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HomeMy WebLinkAboutNC0029033_Supplemental DMR Info Attachment_20240925 Waypoint. 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 8/22/2024 City of Raleigh Robin Scudelari 8500 Battle Bridge Raleigh, NC, 27610 Ref: Analytical Testing Revised Lab Report Number: 24-221-0057 (Original Report Date 8/19/2024) Client Project Description: Raleigh Neuse River Resource Recovery Fa Dear Robin Scudelari: Waypoint Analytical, LLC (Charlotte) received sample(s) on 8/8/2024 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA(including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as- received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, (0'0�w� Terri W Cole Laboratory Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 13 NC 28217 Waypoint 0 449 Springbrook Rd, Charlotte, Main 704.529.6364 ANALYTICAL www.waypointanalytica l.com Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date North Carolina State Program 37735 07/31/2025 North Carolina State Program 402 12/31/2024 South Carolina State Program 99012 07/31/2025 South Carolina State Program 99012 12/31/2024 Laboratory ID: WP GNC: Waypoint Analytical Carolina, Inc. (G), Greenville, NC State Program Lab ID Expiration Date North Carolina State Program 37715 07/01/2024 North Carolina State Program 10 12/31/2024 North Carolina State Program 610 12/31/2024 Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2025 Arkansas State Program 88-0650 02/07/2025 California State Program 2904 06/30/2025 Florida State Program - NELAP E871157 06/30/2025 Georgia State Program C044 11/14/2025 Georgia State Program 04015 06/30/2024 Illinois State Program - NELAP 200078 10/31/2025 Kentucky State Program 90047 12/31/2024 Kentucky State Program 80215 06/30/2025 Kentucky State Program KY90047 12/31/2024 Louisiana State Program - NELAP LA037 12/31/2024 Louisiana State Program - NELAP 04015 06/30/2025 Mississippi State Program MS 11/14/2025 North Carolina State Program 47701 07/31/2025 North Carolina State Program 415 12/31/2024 Pennsylvania State Program - NELAP 68-03195 05/31/2025 South Carolina State Program 84002 06/30/2024 Tennessee State Program 02027 11/14/2025 Texas State Program - NELAP T104704180 09/30/2024 Virginia State Program 00106 06/30/2025 Virginia State Program - NELAP 460181 09/14/2024 Page 1 of 1 00016/24-221-0057 Page 2 of 13 (2) YPO•*nt 449 Springbrook Rd, Charlotte, 28217 Wa Main 704.5.529.6364 64 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 24-221-0057 Client Project Description: Raleigh Neuse River Resource Recovery Fa Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 99751 Effluent Aqueous 08/06/2024 08:33 08/08/2024 13:30 99751 Effluent Aqueous 08/06/2024 08:33 08/08/2024 13:30 1631E WP GNC 99751 Effluent Aqueous 08/06/2024 08:33 08/08/2024 13:30 624.1 WP MTN 99752 Effluent FB Aqueous 08/06/2024 08:33 08/08/2024 13:30 1631E WP GNC WP GNC: Waypoint Analytical-Greenville NC,Greenville, NC WP MTN-Memphis,TN: Waypoint Analytical-TN, Memphis,TN Page 3 of 13 • Waypoint. 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com Client: City of Raleigh CASE NARRATIVE Project: Raleigh Neuse River Resource Recovery Fa Lab Report Number: 24-221-0057 Date: 8/22/2024 This is a revised report and supersedes the original laboratory report dated 8/19/24. N- nitrosodimethylamine has been added to the 625 list. Metals Analyses Method 200.8 Sample 99709 (August SMR) Analyte: Thallium QC Batch No: V50826/V50706 CCB failed high. Sample concentration BRL. Results not affected. Sample 99751 (Effluent) Analyte: Thallium QC Batch No: V50826/V50706 CCB failed high. Sample concentration BRL. Results not affected. Volatile Organic Compounds -GC/MS Method 624.1 QC Batch No: L767011 MSD not reportable due to autosampler error during analysis. 625.1 - Base/Neutrals and Acids by GC/MS Method 625.1 Analyte: Benzidine QC Batch No: V50747/V50712 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged W" to indicate that results should be considered minimum concentration due to the potential for a low bias. Page 4 of 13 •nt�/aJ/pOI■ ■•r,0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 00015 City of Raleigh Project Raleigh Neuse River Resource Recovery Fa Original Report Date : 08/19/2024 Robin Scudelari Revised Report Date: 08/22/2024 8500 Battle Bridge Information : Received : 08/08/2024 Raleigh , NC 27610 Report Number :24-221-0057 REPOR T OF A NA L YSIS Lab No : 99751 Matrix: Aqueous Sample ID : Effluent Sampled: 8/6/2024 8:33 Test Results Units MQL DF Date/Time By Analytical Analyzed Method Phenols(Total) 0.089 mg/L 0.050 1 08/12/24 11:45 SLO 420.1 Antimony <0.002 mg/L 0.002 1 08/14/2417:40 NPC 200.8 Mercury(Total) <1.00 ng/L 1.00 1 08/16/24 10:29 MTM 1631E Thallium <0.0010 mg/L 0.0010 1 08/14/2417:40 NPC 200.8 Analytical Method: 625.1 Prep Batch(es): V50712 08/12/24 09:45 Prep Method: 625.1 (Prep) Test Results Units MQL DF Date/Time By Analytical Analyzed Batch Hexachlorocyclopentadiene <5.00 ug/L 5.00 1 08/12/24 22:07 AMP V50747 Surrogate: Phenol-d5 24.9 Limits: 10-63% 1 08/12/24 22:07 AMP 625.1 Surrogate: 2-Fluorobiphenyl 61.0 Limits: 49-118% 1 08/12/24 22:07 AMP V50747 Surrogate: 2-Fluorophenol 36.2 Limits: 22-84% 1 08/12/24 22:07 AMP V50747 Surrogate: Nitrobenzene-d5 53.0 Limits: 43-123% 1 08/12/24 22:07 AMP V50747 Surrogate: 4-Terphenyl-d14 74.0 Limits: 49-151% 1 08/12/24 22:07 AMP V50747 Surrogate: 2,4,6-Tribromophenol 82.7 Limits: 31-144% 1 08/12/24 22:07 AMP V50747 Qualifiers/ DF Dilution Factor M Minimum value Definitions MQL Method Quantitation Limit Page 5 of 13 �n W�ypOI■ ■�.0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 00015 City of Raleigh Project Raleigh Neuse River Resource Recovery Fa Original Report Date : 08/19/2024 Robin Scudelari Revised Report Date: 08/22/2024 8500 Battle Bridge Information : Received : 08/08/2024 Raleigh , NC 27610 Report Number :24-221-0057 REPOR T OF A NA L YSIS Lab No : 99751 Matrix: Aqueous Sample ID : Effluent Sampled: 8/6/2024 8:33 Analytical Method: 624.1 Prep Batch(es): L767009 08/13/24 08:21 Prep Method: 624.1 (Prep) Test Results Units MQL DF Date/Time By Analytical Analyzed Batch Acrolein <20.0 Ng/L 20.0 1 08/13/24 17:19 HRS L767011 Acrylonitrile <20.0 ug/L 20.0 1 08/13/24 17:19 HRS L767011 Benzene <1.00 Ng/L 1.00 1 08/13/24 17:19 HRS L767011 Bromodichloromethane <1.00 pg/L 1.00 1 08/13/24 17:19 HRS L767011 Bromoform <1.00 Ng/L 1.00 1 08/13/24 17:19 HRS L767011 Bromomethane <1.00 pg/L 1.00 1 08/13/24 17:19 HRS L767011 Carbon Tetrachloride <1.00 Ng/L 1.00 1 08/13/24 17:19 HRS L767011 Chlorobenzene <1.00 pg/L 1.00 1 08/13/24 17:19 HRS L767011 Chlorodibromomethane <1.00 Ng/L 1.00 1 08/13/24 17:19 HRS L767011 Chloroethane <1.00 pg/L 1.00 1 08/13/24 17:19 HRS L767011 2-Chloroethylvinyl Ether <5.00 Ng/L 5.00 1 08/13/24 17:19 HRS L767011 Chloroform <1.00 pg/L 1.00 1 08/13/24 17:19 HRS L767011 Chloromethane <1.00 Ng/L 1.00 1 08/13/24 17:19 HRS L767011 1,2-Dichlorobenzene <1.00 pg/L 1.00 1 08/13/24 17:19 HRS L767011 1,3-Dichlorobenzene <1.00 Ng/L 1.00 1 08/13/24 17:19 HRS L767011 1,4-Dichlorobenzene <1.00 pg/L 1.00 1 08/13/24 17:19 HRS L767011 1,1-Dichloroethane <1.00 Ng/L 1.00 1 08/13/24 17:19 HRS L767011 1,2-Dichloroethane <1.00 pg/L 1.00 1 08/13/24 17:19 HRS L767011 1,1-Dichloroethene <1.00 Ng/L 1.00 1 08/13/24 17:19 HRS L767011 trans-1.2-Dichloroethene <1.00 pg/L 1.00 1 08/13/24 17:19 HRS L767011 1,2-Dichloropropane <1.00 Ng/L 1.00 1 08/13/24 17:19 HRS L767011 cis-1,3-Dich loropropene <1.00 pg/L 1.00 1 08/13/24 17:19 HRS L767011 Qualifiers/ DF Dilution Factor M Minimum value Definitions MQL Method Quantitation Limit Page 6 of 13 �n W�ypOI■ ■�.0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 00015 City of Raleigh Project Raleigh Neuse River Resource Recovery Fa Original Report Date : 08/19/2024 Robin Scudelari Revised Report Date: 08/22/2024 8500 Battle Bridge Information : Received : 08/08/2024 Raleigh , NC 27610 Report Number :24-221-0057 REPOR T OF A NA L YSIS Lab No : 99751 Matrix: Aqueous Sample ID : Effluent Sampled: 8/6/2024 8:33 Analytical Method: 624.1 Prep Batch(es): L767009 08/13/24 08:21 Prep Method: 624.1 (Prep) Test Results Units MQL DF Date/Time By Analytical Analyzed Batch trans-1,3-Dichloropropene <1.00 Ng/L 1.00 1 08/13/24 17:19 HRS L767011 Ethylbenzene <1.00 ug/L 1.00 1 08/13/24 17:19 HRS L767011 Methylene Chloride <10.0 Ng/L 10.0 1 08/13/24 17:19 HRS L767011 1,1,2,2-Tetrachloroethane <1.00 pg/L 1.00 1 08/13/24 17:19 HRS L767011 Tetrachloroethene <1.00 Ng/L 1.00 1 08/13/24 17:19 HRS L767011 Toluene <5.00 pg/L 5.00 1 08/13/24 17:19 HRS L767011 1,1,1-Trichloroethane <1.00 Ng/L 1.00 1 08/13/24 17:19 HRS L767011 1,1,2-Trichloroethane <1.00 pg/L 1.00 1 08/13/24 17:19 HRS L767011 Trichloroethene <1.00 Ng/L 1.00 1 08/13/24 17:19 HRS L767011 Trichlorofluoromethane <1.00 pg/L 1.00 1 08/13/24 17:19 HRS L767011 1,2,4-Trim ethyl benzene <1.00 Ng/L 1.00 1 08/13/24 17:19 HRS L767011 Vinyl Chloride <1.00 pg/L 1.00 1 08/13/24 17:19 HRS L767011 Surrogate: 4-Bromofluorobenzene 105 Limits: 71-131% 1 08/13/24 17:19 L767011 Surrogate: Dibromofluoromethane 98.2 Limits: 70-128% 1 08/13/24 17:19 L767011 Surrogate: 1,2-Dichloroethane-d4 87.4 Limits: 67-136% 1 08/13/24 17:19 L767011 Surrogate: Toluene-d8 97.0 Limits: 70-130% 1 08/13/24 17:19 L767011 Analytical Method: 625.1 Prep Batch(es): V50712 08/12/24 09:45 Prep Method: 625.1 (Prep) Test Results Units MQL DF Date/Time By Analytical Analyzed Batch Acenaphthene <2.00 Ng/L 2.00 1 08/12/24 22:07 AMP V50747 Acenaphthylene <2.00 pg/L 2.00 1 08/12/24 22:07 AMP V50747 Qualifiers/ DF Dilution Factor M Minimum value Definitions MQL Method Quantitation Limit Page 7 of 13 �n W�ypOI■ ■�.0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 00015 City of Raleigh Project Raleigh Neuse River Resource Recovery Fa Original Report Date : 08/19/2024 Robin Scudelari Revised Report Date: 08/22/2024 8500 Battle Bridge Information : Received : 08/08/2024 Raleigh , NC 27610 Report Number :24-221-0057 REPOR T OF A NA L YSIS Lab No : 99751 Matrix: Aqueous Sample ID : Effluent Sampled: 8/6/2024 8:33 Analytical Method: 625.1 Prep Batch(es): V50712 08/12/24 09:45 Prep Method: 625.1 (Prep) Test Results Units MQL DF Date/Time By Analytical Analyzed Batch Anthracene <2.00 Ng/L 2.00 1 08/12/24 22:07 AMP V50747 Benzidine <10.0 M pg/L 10.0 1 08/12/24 22:07 AMP V50747 Benzo(a)anthracene <2.00 Ng/L 2.00 1 08/12/24 22:07 AMP V50747 Benzo(a)pyrene <2.00 pg/L 2.00 1 08/12/24 22:07 AMP V50747 Benzo(b)fluoranthene <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 Benzo(g,h,i)perylene <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 Benzo(k)fluoranthene <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 Benzoic Acid <10.0 pg/L 10.0 1 08/12/24 22:07 AMP V50747 Benzyl alcohol <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 Bis(2-Chloroethoxy)methane <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 Bis(2-Chloroethyl)ether <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 Bis(2-Chloroisopropyl)ether <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 Bis(2-ethylhexyl)phthalate <10.0 Ng/L 10.0 1 08/12/24 22:07 AMP V50747 4-Bromophenyl phenyl ether <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 Butyl benzyl phthalate <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 4-Chloro-3-methylphenol <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 2-Chloronaphthalene <20.0 Ng/L 20.0 1 08/12/24 22:07 AMP V50747 2-Chlorophenol <10.0 pg/L 10.0 1 08/12/24 22:07 AMP V50747 4-Chlorophenyl phenyl ether <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 Chrysene <2.00 pg/L 2.00 1 08/12/24 22:07 AMP V50747 Dibenz(a,h)anthracene <2.00 Ng/L 2.00 1 08/12/24 22:07 AMP V50747 Dibenzofuran <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 Qualifiers/ DF Dilution Factor M Minimum value Definitions MQL Method Quantitation Limit Page 8 of 13 �n W�ypOI■ ■�.0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 00015 City of Raleigh Project Raleigh Neuse River Resource Recovery Fa Original Report Date : 08/19/2024 Robin Scudelari Revised Report Date: 08/22/2024 8500 Battle Bridge Information : Received : 08/08/2024 Raleigh , NC 27610 Report Number :24-221-0057 REPOR T OF A NA L YSIS Lab No : 99751 Matrix: Aqueous Sample ID : Effluent Sampled: 8/6/2024 8:33 Analytical Method: 625.1 Prep Batch(es): V50712 08/12/24 09:45 Prep Method: 625.1 (Prep) Test Results Units MQL DF Date/Time By Analytical Analyzed Batch 1,2-Dichlorobenzene <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 1,3-Dichlorobenzene <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 1,4-Dichlorobenzene <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 3,3'-Dichlorobenzidine <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 2,4-Dichlorophenol <10.0 Ng/L 10.0 1 08/12/24 22:07 AMP V50747 Diethyl phthalate <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 Dimethyl phthalate <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 2,4-Dimethylphenol <20.0 pg/L 20.0 1 08/12/24 22:07 AMP V50747 Di-n-butyl phthalate <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 4,6-Dinitro-2-methylphenol <10.0 pg/L 10.0 1 08/12/24 22:07 AMP V50747 2,4-Dinitrophenol <10.0 Ng/L 10.0 1 08/12/24 22:07 AMP V50747 2,4-Dinitrotoluene <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 2,6-Dinitrotoluene <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 Di-n-Octyl Phthalate <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 1,2-Diphenylhydrazine/Azobenzene <2.00 Ng/L 2.00 1 08/12/24 22:07 AMP V50747 Fluoranthene <2.00 pg/L 2.00 1 08/12/24 22:07 AMP V50747 Fluorene <2.00 Ng/L 2.00 1 08/12/24 22:07 AMP V50747 Hexachlorobenzene <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 Hexachlorobutadiene <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 Hexachloroethane <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 Indeno(1,2,3-cd)pyrene <2.00 Ng/L 2.00 1 08/12/24 22:07 AMP V50747 Isophorone <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 Qualifiers/ DF Dilution Factor M Minimum value Definitions MQL Method Quantitation Limit Page 9 of 13 �n W�ypOI■ ■�.0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 00015 City of Raleigh Project Raleigh Neuse River Resource Recovery Fa Original Report Date : 08/19/2024 Robin Scudelari Revised Report Date: 08/22/2024 8500 Battle Bridge Information : Received : 08/08/2024 Raleigh , NC 27610 Report Number :24-221-0057 REPOR T OF A NA L YSIS Lab No : 99751 Matrix: Aqueous Sample ID : Effluent Sampled: 8/6/2024 8:33 Analytical Method: 625.1 Prep Batch(es): V50712 08/12/24 09:45 Prep Method: 625.1 (Prep) Test Results Units MQL DF Date/Time By Analytical Analyzed Batch 1-Methylnaphthalene <2.00 Ng/L 2.00 1 08/12/24 22:07 AMP V50747 2-Methylnaphthalene <2.00 pg/L 2.00 1 08/12/24 22:07 AMP V50747 Naphthalene <2.00 Ng/L 2.00 1 08/12/24 22:07 AMP V50747 Nitrobenzene <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 2-Nitrophenol <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 4-Nitrophenol <10.0 pg/L 10.0 1 08/12/24 22:07 AMP V50747 N-Nitrosodimethylamine <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 N-Nitrosodiphenylamine <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 N-Nitroso-di-n-propylamine <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 Pentachlorophenol <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 Phenanthrene <2.00 Ng/L 2.00 1 08/12/24 22:07 AMP V50747 Phenol <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 Pyrene <2.00 Ng/L 2.00 1 08/12/24 22:07 AMP V50747 1,2,4-Trichlorobenzene <5.00 pg/L 5.00 1 08/12/24 22:07 AMP V50747 2,4,6-Trichlorophenol <5.00 Ng/L 5.00 1 08/12/24 22:07 AMP V50747 Surrogate: Phenol-d5 24.9 Limits: 10-63% 1 08/12/24 22:07 AMP 625.1 Surrogate: 2-Fluorobiphenyl 61.0 Limits: 49-118% 1 08/12/24 22:07 AMP V50747 Surrogate: 2-Fluorophenol 36.2 Limits: 22-84% 1 08/12/24 22:07 AMP V50747 Surrogate: Nitrobenzene-d5 53.0 Limits: 43-123% 1 08/12/24 22:07 AMP V50747 Surrogate: 4-Terphenyl-d14 74.0 Limits: 49-151% 1 08/12/24 22:07 AMP V50747 Surrogate: 2,4,6-Tribromophenol 82.7 Limits: 31-144% 1 08/12/24 22:07 AMP V50747 Qualifiers/ DF Dilution Factor M Minimum value Definitions MQL Method Quantitation Limit Page 10 of 13 Waypoint,0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 00015 City of Raleigh Project Raleigh Neuse River Resource Recovery Fa Original Report Date : 08/19/2024 Robin Scudelari Revised Report Date: 08/22/2024 8500 Battle Bridge Information : Received : 08/08/2024 Raleigh , NC 27610 Report Number :24-221-0057 REPOR T OF A NA L YSIS Lab No : 99752 Matrix: Aqueous Sample ID : Effluent FB Sampled: 8/6/2024 8:33 Test Results Units MQL DF Date/Time By Analytical Analyzed Method Mercury(Total) <1.00 ng/L 1.00 1 08/16/24 10:21 MTM 1631E Qualifiers/ DF Dilution Factor M Minimum value Definitions MQL Method Quantitation Limit Page 11 of 13 (2) WayPo�nt 449 Springbrook Rd,Charlotte, 28217 Main 704.5.529.6364 ANALYTICAL www.waypointanalytical.com Shipment Receipt Form Customer Number:00015 Customer Name: City of Raleigh Report Number: 24-221-0057 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 Other : 0 UPS 0 Client * Courier Thermometer ID: IRT15 3.8C Shipping container/cooler uncompromised? * Yes 0 No Number of coolers/boxes received F Custody seals intact on shipping container/cooler? U Yes 0 No 0 Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? Yes 0 No COC agrees with sample Iabel(s)? U Yes 0 No COC properly completed U Yes 0 No Samples in proper containers? U Yes 0 No Sample containers intact? Yes 0 No Sufficient sample volume for indicated test(s)? Yes 0 No All samples received within holding time? Yes 0 No Cooler temperature in compliance? Yes 0 No 0 Not Present Cooler/Samples arrived at the laboratory on ice. Yes 0 No Samples were considered acceptable as cooling process had begun. Water- Sample containers properly preserved 0 Yes 0 No 0 N/A Water- VOA vials free of headspace 0 Yes 0 No 0 N/A Trip Blanks received with VOAs 0 Yes * No 0 N/A Soil VOA method 5035—compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F Low concentration EnCore samplers (48 hr) F_ High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes 0 No Comments: Signature: Angelo Norvell Date &Time: 08/08/2024 13:55:08 Page 12 of 13 totomm -V ;0M0 nLLZZT m _ cy m J a m m p y 0 'V '0 ro p = '� Qc 3 -� 3 r r - 7 0 0 z nm� 8 �1�� C37 o rl �� o o D �° D L N m a m m n v a t� o y a is3 w p � a rn O n v 3 m �c nz 3 3 N a o y AG G C N aN �N5 :L z-� 'D Z uo �(� a > > 7� T cn Z L N Z c 7 m C -4 'G 3 �e U I�If Z 7 V ��/ m 0 .. y ;9 a a mm o '". � 1 y z 3U. n L r"' c( Z y m or m ac Er�^ 3 n y 7 ` GC CS3 0 Da m_ QQr!? x D� N m 'l �p a m V Wo D O L L O z� mD cD m Am r D nOL ��" �+ a ati 0m y Q " a� �• 3 L o fg D� lJ N �' t� N - o m w _4 X,�n to A m g G O a O t �'0 r- 0m3 op i r► w lJ" c m3 +� co 0 - A 6 p �jJ V� �'� W z 0 m �` p 0 L G O A o.m G1 <m m Z70a m m� _ 0n 3 3 o3i °. cn s y D zi t/7tOt = mO � � pAO� C7 G L N�C'i A A 7 a m o- x ° �3 CO \ "p v m cx m y m -0 D 5 v <o v i c r`pr m 7 3 0 a p o rJ O m / �11 L L to m o ' � mmt o trmmA'• mz NAp wE a NOy rND9 o ®R AmDO C6, ti O m3i�<N p a� p ° .tenZa3ID. ° ya o D� D 3 r m tl° n m o Con m OO2mm G 7 (myA 2 Znz m N�LL ; o o z m c { a (0 m m n O � f ~ Do �� O A Z c D rn n 0 D N(D N d L N A v y a m r° UGo n° om a m z co D n Z m 1zF L -1 r >4 N r0 � 'a O D = a N0 n <A r O m mLL � .'V 7 A 7. c` N7 OF r^ to T Qp� V Q 1 v c o H L r o ` ^� 2.o wr c� -c N � D � So A 0 aD , - > C `. ° G G O a_i a n O �'? m p ° W m A O c m mm W m m A °\ �to H i -i O m m m c m m n O a a v n O o' r m n tp z D A �. m 3 z y 0 ma m = m a s D n r mC nm cO M. 9 O Z O 2 O Sn W o nDi y `� 0 g n n � n c -izm< 3 ° m l r � -m -, oU, d m CA , D � � a A Z 0 Z � � m � D R O D DID m J' n • III Jill!1111►1I11lol11111111h11111111!1111111111111 :� m � � a J rlYrsf ..a nr 4 Z `I�I �I I' lr 48 N Raleigh Neuse River Resource Recovery Facility J9 15 O O I I I O z Z I I I D Page 13 of 13