps Base Camp Lejeune,Jacksonville, North Carolina. May. United States Environmental Protection Agency (USEPA). 2015. OSWER Guidance for Assessing and Mitigating the Vapor Intrusion Pathway from Subsurface Vapor Sources to Indoor Air.June. EN0623161127CLT 7 7 Tables TABLE 2 Well Construction and Performance Monitoring Summary SWMU 350 Naphthalene Biosparging Treatability Study MCB CAMP LEJEUNE North Carolina 1-Month,2-Month,5-Months and 12 Months Post Start-up Events Construction Summary Groundwater Soil Gas Surficial Screen Screen Treatability Total Depth Naphthalene Alkalinity/Ferrous Iron Benzene/Naphthalene Study Well ID Aquifer (ft bgs) Length Interval Zones (ft) (ft bgs) (USEPA TO-15) (82606) (HACH Field Kits) ` New SWMU350-IW59-45 30-foot 45 2 43-45 Biosparging SWMU350-IW60-45 30-foot 45 2 43-45 Wells SWMU350-IW61-45 30-foot 45 2 43-45 SWMU350-IW62-45 30-foot 45 2 43-45 -- -- SWMU350-IW63-45 30-foot 45 2 43-45 - -- Existing SWMU350-MW06 15-foot 18 10 8-18 X X Groundwater SWMU350-MW16 30-foot 30 10 20-30 X X Monitoring SWMU350-MW47-18 15-foot 18 10 8-18 X X Wells SWMU350-MW47-30 30-foot 30 10 20-30 X X SWMU350-MW48-18 15-foot 18 10 8-18 X X SWMU350-MW48-30 30-foot 30 5 25-30 X X SWMU350-MW49-18 15-foot 18 10 8-18 X X SWMU350-MW49-30 30-foot 30 5 25-30 X X Baseline,1-Month Post Start-up,2-Month and 5 Months Post Start-up New Soil Gas SWMU350-SG06 Vadose 6 6-inches 5.5-6 X Monitoring SWMU350-SG07 Vadose 6 6-inches 5.5-6 X Points SWMU350-SG08 Vadose 6 6-inches 5.5-6 X SWMU350-SG09 I Vadose 6 6-inches 5.5-6 - X QA/QCd X X Count by Event: 12 7 5 Notes: --Not applicable 'Aquifer zone for surficial groundwater monitoring wells unless otherwise specified,or for vadose zone(above water table)for soil gas monitoring points. b Soil gas monitoring point implant includes an AT87 series,6-inch-long,stainless steel,wire mesh screen with top and bottom threaded fittings Soil gas samples for USEPA TO-15 and PID readings collected for each event. dQA/QC for groundwater sampling conducted for VOCs only:for groundwater,QA/QC included one trip blank per cooler,one equipment blank,one duplicate sample,and one matrix spike/matrix spike duplicate sample;for soil gas,QA/QC samples included duplicate samples. ft-feet ft bgs-feet below ground surface Page 1 of 1 9 TABLE 3 Summary of Groundwater Quality Parameters SWMU 350 Naphthalene Biosparging Treatability Study MCB Camp Lejeune,North Carolina Well ID Date Temperature Conductivity DO pH ORP Turbidity (°C) (MS/cm) (mg/L) (SU) (mV) (NTU) 7/15/2015 20.71 0.10 9.75 4.23 278.30 10.2 SWMU350-MW06 8/24/2015 21.26 0.07 10.30 4.15 163.80 2.73 11/4/2015 21.08 0.07 0.73 4.66 282.20 9.62 7/15/2015 19.84 0.06 8.77 4.16 258.80 9.94 SWMU350-MW16 8/25/2015 21.71 0.05 8.70 4.08 302.40 5.36 11/5/2015 19.50 0.06 2.30 3.50 280.30 3.39 SWMU350-MW47-18* 7/15/2015 24.94 0.16 1.10 4.00 332.70 5.78 8/25/2015 25.27 0.14 0.35 3.81 354.40 16.2 7/15/2015 21.19 0.11 2.00 4.18 342.70 696 SWMU350-MW47-30 8/25/2015 22.10 0.10 2.17 3.69 303.30 527 11/4/2015 21.30 0.15 2.69 4.00 285.10 15.5 SWMU350-MW48-18* 7/15/2015 23.78 0.11 0.64 4.34 350.60 8.98 8/24/2015 24.91 0.09 0.95 4.27 180.60 3.85 SWMU350-MW48-30* 7/15/2015 25.96 0.13 0.52 4.95 193.10 9.88 8/24/2015 23.30 0.10 0.11 4.98 -2.50 19.3 SWMU350-MW49-18* 7/15/2015 22.83 0.06 6.43 4.31 238.50 163 8/25/2015 27.39 0.06 6.94 4.24 300.70 259 7/15/2015 21.79 0.08 3.80 4.15 206.40 8.05 SWMU350-MW49-30 8/25/2015 25.55 0.08 6.85 4.06 303.00 14 11/5/2015 21.52 0.05 4.90 4.36 310.90 9.13 Notes: * November 2015 data were not available for some wells because samples were collected using passive diffusion bags(PDB)technique °C-degrees Celcius ORP-oxidation reduction potential mS/cm-milliSiemens per centimeter mV- millivolts DO-dissolved oxygen NTU-nephelometric turbidity unit mg/L-milligram per liter SU-standard unit Page 1 of 1 10 TABLE 4 Summary of Groundwater Elevations SWMU 350 Naphthalene Biosparging Treatability Study MCB CAMP LEJEUNE, North Carolina Well ID Total Depth Screened Interval Ground Surface Elevation Top of Casing Elevation Surface Completion Type Date Depth to Water Depth to Water Groundwater Elevation (ft bgs) (ft bgs) (ft amsl) (ft amsl) (ft btoc) (ft bgs) (ft amsl) 11/6/2013 11.50 9.87 18.06 7/15/2015 9.95 8.32 19.61 SWMU350-MW06 15 8-18 27.93 29.56 Stick Up 8/24/2015 8.53 6.90 21.03 11/4/2015 NM N M NM 11/6/2013 9.80 8.21 17.63 SWMU350-MW16 30 20-30 25.84 27.43 Stick Up 7/15/2015 8.62 7.03 18.81 8/24/2015 7.05 5.46 20.38 11/4/2015 5.71 4.12 21.72 11/6/2013 10.10 10.29 17.67 SWMU350-MW47-18 18 8- 18 27.96 27.77 Flush 7/15/2015 7.83 8.02 19.94 8/24/2015 7.55 7.74 20.22 11/4/2015 5.97 6.16 21.80 11/6/2013 10.51 10.75 17.27 SWMU350-MW47-30 30 20-30 28.02 27.78 Flush 7/15/2015 9.80 10.04 17.98 8/25/2015 7.80 8.04 19.98 11/4/2015 6.60 6.84 21.18 11/6/2013 N M NM NM SWMU350-MW48-18 18 8-18 25.98 25.66 Flush 7/15/2015 5.75 6.07 19.91 8/24/2015 9.09 9.41 16.57 11/4/2015 3.14 3.46 22.52 11/6/2013 N M NM NM SWMU350-MW48-30 30 25-30 25.85 25.59 Flush 7/15/2015 6.70 6.96 18.89 8/24/2015 5.44 5.70 20.15 11/4/2015 4.20 4.46 21.39 11/6/2013 8.89 5.94 17.60 SWMU350-MW49-18 18 8- 18 23.54 26.49 Stick Up 7/15/2015 10.89 7.94 15.60 8/25/2015 6.71 3.76 19.78 11/4/2015 4.77 1.82 21.72 11/6/2013 8.94 5.91 17.54 SWMU350-MW49-30 30 25-30 23.45 26.48 Stick Up 7/15/2015 7.70 4.67 18.78 8/25/2015 6.10 3.07 20.38 11/4/2015 4.82 1.79 21.66 Notes: ft bgs-feet below ground surface ft amsl-feet above mean sea level ft btoc-feet below top of casing NM-Not Measured Page 1 of 1 11 TABLE 5 Groundwater Analytical Results-Naphthalene SWMU 350 Naphthalene Biosparging Treatability Study MCB Camp Lejeune,North Carolina Surficial Aquifer Five-Month 12-Month Sampling Event Baseline One-Month Two-Month (3 month post shut- (10 month post shut- Zone down) down) Sample Date November 2013 July 2015 August 2015 November 2015 May/June 2016 NCGWQS for Naphthalene(µg/L) 6 Naphthalene(µg/I) Station Location SWMU350-MW06 15-foot 74 0.5 U 0.5 U 0.5 U 0.5 U SWMU350-MW16 30-foot 59 0.5 U 0.5 U 0.5 U 0.5 U SWMU350-MW47-18 15-foot 1 U 0.5 U 0.5 U 0.5 U 0.5 U SWMU350-MW47-30 30-foot 7.8 2.4 J 2.6 J 0.5 U 0.5 U SWMU350-MW48-18 15-foot NA 0.5 U 0.5 U 0.5 U 0.5 U SWMU350-MW48-30 30-foot NA 0.5 U 0.5 U 0.5 U 0.5 U SWMU350-MW49-18 15-foot 1 U 0.5 U 0.5 U 0.5 U 0.5 U SWMU350-MW49-30 I 30-foot 0.59 J 0.5 U 0.5 U 0.5 U 0.5 U Notes: NCGWQS-North Carolina Groundwater Quality Standards Shading indicates exceedance of NCGWQS NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The compound was analyzed for,but not detected µg/I-Micrograms per liter Page 1 of 1 12 TABLE 6 Summary of Soil Gas Analytical Results SWMU 350 Naphthalene Biosparging Treatability Study MCB CAMP LEJEUNE, North Carolina Well ID Date Naphthalene Benzene /m3 /m3 6/5/2015 0.8 U 0.4 U SWMU350-SG06 7/9/2015 0.8 UJ 0.4 J 9/3/2015 0.8 U 0.4 U 6/5/2015 0.8 U 0.69 J SWMU350-SG07 7/9/2015 0.8 U 0.4 U 9/3/2015 0.8 U 0.4 U 6/5/2015 NA NA SWMU350-SG08 7/9/2015 NA NA 9/3/2015 NA NA 6/5/2015 0.8 U 0.69 J SWMU350-SG09 7/9/2015 NA NA 9/3/2015 NA NA Notes: NA- Not analyzed fag/m3 - micrograms per meter cubed U - material analyzed for, but not detected J - estimated value Bold values indicate detection Concentrations in soil gas did not exceed the North Carolina Division of Waste Management Residential Vapor Intrusion Screening Level for Sub Slab and Exterior Soil Gas (October 2016) for naphthalene of 20.9 lag/m3 or for benzene of 120 lag/m3 during the treatability study. Page 1 of 1 13 Figures 14 R',ENBG\00 Prd\Tem S no tek\USNavFacEn Com405450\MCBCam Le'eune\Ma Files\SWMU 350\425128 TS TM\2016\Fi ure 1 Site Location Ma .mxd10/25/2016AM038876 SWMU 350 tF PAU ^� O - - Ivy^.. O1�• TT$ - T� W W *" A;Yr W ai W - E) - 0 m NO, p .° SAIPAN DRIVE - — i x r , O '� 4 �O� r UNOW ' �F ^ i is ♦ _;,�, _ - _ - Legend Figure 1 Natural Gas Main Line 0 2013 Naphthalene Biosparging Treatability Study Area Site Location Map SWMU 350 Naphthalene Biosparging Treatability Study Drainage Swale C3 2015 Naphthalene Biosparging Treatability Study Area MCB Camp Lejeune = Highways N North Carolina SWMU 350 Boundary 0 150 300 600 0 Former AST Locations Feet C142M- O Installation Boundary 1 inch = 300 feet 15 R1ENBG\00 Pro\Tem S no tek\USNavFacEn Com405450\MCBCam Leeune\Ma Files\SWMU 350\425128 TS TM\2016\Fi ure 2 Na thalene Treatability Study Location Ma .mxd10/24/2016AM038876 I� O � T , t _ � � �' SWMU350-MW08 • ' ) ,' SWMU350-IW83=45 _ •. )�%W SWMU350-MW49-18 ��� ��'�� �� _r'• SWMU350-MW49-30 • SWMU350-IW59 45 ,�� • �•* • SWM�Uf350-MW16 SWMU350 MW48-18 fll � } SWMU 350=M W48-30. • SWMU350-IW60♦45 ti � � y,• = SWMU350-IW82-45 • • t SWMU350-IW6145 /SWMU350-SG06 SWMU350-MW47-18 SWMU 350-MW47-30 ,SWMU350-SG07 , SWMU350-SG08 r _ SWMU350-SG09 7 Equipment Compound SWMU 350 Boundary >y l .� TT84 O Installation Boundary 2013 Naphthalene Biosparging r. Treatability Study Area ; 0 2015 Naphthalene Biosparging 1 Treatability Study Area so Former AST Plume NCGWQS Exceedances • (November 2013) ! 30ft Zone f - Note: Highlighted wells indicate biosparging � 1 r performance monitoring locations. 116 , Legend „ Figure 2 Biosparging Well Location(45 ft bgs) Monitoring Wells Napthalene Treatability Study Location Map Soil Gas Monitoring Points 15 ft zone SWMU 350 Naphthalene Biosparging Natural Gas Line 30 ft zone N Treatability Study New Biosparging Air Conveyance Line 55 ft zone 0 50 100 MCB Camp Lejeune • New Horizontal Conveyance Boring 75 ft zone M06iiiiiiiii@ Feet North Carolina O 115ft zone 1 inch = 100 feet Ima er Source: ©2015 ESRI � � 16 F F� To SWMU350-IW59-45 P p Pressure Pressure Gauge Flow Meter Check Valve Pressure Flow Meter Globe Valve Regulator Gauge Dwyer Globe Valve Stainless steel, Dwyer model (Brass) (Brass) liquid filled, UV-B112 0-30 PSI Rotary Screw tir Compressor Kaeser BSD-50 R �I' To SWMU350-IW60-45 (50 hp, 83 full load amps) P 460V/3-phase/6OHz, air-cooled, Pressure Gauge Flow Meter Check Valve 125 PSIG max. pressure Globe Valve Stainless steel, Dwyer model (Brass) (Brass) liquid filled, UV-B112 0-30 PSI F� To SWMU350-IW61-45 P Pressure Gauge Flow Meter Check Valve Globe Valve Stainless steel, Dwyer model (Brass) (Brass) liquid filled, UV-B112 0-30 PSI To SWMU350-IW62-45 P Pressure Gauge Flow Meter Check Valve Globe Valve Stainless steel, Dwyer model (Brass) (Brass) liquid filled, UV-B112 0-30 PSI To SWMU350-IW63-45 \ P Pressure Gauge Flow Meter Check Valve Globe Valve Stainless steel, Dwyer model (Brass) (Brass) liquid filled, UV-B112 0-30 PSI Figure 3 Piping and Instrumentation Diagram SWMU 350 Naphthalene Biosparging Treatability Study MCB Camp Lejeune North Carolina dam' R:\USNAVFACENGCOM405450\MCBCAMPLEJEUNE\MAPFILES\SWMU 350\425128 TS TM\2016\FIGURE 4 NAPHTHALENE AND DISSOLVED OXYGEN CONCENTRATIONS11X17.MXD AMITCHUM CH2MHILLENV10/5/20162:21:22PM MV4WW 1420factfrom r*6345 t , 5 100 18 - , 90 I 16 r•t k 1 80 i 14 70 = 60 1050 • �, 40 I _ Ilk 30 I - a , 10 I z 1 - � 1 0 -- D 1"' tid 'tiA 1b 1D` by 1h by tib tib Date —Groundwater Analytical Results-Naphthalene IDO(mg/L) —System Startup --System Shut Down f SWMU350-MW06 - �� SWMU350-IW63145 R MW16-30 20 feet from IW59.45 100 18 - z� _. _ SWMU350-MW4-9 8 I 90 , 16 SWMU350-MW49-30 ? 80 I 14 70 • II SWMU350-IW55 WMU353 1 0-MW48-18 12 - �r i SWMU350-MW48-30 w 60 n I 10 SWMU350-IW60-45 I z 50 a - • 2 8 40 i SWMU350-IW625 I 6 SWMU3501IW61-45 SWMU350-SG06 30 I 20 I SWM U350-M W 47-18 , 10 2 SWMU350-MW47-30' I SWMU350-SG09 SW M U350-SG 07 - o � 0 - SWMU350-SG08 1 _ �~� tia ~� ti° ti°' by by by tib ti6 - Date —Groundwater Analytical Results-Naphthalene =—DO(mg/L) —System5tartup --System Shut Down ' TT84 MW47-30 - 40 feet from IW61-45 IO 18 9 16 1 I t 8 14 SWMU350-MW41' 5 12 6 I m m Equipment Compound 10 SWMU 350 Boundary s , O Installation Boundary 4 8 2013 Naphthalene Biosparging `.; ; 6 Treatability Study Area sWMu350-Mw3s-55 a 2015 Naphthalene Biosparging , U350- W39-75 � SWM M 4 Treatability Study Area z , Former AST Plume NCGWQS Exceedances I 2 - 1 (November 2013) _ I 30ft Zone D I 0 Note: ti3 ti' ti° ti� tia tih tih ,`' tie ti� Highlighted wells indicate biosparging Date performance monitoring locations. —GroundwaterAnalyticalResults-Naphthalene —DO(mg/L) —System Startup --System Shut Down Legend Figure 4 Biosparging Well Location (45 ft bgs) Monitoring Wells Naphthalene and Dissolved Oxygen Concentration • Soil Gas Monitoring Points & 15 ft zone N Trend Graphs - 30-foot zone Biosparging Air Conveyance Line 0 30 ft zone 0 50 100 200 SWMU 350 Naphthalene Biosparging — Horizontal Conveyance Boring & 55 ft zone Feet Treatability Study Natural Gas Line • 75 ft zone MCB Camp Lejeune O 115ft zone 1 inch = 100 feet North Carolina d'12AW 18 Baseline - 5 Months Post Startup - ,.: . 12 Months Post Startup t r �• -.y"�� SWMU350-MWO6 1, 5WMU350-MWO6 5WMU350-MWO6 •� (; SWMU350-IW63d5 + - SWMU350-IW63d5 SWMU350-IW63d5 _ ; + k � �� .<�• _ .. �� ��:t. � ems, _ "�lt. � SWMU350-MW49.18 � �- � SWMU350-MW49.18 SWMU350-MW49-18 T 7 U - O.S U , y� •y SWMU350-MW49-30 - �. � SWMU350-MW49-30 � SWMU350-MW49-30 5 0-M 'I y 4'- MU350-MW16 SWMU30505-MU W48-18 '`1 SWMU350-MWt6 U350-IW59d5 SWMU30505-MW48- 0 SWSWMU350 \MU35 -IW59d SWMU35N 9d SWM 59 18 U "S'SWMU350-MW48-30 Ih b' SWMU350-MW48.30 5WMU350-MW48.30. SWMU350-IW60d5 O.SU -� - r'- '2 ';, ,? SWMU350-IW60d5 0.5U T - SWMU350-IW60d5 0.5U /SWMU350-IW62d5 -� { � 11l SWMU350-IW62d5 - �� /SWMU350-IW62d5 - /SWMU350-SGO6 �• SWMU350-IW61d5 .SWMU350-SGO6 -.. `r SWMU350-SGO6 SWMU350-IW61 d5 Y SWMU350-IW61 d5 T, \/y SWMU350-MW47-18 b SWMU350-MW47-18 !l�!:'\ �i. - SWMU350-MW47-1� r _ SWMU350-MW47-30 = SWMU350-MW47-30= SWMU350-MW47-30 - 7.8 '�- 0.5U SWMU350-SG07 M SWMU350,-SG0707 �•• � SWMU350-SG07 SWMU350SG08 - - - --- ,� SWMU350-SGOB - _ - - --. ,� SWMU350-SG08•. SWMU350-SG09 - - - SWMU350-SG09 - SWMU350-SG09 _-.- fw • - _ - - +"- Y ;' -� _ �r ,�_ _ y� _ ip g - .TT84 �r ELI 'A t. r Legend Notes: ® Equipment Compound Former AST Plume NCGWQS Exceedances • Biosparging Well Location(45 ft bgs) Monitoring Wells 1) Highlighted wells indicate biosparging 6) NCGWQS for Naphthalene is 6 ug/L SWMU 350 Boundary (November 2013) • Soil Gas Monitoring Points 15 ft zone performance monitoring locations 7)J-analyte present,value may or may not � 30ft Zone 2) Concentrations shown in ug/L be accurate or precise North Installation Boundary +■■Biosparging Air Conveyance Line 30 ft zone IO rY 3) Baseline event data collected in November 8) UJ-analyte not detected,quantitation limit 0 50 100 Naphthalene Concentrations—November 0 Horizontal Conveyance Boring 2013 Naphthalene Biosparging 2013 y g 0 55 ft zone 2013 may be inaccurate FTTTSiiiiia Feet Treatability Study Area 60 µg/L 0 75 ft zone 4) 5-Month Post Startup data collected 9) U-analyte analyzed for but not detected IO 2015 Naphthalene Biosparging November 2015 10)NA-Not Analyzed Treatability Study Area 6 µg/L —Natural Gas Line 5) 12 month post startup data collected in May/June,2016 Figure 5 Naphthalene Plume—Surficial Aquifer(30-foot Zone) SWMU 350 Naphthalene Biosparging Treatability Study MCB Camp Lejeune, North Carolina C412W- EN051816115OWDC Fig5_CL_SWMU_350_TS_P1ume_Surflda1Aquifer_30-ft.ai 19 Attachment 1 Well Completion Diagrams 20 PROJECT NUMBER WELL NUMBER 472752.03.PT.PT IW59-45 SHEET 1 OF 1 CH2MHILL WELL COMPLETION DIAGRAM PROJECT:SWMU 350 Naphthalene Biosparging Treatability Study LOCATION:MCIEAST-MCB CAMLEJ DRILLING CONTRACTOR: Terrasonic NORTHING: EASTING: DRILLING METHOD AND EQUIPMENT USED:6"Rotosonic WATER LEVELS: 10 feet bgs START:06/09/15 END:06/09/15 LOGGER:M.Ost 3 3b \ 2 1\ 1-Ground elevation at well NA 2-Top of casing elevation NA 3-Wellhead protection cover type Buried a)Bollards NA b)concrete pad dimensions NA 8--- 40' 4-Dia./type of well casing 2"Sch 40 PVC 42' 43' 5-Type/slot size of screen 2"Sch 40 PVC-0.006 slot 7 45' 6-Type screen filter #1 silica pack 4 a)Quantity used 1 bag 7-Type of seal Bentonite 3/8"chips a)Quantity used 1 bag 5 8-Grout a)Grout mix used Portland Cement,Bentonite grout b)Method of placement tremie c)Vol.of well casing grout 75 gallons Development method Whale Pump 2' 6 Development time 10 minutes Estimated purge volume 20 gallons Comments Biosparging well.Connected to air compressor.Head is buried. Page 1 of 1 21 PROJECT NUMBER WELL NUMBER 472752.03.PT.PT IW60-45 SHEET 1 OF 1 CH2MHILL WELL COMPLETION DIAGRAM PROJECT:SWMU 350 Naphthalene Biosparging Treatability Study LOCATION:MCIEAST-MCB CAMLEJ DRILLING CONTRACTOR: Terrasonic NORTHING: EASTING: DRILLING METHOD AND EQUIPMENT USED:6"Rotosonic WATER LEVELS: 10 feet bgs START:06/10/15 END:06/10/15 LOGGER:M.Ost 3 3b \ 2 1\ 1-Ground elevation at well NA 2-Top of casing elevation NA 3-Wellhead protection cover type Buried a)Bollards NA b)concrete pad dimensions NA 8--- 40' 4-Dia./type of well casing 2"Sch 40 PVC 42' 43' 5-Type/slot size of screen 2"Sch 40 PVC-0.006 slot 7 45' 6-Type screen filter #1 silica pack 4 a)Quantity used 2 bags 7-Type of seal Bentonite 3/8"chips a)Quantity used 1 bag 5 8-Grout a)Grout mix used Portland Cement,Bentonite grout b)Method of placement tremie c)Vol.of well casing grout 75 gallon Development method Whale Pump 2' 6 Development time 10 minutes Estimated purge volume 20 gallons Comments Biosparging well.Connected to air compressor.Head is buried. Page 1 of 1 22 PROJECT NUMBER WELL NUMBER 472752.03.PT.PT IW61-45 SHEET 1 OF 1 CH2MHILL WELL COMPLETION DIAGRAM PROJECT:SWMU 350 Naphthalene Biosparging Treatability Study LOCATION:MCIEAST-MCB CAMLEJ DRILLING CONTRACTOR: Terrasonic NORTHING: EASTING: DRILLING METHOD AND EQUIPMENT USED:6"Rotosonic WATER LEVELS: 10 feet bgs START:06/11/15 END:06/12/15 LOGGER:M.Ost 3 3b \ 2 1\ 1-Ground elevation at well NA 2-Top of casing elevation NA 3-Wellhead protection cover type Buried a)Bollards NA b)concrete pad dimensions NA 8--- 40' 4-Dia./type of well casing 2"Sch 40 PVC 42' 43' 5-Type/slot size of screen 2"Sch 40 PVC-0.006 slot 7 45' 6-Type screen filter #1 silica pack 4 a)Quantity used 2 bags 7-Type of seal Bentonite 3/8"chips a)Quantity used 1 bag 5 8-Grout a)Grout mix used Portland Cement,Bentonite grout b)Method of placement tremie c)Vol.of well casing grout 75 gallons Development method Whale Pump 2' 6 Development time 10 minutes Estimated purge volume 20 gallons Comments Biosparging well.Connected to air compressor.Head is buried. Page 1 of 1 23 PROJECT NUMBER WELL NUMBER 472752.03.PT.PT IW62-45 SHEET 1 OF 1 CH2MHILL WELL COMPLETION DIAGRAM PROJECT:SWMU 350 Naphthalene Biosparging Treatability Study LOCATION:MCIEAST-MCB CAMLEJ DRILLING CONTRACTOR: Terrasonic NORTHING: EASTING: DRILLING METHOD AND EQUIPMENT USED:6"Rotosonic WATER LEVELS: 10 feet bgs START:06/10/15 END:06/11/15 LOGGER:M.Ost 3 3b \ 2 1\ 1-Ground elevation at well NA 2-Top of casing elevation NA 3-Wellhead protection cover type Buried a)Bollards NA b)concrete pad dimensions NA 8--- 40' 4-Dia./type of well casing 2"Sch 40 PVC 42' 43' 5-Type/slot size of screen 2"Sch 40 PVC-0.006 slot 7 45' 6-Type screen filter #1 silica pack 4 a)Quantity used 2 bags 7-Type of seal Bentonite 3/8"chips a)Quantity used 1 bag 5 8-Grout a)Grout mix used Portland Cement,Bentonite grout b)Method of placement tremie c)Vol.of well casing grout 75 gallons Development method Whale Pump 2' 6 Development time 10 minutes Estimated purge volume 20 gallons Comments Biosparging well.Connected to air compressor.Head is buried. Page 1 of 1 24 PROJECT NUMBER WELL NUMBER 472752.03.PT.PT IW63-45 SHEET 1 OF 1 CH2MHILL WELL COMPLETION DIAGRAM PROJECT:SWMU 350 Naphthalene Biosparging Treatability Study LOCATION:MCIEAST-MCB CAMLEJ DRILLING CONTRACTOR: Terrasonic NORTHING: EASTING: DRILLING METHOD AND EQUIPMENT USED:6"Rotosonic WATER LEVELS: 10 feet bgs START:06/12/15 END:06/12/15 LOGGER:M.Ost 3 3b \ 2 1\ 1-Ground elevation at well NA 2-Top of casing elevation NA 3-Wellhead protection cover type Buried a)Bollards NA b)concrete pad dimensions NA 8--- 40' 4-Dia./type of well casing 2"Sch 40 PVC 42' 43' 5-Type/slot size of screen 2"Sch 40 PVC-0.006 slot 7 45' 6-Type screen filter #1 silica pack 4 a)Quantity used 2 bags 7-Type of seal Bentonite 3/8"chips a)Quantity used 1 bag 5 8-Grout a)Grout mix used Portland Cement,Bentonite grout b)Method of placement tremie c)Vol.of well casing grout 75 gallons Development method Whale Pump 2' 6 Development time 10 minutes Estimated purge volume 20 gallons Comments Biosparging well.Connected to air compressor.Head is buried. Page 1 of 1 25 Attachment 2 Operations and Maintenance Logs 26 Biosparging System Information SWMU 350 Naphthalene Biosparging Treatability Study Team: David Seed/RAL Date/Time On-Site: 6/25/15 1408 Lone Worker Check-In: System Status (circle): ON OFF Oil Level (% Full): Biosparging System Flow Information (scfm) Pressure(psig) Comments Air Compressor Pressure on mainpanel) -- 101 Temperature= 176°F Regulator Pressure inside Conex) -- 60 Total System 54.89 -- SWMU350-IW59-45 5.5 21 SW M U 350-I W 60-45 9 15.5 SWMU350-IW61-45 10 18.5 SWMU350-IW62-45 10 18.5 SWMU350-IW63-45 8.5 16.5 Lone Worker Check-Out (Offsite Time): 1430 Signature/Date: 6/25/15 Notes: *Initial Start-Date = 6/15/15 27 Biosparging System Information SWMU 350 Naphthalene Biosparging Treatability Study Team: David Seed/RAL Date/Time On-Site: 7/16/15 1100 Lone Worker Check-In: System Status (circle): ON OFF Oil Level (% Full): Biosparging System Flow Information (scfm) Pressure(psig) Comments Air Compressor Pressure on mainpanel) -- 103 Temperature= 176°F Regulator Pressure inside Conex) -- 52.5 Total System 72.56 -- SW M U350-I W59-45 12 23 SW M U 350-I W 60-45 12 18 SWMU350-IW61-45 12 20 SWMU350-IW62-45 12 19.5 SWMU350-IW63-45 12 18 Lone Worker Check-Out (Offsite Time): 1130 Signature/Date: Notes: *Initial Start-Date = 6/15/15 28 Biosparging System Information SWMU 350 Naphthalene Biosparging Treatability Study Team: David Seed Date/Time On-Site: 7/24/2015 1300 Lone Worker Check-In: System Status (circle): ON OFF Oil Level (% Full): Biosparging System Flow Information (scfm) Pressure(psig) Comments Air Compressor Pressure on mainpanel) -- 105 Temperature= 174 °F Regulator Pressure inside Conex) -- 55.5 Total System 74.66 -- SW M U350-I W59-45 12 23 SW M U 350-I W 60-45 15 18.5 SWMU350-IW61-45 15 20 SWMU350-IW62-45 15 20 SWMU350-IW63-45 12 18 Lone Worker Check-Out (Offsite Time 7/24/2015 Signature/Date: Notes: *Initial Start-Date = 6/15/15 29 Biosparging System Information SWMU 350 Naphthalene Biosparging Treatability Study Team: David Seed/RAL Date/Time On-Site: 7/30/15 1300 Lone Worker Check-In: System Status (circle): ON OFF Oil Level (% Full): Biosparging System Flow Information (scfm) Pressure(psig) Comments Air Compressor Pressure on mainpanel) -- 109 Temperature= 173 °F Regulator Pressure inside Conex) -- 50 Total System 72.88 SWMU350-IW59-45 g 19 increased flow to 12 scfm SW M U 350-I W 60-45 16 15 SWMU350-IW61-45 14 19 increased flow to 15 scfm SWMU350-IW62-45 14 18.5 increased flow to 15 scfm SWMU350-IW63-45 11 16.5 increased flow to 12 scfm Lone Worker Check-Out (Offsite Time): Signature/Date: Notes: *Initial Start-Date = 6/15/15 30 Biosparging System Information SWMU 350 Naphthalene Biosparging Treatability Study Team: David Seed Date/Time On-Site: 8/7/2015 Lone Worker Check-In: 1100 System Status (circle): ON OFF Oil Level (% Full): Biosparging System Flow Information (scfm) Pressure(psig) Comments Air Compressor Pressure on mainpanel) -- 60 Temperature= 176 OF Regulator Pressure inside Conex) -- 114 Total System 63.49 -- SWMU350-IW59-45 12 20 SW M U 350-I W 60-45 12 15.5 SWMU350-IW61-45 12 19 SWMU350-IW62-45 12 20 SWMU350-IW63-45 12 16 Lone Worker Check-Out (Offsite Time): 1130 Signature/Date: Notes: *Initial Start-Date = 6/15/15 31 Biosparging System Information SWMU 350 Naphthalene Biosparging Treatability Study Team: David Seed Date/Time On-Site: 8/10/2015 Lone Worker Check-In: 1300 System Status (circle): ON OFF Oil Level (% Full): Biosparging System Flow Information (scfm) Pressure(psig) Comments Air Compressor Pressure on mainpanel) -- 114 Temperature= 177 OF Regulator Pressure inside Conex) -- 55 Total System 69.45 -- SWMU350-IW59-45 15 20 SW M U 350-I W 60-45 15 15.5 SWMU350-IW61-45 15 19 SWMU350-IW62-45 15 20 SWMU350-IW63-45 15 17.5 Lone Worker Check-Out (Offsite Time): 1330 Signature/Date: Notes: *Initial Start-Date = 6/15/15 32 Biosparging System Information SWMU 350 Naphthalene Biosparging Treatability Study Team: David Seed Date/Time On-Site: 8/14/15 Lone Worker Check-In: 1300 System Status (circle): ON OFF Oil Level (% Full): Biosparging System Flow Information (scfm) Pressure(psig) Comments Air Compressor Pressure on mainpanel) -- 104 Temperature= 176 OF Regulator Pressure inside Conex) -- 60 Total System 72.47 SWMU350-IW59-45 15 19.5 SW M U 350-I W 60-45 15 14.5 SWMU350-IW61-45 15 18 SWMU350-IW62-45 15 19 SWMU350-IW63-45 16 17.5 Lone Worker Check-Out (Offsite Time): 1330 Signature/Date: Notes: *Initial Start-Date = 6/15/15 33 Attachment 3 Data Logging Trend Graphs 34 MW16 (30-foot well) 20 feet from IW59-45 12 100 80 10 60 g E b oa �. c 40 t pp U T 6 O 4' v 20 � > W O W vyi 4 L_ 0 2 -20 0 -40 ATTACHMENT 3 DO (mg/L) Date Data Logging Trend Graphs System Startup SWMU 350 Naphthalene Biosparging Treatability Study Ch2M' 35 MW47-18 40 feet from IW61-45 12 1.5 10 1 v cu J bb 8 GJ 0.5 t pill v V Cu0 A C O 6 4� M v > > O O 0 W 0 v 4 -0.5 2 0 -1 toc (.0 O\� � ATTACHMENT 3 Date Data Logging Trend Graphs DO (mg/L) System Startup SWMU 350 Naphthalene Biosparging Treatability Study Water Level (feet) MCB Camp Lejeune, North Carolina CA2 U- 36 M W47-30 40 feet from IW61-45 12 8 7 10 6 v J u 8 5 E bD c f° t bD 4 V > c O 6 4� cu 3 v O W i N ai 4 2 1 2 - 0 0 1 ATTACHMENT Date Data Logging Trend Graphs DO (mg/L) System Startup SWMU 350 Naphthalene Biosparging Treatability Study Water Level (feet) MCB Camp Lejeune, North Carolina CH?4%- 37