WQ0005910_Monitoring - 07-2024_20240827 (3)

Monitoring Report Submittal
...................................................
Permit Number#* WQ0005910
Name of Facility:* Avoca LLC
Month: * July
Report Information
Type *
NDMR, NDAR-1, NDAR-2, NDMLR
Confirmation Email Address: *
Name of Submitter: *
Signature:
Date of submittal:
Initial Review
Year:* 2024
Upload Document*
Avoca LLC July 2024 NDAR & NDMR.pdf 1.79MB
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59).
[e-mail]
Brian M. Conner
Reviewer: Wanda.Gerald
8/27/2024
This will be filled in automatically

Is the project number correct?* WQ0005910
Is the monitoring report accepted?* Yes No
Regional Office* Washington
Reviewer: _anonymous
Review Date: 8/28/2024

FORM NDMR 03-12 NON -DISCHARGE MONITORING REPORT (NDMR) Page k of 2.
Permit No.: WQ0005910
Facility Name, Avoca - Merry Hill WWTP
County Serbe
Month: July
Year: 2024
PPI 001-7
Flow Measuring Point- ❑ Influent 2 Effluent ❑ No Flow generated
Parameter Monitoring Point: ❑ Influent CO Effluent ❑ Groundwater Lowering ❑ Surface water
Parameter Code ol
50050
00310
00916
00940
00927
00610 1
00625
00620
00600
00400
00665
00931
00929
70300
00536
F 0d
LL
o
?
m
C
ao
F
Yz
z
z
CL
o
o
aa
M
to
o 2: ;o
y-
u, v7
�5p 0
in
24-hr
hrs
GPD
mg/L
mg/L
mg/L
mg/L
mg1L
mg/L
mg1L
mg/L
su
mg/L
Ratio
mgJL
mg1L
mg/L
1
0800
8
31,082
625
2
0730
8
42,973
637
3
0745
8
27,032
643
4
0745
4
23,820
697
5
0745
8
22,145
667
6
07 15
2
1 17,816
7
07 00
2
25,540
8
0730
8
30,010
687
9
0715
8
26,004
6.35
101
07 30
8
29,382
644
111
0730
8
27,252
622
12
0745
8
21,948
665
13
0815
2
11,374
14
0715
2
4,695
15
0745
8
5,083
662
16
0745
8
11,784
668
171
0700
8
5,749
674
18
0700
8
43,228
671
19
0800
8
2,447
691
20
0800
2
17,943
21
0620
2
28,397
22
0745
8
16,198
656
23
0815
8
19,951
759
241
0745
8
23,540
77
25
0745
8
19,831
766
26
0800
8
12,906
701
27
07 40
2
15,990
28
0715
2
14,317
29
0745
8
12,191
1
1
688
301
0730
10
8,819
4500
5,65
115
193
<0 02
11.87
<0 02
11.9
669
2.98
0 638
218
1700
230
311
0915
10
8,338
679
Average:
19,606
4,50000
5.65
115 00
1 93
000
11.87
000
11.90
298
064
21800
1,70000
23000
Daily Maximum:
43,228
4,50000
565
115 00
1.93
002
1187
002
11.90
#REFl
2.98
064
21800
1,70000
23000
Daily Minimum:
2,447
1 4,500 00
5.65
11500
1.93
002
11.87
002
11.90
#REFl
298
1 064
218,00
1,700 00
230.00
Sampling Type:
Recorder
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Calculated
Grab
Grab
Grab
Monthly Avg. Limit:
50,000
Daily Limit -
Sample Frequency:
Continuous
Monthly
3 X Year
3 X Year
3 X Year
Monthly
Monthly
Monthly
Monthly
5 X Week
Monthly
3 X Year
3 X Year
3 X Year
Monthly

FORM: NDMR 03-12
NON -DISCHARGE MONITORING REPORT (NDMR)
Page 2 of 2-
Sampling Person(s) Certified Laboratories
Name: Brian Conner Name: Waypoint Analytical
Name: Name:
Does all monitoring data and sampling frequencies meet the requirements in Attachment A of your permit? El compliant ❑ Nan -compliant
If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-ccmpliance and describe the corrective
action(s) taKen. Attacn aaattlonal sneeis It
Operator in Responsible Charge (ORC) Certification
Permittee Certification
ORC: Briars M. Conner
Permittee: Avoca, LLC
Certification No.: 993283
Signing Official: Sam Tynch
Grade: WW2 Phone Number: 252-482-2133
Signing Officials Title: Plant Manager
Has the ORC changed since the previous NDMR? ❑ Yes p No
Phone Number: 252-482-2133 Permit Expiration: 10/31 /2024
6
Signature Date
Signature Date
By this signature, I certify that this report is accurrate and complete to the best of my knowledge.
I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that all qualified personnel properly gathered and evaluated the information
submitted. Based on my ingwiry of the person or persons who manage the system, or those persons directly responsible for
gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate. and complete. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for
knowing violations.
Mail Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, forth Carolina 27699-1617

FORM NEAR-1 05-16 NON -DISCHARGE APPLICATION REPORT (NDARTfl page 1 of
ll000
Av._ - Merry Hill WWTPAnnual
Did irrigation occur
2 YES El NO
Bermuda Grass
Bermuda Grass
Hourly Rate (in)-
Hourly Rate (in).
Rate (in):
��
// ■/
Field Irrigated?
�
�
r
Monthly Loading,
VOMM. I
W�ZIMMMOMIW/'

FORM NDAR-1 05-16 NOWDISCHARGE APPLICATION REPORT (NQAR-1) Page 2- of
Permit No WQ000591 0
Facility Name, Avoca - Merry Hill VVVVTP
Month: July
i • irrigation occurArea
at this facility?■�
p YES NO
Cacresy
.,
..Cover
C...
..
Annual Rate (in):,
Annual Rate (in)
Annual Rate (in-Y
logo
®
��M
MM
...
%!/!!/®%!////%,.0%/!!///
%///,ON/.I
////
%/f///0"
�'%///f/
N 011

FORM: NDAR-1 05-16 NON -DISCHARGE APPLICATION REPORT (NDAR-1) Page --ZL cf I
Did the application rates exceed the limits in Attachment B of your permit?
Were adequate measures taken to prevent effluent ponding in or runoff from the sites?
Was a suitable vegetative cover maintained on all sites as specified in your permit?
Were all setbacks listed in your permit maintained for every application to each permitted site?
Were all freeboards maintained in accordance with the specified freeboard heights in your permit?
❑� Compliant ❑ Non -Compliant
0 Compliant ❑ Non -Compliant
❑� Compliant ❑ Non -Compliant
21 Compliant ❑ Non -Compliant
0 Compliant ❑ Non -Compliant
If the facifty is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-compfance and describe the corrective
action(s) taken. Attach additional sheets if necessary.
Operator in Responsible Charge (ORC) Certification
Permittee Certification
ORC: Brian M. Conner
Permittee:
Avoca, LLC
Certification No.: 991857, 993283
Signing Official: Sam Tynch
Grade: SI 1 WW2 Phone Number: 252-482-2133
Signing Official's Title: Plant Manager
Has the ORC changed since the previous NDAR-1? ❑ Yes p No
Phone Number: 252-482-2133 Permit Exp.: 10/31/24
v
-
6
Signature Date
Sic}sature Date
By this signature, I certify that this report is accurrate and complete to the best of my knowledge.
I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance
with a system designed to assure that all qualified personnel property gathered and evaluated the information submitted. Based on my
Inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the infermatior, the
information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant
penalties for submitting false information, including the possibility of fees and imprlsonmem for knowing violatons.
Mail Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617

WayPAoint
NALYTICAL
8/19/2024
Avoca, LLC
Brian Conner
P.O. Box 129
Merry Hill, NC, 27957
Ref: Analytical Testing
Lab Report Number: 24-213-0603
Client Project Description: 132 - AVOCA, LLC
Effluent & Wells
114 Oakmont Drive, Greenville, NC 27858
Main 252.756.6208 ° Fax [phone]
www.waypointanalytical.com
Dear Brian Conner:
Waypoint Analytical Carolina (Greenville) received sample(s) on 7/31/2024 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method, Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021).
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
�9 � V�
Ron Boquist
General Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
NC DHHS DW Cert44 37715
NC DEQ WW Cert# 10
NC DEQ W W Satellite Cert4t 610
Page 1 of 8

(2)
114 Oakmont Drive, Greenville, NC 27858
Waypoint, Main 252.756.6208 ° Fax [phone]
ANALYTICAL www.waypointanalyrical.com
Sample Summary Table
Report Number: 24-213-0603
Client project Description: 132 - AVOCA, LLC
Effluent & Wells
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
72686
Effluent
Aqueous
07/30/2024
14:00
07/31/2024
72686
Effluent
Aqueous
07/30/2024
14:00
07/31/2024
300.0
WP
CNC
72687
Well#5
Aqueous
07/30/2024
14:35
07/31/2024
72687
Well
#5
Aqueous
07/30/2024
14:35
07/31/2024
300.0
WP
CNC
72688
Well
#7
Aqueous
07/30/2024
15A5
07/31/2024
72688
Well
#7
Aqueous
07/30/2024
15:45
07/31/2024
300.0
WP
CNC
72689
Well
#8
Aqueous
07/30/2024
15:15
07/31/2024
72689
Well
#8
Aqueous
07/30/2024
15:15
07/31/2024
300.0
WP
CNC
72690
Well
#9
Aqueous
07/30/2024
14:55
07/31/2024
72690
Well
#9
Aqueous
07/30/2024
14:55
07/31/2024
300.0
WP
CNC
72691
Well
#10
Aqueous
07/30/2024
15:30
07/31/2024
72691
Well
#10
Aqueous
07/30/2024
15:30
07/31/2024
300.0
WP
CNC
72692
Well
#11
Aqueous
07/30/2024
14:20
07/31/2024
72692
Well
#11
Aqueous
07/30/2024
14:20
07/31/2024
300.0
WP
CNC
WP CNC - Charlotte, NC: Waypoint Analytical - Charlotte, Charlotte, NC
Page 2 of e

0 0 Oakmont Drive, Greenville, NC 27858
Waypoint. 114 Maid 252.756,62081 Fax [phone]
ANALYTICAL www.waypointanalytical.com
08604
Avoca, LLC
Brian Conner Project 132 - AVOCA, LLC
P.O. Box 129 Information : Effluent & Wells
Merry Hill , NC 27957
Report Number : 24-213-0603
REPORT OF ANALYSIS
Report Date : 08/19/2024
Received : 07/31/2024
Lab No : 72686
Sample ID : Effluent
Matrix; Aqueous
Sampled: 7/30/2024 14:00
Test
ReSURS
Units
MQL
DF Date / Time
By
Analytical
Analyzed
Method
Nitrite (NO2-N)
0.02
mg/L
0.02
1 07/31/24 16:18
K)D
353.2
Nitrate (NO3-N)
<0.020
mg/L
0.020
1 07/31/24 16:18
3RF
EPA-3S12
Ammonia Nitrogen
<0.02
mg/L
0.02
1 08/06/24 16:29
HMM
350.1
Biochemical Oxygen Demand (5-day)
4500
mg/L
2000
1 07/31/24 09:18
AAM
5210E-2016
Bromide
74.8
rng/L
0.500
5 08/11/24 15:36
NDL
300.0
Chloride
115
mg/L
5.00
1 08/09/24 09:30
BNC
4500-CI-B
Nitrate+Nitrite-N
0.03
mg/L
0.02
1 08/01/2412:07
353.2
Total Dissolved Solids
1700
mg/L
50
1 08/06/24 10:38
HMV
254OC-2015
Total Suspended Solids
230
mg/L
62.5
1 08/01/24 10:00
BLV
254OD-2015
Total Kjeldahl Nitrogen
11.87
mg/L
2.00
10 08/08/24 15:46
HMM
EPA-351.2
Total Nitrogen
11.9
mg/L
0,020
1 08/01/24 12:07
CALCULATION
Phosphorus
2.98
mg/L
0.02
1 08/08/2414:19
HMM
365.4
Calcium
5.65
mg/L
0.500
1 08/05/2417:48
MTM
EPA-200.7
Magnesium
1.93
mg/L
0.500
1 08/05/2417:48
MTM
EPA-200.7
Sodium
218
mg/L
2.50
1 08/OS/2417:48
MTM
EPA-200.7
Sodium Absorption Ratio
0.638
Ratio
0.100
1 08/05/24 17:48
CALCULATION
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
L Limit Exceeded
Page 3 of 8

Waypointo
ANALYTICAL
08604
Avoca, LLC
114 Oakmont Drive, Greenville, NC 27858
Main 252.756,6208 ° Fax [phone]
www.waypointatialytical.com
Brian Conner Project 132 - AVOCA, LLC
P.O. Box 129 Information : Effluent & Wells
Merry Hill , NC 27957
Report Date ; 08/19/2024
Report Number : 24-213-0603
REPORT OF ANAL MSIS
Received : 07/31/2024
Lab No : 72687
Matrix: Aqueous
Sample ID : Well #5
Sampled: 7/30/2024 14:35
Test
Results
Units
MQL
DF Date / Time By Analytical
Analyzed Method
Nitrate (NO3-N)
0,030
mg/L
0.020
1 07/31/24 16:26 7RF EPA-353.2
Ammonia Nitrogen
0,06
mg/L
0.02
1 08/06/24 16:06 HMM 350.1
Bromide
10.9
mg/L
0.100
1 08/14/2413:57 NDL 300.0
Chloride
32.0
mg/L
2.00
1 08/09/24 09:30 BNC 4500-CI-B
Total Dissolved Solids
550
mg/L
25
1 08/06/24 10:38 HMV 254OC-2015
Phosphorus
<0.02
mg/L
0.02
1 08/08/2414:21 HMM 365.4
TOC
2.31
mg/L
1.00
1 08/12/2412:22 BLV 531OC-2014
Calcium
32.1
mg/L
0.500
1 08/05/2417:52 MTM EPA-200.7
lab No : 72688
Matrix: Aqueous
Sample ID : Well #7
Sampled: 7/30/2024 15:45
Test
Results
Units
MQL
DF Dale / Time By Analytical
Analyzed Method
Nitrate (NO3-N)
0.760
mg/L
0.Og0
1 07/31/24 16:25 3RF EPA-353.2
Ammonia Nitrogen
<0.02
mg/L
0.02
1 08/06/24 13:57 HMM 350.1
Bromide
8.27
mg/L
0.100
1 08/14/2414:09 NDL 300.0
Chloride
23.0
mg/L
2.00
1 08/09/24 09:30 BNC 4500-CI-B
Total Dissolved Solids
180
mg/L
13
1 08/06/24 10:38 HMV 254OC-2015
Phosphorus
<0.02
mg/L
0.02
1 08/08/2410:53 HMM 365.4
TOC
2.73
mg1L
1.00
1 08/12/2412:22 BLV 531OC-2014
Calcium
10.6
m9/L
0.500
1 08/05/2417:57 MTM EPA-200.7
Qualifiers/ DF Dilution Factor L Limit Exceeded
Definitions MQL Method Quantitation Limit
Page 4 of 8

Waypointo
ANALYTICAL
08604
Avoca, LLC
114 Oakmont Drive, Greenville, NC 27858
Main 252.756.62081 Fax 252,756.0633
www.waypointanalytical.com
Brian Conner Project 132 - AVOCA, LLC
Ro. Box 129 Information : Effluent & Wells
Merry Hill , NC 27957
Report Date : 08/19/2024
Report Number : 24-213-0603
REPORT OFANAL YSIS
Received : 07/31/2024
Lab No : 72689
Matrix: Aqueous
Sample ID : Well #8
Sampled: 7/30/2024 15:15
Test
Results
Units
MCIL
DF Date/Time By Analytical
Analyzed Method
Nitrate (NO3-N)
0.110
rng/L
0.040
1 07/31/24 16:23 3RF EPA-353.2
Ammonia Nitrogen
2.46
mg/L
0.02
1 08/06/24 13:59 HMM 350.1
Bromide
5.82
mg/L
0.100
1 08/14/2414:22 NDL 300.0
Chloride
12.5
mg/L
1.00
1 08/09/24 09:30 BNC 4500-CI-B
Total Dissolved Solids
570
mg/L
25
1 08/06/24 10:38 HMV 2540C-2015
Phosphorus
6.06
mg/L
0.02
1 08/08/2410:55 HMM 365.4
TOC
1.40
mg/L
1.00
1 0811212112:22 BLV 531OC-2014
Calcium
9,32
mg/L
0.500
1 OB/05/2418:01 MTM EPA-200.7
Lab No: 72690
Matrix: Aqueous
Sample ID : Well #9
Sampled: 7/30/2024 14:55
Test
Results
Units
MOL
DF Date 1 Time By Analytical
Analyzed Method
Nitrate (NO3-N)
3.07
mg1L
0.080
1 07/31/24 16:22 7RF EPA-353.2
Ammonia Nitrogen
<0,02
mg/L
0.02
1 08/06/24 13:03 HMM 3SO.1
Bromide
<0.100
mg/L
0.100
1 08/14/2414.34 NDL 300.0
Chloride
27.5
mg1L
1.00
1 08/09/24 09:30 BNC 4500-Cl-B
Total Dissolved Solids
270
mg/L
25
1 08/06/24 10:38 HMV 2540C-2015
Phosphorus
<0.02
mg/L
0.02
1 08/08/24 14:16 HMM 365.4
TOC
<1.00
m9/L
1.00
1 08/12/2412:22 BLV 531OC-2014
Calcium
46.6
mg/L
0.500
1 08/05/2418:05 MTM EPA-200.7
Qualifiers/ DF Dilution Factor
L
Limit Exceeded
Definitions MQL Method Quantitation
Limit
Page 5 of 8

0 • 114 Oakmont Drive, Greenville, INC 27858
Waypoint.Main 252.756.6208 ° Fax [phone]
ANALYTICAL www.waypointanalytical.com
08604
Avoca, LLC
Brian Conner Project 132 - AVOCA, LLC
P.O. Box 129 Information : Effluent & Wells
Merry Hill , NC 27957
Report Date ; 08/19/2024
Report Number : 24-213-0603 REPOR T OFANAL YSIS Received : 07/31/2024
Lab No: 72691
Matrix: Aqueous
Sample ID : Well #10
Sampled: 7/30/2024
15:30
Test
Results
Units
MQL
DF Date / Time By
Analytical
Analyzed
Method
Nitrate (NO3-N)
9.31
mg/L
0.400
1 07/31/24 16:20 JRF
EPA-353.2
Ammonia Nitrogen
<0.02
mg/L
0.02
1 08/06/24 16:21 HMM
350.1
Bromide
<0.100
mg/L
0.100
1 08/14/24 14:46 NDL
300.0
Chloride
71.0
mg/L
1.00
1 08/09/24 09:30 BNC
4500-CI-B
Total Dissolved Solids
380
mg/L
25
1 08/06/24 10:38 HMV
254OC-2015
Phosphorus
0.05
mg/L
0.02
1 08/08/2414:37 HMM
365.4
TOC
1.26
mg/L
1.00
1 08/12/2412:22 BLV
5310G2014
Calcium
26.6
mg/L
0.500
1 08/05/2418:09 MTM
EPA-200.7
Lab No: 72692
Matrix: Aqueous
Sample ID: Well #11
Sampled: 7/30/2024
14:20
Test
Results
Units
MQL
DF Date 1 Time By
Analytical
Analyzed
Method
Nitrate (NO3-N)
0.080
mg/L
0.040
1 07/31/24 16:14 JRF
EPA-353.2
Ammonia Nitrogen
7.81
mg/L
0.02
1 08/06/24 16:27 HMM
350.1
Bromide
9.66
mg/L
0.100
1 08/1412414:59 NDL
300.0
Chloride
27.0
mg/L
2.00
1 08/09/24 09:30 BNC
45MCI-B
Total Dissolved Solids
1100
mg/L
25
1 08/06/24 10:38 HMV
2540C-2015
Phosphorus
0.54
mg/L
0.02
1 08/08/24 14:44 HMM
365.4
TOC
9.57
mg/L
1.00
1 08/12/2412:22 BLV
531OC-2014
Calcum
27.0
mg/L
0.500
1 08/05/2418:13 MTM
EPA-200.7
Qualifiers/ DF Dilution Factor L Limit Exceeded
Definitions MQL Method Quantitation Limit
Page 6 of 8

(2)
Waypoint
ANALYTICAL
114 Oakmont Drive, Greenville, NC 27858
Main 252.756.6208 ° Fax [phone]
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 08604
Customer Name: Avoca, LLC
Report Number: 24-213-0603
Shipping Method
0 Fed Ex 0 US Postal # Lab
0 UPS 0 Client 0 Courier
Other:
Thermometer ID:
11.5c oakton
Shipping container/cooler uncompromised?
Yes
0 No
Number of coolers/boxes received
�1
Custody seals intact on shipping container/cooler?
0 Yes
0 No
0 Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
0 Yes
0 No
COC agrees with sample label(s)?
Yes
0 No
COC properly completed
Yes
0 No
Samples in proper containers?
Yes
0 No
Sample containers intact?
Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
Yes
0 No
0 Not Present
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
Yes
0 No
0 NIA
Water - VOA vials free of headspace
0 Yes
0 No
# NIA
Trip Blanks received with VOAs
0 Yes
0 No
NIA
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
NIA
High concentration container (48 hr) F Low concentration EnCore samplers (48 hr)
High concentration pre -weighed (methanol -14 d) [_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
Comments:
0 Yes 0 No
Signature: I inter Foreman Date & Time: ,07/31/2024 1216:20
Page 7 of 8

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Page 8 of 8