HomeMy WebLinkAboutNC0005088_More Information (Received)_20240923Rogers Energy Complex
573 Duke Power Road
Mooresbom NC 28114
(> DUKE
ENERGY
September 17, 2024 RECEIVED
Sergei Chemikov, PhD. SEP 2 3 20[4
North Carolina Division of Environmental Quality
1617 Mail Service Center
Raleigh, NC 27699-1617 N C D EQ / D W R/ N P D E S
Subject: Duke Energy Carolinas, LLC.
Rogers Energy Complex (Cliffside)
NPDES Permit NC0005088
Chemical Amendment Request to Permit Renewal Application
Dear Dr. Chemikov:
Duke Energy Carolinas, LLC submits this letter to amend our existing NPDES Wastewater
permit application. The amendment is to disclose the use of Hydrex 2252 (Amide Hydrolysate)
and Hydrex 2280 TA (Sulfonated acrylate polymer) for use in the Cooling Towers. Hydrex 2252
is a bio-dispersant which prevents organic deposits and fouling. Hydrex 2280 TA is a particle
dispersant to keep solids suspended to prevent fouling of the heat exchangers. Cooling Tower
Blowdown is processed through the site's Wastewater Treatment System before discharge
through Outfall 005. An updated list of chemicals is attached, as well as the Hydrex 2252 and
Hydrex 2280 TA SDS. Please include this with the relevant permit files.
It is our understanding that with this amendment to the existing permit application, no permit
modification would be necessary, and Duke Energy is authorized to utilize the additives to assure
compliance with NPDES permit limits.
If you have any questions, please contact Mr. Randy Hawkins at (864) 356-8257 or
randv.hawk in s(&.du ke-e nerev.com.
V certify, under penalty of law, that this document and all attachments were prepared under my direction
or supervision in accordance with a system designed to assure that qualif ed personnel properly gather and
evaluate the information submitted. Based on my inquiry of the person or persons who manage the system,
or those persons directly responsible for gathering the information, the information submitted is, to the best
of my knowledge and belief, true, accurate, and complete. / am aware that there are significant penalties
for submitting false information, including the possibility of fines and imprisonment for knowing
violations. "
Sincerely,
Brandon K. Sipe
General Manger III - Rogers Energy Complex
Permit NC0005088 Renewal Amendment Request
September 2024
Attachments:
Form 2C - Section 8 Chemical List
Hydrex 2252 SDS
Hydrex 2280 TA SIDS
Cc:
Randy Hawkins - via email
Steve Hodges - via email
Duke Energy Carolinas, LLC NPDES Permit NC0005088
Rogers Energy Complex (Cliffside) Permit Renewal Amendment
Form 2C — Section 8: Used or Manufactured Toxics - Potential Discharges Not
Covered by Analysis
SUBSTANCE
QUANTITY lbs
SOURCE
Ammonia
829,500
Anhydrous Ammonia Tanks
Benzene
21,231
Gasoline and Diesel Fuel Tanks
Lead
113,883
Batteries
Chlorine
450
150 Pound Cylinders
Ferric Sulfate
11,119
Flocculent used in Water Treatment
Ferric chloride
6,316
Flocculent used in Water Treatment
Zinc
4,068
Anti -corrosion agent
Nickel
2,558
Coating for tubes
Naphthalene
5,211
Gasoline and Diesel Tanks, Oils
Sodium nitrite
513
Corrosion inhibitor
Sodium Hydroxide
41,617
Powerhouse, Storage Tank
Sodium Hypochlorite
15,000
Clarifier, Cooling Towers, FGD WWT
Tote
Sulfuric acid
85,087
Powerhouse Batteries, Storage Tank
Toluene
63,081
Gasoline and Diesel Fuel Tanks, Paint
Calcium hypochlorte
18
Closed loop cooling system
Citric Acid
2,600
Water Treatment, FGD WWT
Hydrochloric Acid
39,180
FGD WWT
Hydrated Lime
49,000
Unit 6 SDA, FGD WWT
Core Shell 71307
4,600
FGD WWT
Nalmet 1689
5,200
FGD WWT
Hydrazine
2,750
Unit 5 Boiler Chemistry
Aluminum Chloride Hydroxide
Sulfate
94,600
FGD WWT
Amide Hydrolysate
4,400
Cooling Towers
Sulfonated acrylate polymer
16,650
Cooling Towers
Permit NC0005088 Renewal Amendment Request
Q VEOLIA
SAFETY DATA SHEET
Product identifier Hydrex 2252
Other means of identification None.
Recommended use
Cooling Water Treatment
Recommended restrictions
INDUSTRIAL USE ONLY.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Supplier
Veolia Water Technologies, Inc
Address
913 Industrial Park Drive
Vandalia, Ohio
45377
Contact Person
Hydrex Product Manager
Telephone
+1-937-890-4075
Fax
+1-937-890-5495
e-mail
hydrex.msds@veolia.com
Global Emergency
+1-760-476-3962 (Code: 333239)
Contact
Physical hazards
Not classified.
Health hazards
Serious eye damage/eye irritation
Environmental hazards
Not classified.
OSHA defined hazards
Not classified.
Nc hazards resulting from
the material as supplied.
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
Category 2
1
Warning
May be harmful in contact with skin. Causes serious eye irritation.
Not applicable.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, If present and
easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention.
Store in accordance with local/regional/national/international regulation.
Dispose of contents/container in accordance with local/regional/national/intemational regulations.
None known.
None.
Mixtures
The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200.
Chemical name Common name and svnonvms CAS number
Amide Hydrolysate Trade Secret 10 - 20
Other components below reportable levels 80 - 90
'Designates that a spec chemical identity and/or percentage of composition has been withheld as a trade secret.
Inhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
Move to fresh air. Call a physician if symptoms develop or persist.
Material name: Hydrex 2252
2223 Version x: 01 Issue date: 06-03-2015 Q VEOLIA 1/7
SDS US
Skin contact
Rinse skin with water/shower. Call a POISON CENTER or doctor/physician if you feel unwell. Get
medical attention if irritation develops and persists.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion
Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell.
Most important
Severe eye Irritation. Symptoms may include stinging, tearing, redness, swelling, and blurted vision.
symptoms/effects, acute and
delayed
Indication of immediate
Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special
Symptoms may be delayed.
treatment needed
General information
If you feel unwell, seek medical advice (show the label where possible). Ensure that medical
personnel are aware of the material(s) Involved, and take precautions to protect themselves. Show
this safety data sheet to the doctor in attendance.
Suitable extinguishing media
5. Fire -fighting measures
Dry chemical, CO2, sand, earth, water spray or regular foam.
Unsuitable extinguishing
Do not use waterjet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from
During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment
Wear suitable protective equipment.
and precautions for
firefighters
Fire fighting
Move containers from fire area if you can do so without risk.
equipment/ instructions
Specific methods
Use standard f refighting procedures and consider the hazards of other involved materials.
General fire hazards
No unusual fire or explosion hazards noted. This product is not flammable.
6. Accidental release measures precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch
emergency procedures damaged containers or spilled material unless wearing appropriate protective clothing. Ensure
adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SOS.
Methods and materials for Following product recovery, flush area with water.
containment and cleaning up
Never return spills to original containers for reuse. For waste disposal, see section 13 of the SDS.
Environmental precautions Do not contaminate water. Avoid discharge Into drains, water courses or onto the ground.
Blinn and stnranF
Precautions for safe handling DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. Avoid contact with eyes. Do not use In areas without adequate
ventilation. Wear appropriate personal protective equipment. Wash thoroughly after handling. Avoid
release to the environment. Observe good industrial hygiene practices. Use care in
handling/storage. Handle an open container with care.
Conditions for safe storage, CAUTION Keep away from heat, sparks and open flame. Store in original lightly closed container.
including any Keep container tightly closed. Keep out of the reach of children. Use care in handling/storage. Store
incompatibilities away from Incompatible materials (see Section 10 of the SDS). Store in accordance with
local/regional/nabonal/international regulation.
Occupational exposure limits No exposure limits noted for ingredient(s).
Biological limit values No biological exposure limits noted for the ingredient(s).
Exposure guidelines No exposure standards allocated.
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should
controls be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other
engineering controls to maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable level. Ensure adequate
ventilation, especially in confined areas. Provide eyewash station. Provide adequate general and
local exhaust ventilation.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear eye/face protection. Wear safety glasses with side shields (or goggles) and a face shield.
Chemical goggles and face shield are recommended. Avoid contact with eyes.
Material name: Hydrex 2252
2223 version #: 01 Issue date: 06-03-2015 0 VEOLIA 2/7
SDS US
Skin protection
Hand protection Use suitable protective gloves if risk of skin contact. Chemical resistant gloves.
Other Wear suitable protective clothing. Chemical resistant gloves. Plastic or rubber gloves, apron and
boots.
Respiratory protection No personal respiratory protective equipment normally required. In case of insufficient ventilation,
wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Avoid contact with eyes. Avoid contact with skin. Always observe good personal hygiene measures,
considerations such as washing after handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties Liquid
Physical state Liquid.
Form Liquid.
Color Dark brown to Off-white
Odor Vinegar-like.
PH 6
Melting point/freezing point 32 OF (0 °C)
Initial boiling point and > 250 °F (> 121.11 °C)
boiling range
Flash point Not available.
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - Not available.
upper (%)
Explosive limit - lower Not available.
(%)
Explosive limit - upper Not available.
(0/a)
Vapor pressure 23.7 mm Hg @ 25 °C
Vapor density 2.25
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octa nol/water)
Auto -ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density 0.85 g/cm3 estimated
Specific gravity 1
r
. Stability and reactivity
Reactivity The product is stable and non -reactive under normal conditions of use, storage and transport,
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Heat, Flames and sparks. Contact with incompatible materials. None under normal conditions.
Incompatible materials Strong oxidizing agents.
Material name: Hydrex 2252
2223 Version #: 01 Issue date: 06-03-2015 0 VEOLIA 3/7
SDS US
Hazardous decomposition No dangerous reaction known under conditions of normal use. No hazardous decomposition
products
products are known.
Toxicological
Information on likely routes of exposure
Inhalation
Not classified.
Skin contact
May be harmful In contact with skin.
Eye contact
Causes serious eye Irritation.
Ingestion
Not classified.
Symptoms related to the
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
physical, chemical and
vision.
toxicological characteristics
Information on toxicological effects
Acute toxicity
May be harmful In contact with skin.
Product Species Test Results
Hydrex 2252
Acute
Dermal
LD50 Rabbit > 2000 mg/kg
Oral
LD50 Rat > 5000 mg/kg
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Classification not possible.
Serious eye damage/eye
Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization
Classification not possible.
Skin sensitization
Classification not possible.
Germ cell mutagenicity
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic. Classification not possible.
Carcinogenicity
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Not classifiable
as to carcinogenicity to humans.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity
Classification not possible.
Specific target organ toxicity
Classification not possible.
- single exposure
Specific target organ toxicity
Classification not possible.
-repeated exposure
Aspiration hazard
Classification not possible.
Further information
This product has no known adverse effect on human health.
Ecological12.
Ecotoxicity
Expected to be harmful to aquatic organisms.
Product
Species Test Results
Hydrex 2252
Aquatic
Crustacea
LC50 Daphnia 10 mg/I, 48 hr
Fish
LC50 Fathead minnow (Pimephales promelas) 25.3 mg/l, 48 hr
Rainbow Trout 71.5 mg/I, 48 hr
* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability, of this product.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Material name: Hydrex 2252
2223 version #: 01 Issue date: 06-03-2015 O VEOLIA 4/7
SDS US
Other adverse effects
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal . .-
Disposal instructions
Contract with a disposal operator licensed by the Law on Disposal and Cleaning. This material and
its container must be disposed of as hazardous waste. Must be Incinerated in a suitable incineration
plant holding a permit delivered by the competent authorities. Do not allow this material to drain
into sewers/water supplies. Dispose of contents/container in accordance with
local/regional/national/international regulations. Dispose of contents/container (in accordance with
related regulations). When your own wastewater treatment plant is not available, collect entire
waste and then charge to a licensed industrial waste management professional with manifests for
industrial waste.
Local disposal regulations
Dispose in accordance with all applicable regulations.
Hazardous waste code
The waste code should be assigned In discussion between the user, the producer and the wastf
disposal company.
Waste from residues /
Dispose of in accordance with local regulations. Empty containers or liners may retain some product
unused products
residues. This material and its container must be disposed of in a safe manner (see: Disposal
instructions).
Contaminated packaging
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not established.
Annex II of MARPOL 73/78
and the IBC Code
3eaulatory informatic
US federal regulations CERCLA/SARA Hazardous Substances - Not applicable.
This product is a "Hazardous Chemical' as defined by the OSHA Hazard Communication Standard,
29 CFR 1910.1200.
One or more components are not listed on TSCA.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Yes
Hazardous chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Ad (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
dal name: Hvdrex 2252
2223 Version !: 01 Issue date: 06-03-2015
SIDS US
Q VEOLIA 5/7
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth
defects or other reproductive harm.
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section
11100)
Not listed.
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right -to -Know Act
Not listed.
US. Pennsylvania Worker and Community Right -to -Know Law
Not listed.
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any
chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region
Inventory name
On inventory (yes/no)*
Australia
Australian Inventory of Chemical Substances (AICS)
No
Canada
Domestic Substances List (DSL)
No
Canada
Non -Domestic Substances List (NDSL)
No
China
Inventory of Existing Chemical Substances in China (IECSC)
No
Europe
European Inventory of Existing Commercial Chemical Substances
No
(EINECS)
Europe
European List of Notified Chemical Substances (ELINCS)
No
Japan
Inventory of Existing and New Chemical Substances (ENCS)
No
Korea
Existing Chemicals Ust (ECL)
No
New Zealand
New Zealand Inventory
No
Philippines
Philippine Inventory of Chemicals and Chemical Substances
No
(PICCS)
United States & Puerto Rico
Toxic Substances Control Act (TSCA) Inventory
No
*A "Yes" Indicates that all components of this product comply with the Inventory requirements administered by the governing country(s)
A "No" Indicates that one or more components of the product are not listed or exempt from listing on the Inventory administered by the governing
country(s).
16. Other
information, including date of preparation or last revision
Issue date
06-03-2015
Version #
01
Further information
HMIS@ is a registered trade and service mark of the NPCA.
NFPA ratings
Health: 2
Flammability: 0
Instability: 0
N FPA ratings
0
Material name: Hydra 2252
2223 Version #: 01 Issue date: 06-03-2015
QVEOLIA 6/7
Firb3rFi
References ACGIH
ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices
EPA: AQUIRE database
HSDn - Hazardous Substances Data Bank
IARC Monographs. Overall Evaluation of Carcinogenicity
National Toxicology Program (NTP) Report on Carcinogens
NLM: Hazardous Substances Data Base
US. IARC Monographs on Occupational Exposures to Chemical Agents
Korea. Toxic Chemical Control Law (TCCL), Existing Chemicals Inventory (KECI)
Korea. Toxic Chemical Control Law (TCCL), pre-1997 List
Korea. Toxic Chemicals (TCCL Article 10)
Korea. Toxic Release Inventory (TRI) Chemicals (TCCL Article 14)
Taiwan. Dangerous Materials (Rules on Hazard Communication of Dangerous Materials and Toxic
Materials)
Taiwan. Industrial Precursor Chemicals (Categories and Regulations Governing Inspection anc
Declaration of Industrial Precursor Chemicals, MOEA Decree No. 87, as amended)
Taiwan. OELs. (Standards on Workplace Atmosphere of Dangerous and Hazardous Materials;
Taiwan. Toxic Chemical Substances (TCS) (Ust of Toxic Chemical Substances announced by the
Environmental Protection Administration)
Taiwan. Toxic Materials (Rules on Hazard Communication of Dangerous Materials and Toxic
Materials)
Japan Society for Occupational Health, Recommendation of Occupational Exposure Limits
]IS Z 7250: 2005 Safety data sheet for chemical products -Part 1:Content and order of sections
JCIA GHS Guideline, October 2008
Disclaimer Veolia Water Technologies is not able to anticipate all conditions under which this information and
its product, or the products of other manufacturers in combination with Its product, may be used.
It is the users responsibility to ensure safe conditions for handling, storage and disposal of the
product, and to assume liability for loss, injury, damage or expense due to Improper use and or non
respect of Veolia Water Technologies' requirement.
Revision Information Product and Company Identification: Alternate Trade Names
Material name: Hydrex 2252
2223 version #: 01 Issue date: 06-03-2015 O VEOLIA 7/7
SDS US
SAFETY DATA SHEET
Q VEOLIA
Product identifier
Hydrex 2280
Other means of identification
None.
Recommended use
Cooling Water Treatment
Recommended restrictions
PROFESSIONAL USE ONLY
Manufacturer/Importer/Supplier/Distributor
information
Manufacturer
Supplier
Address
Contact Person
Telephone
Fax
e-mail
Global Emergency
Contact
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Hazard symbol
Veolia Water Technologies, Inc
913 Industrial Park Drive
Vandalia, Ohio
45377
Hydrex Product Manager
+1-937-890-4075
+1-937-890-5495
hydrex.msds@veolia.com
+1-760-476-3962 (Code: 333239)
Not classified.
Not classified.
Not classified.
Not classified.
None.
Signal word None.
Hazard statement The mixture does not meet the criteria for classification.
Precautionary statement
Prevention
Avoid forming spray/aerosol mists. Observe good industrial hygiene practices.
Response
Wash hands after handling.
Storage
Store In cool place. Protect from sunlight Store away from incompatible materials.
Disposal
Dispose of contents/container to an appropriate treatment and disposal facility in accordance with
applicable laws and regulations, and product characteristics at time of disposal.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.
information
Mixtures
Chemical name Common name and synonyms CAS number %
Sulfonated acrylate polymer Mixture 10 - 20
Other components below reportable levels 90 - 100
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
Inhalation
Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact
Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact
Rinse with water. Get medical attention if irritation develops and persists.
Ingestion
Rinse mouth. Get medical attention if symptoms occur.
Most important
Direct contact with eyes may cause temporary irritation.
symptoms/effects, acute and
delayed
Material name: Hydrex 2280
4431 Version #: 01 Issue date: 06-23-2015 Q VEOLIA 1/6
SDS US
Indication of immediate Treat symptomatically.
medical attention and special
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
5. Fire -fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Not available.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be wom in case of fire.
and precautions for
firefighters
Fire fighting Move containers from fire area if you can do so without risk.
equipment/ instructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.
Personal precautions, Keep unnecessary personnel away. For personal protection, see section 8 of the SDS.
protective equipment and
emergency procedures
Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
containment and cleaning up possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re -use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.
Precautions for safe handling Avoid forming spray/aerosol mists. Observe good Industrial hygiene practices.
Conditions for safe storage, Store In original tightly closed container. Store away from incompatible materials (see Section 10 of
including any the SDS).
incompatibilities
Occupational exposure limits No exposure limits noted for ingredient(s).
Biological limit values
No biological exposure limits noted for the ingredient(s).
Appropriate engineering
Good general ventilation (typically 30 air changes per hour) should be used. Ventilation rates should
controls
be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other
engineering controls to maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures,
such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles) and a face shield. Chemical goggles and face
shield are recommended.
Skin protection
Hand protection Chemical resistant gloves.
Other Wear suitable protective clothing. Chemical resistant gloves.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Avoid forming spray/aerosol
mists.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
Jim
Material name: Hydrex 2280
4431 Version #: 01 Issue date: 06-23-2015 O VEOLIA 2/6
SDS US
General hygiene Always observe good personal hygiene measures, such as washing after handling the material and
considerations before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to
remove contaminants.
Appearance
Clear.
Physical state
Liquid.
Form
Aqueous solution.
Color
Pale yellow to Amber
Odor
Slight Aromatic.
pH
3-4
Melting point/freezing point
< 32 OF (< 0 °C)
Initial boiling point and
> 212 OF (> 100 °C)
boiling range
Flash point
Not available.
Evaporation rate
Not available.
Flammability (solid, gas)
Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower
Not available.
Flammability limit -
Not available.
upper (%)
Explosive limit - lower
Not available.
(°/a)
Explosive limit - upper
Not available.
Vapor pressure
Not available.
Vapor density
Not available.
Solubility(ies)
Solubility (water)
100 %
Partition coefficient
Not available.
(n-octanol/water)
Auto -ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
Not available.
Other information
Density
> 1200.00 kg/m3
Specific gravity
1.12 - 1.18
Reactivity
The product is stable and non -reactive under normal conditions of use, storage and transport.
Chemical stability
Material is stable under normal conditions.
Possibility of hazardous
No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid
Contact with incompatible materials.
Incompatible materials
Strong oxidizing agents,
Hazardous decomposition
At thermal decomposition temperatures, carbon monoxide and carbon dioxide. Nitrogen oxides
products
(NOx). Sulfur oxides.
Information on likely routes of exposure
Inhalation
No adverse effects due to inhalation are expected.
Skin contact
No adverse effects due to skin contact are expected.
Eye contact
Direct contact with eyes may cause temporary irritation.
Ingestion
Expected to be a low ingestion hazard.
Symptoms related to the
Direct contact with eyes may cause temporary irritation.
physical, chemical and
toxicological characteristics
Material name: Hydrex 2280
4431 version B: 01 Issue date: 06-23-2015 O VEOLIA 3/6
SDS US
Information on toxicological effects
Acute toxicity
Product
Hydrex 2280
Acute
Dermal
LD50
Species
Rabbit
Test Results
>= 6600 mg/kg Calculated
Oral
LD50 Rat >= 10000 mg/kg Calculated
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization
Not a respiratory sensitizer.
Skin sensitization
This product Is not expected to cause skin sensitization.
Germ cell mutagenicity
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
US. OSHA Specifically Regulated
Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity
This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity
Not classified.
- single exposure
Specific target organ toxicity
Not classified.
-repeated exposure
Aspiration hazard
Not an aspiration hazard.
Ecotoxicity
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Product
Species Test Results
Hydrex 2280
Aquatic
Acute
Crustacea
EC50 Daphnia >= 500 ni 48 hours Calculated
Fish
LC50 Fish >= 500 mg/I, 96 hours Calculated
* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product
Bioaccumulative potential No data available.
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component
Disposal instructions
Collect and reclaim or dispose in sealed containers at licensed waste disposal site.
Local disposal regulations
Dispose in accordance with all applicable regulations.
Hazardous waste code
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues /
Dispose of in accordance with local regulations. Empty containers or liners may retain some product
unused products
residues. This material and its container must be disposed of in a safe manner (see: Disposal
instructions).
Contaminated packaging
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
Material name: Hydrex 2280
4431 Verslon x: 01 Issue date:
06-23-2015 Q VEOLIA 4/6
SD5 US
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not established.
Annex II of MARPOL 73/78
and the IBC Code
15. Regulatory information
US federal regulations One or more components are not listed on TSCA.
This product is not known to be a "Hazardous Chemical' as defined by the OSHA Hazarc
Communication Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 No
Hazardous chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right -to -Know Act
Not listed.
U5. Pennsylvania Worker and Community Right -to -Know Law
Not listed.
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any
chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On Inventory (yes/no)•
Australia Australian Inventory of Chemical Substances (AILS) No
Canada Domestic Substances List (DSL) Yes
Material name: Hydrex 2280
4431 version #: 01 Issue date: 06-23-2015 Q VEOLIA 5/6
SDS US
Country(s) or region Inventory name
Canada
Non -Domestic Substances List (NDSL)
China
Inventory of Existing Chemical Substances in China (IECSC)
Europe
European Inventory of Existing Commercial Chemical Substances
(EINECS)
Europe
European List of Notified Chemical Substances (ELINCS)
Japan
Inventory of Existing and New Chemical substances (ENCS)
Korea
Existing Chemicals List (ECL)
New Zealand
New Zealand Inventory
Philippines
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
United States & Puerto Rico
Toxic Substances Control Act (TSCA) Inventory
On inventory (yes/no)*
No
Yes
No
No
No
Yes
Yes
Yes
im
xA "Yes" indicates that all components of this product comply with the Inventory requirements administered by the governing country(s)
A "No" Indicates that one or more components of the product are not listed or exempt from listing on the Inventory administered by the governing
country(s).
I 1b. utner intormation, including date of preparation or last revision
Issue date 06-23-2015
Version #
NFPA ratings
NFPA ratings
01
Health: 1
Flammability: 0
Instability: 0
u
Disclaimer Veolia Water Technologies is not able to anticipate all conditions under which this information and
its product, or the products of other manufacturers in combination with its product, may be used.
It is the user's responsibility to ensure safe conditions for handling, storage and disposal of the
product, and to assume liability for loss, injury, damage or expense due to improper use and or non
respect of Veolia Water Technologies' requirement.
Material name: Hydrex 2280
4431 version #: 01 Issue date: 06-23-2015 Q VEOLIA 6/6
SDS Us