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HomeMy WebLinkAboutWI0800219_Permit (Completion)_20241002 FINAL TECHNICAL MEMORANDUM CH2MHILLe Naphthalene Biosparging Treatability Study Solid Waste Management Unit 350 Marine Corps Installations East - Marine Corps Base Camp Lejeune, North Carolina PREPARED FOR: Bryan Beck/NAVFAC Mid-Atlantic Charity Delaney/MCIEAST-MCB CAMLEJ Patti Vanture/MCIEAST-MCB CAMLEJ Beth Hartzell/NCDENR PREPARED BY: CH2M HILL DATE: May 2015 CONTRACT: Comprehensive Long-term Environmental Action Navy(CLEAN) Contract N62470-11-8012 Contract Task Order(CTO) WE15 1 . Introduction This Technical Memorandum (TM) presents a summary of the naphthalene biosparging treatability study, referred to throughout as the treatability study, conducted between April and November 2013 at Resource Conservation and Recovery Act (RCRA) Solid Waste Management Unit (SWMU) 350, Marine Corps Installations East—Marine Corps Base Camp Lejeune (MCIEAST-MCB CAMLEJ), North Carolina (Figure 1). 1 .1 Overview SWMU 350 is a former aboveground storage tank (AST)facility, which consisted of Tanks STT-61 through STT-66, and is located approximately 400 feet east of Iwo Jima Boulevard, a former entrance to the Tarawa Terrace housing development of MCIEAST-MCB CAMLEJ, and 100 feet south of North Carolina State Highway 24 (Figure 2).The site previously accommodated six 30,000-gallon-capacity ASTs that were used to store liquid propane from 1942 to 1984 and waste oil from 1984 to 1993.The ASTs were removed in 1993 and the associated subsurface fuel lines were removed in 2005. While elevated concentrations of various volatile organic compounds (VOCs) and semivolatile organic compounds have been detected in groundwater in the vicinity of the former ASTs and fuel lines since site investigations began in 1991, more recent data have shown a well-defined naphthalene plume in the 15-and 30-foot zones of the surficial aquifer(Former AST plume). During the development of remedial alternatives following completion of a RCRA Facility Investigation (RFI), biosparging was identified for consideration in the removal of naphthalene from this area. Since site-specific data related to the effectiveness of biosparging for the treatment of naphthalene would significantly improve the evaluation of this alternative during the Corrective Measures Study(CMS),this treatability study was proposed and implemented within the Former AST plume area (Figure 3). 1 .2 Objectives The objectives of the naphthalene biosparging treatability study were as follows: • Evaluate the feasibility and effectiveness of biosparging for treating naphthalene in groundwater in the surficial aquifer in the Former AST plume. • Evaluate whether single or shallow and deep clustered biosparging wells would be needed to treat the entire vertical target treatment zone. • Assess VOC and naphthalene concentrations in soil gas during biosparging to evaluate potential vapor intrusion (VI) pathways at nearby buildings if full-scale implementation of biosparging were selected as a corrective measure. Enclosure 1 NAPHTHALENE BIOSPARGING TREATABILITY STUDY SOLID WASTE MANAGEMENT UNIT 350 • Identify design parameters (for example, injection well spacing, pressures, and flow rates)for the design of a full-scale biosparging system in support of the CMS. • Identify design parameters for potential soil vapor extraction (SVE)for evaluation in conjunction with biosparging as a remedial alternative in the CMS. • Investigate the applicability of sustainable elements, such as solar panels,that could be incorporated into the full-scale design for evaluation in the CMS. 2. Treatability Study Implementation In accordance with the Final Naphthalene Biosparging Treatability Study Work Plan, SWMU 350(referred to herein as the Work Plan) (CH21VI HILL, 2013),the treatability study and associated field activities were conducted between April and November 2013. A chronology of the primary activities conducted for the treatability study is presented in Table 1. TABLE 1 Treatability Study Chronology Date Event Treatability Study Preparation April 4,2013 Submittal of Notification of Intent to Construct or Operate Injection Wells to the North Carolina Department of Environment and Natural Resources(NCDENR) April 5,2013 Utility locating April 9-19,2013 Monitoring/biosparging well and soil gas point installation April 22-24,2013 Baseline groundwater sampling May 13-20,2013 Transportation of equipment compound and connection to injection wells Fence installation August 27,2013 Well survey System Operation and Monitoring May 21,2013 Biosparging system turned on June 27-28,2013 1-Month sampling August 8,2013 Biosparging system turned off August 26-28,2013 3-Month sampling November 5-14,2013 6-Month sampling and vegetation clearance December 4,2013 SVE blower testing 2.1 North Carolina Department of Environment and Natural Resources Notification of Intent to Construct On April 12013, MCIEAST-MCB CAMLEJ submitted a Notification of Intent to Construct or Operate Injection Wells to NCDENR in accordance with 15A North Carolina Administrative Code 02C.0217.The Notification detailed the need for installation and operation of six new air injection wells at SWMU 350 for the purpose of evaluating enhanced in situ biodegradation of naphthalene in groundwater in the surficial aquifer. The submittal is included as Attachment 1. 2.2 Site Preparation 2.2.1 Vegetation Clearance Vegetation clearance was accomplished prior to well installation, equipment compound staging, and fence installation using a combination of mechanical and manual methods to fell brush and trees that would potentially interfere with the safe installation and operation of the biosparging system. Additional 2 2 NAPHTHALENE BIOSPARGING TREATABILITY STUDY SOLID WASTE MANAGEMENT UNIT 350 vegetation clearance was conducted following well installation to reduce the snake habitat in the areas surrounding the monitoring wells. 2.2.2 Equipment Compound Staging On May 13, 2013, an equipment compound housing the air compressor used to provide air to the biosparging wells was delivered.The compound was placed in the central portion of the site as shown on Figure 3. Once the compound was situated, an 8-foot-tall chain-link fence was constructed around the perimeter of the treatment area, enclosing the compound, biosparging wells, and conveyance lines. 2.2.3 Utility Locate Prior to site mobilization,the North Carolina One Call Center was called and informed of the upcoming intrusive work at the site so that the participating utilities would be notified.A third-party underground utility locating subcontractor conducted additional utility locating for potential obstructions within a 20-foot radius from the proposed drilling locations. 2.3 Construction and Startup 2.3.1 Well Installation The naphthalene biosparging treatment study area was divided into two study areas.Treatment Area A included two biosparging wells installed to 40-feet below ground surface (bgs) biosparging wells spaced roughly 30 feet apart.Treatment Area B included two biosparging well clusters spaced roughly 30 feet apart, with each cluster containing one biosparging well installed to 25-feet bgs and one biosparging well installed to 40-feet bgs.The purpose of the two treatment areas was to compare the effectiveness of single, deep biosparging wells versus shallow and deep clustered pairs. Five new groundwater monitoring wells, six biosparging wells, one SVE well, and five soil gas points were installed, as shown on Figure 3.The rationale for the placement of these wells is discussed in the Work Plan (CH2M HILL, 2013) and summarized in Table 2 below. Due to shallow groundwater conditions encountered during installation of soil gas points,the locations of SWMU350-SG02 and SMWU350-SG05 were modified slightly from the Work Plan. Well construction details for the biosparging wells, new and existing monitoring wells, and soil gas monitoring points are summarized in Table 2. Well construction diagrams and boring logs for the new biosparging and groundwater monitoring wells are provided in Attachment 2.A geologic cross-section location map through the naphthalene biosparging treatability study area is presented as Figure 4.The corresponding geologic cross-section A-A' is depicted on Figure 5. The monitoring and biosparging wells, along with the SVE well, were installed by a North Carolina-licensed well driller using hollow-stem auger drilling techniques. Monitoring wells were installed to various depths within the water table zone and 30-foot zone of the surficial aquifer and constructed with a 10-foot section of 2-inch-inner-diameter(ID), 0.010-inch machine-slotted polyvinyl chloride (PVC) screen.The six biosparging wells were installed to either 25 or 40 feet bgs and constructed with a 2-foot section of 2-inch- ID, 0.006-inch slot PVC screen.The SVE well was installed to 8 feet bgs and constructed with a 4-foot section of 4-inch-ID, 0.010-inch machine-slotted PVC screen.The soil gas points were installed to a depth of 5.5 feet bgs using Geoprobe direct-push technology. 3 3 NAPHTHALENE BIOSPARGING TREATABILITY STUDY SOLID WASTE MANAGEMENT UNIT 350 TABLE 2 Well Construction Details and Monitoring Rationale Screen Well Well Screen Interval Date Diameter Depth Length (feet Well ID Installed (inches) Zone (feet bgs) (feet) bgs) Installation/Monitoring Rationale Upgradient SWMU350-MW05 12/13/1991 2 15-foot 15 10 5-15 Monitoring wells located approximately 45 feet upgradient of biosparging wells,to monitor the SWMU350-MW06 12/13/1991 2 30-foot 31 10 19-29 15-and 30-foot aquifer zones for any changes as a potential result of downgradient biosparging. Area A SWMU350-IW55-40 4/17/2013 2 30-foot 40 2 37.5-40 Single biosparging wells installed just below the 30-foot surficial aquifer zone to whether only SWMU350-IW56-40 4/16/2013 2 30-foot 40 2 37.5-40 single deeper biosparging wells are needed for full-scale implementation to treat groundwater within both the 15-and 30-foot surficial aquifer zones. SWMU350-MW03 12/13/1991 2 15-foot 15 10 5-15 Monitoring wells located approximately 15 feet between single biosparging wells IW55-40 and SWMU350-MW04 12/13/1991 2 30-foot 31 10 20-30 IW56-40,to monitor the 15-and 30-foot surficial aquifer zones when treated with only deeper surficial aquifer zone(37.5 to 40 feet bgs) biosparging wells. SWMU350-MW56-15 4/15/2013 2 15-foot 15 10 5-15 Monitoring wells located approximately 8 feet from single biosparging well IW55-40,to monitor SWMU350-MW56-30 4/15/2013 2 30-foot 30 10 20-30 the 15-and 30-foot surficial aquifer zones when treated with only deeper surficial aquifer zone (37.5 to 40 feet bgs)biosparging wells. Area B SWMU350-IW57-25 4/11/2013 2 15-foot 25 2 23-25 Nested biosparging wells installed just below the SWMU350-IW57-40 4/12/2013 2 30-foot 40 2 38-40 15-and 30-foot surficial aquifer zones to assess whether nested biosparging wells are needed for SWMU350-IW58-25 4/10/2013 2 15-foot 25 2 23-25 full-scale implementation to treat groundwater SWMU350-IW58-40 4/10/2013 2 30-foot 40 2 38-40 within both the 15-and 30-foot surficial aquifer zones. SWMU350-MW15-15 12/9/1992 2 15-foot 14 10 4-14 Monitoring wells located approximately 7 feet from nested biosparging wells(IW57),to SWMU350-MW15-30 4/11/2013 2 30-foot 30 10 20-30 monitor the 15-and 30-foot surficial aquifer zones and 55-foot upper Castle Hayne aquifer SWMU350-MW15-55 7/29/2011 2 55-foot 55 5 50-55 zone during biosparging operations within the surficial aquifer zone nested biosparging wells (22.5-25 and 37.5-40 feet bgs). SWMU350-MW57-15 4/11/2013 2 15-foot 15 10 5-15 Monitoring wells located located approximately 20 feet from nested biosparging wells(IW58),to SWMU350-MW57-30 4/10/2013 2 30-foot 30 10 20-30 monitor water table aquifer zone treatment when surficial aquifer zone is treated with nested biosparging wells(22.5-25 and 37.5-40 feet bgs). SWMU350-SVOl 4/9/2013 4 Vadose 4 2 5-7 SVE well tinstalled between the two nested pairs of biosparging wells(IW57-25/IW57-40 and IW58-25/IW58-40)to assess the most conservative design parameters that would be needed for a full-scale implementation of an SVE system. SWMU350-SG01 4/17/2013 N/A Vadose 6 6-inches 5.5-6 Soil gas monitoring points installed at various SWMU350-SG02 4/17/2013 N/A Vadose 6 6-inches 5.5-6 distances(6 to 90 feet)from nested biosparging SWMU350 SG03 4/17/2013 N/A Vadose 6 6-inches 5.5-6 well pairs to assess VOC concentrations during biosparing operations. SWMU350-SG04 4/17/2013 N/A Vadose 6 6-inches 5.5-6 SWMU350-SG05 4/18/2013 N/A Vadose 6 6-inches 5.5-6 Downgradient SWMU350-MWll 12/13/1991 2 15-foot 15 10 5-15 Monitoring wells located downgradient of biosparging wells(approximatley 50 feet from SWMU350-MW12 1/9/1992 2 30-foot 31 10 20-30 Area A and 75 feet from Area B),to monitor the 15-and 30-foot aquifer zones for any changes as a potential result of upgradient biosparging. 4 4 NAPHTHALENE BIOSPARGING TREATABILITY STUDY SOLID WASTE MANAGEMENT UNIT 350 2.3.2 Biosparging System Installation The air compressor used for the naphthalene biosparging treatability study was a Kaeser BSD-SO (50- horsepower [hp]) Rotary Screw Air Compressor. Once the equipment compound had been delivered and the biosparging wells were installed,the system was connected with approximately 230 feet of conveyance piping (1-inch-ID high-pressure air hosing) running aboveground from the compressor to the biosparging wellhead connections.Air compressor supporting equipment including valves, hoses, pressure regulators, flow meters, and fittings is referenced in the Piping and Instrumentation Diagram provided in Attachment 3. 2.3.3 Biosparging System Startup The system was started on May 21, 2013. Prior to turning on the system, baseline groundwater and soil gas samples were collected and the water level was gauged in the previously existing and newly installed wells in the vicinity of the biosparging system as discussed in Section 2.5 below. Once the air compressor was turned on, the flow rate at each biosparging well was gradually increased over a 10 hour period until reaching 7 standard cubic feet per minute (scfm), based upon the assumed target biosparging flow rate of less than 10 scfm per well, as specified in the Work Plan,for a total maximum design flow rate of 60 scfm (CH2M HILL, 2013).The following day, after the system had been allowed to equilibrate, another round of depth-to-water gauging data was collected and the flow rate at each sparge well was gradually increased to approximately 10 scfm, with the average observed flow rates and pressures of 8 scfm and 8 pounds per square inch (psi) in the shallow biosparging wells (25 feet bgs) and 10 scfm and 15 psi in the deep biosparging wells (40 feet bgs), respectively. 2.3.4 Operations and Maintenance System parameters including regulator pressure, air compressor flow rate,total system flow rate and pressure, and individual biosparging well flow rates and pressures were recorded weekly to monitor the operation of the biosparging system. 2.3.5 System Shutdown On August 8, 2013,the biosparging system was shut off following an evaluation of the groundwater data collected during the 1-month post-startup sampling event. Since naphthalene was not detected above method reporting limits in samples collected within the observed biosparging area treatment of influence, the system was shut off to assess for potential rebound of naphthalene concentrations after 3 and 6 months. 2.4 As-built Well Survey Following installation of the biosparging system and associated monitoring wells and soil gas points,the vertical and horizontal coordinates,for both top-of-casing and ground surface elevations,were surveyed by a North Carolina Licensed Land Surveyor. 2.5 Performance Monitoring Groundwater sampling and gauging was conducted during a baseline event, prior to the startup of the biosparging system,followed by three post-startup sampling events (1, 3, and 6 months after startup). The water quality parameters measured during these monitoring events are summarized in Table 3. The groundwater elevations measured during these monitoring events are summarized in Table 4. Soil gas samples were collected during the baseline, 3-month, and 6-month post-startup events. 2.5.1 Groundwater Sampling Groundwater samples were collected from the five new monitoring wells and eight existing monitoring wells (Figure 3) during each of the monitoring events.The samples were analyzed for the following parameters: • VOCs and Naphthalene (United States Environmental Protection Agency [USEPA] Method 826013) • Ammonia-N (USEPA Method 350.1/.2) 5 5 NAPHTHALENE BIOSPARGING TREATABILITY STUDY SOLID WASTE MANAGEMENT UNIT 350 • Nitrate, Nitrite, Sulfate, and ortho-Phosphate (USEPA Method 300.0) • Alkalinity and Ferrous Iron (HACH Field Kits) • Naphthalene dioxygenase (gNAH) enzyme (Microbial Analysis for CENSUS DNA) • Water Quality Parameters (In Situ Troll and HANNA Turbidity Meter): o Dissolved Oxygen (DO) o Specific conductivity o pH o Oxidation-Reduction Potential (ORP) o Temperature o Turbidity The results of the groundwater monitoring events are summarized in Table 5 and discussed in the following subsections. 2.5.1.1 VOCs - Naphthalene Throughout the four rounds of groundwater monitoring, no VOCs were detected at concentrations exceeding North Carolina Groundwater Quality Standards (NCGWQS) except naphthalene, as shown in Table 6 and in the raw analytical results included as Attachment 4. Naphthalene concentration trends are included on Figures 6 and 7, and plume maps are included on Figures 8 and 9. The greatest baseline naphthalene concentration was detected in the groundwater sample collected from SWMU350-MW15-15 at 170 micrograms per liter(µg/L)which was the only naphthalene detection in the water table zone.The remainder of the naphthalene detections were in groundwater samples collected from monitoring wells screened in the 30-foot zone, with the highest concentrations detected in samples collected from SWMU350-MW15-30 (64 µg/L) and SWMU350-MW04-30 (56 µg/L). Naphthalene was not detected in samples collected from the upper Castle Hayne aquifer well (SWMU350-MW15-55). After 1 month of system operation, naphthalene concentrations were reduced to levels below the method reporting limit within the radius of influence of the biosparging system. In both Area A with 40-foot biosparging wells and Area B with nested 25-foot and 40-foot biosparging wells, effective reduction of naphthalene concentrations to below method reporting limits was observed. Through the 5 month monitoring period to evaluate for potential naphthalene rebound after the system had been shut down, naphthalene concentrations in groundwater samples collected in the treatment area remained below method reporting limits with the exception of the November 2013 sample collected from SWMU350-MW15-15, which had an estimated concentration (2.4 J µg/L) below the NCGWQS. Naphthalene concentrations in the samples collected from the upgradient wells outside the treatment area (SWMU350-MW05 and SWMU350-MW06) remained stable throughout the treatability study.This indicates that the decrease in naphthalene concentrations observed within the target treatment area was due to biosparging and not plume migration. 2.5.1.2 Nutrients Bacteria require inorganic nutrients such as nitrogen and phosphate to support cell growth and sustain the biodegradation process.The ideal amount of nutrients to support microbial activity is a function of the bacterial population. Enhanced biodegradation typically occurs when the carbon:nitrogen:phosphorus ratio falls in the range of 100:10:1 to 100:1:0.5 (USEPA, 1994). Ammonia was present in the groundwater sampled from many of the wells during the baseline monitoring event at levels roughly 10 times the phosphate concentrations, which would be ideal for anaerobic microbial activity.The 1-, 3-, and 6-month post-startup events showed little to no ammonia; however,there was a corresponding increase in nitrate indicating the ammonia was oxidized as the subsurface environment became aerobic. The nitrogen:phosphorous ratio stayed constant as phosphate concentrations either decreased slightly or remained unchanged. 6 6 NAPHTHALENE BIOSPARGING TREATABILITY STUDY SOLID WASTE MANAGEMENT UNIT 350 2.5.1.3 Microorganisms During the four monitoring events, samples were collected to monitor for the presence or absence of a microbial population capable of biodegrading naphthalene using the naphthalene dioxygenase enzyme. Naphthalene dioxygenase is an enzyme that catalyzes aerobic biodegradation of naphthalene by the incorporation of oxygen into the aromatic ring (Microbial Insights, 2012). Concentrations of naphthalene dioxygenase greater than 103 cells per milliliter(cells/mL) are considered indicative of a healthy microbial population. The baseline results showed an average presence of naphthalene dioxygenase greater than 104 cells/mL in the water table wells and greater than 10'cells/mL in the 30-foot zone wells, indicating the necessary enzyme/microbial population was present to biodegrade naphthalene. Naphthalene dioxygenase concentrations decreased after startup to roughly 102 cells/mL, which is likely attributed to the observed decrease in naphthalene concentrations observed, as shown in Tables 5 and 6. 2.5.1.4 Water Quality Parameters The pH readings in groundwater collected from the biosparging treatment area did not show any significant trends during the operational period.The optimal pH range for bacterial growth is between 6 and 8, but the pH readings in the treatment area, not including the upgradient wells and the upper Castle Hayne aquifer well, ranged from 4.16 to 5.64.These levels are not ideal for bacterial growth, but did not appear to hinder the degradation of naphthalene in this treatability study. It is possible that the age of the plume has allowed the microbes to acclimate to the low pH conditions. The presence of dissolved ferrous iron in groundwater can reduce the permeability of the saturated zone soils during biosparging operations.As dissolved iron is exposed to oxygen, it is oxidized to ferric iron oxide, which can precipitate within the saturated zone and occlude soil pore space (USEPA, 1994). Ferrous iron was detected in groundwater in several wells during the baseline investigation at concentrations ranging from 0.5 to 5.0 milligrams per liter(mg/L) but generally decreased to 0 mg/L by the end of the 6-month investigation period likely due to oxidation and precipitation. The low mass of iron initially present in the groundwater did not appear to result in enough ferric iron oxide formation to hinder the dispersion of oxygen within the treatment area. 2.5.1.5 Zone of Influence Monitoring Water levels and field parameters, including dissolved oxygen (DO), oxidation-reduction potential (ORP), and pH,were monitored continuously with In Situ Troll 9500 water quality instruments with data logging capability during the startup of the biosparging system to evaluate the zone of influence. On May 17, 2013, the data loggers were deployed in treatability study wells SWMU350-MW03, SWMU350-MW04, SWMU350- MW15-15, SWMU350-MW15-30, SWMU350-MW56-15, SWMU350-MW56-30, SWMU350-MW57-15, and SWMU350-MW57-30 prior to the startup of the biosparging system to establish baseline conditions. Data logging was discontinued on June 6, 2013,following approximately 3 weeks of data collection.The data, shown in Attachment 5, were used to assess the zone of influence for the individual biosparging wells. DO and ORP concentrations increased in every treatability study groundwater monitoring well during operation of the biosparging system with the exception of the two upgradient wells (SWMU350-MW05 and MW06) and the 55-foot-deep upper Castle Hayne aquifer well (SWMU350-MW15-55) indicating oxygen was successfully being introduced to the target area as a result of biosparging activities. In the water table zone groundwater, the highest detected ORP concentrations ranged from 135 millivolts (mV) in SWMU350- MW03 (roughly 13 feet downgradient from SWMU350-IW55-40)to 480 mV, also in SWMU350-MW03. In the 30-foot zone,the highest detected ORP concentrations ranged from 198 mV in SWMU350-MW04 (roughly 13 feet downgradient from SWMU350-IW55-40)to 530 mV in SWMU350-MW57-30 (roughly 20 feet downgradient from SWMU350-IW58-40).The average ORP across the treatment area increased from roughly 130 to 375 mV by the 1-month post-startup event and then slightly decreased over the following 5 months with an average ORP of 296 mV measured in the treatment area groundwater during the 6-month post-startup event. In the water table zone groundwater,the highest detected post-operational DO concentrations ranged from 8.16 mg/L in SWMU350-MW11 (roughly 50 feet downgradient from SWMU350-IW56-25)to 11.54 mg/L in NAPHTHALENE BIOSPARGING TREATABILITY STUDY SOLID WASTE MANAGEMENT UNIT 350 SWMU350-MW03 (roughly 15 feet downgradient from SWMU350-IW56-25). In the 30-foot zone,the highest detected DO concentrations ranged from 10.80 mg/L in SWMU350-MW12 (roughly 50 feet downgradient from SWMU350-IW56-40)to 17.50 mg/L in SWMU350-MW04 (roughly 15 feet downgradient from SWMU350-IW56-40). Some of the detected DO concentrations, including the maximum value of 17.50 mg/L, were detected by the data loggers when the system was operating, indicating that bubbles were likely present in the groundwater and influenced the measurements. Elevated DO concentrations were generally detected in the 15-foot monitoring wells and consistently detected in the 30-foot monitoring wells located within 20 feet of a biosparging well through the 6-month post-startup event, 2 months after the system had been turned off as shown in Figures 6 and 7. Monitoring wells SWMU350-MW11 and SWMU350-MW12, located roughly 50 feet downgradient of the nearest biosparging wells, also contained DO concentrations exceeding 1 mg/L throughout the treatability study. Site-wide data collected during the 6-month post-startup monitoring event (4 months after system had been turned off) showed elevated DO concentrations when compared against the 2011 RFI data (CH2M HILL, 2012a), and were also detected in groundwater outside of the treatment area—7.71 mg/L in SWMU350- MW50-18 (roughly 118 feet downgradient from SWMU350-IW58-25) and 1.68 mg/L in SWMU350-MW49-30 (roughly 122 feet downgradient from SWMU350-IW58-25).These lines of evidence suggest a larger zone of influence than the originally expected 30 feet; therefore, a nominal zone of influence of 50 feet will be assumed for estimates in the CMS evaluation. 2.5.2 Soil Gas Sampling Soil gas samples were collected from the five soil gas monitoring points installed in treatment Area B prior to startup and at the 3-and 6-month post-startup monitoring events (Figure 3,Table 2).The samples were analyzed for VOCs and naphthalene by USEPA Method TO-15. Samples were unable to be collected from SWMU350-SG03 and SWMU350-SG05 during the 3-month post-startup event as water was present in the soil gas monitoring point tubing, indicating the water table had risen above the probe depth. Throughout the treatability study, naphthalene was not detected in soil gas at concentrations above the North Carolina Division of Waste Management Residential Vapor Intrusion Screening Level (VISE) for Sub Slab and Exterior Soil Gas (January 2014) of 20.9 micrograms per cubic meter.Three compounds were periodically detected above their respective VISLs: 1,1,2,2-tetrachloroethane (PICA), 1,2-dichloropropane, and trichloroethene (TCE). However, the detection of these compounds was not consistent. Two of the three compounds (1,1,2,2-PCA and 1,2-dichloropropane) were only detected during the baseline event; and TICE, which was detected at the baseline and 3-month post-startup sampling events in different locations, was not detected at the 6-month post-startup sampling event. None of these three compounds were detected above method reporting limits in groundwater samples collected during the treatability study. The lack of consistency in the analytical results suggest that the potential source of these compounds in soil gas is transient (e.g.very low concentrations in groundwater); therefore, it is unlikely that migration of these compounds into soil gas would result in a complete and significant future vapor intrusion pathway. No exceedances were detected in soil gas during the 6-month post-startup event.A summary of the naphthalene soil gas sampling results is shown in Table 7 while a summary of detected compounds is presented in Table 8 and in Attachment 6. 2.6 Soil Vapor Extraction System Testing In order to evaluate the potential for SVE to be used in conjunction with biosparging as a remedial alternative in the CMS, an SVE system test was conducted on December 4, 2013. A blower was set up to pull a vacuum on SWMU350-SV01 (Figure 3), a 4-inch-ID PVC well extending to a depth of 8 feet bgs. Prior to turning on the blower, water levels were measured in the nearby monitoring and biosparging wells and initial vacuum readings were collected from the soil gas points and SWMU350-MW15-15 using a manometer.The data from the SVE blower test are included in Table 9. The blower was turned on with the dilution valve fully open to minimize the risk of extracting groundwater. Once it was determined the water table was low enough to withstand the vacuum,the dilution valve was 8 8 NAPHTHALENE BIOSPARGING TREATABILITY STUDY SOLID WASTE MANAGEMENT UNIT 350 closed to increase the vacuum and measurements were taken every 5 to 30 minutes to observe any rise in water level in the nearby wells and any increase in vacuum in the soil gas points and SWMU350-MW15-15. No significant change to the water level was observed but an increase in vacuum was noted in some of the soil gas points and SWMU350-MW15-15. As would be expected, the largest increases in vacuum were observed in the points closest to SWMU350-SV01.The maximum vacuum increase observed at soil gas monitoring points was 0.3945 inch of water from SWMU350-SG01 (roughly 7.5 feet away from SV01). The maximum vacuum increase observed in groundwater monitoring wells was 0.4730 inch of water from SWMU350-MW15-15 (roughly 8.5 feet away from SV01).A vacuum increase of 0.0112 inch of water was observed as far away as SWMU350-SG03 (roughly 22 feet away from SV01). The SVE test demonstrated the feasibility of SVE if necessary to collect soil vapor. However,the soil gas sampling results (Section 2.5.2) indicate that naphthalene concentrations in soil gas are below the VISL and therefore do not require capture. 3. Sustainable Elements A site-specific solar power impacts evaluation was performed using the CleanSWEEP tool (CH2M HILL, 2012b). CleanSWEEP is a Microsoft Excel spreadsheet tool used to evaluate the viability of wind and/or solar photo voltaic(PV) resources to run small environmental remediation systems (that is, less than 20 kilowatts or 26.8 hp). To complete the solar power impacts evaluation, site-specific location information, system energy requirements, and the estimated system operation time were entered into CleanSWEEP. The CleanSWEEP tool assumes a 30-year lifespan for the PV capital. Since the treatability study only required a few months to achieve naphthalene reduction treatability study goals,full-scale treatment for SWMU 350 would not likely require power for more than 2 months of operation with another 2 months of polishing as needed for a source area treatment and 1 month each quarter during a 4-year performance period for a barrier treatment configuration.Thus,the model was run for a 1-year operational period and assumes the solar panels have an additional 29 years'worth of useful life.This residual value can be quantified into dollars presuming the energy produced thereafter is used to either offset other energy demands by the owner or sold back to the utility provider.The model output data were then converted to a monthly cost for the assessment described in the following paragraphs. From these data,the tool provided the potential solar options for the site, estimated the costs of these options, and calculated the return on investment timeframe under several future energy price scenarios. The CleanSWEEP tool primarily relies upon assumptions specific to all active United States Air Force (USAF) bases in the contiguous United States, Alaska, and Hawaii, and uses industry-published values for renewable energy potential and costs; more information is available from the United States Department of Energy National Renewable Energy Laboratory. Charleston USAF Base was chosen as the basis for the CleanSWEEP tool assumptions, since it is in close geographical proximity to MCIEAST-MCB CAMLEJ and both installations are situated along the Atlantic Ocean. Two options were evaluated for comparison: running the biosparging system with the existing 50-hp air compressor on conventional power (as-is scenario) and running the system with a smaller 15-hp air compressor, assessing both conventional and solar power.A 15-hp air compressor was used for the analysis since it would be large enough for full-scale implementation and MCIEAST-MCB CAMLEJ is in ownership of a 15-hp system from another pilot study. A capital cost of$10,000 was assumed to service and move the system to SWMU 350, which is based on the cost required to service and move the 50-hp system to SWMU 350 for this treatability study. Results from the CleanSWEEP tool evaluation are summarized in Table 10 and the input and output files are included in Attachment 7. Based on this initial evaluation considering the specific conditions of the project site with an anticipated 18-month total operational time of a full-scale system during a 4-year performance monitoring period, a solar PV system is not an economically viable solution for providing power to the 9 9 NAPHTHALENE BIOSPARGING TREATABILITY STUDY SOLID WASTE MANAGEMENT UNIT 350 biosparging system at SWMU 350, although the solar system would pay for itself in 27 years if the solar panels were used elsewhere following remedy completion. Results indicate that the capital costs for a solar powered system alone would exceed the comparable conventional options. However,the 15-hp compressor option operated on conventional power would reduce energy costs and significantly reduce environmental impacts in comparison to the conventional 50-hp as-is scenario, and is recommend for consideration during full-scale implementation. TABLE 10 Solar Power Impacts Evaluation(CleanSWEEP) Results Summary Option 1 Option 2 50-hp Compressor/Conventional Power 15-hp Compressor 15-hp Compressor Criteria (As-is Scenario) Conventional Power Solar Power',' Capital Cost($) $0 $10,000 $141,855 Energy Costs($/month) $2,986 $896 $0 Total Cost of Option ($over remedy lifetime)' $53,739 $26,122 $141,855 Environmental Impacts(Per month) Emissions(Life-Cycle) NO,(tons) 69 21 SO,(tons) 254 76 CO2(tons) 48,852 14,656 3 Renewable Energy Certificates 0 0 74 Notes: 'Assumes source area treatment operation of 4 months,barrier treatment of 4 months per year for 4 years,or 18 months total. Does not account for 0&M costs. 'Assumes that operation would be conducted during daylight hours only. 3Total cost of solar option updated to include the estimated$10,000 to bring 15-hp compressor on site. COZ—carbon dioxide NOX—nitrogen oxides SO.—sulfur oxides 4. Conclusions and Recommendations Based on an analysis of data collected during the naphthalene biosparging treatability study, a summary of the objectives and corresponding conclusions and recommendations are included in Table 11. TABLE 11 Objectives,Conclusions,and Recommendations Summary Table Objectives Conclusions and Recommendations Evaluate the feasibility and effectiveness of Biosparging is feasible and effective since naphthalene concentrations in biosparging for treating naphthalene in groundwater samples collected from performance monitoring wells were groundwater in the surficial aquifer in the observed to decrease to below method reporting limits from the baseline Former AST plume. event to the 1-month post-startup event.Even after shutting the system off prior to the 3-month sampling event to test for potential rebound, naphthalene concentrations remained below method reporting limits after 4 months in all but one sample where naphthalene was detected at an estimated concentration below the NCGWQS(2.4 J µg/L). Evaluate whether single or shallow and deep Both single and nested biosparging well treatment configurations were nested biosparging wells would be needed to shown to be effective at treating naphthalene within their respective treat the entire vertical target treatment zone. target treatment zones.The more cost-effective single deep biosparging well configuration is recommended if this alternative is chosen for full- scale treatment. 10 10 NAPHTHALENE BIOSPARGING TREATABILITY STUDY SOLID WASTE MANAGEMENT UNIT 350 TABLE 11 Objectives,Conclusions,and Recommendations Summary Table Objectives Conclusions and Recommendations Assess naphthalene concentrations in soil gas Volatilization of naphthalene was not observed in soil gas samples out to during biosparging to evaluate potential VI 90 feet(furthest distance soil gas samples were collected from nearest pathways at nearby buildings if full-scale biosparging wells).Naphthalene was not detected exceeding the VISL implementation of biosparging were selected as (January 2014)of 20.9 micrograms per cubic meter. a corrective measure. Identify design parameters(for example, Based on the results of the biosparging treatability study including the injection well spacing,pressures,and flow rates) system operational parameters,the recommended biosparging design for the design of a full-scale biosparging system parameters are as follows: in support of the CMS. . Spacing—Up to 100 feet(Zone of Influence of 50 feet) • 40-foot biosparging well: — Flow rate—10 scfm — Pressure—15 psi Identify design parameters for potential SVE for The SVE evaluation showed that a zone of influence of 20 feet could be evaluation in conjunction with biosparging as a achieved in the surficial aquifer. However,soil gas results indicate that VI remedial alternative in the CMS. is not likely to occur in the vicinity of the Former AST plume as a result of biosparging. Investigate the applicability of sustainable The CleanSWEEP solar power impacts evaluation indicates that solar elements,such as solar panels,that could be energy is not a cost-effective option for powering a biosparging system at incorporated into the full-scale design for SWMU 350 considering the short length of time(less than 4 years) evaluation in the CMS. anticipated to be required for full-scale treatment. It is recommended that a 15-hp compressor be considered for full-scale implementation based on overall cost savings and lesser environmental impacts. 5. References CH2M HILL. 2008. Final Master Project Plans. Marine Corps Base Camp Lejeune,Jacksonville, North Carolina. CH2M HILL. 2012a. Final RCRA Facility Investigation Report, SWMU 350. Marine Corps Base Camp Lejeune, Jacksonville, North Carolina. May. CH2M HILL. 2012b. CleanSWEEP, The United States Air Force Tool for Evaluating Clean Solar and Wind Energy in Environmental Programs, User's Guide. September. CH2M HILL. 2013. Final Naphthalene Biosparging Treatability Study Work Plan. Marine Corps Installations East—Marine Corps Base Camp Lejeune,Jacksonville, North Carolina, April. Microbial Insights. 2012. Environmental Remediation: CENSUS—Diesel—Naphthalene and PAHs. <http://www.microbe.com/index.php/CENSUS/census-applications-diesel-nah.html>. March 2014. United States Environmental Protection Agency. (USEPA). 1994. How to Evaluate Alternative Cleanup Technologies for Underground Storage Tank Sites:A Guide for Corrective Action Plan Reviewers. Office of Underground Storage Tanks. Chapter 8. 11 Tables 12 TABLE 3 Summary of Groundwater Quality Parameters SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLEJ,North Carolina Temperature Conductivity DO pH ORP Turbidity Well ID Date °C m5/cm mg/L SU my NTU 4/22/2013 15.94 0.190 0.39 5.96 -112 1.90 SWMU350-MW05 6/28/2013 21.71 NA 0.01 5.72 -90 2.64 3 8/27/2013 23.41 0.197 0.03 5.68 -152 2.89 11/12/2013 20.57 0.176 0.02 5.70 -139 0.10 4/22/2013 17.68 0.068 0.26 4.69 -37 8.91 CL SWMU350-MW06 6/28/2013 20.85 NA 0.00 4.67 -24 4.65 8/27/2013 21.09 0.811 0.05 4.63 -52 3.45 11/12/2013 20.06 0.073 0.00 4.63 1 4 0.00 4/22/2013 16.41 0.128 0.16 4.47 78 21.1 v SWMU350-MW11 6/28/2013 20.14 0.092 8.16 4.82 360 160 3 8/27/2013 21.72 0.090 3.19 4.97 189 43.8 vw 11/12/2013 21.34 0.080 2.06 4.76 373 9.80 m 4/22/2013 17.83 0.103 0.23 4.43 42 5.77 o SWMU350-MW12 6/28/2013 19.65 0.047 10.80 4.69 390 0.62 a 8/27/2013 20.26 0.089 4.80 4.34 355 7.10 11/12/2013 20.81 0.094 1.40 4.16 354 2.20 4/23/2013 15.34 0.164 0.21 5.18 50 3.82 SWMU350-MWO3 6/27/2013 22.70 0.118 1.28 5.64 246 20.6 8/28/2013 20.87 0.109 0.23 5.54 135 5.00 11/12/2013 20.52 0.088 0.87 5.17 195 4.40 4/23/2013 17.20 0.069 0.15 4.68 95 6.90 SWMU350-MW04 6/27/2013 20.43 0.056 10.86 4.72 400 3.50 8/28/2013 19.29 0.063 10.59 4.78 416 1.10 11/12/2013 18.50 0.074 9.68 4.82 198 0.40 v ¢` 4/23/2013 15.83 0.090 0.60 4.30 117 5.45 SWMU350-MW56-15 6/27/2013 21.09 0.116 7.80 4.65 383 17.1 8/28/2013 21.25 0.089 6.68 4.65 424 5.10 11/12/2013 20.15 0.094 4.26 4.54 338 7.60 4/23/2013 17.39 0.088 0.26 5.09 70 3.17 SWMU350-MW56-30 6/27/2013 20.62 0.052 10.93 4.78 424 1.70 8/28/2013 20.10 0.044 10.75 4.86 394 2.20 11/12/2013 19.66 0.040 10.29 4.87 290 0.30 4/23/2013 14.99 0.102 0.30 4.63 202 0.72 SWMU350-MW15-15 6/27/2013 20.47 0.098 8.92 4.62 400 84.6 8/28/2013 20.74 0.097 2.05 4.86 309 88.3 11/12/2013 19.90 0.072 0.14 4.87 242 85.6 4/23/2013 17.08 0.073 0.29 4.83 99 1.79 SWMU350-MW15-30 6/27/2013 19.00 0.076 11.74 4.36 410 0.50 8/28/2013 19.00 0.487 11.21 4.42 361 2.57 11/12/2013 18.91 0.068 11.00 4.45 364 15.1 v ¢` 4/23/2013 15.87 0.109 0.40 4.60 318 3.07 SWMU350-MW57-15 6/27/2013 21.11 0.098 9.58 5.14 330 33.5 8/28/2013 20.85 0.083 5.23 5.12 145 13.0 11/12/2013 19.14 0.091 1.02 5.00 251 43.6 4/23/2013 17.50 0.084 0.25 5.00 237 6.83 SWMU350-MW57-30 6/27/2013 20.67 0.067 11.71 4.62 410 6.60 8/28/2013 20.74 0.058 10.38 4.63 347 4.57 11/12/2013 18.33 0.065 11.01 4.63 352 1.90 v 4/23/2013 18.11 0.089 0.15 6.07 -42 0.87 a SWMU350-MW15-55 6/28/2013 20.03 0.091 0.02 6.07 -120 1.66 v 8/27/2013 19.64 0.080 0.00 6.12 -73 1.50 11/12/2013 18.64 0.083 0.00 6.15 -99 3.50 Notes: °C-degrees Celcius ORP-oxidation reduction potential mS/cm-milli5iemens per centimeter mv-millivolts DO-dissolved oxygen NTU-nephelometric turbidity unit mg/L-milligram per liter NA-Not available SU-standard unit Page 1 of 1 13 TABLE 4 Summary of Groundwater Elevations SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLEJ,North Carolina Ground Surface Top of Casing Groundwater Total Depth Screened Interval Elevation Elevation Depth to Water Elevation Well ID ft bgs ft bgs ft amsl ft amsl Date ft bTOC ft amsl 4/22/2013 7.90 21.57 SWMU350-MW05 15 5-15 27.93 29.47 6/28/2013 7.60 21.87 3 8/26/2013 9.35 20.12 11/6/2013 10.51 18.96 v 4/22/2013 8.91 20.65 SWMU350-MW06 31 19-29 27.93 29.56 6/28/2013 9.50 20.06 8/26/2013 9.45 20.11 11/6/2013 11.50 18.06 4/22/2013 8.26 21.25 3 SWMU350-MWll 15 5-15 27.30 29.51 6/28/2013 9.29 20.22 8/26/2013 9.44 20.07 w 11/6/2013 11.33 18.18 v 4/22/2013 9.45 19.96 to 329.41 31 17-27 27.26 29.41 6/28/2013 9.83 19.58 0 in 8/26/2013 9.67 19.74 11/6/2013 11.55 17.86 4/22/2013 7.49 21.44 SWMU350-MW03 15 5-15 26.49 28.93 6/28/2013 8.42 20.51 8/26/2013 8.69 20.24 11/6/2013 10.89 18.04 4/22/2013 8.80 20.04 SWMU350-MW04 31 20-30 26.49 28.84 6/28/2013 9.15 19.69 8/26/2013 9.01 19.83 11/6/2013 10.66 18.18 v Q` 4/22/2013 9.46 19.35 SWMU350-MW56-15 15 5-15 25.89 28.81 6/28/2013 9.87 18.94 8/26/2013 9.93 18.88 11/6/2013 11.82 16.99 4/22/2013 10.18 19.74 SWMU350-MW56-30 30 20-30 26.9 29.92 6/28/2013 10.45 19.47 8/26/2013 10.30 19.62 11/6/2013 12.18 17.74 4/22/2013 7.55 20.68 SWMU350-MW15-15 14 4-14 26.37 28.23 6/28/2013 7.61 20.62 8/26/2013 8.09 20.14 11/6/2013 10.02 18.21 4/22/2013 8.99 19.82 SWMU350-MW15-30 30 20-30 25.89 28.81 6/28/2013 9.32 19.49 8/26/2013 9.20 19.61 11/6/2013 11.09 17.72 v < 4/22/2013 8.76 20.28 SWMU350-MW57-15 15 5-15 26.31 29.04 6/28/2013 9.23 19.81 8/26/2013 9.27 19.77 11/6/2013 11.15 17.89 4/22/2013 9.40 19.77 SWMU350-MW57-30 30 20-30 26.28 29.17 6/28/2013 9.73 19.44 8/26/2013 9.60 19.57 11/6/2013 11.45 17.72 m 4/22/2013 8.99 19.81 3: 6/28/2013 9.30 19.50 a SWMU350-MW15-55 55 50-55 26.26 28.8 m 8/26/2013 8.09 20.71 0 11/6/2013 1 11.06 1 17.74 Notes: ft bgs-feet below ground surface ft amsl-feet above mean sea level ft bTOC-feet below top of casing Page 1 of 1 14 TABLE 5 Summary of Groundwater Analytical Results SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLEJ,North Carolina Naphthalene gNAH Ammonia-N Nitrate Nitrite Sulfate o-Phosphate Alkalinity Ferrous Iron Well ID Date µg/L cells/mL mg/L mg/L mg/L mg/L mg/L mg/L mg/L 4/22/2013 1 Ul NA NA NA NA NA NA 0.0 2.0 SWMU350-MW05 6/28/2013 1 U NA NA NA NA NA NA 102 1.2 8/27/2013 1 U NA NA NA NA NA NA NA 1.7 c 11/12/2013 1 U NA NA NA NA NA NA 70.0 1.4 v 4/22/2013 96 J NA NA NA NA NA NA 0.0 2.5 CIO 6/28/2013 77 NA NA NA NA NA NA 6.8 1.4 j SWMU350-MW06 8/27/2013 67 NA NA NA NA NA NA NA 3.0 11/12/2013 74 NA NA NA NA NA NA 0.0 1.5 4/22/2013 1 UJ NA NA NA NA NA NA 0.0 2.4 °1 SWMU350-MW11 6/28/2013 1 U NA NA NA NA NA NA 7.7 0.0 8/27/2013 1 U NA NA NA NA NA NA NA 0.0 (U 11/12/2013 1 U NA NA NA NA NA NA 5.0 0.0 =a 4/22/2013 NA NA NA NA NA NA 0.0 5.0 to 3 SWMU350-MW12 6/28/2013 1 U NA NA NA NA NA NA 7.7 0.0 Q 8/27/2013 1 U NA NA NA NA NA NA NA 0.8 11/12/2013 1 U NA NA NA NA NA NA 0.0 1.6 4/23/2013 1 UJ 5.52E+04 0.0111 0.05 U 0.05 U 16 0.00562 J 0.0 2.0 SWMU350-MW03 6/27/2013 1 U 9.96E+04 0.01 U 0.05 U 0.05 U 16 0.01110 13.6 0.0 8/28/2013 1 U 3.93E+01 0.01 U 0.028 J 0.05 U 13 0.00607 J 20.0 1.6 11/12/2013 1 U 4.08E+01 0.01 U 0.02 J 0.05 U 14 0.00549 J 10.0 0.0 4/23/21 6.06E+05 0.0089 J 0.37 0.05 U 13 0.00776 J 0.0 3.4 c SWMU350-MW04 6/27/2013 1 U 8.32E+04 0.01 U 0.54 0.05 U 11 0.01 U 6.8 0.0 •� m 8/28/2013 1 U 1.56E+02 0.01 U 0.78 0.05 U 14 0.01 U 5.0 0.0 a- 0 11/12/2013 1 U 9.79E+01 0.01 U 0.77 0.05 U 29 0.01 U 5.0 0.0 00 0- 4/23/2013 1 UJ 6.56E+02 0.019 J 0.05 U 0.05 U 13 0.00576 J 0.0 0.5 0 6/27/2013 1 U 2.15E+02 0.01 U 0.05 U 0.05 U 30 0.00885 J 6.8 0.0 SWMU350-MW56-15 Q 8/28/2013 1 U 1.72E+01 0.01 U 0.023 J 0.05 U 10 0.00773 J 0.0 0.0 v 11/12/2013 1 U 5 U 0.01 U 0.021 J 0.05 U 13 0.00602 J 5.0 0.0 Q 4/23/2013 2 9.80E+04 0.03 J 0.13 0.024 J 15 0.00574 J 0.0 3.0 SWMU350-MW56-30 6/27/2013 1 U 2.96E+04 0.01 U 0.44 0.05 U 7.8 0.01 U 6.8 0.0 8/28/2013 1 U 8.33E+01 0.014 J 0.33 0.05 U 6.7 0.01 U 5.0 0.0 11/12/2013 1 U 2.51E+02 0.01 U 0.24 0.05 U 6.9 0.01 U 5.0 0.0 Page 1 of 2 15 TABLE 5 Summary of Groundwater Analytical Results SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLEJ,North Carolina Naphthalene gNAH Ammonia-N Nitrate Nitrite Sulfate o-Phosphate Alkalinity Ferrous Iron Well ID Date µg/L cells/mL mg/L mg/L mg/L mg/L mg/L mg/L mg/L 4/23/2013 J1111VO 1.02E+05 0.092 0.05 U 0.05 U 26 0.01 U 0.0 1.6 6/27/2013 1 U 6.19E+03 0.01 U 0.27 0.05 U 18 0.00943 J 7.7 0.0 SWMU350-MW15-15 to 8/28/2013 1 U 2.80E+02 0.01 U 0.034 J 0.05 U 19 0.0495 5.0 0.0 c 11/12/2013 4.95E+01 0.0065 J 0.037 J 0.05 U 19 0.01 U 10.0 2.0 m a 4/23/2013 64 5.64E+04 0.0481 0.05 U 0.05 U 12 0.00466 J 0.0 1.8 0 0o 6/27/2013 1 U 4.40E+05 0.01 U 0.48 0.05 U 7.2 0.01 U 0.0 0.1 v SWMU350-MW15-30 8/28/2013 1 U 1.67E+04 0.015 J 0.46 0.05 U 5.7 0.01 U 5.0 0.0 v z 11/12/2013 1 U 1.08E+03 0.01 U 0.46 0.05 U 6.8 0.01 U 0.0 0.0 a v 4/23/2013 1 UJ 4.16E+04 0.032 J 0.05 U 0.05 U 19 0.00983 J 0.0 0.2 6/27/2013 1 U 4.04E+02 0.014 J 0.066 J 0.05 U 19 0.0524 7.7 0.0 SWMU350-MW57-15 8/28/2013 1 U 8.62E+02 0.01 U 0.87 0.05 U 17 0.0187 5.0 0.0 3 0 11/12/2013 1 U 3.6 J 0.01 U 0.35 0.05 U 19 0.0235 5.0 0.0 m N 4/23/2013 9.48E+04 0.12 0.021J 0.05 U 15 0.00673J 0.0 2.0 m 6/27/2013 1 U 2.72E+04 0.01 U 0.31 0.05 U 7.6 0.01 U 7.7 0.0 SW M U350-M W 57-30 v 8/28/2013 1 U 1.67E+01 0.01 U 0.20 0.05 U 5.7 0.01 U 5.0 0.0 Q 11/12/2013 1 U 2.85E+01 0.01 U 0.37 0.05 U 5.5 0.01 U 5.0 0.0 4/23/2013 1 UJ NA NA NA NA NA NA 0.0 2.8 v 6/28/2013 1 U NA NA NA NA NA NA 34.0 2.2 n SWMU350-MW15-55 8/27/2013 1 U NA NA NA NA NA NA NA 2.6 11/12/2013 1 U NA NA NA NA NA NA 40.0 3.8 Notes: NA-Not analyzed gNAH-naphthalene dioxygenase µg/L-micrograms per liter mL-milliliter mg/L-milligrams per liter U-material analyzed for,but not detected J-analyte present,value may not be accurate or precise Bold text indicates detection Gray shading indicates exceedance of North Carolina Groundwater Quality Standards(NCGWQS) NCGWQS for naphthalene-6 M/L Page 2 of 2 16 TABLE 6 Groundwater Analytical Results - Exceedances SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLEJ, North Carolina Station ID NCGWQS SWMU350-MW03 SWMU350-MW04 Sample ID (April 2013) SWMU350-GW03-13B-1 SWMU350-GW03-13B-2 SWMU350-GW03-13C SWMU350-GW03-13D SWMU350-GW04-13B-1 SWMU350-GW04-13B-2 SWMU350-GW04-13C SWMU350-GW04-13D Sample Date 04/23/13 1 06/27/13 08/28/13 1 11/12/13 04/23/13 1 06/27/13 1 08/28/13 1 11/12/13 Chemical Name Volatile Organic Compounds(UG/L) Acetone 6,000 2 UJ 2 U 2 U 2 UJ 2 UJ 2 U 2 U 2 UJ Carbon disulfide 700 1 U 1 U 1 UJ 1 U 1 U 1 U 1 UJ 1 U Chloroform 70 1U 1U 1U 1U 1U 1U 1U 1U Chloromethane 3 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Ethylbenzene 600 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Isopropyl benzene 70 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U m-and p-Xylene 500 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U o-Xylene 500 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U Toluene 600 1U 1U 1U 1U 1U 1U 1U 1U ylene,total 500 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U Semivolatile Organic Compounds(UG/L) Naphthalene 6 1 UJ 1 U 1 U 1 U 1 U 1 U 1 U Wet Chemistry(MG/L) Ammonia -- 0.011 J 0.01 U 0.01 U 0.01 U 0.0089 J 0.01 U 0.01 U 0.01 U Nitrate 10 0.05 U 0.05 U 0.028 J 0.02 J 0.37 0.54 0.78 0.77 Nitrite 1 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U Orthophosphate -- 0.00562 J 0.0111 0.00607 J 0.00549 J 0.00776 J 0.01 U 0.01 U 0.01 U Sulfate 250 16 16 13 14 13 11 14 29 Functioning Genes(CELLS/ML) Napthalene Dioxygenase -- 55,200 99,600 39.3 40.8 606,000 83,200 156 97.9 Notes: Grey shading indicates exceedance of NCGWQST' Bold indicates detections NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantitation limit may be inaccurate CELLS/ML-Cells per milliliter MG/L-Milligrams per liter UG/L-Micrograms per liter Page 1 of 8 17 TABLE 6 Groundwater Analytical Results - Exceedances SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLEJ, North Carolina Station ID NCGWQS SWMU350-MW05 SWMU350-MW06 Sample ID (April 2013) SWMU350-GW05-13B-1 SWMU350-GW05-13B-2 SWMU350-GW05-13C SWMU350-GW05-13D SWMU350-GW06-13B-1 SWMU350-GW06D-13B-1 I SWMU350-GW06-13B-2 I SWMU350-GW06-13C SWMU350-GW06-13D Sample Date 04/22/13 1 06/28/13 08/27/13 1 11/12/13 04/22/13 1 04/22/13 1 06/28/13 1 08/27/13 1 11/12/13 Chemical Name Volatile Organic Compounds(UG/L) Acetone 6,000 2 UJ 2 U 2 U 2 UJ 2 UJ 2 UJ 2 U 2 U 2 UJ Carbon disulfide 700 1 U 1 U 1 UJ 1 U 1 U 1 U 1 U 1 UJ 1 U Chloroform 70 1U 1U 1U 1U 1U 1U 1U 1U 1U Chloromethane 3 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Ethylbenzene 600 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Isopropyl benzene 70 1 UJ 1 U 1 U 1 U 1 UJ 1 UJ 1 U 1 U 1 U m-andp-Xylene 500 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U o-Xylene 500 1 UJ 1 U 1 U 1 U 1 UJ 1 UJ 1 U 1 U 1 U Toluene 600 1 U 1 U 1 U 0.31 J 1 U 1 U 1 U 1 U 0.29J ylene,total 500 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U Semivolatile Organic Compounds(UG/L) Naphthalene 6 1 UJ 1 U 1 U 1 U 96 J Wet Chemistry(MG/L) Ammonia -- NA NA NA NA NA NA NA NA NA Nitrate 10 NA NA NA NA NA NA NA NA NA Nitrite 1 NA NA NA NA NA NA NA NA NA Orthophosphate -- NA NA NA NA NA NA NA NA NA Sulfate 250 NA NA NA NA NA NA NA NA NA Functioning Genes(CELLS/ML) Napthalene Dioxygenase -- NA NA NA NA NA NA NA NA NA Notes: Grey shading indicates exceedance of NCGWQST' Bold indicates detections NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantitation limit may be inaccurate CELLS/ML-Cells per milliliter MG/L-Milligrams per liter UG/L-Micrograms per liter Page 2 of 8 18 TABLE 6 Groundwater Analytical Results - Exceedances SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLEJ, North Carolina Station ID NCGWQS SWMU350-MW11 SWMU350-MW12 Sample ID (April 2013) SWMU350-GW11-13B-1 SWMU350-GW11-13B-2 SWMU350-GW11-13C SWMU350-GW11-13D SWMU350-GW12-13B-1 SWMU350-GW12D-13B-1 SWMU350-GW12-13B-2 SWMU350-GW12-13C SWMU350-GW12-13D Sample Date 04/22/13 1 06/28/13 08/27/13 1 11/12/13 04/22/13 1 04/22/13 1 06/28/13 08/27/13 11/12/13 Chemical Name Volatile Organic Compounds(UG/L) Acetone 6,000 2 UJ 2 U 2 U 2 UJ 2 UJ 2 UJ 2 U 2 U 2 UJ Carbon disulfide 700 1 U 1 U 1 UJ 1 U 1 U 1 U 1 U 1 UJ 1 U Chloroform 70 1U 1U 1U 1U 1U 1U 1U 1U 1U Chloromethane 3 0.5 U 0.26 J 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Ethylbenzene 600 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Isopropyl benzene 70 1 UJ 1 U 1 U 1 U 1 UJ 1 UJ 1 U 1 U 1 U m-andp-Xylene 500 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U o-Xylene 500 1 UJ 1 U 1 U 1 U 1 UJ 1 UJ 1 U 1 U 1 U Toluene 600 1U 1U 1U 1U 1U 1U 1U 1U 1U ylene,total 500 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U Semivolatile Organic Compounds(UG/L) Naphthalene 6 1 UJ 1 U 1 U 1 U 24 J 1 U 1 U 1 U Wet Chemistry(MG/L) Ammonia -- NA NA NA NA NA NA NA NA NA Nitrate 10 NA NA NA NA NA NA NA NA NA Nitrite 1 NA NA NA NA NA NA NA NA NA Orthophosphate -- NA NA NA NA NA NA NA NA NA Sulfate 250 NA NA NA NA NA NA NA NA NA Functioning Genes(CELLS/ML) Napthalene Dioxygenase -- NA NA NA NA NA NA NA NA NA Notes: Grey shading indicates exceedance of NCGWQST' Bold indicates detections NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantitation limit may be inaccurate CELLS/ML-Cells per milliliter MG/L-Milligrams per liter UG/L-Micrograms per liter Page 3 of 8 19 TABLE 6 Groundwater Analytical Results - Exceedances SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLEJ, North Carolina Station ID NCGWQS SWMU350-MW15 SWMU350-MW15-30 Sample ID (April 2013) SWMU350-GW15-13B-1 SWMU350-GW15-13B-2 SWMU350-GW15-13C SWMU350-GW15-13D SWMU350-GW15-30-13B-1 SWMU350-GW15-30-13B-2 SWMU350-GW15-30D-13B-2 SWMU350-GW15-30-13C Sample Date 04/23/13 1 06/27/13 08/28/13 1 11/12/13 04/23/13 06/27/13 06/27/13 08/28/13 Chemical Name Volatile Organic Compounds(UG/L) Acetone 6,000 2 UJ 2 U 2 U 2 UJ 2 UJ 2 U 2 U 2 U Carbon disulfide 700 1 U 1 U 1 UJ 1 U 1 U 1 U 1 U 1 UJ Chloroform 70 1U 1U 1U 1U 1U 1U 1U 1U Chloromethane 3 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Ethylbenzene 600 2.1 1 U 1 U 1 U 0.48 J 1 U 1 U 1 U Isopropyl benzene 70 1.7 J 1 U 1 U 1 U 0.96 J 1 U 1 U 1 U m-and p-Xylene 500 3.7 0.5 U 0.5 U 0.5 U 0.52 J 0.5 U 0.5 U 0.5 U o-Xylene 500 7.6 J 1 U 1 U 1 U 0.69 J 1 U 1 U 1 U Toluene 600 1U 1U 1U 1U 1U 1U 1U 1U ylene,total 500 11 1.5 U 1.5 U 1.5 U 1.2 J 1.5 U 1.5 U 1.5 U Semivolatile Organic Compounds(UG/L) Naphthalene 6 170 J 1 U 1 U 2.4 J 64 J 1 U 1 U 1 U Wet Chemistry(MG/L) Ammonia -- 0.092 0.01 U 0.01 U 0.0065 J 0.048 J 0.01 U NA 0.015 J Nitrate 10 0.05 U 0.27 0.034 J 0.037 J 0.05 U 0.48 NA 0.46 Nitrite 1 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U NA 0.05 U Orthophosphate -- 0.01 U 0.00943 J 0.0495 0.01 U 0.00466 J 0.01 U NA 0.01 U Sulfate 250 26 18 19 19 12 7.2 NA 5.7 Functioning Genes(CELLS/ML) Napthalene Dioxygenase -- 102,000 6,190 280 49.5 56,400 440,000 NA 16,700 Notes: Grey shading indicates exceedance of NCGWQST' Bold indicates detections NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantitation limit may be inaccurate CELLS/ML-Cells per milliliter MG/L-Milligrams per liter UG/L-Micrograms per liter Page 4 of 8 20 TABLE 6 Groundwater Analytical Results - Exceedances SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLEJ, North Carolina Station ID NCGWQS SWMU350-MW15-30 SWMU350-MW15-55 Sample ID (April 2013) SWMU350-GW15-30D-13C SWMU350-GW15-30-13D SWMU350-GW15-30D-13D SWMU350-GW15-55-13B-1 SWMU350-GW15-55-13B-2 SWMU350-GW15-55-13C SWMU350-GW15-55-13D Sample Date 08/28/13 1 11/12/13 1 11/12/13 04/23/13 06/28/13 08/27/13 1 11/12/13 Chemical Name Volatile Organic Compounds(UG/L) Acetone 6,000 2 U 2 UJ 2 UJ 2 UJ 2 U 2.7 J 2 UJ Carbon disulfide 700 1 UJ 1 U 1 U 1 U 1 U 1 UJ 1 U Chloroform 70 1 U 1 U 1 U 1 U 1 U 1 U 1 U Chloromethane 3 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Ethylbenzene 600 1 U 1 U 1 U 1 U 1 U 1 U 1 U Isopropyl benzene 70 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U m-and p-Xylene 500 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U o-Xylene 500 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U Toluene 600 1 U 1 U 1 U 1 U 1 U 1 U 0.54 J ylene,total 500 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U Semivolatile Organic Compounds(UG/L) Naphthalene 6 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U Wet Chemistry(MG/L) Ammonia -- NA 0.01 U NA NA NA NA NA Nitrate 10 NA 0.46 NA NA NA NA NA Nitrite 1 NA 0.05 U NA NA NA NA NA Orthophosphate -- NA 0.01 U NA NA NA NA NA Sulfate 250 NA 6.8 NA NA NA NA NA Functioning Genes(CELLS/ML) Napthalene Dioxygenase -- NA 1,080 NA NA NA NA NA Notes: Grey shading indicates exceedance of NCGWQST' Bold indicates detections NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantitation limit may be inaccurate CELLS/ML-Cells per milliliter MG/L-Milligrams per liter UG/L-Micrograms per liter Page 5 of 8 21 TABLE 6 Groundwater Analytical Results - Exceedances SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLEJ, North Carolina Station ID NCGWQS SWMU350-MW56-15 SWMU350-MW56-30 Sample ID (April 2013) SWMU350-GW56-15-13B-1 SWMU350-GW56-15-13B-2 SWMU350-GW56-15-13C SWMU350-GW56-15-13D SWMU350-GW56-30-13B-1 SWMU350-GW56-30-13B-2 SWMU350-GW56-30D-13B-2 Sample Date 04/23/13 06/27/13 08/28/13 11/12/13 04/23/13 06/27/13 06/27/13 Chemical Name Volatile Organic Compounds(UG/L) Acetone 6,000 2 UJ 2 U 2 U 2 UJ 2 UJ 2 U 2 U Carbon disulfide 700 1 U 1 U 1 UJ 1 U 1 U 1 U 1 U Chloroform 70 1 U 1 U 1 U 1 U 0.3 J 1 U 1 U Chloromethane 3 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Ethylbenzene 600 1 U 1 U 1 U 1 U 1 U 1 U 1 U Isopropyl benzene 70 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U m-and p-Xylene 500 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U o-Xylene 500 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U Toluene 600 1U 1U 1U 1U 1U 1U 1U ylene,total 500 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U Semivolatile Organic Compounds(UG/L) Naphthalene 6 1 UJ 1 U 1 U 1 U-06iiiiiiiiiiiiill 22 J 1 U 1 U Wet Chemistry(MG/L) Ammonia -- 0.019 J 0.01 U 0.01 U 0.01 U 0.03 J 0.01 U NA Nitrate 10 0.05 U 0.05 U 0.023 J 0.021 J 0.13 0.44 NA Nitrite 1 0.05 U 0.05 U 0.05 U 0.05 U 0.024 J 0.05 U NA Orthophosphate -- 0.00576 J 0.00885 J 0.00773 J 0.00602 J 0.00574 J 0.01 U NA Sulfate 250 13 10 10 13 15 7.8 NA Functioning Genes(CELLS/ML) Napthalene Dioxygenase -- 656 215 17.2 5 U 98,000 29,600 NA Notes: Grey shading indicates exceedance of NCGWQST' Bold indicates detections NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantitation limit may be inaccurate CELLS/ML-Cells per milliliter MG/L-Milligrams per liter UG/L-Micrograms per liter Page 6 of 8 22 TABLE 6 Groundwater Analytical Results - Exceedances SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLEJ, North Carolina Station ID NCGWQS SWMU350-MW56-30 SWMU350-MW57-15 Sample ID (April 2013) SWMU350-GW56-30-13C SWMU350-GW56-30-13D SWMU350-GW56-30D-13D SWMU350-GW57-15-136-1 SWMU350-GW57-15-13B-2 SWMU350-GW57-15-13C SWMU350-GW57-15-13D Sample Date 08/28/13 11/12/13 1 11/12/13 04/23/13 06/27/13 1 08/28/13 1 11/12/13 Chemical Name Volatile Organic Compounds(UG/L) Acetone 6,000 2 U 2 UJ 2 UJ 2 UJ 2 U 2 U 2 UJ Carbon disulfide 700 1 UJ 1 U 1 U 1 U 1 U 1 UJ 1 U Chloroform 70 1 U 1 U 1 U 1 U 1 U 1 U 1 U Chloromethane 3 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Ethylbenzene 600 1 U 1 U 1 U 1 U 1 U 1 U 1 U Isopropyl benzene 70 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U m-and p-Xylene 500 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U o-Xylene 500 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U Toluene 600 1U 1U 1U 1U 1U 1U 1U ylene,total 500 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U Semivolatile Organic Compounds(UG/L) Naphthalene 6 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U Wet Chemistry(MG/L) Ammonia -- 0.014 J 0.01 U NA 0.032 J 0.014 J 0.01 U 0.01 U Nitrate 10 0.33 0.24 NA 0.05 U 0.066 J 0.87 0.35 Nitrite 1 0.05 U 0.05 U NA 0.05 U 0.05 U 0.05 U 0.05 U Orthophosphate -- 0.01 U 0.01 U NA 0.00983 J 0.0524 0.0187 0.0235 Sulfate 250 6.7 6.9 NA 19 19 17 19 Functioning Genes(CELLS/ML) Napthalene Dioxygenase -- 83.3 251 NA 41,600 404 862 3.6 J Notes: Grey shading indicates exceedance of NCGWQST' Bold indicates detections NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantitation limit may be inaccurate CELLS/ML-Cells per milliliter MG/L-Milligrams per liter UG/L-Micrograms per liter Page 7 of 8 23 TABLE 6 Groundwater Analytical Results - Exceedances SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLEJ, North Carolina Station ID NCGWQS SWMU350-MW57-30 Sample ID (April 2013) SWMU350-GW57-30-13B-1 SWMU350-GW57-30-13B-2 SWMU350-GW57-30-13C SWMU350-GW57-30-13D Sample Date 04/23/13 06/27/13 08/28/13 11/12/13 Chemical Name Volatile Organic Compounds(UG/L) Acetone 6,000 2 UJ 2 U 2 U 2 UJ Carbon disulfide 700 0.33 J 1 U 1 UJ 1 U Chloroform 70 0.87 J 1 U 1 U 1 U Chloromethane 3 0.5 U 0.5 U 0.5 U 0.5 U Ethylbenzene 600 1 U 1 U 1 U 1 U Isopropyl benzene 70 0.94 J 1 U 1 U 1 U m-and p-Xylene 500 0.23 J 0.5 U 0.5 U 0.5 U o-Xylene 500 0.4 J 1 U 1 U 1 U Toluene 600 1 U 1 U 1 U 1 U ylene,total 500 0.63 J 1.5 U 1.5 U 1.5 U Semivolatile Organic Compounds(UG/L) Naphthalene 6 16 J 1 U 1 U 1 U Wet Chemistry(MG/L) Ammonia -- 0.12 0.01 U 0.01 U 0.01 U Nitrate 10 0.021 J 0.31 0.2 0.37 Nitrite 1 0.05 U 0.05 U 0.05 U 0.05 U Orthophosphate -- 0.00673 J 0.01 U 0.01 U 0.01 U Sulfate 250 15 7.6 5.7 5.5 Functioning Genes(CELLS/ML) Napthalene Dioxygenase -- 94,800 27,200 16.7 28.5 Notes: Grey shading indicates exceedance of NCGWQST' Bold indicates detections NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantitation limit may be inaccurate CELLS/ML-Cells per milliliter MG/L-Milligrams per liter UG/L-Micrograms per liter Page 8 of 8 24 TABLE 7 Summary of Soil Gas Analytical Results SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLE✓, North Carolina Naphthalene Well ID Date µgym3 5/21/2013 2.31 J SWMU350-SG01 8/27/2013 0.79 J 11/5/2013 0.52 U 4/24/2013 1.42J SWMU 350-SG02 8/26/2013 0.52 J 11/5/2013 0.63J 5/16/2013 2.57J SWMU350-SG03 -- NA 11/5/2013 0.68J 5/21/2013 0.73J SWMU 350-SG04 8/27/2013 0.84 J 11/5/2013 0.52J 5/16/2013 1.101 SWMU350-SG05 -- NA 11/5/2013 0.52J Notes: NA-Not analyzed µg/m3-micrograms per meter cubed U-material analyzed for,but not detected J-estimated value Bold values indicate detection Naphthalene concentrations in soil gas did not exceed the North Carolina Division of Waste Management Residential Vapor Intrusion Screening Level for Sub Slab and Exterior Soil Gas(January 2014)of 20.9 µg/m3 during the treatability study. Page 1 of 1 25 TABLE 8 Soil Gas Analytical Results - Exceedances SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ, North Carolina Station ID SWMU350-SG01 SWMU350-SG02 Sub Slab and Exterior Sample ID Soil Gas Screening SWMU350-SG0l-13B SWMU350-SG0l-13C SWMU350-SG0l-13D SWMU350-SG02-13B SWMU350-SG02D-13B SWMU350-SG02-13C SWMU350-SG02D-13C SWMU350-SG02-13D Level(June 2014) Sample Date 05/21/13 08/27/13 11/05/13 04/24/13 04/24/13 08/26/13 08/26/13 11/05/13 Chemical Name Volatile Organic Compounds(UG/M3) 1,1,1-Trichloroethane 34,800 0.16 U 0.76 J 0.16 U 0.16 U 0.16 U 0.16 U 0.27 J 0.16 U 1,1,2,2-Tetrachloroethane 16.1 0.69 U 0.69 U 0.69 U 0.69 U 0.69 U 0.69 U 1,1,2-Trichloro-1,2,2-trifluoroethane(Freon-113) 209,000 0.69 J 0.84 J 0.77 J 0.77 J 0.84 J 0.77 J 0.77 U 0.77 J 1,2,4-Trichlorobenzene 13.9 1.04 J 0.74 U 0.74 U 0.74 UJ 0.89 J 0.74 U 0.74 U 0.74 U 1,2,4-Trimethylbenzene 48.7 0.49 U 0.69 J 0.79 J 5.9 J 5.9 J 5.41 0.84 J 1.72 J 1,2-Dichlorobenzene 1,390 0.6 U 0.6 U 0.6 J 0.6 U 0.6 U 0.6 U 0.6 U 0.6 U 1,2-Dichloroethane 36.0 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 1,2-Dichloropropane 27.8 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 1,3,5-Trimethylbenzene -- 1.92 J 0.49 U 0.49 U 6.39 J 4.62 J 2.11 J 0.49 U 0.69 J 2-Butanone 34,800 2.6 J 2.95 5.9 5.9 J 5.6 J 1.09 J 0.68 J 6.19 2-Hexanone 209 0.65 J 0.41 U 0.41 U 1.39 J 1.23 J 0.41 U 0.41 U 0.41 U 2-Propanol -- 33.2 J 0.25 U 43.8 J 13.0 J 14.0 J 4.92 2.41 29.7 4-Ethyltoluene -- 0.49 U 0.49 U 0.49 U 0.49 U 0.49 U 0.49 U 0.49 U 0.49 U 4-Methyl-2-pentanone 20,900 0.41 U 2.5 0.86 J 0.45 J 0.49 J 5.33 0.53 J 1.64 J Acetone 216,000 22.1 J 8.79 21.9 16.9 J 13.5 J 8.79 8.55 0.24 U Benzene 120 3.19 J 0.35 J 0.61 J 0.38 J 0.26 J 0.38 J 0.22 J 0.32 J Bromomethane 34.8 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U Carbon disulfide 4,870 0.65 J 1 J 0.31 U 0.75 J 0.31 J 0.31 U 0.69 J 0.31 U Carbon tetrachloride 156 0.19 U 0.19 U 0.25 J 0.19 U 0.19 J 0.19 U 0.19 U 0.19 U Chloroform 40.7 2.78 J 1.71 J 1.61 J 3.96 J 4.79 J 1.61 J 5.86 0.98 J Chloromethane 626 0.21 U 0.21 U 0.78 J 0.58 J 0.31 J 0.21 U 0.89 J 0.21 J cis-1,2-Dichloroethene -- 0.4 U 0.36 J 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U Cyclohexane 41,700 0.72 J 0.55 J 0.89 J 0.52 J 0.41 J 0.48 J 0.34 U 0.34 U Dichlorodifluoromethane(Freon-12) 695 0.59 J 1.04 J 2.08 J 0.54 J 0.54 J 1.09 J 1.29 J 1.14 J Ethyl acetate 487 0.4 U 2.02 0.4 U 0.4 U 0.4 U 2.86 1.03 J 10.3 Ethylbenzene 374 6.08 J 1.13 J 1 J 0.43 J 0.48 J 1.35 J 0.43 U 1.87 J Heptane -- 5.33 J 1.02 J 2.01 J 0.41 U 0.41 U 1.39 J 0.41 U 3.89 m-and p-Xylene 695 9.12 J 2 J 1.87 J 1.78 J 1.65 J 3.47 J 0.69 J 3 J Methylene chloride 4,170 1.32 J 2.5 10.1 J 1.91 J 2.08 J 11.5 10.4 1.88 J Methyl-tert-butyl ether(MTBE) 3,600 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U Naphthalene 20.9 2.31 J 0.79 J 0.52 U 0.84 J 1.42 J 0.52 J 0.52 UJ 0.63 J n-Hexane 4,870 9.52 J 1.13 J 0.35 U 1.09 J 0.99 J 2.43 1.3 J 10.6 o-Xylene 695 6.52 J 0.96 J 0.83 J 3.95 J 2.39 J 2.22 0.43 J 1.52 J Propylene 20,900 1.24 J 0.17 U 0.17 U 0.17 U 0.17 U 0.17 U 0.17 U 0.17 U Styrene 6,950 8.09 J 0.43 U 0.43 U 0.43 U 0.43 U 5.11 0.43 U 0.51 J Tetrahydrofuran 13,900 0.29 U 1.59 0.62 J 4.13 J 4.42 J 0.29 U 0.29 U 0.29 U Tetrachloroethene 278 0.61 J 5.83 0.75 J 0.54 J 0.61 J 1.76 J 1.56 J 1.7 J Toluene 34,800 29.8 J 6.03 38.4 2.11 J 2.79 J 12.4 1.73 J 59.5 Trichloroethene 13.9 0.16 U 21.0 0.48 J 0.43 J 0.21 J 4.94 6.99 0.59 J Trichlorofluoromethane(Freon-1 1) 4,870 1.4 J 1.63 J 1.46 J 1.4 J 1.46 J 1.57 J 1.52 J 1.24 J Notes: Grey shading indicates exceedance of Division of Waste Management Residential kVapor Intrusion Screening Levels for Sub Slab and Exterior Soil Gas(June 2014) Bold indicates detections NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantitation limit may be inaccurate UG/M3-Micrograms per cubic meter Page 1 of 2 26 TABLE 8 Soil Gas Analytical Results - Exceedances SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ, North Carolina Station ID SWMU350-SG03 SWMU350-SG04 SWMU350-SG05 Sub Slab and Exterior Sample ID Soil Gas Screening SWMU350-SG03-13B SWMU350-SG03-13D SWMU350-SG03D-13D SWMU350-SG04-13B SWMU350-SG04-13C SWMU350-SG04-13D SWMU350-SG05-13B SWMU350-SG05D-13B SWMU350-SG05-13D Level(June 2014) Sample Date 05/16/13 11/05/13 11/05/13 05/21/13 08/27/13 11/05/13 05/16/13 05/16/13 11/05/13 Chemical Name Volatile Organic Compounds(UG/M3) 1,1,1-Trichloroethane 34,800 0.16 U 0.16 U 0.16 U 0.16 U 0.87 J 0.16 U 0.16 U 0.16 U 0.16 U 1,1,2,2-Tetrachloroethane 16.1 0.69 U 0.69 U 0.69 U 0.69 U 0.69 U 0.69 U 0.69 U 0.69 U 0.69 U 1,1,2-Trichloro-1,2,2-trifluoroethane(Freon-113) 209,000 0.77 U 0.61 J 0.61 J 0.69 J 0.84 J 0.69 J 0.77 J 0.54 J 0.77 J 1,2,4-Trichlorobenzene 13.9 0.74 U 0.74 U 0.74 U 0.59 J 0.74 U 0.74 U 0.97 J 1.04 J 0.74 U 1,2,4-Trimethylbenzene 48.7 34.4 1.28 J 2.06 J 0.49 U 6.88 1.67 J 0.49 U 11.8 1.08 J 1,2-Dichlorobenzene 1,390 0.6 U 0.6 U 0.6 U 0.6 U 0.6 U 0.6 U 0.6 U 0.6 U 0.6 U 1,2-Dichloroethane 36.0 2.83 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 1,2-Dichloropropane 27.8 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 1,3,5-Trimethylbenzene -- 8.85 0.49 UJ 0.79 J 1.33 J 2.85 0.54 J 0.49 U 4.92 0.49 U 2-Butanone 34,800 97.9 8.26 10.3 0.56 J 1.39 J 14.5 1.5 1.59 4.42 2-Hexanone 209 0.41U 0.41U 0.41U 0.41U 0.41U 0.41U 0.41U 0.41U 0.41U 2-Propanol -- 84.1 32.5 J 65.9 J 5.65 8.85 53.1 73.3 J 59.0 J 10.8 4-Ethyltoluene -- 9.83 0.49 UJ 0.54 J 0.49 U 0.49 U 0.49 U 0.49 U 0.49 U 0.49 U 4-Methyl-2-pentanone 20,900 21.3 0.7 J 2.05 J 0.41 U 3.73 1.64 J 0.41 U 0.41 U 1.35 J Acetone 216,000 0.24 U 42.1 47.0 6.89 11.6 126 0.24 U 23.5 48.7 Benzene 120 13.7 0.73 J 1.18 J 1.02 J 0.64 J 0.7 J 1.63 1.88 0.42 J Bromomethane 34.8 1.83 J 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U Carbon disulfide 4,870 405 0.31 U 0.31 U 0.31 J 0.31 U 0.31 U 0.47 J 0.44 J 0.31 U Carbon tetrachloride 156 0.57 J 0.19 U 0.19 U 0.19 U 0.19 U 0.19 U 0.19 U 0.19 U 0.19 U Chloroform 40.7 0.49 U 2.2 J 2.2 J 7.81 2 J 19.5 0.49 U 0.2 J 0.49 U Chloromethane 626 1.28 0.5 J 0.43 J 0.21 U 0.21 U 0.74 J 0.21 U 0.21 U 0.43 J cis-1,2-Dichloroethene -- 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U Cyclohexane 41,700 175 1.24 J 1.72 0.41 J 0.79 J 1.76 0.34 U 0.76 J 0.93 J Dichlorodifluoromethane(Freon-12) 695 0.69 J 1.63 J 1.78 J 0.64 J 0.84 J 1.78 J 0.59 J 0.49 U 2.23 J Ethyl acetate 487 129 48.4 57.9 0.4 U 3.53 0.4 U 5.55 10.7 0.4 U Ethylbenzene 374 46.0 1 J 3.52 J 1.48 J 1.56 J 2.26 0.43 U 0.56 J 1.87 J Heptane -- 50.4 3.03 J 10.3 J 1.19 J 1.84 J 7.38 0.74 J 0.66 J 7.79 m-and p-Xylene 695 113 2.13 J 7.38 J 3.69 J 4 J 3.52 J 1.43 J 2.17 J 3.39 J Methylene chloride 4,170 175 1.88 J 1.98 J 1.29 J 3.3 1.98 J 1.67 J 1.18 J 1.84 J Methyl-tert-butyl ether(MTBE) 3,600 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.4 J 0.36 U Naphthalene 20.9 2.57 J 0.68 J 0.52 J 0.73 J 0.84 J 0.52 J 0.79 J 1.1 J 0.52 J n-Hexane 4,870 58.5 0.35 U 0.35 U 2.5 1.44 J 61.7 7.05 6.34 60.3 o-Xylene 695 49.5 1.09 J 2.91 J 2.61 2.82 1.61 J 0.87 J 1.48 J 1.39 J Propylene 20,900 3.44 0.17 U 0.17 U 0.86 0.17 U 0.17 U 0.17 U 0.17 U 0.17 U Styrene 6,950 43.9 0.47 J 1.06 J 0.43 U 7.66 0.64 J 0.43 U 0.43 U 0.43 U Tetrahydrofuran 13,900 110 0.71 J 0.91 J 0.29 U 0.29 U 0.97 J 0.29 U 0."J 0.29 U Tetrachloroethene 278 17.0 3.05 J 1.29 J 0.27 J 8.14 1.49 J 0.61 J 0.47 J 1.97 J Toluene 34,800 256 46.7 J 78.4 J 7.91 19.2 61.1 4.52 3.77 32.8 Trichloroethene 13.9 14.0 0.32 J 0.32 J 0.16 U 36.5 0.27 J 0.16 U 0.16 U 0.27 J Trichlorofluoromethane(Freon-11) 4,870 1.46 J 1.29 J 1.24 J 1.35 J 1.52 J 1.29 J 1.12 J 0.96 J 1.29 J Notes: Grey shading indicates exceedance of Division of Waste Management Residential por Intrusion Screening Levels for Sub Slab and Exterior Soil Gas(June 2014) Bold indicates detections NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantitation limit may be inaccurate UG/M3-Micrograms per cubic meter Page 2 of 2 27 TABLE 9 Soil Vapor Extraction Test Results SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLEJ,North Carolina r SVE Blower T&jL2AJLQJWlon Sheet Client: NAVFAC Mid-Atlantic Initial Data Collection Notes: Location: SWMU350,MCIEAST-MCB CAMLEJ Initial Vac(in H2O) DTW(ft btoc) Stick Up(ft) DTW(ft btoc) Stick Up(ft) ft btoc-feet below top of casing Project Num. 425128.PT.PT MW15-15 -0.0010 MW15-30 11.06 2.92 SV01 I -- 1.04 in H2O-inches of water Date: 12/4/2013 SGOI -0.0165 MW15-55 11.07 2.54 MW15-15 1 9.96 1.86 ft/min-feet per minute Field Team: Bridget Berglind,Kevin Howell SG02 -0.0019 MW57-15 11.09 2.72 DTB(ft btoc) Scrn Lgth(ft) gal-gallons Weather: cloudy,rainy,60s SG03 -0.0009 MW57-30 11.47 2.89 SV01 8.54 4 ppm-parts per million SG04 -0.0011 IW57-25 9.54 1.27 MW15-15 15.84 10 IW57-40 1 9.49 1.32 System Parameters Field Readings Blower Well Head Vacuum Line Dilution Air Knock-Out Effluent PID DTW(ft btoc) Vacuum(in H2O) Vacuum I PressureBlower Vacuum Velocity Velocity Tank Volume Reading Time (in H2O) (in H2O) (in H2O) I (ft/min) (ft/min) (gal) (ppm) MW15-30 IW57-25 I SGOl 1 SG02 1 SG03 SG04 MW15-15 Comments 8:52 Started blower with dilution valve fully open. 8:55 0 0 -17 280 530 0 16 -- 9.55 -0.0478 -0.0780 -0.0065 0.0000 -0.1982 9:05 0 0 -16 206 419 0 4.3 11.08 9.55 -0.1590 -0.0745 -0.0045 -0.0003 -0.1916 9:15 Closed dilution valve 1/4 turn. 9:20 0 0 -30 884 173 0 4.5 11.08 9.55 -0.2570 -0.1283 -0.0080 -0.0005 -0.3380 9:35 0 0 -30 550 168 0 3.7 11.10 9.57 -0.2320 -0.1256 -0.0086 0.0000 -0.3250 9:45 Closed dilution valve fully. 9:50 0 0 -48 780 -- 0 5.5 11.10 9.57 -0.4110 -0.1186 -0.0116 -- -0.4740 10:10 0 0 -48 408 - 0 8.9 11.10 9.57 -0.3350 -0.1679 -0.0121 -- -0.4320 10:30 0 0 -48 225 -- 0 7.2 -- -- -0.3300 -0.1489 -0.0090 -- -0.3910 10:50 0 0 -48 245 -- 0 6.7 -- -- -0.3290 -0.1383 -0.0101 - -0.3570 Temp Vacuum Line-45°F 11:10 0 0 -48 249 -- 0 7 11.10 9.57 -0.3150 -0.1220 -0.0080 0.0015 -0.3100 Temp Vacuum Line-50°F 11:30 0 0 -49 600 -- 0 6.5 -- -- -0.2880 -0.1070 -0.0062 - -0.2830 Temp Vacuum Line-69°F 11:50 0 0 -48 550 -- 0 5.1 -- -- -0.3030 -0.1049 -0.0069 -- -0.2700 Temp Vacuum Line-68°F 12:10 0 0 -48 360 -- 0 9.6 -- -- -0.2650 -0.0985 -0.0068 -- -0.2540 Temp Vacuum Line-71.5°F 12:30 0 0 -48 660 -- 0 9.2 -- -- -0.2620 -0.0955 -0.0055 -- -0.2380 Temp Vacuum Line-72.8°F 12:50 0 0 -48 580 -- 0 9.5 -- -- -0.2290 -0.0882 -0.0055 -- -0.2280 13:10 0 0 -48 589 -- 0 8.7 11.03 9.53 -0.2210 -0.0834 -0.0054 0.0008 -0.2180 Temp Vacuum Line-66.8°F 13:40 0 0 -48 569 -- 0 10.1 11.03 9.53 -0.2270 -0.0821 -0.0051 -- -0.2080 Temp Vacuum Line-68°F 13:55 Blower turned off for a few seconds to switch power source from generator to extension cord running from compound. 14:10 0 0 -44 540 -- 0 5.7 -- -- -0.2270 -0.0615 -0.0044 -- -0.1530 Temp Vacuum Line-70.6°F 14:40 0 0 -44 600 -- 0 4.6 -- -- -0.2010 -0.0602 -0.0051 -- -0.1508 Temp Vacuum Line-69°F 15:10 0 0 -44 670 -- 0 5.4 -- -- -0.1687 -0.0588 -0.0037 -- -0.1484 15:40 0 0 -44 650 -- 0 4.1 11.02 9.50 -0.1744 -0.0587 -0.0040 -- -0.1469 16:10 0 0 -44 665 -- 0 3.7 -- -- -0.1740 -0.0601 -0.0050 -- -0.1485 Temp Vacuum Line-71°F 16:30 0 1 0 1 -44 1 655 -- 0 3.6 11.07 9.53 -0.1675 -0.0581 -- -0.0005 -0.1478 Temp Vacuum Line-70.3°F 16:43 Blower turned off.DTW at MW15-15:9.95 ft btoc. Maximum Change from Initial Measurements 0.04 0.03 0.3945 0.1660 0.0112 -0.0006 0.4730 Page 1 of 1 28 Figures 29 R1USN-FacEn Com405450\MCBCam Leeune\Ma Files\SWMU 350\425128 TS TM\Fi ure 1 Base Location Me mxd9/25/2014bmallhes gT AT W Y 53 r: Camp Geiger SWMU 351 Montford Point/Tarawa Terrace Marine Corps Air ( Station New River ST,q �- �- '+ ti Mainside TE NWY 24 "" �S 07 qTE FIW� Hadn ri Point Industrial Area ; s 2 Greater Sandy Run t Rifle Range Courthouse Bay F '' VA 172 " c 11, STATE HWY w: NC MCIEAST-MCB ��. CAMLEJ Jacksonville Legend Figure 1 Highways Base Location Map SWMU BoundarySWM Naphthalene Biosparging Treatability Study N U 350ap ene MCIEAST-MCB CAMLEJ 0 Installation Boundary 0 7.500 15,000 North Carolina [I Onslow County IFeet 1 inch = 15,000 feet J CH2MHILI 10. 30 R:\USNavFacEnqCom405450\MCBCamiDLejeune\MapFiles\SWMU 350\425128 TS TM\Fi ure 2 Site Location Ma .mxd9/25/2014bmailhes NC ROUTE24 NC ROUTE 24 r O U O > W W {I �I • �'' r. (Y O U C °� 0& SAIPAN DRIVE J Ilk t�� �• U SWMU 350 IPiL� !i ,`ROBERTON STREET ; w. QQ O� O > w -GRAHAM Legend Figure 2 Natural Gas Main Line 0 Installation Boundary Site Location Map 0 Former AST Locations N SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ i -i Approximate 2005-2006 IM Soil Removal Area 0 150 300 600 North Carolina E3 Treatability Study Area Feet SWMU Boundary CH2MI ilLt. 1 inch = 300 feet 31 R�\USNavFacEn Com405450\MCBCam Lejeune\Ma Files\SWMU 350\425128 TS TM\Fi ure 3 Na hthalene Bios ar in Treatabilit Stud Location Ma .mxd9/25/2014bmailhes Former AST Plume Area SWMU350-MW06 SWMU350-MW05 Area A Area B SWMU350-SV01 SWMU350-SG01 SWMU350-MW15-15 SWMU350-IW58-25 SWMU350-IW57 40 SWMU350-IW58-40 SWMU350-IW57-25 SWMU350-IW55-40— SWMU350-MW15-5& SWMU350-IW56 40 SWMU350-MW15-30 SWMU350-SG02 SWMU350-MW57-15 SWMU350=MW03 I SWMU350-MW57-30 SWMU350-SG03 SWMU350-MW04_ SWMU350-MW11 SWMU350-MW12 SWMU350-SG04 SWMU350-MW56-30 SWMU350-MW56-15 SWMU350-SG05 SWMU350-MW49-18 SWMU350-MW49-30 SWMU350-MW13 SWMU350-MW49-55 SWMU350-MW28 SWMU350-MW14 SWMU350-MW16 Note: NCGWQS for Naphthalene is 6 Ng/L Limit of NCGWQS exceedance is based on the analytical results from the Spring/Summer 2011 groundwater sampling event. Limits of extent have been interpolated between monitoring well locations. Actual conditions may differ from those interpreted on this map. Legend Figure 3 Biosparging well location screened 25 ft bgs —Storm Sewer Drainage Line SWMU Boundary Naphthalene Biosparging • Biosparging well location screened 40 ft bgs — —Natural Gas Main Line \ Treatability Study Location Map • Soil Vapor Extraction Well Location Storm Sewer Utility Line \ SWMU 350 Naphthalene Biosparging • Soil Gas Monitoring Point Location Fence �1111 Treatability Study N • Monitoring wells screened across the water table—Water Table Zone Limit of Naphthalene NCGWQS Exceedance MCI EAST-MCB CAMLEJ —30-ft Zone Limit of Naphthalene NCGWQS Exceedance 0 10 20 40 North Carolina Monitoring wells screened to 30 ft bgs Biosparging Air Conveyance Line Feet V CH2MHILL. Monitoring wells screened to55ftbgs Q Treatability Study Area 1 inch = 40 feet � Electrical Utility Line ®Equipment Compound 32 R:\USNavFacEnqCom405450\MCBCampLeeune\MapFiles\SWMU 350\425128 TS TM\Fi ure 4 Cross Section Ma .mxd9/25/2014bmailhes AOft Ilk- • - ROU_rE 24 W j SWMU350 MW25 NC Q SWMU350-MW28 SWMU350-MW24-15 SWMU350-MW07 „ ,- ROUTE24 SWMU350-IW56-40 SWMU350-MW08 SWM U350-MW24 SWMU350-MW56-15 f., SWMU350-'�'MW56-0 SWMU350-MW01 SWMU350-IW57 40 SWMU350-MW02 SWMU350-M W15-15 SWMU350-MW23 SWMU350-MW08 SWMU350-IW57-25 SWMU350-MW22 SWMU350-MW03 SWMU350-MW05 SWMU350-SV01 SWMU350-SG01 SWMU350-MW27 SWMU350-MW51 SWMU350-MW04 SWMU350-IW58-25 SWMU350-IW55-40 SWMU350-MW12 SWMU350-IW58 40 SWMU350-MW1 SWMU350-MW09 �+ Area B I I SWMU350-MW10 SWMU350-MW17 SWMU350=MW15-55 Area A SWMU350-MW15-30 ' U350-MW13 SWMU350-SG05 SWMU.350-MW57-15'_ SWMU350-MW50-18 SWM SWMU350-MW28 SWMU350-SG02 SWMU350-MW57-30 SWMU350-MW56730 SWMU350-SG04 SWMU350-MW50-55 SWMU350-MW18 SWMU350-SG03 SWMU350-MW14 SWMU350-MW16 SWMU350-MW49-18 SWMU350-MW49T30 SWMU350-MW49-55 SWMU350-MW20 SWMU350-MW48-30 SWMU350-MW48-18 Legend Figure 4 • Biosparging well location screened 25 ft bgs —Geologic Cross-Sections 2A Geologic Cross-Section Location Map • Biosparging well location screened 40 ft bgs SWMU Boundary N SWMU 350 Naphthalene Biosparging Treatability Study • Soil Vapor Extraction Well Location Q Treatability Study Area 0 50 100 MCIEAST-MCB CAMLEJ • Soil Gas Monitoring Point Location 0 Installation Boundary North Carolina Monitoring wells screened to 15 ft bgs Feet ♦ Monitoring wells screened to 30 ft bgs 1 inch = 100 feet CH2MHILL. Monitoring wells screened to 55 ft bgs 33 A Former AST Area A' Treatability Study Area A Treatability Study Area B 30 ? 3:3: o�� o� ��� N� mac)-, �o o� I?— 30 cD 0 3 Moo ��� �� ����� oo�w i �000 �� m3: 3: _-_- - ----- Sand with Silt and Clay - - --- -- --= ----- _ --= ---_ --= ----_-= ---= - - ---_ --= ---- --= ------_ ----_-= - 20 - -- --=_-=-----=_-=- _ =_-=- —_ ILI --_--=_-=----=_-= -- =--=-=_-=--=-=_-=-- _- -- - _=----=_-=----=_-= --=_-=----=_-=-- - 20 10 - - _ - --- -- --- - - - - - -- _ - --- - _ - - - --- - _ - --- - _ - --- - _ - --- - 10 7-7 l0 Sand 0 0 LL C O R N W -10 -10 -20 20 -30 30 0 50 100 150 200 250 300 350 400 Distance Along Baseline(feet) Figure 5 LEGEND Generalized Geologic Cross Section A-A' SWMU 350 Naphthalene Biosparging Treatability Study 0 Sand --- Inferred Geologic Contact MCIEAST-MCB CAMLEJ Horizontal:1"=8.3 Sand with Silt and Clay V Groundwater Table Vertical:1 28' North Carolina Groundwater elevation data V.E.=3.4x Screened Interval collected in November 2013 V CH2MHILL® ES062911193625MKE MCB_CamLej_SWMU350_Fig5_Generalized_A-A'_v2 03.28.14 sls 34 R:\USNavFacEnqCom405450\MCBCampLeeune\MapFiles\SWMU 350\425128 TS TM\Fi ure 6 Water Table Zone Naphthalene Bios are Treatability Trend Gra hs.mxd9/25/2014bmailhes 1AW05 MW15-15 Upgradient 5.5 feet from IW57&22 ft from IW58 180 18 180 18 SWMU350-MW07 I I I 160 16 160 i 16 I I 140 i 14 140 14 1120 12 ° =120 12 c I c I w I c w c 100 10 m 100 10 W SWMU350-MW01 z 80 i s 9 Z so I $ o v MW56-15 I > I > 7.5 feet from IW56-40&25 ft from IW55-40 60 6 N 60 6 R 180 1e I N I I I 40 4 40 4 160 i 16 20 2 20 2 .m.140 14 1 0 0 0 0 c 120 12 Date�)A°� ro° \ti°� \�O''� o�°^n/ y\�OyA ,aA° 0 Date OyA \y°� t 100 I 10 L I % 2 80 I 8 O I w > 60 I 6 u� I e 40 4 I 20 2 I 0 0 Date Area A Area B SWMU350-SV01 SWMU350-SG01 J SWMU350-IW58-25 SWMU350-IW57 40 SWMU350-IW58 40 SWMU350-IW57-25 SWMU350-IW55-40 i SWMU350-IW56 40 SWMU350-SG02 MW03 SWMU350-SG03 15 feet from IW55-40&IW56-40 180 1e I I MW57-15 160 I 16 SWMU350-SG04 20 feet from IW58&35 feet from IW57 180 18 140 14 I 160 I 16 1zo 12 E I I W I C 140 14 m 100 10 I z eo e O lzo 12 E I w I c m 100 10 g, 60 I 6 012 L I z 80 i 8 40 4 SWMU350-SG05 I 60 I 6 20 2 C I 40 4 0 0 o'`A oyA oyA d� Date v°1" ,�� .I:'''� yA 20 I 2 0 0 �tiot`°� A\�y\�O� o\�•,\A°� ,\ 0 Datati OyA0 SWMU350-MW49-18 SWMU350-MW13 MW11 Downgradient 180 1e I 160 I 16 I 140 I 14 I I � 120 12 C I y I c t 100 10 t I O z 80 I 8 N I e 60 6 N 1 p 40 4 I 20 2 I 02 1 0 O A e 0", Date 6\1" y\ry 0\ry 9 y0\y r --*—Naphthalene t D0(mg/L) —System Startup — —System Shutdown Legend Figure 6 Biosparging well location screened 25 ft bgs Natural Gas Main Line Naphthalene and Dissolved Oxygen Concentration • Biosparging well location screened 40 ft bgs — Fence Trend Graphs - Surficial Aquifer- 15-foot Zone • Soil Vapor Extraction Well Location — - Biosparging Air Conveyance Line SWMU 350 Naphthalene Biosparging Treatability Study • Soil Gas Monitoring Point Location ® Equipment Compound MCIEAST-MCB CAMLEJ Q� Monitoring wells screened to 15ft bgs Treatability Study Area N North Carolina --- Electrical Utility Line 0 15 30 60 Storm Sewer Utility Line Feet — Storm Sewer Drainage Line Wastewater Utility Line 1 inch = 30 feet CH2MI III I 35 R:\USNavFacEnqCom405450\MCBCampLe eune\Ma Files\SWMU 350\425128 TS TM\Fi ure 7 30 It Zone Naphthalene Biosparging TreatabilitV Trend Gra hs.mxd9/25/2014bmailhes MW06 Upgradient 100 18 SWMU350-MW08-�F 1 90 1 , 16 — 1 80 ... I 14 Y 70 1 12 E w , y 60 C L I 10 m SWMU350-MW02 �50 1 $ o Z 40 i > 1 6 R 30 1 � 20 1 4 MW56-30 1 1 7.5 feet from IW56-40&25 ft from IW55-40 10 2 100 18 , I o 0 90 I 16 0�0^'/ o'� A'' �o'�' Date 80 14 41 I 70 MW15-30 I 12 E k 7.5 feet from IW57&27 from IW58 y 60 C 100 18 c I 10 m I a50 O 90 I 16 Z 40 d Area B 80 14 6 ,° — 30 ' c I 12 E 20 4 W 60 C L I 10 T 10 2 L 50Ne % I m 8 y 0 0 Z 40 ' Date"\^°` tiro^'' A\"°'�' \"°'� 6 30 20 4 I 10 2 I 0 0 SWMU350-IW57 40 0�0+ "01 "os o+ Date�o SWMU350-IW57-25 SWMU350-IW55 40 Area A SWMU350-IW58-40 SWMU350NW56 40 SWMU350-IW58-25 SWMU350-SG02 SWMU350-SG01 SWMU350-SG03 SWMU350-SV01 MW04 15 feet from IW55-40&IW56-40 100 18 I 90 16 SWMU350-SG04 I 80 14 270 I 12 E y 60 C L I 10 y>/ t 50 x a O m 8 y Z 40 � ' 6 u� 30 I � 20 q SWMU350-SG05 10 2 I _ 0 0 Date SWIM 50-MW49-30 SWMU350-MW14 MW12 Dmngradient 100 1e I MW57-30 90 16 SWMU350-MW16 20 feet from IW58&35 feet from IW57 100 18 I , 80 14 90 I 16 70 I 12°9 80 14 60 L , 10 1 70 a50 x C I 12 E I 8 O W 60 Z I 9 i I 10 41 40 L 04 6 C 50 O 30 I C 8 Z 40 I 20 I 4 I 6 O 30 I 2 I e 10 q , 20 0 0 I Date "o'� � \"o'�' \"o'� 10 , 2 0 0 \"oP Date 9^ "0 SWMU350-MW20 —d*­-Naphthalene t DO(mg/ —System Startup — —System Shutdown Legend Figure 7 Biosparging well location screened 25 ft bgs Natural Gas Main Line Naphthalene and Dissolved Oxygen Concentration • Biosparging well location screened 40 ft bgs — Fence Trend Graphs - Surficial Aquifer- 30-foot Zone • Soil Vapor Extraction Well Location — - Biosparging Air Conveyance Line SWMU 350 Naphthalene Biosparging Treatability Study • Soil Gas Monitoring Point Location ® Equipment Compound MCIEAST-MCB CAMLEJ Monitoring wells screened to 30 ft bgs Treatability Study Area N North Carolina --- Electrical Utility Line 0 15 30 60 — Storm Sewer Drainage Line I Feet Storm Sewer Utility Line Wastewater Utility Line 1 inch = 30 feet 4 CH2MI III I 36 R:\USNav Fac En Com405450\MCBCam Leieune\Ma Files\SWMU 350\425128 TS TM\Fi ure 8 Water Table Naphthalene Conc Baseline and 6 Month.mxd 9/25/2014bmail hes Former AST Plume Area Former AST Plume Area SWMU350-MW06 SWMU350-MW06 SWMU350-MW05 1 UJ SWMU350-MW05 1U Area A Area B SWMU350-SV01 Area A Area B SWMU350-SV01 SWMU350-MW15-15 _ _ _ _ SWMU350-SG01 SWMU350-MW15-15 SWMU350-SG01 170 J _ SWMU350-IW58-25 2.q J SWMU350-IW58-25 S W M U350-IW57-4i SWMU 350-IW58-40 SWMU 350-IW57-41 SWMU 350-IW58-40 SWMU350-IW57-2 �ti SWMU350-IW57-2 I r t SWMU350-MW15-55 r SWMU350-MW15- Y ,, - --- '350-IW56-40 SWMU350-MW15-3P _ - - - -- � SWMU350-IW56-40 SWMU350-MW15• SWMU350-S1 SWMU350-MW57-15 SWMU350-S�_ SWMU350-MW57-15 f1UJ 1U SWMU350-MW03 - SWMU350-MW03 1 UJ Sl .IW57-30 SWMU350-MW50-30 1,U _ SWMU350-MW57-30 SWMU350-MW50-30 SWMU350-MW11 7U350-SG03 SWMU350-MW11 �U350-SG03 1 UJ SWMU350-MW50-55 SWMU350-MWO--� CID SWMU350-MW50-55 SWMU350-MW12 SWMU350-SG04 SWMU350-MWb2 'U350-SG04 SWMU350-MW56-3 SWMU350-MW56-30 SWMU350-MW5fi=15 1 UJ SWMU350-MW56-15 1U SWMU350-SG05 SWMU350-SG05 SWMU350-MW49-18 SWMU350-MW49-18 SWMU 350-MW49-30 �'�` SWMU 350-MW49-30 iWMU350-MW13 ``�- SWMU350-MW49-55 SWMU350-MW13 �`�-� SWMU350-MW49-55 WMU350-MW28 `~'_'�"� •9U350-MW28 `~'_'�`� SWMU350-M�" � `1�'`y SWMU350-MW14 1'�"" swmusa�mwib � � SWMU350-MW, � �-�,�,y Concentrations shown in ug/L Baseline event data collected in April 2013 6-Month Post Startup data collected November 2013 NCGWQS for Naphthalene is 6 ug/L J -analyte present, value may or may not be accurate or precise UJ - analyte not detected, quantitation limit may be inaccurate - U - material analyzed for but not detected Legend Figure 8 Biosparging well location screened 25 ft bgs --- Electrical Utility Line Naphthalene Concentrations (dashed where inferred) Naphthalene Plume - Surficial Aquifer (15-foot Zone) • Biosparging well location screened 40 ft bgs — Storm Sewer Drainage Line 6 Ng/L N SWMU 350 Naphthalene Biosparging Treatability Study • Soil Vapor Extraction Well Location Natural Gas Main Line 60 Ng/L 0 10 20 40 MCIEAST-MCB CAMLEJ • Soil Gas Monitoring Point Location — Fence Feet North Carolina Q� Monitoring wells screened to 15 ft bgs — - Biosparging Air Conveyance Line Monitoring wells screened to 30 ft bgs ® Equipment Compound 1 inch = 40 feet Monitoring wells screened to 55 ft bgs 0 Treatability Study Area rJ CH2rvn IILL SWMU Boundary 37 R:\USNav FacEn Com405450\MCBCam Leieune\Ma Files\SWMU 350\425128 TS TM\Fi ure 9 30ft Naphthalene Conc Baseline and 6 Month.mxd9/25/2014bmail hes - 0t►]Y.If11010) i - FormerAST Plume Area r Former AST Plume Area ,'� y`` �� SWMU350-MW06 J SWMU350-MW06 I � � SWMU: '1W0' ' � ♦ - r Area A Area B SWMU350-SV01 Area A Area B SWMU350-SV01 i SWMU350-SG01 - SWMU350-SG01 SW�.,.,.,.,�-MW15-15 � SWMU350-IW58-25 SWMU350-MW15-1! SWMU350-IW58-25 SW M U350-IW57-4i SWMU 350-IW58-40 SWMU 350-IW57-41 SWMU 350-IW58-40 SW M U350-IW57-2 SWMU 350-IW57-2 SWMU350-MW15-�- SWMU350-MW15-55 t, SWMU350-MW15-30 ' SWMU350-MW15-30 SWMU350-IW56-40 64 SWfu MW57-15 SWMU350-IW56-40 1 U SWMU350-SG02 SWMU350-S�_ NMU350-MW57-15 SWMU350-MW57-30 SWMU350-MW57-30 16J _ SWMU350-MVO_ �_ 1 U SWMU350-MW50-30 SWMU350-MW04 SWMU350-SG03 SWMU350-MW04 9U350-SG03 56 J \ SWMU350-MW50-55 1 _. SWMU350-MW50-55 SWMU350-MW11 SWMU350-MW11 SWMU350-MW56-30 SWMU350-SG04 SWMU350-SG04 men SWMU350-MW56-30 SWMU350-MW12 SW 1,11d i MW12 1 U 1 U SWMU350-MW56-1 25 J SWMU350-MW56-15 SWMU350-SG05 SWMU350-SG05 SWMU350-MW49-18 SWMU350-MW49-18 SWMU 350-MW49-30 0-M W49-30 iWMU350-MW13 ``�- SWMU350-MW49-55 SWMU350-MW13 �`�-� ...,_ SWMU350-MW49-55 SWMU350-MW16 Concentrations shown in ug/L Baseline event data collected in April 2013 6-Month Post Startup data collected November 2013 NCGWQS for Naphthalene is 6 ug/L J -analyte present, value may or may not be accurate or precise UJ - analyte not detected, quantitation limit may be inaccurate - U - material analyzed for but not detected Legend Figure 9 Biosparging well location screened 25 ft bgs --- Electrical Utility Line Naphthalene Concentrations (dashed where inferred) Naphthalene Plume - Surficial Aquifer (30-foot Zone) • Biosparging well location screened 40 ft bgs — Storm Sewer Drainage Line 6 Ng/L N SWMU 350 Naphthalene Biosparging Treatability Study • Soil Vapor Extraction Well Location Natural Gas Main Line 60 Ng/L 0 10 20 40 MCIEAST-MCB CAMLEJ • Soil Gas Monitoring Point Location — Fence Feet North Carolina Q� Monitoring wells screened to 15 ft bgs — - Biosparging Air Conveyance Line Monitoring wells screened to 30 ft bgs ® Equipment Compound 1 inch = 40 feet Monitoring wells screened to 55 ft bgs 0 Treatability Study Area SWMU Boundary �J cor2rvrh{iLL 38 Attachment 1 Underground Injection Control Notification Letter 39 UNITED STATES MARINE CORPS MARINE CORPS INSTALLATIONS EAST-MARINE CORPS BASE ` PSC BOX 20005 CAMP LEJEUNE NC 28542-0005 5090.21 BEMD APR 0 4 20113 Ms. Debra Watts Underground Injection Control Program Aquifer Protection Section North Carolina Department of Environment and Natural Resources Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 Dear Ms. Watts: Marine Corps Installations East-Marine Corps Base Camp Lejeune is submitting the enclosure, Notification of Intent to Construct or Operate Injection Wells (Notification) in accordance with 15A NCAC 02C.0217. This Notification is for the construction and operation of six new air injection wells at Resource Conservation and Recovery Act Solid Waste Management Unit (SWMU) 350. The air injection wells are "permitted by rule" and do not require individual permits. The purpose of injecting air into the six new air injection wells is to evaluate enhanced situ biodegradation of naphthalene in groundwater in the surficial aquifer. Section F of the Notification describes the well site physical location, which is depicted in Notification Figure 1. The enclosure provides construction details for the wells. Well construction is scheduled to begin during the week of April 8, 2013. Once the air injection system is operational, the treatability study will continue for approximately six months. If you have any questions regarding this information, please contact Ms. Patti Vanture, Environmental Quality Branch, Environmental Management Division, G-F, at (910) 451-9641. Sincerely, OHN R. TOWNSON irector, Environmental Management By direction of the Commanding General Enclosure: Notification of Intent to Construct or Operate Injection Wells (6) Copy to: NCDENR (Beth Hartzell) NAVFAC (Bryan Beck) CH2MHill (Dan Hockett) File (ODI# 17446) 40 NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES NOTIFICATION OF INTENT TO CONSTRUCT OR OPERATE INJECTION WELLS The following are "permitted by role"and do not require an individual permit when constructed in accordance with the rules of 15A NCAC 02C.0200. This form shall be submitted at least 2 weeks prior to construction. AQUIFER TEST WELLS(15A NCAC 02C.0227) These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics. IN SITU REMEDIATION(15A NCAC 02C.0225) or TRACER WELLS (15A NCAC 02C.0229): 1) Passive Injection Systems - In-well delivery systems to diffuse injectants into the subsurface. Examples include ORC socks, iSOC systems,and other gas infusion methods. 2) Small-Scale Injection Operations—Injection wells located within a land surface area not to exceed 10,000 square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shall be required for test or treatment areas exceeding 10,000 square feet. 3) Pilot Tests -Preliminary studies conducted for the purpose of evaluating the technical feasibility of a remediation strategy in order to develop a full scale remediation plan for future implementation,and where the surface area of the injection zone wells are located within an area that does not exceed five percent of the land surface above the known extent of groundwater contamination. An individual permit shall be required to conduct more than one pilot test on any separate groundwater contaminant plume. 4) Air Injection Wells - Used to inject ambient air to enhance in-situ treatment of soil or groundwater. Print Clearly or Type Information. Illegible Submittals Will Be Returned As Incomplete. DATE: April 1, 2013 1 PERMIT NO. NA (to be filled in by DWQ) A. WELL TYPE TO BE CONSTRUCTED OR OPERATED (1) 6 Air Injection Well......................................Complete sections B-F,K,N (2) Aquifer Test Well.......................................Complete sections B-F,K,N (3) Passive Injection System...............................Complete sections B-F,H-N (4) Small-Scale Injection Operation......................Complete sections B-N (5) Pilot Test.................................................Complete sections B-N (6) Tracer Injection Well...................................Complete sections B-N B. STATUS OF WELL OWNER: Federal Govertunent C. WELL OWNER — State name of entity and name of person delegated authority to sign on behalf of the business or agency: Name: Mr.John Townson—Director of Environmental Management Division Mailing Address:MCIEAST-MCB CAMLEJ;G-F/EMD/EQB; 12 Post Lane City: Camp Lejeune State: NC Zip Code: 28547 County:Onslow Day Tele No.: 910-451-7693 Cell No.: NA EMAILAddress: John.townson@usmc.mil Fax No.: 910-451-1143 DWQMIC/In Situ Rented.Notification(Revised 7/9/2012) t r Page I 41 ,�lG�US[il 'i \l D. PROPERTY OWNER(if different than well owner) Name: Mailing Address: City: State: Zip Code: County: Day Tele No.: Cell No.: EMAIL Address: Fax No.: E. PROJECT CONTACT-Person who can answer technical questions about the proposed injection project. Name: Dan Hockett Mailing Address: 11301 Carmel Commons Blvd Ste 304 City: Charlotte State: NC Zip Code:28226 County: Mecklenburg_ Day Tele No.: 704-543-3264 Cell No.: 704-516-2665 EMAIL Address:Dan.Hockett li2m.com Fax No.: 704-544-4041 F. PHYSICAL LOCATION OF WELL SITE (1) Physical Address: 300 feet east of the intersection of Iwo Jima Blvd and State Highway 24,on southern side of State Highway hgway 24 County: Onslow City: Jacksonville State:NC Zip Code: 28546 (2) Geographic Coordinates: See Attached Figure I in lieu of geographic coordinates.. Latitude": " or ° Longitude": ° "or ° Reference Datum: Accuracy: Method of Collection: "FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES. G. TREATMENT AREA—Not Applicable for air injection. Land surface area of contaminant plume: square feet Land surface area of inj. well network: square feet(< 10,000 ft2 for small-scale injections) Percent of contaminant plume area to be treated: (must be<5%of plume for pilot test injections) H. INJECTION ZONE MAPS—Not Applicable for air injection. Attach the following to the notification. (1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and proposed injection wells;and (2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed monitoring wells,and existing and proposed injection wells. DWQ/UIC/In Situ Rented.Notification(Revised 7/9/2012) Page 2 42 locl sure ( ) I. DESCRIPTION OF PROPOSED INJECTION ACTIVITIES—Not Applicable for air injection. Provide a brief narrative regarding the purpose,scope,and goals of the proposed injection activity. J. INJECTANTS—Not Applicable for air injection. Provide a MSDS and the following for each injectant.Attach additional sheets if necessary. NOTE: Approved it jectants (tracers and remediation additives) can be found online at littp://portal.ttcdetur.or /�tg eb/ivq/aps/gtiWro. All other substances must be revielved by the Division of Public Health, Department of Health and Human Services. Contact the UIC Program for•more it fo (919-807-6496). Injectant: Volume of injectant: Concentration at point of injection: Percent if in a mixture with other injectants: Injectant: Volume of injectant: Concentration at point of injection: Percent if in a mixture with other injectants: Injectant: Volume of injectant: Concentration at point of injection: Percent if in a mixture with other injectants: K. WELL CONSTRUCTION DATA—Please see Attachment 1 for Well Construction Details. (1) Number of injection wells: 6 Proposed 0 Existing (2) Provide well construction details for each injection well in a diagrain or table format. A single diagram or line in a table can be used for multiple wells with the same construction details. Well construction details shall include the following: (a) well type as permanent,direct-push,or subsurface distribution system(infiltration gallery) (b) depth below land surface of grout,screen,and casing intervals (c) well contractor name and certification number DWQ/UIC/In Sinn Reined.Notification(Revised 7/9/2012) Page 3 L. SCHEDULES—Briefly describe the schedule for well construction and injection activities. M. MONITORING PLAN—Describe below or in separate attachment a monitoring plan to be used to determine if violations of groundwater quality standards specified in Subchapter 02L result from the injection activity. N. CERTIFICATION(to be signed as required below or by that person's authorized agent) 15A NCAC 02C .0211(e)requires that all permit applications shall be signed as follows: 1. for a corporation: by a responsible corporate officer; 2. for a partnership or sole proprietorship: by a general partner or the proprietor,respectively; 3. for a municipality or a state, federal, or other public agency: by either a principal executive officer or ranking publicly elected official; 4. for all others: by the well owner; 5. for any other person authorized to act on behalf of the applicant: documentation shall be submitted with the notification that clearly identifies the person, grants them signature authority, and is signed and dated by the applicant. "I hereby certify, under penalty of law, that I have personally examined and ain familiar with the it formation submitted in this docunent and all attaclvnents thereto and that, based on my inquiry of those individuals iuuunediately responsible for obtaining said ittforination, I believe that the information is true, accurate and complete. I am-mvare that there are significant penalties, including the possibility of fines and imprisonment, for submitting false it formation. I agree to construct, operate, maintain, repair, and if applicable, abandon the it jeetion ivell and related appurtet rites in actor nce with the 15A iVCAC 02C 0200 Rules. " u�ln bl� Signature of Applicant Print or Type Full Name Signature of Property Owner(if different from applicant) Print or Type Full Name Signature of Authorized Agent,if any Print or Type Full Name Submit one copy of the completed notification package to: DWQ-Aquifer Protection Section 1636 Mail Service Center Raleigh,NC 27699-1636 Telephone: (919)807-6464 1 Fax: (919) 807-6496 DWQ/UIC/In Situ Reined.Notification(Revised 7/9/2012) Page 4 rty r Q� 44 Euclosure l ,1 � ty.. i44 •xi[` Lam. �#. � '4 r .. y -r i_ �' _ . 't-• aAV '; ` �`. _ J - - i _ �! ��:. �:.^ r� ,+ 's" gam• Mtn i ��!'r. •MWa:. ,..y .._'♦.r �_'_ '{ ._ f •.f 3" •'lyJ'/ � � �::.�'.._ `l Ir ry '�f]l.:.i^LY'i�- .L"R�•- '�� .-. '� 3�'�'�rti .. _ -. yv" �A� -�.' ..�T_rt,T AVI 44ZO. WC New River _ ='` � ' i� 2�� r. � �.�, _ �` ` ,y �� � �.�• �_.-s' a :..��. kill MCIEAST- �� J {�~ �`'' •tea' y �� ,_,� • see ATTACHMENT 1 Well Construction Details SWMU 350 MC/EAST-MCB CAMLEJ, North Carolina Surficial Total Well Screen"b Screen Aquifer Grout Depth Length Interval Contractor Name/ Treatability Study Well ID Zone* (ft b s) (ft b s (ft) (ft bgs) Certification Number Blosparging Wells(Air SWMU350-IW55-40 30-foot 1-31 40 2 38-40 TBD Injection Only) SWMU350-IW56-40 30-foot 1-31 40 2 38-40 TBD SWMU350-IW57-25 Water Table 1-16 25 2 23-25 TBD SWMU350-IW57-40 30-foot 1-31 40 2 38-40 TBD SWMU350-IW58-25 Water Table 1-16 25 2 23-25 TBD SWMU350-IW58-40 30-foot 1-31 40 2 38-40 TBD 46 Attachment 2 Well Construction Diagrams and Boring Logs 47 CH2MHILL PROJECT NUMBER: 425128.PT.PT BORING NUMBER: IW55-40 46 = WELL COMPLETION DIAGRAM PROJECT. LOCATION: SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ,North Carolina DRILLING METHOD: DRILLING CONTRACTOR: HSA&Macrocore DPT Parratt-Wolff Inc.,Hillsborough,NC TOP OF CASING ELEVATION(NAVD 88): NORTHING(UTM Z18 NAD83): EASTING(UTM Z18 NAD83): STATIC WATER LEVEL: TBD 12620987.50 feet 928192.06 feet 7.98 ft BTOC(4/18/2013) GROUND ELEVATION(NAVD 88): START: FINISH: LOGGED BY: 27.85 ft 04/17/2013 04 17 2013 J.High/CLT TOP OF CASING STICK-UP MONUMENT WELL CONSTRUCTION DETAILS CASING MATERIAL: PVC CASING DIAMETER: 2-in(ID) SCREEN TYPE: machine slot SLOT SIZE: 0.006-in FILTER PACK TYPE: #00 Sand SEAL TYPE: 3/8 Bentonite Chips NOTES: BOREHOLE DIAMETER: 6-in ALL DEPTHS ARE REPORTED AS FEET BELOW GROUND SURFACE(ft BGS). BOREHOLE DEPTH: 40.0 ft BGS PORTLAND CEMENT GROUT 33.0 ft BGS TOP OF BENTONITE SEAL 36.0 ft BGS TOP OF FILTER PACK TOP OF SCREEN 38.0 ft BGS BOTTOM OF SCREEN 40.0 ft BGS BOTTOM OF WELL CASING 40.0 ft BGS 40.0 ft BGS BOTTOM OF BOREHOLE WELL DIAGRAM IS NOT TO SCALE 48 CH2MHILL PROJECT NUMBER: 425128.PT.PT BORING NUMBER: IW56-40 46 = WELL COMPLETION DIAGRAM PROJECT. LOCATION: SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ,North Carolina DRILLING METHOD: DRILLING CONTRACTOR: HSA&Macrocore DPT Parratt-Wolff Inc.,Hillsborough,NC TOP OF CASING ELEVATION(NAVD 88): NORTHING(UTM Z18 NAD83): EASTING(UTM Z18 NAD83): STATIC WATER LEVEL: TBD 12620975.49 feet 928220.01 feet 9.63 ft BTOC(4/18/2013) GROUND ELEVATION(NAVD 88): START: FINISH: LOGGED BY: 27.72 ft 04/16/2013 04 16 2013 J.High/CLT TOP OF CASING STICK-UP MONUMENT WELL CONSTRUCTION DETAILS CASING MATERIAL: PVC CASING DIAMETER: 2-in(ID) SCREEN TYPE: machine slot SLOT SIZE: 0.006-in FILTER PACK TYPE: #00 Sand SEAL TYPE: 3/8 Bentonite Chips NOTES: BOREHOLE DIAMETER: 6-in ALL DEPTHS ARE REPORTED AS FEET BELOW GROUND SURFACE(ft BGS). BOREHOLE DEPTH: 40.0 ft BGS PORTLAND CEMENT GROUT 32.5 ft BGS TOP OF BENTONITE SEAL 36.0 ft BGS TOP OF FILTER PACK TOP OF SCREEN 38.0 ft BGS BOTTOM OF SCREEN 40.0 ft BGS BOTTOM OF WELL CASING 40.0 ft BGS 40.0 ft BGS BOTTOM OF BOREHOLE WELL DIAGRAM IS NOT TO SCALE 49 CH2MHILL PROJECT NUMBER: 425128.PT.PT BORING NUMBER: IW57-25 46 = WELL COMPLETION DIAGRAM PROJECT. LOCATION: SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ,North Carolina DRILLING METHOD: DRILLING CONTRACTOR: HSA&Macrocore DPT Parratt-Wolff Inc.,Hillsborough,NC TOP OF CASING ELEVATION(NAVD 88): NORTHING(UTM Z18 NAD83): EASTING(UTM Z18 NAD83): STATIC WATER LEVEL: TBD 12620985.37 feet 928321.56 feet 7.73 ft BTOC(4/18/2013) GROUND ELEVATION(NAVD 88): START: FINISH: LOGGED BY: 27.26 ft 04/11/2013 04 11 2013 B.Propst/CLT TOP OF CASING STICK-UP MONUMENT WELL CONSTRUCTION DETAILS CASING MATERIAL: PVC CASING DIAMETER: 2-in(ID) SCREEN TYPE: machine slot SLOT SIZE: 0.006-in FILTER PACK TYPE: #00 Sand SEAL TYPE: 3/8 Bentonite Chips NOTES: BOREHOLE DIAMETER: 6-in ALL DEPTHS ARE REPORTED AS FEET BELOW GROUND SURFACE(ft BGS). BOREHOLE DEPTH: 25.0 ft BGS PORTLAND CEMENT GROUT 20.0 ft BGS TOP OF BENTONITE SEAL 22.0 ft BGS TOP OF FILTER PACK TOP OF SCREEN 23.0 ft BGS BOTTOM OF SCREEN 25.0 ft BGS BOTTOM OF WELL CASING 25.0 ft BGS 25.0 ft BGS BOTTOM OF BOREHOLE WELL DIAGRAM IS NOT TO SCALE 50 CH2MHILL PROJECT NUMBER: 425128.PT.PT BORING NUMBER: IW57-40 46 = WELL COMPLETION DIAGRAM PROJECT. LOCATION: SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ,North Carolina DRILLING METHOD: DRILLING CONTRACTOR: HSA&Macrocore DPT Parratt-Wolff Inc.,Hillsborough,NC TOP OF CASING ELEVATION(NAVD 88): NORTHING(UTM Z18 NAD83): EASTING(UTM Z18 NAD83): STATIC WATER LEVEL: TBD 12620987.66 feet 928321.78 feet TBD GROUND ELEVATION(NAVD 88): START: FINISH: LOGGED BY: 27.36ft 04/12/2013 04 12 2013 B.Propst/CLT TOP OF CASING STICK-UP MONUMENT WELL CONSTRUCTION DETAILS CASING MATERIAL: PVC CASING DIAMETER: 2-in(ID) SCREEN TYPE: machine slot SLOT SIZE: 0.006-in FILTER PACK TYPE: #00 Sand SEAL TYPE: 3/8 Bentonite Chips NOTES: BOREHOLE DIAMETER: 6-in ALL DEPTHS ARE REPORTED AS FEET BELOW GROUND SURFACE(ft BGS). BOREHOLE DEPTH: 40.0 ft BGS PORTLAND CEMENT GROUT 35.0 ft BGS TOP OF BENTONITE SEAL 37.0 ft BGS TOP OF FILTER PACK TOP OF SCREEN 38.0 ft BGS BOTTOM OF SCREEN 40.0 ft BGS BOTTOM OF WELL CASING 40.0 ft BGS 40.0 ft BGS BOTTOM OF BOREHOLE WELL DIAGRAM IS NOT TO SCALE 51 CH2MHILL PROJECT NUMBER: 425128.PT.PT BORING NUMBER: IW58-25 46 = WELL COMPLETION DIAGRAM PROJECT. LOCATION: SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ,North Carolina DRILLING METHOD: DRILLING CONTRACTOR: HSA&Macrocore DPT Parratt-Wolff Inc.,Hillsborough,NC TOP OF CASING ELEVATION(NAVD 88): NORTHING(UTM Z18 NAD83): EASTING(UTM Z18 NAD83): STATIC WATER LEVEL: TBD 12620986.78feet 928349.38feet 6.13 ft BTOC(4/18/2013) GROUND ELEVATION(NAVD 88): START: FINISH: LOGGED BY: 26.51 ft 04/10/2013 04 10 2013 B.Propst/CLT TOP OF CASING STICK-UP MONUMENT WELL CONSTRUCTION DETAILS CASING MATERIAL: PVC CASING DIAMETER: 2-in(ID) SCREEN TYPE: machine slot SLOT SIZE: 0.006-in FILTER PACK TYPE: #00 Sand SEAL TYPE: 3/8 Bentonite Chips NOTES: BOREHOLE DIAMETER: 6-in ALL DEPTHS ARE REPORTED AS FEET BELOW GROUND SURFACE(ft BGS). BOREHOLE DEPTH: 25.0 ft BGS PORTLAND CEMENT GROUT 20.0 ft BGS TOP OF BENTONITE SEAL 22.0 ft BGS TOP OF FILTER PACK TOP OF SCREEN 23.0 ft BGS BOTTOM OF SCREEN 25.0 ft BGS BOTTOM OF WELL CASING 25.0 ft BGS 25.0 ft BGS BOTTOM OF BOREHOLE WELL DIAGRAM IS NOT TO SCALE 52 CH2MHILL PROJECT NUMBER: 425128.PT.PT BORING NUMBER: IW58-40 46 = WELL COMPLETION DIAGRAM PROJECT. LOCATION: SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ,North Carolina DRILLING METHOD: DRILLING CONTRACTOR: HSA&Macrocore DPT Parratt-Wolff Inc.,Hillsborough,NC TOP OF CASING ELEVATION(NAVD 88): NORTHING(UTM Z18 NAD83): EASTING(UTM Z18 NAD83): STATIC WATER LEVEL: TBD 12620986.58 feet 928351.48 feet 8.63 ft BTOC(4/18/2013) GROUND ELEVATION(NAVD 88): START: FINISH: LOGGED BY: 26.77 ft 04/10/2013 04 10 2013 B.Propst/CLT TOP OF CASING STICK-UP MONUMENT WELL CONSTRUCTION DETAILS CASING MATERIAL: PVC CASING DIAMETER: 2-in(ID) SCREEN TYPE: machine slot SLOT SIZE: 0.006-in FILTER PACK TYPE: #00 Sand SEAL TYPE: 3/8 Bentonite Chips NOTES: BOREHOLE DIAMETER: 6-in ALL DEPTHS ARE REPORTED AS FEET BELOW GROUND SURFACE(ft BGS). BOREHOLE DEPTH: 40.0 ft BGS PORTLAND CEMENT GROUT 35.0 ft BGS TOP OF BENTONITE SEAL 37.0 ft BGS TOP OF FILTER PACK TOP OF SCREEN 38.0 ft BGS BOTTOM OF SCREEN 40.0 ft BGS BOTTOM OF WELL CASING 40.0 ft BGS 40.0 ft BGS BOTTOM OF BOREHOLE WELL DIAGRAM IS NOT TO SCALE 53 CH2MHILL PROJECT NUMBER: 425128.PT.PT BORING NUMBER: MW15-30 46 = WELL COMPLETION DIAGRAM PROJECT. LOCATION: SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ,North Carolina DRILLING METHOD: DRILLING CONTRACTOR: HSA&Macrocore DPT Parratt-Wolff Inc.,Hillsborough,NC TOP OF CASING ELEVATION(NAVD 88): NORTHING(UTM Z18 NAD83): EASTING(UTM Z18 NAD83): STATIC WATER LEVEL: 28.81 ft 12620978.22 feet 928322.08 feet 9.46 ft BTOC(4/16/2013) GROUND ELEVATION(NAVD 88): START: FINISH: LOGGED BY: 25.89 ft 04/11/2013 04 11 2013 B.Propst/CLT TOP OF CASING STICK-UP MONUMENT WELL CONSTRUCTION DETAILS CASING MATERIAL: PVC CASING DIAMETER: 2-in(ID) SCREEN TYPE: machine slot SLOT SIZE: 0.01-in FILTER PACK TYPE: #1 Sand SEAL TYPE: 3/8 Bentonite Chips NOTES: BOREHOLE DIAMETER: 6-in ALL DEPTHS ARE REPORTED AS FEET BELOW GROUND SURFACE(ft BGS). BOREHOLE DEPTH: 32.0 ft BGS PORTLAND CEMENT GROUT 16.0 ft BGS TOP OF BENTONITE SEAL 18.0 ft BGS TOP OF FILTER PACK TOP OF SCREEN 20.0 ft BGS BOTTOM OF SCREEN 30.0 ft BGS BOTTOM OF WELL CASING 30.0 ft BGS 32.0 ft BGS BOTTOM OF BOREHOLE WELL DIAGRAM IS NOT TO SCALE 54 CH2MHILL PROJECT NUMBER: 425128.PT.PT BORING NUMBER: MW56-15 46 = WELL COMPLETION DIAGRAM PROJECT. LOCATION: SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ,North Carolina DRILLING METHOD: DRILLING CONTRACTOR: HSA&Macrocore DPT Parratt-Wolff Inc.,Hillsborough,NC TOP OF CASING ELEVATION(NAVD 88): NORTHING(UTM Z18 NAD83): EASTING(UTM Z18 NAD83): STATIC WATER LEVEL: 29.89 ft 12620967.81feet 928219.00feet 10.09 ft BTOC(4/18/2013) GROUND ELEVATION(NAVD 88): START: FINISH: LOGGED BY: 26.94 ft 04/15/2013 04 15 2013 J.High/CLT TOP OF CASING STICK-UP MONUMENT WELL CONSTRUCTION DETAILS CASING MATERIAL: PVC CASING DIAMETER: 2-in(ID) SCREEN TYPE: machine slot SLOT SIZE: 0.01-in FILTER PACK TYPE: #1 Sand SEAL TYPE: 3/8 Bentonite Chips NOTES: BOREHOLE DIAMETER: 6-in ALL DEPTHS ARE REPORTED AS FEET BELOW GROUND SURFACE(ft BGS). BOREHOLE DEPTH: 15.0 ft BGS PORTLAND CEMENT GROUT 1.0 ft BGS TOP OF BENTONITE SEAL 3.0 ft BGS TOP OF FILTER PACK TOP OF SCREEN 5.0 ft BGS BOTTOM OF SCREEN 15.0 ft BGS BOTTOM OF WELL CASING 15.0 ft BGS 15.0 ft BGS BOTTOM OF BOREHOLE WELL DIAGRAM IS NOT TO SCALE 55 CH2MHILL PROJECT NUMBER: 425128.PT.PT BORING NUMBER: MW56-30 46 = WELL COMPLETION DIAGRAM PROJECT. LOCATION: SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ,North Carolina DRILLING METHOD: DRILLING CONTRACTOR: HSA&Macrocore DPT Parratt-Wolff Inc.,Hillsborough,NC TOP OF CASING ELEVATION(NAVD 88): NORTHING(UTM Z18 NAD83): EASTING(UTM Z18 NAD83): STATIC WATER LEVEL: 29.92 ft 12620968.80feet 928348.72feet 10.63 ft BTOC(4/18/2013) GROUND ELEVATION(NAVD 88): START: FINISH: LOGGED BY: 26.90 ft 04/15/2013 04 15 2013 J.High/CLT TOP OF CASING STICK-UP MONUMENT WELL CONSTRUCTION DETAILS CASING MATERIAL: PVC CASING DIAMETER: 2-in(ID) SCREEN TYPE: machine slot SLOT SIZE: 0.01-in FILTER PACK TYPE: #1 Sand SEAL TYPE: 3/8 Bentonite Chips NOTES: BOREHOLE DIAMETER: 6-in ALL DEPTHS ARE REPORTED AS FEET BELOW GROUND SURFACE(ft BGS). BOREHOLE DEPTH: 32.0 ft BGS PORTLAND CEMENT GROUT 15.0 ft BGS TOP OF BENTONITE SEAL 18.0 ft BGS TOP OF FILTER PACK TOP OF SCREEN 20.0 ft BGS BOTTOM OF SCREEN 30.0 ft BGS BOTTOM OF WELL CASING 30.0 ft BGS 32.0 ft BGS BOTTOM OF BOREHOLE WELL DIAGRAM IS NOT TO SCALE 56 CH2MHILL PROJECT NUMBER: 425128.PT.PT BORING NUMBER: MW57-15 46 = WELL COMPLETION DIAGRAM PROJECT. LOCATION: SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ,North Carolina DRILLING METHOD: DRILLING CONTRACTOR: HSA&Macrocore DPT Parratt-Wolff Inc.,Hillsborough,NC TOP OF CASING ELEVATION(NAVD 88): NORTHING(UTM Z18 NAD83): EASTING(UTM Z18 NAD83): STATIC WATER LEVEL: 28.81 ft 12620966.73feet 928216.08feet 10.00 ft BTOC(4/17/2013) GROUND ELEVATION(NAVD 88): START: FINISH: LOGGED BY: 29.04 ft 04/11/2013 04 11 2013 B.Propst/CLT TOP OF CASING STICK-UP MONUMENT WELL CONSTRUCTION DETAILS CASING MATERIAL: PVC CASING DIAMETER: 2-in(ID) SCREEN TYPE: machine slot SLOT SIZE: 0.01-in FILTER PACK TYPE: #1 Sand SEAL TYPE: 3/8 Bentonite Chips NOTES: BOREHOLE DIAMETER: 6-in ALL DEPTHS ARE REPORTED AS FEET BELOW GROUND SURFACE(ft BGS). BOREHOLE DEPTH: 15.0 ft BGS PORTLAND CEMENT GROUT 1.0 ft BGS TOP OF BENTONITE SEAL 3.0 ft BGS TOP OF FILTER PACK TOP OF SCREEN 5.0 ft BGS BOTTOM OF SCREEN 15.0 ft BGS BOTTOM OF WELL CASING 15.0 ft BGS 15.0 ft BGS BOTTOM OF BOREHOLE WELL DIAGRAM IS NOT TO SCALE 57 CH2MHILL PROJECT NUMBER: 425128.PT.PT BORING NUMBER: MW57-30 46 = WELL COMPLETION DIAGRAM PROJECT. LOCATION: SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ,North Carolina DRILLING METHOD: DRILLING CONTRACTOR: HSA&Macrocore DPT Parratt-Wolff Inc.,Hillsborough,NC TOP OF CASING ELEVATION(NAVD 88): NORTHING(UTM Z18 NAD83): EASTING(UTM Z18 NAD83): STATIC WATER LEVEL: 29.17 ft 12620966.40feet 928348.72feet 10.15 ft BTOC(4/17/2013) GROUND ELEVATION(NAVD 88): START: FINISH: LOGGED BY: 26.28 ft 04/10/2013 04 10 2013 B.Propst/CLT TOP OF CASING STICK-UP MONUMENT WELL CONSTRUCTION DETAILS CASING MATERIAL: PVC CASING DIAMETER: 2-in(ID) SCREEN TYPE: machine slot SLOT SIZE: 0.01-in FILTER PACK TYPE: #1 Sand SEAL TYPE: 3/8 Bentonite Chips NOTES: BOREHOLE DIAMETER: 6-in ALL DEPTHS ARE REPORTED AS FEET BELOW GROUND SURFACE(ft BGS). BOREHOLE DEPTH: 32.0 ft BGS PORTLAND CEMENT GROUT 16.0 ft BGS TOP OF BENTONITE SEAL 18.0 ft BGS TOP OF FILTER PACK TOP OF SCREEN 20.0 ft BGS BOTTOM OF SCREEN 30.0 ft BGS BOTTOM OF WELL CASING 30.0 ft BGS 32.0 ft BGS BOTTOM OF BOREHOLE WELL DIAGRAM IS NOT TO SCALE 58 CH2MHILL PROJECT NUMBER: 425128.PT.PT BORING NUMBER: SV01 46 = WELL COMPLETION DIAGRAM PROJECT. LOCATION: SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ,North Carolina DRILLING METHOD: DRILLING CONTRACTOR: HSA&Macrocore DPT Parratt-Wolff Inc.,Hillsborough,NC TOP OF CASING ELEVATION(NAVD 88): NORTHING(UTM Z18 NAD83): EASTING(UTM Z18 NAD83): STATIC WATER LEVEL: TBD 12620984.25 feet 928335.30 feet TBD GROUND ELEVATION(NAVD 88): START: FINISH: LOGGED BY: 27.13ft 04/09/2013 04 09 2013 B.Propst/CLT TOP OF CASING STICK-UP MONUMENT WELL CONSTRUCTION DETAILS CASING MATERIAL: PVC CASING DIAMETER: 4-in(ID) SCREEN TYPE: machine slot SLOT SIZE: 0.01-in FILTER PACK TYPE: #1 Sand, #00 Sand SEAL TYPE: 3/8 Bentonite Chips NOTES: BOREHOLE DIAMETER: 8-in ALL DEPTHS ARE REPORTED AS FEET BELOW GROUND SURFACE(ft BGS). BOREHOLE DEPTH: 8.0 ft BGS PORTLAND CEMENT GROUT 1.5 ft BGS TOP OF BENTONITE SEAL 3.5 ft BGS TOP OF FILTER PACK TOP OF SCREEN 4.0 ft BGS BOTTOM OF SCREEN 8.0 ft BGS BOTTOM OF WELL CASING 8.0 ft BGS 8.0 ft BGS BOTTOM OF BOREHOLE WELL DIAGRAM IS NOT TO SCALE 59 PROJECT NUMBER: BORING NUMBER: 425128.PT.PT IW55-40 SHEET 1 of 2 CH2MHILL .,� Soil Boring Log CLIENT:NAVFAC PROJECT: SWMU 350 Naphthalene Biosparging Treatability Study LOCATION:MCIEAST-MCB CAMLEJ,North Carolina ELEVATION:27.85 ft above sea level DRILLING CONTRACTOR:Parratt-Wolff Inc.,Hillsborough,NC EAST.NORTH(UTM Z18 NAD83.feet):928192.06,12620987.50 DRILLING METHOD AND EQUIPMENT: HSA&Macrocore DPT WATER LEVEL:7.98 ft BTOC 4/18/2013 START:4/17/2013 END:4/17/2013 LOGGER:J.Hi h/CLT Lu 0 SOIL DESCRIPTION COMMENTS WELL o z o SOIL NAME,USCS GROUP SYMBOL, DIAGRAM M vi a a O r = MOISTURE CONTENT,RELATIVE DEPTH OF CASING,DRILLING Surface a Z v z v w M a a DENSITY OR RATE,DRILLING FLUID LOSS, Completion: o TESTS,&INSTRUMENTATION P o o a c� CONSISTENCY,SOIL STRUCTURE, MINERALOGY SOIL(OL) brown,dry,loose,organic. SILTY SAND(SM) light brown,dry to damp,medium dense, HA-1 0 fine grained. 5 5.0 SAND(SP) light brown,dry to damp,medium dense. SAND(SC) DP-1 32.4 0 tan,dry to damp,medium dense,traces of clay. 8.0 gray/light tan. No Recovery. SILTY SAND(SM) 10 light brown,dry to damp,medium dense, DP-2 36 0 A A fine grained. soft. SANDY CLAY(CL) 12.0 light gray/tan,dry to damp,dense,fine grained,high plasticity. SAND(SP) light gray/brown,damp,loose,dense to soft,fine to medium grained. DP 3 36 0 No Recovery. 15 SAND(SP) 16.0 light gray,damp,medium dense,fine grained. CLAYEY SAND(SC) light gray,damp,medium dense,fine raiend,low plasticity. DP-4 43.2 0 SAND(SP) light gray,wet,medium dense,fine to medium grained. \20. 20 CLAYEY SAND(SCE light gray,wet,medium dense,fine grained. SANDY CLAY(CL) light green/gray,wet,some fine grained DP 5 \24.O 36 0 sand,low plasticity. SAND(SP) light green/gray,wet,medium dense, fine grained,some small shell fragments. 25 -light gray. DP-6 36 0 \28.O 30 DP-7 38.4 0 60 PROJECT NUMBER: BORING NUMBER: 425128.PT.PT IW55-40 SHEET 2 OF 2 CH2MHILL Soil Boring Log CLIENT:NAVFAC PROJECT: SWMU 350 Naphthalene Biosparging Treatability Study LOCATION:MCIEAST-MCB CAMLEJ,North Carolina ELEVATION:27.85 ft above sea level DRILLING CONTRACTOR:Parratt-Wolff Inc.,Hillsborough,NC EAST.NORTH(UTM Z18 NAD83.feet):928192.06,12620987.50 DRILLING METHOD AND EQUIPMENT: HSA&Macrocore DPT WATER LEVEL:7.98 ft BTOC 4/18/2013 START:4/17/2013 END:4/17/2013 LOGGER:J.Hi h/CLT Lu 0 SOIL DESCRIPTION COMMENTS WELL o Z o SOIL NAME,USCS GROUP SYMBOL, DIAGRAM M vi a a O r = MOISTURE CONTENT,RELATIVE DEPTH OF CASING,DRILLING Surface a Z v z v w M a a DENSITY OR RATE,DRILLING FLUID LOSS, Completion: v o TESTS,&INSTRUMENTATION P o o a c� CONSISTENCY,SOIL STRUCTURE, MINERALOGY 32.0 No Recovery. SAND(SP) light tan,wet,loose,fine grained. DP-8 \36.O 36 0 35 -light tan/brown,dense,fine to medium grained. -light gray,medium dense,fine grained. DP-9 0 40 40.0 End of Boring Log at 40'bgs Boring drilled to 40.0'bgs to set well. Abbreviations: bgs-below ground surface DP-Direct Push ft-feet HA-Hand Auger PID-Photo Ionization Detector 45 PPM-parts per million 50 55 60 61 PROJECT NUMBER: BORING NUMBER: 425128.PT.PT IW58-40 SHEET 1 of 2 CH2MHILL .� Soil Boring Log CLIENT:NAVFAC PROJECT: SWMU 350 Naphthalene Biosparging Treatability Study LOCATION:MCIEAST-MCB CAMLEJ,North Carolina ELEVATION:26.77 ft above sea level DRILLING CONTRACTOR:Parratt-Wolff Inc.,Hillsborough,NC EAST.NORTH(UTM Z18 NAD83.feet):928351.48,12620986.58 DRILLING METHOD AND EQUIPMENT: HSA&Macrocore DPT WATER LEVEL:8.63 ft BTOC 4/18/2013 START:4/10/2013 END:4/10/2013 LOGGER:B.Pro st/CLT L SOIL DESCRIPTION COMMENTS WELL o z o SOIL NAME,USCS GROUP SYMBOL, DIAGRAM m vi a a O r = MOISTURE CONTENT,RELATIVE DEPTH OF CASING,DRILLING Surface a Z v z v w a a DENSITY OR RATE,DRILLING FLUID LOSS, Completion: o TESTS,&INSTRUMENTATION P o o a c� CONSISTENCY,SOIL STRUCTURE, MINERALOGY SOIL(OL) dark gray,dry,loose,fine grained, organic. SILTY SAND(SM) light brown/gray,dry to damp,medium HA-1 0 dense,fine grained. 5 5.0 -trace clay. DP-1 48 0 CLAYEY SAND(SC) light gray,damp,dense. SANDY CLAY(CL) 9.0 gray,hard,low to medium plasticity. 10 No Recovery. DP-2 0 0 13.0 SANDY W/SOME SILT(SC/SM) 15 light tan,wet,loose,fine grained. DP-3 36 0 \17.O No Recovery. SANDY W/SOME SILT(SC/SM) light tan,wet,loose,fine grained. DP-4 36 0 20 21.0 SAND(SP) light tan,wet,loose,fine grained. DP-5 24 0 25 25.0 DP-6 36 0 29.0 30 62 PROJECT NUMBER: BORING NUMBER: 425128.PT.PT IW58-40 SHEET 2 of 2 CH2MHILL .� Soil Boring Log CLIENT:NAVFAC PROJECT: SWMU 350 Naphthalene Biosparging Treatability Study LOCATION:MCIEAST-MCB CAMLEJ,North Carolina ELEVATION:26.77 ft above sea level DRILLING CONTRACTOR:Parratt-Wolff Inc.,Hillsborough,NC EAST.NORTH(UTM Z18 NAD83.feet):928351.48,12620986.58 DRILLING METHOD AND EQUIPMENT: HSA&Macrocore DPT WATER LEVEL:8.63 ft BTOC 4/18/2013 START:4/10/2013 END:4/10/2013 LOGGER:B.Pro st/CLT L SOIL DESCRIPTION COMMENTS WELL o Z o SOIL NAME,USCS GROUP SYMBOL, DIAGRAM m vi a a O r = MOISTURE CONTENT,RELATIVE DEPTH OF CASING,DRILLING Surface a Z v z v Lu w a a DENSITY OR RATE,DRILLING FLUID LOSS, Completion: o 9 TESTS,&INSTRUMENTATION P o o a 0 CONSISTENCY,SOIL STRUCTURE, MINERALOGY SAND(SP) DP-7 48 0 light tan,wet,loose,fine grained. 33.0 -medium grained. 35 DP-8 0 37.0 DP-9 0 40 40.0 End of Boring Log at 40'bgs Boring drilled to 40.0'bgs to set well. Abbreviations: bgs-below ground surface DP-Direct Push ft-feet HA-Hand Auger PID-Photo Ionization Detector 45 PPM-parts per million 50 55 60 63 PROJECT NUMBER: BORING NUMBER: 425128.PT.PT MW56-30 SHEET 1 OF 2 CH2MHILL .� Soil Boring Log CLIENT:NAVFAC PROJECT: SWMU 350 Naphthalene Biosparging Treatability Study LOCATION:MCIEAST-MCB CAMLEJ,North Carolina ELEVATION:26.90 ft above sea level DRILLING CONTRACTOR:Parratt-Wolff Inc.,Hillsborough,NC EAST.NORTH(UTM Z18 NAD83.feet):928348.72,12620968.80 DRILLING METHOD AND EQUIPMENT: HSA&Macrocore DPT WATER LEVEL:10.63 ft BTOC 4/18/2013 START:4/15/2013 END:4/15/2013 LOGGER:J.Hi h/CLT L SOIL DESCRIPTION COMMENTS WELL o z o SOIL NAME,USCS GROUP SYMBOL, DIAGRAM M vi a a O r = MOISTURE CONTENT,RELATIVE DEPTH OF CASING,DRILLING Surface a Z vLu 2 z v w M a a DENSITY OR RATE,DRILLING FLUID LOSS, Completion: Lu o TESTS,&INSTRUMENTATION P o o a c� CONSISTENCY,SOIL STRUCTURE, MINERALOGY SOIL(OL) Black,loose,organic,some sand. HA-1 0 4.0 SILTY SAND(SM) 5 light gray,dry to damp,loose,fine grained. DP-1 48 0 CLAYEY SAND(SC) light gray,dry to damp,fine grained. X CLAYEY SAND(SC) Light gray with brown streaking,moist, 10 fine grained. KEE— DP-2 24 0 -clay lens at 9 ft. 12.0 DP-3 36 0 15 SAND(SP) light gray,wet,soft,fine grained. 16.0 SILTY SAND(SM) light gray,wet,loose. DP-4 36 0 SANDY CLAY(SC) light gray/green,wet,loose. SAND(SP) 20 20.0 light gray,wet,loose,fine to medium grained. DP-5 36 0 \24.O 25 DP-6 48 0 X28.0 30 DP-7 36 0 64 PROJECT NUMBER: BORING NUMBER: 425128.PT.PT MW56-30 SHEET 2 OF 2 CH2MHILL .� Soil Boring Log CLIENT:NAVFAC PROJECT: SWMU 350 Naphthalene Biosparging Treatability Study LOCATION:MCIEAST-MCB CAMLEJ,North Carolina ELEVATION:26.90 ft above sea level DRILLING CONTRACTOR:Parratt-Wolff Inc.,Hillsborough,NC EAST.NORTH(UTM Z18 NAD83.feet):928348.72,12620968.80 DRILLING METHOD AND EQUIPMENT: HSA&Macrocore DPT WATER LEVEL:10.63 ft BTOC 4/18/2013 START:4/15/2013 END:4/15/2013 LOGGER:J.Hi h/CLT L SOIL DESCRIPTION COMMENTS WELL o Z o SOIL NAME,USCS GROUP SYMBOL, DIAGRAM M vi a a O r = MOISTURE CONTENT,RELATIVE DEPTH OF CASING,DRILLING Surface a Z v z v w M a a DENSITY OR RATE,DRILLING FLUID LOSS, Completion: L v o TESTS,&INSTRUMENTATION P o o a c� CONSISTENCY,SOIL STRUCTURE, MINERALOGY 32.0 End of Boring Log at 32'bgs Boring drilled to 32.0'bgs to set well. Abbreviations: bgs-below ground surface 35 DP-Direct Push ft-feet HA-Hand Auger PID-Photo Ionization Detector PPM-parts per million 40 45 50 55 60 65 PROJECT NUMBER: BORING NUMBER: 425128.PT.PT MW57-30 SHEET 1 OF 2 CH2MHILL Soil Boring Log CLIENT:NAVFAC PROJECT: SWMU 350 Naphthalene Biosparging Treatability Study LOCATION:MCIEAST-MCB CAMLEJ,North Carolina ELEVATION:26.28 ft above sea level DRILLING CONTRACTOR:Parratt-Wolff Inc.,Hillsborough,NC EAST.NORTH(UTM Z18 NAD83.feet):928348.72,12620966.40 DRILLING METHOD AND EQUIPMENT: HSA&Macrocore DPT WATER LEVEL:10.15 ft BTOC 4/17/2013 START:4/10/2013 END:4/10/2013 LOGGER:B.Pro st/CLT L SOIL DESCRIPTION COMMENTS WELL o z o SOIL NAME,USCS GROUP SYMBOL, DIAGRAM m vi a a O r = MOISTURE CONTENT,RELATIVE DEPTH OF CASING,DRILLING Surface a Z vLu 2 z v w a a DENSITY OR RATE,DRILLING FLUID LOSS, Completion: Lu o TESTS,&INSTRUMENTATION P o o a c� CONSISTENCY,SOIL STRUCTURE, MINERALOGY SOIL(OL) Black,dry,loose,organic. SILTY SAND(SM) HA-1 light gray,dry to damp,loose,fine grained. 5 5.0 -moist,medium dense. DP-1 48 0 CLAYEY SAND(SCE x light gray,dense,fine grained. SANDY CLAY(CL) 10 light gray,hard,low plasticity. DP-2 36 0 CLAYEY SAND(SC) light gray,wet,soft,fine to medium grained. 13.0 SILTY SAND(SMI light gray,wet,soft,fine grained. No Recovery. 15 DP-3 24 0 SAND(SP) light tan,wet,loose,fine grained. 17.0 SILTY SAND(SM) light tan,wet,loose,fine grained. DP-4 48 0 20 SAND(SP) 21.0 light tan,wet,loose,fine grained. DP-5 24 0 25 25.0 DP-6 24 0 \29.O 30 66 PROJECT NUMBER: BORING NUMBER: 425128.PT.PT MW57-30 SHEET 2 OF 2 CH2MHILL Soil Boring Log CLIENT:NAVFAC PROJECT: SWMU 350 Naphthalene Biosparging Treatability Study LOCATION:MCIEAST-MCB CAMLEJ,North Carolina ELEVATION:26.28 ft above sea level DRILLING CONTRACTOR:Parratt-Wolff Inc.,Hillsborough,NC EAST.NORTH(UTM Z18 NAD83.feet):928348.72,12620966.40 DRILLING METHOD AND EQUIPMENT: HSA&Macrocore DPT WATER LEVEL:10.15 ft BTOC 4/17/2013 START:4/10/2013 END:4/10/2013 LOGGER:B.Pro st/CLT L SOIL DESCRIPTION COMMENTS WELL o Z o SOIL NAME,USCS GROUP SYMBOL, DIAGRAM m vi a a O r = MOISTURE CONTENT,RELATIVE DEPTH OF CASING,DRILLING Surface Lu a Z v z v w a a DENSITY OR RATE,DRILLING FLUID LOSS, Completion: Lu o TESTS,&INSTRUMENTATION P o o a c� CONSISTENCY,SOIL STRUCTURE, MINERALOGY DP-7 36 0 SAND(SP) light tan,wet,loose,fine grained. 2.0 End of Boring Log at 32'bgs Boring drilled to 32.0'bgs to set well. Abbreviations: bgs-below ground surface 35 DP-Direct Push ft-feet HA-Hand Auger PID-Photo Ionization Detector PPM-parts per million 40 45 50 55 60 67 Attachment 3 Piping and Instrumentation Diagram 68 Fil To SWMU35O-IW55-40 P Area A Pressure Gauge Flow Meter Check Valve Globe Valve Stainless steel, Dwyer model (Brass) (Brass) liquid filled, UV-B112 0-30 PSI FI To SWMU350-IW56-40 P Pressure Gauge Flow Meter Check Valve Globe Valve Stainless steel, Dwyer model (Brass) (Brass) liquid filled, UV-B112 0-30 PSI FI To SWMU350-IW57-25 FI P P Pressure Gauge Flow Meter Check Valve Pressure Pressure Flow Meter Globe Valve Regulator Globe Valve Stainless steel, Dwyer model (Brass) Gauge Dwyer (Brass) liquid filled, UV-B112 0-30 PSI RotaOirCompressor Kaeser BSD-50 FI To SWMU350-IW57-40 (50 hp, 83 full load amps) P 460V/3-phase/60Hz, Area B Pressure Gauge Flow Meter Check Valve air-cooled, Globe Valve Stainless steel, Dwyer model (Brass) 125 PSIG max. pressure (Brass) liquid filled, UV-13112 0-30 PSI FI To SWMU350-IW58-25 P Pressure Gauge Flow Meter Check Valve Globe Valve Stainless steel, Dwyer model (Brass) (Brass) liquid filled, UV-13112 0-30 PSI Closeup of Biosparging 2" SCI1 80 PVC F, To SWMU35O-IW58-40 I IiREADED PLUG Wellhead Connection Pressure Gauge Flow Meter Check Valve -�- Globe Valve Stainless steel, D (Brass) Dwyer model (Brass) liquid filled, UV-B112 ,,-1.5 x1' SCH 80 PVC REDUCER BUSHI%G 0-30 PSI 1" ID HIGH-PRESSURE 2" SCf i 80 PVC // HOSE (COMPRESSED AIR) FEMALE ADAPTER C 2"x1"x2" SCI1 80 PVC TEE 2"AIR SPARGE WELL —' ATTACHMENT 3 Piping and Instrumentation Diagram 1"ALUMINUM NP1 SWMU 350 Naphthalene Biosparging HOSE BARB Treatability Study GROUND SURFACE — MCIEAST-MCB CAMLEJ North Carolina 11111111110 CH2MHILL:. 69 Attachment 4 Raw Groundwater Analytical Data 70 ATTACHMENT 4 Raw Groundwater Analytical Results SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLEJ,North Carolina Station ID SWMU350-MW03 SWMU350-MW04 SWMU350-MW05 Sample ID SWMU350-GW03-13B-1 SWMU350-GW03-13B-2 SWMU350-GW03-13C SWMU350-GW03-13D SWMU350-GW04-13B-1 SWMU350-GW04-13B-2 SWMU350-GW04-13C SWMU350-GW04-13D SWMU350-GW05-13B-1 SWMU350-GW05-13B-2 SWMU350-GW05-13C SWMU350-GWOSI3D Sample Date 04/23/13 06/27/13 08/28/13 11/12/13 04/23/13 06/27/13 08/28/13 11/12/13 04/22/13 06/28/13 08/27/13 11/12/13 Chemical Name Volatile Organic Compounds(UG/L) 1,1,1-Trichloroethane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,1,2,2-Tetrachloroethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,1,2-Trichloro-1,2,24rifluoroethane(Freon-1 13) 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,1,2-Trichloroethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,1-Dichloroethane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,1-Dichloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,2,4-Trichlorobenzene 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 1,2-Dibromo-3-chloropropane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,2-Dibromoethane 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1,2-Dichlorobenzene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,2-Dichloroethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,2-Dichloropropane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,3-Dichlorobenzene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,4-Dichlorobenzene 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 2-Butanone 2U 2U 2U 2U 2U 2U 2U 2U 2U 2U 2U 2U 2-Hexanone 2UJ 2U 2U 2U 2UJ 2U 2U 2U 2UJ 2U 2U 2U -Methyl-2-pentanone 2 UJ 2 U 2 U 2 U 2 UJ 2 U 2 U 2 U 2 UJ 2 U 2 U 2 U Acetone 2UJ 2U 2U 2UJ 2UJ 2U 2U 2UJ 2UJ 2U 2U 2UJ Benzene 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Bromodichloromethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Bromoform 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Bromomethane 1U 1U 1U 1UJ 1U 1U 1U 1UJ 1U 1U 1U 1UJ Carbon disulfide 1 U 1 U 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 1 UJ 1 U Carbon tetrachloride 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Chlorobenzene 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Chloroethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Chloroform 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Chloromethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U cis-1,2-Dichloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U cis-1,3-Dichloropropene 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U Cyclohexane 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Dibromochloromethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Dichlorodifluoromethane(Freon-12) 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Ethylbenzene 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Isopropylbenzene 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U m-and p-Xylene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Methyl acetate 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Methylcyclohexane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Methylene chloride 1 UJ 1 U 1 U 1 UJ 1 UJ 1 U 1 U 1 UJ 1 UJ 1 U 1 U 1 UJ Methyl-ten-butyl ether(MTBE) 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U o-Xylene 1UJ 1U 1U 1U 1UJ 1U 1U 1U 1UJ 1U 1U 1U Styrene 0.5 UJ 0.5U 0.5U 0.5 UJ 0.5 UJ 0.5U 0.5U 0.5 UJ 0.5 UJ 0.5U 0.5U 0.5 UJ Tetrachloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Toluene 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 0.31J trans-1,2-Dichloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U trans-1,3-Dichloropropene 0.5 UJ 0.5 U 0.5 U 0.5 U 0.5 UJ 0.5 U 0.5 U 0.5 U 0.5 UJ 0.5 U 0.5 U 0.5 U Trichloroethene 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Trichlorofluoromethane(Freon-1 1) 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U Vinyl chloride 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Xylene,total 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U Semivolatile Organic Compounds(UG/L) Naphthalene 1 UJ 1 U 1 U 1 U 56 J 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U Wet Chemistry(MG/L) Ammonia 0.011 J 0.01 U 0.01 U 0.01 U 0.0089 J 0.01 U 0.01 U 0.01 U NA NA NA NA Nitrate 0.05 U 0.05 U 0.028 J 0.02 J 0.37 0.54 0.78 0.77 NA NA NA NA Nitrite 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U NA NA NA NA Orthophosphate 0.00562 J 0.0111 0.00607 J 0.00549 J 0.00776 J 0.01 U 0.01 U 0.01 U NA NA NA NA Sulfate 16 16 13 14 13 11 14 29 NA NA NA NA Functioning Genes(CELLS/ML) Napthalene Dioxygenase 55,200 99,600 39.3 40.8 606,000 83,200 156 97.9 NA NA NA NA Notes: Shading indicates detections NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantitation limit may be inaccurate CELLS/ML-Cells per milliliter MG/L-Milligrams per liter UG/L-Micrograms per liter Page 1 of 5 71 ATTACHMENT 4 Raw Groundwater Analytical Results SWMU 350 Naphthalene Biosparging Treatability Stud MC/EAST-MCB CAMLEJ,North Carolina Station ID SWMU350-MWO6 SWMU350-MW11 SWMU350-MW12 Sample ID SWMU350-GW06-13B-1 SWMU350-GW06D-13B-1 SWMU350-GW06-13B-2 SWMU350-GW06-13C SWMU350-GW06-13D SWMU350-GW11-13B-1 SWMU350-GW11-13B-2 SWMU350-GW11-13C SWMU350-GW11-13D SWMU350-GW12-13B-1 SWMU350-GW12D-13B-1 SWMU350-GW12-13B-2 SWMU350-GW12-13C SWMU350-GW12-13D Sample Date 04/22/13 04/22/13 06/28/13 08/27/13 11/12/13 04/22/13 06/28/13 08/27/13 11/12/13 04/22/13 04/22/13 06/28/13 08/27/13 11/12/13 Chemical Name Volatile Organic Compounds(UG/L) 1,1,1-Trichloroethane 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1,1,2,2-Tetrachloroethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,1,2-Trichloro-1,2,24rifluoroethane(Freon-113) 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,1,2-Trichloroethane 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 1,1-Dichloroethane 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1,1-Dichloroethene 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 1,2,4-Trichlorobenzene 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 1,2-Dibromo-3-chloropropane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,2-Dibromoethane 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1,2-Dichlorobenzene 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 1,2-Dichloroethane 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 1,2-Dichloropropane 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 1,3-Dichlorobenzene 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 1,4-Dichlorobenzene 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 2-Butanone 2U 2U 2U 2U 2U 2U 2U 2U 2U 2U 2U 2U 2U 2U 2-Hexanone 2UJ 2UJ 2U 2U 2U 2UJ 2U 2U 2U 2UJ 2UJ 2U 2U 2U -Methyl-2-pentanone 2 UJ 2 UJ 2 U 2 U 2 U 2 UJ 2 U 2 U 2 U 2 UJ 2 UJ 2 U 2 U 2 U Acetone 2UJ 2UJ 2U 2U 2UJ 2UJ 2U 2U 2UJ 2UJ 2UJ 2U 2U 2UJ Benzene 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Bromodichloromethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Bromoform 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Bromomethane 1U 1U 1U 1U 1UJ 1U 1U 1U 1UJ 1U 1U 1U 1U 1UJ Carbon disulfide 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 1 U 1 UJ 1 U Carbon tetrachloride 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Chlorobenzene 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Chloroethane 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Chloroform 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Chloromethane 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.26J 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U cis-1,2-Dichloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U cis-1,3-Dichloropropene 1 UJ 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 1 UJ 1 UJ 1 U 1 U 1 U Cyclohexane 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Dibromochloromethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Dichlorodifluoromethane(Freon-12) 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Ethylbenzene 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Isopropylbenzene 1 UJ 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 1 UJ 1 UJ 1 U 1 U 1 U m-andp-Xylene 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Methyl acetate 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Methylcyclohexane 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Methylene chloride 1 UJ 1 UJ 1 U 1 U 1 UJ 1 UJ 1 U 1 U 1 UJ 1 UJ 1 UJ 1 U 1 U 1 UJ Methyl-tert-butyl ether(MTBE) 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U o-Xylene 1UJ 1UJ 1U 1U 1U 1UJ 1U 1U 1U 1UJ 1UJ 1U 1U 1U Styrene 0.5 UJ 0.5 UJ 0.5U 0.5U 0.5 UJ 0.5 UJ 0.5U 0.5U 0.5 UJ 0.5 UJ 0.5 UJ 0.5U 0.5U 0.5 UJ Tetrachloroethene 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Toluene 1U 1U 1U 1U 0.29J 1U 1U 1U 1U 1U 1U 1U 1U 1U trans-1,2-Dichloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U trans-1,3-Dichloropropene 0.5 UJ 0.5 UJ 0.5 U 0.5 U 0.5 U 0.5 UJ 0.5 U 0.5 U 0.5 U 0.5 UJ 0.5 UJ 0.5 U 0.5 U 0.5 U Trichloroethene 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Trichlorofluoromethane(Freon-1 1) 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U Vinyl chloride 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Xylene,total 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U Semivolatile Organic Compounds(UG/L) Naphthalene 1 UJ 1 U 1 U 1 U 1 U 1 U 1 U Wet Chemistry(MG/L) Ammonia NA NA NA NA NA NA NA NA NA NA NA NA NA NA Nitrate NA NA NA NA NA NA NA NA NA NA NA NA NA NA Nitrite NA NA NA NA NA NA NA NA NA NA NA NA NA NA Orthophosphate NA NA NA NA NA NA NA NA NA NA NA NA NA NA Sulfate NA NA NA NA NA NA NA NA NA NA NA NA NA NA Functioning Genes(CELLS/ML) Napthalene Dioxygenase NA NA NA NA NA NA NA NA NA NA NA NA NA NA Notes: Shading indicates detections NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantitation limit may be inaccurate CELLS/ML-Cells per milliliter MG/L-Milligrams per liter UG/L-Micrograms per liter Page 2 of 5 72 ATTACHMENT 4 Raw Groundwater Analytical Results SWMU 350 Naphthalene Biosparging Treatability Stud MC/EAST-MCB CAMLEJ,North Carolina Station ID SWMU350-MW15 SWMU350-MW15-30 Sample ID SWMU350-GW15-13B-1 SWMU350-GW15-13B-2 SWMU350-GW15-13C SWMU350-GW15-13D SWMU350-GW15-30-13B-1 SWMU350-GW15-30-13B-2 SWMU350-GW15-30D-13B-2 SWMU350-GW15-30-13C SWMU350-GW15-30D-13C SWMU350-GW15-30-13D SWMU350-GW15-30D-13D Sample Date 04/23/13 06/27/13 08/28/13 11/12/13 04/23/13 06/27/13 06/27/13 08/28/13 08/28/13 11/12/13 11/12/13 Chemical Name Volatile Organic Compounds(UG/L) 1,1,1-Trichloroethane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,1,2,2-Tetrachloroethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,1,2-Trichloro-1,2,24rifluoroethane(Freon-113) 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,1,2-Trichloroethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,1-Dichloroethane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,1-Dichloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,2,4-Trichlorobenzene 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 1,2-Dibromo-3-chloropropane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,2-Dibromoethane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,2-Dichlorobenzene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,2-Dichloroethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,2-Dichloropropane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,3-Dichlorobenzene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,4-Dichlorobenzene 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 2-Butanone 2U 2U 2U 2U 2U 2U 2U 2U 2U 2U 2U 2-Hexanone 2UJ 2U 2U 2U 2UJ 2U 2U 2U 2U 2U 2U -Methyl-2-pentanone 2 UJ 2 U 2 U 2 U 2 UJ 2 U 2 U 2 U 2 U 2 U 2 U Acetone 2UJ 2U 2U 2UJ 2UJ 2U 2U 2U 2U 2UJ 2UJ Benzene 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Bromodichloromethane 0.5 U 0.5 UJ 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Bromoform 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Bromomethane 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 1 U 1 U 1 UJ 1 UJ Carbon disulfide 1 U 1 U 1 UJ 1 U 1 U 1 U 1 U 1 UJ 1 UJ 1 U 1 U Carbon tetrachloride 1 U 1 UJ 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Chlorobenzene 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Chloroethane 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Chloroform 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Chloromethane 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U cis-1,2-Dichloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U cis-1,3-Dichloropropene 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 1 U 1 U 1 U Cyclohexane 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Dibromochloromethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Dichlorodifluoromethane(Freon-12) 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Ethylbenzene 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Isopropylbenzene 1.7 J 1 U 1 U 1 U 0.96 J 1 U 1 U 1 U 1 U 1 U 1 U m-andp-Xylene 3.7 0.5U 0.5U 0.5U 0.52J 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Methyl acetate 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Methylcyclohexane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Methylene chloride 1 UJ 1 U 1 U 1 UJ 1 UJ 1 U 1 U 1 U 1 U 1 UJ 1 UJ Methyl-tert-butyl ether(MTBE) 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U o-Xylene 7.6J 1U 1U 1U 0.69J 1U 1U 1U 1U 1U 1U Styrene 0.5 UJ 0.5U 0.5U 0.5U 0.5 UJ 0.5U 0.5U 0.5U 0.5U 0.5 UJ 0.5 UJ Tetrachloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Toluene 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U trans-1,2-Dichloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U trans-1,3-Dichloropropene 0.5 UJ 0.5 U 0.5 U 0.5 U 0.5 UJ 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Trichloroethene 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Trichlorofluoromethane(Freon-1 1) 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U Vinyl chloride 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Xylene,total 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U Semivolatile Organic Compounds(UG/L) Naphthalene 170 J 1 U 1 U 0000001111 64 J 1 U 1 U 1 U 1 U 1 U 1 U Wet Chemistry(MG/L) Ammonia 0.092 0.01 U 0.01 U 0.0065 J 0.048 J 0.01 U NA 0.015 J NA 0.01 U NA Nitrate 0.05 U 0.27 0.034 J 0.037 J 0.05 U 0.48 NA 0.46 NA 0.46 NA Nitrite 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U NA 0.05 U NA 0.05 U NA Orthophosphate 0.01 U 0.00943 J 0.0495 0.01 U 0.00466 J 0.01 U NA 0.01 U NA 0.01 U NA Sulfate 26 18 19 19 12 7.2 NA 5.7 NA 6.8 NA Functioning Genes(CELLS/ML) Napthalene Dioxygenase 102,000 1 6,190 1 280 49.5 1 56,400 440,000 1 NA 16,700 NA 1,080 NA Notes: Shading indicates detections NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantitation limit may be inaccurate CELLS/ML-Cells per milliliter MG/L-Milligrams per liter UG/L-Micrograms per liter Page 3 of 5 73 ATTACHMENT 4 Raw Groundwater Analytical Results SWMU 350 Naphthalene Biosparging Treatability Stud MC/EAST-MCB CAMLEJ,North Carolina Station ID SWMU350-MW15-55 SWMU350-MW56-15 SWMU350-MW56-30 Sample ID SWMU350-GW15-55-1313-1 SWMU350-GW15-55-13B-2 SWMU350-GW15-55-13C SWMU350-GW15-55-13D SWMU350-GW56-15-13B-1 SWMU350-GW56-15-13B-2 SWMU350-GW56-15-13C SWMU350-GW56-15-13D SWMU350-GW56-30-13B-1 SWMU350-GW56-30-13B-2 SWMU350-GW56-30D-13B-2 SWMU350-GW56-30-13C Sample Date 04/23/13 06/28/13 08/27/13 11/12/13 04/23/13 06/27/13 08/28/13 11/12113 04/23/13 06/27/13 06/27/13 08/28/13 Chemical Name Volatile Organic Compounds(UG/L) 1,1,1-Trichloroethane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,1,2,2-Tetrachloroethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,1,2-Trichloro-1,2,24rifluoroethane(Freon-1 13) 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,1,2-Trichloroethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,1-Dichloroethane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,1-Dichloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,2,4-Trichlorobenzene 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 1,2-Dibromo-3-chloropropane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,2-Dibromoethane 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1,2-Dichlorobenzene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,2-Dichloroethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,2-Dichloropropane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,3-Dichlorobenzene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,4-Dichlorobenzene 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 2-Butanone 2U 2U 2U 2U 2U 2U 2U 2U 2U 2U 2U 2U 2-Hexanone 2UJ 2U 2U 2U 2UJ 2U 2U 2U 2UJ 2U 2U 2U -Methyl-2-pentanone 2 UJ 2 U 2 U 2 U 2 UJ 2 U 2 U 2 U 2 UJ 2 U 2 U 2 U Acetone 2UJ 2U 2.7J 2UJ 2UJ 2U 2U 2UJ 2UJ 2U 2U 2U Benzene 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Bromodichloromethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Bromoform 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Bromomethane 1U 1U 1U 1UJ 1U 1U 1U 1UJ 1U 1U 1U 1U Carbon disulfide 1 U 1 U 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 1 U 1 UJ Carbon tetrachloride 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Chlorobenzene 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Chloroethane 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Chloroform 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Chloromethane 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U cis-1,2-Dichloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U cis-1,3-Dichloropropene 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U Cyclohexane 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Dibromochloromethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Dichlorodifluoromethane(Freon-12) 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Ethylbenzene 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Isopropylbenzene 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U m-andp-Xylene 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Methyl acetate 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Methylcyclohexane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Methylene chloride 1 UJ 1 U 1 U 1 UJ 1 UJ 1 U 1 U 1 UJ 1 UJ 1 U 1 U 1 U Methyl-tert-butyl ether(MTBE) 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U o-Xylene 1UJ 1U 1U 1U 1UJ 1U 1U 1U 1UJ 1U 1U 1U Styrene 0.5 UJ 0.5U 0.5U 0.5 UJ 0.5 UJ 0.5U 0.5U 0.5 UJ 0.5 UJ 0.5U 0.5U 0.5U Tetrachloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Toluene 1U 1U 1U 0. 1U 1U 1U 1U 1U 1U 1U 1U trans-1,2-Dichloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U trans-1,3-Dichloropropene 0.5 UJ 0.5 U 0.5 U 0.5 U 0.5 UJ 0.5 U 0.5 U 0.5 U 0.5 UJ 0.5 U 0.5 U 0.5 U Trichloroethene 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Trichlorofluoromethane(Freon-1 1) 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U Vinyl chloride 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Xylene,total 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U 1.5 U Semivolatile Organic Compounds(UG/L) Naphthalene 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 22 J 1 U 1 U 1 U Wet Chemistry(MG/L) Ammonia NA NA NA NA 0.019 J 0.01 U 0.01 U 0.01 U 0.03 J 0.01 U NA 0.014 J Nitrate NA NA NA NA 0.05 U 0.05 U 0.023 J 0.021 J 0.13 0.44 NA 0.33 Nitrite NA NA NA NA 0.05 U 0.05 U 0.05 U 0.05 U 0.024 J 0.05 U NA 0.05 U Orthophosphate NA NA NA NA 0.00576 J 0.0088 0.00773 J 0.00602 J 0.00574 J 0.01 U NA 0.01 U Sulfate NA NA NA NA 13 10 10 13 15 7.8 NA 6.7 Functioning Genes(CELLS/ML) Napthalene Dioxygenase NA I NA I NA I NA 1 656 1 215 1 17.2 1 5 U 1 98,000 1 29,600 1 NA 83.3 Notes: Shading indicates detections NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantitation limit may be inaccurate CELLS/ML-Cells per milliliter MG/L-Milligrams per liter UG/L-Micrograms per liter Page 4 of 5 74 ATTACHMENT 4 Raw Groundwater Analytical Results SWMU 350 Naphthalene Biosparging Treatability Stud MC/EAST-MCB CAMLEJ,North Carolina Station ID SWMU350-MW56-30 SWMU350-MW57-15 SWMU350-MW57-30 Sample ID SWMU350-GW56-30-13D SWMU350-GW56-30D-13D SWMU350-GW57-15-13B-1 SWMU350-GW57-15-13B-2 SWMU350-GW57-15-13C SWMU350-GW57-15-13D SWMU350-GW57-30-13B-1 SWMU350-GW57-30-13B-2 SWMU350-GW57-30-13C SWMU350-GW57-30-13D Sample Date 11/12/13 11/12/13 04/23/13 06/27/13 08/28/13 11/12/13 04/23/13 06/27/13 08/28/13 11/12/13 Chemical Name Volatile Organic Compounds(UG/L) 1,1,1-Trichloroethane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,1,2,2-Tetrachloroethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,1,2-Trichloro-1,2,24rifluoroethane(Freon-113) 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,1,2-Trichloroethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,1-Dichloroethane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,1-Dichloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,2,4-Trichlorobenzene 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 1,2-Dibromo-3-chloropropane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,2-Dibromoethane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1,2-Dichlorobenzene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,2-Dichloroethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,2-Dichloropropane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,3-Dichlorobenzene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 1,4-Dichlorobenzene 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 2-Butanone 2U 2U 2U 2U 2U 2U 2U 2U 2U 2U 2-Hexanone 2 U 2 U 2 UJ 2 U 2 U 2 U 2 UJ 2 U 2 U 2 U -Methyl-2-pentanone 2 U 2 U 2 UJ 2 U 2 U 2 U 2 UJ 2 U 2 U 2 U Acetone 2 UJ 2 UJ 2 UJ 2 U 2 U 2 UJ 2 UJ 2 U 2 U 2 UJ Benzene 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Bromodichloromethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Bromoform 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Bromomethane 1 UJ 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U 1 UJ Carbon disulfide 1 U 1 U 1 U 1 U 1 UJ 1 U 0.33 J 1 U 1 UJ 1 U Carbon tetrachloride 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Chlorobenzene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Chloroethane 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Chloroform 1U 1U 1U 1U 1U 1U 0.87J 1U 1U 1U Chloromethane 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U cis-1,2-Dichloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U cis-1,3-Dichloropropene 1 U 1 U 1 UJ 1 U 1 U 1 U 1 UJ 1 U 1 U 1 U Cyclohexane 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U Dibromochloromethane 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Dichlorodifluoromethane(Freon-12) 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Ethylbenzene 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Isopropylbenzene 1 U 1 U 1 UJ 1 U 1 U 1 U 0.94 J 1 U 1 U 1 U m-andp-Xylene 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Methyl acetate 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Methylcyclohexane 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Methylene chloride 1 UJ 1 UJ 1 UJ 1 U 1 U 1 UJ 1 UJ 1 U 1 U 1 UJ Methyl-tert-butyl ether(MTBE) 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U o-Xylene 1U 1U 1UJ 1U 1U 1U 0.4J 1U 1U 1U Styrene 0.5 UJ 0.5 UJ 0.5 UJ 0.5U 0.5U 0.5 UJ 0.5 UJ 0.5U 0.5U 0.5 UJ Tetrachloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U Toluene 1U 1U 1U 1U 1U 1U 1U 1U 1U 1U trans-1,2-Dichloroethene 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U 0.5 U trans-1,3-Dichloropropene 0.5 U 0.5 U 0.5 UJ 0.5 U 0.5 U 0.5 U 0.5 UJ 0.5 U 0.5 U 0.5 U Trichloroethene 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U 1 U Trichlorofluoromethane(Freon-1 1) 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U Vinyl chloride 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U 0.5U Xylene,total 1.5U 1.5U 1.5U 1.5U 1.5U 1.5U 0.63J 1.5U 1.5U 1.5U Semivolatile Organic Compounds(UG/L) Naphthalene 1 U 1 U 1 UJ 1 U 1 U 1 U 16 J 1 U 1 U 1 U Wet Chemistry(MG/L) Ammonia 0.01 U NA 0.032 J 0.014 J 0.01 U 0.01 U 0.12 0.01 U 0.01 U 0.01 U Nitrate 0.24 NA 0.05 U 0.066 J 0.87 0.35 0.021 J 0.31 0.2 0.37 Nitrite 0.05 U NA 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U Orthophosphate 0.01 U NA 0.00983 J 0.0524 0.0187 0.0235 0.00673 J 0.01 U 0.01 U 0.01 U Sulfate 6.9 NA 19 19 17 19 15 7.6 5.7 5.5 Functioning Genes(CELLS/ML) Napthalene Dioxygenase 251 NA 41,600 404 862 3.6 J 94,800 27,200 16.7 28.5 Notes: Shading indicates detections NA-Not analyzed J-Analyte present,value mayor may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantitation limit may be inaccurate CELLS/ML-Cells per milliliter MG/L-Milligrams per liter UG/L-Micrograms per liter Page 5 of 5 75 Attachment 5 Data Logging Trend Graphs 76 Area A - Deep Biosparging Wells MW03 15 feet from IW55-40 & IW56-40 18 20 16 16 12 14 a 8 1 J 2 � dA 4 s U 0 a0uo 0 +� �. ca O 8 v M -4 w 0 6 ca 0 -8 4 -12 2 16 0 -20 QIP Date ATTACHMENT 5 Data Logging Trend Graphs DO (mg/L) pH SWMU 350 Naphthalene Biosparging Treatability Study System Startup Water Level (feet) MC/EAST-MCB CAMLE✓, North Carolina v� tP2RA1;II I Page 1 of 8 77 Area A - Deep Biosparging Wells MW04 15 feet from IW55-40 & IW56-40 18 20 16 — 16 14 12 2 � CL 8 v _` hA 12 = E s 4 V c = v 10 C an +.� co x 0 > O ai M 8 W > -4 6 — -8 4 -12 2 -16 0 — -20 115 Date ATTACHMENT 5 DO (mg/L) pH Data Logging Trend Graphs SWMU 350 Naphthalene Biosparging Treatability Study System Startup Water Level (feet) MC/EAST-MCB CAMLEJ, North Carolina th CH2MHILL. Ow Page 2 of 8 78 Area A - Deep Biosparging Wells MW56-15 7.5 feet from IW56-40 & 25 feet from IW56-40 18 20 16 16 12 14 2 � 8 12 - an � 4 s r_ 10 u O 0 ; 0 8 v W > -4 L v 6 -8 4 -12 2 -16 0 -20 Date ATTACHMENTS DO (mg/L) pH Data Logging Trend Graphs SWMU 350 Naphthalene Biosparging Treatability Study System Startup Water Level (feet) MC/EAST-MCB CAMLE✓, North Carolina CH2M1-ill l Page 3 of 8 79 Area A - Deep Biosparging Wells MW56-30 7.5 feet from IW56-40 & 25 feet from IW56-40 18 20 16 15 a 14 10 J � E 12 5 s � U G1 C T 10 C x O 0 > M v 9 8 W L 0 0 -5 tea 6 -10 4 2 -15 0 — - -20 Date ATTACHMENT DO (mg/L) pH Data Logging Trend Graphs System Startup Water Level (feet) SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLE✓, North Carolina C11-112M1-ill l Page 4of8 80 Area B - Nested Biosparging Wells MW15-15 5.5 feet from IW57 & 22 feet from IW58 18 - 20 16 16 y 2 v 12 bb 14 = J � taA 8 U 12 0 r o T4 xx 10 W i 0 W cu cu fa O $ -4 6 -8 4 - -12 2 -16 0 -20 Date ATTACHMENT DO (mg/L) pH Data Logging Trend Graphs SWMU 350 Naphthalene Biosparging Treatability Study System Startup Water Level (feet) MC/EAST-MCB CAMLE✓, North Carolina C11-112M1-ill l Page 5 of 8 81 Area B - Nested MW15-30 7.5 feet from IW57 & 27 feet from IW58 18 20 16 16 12 14 2 v 8 v 12 = E 4 s U 10 0 x 0 co O 8 a>i 0 W cu -4 O *' 6 to p -8 4 — — -12 2 -16 0 - - -20 oti3 oti3 oti3 Date ATTACHMENT 5 DO (mg/L) pH Data Logging Trend Graphs SWMU 350 Naphthalene Biosparging Treatability Study System Startup Water Level (feet) MC/EAST-MCB CAMLE✓, North Carolina CH2M1-ill l Page 6 of 8 82 Area B - Nested MW57-15 20 feet from IW58 & 35 feet from IW57 14 20 16 12 ai ar = 12 Q as c J (p t 10 8 U C O cu 4+ b. 4 M X 8 N O W 0 ai aj 4a > cc O 6 - - -4 4 -8 -12 2 — -16 0 -20 Date ATTACHMENT 5 DO (mg/L) pH Data Logging Trend Graphs SWMU 350 Naphthalene Biosparging Treatability Study System Startup Water Level (feet) MC/EAST-MCB CAMLEJ, North Carolina Page 7 of 8 83 Area B - Nested MW57-30 20 feet from IW58 & 35 feet from IW57 18 20 16 15 = 14 s?. 10 a J1-1 v NO 12 Nt�A 5 c c s qOp 10 U O 0 +� 8 a>i v _ O W -5 6 +' An -10 4 2 -15 0 -20 Date ATTACHMENT 5 DO (mg/L) pH Data Logging Trend Graphs SWMU 350 Naphthalene Biosparging Treatability Study System Startup Water Level (feet) MC/EAST-MCB CAMLE✓, North Carolina C11-112M1-ill l Page 8 of 8 84 Attachment 6 Raw Soil Gas Analytical Data 85 ATTACHMENT 6 Raw Soil Gas Analytical Results SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCS CAMLEJ,North Carol- Station ID SWMU350-SG01 SWMU350-SG02 SWMU350-SG03 SWMU350-SG04 SWMU350-SG05 Sample ID SWMU350-SG0l-13B SWMU350-SG0l-13C SWMU350-SG0l-13D SWMU350-SG02-13B SWMU350-SG02D-13B SWMU350-SG02-13C SWMU350-SG02D-13C SWMU350-SG02-13D SWMU350-SG03-13B SWMU350-SG03-13D SWMU350-SG03D-13D SWMU350-SG04-13B SWMU350-SG04-13C SWMU350-SG04-13D SWMU350-SG05-13B SWMU350-SG05D-13B SWMU350-SG05-13D Sample Date 05/21/13 08/27/13 11/05/13 04/24/13 04/24/13 08/26/13 08/26/13 11/05/13 05/16/13 11/05/13 11/05/13 05/21/13 08/27/13 11/05/13 05/16/13 05/16/13 11/05/13 Chemical Name Volatile Organic Compounds(UGIM3) 1,1,1-Trichloroethane 0.16 U 0.76 J 0.16 U 0.16 U 0.16 U 0.16 U 0.27 J 0.16 U 0.16 U 0.16 U 0.16 U 0.16 tJ 0.16 U 0.16 U 0.16 U 0.16 U 1,1,2,2-Tetrachloroethane 0.69 U 0.69 U 0.69 U 34.3 J 0.69 U 0.69 U 0.69 U 0.69 U 0.69 U 0.69 U 0.69 U 0.69 U 0.69 U 0.69 U 0.69 U 0.69 U 1,1,2-Trichloro-1,2,24rifluoroethane(Freon-113) 0.69 J 0.84 J 0.77 J 0.77 J 0.77 J 0.77 U 0.77 J 0.77 U 0.61 J 0.61 J 0.69 J 0.84 J 0.69 J 0.77 J 0.54 J 0.77 J 1,1,2-Trichloroethane 0.55 U 0.55 U 0.55 U 0.55 U 0.55 U 0.55 U 0.55 U 0.55 U 0.55 U 0.55 U 0.55 U 0.55 U 0.55 U 0.55 U 0.55 U 0.55 U 0.55 U Dichloroethane 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 1,1-Dichloroethane 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 1,2,4-Trichlorobenzene 0.74 U 0.74 U 0.74 UJ 0.89 J 0.74 U 0.74 U 0.74 U 0.74 U 0.74 U 0.74 U 0.74 U 0.74 U 1.04 J 0.74 U 1,2,4-Trimethylbenzene 0.49 U 5.9 J 5.9 J 5.41 0.49 U 1.67 J 0.49 U 11.8 1,2-Dibromoethane 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 1,2-Dichlorobenzene 0.6U 0.6U 0.61 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 1,2-Dichloroethane 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 2.83 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 0.4U 11 2-Dichloropropane 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 76.7 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 1,2-Dichlorotetrafluoroethane(Freon-114) 0.7 U 0.7 U 0.7 U 0.7 U 0.7 U 0.7 U 0.7 U 0.7 U 0.7 U 0.7 U 0.7 U 0.7 U 0.7 U 0.7 U 0.7 U 0.7 U 0.7 U 1,3,5-Trimethylbenzene 1.92 J 0.49 U 0.49 U 6.39 J 4.62 J 2.11 J 0.49 U 0.69 J 0.49 UJ 0.79 J 1.33 J 2.85 0.54 J 0.49 U 4.92 0.49 U 1,3-Butadiene 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 1,3-Dichlorobenzene 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 1,4-Dichlorobenzene 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 0.6U 1,4-Dioxane 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U -Butanone 2.6 J 5.9 J 5.6 J 1.09 J 97.9 14.5 -Hexanone 0.65J 0.41 U 0.41 U 1.39J 1.23J 0.41 U 0.41 U 0.41 U 0.41 U 0.41 U 0.41 U 0.41 U 0.41 U 0.41 U 0.41 U 0.41 U 0.41 U -Propanol 33.2 0.25 U 43.8 J 13.0 J 14.0 J 4.92 2.41 29.7 84.1 32.5 J 65.9 J 5.65 8.85 53.1 73.3 J 59.0 J 10.8 -Ethyltoluene 0.49 U 0.49 U 0.49 U 0.49 U 0.49 U 0.49 U 0.49 U 0.49 U 9.83 0.49 UJ 0.54 J 0.49 U 0.49 U 0.49 U 0.49 U 0.49 U 0.49 U -Methyl-2-pentanone 0.41 U 0.86 J 0.45 J 0.49 J 5.33 0.53 J 1.64 J 21.3 0.7 J 2.05 J 0.41 U 1.64 J 0.41 U 0.41 U 1.35 J cetone 22.1 J 8.79 21.9 16.9 J 13.5 J 8.79 8.55 0.24 U 0.24 U 42.1 47.0 6.89 126 0.24 U 23.5 48.7 Benzene 3.19 J 0.35 J 0.61 J 0.38 J 0.26 J 0.22 J 0.32 J 13.7 0.73 J 1.18 J 1.02 J 1.63 1.88 Benzyl chloride 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U 0.52 U Bromodichloromethane 0.67 U 0.67 U 0.67 U 0.67 U 0.67 U 0.67 U 0.67 U 0.67 U 0.67 U 0.67 U 0.67 U 0.67 U 0.67 U 0.67 U 0.67 U 0.67 U 0.67 U Bromoform 1.03 U 1.03 U 1.03 U 1.03 U 1.03 U 1.03 U 1.03 U 1.03 U 1.03 U 1.03 U 1.03 U 1.03 U 1.03 U 1.03 U 1.03 U 1.03 U 1.03 U Bromomethane 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U Carbon disulfide 0.65 1 J 0.31 U 0.75 J 0.31 J 0.31 U 0. 0.31 U 0.31 U 0.31 U 0.31 J 0.31 U 0.31 U 0.31 U Carbon tetrachloride 0.19 U 0.19 U 0.19 U 0.19 1 0.19 U 0.19 U 0.19 U 0.19 U 0.19 U 0.19 U 0.19 U 0.19 U 0.19 U 0.19 U 0.19 U Chlorobenzene 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U 0.46 U Chloroethane 0.26 U 0.26 U 0.26 U 0.26 U 0.26 U 0.26 U 0.26 U 0.26 U 0.26 U 0.26 U 0.26 U 0.26 U 0.26 U 0.26 U 0.26 U 0.26 U 0.26 U Chloroform 2.78 J 3.96 J 0.49 U 0.49 U 0.49 U Chloromethane 0.21 U 0.21 U 0.78 J 0.58 J 1 J 0.21 U 0.89 J 0.21 J 1.28 0.5 J 0.43 J 0.21 U 0.21 U 0.74 J 0.21 U 0.21 U 0.4 cis-1,2-Dichloroethene 0.4 U 0.36 J 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U cis-1,3-Dichloropropane 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U Cyclohexane 0.72 J 0.55 J 0.89 J 0.52 J 0.41 J 0.48 J 0.34 U 0.34 U 175 1.24 J 1.72 0.41 J 0.79 J 1.76 0.34 U 0.76 J 0.93 J Dibromochloromethane 0.85 U 0.85 U 0.85 U 0.85 U 0.85 U 0.85 U 0.85 U 0.85 U 0.85 U 0.85 U 0.85 U 0.85 U 0.85 U 0.85 U 0.85 U 0.85 U 0.85 U Dichlorodifluoromethane(Freon-12) 0.59 J 1.04 J 2.08 J 0.54 J 0.54 J 1.09 J 1.29 J 1.14 J 0.69 J 1.63 J 1.78 J 0.64 J 0.84 J 1.78 J 0.59 J 0.49 U 2.23 J Ethyl acetate 0.4 U 2.02 0.4 U 0.4 U 0.4 U 2.86 1.03 J 10.3 129 48.4 57.9 0.4 U 3.53 0.4 U 5.55 10.7 0.4 U Ethylbenzene 6.08 J 1 1.13 J 1 J 0.43 J 0.48 J 1.35 J 0.43 U 1.87 J 46.0 1 J 3.52 J 1.48 J 1.56 J 2.26 0.43 U 0.56 J 1.87 J Heptane 5.33 J 1.02 J 2.01 J 0.41 U 0.41 U 1.39 J 0.41 U 3.89 50.4 3.03 J 10.3 J 1.19 J 1.84 J 7.38 0.74 J 0.66 J 7.79 Hexachlorobutadiene 1.07 U 1.07 U 1.07 U 1.07 U 1.07 U 1.07 U 1.07 U 1.07 U 1.07 U 1.07 U 1.07 U 1.07 U 1.07 U 1.07 U 1.07 U 1.07 U 1.07 U m-and p-Xylene 9.12J 2J 1.87J 1.78J 1.65J 3.47J 31 113 2.13J 7.38J 3.69J 4J 3.52J 1.43J 2.17J 3.39J Methylene chloride 1.32 J 2.5 10.1 J 1.91 J 2.08 J 11.5 10.4 1.88 J 175 1.88 J 1.98 J 1.29 J 3.3 1.98 J 1.67 J 1.18 J 1.84 J Methyl-tert-butyl ether(MTBE) 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.4 J 0.36 U Naphthalene 2.31 J 0.79 J 0.52 U 0.84 J 1.42 J 0.52 J 0.52 UJ 0.63 J 2.57 J 0.68 J 0.52 J 0.73 J 0.84 J 0.52 J 0.79 J 1.1 J 0.52 J n-Hexane 9.52 J 1.13 J 0.35 U 1.09 J 0.99 J 2.43 10.6 58.5 0.35 U 0.35 U 2.5 1.44 J 61.7 7.05 6.34 60.3 o-Xylene 6.52 J 0.96 J 0.83 J 3.95 J 2.39 J 2.22 0.43 J 1.52 J 49.5 1.09 J 2.91 J 2.61 2.82 1.61 J 0.87 J 1.48 J 1.39 J Propylene 1.24J 1 0.17U 0.17U 0.17U 0.17U 0.17U 0.17U 0.17U 3.44 0.17U 0.17U 0.86 0.17U 0.17U 0.17U 0.17U 0.17U Styrene 8.09 J 0.43 U 0.43 U 0.43 U 0.43 U 5.11 0.43 U 0.51 J 43.9 0.47 J 1.06 J 0.43 U 7.66 0.64 J 0.43 U 0.43 U 0.43 U etrachloroethene 0.61 J 5.83 0.75 J 0.54 J 0.61 J 1.76 J 1.56 J 1.7 J 17.0 3.05 J 1.29 J 0.27 J 8.14 1.49 J 0.61 J 0.47 J 1.97 J etrahydrofuran 0.29 U 1.59 0.62 J 4.13 J 4.42 J 0.29 U 0.29 U 0.29 U 110 0.71 J 0.91 J 0.29 U 0.29 U 0.97 J 0.29 U 0.44 J 0.29 U Toluene 29.8 J 6.03 38.4 2.11 J 2.79 J 12.4 1.73 J 59.5 256 46.7 J 78.4 J 7.91 19.2 61.1 4.52 3.77 32.8 rans-1,2-Dichloroethene 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U 0.4 U U. U 0.4 U 0.4 U 0.4 U 0.4 U tans-1,3-Dichloropropane 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U 0.45 U richloroethene 0.16 U 21.0 0.48 J 0.43 J 21 J 4.94 6.99 0.59 J 14.0 0.32 J 0.32 J 0.16 U 36.5 0.27 J 0.16 U 0.16 U 0.27 J dchlorofluoromethane(Freon-11) 1.4 J 1.63 J 1.46 J 1.4 J J 1.57 J .52 J 1.24 J 1.46 J 1.29 J 1.24 J 1.29 J Vinyl acetate 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.311 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U 0.36 U Vinyl chloride 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U 0.08 U Notes: Shading indicates detection NA-Not analyzed J-Analyte present,value may or may not be accurate or precise U-The material was analyzed for,but not detected UJ-Analyte not detected,quantilation limit may be inaccurate UG/M3-Micrograms per cubic meter Page 1 of 1 86 Attachment 7 Solar Power Impacts Evaluation (CleanSWEEP) 87 ATTACHMENT 7 Option 1 - 50-hp Compressor - Conventional Power (As-Is Scenario) SWMU 350 Naphthalene Biosparging Treatability Study MC/EAST-MCB CAMLEJ, North Carolina Clean Solar and Wind Energy in Environmental Programs (Clean SWEEP) TOOT Reset Location and System Input Sheet MCIEAST-MCB CAMLEJ: Site SWMU 350, MCIEAST-M Pre-Defined Values User-Defined Values Year System to Utilize Renewable Energy 2014 Location Charleston AFB MCIEAST-MCB CAMLEJ Zip Code 29404 28542 Site Name SWMU 350, MCIEAST-MCB CAMLEJ Elevation (ft above sea level) 46 ft amsl 40 ft amsl Is this a news stem? No If Yes, is grid power available at the system? If No, distance to nearest electrical access ft Cost to bring in electrical ($) $0 System Energy Requirement Water Components Air Components Flow Rate .00 gpm 1,500.00 scfm Head/Pressure .00 ft 50.00 inches H2O Total Horsepower of all Equipment 0.000 HP 50.000 HP Equipment Power Rating 0.000 kW 37.735 kW Energy Consumption 330,559 kWh/yr Percent Energy to be Provided by Renewables % 0.0% Increasing/Decreasing Energy Requirements (%/year) 0.0% per year Is continuous operation required? Yes If no, minimum required operation time (%/year) Expected Remedy Duration (years beyond current) 1.00 years Page 1 of 12 88 ATTACHMENT 7 Option 1 - 50-hp Compressor - Conventional Power (As-Is Scenario) SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ, North Carolina Clean Solar and Wind Energy in Environmental Programs (Clean SWEEP) Energy Input Sheet MCIEAST-MCB CAMLEJ: Site SWMU 350, MCIE Pre-Defined Values User-Defined Values Grid Energy Detail Provider South Carolina Electric & Gas Co - SC Duke/Progress Energy - NC Billing Structure Industrial Projected Energy Inflation Rate (%/yr) 3.00% Current Year Energy Cost cents/kWh 7.44¢/kWh 10.84¢/kWh Emissions NOx Ibs/MWh 1.61 Ibs/MWh SOx Ibs/MWh 5.89lbs/MWh CO2 Ibs/MWh 1135 Ibs/MWh Incentives/Rebates $0 remedy lifetime Renewable Energy Detail Solar PV Solar Panel Efficiency % 15% Mount Type Fixed, Tilt at Latitude Potential kWh/m2/da 5.08 kWh/m2/da 5.12 kWh/m2/da Wind Wind Speed Reference Height m 50 m Reference Wind Speed (m/s) 4.03 m/s Maximum Hub Height m Wind Regime Surface Obstructions Page 2 of 12 89 ATTACHMENT 7 Option 1 - 50-hp Compressor- Conventional Power (As-Is Scenario) SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ, North Carolina Clean Solar and Wind Energy in Environmental Programs (Clean SWEEP) Output Data Sheet MCIEAST-MCB CAMLEJ: Site SWMU 350, M Grid Only Renewable Energy Scenario (Baseline) Grid Wind Solar PV Energy Overview Percentage Desired from Wind or Solar % NA NA 0% 100% Energy Requirement - Base ear kWh/ r 330,559 kWh/yr 330,559 kWh/yr 0 kWh/ r 0 kWh/ r Renewable Energy Power Rating kW NA NA NA 0.00 kW Area Required/System Footprint NA NA NA 0. m2 % Energy Provided 100% 100% 0% 0% Cost Analysis Cost per Watt for Renewable $/kW NA NA NA #DIV/0! Capital Cost $ $0 $0 NA #DIV/0! O&M Cost $ over remedy lifetime NA NA NA #DIV/0! Energy Cost $ over remedy lifetime $35,826 $35,826 $0 Rebates/Incentives $ over remedy lifetime NA NA $0 Total Cost of Option $ over remedy lifetime $35,826 #DIV/0! Remedy Lifetime Cost Reduction NA #DIV/0! Return on Investment NA #DIV/0! Simple Payback Period NA #DIV/0! Total Value of Renewable Post Remediation $0 Environmental Impacts Emissions (Life-Cycle) NOx tons 832 832 Negligible Negligible SOx tons 3,042 3,042 Negligible Negligible CO2 tons 586,225 586,225 0.00 0.00 RECs 0 0 0 0 Page 3 of 12 90 ATTACHMENT 7 Option 1 - 50-hp Compressor- Conventional Power (As-Is Scenario) SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ, North Carolina Cumulative Cost Comparison $40,000 $35,000 $30,000 $25,000 0 v a $20,000 3 E 3 v $15,000 $10,000 $5,000 $0 0 5 10 15 20 25 30 35 Years From Initial Renewable Energy Use Grid Power Only Scenario Renewable Energy Scenario ——— Remedy Duration Page 4 of 12 91 ATTACHMENT 7 Option 2 - 15-hp Compressor- Conventional Power SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ, North Carolina Clean Solar and Wind Energy in Environmental Programs (Clean SWEEP) TOOT Reset Location and System Input Sheet MCIEAST-MCB CAMLEJ: Site SWMU 350 Pre-Defined Values User-Defined Values Year System to Utilize Renewable Energy 2014 Location Charleston AFB MCIEAST-MCB CAMLEJ Zip Code 29404 28542 Site Name SWMU 350 Elevation (ft above sea level) 46 ft amsl 40 ft amsl Is this a news stem? Yes If Yes, is grid power available at the system? No If No, distance to nearest electrical access ft 0 ft Cost to bring in electrical ($) $10,000 $10,000 System Energy Requirement Water Components Air Components Flow Rate .00 gpm 450.00 scfm Head/Pressure .00 ft 50.00 inches H2O Total Horsepower of all Equipment 0.000 HP 15.000 HP Equipment Power Rating 0.000 kW 1 11.321 kW Energy Consumption 99,168 kWh/yr Percent Energy to be Provided by Renewables % 0.0% Increasing/Decreasing Increasing/Decreasing Energy Requirements %/ ear 0.0% per year Is continuous operation required? Yes If no, minimum required operation time %/ ear Expected Remedy Duration (years beyond current) 1.00 years Page 5 of 12 92 ATTACHMENT 7 Option 2 - 15-hp Compressor- Conventional Power SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ, North Carolina Clean Solar and Wind Energy in Environmental Programs (Clean SWEEP) Energy Input Sheet MCIEAST-MCB CAMLEJ: Site SWMU 350 Pre-Defined Values User-Defined Values Grid Energy Detail Provider South Carolina Electric & Gas Co - SC Duke/Progress Energy - NC Billing Structure Industrial Projected Energy Inflation Rate (%/yr) 3.00% Current Year Energy Cost cents/kWh 7.44¢/kWh 10.84¢/kWh Emissions NOx Ibs/MWh 1.61 Ibs/MWh SOx Ibs/MWh 5.89lbs/MWh CO2 Ibs/MWh 1135 Ibs/MWh Incentives/Rebates $0 remedy lifetime Renewable Energy Detail Solar PV Solar Panel Efficiency % 15% Mount Type Fixed, Tilt at Latitude Potential kWh/m2/da 5.08 kWh/m2/da 5.12 kWh/m2/da Wind Wind Speed Reference Height m 50 m Reference Wind Speed (m/s) 4.03 m/s Maximum Hub Height m Wind Regime Surface Obstructions Page 6 of 12 93 ATTACHMENT 7 Option 2 - 15-hp Compressor- Conventional Power SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ, North Carolina Clean Solar and Wind Energy in Environmental Programs (Clean SWEEP) Output Data Sheet MCIEAST-MCB CAMLEJ: Site SWMU 350 Grid Only Renewable Energy Scenario (Baseline) Grid Wind Solar PV Energy Overview Percentage Desired from Wind or Solar % NA NA 0% 100% Energy Requirement - Baseyear (kWh/yr) 99,168 kWh/yr 99,168 kWh/yr 0 kWh/yr 0 kWh/yr Renewable Energy Power Rating kW NA NA NA 0.00 kW Area Required/System Footprint NA NA NA 0. m2 % Energy Provided 100% 100% 0% 0% Cost Analysis Cost per Watt for Renewable ($/kW) NA NA NA #DIV/0! Capital Cost $ $10,000 $10,000 NA #DIV/0! O&M Cost ($ over remedy lifetime) NA NA NA #DIV/0! Energy Cost $ over remedy lifetime $10,748 $10,748 1 $0 Rebates/Incentives ($ over remedy lifetime) NA NA Total Cost of Option $ over remedy lifetime $20,748 #DIV/0! Remedy Lifetime Cost Reduction NA #DIV/0! Return on Investment NA #DIV/0! Simple Payback Period NA #DIV/0! Total Value of Renewable Post Remediation $0 Environmental Impacts Emissions (Life-Cycle) NOx (tons) 249 249 Negligible Negligible SOx tons 913 913 Negligible Negligible CO2 (tons) 175,868 175,868 0.00 0.00 RECs 0 0 0 0 Page 7 of 12 94 ATTACHMENT 7 Option 2 - 15-hp Compressor- Conventional Power SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ, North Carolina Cumulative Cost Comparison $25,000 $20,000 „ $15,000 0 v a c� 3 E $10,000 $5,000 $0 0 5 10 15 20 25 30 35 Years From Initial Renewable Energy Use Grid Power Only Scenario Renewable Energy Scenario ——— Remedy Duration Page 8 of 12 95 ATTACHMENT 7 Option 2 - 15-hp Compressor - Solar Power SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ, North Carolina Clean Solar and Wind Energy in Environmental Programs (Clean SWEEP) TOOT Reset Location and System Input Sheet - MCIEAST-MCB CAMLEJ: Site SWMU 350 Pre-Defined Values User-Defined Values Year System to Utilize Renewable Energy 2014 Location Charleston AFB MCIEAST-MCB CAMLEJ Zip Code 29404 28542 Site Name SWMU 350 Elevation (ft above sea level) 46 ft amsl 40 ft amsl Is this a news stem? Yes If Yes, is grid power available at the system? No If No, distance to nearest electrical access ft 0 ft Cost to bring in electrical ($) $10,000 $10,000 System Energy Requirement Water Components Air Components Flow Rate .00 gpm 450.00 scfm Head/Pressure .00 ft 50.00 inches H2O Total Horsepower of all Equipment 0.000 HP 15.000 HP Equipment Power Rating 0.000 kW 1 11.321 kW Energy Consumption 99,168 kWh/yr Percent Energy to be Provided by Renewables % 99.0% Increasing/Decreasing Increasing/Decreasing Energy Requirements %/ ear 0.0% per year Is continuous operation required? No If no, minimum required operation time %/ ear 30% per year Expected Remedy Duration (years beyond current) 1.00 years Page 9 of 12 96 ATTACHMENT 7 Option 2 - 15-hp Compressor - Solar Power SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ, North Carolina Clean Solar and Wind Energy in Environmental Programs (Clean SWEEP) Energy Input Sheet MCIEAST-MCB CAMLEJ: Site SWMU 350 Pre-Defined Values User-Defined Values Grid Energy Detail Provider South Carolina Electric & Gas Co - SC Duke/Progress Energy - NC Billing Structure Industrial Projected Energy Inflation Rate %/ r 3.00% Current Year Energy Cost (cents/kWh) 7.44¢/kWh 10.84¢/kWh Emissions NOx (Ibs/MWh) 1.61 Ibs/MWh SOx Ibs/MWh 5.89lbs/MWh CO2 Ibs/MWh 1135 Ibs/MWh Incentives/Rebates $0 remedy lifetime Renewable Energy Detail Solar PV Solar Panel Efficiency % 15% Mount Type Fixed, Tilt at Latitude Potential kWh/m2/da 5.08 kWh/m2/day 5.12 kWh/m2/day Wind Wind Speed Reference Height (m) 50 m Reference Wind Speed m/s 4.03 m/s Maximum Hub Height (m) Wind Regime Surface Obstructions Page 10 of 12 97 ATTACHMENT 7 Option 2 - 15-hp Compressor - Solar Power SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ, North Carolina Clean Solar and Wind Energy in Environmental Programs (Clean SWEEP) Output Data Sheet MCIEAST-MCB CAMLEJ: Site SWMU 350 Grid Only Renewable Energy Scenario (Baseline) Grid Wind Solar PV Energy Overview Percentage Desired from Wind or Solar % NA NA 0% 100% Energy Requirement - Base ear kWh/ r 29,750 kWh/yr 298 kWh/yr 0 kWh/ r 29,453 kWh/ r Renewable Energy Power Rating kW NA NA NA 15.76 kW Area Required/System Footprint NA NA NA 140.09 m2 % Energy Provided 100% 1% 0% 99% Cost Analysis Cost per Watt for Renewable $/kW NA NA NA $8,366.32/kW Capital Cost $ $10,000 $0 NA $131,855 O&M Cost $ over remedy lifetime NA NA NA $177 Energy Cost $ over remedy lifetime $3,224 $32 1 $0 Rebates/Incentives $ over remedy lifetime NA NA $0 Total Cost of Option $ over remedy lifetime $13,224 $132,064 Remedy Lifetime Cost Reduction NA -$118,840 Return on Investment NA -90% Simple Payback Period NA 26 years (greater than remedy duration Total Value of Renewable Post Remediation $140,442 Environmental Impacts Emissions (Life-Cycle) NOx tons 75 1 Negligible Negligible SOx tons 274 3 Negligible Negligible CO2 tons 52,760 1 528 0.00 34.02 RECs 0 0 0 884 Page 11 of 12 98 ATTACHMENT 7 Option 2 - 15-hp Compressor - Solar Power SWMU 350 Naphthalene Biosparging Treatability Study MCIEAST-MCB CAMLEJ, North Carolina Cumulative Cost Comparison $140,000 1 $120,000 1 1 1 1 1 $100,000 1 1 1 1 $80,000 1 a.. 1 0 1 U 1 $60,000 1 � 1 E 1 ' 1 U 1 $40,000 1 1 1 1 $20,000 1 1 1 $0 0 1 5 10 15 20 25 11�30 35 $20,00 0 — Years From Initial Renewable Energy Use --*----Grid Power Only Scenario Renewable Energy Scenario ——— Remedy Duration Page 12 of 12 99